214564 經濟部中央標準々貝工消5·合作社印製 可花從彩的 之 形：ί 須 變化 色樣 構及散 種彩 ，多象 色 情 ο 必 之愛 兩花 所散種 1 多色之現 各 之 1 , 好色 有彩 體分一 供的彩明勻 將 勻於調 喜彩 含多 散狀出 提或淡鮮均 著 均整色 是多 成 Γ 分徑現 在霜是出不 藉 不調之 或之 形種 與粒顯 的結使現布 偽 色披後 性上 可一 謾適而 目之即頴塗 , 顔偽膜 樣以 即案 媒由， 其狀 ，可或 節 生徑塗 多色 裝提 散是布 ，革且時份 調 産粒持 之二 塗卽 分而塗 物皮而同部 色 不之保 好現 次亦 由，子 成沙 ，，流 顔。了子了 „ 喜表 一， 偽在滾 組來感感垂 之成為粒為小者可 以料 ，存或 料帶糙樣之 中達-其，地費， 種塗 J 式附 塗，粗一化時 物而料，言能消外 一之 料形吹 種膜之彩裝 . 成中顔性而可於以。案膜 塗之由 Ί; 一塗 度多塗 組漆色散般儘因色趣提塗 樣混藉 域閟之適失生 料淸著分一徑導一興已的 花互， /)領有成來無發 1塗·於之之，粒，單感界色 彩以成 (/偽形帶仍會。術閱練用料時之面於深業別 多非構 明 之明所其時不物技有混使塗同料方對也，識 Γ 並所 説 ：±發後為看且成之，钭関高；顔一界，此可 C 一者態 ^ 業本装並觀，組用按顔有提下色另業料因之 J 此兩狀 '-f産 塗 ，處^-料.習 色 為以著 -塗 上料 ，浮 五 卩、 為漾遠 t化塗C 著 ，m{s化的 以塗 成懸 (請先閲功背面之注念事項再塡寫本頁)214564 Central Standard of Ministry of Economic Affairs 々 Beigongxiao 5. Cooperatives print shapes that can be colored: ί must change the color structure and scatter the color, more like pornography ο 愛 之 爱 两 花 所 scattered 1 multi-color appearance 1 of each, the lustrous color body with a color body divided into one color will be uniformly adjusted to the color of the color, including a lot of loose or light and fresh, evenly colored, the color is more than Γ, the diameter is now out of the cream. The combination of shape and grain shows that the false color of the current cloth can be adapted to the post-painting. The color of the false film is based on the immediate medium, and its shape can be coated with a multi-color dressing. Cloth, leather, and time-adjusted grains hold the second part of the paint, but the skin is painted and the same color is not preserved. This time, it is also made of sand, and Yan Yan. It ’s a good thing. I like the table one. It ’s fake in the roller set. It can be made into small particles. It can be stored in the rough sample. Time and material are expected, words can be eliminated, and the shape of the blown film is colored. It can be used in the middle of the face. The film is painted by Ί; the coating of a multi-coating group is as scattered as the color. The mixed samples are mixed with the raw materials of the field, and the flowers are divided into different paths to lead the way, /) There is no hair for the first time. Still will. The face of the technical reading and practice materials is in the deep industry and the non-constructed knowledge. At the time, there is no mixing of materials and skills. The same material is coated, and the Γ is said and said: ± After the hair is seen and completed,钭 关 高; Yan Yijie, which can be a C-state ^ The business is installed and viewed, the group is used according to the appearance of the color and the other industry material is due to J these two forms of '-f production coating, place ^ -material. Xi The color is based on the material-coated with material, floating for five cents, painted for Yangyuan t with C, m {s is made with paint to hang (please read the notes on the back of Gong first and then write this page)
J •-裝· 訂. 木纸張又度適用中SS家彳準（CNS)甲4规格（210 X 297公ίέ ) 81.9.20,000 9 A6 -；---—~______ 五、發明説明（>) 布之花_。 此種「多彩？t樣塗料」，偽一種與習甩單色塗料不同 之富於色彩變化的塗料‘组成锪，由於消費者喜好之變化或 喜好之多樣性的要求/舆此種「多彩花樣塗料」又有所不 同且展現色彩富有變化之塗钭組成拽，也正由業界銳意研 :究之中。 «· ι是以，有閧一種不是由兩色以上之可識別色所形成的 · ”散布花揉”，而是可展現出由兩色以上色粒子微细地分 散成之”降霜”氣氛狀多彩花樣之塗料，已廣受注目至今 0 然而，為了展現出此種降箱氣氛狀之多彩花樣，卽使 使用粒徑在10 wm以下之不同色顔料粒子混合，在視豈 上只能發現表面上並列之顔料小點完全溶合，且沒有花樣 之單色。 具髏言之，就算是使用此種微粒子，企圔例如營造出 由紅與白之混合物所搆成之降霜花樣，在視·覚上只能形成 桃色之塗膜，無法頭現目的之由兩色以上的色粒子微細分 散而成之”降霜氣氛”狀多彩花揉，是為其課題。 是以，登明人等乃就『可將降霜氣氛』之多彩花樣展 現於塗膜中的富於装飾性之塗料組成物進行銳意研究，曾 發現若諝整平均粒徑10〜200wm之著色粒子，將異 色之箸色粒子與水性清漆一起混練而調整成塗料组成物的 話，可使並列於塗膜表面之著色粒子以布質、沙皮革狀之 木纸張尺度適用中因a家標準（CNS)甲4規格（210 X 297公货) 81.9.20.000 •裝_ 訂- 經濟部中夹標準总負工消費合作社印絜 214564 A6 BG_ 五、發明説明（汐） (諳先閲請背面之注*事項再塡寫衣頁) 多彩花k呈現於視凳中。 具證言之，由於無法將著色顔料大粒子狀地均勻地分 散，因此，莛明人等乃製作樹脂粒子在此粒子表面上形成 塗膜，將此著色粒子分散於淸漆中而形成塗料，而獲得上 述現象。 =〔m明之解決課題〕 j 由發明人等所發現之上述塗料组成物，係在視凳上可 呈現沙皮革狀之降霜氣氛狀多彩花樣的癌良技術，但是， 在諝整淡彩色之色諝時，由逄距離位置來看，無法在視覓 上充份感受到多彩花樣狀，是為其課題。 因此，發明人等乃期望能發明一種即使是淡彩色之色 調，在由塗裝後之天花板面或壁面遠離的位置觀看時，也 能在視覺上鮮明地令人威受到淡彩色的降霜氣氛狀多彩花 樣，而且没有生硬威，可表現出斑駁之色調，同時在塗裝 時也s有垂流部份或塗布不均勻現象之塗料組成物。 〔課題之解決手段〕 烴濟部中央標準局δ工消費合作社印^ 本發明係藉著提供一種塗料组成物，其特擻傜在：含 有在合成樹脂粒子表面形成含著色顔料之合成樹脂塗料被 覆膜所成之平均粒徑1〇〜80um的著色高分子粉粒證 ，以及0. 3〜l〇mm長的短鐵維作為必要成分，以此 塗料组成物可完金解除上述課題。 〔發明之構成〕 以下，Η就本發明塗料组成物之構成進行說明。 81.9.20.000 木纸張尺及適用中四a家伐準（CNS)甲4坭格（210 X 297公:Ϊ ) A6 214564 ____^__ 五、發明說明（4) (請先閲ί·!,背面之注-事項再塡其木R ) 根Js本發明，其中配合有作為必要成分之一的著色高 分子粉粒M,其平均粒徑為10〜80um,偽在合成樹 脂粒子表面，形成含著色顔料之合成樹脂塗料披覆膜而成 〇 此一箸色高分子粉粒S，偽依據 :(L)在分散安定化之著色顔料及乳膠樹脂之混合物，與 含ΐ塑劑之合成樹脂粒子混合所得之混合条中，添加金屬 ·». » 塩； 或是， (b)在具有分散安定化之箸色顔料，且配合有經鹼性中 和之多價羧酸樹脂，同時固形分中之酸價在5以上的塗料 中，混合合成樹脂粒子所得之混合条中，添加金屬塩而可 獲得。 上述著色顔料，俱可適當地使罔習知物，例如可使用 諸如二氧化鈦、琥珀色料、碕酸亞鐵糸紅色顔料、碩黑、 群青、錳紫等之無機条顔料；諸如漢撒黃、聯苯胺黃、甲 苯胺紅、钛花青藍、鈦花青綠、二氧雜吡啶紫等之有機条 顔料。 經濟部中央標準岛员工消"合作社印焚 此外，也可與上逑著色顔料合併使用氧化鋇、碩薛鈣 、粘土、滑石等之體質顔料。 有関此種顔料之添加量，相對乳膠樹脂之固形分或多 價羧酸樹脂之固形分100重量份，最好使甩2〜300 重量份，但並無持殊限定。 木纸張尺度適用中因S家桴準（CNS>甲4峴恪（210 X 297公货〉 81.9.20.000 經濟部中央標準尤員工消*Γ*合作社印¾ A6J • -installation and ordering. Wood paper is again suitable for the SS Family Standard (CNS) A 4 specifications (210 X 297 public) 81.9.20,000 9 A6-; ----- ~ ______ V. Description of invention (>) Cloth flower _. This kind of "colorful? T-like paint" is a kind of paint that is rich in color change unlike Xi monochromatic paint, due to the change of consumers' preferences or the diversity of preferences. "Paint" is different and shows the change of color. It is also being studied by the industry. «· Ι is that there is a kind of" Frosting "which is not formed by two or more recognizable colors" "Spreading flower kneading", but can show a "frost" atmosphere that is finely dispersed by particles of two or more colors Pattern paints have been widely attracted to this day. However, in order to show the colorful pattern of such a drop-off atmosphere, the use of different color pigment particles with a particle size of less than 10 wm is mixed, and it can only be found on the surface. The dots of juxtaposed pigments are completely fused and there is no monochromatic pattern. In a word, even if such particles are used, for example, if a frost pattern composed of a mixture of red and white is created, only a peach-colored coating film can be formed on the eyes and the blush. It is a subject of colorful flowers kneaded in the form of "frosting atmosphere" made up of finely dispersed color particles. Therefore, Tominaki et al. Carried out a keen study on the decorative paint composition which can display the colorful patterns of "frosting atmosphere" in the coating film, and found that if the colored particles with an average particle size