TW214516B - - Google Patents

Description

21l4 ⑽ A 6 B6 V. Description of the invention ι 1; Seal of the Central Standards Bureau of Yaji Ministry-Structure: The cosmetic gel contains a glycolic acid compound and a polymer that can accelerate gelation. It can contain a surfactant and oil solubility. ingredient. SUMMARY OF THE INVENTION: Field of the Invention The present invention is describing a cosmetic gel, especially a water-soluble cosmetic gel with excellent long-term stability and feeling of use. The present invention illustrates a water-soluble cosmetic gel that can contain a considerable portion of oil-soluble ingredients. In addition, the present invention shows that a water-soluble cosmetic gel containing other ingredients does not require an aging step 1 during the manufacturing process. In the previous technology, we know a glycyrrhizic acid component (such as the glycyrrhizic acid described in Keshoh 丨 n (cosmetics) Gen "yo (part) K 丨 jun and Han_Yo Keshoh [n (cosmetics) Genryochu (part)) Aqueous solution) can form a colloid in the acid gum value range from 2.5 to 5.8. For example, Japanese Patent Publication No. Zhuang-45-21397 discloses an aqueous solution containing 0.1 to 10% of glycyrrhizic acid compound, and its pH value Adjusted between 2 and 6, a water-soluble cosmetic gel can be obtained. Japanese Patent Application Publication No. -58-163429 discloses an emulsified sister compound containing glycyrrhizic acid or its salts An oily ingredient 13 stating that the sister compound is a transparent or translucent scorpion-like liquid or stomping. Questions to be Solved by the Invention SS However, the water-soluble glue made from the glyceric acid compound * is due to undesirable conditions The stability of the body, and the shortcomings of poor long-term anti-corrosion 2 In addition, it is used as a cosmetic (please read the precautions on the back and then fill out this page) • Install · • Play. Line. A 4 (210X 297 male; * ί) A6 B6 Fifth, the description of the invention (2), lack of incompatibility and the feeling of refreshing when using Unsatisfactory. The content of glycyrrhizic acid compound is increased to achieve the purpose of improving the stability of the colloid. The resulting colloid loses its ductility when applied to the skin, and at the same time it has a sense of stagnation, so it cannot be regarded as suitable for makeup On the other hand, when the oil-soluble ingredient is added with a glycyrrhizic acid compound as a gelling agent, but still retains the colloidal transparency of the water-soluble glue * The maximum amount that can be added is only 0.1 X. That is It can be said that ingredients that can be used as cosmetics, such as oil-soluble vitamins, cannot be added to an effective amount (such as about 1 «). This is because adding any surfactant to this kind of water-soluble glue to achieve the dissolution of oil-soluble ingredients For the purpose • The result will reduce the force value of the colloid and its long-term stability. In addition • The water-soluble glue containing glycyrrhizic acid compound has a manufacturing problem • It requires the step of aging. For example, the composition must be cooled to ( Please read the precautions on the back before filling out this page) • Laughs. The glue-dissolving water-soluble tfl species 1 is provided. The room is published in this book. According to P. Phase 1, there is a potential for gelatinization. I can use it to find a sense of use. Can have a gel-dissolving water-soluble species1. It is divided into the main body and the personality is dissolved in the oil. "The most famous hair of the Ming Dynasty is the equivalent of the compound glyphosate. The extension of the hair of Yan Zhongming is extended to the sister law method. Fang Zhejian's research step S Yanhua asked some old decisions about this exemption • order. • line. 3! Printed by the Central Bureau of Standards of the Ministry of Economy. The lack of viscous energy is described as the speed of gluing is not added but there is a 'Protection and make-up compound chemically soluble acid waterweed can be found, the time agent has been turned into l ^ ii A 4 (210X 297 乂 尨) A6 B6 214516 V. Description of the invention (3) The combination of high-molecular polymers is beneficial to water-soluble cosmetic gel, which makes it have excellent long-term stability and use feeling. It has also been found that a surfactant can be added to these ingredients. With this, it is possible to add a considerable amount of oil-soluble ingredients without adversely affecting the stability of the gelling agent. The present invention is to describe a cosmetic gel containing a glycolic acid compound and a special high molecular polymer having an accelerated gelation function. The present invention also describes a cosmetic gel containing a glycyrrhizic acid compound and a special polymer having an accelerated gelation function, a surfactant, and an oil-soluble component. The glycyrrhizic acid compound used in the present invention includes glycyrrhizic acid and its salts. The glycyrrhizic acid salt preferably includes an inert salt such as potassium salt, sodium salt, lithium salt and ammonium salt: and an ammonium salt such as monoethylamine salt and triethylamine salt. The amount of this glycyrrhizic acid compound is 0.53 of the total weight of the cosmetics; to 10%, preferably 2¾ to 8SS. If it is less than 2S, the stability of Xuancheng colloid is poor. If it exceeds 10¾, the formed colloid will feel sluggish. Μ and the ductility on the skin is poor, so it is not suitable as a cosmetic. The polymer used in the present invention must have the ability to strengthen and accelerate the gelation of glycyrrhizic acid compounds, including gum, natural water-soluble polymer and synthetic polymer. Examples of special glues are gum arabic • diphenyl ethyl yeast, Dayu resin, resin gum, carrageenan, sea gum, xihuangshen. • Ganma galacto Jupu and QUINCE extract. Special natural water-soluble macromolecular polymers are agar, casein, dextrin, clarification, fruit sodium, sodium pectinate, starch * sodium hyaluronate, methyl salicin, ethyl retinol, carboxymethyl栖 维素 • Hydroxyethyl kinox •• Hydroxypropyl cellulose. Special synthetic high armor 4 (210X 297 public) ............................................ ............... ^ .............................. t .. ........................... Ling (please read the precautions on the back before filling in the textbook) Liji Printed by the Central Bureau of Standards

