TW202216974A - 金屬加工液泡沫控制劑 - Google Patents
金屬加工液泡沫控制劑 Download PDFInfo
- Publication number
- TW202216974A TW202216974A TW110135170A TW110135170A TW202216974A TW 202216974 A TW202216974 A TW 202216974A TW 110135170 A TW110135170 A TW 110135170A TW 110135170 A TW110135170 A TW 110135170A TW 202216974 A TW202216974 A TW 202216974A
- Authority
- TW
- Taiwan
- Prior art keywords
- control agent
- foam control
- foam
- alcohol
- agent
- Prior art date
Links
- 239000006260 foam Substances 0.000 title claims abstract description 47
- 239000012530 fluid Substances 0.000 title claims abstract description 18
- 238000005555 metalworking Methods 0.000 title claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 45
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical group CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 claims description 18
- 150000001298 alcohols Chemical class 0.000 claims description 18
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 7
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 22
- 239000000203 mixture Substances 0.000 description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 13
- -1 sodium alkane sulfonates Chemical class 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 9
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000013530 defoamer Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002202 Polyethylene glycol Chemical class 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 238000005882 aldol condensation reaction Methods 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- JNYAEWCLZODPBN-KVTDHHQDSA-N (2r,3r,4r)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@@H](O)[C@H]1O JNYAEWCLZODPBN-KVTDHHQDSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QAQSNXHKHKONNS-UHFFFAOYSA-N 1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carboxamide Chemical compound CCN1C(O)=C(C(N)=O)C(C)=CC1=O QAQSNXHKHKONNS-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- RXJWAZRJMISPGN-UHFFFAOYSA-N 2-[2-(2-docosanoyloxyethoxy)ethoxy]ethyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCCCCCCCCCCCCCCCCC RXJWAZRJMISPGN-UHFFFAOYSA-N 0.000 description 1
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- TWADYJJNDWPIQS-UHFFFAOYSA-N C(C)(=O)O.C(C)(=O)O.C(CCCCCCCCCCC)N(CCN(CCN)CCCCCCCCCCCC)CCN Chemical class C(C)(=O)O.C(C)(=O)O.C(CCCCCCCCCCC)N(CCN(CCN)CCCCCCCCCCCC)CCN TWADYJJNDWPIQS-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- 159000000021 acetate salts Chemical class 0.000 description 1
