TW202119500A - Semiconductor device and method of manufacturing the same - Google Patents
Semiconductor device and method of manufacturing the same Download PDFInfo
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body
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- H01L27/085—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
- H01L27/088—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
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- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/5222—Capacitive arrangements or effects of, or between wiring layers
- H01L23/5225—Shielding layers formed together with wiring layers
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- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/528—Geometry or layout of the interconnection structure
- H01L23/5283—Cross-sectional geometry
Abstract
Description
本發明是有關於一種半導體裝置以及半導體裝置的製造方法。The present invention relates to a semiconductor device and a manufacturing method of the semiconductor device.
於在矽等的半導體基板上形成有細微元件的半導體裝置中,有將金屬絕緣體半導體場效電晶體(Metal-Insulator-Semiconductor Field-Effect Transistor,MISFET)、電阻元件、熔絲(fuse)元件等半導體元件組合而成的類比(analog)用半導體裝置。In semiconductor devices in which micro devices are formed on semiconductor substrates such as silicon, there are Metal-Insulator-Semiconductor Field-Effect Transistor (MISFET), resistance elements, fuse elements, etc. An analog semiconductor device made up of a combination of semiconductor elements.
作為類比用半導體裝置,例如,可舉出調壓器(voltage regulator)、電壓檢測器(voltage detector)、切換調節器(switching regulator)等。於該些類比用半導體裝置中,伴隨著可佩戴裝置(wearable device)或物聯網(Internet of the Things,IoT)的發展,而開發能夠藉由二次電池等以低電壓、低消耗電流進行長時間驅動的類比用半導體裝置。特別是當在調壓器等的電力管理(power management)積體電路(integrated circuit,IC)中包括基準電壓產生電路的情況下,重要的是減少基準電壓的偏差或長期的穩定性。Examples of analog semiconductor devices include a voltage regulator, a voltage detector, and a switching regulator. Among these analog semiconductor devices, with the development of wearable devices (wearable devices) or the Internet of the Things (IoT), development can be extended with low voltage and low current consumption by secondary batteries. Time-driven analog semiconductor devices. Especially when a reference voltage generating circuit is included in a power management (power management) integrated circuit (IC) such as a voltage regulator, it is important to reduce the deviation of the reference voltage or long-term stability.
然而,於用於此種基準電壓產生電路的MISFET中,自鈍化(passivation)膜等產生的氫鍵合於位於閘極氧化膜與矽基板的界面的懸空鍵(dangling bond)(非鍵合鍵),而有臨限值電壓在製造時產生偏差的情況或隨著時間而變化的情況。However, in the MISFET used in such a reference voltage generating circuit, hydrogen generated from a passivation film or the like is bonded to a dangling bond (non-bonding bond) at the interface between the gate oxide film and the silicon substrate. , And there are cases where the threshold voltage varies during manufacturing or changes over time.
因此,例如,提議一種半導體裝置,於N通道金屬氧化物半導體(Metal-Oxide-Semiconductor,MOS)電晶體等的上方形成有用於屏蔽氫的矽氮化膜,以使氫不擴散至N通道MOS電晶體(例如,參照專利文獻1)。 [現有技術文獻] [專利文獻]Therefore, for example, a semiconductor device is proposed in which a silicon nitride film for shielding hydrogen is formed on an N-channel Metal-Oxide-Semiconductor (MOS) transistor, etc., so that hydrogen does not diffuse into the N-channel MOS. Transistor (for example, refer to Patent Document 1). [Prior Art Literature] [Patent Literature]
[專利文獻1]日本專利特開2003-152100號公報[Patent Document 1] Japanese Patent Laid-Open No. 2003-152100
[發明所欲解決之課題][The problem to be solved by the invention]
於本發明的一個方面中,目的在於提供一種可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況的半導體裝置。 [解決課題之手段]In one aspect of the present invention, an object is to provide a semiconductor device that can suppress the occurrence of defects caused by hydrogen without increasing the film formed. [Means to solve the problem]
本發明的一實施形態的半導體裝置包括: 半導體基板; 場效電晶體,配置於所述半導體基板上,且用於類比電路中,並包括P型閘極電極; 層間絕緣膜,配置於所述場效電晶體上;以及 氫阻擋金屬膜,配置於所述層間絕緣膜上且為所述P型閘極電極的上方附近,阻擋氫。 [發明的效果]A semiconductor device according to an embodiment of the present invention includes: Semiconductor substrate A field effect transistor, which is arranged on the semiconductor substrate and used in an analog circuit, and includes a P-type gate electrode; An interlayer insulating film disposed on the field effect transistor; and A hydrogen barrier metal film is disposed on the interlayer insulating film and is near the upper side of the P-type gate electrode, and blocks hydrogen. [Effects of the invention]
根據本發明的一個方面,能夠提供一種可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況的半導體裝置。According to an aspect of the present invention, it is possible to provide a semiconductor device that can suppress the occurrence of problems caused by hydrogen without increasing the formed film.
