TW305743B - - Google Patents

Download PDF

Info

Publication number
TW305743B
TW305743B TW083109780A TW83109780A TW305743B TW 305743 B TW305743 B TW 305743B TW 083109780 A TW083109780 A TW 083109780A TW 83109780 A TW83109780 A TW 83109780A TW 305743 B TW305743 B TW 305743B
Authority
TW
Taiwan
Prior art keywords
compound
parts
cns
page
please read
Prior art date
Application number
TW083109780A
Other languages
Chinese (zh)
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP27537193A external-priority patent/JP3307026B2/en
Priority claimed from JP5282640A external-priority patent/JPH07133203A/en
Priority claimed from JP28517993A external-priority patent/JP3393899B2/en
Priority claimed from JP14486394A external-priority patent/JP3435810B2/en
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Application granted granted Critical
Publication of TW305743B publication Critical patent/TW305743B/zh

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C07C233/13—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

A7 B7 305743 五、發明説明（1 )A7 B7 305743 5. Description of the invention (1)

Btff ΓΠ Ai*r OB · i®用圆 本發明係關於一種農業/園藝用之殺徽菌組成物。 先前技 以 菌劑， 蔓延的 足。因 因 好的合 文中簡 換 物，其 以 藝及相 前曾使 以控制 情況來 此有必 此，本 作殺徽 稱爲' 言之， 活性成 式I表 關技藝： 用某些殺徽菌劑來作爲農業/園藝用之殺徽 楢物病（如:稻瘟病）。但是，依照植物病 看，以前所用的殺徽菌劑之控制效能顯然不 要發展出更具效力的殺徽菌劑。 發明的目的要是提出一種對於植物病具有良 菌活性之農業/園藝用之殺徽菌組成物（下 本組成物# )。 本發明提出一種農業/園藝用之殺徽菌組成 份包含 示的臁胺衍生物：Btff ΓΠ Ai * r OB · i® Round This invention relates to an agricultural / horticultural microbicidal composition. The previous technique uses bacteria to spread the foot. Because of the good synopsis in the simple text, it is necessary to control the situation by art and phase. This is called the killing emblem. In other words, the active form of the watch I skills: use some killing emblems Bactericides are used as an agricultural / horticultural use to kill chrysalis disease (eg rice blast). However, according to plant diseases, it is obvious that the control efficacy of the previously used antimicrobial agents should not develop more effective antimicrobial agents. The purpose of the invention is to propose an agricultural / horticultural bactericidal composition (below composition #) which has good fungal activity against plant diseases. The present invention proposes an antimicrobial component for agricultural / horticultural use.

CH3 CNI I Π 一 r-CH - C一 NH——CH I || I CH, 〇 CHCH3 CNI I Π-r-CH-C-NH——CH I || I CH, 〇 CH

X 丫 (請先閲讀背面之注意事項再填寫本頁) -裝· 訂X YA (Please read the precautions on the back before filling out this page)-Pack · Order

U 經濟部中夹標準局員工消費合作社印製 其中，X是氳原子或氣康子，Y是氯原子或溴朦子，R是 甲基或乙烯基；及至少一種化合物，選自包括（E) — 2 (2 -氰基苯氧基）晡啶-4 —基氧代〕 苯基}一3 —甲氧基丙烯酸甲麵（化合物A) 、（Z) — 2 &gt; —甲基乙醣苯4，6 _二甲基喃啶一 2 —基腙（化合 物B ) 、〇 —乙基S，S-二苯基供磷連二硫酸癱（化合 本紙張尺度逋用中國國家橾隼（CNS ) A4規格（210X297公釐） A7 B7 五、發明説明（2 ) 物C) 、4，5，6，7 —四氣酞內豳（化合物D)、春 雷徽素（kasugamycin)(化合物 E) 、π，π，α — 三 氟_ 3 &gt; —異丙氣基一鄰—苯乙醣替苯胺（化合物F )、 1— (4 —氣笮基）—1—環戊基—3 —苯基脲（化合物 G)、有效徽索（validamycin)(化合物H) 3** —異 丙氧基一鄰一苯乙醣替苯胺（化合物I) 、6—（3，5U Printed by the Employee Consumer Cooperative of the China Bureau of Standards and Standards, Ministry of Economic Affairs, where X is a K atom or Qi Kang Zi, Y is a chlorine atom or a bromine, R is a methyl or vinyl group; — 2 (2-cyanophenoxy) -pyridin-4-yloxy] phenyl} -3-methoxyacrylic acid (compound A), (Z) — 2 &gt; —methyl ethyl sugar benzene 4,6 _Dimethylpyridine-2-ylhydrazone (Compound B), 〇-ethyl S, S-diphenyl phosphorous dihydrogen disulfate paralysis (combined with the paper scale of China National Falcon (CNS)) A4 specification (210X297mm) A7 B7 5. Description of the invention (2) Object C), 4,5,6,7-four gas phthalocyanine (compound D), kasugamycin (compound E), π , Π, α —Trifluoro_ 3 &gt; —Isopropylamino-o-phenylethylose aniline (Compound F), 1— (4 —Gasyl) -1-cyclopentyl-3-phenylurea (Compound G), effective myocardial (validamycin) (Compound H) 3 **-isopropoxy-o-phenothianiline (Compound I), 6— (3,5

—二氣一4 —甲基苯基）—3 (2H)噠瞭酮（化合物J )、1，3 —二瞎茂烷—2 —炔基丙二酸二異丙麵（化合 物 K) 、5 —甲基一1，2，4-三唑並〔3，4-b〕 苯並瞎唑（化合物L) 、3 —烯丙氧基一 1，2 —苯並異 瞎唑—1，2_二氧化物（化合物M)和1，2，5，6 —四氫—4H —吡咯並〔3，2，1 — i j }喹啉—4- 酮（化合物N )。 本發明所用以式I表示的醣胺衍生物之實例示於表1 (請先閱讀背面之注意事項再填寫本頁) •裝. 、νβ—2-gas-4—methylphenyl) —3 (2H) pyridone (compound J), 1,3-dibromocarbo-2-alkynylmalonate diisopropyl (compound K), 5 —Methyl-1,2,4-triazolo [3,4-b] Benzoazole (compound L), 3-allyloxy-1,2-benzisothiazole—1,2- Dioxide (compound M) and 1,2,5,6-tetrahydro-4H-pyrrolo [3,2,1-ij} quinolin-4-one (compound N). Examples of the sugar amine derivative represented by Formula I used in the present invention are shown in Table 1 (please read the precautions on the back before filling this page) • Install. Νβ

U 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） SG5743 A7 B7 表1 經濟部中央標準局員工消費合作社印袈 化合物 編號1 化學結構式 (1) (；Η 3 C N Cl C Η 3 —(：——CH - C— NH —CH Cl 1 II 1 ch3 0 CH3 (2) ch3 CN Cl CHp — CH — C ——CH - C— NH — CH -l· \—Cl 1 II 1 ch3 o ch3 (3) ch3 cn c丨 CH. C CH C NH CH —U \—Br 1 II 1 C H 3 0 C H 3 (4) ch3 cn ci CHP—CH — C-CH - C— NH — CH -M %—Br 1 II 1 V-/ ch3 〇 ch3 (5) C l·! 3 C N CH. —i；-CH - C— NH — CH -/^ %Cl i ii i A=y C H 3 0 C H 3 (請先閱讀背面之注意事項再填寫本頁) •裝· 訂U The standard paper printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs conforms to the Chinese National Standard (CNS) A4 (210X297 mm) SG5743 A7 B7 Table 1 The compound number 1 chemical structure of the Employee Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs 1) (; Η 3 CN Cl C Η 3 — (: —— CH-C— NH —CH Cl 1 II 1 ch3 0 CH3 (2) ch3 CN Cl CHp — CH — C ——CH-C— NH — CH -l · \ —Cl 1 II 1 ch3 o ch3 (3) ch3 cn c 丨 CH. C CH C NH CH —U \ —Br 1 II 1 CH 3 0 CH 3 (4) ch3 cn ci CHP—CH — C -CH-C— NH — CH -M% —Br 1 II 1 V- / ch3 〇ch3 (5) C l ·! 3 CN CH. —I; -CH-C— NH — CH-/ ^% Cl i ii i A = y CH 3 0 CH 3 (please read the precautions on the back before filling in this page) • Pack · Order

U 線 本紙張尺度適用中國鬮家標準（CNS ) A4規格（2丨〇X297公釐）_ g 05743 A7 B7 經濟部中夬橾隼局員工消費合作社印製 五、發明説明（4 ) 以式I表的臁胺衍生物述於japanese patent Kokai(Laid-〇pen)NO. 2-76846、 2-76845 及 1 — 15695l〇 (E)— 2— {2 —〔6— (2 — 氰基苯氧基）啧啶—4 一基氧代〕苯基}_ 3 一甲氧基丙 烯酸甲酯、（下文中稱之爲、化合物）述於、 Brighton Crop Protection Conference- Pests and Disease’，1992, pp.435-442 及 EP-0382375 (表 1 中之化 合物9 ) 。（Z) ~2 甲基乙醢苯4，6 —二甲基喃 啶-2 —基腙（下文中稱爲 '&quot;化合物β，）述於Japanese Patent Kokai Νο·6 1 — 2 1 5 5 1 〇 〇 —乙基 S , S — 二苯基偶磷連二硫酸酯（下文中稱爲、化合物）述於 Japanese Patent Koka i No.44-12919 ° 4 ， 5 » 6 » 7 一四氣酞內酯（下文中稱爲、化合物D # )述於Japanese Patent Koka i ( La i d - 0 p e n ) N o . 44-32592。春雷 徽素（下文中稱&quot;化合物E# )述於、The Pesticide Manual,9th edition’ ，515頁（由 The British Crop Protection Council 印行）。a » a ， a —三氣一3 一 — 異丙氧基一鄰一苯乙醢替苯胺（下文中稱爲•化合物 )述於 Japanese Patent Kokai No. 56 — 45907。 1 — ( 4 一氣苄基）一 1 一環戊基_ 3 _苯基朦（下文中 稱爲 * 化合物 G’ ）述於 Japanese Patent Kokai No. 5 5 — 5 0 0 1 4。有效徽素（下文中稱爲，化合物h# )述於、T h e P e s t i c i d e M a n u a 1 , 91 h e d i t i ο η ' , 8 5 5 頁（ 由 The British Crop Protection Council印行）。3 一 (請先聞讀背面之注意事項再填寫本頁) -裝· 訂 -線 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） 5 2 3 7 0 4 8 〇 6 -( A7 B7 五、發明説明（5 ) 一異丙氧(基一部一苯乙酿替莱胳The U-line paper size is applicable to the Chinese Kanjia Standard (CNS) A4 specification (2 x 297 mm) _ g 05743 A7 B7 Printed by the Consumer Cooperative of the Central Falcon Bureau of the Ministry of Economic Affairs V. Invention Instructions (4) Formula I Derivatives of the amphetamines in the table are described in Japanese patent Kokai (Laid-〇pen) NO. 2-76846, 2-76845 and 1-1569510 (E) —2— {2— [6— (2—cyanophenoxy Radical) pyridine-4 4-yloxo] phenyl} _3 methyl methoxyacrylate, (hereinafter referred to as compound) described in Brighton Crop Protection Conference- Pests and Disease ', 1992, pp. 435-442 and EP-0382375 (Compound 9 in Table 1). (Z) ~ 2 methylacetophenone 4,6-dimethylpyrimidin-2-ylhydrazone (hereinafter referred to as "&quot; compound β,") is described in Japanese Patent Kokai Νο · 6 1 — 2 1 5 5 1 〇〇—ethyl S, S — diphenylphosphorodiphenyl sulfate (hereinafter referred to as compound) described in Japanese Patent Koka i No. 44-12919 ° 4, 5 »6» 7 one four gas Lactone (hereinafter referred to as compound D #) is described in Japanese Patent Kokai (La id-0 pen) No. 44-32592. Chunlei Huisu (hereinafter referred to as &quot; Compound E #) is described in The Pesticide Manual, 9th edition ’, page 515 (printed by The British Crop Protection Council). a »a, a —Three gas one 3 one — Isopropoxy-o-phenoxyanilide (hereinafter referred to as • compound) is described in Japanese Patent Kokai No. 56 — 45907. 1 — (4 monobenzyl) -1 1 -cyclopentyl_ 3 _phenyl halo (hereinafter referred to as * compound G ’) is described in Japanese Patent Kokai No. 5 5 — 5 0 0 1 4. The effective emblem (hereinafter referred to as compound h #) is described in T h e P e s t i c i d e M a n u a 1, 91 h e d i t i ο η ', page 8 5 5 (printed by The British Crop Protection Council). 3 One (please read the precautions on the back before filling in this page)-Binding · Binding-The size of the line paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 5 2 3 7 0 4 8 〇6-( A7 B7 5. Description of the invention (5) One isopropoxyl

甘本胺（下文中稱爲、化合物I ’）述於 Japanese Patent lUkai No ，二氣—4 一甲基苯基 )-3 (211)_瞭_ (下文中稱爲、化合物】，）述於Glybenamine (hereinafter referred to as Compound I ') is described in Japanese Patent lUkai No, Diqi-4 monomethylphenyl) -3 (211) _ 了 _ (hereinafter referred to as, Compound),) described in

Japanese Patent Rokai ( Laid- Open) No 52 — 34928。i，3 —二睡茂烷—2_炔基丙二酸 二異丙醸（下文中稱爲、化合物〉述於JapaneseJapanese Patent Rokai (Laid- Open) No 52 — 34928. i, 3 —Dithiocarboxane-2-alkynylmalonic acid Diisopropylammonium (hereinafter referred to as compound) is described in Japanese

Patent Kokai Νο·4 7-3 4 1 2 6 。 5—甲基一1 , 2 ,4一三唑並〔3 , 4 — b〕苯並晡唑（下文中稱爲、化 合物 L 〃）述於 japanese Patent Kokai No. 5 4 - 1 8 3 3 8。3 -嫌丙氣基—1，2~苯並異_嗖 氧化物（下文中稱爲、化合物Μ，）述於Patent Kokai Νο · 4 7-3 4 1 2 6. 5-Methyl-1,2,4-triazolo [3,4-b] benzoxazole (hereinafter referred to as compound L 〃) is described in Japanese Patent Kokai No. 5 4-1 8 3 3 8 .3-Pyrogynyl-1,2-benziso-O-oxide (hereinafter referred to as compound M) is described in

