TW311873B - - Google Patents

Download PDF

Info

Publication number
TW311873B
TW311873B TW84104819A TW84104819A TW311873B TW 311873 B TW311873 B TW 311873B TW 84104819 A TW84104819 A TW 84104819A TW 84104819 A TW84104819 A TW 84104819A TW 311873 B TW311873 B TW 311873B
Authority
TW
Taiwan
Prior art keywords
formula
compound
group
alkyl
page
Prior art date
Application number
TW84104819A
Other languages
Chinese (zh)
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Application granted granted Critical
Publication of TW311873B publication Critical patent/TW311873B/zh

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

311873 經濟部中央標準局員工消費合作杜印製 A7 B7 五、發明説明(!) 發明說明 本發明相關於一種選擇性除草組成物用於控制栽種植 物之收成,特別是玉蜀黍收成中之禾箄以及雜草,該組成 物包括除草劑以及保護劑(safener)(防衰枯劑)且保護 栽種植物,而非雜草,免於除草劑之植物毒性,並相關於 該組成物,或除草劑與保護劑(safener)之结合,用於控 制栽種植物之收成中之雜草之用途β 施用除草劑時,栽種植物亦可能由於許多因素而蒙受 駸重的傷害,其包含除草劑之濃度以及施用之型式,栽種 植物本身,土壤之性質,以及氣候狀況如曝露於光線,溫 度以及降兩β ) 為了消除此一問題以及相似的其它問題,已有計割提 出使用不同的化合物作為保護劑(safener),其能夠對抗 除草劑對於栽種植物之有害活性,卽保護栽種植物而使得 針對雜草之除草活性被控制為完全無害。然而,已發現被 提出之保護劑(safener)往往具有強烈的種一特異活性, 不僅相蘭於栽種植物且亦相蘭於除草劑,且在一些例子中 亦視施用之型式而定,邸一種特定的保護劑(safener)將 往往僅適合於一種待定之栽種植物以及一種恃定等级之除 草劑。 -6 - 本紙張用中國國家標準(CNS ) A4規格(210X297公釐) 裝— (請先聞讀背面之注意事項再填寫本頁) 訂 3ί1δ· A7 B7 CH,311873 A7 B7 printed by the Ministry of Economic Affairs, Central Bureau of Standards, and Consumer Cooperation V. Description of the invention (!) Description of the invention The present invention relates to a selective herbicidal composition used to control the harvest of planted plants, in particular the Hezuo in the maize harvest and Weeds, the composition includes herbicides and safeners (anti-decay agents) and protects planted plants, not weeds, from the phytotoxicity of herbicides, and is related to the composition, or herbicides and The combination of safeners is used to control the weeds in the harvest of planted plants. Β When applying herbicides, planted plants may also be damaged by many factors due to many factors, including the concentration of the herbicide and the application of Type, the plant itself, the nature of the soil, and the climatic conditions such as exposure to light, temperature, and two β drops) In order to eliminate this problem and other similar problems, it has been proposed to use different compounds as protective agents (safener) , Which can resist the harmful activity of herbicides on planted plants, and protect planted plants so that weeding activity against weeds Sex is controlled to be completely harmless. However, it has been found that the proposed safeners often have strong species-specific activities, which are not only related to planting plants but also to herbicides, and in some cases also depend on the type of application. A specific safener will often only be suitable for one type of planting plant to be determined and a certain grade of herbicide. -6-This paper is packed in Chinese National Standard (CNS) A4 specification (210X297mm) — (please read the precautions on the back before filling in this page) Order 3ί1δ · A7 B7 CH,

N C(0)-CH2C1 CH— CHoOCH-, 五、發明説明(>) 目前已發現一些氱-以及二氛乙酵胺適合於保護栽種 植物免於化合物式I之aRS, l'S ( —)N— (1' —甲基一 2 一 一甲氣基乙基)一N —氣乙醯基一2 —乙基一 6 —甲基苯胺 之植物毒性 (I), ,其中Ro為甲基或乙基。i 因此,本發明提供一種選擇性除草组成物,除了傳統 的無活性配方助劑類如載劑類,溶劑類以及濕潤劑類以外 ,其包括作為活性成分之以下混合物 .)一種除草性有效份董之式I化合物 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ---I —--.I - -I In -- 1^1 I 1 » 士.¢1 (^1 HI —^1---1 t^i 0¾ 、\έ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央樣窣局員工消費合阼、f±印裝 A7 B7NC (0) -CH2C1 CH— CHoOCH-, V. Description of the invention (>) At present, it has been found that some tri- and dichloroacetamides are suitable for protecting plant plants from aRS, l'S (—) N— (1'—Methyl-2-2-methylaminoethyl) —N—Gasoacetyl-2-ethyl-6-methylaniline phytotoxicity (I), where Ro is methyl or ethyl . i Therefore, the present invention provides a selective herbicidal composition, which includes the following mixtures as active ingredients in addition to traditional inactive formulating auxiliary agents such as carriers, solvents and wetting agents.) A herbicidal effective ingredient The compound of Dong Zhi formula I This paper scale applies the Chinese National Standard (CNS) A4 specification (210X297 mm) --- I ----. I--I In-1 ^ 1 I 1 »taxi. ¢ 1 (^ 1 HI — ^ 1 --- 1 t ^ i 0¾, \ έ (Please read the precautions on the back and then fill out this page) Employee consumption consumption of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs, f ± printed A7 B7

N C(0)-CH2C1 CH— CH2〇CH3 i、發明説明( (I), ,其中R〇為甲基或乙基,以及 b)為了拮抗除草劑,一種防衮枯性(antidotally) 有效份貴之式II化合物作為保護劑(safener) R- CHYC1 (II) ,其中R為右式之一自由基 r33 〇 ,其中 R34 R3 3以及R3 4披此獨立為Ct -Ce烷基或C2 ~Ci - I H I. - - - - 1 ml (請先閲讀背面之注意事項再填寫本頁) a耷年_矢票481¾雪r U肖牵\6乍.:±.?-5^ 烯基;或R3 3以及R3 4,共同為 〇NC (0) -CH2C1 CH—CH2〇CH3 i, Description of the invention ((I), where R〇 is methyl or ethyl, and b) In order to antagonize the herbicide, an antidotally effective (antidotally) is very valuable The compound of formula II as a safener R- CHYC1 (II), where R is one of the right formula radicals r33 〇, wherein R34 R3 3 and R3 4 are independently Ct -Ce alkyl or C2 ~ Ci -IH I.----1 ml (please read the precautions on the back before filling in this page) a 怷 年 _ 葉 票 481¾ Xuer U Xiao Qian \ 6 at first .: ±.?-5 ^ alkenyl; or R3 3 And R3 4, together 〇

(35 R(35 R

36 R3 5 以及R3 6 彼此播立為氬或烷基 ~ 8 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) 311873 A7 B7 五、發明説明(士 或 R3 3以及 R3 4 ,共同為36 R3 5 and R3 6 stand for each other as argon or alkyl ~ 8-This paper size is applicable to the Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 311873 A7 B7 V. Description of invention (Shi or R3 3 and R3 4, together for

及R 3 8 ,共同為一(CH2 ) S R3 9為氫,C t 一 C4烷基或 或R3 3以及Rs 4 ,共同為 、49 义50 R.And R 3 8, together is a (CH2) S R3 9 is hydrogen, C t-C4 alkyl or or R3 3 and Rs 4, together, 49 meaning 50 R.

.^51 'N. ^ 51 'N

54 R R52 r53 55 R3954 R R52 r53 55 R39

0 R,0 R,

47 \ 或 (請先閲讀背面之注意事項再填寫本頁) 48 fl R 4 Ο , R 4 1 , R 4 2 , R 4 3 , R 4 4 , R 4 S , R 4 β » R4 7 » R4 8 . R4 9 » R5 o > R 5 1 , R5 2 . R5 3 ,Rs 4以及Rs 5彼此獨立為氫或Ci 一(:4烷基, 或 R為化學式 〇 .CO- -CH-i 之 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 五、發明説明($ ) A7 B7 一自由基或R為化學式47 \ or (please read the notes on the back before filling in this page) 48 fl R 4 Ο, R 4 1, R 4 2, R 4 3, R 4 4, R 4 S, R 4 β »R4 7» R4 8. R4 9 »R5 o > R 5 1, R5 2. R5 3, Rs 4 and Rs 5 are independently hydrogen or Ci one (: 4 alkyl, or R is the chemical formula 〇.CO- -CH-i This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm). V. Description of the invention ($) A7 B7 A free radical or R is a chemical formula

之一自 由基,其中R! , Rz ,R3 4院基,Cl 一 C4院氣基或Cl —C4窗院基,Rs 7以及R8彼此獨立為氫》Ci _C4烷基或ClOne of the free radicals, among them R !, Rz, R3 4-base, Cl-C4-base gas base or Cl-C4 window-base base, Rs 7 and R8 are independently hydrogen》 Ci_C4 alkyl or Cl

R e , R c4鹵烷基,或R為化學式 R10R e, R c4 haloalkyl, or R is the chemical formula R10

R 11、 R12R 11, R12

CH- CO—Nv /N —CO— Q 之一自由基,其中R9為Ci — C4院基或趣素,Ri o為® 素, !以及I 2彼此獨立為氫或Ci _c4烷基,且Q為 Cj -c4伸烷基或烷基一經取代之h -c4伸烷基, ί —ϋ ϋ— n^i ^^^1 1^1 ml 1· m nn In nn ml 0¾.-5 (請先閲讀背面之注意事項再填寫本頁) 或R為化學式 、14 之一自 (P-X)n 經濟部中央標準局員工消費合作社印製 由基,其中Ri 4為氫,鹵素,Ci -(U烷基,二氣亞甲基 ,h - C4烷氧基,CZ - C4烯基氣,C2 - C4炔基氣或 «基一Ci -C4 烷基,PSC, -C4 烷基,C2 — C4 烯基, c2 - c4炔基,C3 -C8琢烷基,Ci - C4烷氣基一 Ci — C4烷基,C2 _C4烯氣基-Ci -c4烷基,CZ -C4炔氱 基—c, -C4烷基,Ci - C4烷基硫一 C! - C4烷基,Cz _C4嫌基硫一 Cl —C4烧基,C2 - C4快基硫一C1 -10- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7CH-CO—Nv / N—CO—Q is one of the free radicals, where R9 is Ci—C4 group or element, Ri o is ® element, and I 2 are independently hydrogen or Ci_c4 alkyl group, and Q It is Cj -c4 alkylene or alkyl substituted h -c4 alkylene, ί —ϋ ϋ— n ^ i ^^^ 1 1 ^ 1 ml 1 · m nn In nn ml 0¾.-5 (please first Read the precautions on the back and then fill out this page) or R is the chemical formula, one of 14 is printed by (PX) n from the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy, where Ri 4 is hydrogen, halogen, Ci-(U alkyl , Two gas methylene, h-C4 alkoxy, CZ-C4 alkenyl gas, C2-C4 alkynyl gas or «-Ci-C4 alkyl, PSC, -C4 alkyl, C2- C4 alkenyl, c2-c4 alkynyl, C3-C8 alkyl, Ci-C4 alkane-Ci-C4 alkyl, C2 _C4 alkynyl -Ci -c4 alkyl, CZ -C4 alkynyl-c, -C4 alkane Base, Ci-C4 alkyl sulfur one C!-C4 alkyl, Cz _C4 suspected sulfur one Cl-C4 burned base, C2-C4 fast base sulfur one C1 -10- This paper scale is applicable to China National Standard (CNS) A4 Specification (210X297mm) A7

