TW202123496A - Light emitting device - Google Patents
Light emitting device Download PDFInfo
- Publication number
- TW202123496A TW202123496A TW109135450A TW109135450A TW202123496A TW 202123496 A TW202123496 A TW 202123496A TW 109135450 A TW109135450 A TW 109135450A TW 109135450 A TW109135450 A TW 109135450A TW 202123496 A TW202123496 A TW 202123496A
- Authority
- TW
- Taiwan
- Prior art keywords
- light
- wavelength conversion
- sheet
- conversion member
- emitting element
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 claims abstract description 88
- 239000002245 particle Substances 0.000 claims abstract description 21
- 108010043121 Green Fluorescent Proteins Proteins 0.000 claims abstract description 8
- 239000011159 matrix material Substances 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000002096 quantum dot Substances 0.000 description 41
- 230000003287 optical effect Effects 0.000 description 20
- -1 stearyl (octadecyl) amine Chemical class 0.000 description 11
- 125000005843 halogen group Chemical group 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 238000000149 argon plasma sintering Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000013110 organic ligand Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- MNZAKDODWSQONA-UHFFFAOYSA-N 1-dibutylphosphorylbutane Chemical compound CCCCP(=O)(CCCC)CCCC MNZAKDODWSQONA-UHFFFAOYSA-N 0.000 description 1
- IHWDIGHWDQPQMQ-UHFFFAOYSA-N 1-octadecylsulfanyloctadecane Chemical compound CCCCCCCCCCCCCCCCCCSCCCCCCCCCCCCCCCCCC IHWDIGHWDQPQMQ-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- ZJCZFAAXZODMQT-UHFFFAOYSA-N 2-methylpentadecane-2-thiol Chemical compound CCCCCCCCCCCCCC(C)(C)S ZJCZFAAXZODMQT-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229910007709 ZnTe Inorganic materials 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- OJGXEKSQTVUPSN-UHFFFAOYSA-N [PH3]=O.C(CCCCCCC)P(CCCCCCCC)(CCCCCCCC)=O Chemical compound [PH3]=O.C(CCCCCCC)P(CCCCCCCC)(CCCCCCCC)=O OJGXEKSQTVUPSN-UHFFFAOYSA-N 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical class [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- HXWNQXKTQWDQMT-UHFFFAOYSA-N phosphane trioctylphosphane Chemical compound C(CCCCCCC)P(CCCCCCCC)CCCCCCCC.P HXWNQXKTQWDQMT-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920006290 polyethylene naphthalate film Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- GEKDEMKPCKTKEC-UHFFFAOYSA-N tetradecane-1-thiol Chemical compound CCCCCCCCCCCCCCS GEKDEMKPCKTKEC-UHFFFAOYSA-N 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Led Device Packages (AREA)
- Planar Illumination Modules (AREA)
Abstract
Description
本發明係關於一種發光裝置,其使來自發光元件之光經由波長轉換構件而發出白色光。The present invention relates to a light-emitting device that causes light from a light-emitting element to emit white light through a wavelength conversion member.
量子點係由數百~數千個左右之原子構成的粒徑為數nm~數十nm左右之奈米粒子。量子點亦被稱為螢光奈米粒子、半導體奈米粒子、或奈米晶體。Quantum dots are nano-particles composed of hundreds to thousands of atoms with a particle size of several nanometers to several tens of nanometers. Quantum dots are also called fluorescent nanoparticles, semiconductor nanoparticles, or nanocrystals.
如下述專利文獻1中所記載,量子點分散於樹脂中,構成波長轉換構件。波長轉換構件配置於發出藍色光之LED(Light Emitting Diode,發光二極體)晶片上。量子點中包含螢光波長為紅色或綠色之量子點,從發光元件所發出之部分藍色光被各量子點轉換為綠色及綠色,而能夠從波長轉換構件之表面射出白色光。
先前技術文獻
非專利文獻As described in
專利文獻1:國際公開第2015/156226號Patent Document 1: International Publication No. 2015/156226
[發明所欲解決之問題][The problem to be solved by the invention]
波長轉換構件例如形成為片狀,波長轉換構件中所包含之量子點數變多會導致波長轉換構件之製造成本變高之問題。The wavelength conversion member is formed in a sheet shape, for example, and an increase in the number of quantum dots included in the wavelength conversion member causes a problem that the manufacturing cost of the wavelength conversion member becomes higher.
又,從發光元件所發出之光被波長轉換構件波長轉換時,存在因於擴散板等處之擴散、漫反射,而產生色不均或亮度不均(暈圈現象)之問題。In addition, when the light emitted from the light-emitting element is wavelength-converted by the wavelength conversion member, there is a problem of color unevenness or uneven brightness (halo phenomenon) due to diffusion and diffuse reflection at a diffuser or the like.
本發明係鑒於上述各方面而完成者,目的在於提供一種發光裝置,其可控制波長轉換構件之製造成本,並且能夠發出白色光。 [解決問題之技術手段]The present invention was completed in view of the above-mentioned aspects, and its object is to provide a light-emitting device which can control the manufacturing cost of the wavelength conversion member and can emit white light. [Technical means to solve the problem]
本發明之發光裝置之特徵在於:其係具備發光元件、及配置於上述發光元件之光出射側之波長轉換構件者,上述發光元件經調整而能顯色藍色光中混色有藍色以外之可見光而成的光,上述波長轉換構件包含紅色螢光粒子及綠色螢光粒子,來自上述發光元件之光經由上述波長轉換構件而發出白色光。The light-emitting device of the present invention is characterized in that it is provided with a light-emitting element and a wavelength conversion member arranged on the light-emitting side of the light-emitting element, and the light-emitting element is adjusted to produce blue light and mixed with visible light other than blue. The wavelength conversion member includes red fluorescent particles and green fluorescent particles, and the light from the light-emitting element emits white light through the wavelength conversion member.
本發明中,較佳為上述發光元件經調整而能顯色上述藍色光中混色有發光強度弱於上述藍色光之紅色光及綠色光而成的光。 本發明中,上述波長轉換構件較佳為片狀。In the present invention, it is preferable that the light-emitting element is adjusted so that the blue light is mixed with red light and green light whose luminous intensity is weaker than that of the blue light. In the present invention, the above-mentioned wavelength conversion member is preferably in a sheet shape.
本發明中,較佳為複數個上述發光元件以能選擇欲使其發光的上述發光元件之方式呈矩陣狀地配置,來自1個以上之上述發光元件之顯色光經由上述波長轉換構件,從上述波長轉換構件之表面發出白色光。In the present invention, it is preferable that a plurality of the light-emitting elements are arranged in a matrix so that the light-emitting elements to be emitted can be selected, and the color light from one or more of the light-emitting elements passes through the wavelength conversion member. The surface of the wavelength conversion member emits white light.
本發明中,較佳為上述波長轉換構件塗佈或貼合於部分反射片材之表面。In the present invention, it is preferable that the above-mentioned wavelength conversion member is coated or bonded to the surface of the partially reflective sheet.
本發明之發光裝置之特徵在於:其係具備發光元件、及配置於上述發光元件之光出射側之波長轉換構件者,上述波長轉換構件包含紅色螢光粒子及綠色螢光粒子,上述波長轉換構件塗佈或貼合於部分反射片材之表面,來自上述發光元件之光經由上述波長轉換構件而發出白色光。 [發明之效果]The light-emitting device of the present invention is characterized in that it includes a light-emitting element and a wavelength conversion member disposed on the light emitting side of the light-emitting element, the wavelength conversion member includes red fluorescent particles and green fluorescent particles, and the wavelength conversion member It is coated or attached to the surface of the partially reflective sheet, and the light from the light-emitting element emits white light through the wavelength conversion member. [Effects of Invention]
根據本發明之第1發光裝置,發光元件經調整而能發出藍色光中混色有藍色以外之可見光而成的光,藉此,可減少波長轉換構件中所包含之紅色螢光粒子及綠色螢光粒子之含量。According to the first light-emitting device of the present invention, the light-emitting element is adjusted to emit light formed by mixing blue light with visible light other than blue, thereby reducing the red fluorescent particles and green fluorescent particles contained in the wavelength conversion member. The content of light particles.
根據本發明之第2發光裝置,藉由將波長轉換構件配置於部分反射片材,可抑制色不均或亮度不均(暈圈現象)。According to the second light-emitting device of the present invention, by disposing the wavelength conversion member on the partially reflective sheet, it is possible to suppress color unevenness or brightness unevenness (halo phenomenon).
本發明可控制波長轉換構件之製造成本,並且可發出白色光。The invention can control the manufacturing cost of the wavelength conversion component and can emit white light.
<第1實施方式> 雖然已知有一種發光裝置,其於藍色LED之表面配置包含量子點之波長轉換構件,將LED所發出之藍色光波長轉換為白色光,但是若使波長轉換構件為片狀等進行大型化,則用於波長轉換構件之量子點之量增加,從而產生製造成本高漲之問題。<First Embodiment> Although there is a known light-emitting device in which a wavelength conversion member containing quantum dots is arranged on the surface of a blue LED to convert the wavelength of blue light emitted by the LED into white light, if the wavelength conversion member is made into a sheet shape, it can be enlarged. , The amount of quantum dots used for wavelength conversion components increases, which causes the problem of high manufacturing costs.
對此,本發明人等使從LED等發光元件所發出之光混色有藍色光及藍色以外之可見光,從而實現了減少用於波長轉換構件之螢光粒子量。In this regard, the inventors of the present invention mixed blue light and visible light other than blue light emitted from light-emitting elements such as LEDs, thereby realizing a reduction in the amount of fluorescent particles used in the wavelength conversion member.
即,第1實施方式之發光裝置具有以下幾個特點。 (1)具備發光元件、及配置於發光元件之光出射側之波長轉換構件。 (2)發光元件經調整而能顯色藍色光中混色有藍色以外之可見光而成的光。 (3)波長轉換構件包含紅色螢光粒子及綠色螢光粒子。 (4)來自發光元件之光經由波長轉換構件而發出白色光。That is, the light-emitting device of the first embodiment has the following characteristics. (1) A light emitting element and a wavelength conversion member arranged on the light emitting side of the light emitting element are provided. (2) The light-emitting element is adjusted so that it can produce blue light mixed with visible light other than blue. (3) The wavelength conversion member includes red fluorescent particles and green fluorescent particles. (4) The light from the light emitting element emits white light through the wavelength conversion member.
圖1係本實施方式之發光裝置之剖面模式圖。圖2係本實施方式之發光裝置之俯視模式圖。圖3係本實施方式之量子點之模式圖。FIG. 1 is a schematic cross-sectional view of the light-emitting device of this embodiment. FIG. 2 is a schematic plan view of the light-emitting device of this embodiment. FIG. 3 is a schematic diagram of the quantum dot of this embodiment.