本發明的一實施形態的半導體裝置包括:半導體基板;場效電晶體,配置於半導體基板上,且用於類比電路中,並包括P型閘極電極;層間絕緣膜,配置於場效電晶體上;以及氫阻擋金屬膜,配置於層間絕緣膜上且為P型閘極電極的上方附近,阻擋氫。A semiconductor device according to an embodiment of the present invention includes: a semiconductor substrate; a field-effect transistor, which is arranged on the semiconductor substrate and used in an analog circuit, and includes a P-type gate electrode; an interlayer insulating film, which is arranged on the field-effect transistor On; and a hydrogen barrier metal film, disposed on the interlayer insulating film and near the upper side of the P-type gate electrode, blocking hydrogen.
本發明的一實施形態的半導體裝置基於以下的見解而完成。The semiconductor device of one embodiment of the present invention was completed based on the following knowledge.
對類比用半導體裝置所要求的特性,與處理二進制的訊號的邏輯用半導體裝置大不相同。例如,於鋰離子(lithium ion)電池等二次電池的充放電控制電路中,為了儘量降低於行動(mobile)設備等中所使用的二次電池的放電,此數年來大多追求μV單位的規格。用於所述充放電控制電路的基準電壓產生電路,亦追求μV單位的信賴性。因此,需要降低基準電壓產生電路所包括的場效電晶體(以下稱為「MOS電晶體」)的臨限值電壓的偏差、或可藉由長期信賴性試驗而示出的隨著時間的變化。The characteristics required for analog semiconductor devices are quite different from logic semiconductor devices that process binary signals. For example, in the charge and discharge control circuit of secondary batteries such as lithium ion batteries, in order to minimize the discharge of secondary batteries used in mobile devices, etc., the specification of μV units has been mostly pursued for several years. . The reference voltage generating circuit used in the charge and discharge control circuit also pursues reliability in μV units. Therefore, it is necessary to reduce the deviation of the threshold voltage of the field effect transistor (hereinafter referred to as "MOS transistor") included in the reference voltage generating circuit, or the change over time that can be shown by long-term reliability tests. .
於形成所述MOS電晶體時,多為將硼、磷、砷等雜質注入至多晶矽膜而形成閘極電極。作為雜質而注入的硼較磷或砷更易於擴散至多晶矽膜,並擴散至多晶矽膜下的閘極氧化膜。如是,考慮所述閘極氧化膜與注入有磷或砷的情況相比膜質更容易降低,而更容易使如氫般的微小的原子通過。此時,若自鈍化膜等產生的氫即便微量亦鍵合於位於閘極氧化膜與矽基板的界面的懸空鍵(非鍵合鍵),則於需要以μV單位進行調整的類比用半導體裝置中,亦有臨限值電壓在製造時產生偏差或隨著時間而變化的情況。When forming the MOS transistor, impurities such as boron, phosphorus, and arsenic are usually injected into the polysilicon film to form a gate electrode. Boron implanted as an impurity is easier to diffuse into the polysilicon film than phosphorus or arsenic, and to the gate oxide film under the polysilicon film. If so, it is considered that the gate oxide film is more likely to be degraded in quality than the case where phosphorus or arsenic is implanted, and it is easier to pass minute atoms such as hydrogen. At this time, if even a trace amount of hydrogen generated from the passivation film is bonded to the dangling bond (non-bonding bond) at the interface between the gate oxide film and the silicon substrate, it will be used in an analog semiconductor device that needs to be adjusted in units of μV. , There are also cases where the threshold voltage varies during manufacturing or changes over time.
關於此方面,於專利文獻1記載的半導體裝置中,設為於P型閘極電極的上方配置用於屏蔽氫的矽氮化膜,但此舉不僅增加用於形成矽氮化膜的步驟,而且有臨限值電壓因配置於P型閘極電極的附近的矽氮化膜的應力而變化的情況。In this regard, in the semiconductor device described in
因此,本發明的一實施形態的半導體裝置將配置於MOS電晶體上的金屬配線層的面積擴大而用作氫阻擋金屬膜。即,所述半導體裝置藉由在臨限值電壓易於變化的P型閘極電極的上方附近,配置兼作金屬配線層的氫阻擋金屬膜,而可阻擋自鈍化膜等產生的氫,因此可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況。Therefore, the semiconductor device according to an embodiment of the present invention uses an enlarged area of the metal wiring layer arranged on the MOS transistor to be used as a hydrogen barrier metal film. That is, the semiconductor device can block hydrogen generated from the passivation film and the like by disposing a hydrogen barrier metal film that doubles as a metal wiring layer in the vicinity of the P-type gate electrode where the threshold voltage is easily changed. Without increasing the film formed, the occurrence of defects caused by hydrogen is suppressed.
