TW202306855A - Cover tape for packaging electronic components and electronic components package - Google Patents

Cover tape for packaging electronic components and electronic components package Download PDF

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TW202306855A
TW202306855A TW111112114A TW111112114A TW202306855A TW 202306855 A TW202306855 A TW 202306855A TW 111112114 A TW111112114 A TW 111112114A TW 111112114 A TW111112114 A TW 111112114A TW 202306855 A TW202306855 A TW 202306855A
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cover tape
packaging
sealant layer
tape
electronic components
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TW111112114A
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Chinese (zh)
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阿部皓基
山口啓太
上村祥司
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日商住友電木股份有限公司
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Publication of TW202306855A publication Critical patent/TW202306855A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Packaging Frangible Articles (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A cover tape for packaging electronic components according to the invention comprises a base material layer (1), an intermediate layer (2), and a sealant layer (3), in that order, wherein the sealant layer (3) contains an adhesive resin (A), the glass transition temperature of the adhesive resin (A) is greater than 60°C but does not exceed 120°C, and the tack strength of the sealant layer at 60°C is at least 0 N/cm 2but not more than 5.0 N/cm 2.

Description

電子零件包裝用蓋帶及電子零件包裝體Cover tape for electronic component packaging and electronic component package

本發明係有關一種電子零件包裝用蓋帶及電子零件包裝體。The present invention relates to a cover tape for packaging electronic parts and a packaging body for electronic parts.

以往,電晶體、二極體、電容器、壓電元件寄存器等電子零件在電子機器的製造現場中,(i)首先,收容於由連續地形成能夠收納電子零件之袋而成之載體帶和密封於上述載體帶之蓋帶構成之包裝體中實施熱封處理,(ii)然後,在捲繞於紙製或者塑膠製的捲軸上之狀態下,輸送至對電子電路基板等進行表面安裝之作業區域。然後,電子零件在上述作業區域內剝離上述包裝體的蓋帶後,從形成於載體帶之上述袋取出,表面安裝於電子電路基板等。In the past, electronic components such as transistors, diodes, capacitors, piezoelectric element registers, etc. were stored in the manufacturing site of electronic equipment, (i) First, they were stored in a carrier tape formed by continuously forming bags capable of storing electronic components and sealed Heat-sealing treatment is performed on the package body composed of the cover tape of the above-mentioned carrier tape, (ii) Then, in the state of being wound on a paper or plastic reel, it is transported to the surface mounting operation of the electronic circuit board, etc. area. Then, the electronic components are removed from the bag formed on the carrier tape after peeling off the cover tape of the package in the work area, and are surface-mounted on an electronic circuit board or the like.

尤其,對於蓋帶的接著性和剝離性,已經進行了各式各樣的探討。例如,在專利文獻1中,揭示了一種技術,著眼於載體帶與蓋帶之間的剝離電阻力的最大值與最小值的剝離電阻力比α,使剝離性適當。 [先前技術文獻] [專利文獻] In particular, various studies have been made on the adhesiveness and peelability of the cover tape. For example, Patent Document 1 discloses a technique for making the peelability appropriate by paying attention to the peel resistance ratio α between the maximum value and the minimum value of the peel resistance between the carrier tape and the cover tape. [Prior Art Literature] [Patent Document]

[專利文獻1]日本特開2017-171393號公報[Patent Document 1] Japanese Patent Laid-Open No. 2017-171393

[發明所欲解決之課題][Problem to be Solved by the Invention]

在從載體帶剝離蓋帶之步驟中,若從載體帶剝離蓋帶所需的強度即剝離強度過高,則在剝離蓋帶時載體帶振動,有時產生電子零件從儲存袋露出之現象。另一方面,若載體帶與蓋帶的接著強度低,則在封裝體的輸送中,有時蓋帶被剝離,封裝後的電子零件掉落。因此,對於蓋帶,要求相對於載體帶具有充分的接著強度,同時要求在安裝步驟中能夠順利地從載體帶剝離之剝離性。 又,在將由載體帶和蓋帶構成之包裝體輸送至進行表面安裝之作業區域之過程中,有時會成為高溫、高濕度環境。又,由於包裝體捲繞於捲軸上,因此成為在載體帶和蓋帶上施加一定壓力之狀態,載體帶和蓋帶成為在未熱封之部分亦接著之狀態,存在在安裝步驟中載體帶和蓋帶無法順暢地剝離之問題。因此,要求蓋帶具有如下性質:即使在高溫高濕度環境下對載體帶的未熱封之部分施加一定壓力之情況下,蓋帶亦不會與載體帶接著。 In the step of peeling the cover tape from the carrier tape, if the strength required to peel the cover tape from the carrier tape, ie, the peel strength, is too high, the carrier tape vibrates when the cover tape is peeled off, and electronic parts may protrude from the storage bag. On the other hand, if the adhesive strength between the carrier tape and the cover tape is low, the cover tape may be peeled off during the conveyance of the package, and the packaged electronic component may drop. Therefore, the cover tape is required to have sufficient adhesive strength with respect to the carrier tape, and at the same time, peelability that can be smoothly peeled off from the carrier tape in the mounting step is required. Moreover, in the process of conveying the package body which consists of a carrier tape and a cover tape to the work area which performs surface mounting, it may become a high-temperature and high-humidity environment. In addition, since the package is wound on the reel, a certain pressure is applied to the carrier tape and the cover tape, and the carrier tape and the cover tape are in the state of being bonded even at the unheated portion. The problem that the cover tape cannot be peeled off smoothly. Therefore, the cover tape is required to have a property that the cover tape will not be bonded to the carrier tape even when a certain pressure is applied to the unheat-sealed portion of the carrier tape in a high-temperature and high-humidity environment.

本發明的目的之一為提供一種蓋帶,其能夠以適度的接著強度與載體帶接著,且減少了載體帶與蓋帶在未熱封之部分黏住之情況,亦即與載體帶的「接著性」和與載體帶的「耐附著性」的平衡良好。 [解決課題之技術手段] One of the objects of the present invention is to provide a cover tape, which can be bonded to the carrier tape with moderate adhesive strength, and reduces the sticking of the carrier tape and the cover tape in the unheat-sealed part, that is, the "separation" between the carrier tape and the carrier tape. Good balance between "adhesion" and "adhesion resistance" to the carrier tape. [Technical means to solve the problem]

本發明人進行探討之結果,發現藉由在蓋帶的密封劑層中使用具有特定範圍的玻璃轉移溫度之樹脂,能夠解決上述課題。然後,完成了本發明。As a result of investigations by the present inventors, it was found that the above-mentioned problems can be solved by using a resin having a glass transition temperature in a specific range for the sealant layer of the cover tape. Then, the present invention was completed.

本發明如下。 一種電子零件包裝用蓋帶,其依序具有: 基材層; 中間層;及 密封劑層, 該密封劑層含有(A)接著性樹脂, 該(A)接著性樹脂的按照以下<玻璃轉移溫度的測量方法>測量之玻璃轉移溫度大於60℃且為120℃以下, 該密封劑層的藉由以下<黏著力的測量方法>測量之黏著力為0N/cm 2以上且5.0N/cm 2以下。 <玻璃轉移溫度的測量方法> 使用示差掃描熱量儀(DSC),以升溫條件10℃/分鐘使該(A)接著性樹脂的玻璃轉移溫度(℃)升溫至0℃~200℃,並在氮氣環境條件下進行測量。 <黏著力的測量方法> 將以接觸速度30mm/分鐘將接觸面積20mm 2的不鏽鋼材料按壓於該電子零件包裝用蓋帶的該密封劑層,以測量溫度60℃、接觸荷重25N保持20秒鐘後,以600mm/分鐘的速度剝離時的每單位面積的荷重的測量值設為60℃時的黏著力(N/cm 2)。 The present invention is as follows. A cover tape for electronic component packaging, which has in order: a base material layer; an intermediate layer; and a sealant layer, the sealant layer containing (A) adhesive resin, the (A) adhesive resin according to the following <glass transfer Measurement method of temperature> The measured glass transition temperature is greater than 60°C and less than 120°C, and the adhesive force of the sealant layer measured by the following <Measurement method of adhesion force> is 0 N/cm 2 or more and 5.0 N/cm 2 the following. <Measurement method of glass transition temperature> Using a differential scanning calorimeter (DSC), raise the glass transition temperature (°C) of the (A) adhesive resin to 0°C to 200°C at a temperature increase condition of 10°C/min, and heat it under nitrogen gas. measured under ambient conditions. <Measurement method of adhesive force> Press a stainless steel material with a contact area of 20mm 2 against the sealant layer of the cover tape for electronic component packaging at a contact speed of 30mm/min, and hold for 20 seconds at a measurement temperature of 60°C and a contact load of 25N Then, the measured value of the load per unit area when peeled at a speed of 600 mm/min was defined as the adhesive force (N/cm 2 ) at 60°C.

又,本發明如下。 一種電子零件包裝體,其具有: 載體帶,在凹部收容有電子零件;及 上述電子零件包裝用蓋帶, 將該密封劑層側接著於該載體帶上,以密封該電子零件。 [發明之效果] Also, the present invention is as follows. An electronic component packaging body, which has: a carrier tape containing electronic components in recesses; and The above-mentioned cover tape for packaging electronic parts, The sealant layer is side-bonded on the carrier tape to seal the electronic component. [Effect of Invention]

依據本發明,提供一種接著性與耐附著性的平衡良好的電子零件包裝用蓋帶。According to the present invention, there is provided a cover tape for electronic component packaging having a good balance between adhesiveness and adhesion resistance.

以下,使用圖式,對本發明的實施形態進行說明。另外,在所有的圖式中,對相同的構成要素標註相同的符號,並適當省略說明。又,圖為概略圖,與實際的尺寸比率並不一致。Hereinafter, embodiments of the present invention will be described using the drawings. In addition, in all drawings, the same code|symbol is attached|subjected to the same component, and description is abbreviate|omitted suitably. In addition, the figure is a schematic figure, and actual dimensional ratio does not match.

本說明書中的表述「丙烯酸」表示包含丙烯酸和甲基丙烯酸這兩者之概念。The expression "acrylic acid" in this specification shows the concept including both acrylic acid and methacrylic acid.

<電子零件包裝用蓋帶> 圖1係示意性地表示本實施形態的電子零件包裝用蓋帶的一例之圖。 本實施形態的電子零件包裝用蓋帶依序具備基材層1、中間層2及密封劑層3。 在電子零件包裝用蓋帶10中,通常,密封劑層3與載體帶接著。換言之,通常,圖1中的上表面側與載體帶接著。 又,各層亦可以由複數個層構成。 又,密封劑層3含有(A)接著性樹脂,(A)接著性樹脂的藉由規定方法測量之玻璃轉移溫度大於60℃且為120℃以下。 進而,密封劑層3的藉由規定方法測量之黏著力為0N/cm 2以上且5.0N/cm 2以下。 藉此,在本實施形態的電子零件包裝用蓋帶中,能夠使蓋帶與載體帶的接著性和耐附著性的平衡良好。 <Cover Tape for Packaging Electronic Components> FIG. 1 is a diagram schematically showing an example of the cover tape for packaging electronic components according to this embodiment. The cover tape for electronic component packaging of this embodiment includes a base material layer 1, an intermediate layer 2, and a sealant layer 3 in this order. In the cover tape 10 for packaging electronic components, usually, the sealant layer 3 is bonded to the carrier tape. In other words, generally, the upper surface side in FIG. 1 is bonded to the carrier tape. Moreover, each layer may consist of several layers. Moreover, the sealing compound layer 3 contains (A) adhesive resin, and the glass transition temperature of (A) adhesive resin measured by a predetermined method is more than 60 degreeC and 120 degreeC or less. Furthermore, the adhesive force of the sealant layer 3 measured by a predetermined method is not less than 0 N/cm 2 and not more than 5.0 N/cm 2 . Thereby, in the cover tape for electronic component packaging of this embodiment, the balance of the adhesiveness and adhesion resistance of a cover tape and a carrier tape can be made favorable.

電子零件包裝用蓋帶10的接著性與耐附著性的平衡優異的機制的詳細情況尚不明確,但藉由使用玻璃轉移溫度大於60℃之(A)接著性樹脂,將蓋帶與載體帶貼合而製成包裝體,即使在常溫環境或被輸送之環境中,樹脂亦為玻璃狀態,因此認為能夠抑制接著性,並且能夠使耐附著性良好。又,藉由使用玻璃轉移溫度為120℃以下的(A)接著性樹脂,在熱封溫度附近樹脂軟化,因此認為能夠賦予蓋帶和載體帶的良好的接著性。 另外,玻璃轉移溫度的上限較佳為118℃以下,更佳為116℃以下,進一步較佳為114℃以下。 The details of the mechanism for the excellent balance between adhesiveness and adhesion resistance of the cover tape 10 for electronic component packaging are not clear, but by using (A) adhesive resin with a glass transition temperature higher than 60°C, the cover tape and the carrier tape are bonded together. Bonded to form a package, the resin is in a glass state even in a normal temperature environment or a transported environment, so it is considered that the adhesiveness can be suppressed and the adhesion resistance can be improved. In addition, by using (A) an adhesive resin having a glass transition temperature of 120° C. or lower, the resin softens near the heat sealing temperature, and therefore it is considered that good adhesiveness between the cover tape and the carrier tape can be imparted. In addition, the upper limit of the glass transition temperature is preferably at most 118°C, more preferably at most 116°C, further preferably at most 114°C.