The long-term high-molecular-weight polymer supplements a kind of oil-solubility. This invention has a special high score. The glycyrrhizic acid salt of the present invention; and the alkaline glycyrrhizic acid are preferably qualitatively poor. It is widely used in the compound gum * synthesis of acetone, gum, mannose molecular polymer, starch cellulose, and the compound, which is beneficial to the water-soluble cosmetic gel and makes it extremely stable and feel good to use. It has also been discovered that among these ingredients, M surfactant can be used * By this, it is possible to add a considerable amount of ingredients to K without adversely affecting the stability of the gelling agent. This is a cosmetic gel containing a glycyrrhizic acid compound and a sub-polymer with an accelerated gelation function. It also shows that glycyrrhizin used in cosmetics containing glycyrrhizic acid compounds and molecular polymers with accelerated gelation function, surfactants and oil-soluble ingredients preferably includes amine salts, such as 2 S for monoacid compounds: to 8 is better than 10% poor spreading ability, high differentiation ability not invented, polymer polymerized dammar resin, galactoside and agar, and alginate hydroxyethyl grade retinoic acid compound organic compound * ethanolamine salt dosage is reduced. If it is less than that, suitable polymers are formed including trees. Special resin glue · QU IHCE extract casein * • Methylcellulose, and hydroxy, including glycyrrhizic acid such as potassium salt, sodium salt and trizetamine alcohol salt 2% of the weight of cosmetics, the formed colloid will be sticky cosmetic. Must have a reinforced gum, examples of natural water-soluble gum are carrageenan, sea extract. Special dextrin, gelatin, vitamin, ethylcellulose and propyl cellulose. And their salts. The lithium salt and ammonium paste Ο 0.5: «to 10 long-term colloidal sensation, and in the skin and accelerated licorice acid polymer polymerization of raber gum, diphenyl gum, Xihuangqi natural water-soluble high fruit knee , Pectin, Vitamin C, Carboxymethyl special high synthesis ...................................... ( .............. 5t ........................ ^ .... ...................... * ί · I Please read the precautions on the back before filling this page) f4 (21〇Χ 297 -a Μ) A6 B6 V. Description of the invention () & i. Molecular polymers include polyvinyl yeast, polyvinyl methyl ether, polyvinyl pyrrolidone, polyacrylic acid polyacrylate, carboxyvinyl polymer, and polyethyleneimine. The amount of the high molecular polymer is 0.01 to 5¾ of the total weight of the cosmetics, preferably 0.1 to 2.0¾. If it is less than 0.01 ×, the formed gel system has a reduced gel strength, and if it exceeds 5.0¾, it has an excessively strong gel strength and lacks ductility 'and is not suitable for cosmetics. The water-soluble surfactants that can be used in the present invention include nonionic, anionic, cationic and amphoteric surfactants. The type and amount of surfactant to be added depends on the type and amount of oil-soluble ingredients added. The lipophilic hydrophilic balance value of the surfactant is 8 