- ANRCSZILOHNONR-UHFFFAOYSA-N acetic acid;hexadecan-1-amine Chemical compound CC([O-])=O.CCCCCCCCCCCCCCCC[NH3+] ANRCSZILOHNONR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000007866 anti-wear additive Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- BZSWJGHEQUOKIP-UHFFFAOYSA-M didodecyl(diethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](CC)(CC)CCCCCCCCCCCC BZSWJGHEQUOKIP-UHFFFAOYSA-M 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000003879 lubricant additive Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- FYRUYUVOQKFYAR-UHFFFAOYSA-N n-dodecyldodecan-1-amine;2-hydroxypropanoic acid Chemical compound CC(O)C(O)=O.CCCCCCCCCCCCNCCCCCCCCCCCC FYRUYUVOQKFYAR-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23Q—DETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
- B23Q11/00—Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
- B23Q11/10—Arrangements for cooling or lubricating tools or work
- B23Q11/1038—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality
- B23Q11/1061—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality using cutting liquids with specially selected composition or state of aggregation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/50—Defoamers, air detrainers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Lubricants (AREA)
- Auxiliary Devices For Machine Tools (AREA)
- Degasification And Air Bubble Elimination (AREA)
Abstract
一種泡沫控制劑及藉由使用泡沫控制劑控制金屬加工液之泡沫的方法，其中該試劑包括至少一種支鏈醇。
Description
實施例係關於一種用於金屬加工液之泡沫控制劑及控制泡沫的方法，其中該試劑至少包括支鏈醇。
金屬加工液（MWF）用於金屬切削及工具成型的潤滑。此等液體為金屬加工工具提供冷卻，自工具/工件界面移除切割碎屑且有助於提供可接受的加工後成品表面。MWF可為純油、可溶性油、半合成液或合成液。純油及可溶性油含有50-70 wt.%油及油溶性抗磨/極壓添加劑。其提供極佳潤滑性但冷卻效率不佳。合成金屬加工液主要由水與潤滑劑添加劑構成。其提供移除在加工期間產生之熱量的極佳特性，但僅具有平均潤滑性。
半合成液不同於可溶性油及合成金屬加工液，因為其含有大量水，但亦含有10至30 wt.%礦物油、10至30 wt.%乳化劑及其他功能性添加劑。脂肪酸乙醇胺肥皂、烷烴磺酸鈉、醇乙氧基化物及其他界面活性劑用於將礦物油或植物油分散至水中且因此為接觸工作表面之工具金屬提供適當潤滑性。此等表面活性劑促進在金屬加工過程中產生大量泡沫，其造成工具與工件之間的液體潤滑性不足。在一些情況下，此潤滑性缺乏可導致液體自液浴溢出。一些加工過程（尤其是研磨）對泡沫極敏感且在規劃加工時需要特別小心。
基於聚矽氧之泡沫控制劑廣泛用於MWF中以解決發泡問題，因為此等試劑之表面張力極低且不溶於油及水兩者中。然而，聚矽氧消泡劑之生物降解性不佳，且其亦在許多MWF調配物中缺乏穩定性。另外，聚矽氧沈積至金屬之表面上會影響（光滑）表面處理，其亦產生任何後續塗刷步驟的額外問題。
出於所有此等及更多原因，需要用於金屬加工液之泡沫控制劑及控制泡沫的方法。
實施例係關於一種用於金屬加工液之泡沫控制劑及控制泡沫的方法，其中該試劑至少包括支鏈醇。