<其他層> 電子零件包裝用蓋帶10亦可以在各層之間設置接著層(未圖示)。依據該接著層,能夠提高各層之間的接著性。 作為形成接著層之材料,可舉出胺酯系的乾式層合用接著樹脂或者增黏塗層用接著樹脂。較佳地可舉出將聚酯多元醇或聚醚多元醇等聚酯組成物與異氰酸酯化合物組合而成之物質。 又,作為其他層,亦可以設置除了接著層以外的層。作為其他層,例如亦可以設置用於提高薄膜整體的強度的層、水蒸氣阻隔層等。 <Other layers> In the cover tape 10 for packaging electronic components, an adhesive layer (not shown) may be provided between layers. According to this adhesive layer, the adhesiveness between each layer can be improved. Examples of materials for forming the adhesive layer include urethane-based adhesive resins for dry lamination or adhesive resins for tack coats. Preferable examples include combinations of polyester compositions such as polyester polyol and polyether polyol, and isocyanate compounds. In addition, as other layers, layers other than the adhesive layer may be provided. As other layers, for example, a layer for increasing the strength of the entire film, a water vapor barrier layer, and the like may be provided.

<基材層> 基材層1只要具有能夠承受在電子零件包裝用蓋帶10的加工時,與載體帶的熱封時、使用時等施加之外力之機械強度及能夠承受熱封時的熱之耐熱性,則能夠使用加工各種材料之薄膜。 <Substrate layer> As long as the base material layer 1 has mechanical strength capable of withstanding external force applied during processing of the cover tape 10 for packaging electronic components, during heat sealing with the carrier tape, during use, etc., and heat resistance during heat sealing, then It can be used to process films of various materials.

作為構成基材層1之材料的具體例,可舉出酯系樹脂、醯胺系樹脂、烯烴系樹脂、丙烯酸酯系樹脂、甲基丙烯酸酯系樹脂、醯亞胺系樹脂、碳酸酯系樹脂、ABS樹脂等。其中,作為構成基材層1之材料,酯系樹脂及烯烴系樹脂為較佳。尤其,能夠提高機械強度之聚對苯二甲酸乙二酯(polyethylene terephthalate)、聚乙烯為較佳。又,在選擇醯胺系樹脂作為構成基材層1之材料之情況下,使用提高機械強度、柔軟性之尼龍為較佳。Specific examples of the material constituting the base layer 1 include ester-based resins, amide-based resins, olefin-based resins, acrylate-based resins, methacrylate-based resins, imide-based resins, and carbonate-based resins. , ABS resin, etc. Among them, ester-based resins and olefin-based resins are preferable as materials constituting the base material layer 1 . In particular, polyethylene terephthalate and polyethylene which can improve mechanical strength are preferable. Also, when an amide-based resin is selected as the material constituting the base material layer 1, it is preferable to use nylon which improves mechanical strength and flexibility.

作為用於形成基材層1之薄膜的形態,可以為拉伸薄膜,亦可以為沿單軸方向或雙軸方向拉伸之薄膜。從提高電子零件包裝用蓋帶的機械強度之觀點而言,沿單軸方向或雙軸方向拉伸之薄膜為較佳。As a form of the film for forming the base material layer 1, it may be a stretched film, and may be a film stretched in a uniaxial direction or a biaxial direction. From the viewpoint of improving the mechanical strength of the cover tape for packaging electronic components, a film stretched in a uniaxial direction or a biaxial direction is preferable.

基材層1可以由含有上述材料之單層膜形成,亦可以使用在各層中含有上述材料之多層膜來形成。 從減少伴隨載體帶的剝離而產生之靜電量之觀點而言,基材層1可以含有抗靜電劑,亦可以在基材層1中的與設置有中間層2之面相反側的面設置抗靜電層作為基材層中的一層。在將電子零件收容於由載體帶和電子零件包裝用蓋帶10構成之包裝體中進行輸送時,將複數個包裝體堆疊輸送之情況下,含有抗靜電劑之基材層1或抗靜電層的表面具有與堆疊在上面之包裝體的載體帶的底面接觸之可能性。 The base material layer 1 may be formed of a single-layer film containing the above materials, or may be formed using a multilayer film containing the above materials in each layer. From the standpoint of reducing the amount of static electricity associated with the peeling of the carrier tape, the substrate layer 1 may contain an antistatic agent, or an antistatic agent may be provided on the surface of the substrate layer 1 opposite to the surface on which the intermediate layer 2 is provided. The electrostatic layer serves as one of the substrate layers. When storing and transporting electronic components in a package composed of a carrier tape and a cover tape 10 for packaging electronic components, in the case of stacking and transporting a plurality of packages, the antistatic agent-containing base layer 1 or antistatic layer The surface has the possibility of coming into contact with the underside of the carrier tape of the package stacked above.

基材層1的厚度例如為6μm以上,較佳為7μm以上,進一步較佳為8μm以上。又,基材層1的厚度例如為35μm以下,較佳為33μm以下,進一步較佳為30μm以下。若基材層1的厚度為上述上限值以下,則電子零件包裝用蓋帶的剛性不會變得過高,即使對密封後的載體帶施加扭轉應力,亦能夠減少電子零件包裝用蓋帶10追隨載體帶的變形而剝離之可能性。又,若基材層1的厚度為上述下限值以上,則電子零件包裝用蓋帶10的機械強度適當,即使在從載體帶高速剝離電子零件包裝用蓋帶10之情況下,亦能夠減少電子零件包裝用蓋帶10斷裂之可能性。 另外,基材層1亦可以為第一基材層和第二基材層的雙層結構,或者具有更多層之三層以上的結構。在該情況下,材質例如能夠使用在基材層1中使用之材質。又,厚度成為第一基材層、第二基材層等的合計厚度成為「基材層1的厚度」為較佳。 The thickness of the base material layer 1 is, for example, 6 μm or more, preferably 7 μm or more, and more preferably 8 μm or more. Moreover, the thickness of the base material layer 1 is, for example, 35 μm or less, preferably 33 μm or less, more preferably 30 μm or less. If the thickness of the base material layer 1 is below the above-mentioned upper limit, the rigidity of the cover tape for packaging electronic components will not become too high, and even if torsional stress is applied to the carrier tape after sealing, the cover tape for packaging electronic components can be reduced. 10 Possibility of stripping following the deformation of the carrier tape. Also, if the thickness of the base material layer 1 is more than the above-mentioned lower limit, the mechanical strength of the cover tape 10 for packaging electronic components is appropriate, and even when the cover tape 10 for packaging electronic components is peeled off from the carrier tape at a high speed, it can be reduced. Possibility of breakage of the cover tape 10 for packaging electronic components. In addition, the base material layer 1 may also have a two-layer structure of a first base material layer and a second base material layer, or a structure of three or more layers having more layers. In this case, the material used for the base material layer 1 can be used, for example. Moreover, it is preferable that the total thickness of the 1st base material layer, the 2nd base material layer, etc. becomes "the thickness of the base material layer 1".

<中間層> 中間層2為以對本實施形態之電子零件包裝用蓋帶10賦予緩衝性之目的而設置之層。藉此,能夠提高密封時的電子零件包裝用蓋帶10與載體帶的密接性。 <Middle layer> The intermediate layer 2 is a layer provided for the purpose of imparting cushioning properties to the cover tape 10 for packaging electronic components of this embodiment. Thereby, the adhesiveness of the cover tape 10 for packaging electronic components and a carrier tape at the time of sealing can be improved.

中間層2只要能夠對電子零件包裝用蓋帶10賦予緩衝性,則材料沒有特別限定,例如可舉出選自聚丙烯酸衍生物、聚丙烯酸酯衍生物、聚乙酸乙烯酯衍生物、苯乙烯系樹脂、烯烴系樹脂、環狀烯烴樹脂中之1種或2種以上及它們的共聚物。其中,從性能平衡的觀點而言,聚丙烯酸衍生物、聚丙烯酸酯衍生物、烯烴系樹脂及環狀烯烴樹脂為較佳,烯烴系樹脂為更佳,乙烯系樹脂為進一步較佳。The material of the intermediate layer 2 is not particularly limited as long as it can impart cushioning properties to the cover tape 10 for packaging electronic components, and examples thereof include polyacrylic acid derivatives, polyacrylate derivatives, polyvinyl acetate derivatives, styrene-based One or more of resins, olefin resins, and cyclic olefin resins, and their copolymers. Among them, polyacrylic acid derivatives, polyacrylate derivatives, olefin-based resins, and cyclic olefin resins are preferred from the viewpoint of performance balance, olefin-based resins are more preferred, and vinyl-based resins are still more preferred.

從進一步提高密封時的電子零件包裝用蓋帶10與載體帶的密接性之觀點而言,中間層2的厚度典型為10μm以上且50μm以下,較佳為15μm以上且45μm以下。The thickness of the intermediate layer 2 is typically not less than 10 μm and not more than 50 μm, preferably not less than 15 μm and not more than 45 μm, from the viewpoint of further improving the adhesiveness between the cover tape 10 for packaging electronic components and the carrier tape during sealing.

<密封劑層> 密封劑層3含有(A)接著性樹脂,且設置於中間層2的與基材層1相接之面相反側的面側。密封劑層3通常在將電子零件包裝用蓋帶10密封(例如,熱封)於載體帶上時,與載體帶接觸。 通常,密封劑層3具有熱封性,能夠與載體帶接著,顯示出使用時能夠容易地剝離之易剝離性。 <Sealant layer> The sealant layer 3 contains (A) an adhesive resin, and is provided on the surface side of the intermediate layer 2 opposite to the surface in contact with the base material layer 1 . The sealant layer 3 is usually in contact with the carrier tape when the cover tape 10 for packaging electronic components is sealed (for example, heat-sealed) to the carrier tape. Usually, the sealant layer 3 has heat sealability, can be bonded to the carrier tape, and exhibits easy peelability that can be easily peeled off during use.

