經濟部中央標準局β工消費合作社印製 214014 Λ--^_ΐϋ：_ 五、發明説明（1 ) 本發明乃藺於一基質上反反射及反靜電之塗佈’該塗佈 二氧化矽及反閃耀層姐成之雙層。 本發明亦闞於一含顯示蒂之陰極射線管，顗示幕具有— 反反射及反靜霣之塗佈，該塗佈含一由二氧化矽及反閃耀 層組成之雙層姐成。 此發明尚關於在一基質上之反反射及靜電塗佈之製造方 法’塗層含由反靜電層及一反閃耀層姐成之雙層，該反靜 霉層之製1造係經提供一懸濁液，其中至少有一金颺氧化物 在烷基矽甲烷化合物之酒精溶液，再以升高之溫度處理Μ 在至少一傳導金靨氧化物上形成混合之二氣化矽層。 本發明尚闞於在一基質上製造一反反射及反靜電之塗佈 之另一方法，該塗佈.包含由一二氧化矽層及一反閃耀層姐 成之雙層。 反反射塗佈係用在顯示裝置之顯示幕上*光源之色封上 及其他光學元件如窗戶以降低横向光之損失及抑制在像中 之惱人反射。上述之塗佈並特別用於減低特別反射（反閃 耀效應）。反靜電塗佈可用於例如顯示裝置之顯示幕上。 此等層有足夠之電導性以確保出現在裝置外表面上之高靜 電電壓在數秒内即可被除去。因此，用戶在觸碰在螢幕上 時不會被電擊，此外，大氣塵之吸收亦可降低。 在美國專利規則4,945,282號中曾揭示顬示幂。該顯示 幂備有反反射及一反靜電塗佈，塗佈上含由二氧化矽層及 一反反射層組成之雙層。二氧化矽層為一反靜電層，含透 明之導電氧化金屬，配置在基質與反反射層之間，其厚度 本纸張尺度適用中國國家標準（CNS)甲4规格（210 X 297公笼） 81.9.20,000 ?g>/;.i-;s莽項冉碩寫本頁) 裝. 訂· 線. 經濟部中央標準局員工消費合作社印製 Λ 6 ΒΓ. 五、绛明説明（2) 為5〜5 ηιη。反反射層亦含二氧化矽及含二氧化矽夥粒其 直徑為10 — 100毫微米（nm)。如必要時，二層之之功能 可·结合在單一層内。該美國專利規格尚說明製造反反射及 反靜電塗佈之方法。兩種層之製造係由提供烷基矽甲烷化 合物之酒精溶液，接著Μ高溫處理K形成一二氧化矽層。 至於反靜電層之製造，一種如氧化鍚，氧化絪或氧化銻之 導電氧化金羼懋浮於烷基矽甲烷化合物之酒精溶液中。至 於反反射，層之製造，二氧化矽顆粒懸浮於烷基矽甲烷化合 物之酒精溶液中。 用已知方法製造反反射及反靜電塗佈之缺點在於其利用 一種反應的，先天上不穩定的烷基矽甲烷之酒精溶液中。 此種溶液對濕度非常敏感並具有限的保存特質。至於如此 製造之層之结構，尤其Μ烷基矽甲烷化合物之水解作用及 聚合性之程度及溶液之黏性，其再生性不甚理想。尤其在 反反射層中之微结構實際上會影響光學特性，此點特別重 .要。其對較薄之反靜電層重要性不大。此已知方法之另一 缺點為使用有機溶液，當大量使用時，需要採取安全措施 。此外’根據上述方法所製之塗佈由於在表面層中存在二 氧化矽之顆粒，故在機械性較弱。 本發明之目的在提供一基質上之反反射及反靜電層，其 製造之方法並為簡單並可再生。此一方面，本發明目的在 使用稞定之起點材料，具有良好之保持性質。本發明之另 一目的在提供在機械上堅強之餍而具有穩定之特性，其不 受迅速赛質而損害不受潮濕及污染之影響。本發明之特殊 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公笼） 81.9.20,000 ------------------------裝------_玎------線 (^ι.'νι-.'ίίιίυ-ί.,χώΐ^/ϊΛ-^^^τί)Printed 214014 Λ-^ _ lϋ by the β-Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs: _ V. Description of the invention (1) The present invention is antireflective and antistatic coating on a substrate. The coated silicon dioxide and The anti-shine layer is a double layer. The invention is also applied to a cathode ray tube containing a display pedestal. The display screen has anti-reflective and anti-static coatings. The coating contains a double layer composed of silicon dioxide and an anti-glare layer. The invention still relates to a method for manufacturing anti-reflection and electrostatic coating on a substrate. The coating contains a double layer composed of an anti-static layer and an anti-glare layer. The suspension, in which at least one gold oxide is in an alcoholic solution of an alkyl silane compound, is then treated at an elevated temperature to form a mixed two vaporized silicon layer on at least one conductive gold oxide. The present invention is still another method for manufacturing an anti-reflective and anti-static coating on a substrate. The coating includes a double layer composed of a silicon dioxide layer and an anti-blaze layer. Anti-reflective coating is used on the display screen of the display device * the color seal of the light source and other optical elements such as windows to reduce the loss of lateral light and suppress annoying reflections in the image. The above coating is especially used to reduce special reflection (anti-glare effect). Antistatic coating can be used, for example, on the