of 10 ~ 200wm were formed ， When the colored particles of different colors are mixed with water-based varnish and adjusted into a coating composition, the colored particles arranged on the surface of the coating film can be applied to the cloth and sand leather-like wooden paper scale. ) A4 specifications (210 X 297 public goods) 81.9.20.000 • Packing _ order-Ministry of Economic Affairs Zhongji Standard General Negative Work Consumer Cooperative Imprint 214564 A6 BG_ V. Description of invention (XI) (Please read the note on the back * Matters are written on the clothing page again) The colorful flower k is presented in the visual stool. It is testified that because the color pigments cannot be uniformly dispersed in large particles, Zhu Mingren and others made resin particles to form a coating film on the surface of the particles, and dispersed the color particles in the paint to form a coating, and Obtain the above phenomenon. = [Mming's solution] j The above-mentioned paint composition discovered by the inventors is a cancer-bearing technology that can display a sand leather-like frost-like atmosphere and colorful patterns on the visual bench. At the time of deceased, from the perspective of the distance, it is a problem that he cannot fully feel the colorful patterns on the foraging. Therefore, the inventors hope to invent even a light-colored hue, which can be visually and vividly devitrified when viewed from a position away from the ceiling or wall surface after painting. Colorful pattern, and there is no blunt power, can show mottled color, at the same time, there is also a paint composition that has a dripping part or uneven coating during painting. [Solution to the problem] Printed by the Delta Industry Consumer Cooperative of the Central Standards Bureau of the Ministry of Hydrocarbon Economy ^ The present invention is to provide a paint composition whose special features are: a synthetic resin coating containing colored pigments formed on the surface of synthetic resin particles The coloring polymer powder certificate with an average particle size of 10 ~ 80um formed by coating, and a short iron dimension of 0.3 ~ 10mm long as necessary components, so that the coating composition can completely solve the above problems. [Structure of the Invention] Hereinafter, the structure of the paint composition of the present invention will be described. 81.9.20.000 wooden paper ruler and applicable S4 a house cutting standard (CNS) Jia 4 ni (210 X 297 g: Ϊ) A6 214564 ____ ^ __ V. Description of invention (4) (please read ί! ,, Remarks on the back-Matters and issues R) root Js of the present invention, which contains coloring polymer powder M as one of the essential components, the average particle size is 10 ~ 80um, pseudo on the surface of synthetic resin particles, forming It is formed by coating synthetic resin paint of coloring pigment. This color polymer powder S is pseudo-based: (L) a mixture of dispersed and stabilized coloring pigment and latex resin, and synthetic resin particles containing plasticizer In the mixing bar obtained by mixing, metal is added. ».» 塩; Or, (b) In the pigment pigment with dispersion and stability, and mixed with alkali-neutralized polyvalent carboxylic acid resin, while solid content In a paint having an acid value of 5 or more, a metal strip is added to a mixing bar obtained by mixing synthetic resin particles, and a metal salt is obtained. The above-mentioned coloring pigments can be suitably used as conventional materials. For example, inorganic stripe pigments such as titanium dioxide, amber, ferrous aristolate red pigments, solitary black, ultramarine blue, manganese violet, etc .; such as Hansa yellow, Organic strip pigments of benzidine yellow, toluidine red, titanium cyanine blue, titanium cyanine green, and dioxopyridine violet. The Ministry of Economic Affairs, Central Standard Island Employee Consumers' Cooperative Co., Ltd. Printing and Burning In addition, it is also possible to use barium oxide, strontium calcium, clay, talc, and other physical pigments in combination with the Shangqi coloring pigments. The amount of such pigment added is preferably 2 to 300 parts by weight relative to 100 parts by weight of the solid content of the latex resin or the polyvalent carboxylic acid resin, but it is not particularly limited. The standard of wood paper is applicable to Zhongyin S Jiazheng (CNS> A4 Xianke (210 X 297 public goods)> 81.9.20.000 Central Standard of the Ministry of Economic Affairs, Employee Consumers * Γ * Cooperative Society ¾ A6
BG 五、發明説明（(） 又，添加於上述混合条中之金屬塩也無特殊限定，例 如可適當地庋甩氛化鈣、氨化錯、硫發鋁、硫酸亞銅、氛 化鐵、硝駿銀、諸酸鉛等等。 使用金屬S的理由是，可以金屬塩阻礙含箸色顔料之 乳膠樹脂或多價羧憩樹脂之安定注，而在合成樹脂之粒子 :表面.可使含有顔料之乳樹脂或多價羧駿樹脂凝析所致。 h此一金屬塩之添加量，在求得乳膠樹脂或多價羧薛樹 脂與金屬塩混合後凝膠化時之金屬塩量後，只要依此一量 掌握適量即可。 又，也可將水添加於金屬塩中後，以金屬塩水溶疲之 形態混入，此時，含著色顔料之乳膠樹脂溶肢或多價羧酸 樹脂溶液與金屬垣水溶液之重量比，在考慮粒子之安定性 之下，宜為7 : 3〜3 : 7,最好為6 :4〜5 : 5,並 無特殊限制。 以下傜就金屬塩所進行之詳細說明，代替此一金屬塩 ,也可使甩氫氧化鈣。 在使用乳膠樹脂時，可方便地使用可藉著金屬離子之 存在，使乳化安定性受到阻礙，而在含後述可塑劑之合成 樹脂粒子的表面附著成凝集或凝膠戕之乳膠樹脂。例如可 使甩之適當性樹脂的實施洌包括：諸如丙烯酸樹脂、苯乙 烯丙烯酸樹脂、聚酯樹脂、聚胺基甲酸酯樹脂、氯乙烯舘 酸乙烯酯共聚物等之合成樹脂，以及諸如乳香脂、禾木顚 、安息香脂、龍血樹脂、攬香脂、山達脂等之天然樹脂。 (諳先閲访背面之注念事項再項筠本頁) 装· 訂. 木纸張又皮適用中囚囷家i?準（CNS)甲4規格（210 X 297公兌） 81.9.20,000 經濟部中央標準工消费合作社印κ 214564 五、發明説明（ip ) 有雇使用之界面活性劑並無持別限定，可適當地使甩 陽離子、陰離子、非離子、兩性等之界面活柱劑，由於柑 對金屬離子乳膠會不安定化，相對上述乳膠樹脂之添加量 ，其添加量宜在1重量％，而且上逑乳鏐樹脂之粒徑宜在 0 . 1 u m以下，但並無持殊限定。 :、.又.因應必要，也可在乳驩樹脂中添加消泡劑、成膜 助育ίΐ等等。 麵··. 有關合成樹脂係可適當地使用氛乙烯条合成樹脂或其 他之合成樹脂，但並無待殊限定。 有閱氛乙烯条合成樹脂，並無持殊限定，例如可使用 由懸浮聚合法或乳化聚合法等形成之例如氛乙烯均聚物、 氯乙烯、醋酸乙烯酯共聚物、乙烯一氛乙烯共聚物、乙烯 一醋酸乙烯醴一氛乙烯共聚物、胺基甲酸酯一氛乙烯共聚 物、氨化氛乙烯一氛乙烯共聚物等等。 有飼氛乙烯糸以外之其丨也合成樹脂，可適當地使用聚 乙烯、聚丙烯腈、聚甲基丙烯酸甲酯等等。 又，這些合成樹脂，最好能莛擇可使最终所獲得之著 色高分子粉©證的平均粒徑成為1 〇〜8 0 wm者，合成 樹脂之尺寸雖會受可塑劑之添加率等而多少受到左右，但 是可適當地使用平均粒徑為2 0〜5 0 urn之合成樹脂。 有闊混於上述合成樹脂内之可塑劑，並無待殊限制， 可適當地使用苯二酸二一 2 —乙基己酯、苯二酸二庚酯、 苯二酸二正辛酯、苯二酸二壬酯、苯二酸二丁酯、苯二酸 木#氏张又及迫用中园园家標準（CNS) Τ 4規格（210 X 297公ίί ) 81.9.20*000 (請先閲汸背面之注+?事^再項窝夂頁) •裝· 訂. A6 經濟部中央標芈局员工消货合作社印踅 214564_五、發明説明（7 ) 一丁醋.一苄酯、苯二_二異癸酲、四氫苯二酸二一2 -乙 基己酯、己二酸二一 2 —乙基己篚、己二酸二異癸酯、癸 二酸二一 2 —乙基己醋、磷酸三甲苯酯、磷酸三辛醋、乙 頭檸樣駿三丁酯、苯偏三酸三辛篚、苯偏三薛三癸酯、甘 諄丁基钛基丁基酯、環氣化大豆治、苯二駿二烯丙篚、聚 =乙；.諄二甲基丙烯薛酯等等。 ^此一可塑劑之添加率，相對可塑劑添加後之合成樹脂 I» 的重量，宜為47〜5 0重量％,最好為23〜44重量 %，待別是使用以上述愍浮聚合法所獲得之合成樹脂時， 該可塑劑之添加宰宜為3 3〜4 4重量％ ,使闬以上述乳 化聚合法所獲得之合成樹脂時，該可塑_之添加率宜為23〜3 8重量％。 所以如此的理由是，當可塑劑之添加率不諶4. 7重 量％時，含有箸色顔料之乳樹脂無法有效地被覆於合成 樹脂的粒子表面，當該添加率超過5 0重量％時，合成樹 脂的粒子將會變軟，而無法獲得充份之塗膜強度，同時， 粒子間也會産生粘著力，而使得最後難以將其以粒子狀呈 現出所致。 又，有關混合上述合成樹脂及可塑劑之方法，可採吊 利用韓氏混合器等的方法，此時，因應必要，還可混合合 成樹脂之安定劑.、改質劑等等。 