作為密封劑層3的(A)接著性樹脂的材料的具體例,可舉出選自丙烯酸系樹脂、苯乙烯系樹脂、烯烴系樹脂、胺酯系樹脂及酯系樹脂中之1種或2種以上及它們的共聚物等。其中,從良好地溶解或分散抗靜電劑之觀點而言,含有苯乙烯系樹脂、丙烯酸系樹脂及酯系樹脂中的至少1種以上為較佳。 作為苯乙烯系樹脂的具體例,可舉出聚苯乙烯、苯乙烯/丁二烯共聚物(SB)、苯乙烯/丁二烯/苯乙烯嵌段共聚物(SBS)、苯乙烯/乙烯/丁二烯/苯乙烯嵌段共聚物(SEBS)、苯乙烯/異戊二烯/苯乙烯嵌段共聚物(SIS)、苯乙烯/乙烯/丙烯/苯乙烯嵌段共聚物(SEPS)、苯乙烯-(甲基)丙烯酸甲酯共聚物、氫化苯乙烯嵌段共聚物、耐衝擊性聚苯乙烯(HIPS;High Impact Polystyrene)、通用聚苯乙烯樹脂(GPPS;General Purpose Polystyrene)等。亦可以將它們組合2種以上來使用。 其中,從透明性高,且均衡地提高耐附著性和剝離強度之觀點而言,作為使用苯乙烯/丁二烯共聚物(SB)為較佳之丙烯酸系樹脂的具體例,例如為丙烯酸、甲基丙烯酸、丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯、丙烯酸-2-乙基己酯等丙烯酸酯;甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丁酯等甲基丙烯酸酯;由丙烯腈、甲基丙烯腈、丙烯醯胺等單體構成之樹脂。作為丙烯酸系樹脂的構成單體,能夠含有該等例示中的1種或2種以上的單體。又,作為丙烯酸系樹脂的構成單體,亦可以還含有除了該等例示以外的單體。又,亦可以為該等單體的衍生物。 酯系樹脂為醇成分(典型為,二醇)與羧酸成分(典型為,二羧酸)縮聚而成之樹脂。作為醇成分的具體例,例如可舉出乙二醇、1,2-丙二醇、1,3-丙二醇、1,2-丁二醇、1,3-丁二醇、1,4-丁二醇、2,3-丁二醇、2,2-二甲基-1,3-丙二醇、1,6-己二醇、1,8-辛二醇、1,9-壬二醇、1,10-癸二醇、1,12-十二烷二醇等鏈或分支的脂肪族二醇、氫化雙酚A〔2,2-雙(4-羥基環己基)丙烷〕、氫化雙酚A的碳數2以上且4以下的環氧烷(平均加成莫耳數2以上且12以下)加成物等脂環式二醇、丙三醇、新戊四醇、三羥甲基丙烷、山梨糖醇等3元以上的多元醇。該等醇成分可以使用1種或2種以上。 作為羧酸成分,例如可舉出草酸、丙二酸、順丁烯二酸、反丁烯二酸、檸康酸、衣康酸、戊烯二酸、琥珀酸、己二酸、癸二酸、十二烷二酸、壬二酸、十二烷基琥珀酸、十二烯琥珀酸、辛烯基琥珀酸等鏈或分支的脂肪族二羧酸、偏苯三甲酸或其酸酐等3元以上的多元羧酸、鄰苯二甲酸、間苯二甲酸、對苯二甲酸芳香族二羧酸等芳香族二羧酸等。該等羧酸成分可以使用1種或2種以上。 Specific examples of the material of the (A) adhesive resin of the sealant layer 3 include one or two selected from acrylic resins, styrene resins, olefin resins, urethane resins, and ester resins. More than one species and their copolymers, etc. Among them, from the viewpoint of dissolving or dispersing the antistatic agent well, it is preferable to contain at least one or more of styrene-based resins, acrylic resins, and ester-based resins. Specific examples of styrene-based resins include polystyrene, styrene/butadiene copolymer (SB), styrene/butadiene/styrene block copolymer (SBS), styrene/ethylene/ Butadiene/styrene block copolymer (SEBS), styrene/isoprene/styrene block copolymer (SIS), styrene/ethylene/propylene/styrene block copolymer (SEPS), benzene Ethylene-(meth)methyl acrylate copolymer, hydrogenated styrene block copolymer, impact-resistant polystyrene (HIPS; High Impact Polystyrene), general-purpose polystyrene resin (GPPS; General Purpose Polystyrene), etc. These can also be used in combination of 2 or more types. Among them, from the standpoint of high transparency, and a balanced improvement in adhesion resistance and peel strength, styrene/butadiene copolymer (SB) is a specific example of acrylic resin that is preferable, such as acrylic acid, methacrylic acid Acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate and other acrylates; methyl methacrylate, ethyl methacrylate, butyl methacrylate and other methacrylates; A resin composed of monomers such as acrylonitrile, methacrylonitrile, and acrylamide. As a constituent monomer of the acrylic resin, one or two or more of these exemplified monomers can be contained. Moreover, as a constituent monomer of an acrylic resin, you may contain the monomer other than these illustrations further. In addition, derivatives of these monomers may also be used. The ester-based resin is a resin obtained by polycondensation of an alcohol component (typically, diol) and a carboxylic acid component (typically, dicarboxylic acid). Specific examples of alcohol components include ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, and 1,4-butanediol , 2,3-butanediol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, 1,8-octanediol, 1,9-nonanediol, 1,10 - Decanediol, 1,12-dodecanediol and other chain or branched aliphatic diols, hydrogenated bisphenol A [2,2-bis (4-hydroxycyclohexyl) propane], carbon of hydrogenated bisphenol A Alicyclic diols, glycerol, neopentylthritol, trimethylolpropane, sorbose, etc. Alcohols and other polyhydric alcohols with a valence of 3 or more. These alcohol components can be used 1 type or 2 or more types. Examples of the carboxylic acid component include oxalic acid, malonic acid, maleic acid, fumaric acid, citraconic acid, itaconic acid, glutaconic acid, succinic acid, adipic acid, and sebacic acid. , dodecanedioic acid, azelaic acid, dodecylsuccinic acid, dodecenylsuccinic acid, octenylsuccinic acid and other chain or branched aliphatic dicarboxylic acids, trimellitic acid or its anhydride, etc. Aromatic dicarboxylic acids such as the above polyvalent carboxylic acids, phthalic acid, isophthalic acid, terephthalic acid, and aromatic dicarboxylic acids, and the like. These carboxylic acid components can be used 1 type or 2 or more types.

密封劑層3的(A)接著性樹脂的使用示差掃描熱量儀(DSC)以升溫條件10℃/分鐘升溫至0℃~200℃,在氮氣環境條件下測量之玻璃轉移溫度(℃)大於60℃且為120℃以下,且較佳為118℃以下,更佳為116℃以下,進一步較佳為114℃以下。藉由使玻璃轉移溫度在上述範圍內,能夠使電子零件包裝用蓋帶的60℃黏著力在適當的範圍內,進而在將蓋帶與載體帶貼合而製成包裝體,用捲軸捲繞而保管之情況下,在除了藉由熱封接著之部分以外的部位,能夠抑制蓋帶與載體帶的接著。(A) Adhesive resin of sealant layer 3 uses a differential scanning calorimeter (DSC) to heat up to 0°C to 200°C at a temperature of 10°C/min, and the glass transition temperature (°C) measured under nitrogen ambient conditions is greater than 60 °C is 120°C or lower, preferably 118°C or lower, more preferably 116°C or lower, further preferably 114°C or lower. By keeping the glass transition temperature in the above range, the 60°C adhesive force of the cover tape for packaging electronic components can be kept in an appropriate range, and then the cover tape and the carrier tape are bonded together to form a package and wound on a reel On the other hand, in the case of storage, adhesion between the cover tape and the carrier tape can be suppressed at locations other than the portion bonded by heat sealing.

進而,由於上述密封劑層3的(A)接著性樹脂的玻璃轉移溫度(℃)大於60℃,因此即使在將由電子零件包裝用蓋帶和載體帶構成之包裝體在60℃前後的高溫或者高濕度環境下保管一定期間之情況下,亦容易將電子零件包裝用蓋帶對於載體帶的剝離強度的與初始值(剛熱封後)比較時的經時變化率控制於規定範圍內。認為這是因為,即使在60℃前後的高溫環境等中保管之情況下,由於密封劑層3的上述接著性樹脂的玻璃轉移溫度(℃)大於60℃,因此接著性樹脂能夠維持玻璃狀態。玻璃轉移溫度的下限值例如可以大於90℃,可以為91℃以上,亦可以為95℃以上,還可以為100℃以上。 藉由具有這樣的性質,即使在將由載體帶和蓋帶構成之包裝體輸送至進行表面安裝之作業區域之途中,或輸送後,亦能夠使對於載體帶的接著性和剝離性的平衡良好,能夠抑制在輸送中蓋帶剝離,收容於包裝體中之電子零件掉落,或在安裝步驟中蓋帶無法從載體帶順利地剝離之類的不良情況的產生。 Furthermore, since the glass transition temperature (°C) of the (A) adhesive resin of the sealant layer 3 is higher than 60°C, even at a high temperature of around 60°C or Even when stored in a high-humidity environment for a certain period of time, it is easy to control the rate of change over time in the peel strength of the cover tape for packaging electronic components to the carrier tape compared with the initial value (immediately after heat sealing) within a specified range. This is considered to be because the adhesive resin of the sealant layer 3 has a glass transition temperature (°C) higher than 60°C even when stored in a high-temperature environment around 60°C, so the adhesive resin can maintain a glass state. The lower limit of the glass transition temperature may be higher than 90°C, for example, 91°C or higher, 95°C or higher, or 100°C or higher. By having such a property, it is possible to achieve a good balance of adhesion and peelability to the carrier tape even when the package consisting of the carrier tape and the cover tape is transported to the work area for surface mounting or after transport, It is possible to suppress problems such as peeling of the cover tape during transportation, falling of the electronic components contained in the package, or failure of the cover tape to be smoothly peeled off from the carrier tape during the mounting process.

從降低密封劑層3的表面電阻值以抑制伴隨剝離之靜電的產生,並保持密封性之觀點而言,密封劑層3能夠進一步含有(B)抗靜電劑。在密封劑層3中,較佳為在(A)接著性樹脂中溶解或分散(B)抗靜電劑。亦即,較佳為(A)接著性樹脂與(B)抗靜電劑的相溶性良好,在作為矩陣樹脂的(A)接著性樹脂中,(B)抗靜電劑均勻地分散於整個密封劑層3上。作為溶解或分散的態樣,可舉出(B)抗靜電劑經由溶劑溶解於(A)接著性樹脂中之情況、和(B)抗靜電劑水分散於(A)接著性樹脂中之態樣,依據(A)接著性樹脂和(B)抗靜電劑的性質而不同。 作為(B)抗靜電劑的具體例,可舉出摻銻錫、導電性高分子(例如聚噻吩或聚噻吩衍生物)、摻磷錫、摻氟錫、碳奈米管等。從與(A)接著性樹脂的良好的相溶性等而言,(B)抗靜電劑含有由摻銻氧化錫、摻磷氧化錫、摻氟氧化錫及導電性高分子組成之群組中的1種以上為較佳。 The sealing compound layer 3 can further contain (B) an antistatic agent from a viewpoint of reducing the surface resistance value of the sealing compound layer 3, suppressing generation|occurrence|production of static electricity accompanying peeling, and maintaining sealing property. In the sealant layer 3 , it is preferable to dissolve or disperse (B) an antistatic agent in (A) adhesive resin. That is, it is preferable that the compatibility between (A) adhesive resin and (B) antistatic agent is good, and that (B) antistatic agent is uniformly dispersed throughout the sealant in (A) adhesive resin which is a matrix resin. on layer 3. Examples of the state of dissolution or dispersion include (B) the case where the antistatic agent is dissolved in the (A) adhesive resin via a solvent, and the state where (B) the antistatic agent is water-dispersed in (A) the adhesive resin Like this, it varies according to the properties of (A) adhesive resin and (B) antistatic agent. Specific examples of (B) antistatic agents include antimony-doped tin, conductive polymers (such as polythiophene or polythiophene derivatives), phosphorus-doped tin, fluorine-doped tin, and carbon nanotubes. In terms of good compatibility with (A) adhesive resin, etc., (B) the antistatic agent contains antimony-doped tin oxide, phosphorus-doped tin oxide, fluorine-doped tin oxide, and conductive polymers. One or more types are preferred.

作為導電性高分子即聚噻吩或聚噻吩的衍生物,例如可舉出聚噻吩、聚(3,4)-乙烯二氧噻吩、聚(3-噻吩-β-乙磺酸)等。其中,從保持更良好的抗靜電性和密封性之觀點而言,聚3,4-乙烯二氧噻吩或其衍生物為較佳。Examples of polythiophene or polythiophene derivatives that are conductive polymers include polythiophene, poly(3,4)-ethylenedioxythiophene, poly(3-thiophene-β-ethanesulfonic acid), and the like. Among them, poly-3,4-ethylenedioxythiophene or its derivatives are preferred from the viewpoint of maintaining better antistatic properties and sealing properties.

密封劑層3亦可以含有用於使抗靜電劑的分散性良好的分散劑、矽溶膠、調平劑、導電助劑等作為其他添加劑。The sealant layer 3 may contain, as other additives, a dispersant, a silica sol, a leveling agent, a conductive additive, and the like for improving the dispersibility of the antistatic agent.

從適當地進行密封作業和剝離作業之觀點而言,密封劑層3的厚度典型為0.02μm以上且20μm以下為較佳,0.03μm以上且15μm以下為更佳。The thickness of the sealant layer 3 is typically preferably not less than 0.02 μm and not more than 20 μm, more preferably not less than 0.03 μm and not more than 15 μm, from the viewpoint of properly performing the sealing operation and the peeling operation.

從薄膜強度擔保和操作性的平衡的觀點而言,本實施形態之電子零件包裝用蓋帶的厚度為40μm以上且65μm以下為較佳,45μm以上且60μm以下為更佳。From the standpoint of balance between film strength assurance and handleability, the thickness of the electronic component packaging cover tape of this embodiment is preferably 40 μm to 65 μm, more preferably 45 μm to 60 μm.

以下,對本實施形態之電子零件包裝用蓋帶的特性進行說明。Hereinafter, the characteristics of the cover tape for electronic component packaging of this embodiment will be described.

在本實施形態之電子零件包裝用蓋帶中,關於密封劑層3的黏著力,將以接觸速度30mm/分鐘將接觸面積20mm 2的不鏽鋼材料按壓於蓋帶的密封劑層3,以測量溫度60℃、接觸荷重25N保持20秒鐘後,以600mm/分鐘的速度剝離時的每單位面積的荷重的測量值設為60℃時的黏著力。 此時,從耐附著性的觀點而言,密封劑層3在60℃時的黏著力為5.0N/cm 2以下,較佳為4.5N/cm 2以下,進一步較佳為4.0N/cm 2以下。亦即,在低於60℃的熱封溫度的溫度時,藉由以密封劑層3的黏著力充分小的方式設計蓋帶,能夠得到良好的耐附著性。 60℃時的黏著力的下限值沒有限制,例如為0N/cm 2以上,具體而言為0.01N/cm 2以上。 In the cover tape for packaging electronic components of this embodiment, regarding the adhesive force of the sealant layer 3, a stainless steel material with a contact area of 20mm2 is pressed against the sealant layer 3 of the cover tape at a contact speed of 30mm/min to measure the temperature After holding at 60°C for 20 seconds under a contact load of 25N, the measured value of the load per unit area at the time of peeling at a speed of 600 mm/min was defined as the adhesive force at 60°C. At this time, from the viewpoint of adhesion resistance, the adhesive force of the sealant layer 3 at 60° C. is 5.0 N/cm 2 or less, preferably 4.5 N/cm 2 or less, more preferably 4.0 N/cm 2 the following. That is, at a temperature lower than the heat-sealing temperature of 60° C., good adhesion resistance can be obtained by designing the cover tape so that the adhesive force of the sealant layer 3 is sufficiently low. The lower limit of the adhesive force at 60° C. is not limited, and is, for example, 0 N/cm 2 or more, specifically, 0.01 N/cm 2 or more.