本發明係關於用於金屬加工液（MWF）之泡沫控制劑。本發明詳述支鏈醇如何出乎意料地顯示具有優良泡沫控制效能。支鏈醇可為2-烷基-1-烷醇（亦稱為古爾貝特醇（Guerbet alcohol）），且較佳為2-乙基己醇（2-EH）及2-丙基庚醇（2-PH）。古爾貝特醇包含2-丁基-1-辛醇。
此等醇可經由對應醛之醇醛縮合或自一級直鏈醇之古爾貝特反應合成。亦可利用其他生產方法。
目前揭示之消泡劑的通用結構如下：
其中x為2至14之整數且R為具有1-14個碳原子之烷基。
泡沫控制劑亦可描述為包括來自C8-C32之經2-烷基取代之醇。醇可主要為一種異構體（＞95 wt.%）或醇之混合物，其可藉由醛之混合物的醇醛縮合產生或經由古爾貝特反應自醇之混合物產生。
在一些實施例中較佳為C8-C32古爾貝特醇，包含2-乙基己醇及2-丙基庚醇以及由丁醛及戊醛之醇醛縮合產生的C8、C9及C10醇之混合物。
調配之泡沫控制劑中古爾貝特醇之濃度在0.01%至100%範圍內，較佳在30%至100%範圍內。古爾貝特醇可呈固體或液體形式，較佳為液體。若其為固體，則可將材料溶解或分散於溶劑中。該泡沫控制劑可為水溶液或基於有機溶劑之溶液。用於MWF之該泡沫控制劑的使用劑量可變化。用於MWF之此泡沫控制劑的使用劑量在0.01%至5%範圍內，較佳在0.1%至1%範圍內。
其他泡沫控制劑（例如，由環氧乙烷、環氧丙烷及/或環氧丁烷構成的共聚物，無規或嵌段）或其他疏水材料，諸如蠟、油或二氧化矽亦可與支鏈古爾貝特醇一起添加。矽消泡劑可與2-烷基醇結合使用。亦可使用界面活性劑，尤其醇之烷氧基化物。使用支鏈醇作為泡沫控制劑可為基於水的或基於油的。
本發明所揭示之新型泡沫控制劑可呈固體或液體形式。若其為固體，則可將材料溶解或分散於溶劑中，之後用作泡沫控制劑。咸信本發明所揭示之試劑在所有常用金屬加工液存在下起作用。
該化學試劑可用於消泡劑或消泡劑調配物。消泡劑調配物係藉由在氣泡之氣液界面中的聚乙二醇、酯、聚矽氧、溶劑、水及/或其他化學物質之混合物獲得，避免了泡沫形成。亦可使用基於嵌段共聚物之其他兩親性化學物質。在消泡調配物中，除上文所提及之產品以外，其亦可使用植物油、礦物油、蠟及其他油性試劑。
選擇泡沫控制劑中包括的視情況選用之界面活性劑或乳化劑以適合於改善泡沫控制劑與原料之相容性或與支鏈醇之組合物形成乳液。視情況選用之界面活性劑或乳化劑的量在支鏈醇之組合物的0.1-30重量%範圍內。
視情況選用之界面活性劑或乳化劑可為陰離子型、陽離子型或非離子型。適合之陰離子界面活性劑或乳化劑之實例為鹼金屬、銨及胺皂；此類皂之脂肪酸部分含有較佳至少10個碳原子。皂亦可「原位」形成；換言之，脂肪酸可添加至油相且鹼性材料可添加至水相。
適合之陰離子界面活性劑或乳化劑之其他實例為烷基-芳基磺酸之鹼金屬鹽、二烷基磺基丁二酸鈉、硫酸化或磺化油（例如硫酸化蓖麻油）；磺化牛脂及短鏈石油磺酸之鹼金屬鹽。
適合之陽離子界面活性劑或乳化劑為長鏈一級、二級或三級胺之鹽，諸如乙酸油醯胺、乙酸十六胺、乳酸二-十二烷胺、胺乙基-胺乙基硬脂醯胺之乙酸鹽、二月桂醯三伸乙基四胺二乙酸鹽、1-胺乙基-2-十七烯基咪唑啉乙酸鹽；及四級鹽，諸如十六烷基溴化吡錠、十六烷基乙基氯化嗎啉鎓及二乙基二-十二烷基氯化銨。
適合之非離子界面活性劑或乳化劑之實例為高級脂肪醇與環氧乙烷之縮合產物，諸如油醇與10個環氧乙烷單元之反應產物；烷基酚與環氧乙烷之縮合產物，諸如異辛基苯酚與12個環氧乙烷單元之反應產物；高級脂肪酸醯胺與5個或更多個環氧乙烷單元之縮合產物；長鏈脂肪酸之聚乙二醇酯，諸如單棕櫚酸四甘醇酯、單月桂酸六甘醇酯、單硬脂酸九甘醇酯、二油酸九甘醇酯、單花生酸十三甘醇酯、單山崳酸二十三甘醇酯、二山崳酸二十三甘醇酯；多元醇部分高級脂肪酸酯，諸如三硬脂酸脫水山梨糖醇酯；多元醇部分高級脂肪酸酯與其內部酸酐（甘露糖醇-酐，稱為甘露糖酯（Mannitan），及山梨糖醇-酐，稱為山梨醇酐（Sorbitan））之環氧乙烷縮合產物，諸如單棕櫚酸甘油酯與10個環氧乙烷分子反應、單油酸新戊四醇酯與12個環氧乙烷分子反應、單硬脂酸山梨糖醇酯與10-15個環氧乙烷分子反應、甘露糖酯單棕櫚酸酯（mannitan monopalmitate）與10-15個環氧乙烷分子反應之縮合產物；在長鏈聚乙二醇中，一個羥基經高級脂肪酸酯化且另一個羥基經低分子醇醚化，諸如單硬脂酸甲氧基聚乙二醇(550)酯（550意謂聚乙二醇醚之平均分子量）。可使用兩種或更多種此等界面活性劑之組合；例如，陽離子可與非離子或陰離子可與非離子摻合。
泡沫控制劑可進一步包括一或多種添加劑。添加劑之實例包含環氧乙烷/環氧丙烷嵌段共聚物、環氧丁烷/環氧丙烷嵌段共聚物、環氧乙烷/環氧丁烷嵌段共聚物、蠟或基於聚矽氧之材料。對於其中界面活性劑在清潔步驟中引起發泡之其他清潔應用，可使用至多C32的經2-烷基取代之高級醇。
本文所述之泡沫控制劑可用於半合成MWF或合成MWF，其包括松油酸、乙醇胺、KOH、聚烷基二醇潤滑劑、醇乙氧基化物、烷烴磺酸鈉及水。本文所述之泡沫控制劑亦有助於維持給定MWF之透明度且亦為可生物降解的。
實例
測試本發明所揭示之泡沫控制劑及其他物質之功效的實驗可如下進行。
表1 - 用於實驗之原料
測試1 - 消泡搖動測試
| 名稱 | 生產商/ 供應商 | 目的 | 化學及功能 |
| 2-丁基-1-辛醇 （2-BO） | 西格瑪奧德里奇（Sigma Aldrich） | 測試實例 |  |
| 2-乙基己醇 (2-EH) | 西格瑪奧德里奇 | 測試實例 |  |
| 2-丙基庚醇 (2-PH) | 西格瑪奧德里奇 | 測試實例 |  |
| AFE-1510 | 道康寧（Dow Corning） | 比較實例 | 基於聚矽氧之泡沫控制劑 |
