CN104774543A - Leather-like paint - Google Patents

Leather-like paint Download PDF

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Publication number
CN104774543A
CN104774543A CN201510155587.8A CN201510155587A CN104774543A CN 104774543 A CN104774543 A CN 104774543A CN 201510155587 A CN201510155587 A CN 201510155587A CN 104774543 A CN104774543 A CN 104774543A
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CN
China
Prior art keywords
imitation leather
paint
leather paint
paint according
component
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Granted
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CN201510155587.8A
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Chinese (zh)
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CN104774543B (en
Inventor
梁文文
周烨
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Henan Libang Changrunfa Technology Material Co ltd
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SHANGHAI CHANGRUNFA PAINT CO Ltd
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Publication of CN104774543B publication Critical patent/CN104774543B/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a leather-like paint which comprises the following components in percentage by weight: 25-40% of castor oil alkyd resin, 25-40% acrylic resin, 0.5-5% of dispersing agent, 0.01-1% of leveling agent, 0.1-1% of defoaming agent, 1-5% of matting agent, 5-15% of talcum powder, 2-10% of fine silt, 1-5% of antisettling thickener, 0.05-0.15% of drying agent and 5-15% of solvent. The leather-like paint provided by the invention is easy for construction, has realistic leather-like effect, can be sprayed to obtain the leather-like effects with different colors, has the advantages of soft gloss, fine hand feeling, high scratch resistance and realistic leather-like effect, integrates the functions of decoration and protection, and can be used in wood products and artware surface decoration.