本實施形態之電子零件包裝用蓋帶與載體帶的「耐附著性」良好。亦即,抑制了本實施形態之電子零件包裝用蓋帶與載體帶在未熱封之部分黏住。 對於該「耐附著性」,能夠藉由以下<耐附著性試驗>進行定量化。換言之,藉由將以下<耐附著性試驗>中測量之接著痕的長度作為設計指標來設計蓋帶,能夠製造性能更良好的蓋帶。 The "adhesion resistance" of the cover tape for packaging electronic components and the carrier tape of this embodiment is good. That is, sticking of the cover tape for electronic component packaging and the carrier tape in the present embodiment is suppressed at the unheat-sealed portion. This "adhesion resistance" can be quantified by the following <adhesion resistance test>. In other words, by designing the cover tape using the length of the bonding mark measured in the following <adhesion resistance test> as a design index, it is possible to manufacture a cover tape with better performance.

<耐附著性試驗> 在本實施形態之電子零件包裝用蓋帶中,將該電子零件包裝用蓋帶設為寬度10.0mm的尺寸,將該蓋帶的密封劑層側與寬度為8.0mm的尺寸,且凹凸面的平均表面粗糙度(Ra)為0.25μm之聚苯乙烯製薄膜的凹凸面側重合,作為樣品。在該樣品的蓋帶的上表面放置接地部分的寬度為0.5mm,長度為32.0mm,重量為46.0g的剖面為U字型的密封鐵,在60℃90%RH的條件下靜置24小時。靜置後,以附著於聚苯乙烯製薄膜之接著痕評價有無聚苯乙烯製薄膜與該電子零件包裝用蓋帶的接著。具體而言,在附著於聚苯乙烯製薄膜之接著痕中,將聚苯乙烯製薄膜的長度方向的尺寸作為附著於聚苯乙烯製薄膜之接著痕的長度進行測量。附著於聚苯乙烯製薄膜之接著痕的長度較佳為15mm以下,更佳為13mm以下,進一步較佳為11mm以下。附著於聚苯乙烯製薄膜之接著痕的長度的下限值沒有限制,例如為0mm以上。 順帶一提,如上述那樣的形狀/大小的密封鐵例如能夠從作為密封機製造商之Tokyo Weld公司獲得。 <Adhesion Resistance Test> In the cover tape for packaging electronic components of this embodiment, the cover tape for packaging electronic components has a width of 10.0 mm, the sealant layer side of the cover tape has a width of 8.0 mm, and the uneven surface A polystyrene film with an average surface roughness (Ra) of 0.25 μm was used as a sample, with the concave and convex sides superimposed on each other. On the upper surface of the cover tape of this sample, a sealing iron with a U-shaped cross-section with a grounding part width of 0.5mm, a length of 32.0mm, and a weight of 46.0g was placed, and it was left to stand for 24 hours at 60°C and 90%RH. . After standing still, the presence or absence of adhesion between the polystyrene film and the cover tape for packaging electronic components was evaluated by the adhesion marks attached to the polystyrene film. Specifically, in the adhesive trace attached to the polystyrene film, the dimension of the longitudinal direction of the polystyrene film was measured as the length of the adhesive trace attached to the polystyrene film. The length of the adhesive mark attached to the polystyrene film is preferably at most 15 mm, more preferably at most 13 mm, further preferably at most 11 mm. The lower limit of the length of the adhesive mark attached to the polystyrene film is not limited, and is, for example, 0 mm or more. Incidentally, a sealing iron having the above-mentioned shape and size can be obtained from Tokyo Weld Co., Ltd., which is a manufacturer of a sealing machine, for example.

藉由以上述接著痕的長度成為15mm以下之方式設計電子零件包裝用蓋帶,在將電子零件包裝用蓋帶與載體帶貼合而製成包裝體,用捲軸捲繞而保管之情況下,在除了藉由熱封接著之部分以外的部位,能夠進一步抑制蓋帶與載體帶的接著。亦即,能夠進一步提高耐附著性。By designing the cover tape for electronic component packaging so that the length of the above-mentioned adhesive line becomes 15 mm or less, when the cover tape for electronic component packaging and the carrier tape are bonded together to form a package, and the package is wound on a reel and stored, Adhesion between the cover tape and the carrier tape can be further suppressed at locations other than the portion bonded by heat sealing. That is, adhesion resistance can be further improved.

本實施形態之電子零件包裝用蓋帶與載體帶的接著性(與載體帶的熱封性)良好。對此,例如能夠藉由以下<熱封試驗>進行定量化。換言之,藉由將由以下<熱封試驗>得到之剝離強度作為設計指標來設計蓋帶,能夠製造與載體帶的接著性更良好的蓋帶。The cover tape for electronic component packaging of this embodiment has good adhesion to the carrier tape (heat sealability with the carrier tape). This can be quantified by the following <heat seal test>, for example. In other words, by designing the cover tape using the peel strength obtained from the following <heat seal test> as a design index, it is possible to manufacture a cover tape with better adhesion to the carrier tape.

<熱封試驗> 將電子零件包裝用蓋帶製成寬度5.5mm的尺寸,將該電子零件包裝用蓋帶的密封劑層側與寬度為8mm的尺寸,且凹凸面的平均表面粗糙度(Ra)為0.25μm之聚苯乙烯製薄膜的上述凹凸面側貼合,使用單刃為寬度0.4mm、長度28mm的尺寸的雙刃熱封刀,在密封溫度180℃、荷重5kgf、密封時間60毫秒鐘、載體帶輸送間距4mm的條件下進行熱封,作為樣品。使用該樣品,在剝離速度300mm/分鐘、測量溫度25℃、剝離角度170°的條件下進行剝離試驗。該試驗中的剝離強度的下限值較佳為0.2N以上,更佳為0.22N以上,進一步較佳為0.23N以上。又,剝離強度的上限值較佳為0.9N以下,更佳為0.8N以下,進一步較佳為0.7N以下。藉由使該剝離強度在上述範圍內,能夠使對於載體帶的接著性和剝離性的平衡進一步良好。 <Heat seal test> The cover tape for packaging electronic parts is made into a size with a width of 5.5 mm, and the sealant layer side of the cover tape for packaging electronic parts is 8 mm in width, and the average surface roughness (Ra) of the uneven surface is 0.25 μm or less. The above-mentioned concave-convex side of the polystyrene film is bonded, using a double-edged heat-sealing knife with a single blade width of 0.4 mm and a length of 28 mm, at a sealing temperature of 180 ° C, a load of 5 kgf, a sealing time of 60 milliseconds, and a carrier belt. Heat-sealing was carried out under the condition of a distance of 4mm, and it was used as a sample. Using this sample, a peeling test was performed under conditions of a peeling speed of 300 mm/min, a measurement temperature of 25° C., and a peeling angle of 170°. The lower limit of the peel strength in this test is preferably at least 0.2N, more preferably at least 0.22N, still more preferably at least 0.23N. In addition, the upper limit of the peel strength is preferably at most 0.9N, more preferably at most 0.8N, even more preferably at most 0.7N. By making this peel strength into the said range, the balance of the adhesiveness with respect to a carrier tape, and peelability can be made more favorable.

<熱封試驗後,在60℃環境下保管時的剝離強度> 對將由電子零件用蓋帶和載體帶構成之包裝體在高溫保管時的剝離強度進行說明。 將上述<熱封試驗>中得到之樣品在60℃保管30天後,用與上述<熱封試驗>相同的方法對170℃剝離強度進行測量。此時,剝離強度的下限值較佳為0.10N以上,更佳為0.11N以上,進一步較佳為0.12N以上。又,剝離強度的上限值較佳為1.35N以下,更佳為1.20N以下,進一步較佳為1.05N以下。 藉由使該剝離強度在上述範圍內,將載體帶與蓋帶貼合而成之包裝體輸送、保管等之情況下,亦能夠使對於載體帶的接著性和剝離性的平衡進一步良好。 <Peel strength when stored at 60°C after the heat seal test> The peel strength of a package composed of a cover tape for electronic parts and a carrier tape during storage at high temperature will be described. After storing the samples obtained in the above <Heat Seal Test> at 60°C for 30 days, the 170°C peel strength was measured by the same method as in the above <Heat Seal Test>. In this case, the lower limit of the peel strength is preferably at least 0.10N, more preferably at least 0.11N, and still more preferably at least 0.12N. In addition, the upper limit of the peel strength is preferably at most 1.35N, more preferably at most 1.20N, even more preferably at most 1.05N. By setting the peel strength within the above range, the balance of adhesiveness and peelability to the carrier tape can be further improved even in the case of conveyance, storage, etc. of a package in which the carrier tape and the cover tape are bonded together.

<熱封試驗後,在60℃90%RH環境下保管時的剝離強度> 對將由電子零件用蓋帶和載體帶構成之包裝體在高溫高濕保管時的剝離強度進行說明。 將上述<熱封試驗>中得到之樣品在60℃90%RH的條件下保管30天後,用與上述<熱封試驗>相同的方法對170℃剝離強度進行測量。此時,剝離強度的下限值較佳為0.10N以上,更佳為0.11N以上,進一步較佳為0.12N以上。又,剝離強度的上限值較佳為1.35N以下,更佳為1.20N以下,進一步較佳為1.05N以下。 藉由使該剝離強度在上述範圍內,將載體帶與蓋帶貼合而成之包裝體輸送、保管等之情況下,亦能夠使對於載體帶的接著性和剝離性的平衡進一步良好。 <Peel strength when stored at 60℃90%RH after heat seal test> The peel strength of a package composed of a cover tape for electronic parts and a carrier tape during high-temperature and high-humidity storage will be described. After the samples obtained in the above <Heat Seal Test> were stored at 60°C and 90%RH for 30 days, the 170°C peel strength was measured in the same manner as in the above <Heat Seal Test>. In this case, the lower limit of the peel strength is preferably at least 0.10N, more preferably at least 0.11N, and still more preferably at least 0.12N. In addition, the upper limit of the peel strength is preferably at most 1.35N, more preferably at most 1.20N, even more preferably at most 1.05N. By setting the peel strength within the above range, the balance of adhesiveness and peelability to the carrier tape can be further improved even in the case of conveyance, storage, etc. of a package in which the carrier tape and the cover tape are bonded together.

<熱封試驗後,在60℃環境下保管後的剝離強度的變化率> 對將由電子零件用蓋帶和載體帶構成之包裝體在高溫保管時的經時變化定量化之情況進行說明。 將上述<熱封試驗>中測量之170℃剝離強度(亦即剛熱封後的剝離強度)作為P,將上述<熱封試驗後,在60℃環境下保管後的剝離強度>中測量之170℃剝離強度設為P1。以將60℃保管後的剝離強度相對於剛熱封後的剝離強度初始值的變化率作為絕對值之值(|((P1-P)/P)×100|)(%)的上限值較佳為50%以下,更佳為40%以下,進一步較佳為35%以下。又,將剝離強度的變化率作為絕對值之值的下限值沒有特別限制,例如為0%以上。 藉由使該變化率在上述範圍內,將載體帶與蓋帶貼合而成之包裝體輸送、保管等之情況下,亦能夠使對於載體帶的接著性和剝離性的平衡進一步良好。 <Change in peel strength after heat seal test and storage at 60°C> The case of quantifying the time-dependent change of a package composed of a cover tape for electronic parts and a carrier tape during high-temperature storage will be described. The 170°C peel strength measured in the above <heat seal test> (that is, the peel strength immediately after heat sealing) is taken as P, and the peel strength measured in the above <heat seal test after storage at 60°C> The 170°C peel strength was set to P1. The upper limit of the absolute value (|((P1-P)/P)×100|) (%) of the change rate of the peel strength after storage at 60°C relative to the initial value of the peel strength immediately after heat sealing Preferably it is 50% or less, More preferably, it is 40% or less, More preferably, it is 35% or less. Also, the lower limit of the absolute value of the rate of change in peel strength is not particularly limited, and is, for example, 0% or more. By setting the rate of change within the above range, the balance of adhesiveness and peelability to the carrier tape can be further improved even in the case of conveyance, storage, etc. of a package in which the carrier tape and the cover tape are bonded together.

<熱封試驗後,在60℃90%RH環境下保管後的剝離強度的變化率> 對將由電子零件用蓋帶和載體帶構成之包裝體在高溫高濕保管時的經時變化定量化之情況進行說明。 將上述<熱封試驗>中測量之170℃剝離強度(亦即剛熱封後的剝離強度)作為P,將上述<熱封試驗後,在60℃90%RH環境下保管後的剝離強度>中測量之170℃剝離強度設為P2。將60℃保管後的剝離強度相對於剛熱封後的剝離強度初始值的變化率作為絕對值之值(|((P2-P)/P)×100|)(%)的上限值較佳為50%以下,更佳為40%以下,進一步較佳為35%以下。又,將剝離強度的變化率作為絕對值之值的下限值沒有特別限制,例如為0%以上。 藉由使該變化率在上述範圍內,將載體帶與蓋帶貼合而成之包裝體輸送、保管等之情況下,亦能夠使對於載體帶的接著性和剝離性的平衡進一步良好。 <Change in peel strength after heat seal test and storage at 60°C 90%RH> The case of quantifying the time-dependent change of a package composed of a cover tape and a carrier tape for electronic components during storage at high temperature and high humidity will be described. Let the peel strength at 170°C measured in the above <heat seal test> (that is, the peel strength immediately after heat sealing) be P, and the above <peel strength after heat seal test and storage at 60°C and 90%RH> The 170°C peel strength measured in the middle is set as P2. The upper limit of the absolute value (|((P2-P)/P)×100|) (%) of the change rate of the peel strength after storage at 60°C relative to the initial value of the peel strength immediately after heat sealing Preferably it is 50% or less, More preferably, it is 40% or less, More preferably, it is 35% or less. Also, the lower limit of the absolute value of the rate of change in peel strength is not particularly limited, and is, for example, 0% or more. By setting the rate of change within the above range, the balance of adhesiveness and peelability to the carrier tape can be further improved even in the case of conveyance, storage, etc. of a package in which the carrier tape and the cover tape are bonded together.