Japanese Patent Kokai No.4 5-38080 〇 1 » 2 ，5，6 -四氫-吡咯並〔3，2，l-i j }喹啉一4 ~酬（下文中稱爲 化合物N# )述於Japanese Patent Koka iNo.52-48 1 76 〇 本組成物能夠以合作效應的方式控制的植物病包括稻 瘟病（Ρυγ i vu 1 ar i a ory zae )、葉稍紋枯病（Ri zoctonia solani、Helminiathosporiuin sigmoideum、Sclerotiun hvdeoph i1um 、 Sclerotium fumigatua N Sclerotium oryzaesat i vae )、長蟠孢菌葉斑病（Coch 1 i bo 1 us mivabeanus)、由 Sphaerulina orvzina、Magnaoor the sal i vini引發的植物病、果穗紋枯病之類。 以重置爲基礎，賅至少一種化合物與以式1表示的薩 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 丨線 經濟部中央橾準局員工消费合作社印製 經濟部中央標率局員工消費合作杜印装 305743 A7 B7五、發明説明（6 ) 胺衍生物之閱的混合比例通常介於0 . 0 1 :至1 0 0 0 :1之間。胲至少一種化合物輿以式I表示的臁胺衍生物 之間之較佳的m合比例解释如下。 就所得到的組成物之殺徽菌效用來考慮，當胲至少一 種化合物是化合物A時，以1份以式I表示的臁胺化合物 爲基礎，化合物A的混合比例通常爲0. 0 2至10 0份 ，以0. 2至20份爲佳。 就所得到的組成物之殺徽菌效用來考嫌，當賅至少一 種化合物是化合物B、C、D和E中的一或多者時，以1 份以式I表示的臁胺化合物爲基礎，化合物B、C、D和 E的總混合比例通常爲0. 01至1000份，以 0. 02至10份爲佳。更特定言之，將組成物的製造成 本列入考慮時，以1份以式I表示的酺胺化合物爲基礎， 化合物B、C和D的總浼合比例通常爲0. 5至5份，以 1份以式I表示的醢胺化合物爲基礎，化合物C的總混合 比例通常爲0. 1至0. 5份。 就所得到的組成物之殺徽菌效用來考嫌，當骸至少一 種化合物是化合物F、G、H、I和J中的一或多者時， 以1份以式I表示的醣胺化合物爲基礎，化合物F、G、 Η、I和J的總混合比例通常爲0. 0 1至1 0 0 0份， 以0. 02至100份爲隹。 就所得到的組成物之殺徽菌效用來考慮，當賅至少一 種化合物是化合物K、L、Μ和N中的一或多者時，以1 份以式I表示的臁胺化合物爲基礎，化合物K、L、Μ和 (請先閲讀背面之注意Ϋ項再填寫本頁) •裝· 訂 」丨 線 本紙張尺度適用中國國家梯準（CNS ) Α4規格（210Χ297公釐） 經濟部中央橾準扃員工消费合作社印裝 A 7 B7五、發明説明（7 ) N的總混合比例通常爲0. 01至10〇〇份，以〇.1 至10份爲佳。更特定言之，將組成物的製造成本列入考 嫌時，以1份以式I表示的臁胺化合物爲基礎，化合物K 、L、M和N的總混合比例以0. 5至10份爲佳。 以本組成物作爲農業/園藝用之殺徽菌組成物時，活 性成份與固態載镰、液態載體或氣態載《I混合。必要時， 可將界面活性劑或他種辅助劑加入而製成如油溶液、可乳 化的濃綰液、可濶濕的粉末、顆粒、微粒、溶液、懸浮液 、泡沬、微膠裹、ULV、育狀物之類。 道些製劑中所含有活性成份量爲0.1至99. 9重 置％，以0. 2至80重量％爲佳。 使活性成份與散佈劑（如：固態載體、液戆載镰…… …等）及視情況所須而使用的界面活性劑、固定劑、分散 劑、穩定劑、發泡劑或它們的混合物混合，可製得道些製 劑。固態載體之實例包括微細的粉末或頼粒或黏土（如： 高嶺土、较薄土、人工合成的水合氧化砂、Fubasami黏土 、膨瀾土、酸性黏土.........等）、滑石、他種無機物質（ 如：sericite、石英、硫、活性碳、碳酸鈣、水合矽石… ……等）及其類似物。液態載體之實例包括水、醇（如： 甲酵、乙醇.........等）、酮（如：丙酮、丁醑.........等） 、芳族烴（如：苯、甲苯、二甲苯、乙苯、甲某.........等 )、芳族烴（如：正己烷、環己酮、煤油、瓦斯油......... 等）、酯（如：乙醭乙酯、乙酸丁酯.........等）、睛（如 ••乙麻、異丁瞒.........等）、醚（如：二噁烷、二異丙醚 (請先閲讀背面之注意事項再填寫本頁) 裝. 訂 丨線 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公嫠） 3〇5743 Α7 Β7 經濟部中央棣準局員工消费合作社印製 五、發明説明（8 ) .........等）、酸臁胺（如：二甲替甲釀胺、二甲基乙醮胺 .........等）、鹵化烴（如：二氯乙烷、三氣乙烷、四氣化 碳.........等）及其類似物。 界面活性劑之實例包括烷基硫酸臁、烷基礴酸鑒、焼 基芳基礴酸Μ、聚氣化乙烯化合物、聚氣化乙烯乙二醚、 多羥基酵醐類、糖醚衍生物及其類似物。 固定劑和分敝劑之實例包括酪朊、明膠、多糖（如： 澱粉粉末、阿拉伯膠、織維索衍生物、藻朊酸.........等） 、木質索衍生物、膨潤土、糖、人工合成的水溶性聚合物 (如：聚乙烯酵、聚乙烯吡咯啉酮、聚丙烯酸.........等） 及其類似物。穩定劑之實例包括ΡΑΡ(磷酸異丙醮）、 ΒΗΤ (2，6 -二一特丁基一 4_ 甲酚）、ΒΗΑ (2 一特丁基一4 —甲氧基酚和3 —特丁基一 4 一甲氧基酚之 混合物）、植物油、破油、界面活性劑、脂肪酸或其酯類 及其類似物。 藉此而得到的製劑可以其製得形式使用或者可在經過 稀釋（如：以水稀释）之後使用。更特定言之，此製劑可 噴灑在植物上或以微粒形式施用在植物上；或者以顆粒形 式喷灑、以微粒形式施用或分敝在耕地的水面上或耕地的 土壤表面上。將製劑施用在耕地的土壤表面上之後，可不 定期地拥動土壤。同樣地，必要時，可將製劑添加到其表 面已施用過此製劑的土壤中。 此外，本組成物亦可先與他種殺徽菌劑、殺蟲劑、殺 蟎劑、殺線蟲劑、除草劑、植物生長調節劑、肥料或土壤 (請先閲讀背面之注意事項再填寫本頁) .裝. 訂 L 1 線 本紙張尺度逋用中國國家標準（CNS ) Α4规格（210X297公釐） -11 - A 7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（9 ) 調節劑混合之後才使用，或與它們间時施用。 本組成物的施用比例視活性成份的浪合比例、夫氣狀 況、製劑形式、時間、地點和施用方法、疾病種類、作物 種類之類而定。活性成份的施用比例一般是0. 1至 1 0 0 0克/百平公尺，以1至1 0 0克/百平公尺爲佳 。實施上，可乳化的濃鮪液、可濶禪的粉末、懸浮液和溶 液通常以水稀释至0. 0001至1%的澳度，以 0. 0 0 1至0. 1 %爲佳。顙粒和微粒以其製得的形式 施用。 實例： 下列製劑例、測試例之類用以對本發明作更詳細的說 明，但不欲對本發明之範國造成限制。在製劑例中，除非 特別聲明，否則所有的^份#和I百分比'皆以重量計。 此外，澜試用之以式I表示的醃胺衍生物依表I中所列的 化合物編號來辨豚。 製劑例1 1份化合物（選自化合物（1 )至（5 )中之一者以 上）、2份化合物A、8 8份高嶺土和9份滑石充分粉碎 之後混合，得到含有3 %活性成份的微粒。 製劑例2 1. 5份化合物（遘自化合物（1)至（5)中之一 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 U丨 線 表紙張尺度適用中國國家樣準〈CNS ) Μ規格（210X297公嫠） -12 - A7 B7 305743 i、發明説明（10) 者以上）、2. 5份化合物A、8 7份高嶺土和9份滑石 充分粉碎之後混合，得到含有4 %活性成份的微粒。 製劑例3 1 0份化合物（選自化合物（1 )至（5 )中之一者 以上）、1 〇份化合物A、3份聚氧化伸乙基山梨糖醇酐 單油酸酯、3份 CMC(羧甲基纖維索）和74份水泷 合，並進行濕式粉碎而得到含有2 0 %活性成份的想浮液 製劑例4 1 0份化合物（選自化合物（1 )至（5 )中之一者 以上）、2 0份化合物A、3份木質磺酸鈣、2份月桂基 磷酸鈉和6 5份人工合成的水合甎化矽充分粉碎之後混合 ，得到含有3 0%活性成份的可潤濕粉末。 製劑例5 2 0份化合物（遘自化合物（1 )至（5 )中之一者 以上）、3 0份化合物A、3份木質磺酸鈣、2份月桂基 硫酸鈉和4 5份人工合成的水合氧化矽充分粉碎之後混合 ，得到含有5 0 %活性成份的可瀾濕粉末。 製劑例6 1 0份化合物（選自化合物（1 )至（5 )中之一者 (請先閲讀背面之注意事項再填寫本頁) -裝· 、^1 U丨 線 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家樣牟（CNS ) A4规格（210X297公釐） _ ” - 經濟部中央標準局員工消費合作社印裝 A7 __B7 五、發明説明（11) 以上）、2 0份化合物A、1 4份聚氧化乙烯苯乙烯基苯 醚、6份十二碳烷基苯碓酸鈣和5 0份二甲苯充分混合， 得到含有3 0%活性成份的可乳化澳縮液。 製劑例7 1份化合物（遘自化合物（1)至（5)中之一者以 上）、8份化合物A、1份人工合成的水合氧化矽、2份 木質磷酸鈣、3 0份膨_土和5 7份高嶺土充分粉碎及混 合，然後將水加入藉此得到的混合物中。將此已加水的混 合物充分捏和、造粒並乾燥，得到含有1 0 %活性成份的 顆粒。 製劑例8 1. 5份化合物（選自化合物（1)至（5)中之一 者以上）、5份化合物A、1. 5份人工合成的水合氣化 矽、2份木質礁酸鈣、3 0份膨濶土和6 0份高嶺土充分 粉碎及混合。然後將水加入藉此得到的混合物中。將此已 加水的混合物充分捏和、造粒並乾燥，得到含有6. 5 % 活性成份的顆粒。 製劑例9 1份化合物（選自化合物（1)至（5)中之一者以 上）、1份選自化合物B至E之一的化合物、8 8份高嶺 土和1 0份滑石充分粉碎及混合，得到含有2 %活性成份 本紙張尺度適用中國國家樣準（CNS ) Α4規格（210Χ297公釐） -14 - (請先Μ讀背面之注意事項再填寫本頁) -裝. 訂 經濟部中央棣準局員工消費合作社印裝 A7 ____ B7 五、發明説明（12) 的微粒。 製劑例1 0 1 . 5份化合物（選自化合物（1)至（5)中之一 者以上）、2· 5份選自化合物B至E之一的化合物、 8 7份高嶺土和9份滑石充分粉碎及混合，得到含有4 % 活性成份的微粒。 製劑例1 1 1份化合物（遘自化合物（1)至（5)中之一者以 上）、2. 5份選自化合物B至E之一的化合物、8 7份 髙嶺土和9. 5份滑石充分粉碎及混合，得到含有3. 5 %活性成份的微粒。 製劑例1 2 1份化合物（遢自化合物（1)至（5)中之一者以 上）、2份選自化合物F至J之一的化合物、8 8份髙嶺 土和9份滑石充分粉碎及混合，得到含有3 %活性成份的 JUO, »- 微粒。 製劑例1 3 1 · 5份化合物（選自化合物（1)至（5)中之一 者以上）、2. 5份遘自化合物F至J之一的化合物、 8 7份高嶺土和9份滑石充分粉碎及混合，得到含有4 % 本紙張尺度適用中國國家樣準（CNS ) A4規格（210X297公釐） -- (請先閱讀背面之注意事項再填寫本頁) .裝. 訂 -線- 經濟部中夬梂準局貝工消費合作社印製 A7 B7 i、發明説明（13 ) 活性成份的徽粒。 製劑例1 4 1 0份化合物（邐自化合物（1 )至（5 )中之一者 以上）、1 〇份選自化合物F至J之一的化合物、3份聚 氧化伸乙基山梨糖酵酐單油酸廟、3份 CMC (Jt甲基 織維素）和7 4份水浪合，並進行濕式粉碎而得到含有2 0 %活性成份的懸浮液。 製劑例1 5 1 0份化合物（邐自化合物（1 )至（5〉中之一者 以上）、2 0份選自化合物F至J之一的化合物、3份木 質磺酸鈣、2份月桂基磷酸鈉和6 5份人工合成的水合氧 化矽充分粉碎之後混合，得到含有3 0 %活性成份的可髑 濕粉末。 製劑例1 6 2 0份化合物（遘自化合物（1 )至（5 )中之一者 以上）、3 0份選自化合物A至E之一的化合物、3份木 質礴酸鈣、2份月桂基硫酸鈉和4 5份人工合成的水合氧 化矽充分粉碎之後混合，得到含有5 〇 %活性成份的可漏 濕粉末。 製劑例1 7 (請先閲讀背面之注意事項再填寫本頁) -9 Γ 本紙張尺度適用中國國家橾準（CNS ) A4規格（210X297公釐） -16 - 經濟部中央棣準局員工消費合作社印製 A7 B7 五、發明説明（14 ) 1 0份化合物（遘自化合物（1 )至（5 )中之一者 以上）、2 0份選自化合物A至E之一的化合物、1 4份 聚氧化乙烯苯乙烯基苯醣、6份十二碳烷基苯《酸鈣和 5 0份二甲苯充分浪合，得到含有3 0 %活性成份的可乳 化澳艙液。 製劑例1 8 1份化合物（遘自化合物（1)至（5)中之一者以 上）、8份選自化合物A至E之一的化合物、1份人工合 成的水合氣化矽、2份木質《酸銬、3 0份膨土和5 7 份高嶺土充分粉碎及灌合，然後將水加入藉此得到的《合 物中。將此已加水的混合物充分捏和、造粒並乾燥，得到 含有10%活性成份的顆粒。 製劑例1 Θ 1. 5份化合物（遘自化合物（1)至（5)中之一 者以上）、5份選自化合物A至E之一的化合物、1. 5 份人工合成的水合氣化矽、2份木質磺酸鈣、3 0份膨瀾 土和6 0份髙嶺土充分粉碎及混合。然後將水加入藉此得 到的混合物中。將此已加水的灌合物充分捏和、造粒並乾 燥，得到含有6. 5%活性成份的顆粒。 製劑例2 0 4份化合物（選自化合物（1)至（5)中之一者以 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐) _ ]7 - (請先閲讀背面之注意事項再填寫本頁) -裝· 訂 線 經濟部中央棣芈局貝工消費合作杜印製 A7 ____B7_ 五、發明説明（15) 上）、1 2份化合物K、1份人工合成的水合氧化矽、2 份木質礴酸鈣、3 0份膨瀾土和5 1份高複土充分粉碎及 混合。然後將水加入藉此得到的混合物中。將此已加水的 混合物充分捏和、造粒並乾燥，得到含有6 . 5 %活性成 份的顆粒。 製劑例2 1 3份化合物（選自化合物（1 )至（5〉中之一者以 上）、4份化合物L、1份人工合成的水合氣化矽、2份 木質礴酸鈣、3 0份膨漘土和6 0份高嶺土充分粉碎及浪 合。然後將水加入藉此得到的混合物中。將此已加水的混 合物充分捏和、造粒並乾燥，得到含有7 %活性成份的顆 粒。 製劑例2 2 5份化合物（邐自化合物（1)至（5)中之一者以 上）、8份化合物Μ、1份人工合成的水合氧化矽、2份 木質礴酸鈣、3 0份膨瀾土和5 4份高嶺土充分粉碎及混 合。然後將水加入藉此得到的混合物中。將此已加水的混 合物充分捏和、造粒並乾燥，得到含有1 3 %活性成份的 顆粒。 製劑例2 3 5份化合物（選自化合物（1)至（5)中之一者以 本紙張尺度適用中國國家樣準（CNS ) Α4規格（210Χ25»7公釐） -18 - ----------裝------訂-----,I線 (請先閲讀背面之注意事項再填寫本頁) 305743 A7 B7 五、發明説明（16) 上）、2份化合物N、1份人工合成的水合氧化矽、2份 木質«酸鈣、3 0份膨土和6 0份高崔土充分粉碎及灌 合。然後將水加入藉此得到的《合物中。將此已加水的溫 合物充分捏和、造粒並乾燦，得到舍有7 %活性成份的顆 粒。 製劑例2 4 2份化合物（選自化合物（1 )至（5 )中之一者以 上）、2. 5份邐自化合物K至N之一的化合物、2. 5 份化合物Μ、8 5份离《土和8份滑石充分粉碎及拥合， 得到含有7%活性成份的徽粒。 製劑例2 5 1 0份化合物（選自化合物（1 )至（5 )中之一者 以上）、2 0份選自化合物K至N之一的化合物、3份聚 氧化伸乙基山梨糖醇酐單油酸酯、3份 CMC 和 6 4份水充分满合，並進行濕式粉碎而得到含有3 0%活 性成份的懸浮液。 製劑例2 6 1 〇份化合物（選自化合物（1 )至（5 )中之一者 以上）、2 0份選自化合物K至N之一的化合物、、2 0 份化合物Μ、3份木質磷酸鈣、2份月桂基磷酸鈉和4 5 份人工合成的水合氧化矽充分粉碎並混合，得到含有5 〇 -19 - ~~1 ~ (請先閲讀背面之注意事項再填寫本頁) •裝· 訂 h 線 經濟部中央標準局員工消费合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（17) %活性成份的可潤濕粉末。 製劑例2 7 10份化合物（選自化合物（1)至（5)中之一者 上）、2 0份選自化合物K至N之一的化合物、1 4份聚 氧化乙烯苯乙烯基苯醚、6份十二碳烷基苯磺酸鈣和5 0 份二甲苯充分混合，得到含有3 0 %活性成份的可浮化濃 縮液。 利用如下面所述的方法可將化合物（3 )和（4 )製 成製劑。 參考製劑例1 1份化合物（3)或（4) 、90份高嶺土和9份滑 石充分粉碎及混合，得到含有1 %化合物的微粒。 參考製劑例2 10份化合物&lt;3)或（4) 、3份聚氣化伸乙基山 梨糖醉酐單油酸豳、3份 CMC和84份水混合，並進 行濕式粉碎而得到含有1 0 %化合物的懸浮液。 參考製劑例3 20份化合物（3)或（4) 、3份木質礴酸鈣、2 份月桂基硫酸鈉和7 5份人工合成的水合氧化矽充分 粉碎並混合，得到含有2 0 %化合物的可潤濕粉末。 ---------裝— (請先閲讀背面之注意事項再填寫本頁) 訂 丨線 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -20 - 經濟部中央標準局貝工消費合作社印製 A7 B7 五、發明説明（18) 參考製劑例4 15份化合物（3)或（4) 、：14份聚氧化乙烯苯 乙烯基苯醚、6份十二碳烷基苯磺酸鈣和6 5份二甲苯充 分混合，得到舍有1 5 %化合物的可乳化澳艙液。 參考製劑例5 4份化合物（3)或（4) 、1份人工合成的水合氧 化矽、2份木貧礴酸鈣、3 0份膨潤土和6 3份高崔土充 分粉碎及混合。然後將水加入藉此得到的混合物中。將此 已加水的混合物充分捏和、造粒並乾燥，得到含有4 %化 合物的顆粒。 其他的化合物（1) 、（2) 、（5)和A至N也能 依照道些參考製劑例而製成製劑。 下列的測試例證實了就殺徽菌方面而言，以翠獨使用 以式I表示的醣胺衍生物或單獨使用A、B、C、D、E 、F、G、H、I、J、K、L、M或N與使用本組成物 來作爲農業/園繭用之殺徽菌組成物作比較，後者具有極 佳的合作效應。 測試例1:防止發生稻瘇病的活性弒驗 在塑膠盆中塡滿多沙的壤土，將稻（Kinki No. 3 3 )播在其中並於溫室中栽培2 0天。根據製劑例4製得含 有一或多種測試用化學品的可澜濕粉末。以水稀释至預定 本紙張尺度適用中國國家標率（CNS ) A4规格（210X297公釐） -21 - (請先閱讀背面之注意事項再填寫本頁) 裝· 線 A7 B7 五、發明説明（19) 的澳度，並將所得到的化學溶液喷灑在稻的莖和葉上，使 此化學溶液充分的固定在稻苗的葉面上。在化學溶液被風 吹乾之後，將稻瘇病源的胞子懸浮液喷灑在稻苗上使稻苗 受到感染。使此受到感染的稻苗處於2 4 °C、高濕度下 1 0天。第1 0天時，根據下列的控制指數來評估控制的 效果。 捽制指數_控制效果 5 未腐敗 4 不低於9 0 % 3 7 0 至 8 9 % 2 4 1 至 6 9 % 1 1 至 4 0 % 0 0 % 其結果示於表2。 (請先閲讀背面之注意事項再填寫本頁) •裝 -3 線 經濟部中央橾準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -22 - A7 經濟部中央橾準局員工消費合作杜印製 305743 B7 五、發明説明（2〇) 表2 試驗品 活性成份澳度 (ppm) 控制指數 化合物（1 ) 5 4 1 2 化合物（2 ) 5 4 1 2 化合物（3 ) 5 4 1 … 1 ...... 化合物（4 ) 5 4 1 1 化合物（5 ) 5 4 1 2 化合物A 2.5 4 1 3 化合物（1 ) + 5 + 2.5 5 化合物A 1 + 1 4 化合物（2 ) + 5 + 2.5 5 化合物A 1M 4 化合物（3 ) + 5十2 . 5 5 化合物A 卜1 3 化合物（4 ) + 5 + 2.5 5 化合物A 1 + 1 3 化合物（5 ) + 5 + 2,5 5 化合物A 卜1 4 (請先閲讀背面之注意事項再填寫本頁) -裝. 訂 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） A7 B7 五、發明説明（21) 測試例2:藉由水面施用的方式來防止發生稻癟病的活性 試驗 在Wagner盆（0. 0 1平方公尺）中塡滿多沙的壤土 然後加水，將稻（二葉階段，Kink i No.3 3 )移植至盆 中並於溫室中栽培7天。根據製劑例7製得含有一或多種 測試用化學品的颗粒。將它們施用在毎個盆的水面上。施 用7天之後，將稻瘇病源的胞子懸浮液喷灑在稻苗上使稻 苗受到感染。使此受到感染的稻苗處於2 4 °C、高濕度下 1 0天。第1 0天時，以與測試例1相同的方式，根據控 制指數來評估控制的效果。其結果示於表3。 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝工消费合作杜印製 本紙張尺度逋用中國國家標準（CNS}A4规格（210 X 297公釐） -24 - 五、發明説明（22 ) 表3 A7 B7 試驗品 活性成份施用比 例（克/ 1000平 方公尺 控制指數 化合物（1 ) 20 3 5 1 化合物（2 ) 20 3 5 1 化合物（3 ) 20 3 5 1 化合物（4 ) 20 3 5 1 化合物（5 ) 20 3 5 1 化合物A 100 4 60 2 化合物（1 ) + 20+100 5 化合物A 5 + 60 4 化合物（2 ) + 20+100 5 化合物A 5 + 60 4 化合物（3 ) + 20+100 5 化合物A 5 + 60 4 化合物（4 ) + 20+100 5 化合物A 5 + 60 4 化合物（5 ) + 20+100 5 化合物A 5 + 60 4 (請先閱讀背面之注意事項再填寫本頁) -裝. -9 線 經濟部中央標準局員工消費合作社印製 本紙張尺度逋用中國國家橾準（CNS ) A4規格（2丨Ο X 297公釐） -- A7 B7 五、發明説明（23 ) 測試例3:藉由水面施用的方式來防止發生葉稍紋枯病的 活性試驗 在fagner盆（0· 〇1平方公尺）中塡滿多沙的壤土 然後加水，將稻（二葉階段，Kinki No.3 3 )移植至盆 中並於溫室中栽培7天。根據製劑例7製得含有一或多種 測試用化學品的顆粒。將它們施用在每個盆的水面上。施 用7天之後，使稻苗底部受到葉鞲紋括病病源的感染。使 此受到感染的稻苗處於2 7 °C、高濕度下1 0天。第1 0 天時，以與測試例1相同的方式，根據控制指數來評估控 制的效果。其結果示於表4。 (請先閲讀背面之注意事項再填寫本頁) .裝 -訂 經濟部中央標準局員工消费合作社印裝 本紙張尺度逋用中國國家標率（CNS)A4規格（210x297公釐） -26 - 305743 at B7 五、發明説明（立¢) 表4 試驗品 活性成份施用比 例（克/ 1 000平 方公尺 控制指數 化合物（1 ) 200 0 50 0 化合物（2 ) 200 0 50 0 化合物（3 ) 200 0 50 0 化合物（4 ) 200 0 50 0 化合物（5 ) 200 0 50 0 化合物A 100 3 25 1 化合物（1 ) + 20+100 4 化合物A 50 + 25 2 化合物（2 ) + 20+100 4 化合物A 50 + 25 2 化合物（3 ) + 20+100 4 化合物A 50 + 25 2 化合物（4 ) + 20+100 4 化合物A 50 + 25 2 化合物（5 ) + 20+100 4 化合物A 50 + 25 2 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）Ί - 經濟部中央樣隼局員工消费合作社印裝 A7 B7五、發明説明（25) 測試例4:防止發生稻瘇病的活性及殘留作用弒驗 在塑膠盆中填滿多沙的壤土，將稻（Kinki No. 3 3 )播在其中並於溫室中栽培2 0天。根據製劑例4製得含 有一或多種測弒用化學品的可瀾濕粉末。以水稀释至預定 的濃度，並將所得到的化學溶液噴灑在稻的莖和葉上，使 此化學溶液充分的固定在稻苗的葉面上。在澜試防止發生 稻瘇病的效果方面，在化學溶液被風吹乾之後，將稻瘟病 湎的胞子懸浮液嘖瀝在稻苗上使稻苗受到感染。在澜試殘 留作用方面，使稻苗處於溫室達7天之後，將稻瘇病源的 胞子懸浮液瞳灑在稻苗上使稻苗受到感染。使受到感染的 稻苗處於2 4 °C、高湯度下1 0天，然後根據下列的控制 指數來評估控制的效果。 控制指數_控制效果 5 未腐敗 4 不低於9 0 % 3 7 0 至 8 9 % 2 4 1 至 6 9 % 1 1 至 4 0 % 0 0 % 其結果示於表5。 (請先閲讀背面之注意事項再樓寫本頁) •裝. 訂 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -28 - 五、發明説明（％ ) 表5 A7 B7 經濟部中央標準局員工消費合作社印製 試驗品 活性成份濃度 (ppm) 控制指數 殘留 活性 防止 活性 化合物（1 ) 5 4 4 1 2 2 化合物（2 ) 5 4 4 1 2........— ........2 化合物（3 ) 5 4 4 1 1 1 化合物（4 ) 5 4 4 1 1 1 化合物（5 ) 5 4 4 1 2 2 化合物Β 5 1 2 3 0 1 化合物C 5 1 2 3 0 1 化合物D 5 2 3 3 0 1 化合物Ε 5 1 2 3 0 1 化合物（1 ) + 5 + 5 5 5 化合物Β 卜3 4 4 化合物（2 ) + 5 + 5 5 5 化合物Β 1+3 4 4 化合物（3 ) + 5 + 5 5 5 化合物Β 1+3 4 4 化合物（4 ) + 5 + 5 5 5 化合物Β 1+3 4 4 化合物（5 ) + 5 + 5 5 5 化合物Β 卜3 4 4 化合物（1 ) + 5 + 5 5 5 化合物C 1+3 3 3 化合物（1 ) + 5 + 5 5 5 化合物D 1+3 4 4 化合物（1 ) + 5 + 5 5 5 化合物Ε 卜3 4 4 (請先閲讀背面之注意Ϋ項再填寫本頁) 裝·Japanese Patent Kokai No. 4 5-38080 〇1 »2,5,6-tetrahydro-pyrrolo [3,2, li j} quinoline-4 ~ (hereinafter referred to as compound N #) is described in Japanese Patent Koka iNo. 52-48 1 76 〇The plant diseases whose composition can be controlled in a cooperative effect include rice blast (Ρυγ i vu 1 ar ia ory zae), leaf mildew blight (Ri zoctonia solani, Helminiathosporiuin sigmoideum, Sclerotiun hvdeoph i1um, Sclerotium fumigatua N Sclerotium oryzaesat i vae), Coccidiosis leaf spot disease (Coch 1 i bo 1 us mivabeanus), plant diseases caused by Sphaerulina orvzina, Magnaoor the sal i vini, fruit sheath blight and the like. On the basis of resetting, at least one compound and the Sapphire paper scale expressed by Formula 1 are applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the precautions on the back before filling this page) · Booked by the Ministry of Economic Affairs, Central Bureau of Standardization, Employee Consumer Cooperatives, printed by the Ministry of Economic Affairs, Central Standardization Bureau, Employee Consumption Cooperation, Du Printed 305743 A7 B7 5. Invention Instructions (6) The mixing ratio of amine derivatives is usually between 0. 0 1: to 1 0 0 0: 1. The preferred ratio of at least one compound of hydroxylamine to the limonamide derivative represented by formula I is explained as follows. 0 2 至 Based on the microbicide effect of the resulting composition for consideration, when at least one compound of hydroxylamine is compound A, based on 1 part of the compound of formula I represented by formula I, the mixing ratio of compound A is usually 0.0 2 to 100 parts, preferably 0.2 to 20 parts. Based on the bactericidal effect of the obtained composition, when at least one compound is one or more of compounds B, C, D and E, based on 1 part of the compound of formula I represented by formula I 02 至 10 份 的 ，， B, C, D 和 E 的 总 总比 为 usually from 0.01 to 1000 parts, preferably from 0.02 to 10 parts. More specifically, when considering the manufacturing cost of the composition, based on 1 part of the amine compound represented by the formula I, the total ratio of the compounds B, C and D is usually 0.5 to 5 parts, 5 份。 