| ANTA L-61 | 沙索（Sasol） | 比較實例 | EO/PO共聚物 |
| FoamBan 3057 | 上海蒙津有限公司（Munzing Shanghai Co., Ltd） | 比較實例 | 石油餾出物，溶劑脫蠟輕石蠟及石油餾出物，溶劑脫蠟重石蠟 |
| 異丁醇 | 陶氏化學（The Dow Chemical） | 比較實例 | 異丁醇 |
| C12-C14直鏈醇 | 沙索 | 比較實例 | C12-C14直鏈醇 |
| Exxal 13 | 埃克森美孚（Exxonmobil） | 比較實例 | 異C13醇 |
| SY-2 | 本地MWF調配師 | 無泡沫控制劑之商業MWF產品 | 合成MWF，松油酸+乙醇胺+KOH+水+聚烷基二醇潤滑劑 |
| SY-6 | 本地MWF調配師 | 無泡沫控制劑之商業MWF產品 | 半合成MWF，40%礦物油+松油酸+乙醇胺+醇乙氧基化物+烷烴磺酸鈉 |
| BLC | AFTON | 無泡沫控制劑之商業MWF產品 | 半合成MWF，20-30%礦物油+10-19.9%松油、單乙醇胺鹽+10-19.9%長鏈烷基烷醇醯胺+1-5%己二醇+1-5.0%乙醇、2-胺+水至100% |
首先進行篩選搖動測試以評估本發明所揭示之泡沫控制劑和一些比較實例。使用DI水將濃縮之商業金屬加工液BLC稀釋20倍。接著以0.05%（500 ppm）添加測試消泡劑以在8 ml小瓶中製備2公克溶液。接著在實驗室搖動器中在高速設定下搖動小瓶1小時且將此測試結果記錄於下表2中。
表2 - 小瓶搖動篩選結果
測試2 - 消泡搖動測試
| 實例編號 | MWF類型 | 泡沫控制劑 | 發泡外觀 |
| 比較實例1 | BLC | 無 | 大量泡沫 |
| 比較實例2 | BLC | AFE-1510 | 少量泡沫 |
| 實例1 | BLC | 2-PH | 少量泡沫 |
| 實例2 | BLC | 2-EH | 少量泡沫 |
| 實例3 | BLC | 2-BO | 少量泡沫 |
隨後藉由將測試實例及比較實例與其他常見商業MWF調配物混合來進一步評估測試實例及比較實例。表3中所示之樣品藉由將0.100 g泡沫控制劑溶解至9.900 g半合成/合成MWF中且搖動混合物以得到均勻溶液來製備。使用專門設計的圓筒來評估發泡程度。圓筒之0 mL標記與250 mL標記之間的距離為20-21.5 cm，且250 mL標記與塞子底部的距離約為4-6 cm。隨後將2.50 g可溶性油或半合成MWF濃縮物添加至含有95 mL標準物25 ppm硬水之250 mL圓筒中。在用塞子封閉圓筒後，將圓筒在1分鐘內倒置30次，且記錄在時間0秒時之初始泡沫，以及在30秒時、1分鐘時、2分鐘時及3分鐘時之泡沫程度。
用於此測試之標準硬水（25 ppm）係藉由在DI水中添加無水氯化鈣（0.045 g）及六水合氯化鎂（0.023 g）製備，以製備2.0 L 25 ppm之標準硬水。
表3 - 標準圓筒倒置結果
| 實例編號 | MWF類型 | 消泡劑 | 24 h之後的外觀 | 倒置搖動之後的發泡，mL | ||||
| 初始 | 30s | 60s | 120s | 180s | ||||
| 比較實例1 | SY-2 | N/A | 透明 | 175 | 175 | 170 | 170 | 170 |
| 實例2 | SY-2 | 2-PH | 透明 | 130 | 95 | 10 | 0 | 0 |
| 實例3 | SY-2 | 2-BO | 透明 | 125 | 110 | 72 | 20 | 5 |
| 實例4 | SY-2 | 2-EH | 透明 | 160 | 140 | 105 | 45 | 5 |
| 比較實例5 | SY-2 | ANTA L-61 | 透明 | 145 | 140 | 100 | 25 | 20 |
| 比較實例6 | SY-2 | FoamBan 3057 | 混濁 | 130 | 95 | 35 | 5 | 5 |
| 比較實例7 | SY-2 | 異丁醇 | 透明 | 150 | 150 | 140 | 75 | 50 |
| 比較實例8 | SY-2 | C12-C14直鏈醇 | 透明 | 170 | 170 | 100 | 25 | 23 |
| 比較實例9 | SY-2 | Exxal 13 | 混濁 | 140 | 135 | 110 | 25 | 20 |
| 比較實例10 | SY-6 | N/A | 透明 | 170 | 170 | 170 | 170 | 170 |
| 實例11 | SY-6 | 2-BO | 透明 | 135 | 125 | 115 | 110 | 110 |
| 比較實例12 | SY-6 | ANTA L-61 | 透明 | 180 | 180 | 170 | 170 | 170 |
| 比較實例13 | SY-6 | FoamBan 3057 | 混濁 | 160 | 155 | 150 | 140 | 140 |
| 比較實例14 | SY-6 | 異丁醇 | 透明 | 145 | 140 | 135 | 130 | 130 |
| 比較實例15 | SY-6 | C 12-C 14直鏈醇 | 混濁 | 135 | 135 | 130 | 130 | 130 |
| 比較實例16 | SY-6 | Exxal 13 | 混濁 | 145 | 140 | 140 | 140 | 140 |