經濟部中央標準局員工消費合作杜印製 五、發明説明(b ) 院基,Ci 一 C4院基亞儀酵基一 Ci 一 C4院基,Ci 一 C4 院基辑酵基一 Cl 一 C4院基,由一Ct —C4烧基,氣基一C 1 一 C4 院基,2,2 —二一Ci — C4 院氣基—Ci 一 焼基 ,1, 3—二磨茂院一2—基一 Ci — C4炫基,1,3 —二晴茂 院一 4 一基一 Ci 一 C4 燒基,2,2—二一 Ci — C4 烧基一 1 ,3—二暖茂院一 4 —基一 Ci — C4院基,1,3—二磨烧一 2 —基一 Ci — C4院基,2-苯並Oft喃基一Ci 一 CU院基,C i _C4烷氣基羰基或C2 — C4烯基氣羰基或四氫糠基一 c i 一 C4院基,P — X基團亦為齒一 Ci — C4院基,X為0, S ,SO或S〇2 , η為1, 2或3,点為“ 一C8烴基國或為經烷氣 基,烷基硫,氟基,氣基或鹵烷基加以取代之“ 一C8烴 基圃,且Ri 3為氫,Ci _C5烴基團或經烷氣基,聚烷氣 基,鹵素,氣基或三氟甲基加以取代〇 烴基賵;C3 —C8環院基,Cl — C4院基一C3 — C8環院基,一一 Cl -c4烷氣基一c, —c4烷基,1, 3 -二睥茂烷一 2—基一c i - C4烷基,1,3 —二聘茂烷一 4 -基一Cx -C4院基,1 ,3—二聘烷一 2 —基一 Ci -C4烷基,呋喃基一 Cl _C4 烷基,四氫呋喃基一C i 一 c4烷基,或化學式—NHC〇2 Ro i , 一 CH2 C〇2 R0 i , — CH ( CH3 ) C02 R〇 1 或 一 CH ( R o z ) — C ( R〇 3 ) = N0Ro 4之自由基,其中R〇 1為甲 基,乙基,丙基,異丙基或烯丙基,R〇 2以及R〇 3値別 為氫或C! —C4烷基,且R0 4為氫,一“院基,D 一 C4烯基或C2 — C4炔基, -11- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) i mf n^i ^^^^1 ^^^^1 ^^^^1 in^— n 11^ HI— ^^^^1 ^ ^ 、-, (請先閱讀背面之注意事項再填寫本頁) 311873 A7 __ B7__ 五、發明説明(η ) 或 R 為化學式(Hs C2 0) 2 P (〇) CH2 NHCO- r15 或 之自由基,其中Rl R16Printed by the Ministry of Economic Affairs, Central Bureau of Standards for Consumer Consumption V. Description of the invention (b) The hospital base, Ci-C4 hospital base, instrument yeast base-Ci-C4 hospital base, Ci-C4 hospital base series, enzyme base-Cl-C4 hospital base Base, consisting of a Ct-C4 burned base, gas-based C1-C4 hospital base, 2,2-two-one Ci-C4 hospital gas-based-Ci-yaki, 1,3--two-milloyuan one 2-base One Ci — C4 Hyunji, 1,3- Erqing Maoyuan one 4-one base one Ci-C4 burned base, 2,2-two one Ci — C4 burned base one 1, 3 —two Nuan Maoyuan one 4-base one Ci — C4, 1—3-difurcated—2-yl—Ci—C4, 2-benzoftyl—Ci—CU, C i _C4 alkyl carbonyl or C 2 —C 4 alkene The base gas carbonyl group or tetrahydrofurfuryl-ci-C4 group, P-X group is also a tooth-Ci-C4 group, X is 0, S, SO or S〇2, η is 1, 2 or 3, The point is "a C8 hydrocarbon-based country or a alkyl group substituted with an alkyl group, an alkylsulfide, a fluoro group, a gas group, or a haloalkyl group", and a Ri3 is hydrogen, a Ci_C5 hydrocarbon group or an alkyl group Group, polyalkyl gas group, halogen, gas group or trifluoromethyl group is substituted 〇 hydrocarbyl quasi; C3-C8 ring Group, Cl—C4 group, a C3—C8 ring group, a Cl-c4 alkyl group, c, —c4 alkyl group, 1,3-dipercarbo-2-yl-ci-C4 alkyl group, 1,3-Dibromoalkane-4-yl-Cx-C4 hospital group, 1,3-Dibromoalkan-2-yl-Ci-C4 alkyl, furyl-Cl_C4 alkyl, tetrahydrofuranyl-Ci A c4 alkyl group, or the chemical formula—NHC〇2 Ro i, a CH2 C〇2 R0 i, — CH (CH3) C02 R〇1 or a CH (R oz) — C (R〇3) = the freedom of N0Ro 4 Group, wherein R〇1 is methyl, ethyl, propyl, isopropyl or allyl, R〇2 and R〇3 are hydrogen or C! —C4 alkyl, and R0 4 is hydrogen, a "Academy, D-C4 alkenyl or C2-C4 alkynyl, -11- This paper scale is applicable to China National Standard (CNS) Α4 specifications (210Χ297 mm) i mf n ^ i ^^^^ 1 ^^^^ 1 ^^^^ 1 in ^ — n 11 ^ HI— ^^^^ 1 ^ ^,-, (please read the precautions on the back before filling this page) 311873 A7 __ B7__ V. Description of Invention (η) or R Is the chemical formula (Hs C2 0) 2 P (〇) CH2 NHCO- r15 or the free radical, where Rl R16

以及Ri β彼此獨立為羥基,_C4烷基,芳基,Ci -C 4烷氣基,C2 - C4烯基氣,C2 — C4炔基氣,C2 - C4 囪烷氣基,C2 _C8烷氣基烷氣基,h -(;4 «基烷氣基 ,Ci —C4苯基烷氣基或芳基氣或經豳素,银基,硝基或c i -C4烷氣基加以取代之芳基氣,Ri 7為氫,Ci -C4 烷基或苯基,或經鹵素,氣基,硝基或Ci _c4烷氣基加 以取代之苯基,Ri 8為氫,或Ci _c4烷基,Ri 9為氫 或化學式一COCX : X2 - R〇 s之自由基,或烯醯基團,其 包含2至4値硪原子於烯基團中並經鹵素加以取代,且Χι以And Ri β is independently a hydroxy group, a _C4 alkyl group, an aryl group, a Ci-C 4 alkyl gas group, a C2-C4 alkenyl gas, a C2-C4 alkynyl gas, a C2-C4 gas alkyl group, a C2_C8 alkyl gas group Alkyl group, h-(; 4 «alkylalkyl group, Ci —C4 phenylalkyl group or aryl group or aryl group substituted by bismuth, silver, nitro or ci -C4 alkyl group , Ri 7 is hydrogen, Ci -C4 alkyl or phenyl, or phenyl substituted with halogen, gas, nitro or Ci _c4 alkyl gas, Ri 8 is hydrogen, or Ci _c4 alkyl, Ri 9 is Hydrogen or a free radical of COCX: X2-R〇s, or an acetylene group, which contains 2 to 4 atoms in the alkenyl group and is substituted by halogen, and

II

及X2彼此獨立為氫或鹵素,或化學式一 COORo 7或一 C0R 〇 8之自由基或Ci -C4烷基,CZ _C4烯基或h — C4 苯基烷基自由基,其在苯基環上可經鹵素,氰基,硝基或C 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁)And X2 are independently hydrogen or halogen, or a radical of the formula COORo 7 or a COR 〇8 or Ci-C4 alkyl, CZ _C4 alkenyl or h — C4 phenylalkyl radical, which is on the phenyl ring It can be printed by halogen, cyano, nitro or C. Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page)