圖1所示之發光裝置1具備發光元件2及波長轉換片材(波長轉換構件)3(上述(1))。發光元件2例如為LED晶片,複數個發光元件2配置於基板4上。如圖2所示,該等發光元件2呈矩陣狀地排列於互相正交之X、Y方向上。The light-
如圖1所示,於各發光元件2之光出射側(圖示上方向)隔開特定間隔積層有擴散板5、波長轉換片材3、及各種光學片材6、7。光學片材6、7為亮度上升膜或透鏡等,但並無特別限定。As shown in FIG. 1, a diffuser 5, a
本實施方式中,發光元件2經調整而能顯色藍色光中混色有藍色以外之可見光而成的光(上述(2))。此處,從發光元件2所發出之光L1例如為藍色光中混色有黃色光而成的光、或藍色光中混色有紅色光或綠色光而成的光。作為發光元件2,例如應用藍色LED中組合有黃色螢光體而成者、藍色LED中組合有紅色螢光體及綠色螢光體而成者等。又,較佳為從發光元件2所發出之光係藍色光中混色有強度弱於藍色光之紅色光及綠色光。In the present embodiment, the light-emitting
本實施方式中,藉由上述混色,可從發光元件2發出近白色光(大致白色光)。此處,所謂「近白色光」,係指接近白色光的光,係略帶紅色之白色光、略帶黃色之白色光、略帶藍色之白色光、或略帶綠色之白色光等。In this embodiment, by the above-mentioned color mixing, near white light (substantially white light) can be emitted from the light-emitting
本實施方式中,波長轉換片材3包含紅色螢光粒子及綠色螢光粒子(上述(3))。此處,螢光粒子較佳為量子點。In this embodiment, the
對量子點之構成及材質並無限定,例如,本實施方式中之量子點為具有數nm~數十nm左右之粒徑之奈米粒子。The composition and material of the quantum dots are not limited. For example, the quantum dots in this embodiment are nano particles with a particle size of several nm to several tens of nm.
例如,量子點為CdS、CdSe、ZnS、ZnSe、ZnSeS、ZnTe、ZnTeS、Ag2 Te、AgInTe等。此處,量子點較佳為不含Cd,且不含P。Cd因其毒性而在各國限制其使用。又,有機磷化合物因價格昂貴且容易於空氣中氧化而合成不穩定,從而容易導致成本上升或螢光特性不穩定、及製造步驟繁雜。For example, quantum dots are CdS, CdSe, ZnS, ZnSe, ZnSeS, ZnTe, ZnTeS, Ag 2 Te, AgInTe, etc. Here, the quantum dot preferably does not contain Cd and does not contain P. Cd restricts its use in various countries due to its toxicity. In addition, organophosphorus compounds are expensive and easily oxidized in the air, making synthesis unstable, which easily leads to increased costs, unstable fluorescent characteristics, and complicated manufacturing steps.
本實施方式中,由於可減少量子點之含量,故即便使用包含Cd之量子點,亦可減少波長轉換片材3中所包含之Cd量。In this embodiment, since the content of quantum dots can be reduced, even if quantum dots containing Cd are used, the amount of Cd contained in the
如圖3A所示,較佳為於量子點10之表面配位有許多有機配位基11。藉此,可抑制量子點彼此之凝聚,顯現出目標光學特性。可用於反應之配位基並無特別限定,例如,可列舉以下配位基作為代表性的配位基。As shown in FIG. 3A, it is preferable that many
(1)脂肪族一級胺系 油胺:C18 H35 NH2 、硬脂基(十八烷基)胺:C18 H37 NH2 、十二烷基(月桂基)胺:C12 H25 NH2 、癸胺:C10 H21 NH2 、辛胺:C8 H17 NH2 (2)脂肪酸 油酸:C17 H33 COOH、硬脂酸:C17 H35 COOH、棕櫚酸:C15 H31 COOH、肉豆蔻酸:C13 H27 COOH、月桂基酸:C11 H23 COOH、癸酸:C9 H19 COOH、辛酸:C7 H15 COOH (3)硫醇系 十八烷硫醇:C18 H37 SH、十六烷硫醇:C16 H33 SH、十四烷硫醇:C14 H29 SH、十二烷硫醇:C12 H25 SH、癸烷硫醇:C10 H21 SH、辛烷硫醇:C8 H17 SH (4)膦系 三辛基膦:(C8 H17 )3 P、三苯基膦:(C6 H5 )3 P、三丁基膦:(C4 H9 )3 P (5)氧化膦系 三辛基氧化膦:(C8 H17 )3 P=O、三苯基氧化膦:(C6 H5 )3 P=O、三丁基氧化膦:(C4 H9 )3 P=O(1) Aliphatic primary amine oleylamine: C 18 H 35 NH 2 , stearyl (octadecyl) amine: C 18 H 37 NH 2 , dodecyl (lauryl) amine: C 12 H 25 NH 2 , decylamine: C 10 H 21 NH 2 , octylamine: C 8 H 17 NH 2 (2) Fatty acid oleic acid: C 17 H 33 COOH, stearic acid: C 17 H 35 COOH, palmitic acid: C 15 H 31 COOH, myristic acid: C 13 H 27 COOH, lauryl acid: C 11 H 23 COOH, capric acid: C 9 H 19 COOH, caprylic acid: C 7 H 15 COOH (3) mercaptan octadecyl sulfide Alcohol: C 18 H 37 SH, hexadecyl mercaptan: C 16 H 33 SH, tetradecyl mercaptan: C 14 H 29 SH, dodecyl mercaptan: C 12 H 25 SH, decane mercaptan: C 10 H 21 SH, octane mercaptan: C 8 H 17 SH (4) phosphine trioctyl phosphine: (C 8 H 17 ) 3 P, triphenylphosphine: (C 6 H 5 ) 3 P, tributyl Phosphine: (C 4 H 9 ) 3 P (5) phosphine oxide trioctyl phosphine oxide: (C 8 H 17 ) 3 P=O, triphenyl phosphine oxide: (C 6 H 5 ) 3 P=O , Tributyl phosphine oxide: (C 4 H 9 ) 3 P=O
本實施方式中,如圖3B所示,量子點10可為具有內核10a、與被覆於內核10a之表面之外殼10b的核殼結構。如圖3B所示,較佳為於量子點10之表面配位有許多有機配位基11。In this embodiment, as shown in FIG. 3B, the
再者,外殼10b可為固溶於內核10a之表面之狀態。圖3B中以虛線表示內核10a與外殼10b之邊界,這意味著藉由分析不論確認到還是未確認到內核10a與外殼10b之邊界皆可。Furthermore, the
本實施方式中,從發光元件2所發出之光L1為藍色光中混色有藍色以外之可見光而成的光,可減少波長轉換片材3中所包含之紅色發光量子點及綠色發光量子點之含量,以使發光裝置1發出白色光L2。換言之,即便減少波長轉換片材3中所包含之紅色發光量子點及綠色發光量子點之含量,來自發光元件之光L1亦會經由波長轉換片材3作為白色光L2發出(上述(4))。尤其是,若從發光元件2所發出之光L1係藍色光中混色有紅色光及綠色光而成,則可更有效地減少波長轉換片材3中所包含之紅色發光量子點及綠色發光量子點之含量。其結果,可降低波長轉換片材3之製造成本。又,即便量子點包含Cd等受限制對象之重金屬,亦可有效地控制受限制對象之重金屬之量。In this embodiment, the light L1 emitted from the light-emitting
再者,波長轉換片材3中除量子點以外,還可包含螢光顏料、螢光染料等。例如,可為混合有YAG(Yttrium Aluminum Garnet,釔-鋁-石榴石)或Sialon等螢光體者。Furthermore, in addition to quantum dots, the
本實施方式之波長轉換片材3係量子點藉由樹脂而分散之片材狀物,並無限定,例如為於波長轉換片材3之雙側或單側,換言之,於光入射側或光出射側不具備障壁層之構成。再者,波長轉換片材3亦可為形成於基材膜(未圖示)之至少一面之構成。雖然對基材膜並無特別限定,但是就透光性、操作性(處理性)、及與波長轉換片材3之密接性之觀點而言,較佳為PET(聚對苯二甲酸乙二酯)膜。或,亦可使用PEN(聚萘二甲酸乙二酯)膜代替PET膜或PE(polyethylene,聚乙烯)膜。The
波長轉換片材3形成為薄板狀,所謂「片材」,通常係指其厚度相對於長度及寬度而言較小之構成。波長轉換片材3雖然不論是否具有可撓性均可,但較佳為具有可撓性。波長轉換片材3有時被簡稱為片材、或被稱為膜或膜片材等。其中本說明書中,將「膜」定義為具有可撓性之片材物。又,波長轉換片材3可形成為固定厚度,亦可為厚度根據部位不同而變形、或朝向長度方向或寬度方向逐漸變化、或者階段性地變化之構成。The
波長轉換片材3之長度尺寸L、寬度尺寸W、及厚度尺寸T並無限定,根據製品不同而變更各種尺寸。例如,有用於諸如電視機這種大型製品之背光之情形,亦有用於諸如智慧型手機這種小型行動裝置之背光之情形,因此需要匹配製品來決定大小。The length dimension L, width dimension W, and thickness dimension T of the
本實施方式中,作為用於波長轉換片材3之樹脂,並無特別限定,可包含:聚丙烯、聚乙烯、聚苯乙烯、AS(Acrylonitrile-Styrene,丙烯腈-苯乙烯)樹脂、ABS(Acrylonitrile-Butadiene-Styrene,丙烯腈-丁二烯-苯乙烯)樹脂、丙烯酸樹脂、甲基丙烯酸樹脂、聚氯乙烯、聚縮醛、聚醯胺、聚碳酸酯、改性聚苯醚、聚對苯二甲酸丁二酯、聚對苯二甲酸乙二酯、聚碸、聚醚碸、聚苯硫醚、聚醯胺醯亞胺、聚甲基戊烯、液晶聚合物、環氧樹脂、酚系樹脂、脲樹脂、三聚氰胺樹脂、環氧樹脂、鄰苯二甲酸二烯丙酯樹脂、不飽和聚酯樹脂、聚醯亞胺、聚胺基甲酸酯、矽酮樹脂、苯乙烯系熱塑性彈性體或該等幾個物質之混合物等。In this embodiment, the resin used for the
又,本實施方式中,亦可使波長轉換片材3中含有光散射劑或增黏劑。光散射劑對材質並無限定,可提示SiO2
、BN、AlN等微粒子等。作為一例,波長轉換片材3中包含1~10 wt%之光散射劑。又,對增黏劑之材質並無特別限定,可例示:羧乙烯聚合物、羧甲基纖維素、丙烯酸酸甲酯共聚物、膨潤土(矽酸鋁)或鋰膨潤石(矽酸鎂)系添加物等。藉由包含增黏劑,可將構成波長轉換片材3之樹脂組合物調整為適度之黏度,可使波長轉換片材3容易地形成為特定厚度及特定形狀。In addition, in this embodiment, the
又,本實施方式中,為了提高波長轉換片材3中所包含之量子點之分散性,較佳為包含分散劑。對分散劑之材質並無特別限定,可使用:環氧樹脂系、聚胺基甲酸酯系、多羧酸鹽系、萘磺酸鹽之福馬林縮合系聚合物系、聚乙烯二醇系、多羧酸之部分烷基酯系化合物系、聚醚系、聚伸烷基聚胺基、烷磺酸鹽系、四級銨鹽系、高級醇環氧烷系、多元醇酯系、烷基聚胺基系、或多磷酸鹽系之分散劑等,具體而言可例示BYK-Chemie Japan公司製造之DISPERBYK(註冊商標)。Moreover, in this embodiment, in order to improve the dispersibility of the quantum dots contained in the
又,圖1、圖2所示之波長轉換片材3形成為一片,但例如亦可以成為特定大小之方式將複數片波長轉換片材3接合形成。In addition, the
圖2所示之複數個發光元件2被以能選擇是否發光之方式支持,即,不僅能點亮所有發光元件2使用,亦能例如僅點亮1個發光元件2使用。此種驅動方法亦被稱為調光、局部調光、區域分割方式等。The plurality of light-emitting
此處,探討關於例如點亮1個發光元件2之情形,於與先前同樣地使用藍色LED之情形時,已知藍色光被波長轉換片材3波長轉換時,會因擴散板5等處之擴散、漫反射,而產生色不均或亮度不均(暈圈現象)。Here, we will discuss, for example, the case where one light-emitting
相對於此,本實施方式中,即便於不點亮所有發光元件2而例如點亮1個發光元件2之情形時,亦可藉由將從發光元件2所發出之光L1調整為藍色光中混色有藍色以外之可見光而成的光(近白色),不僅可減少波長轉換片材3中所包含之紅色發光量子點及綠色發光量子點之含量,還可抑制色不均或亮度不均(暈圈現象)。又,可抑制色不均或亮度不均(暈圈現象)而不至於太縮窄色域。In contrast to this, in this embodiment, even when not all the light-emitting
<第2實施方式>
第2實施方式中,為了抑制色不均或亮度不均(暈圈現象),而將波長轉換片材3塗佈或貼合於部分反射片材之表面。<Second Embodiment>
In the second embodiment, in order to suppress color unevenness or brightness unevenness (halo phenomenon), the
圖4、圖5係與圖1不同之本實施方式之發光裝置之剖面模式圖。圖4、圖5中,與圖1相同之符號表示與圖1相同之構件。如圖4所示,波長轉換片材3設置於部分反射片材11之表面。部分反射片材(部分反射層)11可使用3M公司製造之「BLT」。4 and 5 are schematic cross-sectional views of the light-emitting device of this embodiment that are different from those in FIG. 1. In FIGS. 4 and 5, the same symbols as in FIG. 1 indicate the same members as in FIG. 1. As shown in FIG. 4, the
波長轉換片材3可塗佈於部分反射片材11之表面,或亦可貼合於部分反射片材11之表面。The
圖5所示之實施方式之發光裝置1與圖4不同,為邊緣型。即,LED(光源)位於導光板12旁,從光源穿透導光板12之光被導光板12朝上方傳送。圖5所示之實施方式中,於導光板12之上設置有部分反射片材11,波長轉換片材3設置於部分反射片材11之表面。The light-emitting
部分反射片材(部分反射層)11能使藍色光透過,並反射紅色光及綠色光。或,部分反射片材(部分反射層)61可反射所有紅色光及綠色光,而部分性地反射藍色光。The partially reflective sheet (partially reflective layer) 11 can transmit blue light and reflect red and green light. Or, the partially reflective sheet (partially reflective layer) 61 can reflect all the red light and the green light, and partially reflect the blue light.
例如,發行元件(LED)13發出藍色光。因此,部分藍色光透過部分反射片材11,於含量子點之構件1被波長轉換為紅色光及/或綠色光。經波長轉換之紅色光及綠色光藉由部分反射片材81並不朝向下方而朝向上方出射。For example, the issuing element (LED) 13 emits blue light. Therefore, part of the blue light passes through the partly
此處,於使用藍色LED之情形時,於無部分反射片材11之構成中,藍色光被含量子點之構件1波長轉換時,存在因擴散、漫反射等而產生色不均或亮度不均(暈圈現象)之情況。對此,如本實施方式,藉由設置部分反射片材11,可抑制暈圈現象。尤其是如圖4所示,於直下型光學元件中LED之數量增加之情形時較為有效。又,藉由利用部分反射片材11降低藍色光之透過,可增加再利用之藍色光之量,從而可實現亮度(發光強度)提高。因此,即便量子點中不含以Cd或Pb為代表之受限制對象之重金屬,亦可獲得高亮度。Here, when a blue LED is used, in the structure of the non-partially
又,圖4、圖5所示之第2實施方式中,雖然從發光元件13所發射之光L3為藍色光,但亦可與圖1所示之第1實施方式同樣地為藍色光中混色有藍色以外之可見光而成的光。例如,光L3可為藍色光中混色有發光強度弱於藍色光之紅色光及綠色光而成的光(近白色光)。
[實施例]In addition, in the second embodiment shown in FIGS. 4 and 5, although the light L3 emitted from the light-emitting
以下,藉由本發明之實施例及比較例對本發明之效果進行說明。再者,本發明並不受以下實施例任何限定。Hereinafter, the effects of the present invention will be described by the examples and comparative examples of the present invention. In addition, the present invention is not limited in any way by the following examples.
<有無部分反射片材之亮度實驗> 實驗中使用以下試樣。 (試樣1) 直下BL(藍色光)+QD片材+稜鏡 (試樣2) 直下BL(藍色光)+塗佈有QD之BLT片材+稜鏡 (試樣3) 直下BL(藍色光)+BLT片材+QD片材+稜鏡 (試樣4) 直下BL(藍色光)+QD片材+稜鏡+DBEF (試樣5) 直下BL(藍色光)+塗佈有QD之BLT片材+稜鏡+DBEF (試樣6) 直下BL(藍色光)+BLT片材+QD片材+稜鏡+DBEF<Brightness experiment with or without partial reflection sheet> The following samples were used in the experiment. (Sample 1) Straight down BL (blue light) + QD sheet + 稜鏡 (Sample 2) Directly down BL (blue light) + BLT sheet coated with QD + 稜鏡 (Sample 3) Straight down BL (blue light) + BLT sheet + QD sheet + 稜鏡 (Sample 4) Straight down BL (blue light) + QD sheet + 稜鏡 + DBEF (Sample 5) Directly down BL (blue light) + BLT sheet coated with QD + 稜鏡 + DBEF (Sample 6) Straight down BL (blue light) + BLT sheet + QD sheet + 稜鏡 + DBEF
再者,BLT片材為3M公司製造之部分反射片材。QD片材中包含發出紅色發光及綠色發光之量子點。塗佈有QD之BLT片材係於BLT片材之表面塗佈包含發出紅色發光及綠色發光之量子點之QD液而形成QD層者。DBEF為3M公司製造之反射型偏光膜。Furthermore, the BLT sheet is a partially reflective sheet manufactured by 3M Company. The QD sheet contains quantum dots that emit red light and green light. The QD coated BLT sheet is coated on the surface of the BLT sheet with QD liquid containing quantum dots emitting red light and green light to form a QD layer. DBEF is a reflective polarizing film manufactured by 3M Company.
實驗中,進行分組,分為試樣1~試樣3、試樣4~試樣6這兩組來測定波長與亮度(發光強度)之關係。發光強度之測定使用分光螢光光度計(日本分光公司製造之FP-8500)。In the experiment, the groups were divided into two groups,
圖6係示出試樣1~試樣3中波長400 nm~700 nm與發光強度之關係的曲線圖。圖7係示出試樣4~試樣6中波長400 nm~700 nm與發光強度之關係的曲線圖。圖8係示出試樣1~試樣3中波長500 nm~700 nm與發光強度之關係的曲線圖。圖9係示出試樣4~試樣6中波長500 nm~700 nm與發光強度之關係的曲線圖。再者,圖8、圖9中,相較於圖6、圖7,擴大了縱軸之發光強度之範圍。Fig. 6 is a graph showing the relationship between the wavelength of 400 nm to 700 nm and the luminous intensity in
如圖6、圖7所示,無部分反射片材之試樣1及試樣4中,藍色發光強度變高。相對於此,具有部分反射片材之試樣2、3、5、6中,控制了藍色發光強度。As shown in Fig. 6 and Fig. 7, in
又,如圖8、圖9所示,無部分反射片材之試樣1及試樣4中,紅色發光強度及綠色發光強度降低,相較於此,具有部分反射片材之試樣2、3、5、6中,提高了紅色發光強度及綠色發光強度。In addition, as shown in Figs. 8 and 9, in the
(試樣7) 邊緣BL(藍色光)+QD片材+稜鏡 (試樣8) 邊緣BL(藍色光)+塗佈有QD之BLT片材+稜鏡 (試樣9) 邊緣BL(藍色光)+BLT片材+QD片材+稜鏡 (試樣10) 邊緣BL(藍色光)+QD片材+稜鏡+DBEF (試樣11) 直下BL(藍色光)+塗佈有QD之BLT片材+稜鏡+DBEF (試樣12)(Sample 7) Edge BL (blue light) + QD sheet + 稜鏡 (Sample 8) Edge BL (blue light) + BLT sheet coated with QD + 稜鏡 (Sample 9) Edge BL (blue light) + BLT sheet + QD sheet + 稜鏡 (Sample 10) Edge BL (blue light) + QD sheet + 稜鏡 + DBEF (Sample 11) Directly down BL (blue light) + BLT sheet coated with QD + 稜鏡 + DBEF (Sample 12)
邊緣BL(藍色光)+BLT片材+QD片材+稜鏡+DBEF
試樣7~試樣12係使用邊緣BL代替試樣1~試樣6之直下BL之實驗例。即,試樣1~試樣6為圖4所示之直下型構成,試樣7~試樣12為圖5所示之邊緣型構成。Edge BL (blue light) + BLT sheet + QD sheet + 稜鏡 +
圖10係示出試樣7~試樣9中波長400 nm~700 nm與發光強度之關係的曲線圖。圖11係示出試樣10~試樣12中波長400 nm~700 nm與發光強度之關係的曲線圖。圖12係示出試樣7~試樣9中波長500 nm~700 nm與發光強度之關係的曲線圖。圖13係示出試樣10~試樣12中波長500 nm~700 nm與發光強度之關係的曲線圖。再者,圖12、圖13中,相較於圖10、圖11,擴大了縱軸之發光強度之範圍。Fig. 10 is a graph showing the relationship between the wavelengths of 400 nm to 700 nm and the luminous intensity in
如圖10、圖12所示,無部分反射片材之試樣7及試樣10中,藍色發光強度變高,相較於此,具有部分反射片材之試樣8、9、11、12中,控制了藍色發光強度。As shown in Fig. 10 and Fig. 12, the blue luminous intensity of
又,如圖12、圖13所示,無部分反射片材之試樣7及試樣10中,紅色發光強度及綠色發光強度降低,相較於此,具有部分反射片材之試樣8、9、11、12中,提高了紅色發光強度及綠色發光強度。In addition, as shown in Figs. 12 and 13, in the
如上所述,可知藉由使用部分反射片材,可控制藍色發光強度,並且提高紅色發光強度及綠色發光強度,可對來自藍色LED之光進行波長轉換而提高所發出之白色光之亮度,並且可抑制亮度不均。As mentioned above, it can be seen that by using a partially reflective sheet, the blue luminous intensity can be controlled, and the red luminous intensity and the green luminous intensity can be increased. The wavelength of the light from the blue LED can be converted to increase the brightness of the white light emitted. , And can suppress uneven brightness.
再者,將QD塗佈於BLT片材之表面之情形與將QD片材重疊於BLT片材上之情形,在發光強度上未見太大差異。 [產業上之可利用性]Furthermore, there is not much difference in luminous intensity in the case of applying QD on the surface of the BLT sheet and the case of overlapping the QD sheet on the BLT sheet. [Industrial availability]
根據本發明,可提供一種發光裝置,其可減少波長轉換片材中所包含之紅色發光量子點及綠色發光量子點之含量,可降低波長轉換片材之製造成本,並且抑制暈圈現象,能夠發出白色光。發光裝置例如可用作顯示裝置之背光裝置。According to the present invention, a light-emitting device can be provided, which can reduce the content of red light-emitting quantum dots and green light-emitting quantum dots contained in the wavelength conversion sheet, reduce the manufacturing cost of the wavelength conversion sheet, and suppress the halo phenomenon. Glows white light. The light-emitting device can be used as a backlight device of a display device, for example.
本申請案基於2019年10月15日提出申請之日本專利特願2019-188398。其全部內容包含於本文中。This application is based on Japanese Patent Application No. 2019-188398 filed on October 15, 2019. Its entire content is included in this article.
1:發光裝置
2:發光元件
3:波長轉換片材
4:基板
5:擴散板
6,7:光學片材
10:量子點
10a:內核
10b:外殼
11:有機配位基
12:導光板
13:發光元件
L:波長轉換片材3之長度尺寸L
L1:從發光元件2所發出之光
L2:白色光
L3:從發光元件13所發射之光
T:波長轉換片材3之厚度尺寸
W:波長轉換片材3之寬度尺寸1: Light-emitting device
2: Light-emitting element
3: Wavelength conversion sheet
4: substrate
5:
圖1係本實施方式之發光裝置之剖面模式圖。 圖2係本實施方式之發光裝置之俯視模式圖。 圖3A係本實施方式之量子點之模式圖。 圖3B係本實施方式之量子點之模式圖。 圖4係與圖1不同之本實施方式之發光裝置之剖面模式圖。 圖5係與圖1不同之本實施方式之發光裝置之剖面模式圖。 圖6係示出波長(400 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之直下型光學元件、及不具備部分反射片材之含量子點之直下型光學元件進行的結果。 圖7係示出波長(400 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之直下型光學元件(附DBEF(Dual Brightness Enhancement Film,反射型偏光膜))、及不具備部分反射片材之含量子點之直下型光學元件(附DBEF)進行的結果。 圖8係示出波長(500 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之直下型光學元件、及不具備部分反射片材之含量子點之直下型光學元件進行的結果。 圖9係示出波長(500 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之直下型光學元件(附DBEF)、及不具備部分反射片材之含量子點之直下型光學元件(附DBEF)進行的結果。 圖10係示出波長(400 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之邊緣型光學元件、及不具備部分反射片材之含量子點之邊緣型光學元件進行的結果。 圖11係示出波長(400 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之邊緣型光學元件(附DBEF)、及不具備部分反射片材之含量子點之邊緣型光學元件(附DBEF)進行的結果。 圖12係示出波長(500 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之邊緣型光學元件、不具備部分反射片材之含量子點之邊緣型光學元件進行的結果。 圖13係示出波長(500 nm~700 nm)與亮度之關係的曲線圖,該圖係使用具備部分反射片材之含量子點之邊緣型光學元件(附DBEF)、及不具備部分反射片材之含量子點之邊緣型光學元件(附DBEF)進行的結果。FIG. 1 is a schematic cross-sectional view of the light-emitting device of this embodiment. FIG. 2 is a schematic plan view of the light-emitting device of this embodiment. FIG. 3A is a schematic diagram of the quantum dot of this embodiment. FIG. 3B is a schematic diagram of the quantum dot of this embodiment. FIG. 4 is a schematic cross-sectional view of the light-emitting device of this embodiment that is different from FIG. 1. FIG. 5 is a schematic cross-sectional view of the light-emitting device of this embodiment that is different from FIG. 1. Figure 6 is a graph showing the relationship between wavelength (400 nm ~ 700 nm) and brightness. This graph uses a direct-type optical element with the content of the partially reflective sheet and the content of the non-reflective sheet. The result of the point-of-point direct-type optical element. Figure 7 is a graph showing the relationship between wavelength (400 nm ~ 700 nm) and brightness. This graph uses a direct type optical element with a content of sub-points of a partially reflective sheet (with DBEF (Dual Brightness Enhancement Film, reflective type) Polarizing film)), and the result of a direct-type optical element (with DBEF) that does not have the content of sub-points of a partially reflective sheet. Figure 8 is a graph showing the relationship between wavelength (500 nm ~ 700 nm) and brightness. This graph uses a direct-type optical element with the content of the partially reflective sheet and the content of the non-reflective sheet. The result of the point-of-point direct-type optical element. Figure 9 is a graph showing the relationship between wavelength (500 nm to 700 nm) and brightness. This graph uses a direct-type optical element (with DBEF) that has a partially reflective sheet and does not have a partially reflective sheet. The result of the direct-type optical element (with DBEF) with the content of the sub-point of the material. Figure 10 is a graph showing the relationship between wavelength (400 nm ~ 700 nm) and brightness. This graph uses edge-type optical elements with the content of the partially reflective sheet and the content of the non-reflective sheet. The result of point-of-edge optics. Figure 11 is a graph showing the relationship between wavelength (400 nm to 700 nm) and brightness. This graph uses an edge-type optical element (with DBEF) with the content of sub-points of a partially reflective sheet and does not have a partially reflective sheet The result of the edge-type optical element (with DBEF) with the content of the sub-point of the material. Figure 12 is a graph showing the relationship between wavelength (500 nm ~ 700 nm) and brightness. This graph uses edge-type optical elements with a partially reflective sheet's content sub-points, and does not have a partially reflective sheet's content sub-points The result of edge optics. Figure 13 is a graph showing the relationship between wavelength (500 nm to 700 nm) and brightness. This graph uses an edge-type optical element (with DBEF) with the content of sub-points of a partially reflective sheet and does not have a partially reflective sheet The result of the edge-type optical element (with DBEF) with the content of the sub-point of the material.
1:發光裝置 1: Light-emitting device
2:發光元件 2: Light-emitting element
3:波長轉換片材 3: Wavelength conversion sheet
4:基板 4: substrate
5:擴散板 5: diffuser
6,7:光學片材 6, 7: Optical sheet
L1:從發光元件2所發出之光
L1: Light emitted from light-emitting
L2:白色光 L2: white light
T:波長轉換片材3之厚度尺寸
T: The thickness of the
Claims (6)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019188398 | 2019-10-15 | ||
JP2019-188398 | 2019-10-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW202123496A true TW202123496A (en) | 2021-06-16 |
Family
ID=75538497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW109135450A TW202123496A (en) | 2019-10-15 | 2020-10-14 | Light emitting device |
Country Status (2)
Country | Link |
---|---|
TW (1) | TW202123496A (en) |
WO (1) | WO2021075394A1 (en) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013033833A (en) * | 2011-08-01 | 2013-02-14 | Panasonic Corp | Wavelength conversion film and light emitting device and lighting device which use the same |
TWI436507B (en) * | 2011-08-05 | 2014-05-01 | Au Optronics Corp | Light emitting device and light source module |
US9634201B2 (en) * | 2012-05-14 | 2017-04-25 | Koninklijke Philips N.V. | Light emitting device with nanostructured phosphor |
JP2015084305A (en) * | 2013-10-25 | 2015-04-30 | スタンレー電気株式会社 | Light lighting device |
US20170096538A1 (en) * | 2014-03-18 | 2017-04-06 | Kuraray Co., Ltd. | Electronic device |
CN106816520A (en) * | 2015-11-30 | 2017-06-09 | 隆达电子股份有限公司 | Wavelength conversion material and application thereof |
JP6797624B2 (en) * | 2016-09-27 | 2020-12-09 | エルジー ディスプレイ カンパニー リミテッド | Light source device and display device |
-
2020
- 2020-10-12 WO PCT/JP2020/038429 patent/WO2021075394A1/en active Application Filing
- 2020-10-14 TW TW109135450A patent/TW202123496A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2021075394A1 (en) | 2021-04-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10866463B2 (en) | Strip, and backlight unit and liquid crystal display including the same | |
US10670230B2 (en) | Wavelength conversion member, molded body, wavelength conversion apparatus, sheet member, light emitting apparatus, light guide apparatus and display apparatus | |
CA2905129C (en) | Light emitting device | |
US9927649B2 (en) | Backlight unit for display devices | |
JP7046935B2 (en) | Backlight unit for display device | |
US10509263B2 (en) | Backlight units for display devices | |
CN104819402B (en) | Backlight assembly and display equipment with backlight assembly | |
KR20130009020A (en) | Optical member, display device having the same and method of fabricating the same | |
US10649114B2 (en) | Backlight unit with optical member and protective member and display device including the same | |
JP2020531903A (en) | Use of multiple excitation wavelengths in nanostructure-based display devices | |
KR20130110946A (en) | Optical member and display device having the same | |
KR20130044032A (en) | Optical member and display device having the same | |
TW202123496A (en) | Light emitting device | |
JP2022530624A (en) | Backlight unit with quantum dots | |
JP2021535431A (en) | Increased color gamut performance and efficiency in quantum dot color conversion layers | |
US11209697B1 (en) | Backlight unit with phosphors and quantum dots | |
KR102218345B1 (en) | Lighting devicee | |
TWI831382B (en) | Backlight module and display apparatus | |
KR102135514B1 (en) | Backlight unit and display including the same | |
JP2019061951A (en) | Backlight unit, display device, and method for producing display device | |
KR102500214B1 (en) | Display apparatus including the thermal spreading shee | |
KR102310178B1 (en) | Backlight unit and display device comprising the same | |
KR20210077259A (en) | Liquid Crystal Display device | |
KR20130044031A (en) | Optical member and display device having the same |