to 18. The oil-soluble ingredients that can be used in the present invention include those commonly used in makeup, such as fragrances, hormones, and oil-soluble vitamins. Other oil-soluble ingredients can also be added depending on the use. Example: {Please first read the notes on the back and then fill out this I) • Installed • • Ordered. _ 咪 ， 甲 4 (210X297 public) 21451 ^ 82. ί · · Fifth, the invention description () A6 B6 has the following table 1 The sister-in-law cosmetics * test its simple manufacturing method, the properties of the finished product, long-term colloidal stability, and fluid mechanics. 1 m into a case 1 case comparison example 1 vs Zhao case? (Weight S!) (Chong Dong! ") (Reset"!) (Weight%) Component A Monoamine Glycyrrhizate 4.0 4.0 4.0 Pure Water 85.0 83.4 83. 8 87.4 Carboxyethylene polymer 0.3 0.3 _ — 0.3 Hydrogenation Nano 0.1 0.1 0.1 Ingredient B Alcohol 10.0 10.0 10.0 10.0 Polyoxyethylene glycerol pyro-glutamate (25E.0) 0.5 1.5 1.5 1.5 Vitamin E 0.05 0.1 0. 1 0.1 Ba-o-dimethyl benzoic acid Ester 0.5 0.5 0.5 0.5 Perfume 0.05 0.1 0. 1 0.1 (please read the precautions on the back before filling this page) _ ^. _ Order · Indole-A 4 (210X 297 public) 214516 82 · 1. 3〇A6 B6 V. Description of the invention (Fu Bei will dissolve the content of component A at 70T: ‘dissolve’ at 70 ¾ and drop it into the component of homogeneously dissolved component B at 70¾, and stir it. It can be stirred at room temperature until the mixture is cooled to 3010. If necessary, the mixture can be cooled to 5 * C, and the colloid aging step is carried out at this temperature. The simple method of making colloids, forming the properties of the finished product, long-term The colloidal stability and fluid mechanics are shown in Table 2. (Please read the notes on the back « (This page is written) Table 2. Installation · m Simple preparation method without aging Example 2 Easy to decompose colloid without aging properties Easy to decompose colloid Long-term colloidal stability is excellent Excellent control example 1 It takes 6 hours of aging easy to decompose colloid bad control Li 2 It takes 6 hours to aging the rolling liquid in bark state. &Quot; Easily decomposable colloid " here means that the colloid will show a high degree of shake, that is, a strong force (resistance) will be shown at the beginning of the load , When the load exceeds a certain limit, this pressure (resistance) will be suddenly lost. From the results seen in Table 2, each of the sisters in Example 1 and Example 2 (Example 2 contains 0.7% oil-soluble components) .Gelification without aging in the box, with 4-8 in frozen-8 (210X297 public) 82. V. Description of invention () ~ Gun-style coriander k pass 0 ^ ^ 0 ^ ^ Substantial investment ib-i B 0 Gou -zstf .-I -1 ^ ¾¾¾ --Ξ5ηϊ / v — ifl — ζ: φ- 丨 一 fa ^ --- 24 ο · or) 4.0 s. ο o.:i 0.1 10.0 ο: ΟΊ 0.05 ^ * ο Η: i. 二 Ο.: 5 0.1 10.0 J 0.1 ο: ") 0.1 G. Ο Ξι 0.3 Ο _ 1 1 Ο. Ο J. Γ) 0.1 Ο. Γι π. 1 0.- '0.1 Η. Ο 7 ί ~-ρ: ί π- ()-Γ 「〕 A6B6 01 a_ F—4 t, please read the precautions on the back before filling in this page) .it. 3 • Hit. Ο Ο. ().:"] 10.0 4.0 Η-. 8 87 1 Ο.: I 0.1 Η). Ο 1: "> 0.1 0.5 ί)-(). (Ί .Γ >