1 _C4烷氣基加以取代,且R2 0為氫,— C4烷基,C 2 — C4烯基或Cz — C4炔基,R0 e為氫,齒素或“ _C e烷基,R0 7為Ci - C4烷基,Ci _C4苯基烷基或Ct —C4苯基烷基,其在苯基園上經齒素,氰基•硝基或{^ -C4烷氣基加以取代,且R〇 8為C t 一 C4烷基,C2 - C 4烯基,C2 _C4炔基,苯基,Ci — C4苯基烷基或G _ -1 2- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) Β7 Β7 五 經濟部中央標準局ηΛ工消費合作社印製 發明説明( C4苯基烷基,其在苯基圈上經豳素.银基,硝基或Ci —c 4烷氣基加以取代, R25 -〇 —ch2-nr21-co- 或R為化學式 r23 y~ -d 或化學式 R2S \ Π0 / r22 )—ch2-nr21-co- 之自由 基, 其中 R2 i為甲基,乙 闩22 〇 (請先閱讀背面之注意事項再填寫本頁) 基,丙基,1 一甲基乙基,2 —丙烯基,2_ 丁烯基,1, 1一 二甲基一 2—丙烯基,2—丙炔基或2-甲基一 2—丙炔基, 且Rz 2 , Rz 3 , R2 4以及Rz s彼此橱立為氫或甲基, 且Y為氛,或 i 當R為化學式(Hs C2 0) 2 P ( 〇) CH2 NHCO-之自由 基時Y為氫。 相關於式II化合物之列舉烷基圔可以為直鏈或分支且 典型地為甲基,乙基,丙基,丁基,戊基與己基,以及其 分支之異構物。適合的烯基圃為衍生自前述之烷基團。芳 基氧最適合為苯基以及萘氣基。烴基團將以硪以及氫之單 價或雙價,飽和或未飽和之直鏈或分支,或飽和或未飽和 之環基團之意義被了解,典型地為烷基,環烷基,烯基, -13-本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 3ίί873 Α7 Β7 五、發明説明(彳) 炔基,瓖烯基以及苯基。 本發明進一步相鼷於該新頴組成物作為控制栽種植物 ,待別是玉蜀黍之收成中之雜草以及禾草之用途。 作為新穎组成物中使用之偏好之式II化合物, 其中 R33 0\ II R為化學式 尸 之自由基,其中R 3 r34 _ 以及 R3 4共同為 r391 _C4 alkyl group is substituted, and R2 0 is hydrogen, —C4 alkyl, C 2 —C4 alkenyl or Cz — C4 alkynyl, R0 e is hydrogen, halogen or “_C e alkyl, R0 7 is Ci -C4 alkyl, Ci_C4 phenylalkyl or Ct-C4 phenylalkyl, which is substituted on the phenyl by a halogen, cyano • nitro or {^ -C4 alkyl gas group, and R〇8 It is Ct-C4 alkyl, C2-C4 alkenyl, C2_C4 alkynyl, phenyl, Ci — C4 phenylalkyl or G _ -1 2- This paper scale applies the Chinese National Standard (CNS) A4 specification ( 210X297mm) Β7 Β7 The Ministry of Economy Central Standards Bureau ηΛ 工 consumer cooperative printed a description of the invention (C4 phenyl alkyl, which is on the phenyl ring by Bin Su. Silver, nitro or Ci — C 4 alkyl gas To be substituted, R25 -〇-ch2-nr21-co- or R is the chemical formula r23 y ~ -d or the chemical formula R2S \ Π0 / r22)-radical of ch2-nr21-co-, wherein R2 i is methyl, ethyl bolt 22 〇 (please read the precautions on the back before filling in this page) radical, propyl, 1-methylethyl, 2-propenyl, 2-butenyl, 1, 1-dimethyl-2-propenyl, 2-propynyl or 2-methyl-2- Propynyl, and Rz 2, Rz 3, R2 4 and Rz s stand for each other as hydrogen or methyl, and Y is an atmosphere, or i when R is the chemical formula (Hs C2 0) 2 P (〇) CH2 NHCO- Free radicals when Y is hydrogen. The enumerations related to compounds of formula II can be straight chain or branched and are typically methyl, ethyl, propyl, butyl, pentyl and hexyl, and the isomerization of their branches Suitable alkenyl gardens are derived from the aforementioned alkyl groups. Aryloxy is most suitable for phenyl and naphthalene gas groups. Hydrocarbon groups will be monovalent or divalent, saturated or unsaturated, straight or The meaning of branching, or saturated or unsaturated cyclic groups is understood, and is typically alkyl, cycloalkyl, alkenyl, -13-This paper scale is applicable to China National Standard (CNS) Α4 specification (210Χ297mm) 3ίί873 Α7 Β7 5. Description of the invention (彳) The alkynyl group, the alkenyl group and the phenyl group. As a preferred compound of formula II used in novel compositions, where R33 0 \ II R is Free radicals of the corpse, of which R 3 r34 _ and R3 4 are both r39

-R.3 7以及 R3 8彼 H » -1 ^^1 _—In - - - ,士- - - -I 1 ^^1 ...... (請先閱讀背面之注意事項再填寫本頁) CH2) » 且纪3 9為氣,Cl — CU院基或 經濟部中夬樣隼局員Μ消費合阼汪"焚 中 特別合適之式II化合物之實例陳列於下列表1以及表 表1 :式11之化合物 -1 4 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ25»7公釐) 五、發明説明( 33、-R.3 7 and R3 8 H »-1 ^^ 1 _—In---, 士----I 1 ^^ 1 ...... (Please read the notes on the back before filling in this Page) CH2) »Qiji 3 9 is gas, Cl — CU courtyard or the Ministry of Economic Affairs, the member of the Falcon Bureau M consumption example, examples of particularly suitable compounds of formula II in burning are shown in Table 1 and Table below 1: Compound of formula 11-1 4-This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ25 »7mm) Fifth, the invention description (33,

Η c 釋 :c N 34 A7 B7Η c Interpretation: c N 34 A7 B7

Cmpd.No. R33 R34 R33 + R34 1.001 1.002 1.003 CH2=CHCH2 CH2:CHCH2 CH3 CH3 ch3、 CH3 CH3 厂 〇 訂 (請先閱讀背面之注意事項再填寫本頁) 1.004 1.005Cmpd.No. R33 R34 R33 + R34 1.001 1.002 1.003 CH2 = CHCH2 CH2: CHCH2 CH3 CH3 ch3, CH3 CH3 factory 〇 order (please read the precautions on the back before filling this page) 1.004 1.005

1.0061.006

-15- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 五、發明説明( 1.007 1.008 1.009 1.010 CH· A7 B7-15- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of the invention (1.007 1.008 1.009 1.010 CH · A7 B7

0. .00. .0

---------裝-- (請先閱讀背面之注意事項再填寫本頁) 訂 ,=CHdH2 CH2-CH2- och3 ,och3 1.011 (CH3)2CH- ch2- -16 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 B7 五、發明説明( 表2 :式11之化合物--------- install-- (Please read the precautions on the back before filling in this page) Order, = CHdH2 CH2-CH2- och3, och3 1.011 (CH3) 2CH- ch2- -16 This paper size is applicable China National Standard (CNS) A4 specification (210X297mm) A7 B7 5. Description of invention (Table 2: Compound of formula 11

2.1 (C2H50)2P(0)-CH2-NHC0-CH2-CI 2.2 0^0 CH〇 、(:HCI, (請先閱讀背面之注意事項再填寫本頁) 裝. S —組镉好之式II化合物所包括的化合物,其中R為 -9 R 25 \ 1—0 化學式 / H22 L〇 -CH2*NR2^-CO- 之自由基,其中 \ R2 1 甲基, 乙基, 丙基, 2—丙烯基 或2— 丁烯基,且 R2 Z 及Rz 5 為氫。 在此 組化合物中, 待別偏好的化合物為其 中r2 t為 2—丙烯基》 進一步偏好之式II化合物為,其中R為化學式2.1 (C2H50) 2P (0) -CH2-NHC0-CH2-CI 2.2 0 ^ 0 CH〇, (: HCI, (please read the precautions on the back before filling in this page) Packed. S-group cadmium good formula II Compounds included compounds, where R is -9 R 25 \ 1-0 chemical formula / H22 L〇-CH2 * NR2 ^ -CO- free radical, where \ R2 1 methyl, ethyl, propyl, 2-propene Group or 2-butenyl, and R2 Z and Rz 5 are hydrogen. In this group of compounds, the preferred compound is where r2 t is 2-propenyl. The compound of formula II which is further preferred is where R is the chemical formula

之自由基,其中]^至R8彼此獨 -17- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐〉 3 Α7 Β7Free radicals, where] ^ to R8 are independent of each other -17- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm> 3 Α7 Β7

(P-X)n 五、發明説明(G) 立為氫或Cx _C4烷基。那些其中I至1^7為氫且R8為甲 基之化合物為特別合適的β 在另一組持別偏好之化合物中R為化學式 尺14 1 之自由基,其中Rl4為氫,(P-X) n V. Description of the invention (G) stands for hydrogen or Cx_C4 alkyl. Compounds in which I to 1 ^ 7 are hydrogen and R8 is methyl are particularly suitable. In another group of compounds with different preferences, R is a free radical of formula 14 1 in which R14 is hydrogen,

Ci — C4院基或Ci ~~C4院氣基,P為Ci — C4院基,C2 —c4烯基或C2 — C4炔基,X為0或S,η為1,Age, —C8 經基匾且1^ 3為氬或-Cs烴基團。在此组化合物中, 那些其中4為Cx - C4烷氣基,P為C: 一 C4烷基,X為 0, A為Ci -C4伸烷基且R, 3為“ -C4烷基之式II之化 合物為特別合適的。其中Ri 4為甲氣基,P為甲基,A為亞 i 甲基且Ri 3為異丙基之化合物為待別有利的。 進一步之一組式11之偏好化合物,為其中R為化擧式 裝-- (請先閱讀背面之注意事項再填寫本頁) '1ΤCi — C4 hospital group or Ci ~~ C4 hospital gas group, P is Ci — C4 hospital group, C2- C4 alkenyl group or C2- C4 alkynyl group, X is 0 or S, η is 1, Age, —C8 meridian group Plaque and 1 ^ 3 is argon or -Cs hydrocarbon group. In this group of compounds, those in which 4 is Cx-C4 alkane, P is C: a C4 alkyl, X is 0, A is Ci -C4 alkylene and R, 3 is "-C4 alkyl Compounds of II are particularly suitable. Compounds in which Ri 4 is a methyl group, P is a methyl group, A is a methylene group and Ri 3 is an isopropyl group are further advantageous. A further preference of group 11 Compounds, in which R is a chemical lifting device-(Please read the precautions on the back before filling this page) '1Τ

R 15R 15

R ^PCOJ-CR^R^-NfNR^R^-CO- 16 之自由基者,其中 RlS及R ^ PCOJ-CR ^ R ^ -NfNR ^ R ^ -CO- 16 free radicals, of which RlS and