有閟乳膠樹脂之.使用量（固形分），當包含可塑劑之 合成樹脂的使用量為1重量份時，其為◦. 05〜2. 0 (請先閲功背面之注念事項再項其本頁) -裝. 訂. 本纸伍尺Λ適用中SS家桴準（CNS)甲4晛格（210 X 297公；Ϊ ) 81.9.20,000 垤濟部中央標準局|®工消！ίΗ合作社印¾ 214¾^4_B6__ 五、發明説明（咨） 重量份丨最好為0 . 1〜1重量份。 .所以如此的理由是，當該使甩量不諶0. 05時，無 法充份地被覆含有可塑劑之合成樹脂粒子，以致成為箸色 性不良的樹脂；當該使用量超過2 . 0時，將會獲得只有 乳朦樹脂之粒子凝集的凝謬化锪，而使粒子強度葱弱所致 ；5 ^又，當合成樹脂之量較多時，由於流動性將會降低， 因此，可因應必要添加水以確保流動性。 將以上之含有箸色顔料之乳P樹脂與含有可塑劑之合 成樹脂粒子混合攪拌，將此混合锪與金屬塩混合，而可獲 得合成樹脂粒子表面形成有f成樹脂乳膠塗料之被覆膜的 著色高分子粉粒體分散液。 由上述分散液，將箸色高分子粉粒體與分散媒證分離 ,可獲得著色高分子粉粒證。 另一方面，使用多價羧酸樹脂時，可適當地使用丙烯 酸樹脂、苯乙烯丁二烯樹脂、苯乙烯馬來酸樹脂、醇酸樹 脂、藻朊酸等之多價羧酸樹脂3 有關用以將此等多價羧酸樹脂可溶化之中和割，偽可 適當地使用氨水、三乙胺、二甲乙諄胺、氫氧化鉀、氫氧 化鈉等等。 又，因腠必要，還可添加消泡劑、成膜助劑等。 又，有鬨混合於配合有上逑多價羧酸樹脂而且固形分 中之酸價在5以上的塗料中之合成樹脂粒子，除了上述氨 -1 0- 本纸張尺及適用中SS家桴準（CNS〉甲4規格（210 X 297公犮） 81.9.20,000 (請先閲诗背面之注念事項再塡駕本頁) 装· 訂. A6 ¢14¾¾4 五、發明説明（θ) (請先閲-背面之：;i&事項再填寫本頁) 乙烯条合成樹脂以外，還可適當地便兩以乳化聚合、懸浮 聚合及機域粉碎等方法所形成之丙烯馥樹脂、聚酯樹脂或 其他之樹脂。 再者，有鬨此種合成樹脂粒子，宜莛擇在最後能使著 色高分子粉粒體之平均粒徑成為1 0〜8 Ο μ m者，最好 :能蓮.擇成為2 0〜5 0 wm者。 f . 著色塗料（換算成固形分）之使用量，當以合成樹脂 ¥ 粒子之使用量為1重量份時，其宜為0. 05〜2. 0重 量份，最好為0 . 1〜1重量份。 所以如此的理由是，當該使用量不諶0. 05重量份 時，無法充份地披覆合成樹脂粒子，以致成為著色性不佳 的粒子；當該使闬量超過2 . 0時，將會獲得只有過剩部 份之多價羧謖樹脂粒子凝集之凝膠化锪，這些凝膠化物之 粒徑小，在塗料化時，難以形成沙皮革狀花樣，不管任何 場合均不受喜愛所致。 經濟部中央標準局員工消費合作社印^ 於本發明中，有関着色高分子粉粒體，俱可適當地使 用由上述方法所獲得之箸色高分子粉粒體，除上逑方法以 外，有閟著色顔料，還可使用以含有載體樹脂之塗料形成 塗膜，將該塗膜予以粉碎所獲得之著色高分子粉粒證。 此時所使用之載a樹脂，偽採甬玻璃轉移溫度τ g在 2 〇 °c以上之樹脂，洌如可適當地採芾丙烯酸、苯乙烯丙 烯酸、聚酯、氛乙烯.、丙烯酸共聚物等之合成樹脂。 此等塗料傜塗布在剝離性材料之表面，形成在2 0 0 -1 1- 81.9.20,000 木纸張尺沒远用中囚园家桴準（CNS)甲規格（210 X 297 乂兌）BG 5. Description of the invention (() In addition, the metal salt added to the above mixing bar is also not particularly limited, for example, it can be appropriately shaken calcium oxychloride, ammonium trichloride, aluminum sulfite, cuprous sulfate, iron oxychloride, Nitrogen silver, lead acids, etc. The reason for using metal S is that it can hinder the stability of latex resins or multivalent carboxyl resins containing pigments, and the particles on synthetic resins: surface. It is caused by the condensation of the pigment's emulsion resin or polyvalent carboxyl resin. H The amount of this metal salt is obtained after the amount of metal gel when the latex resin or polyvalent carboxyl resin is mixed with the metal salt and gelled. As long as the appropriate amount is controlled according to this amount, it is also possible to add water to the metal salt and mix it in the form of water-soluble metal salt. In this case, the latex resin containing colored pigments or polyvalent carboxylic acid resin solution The weight ratio of the metal to the aqueous solution of the metal, considering the stability of the particles, is preferably 7: 3 ~ 3: 7, preferably 6: 4 ~ 5: 5, and there is no special restriction. Detailed description, instead of this metal salt, can also throw calcium hydroxide. When using latex resins, it is convenient to use latex resins that can impede the stability of emulsification by the presence of metal ions, and the surface of synthetic resin particles containing plasticizers to be described later is aggregated or gelled. For example, Examples of suitable resins include synthetic resins such as acrylic resins, styrene acrylic resins, polyester resins, polyurethane resins, vinyl chloride and vinyl ester copolymers, and synthetic resins such as frankincense resins and wo Natural resins such as Muko, benzoin, dragon blood resin, balsam, and sandalwood. (Please read the notes on the back first and then go to this page) Binding and ordering. Wooden paper and leather are suitable for prisoners Home i? Quasi (CNS) A 4 specifications (210 X 297 public conversion) 81.9.20,000 Printed by the Ministry of Economic Affairs Central Standards Industry and Consumer Cooperatives κ 214564 5. Description of invention (ip) There are no restrictions on the use of surfactants for employment, The interface active column agent of cationic, anionic, non-ionic, amphoteric, etc. can be properly made. Since citrus will make the metal ion latex unstable, it should be 1% relative to the amount of the above latex resin. %, And the particle size of the upper lactotrope resin should be below 0.1 um, but there is no special limit.:, And. If necessary, you can also add defoamer and film-forming aid to the milk resin Education, etc. Noodles .. For synthetic resins, vinyl-strip synthetic resins or other synthetic resins can be used as appropriate, but there are no special restrictions. There are no special restrictions for vinyl-strip synthetic resins, such as For example, a vinyl chloride homopolymer, vinyl chloride, vinyl acetate copolymer, ethylene-vinyl acetate copolymer, ethylene-vinyl acetate-vinyl acetate copolymer, aminomethacrylate formed by suspension polymerization or emulsion polymerization can be used Ester-vinyl ethylene copolymer, ammonium-vinyl ethylene-vinyl ethylene copolymer, etc. There are synthetic resins other than ethylene vinyl, and polyethylene, polyacrylonitrile, polymethyl methacrylate can be used as appropriate and many more. In addition, these synthetic resins are preferably selected so that the average particle diameter of the color polymer powder obtained in the end will be 10 to 80 wm. Although the size of the synthetic resin will be affected by the addition rate of the plasticizer, etc. It is somewhat affected, but synthetic resins with an average particle size of 20 to 50 urn can be used appropriately. There are plasticizers widely mixed in the above-mentioned synthetic resins, without any special restrictions, and 2-ethylhexyl phthalate, diheptyl phthalate, di-n-octyl phthalate, benzene can be used appropriately Dinonyl diacid, dibutyl phthalate, phthalic acid wood # 's Zhang You and forced Zhongyuanyuanjia Standard (CNS) Τ 4 specifications (210 X 297 public) 81.9.20 * 000 (please first Read the note on the back of the board +? ^ ^ Another item on the page) • Packing and ordering. A6 Printed by the Employee Consumer Goods Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs 214564_ V. Description of invention (7) One butyl vinegar. One benzyl ester, Phthalodiisodecane, tetrahydrophthalic acid di-2-ethylhexyl ester, adipic acid di-2-ethylhexanoate, adipic acid diisodecyl ester, sebacic acid di-2-ethyl Ghexyl vinegar, tricresyl phosphate, trioctyl phosphate, tributyl ethoxylate, trioctyl trimellitate, tridecyl trimellitate, butyl titanyl butyl ester, ring gasification Glycine soy, phthalene diene propylene oxide, poly = B; dimethypropylene, etc. ^ The addition rate of this plasticizer