TW205053B - - Google Patents

Description

205053 A6 B6 V. Description of the invention (t) [Technical Field] The present invention relates to a novel pre-stained compound, a composite shaped skull obtained by forming the pre-collapse Nuo and its preparation method. To further elaborate, the pseudo-element is a pre-stained body formed by a high-strength, high-elasticity film layer and a resin layer and / or iron-reinforced resin laminate layer, and the pre-stained body is formed and has a Significantly improved sun-shock resistance and improved to have superior isotropic strength. Compound pseudo-numerical shaped skulls. Among these shaped skulls, the method of making tubular or rod shaped bodies. [Background Technology] Thermosetting resins such as ring gas resins, phenol resins, and so-called fiber-reinforced resin composites reinforced with fibrous fibers, glass fibers, aromatic polyacetal (Araaid) fibers, etc., in particular, sulfon fiber-reinforced resins Composite materials, due to their superior specific strength and specific elasticity, have been widely used in fields requiring high strength, light weight, corrosion resistance, and other properties, such as aviation mechanism flat members, rackets, golf club shafts and other lotus Animal supplies, etc. On the other hand, reflecting recent technological advances, composite materials are required to have multiple energy functions. The long iron-dimensional reinforced composite material represented by the sulfonated fiber reinforced ring gas resin generally lacks the properties and therefore has poor impact properties. Once fractured, the reinforced ore dimension will reveal a finely divided sharp fracture surface, which has these shortcomings. As a means for overcoming the aforementioned problem of sun-shock resistance, there are proposed alternate layers (In Ter No. 3472730, Japanese Patent Laid-Open No. 60-63229, and Japanese Patent Laid-Open No. 60-231738, etc.). leave) composite material. Among the earliest of these publications, USP3472730 shows that it will contain A4 (210X 297 male eaves) (please read the precautions on the back before filling this page). Install · Order · Line, 3 2〇 δ〇〇3 Α6 Β6 V. Description of the invention (2) The ring gas resin with a mash-like substance is arranged in the sulfonate fiber-reinforced ring gas resin layer as an alternate layer user. However, the problem is that the spacer layer exhibits softening fluidity at the curing and forming temperature, so it is difficult to form a uniform layer, or even alternating layers disappear. In order to solve this problem, Japanese Patent Laid-Open No. 60-63229 provides a technique that can control the viscosity of an alternating layer resin made of an oxygen-containing resin containing a rubber-like substance to a specific range. The No. Gazette shows a technique of supporting alternating resin layers with non-woven fabrics. The basic idea of these alternate layer technologies is that, as shown in each of the specifications, the resin layer with greater elongation, that is, the soft resin layer, is arranged alternately with the fiber-reinforced resin layer, so that The deflection, shear energy or fracture energy of the composite material when deformed can be attracted by the deformation of the interstitial resin layer. With these conventional techniques, although the problem of sun-shock resistance can indeed be improved, however, the strength and elasticity of the composite material that can be obtained, that is, the strength of the molded body, is lower than that of the molded body without alternating layers. The major problem is that it has not yet reached a satisfactory level in terms of forming a uniform resin layer as an alternating layer. Alternate layer technology is a pseudo-use of thermoplastic resin film and rust is proposed. Japanese Patent Laid-Open No. 60-231738 shows an alternating layer of thermoplastic resin, among which the use of polyetherimide, polyether ether ketone, and polyacrylic acid resin-made film as the alternating layer的 实施 例。 Examples. In addition, in recent years, there has been a technique of using a polyimide resin film with a specific structure and applying a subsequent layer as an alternate layer. Please read the precautions on the t side before filling out this page. Order. • Line · A 4 (210 to 297 common eaves) A6 B6 2050〇3 V. Description of the invention (3) It is shown in Japanese Unexamined Patent Publication No. 64-129, holding Japanese Unexamined Patent Publication No. 64-87246, etc. In the technology disclosed in Japanese Patent Laid-Open No. 64-129, etc., the effect can be obtained by using alternating layers of thermoplastic resin. One of the important factors is that the molecular structure of the polyimide must be selected to increase It can be seen from the stretchability of the large film that these technologies are still based on the aforementioned alternate layer technology, that is, the technology to improve the ketone impact by introducing a soft structure. Due to the use of these thermoplastic resin alternating layer technologies, uniform alternating layer formation can be achieved. Furthermore, the technology disclosed in Japanese Patent Laid-Open No. 60-231738 still cannot avoid the reduced strength compared with the forming layer with no alternating layers. The technology disclosed in Japanese Patent Laid-Open No. 64-129 can be borrowed The polyimide film with greater deformation performance uses the bending strain of the composite material under plaque force absorption, and as a result, the composite material can increase the value of the fracture deflection, so that a composite material with improved resistance to cracking can be obtained. However, by introducing a soft structure to increase the strain value under a given stress, in other words, to reduce the Zen pseudo-number, this will sacrifice the elastic pseudo-number, which is one of the excellent characteristics of the Yen Tie-dimensional reinforced resin composite material. Other issues of fiber-reinforced resins are anisotropy in mechanical properties and dimensional stability. It is generally known to improve the anisotropy by applying a laminate in which the orientation direction of the reinforcing fiber is changed so as to achieve a pseudo-equalization method. However, according to this method, it takes a lot of time and labor from cutting out the pre-stained body to accurately superposing. In addition, another conventional method is to randomly orient the reinforcing fibers cut into appropriate lengths and then process them into a mat shape, and impregnate them with a matrix (Matr ix) resin to make them into shaped bodies. Method, but this method cannot fully exert the inherent function of reinforcing fiber. A4 (210X297 Gong Peng) (Please read the precautions on the back before filling in this page) • Installed. Line. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 5 _0b3 A6 B6 5. Description of invention (4) To solve this problem, A possible method is to use a film with uniform physical properties in the plane direction as a reinforcing material, but in general the strength and elasticity of the film are both one yard or more smaller than that of the follow-up. Therefore, it is considered that the use of the film as the so-called reinforcement is not Appropriate, this is the common sense of the industry. The most basic compound representing the strength and elasticity of the composite material is shown in the following equations (1) and (2).

Ec = Et. Vf + Em · Vm …… (1) σε = af * Vf + * Vm ...... (2) Press, Ee: the elasticity of the composite material is σ. ： Strength of composite material Ef: Elastic image number of reinforcing material: Strength of reinforcing material Em: Elastic Dai number of basal condyle resin: Strength of matrix resin

Vf: Volume content rate in the composite material of the reinforcing material Vm: Volume content rate in the composite material of the base condyle resin (vf + vm = 1) From the equations (1) and (2), if the resin is constant, then The physical properties of the composite material are also determined by the elastic image number or strength, which will be greatly affected by the physical properties of the reinforcing material. The reason why the film is not considered as a reinforcing material can be more clearly understood. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs. In summary, the above-mentioned alternating layer technology can be used as an example of using a film as a reinforcing material for a composite material to improve the physical properties of a molded body. The technology of elastic pseudo-number and strength, which is the biggest characteristic of composite materials, is appreciated. δ {Please read the precautions on the back before filling out this page) A4 (210X297 eaves) ^ 05053 Α6 Β6 Printed by the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (5) [Invention of the invention] The present invention is based on the above shortcomings The completed, that is, a method of joining a high-strength * high-elasticity number of films and a resin layer and / or iron-dimensional reinforced resin layer, which has been developed in recent years by a stack, provides a useful novel pre-crushed body And composite forming buns. That is, the first object of the present invention is to provide a pre-stained body composed of a high-strength, high-elasticity pseudo film and a resin layer laminated to obtain a high-strength, high-impact composite material . The second object of the present invention is to provide one or more high-strength, high-elasticity pseudo-numerical films and more than one layer of fiber-reinforced resin layer laminated to obtain high strength, high elasticity, high resistance It is a pre-stained composite material of impact. A third object of the present invention is to provide a tube-shaped or rod-shaped shaped body formed by rolling the pre-stained body. A fourth object of the present invention is to provide a plate-shaped molded body formed by laminating and molding the aforementioned pre-stained body. The fifth object of the present invention is to provide a method for forming a tubular body or a rod-shaped body by winding a fiber-reinforced resin and then winding it on the outside to join a high-strength, high-elasticity pseudo-number film and resin By. The first object of the present invention is at least one film made of an organic strip polymer that does not substantially have a melting point and has a tensile zeniness coefficient of 700 »« / «^ or more and a tensile strength of 35kg / mm2 or more, A pre-stain made of at least one resin layer and the film and the resin layer are joined together (please read the precautions on the back before filling this page) A 4 (210X297 common eaves) 7 205053 a6 B6 5. Description of invention (a). The second object of the present invention is to be formed by an organic polymer that does not substantially have a melting point and has a tensile strength of 700 kg / mm8 or more and a tensile strength of 35 kg / # or more, at least one film, and at least A pre-fracture made of a woven-strengthened reinforced resin layer formed by joining the film and the fiber-reinforced resin is thus achieved. The third object of the present invention is to form a tubular shaped body formed by at least one film and at least one resin layer and / or braid-strengthened resin layer, wherein the aforementioned film strip is composed of an organic strip polymer having substantially no melting point A tubular body with a tensile elasticity of 700 kg / # or more and a tensile strength of 35 kg / Bin2 or more, which is bonded to each other by the aforementioned film and the resin layer and / or fiber-reinforced resin layer, is so achieved. The fourth object of the present invention is to form a plate-shaped molded body formed by at least one film and at least one resin layer and / or fiber-reinforced resin layer, wherein the aforementioned film is composed of an organic strip polymer having substantially no melting point It is made of a plate-like body with a tensile elasticity of 700kg or more and a tensile strength of 35kg / uni2 or more. The film and the resin layer and / or the fiber-reinforced resin layer are laminated on each other. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) • Hit the line. The fifth object of the present invention is to be essentially made of a polymer of organic strips that does not have fusion bonding, and At least one thin sheet with a tensile strength of 700kg / · # or more and a tensile strength of S35kg / n # or more and at least one layer of gauze-strengthened tree waist layer are wound and laminated into a tubular body. The method of making tubular pus with a pulling force of 8kg / # or more applied to the film while winding the aforementioned film is so successful. A4 (210X297 public love) 8 2050 ^ 3 A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (7) [Best form of invention] Η Detailed description of pre-stained body and composite molded body using high-performance film And the manufacturing method of the tubular shaped body. First, the requirements for the "film j mole" will be described. The "film" of the present invention is made of an organic strip polymer having substantially no melting point. Here, "substantially no melt adhesion j" means that the temperature range from room temperature to 400T! Will not separate, melt or soften the deformation. This is, for example, when a combined thermosetting resin is used for curing and molding, or, When combined with a thermoplastic resin with a high melting point and heated to melt and press-form, "the film is not subject to deterioration, deformation, melting, decomposition, etc. due to heat. It can be classified as such an organic polymer, for example, aromatic polymer Acetylene, polyimide, polybenzazole, polybenzobisthiazole, etc., but based on the good or bad connection with the resin and the difficulty of finding high strength and high elasticity, the aromatic polyamide And polyimide is suitable, in particular, aromatic polyimide is preferred. Aromatic polyamines with better effects are constructed by the following general formulas (I), U), or these -(-CR, -C-NII-Rz—Nll-^-m (I) II II ο ο or + C-R3 —Ν 丨 丨 十 m (Π) IIο where R ,, RZ and R3 is from — (〇) — »— (〇) 一 (〇) ~.-— -G — A4 (210X297 public broadcasting) (Please read the note on the back first Please fill in this page again for details) • Packing • • Ordering • • Lines • 205053 A6 B6 5. Description of the invention (8) is selected, these hydrogen atoms can be replaced by halogen, methyl, ethyl, methoxy, nitro, Substituted by functional groups such as milling groups. Η is the average degree of polymerization of about 50 to 100. In addition, polyimide, for example, can be used by compounds represented by the following formulas for better results. 0 0

{Please read the precautions on the back before filling out this page) • Packed. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs

• Order.-Line. 肀 4 (210X297 W eaves) 10 ^, 050 ^ > 3_ί a,: d Printed by the Ministry of Economic Affairs 屮 央 榀 斀 局 employee 消 # Cooperative Society • V, .. / V. Description of invention (y ) η is the average degree of polymerization, about 30-500 〇Polymimide glass transition temperature is 2 8 5 ~ 5 0 0 〇 This factory film J 1 such as aromatic polym amine film 1 can be borrowed Patent Unexamined Patent Publication No. Sho 57-1 -1 7 8 8 6 and Unexamined Patent Publication No. 62 -19270 Unexamined Patent Publication No. 62 -3 7 1 24 N Unpublished Patent Publication No. 62 -1 74 11 No. 3 The obtained polyimide film can be obtained by the method shown in Japanese Patent Laid-Open No. 55-28822, etc. 0 plant film J can also be contained in a small amount of the above-mentioned organic matter without affecting the effect of the present invention. Ingredients other than Shito polymer »For example, may contain a small amount of organic Shito polymerization certificate other than the above, organic% low molecular weight compound, none Machine compound, etc. Factory film J can be made of m (C 〇m P 〇 si te) products whose tensile strength in the necessary direction to increase the tensile strength and tensile elasticity of the so-called stretch type 0 However,> The advantage of the factory film J 1 with equal properties is that it has the advantages of less mechanical direction and dimensional stability of the resulting molded body. In the present invention, at least one direction of tensile strength and tensile elasticity coefficient satisfies the foregoing The value can be 1 as long as any jae. The average value of the mutually orthogonal 2 tilt directions selected is preferably satisfied with the aforementioned value. In the present invention, in order to make the reinforcement effect sufficiently found »Between the film and the resin Then the force should be very large. 0 The very large adhesive force can be achieved by the following method. The preferred method that can be used is t. For example, the method used in the film-forming project »or by physical or chemical after film-forming Etch (Et C hi ns) and other treatments to make the surface of the film or thin strip (T ape) thicker> by corona discharge treatment, plasma treatment flame treatment chemical decomposition, etc. to introduce chemically activated species into the surface 9 borrow gas Compound isocyanate m Compound, resorcinol • A liquid m ♦ Milk m Mixture order-line 1 (please read the back and forth precautions #Fill the page this page '装-This paper size is easy to use (CNS) A 4 specifications (210x297 male dragon) IT Zhengyu 81. 7. 20,00 () ¾ (II) A6 B6 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs V. Description of invention (i〇) for subsequent use Pre-dipping treatment, or a combination of these methods. The "thickness of the film J in the present invention is determined by considering the structure of the laminate with the resin layer or the fiber-reinforced resin layer in the molded product. The thickness of the" film "is usually 2 ~ 100we, preferably For 5 ~ 50 «. 2wm or less or 100wi or more is not easy to handle, and it is difficult to control the ratio of the film layer in the pre-preg and the molded body obtained by lamination, so it is not appropriate. Secondly, the "film" must have a tensile strength of 35 kg / · ™ 2 or more and a tensile elastic pseudo-number of 700 kg / b # or more. In particular, it is preferable to have a tensile strength of 45 kg / * # or more and a tensile elastic image number of 1000 kg / nun2 or more. As mentioned above, the strength and elastic pseudo-numbers of composite materials can be generally expressed by equations (1) and (2). Therefore, in order to obtain a composite material with high physical properties, "the physical properties of the film j must be very high. However, it should be noted, especially when it is combined with the woven reinforced resin. For example, the 0-degree resistance of the dimensional reinforced resin laminate Bending strength and elasticity, for example, as shown in the comparative example described below, are 128kg / # · 6900kg, which can be compared with the elasticity of the above "film". Therefore, in particular, the elastic supply will be reduced in proportion to the volume content of the introduced film, which is a thin film that is outside the scope of the present invention, that is, a film with a low flexibility of less than 700kg / «1, Correctly, this phenomenon was observed (Comparative Example 5). However, it is extremely unexpected that in the present invention, as shown in Example 12, although the ratio of the sulfonate fiber-reinforced resin layer (CP resin layer for short) was reduced, no decrease was observed (Experimental Example 8). If converted by the ratio of the CF resin layer, the bending strength and the elastic coefficient can be improved by about 10% or more. The same applies to the 90-degree bending elastic pseudo-number. In addition, the anti-midge strength is a film (please read the precautions on the back before filling in this page) • Binding · Ordering · Line. A 4 (210X297 Eaves) 12 The Central Bureau of Economic Affairs of the Ministry of Economic Affairs cracked A6 B6 V. Description of the invention (il) The greater the strength, the greater the increase. When the strength of the film satisfies the requirements of the present invention, it is known from the circumferential bending strength of the tubular molded body that its value will play the role of the so-called oblique stack with the CF resin layer The effect equal to or higher (for example, Experimental Example 16 and Comparative Example 2). Generally speaking, in polymer materials, the physical properties change according to the degree of molecular bond orientation. The greater the elasticity of the orientation progress, the lower the elongation at break. The elongation of the film used in the present invention is, in fact, much smaller than the film used in the alternate layer technique described previously. However, the "Izod" rigid impact strength and the impact energy absorbed by the drop weight can be obtained with comparable values, which is also worth a special book. That is, when "the film j meets the requirements of the present invention, a composite material excellent in strength, elasticity, and impact resistance can be obtained, which is compared with the alternating layer technology implemented by the conventionally known high-elongation soft structure, It is necessary to understand that it is a completely different technical idea and even the effect obtained is completely different. Next, the resin and fiber-reinforced resin used in the present invention will be described. The thermosetting resin used in the present invention is not particularly limited, for example, It can be selected from ring gas resins, phenol resins, polyimide resins, polyester resins, etc. Furthermore, ultraviolet absorbers, flame retardants, anti-gasification agents, slip agents, colored steel, etc. can be added to these resins Thermal stability planning, anti-aging agent, reinforcing short fiber, reinforcing powder and granules, molding agent, thermoplastic resin, elasticity (Elasto ^), rubber-like, other general resin addition and cutting. The thermoplastic used in the present invention The resin is not particularly limited, for example, it can be polyolefin, polyester, polyamide, polyacrylate, polycyanate, etc., but from (please read the precautions on the back before filling in Page) • Installation · • Line · Sorry 4 (210X297 Gong Hun) 13 A6 B6 5. Description of the invention (1) (Please read the precautions on the back before filling in this page) W thermal or usable temperature of the obtained molded body From the perspective of other perspectives, the super engineering plastics (Super engineering plastics) -classes have better results. Examples of such are Polysulfone, Polya * ideUide, Poly Etherimine, polyether_, polyetherether_ (Polyetherethrketones), polyamines, polyphenyl compounds etc. When using these resins, for example, they can be used in the form of a solution or dispersion of an appropriate solvent and heated to It is melted and used. In addition, as long as it can be formed into a film, it can also be used directly by laminating the film. In this case, the film is subjected to surface treatment by a conventional method, such as Xiaoyu discharge treatment, plasma treatment, etc. It is also effective to improve its adhesiveness. The reinforcing fibers used in the present invention can be: glass fiber, fiber, aromatic polyamidite, polybenzazole fiber, polybenzoxazole fiber, Or, for example, a shovel Those who have applied Jin Jin coating to them, including inorganic fibers such as alumina fibers and sulfonated silicon fibers, are also included, and two or more of these compounds can be used in combination. Unidirectionally straightened sheet shape (UD sheet), or used in the form of suspects or edited suspects, especially if the required is an isotropic mechanical physical property, it can be cut into suitable The flute-length fibers are used in the form of non-woven fabrics or mats. The iron standard reinforced resin layer printed by the Central Standards Bureau of the Ministry of Economic Affairs can be used, for example, impregnated in the above-mentioned reinforced dimension UD Η and suspected fabrics, non-woven fabrics or mats. After using the resin solution or dispersion, the method of removing the solvent by heating, the method of impregnating the resin melted by heating, or the resin pre-formed into a film shape under heating, the layer impregnation method, etc. Technology manufacturing.