Based on 1 part of the amide compound represented by the formula I, the total mixing ratio of the compound C is usually 0.1 to 0.5 parts. According to the antibacterial effect of the obtained composition, when at least one compound of the skeleton is one or more of the compounds F, G, H, I and J, 1 part of the glycosamine compound represented by the formula I As a basis, the total mixing ratio of the compounds F, G, Η, I and J is usually from 0.01 to 100 parts, and from 0.02 to 100 parts as a clam. Considering the fungicidal effect of the resulting composition, when at least one compound is one or more of the compounds K, L, M and N, based on 1 part of the compound of formula I represented by formula I, Compounds K, L, Μ and (please read the note Ϋ on the back before filling in this page) • Binding and Ordering 丨 The size of the paper is applicable to China National Standards (CNS) Α4 specifications (210 × 297 mm) Central Ministry of Economic Affairs Printed and printed by the quasi-employee consumer cooperative A 7 B7 V. Description of invention (7) The total mixing ratio of N is usually 0.01 to 100,000 parts, preferably 0.1 to 10 parts. More specifically, when the manufacturing cost of the composition is taken into consideration, based on 1 part of the compound of formula I represented by formula I, the total mixing ratio of the compounds K, L, M and N is 0.5 to 10 parts Better. When this composition is used as an antimicrobial composition for agriculture / horticulture, the active ingredient is mixed with a solid sickle, a liquid carrier, or a gaseous carrier. If necessary, surfactants or other auxiliary agents can be added to make oil solutions, emulsifiable concentrates, wettable powders, granules, microparticles, solutions, suspensions, foams, microgels, ULV, Yuyu and the like. The amount of active ingredient contained in these formulations is 0.1 to 99.9% by reset, preferably 0.2 to 80% by weight. Mix the active ingredient with the dispersing agent (eg solid carrier, liquid carrier sickle ... etc.) and the surfactant, fixing agent, dispersing agent, stabilizer, foaming agent or mixtures of them if necessary , Some preparations can be made. Examples of solid carriers include fine powder or perlite or clay (such as: kaolin, thinner soil, synthetic hydrated oxidized sand, Fubasami clay, bentonite, acid clay ... etc.), Talc, other inorganic substances (such as: sericite, quartz, sulfur, activated carbon, calcium carbonate, hydrated silica ... etc.) and the like. Examples of liquid carriers include water, alcohol (e.g., formazan, ethanol ..., etc.), ketones (e.g., acetone, butadiene ..., etc.), aromatic hydrocarbons (Such as: benzene, toluene, xylene, ethylbenzene, methyl .........), aromatic hydrocarbons (such as: n-hexane, cyclohexanone, kerosene, gas oil ... ... etc.), esters (e.g. ethyl ethyl acetate, butyl acetate ... etc.), eyes (e.g. acetoin, isobutyl conceal ... Etc.), ether (e.g. dioxane, diisopropyl ether (please read the precautions on the back and then fill out this page) for installation. The order of the paper size is applicable to the Chinese National Standard (CNS) A4 (210X297) 3〇5743 Α7 Β7 Printed by the Consumer Cooperative of the Central Department of Economics of the Ministry of Economic Affairs 5. Description of invention (8) ......... etc.), acid amine (eg: dimethylformamide, dimethylamine) Ethyl acetamide ... etc.), halogenated hydrocarbons (such as: dichloroethane, tri-gas ethane, tetra-gasified carbon ... etc.) and the like . Examples of surfactants include alkylsulfate, alkylsulfate, arylarylsulfate M, polygasified ethylene compounds, polygasified ethylene glycol diether, polyhydroxylase, sugar ether derivatives and Its analogs. Examples of fixatives and splitting agents include casein, gelatin, polysaccharides (such as: starch powder, acacia gum, vegetative derivatives, alginic acid, etc ...), lignin derivatives, Bentonite, sugar, synthetic water-soluble polymers (such as: polyvinyl yeast, polyvinylpyrrolidone, polyacrylic acid ... etc.) and the like. Examples of stabilizers include PAP (isopropyl phosphate), BHT (2,6-di-tert-butyl-4-cresol), BHA (2-tert-butyl-4-methoxyphenol and 3-tert-butyl 1-4 mixture of methoxyphenol), vegetable oil, oil breaker, surfactant, fatty acid or its esters and the like. The preparations obtained therefrom can be used in their prepared form or can be used after being diluted (for example, with water). More specifically, the preparation can be sprayed on plants or applied to plants in the form of particles; or sprayed in granular form, applied in the form of particles or divided on the water surface of cultivated land or the soil surface of cultivated land. After applying the formulation on the soil surface of the cultivated land, the soil can be occasionally agitated. Similarly, if necessary, the preparation may be added to the soil on which the preparation has been applied. In addition, this composition can also be combined with other kinds of fungicides, insecticides, acaricides, nematicides, herbicides, plant growth regulators, fertilizers or soil (please read the precautions on the back before filling in this Page). Packing. Order L 1 line paper size using Chinese National Standard (CNS) Α4 specifications (210X297 mm) -11-A 7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (9) The regulator is used after mixing, or it is sometimes applied with them. The application ratio of this composition depends on the wave combination ratio of the active ingredient, the state of the husband's gas, the form of the preparation, the time, the location and the method of application, the type of disease, and the type of crop. The application rate of the active ingredient is generally 0.1 to 100 g / 100 m, preferably 1 to 100 g / 100 m. In practice, emulsifiable concentrated tuna liquid, powders, suspensions, and solutions of Cuichan are usually diluted with water to an Australian degree of from 0.0001 to 1%, preferably from 0.01 to 0.1%. The granules and granules are applied in the form they are prepared. Examples: The following preparation examples, test examples and the like are used to explain the present invention in more detail, but do not intend to limit the scope of the present invention. In the formulation examples, unless specifically stated otherwise, all ^ Part # and I% 'are by weight. In addition, Lan tried the pickled amine derivatives represented by formula I to identify dolphins according to the compound numbers listed in Table I. Formulation Example 1 1 part of the compound (selected from one or more of compounds (1) to (5)), 2 parts of compound A, 88 parts of kaolin and 9 parts of talc are thoroughly pulverized and mixed to obtain fine particles containing 3% of the active ingredient . Formulation Example 2 1. 5 parts of the compound (from one of the compounds (1) to (5) (please read the precautions on the back before filling out this page) CNS) Μ specifications (210X297 gong mai) -12-A7 B7 305743 i, description of invention (10) or more), 2.5 parts of compound A, 87 parts of kaolin and 9 parts of talc are fully pulverized and mixed to obtain a content of 4% Particles of active ingredients. Formulation Example 3 10 parts of compound (selected from one or more of compounds (1) to (5)), 10 parts of compound A, 3 parts of polyoxyethylene sorbitan monooleate, 3 parts of CMC (Carboxymethylcellulose) was mixed with 74 parts of water and wet-pulverized to obtain a floating liquid formulation containing 20% of the active ingredient. Example 4 10 parts of the compound (selected from compounds (1) to (5)) One or more), 20 parts of compound A, 3 parts of calcium lignosulfonate, 2 parts of sodium lauryl phosphate, and 65 parts of synthetic hydrated fused silica are fully crushed and mixed to obtain a solution containing 30% of the active ingredient. Wetting powder. Formulation Example 5 20 parts of the compound (from one of the compounds (1) to (5) or more), 30 parts of the compound A, 3 parts of calcium lignosulfonate, 2 parts of sodium lauryl sulfate and 45 parts of artificial synthesis The hydrated silica is fully pulverized and mixed to obtain a wet powder containing 50% active ingredient. Formulation Example 6 10 compounds (selected from one of the compounds (1) to (5) (please read the precautions on the back and then fill out this page) -installed The paper printed by the consumer cooperative applies the Chinese national sample (CNS) A4 specification (210X297 mm) _ ”-A7 __B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention description (11) and above), 20 copies Compound A, 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of calcium dodecyl phthalate, and 50 parts of xylene were thoroughly mixed to obtain an emulsifiable Australian shrinkage liquid containing 30% of the active ingredient. Example 7 1 part compound (from one of compounds (1) to (5) or more), 8 parts Compound A, 1 part synthetic hydrated silica, 2 parts calcium lignophosphate, 30 parts bentonite and 5 7 parts of kaolin clay were fully crushed and mixed, and then water was added to the mixture thus obtained. This water-added mixture was kneaded, granulated, and dried to obtain granules containing 10% of the active ingredient. Formulation Example 8 1. 5 parts of compound (selected from one or more of compounds (1) to (5) ), 5 parts of compound A, 1.5 parts of artificially synthesized hydrated gasified silicon, 2 parts of calcium wood reefate, 30 parts of bentonite clay and 60 parts of kaolin clay are fully crushed and mixed. Then water is added In the mixture, the mixture to which water has been added is kneaded, granulated and dried to obtain granules containing 6.5% of the active ingredient. Formulation Example 9 1 part of the compound (selected from one of the compounds (1) to (5) Above), 1 part of compound selected from one of compounds B to E, 88 parts of kaolin and 10 parts of talc are fully crushed and mixed to obtain 2% active ingredients. This paper scale is applicable to China National Standards (CNS) Α4 specifications ( 210Χ297 mm) -14-(Please read the precautions on the back before filling in this page)-Pack. Order A7 ____ B7 printed by the Ministry of Economic Affairs, Central Bureau of Precinct Employee Consumer Cooperative V. Fifth, the invention (12) fine particles. Preparation Example 10 1.5 parts of the compound (selected from one or more of the compounds (1) to (5)), 2.5 parts of the compound selected from one of the compounds B to E, 87 parts of kaolin and 9 parts of talc are sufficient Pulverize and mix to obtain fine particles containing 4% of the active ingredient. 5 parts (from one of the compounds (1) to (5) or more), 2.5 parts of the compound selected from one of the compounds B to E, 8 7 parts of high-quality clay and 9.5 parts of talc fully crushed and mixed To obtain fine particles containing 3.5% of the active ingredient. Formulation Example 1 21 parts of the compound (from one or more of the compounds (1) to (5)), 2 parts of the compound selected from one of the compounds F to J, 8 8 parts of high-quality clay and 9 parts of talc are fully pulverized and mixed to obtain JUO, »-fine particles containing 3% of active ingredients. Formulation Example 1 3 1 · 5 parts of compound (selected from one or more of compounds (1) to (5)), 2.5 parts of compound from one of compounds F to J, 8 parts of kaolin and 9 parts of talc Fully crushed and mixed to obtain 4%. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm)-(please read the precautions on the back before filling this page). Packing. Order-Line-Economy A7 B7 i, invention description (13) of the active ingredient emblem printed by the Ministry of Economic Affairs and Industry Bureau of Pear Industry Consumer Cooperatives. Formulation Example 1 4 10 parts of a compound (one or more of compounds (1) to (5)), 10 parts of a compound selected from one of compounds F to J, 3 parts of polyoxyethylene sorbitan Anhydride monooleic acid temple, 3 parts of CMC (Jt methyl woven cellulose) and 74 parts of water waves are combined, and wet pulverized to obtain a suspension containing 20% of the active ingredient. Formulation Example 1 5 10 parts of the compound (compounding from one of the compounds (1) to (5) or more), 20 parts of the compound selected from one of the compounds F to J, 3 parts of calcium lignosulfonate, 2 parts of laurel Sodium phosphate and 65 parts of synthetic hydrated silica are fully crushed and mixed to obtain a wettable powder containing 30% of the active ingredient. Formulation Example 1 6 20 parts of the compound (from compound (1) to (5)) One or more of), 30 parts of a compound selected from one of compounds A to E, 3 parts of calcium lignate, 2 parts of sodium lauryl sulfate, and 45 parts of synthetic hydrated silica are fully pulverized and mixed to obtain Wettable powder containing 50% active ingredient. Formulation Example 1 7 (please read the precautions on the back before filling this page) -9 Γ This paper size is applicable to China National Standards (CNS) A4 (210X297mm) -16-A7 B7 printed by the Employee Consumer Cooperative of the Central Department of Economics and Trade of the Ministry of Economic Affairs V. Description of the invention (14) 10 parts of the compound (more than one of the compounds (1) to (5)), 20 parts are selected from Compound of one of compounds A to E, 14 parts polyoxyethylene styryl benzene sugar, 6 parts Dodecyl benzene "calcium acid and 50 parts of xylene are fully mixed to obtain an emulsifiable Australian cabin liquid containing 30% of the active ingredient. Formulation Example 18 1 part of the compound (from compound (1) to (5) One or more of), 8 parts of a compound selected from one of compounds A to E, 1 part of synthetic hydrated gasified silicon, 2 parts of wood "acid shackles, 30 parts of bentonite, and 5 7 parts of kaolin fully crushed and Pouring, and then adding water to the thus obtained mixture. The water-added mixture is kneaded, granulated, and dried to obtain granules containing 10% of the active ingredient. Formulation Example 1 Θ 1.5 parts of the compound ( From one of compounds (1) to (5) or more), 5 parts of a compound selected from one of compounds A to E, 1.5 parts of synthetically hydrated gasified silicon, 2 parts of calcium lignosulfonate, 3 5 Parts of bentonite and 60 parts of high-quality clay were fully crushed and mixed. Water was then added to the mixture thus obtained. The water-filled potting compound was kneaded, granulated, and dried to obtain a solution containing 6.5 % Active ingredient granules. Formulation Example 204 4 parts of compound (one selected from compounds (1) to (5) is based on the size of the paper Applicable to China National Standards (CNS) A4 specifications (210X297mm) _] 7-(Please read the notes on the back before filling in this page)-Installation · Threading and Printing A7 ____B7_ V. Description of the invention (15) above), 12 parts of compound K, 1 part of synthetic hydrated silicon oxide, 2 parts of calcium lindenate, 30 parts of bentonite and 51 parts of high-compound clay are fully crushed and mixed Then water is added to the mixture thus obtained. This water-added mixture is sufficiently kneaded, granulated and dried to obtain granules containing 6.5% of the active ingredient. Formulation Example 2 13 parts of compound (selected from one of compounds (1) to (5) or more), 4 parts of compound L, 1 part of synthetic hydrated gasified silicon, 2 parts of calcium lignosulfate, 30 parts The bentonite and 60 parts of kaolin are fully crushed and combined. Then water is added to the mixture thus obtained. This water-added mixture is sufficiently kneaded, granulated and dried to obtain granules containing 7% of the active ingredient. 