is preferably 47 ~ 50% by weight, preferably 23 ~ 44% by weight, relative to the weight of the synthetic resin I »after the addition of the plasticizer. In the case of the obtained synthetic resin, the addition of the plasticizer should be 3 3 to 4 4% by weight. When the synthetic resin obtained by the above-mentioned emulsion polymerization method is used, the addition rate of the plasticizer should be 23 to 38% by weight. %. So the reason is that when the addition rate of the plasticizer is not 4.7% by weight, the emulsion resin containing the pigment can not effectively coat the surface of the particles of the synthetic resin. When the addition rate exceeds 50% by weight, The particles of the synthetic resin will become soft, and the strength of the coating film will not be obtained. At the same time, the adhesion between the particles will be generated, making it difficult to present them in the form of particles. In addition, as for the method of mixing the above-mentioned synthetic resin and plasticizer, a method of using a Han mixer or the like may be used. In this case, if necessary, a stabilizer for synthetic resin, a modifier, etc. may also be mixed. The usage amount of solid latex resin (solid content), when the amount of synthetic resin containing plasticizer is 1 part by weight, it is ◦. 05 ~ 2. 0 (please read the notes on the back of the merits first This page)-Installed. Ordered. This paper size Λ is suitable for the 4th grid (210 X 297 g) in the SS home frame (CNS) (210 X 297; Ϊ) 81.9.20,000 Central Standards Bureau of the Ministry of Economic Affairs | ®Worker! ίΗCooperative seal ¾ 214¾ ^ 4_B6__ V. Description of the invention (consultation) The weight part 丨 is preferably 0.1 ~ 1 weight part. Therefore, the reason is that when the amount of flicking is not less than 0.05, the synthetic resin particles containing plasticizer cannot be adequately covered, so that it becomes a resin with poor color properties; when the amount of use exceeds 2.0 , It will be obtained by coagulation of only particles of milky haze resin, resulting in weak particle strength; 5 ^ In addition, when the amount of synthetic resin is large, the fluidity will be reduced, so it can be dealt with It is necessary to add water to ensure fluidity. Mixing and mixing the above-mentioned emulsion P resin containing crimson pigments and synthetic resin particles containing plasticizers, and mixing this mixed sulfonium with metal salt to obtain a coating film formed with resin emulsion paint on the surface of the synthetic resin particles Coloring polymer powder granular dispersion. From the above dispersion liquid, the color polymer powder particles are separated from the dispersion medium to obtain a color polymer powder certificate. On the other hand, when using a polyvalent carboxylic acid resin, a polyvalent carboxylic acid resin such as acrylic resin, styrene butadiene resin, styrene maleic acid resin, alkyd resin, alginic acid, etc. can be suitably used. In order to dissolve and neutralize these polyvalent carboxylic acid resins, ammonia water, triethylamine, dimethylacetamide, potassium hydroxide, sodium hydroxide, etc. can be suitably used. In addition, defoamers, film-forming aids, etc. can be added as necessary. In addition, there are synthetic resin particles mixed in the paint containing the polyvalent carboxylic acid resin and the acid value in the solid content of 5 or more, except for the above-mentioned ammonia -10. Standard (CNS> A 4 specifications (210 X 297 Gonglu)) 81.9.20,000 (please read the notes on the back of the poem before driving this page) Binding and ordering. A6 ¢ 14¾¾4 V. Invention description (θ) (please first Read-back: "i & matters, then fill out this page) In addition to vinyl strip synthetic resins, propylene resins, polyester resins or other resins formed by emulsification polymerization, suspension polymerization and machine-domain pulverization can also be used as appropriate. In addition, there are some synthetic resin particles that should be selected in the end so that the average particle size of the colored polymer powder particles can be 10 ~ 8 Ο μ m, preferably: Nenglian. Select become 2 0〜5 0 wm。 f. The amount of coloring paint (converted into solid content), when the amount of synthetic resin ¥ particles is 1 part by weight, it is preferably 0. 05 ~ 2. 0 parts by weight, most It is preferably 0.1 to 1 part by weight. So the reason for this is that when the amount used is not 0. 05 parts by weight, it is not sufficient Coated with synthetic resin particles, so as to become poorly colored particles; when the amount of hazel should exceed 2.0, you will get only a surplus part of the polyvalent carboxyl radon resin particles agglomerated sulfide, these gel The particle size of the chemical compound is small, and it is difficult to form a sand leather-like pattern during coating, and it is not loved in any occasion. It is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ In the present invention, the coloring polymer powder In addition to the above method, the color polymer powders and granules obtained by the above method can be suitably used. In addition to the above method, there are color pigments, and a coating film containing a carrier resin can also be used to form a coating film. The color polymer powder certificate obtained by crushing. The resin loaded with a at this time, the resin with pseudo glass-fiber transition temperature τ g above 20 ° C, such as acrylic acid, styrene acrylic acid, etc. Synthetic resins such as polyester, vinyl chloride, acrylic copolymer, etc. These coatings are applied on the surface of the peelable material and are formed on 2 0 0 -1 1- 81.9.20,000 wooden paper rulers. Huanzhun (CNS) Specifications (210 X 297 qe against)
