1 1 經濟部中央標準局負工消費合作社印裝 320600 a7 B7__ 五、發明説明（1 ) 〔有鼷發明之技術領域〕 本發明係有團一種淸挿棋具用之樹脂组成物錠劑，是 針對Μ硬化性樹脂成形材料成形時，去除棋具表面污垢者 ，不但有良好之棋具淸掃效果，並具有緻密不易變形之特 性。 〔技術背景〕 如環氧樹脂等硬化性樹脂，笛利用在積髅霄路等彌封 成形物之成形時，長時間連繙成形後* 一旦楔具內部表面 受到污染，運如此繼纘成形時，常曹發生污染彌封成形物 表面，或使彌封成形物附著於楔具上，而無法《續進行成 形作業之情況。因此棋具須要定期淸掃，而有每當成形材 料射出成形數百次時，即醮Μ清掃棋具用樹脂射出成形數 次，依此比例棋具之淸拥的提案。 舉例來說在特公眧52-788¾公報中，曾提出「一種Μ 氨基条樹脂為主匾材料進行成形，俥淸掃以硬化性樹脂成 形材料（但氨基糸樹脂成形材料除外）成形時，經污染之棋 具表面的方法，並提及一棰淸挿棋具用之樹脂組成物，係 由氨基条樹脂、有機質機材/或者由無機質基材、離型薄 所構成。再者，在特公昭64-10162號公報中，也曾提及一 棰Μ氨基条樹脂與酚条樹酷之共缩合樹脂與新莫氏硬度6 〜15之礦物性粉體所構成之淸禰棋具用樹脂组成物。 通常如環氧樹脂等硬化性樹脂，當利用在稹醱電路等 彌封成形物之成形時，先將彌封用硬化性樹脂予備成形為 錠片形狀，再隨將該錠劑予熱後，插入材料室內，經轉移 本紙張尺度適用中國國家揉準（CNS ) Α4洗格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) .裝. 訂 經濟部中央揉準局属工消费合作社印装 A7 B7_五、發明説明（2 ) 一成形方式所成形者。淸掃棋具用樹脂組成物《由於適用 於彌封用硬化性樹脂成形過程之同樣的成形條件，通常如 同彌封用環氧樹脂一般，經轉移成形方式進行成形，且大 多使用舆成形材料同一規格之錠劑形狀，將錠劑先行予熱 軟化，然後進行成形遇程，當淸掃棋具用樹脂组成物充《 棋具全體内部，一旦硬化時將棋具表面污垢酴取出，俥Μ 淸掃棋具表面。 轉移成形方式，有板式充填鏟棋與雙段式壓簿棋兩類 。板式充填鑄棋，即針對1傾»型，使用一傾比較大型的 樹脂錠片，通常採用使棋具内澆道等速到最狹小，但一方 使棋具之成形品室數逹到最大限的設計，以1値材料室為 中心，在最短距離内配置數十個Μ至數百傷成形品室，呈 分枝狀的構造。雙段式Ε鑄棋，即每當一個補肋油S晒筒 裝置，限定少數幾鵪成形品室，澆道使之最狹小，且同時 具備多數值油壓《筒裝置，酋小形錠片自動在各晒简装置 同時固定後，在材料室内予熱進行轉移一成形的方式。 伴隨著IC· LSI等高集積化、薄型化、表面實裝 化以及成形品多樣化之演進，因此針對各種成形品，痛要 使用棰種大小規格之錠片，淸播棋具用樹脂组成物也須相 對應，如同彌封用環氧樹脂錠爾有種種形狀錠片之需求。 舉例來說，採取轉移一成形之板式《充縳模方式中* 通常使用數十〜數百成形品之大型棋具時，傅统形態上提 供之錠劑直徑，約30〜70··程度左右。 另一方面，由於成形無人化、淸潔化之要求，導至硬 (請先閲讀背面之注意事項再填寫本頁) •裝· 訂 • . 本紙張尺度適用中國國家標準（CNS〉八4洗格（210'X 297公釐） 320600 經濟部中央樣準局員工消費合作社印裝 A7 B7 _五、發明説明（3 ) 化性樹脂自動成形機之開發、自動化成形竇泛地被應用。 此類自動成形機，《用在IC*LSI等彌封成形物，通常藉 由數艏〜十數傭成形品之5段式壓》棋方式所成形，其使 用之彌封用硬化性樹脂，一般供给所謂之小形錠片，其直 徑約在5〜30*a程度，而淸掃模具用榭脂組成物，也使用 相同尺寸直徑5〜30«m程度之小型錠片。 又在待公昭52-788號公報中之開示，曾述及遇去周知 之清播棋具用樹脂组成物，通常錠片化後而應用於一般棋 具淸掃。但是此類清掃棋具用樹脂組成物經錠片成形檐進 行錠片化時，為避免錠片成形用模具損耗，通常大多使用 超網材料等，成形後之錠薄（，常因由棋具中取出困難，故 在取出時*須要提高壓力，致使有摩擦雜音、或易發生割 裂、破碎等缺點、造成不良率之增加。 在特公昭52-788號公報中所例示：曾提及嘗試增加淸 掃棋具用樹脂組成物之滑劑含有量，提高錠片化之生產能 率。但是一旦增加滑劑之含有置，由於滑劑本身之滲出現 象，反而成為棋具之污染要因，致使淸掃模具效果大輻低 下，因而不得不增加淸播棋具之射出數，產生”過猶不及 M的結果。 當清掃模具用樹脂組成物進行錠片成形時，由於該樹 脂組成物呈粉醱形狀，通常将該粉鳗投入錠劑成形機，成 形而得。 但是由於該粉糴相對密度過小，當該粉體進行錠片成 形時，須要較大的壓力，而所播得之錠劑*通常重量分佈 (诗先閲讀背面之注意Ϋ項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 6 經濟部中央標準局貝工消费合作杜印袈 A7 B7_ 五、發明説明（4 ) 範圍甚不平均，再者由棋具内拔出時，須要更大的壓力， 而致產生割裂、破損等不良率的增加。 諸如此類事情之故，因此追求一種待別具有良好錠薄 成形性、良好淸拥性，而且不易發生割裂、破攒等成形不 良之優秀錠劑。 〔發明之開示〕 本發明群經銳意硏究的结果，在不增加滑劑之含有置 ，同時又能提离錠片化生產能率之方法；邸淸揷棋具用樹 脂组成物，由特定粒徑之粒子與特定粒徑之粉醱呈混合物 狀態使用，當該混合物進行成形時，不但能繼鳙保持其良 好的淸掃性，同時又能改菩其錠片成形性，其真知灼見於 足完成了本發明。 本發明即是提供一種針對硬化性樹脂成形材料在成形 時，俥Μ去除棋具表面圬垢之清掃棋具用樹脂组成物錠片 ，該錠剤是經由42#篩S不通遇粒子50%重ΜΜ上之樹脂 組成物粒子（Α)和經由80#篩班通過之粒子90%重量以上之 樹脂組成物粉霞（Β)呈混合物狀態之成形品，其粒子（Α)/ 粉鼸（Β)之重量比，在1/9以上者。 本發明理想之淸拥棋具用樹脂组成物錠劑，錠片直徑 在30·ι«以上一般使用在板式充填鑄棋方式之淸掃·•若粒子 (Α)/粒髅（Β>之重量比維持在7/3以上而且錠片直徑未滿 30··，通常則是應用在多段式S鑄棋方式之淸掃；又其樹 脂组成物中，納離子濃度須在50〇ΡΡ»Μ下、鉀離子濃度在 500ρρβ以下，其他氦離子濃度必須在200ρρ·以下之淸掃棋 本紙張尺度適用中國國家橾準（CNS ) A4洗格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) -裝· 訂 經濟部中央標準局員工消費合作社印裝 A7 B7 五、發明説明（5 ) 真用樹脂组成物淀劑。 〔發明的詳細說明〕 Η將本發明詳細說明如下。 本發明樹脂组成物粉體（Β)，即氨基糸樹脂中包含作 為滑劑之金靨皂、礦物質粉醒、無機或有機充填劑、Μ及 加入其他添加劑等，将逭些成分使用各種方法混合均一後 而成组成物，再將該組成物粉碎而成粉鱧。上述粉«(B) ，其粒徑經80#篩落通過之粒子含有90%重量以上者，若 逢到93%重置Μ上者更佳，含有95%重量Μ上者則更爲理 想。 又本發明之樹脂组成物粒子（Α)，即上述樹脂组成物 粉嫌（Β)粒狀化後而得，該粒狀化遇程並沒有待別規範， 其化表方法，即将該粉黼經錠片成形後，再將該錠片依須 要之粒徑大小粉碎而成。上述粒子（Α)，其粒徑大小經42# 篩殘之粒子含有50%重量Μ上者；含有70%重量以上者較 合適，若逢到75%重量以上者更佳，若能含有80%重量Μ 上者則最為理想。 再者有闢本發明錠片成形用材料（淸禰模具用樹脂組 成物），是由上述之粒子（Α)和上述之粉覦（Β)呈混合物形 態而得，其粒子（Α)/粉體（Β)之比率，雒持在1/9 Μ上之 範圍者。若粉醍（Β)超過該範圍而形成之錠劑，其不良率 、重量分布不均現象相對增加；但若粒子（Α)過多時其粒 狀化材料之用量，熱必增多，再錠片化時之材料供给量相 對增加，在經濟考量上則不划算。 本紙張尺度逍用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閲1»背面之注意事項再填寫本頁) -裝· 訂 320600 經濟部中央梂準局貝工消费合作社印袈. A7 B7___五、發明説明（6 ) 當使用於板式充填鑄棋之淸掃用錠劑，錠劑直徑多數 30«aM上，其上述粒子（A)/粉« (B)之範匾，檯可能維持 在2/8〜8/2範函內，若能在3/7〜7/3之範圃則更為理想。 又使用於該雙段式壓»棋之淸掃用錠劑*錠片直徑通 常未滿30·*，其粒子（A>/粉讎（B>之範園7/3 Μ上者為妥 適*當粉讎（Β)超遇該範園而成形之錠劑，其不良率、重 量分佈不勻邸相對提高，但粒子（Α)遇多時，則又不符合 經濟原則，故上述粒子（Α>/粉麵（Β)之範園，儘可能維持 在8/2 Μ上之妥適範圍，若能逹到8/2〜9/1之範園内則更 為理想。 本發明中之上逑氨基条樹脂係由樹脂组成物粉鑛（Β) 以及樹脂組成物粒子（Α)所構成，舉凡蜜胺樹脂、尿素樹 脂、蜜胺-酚共编合樹脂或是蜜胺一尿素共縮合樹脂及其 上述成分之諸混合物者皆屬之。 上述萤胺-酚共縮合樹脂，是屬蜜胺等之三氮雜苯類 、酚類、Μ及與甲醛等之醛類共縮合形成之缩合物；上述 蜜胺-尿素共縮合樹脂，是由蜜胺等之三気雜苯類、尿索 類，以及甲醛等之醛類共縮合形成之縮合物。又上述蜜胺 樹脂，是由蜜胺等之三«雜苯類與醛類共縮合取得之缩合 物；上述尿素樹脂則是由尿索類與醛類共缩合而得之缠合 物。上述三«雜苯類除了蜜胺之外，該三《雜笨類Κ 100 重量部計時，如 BENZOGUANIGINE、ACETOGUANAMINE 等除蜜 胺外之三*雜苯類，凡含有30重量部Μ下比例者，均可適 用。又上述之酚類，除了酚之外，該酚類若Μ 100重置部 (請先閲讀背面之注意事項再填寫本頁) -裝. ,-ιτ 本紙張尺度適用中國國家梯隼（CNS ) Μ洗格（210X297公釐） ~ 9 - 1.-5 經濟部中央橾準局貝工消费合作社印裝 A7 B7___五、發明説明（7 ) 計算，如甲酚、二甲酚、乙基笨酚、丁基苯酚等屬酚以外 之酚類，凡含有30重量部以下比例者皆可適用。 更有者本發明之錠劑成形材料（淸掃棋具用樹脂組成 物），上述氨基糸樹脂有可能混合其他副次量之樹脂類， 但Μ不會帶給上述淸播棋具用樹脂組成物改善性質之惡彩 *範園者均可配合使用。此類樹脂諸如醇酸樹脂、多元酯 樹脂、丙烯酸樹脂、環氧樹脂、Μ及橡膠類等例皆是。 又本發明中上述氨基糸樹脂所添加之金屬皂，是有Ρ 溶融樹脂在模具内之流動性以及樹脂硬化後離型性之向上 ，如硬脂酸鈣、硬酯酸鋅、十四烷基酸鋅等皆是。諸如此 類金屬皂添加纛，若淸掃棋具用樹脂組成物Μ 1〇〇重量部 計箄，其適當添加麗介於0.1〜1.5重量部，0.2〜1重置部 間更佳，0.3〜0.8重鼉部間添加董則特別理想。酋金羼皂 添加不足時，淸掃用樹脂组成物不能充滿棋具內後雜微小 的部分，而導至淸掃不足，Μ及硬化後因淸掃用樹脂離型 不良，造成淸拂不良的情況。 在本發明中上述錠劑成形用材料（淸掃棋具用樹脂組 成物）所能添加之滑劑，其中包括脂肪酸醢胺条滑劑、脂 肪酸糸滑劑、乙酵条滑剤、石腊条滑劑、矽元素糸滑劑等 ;該脂肪酸醯胺滑劑，如十二烷基酸醢胺、十四垸基醯胺 、工儿力、酸醢胺、油酸醯胺、硬脂酸醢胺之諸如此類飽和 或不飽和單醢胺型》型；甲叉雙硬脂酸醢胺、乙叉雙硬腊 酸醯胺、乙叉雙油酸醢胺之如此類飽和或不飽合雙醯胺型 滑剤等皆是；又脂肪酸条滑劑如硬脂肪酸、硬脂酸丁醋等 張尺度適用中困國家標準（CNS ) Α4規格（210X297公釐）~ (請先閲讀背面之注意事項再填寫本頁) • —4 · .裝- 訂 -10 - 經濟部中央標準局員工消費合作社印装 A7 ^__^_B7_ 五、發明説明（8 ) :乙酵条滑劑，如高级乙酵等；矽元素条滑劑如矽油等例 皆是。諸如此類各種滑劑可與上述金羼皂条》劑一起併用 。又此類各種滑劑添加量，若淸掃棋具用樹脂组成物以100 重Μ部計算，適當添加量在0.1〜1.5重ft部間，若能連到 0.2〜0.8重ft部間更佳，若能在0.2〜0.6重量部間則更為 S想。 因此爲了保持良好的棋具澝挿性，上述滑劑之合計量 ，通常雷淸拂棋具用樹脂組成物以100重量部計，適當之 添加量儘可能維持在1.5重量部以下，若能在1重量部以 下則更理想。 又本發明之淸捕棋具用樹脂組成物，除既述之樹脂外 *還可包含其他礦物性粉髏。該礦物質粉釀如金_砂、刚 玉粉、樓右、矽石等天然材K及矽、嫌、钛、鈣、续、鋁 、絡、礪等氧化物或硪化物，此類氧化物或者磺化物如二 氧化矽、氧化錳、氣化鋁、磺化矽、硪化画等皆靨之。 上述礦物質粉《之粒度，並沒有特定的限制，一般多 介於#10〜#8000間，#50〜4000間較妥適，若能連到#100 〜#2000之範圍内則更為理想。當粒度小於#8000，常會導 至清捕效果低下，取用時容易發生粉*、作業環塊惡化等 缺點；但若粒度大於#10時，刖反容易造成模具損傷、發 生淸禰不均等缺點。 又上述礙物質粉饑之使用置，用*一沒有特別限制， 若淸掃棋具用樹脂组成物Μ 100重貴部計，適當之使用量 在10〜90重量部，15〜30重量部間更爲妥適、若能維持在 本紙伕尺度適用中國國家梯準（CNS ) Α4規格（210:<297公釐） -11 - (請先閲讀背面之注意事項再填寫本頁) -裝.1 1 Printed and printed 320600 a7 B7__ by the National Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives V. Description of the invention (1) [Technical field with inventions] The present invention is a resin composition lozenge for inserting chess sets, which is aimed at When the hardening resin molding material is molded, removing the dirt on the surface of the chess tool not only has a good sweeping effect of the chess tool, but also has the characteristics of compactness and easy deformation. 