2 2 5 parts of compound (one or more of compounds (1) to (5)), 8 parts of compound M, 1 part of synthetic hydrated silica, 2 parts of calcium lignosulfate, 30 parts of bentonite Pulverize and mix well with 54 parts of kaolin. Then add water to the mixture thus obtained. This water-added mixture is kneaded, granulated, and dried to obtain granules containing 13% of the active ingredient. Formulation Example 2 3 5 parts of the compound (one of the compounds (1) to (5) is applicable to the Chinese National Standards (CNS) Α4 specifications (210Χ25 »7mm) at this paper scale -18--------- --Installed ------ ordered -----, I line (please read the notes on the back before filling this page) 305743 A7 B7 5 Description of the invention (16) above), 2 parts of compound N, 1 part of synthetic hydrated silica, 2 parts of wood calcium carbonate, 30 parts of bentonite and 60 parts of kaite clay are fully crushed and infused. Then water Add it to the resulting compound. The water-added temperature compound is fully kneaded, granulated and dried to obtain granules containing 7% of the active ingredient. Preparation Example 2 42 parts of the compound (selected from the compound ( 1) to (5) or more), 2.5 parts of the compound from one of the compounds K to N, 2.5 parts of the compound M, 8 5 parts of the soil and 8 parts of talc are fully crushed and congested To obtain emblems containing 7% of the active ingredient. Formulation Example 2 5 10 parts of a compound (one or more selected from compounds (1) to (5)), 20 parts of a compound selected from one of compounds K to N , 3 parts of polyoxyethylidene sorbitan monooleate, 3 parts of CMC and 64 parts of water are fully filled, and wet pulverized to obtain a suspension containing 30% of the active ingredient. Formulation Example 2 6 10 parts of compound (selected from one or more of compounds (1) to (5)), 20 parts of compound selected from one of compounds K to N, and 20 parts of compound Substance M, 3 parts calcium lignophosphate, 2 parts sodium lauryl phosphate and 4 5 parts synthetic hydrated silica are fully pulverized and mixed to obtain a solution containing 5 〇-19-~~ 1 ~ (please read the notes on the back first (Fill in this page) • Packing and Ordering H The Central Standards Bureau of the Ministry of Economic Affairs Employee Consumer Cooperative printed this paper in accordance with the Chinese National Standard (CNS) A4 (210X297mm). The Ministry of Economic Affairs Central Standards Agency Employee Consumer Cooperative printed A7 B7. 2. Description of the invention (17)% wettable powder of active ingredient. Formulation Example 2 7 10 parts of compound (selected from one of compounds (1) to (5)), 20 parts of compound selected from one of compounds K to N, 14 parts of polyoxyethylene styryl phenyl ether 6. 6 parts of calcium dodecylbenzene sulfonate and 50 parts of xylene are thoroughly mixed to obtain a floatable concentrate containing 30% of the active ingredient. Compounds (3) and (4) can be prepared into formulations by the methods described below. Reference Formulation Example 1 1 part of compound (3) or (4), 90 parts of kaolin and 9 parts of talc are sufficiently pulverized and mixed to obtain fine particles containing 1% of the compound. Reference Formulation Example 2 10 parts of compound &lt; 3) or (4), 3 parts of polygasified ethoxylated sorbitan monooleate, 3 parts of CMC and 84 parts of water are mixed, and wet pulverized to obtain 10% suspension of compound. Reference Formulation Example 3 20 parts of compound (3) or (4), 3 parts of calcium lignate, 2 parts of sodium lauryl sulfate, and 75 parts of artificially synthesized hydrated silica are sufficiently pulverized and mixed to obtain a compound containing 20% of the compound Wettable powder. --------- installed — (Please read the precautions on the back before filling in this page) The book size of the line book is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) -20-Central Ministry of Economic Affairs A7 B7 printed by Beigong Consumer Cooperative of the Bureau of Standards 5. Description of the invention (18) Reference formulation example 4 15 parts of compound (3) or (4): 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of dodecane Calcium benzene sulfonate and 65 parts of xylene were mixed thoroughly to obtain an emulsifiable liquid containing 15% of the compound. Reference Formulation Example 5 4 parts of compound (3) or (4), 1 part of synthetic hydrated silica, 2 parts of calcium lindenate, 30 parts of bentonite, and 63 parts of kaite clay are fully pulverized and mixed. Then water was added to the mixture thus obtained. This water-added mixture was sufficiently kneaded, granulated and dried to obtain granules containing 4% of the compound. Other compounds (1), (2), (5), and A to N can also be formulated according to these reference formulation examples. The following test examples confirm that in terms of bactericidal fungi, the sugar amine derivative represented by formula I is used in Cui alone or A, B, C, D, E, F, G, H, I, J, K, L, M or N is compared with the use of this composition as a microbial killing composition for agriculture / cocoon, the latter has an excellent cooperative effect. Test Example 1: Activity test for preventing rice gall disease In a plastic pot filled with sandy loam, rice (Kinki No. 3 3) was sown in it and cultivated in a greenhouse for 20 days. According to Formulation Example 4, a wettable powder containing one or more test chemicals was prepared. Dilute with water to the predetermined paper size. Applicable to China National Standard (CNS) A4 specification (210X297mm) -21-(please read the precautions on the back before filling in this page) Installation · Line A7 B7 V. Invention description (19 ), And spray the resulting chemical solution on the stems and leaves of rice, so that the chemical solution is sufficiently fixed on the leaf surface of rice seedlings. After the chemical solution was blown dry by the wind, the cell suspension of rice gall disease was sprayed on the rice seedlings to infect the rice seedlings. Leave the infected rice seedlings at 24 ° C and high humidity for 10 days. On the 10th day, the control effect is evaluated according to the following control index. Control index_Control effect 5 No corruption 4 No less than 90% 3 7 0 to 8 9% 2 4 1 to 6 9% 1 1 to 4 0% 0 0% The results are shown in Table 2. (Please read the precautions on the back and then fill out this page) • Packing-3 lines This paper printed by the Central Consumers ’Bureau of the Ministry of Economic Affairs Employee Consumer Cooperative applies to the Chinese National Standard (CNS) A4 (210X 297mm) -22- A7 Printed by the Ministry of Economic Affairs of Central Central Bureau of Consumer Affairs and Cooperative Printing 305743 B7 V. Description of the invention (2〇) Table 2 Active ingredients of the test product (ppm) Control index Compound (1) 5 4 1 2 Compound (2) 5 4 1 2 Compound (3) 5 4 1… 1 ...... Compound (4) 5 4 1 1 Compound (5) 5 4 1 2 Compound A 2.5 4 1 3 Compound (1) + 5 + 2.5 5 Compound A 1 + 1 4 Compound (2) + 5 + 2.5 5 Compound A 1M 4 Compound (3) + 5 X 2. 5 5 Compound A Bu 1 3 Compound (4) + 5 + 2.5 5 Compound A 1 + 1 3 Compound ( 5) + 5 + 2,5 5 Compound A Bu 1 4 (please read the precautions on the back before filling in this page)-Packing. The paper size of the binding book is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm ) A7 B7 V. Description of the invention (21) Test Example 2: Preventing the occurrence of rice warts by applying water Wagner pots of loam soil resistance test (0. 01 m ^) in Chen full sandy then adding water, the rice (two-leaf stage, Kink i No.3 3) are transplanted to pots and cultivated in the greenhouse for 7 days. According to Formulation Example 7, granules containing one or more test chemicals were prepared. Apply them on the surface of each pot. Seven days after the application, the cell suspension of rice gall disease was sprayed on the rice seedlings to infect the rice seedlings. Leave the infected rice seedlings at 24 ° C and high humidity for 10 days. On the 10th day, in the same manner as in Test Example 1, the control effect was evaluated based on the control index. The results are shown in Table 3. (Please read the precautions on the back before filling in this page) The Ministry of Economic Affairs, Central Bureau of Standards, Puiong Consumer Co., Ltd. printed this paper using the Chinese National Standard (CNS) A4 (210 X 297 mm) -24-5 2. Description of the invention (22) Table 3 A7 B7 Application ratio of the active ingredients of the test article (g / 1000 m² Control index Compound (1) 20 3 5 1 Compound (2) 20 3 5 1 Compound (3) 20 3 5 1 Compound (4) 20 3 5 1 Compound (5) 20 3 5 1 Compound A 100 4 60 2 Compound (1) + 20 + 100 5 Compound A 5 + 60 4 Compound (2) + 20 + 100 5 Compound A 5 + 60 4 Compound (3) + 20 + 100 5 Compound A 5 + 60 4 Compound (4) + 20 + 100 5 Compound A 5 + 60 4 Compound (5) + 20 + 100 5 Compound A 5 + 60 4 (Please read first (Notes on the back and then fill out this page)-Packing. -9 This paper is printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is based on the Chinese National Standard (CNS) A4 specification (2 丨 Ο X 297mm)- A7 B7 V. Description of the invention (23) Test example 3: Preventing the occurrence of leaf wrinkles by applying water Activity test for blight in sandy fagner pots (0.01 square meters) filled with sandy loam and then added water, transplanted rice (two-leaf stage, Kinki No. 3 3) into pots and cultivated in the greenhouse for 7 days The granules containing one or more test chemicals were prepared according to Formulation Example 7. They were applied to the water surface of each pot. After 7 days of application, the bottom of the rice seedlings was infected by the pathogen of leaf streaks. Make this The infected rice seedlings were exposed to high humidity at 2 7 ° C for 10 days. On the 10th day, the control effect was evaluated according to the control index in the same manner as in Test Example 1. The results are shown in Table 4. ( Please read the precautions on the back and then fill out this page). Binding-book-printed papers printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The paper size is based on the China National Standard Rate (CNS) A4 specification (210x297 mm) -26-305743 at B7 V. Description of the invention (set ¢) Table 4 Application ratio of the active ingredients of the test article (g / 1 000 m 2 Control index Compound (1) 200 0 50 0 Compound (2) 200 0 50 0 Compound (3) 200 0 50 0 Compound (4) 200 0 50 0 Compound 5) 200 0 50 0 Compound A 100 3 25 1 Compound (1) + 20 + 100 4 Compound A 50 + 25 2 Compound (2) + 20 + 100 4 Compound A 50 + 25 2 Compound (3) + 20 + 100 4 Compound A 50 + 25 2 Compound (4) + 20 + 100 4 Compound A 50 + 25 2 Compound (5) + 20 + 100 4 Compound A 50 + 25 2 (Please read the notes on the back before filling this page) The paper printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 specification (210X 297mm) Ί-A7 B7 printed by the Employee Consumer Cooperative of the Central Sample Falcon Bureau of the Ministry of Economic Affairs V. Invention Instructions (25) Test Example 4: Activity and residual effect to prevent rice gall disease The plastic pots were filled with sandy loam, and rice (Kinki No. 3 3) was sown in it and cultivated in the greenhouse for 20 days. According to Formulation Example 4, a wettable powder containing one or more measuring chemicals was prepared. Dilute with water to a predetermined concentration, and spray the resulting chemical solution on the stems and leaves of rice, so that the chemical solution is sufficiently fixed on the leaf surface of the rice seedlings. In terms of the effectiveness of the Lanshi trial to prevent the occurrence of rice gall disease, after the chemical solution was blown dry by the wind, the suspension of rice blast cells was dripped on the rice seedlings to infect the rice seedlings. Regarding the residual effect of the Lan test, after leaving the rice seedlings in the greenhouse for 7 days, the rice seed infection cell suspension was sprinkled on the rice seedlings to infect the rice seedlings. Leave the infected rice seedlings at 24 ° C and high soup for 10 days, and then evaluate the control effect according to the following control index. Control index_Control effect 5 Not corrupt 4 Not less than 9 0% 3 7 0 to 8 9% 2 4 1 to 6 9% 1 1 to 4 0% 0 0% The results are shown in Table 5. (Please read the precautions on the back before writing this page) • Packing. The paper size of the binding is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) -28-V. Invention description (%) Table 5 A7 B7 Concentration of Active Ingredients (ppm) Controlled Index Residual Activity Prevention Active Compound (1) 5 4 4 1 2 2 Compound (2) 5 4 4 1 2 ....... . — ........ 2 Compound (3) 5 4 4 1 1 1 Compound (4) 5 4 4 1 1 1 Compound (5) 5 4 4 1 2 2 Compound B 5 1 2 3 0 1 Compound C 5 1 2 3 0 1 Compound D 5 2 3 3 0 1 Compound E 5 1 2 3 0 1 Compound (1) + 5 + 5 5 5 Compound B Bu 3 4 4 Compound (2) + 5 + 5 5 5 Compound Β 1 + 3 4 4 compound (3) + 5 + 5 5 5 compound Β 1 + 3 4 4 compound (4) + 5 + 5 5 5 compound Β 1 + 3 4 4 compound (5) + 5 + 5 5 5 Compound B Bu 3 4 4 Compound (1) + 5 + 5 5 5 Compound C 1 + 3 3 3 Compound (1) + 5 + 5 5 5 Compound D 1 + 3 4 4 Compound (1) + 5 + 5 5 5 Compound Ε Bu 3 4 4 ( Read the back of the note term Ϋ then fill out this page) installed ·