A6 BG 經濟部中央標準^β工消費合作社印52 五、發明説明（/C) o w〜b ο ο o u間之均勻厚度，以之而形成塗膜。 在此塗膜乾燥後，將塗膜由作為基材之剝離性材料剝 離，並以微球磨機等之微粉碎機將其粉碎所獲得的平均粒 徑為1 0〜80 um之著色高分子粉粒體，也可適當地使 兩。 :、.以上述方法所獾得之著色高分子粉粒S的平均粒徑為 t . 10〜8〇um,最好為20〜50wmD 所以如此的理由是，在混缲異色之著色高分子粉粒韹 時，若粒徑不湛1 0 u m的話，無法傾別以肉眼識別，而 無法使多數色之粒子以完全溶合之多彩花樣狀在視覚上被 補捉所致；另一方面，當上述粒徑超過8〇Wm時，多彩 花樣之色分布將會粗槌化，而無法顯現出裝飾性佳之布質 、沙皮革狀多彩花樣，此外，其馘感也呈粗撻，無法獲得 柔軟之觸或，因此，上述低於10wm及高於80um之 粒徑均不受歡迎。 粒徑20〜50um時，諉感最佳，而且布質、沙皮 革狀之質感最為顯著。 其次，Η就本發明塗料組成物之另一必要成分的0 . 3〜1 Ο μ m長之短鐵雒，進行說明。 有關此等短纖雒之材質，其適當之實施例包括嫖縈.、 酎隆、雒尼11、賽璐玢等，並無持殊限制。 此等短纖維宜以長0. 3〜10mm,更宜以0. 5 . mm程度之長度，以0. 05〜4. 0重量份之量，配合 -1 2- 木纸浓又ylii用中aa家1?準（CNS)甲·！现格（210 X 297公盆） 81.9.20,000 (諳先閲-背面之注念事項再塡寫太頁)A6 BG Central Standard of the Ministry of Economic Affairs ^ βIndustry and Consumer Cooperatives Co., Ltd. Printed 52. V. Description of the Invention (/ C) o w ~ b ο ο o u The uniform thickness between the two, to form a coating film. After the coating film is dried, the coating film is peeled off from the peelable material as the base material, and the colored polymer powder particles with an average particle size of 10 to 80 um are obtained by crushing it with a micro-pulverizer such as a micro-ball mill. The body can also make two appropriately. :. The average particle size of the colored polymer powder S obtained by the above method is t. 10 ~ 8um, preferably 20 ~ 50wmD, so the reason is that the colored polymer powder mixed with different colors In the case of granules, if the particle size is less than 1 0 um, it cannot be distinguished by the naked eye, and the particles of most colors cannot be captured by the visual fusion in the form of a colorful pattern of complete fusion; on the other hand, when When the above-mentioned particle size exceeds 8〇Wm, the color distribution of the colorful pattern will be roughened, and the cloth texture and sand leather-like colorful pattern with good decoration will not be shown. In addition, the sense of bun will also be rough, and the soft pattern will not be obtained Touching, therefore, the above-mentioned particle sizes below 10wm and above 80um are not welcome. When the particle size is 20 ~ 50um, the texture is the best, and the texture of cloth and sand leather is the most significant. Next, Η will describe another short component of 0.3 to 1 Ο μ m of a short iron lobe, another essential component of the coating composition of the present invention. Regarding the materials of these short-staple fibers, suitable examples include 嫖 萦., Suolong, Luo Ni 11, Celluloid, etc., without special restrictions. These short fibers should preferably have a length of 0.3 to 10 mm, and more preferably a length of 0.5 to 0.5 mm, with an amount of 0.05 to 4.0 parts by weight, with -1 2- wood paper thick and ylii used aa home 1? quasi (CNS) A! Cash (210 X 297 public pots) 81.9.20,000 (know first-read the notes on the back and then write a page)
U 丨裝· 訂. 經濟部中央標準局員工消ί合作社印ίϊ 五、發明説明（/y ) 於塗料组成锪1 0 0重量份之中。 所以如此的理由是，當短議雒之長度不滿0 . 3 m m 時，鍩雒之坊斷将會變得困難，又，當短鐵維之配合量不 諶0. 0 5重量份時，將無法表現作為本發明目的之塗装 後的塗膜上”降H ”狀多彩花樣以及適度的多彩玆；另一 '·方面.，當該長度超過10 mm時，塗装後之塗膜上將不會 顯現出沙皮革烕。又，當上述配合量超過4. 0重量份時 ，塗料之流動性將會喪失，以致塗装困難，不令人喜愛。 又，藉彗配合0. 6重量份之長度為0. 5mm程度 的短纖維，不僅可顯現出降霜狀之多彩花樣，同時，即使 是淡彩色，也能顯現出令人匿目之花樣，而且，還能有效 地為塗膜賦與肌菡或，幾乎可完全防止塗裝時之垂流現象 或塗布不均勻現象。 可將以上所述之短纖維，直接混合於箸色高分子粉粒 證之分散液中，或是將著色高分子粉粒體由分散肢取出， 將其與短纖維一起混練於水性清漆中，並在必要時將消泡 劑或增钻劑等添加於其中，也可依此獲得塗料組成挠。 或是，也可在將塗料譌整後，再將短讖維配合之，但 並持別受此限劁。 有關水性清漆，並無待殊限制，可使用乳膠樹脂或水 溶性樹脂，例如可適當地使罔丙烯玆条、醋酸条或其他条 之樹脂。 又，藉著將上述水性清漆或著色高分子粉粒體之硬度 -13- 本纸尺及適用中aa家標準（CNS)甲«_烙（210 X 297公S ) 81.9.20,000 (請先閲筇背面之注念事項再塡驾各頁) -裝. 訂. A6 五、發明説明（/>) 或柔軟.&愛化，也可獲得具有各種辑威之被覆膜。 又，藉著將多種頚之異色箸色高分子粉粒證適當地組 合，並將其與短纖維一起混辣於水性清漆中，也可獲得可 形成多彩花樣之塗料。 〔實施例〕 :、.以下，Η以若干實施例，將本發明塗料组成物之效果 I . 進一步明確化D (實施例1 ) 於此實施例中，偽使用不揮發成分47%之苯乙烯丙 烯酸乳膠（商品名稱Acronal YJ 12 1 0D,三菱油化巴地歇 公司裂）8 0重置份作為乳饜合成樹脂，使用二氧化鈦4 0重量份與其混合。 其次，在作為氮乙烯条合成樹脂之平均粒徑為4 0 w m的氛乙烯聚合物（商品名Zeun 103 ZXA 日本賽王公司 製）中，混入作為可塑劑之苯二駿二正辛酯，使其含量為 29重量％，將其諝裂150重量份。 <諳先閲^背面之注念事頊再項其4頁> .装. 訂. 經濟部中央標準局5工消贲合作社印5< 氣靥著 饅份高 之金之 粒量色 劑為m粉重箸 塑作 W 子4.色 可合 3 分 .黑 有混4 高 4 的 含 ，為 色合出 與後徑 著混取 脂加粒 色替製 樹添均 白代調 瞟量平 之黑式 乳適得 出磺方 之水獲 取以之 料將 , 。所料同 顔在份液液顔相 色 ，量散散將述 著合重分分了上 有混 1 的之除與 含脂 .if得與依 將樹 1 粒獲 ，均 ，成鈣粉所份他 後合化子由量其 而条氛分將重 ， 烯之高 9 外 乙塩色 9 之 81.9.20.000 木纸張又度通用中HS家標準（CNS)甲4现格（210 X 297公兌） A6 B6 ¢14^64- 五、發明説明（/>) 分子粉έ證1重量份分別混合後，再將不揮發成分5 5 % 之水性清漆5 0重量份及蹂縈短鐵維（平均長0 . 5 m m )Ο . 6重量份與其混综，獲得多彩之塗料組成物。 (實施例2 ) 於本實旋钶中，多價羧玆合或樹脂，偽採m由不揮發 :成分5 0%的Micasol RX291 (日本Carbide工業股份有限 鳥« 公g製，商品名）丙烯酸苯乙烯樹脂（酸價20) 2.2. ·> '6重量份及Nicaso丨 RX669 (商品名）（酸 價0 ,不揮發成份5 0 % )丙烯酸苯乙烯樹脂5 2 . 6重 量份所组成之合成樹脂7 5 . 2重量份，相對此一合成樹 脂，混合以二氧化鈦4 0重量伤作為著色顔料。 其次，諝製150重量份之平均粒徑為40UID的氮 乙烯聚合物（商品名費王ΙΟ3 ZXA,日本賽王公司製） ，作為合成樹脂粉粒疆。 而後，將由含有著色顔料之上逑多價羧酸樹脂（酸價 6 )所構成之乳膠樹脂舆合成樹脂粉粒疆混合，在適量地 添加水後，混合1 : 1 ,重量份之氯化鈣作為金屬塩，獲得 平均粒徑為42 xxm之著色高分子粉粒饅的分散液。 將由所獲得之分散掖所取出之白色著色高分子粉粒體 9 9重量份，舆除了將顔料以碩黑代替混合4 . 4重量份 之外，其他均胶與上述相同之方式調製取出的黑色著色高 分小粉粒謾1重量份分別混合後，再將不揮發成分5 5 % 之水性清漆5 0重量份及耐隆短鐵維（平均長10mm) -15- 本纸张尺Λ適用中囚西家桴準（CNS)甲说恪（210 X 297公犮〉 ------------------ί-----裝------ΤΓ------^ (請先聞-背面之注-事項再塡窵本頁) 經濟部中央標準^δ工消費合作社印- 81.9.20,000 經濟部中央標準局8工消費合作社印製 扒辦4 五、發明説明（/γ) 0 . 量份與其混練，獲得淡彩色之塗料組成物。 (實施例3 ) 於此實施例中，箸色顔料俱使用二氣化鈦，載體樹脂 係使用除去成膜助劑之由丙烯酸樹脂所構成的塗料（旭塗 料股份有限公司製；潘西塔待1ί 100半光澤性白（除去 成R助劑），在剝離性材料之表面，塗設4000«m之 塗膜2 0 m 2。 乾燥後，將塗膜剝離，並以球磨機將其粉碎，獾得平 均粒徑為80wm之著色高分子粉粒醱。 取所獲得之白色著色高分子粉粒腰99重置份，與除 了將顔料以硪黑代替混合4.4重貴份之外，其他均依與 上述相同之方式諝裂取出的黑色著色高分粉粒體1重量份 分別混合後，再將不揮發成份55%之水性淸漆50重置 份及維尼降短鐵維（平均長1. 0mm) 4. 0重置份與 其混練，獲得淡彩色之塗料组成物。 (實施例4 ) 於此實施例中，像使用平均粒徑40wm,不揮發成 份60%之『卡内博約德索爾 P43J (商品名），作 為乳睡合成樹脂，将此乳繆合成樹脂80重置份與二氣化 鈦40重量份混合，調製成著色塗料。 其次，作為合成樹脂，調製由聚乙烯樹脂所構成之平 均粒徑20 ttm的塑踴粉碎物1 5 0重貴份。 而後，在上述著色塗料中，混合入由合成樹脂所構成 -16- A6 B6 (請先閲讀背面之注意事項再填寫本頁) -裝_ 訂- -線· 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公釐） 82.6. 40,000 A6 B6 經濟部中央標準局8工消費合作社印製 五、發明説明（G) 之塑膠#碎物，將水及作為凝集劑之氣化》添加於其中· 獲得在合成樹脂塑膠之表面，形成有著色塗料被覆膜之平 均粒徑2 5 wm的著色高分子粉粒體的分散液。 將由所播得之分散液所取出之白色著色高分子粉粒體 99重量份，與除了將顔料以磺黑代替混合4. 4重量份 之外、》其他均依與上述梓同之方式調製取出的黑色著色高 分子^粒體1重暈份分別混合後•再於不揮發成分55% ·. * 之水性淸漆50重量份中，将此等著色高分子粉粒B及作 為短餓維之平均長為5mm之赛璐玢«维2. 0重fi份混 練，獲得淡彩色之塗料组成物》 於此實施例中，俱使用不揮發成分47%之苯乙烯丙 烯酸乳睡（商品名稱 Acronal YJ 121 0D,三爱油化巴地 歇公司製）80重量份作為乳踴合成樹脂，使用漢撒黃4 0重董份與其混合，調裂成着色塗料》 其次，使用作為合成樹脂之平均粒徑為1 〇 wm之聚 甲基丙烯酸甲酯条樹脂（商品名：塔Λ齊克一A166 ( 東洋纺雜公司製），在此合成樹脂中混入作為可塑雜之苯 二酸二正丁酯，使其含量為2 9重量％，將其諝製成1 5 0重置份。 而後，將上述著色塗料與含有可塑劑之合成樹脂混合 ，在將水適量添加後，將作為金屬發之氛化鈣1. 1重量 份添加，獾得在合成樹脂粒子表面形成有著色塗料被覆膜 之平均粒徑為12的著色高分子粉粒Β之分散液。 -1 7 - (請先閲讀背面之注意事項再塡寫本頁) —裝· 訂· -丨^_ 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公* ) 82.6. 40,000 214564 經濟部中央標準屬貝工消費合作社印製 A6 B6 五、發明説明（丨心） 將由所獲得之分散液所取出之黃色箸色高分子粉粒體 9 9重量份，與除了將上述著色塗料中混合的顔料以肽花 青藍代替混合4.4重量份之外，其他均依舆上述相同之 方式調製取出的藍色著色高分小粉粒饅1重量份分別混練 後，再於不揮發成分5 5%之水性淸漆5 0重量份中，將 :此等著色离分子粉粒β及作為短《維之聚酯雄維（平均長 0. 5mm) 4. 0重置份舆其混練，獲得淡彩色之塗料 组成物。 (實施例6 ) 於此實施例中，除了使用平均粒徑為50«m之聚胺 基甲酸酯樹脂（商品名：優利亞粉（北辰公司製））以外 ，其他方面與上述實施例5相同，混合含有相同可塑劑之 合成樹脂及著色塗料，獲得平均粒徑為57wm之黄色着 色高分子粉粒體的分散液及藍色著色高分子粉粒《的分散 液〇 將由所獲得之分散液取出之S色箸色高分子粉粒鳢9 9重量份及藍色高分子粉粒S1重量份分別予以混練後， 再於不揮發成分55%之水性淸漆50重量份中，將此等 著色高分子粉粒體及作為短纖維之聚醋鑛維（平均長0. 3mm) 1. 0重量份與其混練，獲得淡彩色之塗料組成 物。 (實施例7 ) 於此實施例中，除了使用平均粒徑為20tfm之聚丙 -18- 本紙張尺度適用中國國家律準（CNS)甲4规格（210 X 297公釐） 82.6. 40,000 ----------------ί-------裝------訂-----(·ν (請先聞讀背面之注意事項再塡寫本頁) ， 214564 A6 B6 經濟部中央標準局w工消费合作社印製 五、發明説明（/y) 烯腈条樹脂（商品名：塔虎齊克AR (東洋紡鐵公司製） )以外，其他方面與上述實施例5相同，混合含有相同可 塑爾之合成樹脂及著色塗料，獲得平均粒徑為25之 黃色著色高分子粉粒涯的分散液及藍色著色高分子粉粒體 的分散液。 '’將由所獲得之分散液取出之黄色著色高分子粉粒體9 t . ,导重量份，與除了將上述著色塗料中混合的顔料以it花青 藍代替混合4. 4重置份之外，其他均依與上述相同之方 式調裂取出的藍色著色高分子粉粒β1重置份分別混練後 Λ再於不揮發成份5 5%之水性淸漆5 0重置中，將此等 着色高分子粉粒釀及作為短纖維之賽璐玢《維（平均長7 mm) 1. 0重量份與其混鍊，獲得淡彩色之塗料组成物 〇 (比較例1 > 除了不混入嫘縈短雄維之外，其他步《均與實施例1 相同，獲得塗料組成物》 (比較例2 ) 除了不混入耐隆短雄維之外，其他步《均與實施例2 相同，獲得塗料组成物。 (比較例3 ) 除了不混入維尼隆短維維之外，其他步驟均與實施例 3相同，獲得塗料組成物。 (試驗例） -19- <請先閲讀背面之注意事項再塡寫本頁) 」 訂· 線. ΜΛ張度適用中國國家標準（CNS)甲4规格（210 X 297公釐 214 沾 4 A6 __B6_ 五、發明説明（β ) 將上述實施例1〜3及比較例所得之塗料组成物，兩 度塗布於石板試驗Η之表面，並觀察塗膜之外觀、腾威， 以及塗料之垂流狀萠。 就各值實施例及比較例，其外觀供藉由在塗布後之2 小時，在離開3公尺之狀況下，以目視戡察彩色之多彩戚 :的S目程度（沙皮革感），進行評估。 i . 觸成係藉著在塗布24小時後，以指尖觸摸時，戥察 .0 是否有粗植感，以之而進行評估。 有鼸塗料之垂流狀，供以垂弛拥試計進行塗布，以垂 流部份之重量膜厚進行評估。 評估時，係随機選出男女20人之志願者，以評價最 優者得10黏，最劣者得0黏，以1黠為階级差進行評估 ，各、者之平均點係如表1所示。 (請先Η讀背面之注意事項再堉寫本頁) —裝. 訂_ 蛭濟部中央標準局R工消费合作社印製 -20- 82.6. 40,000 本紙張尺度適用中國國家標準（CNS>甲4规格（210 X 297公藿） A6 B6 五、發明説明（丨^ )U 丨 Installation · Order. Printed by the Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (/ y) in the paint composition of 100 parts by weight. So the reason is that when the length of the short-speaking Luo is less than 0.3 mm, it will become difficult to break the square of the Luo, and when the amount of the short-iron dimension is not 0.05 parts by weight, it will Can not express the "drop H" -shaped colorful pattern and moderate colorfulness on the coating film as the purpose of the present invention; on the other hand, when the length exceeds 10 mm, the coating film after coating will not Sandy leather skin appears. Also, when the above blending amount exceeds 4.0 parts by weight, the fluidity of the paint will be lost, so that the coating is difficult and unfavorable. In addition, by combining the short fibers with a length of 0.5 mm by 0.6 weight parts, not only can the frost-like colorful patterns appear, but even the pale colors can also show the blinding patterns, and , It can also effectively impart muscle to the coating film, which can almost completely prevent the phenomenon of dripping or uneven coating. The short fibers mentioned above can be directly mixed into the dispersion liquid of the color polymer powder certificate, or the colored polymer powder particles can be taken out from the dispersing limb, and mixed with the short fibers in the water-based varnish, And if necessary, add defoaming agent or drilling agent to it, and the paint composition can be obtained accordingly. Or, after the paint has been prepared, the short tentacles can be combined with it, but not subject to this restriction. Regarding the water-based varnish, there are no special restrictions, and latex resins or water-soluble resins can be used, for example, resins with acrylic strips, acetate strips or other strips can be suitably used. In addition, by applying the hardness of the above-mentioned water-based varnish or colored polymer powder to -13- this paper ruler and the applicable Chinese Standard (CNS) A «_ branding (210 X 297 public S) 81.9.20,000 (please read first The notes on the back of the qiong will be on each page)-Packing. Ordering. A6 5. Description of the invention (/ >) or softness. &Amp; Aihua, you can also get coatings with various albums. In addition, by appropriately combining a variety of color-coded polymer powders with different colors, and mixing them with short fibers in water-based varnishes, paints that can form colorful patterns can also be obtained. [Examples]: Below, Η takes several examples to illustrate the effect I of the coating composition of the present invention. Further clarify D (Example 1) In this example, styrene with a nonvolatile content of 47% is used pseudo Acrylic latex (trade name Acronal YJ 12 1 0D, Mitsubishi Oil Chemical Co., Ltd. crack) 80% replacement part as a latex synthetic resin, using 40 parts by weight of titanium dioxide mixed with it. Secondly, in an ethylene vinylidene polymer (product name: Zeun 103 ZXA manufactured by Japan Saiwang Co., Ltd.), which has an average particle diameter of 40 wm as a synthetic resin of nitroethylene, it is mixed with phenylenedi-n-octyl ester as a plasticizer to make The content is 29% by weight, and 150 parts by weight of the compound are split. < Recognize first ^ Notes on the back of the book and then go to its 4 pages >. Installed. Ordered. Printed by the Ministry of Economic Affairs, Central Standards Bureau, 5 Gongxiao Ben Cooperative Society 5 < It is made of m powder heavy plastic. It can be made up of 3 sub-colors. Black can be mixed with 4 and 4 with high content. It can be mixed with the back diameter and mixed with the fat. The black milk is suitable for obtaining the water of sulfonate. It is expected that the same color will be in the same liquid and the color of the liquid will be mixed, and the amount will be divided into the weight and the weight of the mixed and divided. If it is obtained and 1 will be obtained by Yijiangshu, it will become a calcium powder. The amount of the chemistries will be determined by the amount of weight, the height of the ene is 9 and the color of the outer is 9 is 81.9.20.000. The wood paper is once again in the general HS home standard (CNS) A 4 cash (210 X 297 Public conversion) A6 B6 ¢ 14 ^ 64- V. Description of the invention (/ >) After mixing 1 part by weight of molecular powder, then 50% by weight of non-volatile components of 5% aqueous varnish and 0% by weight of ferrite Dimension (average length 0.5 mm) Ο. 6 parts by weight mixed with it to obtain a colorful paint composition. (Example 2) In this real spin columbium, polyvalent carboxyl compound or resin, pseudo-minimum is made of non-volatile: Micasol RX291 (component 50% of Japan Carbide Industrial Co., Ltd. «g system, trade name) acrylic acid Styrene resin (acid value 20) 2.2. ·> 6 parts by weight and Nicaso 丨 RX669 (trade name) (acid value 0, non-volatile content 50%) composed of acrylic styrene resin 52.6 parts by weight 75.2 parts by weight of synthetic resin, with respect to this synthetic resin, 40% by weight of titanium dioxide is mixed as a coloring pigment. Next, 150 parts by weight of an ethylene-nitrogen polymer with an average particle size of 40 UID (trade name Feiwang ΙΟ3 ZXA, manufactured by Japan Saiwang Corporation) was produced as a synthetic resin powder. Then, the latex resin composed of polyvalent carboxylic acid resin (acid value 6) containing colored pigment is mixed with synthetic resin powder, and after adding water in an appropriate amount, 1: 1, by weight of calcium chloride is mixed As a metal salt, a dispersion of colored polymer powder buns with an average particle size of 42 xxm was obtained. 