display screen of a display device. These layers have sufficient electrical conductivity to ensure that the high electrostatic voltage appearing on the outer surface of the device can be removed within seconds. Therefore, users will not be shocked when they touch the screen, and the absorption of atmospheric dust can also be reduced. In the United States Patent Regulation No. 4,945,282, the power of a puppet was disclosed. The display is equipped with anti-reflection and an anti-static coating. The coating contains a double layer composed of a silicon dioxide layer and an anti-reflection layer. The silicon dioxide layer is an antistatic layer, which contains transparent conductive oxide metal, and is arranged between the substrate and the anti-reflective layer. The thickness of this paper is in accordance with the Chinese National Standard (CNS) Grade 4 (210 X 297 male cage) 81.9.20,000? G >/;.i-; s Mang Xiang Ranshuo wrote this page) Packed. Ordered. Line. Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Λ 6 ΒΓ. Fifth, Jiang Ming instructions (2) 5 ~ 5 ηιη. The anti-reflective layer also contains silicon dioxide and silicon dioxide particles with a diameter of 10-100 nanometers (nm). If necessary, the functions of the second layer can be combined in a single layer. The U.S. patent specification still describes the method of manufacturing anti-reflection and anti-static coating. The two layers are manufactured by providing an alcohol solution of an alkyl silane compound, followed by a high temperature treatment K to form a silicon dioxide layer. As for the manufacture of the antistatic layer, a conductive oxide such as thorium oxide, oxide oxide or antimony oxide floats in an alcohol solution of an alkyl silane compound. As for the anti-reflection, the manufacture of the layer, the silica particles are suspended in the alcohol solution of the alkyl silane compound. The disadvantage of manufacturing anti-reflective and anti-static coatings by known methods is that it uses a reactive, inherently unstable alcoholic solution of alkyl silane. This solution is very sensitive to humidity and has limited storage characteristics. As for the structure of the layer thus manufactured, especially the degree of hydrolysis and polymerizability of the M alkylsilyl compound and the viscosity of the solution, its reproducibility is not ideal. Especially the microstructure in the anti-reflection layer actually affects the optical characteristics, which is particularly important. It is of little importance for thin antistatic layers. Another disadvantage of this known method is the use of organic solutions, which require safety measures when used in large quantities. In addition, the coating prepared according to the above method is weak in mechanical properties because of the presence of silica particles in the surface layer. The object of the present invention is to provide an anti-reflective and anti-static layer on a substrate, and its manufacturing method is simple and reproducible. On the one