,1T 本紙張尺度適用中國國家樣準（CNS ) A4規格（210X297公釐） -i7?- A7 B7 _ 五、發明説明（27) 測試例5:對於稻疽病的治療活性試驗 在塑膠盆中塡滿多沙的壤土，將稻（Kinki No. 3 3 )播在其中並於溫室中栽培2 0天。將稻瘇病濂的胞子懇 浮液嘖漏在稻苗上使稻苗受到感染。使此受到感染的稻苗 處於2 4 °C、高濕度下1天。然後，以水將根據製劑例8 製之得含有一或多種測試用化學品的可乳化澳鮪液稀_至 預定的澳度，並將所得到的化學溶液喷灑在稻的莖和葉上 ，使此化學溶液充分的固定在稻苗的葉面上。在化學溶液 被風吹乾之後，使稻苗處於2 4 °C、高濕度下1 〇天，然 後比與測試例1相同的方式、根據控制指數來肝估控制的 效果。 其結果示於表6。 (請先閲讀背面之注意Ϋ項再填寫本頁) .裝. -6 線 經濟部中央標準局員4消費合作杜印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -30 - A7 B7 五、發明説明（）表6 試驗品 活性成份满度 (ΡΡΒ ) 控制指數 化合物（1 ) 200 0 化合物（2 ) 200 0 化合物（3 ) 200 0 化合物（4 ) 200 0 化合物（5 ) 200 0 化合物Β 10 .......„3 化合物C 2 5 2 化合物D 200 0 化合物Ε 5 3 化合物（1 ) + 200+10 4 化合物Β 化合物（2 ) + 200+10 4 化合物Β 化合物（3 ) + 200+10 4 化合物Β 化合物（4 ) + 200+10 4 化合物Β 化合物（5 ) + 200+10 4 化合物Β 化合物（1 ) + 200+25 4 化合物C 化合物（1 ) + 200 + 5 4 化合物Ε 化合物（1 &gt; + 200+25+200 5 化合物C + 化合物D 化合物（1 ) + 200+25+5 5 化合物D + 化合物Ε (請先閲讀背面之注意事項再填寫本頁) -裝- *-β 線- 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家橾準（CNS ) Α4規格（210Χ297公嫠） 305743 A? B7 經濟部中央標牟局員工消费合作社印裝 五、發明説明（29 ) 測試例6:防止發生稻痕病的活性試驗 在塑膠盆中塡滿多沙的壤土，將稻（Kinki No. 3 3 )播在其中並於溫室中栽培2 0天。根據製劑例4製得含 有一或多種測試用化學品的可濶濕粉末。以水稀釋至預定 的濃度，並將所得到的化學溶液嘖灑在稻的莖和葉上，使 此化學溶液充分的固定在稻苗的葉面上。在化學溶裤被風 吹乾之後，將稻瘇病灝的胞子懸浮液嘖灑在稻苗上使稻苗 受到感染。使此受到感染的稻苗處於2 4 *€、高濕度下 1 〇天，然後根據下列的控制指數來評估控制的效果。 控制指數_控制效果 5 未腐敗 4 不低於9 0 % 3 7 0 至 8 9 % 2 4 1 至 6 9 % 1 1 至 4 0 % 0 0 % 其結果示於表7。 裝—— I I訂—— 線 (請先閲讀背面之注f項再填寫本頁) 本紙張尺度適用中國國家梂準（CNS ) A4规格（210X297公釐） -32 - 五、發明説明（30) 表7 A7 B7 經濟部中央標準局員工消費合作社印製 試驗品 活性成份澳度 (ppm) 控制指數 化合物（1 ) 5 4 1 2 化合物（2 ) 5 4 1 2 化合物（3 ) 5 4 化合物（4 ) 1 5 4 化合物（5 ) 1 5 1 4 1 2 化合物F 500 0 100 0 化合物G 500 0 100 0 化合物Η 500 0 100 0 化合物I 500 0 100 0 化合物J 500 0 100 0 化合物（1 ) + 5 + 500 5 化合物F 1 + 100 4 化合物（2 ) + 5 + 500 5 化合物F 1 + 100 4 化合物（3 ) + 5 + 500 5 化合物F 卜100 3 化合物（4 ) + 5 + 500 5 化合物F 1 + 100 3 化合物（5 ) + 5 + 500 5 化合物F 1 + 100 4 化合物（1 ) + 5 + 500 5 化合物G 1 + 100 4 化合物（1 ) + 5 + 500 5 化合物Η 卜100 4 化合物（1 ) + 5 + 500 5 化合物I 1 + 100 4 化合物（1 ) + 5 + 500 5 化合物J 1 + 100 4 (請先閲讀背面之注意事項再填寫本頁) -裝· 訂 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 33 - 經濟部中央掭率局員工消费合作社印装 A7 B7五、發明説明（31) 測試例7:藉由水面施用的方式來防止發生稻瘇病的活性 試驗 在Wagner盆（0. 0 1平方公尺）中填滿多沙的壤土 然後加水，將稻（二葉階段，Kink i No .3 3 )移植至盆 中並於溫室中栽培7天。根據製劑例7製得含有一或多種 測試用化學品的顆粒。將它們施用在毎個盆的水面上。施 用7天之後，將稻瘇病源的胞子懸浮液喷灑在稻苗上使稻 苗受到感染。使此受到感染的稻苗處於2 4Ό、高濕度下 10天。第10天時，以與測試例1相同的方式，根據控 制指數來評估控制的效果。其結果示於表8。 (請先閲讀背面之注意Ϋ項再填寫本頁) -裝 訂 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） ~ 34 &quot; B7 五、發明説明（32) 表8 試驗品 活性成份施用比 例（克/ 1 000平 方公尺 控制指數 化合物（1 ) 20 3 5 1 化合物（2 ) 20 3 化合物（3 ) D 20 1 .........3 化合物（4 ) 0 20 1 3 5 1 化合物（5 ) 20 3 5 1 化合物F 400 0 100 0 化合物（1 ) + 20+400 4 化合物F 5+100 3 化合物（2 ) + 20+400 4 化合物F 5 + 100 3 化合物（3 ) + 20十400 4 化合物F 5+100 3 化合物（4 ) + 20+400 4 化合物F 5+100 3 化合物（5 ) + 20+400 4 化合物F 5+100 3 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） -35 - 305743 A7 _B7__ 五、發明説明（33) 渕試例8:防止發生葉鞘紋枯病的活性試驗 在盆中塡滿多沙的壤土，將稻（Kinki No.3 3 ) # 在其中並於溫室中栽培2 0天。根據製剤例3製得含有一 或多種澜弑用化學品的懸浮液。以水稀釋至預定的澳度， 並將所得到的化學溶液喷灑在稻的莖和葉上，使此化學溶 液充分的固定在稻苗的葉面上。在化學溶液被風吹乾之後 ，使稻苗底部受到葉糖紋枯病病源於感染。使此受到感染 的稻苗處於2 7 °C、高濕度下1 0天，然後以與測轼例1 相同的方式、根嫌控制指數來評估控制的效果。其結果示 於表9。 -- f { I I I I I 1 I I 裝— I I I I I 訂 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 本紙張尺度適用中國國家梯準（CNS ) A4規格（210X297公釐） -36 ~ A7 B7 五、發明説明（34) 表9 經濟部中央榡準局員工消費合作社印製 試驗品 活性成份澳度 (ppm) 控制指數 化合物（1 ) 500 0 100 0 化合物（2 ) 500 0 100 0 化合物（3 ) 500 0 100 -......... 化合物（4 ) 500 0 100 0 化合物（5 ) 500 0 100 0 化合物F 10 3 5 1 化合物G 5 3 1 . 25 1 化合物Η 10 3 5 1 化合物I 30 3 10 0 化合物J 30 3 10 0 化合物（1 ) + 500+10 4 化合物F 100 + 5 2 化合物（2 ) + 500+10 4 化合物F 100 + 5 2 化合物（3 ) + 500+10 4 化合物F 100.5 2 化合物（4 ) + 500+10 4 化合物F 100 + 5 2 化合物（5 ) + 500 + 5 4 化合物F 100 + 5 2 化合物（1 ) + 500 + 5 4 化合物G 100+1.25 2 化合物（1 ) + 500+10 4 化合物Η 100 + 5 2 化合物（1 ) + 500+30 4 化合物I 100+10 1 化合物（1 ) + 500+30 4 化合物J 100+10 1 (請先閲讀背面之注意事項再填寫本頁) 本紙張又度適用中國國家揉準（CNS ) A4规格（210X297公嫠） -37 - A7 B7 五、發明説明（35) 測試例9:藉由水面施用的方式來防止發生菜鞲紋枯病的 活性試驗 在Wagner盆（0· 0 1平方公尺）中填滿多沙的壤土 然後加水，將稻（二葉唯段，Kinki No.3 3 )移植至盆 中並於溫室中栽培7天。根嫌製劑例7製得含有一或多種 澜試用化學品的顆粒。將它們施用在毎個盆的水面上。施 用7天之後，將稻苗底部受到葉鞲紋枯病病灝的感染。使 此受到感染的稻苗處於2 7 eC、高濕度下1 0天，然後以 與澜試例1相同的方式、根鐮控制指數來評估控制的效果 。其結果示於表1 0。 (請先閱讀背面之注意事項再填寫本頁) -裝. 、-=* 經濟部中央標準局員工消費合作杜印製 本紙張尺度適用中國國家標準（CNS &gt; A4規格（210 X 297公釐） ** 38 ~ 305743 A7 B7 五、發明説明（36 ) 表1 0 試驗品 活性成份施用比 例（克/ 1000平 方公尺 控制指數 化合物（1 ) 200 0 50 0 化合物（2 ) 200 0 50 0 化合物（3 ) 200 .......〇 50 0 化合物（4 ) 200 0 50 0 化合物（5 &gt; 200 0 50 0 化合物F 30 3 10 1 化合物（1 ) + 200+30 4 化合物F 50+10 2 化合物（2 ) + 200+30 4 化合物F 50 + 10 2 化合物（3 ) + 200+30 4 化合物F 50+10 2 化合物（4 ) + 200+30 4 化合物F 50+10 2 化合物（5 ) + 200+30 4 化合物F 50+10 2 裝 —訂 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家橾準（CNS )八4規格（210X297公釐&gt; -39 - A7 B7 五、發明説明（37) 测試例10:防止發生稻瘟病的活性及殘留作用弒驗 在塑膠盆中塡滿多沙的壤土，將稻（Kinki No. 3 3 )播在其中並於溫室中栽培2 0天。根據製劑例7製得含 有一或多種测試用化學品的可潤濕粉末。以水稀釋至預定 的濃度，並將所得到的化學溶液啸漏在稻的莖和葉上，使 此化學溶液充分的固定在稻苗的葉面上。在測試防止發生 稻瘇病的效果方面，在化學溶液被風吹乾之後，將稻瘇病 源的胞子懸浮液喷灑在稻苗上使稻苗受到感染。在測試殘 留作用方面，使稻苗處於溫室達7天之後，將稻瘇病源的 胞子懸浮液嘖灑在稻苗上使稻苗受到感染。使受到感染的 稻苗處於2 4 eC、髙漯度下1 〇天，然後根據下列的控制 指數來評估控制的效果。 n I I n I I I I n 訂 (請先閲讀背面之注意事項再填寫本頁) 控制指齡 控制效果 經濟部中央榡準局員工消費合作衽印製 5 4 3 2 1 0 其結果示於表1 1 未腐敗 不低於9 0 % 7 0 至 8 9 % 4 1 至 6 9 % 1 至 4 0 % 0 %, 1T This paper scale is applicable to China National Standards (CNS) A4 specifications (210X297 mm) -i7?-A7 B7 _ V. Description of invention (27) Test example 5: Test for the therapeutic activity of rice anthracnose in a plastic basin It was filled with sandy loam, and rice (Kinki No. 3 3) was sown in it and cultivated in the greenhouse for 20 days. Infect the rice seedlings by leaking the floating cells of rice galls onto the rice seedlings. Leave the infected rice seedlings at 24 ° C and high humidity for 1 day. Then, the emulsifiable mackerel liquid containing one or more test chemicals prepared according to Formulation Example 8 was diluted with water to a predetermined degree, and the resulting chemical solution was sprayed on the stems and leaves of rice So that the chemical solution is sufficiently fixed on the leaf surface of rice seedlings. After the chemical solution was dried by the wind, the rice seedlings were placed at 24 ° C and high humidity for 10 days, and then the control effect was evaluated according to the control index in the same manner as in Test Example 1. The results are shown in Table 6. (Please read the note Ϋ on the back before filling in this page). Packing. -6 Members of the Central Standards Bureau of the Ministry of Economic Affairs 4 Consumer Cooperation Du Printed Paper The standard of this paper is the Chinese National Standard (CNS) A4 specification (210X 297 mm)- 30-A7 B7 V. Description of the invention () Table 6 The fullness of the active ingredients of the test article (PPB) Control index Compound (1) 200 0 Compound (2) 200 0 Compound (3) 200 0 Compound (4) 200 0 Compound (5 ) 200 0 Compound B 10... „3 Compound C 2 5 2 Compound D 200 0 Compound E 5 3 Compound (1) + 200 + 10 4 Compound B Compound (2) + 200 + 10 4 Compound B Compound (3) + 200 + 10 4 Compound B Compound (4) + 200 + 10 4 Compound B Compound (5) + 200 + 10 4 Compound B Compound (1) + 200 + 25 4 Compound C Compound (1) + 200 + 5 4 compound E compound (1 &gt; + 200 + 25 + 200 5 compound C + compound D compound (1) + 200 + 25 + 5 5 compound D + compound E (please read the notes on the back before filling this page ) -Installed- * -β Line-Member of the Central Standards Bureau of the Ministry of Economic Affairs The paper standard printed by the consumer cooperative applies the Chinese National Standard (CNS) Α4 specification (210Χ297 public daughter) 305743 A? B7 Printed by the consumer consumer cooperative of the Central Standard Bureau of the Ministry of Economy V. Invention description (29) Test example 6: Prevent occurrence The activity test of rice scar disease is filled with sandy loam in a plastic pot, and rice (Kinki No. 3 3) is sown in it and cultivated in the greenhouse for 20 days. It is prepared according to Formulation Example 4 and contains one or more tests Wettable powder of chemicals. Dilute with water to a predetermined concentration, and sprinkle the resulting chemical solution on the stems and leaves of rice, so that the chemical solution is fully fixed on the leaf surface of rice seedlings. After the trousers were dried by the wind, the cell suspension of rice gall disease was sprinkled on the rice seedlings to infect the rice seedlings. The infected rice seedlings were exposed to 24 * €, high humidity for 10 days, and then according to The following control index is used to evaluate the effect of control: control index_control effect 5 not corrupt 4 not less than 9 0% 3 7 0 to 8 9% 2 4 1 to 6 9% 1 1 to 4 0% 0 0% The result Shown in Table 7. Packing-II order-line (please read the back of the first Please fill in this page again in item f) This paper scale is applicable to China National Standards (CNS) A4 (210X297 mm) -32-V. Description of invention (30) Table 7 A7 B7 Printed test by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Active ingredient au-degree (ppm) Control index Compound (1) 5 4 1 2 Compound (2) 5 4 1 2 Compound (3) 5 4 Compound (4) 1 5 4 Compound (5) 1 5 1 4 1 2 Compound F 500 0 100 0 Compound G 500 0 100 0 Compound H 500 0 100 0 Compound I 500 0 100 0 Compound J 500 0 100 0 Compound (1) + 5 + 500 5 Compound F 1 + 100 4 Compound (2) + 5 + 500 5 Compound F 1 + 100 4 Compound (3) + 5 + 500 5 Compound F Bu 100 3 Compound (4) + 5 + 500 5 Compound F 1 + 100 3 Compound (5) + 5 + 500 5 Compound F 1 + 100 4 Compound (1) + 5 + 500 5 Compound G 1 + 100 4 Compound (1) + 5 + 500 5 Compound H Bu 100 4 Compound (1) + 5 + 500 5 Compound I 1 + 100 4 Compound (1 ) + 5 + 500 5 Compound J 1 + 100 4 (Please read the notes on the back before filling This page)-The paper size of the binding and binding book is in accordance with the Chinese National Standard (CNS) A4 (210X 297 mm) 33-The A7 B7 printed by the Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs V. Invention description (31) Test example 7: Active test to prevent the occurrence of rice gall disease by water surface application. Fill the sandy loam in the Wagner pot (0.01 square meters) and add water to remove the rice (two-leaf stage, Kink i No .3 3) Transplanted into pots and cultivated in the greenhouse for 7 days. According to Formulation Example 7, granules containing one or more test chemicals were prepared. Apply them on the surface of each pot. Seven days after the application, the cell suspension of rice gall disease was sprayed on the rice seedlings to infect the rice seedlings. The infected rice seedlings were exposed to 2 4Ό and high humidity for 10 days. On the 10th day, in the same manner as in Test Example 1, the control effect was evaluated based on the control index. The results are shown in Table 8. (Please read the note Ϋ on the back before filling in this page) -The size of the bound paper is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) ~ 34 &quot; B7 V. Invention description (32) Table 8 Test activity Ingredient application rate (g / 1,000 m² control index Compound (1) 20 3 5 1 Compound (2) 20 3 Compound (3) D 20 1 ......... 3 Compound (4) 0 20 1 3 5 1 Compound (5) 20 3 5 1 Compound F 400 0 100 0 Compound (1) + 20 + 400 4 Compound F 5 + 100 3 Compound (2) + 20 + 400 4 Compound F 5 + 100 3 Compound ( 3) + 20 + 400 4 Compound F 5 + 100 3 Compound (4) + 20 + 400 4 Compound F 5 + 100 3 Compound (5) + 20 + 400 4 Compound F 5 + 100 3 (Please read the notes on the back first Please fill in this page again.) The paper standard printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) -35-305743 A7 _B7__ 5. Description of the invention (33) Example 8 : An activity test to prevent the occurrence of leaf sheath sheath blight in a pot filled with sandy loam, rice (Kinki No.3 3) # In it and cultivated in the greenhouse for 20 days. According to Preparation Example 3, a suspension containing one or more chemicals for Lanji was prepared. It was diluted with water to a predetermined degree and the obtained The chemical solution is sprayed on the stems and leaves of the rice, so that the chemical solution is sufficiently fixed on the leaf surface of the rice seedlings. After the chemical solution is blown dry by the wind, the bottom of the rice seedlings is infected with the sugarcane blight disease. The infected rice seedlings were exposed to high temperature and humidity for 10 days at 2 7 ° C, and then the control effect was evaluated in the same manner as in Test Example 1. The results were shown in Table 9.-f {IIIII 1 II Pack-IIIII Stranding (please read the notes on the back before filling in this page) The printed printing paper of the Ministry of Economic Affairs, Central Bureau of Standards, and consumer cooperation is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm ) -36 ~ A7 B7 V. Description of the invention (34) Table 9 Active Ingredients (ppm) Control Index Compound (1) 500 0 100 0 Compound (2) 500 0 100 0 Compound (3) 500 0 10 0 -......... Compound (4) 500 0 100 0 Compound (5) 500 0 100 0 Compound F 10 3 5 1 Compound G 5 3 1 .25 1 Compound H 10 3 5 1 Compound I 30 3 10 0 Compound J 30 3 10 0 Compound (1) + 500 + 10 4 Compound F 100 + 5 2 Compound (2) + 500 + 10 4 Compound F 100 + 5 2 Compound (3) + 500 + 10 4 Compound F 100.5 2 Compound (4) + 500 + 10 4 Compound F 100 + 5 2 Compound (5) + 500 + 5 4 Compound F 100 + 5 2 Compound (1) + 500 + 5 4 Compound G 100 + 1.25 2 Compound (1 ) + 500 + 10 4 Compound H 100 + 5 2 Compound (1) + 500 + 30 4 Compound I 100 + 10 1 Compound (1) + 500 + 30 4 Compound J 100 + 10 1 (Please read the notes on the back first (Fill in this page again) This paper is again applicable to the Chinese National Standard (CNS) A4 specification (210X297 public daughter) -37-A7 B7 5. Description of the invention (35) Test Example 9: Prevent the occurrence of vegetables by water surface application The activity test of Rhizoctonia solani was filled with sandy loam in Wagner pots (0 · 0.1 square meters) and then water was added to remove the rice (Two leaves only, Kin ki No. 3 3) Transplanted into pots and cultivated in the greenhouse for 7 days. Based on the preparation example 7, granules containing one or more chemicals for trial use were prepared. Apply them on the surface of each pot. Seven days after the application, the bottom of the rice seedlings was infected with the leaf blight disease. The infected rice seedlings were exposed to 27 eC and high humidity for 10 days, and then the root sickle control index was used to evaluate the control effect in the same manner as in Lan Test Example 1. The results are shown in Table 10. (Please read the precautions on the back and then fill out this page)-installed.,-= * Printed copies of this paper are applicable to Chinese national standards (CNS &gt; A4 specifications (210 X 297 mm ) ** 38 ~ 305743 A7 B7 V. Description of the invention (36) Table 1 0 Application ratio of the active ingredients of the test article (g / 1000 m² Control index Compound (1) 200 0 50 0 Compound (2) 200 0 50 0 Compound (3) 200... 〇50 0 compound (4) 200 0 50 0 compound (5 &gt; 200 0 50 0 compound F 30 3 10 1 compound (1) + 200 + 30 4 compound F 50+ 10 2 Compound (2) + 200 + 30 4 Compound F 50 + 10 2 Compound (3) + 200 + 30 4 Compound F 50 + 10 2 Compound (4) + 200 + 30 4 Compound F 50 + 10 2 Compound (5 ) + 200 + 30 4 Compound F 50 + 10 2 Binding—binding line (please read the precautions on the back before filling out this page) The paper standard printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) Eight 4 specifications (210X297 mm> -39-A7 B7 V. Invention description (37) Test example 10: The activity and residual effect of the occurrence of rice blast were tested in a plastic pot filled with sandy loam, and rice (Kinki No. 3 3) was sown in it and cultivated in the greenhouse for 20 days. Wettable powder of one or more test chemicals. Dilute with water to a predetermined concentration, and leak the resulting chemical solution on the stems and leaves of rice, so that the chemical solution is sufficiently fixed on the leaves of rice seedlings In terms of testing the effect of preventing rice gall disease, after the chemical solution is blown dry by wind, the cell suspension of rice gall disease is sprayed on the rice seedlings to infect the rice seedlings. In terms of testing the residual effect, the rice After the seedlings were in the greenhouse for 7 days, the cell suspension of rice gall disease was sprinkled on the rice seedlings to infect the rice seedlings. The infected rice seedlings were placed at 24 eC, high temperature for 10 days, and then according to the following Control index to evaluate the effect of control. N II n IIII n order (please read the notes on the back before filling in this page) control finger age control effect Printed by the Central Bureau of Economics of the Ministry of Economic Affairs Employee Consumption Cooperation 5 4 3 2 1 0 The results are shown in Table 1. 1 No corruption not less than 90% 7 0 to 8 9% 4 1 to 6 9% 1 to 4 0% 0%