9 9 parts by weight of the white colored polymer powders and granules taken out from the obtained dispersion, except that 4.4 parts by weight of the pigment is replaced with a master black, and other homogels are prepared in the same way as above. After mixing 1 part by weight of the small colored powder particles, mix 50% by weight of water-based varnish with non-volatile content of 55% and Nylon short iron dimension (average length 10mm) -15- This paper ruler is suitable for prisoners Xi Jiazheng (CNS) Jia Sao Ke (210 X 297 Gongluo) ------------------ ί ----- installed ------ ΤΓ- ----- ^ (please read first-note on the back-matters and then reprint this page) Ministry of Economic Affairs Central Standards ^ δ printed by the Workers and Consumers Cooperative-81.9.20,000 Printed by the Central Bureau of Standards of the Ministry of Economics and Industry 8 printed by the Consumers ’Cooperative 4 V. Description of the invention (/ γ) 0. Mix the quantity with it to obtain a light-colored paint composition. (Example 3) In this example, the pigment is used as titanium dioxide, and the carrier resin is used to remove Film additives made of acrylic resin (made by Asahi Paint Co., Ltd .; Pansita 1 100 semi-gloss white (removed into R additives), in the table of peelable materials ， Coat a coating film of 4000 m 2 20 m 2. After drying, peel off the coating film and crush it with a ball mill to obtain colored polymer powder particles with an average particle size of 80wm. Take the obtained white coloring 99 parts of high-molecular powder grain waist is replaced with 1 part by weight of black colored high-particulate granules which are taken apart in the same way as above except that the pigment is replaced with black pigment instead of 4.4 parts. After that, 50 parts of water-based paint with 55% of non-volatile content and 50 parts of Pooh's short iron (average length 1.0 mm) 4.0 parts are mixed with it to obtain a light-colored paint composition. 4) In this embodiment, like "Carne Boyo De Sole P43J (trade name) with an average particle size of 40wm and a non-volatile content of 60%, as the nipple synthetic resin, reset this nipple synthetic resin 80 It is mixed with 40 parts by weight of titanium dioxide to prepare a coloring paint. Secondly, as a synthetic resin, a plastic pulverized product with an average particle diameter of 20 ttm composed of polyethylene resin is prepared to be 150 parts by weight. The above colored paint is mixed with synthetic resin-16- A6 B6 (please Read the precautions on the back before filling in this page) -Installation_ Order- -Line · This paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 82.6. 40,000 A6 B6 Central Bureau of Standards 8 Printed by the Industrial and Consumer Cooperatives. V. Description of the invention (G) Plastic #Fragment, adding water and gasification as a coagulant "to it · Obtained on the surface of the synthetic resin plastic, an average particle formed with a colored coating film A dispersion of colored polymer powders and granules with a diameter of 2 5 wm. 99 parts by weight of the white colored polymer powders and granules taken out from the broadcasted dispersion liquid, except for 4.4 parts by weight except that the pigment is replaced with sulfone black,》 Others are prepared in the same manner as above After mixing the 1 part of the black colored polymer ^ granules with 1 weight part, then in 50 parts by weight of the non-volatile content of water-based paint, use these colored polymer powder particles B and as a short hunger. Celluloid with an average length of 5mm «Dimension 2.0 mixed with fi parts to obtain a light-colored paint composition» In this example, 47% non-volatile styrene acrylic nipple (trade name Acronal YJ 121 0D, manufactured by Sanai Oil Chemical Co., Ltd.) 80 parts by weight is used as a synthetic resin of milky chrysanthemum, using 40 parts of Hansa yellow and mixed with it, and it is cracked into a colored paint. Second, the average particle size of the synthetic resin is used It is 1 〇wm polymethyl methacrylate strip resin (trade name: Ta Λ Qike A A166 (manufactured by Toyobo Co., Ltd.)), and this synthetic resin is mixed with di-n-butyl phthalate as a plastic hybrid, so that Its content is 29% by weight, and its content is made into 1 5 0 reset Then, the above colored paint is mixed with a synthetic resin containing a plasticizer, and after adding an appropriate amount of water, 1.1 parts by weight of calcium hydroxide as a metallic hair is added, and the colored paint coat is formed on the surface of the synthetic resin particles. The dispersion of coloring polymer powder B with an average particle size of 12 is coated. -1 7-(Please read the precautions on the back side before writing this page) —Package · Order ·-丨 ^ _ This paper size is applicable China National Standard (CNS) A4 specification (210 X 297 g *) 82.6. 40,000 214564 Central Standard of the Ministry of Economic Affairs is printed by the Beigong Consumer Cooperative Society A6 B6 V. Description of the invention (丨 heart) will be taken out of the obtained dispersion The yellow pigment polymer powder and granules are 9 9 parts by weight, and the blue coloration is prepared in the same manner as above except that the pigment mixed in the coloring paint is replaced with 4.4 parts by weight of peptide cyanine blue. After mixing 1 part by weight of the high-quality small powder buns, and then in 50 parts by weight of the non-volatile component 5 5% water-based paint, the coloring of these molecular powders β and the short polyester Dimension (average length 0.5mm) 4.0 reset After mixing it together, a light-colored coating composition is obtained. (Example 6) In this example, in addition to the use of a polyurethane resin with an average particle size of 50 m (trade name: Uria Powder (Beichen Company Except for the above), the other aspects are the same as in Example 5 above. A synthetic resin containing the same plasticizer and a coloring paint are mixed to obtain a dispersion of yellow colored polymer powder particles with an average particle size of 57wm and blue colored polymer powder The dispersion liquid of the particle 〇. After mixing 9 parts by weight of the S-color cinder-colored polymer powder particle Snake and the blue polymer powder S1 part by weight taken from the obtained dispersion liquid, the non-volatile content is 55% In 50 parts by weight of the water-based paint, these colored polymer powder particles and the vinegar dimension (average length 0.3 mm) as short fibers are mixed with 1.0 part by weight to obtain a light-colored paint composition. (Example 7) In this example, in addition to the use of polypropylene-18 with an average particle size of 20tfm- This paper scale is applicable to China National Standards (CNS) Grade 4 specifications (210 X 297 mm) 82.6. 