本實施形態之電子零件包裝用蓋帶的在25℃50%RH的條件下測量之上述基材層的表面的表面電阻值較佳為1.0×10 3Ω以上,更佳為1.0×10 4Ω以上,進一步較佳為1.0×10 5Ω以上,且較佳為1.0×10 13Ω以下,更佳為1.0×10 12Ω以下,進一步較佳為1.0×10 11Ω以下。藉由使電子零件包裝用蓋帶的上述基材層的表面電阻值在上述範圍內,能夠將因各種原因產生之靜電高效率地釋放到外部。 另外,上述基材層的表面係指上述電子零件包裝用蓋帶的基材層的露出面側(亦即,係指上述基材層的不與上述中間層相接之面)。 The surface resistance value of the surface of the above-mentioned substrate layer measured under the condition of 25°C and 50%RH of the cover tape for packaging electronic parts according to this embodiment is preferably 1.0×10 3 Ω or more, more preferably 1.0×10 4 Ω Above, more preferably 1.0×10 5 Ω or more, and preferably 1.0×10 13 Ω or less, more preferably 1.0×10 12 Ω or less, still more preferably 1.0×10 11 Ω or less. By setting the surface resistance value of the base material layer of the cover tape for packaging electronic components within the above range, static electricity generated due to various causes can be efficiently released to the outside. In addition, the surface of the base layer refers to the exposed side of the base layer of the cover tape for packaging electronic components (that is, the surface of the base layer that is not in contact with the intermediate layer).

本實施形態之電子零件包裝用蓋帶的在25℃、50%RH的條件下測量之上述密封劑層的表面的表面電阻值較佳為1.0×10 3Ω以上,更佳為1.0×10 4Ω以上,進一步較佳為1.0×10 5Ω以上,且較佳為1.0×10 12Ω以下,更佳為1.0×10 11Ω以下,進一步較佳為1.0×10 10Ω以下。藉由使電子零件包裝用蓋帶的在25℃、50%RH的條件下測量之上述密封劑層的表面的表面電阻值在上述範圍內,能夠製成伴隨載體帶的剝離之抗靜電性更優異的電子零件包裝用蓋帶。 另外,上述密封劑層的表面係指上述電子零件包裝用蓋帶的密封劑層的露出面側(亦即,係指上述密封劑層的不與上述中間層相接之面)。 The surface resistance value of the surface of the sealant layer measured under the conditions of 25°C and 50%RH of the cover tape for packaging electronic parts according to this embodiment is preferably 1.0×10 3 Ω or more, more preferably 1.0×10 4 Ω or more, more preferably 1.0×10 5 Ω or more, and preferably 1.0×10 12 Ω or less, more preferably 1.0×10 11 Ω or less, further preferably 1.0×10 10 Ω or less. By making the surface resistance value of the surface of the sealant layer of the cover tape for electronic component packaging measured under the conditions of 25°C and 50%RH fall within the above range, it is possible to make the antistatic property better accompanying the peeling of the carrier tape. Excellent cover tape for electronic parts packaging. In addition, the surface of the sealant layer refers to the exposed surface side of the sealant layer of the cover tape for packaging electronic components (that is, the surface of the sealant layer that is not in contact with the intermediate layer).

本實施形態之電子零件包裝用蓋帶的依據JIS K 7361-1(1997)之利用光源D65測量時的總透光率較佳為70%以上,更佳為75%以上,進一步較佳為80%以上,且較佳為95%以下,更佳為94%以下,進一步較佳為93%以下。藉此,在由電子零件包裝用蓋帶10和載體帶構成之包裝體100中,能夠賦予能夠檢查電子零件是否正確地收容於上述載體帶的袋內之程度的透明性。亦即,藉由將電子零件包裝用蓋帶的總透光率設為上述下限值以上,能夠從該包裝體100的外部目視確認收容於由電子零件包裝用蓋帶10和載體帶構成之包裝體100的內部之電子零件。The total light transmittance of the cover tape for electronic component packaging according to the present embodiment is preferably 70% or more, more preferably 75% or more, and still more preferably 80% when measured with light source D65 based on JIS K 7361-1 (1997). % or more, and preferably less than 95%, more preferably less than 94%, further preferably less than 93%. Thereby, in the package body 100 which consists of the cover tape 10 for packaging electronic components, and the carrier tape, the transparency of the grade which can check whether electronic components are accommodated correctly in the pocket of the said carrier tape can be provided. That is, by setting the total light transmittance of the cover tape for packaging electronic components to be equal to or greater than the above-mentioned lower limit value, it is possible to visually confirm the package contained in the cover tape 10 and the carrier tape from the outside of the package 100 . Electronic components inside the packaging body 100 .

本實施形態之電子零件包裝用蓋帶的依據JIS K 7136(2000)之利用光源D65測量之外部霧度較佳為5%以上,更佳為6%以上,最佳為7%以上,且較佳為50%以下,更佳為45%以下,最佳為40%以下。藉由將電子零件包裝用蓋帶的外部霧度設為上述上限值以下,在由電子零件包裝用蓋帶10和載體帶構成之包裝體中,能夠賦予能夠檢查電子零件是否正確地收容於上述載體帶的袋內之程度的透明性。The external haze of the cover tape for electronic component packaging according to the present embodiment measured by light source D65 based on JIS K 7136 (2000) is preferably 5% or more, more preferably 6% or more, most preferably 7% or more, and is relatively Preferably it is less than 50%, more preferably less than 45%, most preferably less than 40%. By setting the external haze of the cover tape for packaging electronic parts below the above-mentioned upper limit, in the package composed of the cover tape 10 for packaging electronic parts and the carrier tape, it is possible to provide The degree of transparency inside the bag of the above-mentioned carrier tape.

在本實施形態中,例如藉由適當地選擇構成電子零件包裝用蓋帶之基材層1、中間層2、密封劑層3中所含有之各成分的種類、性質或摻合量、電子零件包裝用蓋帶的製作方法等條件,能夠控制上述電子零件包裝用蓋帶在60℃時的黏著力。又,在本實施形態中,除了在密封劑層3中使用具有特定範圍的玻璃轉移溫度之(A)接著性樹脂以外,還藉由進一步鑽研其他條件,能夠抑制上述聚苯乙烯製薄膜與蓋帶的不需要的接著,能夠控制基材層1的表面電阻值、密封劑層3的表面電阻值、總透光率及外部霧度中的1個或2個以上。藉此,在電子零件包裝用蓋帶中,在將蓋帶與載體帶貼合而製成包裝體時的輸送中,在除了藉由熱封接著之部分以外的部位,能夠抑制產生蓋帶與載體帶的接著,能夠抑制剝離時的靜電,更能夠賦予能夠從外部目視確認電子零件之程度的透明性。In this embodiment, for example, by appropriately selecting the types, properties, or blending amounts of the components contained in the base material layer 1, the intermediate layer 2, and the sealant layer 3 constituting the cover tape for packaging electronic parts, the electronic parts Conditions such as the production method of the cover tape for packaging can control the adhesive force of the above-mentioned cover tape for packaging electronic components at 60°C. In addition, in this embodiment, in addition to using (A) an adhesive resin having a glass transition temperature in a specific range for the sealant layer 3, by further studying other conditions, it is possible to suppress the above-mentioned polystyrene film and cover. One or more of the surface resistance value of the base material layer 1, the surface resistance value of the sealant layer 3, the total light transmittance, and the external haze can be controlled. Thereby, in the cover tape for electronic component packaging, when the cover tape and the carrier tape are bonded together to form a package, it is possible to suppress the generation of the cover tape and the carrier tape at parts other than the portion bonded by heat sealing. The adhesion of the carrier tape can suppress static electricity at the time of peeling, and can provide transparency to the extent that electronic components can be visually recognized from the outside.

<電子零件包裝用蓋帶之製造方法> 對本實施形態之電子零件包裝用蓋帶之製造方法的一例進行說明。 首先,在基材層1的表面形成中間層2。中間層2的形成例如能夠藉由擠出層合法或乾式層合法來形成。接著,在中間層2上,使用規定材料製作密封劑層塗佈液,藉由塗佈法塗佈並乾燥,或藉由擠出層合法積層,藉此形成密封劑層3。 作為密封劑層塗佈液的製作方法,可舉出將(A)接著性樹脂的水分散體和(B)抗靜電劑的水分散體進行混合之方法、藉由溶劑將(A)接著性樹脂和(B)抗靜電劑進行混合之方法。依據(A)接著性樹脂及(B)抗靜電劑的種類選擇任一種方法。 <Manufacturing method of cover tape for packaging electronic parts> An example of the manufacturing method of the cover tape for electronic component packaging of this embodiment is demonstrated. First, the intermediate layer 2 is formed on the surface of the base material layer 1 . The intermediate layer 2 can be formed by, for example, extrusion lamination or dry lamination. Next, on the intermediate layer 2 , a sealant layer coating liquid is prepared using a predetermined material, applied by a coating method and dried, or laminated by an extrusion lamination method to form a sealant layer 3 . Examples of methods for preparing the sealant layer coating solution include mixing (A) an aqueous dispersion of an adhesive resin and (B) an aqueous dispersion of an antistatic agent, and mixing (A) an adhesive resin with a solvent. The method of mixing resin and (B) antistatic agent. Choose any method according to the type of (A) adhesive resin and (B) antistatic agent.

又,在形成上述接著層之情況下,只要藉由以往公知的塗佈方法,在成為對象之層的面上塗佈接著層的材料即可。Moreover, when forming the said adhesive layer, what is necessary is just to coat the material of an adhesive layer on the surface of a target layer by the conventionally well-known coating method.

本實施形態之電子零件包裝用蓋帶能夠貼附於載體帶上作為包裝體使用。亦即,製成如下包裝體為較佳,該包裝體具備:具有收納電子零件之複數個收納部之載體帶、收納於上述收納部中之電子零件及以覆蓋上述收納部之方式配置之上述電子零件包裝用蓋帶。 若為這樣的包裝體,則能夠抑制靜電的產生,能夠更確實地保護收納於收納部中之電子零件免受靜電影響。 The cover tape for packaging electronic components of this embodiment can be attached to a carrier tape and used as a package. That is, it is preferable to manufacture a package comprising: a carrier tape having a plurality of storage sections for storing electronic components, the electronic components stored in the storage sections, and the above-mentioned storage sections arranged so as to cover the storage sections. Cover tape for electronic parts packaging. According to such a package, generation|occurrence|production of static electricity can be suppressed, and the electronic component accommodated in a storage part can be protected more reliably from static electricity.

<電子零件包裝體> 由上述中說明之本實施形態的電子零件包裝用蓋帶和在凹部收容有電子零件之載體帶,能夠得到電子零件包裝體。對此,參閱圖2進行說明。 <Electronic parts package> An electronic component package can be obtained from the cover tape for packaging electronic components of the present embodiment described above and the carrier tape in which the electronic components are housed in the recesses. This will be described with reference to FIG. 2 .

在圖2中,電子零件包裝用蓋帶10用作帶狀的載體帶20的蓋材,該帶狀的載體帶20的蓋材配合電子零件的形狀而連續地設置有凹狀的袋21。 具體而言,電子零件包裝用蓋帶10以覆蓋載體帶20的袋21的開口部整面之方式接著(通常為熱封)於載體帶20的表面。另外,以後,將電子零件包裝用蓋帶10與載體帶20接著而得到之結構體稱為電子零件包裝體100。 In FIG. 2 , a cover tape 10 for packaging electronic components is used as a cover material for a belt-shaped carrier tape 20 with concave pockets 21 continuously provided in accordance with the shape of the electronic components. Specifically, the cover tape 10 for packaging electronic components is bonded (usually heat-sealed) to the surface of the carrier tape 20 so as to cover the entire opening of the bag 21 of the carrier tape 20 . In addition, hereafter, the structure which bonded the cover tape 10 for electronic component packaging, and the carrier tape 20 is called the electronic component packaging body 100.