〔Technical background〕 When using hardened resins such as epoxy resin and flute in the formation of sealed moldings such as Jushixiao Road, after a long period of continuous molding * Once the internal surface of the wedge is contaminated, this is the case In this case, Chang Cao contaminated the surface of the molded product or attached the molded product to the wedge, and could not continue the forming operation. Therefore, the chess set needs to be cleaned regularly, and every time the molding material is injection-molded hundreds of times, that is, the resin used to clean the chess set is injection-molded several times. For example, in the gazette 52-788¾, it was proposed that "an M amino strip resin is mainly formed by plaque material, and when it is formed with a curable resin molding material (except amino amino resin molding material), the The method of contaminating the surface of the chess set, and mentioned that the resin composition for a piece of chess set is composed of amino strip resin, organic material / or inorganic base material, and thin release. Furthermore, in the special public Zhao 64- In No. 10162, there is also mentioned a resin composition for 抸 祢 chess set composed of a co-condensation resin of amino acid strip resin and phenol strip resin and mineral powder with neo-Mohs hardness 6 ~ 15. When the hardening resin such as epoxy resin is used in the molding of encapsulated molded products such as Zhenyu circuits, the hardening resin for encapsulation is first formed into the shape of tablets, and then the tablets are preheated and inserted into the material chamber The standard of this paper after transfer is applicable to China National Standardization (CNS) Α4 wash grid (210X297mm) (please read the precautions on the back and then fill out this page). Installed. Ordered by the Ministry of Economic Affairs Central Counseling Bureau Industrial and Consumer Cooperative Printed Install A7 B 7_ 五 、 Description of the invention (2) One molded by the molding method. The resin composition for sweeping chess set "Because of the same molding conditions applicable to the molding process of the curable resin for sealing, it is generally like the epoxy resin for sealing. , Formed by transfer molding, and most of them use the same shape of the tablet as the forming material. The tablet is pre-heated and softened, and then the forming process is performed. When the sweeping chess tool is filled with the resin composition, the entire interior of the chess tool is once hardened. When the dirt on the surface of the chess set is removed, the surface of the chess set is cleaned. There are two types of transfer forming methods: plate filling shovel chess and double-stage pressure chess. The plate filling and casting chess, that is, for the 1 tilt »type, use a tilt comparison Large resin ingots are usually designed to make the runner of the chess tool the same speed to the narrowest, but one side maximizes the number of molded product chambers of the chess tool, with a single value material center as the center and a few dozens arranged in the shortest distance There are several molding chambers ranging from Μ to hundreds of wounds, with a branched structure. The two-stage E casting chess, that is, whenever a rib oil S drying tube device, a few quail molding chambers are limited, and the sprue makes it It is narrow and equipped with multi-value oil pressure "tube device. The small-sized ingots are automatically fixed in each drying device at the same time, and then transferred to the material room for preheating and forming. With the high integration and thinning of IC · LSI, etc. , Surface mounting and the evolution of diversification of molded products. Therefore, for various molded products, it is necessary to use ingots of various sizes and specifications, and the resin composition for playing chess must also correspond, just like epoxy resin ingots for sealing There is a demand for tablets of various shapes. For example, when adopting the transfer-formed plate type "in the filling die mode *", when using large chess sets with dozens to hundreds of shaped products, the diameter of the tablets provided in the traditional form, About 30 ~ 70 ·· degree. On the other hand, due to the requirements of unmanned molding and cleaning, it is hard (please read the precautions on the back before filling out this page) • Packing · Ordering ·. This paper size is applicable China National Standards (CNS> Avatar 4 Washing (210'X 297mm) 320600 Printed and printed A7 B7 by the Employees ’Consumer Cooperative of the Central Prototype Bureau of the Ministry of Economic Affairs _V. Description of the invention (3) Development of chemical resin automatic forming machine , Automated plastic sinus is widely used. This type of automatic molding machine, "Impressed molded products used in IC * LSI, etc., is usually formed by a five-stage pressing of several bows to dozens of molded products" chess method, which uses hardening resin for sealing, The so-called small ingots are generally supplied with a diameter of about 5 to 30 * a, and the resin composition for sweeping molds also uses small ingots of the same size with a diameter of about 5 to 30 mm. In addition, in the publication of Gazette No. 52-788, it was mentioned that the resin composition for clear broadcasting chess equipment that has been known to the public is usually used as a general chess equipment after being ingot. However, in order to avoid the loss of ingot forming molds, the resin composition for cleaning chess tools is ingot formed by ingot forming eaves, and most of them use super-net materials, etc. The ingot after forming is thin (often due to the difficulty in taking out from the chess tool Therefore, when you take it out, you need to increase the pressure, which causes friction noise, or is prone to splitting, crushing and other shortcomings, resulting in an increase in the defect rate. As exemplified in the Special Publication No. 52-788: It has been mentioned that attempts to increase the chessboard The content of the slip agent used in the resin composition improves the production efficiency of tableting. However, once the slip agent content is increased, due to the leakage of the slip agent itself, it becomes the cause of the pollution of the chess set, which makes the sweeping mold effect greatly reduced. Therefore, it is necessary to increase the number of shots of the game chess, which results in "too much less than M. When the resin composition for cleaning