U A4 (210X297 male eaves) A6 B6 V. Description of the invention as) The ratio of reinforcing fiber to resin can be appropriately selected according to the shape of the reinforcing fiber sheet and the type of reinforcing fiber, usually, to reinforce the volume of the following dimension The rate of 40 ~ 70¾: the field is better. The pre-crushed body of the present invention is composed of the above-mentioned "film j and resin and / or fiber-reinforced resin layer. The first aspect is that it is substantially composed of an organic strip polymer having no melting point and having 700 kg / * At least one film with tensile strength above 35kg / »# and tensile strength above 35 is formed with at least one resin layer, the film and the resin layer are joined together, and thus the pre-crushed body is formed. "Thin film J itself has almost no thermal fusion and thermal warmth, so the pre-prepared body has a structure in which" film "and resin are alternately laminated as shown in Figures 1 and 7. The pre-crushed body is included regardless of whether the "film" and the resin are joined one by one or one layer at a time, or each one is joined by a plurality of layers or a plurality of layers, and its shape can also be thin Η, plate, tube The shape is not particularly limited. In addition, the resin is a thermosetting resin, which is used as a pre-stained body in the state where the resin is uncured or semi-cured (the stage B), and the thermoplastic resin is formed by reading before the final product is obtained. The state of use of the material is marked as a pre-stain. Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs in the pre-stained body obtained by joining the "film J and the resin layer, the ratio of the film to the resin, as long as it is the" product of the film j in the molded body is taken from 40 to 95 X If it is not "8 40 Χ, you will not be able to obtain the forming properties of sufficient physical properties, and when it exceeds 95 Χ, it is difficult to shovel. It should be 60 ~ 903; preferably, the range of 70 ~ 85 Χ Even better. The second aspect of the pre-stain is that it consists essentially of organic armor 4 (210X297 common eaves) that does not have a melting point (please read the precautions on the back before writing this page) Τ5 A6 B6 2〇5 〇i3b V. Description of the invention (ΙΛ) (Please read the precautions on the back before filling in this page) The polymer is made and has a tensile strength of 7〇〇te / · ® " above 35kg / e # The at least one film with the above tensile strength is formed of at least one iron-reinforced resin layer, and a pre-preg is formed by joining the film and the fiber-reinforced resin layer. The second pre-preg is: For example, as shown in the second country to the sixth country or the eighth garden to the tenth regiment, various laminated structures can be used. That is, there are "thin film" and Join one or one layer of pre-stained structure with the simplest structure in the two layers of the dimensional strengthening tree (2nd circle); join a plurality of "pre-stained bodies of thin film J (3rd and Figure 8 > "Thin_" layer is bonded to the pre-preg of the fiber-reinforced resin layer (inner layer) (Figure 4_>; "Film" layer is bonded to the pre-preg of both sides of the fiber-reinforced resin layer ( Fifth and ninth plaques; a fiber-reinforced resin layer and a "pre-crushed body in which film J is alternately joined (6th and 10th plaques); etc; Included in the pre-stained body of the present invention. The pre-stained carcass of the present invention can be constructed into these various structures and used to obtain extremely superior effects as shown in the experimental examples. The present invention is only useful when the adhesion is limited to interactive lamination The aforementioned alternating layer technology is used as a dividing line, and it is a technology that can be widely used in 81. Figures 7 to 10 show the layers, that is, the "film", resin layer and / or fiber reinforced resin layer The laminated structure is a concentric structure to explain it. However, the structure of the tubular body is often rubbed Each layer is a spiral laminated structure wound by each layer or multiple layers. When the Central Bureau of Standards of the Ministry of Economic Affairs prints a plurality of "Film J as a layer and joins, it is falsely used" Film J penetrates the resin and is The jointer. The resin can be different from the matrix resin of iron-dimensional reinforced resin, but due to the advantage of being moldable under the same conditions, A 4 (210X297 common eaves) 15 2050〇c5 A6 B6 V. Description of the invention (15) It is better to use the same resin. When the base of the mineral-dimensional reinforced resin is a thermosetting resin, the uncured or semi-cured state is the pre-stained body; when it is a thermoplastic resin, it can be used as the final product. The state of the material used is a pre-stained body to make a plaque. In addition, in the pre-stained body obtained by joining the "film j and the iron-dimensional reinforced resin layer, the integral rate of the thin skeleton to the whole shape of the skeleton is taken to be between 5 and 50X, of which 10 to 30¾ is preferable. Because it is less than 5X It can only obtain a molding sump that does not satisfy the impact improvement effect of W. On the contrary, if it exceeds 50X, the rigidity of the molded body is reduced. The molded body of the present invention is composed of at least one film and at least one resin layer and / or A tube-shaped molded body made of a fiber-reinforced resin layer, in which the aforementioned film is made of an organic bar polymer skeleton having substantially no melting point, and has a tensile elastic image number of 700 kg or more and a tensile strength of 35 kg / iff18 or more , A tubular body in which the aforementioned film and resin layer and / or fiber-reinforced resin layer are laminated to each other, and a plate-shaped shaped body formed by at least one film, and at least one resin layer and / or iron-dimensional reinforced resin layer , Where the aforementioned film is made of an organic bar polymer which does not substantially have a melting point, and has a tensile elasticity of 700 kg / # or more and a tensile strength of 35 kg / # or more, the aforementioned film and resin layer and / Fiber-reinforced tree The layers are layered on top of each other. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in this page) The molded body made of "film j resin layer and / or fiber-reinforced resin layer" The laminated structure is the same as the pre-prepared body. That is, the structure where the "film j and the resin layer is a ΓΒ film" and the resin layer are alternately joined, and the "film" and the iron-reinforced resin layer are formed The body is, for example, Figure 2 A 4 (210X297 public transmutation) 17 Α6 Β6 ^ 〇5〇ϋ3 V. Description of the invention (1Λ) ~ Sixth circle, Figure 8 ~ Circle 10 have various structures. For the molded body, when the base resin of the resin layer or fiber-reinforced resin layer is thermosetting, the resin has been heated and cured to be shaped into the desired shape; if it is a thermoplastic resin, it is in the resin At a temperature above the melting point, the product obtained by shaping the desired shape is distinguished from the pre-stained body. The cross-section of the tubular body of the present invention can be, for example, a variety of shapes such as a country shape, a squint shape, a polygonal shape, a straight pipe with a certain diameter, or a curved pipe, a push-out shape, and the diameter and wall thickness are Local changes are also included. A special example is the use of a rod made of resin or fiber-reinforced resin as a chess set during molding, and the solid rod shape obtained by combining the mold with a synthetic product is also included. The plate-shaped body of the present invention includes, in addition to the so-called flat plate, those with a cross-sectional shape such as an L-shape, an H-shape, and the like, and a shape that is wholly or partially curved like a reflector of a parabolic antenna. In addition, the forming process of the present invention also includes a shaped body formed into a tube by the so-called rolling H method and the like, a pre-stained shape cut into a thin band, and a plate shaped body obtained by laminating without gaps, in parallel or A tube-shaped shaped dish obtained by winding a thin pre-stained body at an angle. Next, the preparation method of the pre-stained skull and the formed tattoo of the present invention will be described. The pre-stained skull and shaped condyle of the present invention can be manufactured by various methods. (1> Pre-fracture of laminating and joining a film and a resin. A. "Film" / Precursor of thermosetting resin. For example, at least one side of the film of the present invention uses a fixed thickness applicator 4 (210X297 ) (Please read the precautions on the back before filling out this page) • Installed • • Ordered • • Line. Τ8 2050 ^^ A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention Instructions (17) (Doctor coater) and other coatings The solution or the solution of the thermosetting resin is heated as necessary, and can be used to produce a so-called B-stage film-like prepreg with the simplest composition of the film and the resin laminated layer according to each layer. For example, a strip-shaped pre-stained body with a width of 50 m or less; or a sheet-shaped pre-stained body with a width of 500 m or 1000 m for use. In addition, the pre-stained body can be used directly in one layer, or can be pre-made for multiple layers It can be used with a pre-stained body of appropriate thickness. It can also be made into a tube-shaped pre-stained body by pulling out the pin mold and rolling out a single layer of pre-stained body for the pre-rolling of the pin mold to be demolded. Very high number and tough "film", the pre-stained body For processing, the so-called hand lay-up can be easily performed. B. "Film" / pre-preparation of thermoplastic resin This pre-precipitation is, for example, the same as a, which can be applied by the "film j coating thermoplastic resin solution" It is made by the method of melt or melt. In addition, the thermoplastic resin is formed into a film from the state of the melt or solution, and then heated and pressed with the "film" and other methods can be used to produce the "film" and the thermoplastic resin layer is joined by each layer In addition, the obtained pre-preserved body is laminated with a plurality of layers by heating and pressing, so that a pre-prepared body for joining a plurality of "films" and thermoplastic resin layers can be manufactured. Also, multiple sheets can be alternately laminated at this time. "Film j" and a thermoplastic resin film, and then, for example, a plurality of films and a thermoplastic resin film are joined by a hot press, etc. (2) A pre-prepared body joining a "film" and a reinforced resin layer a. "Film" / fiber Reinforced heat-curable resin pre-preparation body For example, the pre-preg body can be manufactured by pressing the fiber-reinforced heat-curable resin pre-preparation body of section B with "film j." (Please read the back Please fill in this page if you need to.) • Installed • • Ordered • • Fate • A 4 (210X297 膻) 19 A6 B6 printed by the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (18) Thermosetting resin in molten state, or use A solution or a mixed solution of an appropriate solvent is applied and heated to remove the solvent, and then manufactured by the method of pressing with the reinforcing fiber sheet under heating. The pre-preserved body can be formed into a plurality of layers by using a laminator (Lamina ter), etc. The laminate is used to manufacture a pre-prepared body with a large thickness. In addition, the pre-prepared body and the fiber-reinforced thermosetting resin pre-prepared body are bonded on one side of the "film" in advance, for example, using a laminator etc. Overlap can be used to produce pre-stained bodies with various daytime structure, such as lamination by winding around a stainless copper pin mold, and tubular pre-stained bodies can also be manufactured. The pre-stained body joining "Film J and fiber-reinforced thermosetting resin" can be used to reinforce the "film" due to its large elastic pseudo-number, so it is extremely easy to handle. It is due to the fact that it is joined to the so-called UD pre-stained body that aligns the fibers in one direction. When it is processed, it can be cracked or split along the fiber direction, and the manual lamination can also be easily implemented. . b. "Film" / thermoplastic resin pre-precipitation body For example, this pre-precipitation body can be used to make fiber-reinforced thermoplastic resin H and "Film J are heated and fused at a temperature above the melting point of the resin, or" Film j and pre-formed The film-shaped thermoplastic resin and the reinforced fiber sheet are manufactured by heating, pressurizing, and joining at a temperature above the melting point of the resin. The pre-stained hair fiber-reinforced thermoplastic resin is pre-bonded with one piece of "film" and one layer of thermoplastic resin layer. The stained body can be laminated and joined by, for example, a laminator or the like, whereby pre-stained bodies having various laminated structures can be manufactured. (3) Tubular shaped body The tubular shaped body is, for example, a preformed body shown in (1) and (2) wound around a rod-shaped pin mold made of stainless pins of various cross-sectional shapes and subjected to heating and curing to form a nail 4 (210X297 Gongchu) (please read the precautions on the back before filling in this page). Install. • Wire. A6 B6 5. Description of the invention α9) Melt and shape by heating, so you can get it. In addition, for example, a pre-prepared cylindrical pre-stained pot can be placed in a copper mold of a desired shape, and the inside can be manufactured by heating while applying pressure. In addition, for example, a rod made of a woven-strength reinforced resin made by drawing may be used as a mold for winding a pre-stained body, and cured in this state, so that a solid rod-shaped molded body can be obtained. Furthermore, after winding the tapered dimensionally-strengthened resin layer with the stainless steel pin wedge of the various cross-sectional shapes mentioned above, at least one side of the "film" can be wound with a ribbon-shaped prestained crossbond wound into a spiral shape and joined. It is manufactured by the method of thermoforming. In this forming method using the Taping method, in the tape joining process, the tensile force imparted to the strip-shaped pre-preparation body is extremely important for obtaining a good molded body, so it is necessary to maintain the tensile force in the "film" Each cross-sectional area is more than 8 kg / niif. It is better to keep above 10kg / · #, Wkg / m # is even better. For example, when it is wound with a tension of 8 kg / B # or less, the adhesion between the stacked layers is not good, and delamination is likely to occur, so that only a molded body with insufficient physical properties can be obtained. In addition, the constituent elements in the molded body may easily cause wrinkles, which may cause physical properties to be reduced, and the appearance is not good. It is presumed that the film is wound with high tension to not only make the dimension-reinforcing resin layer strong during forming, but also the film can be tightly bonded to make the base resin uniformly distributed evenly, and it can still be left on the thin shell after forming. The binding force of the stress exerts the effect of suppressing the change of the shape of the molded body due to the applied load. A 4 (210X297 public love) (please read the precautions on the back before filling in this page) • Install · • Line-21 3 ϋ ο ro ο 2

AB The Ministry of Economic Affairs Central Standards Bureau prints five. Description of the invention (20) The above-mentioned preparation method is the fifth invention of the invention, in which "thin J should be a high-strength and high-elasticity pseudo-number. Molding is also very important. (4> Plate shaped skulls, for example, put the pre-stains shown in (1) and (2) into a pin mold of the desired shape, and pressurize at the curing temperature of the thermosetting resin Under solidification molding, or melting and molding at a temperature above the melting point of the thermoplastic resin, this can be used to obtain a plate-shaped molded body. By selecting an appropriate pin mold shape and a method of laminating the pre-stained body, in addition to the so-called flat plate The zigzag shape of the L-shaped and H-shaped cross-sections of the manufacturing tool, and the molded body with a curved shape partially or entirely, these are included in the plate-shaped molded body. In addition, when forming, except once In addition to pre-preformed body reshaping, a method of directly laminating "film j, resin film and / or reinforced iron dimensional H into a pin mold and then heating and pressurizing. As described above, according to the present invention The formed body of the obtained composite material, which It has excellent physical properties such as unprecedented strength, elasticity, W impact, etc., and it has excellent characteristics such as vibration absorption, light weight, corrosion resistance, and easy forming processability. It can be widely used in golf club shafts, fishing rods, ski poles, tennis and badminton racket frames and other sports equipment, as well as bicycle frames, automobiles, ships and other outer plates and structural members, and furthermore, rockets The fields of aerospace, structural materials for aircrafts, structural members for space stations (Station) and other aerospace fields. The comprehensive description of the present invention refers to the "methods for measuring the physical properties of film j and molded bodies as follows. (Please read the precautions on the back before filling in This page) .Installed _ .Organized • • Wire armor 4 (210X297 Gongchu) 2050 ^ 3 A6 B6 Printed by the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (¾l) a · Tensile tensile elongation and elastic pseudo-number of the film Using a fixed-speed elongation type with high elongation (fixing machine (Autograph DSS-500 model manufactured by Shimadzu Corporation), cut a rectangular sample 100m X 10 «whose thickness is measured by dial gauge (Dial gage), and hold the length 30μ for the first time ",Pull The elongation rate of 30 ·· / min makes it draw a load-strain curve, from which the tensile strength TSikg / ·! #), Elongation at break TEX, tensile elastic pseudo-number Mi (kg / # > 〇P TS =-lot see TE --- X 100 30 Pi 30 Mi --- xl〇t ϋ i Press, P: tensile breaking load (kg) t: film thickness (M > A: tensile breaking strain (M >; Pi: the linear part of the load-strain curve, the load at strain Jli b. The tensile strength and elasticity of the plate-shaped molded body; the plate-shaped shape obtained by forming the β-layer "film" and resin together Cut out a large sample with a width of l〇m and a length of 150 «·, and then use push-out glass fiber at both ends (please read the precautions on the back before filling in this page). Install. • Order · • Thread · A4 (210X297 g) A6 B6 2〇5〇i> 3 V. Description of the invention (Suppression) Reinforced resin label (Tab) (length 50m) as the test Η. The aforementioned test piece was set in a universal testing machine (trade name, Autograph AG-10 model manufactured by Shimadzu Corporation with a clamping chamber of 50 ··) at a tensile speed of 〇5βι / in and obtained from the obtained load curve; Strong / Μ2), breaking strain (%), tensile properties are all EτΟϊκ / βππ2). Ρ στ =-·

Wt £ ε τ-X 100 50

Pi 50 Ετ =-*-

Wt ϋ i Press, P: tensile breaking load (kg) t: test Η thickness (m) W: width of the test piece (》 > g: tensile breaking breaking mole change (u)

Pi: The straight part of the load-strain curve, the load at the strain Jli (kg > c. Axial compressive strength: a test piece with a length of 13 «was cut from the tubular shaped body, and a universal testing machine manufactured by Shimadzu Corporation (trade name) Autograph AG-10 type), compress at a compression speed of 1 «· / longitudinal tube to obtain the maximum breaking strength. The shaft compression strength is calculated according to the following formula. A 4 (210X297 public love) (please read the back (Notes and then fill this page)

X • Installed • • Line • A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (43) 4P σl --- π (d22 i2) Press :: John Compressive Strength (kg / · #) CU: Test piece Inner diameter (> >: Outer diameter of test H (》) Ρ: Maximum breaking strength (kg) d. Surface compressive strength: a test H with a length of 17 »cut from the tube forming metal, at a compression speed of 1» / min Compress in the radial direction of the pipe to find the maximum breaking strength. You can calculate the surface compressive strength according to the following formula. 3Ρ (d2 + d,) 2 σ2 =-x-n Ldj (d2-d ^) Press, surface compression Strength (kg / # > L: Length of test piece (β) Other symbols are the same as the measurement method of compressive strength of sag. E. Energy harvested by cantilever impact impact •• Examination of 64 «· from test tube shaped body Direct use. Use the cantilever beam impact tester made by Toyo Seiki Co., Ltd. to test with a hammer weight of 3.874kg and a lifting angle of 135 degrees. You can find the energy of the impact by the following formula. 4 λ R (c 〇s / 3-c 〇s 13 5 °) Ε =-n (d22 -d, 2) Press, E: cantilever impact energy absorption (kg · c «/ CBn (please read the precautions on the back before filling this page ) • Pack. • Order . Line. A 4 (210X297 public transmutation) Α6 Β6 2050 ^ 3 V. Description of the invention (24) W: weight of the mallet (3.874kg > (please read the precautions on the back before filling out this page) R: the axis of the mallet The distance from the center of gravity (22.41c ·) / 3: the angle (degree) that the mallet lifts the sample to the opposite Μ after breaking the sample f: the bending strength of the tubular skeleton and the number of bending elastic images cut out a length of 120 test H, Using a universal testing machine manufactured by Shimadzu Corporation, the test is performed with a distance between fulcrums of 100m and a bending speed of 3m / min. If the front end of the compression wedge is R5 and the front end of the fulcrum is R2, the load-deflection curve line is used to obtain the resistance Bending strength afp and bending elastic image number Efp.