電子零件包裝體100例如能夠按照以下步驟製作。 首先,在載體帶20的袋21內收容電子零件。 接著,以覆蓋載體帶20的袋21的開口部整面之方式,藉由熱封法將電子零件包裝用蓋帶10接著於載體帶20的表面上。此時,使電子零件包裝用蓋帶10中的密封劑層3與載體帶20相接(亦即,使圖2中的電子零件包裝用蓋帶10的「背面」成為密封劑層3而進行熱封)。 只要電子零件包裝用蓋帶10與載體帶20充分牢固地接著,則熱封的具體方法或條件沒有特別限定。典型為,使用公知的熱封機,能夠在溫度100~240℃、荷重0.1~10kgf、時間0.0001~1秒的範圍內進行。 The electronic component package 100 can be produced in the following steps, for example. First, electronic components are accommodated in the pocket 21 of the carrier tape 20 . Next, the cover tape 10 for packaging electronic components is adhered to the surface of the carrier tape 20 by a heat-sealing method so as to cover the entire surface of the opening of the bag 21 of the carrier tape 20 . At this time, the sealant layer 3 in the cover tape 10 for packaging electronic components is brought into contact with the carrier tape 20 (that is, the "back side" of the cover tape 10 for packaging electronic components in FIG. heat seal). As long as the cover tape 10 for electronic component packaging and the carrier tape 20 are sufficiently firmly bonded, the specific method and conditions of heat sealing are not particularly limited. Typically, using a known heat sealer, it can be carried out within the range of temperature 100-240° C., load 0.1-10 kgf, and time 0.0001-1 second.

藉此,得到密封收容有電子零件之結構體(電子零件包裝體100)。 該結構體(電子零件包裝體100)例如捲繞於捲軸上,然後輸送至將電子零件安裝於電子電路基板等上之作業區域。捲軸的材料可以為金屬製、紙製、塑膠製等。 Thereby, a structure (electronic component package 100 ) in which electronic components are hermetically accommodated is obtained. This structure (electronic component package 100 ), for example, is wound up on a reel, and then conveyed to a working area where electronic components are mounted on an electronic circuit board or the like. The material of the scroll can be metal, paper, plastic or the like.

在電子零件包裝體100輸送至作業區域後,將電子零件包裝用蓋帶10從載體帶20剝離,取出所收容之電子零件。After the electronic component package 100 is transported to the work area, the electronic component packaging cover tape 10 is peeled off from the carrier tape 20 to take out the housed electronic components.

收容於電子零件包裝體100內之電子零件沒有特別限定。能夠舉出半導體晶片、電晶體、二極體、電容器、壓電元件、光學元件、LED相關構件、連接器、電極等用於電氣電子機器的製造之全部零件。The electronic components accommodated in the electronic component package 100 are not particularly limited. Examples include semiconductor wafers, transistors, diodes, capacitors, piezoelectric elements, optical elements, LED-related components, connectors, electrodes, and all other parts used in the manufacture of electrical and electronic equipment.

以上,對本發明的實施形態詳細地進行了說明,但該等僅為本發明的例示。又,能夠採用除了上述以外的各式各樣的結構。又,本發明並不限定於上述實施形態。 [實施例] As mentioned above, although embodiment of this invention was described in detail, these are only illustrations of this invention. In addition, various configurations other than the above can be adopted. In addition, this invention is not limited to the said embodiment. [Example]

基於實施例及比較例對本發明的實施形態詳細地進行說明,但本發明並不限定於該等。Embodiments of the present invention will be described in detail based on Examples and Comparative Examples, but the present invention is not limited thereto.

表1及表2所示之密封劑層的各構成材料如下。 (接著性樹脂) ・樹脂1:苯乙烯系樹脂(旭化成公司製造「L8900」) ・樹脂2:酯系樹脂(UNITIKA公司製造「Elitel KA-3556」) ・樹脂3:丙烯酸系樹脂(三菱化學公司製造「MB-2660」) ・樹脂4:丙烯酸系樹脂(星光PMC公司製造「US-1071」) ・樹脂5:丙烯酸系樹脂(楠本化成公司製造「B―811」) ・樹脂6:苯乙烯系樹脂(旭化成公司製造「L1432」) ・樹脂7:丙烯酸系樹脂(Daicel Ornex公司製造「VSC6828w」) ・樹脂8:酯系樹脂(UNITIKA公司製造「Elitel KA-0134」) ・樹脂9:丙烯酸系樹脂(星光PMC公司製造「X-310」) ・樹脂10:丙烯酸系樹脂(星光PMC公司製造「TE-1048」) (抗靜電劑) ・抗靜電劑1:摻銻氧化錫(三菱綜合材料公司製造「T-1」) ・抗靜電劑2:聚噻吩衍生物(PEDOT:PSS)(賀利氏公司製造「Clevios P1000」) ・抗靜電劑3:聚噻吩衍生物(信越Polymer公司製造「SEPLEGYDA SAS-16」) Each constituent material of the sealant layer shown in Table 1 and Table 2 is as follows. (adhesive resin) ・Resin 1: Styrene-based resin ("L8900" manufactured by Asahi Kasei Co., Ltd.) ・Resin 2: Ester-based resin ("Elitel KA-3556" manufactured by UNITIKA Corporation) ・Resin 3: Acrylic resin ("MB-2660" manufactured by Mitsubishi Chemical Corporation) ・Resin 4: Acrylic resin ("US-1071" manufactured by Starlight PMC Co., Ltd.) ・Resin 5: Acrylic resin ("B-811" manufactured by Kusumoto Chemical Co., Ltd.) ・Resin 6: Styrene-based resin ("L1432" manufactured by Asahi Kasei Co., Ltd.) ・Resin 7: Acrylic resin ("VSC6828w" manufactured by Daicel Ornex Co., Ltd.) ・Resin 8: Ester-based resin ("Elitel KA-0134" manufactured by UNITIKA Corporation) ・Resin 9: Acrylic resin ("X-310" manufactured by Starlight PMC Co., Ltd.) ・Resin 10: Acrylic resin ("TE-1048" manufactured by Starlight PMC Co., Ltd.) (antistatic agent) ・Antistatic agent 1: Antimony-doped tin oxide ("T-1" manufactured by Mitsubishi Materials Corporation) ・Antistatic agent 2: Polythiophene derivatives (PEDOT:PSS) ("Clevios P1000" manufactured by Heraeus) ・Antistatic agent 3: Polythiophene derivative ("SEPLEGYDA SAS-16" manufactured by Shin-Etsu Polymer Co., Ltd.)

<實施例1> 在厚度12μm的抗靜電聚對苯二甲酸乙二酯(PET)薄膜(東洋紡公司製造「E7455」)上,藉由凹版塗佈濕式塗佈4μm的增黏塗層劑,在100℃條件下乾燥。然後,將低密度聚乙烯(住友化學公司製造「SUMIKATHENE L705」37μ厚)擠出層合,用冷卻輥(表面溫度20℃)進行冷卻。如此,製作了由基材層及中間層形成之積層薄膜。 <Example 1> On an antistatic polyethylene terephthalate (PET) film (manufactured by Toyobo Co., Ltd. "E7455") with a thickness of 12 μm, a 4 μm adhesion-promoting coating agent is wet-coated by gravure coating at 100°C dry. Then, low-density polyethylene ("SUMIKATHENE L705" manufactured by Sumitomo Chemical Co., Ltd., "SUMIKATHENE L705", 37 μ thick) was extrusion laminated, and cooled with a cooling roll (surface temperature: 20° C.). In this way, a laminated film composed of the base material layer and the intermediate layer was produced.

在所得到之積層薄膜的中間層側的面上,藉由凹版塗佈法將表1所示之摻合的成分以成為膜厚0.5μm之方式製膜。如此,設置了密封劑層。 將蓋帶整體的厚度示於表1及表2。 On the surface of the obtained laminated film on the side of the intermediate layer, the blended components shown in Table 1 were formed into a film by the gravure coating method so as to have a film thickness of 0.5 μm. In this way, a sealant layer is provided. Table 1 and Table 2 show the thickness of the entire cover tape.

<實施例2~6及比較例1~5> 按照表1及表2中記載之摻合,用與實施例1相同的方法製作了電子零件包裝用蓋帶。 <Examples 2 to 6 and Comparative Examples 1 to 5> According to the blends described in Table 1 and Table 2, a cover tape for electronic component packaging was produced in the same manner as in Example 1.

<玻璃轉移溫度> 對於實施例、比較例中使用之上述接著性樹脂,使用示差掃描熱量儀(DSC)(日立先端科技公司製造、「DSC7000X」),以升溫條件10℃/分鐘從0℃升溫至200℃,在氮氣環境條件下,測量了玻璃轉移溫度(℃)。 <Glass transition temperature> For the above-mentioned adhesive resins used in Examples and Comparative Examples, using a differential scanning calorimeter (DSC) (manufactured by Hitachi Advanced Technology Co., Ltd., "DSC7000X"), the temperature was raised from 0°C to 200°C at a temperature increase condition of 10°C/min. Under nitrogen ambient conditions, the glass transition temperature (°C) was measured.

<60℃時的黏著力> 使用RHESCA公司製造的黏性試驗機TAC0-1000對將接觸面積20mm 2的不鏽鋼材料(SUS304)以接觸速度30mm/分鐘按壓於蓋帶的密封劑層,以測量溫度60℃、接觸荷重25N保持20秒鐘後以600mm/分鐘的速度剝離時的每單位面積的荷重進行測量,作為60℃時的黏著力(N/cm 2)。另外,上述不鏽鋼材料附屬於黏性試驗機。 <Adhesion at 60°C> Using a tack tester TAC0-1000 manufactured by RHESCA, press a stainless steel material (SUS304) with a contact area of 20mm2 against the sealant layer of the cover tape at a contact speed of 30mm/min to measure the temperature The load per unit area when peeling off at a speed of 600 mm/min after holding at 60°C for 20 seconds under a contact load of 25 N was measured as the adhesive force (N/cm 2 ) at 60°C. In addition, the above-mentioned stainless steel material is attached to the viscosity tester.

<耐附著性試驗>(接著痕的長度的測量) 將上述中得到之電子零件包裝用蓋帶製成寬度10.0mm的尺寸,將該蓋帶的密封劑層側與寬度為8.0mm的尺寸且凹凸面的平均表面粗糙度(Ra)為0.25μm之聚苯乙烯製薄膜(住友電木公司製造「CEL-E980A」)的凹凸面側重合,作為樣品。 將該樣品以蓋帶側為上表面之方式放置於平面上。然後,在蓋帶的上表面放置接地部分的寬度為0.5mm,長度為32.0mm,重量為46.0g的剖面為U字型的密封鐵,在60℃90%RH的條件下放置24小時。為了參考,將在此使用之密封鐵的形狀示於圖3。在圖3中,a=0.5mm、b=32.0mm、c=3.1mm。 然後,將附著於聚苯乙烯製薄膜之接著痕(可見光澤)中的聚苯乙烯製薄膜的長度方向的尺寸作為附著於聚苯乙烯製薄膜之接著痕的長度進行了測量。順帶一提,「接著痕的長度」表示在斷續地(斷斷續續)觀察到接著痕之情況下,各個接著痕的合計長度。 該接著痕越短,則可以說抑制了蓋帶的未與載體帶熱封之部分與載體帶接著之情況(不期望的接著)。 <Adhesion resistance test> (Measurement of the length of adhesion marks) The cover tape for packaging electronic parts obtained above was made into a size with a width of 10.0 mm. The sealant layer side of the cover tape and the size with a width of 8.0 mm and the average surface roughness (Ra) of the uneven surface were 0.25 μm or less. A polystyrene film ("CEL-E980A" manufactured by Sumitomo Bakelite Co., Ltd.) was superimposed on the concave and convex sides and used as a sample. This sample was placed on a flat surface with the cover tape side as the upper surface. Then, on the upper surface of the cover tape, a sealing iron having a U-shaped cross-section with a ground portion width of 0.5 mm, a length of 32.0 mm, and a weight of 46.0 g was placed, and left for 24 hours at 60° C. and 90% RH. For reference, the shape of the sealing iron used here is shown in FIG. 3 . In Fig. 3, a=0.5mm, b=32.0mm, c=3.1mm. Then, the dimension in the longitudinal direction of the polystyrene film in the adhesive mark (visible gloss) attached to the polystyrene film was measured as the length of the adhesive mark attached to the polystyrene film. Incidentally, "the length of the bonding marks" indicates the total length of the bonding marks when the bonding marks are observed intermittently (intermittently). The shorter the bond line, it can be said that the part of the cover tape which is not heat-sealed with the carrier tape is bonded to the carrier tape (undesired bond).