the mold is used for ingot molding, the resin composition is usually in the shape of a powder, so the powdered eel is usually put into the lozenge. It is obtained by forming machine. However, because the relative density of the powder is too small, when the powder is formed into tablets, a large pressure is required. Tablets obtained * Normal weight distribution (Read the notes on the back of the poem before filling in this page) The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 6 Ministry of Economic Affairs Central Standards Bureau Bei Gong Consumer Cooperation Du袈 A7 B7_ V. Description of the invention (4) The range is very uneven. Furthermore, when it is pulled out from the chess set, more pressure is needed, which leads to an increase in the rate of defects such as splitting and damage. For such reasons, we pursue It is an excellent tablet that has good thin formability, good supportability, and is not prone to forming defects such as splitting and cracking. [Explanation of the invention] As a result of keen research, the present group does not increase the slip agent Containing device, and at the same time can lift off the tableting production rate of energy; the resin composition for Di Dian Ju Chess is used in the state of a mixture of particles of a specific particle size and a powder of a specific particle size, when the mixture is shaped, not only It can maintain the good sweeping performance of the bighead carp, and at the same time it can improve the formability of the tablet, and its real knowledge is enough to complete the present invention. The present invention is to provide a hard The resin composition ingots used to clean the surface of the chess set during the molding process of the resin molding material are formed through the use of a 42 # sieve S which is not accessible to the particles. The resin composition particles (Α) and 50% on the MM 90% by weight of the resin composition passing through the 80 # sieve, the resin composition Fen Xia (B) is a molded product in the form of a mixture, and the weight ratio of the particles (A) / Powder (B) is 1/9 or more. The ideal resin composition lozenges for chess holders of the present invention, with a tablet diameter of 30 · ι «or more, are generally used in the plate-filled chess-playing method of sweeping • weight ratio of particles (Α) / particles (Β >) Maintained above 7/3 and the diameter of the ingot is less than 30 ··, it is usually used in the sweeping of the multi-stage S-casting method; and in the resin composition, the concentration of sodium ions must be under 50〇ΡΡ »Μ, Potassium ion concentration is below 500ρρβ, and other helium ion concentration must be below 200ρρ · The paper size of the chessboard is applicable to the Chinese National Standard (CNS) A4 wash grid (210X297mm) (please read the precautions on the back before filling in this Page)-Binding and Ordering of the Staff Consumption Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Five community A7 B7 printing equipment, described (5) The resin composition of the invention true precipitant. [Detailed Description of the Invention] Η The present invention will be described in detail as follows. The powder (B) of the resin composition of the present invention, that is, the amino-shito resin contains gold luteum soap as a slip agent, mineral powder, inorganic or organic fillers, Μ, and other additives, etc., using various methods for these ingredients After mixing uniformly, a composition is formed, and then the composition is crushed to form a powdery snakehead. The above powder «(B), the particles whose particle size passed through the sieve of 80 # contain more than 90% by weight. It is better to reset the M at 93%, and it is more ideal to contain 95% by weight. In addition, the resin composition particles (Α) of the present invention are obtained by granulating the above resin composition powder (B). The granulation process has not yet been regulated. After the ingot is formed, the ingot is crushed according to the required particle size. The above particles (Α) whose particle size has passed through the 42 # sieve residue contain 50% by weight or more; those containing 70% by weight or more are more suitable; if they reach 75% by weight or more, it is better if they can contain 80% The weight above M is the most ideal. Furthermore, the material for ingot forming of the present invention (resin composition for molds) is obtained from the above-mentioned particles (Α) and the above-mentioned powders (B) in the form of a mixture, and the particles (Α) / powder The ratio of body (B), which is within the range of 1/9 Μ. If the tablet formed by the powder (B) exceeds this range, the defect rate and uneven weight distribution will increase relatively; but if the number of particles (Α) is too much, the amount of the granular material will increase the heat, and then the tablet The supply of materials at the time of transformation is relatively increased, which is not cost-effective in terms of economic considerations. The size of this paper is in accordance with Chinese National Standard (CNS) Α4 specifications (210Χ297mm) (please read the notes on the back of 1 »and then fill out this page)-Binding · Order 320600 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs . A7 B7___ V. Description of the invention (6) When used in plate-filled lozenges for sweeping chess, the diameter of the lozenge is mostly 30 «aM, and the above-mentioned particles (A) / powder« (B) are plaques, The station may be maintained in the 2/8 ~ 8/2 norm letter, and it is more ideal if it can be in the 3/7 ~ 7/3 norm. It is also used in this two-stage press »lozenges for the sweeping of chess * The diameter of the tablets is usually less than 30 · *, and the particles (A > / Powder (B >) Fan Garden 7/3 Μ above are appropriate * When the powder formed by the powder (B) exceeds the fan garden, the defect rate and uneven weight distribution are relatively increased, but when there are many particles (A), it does not meet the economic principle, so the above particles ( The range of Α > / Noodle (B) should be kept within the proper range of 8/2 Μ as much as possible, and it is more ideal if it can reach the range of 8/2 ~ 9/1. The amino resin is composed of resin composition powder (B) and resin