8 ♦ L ♦ d2 * P σ fp = *-* π (d2 * -d /) Press, σ fp: bending strength (kg): inner diameter of test H) d2: outer diameter of test piece (μ) L : Distance between fulcrums (MB) P: Bending breaking load (kg)

4 · L 3 F

Efp =--2 n (d24 _di4) y Press, Ef p: bending elasticity (kg / # > printed by the Central Bureau of Standards of the Ministry of Economic Affairs P / y: the slope of the straight part of the load-deflection curve ( kg / κι) g. Plate-shaped body bending strength and bending elastic pseudo-number: a test piece with a width of 25 μ and a length of 50n was cut out from the laminated plate, using a universal testing machine (trade name Autograph AG) manufactured by Shimadzu Corporation -10 type), 35 halls between fulcrums, curved armor 4 (210X297 Gongguang) Μ-2〇ί> 〇υ3 Α6 Β6 V. Description of the invention (25) Speed 2 »» / min for the test. Use pressurization The front end of the wedge is R5 and the front end of the fulcrum is R2. From the obtained load-deflection curve, the anti-stress strength (σ f) and the bending elasticity (Ef) are calculated according to the following formula.

3PL σ {= --- 2Wh 2 Press, σ f: bending strength (kg / · #) W: width of test piece (μ) h: thickness of test Η (μ) L: distance between fulcrums (》) P : Maximum breaking load (kg)

L5 F

Ef ------ 4Wh3 y Press, Ef: bending elasticity number (kg / · #) E / y: inclination of the straight part of load-deflection curve (kg / «) h · drop weight impact test: A test piece of 100 «X l〇n was cut out from the laminated board, using a drop weight counterweight tester manufactured by Lei Meicuike Co., Ltd., with a weight of 30kg and a height of 20〇 > at a test speed of 2 · / sec. For testing. From the obtained absorption energy curve, the absorption energy is obtained. The present invention will be described in further detail using experimental examples. First, the method for producing the aromatic polyamine film used in the experimental example will be described. Poly-p-phenylene para-phenylenediamine (Poly-p-phenylene seven 6 "^" 113131 «丨 < ^) (abbreviated?? 7 steam) was used to make diaromatic amine awakening film. Put the front armor 4 (210X297 male eaves) (please read the precautions on the back before filling out this page). Install .. hit the line. »7 A6 B6 5. Invention description (2β) (please read the precautions on the back first (Fill in this page again) The PPTA is dissolved in 98X concentrated sulfuric acid at a polymer concentration of 0.5g / 100 * Jl. The log viscosity measured at 30 t: 5.5 was 5.5. The aforementioned PPTA was dissolved in 99.5X sulfuric acid to make the polymer concentration 12%, and a photo-anisotropic coating (Dope) was obtained. Allow the paint to deflate under vacuum. After filtration, penetrate the gear pump, squeeze out from the slit die, pour it on a belt (Belt) made of Tantalun, which is ground into a mirror surface, and let it pass through the orange to 40X humidity The air pressure of about 90Ό will optically equalize the cast coating and lead it together with the belt to 20t: 30X sulfuric acid aqueous solution to solidify it. Next, the solidified film was peeled from the tape, neutralized with caustic soda, and washed with water. After washing, the film is rolled in the long direction (MD direction) with a roller, and then stretched in the width direction (TD direction) with a tenter (Tenter), while maintaining a fixed length on one side, and 200Ϊ on one side: dry, Then, 300C is used as a fixed-length heat treatment to obtain a 20-thick PPTA film (thin film A) and a 10-thick PPTA film (thin film B). Table 1 shows the physical properties of film A and film B, as well as other experimental examples and comparative examples, using Ubel Industries Co., Ltd. Ubeles 20S, Ubeles 20R, Dupont Copton 100H and T- The physical properties of the 20w polyethylene terephthalate (Polyethlene terephthalate) (PET for short) film obtained by melting the film. Films A, B and Uberes 20S are more suitable for the present invention, other thin films are not suitable for the Central Bureau of Economic Standards of the Ministry of Economic Affairs to print the cracked armor 4 (210X297 Gongchu) 28 A6 B6 V. Description of the invention (27) Table 1 Names of physical properties of various films (Absolute degree: Qing) Tensile strength (kg / mmz) Tensile elasticity coefficient (kg / mm *) Breaking degree (%) Melting point or decomposition temperature CC) m Film A ( 20) 43.9 1290 23.5 above 400 Film B (10) 44.8 1350 25.6 above 400 Uberes 20 S (20) 42.2 810 34.2 above 400 Ube Industries Co., Ltd.Uberes 20 R (20) 34.0 380 145.1 above 400 / / Capton 10011 (25) 31.0 300 92.7 400 or more DuPont PET (20) 25.1 400 130.3 270! (Please read the precautions on the back before filling in this page)-Installed. Ordered • • Line. Ministry of Economic Affairs Central Printed armor 4 of the Bureau of Standards (210X297 Gongai) 29 78. 8. 3,000 V. Description of invention (28) A6 B6 Announcement of the Economic Central Standards Bureau ip First, to show the pre-stained body and resin obtained by joining the "film" and the resin Experimental examples of molded bodies (Experimental Examples 1 to 5). Experimental Example 1 On one side of the film A, using a coating machine manufactured by Rigaku Machinery Co., using a Kangmar direct method, it was coated into a ring gas resin it7714 (butan mixed liquid, solid content 70% by weight) manufactured by Burltech. ), Then 100t: heating to make film A / epoxy pre-crushed body. The thickness of the epoxy resin is about 10WB1. The above pre-stained body is pressed with a nip roll-side, continuously wound on one side and laminated on a stainless steel rod with a diameter of 100 sun-treated by Teflon coated film until 35 layers of pre-stain are overlapped body. A part of the obtained roll body was cut along the axis to obtain an elongated sheet-like laminated pre-stained body. This was put into a rectangular flat mold, held at 120¾ and 0.5 kg / mm2 for 15 minutes, and further heated at 150 ° C and 50 kg / ππη2 for 60 minutes. After the die was cooled to room temperature, the molded body was taken out to obtain a laminate with a thickness of 1 mm. Table 2 shows the physical properties of the resulting laminate. Understandably, as in the case of Experimental Example 4 described later, the strength of the molded body obtained by joining the "film" and the resin of the present invention is extremely high. That is, the physical properties of resin materials such as industrial plastics are generally as shown below. Tensile strength: 10 ~ 2 0 kg / ffl -m2 Bending strength: .3 ~ 20kg / mnf Bending elasticity coefficient: 300 ~ 500kg / m # (please read the notes on the back before filling this page) • Xiang · • Order · • Line · A 4 (210X297 public) 30 revised page A6 B6 printed by the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention) Even when strengthened with glass short iron dimension, it is as shown below. Tensile strength: 15 ~ 20kg / Acid # Bending strength: 15 ~ 30kg / bid2 Bending elastic pseudo-number: 700 ~ 110kg / · ^ Compare these values with the values in Table 2, the strength of the shaped body of the present invention is The superiority is very obvious. On the other hand, compared with the gauze-reinforced resin described later, it has a larger strain, and the results of these show that the molded body obtained by joining the "film" and the resin of the present invention is unprecedented and rich in toughness (Tough ) 'S new Ying shaped body. Experimental Example 2 Using a strip made of stainless steel with a diameter of 10 m as a pin mold, it was supplied from a direction perpendicular to the copper mold. In Experimental Example 1, a pre-stained body obtained by coating with oxygen resin was applied to make 35 coils. Around the stack. It was wrapped with polyethylene terephthalate tape (PET tape for short) 15m thick and 30 mm thick, which was subjected to demolding treatment, and allowed to cure for 2 hours in a 140C hot air heating device. Take out the cured molded body, remove the PET tape, and remove the steel mold to obtain a tubular molded body with an inner diameter of 10 m and an outer diameter of about 12 »«. Experimental Example 3 A pre-stained cut of the pre-stained air-bonded resin bonded to the film A obtained in Experimental Example 1 was cut to a width of 15 inches to prepare a strip-shaped pre-stained body. Using the Taping machine made by Shimano Industries, the tape-shaped pre-stained body is fed in the long direction at a pitch of 3 · », and the other side is wound on an uncuffed steel with a diameter of lOm with lOte / mn2 tension Coil pin mold. While the winding direction is reversed, the operation is repeated 7 times, and a spirally formed body can be obtained. Same as Experiment 2 with PET 4 (210X297 public issue) Μ (please read the precautions on the back before filling the nest page) • Installed. Line A6 B6 5. Description of the invention (30) Bandage it and remove it after curing PET tape, and then pulling out the copper mold, can obtain a tubular composite material with an inner diameter of 10 mm and an outer diameter of about 12m. Comparative Example 1 Using Capton 100H and PET_ _ as films, a pre-cracked snakehead with epoxy resin was produced in the same manner as in Experimental Example 1. These two kinds of pre-stained bodies were wound around the laminate in the same manner as in Experimental Example 2 to produce two kinds of tubular shaped satins with an inner diameter of 10 »and an outer diameter of about 12». Experimental Example 4 Polyphenylene sulfide (PPS) made by Dong) S · Munlipo Co., Ltd. at 340Ϊ; heated and melted, extruded from a slit die, and film A on a roller traveling directly under the chess set The upper mold was pressed and pressed between a pair of clamping rods placed immediately after S to split into a pre-stained body with a thickness of 30 w · "film j and PPS. The pre-stain was cut into elongated H-shape and overlapped 35 sheets are set in a rectangular flat steel mold. This is heated and pressurized for 10 minutes under the condition of 350t :, 20kg / Ciif using a hot pressing device, and then cooled to 501C to obtain a laminated board with a thickness of about 1M. 5 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in this page). Cut the pre-stained body obtained in Experimental Example 4 into a width of 10 «squeezed shape« to obtain a strip-shaped pre-crushed. The tape splicing machine feeds the strip-shaped pre-stained body with a pitch of 2.5 «· on one side, and rolls a copper mold with a 10m diameter on a side that is not covered by a copper spatula made of shovel copper. Repeat this operation 8 times to apply the overlap of film A. After stacking the 32 layers, fix the ends of the coil and the final coil with stainless steel hoist (Collar *), and bake at 350 * 0 (〇ven > heating for 5 minutes. After cooling to room temperature, nail puller 4 (210X297 public release) 32 2050 ^ 3 is A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs. V. Description of the invention (31, _Dysprosium can be Obtain an inner diameter of 10%> Comparative Example 2 Nitrocellulose-reinforced epoxy resin tube (C / P epoxy resin tube) In order to clearly locate the physical properties of the molded body obtained from the pre-precipitated body where the film j and the resin layer are joined, the The CP / ring resin tube is molded as follows. CF / ring resin UD pre-stained product (commercialized $ nose bird (0.2 ram thick)) made by Asahi Complex Co., Ltd. to make the fiber axis and pin die length direction 0 After winding 5 layers at the angles of 25 ° and 25 ° to wrap the stripped PET tape, it is heated in a 150 t oven to solidify it. After cooling to room temperature, the pin mold is pulled out to make an inner diameter of 10. Two types of * layer tubes with an outer diameter of approximately 12 mm are available. Comparative Example 3 The tubes made of gold and aluminum are made of aluminum and iron to clearly define the physical properties of the molded body obtained by joining the "pre-stained body of film J and resin". The physical properties of the inner diameter 10 · »and outer diameter 12« «tubes were evaluated. Table 2 shows the physical properties of the laminates of Experimental Examples 1 and 4. It is excellent when using thermoplastic resin In order to simplify the forming operation, the high elasticity achieved by the increase in the strain of the molded body is achieved. Table 3 shows the results of Experimental Examples 2, 3, and 5 and Comparative Examples 1 to 3. As expected from the physical properties of the plate-shaped body The strength and physical properties of the tubular skull of the present invention are comparable to those of the inclined tube CF * UD pre-stained body, and it is suggested that it can be reinforced in directions other than the fiber orientation direction, and the properties that impart more equivalence are not suitable. The physical properties of the flexible film of the present invention can only reach the level that can be obtained by the conventional general-purpose resin material. The outer diameter of the tube is about 12m «day layer tube {please read the precautions on the back and fill in this page first) Line A 4 (210X297 public) 5. Description of the invention Α6 Β6 Table 2 PPTA film / resin laminate physical properties, \ Avoidance of physical properties \\ experimental example i experimental example 5 2) f / mPPTA film 20 // mPPTA film epoxy resin PPS Hang tensile strength (kg / mm z) 4 1. G 4 3. 7 Specific strength 2 9. 7 3 1. 4 Tensile properties. System Ug / mtnz) 116 0 118 0 冏 比 弾 W: tie down 0 3 0 8 5 0 Tensile breaking strain (%) 2 11 2 3 1. 4 hip strength (kg / mm z) 3 4. 6 3 7. 2 丨 nj specific strength 2 4. 7 2 G. 8 Bending performance system (kg / imnz) 9 7 0 9 8 0 冋 Specific property coefficient 7 0 0 7 0 0 (Please read the precautions on the back first (Fill in this page) 4 Armored Printed by the Central Bureau of Standards of the Ministry of Economic Affairs (210X297) 3 Revised Page (〇5〇 ^ 3 A6B6 V. Description of Invention (33) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs

............................... {........... installed ..., .............................. Order (please read the notes on the back before filling out this page). A 4 (210X297 publish) 35 a〇5〇 ^ 3 A6 B6 5. Description of the invention (34) Next, according to the experimental example (Experimental examples 6 to 12), the description will be made on the bonding of the pre-precipitation body obtained by "film j and fiber-reinforced resin and forming this The obtained plate-shaped molded body. Experimental Example 6 The film A was laminated to a C / F epoxy UD pre-preparation body (manufactured by Asahi Composites Co., Ltd.) at a temperature of 80 C and a linear pressure of 101 «using a laminate roll (Laminate roll) (Phibolds) single-sided pre-preparation. Generally speaking, the above-mentioned UD pre-precipitation is made of CP yarn (CP Yarn) that is mostly impregnated with uncured ring air resin. The body is cut to the desired size, or when peeling off the release paper where the pre-stain is placed during the layering, it is easy to create gaps between the CF yarns, so it needs to be treated carefully. On the contrary, the pre-preparation of the present invention The stain is a thin film with strong adhesion, which can be directly used as an integral molded body. Therefore, the fibers constituting the UD pre-stain will not be generated It is extremely easy to handle. 9 sheets of the above-mentioned pre-stained body are re-coated in such a way that the carbon fiber can be oriented in the same direction, using a vacuum bag hot pressing (Vacuum bagm toe lave) method at a temperature of 150 ° C. (7 ° C / era2 pressure) It takes 2 hours to form a laminated board. The thickness of the resulting laminated board is about 2nrm, and it has a structure in which the film layer and the CF / epoxy layer are alternately laminated. Experimental Example 7 and Comparative Example 4 use Ubi Les 20S (Experimental Example 7), Capton 1 00H (Comparative Example 4) using warp as a thin film, respectively formed under the conditions of Experimental Example 6 to produce laminated plates. $ Experimental Example 8 + — I in thin film ΑApply a coating machine made by Lee Kang Machinery Co. in a direct gravure coating if ^ (Direct gravure) method 5 «m thickness of the formation of Philippine Corporation armor 4 (210X297 伂 发) {Please read the back of the first (Notes and then fill out this page) 36 Amendment page Α6 Β6 V. Description of invention (35) Ring gas resin # 7714. Then, heat it for 15 minutes to make a thin film A / ring gas resin pre-stained skull. Use a lamination stick first Pre-stain 4 pieces of the film A / ring resin and pre-stain CF / Chen resin UD (Asahi Corporation) Burbeds, 0.2m thick > 14 sheets with fibers in the same direction, and then 4 sheets of film A / Chen resin pre-pregs were laminated in sequence. This is the same as in Experimental Example 6. Air bag-autoclave (air bag-autoclave) was formed under the conditions to obtain a daylight laminate with a thickness of about 3 mm. The laminated plate is composed of a layer A (Safidvich) CF / cyclic gas resin layer of film A. Comparative Example 5 Using a Cap collar 100H as a film, it was formed under the same conditions as in Experimental Example 8 to spread a laminate. Comparative Examples 6 and 7 were pre-collapsed with CP / Chen resin UD only, aligned with the direction of the ore dimension, and stacked 10 sheets (Comparative Example 6) or 15 sheets (Comparative Example 7) respectively and applied hot pressing to obtain a thickness of 2im or 3 · Laminated board of η. Table 4 shows the properties of the plate-shaped objects of Experimental Examples 6 and 7, and Comparative Examples 4 and 6. Table 5 shows the physical properties of the plate-shaped buns of Experimental Example 8, Comparative Examples 5 and 7. The standard shoulder system made by the Drip Division (please read the precautions on the back before filling in this page) The plate-like body obtained by using the film in the examples and comparative examples has been greatly improved its impact. However, in terms of strength and elasticity, when compared with a plate-like body that does not use a film, the embodiments of the present invention can achieve the same degree of physical properties. As stated in the general description, the physical properties of the composite material are determined by the sum of the physical properties of the tilting material constituting the composite material. A 4 (210X297 gong) 37 A6 B6 V. Description of the invention (3δ) Due to the increase in the direction of the iron dimension, especially the elasticity, the number is expected to decrease as the fiber strengthens the resin layer and decreases as the film increases. In this case, not only can the plate-shaped skull of the present invention maintain the same strength, but also the elasticity of the image can be maintained to the same degree, so it can be said that it has been an unexpected result. In addition, as for the direction at right angles to the fiber direction, it is obvious from the comparative example that when the film is large in extension and soft, it is easy to deform, and the film can be imparted with impact resistance without sacrificing the characteristics of the secondary reinforcement resin. Therefore, the film of the present invention alone can become such a requirement. (Please read the precautions on the back before filling in this page) 38 A 4 (210X297 eaves) printed by the Central Standards Bureau of the Ministry of Economic Affairs A6 B6 5. The description of the invention) Printed by the Central Standards Bureau of the Ministry of Economic Affairs rf 戋 CJ1 M 00 m Quotient to 〇 > 1 ^ T3 -〇 • -3 * 1 «ΤΓ C5 〇rn 硪 弥» — »1— * h— ·, to oo 〇--4 to oo s- ^ 〇 Cong. Miao: o O 'oo cn Ol A o —J Co o 〇 > ^ Ip 2 * r * itco ^ H? 3 ^ tO to to CO CO a shop V __ ^ h— * H- * I—4 »—» ♦ — · to Sii? Cn CO ΟΊ 3M River V_✓ to ο -4 CO A cn CO CO \ —1 — ~ J CO > — * to tPi 1 锒 N 烟 V- ^ • Compensation CD oo Ol ro CD CD c mm CD cn CD l side tricks 5 fine crowd c.p < -rug {bffi »ss ± slBi ^ 瘌 凝 弥 缀 闼 燼 燈 雃 ^ 翁 阵 CJ) M 婼 M CD miscellaneous τ (γ ball 1-1 〇〇 > 1 CO 〇I hj 5 = > m 叇 to o GO Mi ►— »H- * η-i Sm \ CO cn CO oo CO CO CO-« .__ ^ o UD ►— * CO ο CO CO » CD CO 1—1 o CD »— * C3 i. 逄 w ·· Weng'w ^ • II e V—» cn Η- »cn H- * cn v— ^ cn m ►—» »— * ♦ — * CO ►— · ►— * cn , Οι cr > cn Km Nw. »CD CZ > CO CO cn 〇 > cn oo —j to · 〇s§ I dye> w. • m noi» oo CO 1 to VO ot * o CO CO 〇 > —J 4 ^. cn cn e mm ί nm Chi 4 绁 展 ssC Fls ^ ii®M ™ ^ N * iils © i ^ gr ^ # Fff (please read the notes on the back before filling in this) • Min . • Order · • Line · A 4 (210X297 public) 39 amended shell 205053 A6 B6 V. Description of the invention (38) Experimental example 9 The pre-prepared body of the film and PPS (referred to as thin mold / PPS) ), Laminated with sulfonated fiber (jD sheet / PPS pre-stained body (trade name Leiden ACH) manufactured by Burup Oil Co., Ltd. as follows. Four sheets of A / PPS were laminated first, and then 9 sheets of ACM (trade name) were aligned on top of them, and then four sheets of A were laminated to obtain a hard pre-stain. Put the hard pre-stained skull into a rectangular radium flat pin mold, and heat and press for 20 minutes under the conditions of temperature 3501 and pressure 20kg / c #. After cooling to 50 * 0, take it out to obtain a laminated board with a thickness of about 2m. Experimental Example 10 A hard pre-stained body like Experimental Example 9 was filled in a steel mold with a curved surface having a radius of curvature of 500 «, heated and pressurized under the conditions of temperature 350Ϊ :, pressure ZOkg / cffl2, and cooled to 5〇υ After taking out the molded body, it can be formed into a dish-shaped shape. Following Experimental Example 11, the surface of the film B was subjected to blasting (Blast) processing using 180 mesh river sand particles. The film was impregnated with poly »ether_ (abbreviated as PEEK) ), ICI company made fibrous fiber UDH (trade name APC-2), which is laminated between a pair of heating rods heated at 350 ° C under a linear pressure of 10 kg to make a pre-crushed body. Compared with APC-2, the pre-stained body reinforced by the film rarely cracks in the direction of the iron lobe, which is extremely easy to handle. The pre-stained hip is aligned with the direction of the fiber and overlapped 10 layers. This is placed in dysprosium chess, heated and pressurized for 20 minutes under the conditions of 360T :, 45kg / c #, and cooled to 60P. Laminated board. Experimental Example 12 (Please read the precautions on the back before filling in this page) • Packing • Ordering • Line • A 4 (210X297 male irrigation) 40 A6 B6 2050 ^ 3 5. Description of the invention (39) {Please read the back side first Please pay attention to this note and write this page.) Dupont's Fangfan glycosamine iron dimension, (trade name Kevlar 49) 1420d yarn (YarrO is set in the yarn holder (Creel), and guide the above-mentioned dimension to ICI. Dip the solution in the 25X DUethylacetadde (DMAC) solution of polyether (abbreviated as PES) on one side, and then pay attention to prevent the occurrence of gaps between the banknotes and the bar while taking care Roll away from the pavilion carefully to the pre-set silicone (SiH cone) release paper made of non-shovel copper _ cylinder (0 "11 ·). At 100t: turn the cylinder on the next side and heat for 3 hours to remove the solvent , Cut a part together with the release paper to obtain PES reinforced PES with a thickness of 0.2 «·. On the other hand, apply PES 25X DMAc solution to film A with a gravure coater (Gravure coater) and heat Desolventized to obtain single 40% thick film-like pre-stained body coated with PES. To overlap 3 layers On the film-shaped pre-stained body, 9 layers of aromatic polyamine amine reinforced PES aligned with the direction of the fiber axis are stacked, and then 3 layers of the above-mentioned film-shaped pre-stained body are stacked, put into a rectangular flat steel mold, at 320 it, 100 kg / B # under heat and pressure for 20 minutes. After cooling to 601C, remove the laminate from the pin mold. The thickness of the resulting laminate is about 2 rewards. Comparative Example 8 Sulfairon UD / PPE (commodity only) Mingleton ACM) overlapped 10 sheets, and formed under the same molding conditions as in Experimental Example 9 to obtain a unidirectional stacked plate with a thickness of 2 · ». Comparative Example 9 of the Ministry of Economic Affairs Central Standard Bureau printed cracks only using PEEK impregnated Sulfo-dimensional UD pre-stained body (trade name AP-C2) overlaps 10 sheets, using the same molding conditions as in Experimental Example 11, a badger with a thickness of 2 »can be obtained 4 (210X297 mm) A6 B6 V. Description of invention (40 ) Unidirectional laminated board. Comparative Example 10 Only 10 sheets of Kevlar 49 fiber UD pre-dip body impregnated with the same PES as used in Experimental Example 12 were superimposed, and they were also formed under the molding conditions used in Experimental Example 12 to obtain a thickness of 2 m. Unidirectional laminate. Table 6 shows the laminates obtained in Experimental Examples 9, 11, 12 and Comparative Examples 8, 9, and 12. The physical properties of the board. (Please read the precautions on the back before filling in this page). Installation ·-Line. Printed by the Central Standards Bureau of the Ministry of Economic Affairs 43 A 4 (210X297 public splashes) 5. Description of the invention (41) A6 B6 Central Ministry of Economic Affairs Standard Bureau printed armor 4 (210X297 male) lion 丨 j9 MPJ8 ^ «12 1 1 mmi \ 1 1 fiber! 19 Tengpu 2fWPPTA film | 10_, PPTA (sandblasting | ilDIEnn) j | 2 (knf PTA film St Csu m Aromatic poly hybrid carbon fiber carbon fiber 1 m carbon chick! 1 carbon following IS PES! TD i PPS PES S 1 00 1 AF strong ftPES layer bonded film on both sides _ 麁 m No IcF / PPS layer bonded film on both sides_ li Luyi ΓΓ § jJ to 1 strength j (ks / min2) o CT) 8 1 1 S 12700 Η -»I ^ iiS 'ΌΟ In —'4 < X > cr > s 〇〇〇1 ig Ol Jif CO bo bl 广] po 〇〇—, 4 CO 1 鸎 鲥 6 绁 Bribery π > 裒 飒 ® ItasfCTl Gamble Xuelian SSN-Ruping Cocoon N-Suishang (please read the precautions on the back before filling in this page). Equipment • Line. 43 A6 B6 〇〇5〇ί > 3 V. Description of Invention (42) Followed Take the experimental example of the tubular body (Experimental Examples 13 to 15). Experimental Example 13 In the same manner as Experimental Example 6, the film A and the CP / epoxy UD pre-precipitate were bonded to each layer. The prebonded body used for forming the tubular body is wound by stacking the joined pieces with five layers in the direction of the fiber axis in the direction of an unbroken pin bar (pin wedge) with a diameter of 10 «. Next, in the state of pre-stained body rolling, it was directly wrapped with a PET strip (thickness 25 w μ) subjected to release treatment, and cured in a 1401: hot air circulation heating device 2 hour. Remove the product from the heating furnace, remove the PET tape, and pull out the pin mold to obtain a laminated tube, that is, a laminated tube shaped into a tube. The laminated tube has an inner diameter of 10 »and an outer diameter of about 12« m. The pseudo-CP pre-soil layer and the PPTA film layer are alternately laminated. In Comparative Examples H and 12, instead of the thin film A, a laminated tube having an inner diameter of 10 and an outer diameter of about 12 »was produced in the same manner as in Experimental Example 13 using Capton 100H and Eupirides 20R, respectively. Table 7 shows the physical properties of the laminated tubes of Experimental Example 13, Comparative Examples 11 and 12, and the CP / Chenqi (0 ° laminated) tube manufactured in Comparative Example 2. The results in Table 7 more clearly show that the physical properties of the film can satisfy the requirements of the present invention, and can bring better results. That is, only the experimental example of the present invention can obtain a reinforcing effect at right angles to the fiber, increase the W property in the same direction of the tube, and significantly improve the bending properties, and the strength can also increase in the continuous dimension. In addition, the impact resistance, although it is a physical property contrary to the technical thinking of the alternating layer, but can still get a larger arm-type stab value. (Please read the precautions on the back before filling this page) • Installed • • Played • • Line • Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 4 (210X297 public splashes) 44 Α6 Β6 V. Description of the invention (43) Experimental example 14 will The film A produced in Experimental Example 1 was coated on one side with a pre-stained skull made of Chen gas resin, cut to 10 mm wide, and processed into a band shape. The CF pre-stained body is wound in a layer of 4 layers with a diameter of 10 mm and a non-rotating pin round in such a way that the fibers are aligned with the longitudinal direction. On this, the aforementioned film A was coated with a belt of ring air, and the same conditions as the method shown in Experimental Example 3 were used to wind up at a pitch of 2.5 ««, tensile force Ιδίβ / ιηπ2 using a tape bonding machine to produce 8 layers. Film A, and was bonded to the pre-stain on the outside of the CF / Chen layer. Next, in the state of being wound around the copper chess, the pre-crushed body was directly wrapped with a PET strip (thickness 25 «) that had been subjected to demolding treatment, so that it was placed in the hot air circulation heating device of 140 υ Cure for 2 hours. The product was taken out from the heating furnace, the PET tape was removed, and the copper mold was pulled out to obtain a laminated tube. The laminated tube has an inner diameter of 10 »and an outer diameter of about 12β. The thin outer layer is joined to the outer diameter of the CF pre-stained body layer. In Comparative Examples 13 and 14, Capton 100H and Eubelius 20R were used instead of film A, and epoxy resin (Chemical Fibers made by Special Corporation »7714) was applied under the same conditions as in Experimental Example 1, and then cut. Made into 10 «« wide belts. Except for using this belt, a tubular body was produced in the same manner as in Experimental Example 14. Table 8 shows the physical properties of the CF / Chen oxygen (0 ° laminated) tube manufactured in Comparative Example 2 of the stacked tube S of Experimental Example 14, Comparative Examples 13 and 14. It can also be understood from the results in Table 8 that the present invention is based on a completely different idea from the alternating layer technology. That is, the film does not need to be interacted with the fiber-reinforced resin layer "Layer, Special A 4 (210X297 Public Broadcasting) (Please read the precautions on the back before filling out this page) • Install. • Order.-Green · 45 3 ύο Γοο