40,000 --- ------------- ί ------- installed ------ order ----- (· ν (please read the notes on the back before writing Page), 214564 A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives V. Invention description (/ y) Acrylonitrile strip resin (trade name: Tahoo Chic AR (manufactured by Toyobo Iron & Steel Co., Ltd.)) The same as in Example 5 above, a synthetic resin containing the same plastics and a coloring paint are mixed to obtain a dispersion of yellow colored polymer powder particles with an average particle size of 25 and a dispersion of blue colored polymer powder particles. The red colored polymer powders and granules 9 t taken out of the obtained dispersion liquid, 9 parts by weight, with the addition of the pigment mixed in the above-mentioned colored paint with it flower blue blue instead of mixing 4.4 reset parts, other All the blue colored polymer powder β1 reset parts that were split and taken out in the same way as above were mixed after mixing, and then washed with a non-volatile component of 5 5% water During the reset of lacquer 50, these colored polymer powders are brewed and the celluloid "dimensions (average length 7 mm) as short fibers 1. 0 parts by weight are mixed with it to obtain a light-colored paint composition. Comparative Example 1 > The steps "all are the same as in Example 1, except that the rayon short male dimension is not mixed" (Comparative Example 2) The other step "not including the nylon long male dimension" The coating composition was obtained in the same manner as in Example 2. (Comparative Example 3) The procedure was the same as that in Example 3 except that the short-dimensional dimension of Vinylon was not mixed. (Test Example) -19- < Please read the precautions on the back before writing this page) ”Order · Line. ΜΛ Zhang degree is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm 214 Zhan 4 A6 __B6_ V. Invention description (β) The coating compositions obtained in the above Examples 1 to 3 and Comparative Examples were applied to the surface of the slate test H twice, and the appearance of the coating film, Tengwei, and the vertical flow of the coating were observed. Comparative example, the appearance is provided by the state of 3 meters away from the surface 2 hours after coating Under the circumstances, visually inspect the colorfulness of the color: the degree of S mesh (sand leather feel) to evaluate. I. Touching is based on 24 hours after coating, when touching with your fingertips, check if there is .0 Coarse planting feeling, and then evaluate it. There is a drip-like paint, which can be applied by the sag tester, and the weight and film thickness of the drip part are evaluated. During the evaluation, 20 men and women are randomly selected For the volunteers, the best ones get 10 sticks, the worst get 0 sticks, and 1 point is used as the class difference. The average points of each person are shown in Table 1. (Please read the precautions on the back before writing this page) — Binding. Order _ Printed by Rong Consumer Cooperative, Central Bureau of Standards, Jijiji -20- 82.6. 40,000 This paper size is applicable to the Chinese National Standard (CNS> A4 Specification (210 X 297 commonweed) A6 B6 V. Description of invention (丨 ^)
V (請先閲讀背面之注意事項再填S本頁) 表 1V (Please read the precautions on the back before filling in this page) Table 1
外 觀 觸 g£ 塗料之垂流狀態 實施例1 10 10 〇 i . 鸾施例2 10 10 〇 實施例3 10 7 〇 比較例1 2 8 △〜X 比較例2 2 8 △〜X 比較例3 5 5 X Ο : 3 0 0 JU 〜 △ : 200 〜300u 經濟部中央標準局Β工消費合作社印製 X : 2 0 0以未滿 〔發明之效果〕 如上所詳述，本發明之塗料组成物，其持徽你在：含 有在合成樹脂粒子表面形成含箸色顔料之合成樹脂塗料被 -2 1- 82.6. 40,000 本纸張尺度適用中國國家標準（CNS)甲4规格（210 X 297公;^ ) A6 B6 五、發明説明o^7) ·.· · 覆膜所形成的平均粒徑為1 0〜8 0 Mm之着色高分子粒 粉粒體，以及〇. 3〜10m長之短纖維，作為必要成分 ，因此，由上述實施例可知，塗装後之塗膜上，偽形成沙 皮革狀之降霜氣氛的多彩花樣，可賦與適度之如肌虜般的 觸越，而且，即使塗裝後之塗膜呈淡彩.色，由遠方觀察時 :之多彩花樣戚也不致喪失，可表現》待且沈棰之鮮明色調 * · ,,而且在塗琴時之垂流現象或塗布不均勻現象均不致於發 生，實為一種優異之塗料组成物。 (請先«讀背面之注意事項再墦寫本頁) —裝. 訂· 經濟部中央標準局具工消费合作社印製 -22- 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 2耵公釐） 82.6. 40,000Appearance touches the paint dripping state Example 1 10 10 〇i. Luan Example 2 10 10 〇 Example 3 10 7 〇 Comparative Example 1 2 8 △ ~ X Comparative Example 2 2 8 △ ~ X Comparative Example 3 5 5 X Ο: 3 0 0 JU ~ △: 200 ~ 300u Printed by the Central Standards Bureau of the Ministry of Economic Affairs B Industry Consumer Cooperatives X: 2 0 0 or less [Effect of the invention] As detailed above, the coating composition of the present invention, Its emblem is with you: the synthetic resin coating containing synthetic pigments formed on the surface of the synthetic resin particles-2 1- 82.6. 40,000 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 g; ^ ) A6 B6 5. Description of the invention o ^ 7) ···· The colored polymer particles and granules with an average particle size of 10 to 80 Mm formed by the coating, and short fibers of 0.3 to 10 m in length, As an essential component, therefore, as can be seen from the above examples, the colorful pattern that pseudo-forms the frost-like atmosphere of sand leather on the coating film after painting can impart a moderate touch like a muscle, and even after painting The coating film is pale. The color, when viewed from a distance: the colorful pattern will not be lost, it can be expressed " The problem, vivid hues * * ,, and when coated piano vertical flow phenomenon of coating unevenness or as not occur are, in fact, of a coating composition is excellent. (Please first «read the notes on the back and then write this page) — Binding. Order · Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Co-operative Consumer Cooperatives-22- This paper scale applies to China National Standards (CNS) A4 specifications (210 X 2 kmm) 82.6. 40,000