如表3中所示，在典型合成MWF調配物中，1%劑量之三種測試支鏈醇與空白樣品相比有助於增加泡沫破裂。2-PH顯示最佳消泡劑效能且相比於市場中現有的非聚矽氧消泡劑在調配物中穩定。在含有較高含量高發泡乳化劑之典型半合成MWF中，與公認的泡沫控制劑FoamBan 3057相比，2-BO呈現更好的消泡特性，且2-BO在調配物中亦更穩定且維持透明度。
無
無
Claims (9)
- 一種適用於金屬加工液之泡沫控制劑，其包括具有以下結構之支鏈醇：其中x為2至14之整數且R為具有1-14個碳原子之烷基。
- 如請求項1之泡沫控制劑，其中支鏈醇濃度按該泡沫控制劑之重量計在0.01至100 wt%範圍內。
- 如請求項1之泡沫控制劑，其中該支鏈醇為古爾貝特（Guerbet）醇。
- 如請求項1之泡沫控制劑，其中該試劑為經2-烷基取代之醇。
- 如請求項之泡沫控制劑，其中該試劑為2-丁基-1-辛醇、2-乙基己醇或2-丙基庚醇。
- 一種藉由使用泡沫控制劑控制金屬加工液之泡沫的方法，其中該試劑包括至少一種具有以下結構之支鏈醇：其中x為2至14之整數且R為具有1-14個碳原子之烷基。
- 如請求項5之方法，其中使用至少一種其他泡沫控制劑或疏水性材料。
- 如請求項5之方法，其中該金屬加工液在與該泡沫控制劑組合時為透明的。
- 如請求項5之方法，其中該方法用於金屬加工。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2020/123535 WO2022087764A1 (en) | 2020-10-26 | 2020-10-26 | Metal working fluids foam control agent |
| WOPCT/CN2020/123535 | 2020-10-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW202216974A true TW202216974A (zh) | 2022-05-01 |
Family
ID=81381602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW110135170A TW202216974A (zh) | 2020-10-26 | 2021-09-22 | 金屬加工液泡沫控制劑 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US12116544B2 (zh) |
| EP (1) | EP4232535A4 (zh) |
| JP (1) | JP2024500209A (zh) |
| CN (1) | CN116507605A (zh) |
| TW (1) | TW202216974A (zh) |
| WO (1) | WO2022087764A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI803985B (zh) * | 2020-10-26 | 2023-06-01 | 美商陶氏全球科技有限責任公司 | 工業及機構清潔泡沫控制劑 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3013391A1 (de) * | 1980-04-05 | 1981-10-29 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung eines entschaeumers fuer waessrige systeme und seine verwendung als schauminhibitor |
| DE3929071A1 (de) | 1989-09-01 | 1991-03-07 | Henkel Kgaa | Universalschmiermittel auf der basis einer syntheseoelloesung |
| WO1991018074A1 (en) * | 1990-05-14 | 1991-11-28 | Idemitsu Kosan Co., Ltd. | Lubricant composition for metal working |
| DE10243362A1 (de) * | 2002-09-18 | 2004-04-01 | Basf Ag | Herstellung von Alkanolalkoxylaten bei optimierten Reaktionstemperaturen |
| JP4502709B2 (ja) * | 2004-05-20 | 2010-07-14 | 日本エンバイロケミカルズ株式会社 | 殺菌剤組成物及び安定化方法 |
| AU2009327174B2 (en) | 2008-12-18 | 2011-12-01 | Akzo Nobel Chemicals International B.V. | Defoamer composition comprising alkoxylated 2-propylheptanol |
| JP5566037B2 (ja) * | 2009-02-10 | 2014-08-06 | Ｊｘ日鉱日石エネルギー株式会社 | 極微量油剤供給式アルミニウム加工用油剤組成物 |
| CN106479654A (zh) | 2016-09-06 | 2017-03-08 | 深圳市宏达威表面处理技术有限公司 | 水基金属切削液 |
| CN107034003A (zh) | 2017-04-19 | 2017-08-11 | 清华大学 | 超低泡全合成水基润滑液 |
| CN107502910A (zh) | 2017-08-25 | 2017-12-22 | 广东长菱空调冷气机制造有限公司 | 一种热泵热水器生产用的水基型金属表面油污清洗剂 |
| JP7317033B2 (ja) * | 2018-03-16 | 2023-07-28 | ダウ グローバル テクノロジーズ エルエルシー | 泡制御 |
| CN111013201B (zh) | 2019-12-03 | 2022-05-03 | 江苏四新科技应用研究所股份有限公司 | 消泡剂组合物 |
-
2020
- 2020-10-26 WO PCT/CN2020/123535 patent/WO2022087764A1/en active Application Filing
- 2020-10-26 JP JP2023524285A patent/JP2024500209A/ja active Pending
- 2020-10-26 US US18/248,156 patent/US12116544B2/en active Active
- 2020-10-26 CN CN202080106689.XA patent/CN116507605A/zh active Pending
- 2020-10-26 EP EP20958930.8A patent/EP4232535A4/en active Pending
-
2021
- 2021-09-22 TW TW110135170A patent/TW202216974A/zh unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI803985B (zh) * | 2020-10-26 | 2023-06-01 | 美商陶氏全球科技有限責任公司 | 工業及機構清潔泡沫控制劑 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2024500209A (ja) | 2024-01-05 |
| US20240026241A1 (en) | 2024-01-25 |
| US12116544B2 (en) | 2024-10-15 |
| EP4232535A4 (en) | 2024-07-24 |
| WO2022087764A1 (en) | 2022-05-05 |
| EP4232535A1 (en) | 2023-08-30 |
| CN116507605A (zh) | 2023-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0206833B1 (en) | Aqueous fluids | |
| GB2351294A (en) | Cutting oil composition | |
| JP2010070736A (ja) | 水溶性金属加工油剤および金属加工用クーラント | |
| US3518917A (en) | Method of supplying fluids to machine tools | |
| US20150025182A1 (en) | Process for preparation of stable fatty alcohol emulsion | |
| US3950258A (en) | Aqueous lubricants | |
| TW202216974A (zh) | 金屬加工液泡沫控制劑 | |
| CA1294511C (en) | Aqueous fluids | |
| JP3468752B2 (ja) | 水溶性切削油剤組成物 | |
| JP6504342B2 (ja) | 水溶性金属加工油 | |
| JP2011132284A (ja) | 抗乳化剤、その製造法及びそれを含有する水溶性加工油剤組成物 | |
| US9499662B2 (en) | Foam control compositions | |
| GB2244279A (en) | Fluorosilicone anti-foam additive | |
| JP2006096826A (ja) | 水溶性切削油剤組成物及びそれを用いた切削加工方法 | |
| TWI803985B (zh) | 工業及機構清潔泡沫控制劑 | |
| US20230303947A1 (en) | Water based semi-synthetic metalworking fluid composition | |
| CA3022489A1 (en) | A new anti-foaming composition | |
| JPS6116485B2 (zh) | ||
| JP3205911B2 (ja) | 消泡剤 | |
| JPH0940982A (ja) | 金属加工用潤滑油 | |
| TWI815185B (zh) | 農用產品泡沫控制劑 | |
| CN116419911A (zh) | 废水泡沫控制剂 | |
| US20230383469A1 (en) | Paper and pulp foam control agent | |
| JP2006176604A (ja) | 水溶性金属加工剤組成物 | |
| RU2385341C2 (ru) | Смазочная добавка для буровых растворов |