-40 - 305743 A7 —B7 五、發明説明（38) 表1 1 試驗品 活性成份*度 (ppm) 控制指較 殘留 活性 防止 活性 化合物（1 ) 5 4 4 1 2 2 化合物（2 ) 5 4 4 1 2 2 化合物（3 ) 5 4 4 1 1 1 化合物&lt; 4 ) 5 4 4 1 1 1 化合物（5〉 5. 4 4 1 2 2 化合物L 5 3 2 1 1 0 化合物（1 ) + 5 + 5 5 5 化合物L 卜1 4 4 化合物（2 ) + 5 + 5 5 5 化合物L 卜1 4 4 化合物（3 ) + 5 + 5 5 5 化合物L 1 + 1 4 4 化合物（4 ) + 5 + 5 5 5 化合物L 卜1 4 4 化合物（5 ) + 5 + 5 5 5 化合物L 1 + 1 4 4 (請先聞讀背面之注意事項再填寫本I) 裝 訂 線 經濟部中央標华局只工消资合阼it印装 本紙伕尺度通用中國國家梯率（CNS ) A4規格（210X297公釐） -41 - 305743 A7 ___ B7 五、發明説明（39) 測試例11:藉由水面施用的方式來防止發生稻瘙病的活 性試驗 在fagner盆（0. 0 1平方公尺）中塡滿多沙的壙土 然後加水，將稻（二葉階段，Kinki No.3 3 )移植至盆 中並於溫室中栽培7天。根據製例1製得含有一或多種 測試用化學品的顆粒。將它們施用在毎個盆的水面上。在 連績施用7天（下文中稱爲•試驗）或1 4天（下文 中稱爲~試驗b# 〉之後，將稻瘋病源的胞子懸浮液喷灑 在稻苗上使稻苗受到感染。使此受到感染的稻苗處於2 4 °C、高濕度下1 0天，第1 〇天時，以與澜試例1相同的 方式、根據控制指數來評估控制的效果。其結果示於表 (請先閏讀背面之注意事項再填寫本頁) -裝. 訂 經濟部中央標率扃員工消費合作杜印裝 -42 - 本紙張尺度適用中國國家標半（CNS ) A4規格（2丨OX297公釐） 經濟部中央標準局員工消費合作社印製 305743 A7 B7 五、發明説明（4〇) 表1 2 試驗品 活性成份施用比 例（克/ 1 000平 方公尺 控制指數 拭驗 a 試驗 b 化合物（1 ) 20 3 3 5 1 1 化合物（2 ) 20 3 3 5 1 1 , 化合物（3 ) 20 3 3 5 1 1 化合物（4 ) 20 3 3 5 1 1 化合物（5 ) 20 3 3 5 1 1 化合物K 200 2 1 50 1 0 化合物L 50 2 1 10 1 0 化合物Μ 100 2 1 30 1 0 化合物Ν 50 3 2 10 1 0 化合物（1 ) + 20+200 5 5 化合物Κ 5 + 50 4 3 化合物（1 ) + 20 + 50 5 5 化合物L 5+10 4 3 化合物（1 ) + 200+100 5 5 化合物Μ 5 + 35 4 3 化合物（1 ) + 20 + 50 5 5 化合物Ν 5十10 4 3 化合物（2 ) + 20 + 50 5 5 化合物L 5+10 4 3 化合物（3 &gt; + 20 十 50 5 5 化合物L 5 + 10 4 3 化合物（4 ) + 20*50 5 5 化合物L 5+10 4 3 化合物（5 ) + 20 + 50 5 5 化合物L 5+10 4 3 ---------^------ΪΤ-----.1,線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -43 --40-305743 A7-B7 V. Description of the invention (38) Table 1 1 Active ingredient * degree of the test article (ppm) Control refers to the residual activity to prevent the active compound (1) 5 4 4 1 2 2 Compound (2) 5 4 4 1 2 2 Compound (3) 5 4 4 1 1 1 Compound &lt; 4) 5 4 4 1 1 1 Compound (5> 5. 4 4 1 2 2 Compound L 5 3 2 1 1 0 Compound (1) + 5 + 5 5 5 Compound L Bu 1 4 4 Compound (2) + 5 + 5 5 5 Compound L Bu 1 4 4 Compound (3) + 5 + 5 5 5 Compound L 1 + 1 4 4 Compound (4) + 5 + 5 5 5 Compound L Bu 1 4 4 Compound (5) + 5 + 5 5 5 Compound L 1 + 1 4 4 (Please read the precautions on the back before filling in this I) Binding Line, Ministry of Economic Affairs, Central Standardization Bureau Zheitit Printed Paper Paper Standard Universal Chinese National Gradient (CNS) A4 Specification (210X297mm) -41-305743 A7 ___ B7 5. Description of the invention (39) Test Example 11: Prevent by surface application The activity test for occurrence of rice pruritus was filled with sandy soil in fagner pots (0.01 square meters) and then water was added to remove rice (two-leaf stage, Kinki No. 3 3) Go to pots and cultivate in the greenhouse for 7 days. Prepare pellets containing one or more test chemicals according to Preparation Example 1. Apply them to the surface of each pot. Apply for 7 days in a row (hereinafter referred to as • Test) or after 14 days (hereinafter referred to as ~ Test b #), spray the rice spore suspension on the rice seedlings to infect the rice seedlings. Leave the infected rice seedlings at 2 4 ° C 1. At 10 days under high humidity, at the 10th day, evaluate the control effect according to the control index in the same way as in Test Example 1. The results are shown in the table (please read the notes on the back before filling in this Page)-Pack. Ordered by the Ministry of Economic Affairs, Central Standard Rate, Employee Consumption Cooperation Du Printing -42-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 OX297mm). Preparation 305743 A7 B7 V. Description of the invention (4〇) Table 1 2 Application ratio of the active ingredients of the test article (g / 1 000 m 2 control index swipe a test b Compound (1) 20 3 3 5 1 1 Compound (2) 20 3 3 5 1 1, compound (3) 20 3 3 5 1 1 Compound (4) 20 3 3 5 1 1 Compound (5) 20 3 3 5 1 1 Compound K 200 2 1 50 1 0 Compound L 50 2 1 10 1 0 Compound M 100 2 1 30 1 0 Compound N 50 3 2 10 1 0 Compound (1) + 20 + 200 5 5 Compound K 5 + 50 4 3 Compound (1) + 20 + 50 5 5 Compound L 5 + 10 4 3 Compound (1) + 200 + 100 5 5 Compound M 5 + 35 4 3 Compound (1) + 20 + 50 5 5 Compound N 5 10 10 4 3 Compound (2) + 20 + 50 5 5 Compound L 5 + 10 4 3 Compound (3 &gt; + 20 10 50 5 5 Compound L 5 + 10 4 3 Compound (4) + 20 * 50 5 5 Compound L 5 + 10 4 3 Compound (5) + 20 + 50 5 5 Compound L 5 + 10 4 3 --------- ^- ----- ΪΤ -----. 1, line (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specifications (210X297mm) -43-