A B 5. Description of invention (44) It is the manufacture of a tubular body, and the aforementioned laminated structure can be effectively utilized. In addition, the experimental examples and comparative examples shown in Table 8 show that even the impact resistance is included, and that they can obtain a remarkable effect by the constitution of the present invention. (Please read the precautions on the back before filling in this page) -Installed • • Ordered • • Line. The Central Bureau of Economic Affairs of the Ministry of Economic Affairs printed cracked A 4 (210X297 public eaves) 3 · ϋ ο Γο ο ί ·· α

AB V. Description of the invention (prepared for general purpose) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs% tvD H- * 宜 Η- * CO 滢 H- * Fujiko to 0 1 璊 m 蟊 C5 〇-t3 3 ^ > tear dimension m to CE umi cn cn cn CO ○ • Pw CO \ 3 ffl CO to cn CO 3M 綘 harmonic '— ^ CO ro CO Ϊ _Si CO CO CO \ 3 m CO a > K > H-1 3m nm V ^ · Η -»Η- * > — * i pride to • o •-^ 3» N— / in \ 〇r CH M IN »1 & J m II m» CO o C £ > (〇 > 〇CO -m H- * to ro to ♦ 遨 ΟΊ CO —J — cn CO CO \ §. »W ^ 雒 00 姗 CF® ?? 繊 贵 琏 cmrapN · ^ 达 * _ 隊 弥 N-4 萍 _s 蓉 阵Shallow Cv3 h- ^ I—4 h—1 CO τ (τ to o cockroach st ~ ^ m CD o 33 m to < z > Mi cn CO cn A —J oo CO 、、 彐 m CO to —J CO 3m mm ^^ ►—t to S iSSi to cn to 〇 彐 m cn to cn CO 3N 河 斟 h— ^ H- * Sm • to «o • Η-» oo Km IM; 〇rf— * Λ? Rm Jii Ul Co 〇1100! I 1410 tm I m JSr oo 丨, song ^ v branch h- ^ to to CO * M m cn 4 ^-cn —j CO to o S ί \ fine 7 fine cat Mi Mei CF CF 沗 存 Burma «Trace garlic no Ν '#_ Ν · 1 = Ping Cocoon S — (Please read the precautions on the back before filling in this page) • Line · A 4 (210X297 common eaves) Ϊ7 A6 B6 V. Description of the invention (4β) Experimental example 15 will be preheated for 150 t; Shuo Tiewei UD film / PPS (trade name Leton ACM) uses a rolling device to roll the steel weaving direction to the direction of the pin die length on a steel die with a diameter of 10 «# 1 pin round bar Around 4 layers. From thereon, a tape bonding machine was used to wind 2 turns of 10 η * wide-band-shaped pre-crushed bodies obtained in Experimental Example 4 at a pitch of 2.5 m and a pulling force of 12 kg. After fixing both ends of the laminate with a non-hammer-made quarry, it was heated in an oven at 350 ° C for 10 minutes. After cooling to room temperature, the steel mold is pulled out to obtain a laminated tube with an inner diameter of 10m and an outer diameter of about 12 ». Comparative Example 15 A PPS-bonded film was produced by the method of Experimental Example 4 instead of the film A, using Ubelius 20R, and a laminated tube having an inner diameter of 10 mm and an outer diameter of about 12 m was obtained in the same manner as in Experimental Example 15. Comparative Example 16 Under the same conditions as Experimental Example 15, 5 layers of sulfonate fiber UD sheet / PPS (trade name is ACM) were wound with a pin of 10 m in diameter as a pin mold. After forming, the film A of the outermost layer of the obtained laminated tube was peeled off as a sample. Table 9 shows the physical properties of the tubular squat in Experimental Example 15 and Comparative Examples 15 and 16. (Please read the precautions on the back before filling out this page) • Installed • • Played. • Line • The Central Standards Bureau of the Ministry of Economic Affairs printed the split armor 4 (210X297 public) 5. Description of the invention (47) Comparative Example 16 ί Comparative Example 15 Example 15 Pu i Eubilis 20 Qing PPTA thin m tO Mi P ϋ Η- * 48.1 ΟΙ cn Uranium constriction strength j (kg / mmz) -J CO CO CO V-1 zn to Fen mm ^ m 3M river harmonic • * W ^ ① CO H- * oo Η-4 private C / l Sm -—✓ in l〇r OD 〇OD CO 〇 > 1200 e, s tasting B ^ m 'w ^ mm ~ * 3 h- 1 CO tND H- * OO cantilever wedge impact (kg · cm y ci) 1 A6B6 (please read the notes on the back before filling this page) A 4 (210X297 public splash) 78. 8. 3,000 A6 B6 V. Invention Description (48) The connection with the following experimental example and comparative example shows that the tubular skeleton with the ink layer wound on the outer side of the iron-strengthened resin layer is wound by the tension of the wound film as it wraps around the film layer. Experimental Example 16 Oxygen resin was coated on one side of the film A, and cut into a strip preform with a width of 10 m, except that the tensile force was 8 kg / · #. A laminated tube with a diameter of 10m and an outer diameter of about 12m. The obtained laminated tube was cut in a direction perpendicular to the longitudinal direction, and its cross-section was observed with an electron microscope, and almost no voids were observed at the thin film layer or at the interface between the two. Comparative Example 17 In the same way as Experimental Example 16, except that the tensile force was 5 kg / · #, a layered tube with an inner diameter of 10 »and an outer diameter of about 12« was manufactured in the same manner as in Experimental Example 14 At the interface between the fiber-reinforced resin layer and the sulfonated fiber-reinforced resin layer and the film layer, many voids were observed. Further, at the aforementioned interface, wrinkles can be observed with the naked eye along the orientation direction of the sulfonate fibers, and the cantilever beam test piece has a fracture along the wrinkles. Table 10 shows the physical properties of the laminated tubes of Experimental Examples 14, 16 and Comparative Example 17 ................................ ........ (........... ^ ...................................... .ir ...... 一 ............ ball (please read the notes on the back before writing this page) Economy $ Printed by the Central Standards Bureau 4 (210X297 Father Chu) 50 (j A6 B6 V. Description of the invention (49) Comparative example Π Comparative example 16 Experimental example 14 13 13 20 Dance PPTA thin * Mi | i H-m cn CD cn P CO CD CO CjD Shrinking strength (kg / mmz) CO CO CO to oo l—l surface constriction strength (kg / min2) CO oh— * to cn ro cn Ca ^. er umm \ 涶 擊 一 〇 觖 卧 赈 #_ 球 c FIJTJshaialstznnJBN- ^ es'nnl ^^ N · — (please Read the precautions on the back before filling in this page) • Install · Order · Line · Ministry of Economic Affairs Central Standard Lip Print Armor 4 (210X297 Public Splash) 51 A6 B6 Five 'Invention Description (49a) Experimental Example -17 Make the above PPTA polymer (this polymer is dissolved in 98% concentrated sulfuric acid at a concentration of 0.5 g / 100rajl at 30t: the measured log viscosity is 5.5) dissolved in 99.5% 'sulfuric acid at a concentration of 12% polymer to obtain a light direction The opposite sex paint (d ope). After the paint is deflated and filtered under vacuum, it is extruded from the slot die through a gear pump and poured into a button belt ground into a mirror surface. Then, it passes through the air with a relative humidity of 40¾ and a temperature of about 90t: In the atmosphere zone, the cast coating is optically equalized and the giant belt is led to the 301 of 20¾: sulfuric acid aqueous solution to solidify. Peel the solidified film from the giant belt, neutralize with caustic soda aqueous solution, and wash it with water. After that, the film was dried in 2001 without being stretched and kept at a certain length, and then subjected to fixed-length heat treatment at 300 ° C to obtain a PPTA thin film (film C) with a thickness of 1δα m. The characteristics of film C are shown in Table 11 (Please read the precautions on the back of Cun Qi to write the book). * Physical properties and thickness of film C in table U (um) Tensile strength (Kg / rom2) Tensile elastic pseudo-number (Kg / mm 2) Elongation at break (%) 16 3 7.3 790 36.5 • Line. In the same way as the experimental example, the film c is coated with 5 W 10 thickness of the ring gas resin U77.14), and it is the same as the method of experimental example -I After being laminated to make a pre-stained body with an elongated H shape, it is formed under heating and pressure to obtain a thickness of 1 level board. The physical properties of the resulting laminate are shown in Table 12. From this result, it can be seen that the strength of the film used in the present invention must reach 35Kg / m®2 before it can achieve its super middle 4 (210X297 g; A6 __ B6 _ ^ ___ _ V. Description of the invention (4%) over 30Kg / division) 2 The strength strength material is traditional engineering plastics (please read the precautions on the back before filling this page). Table 12 Physical properties of thin film C laminate