Description

A kind of imitation leather paint
Technical field
The present invention relates to a kind of traditional wood lacquer, particularly relate to a kind of imitation leather paint.
Background technology
Imitative decorations paint (faux finish) are the matter lines imitating various building materials or decorative material with coating, as parian, grouan, wood grain, metal, leather, cloth etc.This " imitative decorations " effect of mixing the spurious with the genuine is made on the building surfaces such as metope, cylinder, top ceiling, just cries " imitative decorations paint ".
From coating type, imitative decorations paint point two large classes: plane imitative decorations paint and the imitative decorations paint of solid.Wherein, cause imitative decorations effect from directly changing coating, plane imitative decorations paint is also called metallic paint (metallic paint), nacrolacquer (pearlescent paint) or imitation leather paint (suede paint).
Imitation leather paint is a kind of paint with special perception and sense of touch, and coating surface is uniform sand material shape and crackle special-effect.Do solid work rear hand and touch film coated surface, seemingly have the sensation of corium, magnificent noble quality, be specially adapted to the external coating of office series furniture and top grade decoration.
Chinese patent CN101638538A discloses a kind of waterborne suede coating, form primarily of water, talcum powder, fine particle calcium carbonate, defoamer, ammoniacal liquor, benzene emulsion, film coalescence aid, glass microballon and mill base, the coating of preparation has outstanding velvet and stereoscopic sensation, makes facing produce the effect of seemingly senior imitative fine hair.Japanese Patent JPH03227377A discloses a kind of coating with magnificent outward appearance and imitative fine hair sense, by the staple fibre (such as nylon fiber) that (A) 1-20wt% length is 0.1-2.0mm, (B) particle diameter of 1-70wt% is 1-500 μm, the particle (such as nylon or acrylic resin) of Mohs' hardness≤7, (C) 5-80wt% for disperse the solvent of staple fibre and particle (such as dimethylbenzene) and (D) 3-60wt% for the medium on bottom (such as acrylic polyol resin) by the staple fibre of described mixing and dispersion and particle bond.
But the imitation leather paint that above-mentioned patent provides, due to characteristic and the construction technology of imitation leather paint material, often there is the problems such as the weak effect of imitation leather paint, feel are bad, surface irregularity, imitation leather paint Integral decoration effect may be destroyed, even can cause quality problems.
Summary of the invention
The present invention solves the aforementioned problems in the prior proposition.
The invention provides a kind of easy construction, imitation leather paint that imitation leather effect is true to nature; it can spray the imitation leather effect varied in color; and there is the effect that gloss is soft, feel is fine and smooth, scrath resistance is strong, leather texture imitation effect is true to nature; integrate ornamental with protectiveness, can be used on wooden articles and handicraft surface decoration.
For achieving the above object, the present invention is by the following technical solutions:
One aspect of the present invention is to provide a kind of imitation leather paint, and the weight percent content of each component and each component comprises:
In the component of above-mentioned imitation leather paint, the effect of described ricinoleyl alcohol acid resin improves sticking power and paint film property.
In the component of above-mentioned imitation leather paint, preferably, the molecular weight of described acrylic resin is 50-5000, is more preferably 80-3000, is especially preferably 100-1500.
In the component of above-mentioned imitation leather paint, preferably, described dispersion agent is selected from the carboxylate salt, poly-containing any one in the carboxylate salt of hydroxyl unsaturated polyester acid amides or multiple of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
In the component of above-mentioned imitation leather paint, preferably, described flow agent be selected from silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described defoamer be selected from natural fats and oils (as soya-bean oil, Semen Maydis oil), polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described matting agent be selected from polyester matting resin RB608 or RB3329, white carbon black any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described talcous particle diameter is 4000 orders, and its effect promotes the smooth feel of paint film.
In the component of above-mentioned imitation leather paint, preferably, described thin frosting powder is through the high molecular weight polypropylene wax that about 330 DEG C of refining glue do not melt, and size distribution D50 is preferably 6-9 μm, and particle diameter is preferably 6-10 μm, and feel is smooth.
In the component of above-mentioned imitation leather paint, preferably, described anti-settling thickening material be selected from organobentonite, aerosil, modified hydrogenated Viscotrol C, polyamide wax any one or multiple, be more preferably aerosil.
In the component of above-mentioned imitation leather paint, preferably, described solvent is selected from dibasic alcohol ethers, lipid solvent, comprise in ethyl acetate, butylacetate, pimelinketone any one or multiple.
Embodiment
Carry out detailed and concrete introduction below by specific embodiment to the present invention, to make better to understand the present invention, but following embodiment does not limit the scope of the invention.
embodiment 1
The present embodiment provides a kind of two component imitation leather paint, and the weight percent content of each component and each component comprises:
In the component of above-mentioned imitation leather paint, the effect of described ricinoleyl alcohol acid resin improves sticking power and paint film property.
In the component of above-mentioned imitation leather paint, preferably, the molecular weight of described acrylic resin is 50-5000, is more preferably 80-3000, is especially preferably 100-1500.
In the component of above-mentioned imitation leather paint, preferably, described dispersion agent is selected from the carboxylate salt, poly-containing any one in the carboxylate salt of hydroxyl unsaturated polyester acid amides or multiple of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
In the component of above-mentioned imitation leather paint, preferably, described flow agent be selected from silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described defoamer be selected from natural fats and oils (as soya-bean oil, Semen Maydis oil), polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described matting agent be selected from polyester matting resin RB608 or RB3329, white carbon black any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described talcous particle diameter is 4000 orders, and its effect promotes the smooth feel of paint film.
In the component of above-mentioned imitation leather paint, preferably, described thin frosting powder is through the high molecular weight polypropylene wax that about 330 DEG C of refining glue do not melt, and size distribution D50 is preferably 6-9 μm, and particle diameter is preferably 6-10 μm, and feel is smooth.
In the component of above-mentioned imitation leather paint, preferably, described anti-settling thickening material be selected from organobentonite, aerosil, modified hydrogenated Viscotrol C, polyamide wax any one or multiple, be more preferably aerosil.
In the component of above-mentioned imitation leather paint, preferably, described solvent is selected from dibasic alcohol ethers, lipid solvent, comprise in ethyl acetate, butylacetate, pimelinketone any one or multiple.
embodiment 2
The present embodiment provides a kind of two component imitation leather paint, and the weight percent content of each component and each component comprises:
In the component of above-mentioned imitation leather paint, the effect of described ricinoleyl alcohol acid resin improves sticking power and paint film property.
In the component of above-mentioned imitation leather paint, preferably, the molecular weight of described acrylic resin is 50-5000, is more preferably 80-3000, is especially preferably 100-1500.
In the component of above-mentioned imitation leather paint, preferably, described dispersion agent is selected from the carboxylate salt, poly-containing any one in the carboxylate salt of hydroxyl unsaturated polyester acid amides or multiple of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
In the component of above-mentioned imitation leather paint, preferably, described flow agent be selected from silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described defoamer be selected from natural fats and oils (as soya-bean oil, Semen Maydis oil), polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described matting agent be selected from polyester matting resin RB608 or RB3329, white carbon black any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described talcous particle diameter is 4000 orders, and its effect promotes the smooth feel of paint film.
In the component of above-mentioned imitation leather paint, preferably, described thin frosting powder is through the high molecular weight polypropylene wax that about 330 DEG C of refining glue do not melt, and size distribution D50 is preferably 6-9 μm, and particle diameter is preferably 6-10 μm, and feel is smooth.
In the component of above-mentioned imitation leather paint, preferably, described anti-settling thickening material be selected from organobentonite, aerosil, modified hydrogenated Viscotrol C, polyamide wax any one or multiple, be more preferably aerosil.
In the component of above-mentioned imitation leather paint, preferably, described solvent is selected from dibasic alcohol ethers, lipid solvent, comprise in ethyl acetate, butylacetate, pimelinketone any one or multiple.
embodiment 3
The present embodiment provides a kind of two component imitation leather paint, and the weight percent content of each component and each component comprises:
In the component of above-mentioned imitation leather paint, the effect of described ricinoleyl alcohol acid resin improves sticking power and paint film property.
In the component of above-mentioned imitation leather paint, preferably, the molecular weight of described acrylic resin is 50-5000, is more preferably 80-3000, is especially preferably 100-1500.
In the component of above-mentioned imitation leather paint, preferably, described dispersion agent is selected from the carboxylate salt, poly-containing any one in the carboxylate salt of hydroxyl unsaturated polyester acid amides or multiple of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
In the component of above-mentioned imitation leather paint, preferably, described flow agent be selected from silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described defoamer be selected from natural fats and oils (as soya-bean oil, Semen Maydis oil), polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described matting agent be selected from polyester matting resin RB608 or RB3329, white carbon black any one or multiple.
In the component of above-mentioned imitation leather paint, preferably, described talcous particle diameter is 4000 orders, and its effect promotes the smooth feel of paint film.
In the component of above-mentioned imitation leather paint, preferably, described thin frosting powder is through the high molecular weight polypropylene wax that about 330 DEG C of refining glue do not melt, and size distribution D50 is preferably 6-9 μm, and particle diameter is preferably 6-10 μm, and feel is smooth.
In the component of above-mentioned imitation leather paint, preferably, described anti-settling thickening material be selected from organobentonite, aerosil, modified hydrogenated Viscotrol C, polyamide wax any one or multiple, be more preferably aerosil.
In the component of above-mentioned imitation leather paint, preferably, described solvent is selected from dibasic alcohol ethers, lipid solvent, comprise in ethyl acetate, butylacetate, pimelinketone any one or multiple.
performance test
1, paint film appearance test:
Table 1 asked for an interview by the embodiment of the present invention and traditional imitation leather paint paint film appearance synopsis.
Table 1
Test group Paint film appearance
Standard group Imitation leather is effective, and texture is good, and sense of touch is better
Embodiment 1 Imitation leather is effective, and texture is good, and sense of touch is better
Embodiment 2 Imitation leather is effective, and texture is good, and sense of touch is better
Embodiment 3 Imitation leather is effective, and texture is good, and sense of touch is better
Tradition imitation leather paint Feel is poor, surface irregularity
As can be known from Table 1, in embodiment of the present invention 1-3, the imitation leather paint coating surface imitation leather of gained is effective, texture is good, sense of touch is better, but the coating surface feel of traditional imitation leather paint is poor, surface irregularity, in the visible embodiment of the present invention 1-3 feel of the imitation leather paint coating surface of gained and texture all more satisfactory.
2, the substrate adhesion test of imitation leather paint:
Testing method: by embodiment 1-3 and traditional imitation leather paint, the associated viscera with reference to GB9286-88 " paint film adhesion testing standard " (drawing compartment apart from 2mm) is tested, and test result is as shown in table 2.
Table 2
Experimental group Paint film adhesion
Standard-required ≤ 1 grade
Embodiment 1 1 grade
Embodiment 2 1 grade
Embodiment 3 1 grade
Tradition imitation leather paint 2 grades
As can be known from Table 2, in the embodiment of the present invention 1-3 sticking power of the imitation leather paint of gained all≤1 grade, meet the standard of paint film adhesion, and the sticking power of traditional imitation leather paint is 2 grades, sticking power is not good.
3, test time of drying of imitation leather paint:
Testing method: by embodiment 1-3 and traditional imitation leather paint, test with reference to the associated viscera in GB/T1728-1979 (1989) " paint film, putty membrane assay method time of drying ", test result is as shown in table 3.
Table 3
Experimental group Surface drying time Do solid work the time
Standard-required ≤2h ≤24h
Embodiment 1 15min 2h
Embodiment 2 10min 1.5h
Embodiment 3 20min 3h
Tradition imitation leather paint 38min 6h
As known from Table 3, in the embodiment of the present invention 1-3 surface drying time of the imitation leather paint of gained all≤20min, the shortest time of doing solid work can be low to moderate 8min; Do solid work time then all≤3h, the shortest time of doing solid work is 1h.By contrast, surface drying time and the time of doing solid work of traditional imitation leather paint are the twice of embodiment of the present invention 1-3, and drying rate is well below the imitation leather paint of gained in embodiment of the present invention 1-3.
In sum, the imitation leather paint of embodiment of the present invention gained not only has quick-drying and paint film imitation leather is effective, texture good, sense of touch is better and have stronger sticking power.
Be described in detail specific embodiments of the invention above, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.

Claims (10)

1. an imitation leather paint, is characterized in that, the weight percent content of each component and each component comprises:
2. imitation leather paint according to claim 1, is characterized in that, the molecular weight of described acrylic resin is 50-5000.
3. imitation leather paint according to claim 1, is characterized in that, described dispersion agent is selected from the carboxylate salt, poly-containing any one in the carboxylate salt of hydroxyl unsaturated polyester acid amides or multiple of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
4. imitation leather paint according to claim 1, is characterized in that, described flow agent be selected from silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane any one or multiple.
5. imitation leather paint according to claim 1, is characterized in that, described defoamer be selected from natural fats and oils, polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon any one or multiple.
6. imitation leather paint according to claim 1, is characterized in that, described matting agent be selected from polyester matting resin, white carbon black any one or multiple.
7. imitation leather paint according to claim 1, is characterized in that, described talcous particle diameter is 4000 orders.
8. imitation leather paint according to claim 1, is characterized in that, described thin frosting powder is high molecular weight polypropylene wax.
9. imitation leather paint according to claim 1, is characterized in that, described anti-settling thickening material be selected from organobentonite, aerosil, modified hydrogenated Viscotrol C, polyamide wax any one or multiple.
10. imitation leather paint according to claim 1, is characterized in that, described solvent is selected from dibasic alcohol ethers, lipid solvent, comprise in ethyl acetate, butylacetate, pimelinketone any one or multiple.
CN201510155587.8A 2015-04-02 2015-04-02 Imitation leather paint Active CN104774543B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN104774543B CN104774543B (en) 2020-03-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108610907A (en) * 2017-01-14 2018-10-02 北京赛瑞迪普家居装饰有限公司 Leather dope and preparation method thereof
CN112778895A (en) * 2021-01-12 2021-05-11 上海涂固安高科技有限公司 Wood grain imitation leather coating for magnesium aluminum alloy plate and preparation method thereof
CN114933831A (en) * 2021-12-16 2022-08-23 亘彩(浙江)新材料科技有限公司 Coating capable of forming cortex and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202005007762U1 (en) * 2005-05-18 2005-08-18 Gimm, Ulf Paint spray can kit for producing a leather-like surface comprises an acrylic basecoat paint and a silica-filled acrylic grain effect paint
CN104046225A (en) * 2014-07-02 2014-09-17 江苏海田技术有限公司 High-definition silky finish and preparation method thereof
CN104130648A (en) * 2014-07-22 2014-11-05 信和新材料股份有限公司 Aqueous crackle paint and coating technology thereof
CN104164171A (en) * 2014-08-19 2014-11-26 苏州羽帆新材料科技有限公司 Alkyd resin outer wall paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202005007762U1 (en) * 2005-05-18 2005-08-18 Gimm, Ulf Paint spray can kit for producing a leather-like surface comprises an acrylic basecoat paint and a silica-filled acrylic grain effect paint
CN104046225A (en) * 2014-07-02 2014-09-17 江苏海田技术有限公司 High-definition silky finish and preparation method thereof
CN104130648A (en) * 2014-07-22 2014-11-05 信和新材料股份有限公司 Aqueous crackle paint and coating technology thereof
CN104164171A (en) * 2014-08-19 2014-11-26 苏州羽帆新材料科技有限公司 Alkyd resin outer wall paint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108610907A (en) * 2017-01-14 2018-10-02 北京赛瑞迪普家居装饰有限公司 Leather dope and preparation method thereof
CN112778895A (en) * 2021-01-12 2021-05-11 上海涂固安高科技有限公司 Wood grain imitation leather coating for magnesium aluminum alloy plate and preparation method thereof
CN114933831A (en) * 2021-12-16 2022-08-23 亘彩(浙江)新材料科技有限公司 Coating capable of forming cortex and preparation method thereof

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