Claims (1)

SB574S A8 B8 C8 D8 圍 ,，，氣&quot;tor —I 附件一（A )： 第83 1 09780號專利申請案 中文申請專利範圔修正本 民國86年3月修正 1. 一種農業/園藝用之殺黴菌組成物，其特徵爲其 活性成份包含： —種選自下式表示的醯胺衍生物，以及 C I CH. CN 1丨 r C H - = C Η — C-C Η - C — N H — C H _(f N)—C II II I ch, o CH： CH 3 CH3 CN I I c-CH - C — NH—CHI II I ch. o CH Cl Br 3 CH. CN I I r CH〇 = C H 一 C-CH - C — NH— C H I II I CH, 0 CH Cl Br CH· CH. CN l l C _丨丨 C H — C—~ N H — C HI II ISB574S A8 B8 C8 D8 Wai ,,, gas &quot; tor —I Annex I (A): No. 83 1 09780 Patent application Chinese application patent Fan Xi Amendment The Republic of China in March 86 Amendment 1. An agricultural / horticultural use A fungicidal composition, characterized in that its active ingredients include:-a amide derivative selected from the following formula, and CI CH. CN 1 丨 r CH-= C Η-CC Η-C-NH-CH _ ( f N) —C II II I ch, o CH: CH 3 CH3 CN II c-CH-C — NH—CHI II I ch. o CH Cl Br 3 CH. CN II r CH〇 = CH 一 C-CH- C — NH— CHI II I CH, 0 CH Cl Br CH · CH. CN ll C _ 丨 丨 CH — C— ~ NH — C HI II I -------------、1------^ I (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製 CH 3 0 CH. 一種化合物，選自包含（E) — 2— {2 —〔6-（ 2 —氰基苯氧基）嘧啶—4 —基氧代〕苯基} — 3 —甲氧 基丙烯酸甲酯、（Z) — 2 / —甲基乙醯苯4 ，6 —二甲 基嘧啶—2 -基腙、α，α，α —三氟—3 &lt; —異丙氧基 —鄰—苯乙醯替苯胺、和5-甲基—1 ，2 ，4 —三唑並 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 305743 A8 B8 C8 D8 申請專利範圍 〔3，4~b〕苯並睡唑。 2 .如申請專利範國第1項之組成物，其中，該所選 之一種化合物是（E) — 2 - {2 —〔6-（2 -氰基苯 氧基）嘧啶—4 —基氧代〕苯基} — 3 —甲氧基丙烯酸甲 酯 .如申請專利範園第1項之組成物，其中，包含所 示的醯胺衍生物及（Z) - 2 甲基嘧啶一2 —基腙。 甲基乙醯苯4 6 一 4 _如申請專利範圈第1項之組成物，其中，包含所 示的醯胺衍生物及α，α，α —三氟—3 異丙氧基- 鄰一苯乙醯替苯胺》 5 .如申請專利範圍第1項之組成物，其中，包含所 示的醯胺衍生物及5 —甲基—1 ，2，4 一三唑並〔3， 4 — b〕苯並_唑。 6 . —種農業/園藝用之殺黴菌組成物，其特徵爲其 活性成份包含： 以下式表示的醢胺衍生物，以及 ----1--Λι{------訂------声- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印裝 CH, CN I I u C H -a — C —— C Η — C — N H I II Chu 〇 C i CH. 一種化合物，選自包含（E) — 2— (2 —〔6—( 2 —氰基苯氧基）嘧啶—4 一基氧代〕苯基丨一 3_甲氧 L紙張尺度適用中國國家標率（CNS &gt; A4規/格（210 X 297公着） 經濟部中央標準局貝工消費合作社印製 3阶43 SS C8 D8六、申請專利範圍 基丙烯酸甲酯' (Z) — 2 β —甲基乙醯苯4 ，6 —二甲 基嘧啶—2 —基腙、0 -乙基S，S —二苯基偶磷連二硫 酸酯、4 ，5 ，6 ，7 —四氯酞內酯、春雷黴素（kasu-gamycin) 、 α ’ α ， α— 三氟一 3 一一異丙氧基 ―鄰― 苯乙醯替苯胺、1— (4 —氯苄基）—1—環戊基—3 — 苯基腺、有效黴素（validamycin) 、3 ——異丙氧基— 鄰一苯乙醯替苯胺、6— (3，5 —二氯一4 —甲基苯基 )—3 (2H)噠嗪酮、1 ，3_二瞎茂基—2 -炔基丙 二酸二異丙酯、5 —甲基—1 ，2，4 一三唑並〔3 ，4 —b〕苯並_唑、3 —烯丙氧基一1 ，2-苯並異_唑— 1 ，1—二氧化物和1 ，2，5，6 —四氫一4H —吡咯 並〔3，2，1-i j }喹啉—4 —酮。 7. —種農業/園藝用之殺黴菌組成物，其特徵爲其 活性成份包含： 以下式表示的醯胺衍生物 ch3 I CN | C 1 \_ 1 C一 I -CH - ,C一 II -NH—CH ' 1 ch3 II 〇 1 ch3 4 ，5 ，6 ，7 —四氯酞內酯；以及 一種化合物，選自0_乙基一 S，S —二苯基偶磷連 二硫酸酯及春雷黴素（kasngamycin)。 (請先閱讀背面之注意事項再填寫本頁)-------------, 1 ------ ^ I (Please read the precautions on the back before filling out this page) Printed CH 3 0 by the Consumer Labor Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs CH. A compound selected from the group consisting of (E)-2-{2-[6- (2-cyanophenoxy) pyrimidine-4-oxo] phenyl}-3-methyl methacrylate, (Z) — 2 / —Methylacetophenone 4,6-Dimethylpyrimidine-2-ylhydrazone, α, α, α —Trifluoro-3 &lt; —Isopropoxy—o-phenylacetonitrile Aniline, and 5-methyl-1,2,4-triazolo paper standards are applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) 305743 A8 B8 C8 D8 Patent scope [3, 4 ~ b] benzene And sleep azole. 2. The composition as described in item 1 of the patent application country, wherein the selected compound is (E)-2-{2- (6- (2-cyanophenoxy) pyrimidine-4-yloxy 〕 Phenyl} — 3-methoxymethyl acrylate. The composition as described in item 1 of the patent application park, which contains the indicated amide derivative and (Z)-2 methylpyrimidine-2-ylhydrazone . Methylacetophenone 4 6-4 _ The composition as described in item 1 of the patent application circle, which contains the indicated amide derivatives and α, α, α —trifluoro-3 isopropoxy-o-one "Phenylacetanilide" 5. The composition as described in item 1 of the patent application scope, which includes the indicated amide derivatives and 5-methyl-1,2,4-triazolo [3,4-b 〕 Benzo_azole. 6. A kind of fungicidal composition for agricultural / horticultural use, characterized in that its active ingredients include: amide derivatives represented by the following formula, and ---- 1--Λι {------ book-- ---- Sound-(Please read the notes on the back before filling in this page) Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs CH, CN II u CH -a — C —— C Η — C — NHI II Chu 〇 C i CH. A compound selected from the group consisting of (E) — 2— (2 — [6— (2-cyanophenoxy) pyrimidine — 4 monoyloxo] phenyl 丨 3_methoxy L paper size Applicable to China's national standard rate (CNS &gt; A4 regulation / grid (210 X 297 public)) The Ministry of Economic Affairs Central Standards Bureau Beigong Consumer Cooperative Printed 3rd Order 43 SS C8 D8 VI. Patent application scope Methyl Acrylate '(Z) — 2 β —methylacetophenone 4, 6-dimethylpyrimidine-2-ylhydrazone, 0-ethyl S, S-diphenylphosphorodithioate, 4, 5, 6, 7-tetra Chlorophthalide, kasu-gamycin, α'α, α-trifluoro-3 3-one isopropoxy-o-phenylacetophenone, 1- (4-chlorobenzyl) -1 —Cyclopentyl—3 — Basal gland, validamycin (validamycin), 3-isopropoxy-o-phenyl phenethyl aniline, 6-(3,5-dichloro-4-methylphenyl)-3 (2H) pyridazine Ketone, 1,3_dibromo-2-ynylmalonate diisopropyl, 5-methyl-1,2,4-triazolo [3,4-b] benzoxazole, 3- Allyloxy-1,2-benziso-oxazole-1,1-dioxide and 1,2,5,6-tetrahydro-4H-pyrrolo [3,2,1-ij} quinoline- 4-Ketone 7. A kind of fungicidal composition for agricultural / horticultural use, characterized in that its active ingredients include: amide derivatives ch3 I CN | C 1 \ _ 1 C 一 I -CH-, represented by the following formula C-II-NH-CH '1 ch3 II 〇1 ch3 4, 5, 6, 7-tetrachlorophthalolactone; and a compound selected from 0_ethyl-S, S-diphenylaphosine Sulfate and kasngamycin (Please read the notes on the back before filling this page) 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 3The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 3
TW083109780A 1993-11-04 1994-10-21 TW305743B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP27537193A JP3307026B2 (en) 1993-11-04 1993-11-04 Agricultural and horticultural sterilizing composition
JP5282640A JPH07133203A (en) 1993-11-11 1993-11-11 Agricultural and hoticultural microcidal composition
JP28517993A JP3393899B2 (en) 1993-11-15 1993-11-15 Agricultural and horticultural sterilizing composition
JP14486394A JP3435810B2 (en) 1994-06-27 1994-06-27 Agricultural and horticultural sterilizing composition