A PPTA film coated with a ring gas resin as used in Example-17 was laminated on the CF / ring gas UD pre-preparation body, and both layers were overlapped in the same direction of the CF orientation by 10 layers. The pre-stained body of the Gu layer is filled in a rectangular flat mold, and maintained at a pressure of 100 kg / cm2 for 60 minutes under heating at 150 ° C. After cooling the mold to room temperature, the Gu layer board with a thickness of about 2 mm was taken out. Comparative Example -18 11 layers were superposed with CP / circumferential pre-stains, and hot press forming was carried out in the same way as Experimental Example -1δ to produce a CFRP Gu laminate with a thickness of about 2 strokes. The physical properties of each laminate in Experimental Example -18 and Comparative Example -18 are shown in Table 3]. The cantilever beam collision values in this table are pseudo-use. The width φ Λ nv * 9Q7V is cut from the resulting laminate-Ί- 51 h-private ^ window__ — 3 ΰ% ο 2

A V. Description of the invention (49c) 12.5 coffee, length 65nn test H to determine. From the results shown in the table, it can be seen that although the ratio of CF is reduced, it is surprising that almost the same strength and elastic pseudo-numbers can be obtained. And at the same time, a significant improvement in impact can be achieved, which is extremely significant in improving the reliability of the material. However, when considered together with the results in Table 4 above, in order to balance the strength and elasticity in the high dimension, the physical properties of the film itself are affected, and the film must have a strength of 35Kg / Payment 2 or more, 700Kg / Elastic pseudo-numbers above ran2. Table 13 Physical properties of laminates (please read the precautions on the surface before filling in this page) • Insects. Experimental examples lδ Comparative example 1 8 film 16 / i mPPTA film-far black bending strength (iU / paid 2 ) 1G7 169 Flexural elasticity number (Kg / miB2) 1007Θ 10800 Cantilever beam type 221 134 Collision value (impact) (Kgcm / cm 2) Experimental example-1 9 • Line, the epoxy resin-coated ρρτΛ used in the example The film is cut into strip-shaped pre-stains at a width of 15mi and used. This strip-shaped pre-stained body is shaped like a tube in the outermost layer, except that the tape is laminated at a pitch of 1.5 mm. The physical properties of the above-mentioned tubular shaped skulls are shown in Table 4 of Table 1. Compared with Table 8, it can be seen that the physical properties of the film used in this example are not only impact-resistant, but also basically strengthen the iron elasticity of the larger elastic pseudo-51c A4 (210X '297 public) A6 B6 V. Description (d) The number and strength of the invention can achieve significant effects. Table 14 Physical property test examples of laminated tubes 1 9 Film 16 / i mPPTA film axial compressive strength (Kg / n! 2) 60.3 Surface compressive strength (Kg / rnn 2) 29.3 Bending strength (fU / 醐! 2) 17.5 Bending elastic pseudo-number (Kg / nrn2) 1530 Cantilever beam type 285 Impact value (impact) (Kgcm / cm2) ............................... ........ ί ............. ^ .............................. ... order ......... W ............... margin {please read the precautions on the back before filling in this page) Ministry of Economic Affairs won the bid 4 ( 210X297 father hair) -51d-Amendment page 〇 Lion 3

B6 Announcement V. Description of the invention (49e) Experimental Example 2Θ Winding glass fiber / circular resin UD pre-stains (hy-E UD pre-cleans) manufactured by Huaji Jiwei Special Co., Ltd. on a stainless steel drawing strip with a diameter of 10 On the pin mold, the payment axis is aligned in the length direction of the mold to obtain a 4-layer laminate. Then, the same film A ribbon pre-stain as used in Experimental Example 5 was helically wound on it with a 1.9 m pitch and covered with PET tape and heated at 140 t for 60 minutes to harden. Finally, the PET tape is removed and the mold is removed to obtain a tubular shaped body with an inner diameter of 10BB and an outer diameter of 12ι «. Experimental Example 21 Except that the chemical fiber was used to manufacture glass fiber susceptor / Chen gas resin pre-ultrast (hy-E cross pre-stain), the rest was carried out in the same way as Experimental Example 20, and the inner diameter was 1β «η «, Tubular shaped body with an outer diameter of 12ma. I; Examples 19 and 20 are similar to Examples 20 and 21, each with glass fiber UD / ring resin pre-stain and glass fiber fabric rolled on a stainless steel mold for 5 layers, and then covered with PET tape and hardened by heating And mold release, each of which can obtain glass fibers (tubular shaped body made of JD / cyclic gas resin and glass fiber / circular gas resin cracked tubular shaped body with inner diameter and outer diameter of 12m. The properties of the obtained shaped body are shown in Table 15. Please read the note 1 on the t side before writing this page). Install. • Order • • Line, printed by the Central Wiping Bureau of the Ministry of Economic Affairs 'Λί9ΙΠν ^ Ρ7 ^ /: ^' > -51e- Amendment true 3 • ruο 5ο 2

AB V. Description of the invention (49f) Table 15 The film is laminated on the outer layer of glass fiber reinforced ring gas resin and the physical properties of the film of the day layer tube obtained by the axial compression strength surface compression strength surface compression strength three-point bending cantilever Beam type (kg / aim2) (kg / nm2) Strength strong pseudo-number impact (kg / * B?) (Kg / BB2) (kg * as / cm2) Experimental example 20 / i βι 51.5 32.2 16.3 1490 28Θ 20 PPTA Film experiment example 2d um 40.8 41.1 23.4 131Θ 341 21 PPTA film comparative example no 43.0 10.5 12.1 520 177 19 comparative example no 37.2 39.5 20.8 1178 233 20 (please first read the precautions on the back and fill in this page) C? Inv 9Q7 ^. 'ϋ) -51f- amended to buy A6 B6 V. Description of the invention ($ 0) [Simple description of the garden style] The 1st to the 10th circles show the sectional garden of the example of the structure of the pre-stained body or shaped body of the invention , Where 1_ ~ 6_ is an example of a plate-shaped pre-stained body or shaped body, and the 7th circle ~ 10th circle is an example of a tubular pre-stained skull or shaped body. The film used as a reinforcing material in the present invention is hereinafter referred to as "Film J. The first country is the cross-sectional garden where the film j and the Shusheng layer are laminated and bonded to each other. The second garden is" Film "and Tiewei The cross section of the reinforced resin layer is an example of layer bonding. The third circle is a cross-sectional view in which a plurality of "film j" examples are joined to one side of the fiber-reinforced resin layer. The fourth circle is a cross-section in which a plurality of "film J is an inner layer examples" are joined between two fiber-reinforced resin layers Circle 5. The fifth group is a cross-sectional view of an example of a "film j" in which a plurality of tweed-strength reinforced resin layers are laminated on both sides. The sixth circle is a cross-section of an example in which an iron-dimensional reinforced resin layer and "film j are alternately joined" Circle 7. The seventh country is a cross section of an example of a tube in which multiple layers of film j and a resin layer are joined to each other. The eighth circle is a cross section of an example of a tube in which multiple films are joined to the outside of a plurality of fiber-reinforced resin layers The ninth regiment printed by the Central Bureau of Standards of the Ministry of Economic Affairs is a cross-sectional area where a plurality of "tubes of film J" are joined to the inner and outer surfaces of the last few layers of reinforced resin layers. Circle 10 is iron reinforced An example of a tubular cross-section in which a resin layer and a "film" are alternately joined. A 4 (210X297 public transmutation) {Please read the precautions on the back before filling this page}

Claims (1)