composition particles (Α), such as melamine resin, urea resin, melamine-phenol co-combination resin or melamine-urea co-condensation resin The above-mentioned mixtures of these components are all belong to. The above-mentioned fluoramine-phenol co-condensation resin is a condensate formed by co-condensation of triazabenzenes such as melamine, phenols, M and aldehydes such as formaldehyde The above-mentioned melamine-urea co-condensation resin is a condensate formed by co-condensation of melamines, such as tribenzene, urea, and formaldehyde. The above-mentioned melamine resin is a condensate obtained by melamine and other «co-condensation of heterobenzenes and aldehydes; the above-mentioned urea resin is an entangled compound obtained by co-condensation of urea and aldehydes. In addition to melamine, the three "Miscellaneous K 100 weight parts, such as BENZOGUANIGINE, ACETOGUANAMINE and other three melamines other than melamine, all containing 30% by weight of the proportion of M can be applied . In addition to the phenols mentioned above, in addition to phenols, if the phenols are replaced by M 100 (please read the precautions on the back before filling out this page) -installation., -Ιτ This paper size is applicable to China National Falcon (CNS ) Μ wash grid (210X297 mm) ~ 9-1.-5 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs Beigong Consumer Cooperative A7 B7___ V. Description of invention (7) Calculation, such as cresol, xylenol, ethyl Phenols other than phenol, such as stupid phenol and butylphenol, can be applied to those containing less than 30 parts by weight. Furthermore, the tablet-forming material of the present invention (resin composition for sweeping chess set), the above-mentioned amino resin It may be possible to mix other sub-quantity resins, but M will not bring the above-mentioned game Poisonous colors that improve the properties with resin compositions can be used together. Fans such as alkyd resins, polyester resins, acrylic resins, epoxy resins, M and rubbers are all examples. Also in the present invention The metal soap added to the above amino resin has the fluidity of the fused resin in the mold and the upward release of the resin after curing, such as calcium stearate, zinc stearate, zinc tetradecylate, etc. Yes. The addition of such metal soaps, if the resin composition for sweeping chess sets Μ100 is calculated by weight, the appropriate addition of Li is between 0.1 ~ 1.5 parts by weight, preferably 0.2 ~ 1 between reset parts, 0.3 ~ 0.8 It is especially ideal to add Dong between the heavy-duty ministries. When there is insufficient addition of Ekinjin Soap, the sweeping resin composition cannot fill the tiny parts of the chessboard, which leads to insufficient sweeping, Μ and hardening due to poor release of the sweeping resin after hardening, resulting in poor sweeping . In the present invention, the slip agents that can be added to the above-mentioned lozenge-forming materials (resin compositions for sweeping chess sets) include fatty acid acetamide stick slips, fatty acid slip slips, ethyl yeast slip slips, and paraffin slip slips , Silicone slip agent, etc .; the fatty acid amide slip agent, such as dodecyl acid amide, tetradecyl amide, ketal, acid amine, oleate amide, stearate amine Such as saturated or unsaturated monoacetamide type; type; methyl formate bisstearic acid amide, ethyl bis bis stearic acid amide, ethyl bis oleate amide, and the like, saturated or unsaturated bis amide type slip All are the same; and fatty acid strips such as hard fatty acid, stearic acid butyl vinegar and other scales are applicable to the national standard (CNS) Α4 specification (210X297mm) ~ (please read the precautions on the back before filling this page) • —4 · .Package-Order -10-Printed and printed A7 ^ __ ^ _ B7_ by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of invention (8): Ethanol strip slips, such as advanced ethyl yeast, etc. Agents such as silicone oil are common examples. Various slip agents such as these can be used together with the aforementioned Jin Yi soap bar agent. The addition amount of various kinds of slip agents is calculated if the resin composition for sweeping chess tools is 100 weight M parts, and the appropriate addition amount is between 0.1 ~ 1.5 weight ft parts, and it is better if it can be connected between 0.2 ~ 0.8 weight ft parts. If it can be between 0.2 ~ 0.6 weight parts, it is even more difficult to think. Therefore, in order to maintain good insertability of the chess set, the total amount of the above-mentioned slip agents is usually calculated based on 100 parts by weight of the resin composition for chess sets, and the appropriate addition amount should be kept as low as 1.5 parts by weight if possible. Subordinates are more ideal. In addition to the resin composition for the chess game of the present invention, in addition to the resin mentioned above, it can also contain other mineral powders. The mineral powder is made of natural materials such as gold, sand, corundum powder, Louyou, and silica, as well as oxides or oxides of silicon, silicon, titanium, calcium, aluminum, aluminum, copper, aluminum, etc. Such oxides or Sulfonates such as silicon dioxide, manganese oxide, vaporized aluminum, sulfonated silicon, and paintings are all examples. There is no specific limit to the particle size of the above mineral powder, generally between # 10 ~ # 8000, # 50 ~ 4000 is more appropriate, and it is more ideal if it can be connected to the range of # 100 ~ # 2000 . When the particle size is less than # 8000, it will often lead to a low cleaning effect, and it is easy to cause defects such as powder * and deterioration of the operating ring block when taking it; but if the particle size is greater than # 10, it will easily cause mold damage and uneven unevenness. . In addition, the use of the above-mentioned substances that hinder the use of powder hunger is not particularly limited. If the resin composition for sweeping chess sets M 100 is expensive, the appropriate amount is 10 to 90 parts by weight, and 15 to 30 parts by weight. In order to be suitable, if it can be maintained on this paper, the Chinese National Standard (CNS) Α4 specification (210: < 297 mm) -11-(please read the precautions on the back before filling this page)-installed.