Publications (1)

Publication Number Publication Date
TW305743B true TW305743B (en) 1997-05-21

Family

ID=27472597

Family Applications (1)

Application Number Title Priority Date Filing Date
TW083109780A TW305743B (en) 1993-11-04 1994-10-21

Country Status (4)

Country Link
KR (1) KR100309896B1 (en)
CN (2) CN1150822C (en)
BR (1) BR9404349A (en)
TW (1) TW305743B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW384208B (en) * 1995-09-22 2000-03-11 Basf Ag Compositions and methods for controlling harmful fungi
ITMI20080155A1 (en) * 2008-01-31 2009-08-01 Isagro Ricerca Srl MIXTURES AND FUNGICIDE COMPOSITIONS FOR THE CONTROL OF FITOPATOGENIC MUSHROOMS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1024317C (en) * 1988-09-01 1994-04-27 罗纳-普朗克农业化学公司 Antifungal agents based on amides containing phenyl group
JPH0386337A (en) * 1989-08-28 1991-04-11 Maeda Seisakusho:Kk Multiple seaming matching provided with expanding chuck and method for multiple seaming
US5223526A (en) * 1991-12-06 1993-06-29 Monsanto Company Pyrazole carboxanilide fungicides and use

Also Published As

Publication number Publication date
CN1530011A (en) 2004-09-22
KR950013366A (en) 1995-06-15
CN1150822C (en) 2004-05-26
BR9404349A (en) 1995-07-04
CN1104845A (en) 1995-07-12
CN100382690C (en) 2008-04-23
KR100309896B1 (en) 2002-11-30

Similar Documents

Publication Publication Date Title
CN110113944A (en) Fungicidal composition
TW305743B (en)
CN107249328A (en) Control the Herbicidal combinations and method of plant growth
CN108419804A (en) A kind of bactericidal composition and its application
JP2002541163A (en) Paddy field herbicide composition
JPH0443881B2 (en)
CN101747263A (en) Pyridyloxy phenoxyalkanoic acids compound and application
JPH07330512A (en) Fungicidal composition
CN107006509A (en) Cyfluthrin water emulsion and preparation method thereof
JPS63301801A (en) Herbicidal composition
JPH07157404A (en) Microbicidal composition for agricultural and horticultural use
JPS6156104A (en) Seed fungicide comprising disulfide as active ingredient
JPS5839126B2 (en) Herbicidal composition
JPS63225306A (en) Herbicidal composition
JPH0232004A (en) Herbicidal composition
JPS63183503A (en) Seed disinfectant
JPS5995204A (en) Herbicidal composition
JPS63179805A (en) Herbicidal composition
TW311873B (en)
JPS59108701A (en) Herbicidal composition
JPH03151311A (en) Herbicide composition
JPS62292708A (en) Herbicide composition for paddy field
JPS60149507A (en) Fungicidal composition for agricultural and horticultural use
JPS63190805A (en) Herbicidal composition
JPS5995207A (en) Herbicidal composition

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees