TW202203891A - Oil-based cosmetic - Google Patents

Abstract

The present invention addresses the problem of providing an oil-based cosmetic which has long-lasting makeup wear resistance without causing tightness or dryness and exhibits a good effect of being free of secondary adhesion to clothes or dishes. The oil-based cosmetic comprises: (A) a silicone resin having a weight average molecular weight of 1500-40000 and having structural units of (A-1) (R1 3SiO1/2)a, (A-2) (R2 2SiO2/2)b, (A-3) (R3SiO3/2)c, and (A-4) (SiO4/2)d (in the formulae, R1, R2, and R3 are each independently a group selected from among a C1-8 alkyl group, a C6-12 aryl group, and a C1-8 fluorene-substituted alkyl group, a has a value of 0.2-0.5, b has a value of 0.0-0.1, c has a value of 0.2-0.6, d has a value of 0.2-0.5, the value of a+b+c+d is 1.0, the value of a/(c+d) is 0.3-0.9, and the value of c/d is 0.4-3.0); (B) a volatile oil; (C) one or more selected from among hydrocarbon oils and ester oils having a weight average molecular weight of 700-5000; and (D) one or more selected from among oil-based gelling agents and waxes.

Description

oily makeup

The present invention relates to an oily cosmetic.

Oil-based cosmetics are mostly used to impart color or luster to the skin or lips. They are cosmetic materials with good color development and glossy oily effects, which can greatly change the facial impression. Therefore, maintaining the makeup effect for a long time is a very important quality item. Various studies have previously been conducted on techniques for improving the durability of makeup (ie, the long-term durability of makeup effects or makeup films). Heretofore, the following techniques can be exemplified: by including a film-forming agent and a volatile oil agent, the volatile oil agent forms a firm film on the skin after volatilization, thereby achieving good makeup durability; Oil-repellent fluorine-based oils prevent make-up caused by sweat or sebum, and improve the durability of makeup; or use oil-soluble dyes to dye the skin or lips, and maintain the color for a long time. . Specifically, for example, the technology of formulating a cosmetic cosmetic material having a specific structure, volatile silicone oil, and powder, and having good water resistance and oil resistance and excellent cosmetic durability (patent Document 1); by containing a perfluoropolyether compound having a specific structure with an amine group, it provides water and oil repellency, prevents adhesion to tableware or clothes, etc., prevents color smudges and makeup over time, and is excellent in use. The technology of cosmetic materials for lips (Patent Document 2); the technology of formulating a silicone resin having a specific structural unit combined structure and a specific molecular weight (Patent Document 3); and the oil phase contains a specific ratio of non-volatile hydrocarbon oil and Specific silicone oil, the technology of oil-in-water lip cosmetic containing dyes and other colorants in the water phase (Patent Document 4), etc. prior art literature Patent Literature

Patent Document 1: Japanese Patent Laid-Open No. 8-143426 Patent Document 2: Japanese Patent Laid-Open No. 2018-52824 Patent Document 3: Japanese Patent Laid-Open No. 2018-2643 Patent Document 4: Japanese Patent Laid-Open No. 2018-2626

[Problems to be Solved by Invention]

Patent Document 1 is an invention of a cosmetic cosmetic material of a silicone resin of a specific structure, and Patent Document 2 is a cosmetic product obtained by the water resistance or oil resistance of the perfluoropolyether compound of the specific structure, which has good durability, and is smooth and smooth. The invention of a cosmetic cosmetic material that is excellent in a refreshing feel to the touch, but sometimes the softness of the film applied to the skin or lips or the lack of tightness at a moderate film-forming speed is not sufficient for the adhesion of cosmetic films. full. In Patent Document 3, there is room for improvement in the moderate film-forming speed and softness of the cosmetic film after the volatile oil agent has been volatilized. In addition, there is room for improvement in that the oil agent used in combination plasticizes the cosmetic film and reduces the effect of non-secondary adhesion. Furthermore, Patent Document 4 is an invention that maintains the color tone by dyeing the lips with a water-soluble dye prepared in the water phase, and there is a possibility that the persistence of the cosmetic film itself or the effect of no secondary adhesion (that is, the prevention of secondary adhesion cannot be sufficiently obtained) effect of attachment). That is, in a word, if the long-term durability of the cosmetic film is pursued, or the effect of non-adhering to clothes or tableware is improved, the film-forming speed of the cosmetic film will be too fast, which will cause the skin to feel uncomfortable and tight. Or because the softness of the cosmetic film is poor, the skin may feel uncomfortable, etc., and there is a tendency to lose the adhesion and comfort of the cosmetic film. Therefore, it is technically difficult to achieve a good balance of all these qualities to improve overall satisfaction. Therefore, an object of the present invention is to provide a softness that follows the movements of the skin or lips, and is excellent in usability such as no tightness, dryness, or stickiness at a moderate film-forming speed, and which is excellent in rub resistance and skin or lip Because of its excellent adhesion to lips, the cosmetic film has long-lasting durability, and is an oil-based cosmetic that has a good effect without secondary adhesion to clothes or tableware. [Technical means to solve problems]

The inventors of the present invention have made diligent studies in view of the above-mentioned actual situation, and as a result found that by including R ¹ ₃ SiO _1/2 units (M units) and R ² ₂ SiO _2/2 units (D units) in a specific range and a specific ratio ), R ³ SiO _3/2 (T unit), and SiO _4/2 unit (Q unit) silicone resin, volatile oil, hydrocarbon oil and/or ester oil with a molecular weight of 700-5000, and oily gelling The combination of agent and/or wax can obtain the following cosmetic materials, that is, since it has the flexibility to follow the movements of the skin or lips, the cosmetic film will not lose continuity such as defects, and there is no tightness at a moderate film-forming speed. It has excellent usability such as stretchy, dry or sticky feeling, and is excellent in abrasion resistance and adhesion to the skin or lips, so the cosmetic film has a long-term lasting effect, and there is no secondary adhesion effect to clothes or tableware. Good, and completed the present invention.

That is, the present invention is specified by the following matters. [1] An oil-based cosmetic comprising the following components (A) to (D): (A) The structural unit is represented by the following general formulae (A-1), (A-2), (A-3), (A) -4) Silicone resin with a weight average molecular weight of 1500-40000, (A-1)(R ¹ ₃ SiO _1/2 )a, (A-2)(R ² ₂ SiO _2/2 )b, (A-3) (R ³ SiO _3/2 )c, and (A-4) (SiO _4/2 )d (wherein R ¹ , R ² and R ³ are independently selected from the group consisting of 1 to 8 carbon atoms In the alkyl group, the aryl group having 6 to 12 carbon atoms, and the fluorine-substituted alkyl group having 1 to 8 carbon atoms, a has a value of 0.2 to 0.5, b has a value of 0.0 to 0.1, and c has a value of 0.2 to 0.6. value, d has a value of 0.2 to 0.5, a+b+c+d has a value of 1.0, a/(c+d) has a value of 0.3 to 0.9, and c/d has a value of 0.4 to 3.0); (B) volatile oil; (C) Hydrocarbon oil and/or ester oil with a weight average molecular weight of 700-5000; (D) Oil-based gelling agent and/or wax. [2] The oil-based cosmetic according to the above [1], which contains the component (A) in an amount of 1.0 to 45.0 mass %. [3] The oil-based cosmetic according to the above [1] or [2], further comprising a component (E) which is a liquid nonvolatile silicone oil at 25°C. [4] The oil-based cosmetic according to the above [3], wherein the component (E) is selected from the group consisting of phenyl-modified silicone, fluorine-modified silicone, and a viscosity of 1000 mm ² /s or more at 25° C. One or more of dimethylpolysiloxanes. [5] The oil-based cosmetic according to any one of the above [1] to [4], which is a lip cosmetic. [6] The oil-based cosmetic according to any one of the above [1] to [5], wherein the weight average molecular weight of the component (A) is 20,001 to 40,000. [7] The oil-based cosmetic according to any one of the above [1] to [6], wherein the component (C) is a semi-solid oil having a hardness of 0.1 to 10 N at 25°C. [8] The oil-based cosmetic according to any one of the above [1] to [7], wherein the component (C) contains one or two kinds of stearyl groups, behenic groups, or phytosterol groups The above is used as ester oil. [9] The oil-based cosmetic according to any one of the above [1] to [8], wherein the component (C) contains dimerized linoleic acid (phytosteryl/isostearyl) selected from the group consisting of ester oils base/cetyl/stearyl/behenyl) ester, hexa(hydroxystearic acid/stearic acid/rosin acid) dipentaerythritol ester, lauric glutamic acid di(octyldodecyl/vegetable solid) Alcohol/Behenyl) Ester, Hydrogenated Castor Oil Stearate, Di(cholesteryl/Behenyl/Octyldodecyl) Lauryl Glutamate, and Di(cholesteryl Lauryl Glutamate) /octyldodecyl) ester, and one or more of vaseline as hydrocarbon oil. [10] The oil-based cosmetic according to any one of the above [1] to [6], which contains a polyglycerol fatty acid ester as the component (C).

Moreover, as other embodiment of this invention, the following are mentioned. [11] The oil-based cosmetic according to any one of the above [7] to [9], which further contains a polyglycerol fatty acid ester as the component (C). [12] The oil-based cosmetic according to any one of the above [1] to [11], wherein 60% or more of the total of R ¹ , R ² and R ³ of the component (A) is a methyl group. [13] The oil-based cosmetic according to any one of the above [1] to [12], which contains the component (C) in an amount of 1 to 95% by mass. [14] The oil-based cosmetic according to any one of the above [1] to [13], which contains the component (D) in an amount of 0.5 to 30% by mass. [15] The oil-based cosmetic according to any one of the above [1] to [14], which contains the component (E) in an amount of 5 to 35% by mass. [16] The oil-based cosmetic according to any one of the above [1] to [15], which contains the component (A) and the component (C) in a mass ratio of 1:60 to 9:2. [17] The oil-based cosmetic according to any one of the above [1] to [16], which contains the component (A) and the component (D) in a mass ratio of 1:11 to 2:1. [Effect of invention]

The present invention provides a softness that follows the movements of the skin or lips, is excellent in usability such as no tightness, dryness, or stickiness at a moderate film-forming speed, and is excellent in abrasion resistance and adhesion to the skin or lips. Therefore, the cosmetic film has a long-term durability, and is an oily cosmetic that has no secondary adhesion to clothes or tableware.

Hereinafter, the present invention will be described in detail. In addition, in this specification, hereafter, mass % may be described only as "%", which means mass %, and when a numerical range is represented by -, the numerical value of both ends is included in the range.

The silicone resin-based structural unit of the component (A) used in the present invention comprises the following general formulae (A-1), (A-2), (A-3), (A-4) and has a weight average molecular weight of 1500～40000 silicone resin: (A-1)(R ¹ ₃ SiO _1/2 )a, (A-2)(R ² ₂ SiO _2/2 )b, (A-3)(R ³ SiO _{3 /2} )c, and (A-4)(SiO _4/2 )d.

R ¹ , R ² and R ³ in the above silicone resin are independently selected from the group consisting of alkyl groups having 1 to 8 carbon atoms, aryl groups having 6 to 12 carbon atoms, and fluorine-substituted alkyl groups having 1 to 8 carbon atoms. base. Specifically, a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, and an octyl group are mentioned as a C1-C8 alkyl group. Trifluoropropyl etc. are mentioned as a C1-C8 fluorine-substituted alkyl group. A phenyl group, a tolyl group, etc. are mentioned as a C6-C12 aryl group. Preferably it is a C1-C3 alkyl group, or a phenyl group, More preferably, it is selected from a methyl group and a phenyl group. Furthermore, preferably 50% or more of the total of R ¹ , R ² and R ³ are methyl groups, more preferably 60% or more of the total of R ¹ , R ² and R ³ are methyl groups, and most preferably R ¹ and R ² and 70% or more of the total of R ³ are methyl groups.

The value of a+b+c+d is 1.0. a has a value of 0.2 to 0.5. When a is less than 0.2, the film becomes hard and brittle, and when it exceeds 0.5, the film becomes sticky or liquid. a is more preferably 0.25 to 0.40. b has a value of 0.0 to 0.1. If b is greater than 0.1, the film is sticky. b is more preferably 0.0 to 0.05. c has a value of 0.2 to 0.6. If c is less than 0.2, the film becomes hard and brittle, and if it is greater than 0.6, the film becomes sticky. c is more preferably 0.2 to 0.5. d has a value of 0.2 to 0.5. If d is less than 0.2, the film becomes sticky, and if it is greater than 0.5, the film becomes hard and brittle. Furthermore, the ingredient (A) used in the present invention is more preferably one whose b is 0.0. When b is 0.0, the INCI name (according to INCI: International Nomenclature for Cosmetic Ingredients, "International Nomenclature of Cosmetic Ingredients" The international name of the named cosmetic ingredient) is recorded as POLYMETHYLSILSESQUIOXANE/TRIMETHYLSILOXYSILICATE, and the Japanese name is preferably polymethylsilsesquioxane/trimethylsiloxysilicic acid.

The value of a/(c+d) is 0.3 to 0.9. If a/(c+d) is less than 0.3, the film becomes hard and brittle, and if it is greater than 0.9, the film becomes sticky. a/(c+d) is more preferably 0.35 to 0.85. The value of c/d is 0.4 to 3.0. If c/d is less than 0.4, the film becomes hard and brittle, and if it exceeds 3.0, the film becomes sticky. It is more preferable that c/d is 0.6-2.5, and it is still more preferable that it is 0.9-2.0.

The weight average molecular weight of the silicone resin of the component (A) is 1,500 to 40,000. The weight average molecular weight is preferably 5,000 to 40,000, more preferably 8,500 to 40,000, more preferably 20,001 to 40,000, and still more preferably 28,000 to 40,000. The silicone resin can form a non-brittle, transparent, uniform and non-sticky film. In particular, because it contains 4-functional SiO _4/2 units and tri-functional R ³ SiO _3/2 units in a specific range of composition, it can form a non-sticky, soft and non-brittle film, which is stable over time. properties, water resistance, etc. become good. Therefore, the cosmetic material of the present invention formulated with the component (A) is not sticky when applied, spreads well, has an excellent feel in use, has good water resistance, and has good adhesion to the skin. Attachment to clothes, etc. (secondary attachment). In addition, the weight average molecular weight can be calculated|required by the weight average molecular weight in terms of polystyrene in gel permeation chromatography (GPC) analysis.

The silicone resin of the present invention is usually a solid, so it can be a pulverized solid, or can also be a solution diluted with an oil that can be used in cosmetics.

The silicone resin of the present invention can be produced by a known method. That is, the organosilicon compounds represented by the following formulae (1) and (2) and the compounds represented by the following formula (3), the following formula (4), and the following formula (5) can be hydrolyzed , to carry out a condensation reaction to manufacture. In addition, regarding the compound represented by following formula (3)-(5), the partial hydrolyzate may be used instead of this compound, and the partial hydrolyzate may be used in addition to this compound. R ¹ ₃ SiOSiR ¹ ₃ (1) R ¹ ₃ SiOR ⁴ (2) R ² ₂ Si(OR ⁴ ) ₂ (3) R ³ Si(OR ⁴ ) ₃ (4) Si(OR ⁴ ) ₄ (5) ( R ¹ , R ² and R ³ are the same as above, and R ⁴ is any one of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms)

The hydrolysis and condensation reactions are preferably carried out under acidic conditions, and an acidic substance is added as a catalyst. As an acidic substance, hydrochloric acid, sulfuric acid, p-toluenesulfonic acid, methanesulfonic acid, trifluoromethanesulfonic acid, phosphoric acid, acetic acid, citric acid, etc. are mentioned. The usage amount thereof is preferably a small amount, preferably in the range of 0.001 to 10% by mass of the entire system.

Moreover, a solvent can be used when performing a hydrolysis and a condensation reaction. Examples of the solvent include hydrocarbon-based solvents such as toluene, xylene, and isoalkane, ether-based solvents such as tetrahydrofuran, and alcohol-based solvents such as methanol, ethanol, (iso)propanol, and butanol. The solvent is preferably ethanol or (iso)propanol.

As a specific method of the said hydrolysis and condensation reaction, the method shown below can be mentioned. First, a solvent and a hydrolyzable raw material are put into a reactor, an acid is added, and water is added dropwise while stirring. The temperature at the time of dropwise addition of water is 0 to 80°C, preferably 0 to 50°C, and the amount of water to be added dropwise is preferably in the range of 0.6 to 2.0 in molar ratio with respect to the hydrolyzable group. After water is added dropwise, it is heated at 50 to 150° C., preferably 80 to 120° C. for 2 to 8 hours to carry out hydrolysis and condensation reactions. After hydrolysis, acid removal is carried out. In the removal of the acid, a method of neutralization using an alkali metal carbonate, an alkali metal hydrogen carbonate, an alkali metal hydroxide, or the like can be used. In addition, an acid can also be removed by a water washing process. After neutralizing the acid, add an oil that can be used in cosmetics, and only heat to remove the generated alcohol and excess water under normal pressure or reduced pressure, thereby obtaining a silicone resin solution. Moreover, the oil agent which can be used for cosmetics can also be added at the time of hydrolysis and condensation reaction.

In the oil-based cosmetic of the present invention, the content of component (A) in the total composition components (that is, in the total mass of the cosmetic), the lower limit is preferably 0.5% or more, more preferably 1% or more, and more preferably 5%. %. The upper limit may, for example, be 45% or less, more preferably 30% or less, still more preferably 20% or less, and still more preferably 15% or less. Furthermore, in the oil-based cosmetic, the content of the component (A) may, for example, be 1 to 45%, preferably 1 to 30%, more preferably 2.5 to 20%, and still more preferably 5 to 15%. Within this range, it is possible to obtain a softness that follows the movements of the skin or lips, and is excellent in usability without tightness, dryness, or stickiness, and is excellent in abrasion resistance and adhesion to the skin or lips. Cosmetic film is an oily cosmetic that has a long-term lasting effect, and has no secondary adhesion to clothes or tableware.

The volatile oil agent of the component (B) in the present invention is an oil agent that is volatile at room temperature, and preferably has a boiling point of 165-250°C under 1 atmosphere. These are not particularly limited as long as they are commonly used in cosmetic materials, and examples thereof include hydrocarbon oils such as isododecane and isohexadecane, decamethylcyclopentasiloxane, and octamethyl. Cyclotetrasiloxane, Dodecamethylcyclohexasiloxane, Methyl Trimethicone, Low Molecular Dimethyl Polysiloxane, Decamethyl Tetrasiloxane, Ethyl Trisiloxane, Disiloxane Wait. In addition to adjusting the touch of the component (B) during application, it can also form a film by dissolving the silicone resin of the component (A), which can also exhibit the effect of makeup durability and no secondary adhesion. One or more of these volatile oil agents may be used as needed.

The content of the component (B) in the oil-based cosmetic of the present invention is not particularly limited, and the lower limit is preferably 1% or more, more preferably 5% or more, in all components (that is, in the total mass of the cosmetic), and further Preferably it is 10% or more. The upper limit is preferably 90% or less, more preferably 80% or less, and still more preferably 70% or less. Within this range, the oil-based cosmetic is particularly excellent in terms of flexibility, film-forming speed, and durability of the cosmetic film.

The component (C) in the present invention is not particularly limited as long as it is a liquid or paste-like hydrocarbon oil or ester oil having a weight average molecular weight of 700 to 5,000, and one or two or more can be used. The lower limit of the weight average molecular weight is 700 or more. The upper limit of the weight average molecular weight is preferably 5,000 or less, more preferably 4,000 or less, and still more preferably 3,500 or less. Within this range, the compatibility of the components (C) and (A) is low, so the function of (A) is not hindered, and the stickiness of (A) is not enhanced. At the same time, since it is difficult to plasticize the cosmetic film, the effect of no secondary adhesion is not reduced. Therefore, it is possible to obtain a softness that follows the movements of the skin or lips, and is excellent in usability without tightness, dryness, or stickiness at a particularly moderate film-forming speed. Because of its excellent properties, the cosmetic film has long-term durability, and it is an oil-based cosmetic that has a good effect without secondary adhesion to clothes or tableware.

Examples of hydrocarbon oils include polybutene, hydrogenated polyisobutylene, α-olefin oligomers, liquid paraffin, heavy liquid isoparaffin, petrolatum, and the like, and examples of commercially available products include Parleam 18/24 /46 (the above are manufactured by NOF Corporation), refined polybutene HV-100F (SB) (manufactured by Japan NATURAL-PRODUCTS Co., Ltd.), Nippon Stone Polybutene HV-35/HV-100/300F/1900F (the above are JX Sunstone Energy Corporation), Nomcort HP100 (Nisshin OilliO Group Corporation), SNOW WHITE SPECIAL (SONNEBORN Corporation), Nomcort W (Nisshin OilliO Group Corporation), CROLATUM V (Croda Corporation), Sun White P-150 (manufactured by NIKKO RICA) etc.

As the ester oil, for example, polyglycerol-2 triisostearate (diglyceryl triisostearate), polyglycerol-2 tetraisostearate (diglyceryl tetraisostearate) may be mentioned. , glycerol triisostearate, polyglycerol-10 pentaisostearate (pentaisostearate ten glycerol), polyglycerol-10 nonaisostearate (nonaisostearate ten glycerol) , Polyglycerol-10 Deca Isostearate (Deca Isostearate), Polyglycerol-10 Deca Isooctanoate (Deca Isooctanoate) and other polyglycerol fatty acid esters, (vinylpyrrole) pyridone/eicosene) copolymer, (vinylpyrrolidone/hexadecene) copolymer, castor oil, tritridecyl trimellitate, dimerized linoleic acid (phytosteryl /isostearyl/cetyl/stearyl/behenyl) ester, dimerized linoleic alcohol hydrogenated rosin condensate, pentaerythritol tetraisostearate, hexa(hydroxystearic acid/stearic acid/rosin) acid) dipentaerythritol, lauryl glutamic acid di(octyldodecyl/phytosteryl/behenyl) ester, hydrogenated castor oil stearate, lauryl glutamic acid di(cholesteryl/behenyl) Carboxyl/octyldodecyl) ester, di(cholesteryl/octyldodecyl) lauryl glutamate, sucrose tetraisostearate, sucrose hexatetraisostearate, etc., especially More preferably, polyglycerol fatty acid esters, or ester oils having C14-24 straight-chain saturated fatty groups such as stearyl and behenyl groups, or ester oils having phytosterol groups, etc. can be exemplified. In particular, the polyglycerol fatty acid ester also has the effect of improving the dispersibility of the pigment, and it is more preferable to use it together with the other component (C). Commercially available products include: Cosmol43V, Cosmol44V, Cosmol168ARNV (the above are manufactured by Nisshin OilliO Group), IS-1005P, IS-1009P (the above are manufactured by Sakamoto Pharmaceutical Co., Ltd.), ANTARON V216, V220 (manufactured by ISP Japan Co., Ltd.) ), LIPONATE TDTM (manufactured by LIPO CHEMICALS), DOCADIT TM-13N (manufactured by Nisshin OilliO Group), PLANDOOL-S, LUSPLAN DD-DHR, PLANDOOL-LG3 (manufactured by Nippon Seika Co., Ltd.), ELDEW PS-306 ( Ajinomoto Co., Ltd.), Castride MS (manufactured by National Mimatsu Co., Ltd.), and the like.

Furthermore, the component (C) in the present invention is particularly preferably semi-solid from the viewpoint of improving the flexibility or the sustainability of the cosmetic film without hindering the film-forming properties of the component (A) after application. Oil, among them, hydrocarbon-based semi-solid oil is more preferable. Semi-solid means that it does not show fluidity when stored at normal temperature (25°C). For example, it is preferable that the hardness in normal temperature (25 degreeC) exists in the range of 0.1-10 N, and it is more preferable that it exists in the range which becomes 0.5-5 N of hardness. In particular, as the hydrocarbon-based semi-solid oil, petrolatum is preferred. In addition, as long as it is a semi-solid oil having the hardness as described above, even an ester-based semi-solid oil can have the same effect. In particular, as an ester-based semi-solid oil, dimerized linoleic acid ( Phytosteryl/isostearyl/cetyl/stearyl/behenyl) ester, hexa(hydroxystearic acid/stearic acid/rosin acid) dipentaerythritol ester, di(octyl lauroglutamic acid) Dodecyl/Phytosteryl/Behenyl) Ester, Hydrogenated Castor Oil Stearate, Di(cholesteryl/Behenyl/Octyldodecyl) Lauryl Glutamate, Lauryl Glutamate Di(cholesteryl/octyldodecyl) glutamate, etc. Furthermore, the hardness in the present invention is a value measured by using a rheometer manufactured by Rheotech with an adapter of 5 ϕ , a penetration speed of 2 cm/min, and a penetration of 3 mm.

The content of the component (C) in the oil-based cosmetic of the present invention is not particularly limited, and the lower limit is preferably 1% or more, more preferably 3% or more, in all components (that is, in the total mass of the cosmetic), and more preferably The best is more than 10%. The upper limit is preferably 95% or less, more preferably 80% or less, and still more preferably 70% or less. Within this range, an oil-based cosmetic that is particularly excellent in terms of flexibility and durability of a cosmetic film can be obtained.

The component (D) in the present invention is a component commonly used in cosmetic materials, as long as it is a component capable of solidifying or gelling the oily component, the others are not particularly limited, and can be determined according to the properties of the cosmetic material such as solid form and paste form. One type or two or more types are appropriately selected and blended. Examples of oil-based gelling agents include fumed silicon such as dextrin fatty acid esters, sucrose fatty acid esters, inulin fatty acid esters, 12-hydroxystearic acid, metal soaps, and dimethylsilylated silica. Acid Anhydride, (Behenic Acid/Eicosandioic Acid) Glycerides, (Dimethyl Polysiloxane/ Vinyl Dimethyl Polysiloxane) Crosspolymer, (Vinyl Dimethyl Polysiloxane) /alkyldimethylpolysiloxane) crosspolymer, (dimethylpolysiloxane/phenylvinyldimethylpolysiloxane) crosspolymer, (dimethylpolysiloxane) /PEG (Polyethylene Glycol, polyethylene glycol)) cross-linked polymer, silicone cross-linked polymers such as (alkyldimethylpolysiloxane/PEG) cross-linked polymer, and serratium chloride hectorite, Organically modified clay minerals such as distearyl dimethylammonium hectorite, amino acid-based gelling agents such as dibutyl lauryl glutamine and dibutyl ethyl hexyl glutamine, etc. As the wax, for example, paraffin wax, ozokerite wax, montan wax, microcrystalline wax, synthetic wax, ethylene-propylene copolymer, polyethylene wax, hydrocarbon wax such as Fischer-Tropsch wax, or candrillara wax, carnauba wax, honey can be exemplified. Waxes, rice bran wax, sunflower wax, jojoba and other ester waxes, etc. When the oily cosmetic is solid, using a wax as the component (D) is preferable in terms of the shape retention of the cosmetic, and it is more preferable to use a wax whose melting point is 80°C or higher. When the oil-based cosmetic is in the form of a paste or a liquid, it is preferable to use an oil-based gelling agent as the component (D), in terms of obtaining a smooth touch or improving usability.

The content of the component (D) is not particularly limited, but the lower limit is preferably 0.5% or more, more preferably 1% or more, and still more preferably 5% or more in the total composition components (that is, the total mass of the cosmetic). The upper limit is preferably 30% or less, more preferably 20% or less, and still more preferably 15% or less. Within this range, usability, film-forming speed, rubbing resistance, durability of cosmetic film, or no secondary adhesion effect can be improved.

By making the oil-based cosmetic of the present invention further contain the component (E) which is a liquid non-volatile silicone oil at 25° C., the film-forming speed, the sustainability of the cosmetic film, or the effect of no secondary adhesion can be improved. The non-volatile silicone oil that is liquid at 25° C. of the component (E) used in the present invention can be used without particular limitation, and one or two or more kinds can be prepared. Specifically, for example, dimethylpolysiloxane, methyltrimethicone, diphenylsiloxyphenyltrimethicone, phenyltrimethicone, diphenyldimethicone, and trimethylpentaphenyl can be mentioned. Phenyl-modified silicone such as trisiloxane, fluorine-modified silicone such as trifluoropropyl cyclopolysiloxane, etc. In particular, in the case of phenyl-modified silicone, fluorine-modified silicone, and dimethylpolysiloxane having a viscosity of 1000 mm ² /s or more at 25°C, the stickiness of the cosmetic film is suppressed. , no secondary adhesion effect is improved, and it is better. It does not specifically limit as a commercial item, KF-96A-1000CS, KF-96-5000CS, KF-96-10,000 CS, KF-96-100,000 CS, KF-56, KF-54, KF-54HV, FL-100-100CS, FL-100-450CS, FL-100-1000CS, FL-100-10000CS (the above are manufactured by Shin-Etsu Chemical Co., Ltd.), etc.

The content of the ingredient (E) is not particularly limited, but in terms of improving the film-forming speed, the sustainability of the cosmetic film, or the absence of secondary adhesion effects, among all the components (that is, the total mass of the cosmetic), it is preferably 5 to 35%, more preferably 10 to 30%.

The ratio of the content of the components (A) to (E) is not particularly limited, and in terms of mass ratio, it is preferably component (A):(C)=1:60 to 9:2, preferably the component (A): (D) = 1:11 to 2:1.

The present invention may contain any components other than the components (A) to (E) in addition to the above-mentioned components (A) to (E), within a range that does not impair the effects of the present invention, that is, the components (A) to (E) may be contained. Generally known components such as oily components other than (E), surfactants, powders, aqueous components, ultraviolet absorbers, moisturizing agents, antioxidants, cosmetic components, preservatives, pigments, and fragrances.

The oily components other than the components (A) to (E) are not particularly limited as long as they are commonly used in the fields of cosmetics, pharmaceuticals, and pharmaceuticals, and the others are solid, semisolid, liquid oil, Or animal oil, vegetable oil, mineral oil, synthetic oil, can be used.

The surfactant is not particularly limited as long as it can be used in the fields of cosmetics, pharmaceuticals, and pharmaceuticals such as ionic surfactants and nonionic surfactants.

The powder may be any powder generally used in cosmetics, and is not particularly limited to shapes such as spherical, plate, needle, aerosol, fine particles, pigment grade, particle size, porosity, non- Particle structures such as pores include inorganic powders, photoluminescent powders, organic powders, pigment powders, metal powders, composite powders, and the like. Specific examples include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate; colored inorganic pigments such as iron oxide, titanium-titanium oxide sintered product, chromium oxide, chromium hydroxide, iron blue, and ultramarine blue. Inorganic pigments; muscovite, phlogopite, red mica, biotite, synthetic mica, sericite, synthetic sericite, kaolin, silicon carbide, bentonite, bentonite, silicic anhydride, alumina, magnesia, zirconia, Diatomite, aluminum silicate, aluminum magnesium metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride and other white body powders; titanium dioxide coated mica, Titanium dioxide is coated with photoluminescent powders such as bismuth oxychloride, iron oxide mica titanium, iron blue treated mica titanium, magenta treated mica titanium, bismuth oxychloride, fish scale foil and other photoluminescent powders; Acrylic resins, polyester resins, fluorine resins, cellulose resins, polystyrene resins, styrene-acrylic copolymer resins and other copolymer resins, polypropylene resins, polyurethane resins and other organic polymer resin powders; Organic low molecular weight powders such as zinc stearate and N-acetyl lysine, natural organic powders such as silk powder and cellulose powder; Red No. 201, Red No. 202, Red No. 205, Red No. 226, Red No. 228 No., Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, etc., or Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. Organic pigment powders such as zirconium, barium or aluminum lake in color No. 1; metal powders such as aluminum powder, gold powder, silver powder, etc.; microparticle titanium oxide coated mica titanium, microparticle zinc oxide coated mica titanium, barium sulfate coated mica titanium, Silica containing titanium oxide, silica containing zinc oxide and other composite powders such as nylon, polyester, rayon, cellulose and other fibers. These can also be surface-treated with fluorine compounds, silicone oils, powders, oils, gelling agents, emulsion polymers, surfactants, and the like. One or more of these powders may be used, and powders further compounded may be used.

As the aqueous component, polyhydric alcohols such as water, propylene glycol, 1,3-butanediol, dipropylene glycol, glycerin, diglycerol, polyethylene glycol, sorbitol, and maltitol, carboxyvinyl polymers, and sodium alginate may, for example, be mentioned. , polyvinyl alcohol, polyvinyl pyrrolidone, etc., water-soluble polymers such as polyvinyl pyrrolidone, or mucilage such as resins, etc., as long as they are generally used in ordinary cosmetics, and others are not particularly limited. In particular, even if glycol ethers such as dipropylene glycol, tripropylene glycol, and ethylhexylglycerin are blended, the film-forming properties of the component (A) are unlikely to be hindered, which is preferable.

As a moisturizing agent, protein, mucopolysaccharide, collagen, elastin, keratin etc. are mentioned, for example.

Examples of antioxidants include vitamin E, ascorbic acid, and the like, examples of cosmetic ingredients include vitamins, anti-inflammatory agents, natural medicines, and the like, and examples of preservatives include parabens, Phenoxyethanol, 1,2-pentanediol, etc.

As the ultraviolet absorber, for example, anthranilic acid-based, dibenzoylmethane-based such as butylmethoxydibenzylmethane and isopropyldibenzylmethane, and ethylhexyl methoxycinnamate can be mentioned. , cinnamic acids such as isopropyl methoxycinnamate or 2-ethoxyethyl 4-methoxycinnamate, salicylic acids such as ethylhexyl salicylate, camphor-based, benzophenone- 3 and other benzophenone series, triazine series such as bis-ethylhexyloxyphenol methoxyphenyl triazine or ethylhexyl triazine ketone, benzotriazole, benzalmalonate series, benzene Bis-benzoxazole-based, p-aminobenzoic acid-based, diphenyl acrylate-based such as octocrylene, urocanic acid-based, and the like.

In addition to lip cosmetic materials such as lipstick, lip gloss, lip balm, lip balm, lip primer, lipstick film and the like, the oil-based cosmetic of the present invention can also be exemplified by eye shadow, eyebrow pencil, mascara, eyeliner, blush (cheek) ), sunscreen, concealer, powder, foundation, rouge (face color), body massage oil, hair care oil, etc., considering the softness, friction resistance, and no secondary adhesion of the cosmetic film, it may be better used in lip cosmetic.

The oil-based cosmetic of the present invention can be applied to an oil-based cosmetic containing an oil agent as a main ingredient, and a water-in-oil type cosmetic in which an outer layer serves as a continuous phase of the oil agent to disperse an aqueous ingredient. From the viewpoint of exerting the effects of the present invention, Preferably, the content of water is 1% or less, more preferably 0.5% or less, in the entire composition (that is, in the total mass of the cosmetic), and is an oil-based cosmetic that does not contain substantially water. [Example]

Next, although an Example is given and this invention is demonstrated more concretely, this invention is not limited by an Example at all. [Example I] Silicone resins 1 to 3 manufactured by Shin-Etsu Chemical Co., Ltd. were obtained. The manufacturing method of the silicone resins 1-3 in Shin-Etsu Chemical Co., Ltd. is as follows. In addition, the weight average molecular weight of each silicone resin was calculated|required by the polystyrene conversion weight average molecular weight in gel permeation chromatography (GPC) analysis. In addition, the molar ratio of R ₃ SiO _1/2 unit, R ₂ SiO _2/2 unit, RSiO _3/2 unit, and SiO _4/2 unit of each silicone resin is based on the assumption that the amount of each raw material added is calculated. ratio. [Production Example of Silicone Resin 1 of Component (A)] 180 g of hexamethyldisiloxane, 514 g of triethoxymethylsilane, and 40% SiO ₂ components were added to a reactor as raw materials 233 g of polyethyl silicate, 300 g of IPA (isopropyl alcohol) as a solvent, 6 g of methanesulfonic acid was added, cooled to 10-20°C, and 180 g of water was added dropwise while stirring. After completion of the dropwise addition, the solution was heated at 70 to 90° C. for 5 hours, and hydrolyzed and condensed to obtain a silicone resin solution. Next, 9.6 g of a 25% aqueous sodium hydroxide solution and 1.24 g of calcium carbonate were added to neutralize the acid, and then 400 g of isododecane was added, heated to 130° C., and the resulting ethanol and excess water were removed, followed by cooling. Further, after being distilled off under reduced pressure, it was diluted and adjusted with isododecane so that the concentration of the silicone resin would be 50%, followed by filtration to obtain a weight-average molecular weight of 33,000 and (CH ₃ ) ₃ SiO _1/2 Units: CH ₃ SiO _3/2 units: SiO _4/2 units The molar ratio (assumed ratio) was 0.33:0.43:0.23 in a 50% solution of silicone resin in isododecane.

[Production example of silicone resin 2 of component (A)] As raw materials, 175 g of hexamethyldisiloxane, 465 g of triethoxymethylsilane, and polysilicic acid containing 40% of SiO ₂ were used. 289 g of ethyl ester was hydrolyzed, condensed, and neutralized in the same manner as in Silicone Resin 1, except that 400 g of isododecane was added, heated to 130°C, and the generated ethanol and excess water were removed. Cool down. Furthermore, after being distilled off under reduced pressure, it was diluted and adjusted with isododecane so that the concentration of the silicone resin would be 50%, followed by filtration to obtain a weight average molecular weight of 35500, (CH ₃ ) ₃ SiO _1/2 Units: CH ₃ SiO _3/2 units: SiO _4/2 units The molar ratio (assumed ratio) was 0.32:0.39:0.29 in a 50% solution of silicone resin in isododecane.

[Production Example of Silicone Resin 3 of Component (A)] As raw materials, 185 g of hexamethyldisiloxane, 368 g of triethoxymethylsilane, and polysilicic acid containing 40% of SiO ₂ were used. 342 g of ethyl ester were hydrolyzed, condensed, and neutralized in the same manner as in Silicone Resin 1, except that 400 g of isododecane was added, and the mixture was heated to 130° C. to remove the generated ethanol and excess water. Cool down. Further, after being distilled off under reduced pressure, it was diluted and adjusted with isododecane so that the silicone resin concentration would be 50%, and then filtered to obtain a weight-average molecular weight of 31,500 and (CH ₃ ) ₃ SiO _1/2 Units: CH ₃ SiO _3/2 units: SiO _4/2 units The molar ratio (assumed ratio) was 0.34:0.31:0.34 in a 50% solution of the silicone resin in isododecane.

The R ₃ SiO _1/2 unit, the R ₂ SiO _2/2 unit, the RSiO _3/2 unit, and the SiO _4/2 unit of the component (A) in the present invention are indicated as follows, respectively. R ₃ SiO _1/2 unit→M, R ₂ SiO _2/2 unit→D, RSiO _3/2 unit→T, and SiO _4/2 unit→Q Silicone resin 1 belonging to the component (A) in the present invention The weight average molecular weights of ~3 and the molar ratios of M, D, T, Q (the assumed ratios calculated based on the added amount) are shown in Table 1 below. Furthermore, the comparative silicone resin 4 which does not belong to the component (A) in the present invention has M and T, and is SILFORM FLEXIBLE RESIN (manufactured by Momentive High-Tech Materials Japan Co., Ltd.) (solid content 100%).

[Table 1] weight average molecular weight M/D/T/Q (assumed ratio) M/(T+Q) (assumed ratio) T/Q (assumed ratio) Silicone Resin 1 33000 0.33/0/0.43/0.23 0.5 1.87 Silicone Resin 2 35500 0.32/0/0.39/0.29 0.47 1.34 Silicone Resin 3 31500 0.34/0/0.31/0.34 0.52 0.91

Examples 1-4, Comparative Examples 1-2: Lip Glaze The lip gloss of the formula shown in the following table 2 was prepared, regarding (a) softness, (b) abrasion resistance, (c) persistence of cosmetic film, (d) no secondary adhesion effect, by the following Evaluation methods 1 to 4 were used for determination. The results are also shown in Table 2 together.

[Table 2] (%) Element Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Comparative Example 2 (1) 50% Isododecane Solution of Silicone Resin 1 30 - - - - - (2) 50% isododecane solution of silicone resin 2 - 30 - - - - (3) 50% isododecane solution of silicone resin 3 - - 30 30 - - (4) Comparing Silicone Resin 4 in 50% Isododecane Solution - - - - - 30 (5) Isododecane (boiling point 176～192℃ at 1 atmosphere) The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount (6) Decamethylcyclopentasiloxane (boiling point 210°C at 1 atmosphere) - - - - - - (7) Tris(tridecyl) trimellitate (weight average molecular weight 757) 2 2 2 2 2 2 (8) Deca isostearate decaglyceride (weight average molecular weight 3383) - - - - - - (9) Diglyceryl tetraisostearate (weight average molecular weight 1230) 2 2 2 - 2 2 (10) Vaseline*1 - - - 2 - - (11) Paraffin ※2 2 2 2 2 2 2 (12) cetyl isononanoate - - - - - - (13) Squalane 1 1 1 1 1 1 (14) distearyldimethylammonium hectorite 5 5 5 5 5 5 (15) Isododecane 20 20 20 20 20 20 (16) Butanediol 1 1 1 1 1 1 (17) Dimethylsilylated silica*3 3 3 3 3 3 3 (18) calcium carbonate 0.1 0.1 0.1 0.1 0.1 0.1 (19) DPG 0.5 0.5 0.5 0.5 0.5 0.5 (20) BHT 0.01 0.01 0.01 0.01 0.01 0.01 (twenty one) Synthetic mica*4 5 5 5 5 5 5 (twenty two) Methyl methacrylate cross-linked polymer 1 1 1 1 1 1 (twenty three) Mica※5 - - - - - - (twenty four) Iron Dan 0.5 0.5 0.5 0.5 0.5 0.5 (25) Red No. 202 1.5 1.5 1.5 1.5 1.5 1.5 (26) Red No. 104 0.5 0.5 0.5 0.5 0.5 0.5 (27) Yellow No. 4 2 2 2 2 2 2 (28) Silicone 1% treated titanium oxide 3 3 3 3 3 3 (29) Perfluorohexylethyltriethoxysilane 2% black iron oxide 0.2 0.2 0.2 0.2 0.2 0.2 <Evaluation Items and Judgment Results> (a) Softness ◎ ◎ ◎ ◎ ◎ ◎ (b) Friction resistance ◎ ◎ ◎ ◎ × × (c) Persistence of cosmetic film ◎ ◎ ◎ ◎ × 〇 (d) No secondary adhesion effect ◎ ◎ ◎ ◎ × × ※1: Nomcort W (manufactured by Nisshin OilliO) ※2: PARACERA 256 (manufactured by PARAMELT) ※3: AEROSIL R976S (manufactured by Nippon Aerosil) ※4: PDM-20L (manufactured by Tobei Industries) ※5: Sericite FSE (manufactured by Sanshin Mining Co., Ltd.)

(Production method) A. The components (1) to (6) are heated to 80°C and dissolved uniformly. B. The components (7) to (17) are heated to 80° C., uniformly mixed and dispersed, and prepared into a gel. C. Add components (18) to (29) to A.B, and mix and disperse them uniformly. After defoaming, it was filled into a container to obtain a lip gloss.

[Evaluation method 1] (a) Softness About each sample, the coating film of 200 micrometers was produced on the aluminum plate, and after drying, the bending test was performed using the cylindrical mandrel bending tester, and the state of the coating film was evaluated. The test was evaluated by the method according to JIS K5600-5-1. This experiment was performed 5 times for each sample, and the evaluation and scoring were carried out in 5 grades according to the following evaluation criteria, and the average value was calculated from the scores of the 5 times, and the judgment was made according to the following judgment criteria. Tester: Cylindrical mandrel bending tester KT-SP1820 manufactured by TQC Company Use mandrel: diameter 32 mm <Evaluation Criteria> (rating): (evaluation) 5: No cracks are generated on the coating film 4: Very few transverse cracks are generated on the coating film 3: Transverse cracks on the coating film 2: Small transverse cracks and longitudinal cracks are generated on the coating film 1: Many transverse cracks and longitudinal cracks are produced on the coating film <Judgment Criteria> (judgment): (average of scores) ◎: More than 4.5 points: Very high flexibility 〇: More than 3.0 points and 4.5 points or less: High flexibility △: More than 2.0 points and 3.0 points or less: Low flexibility ×: 2.0 points or less: Very low flexibility

[Evaluation method 2] (b) Abrasion resistance Apply a lipstick with a thickness of 1.0 mg/cm ² on artificial leather, and after drying, place a 50 g weight in a cylindrical shape with a diameter of 10 mm (a 3M weight is attached to the bottom surface) The precision abrasive paper manufactured by the company is used to grind the film sheet #600), and the change of the coating film after 5 round trips in the horizontal direction is observed. The test was performed three times for each sample, and the evaluation and scoring were carried out in five grades according to the following evaluation criteria, and the average value was calculated based on the total of the three scores. <Evaluation Criteria> (Score): (Evaluation) 5: The coating film was slightly thinned 4: The coating film was uniformly thinned 3: The coating film was partially collapsed and fell off 2: The coating film was collapsed and became extremely thin Thin 1: Coating film collapsed and almost no residue <Criteria for judgment> (judgment): (average of scores) ⊚: 4 points or more: very good ○: 3 points or more and less than 4 points: good ×: less than 3 points Score: Bad

[Evaluation method 3] (c) Persistence of cosmetic film Each sample was subjected to a use test by 20 professional functional inspectors. Each sample was applied, and the sensory inspector was allowed to carry out a normal life, and thereafter, the state of the coating film and color of the lipstick on the lips was evaluated after 6 hours. Each of the sensory examiners was evaluated and scored on five levels according to the following evaluation criteria, and the average value was calculated based on the scores of all the sensory examiners, and the judgment was made according to the following evaluation criteria. <Evaluation Criteria> (rating): (evaluation) 5: There is no change in the color of the lipstick and the state of the coating film, which is very good 4: There is no major change in the color of the lipstick and the state of the coating film, which is relatively good 3: The color of the lipstick and the coating film are slightly off 2: The color of the lipstick and the coating film fall off considerably 1: The color of the lipstick and the coating film almost fall off <Judgment Criteria> (judgment): (average of scores) ◎: More than 4.5 points: Very good ○: More than 3.0 points and 4.5 points or less: Good △: More than 1.5 points and 3.0 points or less: Defective ×: 1.5 points or less: Very bad

[Evaluation method 4] (d) No secondary adhesion effect After 1 minute of coating on the wrist, the paper towel was pressed lightly, and the evaluation was performed based on whether the coating film/color was transferred to the paper towel. The test was performed three times for each sample, and the evaluation and scoring were carried out in five grades according to the following evaluation criteria, and the average value was calculated based on the total of the three scores. <Evaluation Criteria> (rating): (evaluation) 5: The coating film/color does not transfer at all 4: Very little coating film/color transfer 3: Coating film/color transfer a little 2: Coating film/color transfer quite a lot 1: Coating film/color transfer most of <Judgment criteria> (judgment): (average of scores) ◎: Over 4.5 points: Very high non-secondary adhesion effect ○: More than 2.0 points and 4.5 points or less: No secondary adhesion effect is low ×: 2.0 points or less: almost no secondary adhesion effect is seen

From the results in Table 2, it is clear that Examples 1 to 4 obtained very good results in all the evaluation items. On the other hand, in Comparative Example 1 which does not contain the component (A), the cosmetic film is only an oil film, the fluidity is high, and the silicone resin film is not formed, so the abrasion resistance and the sustainability of the cosmetic film cannot be obtained. Obtain no secondary adhesion effect. In Comparative Example 2 using Comparative Silicone Resin 4 that does not contain a Q unit, a film with flexibility can be obtained, but it has a sticky feel, and is poor in abrasion resistance and no secondary adhesion.

[Predictive Example I] Oil-based cosmetics containing the following silicone resins 4 to 13 and comparative silicone resins 1 to 3 disclosed in Japanese Patent Laid-Open No. 2018-2643 were obtained. Furthermore, the silicone resins 4 to 13 belong to the component (A) in the present invention, while the silicone resins 1 to 3 do not belong to the component (A) in the present invention. [table 3] weight average molecular weight M/D/T/Q M/(T＋Q) T/Q Silicone Resin 4 9350 0.32/0/0.40/0.28 0.47 1.43 Silicone Resin5 2260 0.30/0.00/0.44/0.26 0.43 1.69 Silicone Resin 6 3950 0.25/0.00/0.50/0.25 0.33 2 Silicone Resin7 3210 0.40/0.10/0.25/0.25 0.8 1 Silicone Resin 8 4330 0.35/0.00/0.45/0.20 0.54 2.25 Silicone Resin9 4550 0.25/0.00/0.35/0.40 0.33 0.88 Silicone Resin 10 5870 0.23/0.00/0.55/0.22 0.3 2.5 Silicone Resin 11 9200 0.45/0.05/0.30/0.20 0.9 1.5 Silicone Resin 12 3680 0.30/0.025/0.30/0.375 0.44 0.8 Silicone Resin 13 5000 0.25/0.05/0.50/0.20 0.36 2.5 Compare Silicone Resins 1 3400 0.55/0.00/0.30/0.15 1.2 2 Compare Silicone Resins 2 6100 0.20/0.00/0.40/0.40 0.25 1 Compare Silicone Resins 3 5220 0.40/0.00/0.00/0.60 0.67 0

Examples 5 to 11, Comparative Examples 3 to 7: lipstick (solid form) Lipsticks with the formulations shown in Table 4 below were prepared and judged for (a) softness, (b) abrasion resistance, (c) durability of cosmetic film, and (d) no secondary adhesion effect. (a) Evaluation and determination were performed by the following evaluation method 5, and (b) to (d) were evaluated and determined by the above-mentioned evaluation methods 2 to 4. The predicted results are also shown in Table 4. Regarding Comparative Examples 3 to 5, the lipsticks were adjusted and evaluated and judged.

[Table 4] (%) Element Example 5 Implementation side 6 Example 7 Example 8 Example 9 Example 10 Example 11 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 (1) 50% decamethylcyclopentasiloxane solution of silicone resin 4 15 - 15 15 15 20 2 - - - 15 15 (2) 50% Isododecane Solution of Silicone Resin 11 - 15 - - - - - - - - - - (3) Trimethylsiloxysilicic acid (*6) - - - - - - - - 7.5 3 - - (4) Compare silicone resin 4 (*7) - - - - - - - - - 3 - - (5) Isododecane (boiling point 176～192℃ at 1 atmosphere) 5 5 - 5 5 18 10 10 7.5 5 5 5 (6) Dimethylpolysiloxane (viscosity 2 mm ² /s at 25°C, boiling point 230°C at 1 atmosphere) - - - 10 - - 7 - - - - - (7) Methyl trimethicone (boiling point 191°C at 1 atmosphere) - - 5 - - - - - - - - - (8) Tris(tridecyl) trimellitate (weight average molecular weight 757) 20 20 20 20 20 20 20 20 20 20 - - (9) Decaisocaprylic acid decaglyceride (weight average molecular weight 1983) 20 20 20 20 20 20 20 20 20 - - (10) Deca isostearate decaglyceride (weight average molecular weight 3383) - - - 10 - - - - - - - - (11) Diglyceryl triisostearate (weight average molecular weight 966) The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount - - (12) Heavy liquid isoparaffin (weight average molecular weight about 1000)※8 - - - 10 - - - - - - - - (13) Cetyl isononanoate (weight average molecular weight 383) - - - - - - - - - - The remaining amount - (14) Hydrogenated polyisobutylene (weight average molecular weight 336)*9 - - - - - - - - - - - The remaining amount (15) Ethylene/propylene copolymer*10 3 3 3 3 3 3 3 3 3 3 3 3 (16) Synthetic Wax※11 5 5 5 5 5 5 5 5 5 5 5 5 (17) Candila Wax ※12 2 2 2 2 2 2 2 2 2 2 2 2 (18) Dimethylsilylated silica*3 1 1 1 1 1 1 1 1 1 1 1 1 (19) Dimethylpolysiloxane (viscosity 1000 mm ² /s at 25°C) - - - - 9 - - - - - - - (20) Diphenyl dimethicone ※13 - - - - 9 - - - - - - - (twenty one) Trifluoropropyl Dimethicone ※14 - - 18 - - - - - - - - - (twenty two) calcium carbonate 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 (twenty three) Phenoxyethanol 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 (twenty four) Natural Vitamin E 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (25) Synthetic mica*4 1 1 1 1 1 1 1 1 1 1 1 1 (26) Mica※5 1 1 1 1 1 1 1 1 1 1 1 1 (27) Silicone 2% treated mica titanium 2 2 2 2 2 2 2 2 2 2 2 2 (28) Red No. 202 1 1 1 1 1 1 1 1 1 1 1 1 (29) Yellow No. 4 2 2 2 2 2 2 2 2 2 2 2 2 (30) Isopropoxytitanium triisostearate 1% treated titanium oxide 2 2 2 2 2 2 2 2 2 2 2 2 (31) Silicone 2% Black Iron Oxide 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 <Evaluation Items and Judgment Results> (a) Softness ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ × △ ◎ ◎ (b) Friction resistance ◎ 〇 ◎ ◎ 〇 ◎ 〇 × 〇 〇 × × (c) Persistence of cosmetic film ◎ ◎ ◎ ◎ ◎ ◎ 〇 × △ △ × × (d) No secondary adhesion effect ◎ 〇 ◎ 〇 ◎ 〇 〇 × 〇 × × × *6: SR1000 (manufactured by Momentive Advanced Materials Co., Ltd.) *7: Comparative Silicone Resin 4 (Polymethyl Silsesquioxane): SILFORM FLEXIBLE RESIN (manufactured by Momentive Advanced Materials Co., Ltd.) *8: Parleam18 (NOF Corporation Manufacturing) ※9: Parleam6 (manufactured by NOF Corporation) ※10: Petrolite EP-700 (manufactured by Baker Petrolite Corporation) ※11: CIREBELLE 109L (manufactured by CIREBELLE Corporation) PRODUCTS Co., Ltd.) ※13: KF-54 (made by Shin-Etsu Chemical Industry Co., Ltd.) ※14: FL-100-100CS (made by Shin-Etsu Chemical Co., Ltd.)

(Production method) A. The components (1) to (7) are heated to 80°C and dissolved uniformly. B. Add components (8) to (21) to A, heat to 100°C, and mix uniformly. C. Add components (22) to (31) to B and disperse them uniformly. After heating to 100° C., it was filled in a container, cooled to room temperature, and solidified to obtain a lipstick. For Comparative Examples 3 to 5, lipsticks were obtained.

[Evaluation method 5] (a) Softness Each sample was subjected to a use test by 20 professional functional inspectors. Each sample was applied, and the state of the cosmetic film on the lips after 5 minutes was observed, and it was evaluated whether the film did not break and maintained continuity when the lips were moved. Each of the sensory examiners was evaluated and scored on five levels according to the following evaluation criteria, and the average value was calculated based on the scores of all the sensory examiners, and the judgment was made according to the following evaluation criteria. About Comparative Examples 3-5, evaluation and determination were performed. <Evaluation Criteria> (rating): (evaluation) 5: The continuity of the film is maintained, and no rupture (crack) of the film is seen 4: The continuity of the membrane is maintained, but very small ruptures are seen locally 3: The continuity of the membrane is roughly maintained, but minor ruptures are seen 2: The film is cracked and the continuity is slightly damaged 1: On the whole, more ruptures are seen, and the continuity is damaged <Judgment Criteria> (judgment): (average of scores) ◎: 4.5 points or more: very good ○: More than 3 points and less than 4.5 points: Good △: More than 1.5 points and less than 3 points: Defective ×: 1.5 points or less: Very bad

In Comparative Example 3, which does not contain the component (A), the cosmetic film is only an oil film, which has high fluidity and does not form a silicone resin film. Therefore, the abrasion resistance and the continuity of the cosmetic film cannot be obtained, and there is no secondary adhesion. Effect. Regarding Comparative Example 4 using trimethylsiloxysilicic acid instead of component (A), the coating film was hard and brittle, so it had no flexibility, and cracks occurred in the film, but a certain degree of abrasion resistance, The persistence of cosmetic film and no secondary adhesion effect. Regarding Comparative Example 5 in which trimethylsiloxysilicic acid and polymethylsilsesquioxane were used in combination in place of component (A), the coating film was hard and brittle, so it had no flexibility, and the volatile oil was volatilized. The sticky feeling during the period up to now was strong, so the effect of no secondary adhesion could not be obtained. In addition, in Comparative Examples 6 and 7 which do not contain the component (C), since the uniform film of the component (A) was not formed, it is predicted that the abrasion resistance, the continuation of the cosmetic film, and the secondary adhesion effect cannot be obtained. On the other hand, as shown in Table 4, with regard to Examples 5 to 11, it is predicted that favorable results can be obtained as compared with those of Comparative Examples 3 to 7.

Examples 12-24, Comparative Examples 8-11: Lip Glaze The lip enamels of the formulas shown in the following Tables 5 and 6 were prepared by the same method as the lip enamels of the above-mentioned Examples 1 to 4 and Comparative Examples 1 to 2. Regarding (a) softness, (b) friction resistance, (c) Persistence of the cosmetic film and (d) No secondary adhesion effect were determined by the above-mentioned evaluation methods 1 to 4. The predicted results are also shown in Table 5 and Table 6 together.

[table 5] (%) Element Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 (1) 50% decamethylcyclopentasiloxane solution of silicone resin 4 30 - - - - - - - - - (2) 50% tris(trimethylsiloxy)methylsilane solution of silicone resin 5 - 30 - - - - - - - - (3) Silicone resin 6 in 50% isododecane solution - - 30 - - - - - - - (4) Silicone resin 7 in 50% isododecane solution - - - 30 - - - - - - (5) 50% decamethylcyclopentasiloxane solution of silicone resin 8 - - - - 30 - - - - - (6) 50% decamethylcyclopentasiloxane solution of silicone resin 9 - - - - - 30 - - - - (7) Silicone resin 10-50% decamethylcyclopentasiloxane solution - - - - - - 30 - - - (8) 50% Isododecane Solution of Silicone Resin 11 - - - - - - - 30 - - (9) Silicone resin 12 in 50% isododecane solution - - - - - - - - 30 - (10) 50% decamethylcyclopentasiloxane solution of silicone resin 13 - - - - - - - - - 30 (11) Comparing Silicone Resin 1 in 50% Isododecane Solution - - - - - - - - - - (12) Comparison of 50% decamethylcyclopentasiloxane solution of silicone resin 2 - - - - - - - - - - (13) Comparing Silicone Resin 3 in 50% Isododecane Solution - - - - - - - - - - (14) Comparison of 50% decamethylcyclopentasiloxane solution of silicone resin 4 - - - - - - - - - - (15) Isododecane (boiling point 176～192℃ at 1 atmosphere) The remaining amount - The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount (16) Decamethylcyclopentasiloxane (boiling point 210°C at 1 atmosphere) - The remaining amount - - - - - - - - (17) Tris(tridecyl) trimellitate (weight average molecular weight 757) 2 2 2 2 2 2 2 2 2 2 (18) Deca isostearate decaglyceride (weight average molecular weight 3383) - - - - - - - - - - (19) Diglyceryl tetraisostearate (weight average molecular weight 1230) 2 2 2 2 2 2 2 2 2 2 (20) Vaseline*1 - - - - - - - - - - (twenty one) Paraffin ※2 2 2 2 2 2 2 2 2 2 2 (twenty two) cetyl isononanoate - - - - - - - - - - (twenty three) Squalane 1 1 1 1 1 1 1 1 1 1 (twenty four) distearyldimethylammonium hectorite 5 5 5 5 5 5 5 5 5 5 (25) Isododecane 20 20 20 20 20 20 20 20 20 20 (26) Butanediol 1 1 1 1 1 1 1 1 1 1 (27) Dimethylsilylated silica*3 3 3 3 3 3 3 3 3 3 3 (28) calcium carbonate 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 (29) DPG 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (30) BHT 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 (31) Synthetic mica*4 5 5 5 5 5 5 5 5 5 5 (32) Methyl methacrylate cross-linked polymer 1 1 1 1 1 1 1 1 1 1 (33) Mica※5 - - - - - - - - - - (34) Iron Dan 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (35) Red No. 202 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 (36) Red No. 104 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (37) Yellow No. 4 2 2 2 2 2 2 2 2 2 2 (38) Silicone 1% treated titanium oxide 3 3 3 3 3 3 3 3 3 3 (39) Perfluorohexylethyltriethoxysilane 2% black iron oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 <Evaluation Items and Judgment Results> (a) Softness ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ (b) Friction resistance ◎ 〇 〇 ◎ 〇 ◎ 〇 ◎ ◎ 〇 (c) Persistence of makeup sighs ◎ 〇 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ (d) No secondary adhesion effect ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎

[Table 6] (%) Element Example 22 Example 23 Example 24 Comparative Example 8 Comparative Example 9 Comparative Example 10 Comparative Example 11 (1) 50% decamethylcyclopentasiloxane solution of silicone resin 4 20 5 40 - - - - (2) 50% tris(trimethylsiloxy)methylsilane solution of silicone resin 5 - - - - - - - (3) Silicone resin 6 in 50% isododecane solution - - - - - - - (4) Silicone resin 7 in 50% isododecane solution - - - - - - - (5) 50% decamethylcyclopentasiloxane solution of silicone resin 8 - - - - - - - (6) 50% decamethylcyclopentasiloxane solution of silicone resin 9 - - - - - - - (7) Silicone resin 10-50% decamethylcyclopentasiloxane solution - - - - - - - (8) 50% Isododecane Solution of Silicone Resin 11 - - - - - - - (9) Silicone resin 12 in 50% isododecane solution - - - - - - - (10) 50% decamethylcyclopentasiloxane solution of silicone resin 13 - - - - - - - (11) Comparing Silicone Resin 1 in 50% Isododecane Solution - - - 30 - - - (12) Comparison of 50% decamethylcyclopentasiloxane solution of silicone resin 2 - - - - 30 - - (13) Comparing Silicone Resin 3 in 50% Isododecane Solution - - - - - 30 15 (14) Comparison of 50% decamethylcyclopentasiloxane solution of silicone resin 4 - - - - - - 15 (15) Isododecane (boiling point 176～192℃ at 1 atmosphere) The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount The remaining amount (16) Decamethylcyclopentasiloxane (boiling point 210°C at 1 atmosphere) 15 - - - - - - (17) Tris(tridecyl) trimellitate (weight average molecular weight 757) - 2 2 2 2 2 2 (18) Deca isostearate decaglyceride (weight average molecular weight 3383) 5 - - - - - - (19) Diglyceryl tetraisostearate (weight average molecular weight 1230) - 2 2 2 2 2 2 (20) Vaseline*1 - - - - - - - (twenty one) Paraffin ※2 - 2 2 2 2 2 2 (twenty two) cetyl isononanoate - - - - - - - (twenty three) Squalane 1 1 1 1 1 1 1 (twenty four) distearyldimethylammonium hectorite 5 5 5 5 5 5 5 (25) Isododecane 20 20 20 20 20 20 20 (26) Butanediol 1 1 1 1 1 1 1 (27) Dimethylsilylated silica*3 3 3 3 3 3 3 3 (28) calcium carbonate 0.1 0.1 0.1 0.1 0.1 0.1 0.1 (29) DPG 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (30) BHT 0.01 0.01 0.01 0.01 0.01 0.01 0.01 (31) Synthetic mica*4 5 5 5 5 5 5 5 (32) Methyl methacrylate cross-linked polymer 1 1 1 1 1 1 1 (33) Mica※5 10 - - - - - - (34) Iron Dan 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (35) Red No. 202 1.5 1.5 1.5 1.5 1.5 1.5 1.5 (36) Red No. 104 0.5 0.5 0.5 0.5 0.5 0.5 0.5 (37) Yellow No. 4 2 2 2 2 2 2 2 (38) Silicone 1% treated titanium oxide 3 3 3 3 3 3 3 (39) Perfluorohexylethyltriethoxysilane 2% black iron oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 <Evaluation Items and Judgment Results> (a) Softness ◎ ◎ 〇 ◎ × × × (b) Friction resistance ◎ 〇 ◎ × × × 〇 (c) Persistence of cosmetic film ◎ 〇 ◎ △ 〇 〇 〇 (d) No secondary adhesion effect ◎ 〇 ◎ × 〇 〇 ×

(Production method) A. The components (1) to (16) are heated to 80°C and dissolved uniformly. B. The components (17) to (27) are heated to 80° C., and uniformly mixed and dispersed to prepare a gel. C. Add components (28) to (39) to A and B, and mix and disperse them uniformly. After defoaming, it was filled into a container to obtain a lip gloss.

As shown in Tables 5 and 6, it is predicted that Examples 12 to 24 can obtain good results in all the evaluation items. On the other hand, in Comparative Example 10 using Comparative Silicone Resin 3 that does not contain a T unit, and Comparative Example 9 using Comparative Silicone Resin 2 having a large total ratio of T and Q, since the coating film is hard and brittle, Therefore, there is no flexibility, and since the cracked cosmetic film will fall off due to friction, the friction resistance is also poor, but it is predicted that a certain degree of persistence of the cosmetic film and no secondary adhesion effect can be obtained. Regarding Comparative Example 8 using Comparative Silicone Resin 1 with a small total ratio of T and Q, although a film having flexibility was obtained, it was predicted that it had a sticky feeling, and was poor in abrasion resistance and no secondary adhesion effect. Regarding Comparative Example 11 in which the component (A) was replaced with the comparative silicone resin 3 not containing the T unit and the comparative silicone resin 4 not containing the Q unit, the coating film was hard and brittle, so it had no flexibility, and it was easy to volatilize. The sticky feeling is strong during the period until the oil is volatilized, so it is predicted that the effect of no secondary adhesion cannot be obtained.

[Example II] Example 25: Lip gloss component mass % 1. 50% isododecane solution of silicone resin 1 of component (A) 10 2. Methyltrimethicone 5 3. Decamethylcyclopentasiloxane 15 4. Triglyceryl Tetraisostearate 30 5. Polybutene ※15 Remainder 6. Diphenyl Dimethicone 25 7. Dextrin Palmitate 5 8. Dimethyl Polysiloxane (25℃ Viscosity 20 mm ² /s) 0.5 9. Phenoxyethanol 0.5 10. Dibutylhydroxytoluene 0.01 11. Silicon dioxide 1 12. Calcium carbonate 0.1 13. Barium sulfate 0.1 14. Red No. 202 0.1 15. Titanium oxide coating Glass powder 0.5 16. Hyaluronic acid 0.05 17. Marine collagen 0.05 18. Rosehip oil 0.1 19. Fragrance 0.05 ※15: Nippon Oil Polybutene HV-100 (manufactured by JX Nippon Oil & Energy Co., Ltd.)

[Production method] A. The components (1) to (3) are heated to 80°C and dissolved uniformly. B. Add components (4) to (10) to A, heat to 100°C, and mix uniformly. C. Add components (11) to (19) to B, and disperse them uniformly. After heating to 70 degreeC, it filled in a container, and it cooled to room temperature, and obtained the lip gloss.

Since the lip gloss of the present invention has the flexibility to follow the movements of the lips, it is excellent in usability without tightness, dryness, or stickiness, and is excellent in abrasion resistance and adhesion to the skin or lips, so the cosmetic film has a long lasting effect. Durability over time, and thus no secondary adhesion to clothes or tableware, is also good and satisfactory in all respects.

Example 26: Eye shadow (solid) Ingredient mass % 1. 50% isododecane solution of silicone resin 2 of ingredient (A) 15 2. Remaining amount of isododecane 3. Triisocaprylic acid glyceride (weight average molecular weight 470) 5 4. Tridecyl trimellitate 10 5. Polybutene※15 5 6.Trifluoropropylcyclopentasiloxane5 7.Polyethylene wax※16 3 8.Microcrystalline Wax ※17 5 9. Dimethyl polysiloxane (viscosity 1000 mm ² /s at 25℃) 5 10. Dipropylene glycol 0.1 11. (Vinyl dimethyl polysiloxane/methyl polysiloxane sesqui Siloxane) Cross-linked polymer 3 12. Dimethylsilylated silica 2 13. Mica ※5 20 14. Silicone treatment 2% iron dan 0.1 15. Aluminum hydroxide treatment 0.5% titanium oxide 2 16. Oxidation Iron 0.05 17. Synthetic mica ※4 10 18. Natural Vitamin E 0.1 19. Fragrance 0.05 ※16: PERFORMALENE 500 (manufactured by New Phase Technologies) ※17: MULTIWAX W445 (manufactured by Sonneborn)

[Production method] A. The components (1) to (2) are heated to 80°C and dissolved uniformly. B. Add components (3) to (10) to A, heat to 100°C, and mix uniformly. C. Add components (11) to (19) to B, and disperse them uniformly. After heating to 100°C, it was filled in a container, and cooled to room temperature to obtain a solid eye shadow.

Since the eye shadow of the present invention has a softness that follows the action of the skin, it is excellent in usability without tightness, dryness, or stickiness, and is excellent in abrasion resistance and adhesion to the skin or lips, so the cosmetic film has a long lasting effect. Duration of time, and furthermore, the effect of no secondary adhesion to clothes and the like was also good, and was satisfactory in all respects.

Example 27: Sunscreen Cream (Shake Type) Ingredient Mass % 1. 50% Isododecane Solution of Silicone Resin 3 of Ingredient (A) 5 2. Methyl Trimethicone 5 3. Decamethylcyclopentasiloxane Remaining Amount 4. Decaisocaprylate 5 5. Ethylhexyl Methoxycinnamate (weight average molecular weight 290) 5 6. Polysilicon-15 1 7. Trimethylsiloxyphenyldimethyl Polysiloxane 5 8. Lauryl PEG-9 Polydimethylsiloxyethyl Polydimethylsiloxane Dimethylpolysiloxane (viscosity 100 mm ² /s at 25°C) 3 9. Dimethicone Siloxane 3 10. Phenoxyethanol 0.5 11. (Styrene/DVB) Copolymer 5 12. Trimethylsilsesquioxane ※18 20 13. Silicone-treated titanium oxide 5 14. Silicone Treating Zinc Oxide 10 15. Mica 0.5 16. Hyaluronic acid 0.05 17. Argan oil 0.05 18. Ethanol 1 19. Menthol 0.01

[Production method] A. The components (1) to (3) are heated to 80°C and dissolved uniformly. B. Add components (4) to (8) to A, and mix uniformly. C. Add components (9) to (19) to B, and disperse them uniformly. Fill into a container for sunscreen.

Since the sunscreen of the present invention has the flexibility to follow the action of the skin, it is excellent in usability without tightness, dryness, or stickiness, and is excellent in abrasion resistance and adhesion to the skin or lips, so the cosmetic film has The long-term durability and the effect of no secondary adhesion to clothes and the like are also good, and are satisfactory in all respects.

Example 28: Lipstick film component mass % 1. 50% isododecane solution of silicone resin 1 of component (A) 10 2. Decamethylcyclopentasiloxane 10 3. Dimethylpolysiloxane (Viscosity 20 mm ² /s at 25°C) 10 4. (Vinylpyrrolidone/hexadecene) copolymer 1 5. Trifluoropropyldimethylpolysiloxane ※14 Remaining amount 6. Ethanol 0.1 7. Natural vitamin E 0.05 8. Vaseline (melting point 38～60℃) 1 9. Dimethyl siloxane 5 10. (Dimethyl polysiloxane/phenylvinyl dimethyl polysiloxane) Cross Copolymer 0.5 11. Diphenylsiloxyphenyl trimethicone 2 12. Titanium oxide-coated glass powder 0.5 13. Silica *19 1 *19: Sunsphere NP-30 (manufactured by AGC Si-Tech)

[Production method] A. Mix components (1) to (8) uniformly. B. Add components (9) to (13) to A, and mix and disperse them uniformly. C. Fill B into a container to obtain a lipstick protective film.

Since the lipstick film of the present invention has the flexibility to follow the movements of the lips, it is excellent in usability without tightness, dryness, or stickiness, and is excellent in abrasion resistance and adhesion to the lips, so the cosmetic film has a long lasting effect. The effect of lasting time and preventing the secondary adhesion of the lipstick to clothes is also good, and it is satisfactory in all respects.

Example 29: Lip Glaze (2 dosage forms) 1st agent (lip glazing) Ingredient mass % 1. 50% isododecane solution of silicone resin 2 of component (A) 30 2. Remaining amount of isododecane 3. Diglyceryl tetraisostearate 5 4. Dimethyl polysiloxane (viscosity 10000 mm ² /s at 25°C) 10 5. Dimethyl silylated silica 0.5 6. Distearyl dimethylammonium lithium monoxide Destone 5 7. Dipropylene glycol 0.5 8. Dibutylhydroxytoluene 0.01 9. Synthetic mica 0.5 10. Lecithin-treated 1% titanium oxide 1 11. Red No. 202 0.3 12. Yellow No. 4 0.5 13. Black iron oxide 0.02 14 .Squalane 0.1 15. Fragrance 0.02 The second agent (lip gloss used on lip gloss) Ingredient mass% 16. Diglyceryl triisostearate 10 17. Glyceryl triisostearate Oil Esters Remaining Amount 18. Deca-isostearate 30 19. Dextrin Palmitate 5 20. Dimethylsilyl Dioxide 3 21. Vitamin A Palmitate 0.01 22.1,3-Butanediol 0.2

[Production method] A. The components (1) and (2) were heated to 80°C and dissolved uniformly. B. Add components (3) to (15) to A, and mix and disperse them uniformly. C. Fill B into the lip glaze container with the coated body to obtain the lip glaze. D. The components (16) to (19) are heated to 100° C., and mixed and dissolved. E. Add components (20) to (22) to D, and mix and disperse them uniformly. F. Fill E into the lip gloss container with the coated body to obtain lip gloss. When using, apply the 1st dose of lip gloss on the lips, and then apply the 2nd dose of lip gloss on top.

The 2-part lip glaze of the present invention has the flexibility to follow the movements of the lips, so it has no tightness, dryness, or stickiness. The effect of preventing the lipstick from adhering to clothes for a long time is also good, and it is satisfactory in all aspects.

Claims (10)

An oil-based cosmetic comprising the following components (A) to (D): (A) Structural units include the following general formulae (A-1), (A-2), (A-3), (A-4) Silicone resin with a weight average molecular weight of 1500-40000, (A-1)(R ¹ ₃ SiO _1/2 )a, (A-2)(R ² ₂ SiO _2/2 )b, (A-3) (R ³ SiO _3/2 )c, and (A-4)(SiO _4/2 )d (wherein, R ¹ , R ² and R ³ are independently selected from the group consisting of an alkyl group having 1 to 8 carbon atoms, a carbon In the aryl group having 6 to 12 carbon atoms and the group in the fluorine-substituted alkyl group having 1 to 8 carbon atoms, a has a value of 0.2 to 0.5, b has a value of 0.0 to 0.1, c has a value of 0.2 to 0.6, and d has a value of 0.2 The value of ~0.5, the value of a+b+c+d is 1.0, the value of a/(c+d) is 0.3-0.9, and the value of c/d is 0.4-3.0); (B) Volatile oil agent; (C) The weight average molecular weight is 700 ~5000 hydrocarbon oil and/or ester oil; (D) oily gelling agent and/or wax. The oil-based cosmetic according to claim 1, which contains 1.0 to 45.0 mass % of the above-mentioned (A) component. The oil-based cosmetic of claim 1 or 2 further contains component (E) which is a liquid non-volatile silicone oil at 25°C. The oil-based cosmetic according to claim 3, wherein the component (E) is selected from the group consisting of phenyl-modified silicone, fluorine-modified silicone, and dimethyl polysiloxane with a viscosity of 1000 mm ² /s or more at 25°C One or more of the alkanes. The oily cosmetic according to any one of claims 1 to 4, which is a lip cosmetic. The oil-based cosmetic according to any one of claims 1 to 5, wherein the weight average molecular weight of the component (A) is 20,001 to 40,000. The oil-based cosmetic according to any one of claims 1 to 6, wherein the component (C) is a semi-solid oil with a hardness of 0.1 to 10 N at 25°C. The oily cosmetic according to any one of claims 1 to 7, wherein the component (C) contains one or more of a stearyl group, a behenyl group, or a phytosterol group as an ester oil. The oily cosmetic according to any one of claims 1 to 8, wherein the above-mentioned component (C) contains dimerized linoleic acid (phytosteryl/isostearyl/cetyl/stearyl) as an ester oil selected from the group consisting of base/behenyl) ester, hexa(hydroxystearic acid/stearic acid/rosin acid) dipentaerythritol ester, di(octyldodecyl/phytosteryl/behenyl) laurel glutamic acid ester , Hydrogenated castor oil stearate, di(cholesteryl/behenyl/octyldodecyl) lauryl glutamic acid, and di(cholesteryl/octyldodecyl) lauryl glutamic acid Esters, and one or more of vaseline as hydrocarbon oil. The oily cosmetic according to any one of claims 1 to 6, which contains a polyglycerol fatty acid ester as the component (C).