hand, the purpose of the present invention is to use the starting material of the barley, which has good retention properties. Another object of the present invention is to provide mechanically strong and stable characteristics, which are not subject to rapid competition and are not affected by moisture and pollution. The special paper size of the present invention is applicable to the Chinese National Standard (CNS) Grade A (210 X 297 male cage) 81.9.20,000 ----------------------- -装 ------_ 玎 ------ 线 (^ ι.'νι-. 'Ίίιίυ-ί., Χώΐ ^ / ϊΛ-^^^ τί)
An ΗΓ) 21401^ 五、發明説明（？） MTt'""背曲之：;1*事項冉塡寫本頁) 目的在於提供顯示螢幕上有此反反射及反靜電塗佈之陰極 射線管。本發明另一目的在於提供一種簡單可靠的製造反 反射及反靜電塗佈之方法°因此，本發明目的在將有機酸 之使用減至最低程度。 提供在具有顯示幂上有反反射及反靜電塗佈之陰極射線 管之達成係纆由在首段中所提之反反射及靜電塗佈，該塗 佈包含由二氧化矽層及一反閃耀層之雙層姐成，該塗佈之 特擞為反·閃燿層含矽酸鋰。 在一本發明之適當具體實例中，二氧化矽層係一反靜電 層，其含有至少一導電的氧化金羼。逋當之透明，導電之 氧化金屬為一氧化錫，一氧化絪，一氧化銻及該氧化物之 混合物。其材料如水中材料及金靥與金屬化合物’特別是 鈀化合物可用來提供具有所需電導性之反靜電層° 根據本發明之第一個特別具體實例，二氧化砂層位於基 質與矽酸鋰層之間。如必要時，層内可增加材料以改變光 .，機械及其他特性。最好，二氧化矽層含至少一染料°此 所Μ適宜，因為矽酸鋰再加染料，因加入染料後此層較不 耐久。 根據本發明塗佈之第二個特別具體實例，其中以與第一 具體實例相反順序提供各層，矽酸鋰層位於基質與=氧& 矽層之間。 經濟部中央標準局員工消費合作社印製 根據本發明之塗佈之第三涸特別具體實例，其中反閃嫌 及反靜電功能结合一單一層中，矽酸鋰曆為一反靜電11 ’ 其中含至少一導電金靨氧化物，該層位於基質與氧化砂± 本纸張尺度適用中gg家橒準（CNS)甲4規格（210 X 297公笼) 81.9.20,000 Αβ Hi； 214014 五、發明説明（4) 之間。所用之導電金靨氧化物或具有導電性之其他材料可 與上述之二個具體實例中二氧化矽層中在相同。在第三個 具體實例中，二氧化矽層目的在保證加在矽酸鋰層中之材 料能永遠併入其中。 如需要再加入額外材枓如一或更多染料在本發明塗佈之 第二或第三個具體實例中，該染料可隨意加在各層中。特 別是在雙層之至少一層中含一染料。在二氧化矽層中，染 料永久併.入而矽酸鋰層係K二氧化矽層覆蓋，俾可獲得絕 對穩定塗佈。 如必要時•含本發明之塗佈之基質可備有反反射層，各 所周知其係用來減少缌特別反射及特擴散反射。為此目的 ，具有低折射指數的氟化鎂層可用為作最外層，或具有高 及低折射指數之許多層亦可使用。 本發明之塗佈可用增添摻雜劑而改變其折射指數，特別 是加於二氧化矽層内。適於降低特反射的許多層含二氧化 砂之第一反靜電層並額外摻以二氧钛（折射指數1.7 )及 第二二氧化钛層（折射指數2.1其製造方法與製造二氧化 矽之方法類似）及一最外部之矽酸鋰之反閃耀層（折射指 數1.43) °每層之厚度為1〇〇至150 製造一反反射及反靜電塗佈之方法之目的各在首段所說 明之方法達成，其中所製造之雙層含一反靜電層及一反閃 耀層，反靜電層係撢供至少一導電金屬氧化物於院基矽基 烷化合物酒精溶液之混懸液中，接著以提高之溫度予W處 理Μ構成二氧化矽及至少一導電金靥氧化物之混合層’本 一 6 - 本紙張又度適用中國國家標準（CNS)甲4规格（210 X 297 Κ釐） ------------------------裝------，玎------'% 經濟部中央標準局員工消費合作社印製 81.9.20,000 Λ(ί Η»； 214014 五、發明説明（5) f t:y,";i而之：:,ώ莽項再場寫本") 發明之方法之持激為其中反閃耀層係提供氧化鋰穗定之二 氧化矽膠溶體於水中’接著增高之溫度處理以形成矽酸鋰 層。與本發明上述之塗佈之二具體實例，反靜電層及反閃 耀層可提供在一基質上’例如W任何有闞次序提供在陰極 射線管之顯示螢蒂上。 與本發明之塗佈之第三個具體實例一改’根據本發明之 另一方法之特微為其中之具反靜電效應之反閃耀層係提供 至少一導.電金鼷氧化物於氧化鋰穩定之二氧化矽膠溶體之 混懸液於水中，再以升高之溫度處理以形成矽酸鋰及至少 一種導電之氧化金臈之混合暦，之後再Μ烷基矽甲烷化合 物之酒精溶液製造保_層’接著Κ升高之溫度形成一二氧 化矽層。 經濟部中央標準局員工消費合作社印製 根據本發明，所用之二氧化矽層可依照美國專利規格 U.S. 4,945,282號所揭示之方法予Κ製造。根據本發明， 此層用來作為一反靜電層或一保護層。供二種用途可用具 有低於200nm之厚度，最好為5至50nm之薄層。由此方法 ，所需之反應性及不潘定之烷基矽甲烷化合物及有機溶劑 數量可以往技術所用者為少。根據本發明，矽酸鋰層係用 用Μ作為反閃耀層，該矽酸鋰不含個別顆粒因此，顯示較 強機械應力。在美國專利規格US 3,940,51 1中曾揭示矽酸 鋰之反反射層及製造該層方法*該層含有顔色校正装置為 油煙及染料，但纆調査顯示不用其他方法，此層不適合永 久併入導電金靨化合物或染料。本發明之方法將已知技術 之儍點结合並將每一技術之缺點減至最小。 81.9.20,000 本紙張尺度適用中國國家標準（CNS)甲規格（21ϋ X 297么、笙） 214014 五、發明説明（6 ) 本發明將以舉例具體實例及所附圖說予Μ詳細說明： _ 1至3為本發明含塗佈層之基質之不同具賴實例之圖 解剖面圖； 圖4為本發明之陰極射線管一具體實例之部分割視圖。 範例具體賁例1 圖1顯示基質2具有本發明之第一具體實例之反反射及 反靜電塗佈，該塗佈含一涸雙曆，該雙層含二氧化矽之反 靜電層4,及至少一個導電金属氧化物及一矽酸鋰之反閃耀 層6。 此種塗佈係依照本發明之下列方法製造。陰極射線管之 顯示蒂激底清洗，之後旋轉塗佈方式提供第一個及靜電層 。塗佈材料包含百分之二重量之在酒精中之四乙基原矽酸 (Si(C〇2Hs)4溶液，其中百分之一的1比0.15二氧化鍚 Sn〇2及三氧化二銻（Sb2〇3)之混合物作為導電材料而分散 。如必要時，塗佈材料可含染料，例如0.2 %重量之得自 .Merck之蔷薇紅B。在混懸液中所含之氧化金鼷顆粒及染 料之大小小於50η πΚ防止光擴散。