Ri 6彼此獨立為羥基,Ci _C4烷基或Ci — c4烷氣基, Ri 7及Ri 8彼此獨立為氫或Ci — C4烷基,且Ri 9為氳 或化學式一 COOR0 7之自由基,其中R〇 tSc, — C4烷基 -1 8 - 本紙張尺度適用中國國家標準(CNS ) Α4说格(210X297公釐) 五、發明説明(4 A7 B7 ,且R2 〇為氫或Ci 一 C4烷基。最偏好Ri S以及Ri 5為 Cl — C4院氣基,Rl 7以及Rl 8為氮,Rl 9為,化學式 —COOR0 7之自由基,其中R〇 7為(^ ~C4烷基,且R2 〇為氫》其中s以及Ri s為異丙氣基且I 9為一 C00C 2 H s之化合物為特別重要的。 待別合適之組成物包含,如式II之化合物,式III之化 合物 CH, (in) CO-CHCI,Ri 6 is independently hydroxy, Ci_C4 alkyl or Ci-c4 alkyl, Ri 7 and Ri 8 are independently hydrogen or Ci-C4 alkyl, and Ri 9 is a free radical of the chemical formula COOR0 7, wherein R〇tSc, — C4 alkyl-1 8-This paper scale is applicable to the Chinese National Standard (CNS) Α4 said grid (210X297 mm) 5. Description of the invention (4 A7 B7, and R2 〇 is hydrogen or Ci-C4 alkyl The most preferred Ri S and Ri 5 are Cl-C4 gas group, Rl 7 and Rl 8 are nitrogen, Rl 9 is a free radical of the formula -COOR0 7, wherein R〇7 is (^ ~ C4 alkyl, and R2 〇 is hydrogen》 Compounds in which s and Ri s are isopropyl and I 9 is a C00C 2 H s are particularly important. Other suitable compositions include, for example, compounds of formula II, compounds of formula III CH, (in) CO-CHCI,

或式IVOr formula IV

或式 V cr 0 N ——CO-CHCU (IV) H3C XCH, .CH, N N——CO-CHCI·;Or V cr 0 N ——CO-CHCU (IV) H3C XCH, .CH, N N——CO-CHCI ·;

H3C . 'CH3 (V). i 裝 訂 (請先閱讀背面之注意事項再填寫本頁) -19 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟郎中夬瞟隼苟員1.¾費合ftfi.千ai Α7 Β7 五、發明説明(A ) 本發明實施中使用之式I化合物以及其製備被描述於,待 別是 US - A— 5 002 606中β使用於新穎組成物中之式II 化合物以及其製備特別被描逑於US Α— 4 9 7 1 6 1 8 , US-A- 3 9 5 9 3 0 4 , US- A- 4 2 5 6 48 1, US - A - 4 7 0 8 7 3 5 , EP- A- 1 49 974, EP-A- 3 0 4 40 9 , EP- A- 31 686 , EP- A- 54 278, EP- A- 2 3 3 0 5 , US- A - 4 846 880 , EP- A- 143 0 78, EP-A- 1 63 60 7 , EP- A - 1 2 6 7 1 0,以及 DE-A— 2 9 48 5 3 5 中。 本發明亦相親於一種選擇性控制栽種植物之收成中之 雜草之方法,其包括利用除草性有效份量之式I化合物以及 ,為了對抗除草劑,一防衮枯(antidotally)性有效份量 之式II化合物,同時地或分開地,對栽種植物,種子或幼 苗或其收成區域進行處理。 合適之栽種植物,其能夠被式II之化合物保護而對抗 前述除草劑之有害活性,镐好為那些有利於食物或紡纗部 分(textile sector),典型地為蔗耱以及,特別地,粟 以及玉蜀黍,以及稻米和其它不同的穀物如小麥,裸麥, 大麥以及燕麥。 欲控制之雜草可以為單子葉植物以及雙子葉植物雜草 〇 -2 0 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ---------裝— (請先閱讀背面之注意事項再填寫本頁) 訂 A7 B7 五、發明説明(+ ) 收成區域為已利用農作植物或其種子進行栽種中之匾 域,以及意欲利用該農作植物進行栽種之區域》 根據最後之用途,式II之保護劑(safener)可用作前 處理農作植物之種子(種子或幼苗之被覆)或其可在播種 之前或之後被纳入土壊中β然而其亦可單獨地或與萌發前 (preenergence)或萌發後(posteaergence)除草劑一起 施用。因此以保護劑(safener)處理植物或種子原則上可 不考慮植物毒性化學蕖品之施用時間而加以實行。然而植 物之處理亦可經由同時施用植物毒性化學藥品以及保護劑 (safener)而加以實行(罐式(tank)混合物> 。 保護劑(safener)相對於除草劑之欲被施用之濃度基H3C. 'CH3 (V). I binding (please read the precautions on the back before filling in this page) -19 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Economic Lang Zhongzuo Gou 1 .¾ 费 合 ftfi. 千 ai Α7 Β7 V. Description of the invention (A) The compound of formula I used in the practice of the present invention and its preparation are described below, except that US-A-5 002 606 is used in novel compositions The compound of formula II and its preparation are described in particular in US Α-4 9 7 1 6 1 8, US-A- 3 9 5 9 3 0 4, US- A- 4 2 5 6 48 1, US-A -4 7 0 8 7 3 5, EP- A- 1 49 974, EP-A- 3 0 4 40 9, EP- A- 31 686, EP- A- 54 278, EP- A- 2 3 3 0 5 , US- A-4 846 880, EP- A- 143 0 78, EP-A- 1 63 60 7, EP- A-1 2 6 7 1 0, and DE-A-2 9 48 5 3 5 The present invention is also blind to a method for selectively controlling weeds in the harvest of planted plants, which includes the use of a herbicidally effective amount of a compound of formula I and, in order to combat herbicides, an antidotally effective amount Compound II, simultaneously or separately, treats the planted plant, seed or seedling, or its harvest area. Suitable planting plants, which can be protected by the compound of formula II against the harmful activity of the aforementioned herbicides, are preferably those that are beneficial to food or the textile sector, typically sugarcane and, in particular, millet and Maize, as well as rice and other different grains such as wheat, rye, barley and oats. The weeds to be controlled can be monocotyledonous and dicotyledonous weeds. 0-2 0-This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) --------- installed-( Please read the precautions on the back before filling out this page) Order A7 B7 V. Description of the invention (+) The harvest area is the plaque field in which the agricultural plant or its seeds have been used for planting, and the area intended to use the agricultural plant for planting. " Depending on the final use, the safener of formula II can be used to pre-treat the seeds of agricultural plants (covering of seeds or seedlings) or it can be incorporated into the soil before or after sowing. However, it can also be used alone or Apply with preenergence or posteaergence herbicides. Therefore, treatment of plants or seeds with a safener can be carried out in principle without considering the application time of phytotoxic chemicals. However, the treatment of plants can also be carried out by the simultaneous application of phytotoxic chemicals and a safener (tank mixture). The concentration of the safener relative to the herbicide to be applied

I 本上將視施用之型式而定。當—田野處理是經由使用含有 保護劑(safener)與除草薄I相結合之罐式(tank)混合物 或經由保護劑(safener)輿除草劑分別施用加以實行時, 保護劑(safener)與除草劑之比例通常将為自1: 1〇〇至1 :1 ,瘺好自1 : 50至1 : 10。 在田野處理時,通常將施用〇· 〇〇1至5· 0公斤/公頃 ,偏好0. 001至0, 5公、斤/公頃之保護劑(safener) β -2 1- 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ^^1 -- j - - - -1 In 1^1 J I 少^/ ί n -- 1· ml m 0¾. 、-° (請先閲讀背面之注意事項再填寫本頁) 法 方 用 施 ί 有後 所發 之萌 , 農用 於施 用} … Θ 使 C 通ell i s 普 Γ G 於 a 合 適pr 為 ί 物前 成發 組萌 穎含 新包 其 A7 B7 一- - 五、發明説明(η ) 除草劑之濃度通常為自〇. 001至10公斤/公頃之範園 内,但偏好為自0. 005至5公斤/公頃β posteaergence)施用以及種子被覆β 在種子被覆而言,通常將施用〇. 001至公克之保護 劑(safener) /公斤之種子,偏好〇· 至2公克之保護劑 (safener) /公斤之種子,。當保護劑(safener)是以 液態型式在播種前短暫地被使用以達到浸泡作用,則其镳 好使用含有1至10000PPB, Μ好100至10Q0PP·濃度之活性成 分之保護劑(safener)溶液β i 在施用方面,其偏好將式11之化合物,或式11化合物 與式I除草劑之混合物,與方便使用於調劑技術中之肋劑一 起被加工成為典型地乳化性旗缩物類,包覆性之糊狀物類 ,可直接噴躧或經稀釋之乳劑類,溼潤性粉末類,溶解性 粉末類,粉塵類,顆粒類或撤駿囊類。 配方是以熟知之方式加以製備,例如經由均質化混合 以及/或研磨活性成分與添加劑,典型地與溶劑類或固體 載劑類。表面活性化合物(界面活性劑)可額外地被使用 -22- 本纸張尺度適用中國國家標準(CNS ) A4規格(210Χ:29·7公釐)I This will depend on the type of application. When the field treatment is carried out through the use of a tank mixture containing a safener combined with the herbicide I or through separate application of the safener and herbicide, the safener and herbicide The ratio will usually be from 1: 100 to 1: 1, and the fistula is from 1:50 to 1:10. In field treatment, usually 〇.〇〇1 to 5.0 kg / hectare, the preference is 0.001 to 0, 5 kg, hectare / hectare protective agent (safener) β -2 1- This paper size is applicable China National Standard (CNS) A4 specification (210X297mm) ^^ 1-j----1 In 1 ^ 1 JI less ^ / ί n-1 · ml m 0¾.,-° (please read the back first Please pay attention to this page and then fill out this page) The French side uses ShiLu after the germination, which is used for agricultural application}… Θ makes C Tongell is 普 Γ G 于 a suitable pr is ί before the growth group Mengying contains new packages Its A7 B7 1--5. Description of the invention (η) The concentration of the herbicide is usually from 0.001 to 10 kg / ha in the garden, but the preference is from 0.005 to 5 kg / ha β posteaergence) application and seeds Coating β In the case of seed coating, usually 0.001 to gram of safener / kg of seed will be applied, and 〇 to 2 g of safener / kg of seed will be preferred. When the safener is used in a liquid form for a short time before sowing to achieve the soaking effect, the safener solution β containing an active ingredient with an active ingredient concentration of 1 to 10000PPB, 100 to 10Q0PP · i In terms of application, it prefers to process the compound of formula 11, or the mixture of the compound of formula 11 and the herbicide of formula I, together with the rib agent that is convenient to be used in the preparation technology, into a typical emulsified constrictor, coated Sexual pastes can be sprayed directly or diluted emulsions, moist powders, soluble powders, dusts, granules or sachets. The formulations are prepared in a well-known manner, for example by homogenous mixing and / or grinding the active ingredients and additives, typically with solvents or solid carriers. Surface-active compounds (surfactants) can be used additionally -22- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210Χ: 29.7mm)

In m 1^1 m - - -H —^ϋ m f I i m I- -I In --—-I- nt ^ij 、-* (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼馬員工消費合阼汪中裝In m 1 ^ 1 m---H — ^ ϋ mf I im I- -I In --—- I- nt ^ ij,-* (please read the precautions on the back before filling in this page) Falcon employee consumption suits

i、發明説明(π ). 於製備此配方《> 批衣-- (請先閲讀背面之注意事項再填寫本頁) 合逋之溶劑類可典型地為:芳番性烴類,禳好為包含8 至12個硪原子之部分,例如二甲苯混合物或經取代之萘類 ;酞酸酯類如鈦酸二丁基酯或酞酸二辛基酯;脂肪性烴類 如環己烷或石臘類;酒精類以及乙二醇類及其鰱類及酯類 ,例如乙醇,伸乙基乙二酵,2 —甲氣基乙酵或2 —乙氣基 乙醇;銅類如環己酮;強烈極性溶劑類如N—甲基- 2 —吡 咯酮,二甲基亞《或二甲基甲醛胺;以及植物油類或璟氣 化之植物油類如環氣化椰子油或黃豆油;或水。 訂 針對粉塵類或可散佈之粉末類所典型使用之固體載劑 類通常為天然礦物質填料類如方解石(calcite),滑石, 高嶺土 ( k a 〇 i i η),縈脱土 ( b ο n t at 〇 r i 1 i ο n i t e)或美國活i. Description of the invention (π). In the preparation of this formula "> batch clothing-(please read the precautions on the back before filling in this page) The combined solvents can be typically: aromatic hydrocarbons, good It is a part containing 8 to 12 atoms, such as xylene mixtures or substituted naphthalenes; phthalates such as dibutyl titanate or dioctyl phthalate; aliphatic hydrocarbons such as cyclohexane or Paraffins; alcohols and ethylene glycols and silver carp and esters, such as ethanol, ethylidene, 2-methylaminoethyl or 2-ethylaminoethanol; copper such as cyclohexanone ; Strong polar solvents such as N-methyl-2-pyrrolidone, dimethyl sulfoxide or dimethyl formaldehyde amine; and vegetable oils or vegetable oils such as cyclic gasified coconut oil or soybean oil; or water . The solid carriers typically used for dusts or dispersible powders are usually natural mineral fillers such as calcite, talc, kaolin (ka 〇ii η), and bleached soil (b ο nt at 〇 ri 1 i ο nite) or American live

I 性白土 (attapulgite)。為了改善其物理特性,亦有可能 加入高度散佈之矽酸或高度散佈吸收性之聚合物。適合之 粒狀吸收性載劑類為多孔性型態,其包含浮石(pumice) ,碎磚(brokenbrick),海泡石(sepioiite)或澎潤土 (bentonite);且合適之非吸收性載劑類為例如方解石( calcite)或砂等材料》此外,可使用無機或有機來源之大 量先成顆粒狀材料,特別是白雲石(dolomite)或粉碎之 植物殘留物類。 -23- 本紙張尺度逋用中國國家標準(CNS > A4規格(210X297公釐〉 經濟邹中央螓隼苟員工消費合阼汪中襄 A7 __— _B7_ 五、發明説明(Λ ) 根據保護劑(safener),通常亦根據除草劑而定,合 適之表面活性化合物類為非離子性,陽離子性及/或陰離 子性界面活性劑類,其具有良好之乳化,散佈及濕潤特性 。界面活性劑類亦可被瞭解為界面活性劑類的混合物類β 合適之陰離子性界面活性劑類可以為水溶性皂類及水 溶性人工合成之表面活性化合物類^ 合適的皂類為驗金颶鹽類,鹼土金鷗鹽類,銨鹽類或 較高级脂肪酸0 — C2 2 )之經取代之銨鹽類,例如 油酸或硬脂酸之納或鉀鹽類,或可得到之天然脂肪酸,尤 其是得自椰子油或牛脂油,之混合物之納或鉀鹽類*進一 步合適之皂類劑亦為脂肪酸甲基牛臛驗(taurin)鹽類β 然而,所諝的人工合成界面活性劑類被使用的更加頻 繁,持別是脂族磺酸酯類,脂族硫酸酯類,磺化笨並味唑 衍生物類或或烷基芳基磺酸酯類。 脂族醇磺酸酯類或硫酸酯類通常為鐮金屬鹽類,齡土 金屬鹽類,銨鹽類或經取代之銨鹽類之型式,且它們含有C S -CZ 2烷基圃,其亦包含醯基自由基之烷基團,例如木 素磺酸之納或鈣鹽,十二烷基硫酸之鈉或鈣鹽,或得自天 然脂肪酸之脂族醇硫酸酯類之混合物之鈉或鈣鹽。這些化 -24- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) —^1 - i n^i - -- -I l^n I »^—^1 ml l^n mu 一OJ (請先閱讀背面之注意事項再填寫本頁) 經濟郎中夬螓隼¾員I.消费合^f±.;pai A7 ____B7_ 五、發明説明(>") 合物亦包括硫化及磺化脂族醇/乙烯氣化物加成化合物之 鹽類。磺化之苯並昧唑衍生物類镉好包含兩傾磺酸基團以 及一個含有8至22値硪原子之脂肪酸基圃。烷基芳基磺酸酸 類之說明實例為十二烷基苯磺酸之鈉,鈣或三乙酵胺鹽類 ,二丁基萘磺酸,或萘磺酸與甲醛之缩合物之鈉,鈣或三 乙醇胺鹽類。 相關之磷酸盥類,典型地含有4至14莫耳乙烯氣化物之 Ρ-壬基酚加成化合物之磷酸酯之鹽類,或磷脂類亦為合適 的。 非離子性界面活性劑類偏好為脂族或環脂族酵類之聚 乙二醇醚衍生物類,或飽和的或未飽和脂肪酸類以及烷基 酚類之聚乙二醇醚衍生物類,該衍生物類包含3至30値乙二I sex white clay (attapulgite). To improve its physical properties, it is also possible to add highly dispersed silicic acid or highly dispersed absorbent polymers. Suitable granular absorbent carriers are porous and include pumice, broken brick, sepioiite or bentonite; and suitable non-absorbing carriers Classes are materials such as calcite or sand. In addition, a large number of pre-granulated materials from inorganic or organic sources can be used, especially dolomite or crushed plant residues. -23- The standard of this paper adopts Chinese National Standard (CNS> A4 specification (210X297mm) Economy Zou Central Falcon employees consumption consumption Wang Zhongxiang A7 __— _B7_ V. Description of invention (Λ) According to safener , Usually depending on the herbicide, suitable surface-active compounds are nonionic, cationic and / or anionic surfactants, which have good emulsification, dispersion and wetting properties. Surfactants can also be Known as a mixture of surfactants. Β Suitable anionic surfactants can be water-soluble soaps and water-soluble synthetic surface-active compounds. ^ Suitable soaps are gold test salts and alkaline earth gold gull salts. , Ammonium salts or higher fatty acids 0-C2 2) substituted ammonium salts, such as sodium or potassium salts of oleic acid or stearic acid, or available natural fatty acids, especially from coconut oil or Tallow oil, sodium or potassium salts of mixtures * Further suitable soaps are also fatty acid methyl taurin salts (beta). However, the synthetic surfactants used are more Frequently, they are aliphatic sulfonates, aliphatic sulfates, sulfonated benzotriazole derivatives or alkylarylsulfonates. Aliphatic alcohol sulfonates or sulfates are usually It is a type of sickle metal salt, aged earth metal salt, ammonium salt or substituted ammonium salt, and they contain a CS-CZ 2 alkyl nursery, which also contains an alkyl group of an acyl radical, such as wood Sodium or calcium salt of sodium sulfonate, sodium or calcium salt of dodecyl sulfate, or sodium or calcium salt of a mixture of aliphatic alcohol sulfates derived from natural fatty acids. National Standard (CNS) A4 specification (210X297 mm) — ^ 1-in ^ i---I l ^ n I »^ — ^ 1 ml l ^ n mu one OJ (please read the notes on the back before filling in This page) Economical Langzhong Falcon Falcon ¾ member I. Consumption ^ f ± .; pai A7 ____B7_ V. Description of the invention (> ") Compounds also include sulfurized and sulfonated aliphatic alcohol / ethylene gas compound addition compounds The salts of sulfonated benzodazole derivatives include cadmium sulfonic acid groups and a fatty acid base containing 8 to 22 atoms. Alkyl aryl sulfonic acid Illustrative examples of the class are sodium, calcium or triethanolamine salts of sodium dodecylbenzenesulfonate, calcium or triethylpyramide, dibutylnaphthalenesulfonic acid, or condensates of naphthalenesulfonic acid and formaldehyde. Related phosphoric acid detergents, typically salts of phosphate esters of P-nonylphenol addition compounds containing 4 to 14 moles of ethylene vapor, or phospholipids are also suitable. The preference for nonionic surfactants is Polyethylene glycol ether derivatives of aliphatic or cycloaliphatic enzymes, or polyethylene glycol ether derivatives of saturated or unsaturated fatty acids and alkylphenols, the derivatives containing 3 to 30 B2

I 醇Κ基園以及8至2 0锢碩原子於(脂族)烴基園中以及6至 18値碩原子於烷基酚類之烷基匾中。 進一步合適之非離子性界面活性劑類為聚乙烯氧化物 與聚丙烯乙二酵之水溶性聚加成化合物類,乙烯二胺基聚 丙烯乙二醇以及含有1至10値碩原子於烷基鐽中之烷基聚丙 烯乙二醇,該聚加成化合物類包含20至2 5 0値乙烯乙二醇酸 基圃以及10至100値丙烯乙二醇醚基團β這些化合物通常為 每锢丙烯乙二醇單位包含1至5健乙烯乙二醇單位β -25- 本紙張U適用中國國家標準(CNS ) Α4規格(210Χ297公釐) I — · - m - - - - |士良- 1— - —1 - - I — n τ» 'νβ (請先閱讀背面之注意事項再填寫本頁) B7 五、發明説明(vl ) 非離子性界面活性劑類之説明實例為壬基酚聚乙氣基 化物類,聚乙氣基化Μ麻油,聚丙烯與聚乙烯氣化物之聚 加成化合物類,三丁基酚聚乙氣基化物,聚乙烯乙二醇以 及辛基酚聚乙氣基化物<» 聚氣乙烯山梨聚耱之脂肪酸酯類亦為合適的非離子性 界面活性劑類,典型地為聚氣乙烯山梨聚糖三油酸酯β 陽離子性界面活性劑類偏好為四级銨鹽類,其如Ν—取 代物,帶有至少一傾C8 — Cz 2烷基團以及,如進一步的 取代物,帶有未經取代之或鹵化之較低级烷基,苄基或羥 基-較低级烷基團β鹽類镐好為囱化物類,硫酸甲基鹽類 或硫酸乙基鹽類之型式,例如硬脂酵三甲基銨氛化物或苄 基雙(2_氣乙基)乙基銨溴化物β 經濟部中夬樣隼局員工消費合阼; (請先閱讀背面之注意事項再填寫本頁) 習慣施用於調劑業界中之界面活性劑類被描述於,特 別是,Λ M c Cutcheon ^ s Detergents and Emulsifiers Annual ^ , M C Publishing C o r p. , Glen Rock, NewI Alcohol K group and 8 to 20 atoms in the (aliphatic) hydrocarbon group and 6 to 18 atoms in the alkyl phenol alkyl plaque. Further suitable nonionic surfactants are water-soluble polyaddition compounds of polyethylene oxide and polypropylene glyoxylate, ethylene diamine polypropylene glycol and containing 1 to 10 large atoms in alkyl groups Alkyl polypropylene glycols in the compound, the polyaddition compounds containing 20 to 250 vol ethylene glycol acid base and 10 to 100 propyl propylene glycol ether groups β These compounds are usually Propylene glycol unit contains 1 to 5 healthy ethylene glycol units β -25- This paper U is suitable for China National Standard (CNS) Α4 specification (210Χ297 mm) I — ·-m----| Shiliang-1 —-—1--I — n τ »'νβ (please read the precautions on the back before filling in this page) B7 5. Description of invention (vl) Non-ionic surfactants are examples of nonylphenol polyethylene Gas-based compounds, polyethylene gas-based sesame oil, polyaddition compounds of polypropylene and polyethylene gas compounds, tributylphenol polyethylene gas-based compounds, polyethylene glycol and octylphenol polyethylene gas-based Compounds < »Fatty acid esters of polygas ethylene sorbitan are also suitable nonionic interfaces Agents, typically polyoxyethylene sorbitan trioleate β. Cationic surfactants prefer quaternary ammonium salts, such as N-substitutes, with at least one C8-Cz 2 alkyl group Groups and, if further substituted, with unsubstituted or halogenated lower alkyl groups, benzyl or hydroxy-lower alkyl groups, beta salts are preferably halide compounds, methyl sulfate salts Or the type of ethyl sulfate, such as stearyl trimethylammonium chloride or benzyl bis (2_ gas ethyl) ethyl ammonium bromide β Consumption of employees of the Falcon Bureau of the Ministry of Economic Affairs; (please Read the precautions on the back before filling out this page) Surfactants used in the conditioning industry are described in, in particular, Λ M C Cutcheon ^ s Detergents and Emulsifiers Annual ^, MC Publishing C or p., Glen Rock , New

Jersey , 1981, fl. Stache ,々 Tens id - Taschenbuch " (Handbook of Surfactants) , Carl Hanser Verlag, Munich/ Vienna 1981,以及 J. Ash, "Encyclopedia of Surfactants’’, V o 1. I — III. Chenical -26- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 S11873 B7 五、發明説明(分)Jersey, 1981, fl. Stache, 々Tens id-Taschenbuch " (Handbook of Surfactants), Carl Hanser Verlag, Munich / Vienna 1981, and J. Ash, " Encyclopedia of Surfactants '', V o 1. I — III . Chenical -26- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) A7 S11873 B7 V. Invention description (minutes)

Publishing Co. , New York, 1980— 81 中0 (請先閣讀背面之注意事項再填寫本頁) 農業化學配方通常將包含式II保護劑(safener)或保 護劑(safener)與除草劑之混合物之重董百分比為自〇. 1 至99%,偏好自0. 1至95%重董百分比,固體或液體配方 助劑之重量百分比為自1至99· 9%,偏好為自5至99. 8% 重量百分比,以及界面活性劑之重量百分比為自0至25%, 徧好0. 1至25%重置百分比。 雖然偏好調製商品為濃縮物類,使用者一般將使用稀 釋配方。 組成物亦可包含進一步的成分如穩定劑類,防沫劑類 ,黏度調控劑類,結合劑類,粘合劑類,以及肥料或其它 i 化學剤類,如商品化乙醯氯苯胺類如 Frontier, Metazachlor, Acetochlor, Alachlor, Metolachlor或 Butachlor,以供達成特別之效果 經濟部中夬標隼局員工消費合作;ϋ印裂 不同的方法以及技術可適當地被用作施用式11化合物 或包含它們的组成物以供保護栽種植物免於式I除草劑之有 害影蜜,典型地為如下所列: i)種子被覆 -2 7 _ 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 經濟部中夬標隼局員工消費合阼汪中" A7 ___ _B7 五、發明説明(Λ ) a) 利用式II化合物之潮溼性粉末配方被覆種子,其經 由在一容器中搖動直到保護劑(safener)均勻地分佈於種 子表面(乾燥處理),每10Q公斤之種子使用達〇· 1至500 公克之式II化合物(4公克至2公斤之潮溼性粉末)》 b) 利用式II化合物之乳化性濃縮物經由方法a)被覆 種子(潮溼處理)。 c) 經由將種子浸泡於含有1〇〇至1000PPB之式II化合物 之混合物中達1至72小時進行被覆,使其保持潮溼或接箸將 其乾燥(種子浸泡)β 發芽幼苗之種子被覆或處理自然而然為鴒好之施用方 法,如同保護劑(safener)之處理是完全地集中在標的農 作物上》通常1至1000公克,鴒好5至250公克,之保護劑( safener)被使用於每100公斤之種子。然而,依據使用之 方法而定,其亦允許使用其它化學劑或徹滋養物·自指示 之限制濃度正或負偏差均為可能的(重覆被覆)。 ii)自一罐式(tank)混合物之施用 使用保護劑(safener)以及除草劑混合物之液體配方 -28- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) m n nn m^i nn nn n· nn nn -In- —^ϋ ^^^1 - J% 、vd (請先閲讀背面之注意事項再填寫本頁) A7 B7 〜____ - - - - ..... - 五、發明説明(,ο (相互比例為自ίο: 1至1: 100),除草劑之潘度為自0· 01至10公斤/公頃。此罐式(tank)混合物是在播種之前 或之後施用β iii) 田畦中之應用 保護劑(safener)被調製成為乳化性濃编物,潮溼性 粉末或顆粒而被施用至開放田畦,其中種子已被播種。覆 蓋田畦之後,以傳统方式施用萌發前(preeaergence)除 草劑。 iv) 保護剤(safener)之控制性釋出 ^1» - - I - - III /^1 I n^i 1^1 I I - - .^ϋ 、T (請先閣讀背面之注意事項再填寫本頁) 画 0 性物 合覆 聚包 或一 質用 受施 粒地 顆外 機額 無—可 至 〇 用燥 施乾 被其 液使 溶並 之 } 物醛 合甲 化 \ II素 式尿 /|\ 粒 經濟部中央標隼局員工消費合作狂印裝 其使得保護劑(safener)之控制性釋出長逹到持定時期。 下列實例更加詳细地説明新穎组成物之活性》 式I化合物以及式II保護劑(safener)之混合物之配 方實施例(之中,百分比為重量百分比) F1·乳化性濃编物類 a) b) c) d) -29- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 五、發明説明(A ) 化合物混合物 5% 10% 25% 50% 十二烷基苯磺酸鈣 6% 8 % 6% 8% 聚乙氣基化蓖麻油 4% — 4% 4% (36莫耳Ε0) 辛基酚聚乙氣基化物 — 4 % 一 2 % (7 — 8 莫耳 Ε0) 環己酮 — — 10 % 20 % 芳香性烴類之混合物 85% 78% 55% 16% C 9 — C 1 2 (請先閱讀背面之注意事項再填寫本頁) 任何想要濃度之乳劑類可經由加水稀釋自該濃縮物進 行製備β F 2 . 溶液類 a) b) c) d) 化合物混合物 5 % 10 % 50% 90% 1 一甲氣基一 3 —(3—甲氣基 一 20 % 20% — 丙氣基)—丙 院 聚乙烯乙二醇 4 0 0 2 0 % 1 0 % — — Ν -甲基一2 — 吡咯烷嗣 一 — 30% 10% 芳香性烴類之 混合物 75% 60 % — — C 9 — C 1 2 -30- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) Μ SU873 五、發明説明(丄) 此溶液適合以撖滴型式使用《> 經濟部中央標隼局員工消費合作社印製 F3. 潮溼性粉末類 a) b) c) d) 化合物混合物 5% 25% 50 % 80% 木素磺酸鈉 4% — 3% — 月桂基硫酸納 2% 3% — 4% 二異丁基萘磺酸銪 — 6% 5% 6% 辛基酚聚乙氣基化物 — 1% 2% — (7— 8 莫耳 E0) 高度分散之矽石 1 % 3% 5% 10% 高嶺土 88% 62 % 35% 將化合物混合物與佐劑 類充分地混合且混合物在適當 的粉碎器中研磨以得到潮溼性粉末 ,其可利用水稀釋得到 任何想要濃度之懸浮液。 F4. 包覆性顆粒類 a) b) c) 化合物混合物 0 . 1% 5% 15% 高度分散之矽石 0. 9% 2% 2% 無機性載劑 99. 3 1- 0 % 93% 83% 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) n ^^^1 t^i m^i - - 1 11^1 m ί· - - If ml nn 1^1 nn 1^1—"V 、vd (請先閱讀背面之注意事項再填寫本页) 經濟部中央標準局員工消費合作社印製 A7 B7_ 五、發明説明(a ) (Φ 0. 1 - 1 毫米)) 如 CaC〇3 或 SiOz 將化合物混合物溶解於亞甲基氣化物中,溶液噴爾至 載劑上,並在真空下除去溶劑。 F5. 包覆性顆粒類 a) b) c) 化合物混合物 0. 1 % 5% 15% 聚乙烯乙二醇 200 1. 0% 2% 3% 高度分散之矽石 0. 9% 1% 2% 無機性載劑 98.0% 92% 80% (Φ 0· 1 - 1 毫米) 如 CaC〇3 或 Si〇2Publishing Co., New York, 1980— 81 in 0 (please read the precautions on the back before filling in this page) Agrochemical formulas will usually contain a formula II protective agent (safener) or a mixture of protective agent (safener) and herbicide The percentage of heavy Dong is from 0.1 to 99%, the preference is from 0.1 to 95% of the heavy Dong percentage, the weight percentage of the solid or liquid formulation auxiliary is from 1 to 99.9%, the preference is from 5 to 99. 1% to 25% reset percentage. 8% by weight, as well as the weight percentage of the surfactant is from 0 to 25%, preferably 0.1 to 25%. Although the preference is to make the product a concentrate, users will generally use dilute formula. The composition may also contain further ingredients such as stabilizers, antifoams, viscosity modifiers, binders, adhesives, and fertilizers or other chemical compounds, such as commercially available acetochloroanilides such as Frontier, Metazachlor, Acetochlor, Alachlor, Metolachlor or Butachlor, for special effects to achieve consumer cooperation in the Ministry of Economic Affairs, China Falcon Bureau employees; ϋ different methods and techniques can be used as appropriate to apply or contain the compound of formula 11 The composition is used to protect planted plants from the harmful shadow honey of formula I herbicides, which are typically listed as follows: i) Seed coating-2 7 _ This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 mm ) Ministry of Economic Affairs Zhongshen Biao Falcon Bureau employee consumption center Wangzhong " A7 ___ _B7 V. Description of the invention (Λ) a) The seeds are coated with the moist powder formula of the compound of formula II, which is shaken in a container until the protective agent (Safener) Evenly distributed on the surface of the seeds (drying treatment), use 0.1 to 500 g of the compound of formula II per 10Q kg of seeds (4 g to 2 kg of moist powder )》 B) Using the emulsifiable concentrate of the compound of formula II to cover the seeds by method a) (moisture treatment). c) Coating by immersing the seeds in a mixture containing the compound of Formula II containing 100 to 1000 PPB for 1 to 72 hours to keep them wet or drying them (seed soaking). Seed coating or treatment of germinated seedlings Naturally, it is a good method of application, as the treatment of the safener is completely concentrated on the target crops. Usually 1 to 1000 grams, 5 to 250 grams of the safe, the safener is used for every 100 kilograms. Seed. However, depending on the method used, it also allows the use of other chemicals or thorough nourishment. Self-instructed limit concentration positive or negative deviations are possible (repeated coating). ii) From the application of a tank mixture, use the safener and the liquid formulation of the herbicide mixture-28- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) mn nn m ^ i nn nn n · nn nn -In- — ^ ϋ ^^^ 1-J%, vd (please read the precautions on the back before filling in this page) A7 B7 ~ ____----.....-V. Description of the invention (, ο (mutual ratio from ίο: 1 to 1: 100), the herbicide pan degree is from 0.01 to 10 kg / ha. This tank mixture is applied before or after sowing. iii) The application of safeners in Tianqi is formulated into emulsified thick weaves, and moist powder or granules are applied to open Tianqi, where the seeds have been sown. After covering the fields, the preeaergence herbicide is applied in the traditional way. iv) The controlled release of the safener ^ 1 »--I--III / ^ 1 I n ^ i 1 ^ 1 II--. ^ ϋ, T (please read the notes on the back before filling in This page) Draw 0 Synthetic compound coating or one particle with the external size of the granules to be applied. No-to-zero. Dry and apply the liquid to be dissolved by the liquid. / | \ The Ministry of Economy and Economics, Central Standard Falcon Bureau employee consumption cooperation mania printed that it makes the release of the protective agent (safener) into a fixed period of time. The following examples illustrate the activity of the novel composition in more detail. Examples of formulations of a mixture of a compound of formula I and a safener of formula II (in which the percentage is a percentage by weight) F1 · Emulsified concentrated a) b) ) c) d) -29- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 5. Description of the invention (A) Compound mixture 5% 10% 25% 50% calcium dodecylbenzenesulfonate 6% 8% 6% 8% Polyethylene gasified castor oil 4% — 4% 4% (36 mol Ε0) Octylphenol polyethylene gas compound — 4%-2% (7 -8 mol Ε0) Cyclohexanone — 10% 20% Aromatic Hydrocarbon Mixture 85% 78% 55% 16% C 9 — C 1 2 (Please read the precautions on the back before filling in this page) Any desired concentration of emulsion can be Β F 2 is prepared from this concentrate by dilution with water. Solutions a) b) c) d) Compound mixture 5% 10% 50% 90% 1 monomethyl group 3 — (3-methyl group 20% 20% — Propyl gas group) —Propylene glycol polyethylene glycol 4 0 0 2 0% 1 0% — — Ν -Methyl-2 — Pyrrolidine Si-30% 10% Aromatic hydrocarbons Mixture 75% 60% — — C 9 — C 1 2 -30- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297mm) Μ SU873 V. Description of the invention (丄) This solution is suitable for use in the drop type "≫ Printed F3. Moisture powder a) b) c) d) Compound mixture 5% 25% 50% 80% Sodium lignosulfonate 4% — 3% — Laurel Sodium sulfate 2% 3% — 4% Europium diisobutylnaphthalenesulfonate — 6% 5% 6% octylphenol polyethylene gas — 1% 2% — (7-8 mole E0) highly dispersed Silica 1% 3% 5% 10% Kaolin 88% 62% 35% The compound mixture and adjuvants are thoroughly mixed and the mixture is ground in a suitable pulverizer to obtain a wet powder, which can be diluted with water to obtain any desired Suspension of desired concentration. F4. Coated particles a) b) c) Compound mixture 0.1% 5% 15% highly dispersed silica 0.9% 2% 2% inorganic carrier 99.3 1-0% 93% 83 % This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) n ^^^ 1 t ^ im ^ i--1 11 ^ 1 m ί ·--If ml nn 1 ^ 1 nn 1 ^ 1— " V, vd (please read the precautions on the back before filling this page) A7 B7_ printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of Invention (a) (Φ 0. 1-1 mm)) Such as CaC 3 or SiOz The compound mixture is dissolved in the methylene vapor, the solution is sprayed onto the carrier, and the solvent is removed under vacuum. F5. Coated particles a) b) c) Compound mixture 0.1% 5% 15% Polyethylene glycol 200 1. 0% 2% 3% Highly dispersed silica 0.9% 1% 2% Inorganic carrier 98.0% 92% 80% (Φ 0 · 1-1 mm) such as CaC〇3 or Si〇2

I 將細碎研磨之化合物混合物在混合器中均勻地施用至 以聚乙烯乙二酵溼潤之高嶺土 (kaolin)。無粉塵包费性 顆粒為以此方式得到〇 F6.擠出顆粒類 a) b) c) d) 化合物混合物 0. 1 % 3% 5% 15% 木質素磺酸納 1. 5% 2% 3% 4% -32- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) —^1 »^^1 HH ^^1· -HI- m >^^1 ϋ^— (^n ^in 、νβ (請先閱讀背面之注意事項再填寫本頁)I Apply the finely ground compound mixture uniformly in a mixer to kaolin moistened with polyethylene glycolate. Dust-free dusty particles are obtained in this way. Extruded particles a) b) c) d) Compound mixture 0.1% 3% 5% 15% sodium lignosulfonate 1.5% 2% 3 % 4% -32- This paper scale applies the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) — ^ 1 »^^ 1 HH ^^ 1 · -HI- m > ^^ 1 ϋ ^ — (^ n ^ in, νβ (Please read the precautions on the back before filling this page)

、發明説明(J) _基申基鐵雒素 1. 4% 2% 2% 2% 97 . 0 % 93% 90 % 79% 将化合物混合物輿佐劑類混合且混合物以水溼潤。將此 €合物通過擠出器且之後在氣流中進行乾燥。 F7. 粉塵類 a) b) c) 化合物混合物 0. 1% 1% 5% 滑石 39. 9% 49% 35% 高嶺土 60. 0% 50% 60% 備用粉塵類是經由将化合物混合物舆載Ϊ«類混合加以 得到並在適合粉碎器上研磨如此得到之混合物。 I I —^I (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印裝 F8. 懸浮液濃縮物類 a) b) c) d) 化合物混合物 3% 10% 25% 50¾ 乙烯乙二酵 5% 5% 5¾ 5% 士基酚聚乙氣基化物 — 1% 2% — (15莫耳E0) 木素磺酸納 3% 3% 4% 5% 羧基甲基纖維素 1 % 1 % 1 % 1 % -33- 本紙張尺度適用中國國家標隼(CMS ) A4規格(210X297公釐) A7 B7 經濟部中央樣隼局員工消費合作社印裝 五、發明説明(Λ ) 37% 甲β水溶液 0. 2% 0. 2% 0. 2% 0. 2% 矽氣烷油狀乳劑 0 . 8% 0. 8% 0. 8% 0. 8% 水 87 % 79% 62% 38% 將细碎研磨之化合物混合物輿佐劑類密切地混合以得 到懸浮液濃缩物,經由以水稀釋可自其製備任何想要濃度 之懸浮液類。 實施例B1:式I除草劑以及除草繭輿式II保護劑( s a f e n e r)混合物對於玉蜀黍之萌發前(P r e e e r g e n c e >植 物毒性2. Description of the invention (J) _Geshenyl iron serotonin 1.4% 2% 2% 2% 97.0% 93% 90% 79% The compound mixture and adjuvants are mixed and the mixture is moistened with water. This compound was passed through an extruder and then dried in a stream of air. F7. Dust category a) b) c) Compound mixture 0.1% 1% 5% Talc 39.9% 49% 35% Kaolin 60.0% 50% 60% Spare dusts are obtained by loading the compound mixture with Ϊ « A similar mixture is obtained and the mixture thus obtained is ground on a suitable grinder. II — ^ I (Please read the precautions on the back before filling this page) F8 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Suspension concentrates a) b) c) d) Compound mixture 3% 10% 25% 50¾ Ethylene Glyoxygen 5% 5% 5¾ 5% Styrene-polyethylene glycolate — 1% 2% — (15 mole E0) sodium lignosulfonate 3% 3% 4% 5% carboxymethyl cellulose 1% 1% 1% 1% -33- This paper scale is applicable to the Chinese National Standard Falcon (CMS) A4 specification (210X297 mm) A7 B7 Printed by the Consumer Consortium of the Central Falcon Bureau of the Ministry of Economic Affairs V. Invention Instructions (Λ) 37 % A β aqueous solution 0.2% 0.2% 0.2% 0.2% silicon oil emulsion 0.8% 0.8% 0.8% 0.8% water 87% 79% 62% 38 % The finely ground compound mixture and adjuvants are mixed intimately to obtain a suspension concentrate, from which suspensions of any desired concentration can be prepared by dilution with water. Example B1: the mixture of the herbicide of formula I and the herbicide cocoon and the protective agent of formula II (s a f e n e r) for the pre-emergence of maize (P r e e e r g e n c e > phytotoxicity

Maize被播種在塑膠花盆内之樣準土壤中。緊接著播種 之後,花盆以受試物質(50 0公升水/公頃)之懸浮水溶液 i 進行噴濯,受試物質由上述配方1至8之一種加以裂備。式1 除草劑之濃度為4000,3000以及2000公克/公頃。保護劑 (safener)第1· 0 0 6號以相對於除草_1: 18, 1: 24以及 1: 30之比例施用。受試植物之後在最適宜之條件下栽種於 溫室中。除草劑對於玉蜀黍之植物毒性(植物毒性百分比 >是在試驗期間22天之後進行評估》 a)除草劑之濃度:4000公克/公頃 -34- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝. 訂 311873 Μ Β7五、發明説明(ρ ) 除草劑相對保護劑之比例 % 植物毒性 無保護劑 65 18 : 1 20 24 : 1 20 30 : 1 15 b)除草劑之濃度:300 0公克/公頃 除草劑相對保護劑之比例 % 檀物毒性 無保 護 劑 55 18 : 1 0 24 : 1 1 0 30 ; 1 0 ^^^1 ^—B—1 nn n·— I— m. ^m— —ml t^i^— n^— i l J (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 c)除草劑之濃度:2 0 0 0公克/公頃 除草劑相對保護劑之比例 % 植物毒性 無保護劑 25 18 : 1 0 2 4 : 1 0 -35- 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 311873 五、發明説明(w ) A7 B7 30 結果顯示式II之化合物能夠顯著地減少由除草劑對栽 種植物造成之傷害。 1 木衣 、v't> (請先閱讀背面之注意事項再填寫本頁) 經濟部中央樣隼局員工消費合作社印装 -36 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)Maize is sown in quasi-soil in plastic pots. Immediately after sowing, the flower pot was sprayed with a suspended aqueous solution i of the test substance (500 liters of water / ha), and the test substance was prepared by one of the above formulas 1 to 8. The concentration of formula 1 herbicide is 4000, 3000 and 2000 g / ha. Safener No. 1 · 0 0 6 was applied in the ratio of weeding 1: 18, 1: 24 and 1: 30. The tested plants are then planted in the greenhouse under the most suitable conditions. The phytotoxicity of herbicides to maize (percentage of phytotoxicity> is evaluated after 22 days of the test period "a) The concentration of herbicides: 4000 g / ha-34- This paper scale applies the Chinese National Standard (CNS) A4 specification 210X297mm) (Please read the precautions on the back before filling in this page) Packing. Order 311873 Μ Β7 V. Description of invention (ρ) The ratio of herbicides to protective agents% Phytotoxic without protective agents 65 18: 1 20 24: 1 20 30: 1 15 b) Concentration of herbicide: 300 0 g / ha of herbicide relative to protective agent% Sandalwood toxicity No protective agent 55 18: 1 0 24: 1 1 0 30; 1 0 ^^^ 1 ^ —B—1 nn n · — I— m. ^ M— —ml t ^ i ^ — n ^ — il J (Please read the precautions on the back before filling out this page) Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs System c) Concentration of herbicides: 2 0 0 0 g / ha ratio of herbicides to protective agents% Phytotoxic without protective agents 25 18: 1 0 2 4: 1 0 -35- This paper scale is subject to Chinese national standards ( CNS) A4 specification (210X297mm) 311873 V. Description of invention (w) A7 B7 3 0 The results show that the compound of formula II can significantly reduce the damage caused by the herbicide to the plants planted. 1 Muyi, v't> (Please read the precautions on the back before filling in this page) Printed by the Consumer Cooperative of Central Falcon Bureau of the Ministry of Economic Affairs-36 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm )

Claims (1)

Μ C(0)-CH2C1 CH— CH2〇CH3 1· 一種用於選擇性控制在栽種植物之收成中之雜草之 組成物,其包括,除了無活性之載劑類以及佐劑類以外, 作為活性成分之下列混合物 a) —種除草性有效份量之式I化合物 0), ,其中R〇為甲基或乙基,K及 b)為了拮抗除草劑,一種防衰枯性(a n U d 〇 t a 1 1 y)有效 份量之式I 11化合物作為保護劑(s a f e n e r) m —IB— Dm —^ϋ 1« tl^il ml t B^m fm —flu T· 牙-5 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貞工消費合作社印«. rr° CO-CHCU •CH, (III) 本纸张尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) J θ 3 6 ABCD 々、申請專利範圍 2· —種選擇性控制栽種植物之收成中之雜草以及禾 草之方法,其包括同時或分別地利用如申請利範圍第1項之 有效份量之式I除草劑K及,為了拮抗該除草劑,如申請專 利範圍第1項之防衰祜性有效份量之式I I I化合物對該植物 >種子或其所在地進行處理。 3·根據申請專利範圍第2項之方法,其包括利用0· 0 0 1至1 0公斤/公頃之如申請專利範圍第1項之式I化合物Μ 及0 · 0 0 5至0 · 5公斤/公頃量之如申請專利範圍第1項之式 III化合物處理裁種植物之收成或意欲種植栽種植物之區域 0 4 ·根據申請專利範圍第3項之方法,其選擇性控制玉蜀黍 之收成中之雜草Μ及禾草。 mu mu m nn - - 1^1 I*I _ n^n —^ilf vn —^ϋ Hit ΐ Li (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)Μ C (0) -CH2C1 CH—CH2〇CH3 1. A composition for selective control of weeds in the harvest of planted plants, which includes, in addition to inactive carriers and adjuvants, as The following mixture of active ingredients a)-a herbicidally effective amount of a compound of formula I 0), where R〇 is methyl or ethyl, K and b) in order to antagonize the herbicide, an anti-fade (an U d 〇 ta 1 1 y) effective amount of compound of formula I 11 as a safener m —IB— Dm — ^ ϋ 1 «tl ^ il ml t B ^ m fm —flu T · tooth-5 (please read the back side first (Notes to fill out this page) Printed by the Ministry of Economic Affairs Central Standards Bureau Zhengong Consumer Cooperative «. Rr ° CO-CHCU • CH, (III) This paper scale is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) J θ 3 6 ABCD 々, patent scope 2 ·-a method for selective control of weeds and grasses in the harvest of planted plants, which includes the simultaneous or separate use of the effective portion of formula I as in claim 1 Herbicide K and, in order to antagonize the herbicide, if the patent application scope item 1 The effective amount of hu senility of Formula I I I compounds to the plant > for treatment of seed or the locus thereof. 3. The method according to item 2 of the patent application scope, which includes using 0 · 0 0 1 to 10 kg / ha of the compound M of formula I and 0 · 0 0 5 to 0 · 5 kg as in the patent application item 1 / Hectares such as the compound of formula III in the first paragraph of the scope of patent application to treat the harvest of crop plants or areas intended to be planted with plants 0 4 · According to the method of the third paragraph of the patent application, it selectively controls the harvest of maize Weed M and grass. mu mu m nn--1 ^ 1 I * I _ n ^ n — ^ ilf vn — ^ ϋ Hit ΐ Li (please read the precautions on the back before filling this page) Printed copy of Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs The paper size is in accordance with Chinese National Standard (CNS) A4 (210X297mm)
TW84104819A 1994-06-03 1995-05-16 TW311873B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH175894 1994-06-03

Publications (1)

Publication Number Publication Date
TW311873B true TW311873B (en) 1997-08-01

Family

ID=51566443

Family Applications (1)

Application Number Title Priority Date Filing Date
TW84104819A TW311873B (en) 1994-06-03 1995-05-16

Country Status (1)

Country Link
TW (1) TW311873B (en)

Similar Documents

Publication Publication Date Title
EA000947B1 (en) Synergistic herbicidal compositions of metolachlor
UA55406C2 (en) Herbicidal synergetic composition and a weed control method
JPS63115803A (en) Synergistic composition for selectively removing weeds in rice crop
JP4214052B2 (en) Herbicide containing benzoylpyrazole and safener
JP2011513256A (en) Diflufenican-containing herbicide combinations
JP2011513255A (en) Diflufenican-containing herbicide combinations
EP0595842B1 (en) Herbicidal composition for paddy fields
JP3639316B2 (en) Herbicidal composition for controlling weeds in rice cultivation
TW552112B (en) Herbicidal compositions for paddy fields
JP5467059B2 (en) Diflufenican-containing herbicide combinations
TW311873B (en)
CN109310092A (en) 6- aniline purine derivative is used to improve the purposes of the heat stress tolerance of rice seedlings
CN104904719B (en) A kind of Pesticidal combination and its method for controlling harmful organism
SU612606A3 (en) Composition for regulating growth of plants
JPS6368505A (en) Agricultural, insecticidal and germicidal composition
JPH02264770A (en) Composition for protecting plant from disease
JPH07330506A (en) Selective weed killing composition
JP3869063B2 (en) Agricultural and horticultural sterilization composition
KR100309896B1 (en) Agricultural/horticultural fungicidal composition)
JPH06172102A (en) Selective herbicidal composition
EP0064353A1 (en) Use of 2,4-disubstituted-5-thiazolecarboxylic acids and derivatives for reducing injury to crop plants by acetamide herbicides
JPH041103A (en) Detoxicated herbicidal composition and detoxicating composition
KR100314196B1 (en) Agricultural Horticultural Fungicide Composition
JPH03284601A (en) Bactericidal composition for agriculture and horticulture
JPS62161704A (en) Fungicida composition for agricultural and horticultural purpose

Legal Events

Date Code Title Description
MK4A Expiration of patent term of an invention patent