,tT 經濟部中央樣準局負工消费合作杜印輦 A7 _B7_五、發明説明（9 ) 17〜29重量部之範園內則更爲理想。 本發明之淸挿棋具用樹脂組成物，除既逑之礦物性粉 鐮外，其他尚可包含無機或有機之充填劑、著色劑、硬化 觸媒、抗氧化劑等諸添加物。諸如此類添加劑*如紙漿、 木粉、聚乙烯酵鐵維、玻琍粉、玻闲玀維、無處理碩酸鈣 、滑石粉、氫氣化鋁、硫酸鋇、硫化鋅皆屬無機或有機之 充填剤；如二氧化鈦、炭黑、鋅白、鎘黄、<二方，等無 機顔料；酞花育条、偁«条、重《条等有機顔料；苯氧氮 条、萘酚偁«糸、靠蔓酸条等螢光顔料；葸醒条、靛藍条 、偶兔糸等染料以上皆羼添加著色劑；如安息香酸，無水 鉍酸酐、草酸、祿胺酸、對位甲苯痛酸等有機酸，鹽酸、 碕酸等無機酸，Μ上諸酸類與三乙基胺、三乙酵胺、/3-二甲基胺乙酵、2-甲基-2-胺基-1-丙酵等所组成之鹽類， 皆屬添加之硬化觸媒；如萘基胺条抗氧化剤、Ρ-苯基二胺 糸抗氧化爾、硫代雙酚条抗氧化劑等皆颶添加之抗氧化两 〇 又上逑紙漿*一般使用$紙漿、竹紙漿、木材紙漿（ 針窠樹紙漿、《蒱樹紙漿）等，其他如化當紙漿、機械紙 漿中任何一種亦可。 又上述紙漿、木粉等潘雄索充填劑之規格，並沒有特 別加以限制，一般介於5〜1000 W m，但以10〜200 « a範 .内，較為委適。 又缕維素充«劑之添加置，若上述氨基条樹脂以1〇〇 重量部計，15〜70重量部爲適當添加逢，但在20〜60重量 ---_---*·---裝------訂------^ΪΝ (請先閲讀背面之注意Ϋ項再填寫本頁) 本紙張尺度逍用中囷國家標準（CNS ) A4规格（210X297公釐）, tT Ministry of Economics Central Sample Bureau of the Ministry of Labor and Consumer Cooperation Du Yinlong A7 _B7_ V. Description of the invention (9) 17 ~ 29 The weight of the Fanyuan is more ideal. The resin composition of the present invention can include inorganic or organic fillers, colorants, hardening catalysts, antioxidants and other additives in addition to the existing mineral powder scythe. Additives such as paper pulp, wood flour, polyethylene ferric ferment, glass powder, glass ferment, untreated calcium monate, talc, aluminum hydroxide, barium sulfate, zinc sulfide are all inorganic or organic fillers ; Inorganic pigments such as titanium dioxide, carbon black, zinc white, cadmium yellow, < difang, etc .; organic pigments such as phthalocyanine strips, strips «strips, heavy strips; phenoxy nitrogen strips, naphthol strips« Shito Fluorescent pigments such as citric acid strips; dyes such as awakening strips, indigo strips, and even rabbits are added with colorants; such as benzoic acid, anhydrous bismuth anhydride, oxalic acid, lulic acid, para-toluic acid and other organic acids, Inorganic acids such as hydrochloric acid and benzoic acid, composed of various acids on M and triethylamine, triethylamine, / 3-dimethylaminoethylase, 2-methyl-2-amino-1-propanase, etc. The salts are all added hardening catalysts; such as naphthylamine strip antioxidants, P-phenyldiamine Shito antioxidant, thiobisphenol strip antioxidants, etc. are all added antioxidants.黑 纸 粉 * Generally use $ pulp, bamboo pulp, wood pulp (needle pulp, konjac pulp), etc., such as Huadang pulp, machine Any kind of mechanical pulp can also be used. In addition, the specifications of the above-mentioned paper pulp, wood powder and other Panxiong fillers are not particularly limited, generally between 5 ~ 1000 W m, but within 10 ~ 200 «a range, which is more suitable. For the addition of the serotonin filler, if the above-mentioned amino strip resin is based on 100 parts by weight, 15 ~ 70 parts by weight is added appropriately, but it is 20 ~ 60 parts by weight ---_--- * ·- --Installation ------ Order ------ ^ ΪΝ (Please read the note Ϋ on the back first and then fill in this page) This paper is used in the national standard (CNS) A4 specification (210X297mm )
SS
經濟部中央樣準局WC工消費合作社印裝 A7 B7五、發明説明（10 ) 部之範匾内則較妥適。 本發明之澝挿棋具用樹脂組成物錠劑，最好能将納離 子濃度維持在500ρρ·Μ下，鉀離子500ρρ·以下、及氣離子 200ΡΡ1Μ下為理想。即上述澝掃棋具用樹脂組成物錠劑， 經轉移-薄棋成形方式洗淨棋具表面時，若淸掃膜片中含 有離子性不純物，殘留在棋具表面，有可能會導至此類離 子性不純物進入成形之半導醱索子當中，若上述離子性不 純物進入此類半導體素子中，恐會發生腐食性方面的重大 問題。因此上述淸掃棋具用樹脂組成物錠剤之製造時，對 使用原料應十分慎重，希望能避免使用含有上述所提及含 有離子性不純物之原料。 調製本發明之组成物時，氨基糸樹脂、礦物質粉醱、 其他依實際須要之副次量樹脂、添加劑類等可採用任意工 程手段加Μ均一混合。如使用捏合檐、帶式混合機、漢氏 混合機、球髏硏磨機、混練滾輪、攬拌播溃機、轉鼓等。 經Μ上工程手段獲取之组成物，然後進行錠薄I成形。 錠爾形狀有囫柱形、長方形、棒狀、立方鳢等依棋具之構 造而有種種不同形狀，像半導髏彌封用棋具*常使用圚柱 形彌封用硬化性樹脂錠劑，故淸掃棋具用樹脂组成物也須 使用同形狀之錠劑。 錠劑之成形，通常將前述之澝搏棋具用樹脂組成物粒 子（Α)和粉體（Β)之混合物放入縱型或棋型之棋具中*利用 機械式或油壓式等活塞加S，使該組成物固化而成。錠爾 成形壓力依錠片成形機之構造、錠劑直徑、高度等而有所 (請先閲讀背面之注意事項V.填寫本頁) .装. 訂 本紙張尺度適用中國围家標隼（CMS ) Α4洗格（210X297公釐） -13- 經濟部中夬搮隼局β;工消费合作社印装 A7 B7五、發明説明（η ) 不同，一般在 200 〜15001cg/caa 之間，300 〜1200kg/cBa 範圃内則較理想。 錠_成形前，滑剤等添加劑在不妨害淸掃性範園内添 加無妨。錠_成形後添加之滑劑，因高濃.度存在於粉《/ 粒子塊界面，可Μ改善綻劑由棋具取出之困難度。 錠爾密度，因组成物之成形壓而略有不同，概略在1.1 〜1.8g/c«3之範函内。 本發明之淸播棋具用樹腊組成物錠爾所使用之淸樺棋 具硬化性樹脂成形材料，包含如環氧樹脂成形材料、酚樹 脂成形材料等，其中以瑷氧樹脂成形材料較佳，半導體彌 封用瓖氧樹脂成形材料則更理想。 又有两適合使用本發明之淸挿楔具用樹脂组成物錠劑 之棋具，凡是硬化性樹脂成形材料成形時所使用之棋具， 均可使用，一般由鐵、鉻等材質製成之棋具使用上較為貼 適。 本發明之淸捕棋具用樹脂組成物錠两*不但不會使淸 播效果低下，反而能使生產能率向上。 〔實施例〕 有鼷本發明之淸拥棋具用樹脂組成物錠劑，參照以下 實施例與比較例之混列，再進一步詳加說明。 淸播效果之試驗方法： «子回路之彌封成形品，一般使用市販之環氧樹脂成 形材料錠劑（日東電工（株）社製NITRON MP商品名 > 經轉移 -成形方式成形而成。在經遇400次射出成形之後，利用與 (請先閲讀背面之注意事項再填寫本頁) -装· 本紙张尺度逍用中國囷家標準（CNS ) A4洗格（210X297公釐） -14 - 經濟部中央標準局貝工消费合作杜印製 A7 B7 五、發明説明（l2 ) 上述材料同形狀之試驗用淸播棋具用樹禊组成物錠爾，在 同棋具内成形，然後調査其射出數舆淸播效果。至於淸播 效果的判定，依目視可分5階段作爲判定基準。 5:殘留物等完全沒有 4:殘留物等幾乎沒有 3 :稍有殘留物 2:仍有殘留物 1 :(成形品 > 污染殘留多且有缺陷。 (2) 粒度之測定法： 粒度之規定依JIS-R6001 (1973)文獻之記載，而其拥 定法則根據JIS-R6002文獻所述測定之。 本明細害中使用之” #"，是指番或是MESH。 (3) 錠劑成形性之評價方法： 〔板式充填鑄棋用〕 首先備妥錠劑成形用棋具（48b· 0 X 32··Η>並将錠劑 成形檐之錠片重Μ予作調整為75g，接著將準備之錠涮成 形材料經給料漏斗投入機内，透遇加壓裝置加®至1000kg “8爲止，保持壓力約1〇秒間，錠劑於是成形。成形之後 ，將棋具下部卸下，繼續提升力直至錠片被拔出，此時讀 取加壓之最高值，同時觀察錠_是否有破損（剌裂、破碎） 等不良現象發生。經同樣作業程序100值錠劑成形過程中 ，計算出其不良率，並且測定其重量，若重量分佈位在75 土 3g(4%>容許範圈内則以〇檷示之。 〔雙段式壓縳楔用〕 本紙張尺度速用中國國家標準（CNS ) A4^格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) .裝. 訂Printed and printed by the WC Industrial and Consumer Cooperative of the Central Prototype Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (10) It is more appropriate in the model plaque of the Ministry. The resin composition lozenge for a chess game of the present invention preferably has a nano ion concentration of 500 ρρ · Μ, a potassium ion of 500 ρρ · or less, and a gas ion of 200PP1M. In other words, when the above-mentioned resin composition lozenge for scouring chess tools is washed by the transfer-thin chess molding method, if the scouring membrane contains ionic impurities and remains on the surface of the chess tools, it may lead to such ionic impurities Entering the formed semiconducting cable, if the above-mentioned ionic impurities enter into this kind of semiconductor element, there may be a major problem in decay. Therefore, when manufacturing the above resin composition ingots for sweeping chess sets, the use of raw materials should be very careful, and it is hoped that the use of raw materials containing ionic impurities mentioned above can be avoided. When preparing the composition of the present invention, the amino sulfonate resin, mineral powder, other secondary secondary resins, additives, etc. as required may be mixed uniformly by any engineering means. Such as the use of kneading eaves, belt mixers, Hans mixers, ball mills, kneading rollers, mixers, drums, etc. The composition obtained by the engineering method above M is then subjected to ingot thin I forming. The shape of the ingots is cylindrical, rectangular, rod-shaped, cubic cub, etc. There are various shapes according to the structure of the chess set, like the semi-conducting cross-shaped sealing chess set. * The hardened resin tablets for the cylindrical sealing are often used, so For the resin composition used for sweeping chess sets, lozenges of the same shape must also be used. For the formation of lozenges, usually the mixture of the resin composition particles (Α) and powder (Β) for the aforementioned chessboard chess set is placed in a vertical or chess-type chess set. * Use mechanical or hydraulic pistons to add S , Made by curing the composition. The ingot forming pressure depends on the structure of the tablet forming machine, the diameter of the tablet, the height, etc. (please read the precautions on the back V. fill in this page). Packing. The size of this paper is suitable for the Chinese Weijia Standard Falcon (CMS) ) Α4 Washing grid (210X297mm) -13- The Ministry of Economic Affairs Zhongzong Falcon Bureau β; industrial and consumer cooperatives printed A7 B7 V. Invention description (η) is different, generally between 200 ~ 15001cg / caa, 300 ~ 1200kg / cBa Fanpu is ideal. Before the ingot_forming, additives such as slips can be added in the fan garden without hindering the sweepability. Ingot_The slip agent added after forming, due to the high concentration, exists at the interface of the powder / particle block, which can improve the difficulty of removing the agent from the chess set. The ingot density is slightly different depending on the forming pressure of the composition, and is roughly within the range of 1.1 to 1.8g / c «3. The hardening resin molding material used for the birch chess set used in the tree wax composition ingot of the present invention includes, for example, epoxy resin molding material, phenol resin molding material, etc., among which the oxygen resin molding material is preferred, and the semiconductor Oxygen resin molding materials for encapsulation are more ideal. There are also two chess pieces suitable for the use of the resin composition tablet for the insertion wedge of the present invention. Any chess piece used for forming a curable resin molding material can be used. Generally, chess pieces made of iron, chromium and other materials are used On the more appropriate. The resin composition ingots for the chess game of the present invention not only does not reduce the effect of the broadcasting, but also increases the production rate. [Examples] The resin composition lozenges for the Cheong chess set of the present invention refer to the following examples and comparative examples, and further detailed explanations will be given. The test method of the sowing effect: «The sub-circuit of the sealed molded product is generally formed by the transfer-molding method using commercially available epoxy resin molding material tablets (NITRON MP trade name manufactured by Nitto Denko Corporation). After 400 times of injection molding, use and (please read the precautions on the back before filling out this page) -installed · This paper size is used in accordance with the Chinese standard (CNS) A4 washing grid (210X297mm) -14- A7 B7, printed by Beigong Consumer Cooperation, Central Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (l2) The above-mentioned materials have the same shape and are used to test the tree-shaped composition of the sowing chess set, formed in the same chess set, and then the number of shots is investigated. Public broadcast effect. As for the determination of the broadcast effect, 5 stages can be used as the criterion for visual judgment. 5: There is no residue at all 4: There is almost no residue at all 3: Slight residue 2: There is still residue 1: (Molded products> There are many pollution residues and defects. (2) Particle size measurement method: The particle size is determined in accordance with the JIS-R6001 (1973) document, and its approval method is measured in accordance with the JIS-R6002 document. Use it in details "# & q uot; refers to Fan or MESH. (3) Evaluation method of tablet formability: [for board-type filling and casting chess] First prepare a tablet-forming chess set (48b · 0 X 32 ·· H> and apply tablets The weight of the ingot of the forming eaves is adjusted to 75g, and then the prepared ingot-shaping forming material is put into the machine through the feeding funnel, and the pressure is added to 1000kg "8 until the pressure device is maintained, and the pressure is maintained for about 10 seconds. After forming, remove the lower part of the chess set and continue to lift until the ingot is pulled out. At this time, read the highest value of pressurization and observe whether the ingot _ is damaged (cracking, breaking) and other bad phenomena. In the same operation procedure, during the 100-value tablet forming process, the defect rate is calculated and its weight is measured. If the weight distribution is within 75 ± 3g (4% >> allowable range, it will be shown as 0. [Two-stage type For binding wedges] This paper uses the Chinese National Standard (CNS) A4 ^ grid (210X297mm) (please read the precautions on the back before filling out this page). Pack. Order
~ 15_ 經濟部中央標準局貝工消費合作社印裝 A7 B7 五、發明説明（l3 ) 首先備妥錠劑成形用棋具（14ββιΦ X 22.5bhH>並將錠 劑成形機之錠片重量予作調整為4. 5g·，接著將準備之錠 劑成形材料經给料漘斗投入機内，透遇加E裝置加E至 350kg/CI«a為止，保持此壓力約1分間，錠剤於是成形。 成形Μ後，将楔具下部卸下，再提离壓力直至綻剤被拔出 ，此時讀取其加壓最高值，同時觀察錠片是否有破損（剌 裂、破碎）等不良現象發生。經同樣作業程序100傾錠剤 成形遇程中，計算出其不良率，並測定其重量，若重量分 佈位於4.5g土 0.45g容許範園内則以” 0 w檷示之。 〔錠劑成形材料〕 Μ蜜胺343重量部和酚130重覺部和甲醛（3796水溶液> 517重量部與氫氧化鉀4重量部投入在付有攪拌檐装置之反 應槽中加熱反應而成蜜胺-酚共编合樹脂液。該蜜胺一酚 共缩合榭脂液190重纛部舆紙漿50重景部經揉捏機混辣後 乾燥，再加以粉碎而成樹脂混合物；取其30重量部輿曰本 力-八彳卜•工業（株）製二力b尹> S-176(商品名）50重*部 、粒度#200之矽石粉20重量部、安患香酸0.1重量部以及 加入十四烷基酸鋅0.5重量部，在球驩硏磨機内混合粉碎 而成樹脂组成物粉體（B〉。 另一方面，將上述過程所獲得樹脂成形物粉龌（B〉經 錠片成形機之給料漘斗供给成形後，再将該成形錠爾投入 錠Η粉碎機内依所#望之粒度大小，加以粉碎而得樹脂组 成物粒子（Α)。 上粒樹脂组成物粉鱧（Β>、上述樹脂组成物粒子（Α)， 本紙浪尺度適用中國國家標準（CNS ) Α4洗格（2丨0Χ297公釐） -1 6 - (請先閲讀背面之注意事項再填寫本頁) .裝- 訂 % % 經濟部中央揉準局貝工消費合作社印袈 32〇6〇q A7 B7 五、發明説明（Η ) Μ及依所望比率粉《(B)與粒子（Α)所組成各棰錠劑成形用 混合物，然後拥定表列中①〜⑨不同比率錠劑成形材料之 物性（相對比重及粒度分佈），並将所得结果記入表⑴内。 〔表1〕 ; :JT劑成形材嵙 粉鼉⑧ φ ③ ④ ⑤ ⑧ ⑦ ⑧ ⑨ 泣袖 拉刊0 :粉鳙⑧ 0 :10 1:9 2 : 8 3 : 7 4 : 6 5:5 6:4 7 : 3 8:2 9 : 1 10: 0 見掛比重 0.425 0.«5 α503 α545 0.578 1616 α647 0.701 α731 0.782 0.810 拉度分布（重量90 ΚΧ5»目癱餘:： 24期目鐮择 42獮目鐮餘： 80绢目β餘.. 8〇網目誨過. 0 0 0 5.9 94.1 2.8 2.7 1.4 &2 86.9 5.9 &1 2.5 6.0 79.5 9.5 8.5 4.4 6.1 71.5 IU 11.9 49 7.0 64.4 145 15.0 7.0 6.7 56.8 19.0 17.4 7.2 &7 49.7 21.3 20· 6 9.2 6.3 42.6 22.2 25.3 ία 3 6.1 36.1 2&1 27.3 12.4 5.8 2Β.4 31.1 29.9 143 5.2 19.5 (實施例1〜10及比較例1，2 ) 首先備妥錠劑成形用棋具（48βπι必X 32»bH)並將錠劑 成形機之錠片成形重量予作調整為75g，然後將上述表1内 所列示之錠剤成形材料，經给料漏斗投入機内，透過加壓 装置加壓至l〇〇〇kg/c·*，保持此壓力狀筋約10秒間，錠爾 於是成形。當加壓直至錠劑拔出時，讚取其加壓最高值， 計算其錠劑不良率、重鼉分佈範圍，以及測定其淸掎效果 ，將所獲得之结果記入表2内。 又完全由粉«成形之錠_，若其不良率必須降低至5% Μ下時，金靨皂之添加量必須維持在1.5重量部以上，若 比較例1中之金羼皂之添加量增加至1_7重量部時，其测 定結果如比較例2中所示。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 17~ 15_ Printed A7 B7 by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (l3) First prepare lozenge forming chess pieces (14ββιΦ X 22.5bhH > and adjust the tablet weight of the lozenge forming machine to 4. 5g ·, then put the prepared lozenge molding material into the machine through the feeding bucket, through the E adding device to add E to 350kg / CI «a, maintain this pressure for about 1 minute, the ingot is then shaped. After forming Μ , Remove the lower part of the wedge, and then lift off the pressure until the crack is pulled out. At this time, read the highest pressure value and observe whether the ingot is damaged (cracked, broken) and other bad phenomena. After the same operation In the process of forming a 100-pile ingot, the defect rate is calculated, and its weight is measured. If the weight distribution is within the allowable range of 4.5g soil and 0.45g, it will be shown as "0 w". [Tablet molding material] Μmelamine 343 parts by weight and phenol 130 parts by weight and formaldehyde (3796 aqueous solution> 517 parts by weight and 4 parts by weight of potassium hydroxide are put into a reaction tank equipped with a stirring eaves device and heated to react to form a melamine-phenol co-resin resin solution 。 The melamine monophenol co-condensation Xie fat solution 190 The 50-weight section of the Yubuyu Pulp 50 was mixed with a kneader and dried, and then crushed to form a resin mixture; the 30-weight portion of the Yuyue Benli-Hachibu • Industry Co., Ltd. Erli b Yin > S-176 (trade name) 50 weight * parts, 20 weight parts of silica powder with particle size # 200, 0.1 weight part of benzoic acid, and 0.5 weight part of zinc myristate added, mixed and crushed in a ball mill Resin composition powder (B>. On the other hand, after the resin molded product powder obtained in the above process (B> is fed to the feed hopper of the tablet forming machine for molding, the molded ingot is then poured into the ingot H for crushing The machine is crushed to obtain the resin composition particles (Α) according to the desired particle size. The upper resin composition powder (B>, the above resin composition particles (Α), the paper wave scale is applicable to the Chinese National Standard (CNS ) Α4 wash grid (2 丨 0Χ297mm) -1 6-(please read the precautions on the back and then fill out this page). Outfit-booked%% Central Ministry of Economic Affairs Bureau of Industry and Commerce Cooperative Printing Co., Ltd. 32〇6〇 q A7 B7 V. Description of the invention (Η) Μ and the ratio of powder (B) and particles (Α) according to the desired ratio Mixtures for the formation of each tablet, and then agree on the physical properties (relative specific gravity and particle size distribution) of the tablet forming materials with different ratios ① ~ ⑨ in the table, and record the results in Table ⑴. [Table 1];: JT agent Forming material 絙 粉 鼍 ⑧ φ ③ ④ ⑤ ⑧ ⑦ ⑧ ⑨ Weeping sleeves 0: powdered turtle ⑧ 0:10 1: 9 2: 8 3: 7 4: 6 5: 5 6: 4 7: 3 8: 2 9: 1 10: 0 See hanging specific gravity 0.425 0. «5 α503 α545 0.578 1616 α647 0.701 α731 0.782 0.810 Tensile distribution (weight 90 ΚΧ5» Muscular parasitic surplus :: 24th period Simu selected 42 绝 目 sequal Yu: 80 silk mesh Beta Yu: 8〇 Net mesh error. 0 0 0 5.9 94.1 2.8 2.7 1.4 & 2 86.9 5.9 & 1 2.5 6.0 79.5 9.5 8.5 4.4 6.1 71.5 IU 11.9 49 7.0 64.4 145 15.0 7.0 6.7 56.8 19.0 17.4 7.2 & 7 49.7 21.3 20 · 6 9.2 6.3 42.6 22.2 25.3 ία 3 6.1 36.1 2 & 1 27.3 12.4 5.8 2Β.4 31.1 29.9 143 5.2 19.5 (Examples 1 to 10 and Comparative Examples 1, 2) First prepare chess pieces for tablet formation ( 48βπι 必 X 32 »bH) and the tablet forming weight of the tablet forming machine is adjusted to 75g, and then the ingot forming materials listed in Table 1 above are The feeding funnel is put into the machine, and pressurized to 1000 kg / c · * through the pressurizing device, and this pressure-like rib is maintained for about 10 seconds, and the ingot is then formed. When pressurized until the tablet is pulled out, praise the highest value of pressurization, calculate the defect rate of tablet, distribution range of heavy mastic, and measure its effect, and record the obtained results in Table 2. If the defect rate must be reduced to 5% Μ, the addition amount of gold tar soap must be maintained at more than 1.5 parts by weight. If the addition amount of gold 羼 soap in Comparative Example 1 is increased When the weight reaches 1-7, the measurement results are as shown in Comparative Example 2. This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297mm) (please read the precautions on the back before filling in this page)
7 7 A B 五、發明説明（I5 ) 〔表2〕 '錠劑 成形材料^ 拉:扮 錠劑成形性 淸掃性 isasjsm (kg/cd) 不良率 (¾) .童舳 .敢佈 淸掃用樹脂组成物 射出數及淸押效果 1 2 3 4 5 6 7 8 ami 粉蘸〔B) .1 0 :10 '54.5 6 X 3 4 4 5 5 5 5 5 實施例1 ① 1:9 5 0.5 4 〇 3 4 5 5 5 5 5 5 實施例2 ② 2:8 47.5 3 〇 3 4 5 5 5 5 5 5 實施例3 ③ 3:7 45.0 2 〇 3 4 4 5 5 5 5 5 實施例4 ④ 4:6 42.0 1 〇 3 4 5 5 5 5 5 5 實施例5 ⑤ 5:5 38.0 2 〇 3 4 4 5 5 5 5 5 *施例6 ⑥ 6:4 35.0 1 〇 3 4 5 5 5 5 5 5 實施例7 ⑦ 7:3 32.0 0 〇 3 4 5 5 5 5 5 5 實施例8 ⑧ 8:2 28.5 1 〇 3 4 5 5 5 5 5 5 實施例9 <3) 9:1 25.5 1 〇 3 4 4 5 5 5 5 5 實施例10 拉福 10: 0 22.0 1 〇 3 4 5 5 5 5 5 5 賊例2 粉》(B) 〃 0 :10 5 0.0 4 X 2 2 3 3 3 4 4 5 *1 :含有金羼皂（十四烷基鋅）0.5重量部含有。 (請先閲讀背面之注意事項再填寫本頁) .裝·7 7 AB V. Description of the invention (I5) [Table 2] 'Tablet forming materials ^ Pull: Formability of tablet formability isasjsm (kg / cd) Defective rate (¾). Tong Ge. Dare to use for sweeping Number of injections of resin composition and pressing effect 1 2 3 4 5 6 7 8 ami powder dipping (B) .1 0: 10 '54 .5 6 X 3 4 4 5 5 5 5 5 Example 1 ① 1: 9 5 0.5 4 〇3 4 5 5 5 5 5 5 Example 2 ② 2: 8 47.5 3 〇3 4 5 5 5 5 5 5 5 Example 3 ③ 3: 7 45.0 2 〇3 4 4 5 5 5 5 5 Example 4 ④ 4 : 6 42.0 1 〇3 4 5 5 5 5 5 5 Example 5 ⑤ 5: 5 38.0 2 〇3 4 4 5 5 5 5 5 * Example 6 ⑥ 6: 4 35.0 1 〇3 4 5 5 5 5 5 5 Example 7 ⑦ 7: 3 32.0 0 〇3 4 5 5 5 5 5 5 Example 8 ⑧ 8: 2 28.5 1 〇3 4 5 5 5 5 5 5 Example 9 < 3) 9: 1 25.5 1 〇3 4 4 5 5 5 5 5 Example 10 Rafel 10: 0 22.0 1 〇3 4 5 5 5 5 5 5 Thief Example 2 Powder》 (B) 〃 0: 10 5 0.0 4 X 2 2 3 3 3 4 4 5 * 1: Contains Jinyi soap (tetradecyl zinc) 0.5 parts by weight. (Please read the precautions on the back before filling in this page).