該層在60 1C溫度下烘乾 ，其厚度在50 — 100 nm之間。 其次，第二個反閃耀層Μ旋轉塗佈方法提供。塗佈材料 含氧化鋰穩定之二氧化矽膠溶體於水中，水具有百分之二 固體含量之克分子比為8比1的Si02&LU0。該層之厚度 約為1000η»。其次，兩層均Μ溫度160 TC處理三十分鐘， 在處理中第一層轉換成二氧化矽，第二層轉換成矽酸鋰， 最後，顯示幕再Κ自來水清洗後烘乾。 本纸張又度適用中國國家標準（CNS)甲4現格（210 X 297公釐） --4 Τ 經濟部中央標準局員工消費合作社印哲 81.9.20,000 214014An ΗΓ) 21401 ^ V. Description of the invention (?) MTt '" " Backward :; 1 * Matter Ran Cheng wrote this page) The purpose is to provide cathode rays with anti-reflection and anti-static coating on the display screen tube. Another object of the present invention is to provide a simple and reliable method for manufacturing anti-reflection and anti-static coating. Therefore, the object of the present invention is to minimize the use of organic acids. The provision of a cathode ray tube with anti-reflection and anti-static coating on the display power is based on the anti-reflection and electrostatic coating mentioned in the first paragraph. The coating includes a layer of silicon dioxide and an anti-glare The double layer of the layer is made up, and the special feature of the coating is that the anti-glare layer contains lithium silicate. In a suitable embodiment of the present invention, the silicon dioxide layer is an antistatic layer that contains at least one conductive gold oxide. The transparent, conductive metal oxide is tin monoxide, monoxide, antimony monoxide and a mixture of the oxides. Its materials such as water materials and gold compounds and metal compounds, especially palladium compounds can be used to provide antistatic layers with the required electrical conductivity between. If necessary, materials can be added in the layer to change the optical, mechanical and other characteristics. Preferably, the silicon dioxide layer contains at least one dye. This is suitable because lithium silicate is added with a dye, because this layer is less durable after the dye is added. According to a second specific embodiment of the coating according to the present invention, in which the layers are provided in the reverse order of the first embodiment, the lithium silicate layer is located between the substrate and the = oxygen & silicon layer. A special example of the third coating of the coating according to the present invention is printed by an employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, in which anti-flash and anti-static functions are combined in a single layer. At least one conductive gold oxide oxide, this layer is located in the matrix and oxidized sand ± This paper scale is applicable to the gg family quasi (CNS) A 4 specifications (210 X 297 male cage) 81.9.20,000 Αβ Hi; 214014 V. Description of the invention (4) Between. The conductive gold-tallow oxide or other materials having conductivity may be the same as those in the silicon dioxide layer in the two specific examples above. In the third specific example, the purpose of the silicon dioxide layer is to ensure that the material added to the lithium silicate layer can be incorporated into it forever. If it is necessary to add additional materials such as one or more dyes in the second or third specific example of the coating of the present invention, the dyes can be added to each layer at will. In particular, a dye is contained in at least one layer of the double layer. In the silicon dioxide layer, the dye is permanently incorporated. The lithium silicate layer is covered with a K silicon dioxide layer, so that it can obtain an absolutely stable coating. If necessary, the coated substrate containing the present invention may be provided with an anti-reflective layer, which is well known to reduce special reflection and special diffuse reflection. For this purpose, a magnesium fluoride layer with a low refractive index can be used as the outermost layer, or many layers with high and low refractive indexes can also be used. The coating of the present invention can be added with a dopant to change its refractive index, especially in the silicon dioxide layer. Many layers suitable for reducing special reflections contain the first antistatic layer of sand dioxide and are additionally doped with titanium dioxide (refractive index 1.7) and second titanium dioxide layer (refractive index 2.1). The manufacturing method is similar to the method for manufacturing silicon dioxide ) And an outermost anti-glare layer of lithium silicate (refractive index 1.43) ° The thickness of each layer is 100 to 150. The purpose of the method of manufacturing an anti-reflection and anti-static coating is the method described in the first paragraph Achieved, the manufactured double layer contains an anti-static layer and an anti-blaze layer, the anti-static layer is used to supply at least one conductive metal oxide in the suspension of the alcohol solution of the silyl silane compound, and then to improve The temperature is treated with W to form a mixed layer of silicon dioxide and at least one conductive gold oxide oxide. Ben 6-This paper is also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 KM) ---- -------------------- Installed ------, 玎 ------ '% Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 81.9.20,000 Λ (ί Η »; 214014 Fifth, the description of the invention (5) ft: y, "; i :: ,,,,, and ,,,,,,,,,,,,,,,,,,, Wherein the anti-shock layer system provides shine prescribed lithium oxide ear melt silicone dioxide in water 'process then increasing the temperature to form a layer of lithium silicate. In contrast to the above-mentioned two specific examples of the coating of the present invention, the antistatic layer and the anti-glare layer can be provided on a substrate ', for example, in any order, on the display pedestal of the cathode ray tube. The third specific example of coating according to the present invention is modified. Another feature of the method according to the present invention is to provide at least one lead for the anti-blaze layer with anti-static effect therein. Stable suspension of silica gel solution in water, and then treated at elevated temperature to form a mixture of lithium silicate and at least one conductive oxidized gold oxide, and then manufactured by alcohol solution of M alkyl silane compound The protection layer then forms a silicon dioxide layer at an elevated temperature of K. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs According to the present invention, the silicon dioxide layer used can be manufactured by K according to the method disclosed in U.S. Patent Specification U.S. 4,945,282. According to the invention, this layer is used as an antistatic layer or a protective layer. It can be used for two purposes. It has a thickness of less than 200 nm, preferably a thin layer of 5 to 50 nm. By this method, the required reactivity and the amount of non-patidine alkylsilyl compounds and organic solvents can be reduced to those used in the technology. According to the present invention, the lithium silicate layer uses M as the anti-blaze layer. The lithium silicate does not contain individual particles. Therefore, it shows strong mechanical stress. In the US Patent Specification US 3,940,51 1, the anti-reflective layer of lithium silicate and the method of manufacturing the layer have been disclosed Conductive gold compound or dye. The method of the present invention combines the stupidity of known technologies and minimizes the disadvantages of each technology. 81.9.20,000 This paper scale is applicable to the Chinese National Standard (CNS) Grade A (21ϋ X 297, Sheng) 214014 V. Description of the invention (6) The present invention will be described in detail with examples and drawings attached: _ 1 to 3 is a diagrammatic cross-sectional view of different examples of the substrate containing the coating layer of the present invention; FIG. 4 is a partial cutaway view of a specific example of the cathode ray tube of the present invention. EXAMPLES Specific Example 1 FIG. 1 shows that the substrate 2 has the anti-reflective and anti-static coating of the first specific example of the present invention, the coating includes a dual calendar, the double-layer anti-static layer 4 containing silicon dioxide, and At least one conductive metal oxide and an anti-blaze layer 6 of lithium silicate. This coating is manufactured according to the following method of the present invention. The cathode of the cathode ray tube is cleaned, and then the first and electrostatic layer are provided by spin coating. The coating material contains 2% by weight of tetraethylorthosilicate (Si (C〇2Hs) 4 solution in alcohol, of which 1% is 1 to 0.15 strontium dioxide Sn02 and antimony trioxide The mixture of (Sb203) is dispersed as a conductive material. If necessary, the coating material may contain a dye, for example, 0.2% by weight of Rose Red B from .Merck. Gold oxide particles contained in the suspension And the size of the dye is less than 50η πΚ to prevent light diffusion. The layer is dried at a temperature of 60 1C, and its thickness is between 50-100 nm. Secondly, the second anti-blaze layer M spin coating method is provided. The coating material contains Lithium oxide stabilized silica dioxide solution in water, water has a 2% solids content of 8: 1 Si02 & LU0. The thickness of this layer is about 1000η ». Secondly, both layers have a temperature of 160 TC treatment for 30 minutes, the first layer is converted to silicon dioxide, the second layer is converted to lithium silicate, and finally, the display screen is then washed with tap water and dried. This paper is also applicable to the Chinese National Standard (CNS ) A 4 cash (210 X 297 mm) --4 Τ Employee of Central Bureau of Standards, Ministry of Economic Affairs Fee cooperatives Indian philosophy 81.9.20,000 214 014
Hf； 五、發明説明（7 ) (--^^-.^^之，；i'-莽項再塡寫本頁) 因而獲得之顯示幂已足可導電並能反靜電。在K特殊反 射之代價增加擴散反射可協肋抑制影像之干擾，如在顯示 蒂上之外光源干擾。 除了上述之四乙基原矽酸•其他Si(0R)4型烷基矽甲烷 化合物亦可作為備用•其中R為烷基群具有1至5之碳原 子。例如，亦可用甲酵作為溶劑。具有無櫬酸之少量水亦 可加在溶液中以提高轉換為二氧化矽之速度。在美國專利 規格No 1 945,282號中曾揭示適當之成分*其中亦提及適 當之導電金屬氧化物可用來加在反靜電層中。除了導電金 屬氧化物外，可用鈀，钛或金等化合物Μ獲得導電特性， 無見美國專利規格No.4,563,612號。在美國專利規格 No.3,940,511及No.4,563,612中亦揭示過如氧化鋰穩定之 二氧化矽膠溶體於水中亦為逋當之成分。 範例具體實例2 圖4圖解顯示一陰極射線管，含一玻璃包封31，具有顯 示窗32，錐部33及頚部34。在頸部備有電子槍35仍產生電 束36。該電束36聚焦在顯示幕37之上K形成一目標光點 38。電束36由偁掃線綣39横過顯示幕偏掃為互相垂直之方 向X — y方向。在顯示幂37上有發亮材料層（燐）。顬示 窗32之外備有反反射及反靜電層40，依照範例具賭實例1 之方法所造。 經濟部中央標準局員工消費合作社印製 範例具體實例3 圖2顯示一根據本發明之第二個具體實例之具有反反射 及靜霉塗佈之基質’該塗佈由一雙層姐成，該雙層含一矽 —9 - 81.9.20,000 本纸張尺度適用中as家標準（CNS)甲·4規格（2丨0 X 297公釐） Λ Η Η(； 214014 五、發明説明（8 ) 酸鋰反閃燿層16及一反靜電層14其二氧化矽14含至少一導 電氧化金靨。 此種塗佈係使用範例具體簧例1中之材料及方法所製， 但其中提供層之順序則相反。在提供氣化鋰穗定之二氧化 矽膠溶體層之後，該層Μ 60 "C溫度加Μ烘乾。在提供含烷 基矽甲烷化合物之層後，二層均在160 1C溫度下退大三分 鐘，之後顯示螢幕再Κ自來水清洗後烘乾。所得之结果與 範例具賸第例1所述者相同。 範例具體寘例4 圖3顯示一具有反反射及反靜電塗佈之基質，該塗佈含 有一雙層，雙層由一反閃皤及矽酸鋰之反靜電層26，矽酸 鋰包含至少一導電氧化金鼷，及二氧化矽之保護層28等姐 成。 此塗佈係由利用範例具體實例3中所述之材料及方法所 製，除了導電之金屬氧化物係懸垂於氧化鋰穩定之二氧化 .砂膠溶體之水中而非在烷基矽甲烷化合物之酒精溶液中。 所用之量，處理步驟及結果與具體賁例3均相同。 經由本發明，可用簡單而可再生之方式製造有效之塗佈 ，該塗佈可適合用於陰極線管之顯示幂上，並表現出滿意 之反閃耀及反靜電之特質，並展現其對四周之如潮濕及機 械損害之影響有滿意之抵抗作用。 裝------.玎------線 f ^t5T.w.背.5之;1-:&事項冉場寫本頁> 經濟部中央標準局員工消費合作社印製 -1〇 - 衣紙張仏適用中國因家辟（CNS)甲4規格（21〇 χ视^ 81.9.20,000Hf; Fifth, the description of the invention (7) (-^^-. ^^ ,; i'-mang then write this page) The display power thus obtained is sufficiently conductive and antistatic. Increasing diffuse reflection at the cost of K special reflections can help suppress image interference, such as light source interference on the display pedestal. In addition to the above-mentioned tetraethylorthosilicate • Other Si (0R) 4 type alkylsilyl compounds can also be used as backups • where R is a carbon atom with an alkyl group of 1 to 5. For example, formazan can also be used as a solvent. A small amount of water without tartaric acid can also be added to the solution to increase the conversion rate to silica. Appropriate compositions have been disclosed in U.S. Patent Specification No. 1 945,282 * which also mentions that suitable conductive metal oxides can be used in the antistatic layer. In addition to conductive metal oxides, compounds M, such as palladium, titanium, or gold, can be used to obtain conductive properties. No see US Patent Specification No. 4,563,612. U.S. Patent Specification No. 3,940,511 and No. 4,563,612 also disclose that the silica gel solution stabilized by lithium oxide is also an effective component in water. EXAMPLES Specific Example 2 FIG. 4 diagrammatically shows a cathode ray tube, including a glass envelope 31, with a display window 32, a tapered portion 33, and a mottled portion 34. An electron gun 35 is provided on the neck and still generates the beam 36. The beam 36 is focused on the display screen K to form a target light spot 38. The electric beam 36 is swept across the display screen from the scan line 39 to the mutually perpendicular direction X-y direction. On the display power 37 there is a layer of shiny material (燐). The display window 32 is provided with an anti-reflective and anti-static layer 40, which is made according to the method of Example 1. Printed example of an example of printing by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Figure 2 shows a second example of a substrate with anti-reflective and static mold coatings according to the present invention. The double layer contains a silicon-9-81.9.20,000 The paper size is applicable to the Chinese standard (CNS) A · 4 specifications (2 丨 0 X 297 mm) Λ Η Η (; 214014 V. Description of the invention (8) Acid The lithium anti-glare layer 16 and an anti-static layer 14 whose silicon dioxide 14 contains at least one conductive gold oxide. This coating is made using the materials and methods in Example 1 and the order in which the layers are provided On the contrary. After providing the silicon dioxide solution layer of the vaporized lithium sulfide, the layer is dried at M 60 " C temperature. After providing the layer containing the alkyl silane compound, both layers are retreated at 160 1C. Three minutes later, the display screen is then washed with tap water and dried. The results obtained are the same as those described in Example 1. Example specific example 4 Figure 3 shows a substrate with anti-reflection and anti-static coating. The coating contains a double layer, which consists of a flashback and silicon The antistatic layer 26 of lithium, lithium silicate includes at least one conductive gold oxide, and a protective layer 28 of silicon dioxide, etc. This coating is made by using the materials and methods described in Example 3, Except that the conductive metal oxide is suspended in lithium oxide-stabilized dioxide. The water of the mortar solution is not in the alcohol solution of the alkyl silane compound. The amount used, the processing steps and the results are the same as the specific example 3. Through the present invention, an effective coating can be produced in a simple and reproducible manner, which can be suitably used for the display power of a cathode line tube, and exhibit satisfactory anti-glare and anti-static characteristics, and show its surroundings Like the effects of moisture and mechanical damage, it has a satisfactory resistance. Install ------. 玎 ------ line f ^ t5T.w.back.5 of; 1-: & matters Ran field write This page > Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-1〇