1 Q, U (; .0 Μ 1 Β .Green. 0- Ο .Γ) ()-1 () · () Β. Ο /(".Η ο Ί- 甲 4 (210X297 public) 21451 «A6 B6 V. Description of the invention (9) Now that Comparative Example 4 cannot form a colloid and only produces an emulsion-like product, there is no need to perform a sensory identification test. In the case where the composition of each sample is not known | The feeling of using the sample. Μ "Easy to choose " · Λ ductility" by hand, "Feel after use" | "Like" & "Easy to decompose" and other items for evaluation, the rating criteria are as follows: + 1 Means "good", 0 means "medium", and -1 means "bad". The scores of each item are added together. The scores are as follows. The results are shown in Table 4. (Please read "Back" first (Please fill in this page again). Xiang.. Order .. Green · Printed by the Central Standardization Bureau of Bayu Ministry of Economic Affairs 4 (210X297 Public Issue) _-11- 9. Printed by the Ministry of Economic Affairs, the quasi-AM industrial consumer cooperation cooperative ^ 4516 V. Description of the invention (Sichuan) sitsilie? Siff 72 81: 52 Γ > 2 29 17 15 18】 0

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Q 4 (please read first and back to the attention matter) # fill in this F, Γ -113 $ r-s " M-fi _:! &Quot; "r M_Mbb This paper scale is used in the" «家 t? 准 (〇 Ν5) Ή specifications (21? :) < 2Ό7 male dragon) -12- 81. 7. 20.000 伥 (II) 214516 A6 B6 V. Description of the invention 11, ι As seen from Table 4, cosmetics according to the present invention and Compared with the control group containing monoamine glycyrrhetinate, satisfactory results can be achieved • For example, Comparative Examples 3 and 3, Comparative Examples 5 and 5, and Comparative Examples 6 and 6. In the above test, the long-term stability test is carried out on those test items whose score is greater than or equal to 50. The samples of each period are stored in a greenhouse with a temperature setting of 4〇, 2〇υ or ίου. In the first month and the second month, take out the kneaded product. Μ The following method is used for evaluation. Poor ---- the flow of the colloid can be observed moderately ---- the gel condyle can be observed a little flow Good ------ The flow results of colloid cannot be observed as shown in the following Table 5. {Please read the notes on the back before filling in this page) • Ordered · Printed by the Central Bureau of Standards of the Ministry of Economic Affairs-Month 1 Example 3 5 Example 4 Yes Example. 3 40 Allison Poor 20 r Allison Plus 1 0 π Allison Plus 2 month 40 t Allison Difference 20V Allison Medium 1 0 Τ: Allison • Allison 4 (210X 297W hair) -13- A6 B6 contains the most (weight 4.0 93.5 214516 V. Description of the invention) As seen in Table 5, Example 3 and Example 4 have excellent long-term stability. Comparative Example 3 only uses the glycyrrhizic acid compound as the only gelling agent. It will interfere with the long-term stability. Example 7 The soft drink free of booze, a non-alcohol cosmetic with the following sister formula, can be prepared according to the method in Example 1. Ingredients

Ingredient A Glycyrrhizin Monopure Water

Carboxymethylcellulose sodium component B Polyoxyethylene (20) Sorbitan monolaurate 1.5 Vitamin E 0.1 Isosyl 30 0.5 Perfume 0.1 The cosmetic products formed are good for use and have excellent long-term stability-14 A 4 (210X 297 异 发) .......................................... ........ it .............................. fight .......... ........... Sigh (please read the precautions on the back before filling in this page) 214516 82 · 1. 30 A6 B6 V. Description of the invention () m_a_ Anti-cut window . Dolphin is a cosmetic product with the following composition, which can be prepared according to the method in the example. Component A Monoamine Glycyrrhizin Pure Water Xanthan Gum Containing (weight S!) 98.1 Component B Alcohol 5.0 Polyoxyethylene ( 20) Sorbitan monolaurate 1.7 Vitamin E 0.1 Octa-p-dimethylamino benzoate 0.6 Oxyphenyl 0.1 Perfume 0.1 The cosmetic use formed is good, and has excellent long-term stability 15. .................................................. Pretend ........................ Order ............... ............ line (please read "Notes on the back and then write this page") 4 (210X 297 伂 发) 214516 82. ί.3〇Α6 Β6 V. Description of the invention () Μ_a Anti-sleep building, no (without distillate) A non-alcohol cosmetic with the following sister, can be according to Example 1 Method. Ingredients containing the most (weight ao ingredient A monona glycyrrhizate 5.0 pure water 91.7 carboxyethyl cellulose sodium '0.3 ingredient B polyoxyethylene (20) olive ether 2.0 formazan 0.1 vitamin E 0. 1 octa-p-dimethyl Amino benzoate 0.6 Oxybenzophenone 0.1 Perfume 0.1 The cosmetic products formed are of good quality and have excellent long-term stability (please read the precautions on the back before filling this page). .Subscribe., ^, A4 (210X 297 佂 没) 214516 A6 B6 V. Description of invention (

JO is a cosmetic product with the following success, which can be prepared according to the method in Example 1. Component A Monona glycyrrhizinate pure water xanthan gum component B Alcohol polyoxyethylene glycerol (25E · 0) Pyroglutamic acid iso Stearate Vitamin E Acetic Acid Tocopherol Fragrance Containing (Weight! Η 85.6 The cosmetic product formed is good in use and has excellent long-term stability. Short description of the graphs. FIG. 1 shows examples 1 and 2 and The hydrodynamic plaques of the elder sisters obtained in Comparative Example 1 and Comparative Example 2. The vertical bar represents pressure, and the horizontal bar represents time (minutes). 17 (please read "Precautions on the back and then fill in this page"). _. Hit. • 竦. A 4 (210Χ 297 异 发)

Claims (1)

6. Application for 4 kg 82. 〇. A public Aν; A7 B7 C7 D7 1 · A cosmetic gel sister compound, which contains a weight ratio of 2% to 10% glycyrrhizic acid compound and 0.01% to 5% of the acceleration glue Polymer, wherein the glycyrrhizic acid compound is selected from glycyrrhizic acid, inorganic glycyrrhizic acid eel selected from potassium salt, sodium salt, lithium salt and ammonium cyanide, etc., and is selected from monoethylase and triethylase Ammonium salt of sickle glycyrrhizin. 2. The cosmetic gel composition according to item 1 of the patent application. Wherein, the knee-accelerating polymer is selected from gum, natural water-soluble polymer, and synthetic polymer. 3. According to item 1 of the patent application, the cosmetic gel sister compound, where the gel can contain a surfactant and oil-soluble ingredients. (Please read the notes on the back before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs ¾ A 4 (210X 297 Public Broadcasting) 1-