、1T 經濟部中央梂準局員工消费合作社印製 *2:含有金靥皂（十四烷基鋅）1.7重量部含有。 (實施例11〜20及比較例3，4) 首先備妥錠爾成形用棋具（14βο«ΦΧ22.5βιβΗ)並特錠 片成形機之辁劑成形重量予作調整至4. 5g，再上述表1中 所列示之錠片成形材料經给料漏斗投入機内，透過加壓裝 置加®至350kg/c·8為止，保持此®力狀態約1分間，錠劑 於是成形。當加S直至錠劑拔出時，讀取其加壓最高值， 計算其錠劑不良率、重量分佈範圍、以及测定其淸掃效果 ，將所得之结果，記入表3內。 又完全由粉體成形之錠剤，若其不良率須維持在5 % 本紙張尺度適用t國國家橾準（CNS ) A4規格（210X297公釐） 18 - S2〇6Qq A7 B7 五、發明説明（l6 ) 以下時，金羼皂之添加童必須在1·5重董部Μ上；比較例3 中之金屬皂添加1增加至1.7重置部時，其拥定结果如比 較例4所示。 〔表3〕 錠劑成形性.. 淸 掃 性 .錠劑 拉:扮 加既滴値 不良率 重置 澝掃用樹脂组成物 .成形材科 散佈 Ιί出數及清播效果 〇cg/ai) (%) 1 2 3 4 5 6 7 8 amz 粉》〔Β) μ 0 :10 59.5 14 X 3 3 4 5 5 5 5 5 實施例11 ① 1:9 55.5 11 X 3 4 5 5 5 5 5 5 »施例12 (2) 2:8 52.0 7 X 3 4 5 5 5 5 5 5 買施例13 ③ 3 : 7 4 9.5 5 X 3 4 4 5 5 5 5 5 實施例14 ④ 4:6 4 7.0 3 X 3 4 5 5 5 5 5 5 實施例15 ⑤ 5:5 43.5 2 X 3 4 4 5 5 5 5 5 貢施例16 ⑥ 6 : 4 41.0 1 X 3 4 5 5 5 5 5 5 實施例17 ⑦ 7:3 3 7.0 1 〇 3 4 5 5 5 5 5 5 實施例18 ⑧ 8:2 33.5 0 〇 3 4 5 5 5 5 5 5 *施例19 ⑨ .9:1 29.5 1 〇 3 4 5 5 5 5 5 5 貧麁树20 mw 10: 0 27.0 1 〇 3 4 5 5 5 5 5 5 ismu 粉IKB) ·* 0 :10 5&0 5 X 2 2 2 3 3 4 4 5 經濟部中央揉準局貝工消费合作杜印製 *1 :含有金屬皂（十四烷基鋅）〇·5重*部含有。 *2:含有金屬皂（十四烷基鋅）1.7重董部含有。 〔產業上利用之可能性〕 本發明之淸揷棋具用樹脂組成物錠劑，不但不會使淸 掃棋具樹脂组成物的淸挿效果低下，更可Μ改善錠劑不良 率以及重Λ分佈狀態。 (請先閲讀背面之注意事項再填寫本頁)1. Printed by the 1T Employee Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. * 2: Contains 1.7 weight parts of gold tar soap (tetradecyl zinc). (Examples 11 to 20 and Comparative Examples 3 and 4) First prepare a chess set for ingot forming (14βο «ΦΧ22.5βιβΗ) and adjust the forming weight of the special tablet forming machine to 4. 5g, then the above table The ingot forming material listed in 1 is put into the machine through the feeding funnel, and is added to 350kg / c · 8 through the pressurizing device, and the force state is maintained for about 1 minute, and the tablets are then formed. When adding S until the tablet is pulled out, read the highest pressure value, calculate the tablet defect rate, weight distribution range, and measure its sweep effect, and record the results in Table 3. Ingots that are completely formed of powder, if the defect rate must be maintained at 5%, the paper scale is applicable to the national standard (CNS) A4 specifications (210X297 mm) of the country t 18-S2〇6Qq A7 B7 V. Description of the invention (l6 ) In the following cases, the addition of Jinyi soap must be on the 1.5-weight Dongbu M; when the metal soap added 1 in Comparative Example 3 is increased to the 1.7 reset, the result of its approval is shown in Comparative Example 4. [Table 3] Lozenge formability .. Sweepability. Lozenge pull: add a drop drop rate to reset the resin composition for sweeping. Forming materials division distribution number and cleaning effect (cg / ai) (%) 1 2 3 4 5 6 7 8 amz powder》 (Β) μ 0: 10 59.5 14 X 3 3 4 5 5 5 5 5 Example 11 ① 1: 9 55.5 11 X 3 4 5 5 5 5 5 5 »Example 12 (2) 2: 8 52.0 7 X 3 4 5 5 5 5 5 5 Buy Example 13 ③ 3: 7 4 9.5 5 X 3 4 4 5 5 5 5 5 Example 14 ④ 4: 6 4 7.0 3 X 3 4 5 5 5 5 5 5 Example 15 ⑤ 5: 5 43.5 2 X 3 4 4 5 5 5 5 5 5 Gong Shi Example 16 ⑥ 6: 4 41.0 1 X 3 4 5 5 5 5 5 5 Example 17 ⑦ 7: 3 3 7.0 1 〇3 4 5 5 5 5 5 5 Example 18 ⑧ 8: 2 33.5 0 〇3 4 5 5 5 5 5 5 * Example 19 ⑨ .9: 1 29.5 1 〇3 4 5 5 5 5 5 5 Poor tree 20 mw 10: 0 27.0 1 〇3 4 5 5 5 5 5 5 ismu pink IKB) * 0:10 5 & 0 5 X 2 2 2 3 3 4 4 5 Central Ministry of Economics Produced by Dupont Consumer Products Co., Ltd. * 1: Contains metal soap (tetradecyl zinc). Contains 5 parts *. * 2: Contains metal soap (tetradecyl zinc) 1.7 heavy board contains. [Possibility of industrial use] The resin composition lozenge for the game of chess of the present invention not only does not reduce the insertion effect of the resin composition of the game of chess, but also can improve the defect rate of the tablet and the distribution state of the heavy Λ . (Please read the notes on the back before filling this page)
各紙張尺度適用中國國家揉準（CNS ) Α4规格（210X297公釐） 19Each paper size is suitable for China National Standardization (CNS) Α4 specification (210X297mm) 19