v A7;; do \ W 'B7 丨 ...' C7 1 -------- D7 82. 1. 20 Amendment Sixth, apply for patent Fan Garden 1. A pre-stained body, which is selected from aromatic Polyamide (Aramide) and glass transition temperature is 285 ~ 500. The polymer group composed of its polyimide is substantially composed of organic polymers with no melting point and has a stretch of 700 kg / mir2 to 1400 kg / nm2. At least one film with a tensile strength of S 35kg / mn ^ to 45kg / mm2, and an epoxy resin, or selected from the group consisting of polyphenylene sulfide, polyether-ether ketone and polyether resin At least one resin layer of a thermoplastic resin, formed by bonding or adhering the aforementioned film and the aforementioned resin 2. The pre-stained body as described in item 1 of the patent application scope, wherein the resin layer is formed of a ring-shaped resin . (Please read the precautions on the back before writing this page) This is the TX item of the description of the body stains in the fat tree. Fan Chengli's specialty please apply for a good performance 3 Hot by the η i Interterm 15 crosses are surrounded as a fan layer Fanlizhi special special request for a number of applications Shen Rufu 4 and 5 \ Membrane Periphery thin HJ number complex whose body stains are predicated and combined together HJ number complex his body stains predicated item 2 Bo Gen HJ number complex among them ο 捿. ^ ^ ^ Two πf 2 f ^ ^ joint y connected to the intersection of 3ΓΙ is divided into the layer of the layer • layer 淺 利 指? .- 3-. 31 '· tree special tree layer please apply for the number of layers Fuyou 6 and Membrane Membrane are described in terms of their body stains in the thin film 2 ο The first membrane enclosure is thin, and the Licheng Specialty Institute asks for amine application, such as poly 7-group aromatics. ΤΓ. U m. Ministry of Economic Affairs Printed by the Central Bureau of Standards and Staff Consumer Cooperatives for the transfer of temperature-temperature melting transfer tools to glass and glass, and the amine group II polymer group polyaromatic composition. · Τ 8 5 to the long purpose of pulling HJ ΠΗ 1 The tree is reduced to the strongest dimension, the slenderness is pulled up: Resistance, Into the formation s So 0 / layer 0 S Dagger said 7 k ffn. There are 45 trees with metamorphosis and In2 research m 隹 結 kg fiber Institute ΓΟ The layer body is a good number of polyunions, and it is thin and has a thin elastic film. This paper is also suitable for the Chinese National Standard (CNS) A 4 specifications (210 X 297 ） I A7 B7 C7 D7 VI. The resin used in the patent application layer is selected from Jing oxygen resin or selected from polyphenylene sulfide, polyether- Brew '# 体脂 成 ii ί ί stained tree i Predict the plastic adhesion of IB h heat or 7f ^ group connection 8 The fat is surrounded by the tree layer to form a fat fan group. The specialty is strong. Please ether the "Wei Shen Poly" fiber as described, 9 _ before and before the thin film. As a result, in the strong-dimensional fiber, its strong-dimensional fiber has its body stains. The predecessor's fat description tree is Λ for the purpose of the fat tree. For example, 0 fat 10 tree items. 8th Fan Fan Li, please apply for the bow 1 at least to its body. The pre-fat tree stained by the stainer described the item's heat 'for the purpose of the fat tree so that the layer is like a fat 11 tree However, when the layers are stacked or covered by the film and the thin layer, the length of the tree is reduced to the strong medium dimensional fiber, and the body is stained with one of the pre-layers. The ^ ^ Μ periphery ΛZ fan S layer profit ffi is exclusively 0 ^ Ϊ film application two 12th, iv with 1 I as few as its body stain prediction c item L 0 1 is the first and the layer is outside profit Or special 0 application layer is less than the laminated film and 3! Thin application layer. On the J 3 I of the 1 'layer' Zhang Shuhua strong dimensional fiber on top of the layer of S · layer 14 purpose application and thin film. The predicate of his body stains is 8Γ, and the outer layer of the first layer is outside the fan or benefit and the words are divided into layers of fat tree, strong, strong, and special. Φ ---------: ---.-- -^ ------- install ------ order ---- {^ (please read the precautions on the back before writing this page) Central China Bureau of Hydrocarbon Economy Standardization Bureau Consumer Cooperation The printing is divided into layers of fat tree such as l 5 fcK 1. Strong dimensional 〇 money ο and those who form a film into a thin layer of the stratification layer «Mutual, intersecting body intersects the number of sheets of stains pre-multiplexed according to the description Or by Zhang Xiang Zhang press 9 Press ^ ^ ^ y Wai · = η S Fan Yu and its thin film in the thin film of the body of the pre-reported items 0 11 No. Μ 利利 申 申 者 者 成 成 层 «Mutual exchange long ηη number multiple presses or R PT- is divided into layers of fat trees according to the classification Ε Qianweiweidi Diwei Fanli specifically requested the application of fiber carbon from the use of r layer 7 17 fat trees into strong dimensional fiber fibers The dimensions of the glass items on the glass sheets of the dimensional description of the fiber group are applicable to the Chinese National Standard (CNS) A4 specifications (210 X 297 g). 2 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5 of 3 ^ _D7 Sixth, the group of patent applicants was strengthened by the selected Zuo Luo. 18. The prepreg described in item 9 of the patent application, in which the fiber-reinforced resin layer is reinforced by selected fibers composed of sulfonate fibers, glass fibers, and aromatic polyamide fibers. 19. The pre-stained body as described in item 10 of the patent application scope, in which the fiber-reinforced resin layer is pseudo-reinforced by a group of selected fibers reinforced by sulfonate fiber, glass fiber, and aromatic polyamide fiber . 20. The prepreg as described in item 8 of the patent application, wherein the reinforcing fibers in the fiber-reinforced resin layer are sheets in which the fibers are aligned in one direction. 21. The pre-stained body as described in item 9 of the scope of the patent application, in which the reinforced secondary dimension in the strand-strengthened resin layer is a sheet-like one that stretches the fibers in one direction. 22. The pre-stained body as described in item 10 of the scope of the patent application, wherein the reinforced secondary dimension in the fiber-reinforced resin layer is a sheet-like one that stretches the strand dimension in one direction. 23. The prepreg according to item 8 of the scope of the patent application, wherein the reinforcing fibers of the fiber-reinforced resin layer are selected from the group consisting of a wrinkle, a woven fabric, a non-woven fabric, and a mat-shaped object. 24. The prepreg described in item 9 of the patent application, wherein the reinforcing fibers of the fiber-reinforced resin layer are selected from the group consisting of: fabrics, braids, non-woven fabrics, and cushions. 25. The prepreg according to item 10 of the patent application scope, wherein the reinforcing strands of the fiber-reinforced resin layer are selected from the group consisting of: fabrics, braids, non-woven fabrics, and cushions. 26. The prepreg described in item 8 of the patent application, wherein the film is a film made of aromatic polycyanamide. This paper scale is applicable to China's 0 Standards (CNS) A4 specifications (2〗 Ο X 297 public goods) (please read the precautions on the back before filling out this page) • Install.-Order · < 0 Α7 Β7 C7 D7 六、 Applicable patent scope 27. A kind of tubular skeleton, which is a tubular shaped shaped body formed by at least one film and at least one resin layer / and / or fiber reinforced resin layer, wherein the aforementioned film is selected from aromatic polyamide And a polymer group composed of polyimide with a glass transition temperature of 285 ~ 500 * 0, which is composed of a substantially non-melting organic Shito polymer and has a tensile elasticity of 700kg / mn ^ to 1400kg / mni5 and 35kg / fflV to 45kg / min2 tensile strength, the resin used in the resin layer or fiber-reinforced resin layer is selected from the group consisting of ring gas resin or thermoplastic resin selected from the group consisting of polyphenylene sulfide, polyether-ether ketone and polyether Resin, the film and the resin layer and / or the fiber-reinforced resin layer are adhered to each other or sticky> 28. The tubular body as described in item 27 of the patent application, which is used for the resin layer and the compound of the reinforced resin layer The resin is Chen Qi resin. 29. The tubular body as described in item 27 of the patent application, wherein the resin used in the resin layer and the fiber-reinforced resin layer is a thermoplastic resin. 'Treatment 30. The tubular body according to item 27 of the patent application scope, wherein at least one film is laminated on the inner layer and / or the outer layer of the fiber-reinforced resin layer with at least one β layer. 31. The tubular body as described in item 28 of the patent application scope, wherein at least one film is laminated on the inner layer and / or the outer layer of the fiber-reinforced resin layer to be laminated. Printed by the Central Standard of the Ministry of Economy and Economy, R-Consumer Cooperative (please read "Notes on the back and then write this page") f 32. The tubular body as described in item 29 of the scope of patent application, including at least one The film is formed by layering the layer on the inner layer and / or outer layer of more than one fiber-reinforced resin layer. 3 3. The tubular body as described in item 27 of the patent application scope, in which the film and the dimension-reinforced resin layer are formed by layering or multiple layers alternately laminated respectively. This paper is widely used in the national B standard (CNS) A 4 specifications (210 X 297 mm) -i A7 B7 C7 D7 Printed by the Pinggong Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 51 VI. Patent application ffi 34. As stated in item 28 of the patent application scope Tubular body, where the film and the strand-reinforced resin layer are formed by alternately laminating sheets or sheets, respectively. 35. The tubular body as described in item 29 of the patent application, in which the film and the fiber-reinforced resin layer are respectively 36. The tubular body as described in Item 27 of the patent application scope, wherein the fiber-reinforced resin layer is made of: sulfonate fiber, glass fiber and aromatic polyamine iron The formed group is strengthened by the selected fibers. 37. The tubular body as described in item 28 of the patent application, in which the fiber-reinforced resin layer is pseudo-adopted by a group consisting of: sulfowei, glass fiber, and aromatic polyamine fiber reinforced by the selected weave. 38. The tubular body as described in item 29 of the patent application, in which the fiber-reinforced resin layer is pseudo-adopted by a group consisting of: Shun Panwei, glass fiber and aromatic polyamide fiber reinforced by #selected fiber. 39. The tubular body as described in item 27 of the patent application scope, in which the reinforcing fibers in the purpose layer of the Ewei Strengthening Tree are sheet-shaped ones that pull the fibers in one direction. 40. The tubular body as described in item 28 of the scope of the patent application, wherein the reinforcing fibers in the flier layer of the fiber-reinforced tree are flakes that pull the fibers in one direction. 41. The tubular body as described in item 29 of the scope of the patent application, in which the reinforcing fibers in the fiber-reinforced resin layer are in the form of sheets that align the fibers in one direction. 42. The tubular body as described in item 27 of the patent application range, wherein the reinforcing cone dimension of the fiber-reinforced resin layer is a H-shaped one selected from the group consisting of woven fabrics, woven fabrics, non-woven fabrics, and mats. 43. The tubular body as described in item 28 of the patent application scope, in which the fiber-reinforced tree "the reinforcing fibers of the purpose layer are made of fabric, woven fabric, non-woven fabric and cushion shape (please read the precautions on the back and then fill in the hundred) • Installation. • Line · This paper ruler 7k is applicable to China ’s g-standard (CNS) A4 specifications (210x297 full goods) Α7 Β7 C7 D7 Printed by the 8th Industrial and Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy Those who are selected by the group. 44. The tubular body as described in item 29 of the scope of the patent application, in which the reinforced fiber of the fiber-reinforced resin layer is a sheet-like one selected from the group consisting of woven fabric, braided fabric, non-woven fabric, and cushion-like material. 45. The tubular body as described in item 27 of the patent application, in which the film is made of aromatic polyamine. 46. A kind of plate-like body, a plate-shaped shaped body formed by at least one film and at least one resin layer »and / or fiber-reinforced resin layer, wherein the film is selected from aromatic polyamine And the polymer group composed of polyimide is substantially composed of organic strip polymer without melting point and has 7001 ^ 8/0)! ^ To 1400kg / mm2 tensile elasticity guarantee: several and 35kg / mm2 to 45kg / Tensile strength of mm2, the resin used in the resin layer or Lewis reinforced resin layer is a thermoplastic resin selected from the group consisting of ring gas resins or resin groups composed of polyphenylene sulfide, polyether and polyether®, the aforementioned films and resins The layers and / or dimensional reinforced resin layers are adhered or adhered to each other. 47. The plate-like body as described in item 46 of the scope of the patent application, wherein the resin used in the resin layer and the fiber-reinforced resin layer is a ring gas resin. 48. The plate-like body as described in item 46 of the patent application, wherein the resin used for the resin layer and the fiber-reinforced resin layer is a thermoplastic resin layer. 49. The plate-like body as described in item 46 of the patent application scope, wherein at least one thin film is barrier-layered to an inner layer and / or an outer layer of at least one fiber-reinforced resin layer coated with at least one layer. 50. The plate-like body as described in item 47 of the patent application scope, in which at least one or more films are reinforced by a gu layer and at least one layer of laminated fiber (please read the precautions on the back side first) (This page is written) — Binding. Ordering. Thread and Tai paper are applicable to Shitongjia Standard (CNS) A 4 specifications (210 X 297 male yak) 6 3ο 5ο AB c D printed by the Industrial and Consumer Cooperative Society System 6. The inner layer and / or outer layer of the patent-pending solid resin layer. 51. The plate-like body as described in item 48 of the patent application scope, in which at least one or more films are layered on the inner layer and / or outer layer of at least one fiber-reinforced resin layer laminated at least one day. 52. The plate-like body as described in item 46 of the patent application, in which the film and the iron-reinforced resin layer are formed by lamination or multiple laminations, respectively. 53. The plate-shaped skull as described in item 47 of the patent application scope, in which the film and the Ewei-reinforced resin layer are formed by laminating or alternately laminating them, respectively. 54. The plate-like body as described in item 48 of the scope of the patent application, in which the film and the fiber-reinforced resin layer are formed by layering or layering multiple layers. 55. The plate-like body as described in item 46 of the patent application scope, in which the fiber-reinforced resin layer is pseudo-adopted from the group consisting of: sulfacarb, glass fiber, and aromatic polyamide to be reinforced by the selected star By. 56. The plate-like body as described in item 47 of the patent application scope, in which the fiber-reinforced resin layer is reinforced by selected fibers composed of: master fibers, glass fibers, and aromatic polyamines. 57. The plate-shaped body as described in item 48 of the patent application scope / in which the fiber-reinforced resin is artificially reinforced by selected fibers reinforced by a group consisting of: master fiber, glass fiber and aromatic polyamide fiber. 58. The plate-like body as described in item 46 of the scope of the patent application> wherein the reinforcing fibers in the fiber-reinforced resin layer are sheet-shaped fibers that are aligned in one direction. 59. The plate-like body as described in item 47 of the patent application scope, wherein the reinforcing fibers in the fiber-reinforced resin layer are sheet-like ones that straighten the fiber in one direction. 60. The plate-like body as described in item 48 of the patent application scope, in which the fiber is strong (please read the precautions on the back before filling in this page). Installed. Ordered ♦ This paper scale is applicable to the Chinese National Standard (CNS) A 4 Specifications (210x297 mm) A7 B7 C7 D7 printed by the Monthly Industry and Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 6. The patented reinforced fiber in the resin layer is a H-shaped one that pulls the fiber to one direction. 6 1. The plate-like body as described in item 46 of the patent application, wherein the reinforcing fibers of the fiber-reinforced resin layer are selected from the group consisting of woven fabric, woven fabric, non-woven fabric, and cushion-like material. 62. The plate-shaped body as described in Item 47 of the patent scope, in which the reinforced fibers of the fiber-reinforced resin layer are selected from the group consisting of: fabric, braid, non-woven fabric and cushion . 63. The plate-like body as described in item 48 of the patent application scope, wherein the reinforcing fibers M of the fiber-reinforced resin layer are selected from the group consisting of: knitting, woven, non-woven fabric, and cushion-like objects. 64. The plate-like body as described in Item 46 of the patent scope, in which the film is made of aromatic polyamine. & 65.—A method of manufacturing a tubular body, which is a solid organic polymer with no melting point selected from the group consisting of an aromatic polyamide and a polyimide with a glass transition temperature of 2δ5 to 5001. At least one film composed of 700kg / nm2 to 1400U / Ca2 tensile elastic pseudo-number and 35kg / plane 2 to 45kg / ran2 tensile strength is selected from epoxy resin or polyphenylene sulfide, In the method in which at least one fiber-reinforced resin layer of a thermoplastic resin composed of polyether-ether ketone and polyether satin is wound and laminated to form a tubular body, the tensile force added to the film when winding the aforementioned film is 8kg / im2 or more. 66. The method as described in item 65 of the patent application scope, in which the film is a film made of aromatic polyamide and the resin used in the fiber-reinforced resin layer is Chen Qi resin; this paper is also applicable to China Standard (CNS) Grade 4 (210 X 297 male) 81.9.10,000 ---------- I—7 ---- ^ I (Please read the precautions on the back before filling this page ). Install. Order-