<熱封試驗:對聚苯乙烯製薄膜的170°剝離強度> 將上述中得到之各電子零件包裝用蓋帶製成寬度5.5mm的尺寸,將該電子零件包裝用蓋帶的密封劑層側與寬度為8mm的尺寸且凹凸面的平均表面粗糙度(Ra)為0.25μm之聚苯乙烯製薄膜(住友電木公司製造「CEL-E980A」)的上述凹凸面側重合。對於該重合之材料,使用單刃為寬度0.4mm、長度28mm的尺寸的雙刃熱封刀,在密封溫度180℃、荷重5kgf、密封時間60毫秒鐘、載體帶輸送間距4mm、2列・7次打壓的條件下使用熱封機(Tokyo Weld公司製「TWA-6621」)進行熱封,作為樣品。使用所得到之樣品,對電子零件包裝用蓋帶對於上述聚苯乙烯製薄膜的剛熱封後的剝離強度(N)進行了測量。另外,剝離強度的測量使用剝離試驗機(EPI公司製造「PTS-5000」),在剝離速度300mm/分鐘、剝離角度170°、測量溫度25℃的條件下進行。將結果示於表1及表2。 另外,關於聚苯乙烯製薄膜的表面粗糙度(Ra),對於上述中使用之聚苯乙烯製薄膜中的與上述電子零件包裝用蓋帶貼合之部分,在與上述電子零件包裝用蓋帶貼合之前,依據JIS B 0601(2001),使用表面粗糙度測量器(三豐公司製造「SJ-210」)進行了測量。 <Heat seal test: 170°peel strength against polystyrene film> Each of the cover tapes for packaging electronic components obtained above was made into a size with a width of 5.5 mm, and the average surface roughness (Ra) of the uneven surface of the cover tape for packaging electronic components with a size of 8 mm in width and a sealant layer side The above-mentioned concavo-convex surfaces of a 0.25 μm polystyrene film (“CEL-E980A” manufactured by Sumitomo Bakelite Co., Ltd.) were superimposed on each other. For the superimposed material, use a double-edged heat-sealing knife with a single-edged width of 0.4mm and a length of 28mm, at a sealing temperature of 180°C, a load of 5kgf, a sealing time of 60 milliseconds, a carrier belt conveying distance of 4mm, and 2 rows·7 The samples were heat-sealed using a heat sealer (“TWA-6621” manufactured by Tokyo Weld Co., Ltd.) under the conditions of the first pressing. Using the obtained sample, the peel strength (N) immediately after heat-sealing of the cover tape for electronic component packaging with respect to the said polystyrene film was measured. In addition, the peel strength was measured using a peel tester ("PTS-5000" manufactured by EPI Corporation) under conditions of a peel speed of 300 mm/min, a peel angle of 170°, and a measurement temperature of 25°C. The results are shown in Table 1 and Table 2. In addition, with regard to the surface roughness (Ra) of the polystyrene film, the portion of the polystyrene film used above that is bonded to the above-mentioned cover tape for packaging electronic components is Before lamination, measurement was performed using a surface roughness measuring device ("SJ-210" manufactured by Mitutoyo Corporation) in accordance with JIS B 0601 (2001).

<將熱封後樣品在60℃保管及在60℃90%RH的條件下保管之試驗:對聚苯乙烯製薄膜的170°剝離強度> 將該的<熱封試驗:對聚苯乙烯製薄膜的170°剝離強度>中得到之樣品在60℃(0%RH~20%RH)環境或60℃90%RH環境下放置30天,分別作為60℃保管樣品、60℃90%RH保管樣品。使用60℃保管樣品及60℃90%RH保管樣品,以與該<熱封試驗:對聚苯乙烯製薄膜的170°剝離強度>中記載之條件相同的方式,測量170°剝離強度(N),分別作為P1(N)、P2(N)。又,將該電子零件包裝用蓋帶對於聚苯乙烯製薄膜的剛熱封後的剝離強度(N)作為P(N)。由P、P1、P2的值,藉由以下式(1)及(2),計算60℃保管後的170°剝離強度的變化率(絕對值)及60℃90%RH保管後的170°剝離強度的變化率(絕對值)。 在60℃條件下保管30天後的從初始剝離強度的變化率(絕對值)(%):|((P1-P)/P)×100|・・・(1) 在60℃90%RH的條件下保管30天後的從初始剝離強度的變化率(絕對值)(%):|((P2-P)/P)×100|・・・(2) 將|((P1-P)/P)×100|及|((P2-P)/P)×100|的值示於表1及2。 <Tests of storing heat-sealed samples at 60°C and at 60°C90%RH: 170° peel strength to polystyrene film> The sample obtained in <Heat Seal Test: 170°Peel Strength to Polystyrene Film> was placed in an environment of 60°C (0%RH to 20%RH) or 60°C 90%RH for 30 days, respectively. As a 60°C storage sample, a 60°C 90%RH storage sample. Using the samples stored at 60°C and 60°C at 90%RH, the 170° peel strength (N) was measured under the same conditions as described in <Heat seal test: 170° peel strength to polystyrene film> , as P1(N) and P2(N) respectively. Moreover, the peeling strength (N) immediately after heat-sealing this cover tape for electronic component packaging with respect to the polystyrene film was made into P(N). From the values of P, P1, and P2, the change rate (absolute value) of the 170° peel strength after storage at 60°C and the 170° peel strength after storage at 60°C and 90%RH are calculated by the following formulas (1) and (2). Rate of change of intensity (absolute value). Change rate from initial peel strength (absolute value) (%) after storage at 60°C for 30 days: |((P1-P)/P)×100|・・・(1) Change rate from initial peel strength (absolute value) (%) after storage at 60℃90%RH for 30 days: |((P2-P)/P)×100|・・・(2) Tables 1 and 2 show the values of |((P1-P)/P)×100| and |((P2-P)/P)×100|.

<基材層的表面電阻值> 使用SIMCO公司製造的表面電阻測量器(SIMCO公司製造「ST-3」),在25℃50%RH環境下對上述中得到之電子零件包裝用蓋帶的基材層表面的表面電阻值(Ω)進行了測量。將結果示於表1。 另外,表1及表2中記載之例如實施例1的「5.E+10」表示「5×10 10」。 <Surface resistance value of base material layer> Using a surface resistance measuring device manufactured by SIMCO Corporation ("ST-3" manufactured by SIMCO Corporation), the substrate of the cover tape for packaging electronic parts obtained above was measured in an environment of 25°C and 50%RH. The surface resistance value (Ω) of the material layer surface was measured. The results are shown in Table 1. In addition, "5.E+10" in Example 1 described in Table 1 and Table 2 means "5×10 10 ", for example.

<密封劑層的表面電阻值> 使用SIMCO公司製造的表面電阻測量器(SIMCO公司製造「ST-3」),在25℃50%RH環境下對上述中得到之電子零件包裝用蓋帶的密封劑層表面的表面電阻值(Ω)進行了測量。將結果示於表1。 另外,表1及表2中記載之例如實施例1的「1.E+07」表示「1×10 7」。 <Surface resistance value of sealant layer> Using a surface resistance measuring device manufactured by SIMCO Corporation ("ST-3" manufactured by SIMCO Corporation), the sealing of the cover tape for packaging electronic parts obtained above was carried out in an environment of 25°C and 50%RH. The surface resistance value (Ω) of the agent layer surface was measured. The results are shown in Table 1. In addition, "1.E+07" of Example 1 described in Table 1 and Table 2, for example, represents "1×10 7 ".

<總透光率> 依據JIS K 7361-1(1997),使用日本電飾工業公司製造的Haze Meter NDH 2000,利用光源D65對上述中得到之電子零件包裝用蓋帶的總透光率(%)進行了測量。將結果示於表1及表2。 <Total light transmittance> According to JIS K 7361-1 (1997), the total light transmittance (%) of the cover tape for packaging electronic parts obtained above was measured using a Haze Meter NDH 2000 manufactured by Nippon Densho Kogyo Co., Ltd., using a light source D65. The results are shown in Table 1 and Table 2.

<外部霧度> 依據JIS K 7136(2000),使用日本電飾工業公司製造的Haze Meter NDH 2000,利用光源D65對上述中得到之電子零件包裝用蓋帶的外部霧度(%)進行了測量。將結果示於表1及表2。 <External Haze> According to JIS K 7136 (2000), the external haze (%) of the cover tape for packaging electronic components obtained above was measured using a Haze Meter NDH 2000 manufactured by Nippon Densho Kogyo Co., Ltd. with a light source D65. The results are shown in Table 1 and Table 2.

【表1】    單位 實施例1 實施例2 實施例3 實施例4 實施例5 實施例6 蓋帶整體的厚度 μm 50 50 50 50 50 50 基材層 - 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 中間層 - LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 密封劑層 樹脂1 質量% 90                樹脂2 質量%    90             樹脂3 質量%       40       85 樹脂4 質量%          40       樹脂5 質量%             40    樹脂6 質量%                   樹脂7 質量%                   樹脂8 質量%                   樹脂9 質量%                   樹脂10 質量%                   抗靜電劑1 質量%       60 60 60    抗靜電劑2 質量% 10 10             抗靜電劑3 質量%                15 (A)接著性樹脂的玻璃轉移溫度 100 80 63 104 110 63 60℃時的黏著力 N/cm 2 0.70 1.25 1.00 1.00 0.90 1.00 耐附著性試驗(接著痕的長度) mm 0 7 0 3 0 0 對聚苯乙烯製薄膜的170°剝離強度(P) N 0.55 0.37 0.36 0.36 0.24 0.42 在60℃條件下保管30天後的170°剝離強度(P1) N 0.61 0.44 0.46 0.46 0.30 0.50 在60℃90%RH的條件下保管30天後的170°剝離強度(P2) N 0.55 0.38 0.37 0.44 0.29 0.35 在60℃條件下保管30天後的從初始剝離強度的變化率(絕對值) |(P1-P)/P×100| % 11 20 28 28 25 18 在60℃90%RH的條件下保管30天後的從初始剝離強度的變化率(絕對值) |(P2-P)/P×100| % 1 4 3 22 20 -17 表面電阻值(基材層) Ω 5.E+10 5.E+10 5.E+10 5.E+10 5.E+10 5.E+10 表面電阻值(密封劑層) Ω 1.E+07 2.E+06 2.E+08 2.E+08 6.E+08 8.E+08 總透光率 % 89 88 87 87 88 86 外部霧度 % 8 13 18 20 23 8 【Table 1】 unit Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Overall thickness of cover tape μm 50 50 50 50 50 50 Substrate layer - Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 middle layer - LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 sealant layer Resin 1 quality% 90 Resin 2 quality% 90 Resin 3 quality% 40 85 Resin 4 quality% 40 Resin 5 quality% 40 Resin 6 quality% Resin 7 quality% Resin 8 quality% Resin 9 quality% Resin 10 quality% Antistatic agent 1 quality% 60 60 60 Antistatic agent 2 quality% 10 10 Antistatic agent 3 quality% 15 (A) Glass transition temperature of adhesive resin 100 80 63 104 110 63 Adhesion at 60°C N/ cm2 0.70 1.25 1.00 1.00 0.90 1.00 Adhesion resistance test (the length of the adhesion mark) mm 0 7 0 3 0 0 170°peel strength of polystyrene film (P) N 0.55 0.37 0.36 0.36 0.24 0.42 170° peel strength after storage at 60°C for 30 days (P1) N 0.61 0.44 0.46 0.46 0.30 0.50 170°peel strength (P2) after storage at 60°C 90%RH for 30 days N 0.55 0.38 0.37 0.44 0.29 0.35 Rate of change from initial peel strength after storage at 60°C for 30 days (absolute value) |(P1-P)/P×100| % 11 20 28 28 25 18 Change rate from initial peel strength (absolute value) |(P2-P)/P×100| % 1 4 3 twenty two 20 -17 Surface resistance value (substrate layer) Ω 5. E+10 5. E+10 5. E+10 5. E+10 5. E+10 5. E+10 Surface resistance value (sealant layer) Ω 1. E+07 2. E+06 2. E+08 2. E+08 6. E+08 8. E+08 Total light transmittance % 89 88 87 87 88 86 External Haze % 8 13 18 20 twenty three 8

【表2】    單位 比較例1 比較例2 比較例3 比較例4 比較例5 蓋帶整體的厚度 μm 50 50 50 50 50 基材層 - 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 抗靜電 PET薄膜 E7455 中間層 - LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 密封劑層 樹脂1 質量%                樹脂2 質量%                樹脂3 質量%                樹脂4 質量%                樹脂5 質量%                樹脂6 質量% 90             樹脂7 質量%    90          樹脂8 質量%       90       樹脂9 質量%          40    樹脂10 質量%             90 抗靜電劑1 質量%          60    抗靜電劑2 質量% 10 10 10    10 抗靜電劑3 質量%                (A)接著性樹脂的玻璃轉移溫度 18 42 40 53 123 60℃時的黏著力 N/cm 2 7.99 5.24 18.17 5.99 0.90 耐附著性試驗(接著痕的長度) mm 32 18 32 30 0.00 對聚苯乙烯製薄膜的170°剝離強度(P) N 0.64 0.00 0.38 0.39 0.00 在60℃條件下保管30天後的170°剝離強度(P1) N 1.17 - 0.48 0.65 - 在60℃90%RH的條件下保管30天後的170°剝離強度(P2) N 1.23 - 0.65 0.70 - 在60℃條件下保管30天後的從初始剝離強度的變化率(絕對值) |(P1-P)/P×100| % 83 無法評價 25 66 無法評價 在60℃90%RH的條件下保管30天後的從初始剝離強度的變化率(絕對值) |(P2-P)/P×100| % 92 無法評價 69 80 無法評價 表面電阻值(基材層) Ω 5.E+10 5.E+10 5.E+10 5.E+10 5.E+10 表面電阻值(密封劑層) Ω 1.E+07 2.E+07 7.E+07 3.E+08 3.E+08 總透光率 % 88 88 88 87 86 外部霧度 % 13 13 17 16 21 【Table 2】 unit Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Comparative Example 5 Overall thickness of cover tape μm 50 50 50 50 50 Substrate layer - Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 Antistatic PET film E7455 middle layer - LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 LDPE SUMIKATHENE L705 sealant layer Resin 1 quality% Resin 2 quality% Resin 3 quality% Resin 4 quality% Resin 5 quality% Resin 6 quality% 90 Resin 7 quality% 90 Resin 8 quality% 90 Resin 9 quality% 40 Resin 10 quality% 90 Antistatic agent 1 quality% 60 Antistatic agent 2 quality% 10 10 10 10 Antistatic agent 3 quality% (A) Glass transition temperature of adhesive resin 18 42 40 53 123 Adhesion at 60°C N/ cm2 7.99 5.24 18.17 5.99 0.90 Adhesion resistance test (the length of the adhesion mark) mm 32 18 32 30 0.00 170°peel strength of polystyrene film (P) N 0.64 0.00 0.38 0.39 0.00 170°peel strength after storage at 60°C for 30 days (P1) N 1.17 - 0.48 0.65 - 170°peel strength (P2) after storage at 60°C 90%RH for 30 days N 1.23 - 0.65 0.70 - Rate of change from initial peel strength after storage at 60°C for 30 days (absolute value) |(P1-P)/P×100| % 83 Can't comment 25 66 Can't comment Change rate from initial peel strength (absolute value) |(P2-P)/P×100| % 92 Can't comment 69 80 Can't comment Surface resistance value (substrate layer) Ω 5. E+10 5. E+10 5. E+10 5. E+10 5. E+10 Surface resistance value (sealant layer) Ω 1. E+07 2. E+07 7. E+07 3. E+08 3. E+08 Total light transmittance % 88 88 88 87 86 External haze % 13 13 17 16 twenty one

在實施例1~6中,得到了耐附著性試驗(接著痕的長度)中評價之耐附著性良好且對聚苯乙烯製薄膜的170°剝離強度中評價之熱封強度適當的電子零件包裝用蓋帶。又,在實施例1~6中,60℃保管後及60℃90%RH保管後的剝離強度的經時變化率小。 另一方面,比較例1~5的(A)接著性樹脂的玻璃轉移溫度為60℃以下,或超過120℃,因此結果與實施例相比差。又,在比較例1~5中,60℃保管後及60℃90%RH保管後的剝離強度的經時變化率大。 In Examples 1 to 6, electronic component packages with good adhesion resistance evaluated in the adhesion resistance test (length of the adhesive mark) and appropriate heat seal strength evaluated in the 170° peel strength to polystyrene films were obtained Use cover tape. Moreover, in Examples 1-6, the time-dependent change rate of the peeling strength after 60 degreeC storage and 60 degreeC90%RH storage was small. On the other hand, since the glass transition temperature of (A) adhesive resin of Comparative Examples 1-5 was 60 degreeC or less, or exceeded 120 degreeC, the result was inferior to an Example. In addition, in Comparative Examples 1 to 5, the rate of change over time in the peel strength after storage at 60° C. and after storage at 60° C. and 90% RH was large.

本申請主張基於2021年3月31日申請之日本專利申請特願2021-060188號、2021年7月7日申請之日本專利申請特願2021-112596號及2021年10月22日申請之日本專利申請特願2021-172916號的優先權,將其揭示的全部內容引入於此。This application is based on Japanese Patent Application No. 2021-060188 filed on March 31, 2021, Japanese Patent Application No. 2021-112596 filed on July 7, 2021, and Japanese Patent Application on October 22, 2021 The priority of Japanese Patent Application No. 2021-172916 is incorporated here.

1:基材層 2:中間層 3:密封劑層 10:蓋帶 20:載體帶 21:袋 100:電子零件包裝體 1: Substrate layer 2: middle layer 3: Sealant layer 10: Cover tape 20: Carrier belt 21: bag 100: electronic parts package

[圖1]係示意性地表示本實施形態的電子零件包裝用蓋帶的一例之圖。 [圖2]係表示將電子零件包裝用蓋帶接著(熱封)於載體帶上之狀態的一例之圖。 [圖3]係用於說明「耐附著性試驗」中使用之密封鐵的形狀的圖。 [ Fig. 1 ] is a diagram schematically showing an example of a cover tape for packaging electronic components according to this embodiment. [ Fig. 2 ] is a diagram showing an example of a state where the cover tape for packaging electronic components is adhered (heat-sealed) to the carrier tape. [Fig. 3] It is a diagram for explaining the shape of the sealing iron used in the "adhesion resistance test".

none

1:基材層 1: Substrate layer

2:中間層 2: middle layer

3:密封劑層 3: Sealant layer

10:蓋帶 10: Cover tape

Claims (11)

一種電子零件包裝用蓋帶,其依序具有: 基材層; 中間層;及 密封劑層, 該密封劑層含有(A)接著性樹脂, 該(A)接著性樹脂的按照以下<玻璃轉移溫度的測量方法>測量之玻璃轉移溫度大於60℃且為120℃以下, 該密封劑層的藉由以下<黏著力的測量方法>測量之黏著力為0N/cm 2以上且5.0N/cm 2以下, <玻璃轉移溫度的測量方法> 使用示差掃描熱量儀(DSC),以升溫條件10℃/分鐘使該(A)接著性樹脂的玻璃轉移溫度(℃)升溫至0℃~200℃,並在氮氣環境條件下進行測量, <黏著力的測量方法> 將以接觸速度30mm/分鐘將接觸面積20mm 2的不鏽鋼材料按壓於該電子零件包裝用蓋帶的該密封劑層,以測量溫度60℃、接觸荷重25N保持20秒鐘後,以600mm/分鐘的速度剝離時的每單位面積的荷重的測量值設為60℃時的黏著力(N/cm 2)。 A cover tape for electronic component packaging, which has in order: a base material layer; an intermediate layer; and a sealant layer, the sealant layer containing (A) adhesive resin, the (A) adhesive resin according to the following <glass transfer Measurement method of temperature> The measured glass transition temperature is greater than 60°C and less than 120°C, and the adhesive force of the sealant layer measured by the following <Measurement method of adhesion force> is 0 N/cm 2 or more and 5.0 N/cm 2 Hereinafter, <Measurement method of glass transition temperature> Using a differential scanning calorimeter (DSC), raise the glass transition temperature (°C) of the (A) adhesive resin to 0°C to 200°C at a heating condition of 10°C/min, and The measurement was carried out under nitrogen ambient conditions. <Measurement method of adhesion> A stainless steel material with a contact area of 20mm 2 was pressed against the sealant layer of the cover tape for electronic component packaging at a contact speed of 30mm/min, and the measurement temperature was 60°C , The measured value of the load per unit area when peeled at a speed of 600 mm/min after holding a contact load of 25 N for 20 seconds was defined as the adhesive force (N/cm 2 ) at 60°C. 如請求項1之電子零件包裝用蓋帶,其中, 該密封劑層的該(A)接著性樹脂含有苯乙烯系樹脂、丙烯酸系樹脂及酯系樹脂中的至少1種以上。 Such as the cover tape for packaging electronic parts of claim 1, wherein, The (A) adhesive resin of the sealant layer contains at least one or more of styrene-based resins, acrylic resins, and ester-based resins. 如請求項1或2之電子零件包裝用蓋帶,其中, 該密封劑層還含有(B)抗靜電劑。 The cover tape for packaging electronic parts as claimed in item 1 or 2, wherein, The sealant layer also contains (B) an antistatic agent. 如請求項3之電子零件包裝用蓋帶,其中, 該(B)抗靜電劑含有由摻銻氧化錫、摻磷氧化錫、摻氟氧化錫及導電性高分子組成之群組中的1種以上。 Such as the cover tape for packaging electronic parts of claim 3, wherein, The (B) antistatic agent contains one or more species selected from the group consisting of antimony-doped tin oxide, phosphorus-doped tin oxide, fluorine-doped tin oxide, and a conductive polymer. 如請求項1或2之電子零件包裝用蓋帶,其中, 該中間層含有選自由聚丙烯酸衍生物、聚丙烯酸酯衍生物、烯烴系樹脂及環狀烯烴樹脂組成之群組中之1種或2種以上的樹脂。 The cover tape for packaging electronic parts as claimed in item 1 or 2, wherein, The intermediate layer contains one or two or more resins selected from the group consisting of polyacrylic acid derivatives, polyacrylate derivatives, olefin resins, and cyclic olefin resins. 如請求項1或2之電子零件包裝用蓋帶,其中, 在藉由以下<耐附著性試驗>進行評價之情況下,附著於聚苯乙烯製薄膜之接著痕的長度為0mm以上且15mm以下, <耐附著性試驗> 將該電子零件包裝用蓋帶設為寬度10.0mm的尺寸,將該蓋帶的密封劑層側與寬度為8.0mm的尺寸,且凹凸面的平均表面粗糙度(Ra)為0.25μm之聚苯乙烯製薄膜的該凹凸面側重合,作為樣品,在該樣品的蓋帶的上表面放置設置部分的寬度為0.5mm,長度為32.0mm,重量為46.0g的密封鐵,在60℃90%RH的條件下靜置24小時,靜置後,在附著於聚苯乙烯製薄膜之接著痕中,將聚苯乙烯製薄膜的長度方向的尺寸作為附著於聚苯乙烯製薄膜之接著痕的長度進行測量。 The cover tape for packaging electronic parts as claimed in item 1 or 2, wherein, In the case of evaluation by the following <adhesion resistance test>, the length of the adhesive mark attached to the polystyrene film is not less than 0mm and not more than 15mm, <Adhesion Resistance Test> This cover tape for packaging electronic parts has a width of 10.0 mm, and the sealant layer side of the cover tape has a width of 8.0 mm. Polyphenylene with an average surface roughness (Ra) of 0.25 μm on the uneven surface The concave and convex sides of the vinyl film are superimposed, and as a sample, a sealing iron with a width of 0.5mm, a length of 32.0mm, and a weight of 46.0g is placed on the upper surface of the cover tape of the sample, and the temperature is 60°C 90%RH After standing still for 24 hours, in the adhesive marks attached to the polystyrene film, the dimension in the longitudinal direction of the polystyrene film is taken as the length of the adhesive mark attached to the polystyrene film Measurement. 如請求項1或2之電子零件包裝用蓋帶,其中, 在25℃、50%RH的條件下測量之該基材層的表面的表面電阻值為1.0×10 3Ω以上且1.0×10 13Ω以下。 The cover tape for packaging electronic components according to Claim 1 or 2, wherein the surface resistance value of the surface of the base material layer measured under the conditions of 25°C and 50%RH is 1.0×10 3 Ω or more and 1.0×10 13 Ω or less. 如請求項1或2之電子零件包裝用蓋帶,其中, 在25℃、50%RH的條件下測量之該密封劑層的表面的表面電阻值為1.0×10 3Ω以上且1.0×10 12Ω以下。 The cover tape for packaging electronic parts according to claim 1 or 2, wherein the surface resistance value of the surface of the sealant layer measured under the conditions of 25°C and 50%RH is 1.0×10 3 Ω or more and 1.0×10 12 Ω or less. 如請求項1或2之電子零件包裝用蓋帶,其中, 依據JIS K 7361-1(1997)之利用光源D65測量之總透光率為70%以上且95%以下。 The cover tape for packaging electronic parts as claimed in item 1 or 2, wherein, The total light transmittance measured by light source D65 based on JIS K 7361-1 (1997) is 70% or more and 95% or less. 如請求項1或2之電子零件包裝用蓋帶,其中, 依據JIS K 7136(2000)之利用光源D65測量之外部霧度為5%以上且50%以下。 The cover tape for packaging electronic parts as claimed in item 1 or 2, wherein, The external haze measured by light source D65 based on JIS K 7136 (2000) is 5% or more and 50% or less. 一種電子零件包裝體,其具有: 載體帶,在凹部收容有電子零件;及 請求項1至10中任一項之電子零件包裝用蓋帶, 將該密封劑層側接著於該載體帶上,以密封該電子零件。 An electronic component packaging body, which has: a carrier tape containing electronic components in recesses; and The cover tape for packaging electronic parts according to any one of claims 1 to 10, The sealant layer is side-bonded on the carrier tape to seal the electronic component.
TW111112114A 2021-03-31 2022-03-30 Cover tape for packaging electronic components and electronic components package TW202306855A (en)

Applications Claiming Priority (6)

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JP2021060188 2021-03-31
JP2021-060188 2021-03-31
JP2021-112596 2021-07-07
JP2021112596 2021-07-07
JP2021-172916 2021-10-22
JP2021172916A JP2022158849A (en) 2021-03-31 2021-10-22 Cover tape for electronic component packaging, and electronic component package

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JPH074221Y2 (en) * 1988-04-11 1995-02-01 株式会社巴川製紙所 Electronic component storage
JP2001106256A (en) * 1999-10-07 2001-04-17 Sumitomo Bakelite Co Ltd Cover tape for packaging electronic parts
JP2002002786A (en) * 2000-06-28 2002-01-09 Denki Kagaku Kogyo Kk Carrier tape body and cover tape
JP2005126081A (en) * 2003-10-21 2005-05-19 Shin Etsu Polymer Co Ltd Resin composition for cover tape, cover tape using resin composition, and package
JP5463193B2 (en) * 2010-04-22 2014-04-09 電気化学工業株式会社 Cover tape
JP5762556B2 (en) * 2010-12-17 2015-08-12 スリーエム イノベイティブ プロパティズ カンパニー Cover tape for packaging heat seals and electronic components
WO2012143994A1 (en) * 2011-04-18 2012-10-26 電気化学工業株式会社 Cover film
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