接著,作為本發明的一實施形態的半導體裝置的一例,參照圖式對將類比電路設為增強/耗盡(enhancement/depletion,ED)型基準電壓產生電路的實施形態進行說明。Next, as an example of a semiconductor device according to an embodiment of the present invention, an embodiment in which the analog circuit is an enhancement/depletion (ED) type reference voltage generating circuit will be described with reference to the drawings.
再者,圖式為示意性的圖式,膜厚與平面尺寸的關係、各膜厚的比率等並非如圖式所示般。又,於半導體基板中,將使用半導體製造製程而積層有其他膜或層一側的面稱為「上表面」,將與上表面相向一側的面稱為「下表面」。進而,於下文中,多個膜或將所述多個膜結構性地組合而獲得的半導體元件的數量、位置、形狀、結構、大小等,並不限定於以下所示的實施形態,可設為較佳的數量、位置、形狀、結構、大小等用以實施本發明。In addition, the drawing is a schematic drawing, and the relationship between the film thickness and the plane size, the ratio of each film thickness, etc. are not as shown in the drawing. In addition, in a semiconductor substrate, the surface on the side where other films or layers are laminated using a semiconductor manufacturing process is called the "upper surface", and the surface on the side facing the upper surface is called the "lower surface". Furthermore, in the following, the number, position, shape, structure, size, etc. of the plurality of films or the semiconductor elements obtained by structurally combining the plurality of films are not limited to the embodiments shown below, and can be set The preferred number, position, shape, structure, size, etc. are used to implement the present invention.
[第一實施形態]
圖1是表示本發明的第一實施形態的半導體裝置的類比電路的電路圖。如圖1所示,本實施形態的半導體裝置100包括類比電路即ED型基準電壓產生電路,具有耗盡(depletion)型N通道場效電晶體110、以及增強(enhancement)型N通道場效電晶體120。[First Embodiment]
Fig. 1 is a circuit diagram showing an analog circuit of a semiconductor device according to a first embodiment of the present invention. As shown in FIG. 1, the
再者,下文中,有時將「耗盡型N通道場效電晶體」稱為「D型NMOS電晶體」,有時將「增強型N通道場效電晶體」稱為「E型NMOS電晶體」。Furthermore, hereinafter, sometimes the "depletion-mode N-channel field effect transistor" is referred to as the "D-type NMOS transistor", and sometimes the "enhanced N-channel field effect transistor" is referred to as the "E-type NMOS transistor". Crystal".
D型NMOS電晶體110作為定電流源而發揮功能,當對與電源端子100a連接的汲極施加電源電壓VDD時,將不依存於電源電壓VDD的定電流自源極供給至E型NMOS電晶體120。E型NMOS電晶體120基於自D型NMOS電晶體110供給的定電流,使基準電壓端子100c產生基準電壓Vref
。如此般,ED型基準電壓產生電路藉由組合D型NMOS電晶體110與E型NMOS電晶體120而形成。The D-
於D型NMOS電晶體110的源極,連接有D型NMOS電晶體110的閘極、背閘極、基準電壓端子100c、以及E型NMOS電晶體120的閘極及汲極,而將該些部件設為相同電位。又,於E型NMOS電晶體120的源極,連接有背閘極及接地端子100b,而將該些部件設為相同電位。To the source of the D-
此處,當求取D型NMOS電晶體110的汲極電流Id1
時,若將非飽和運作時或者飽和運作時的互導率(conductance)設為gmD,則可如以下的式(1)般示出。再者,如上文所述般,由於D型NMOS電晶體110的閘極與源極連接,故於下述式(1)中,閘極-源極間電壓Vg1
為0 V。因此,D型NMOS電晶體110的輸出電流即汲極電流Id1
依存於臨限值電壓Vtd
。
Id1
=1/2·gmD·(Vg1
-Vtd
)2
=1/2·gmD·(|Vtd
|)2
···(1)Here, when the drain current I d1 of the D-
接著,當求取E型NMOS電晶體120的汲極電流Id2
時,若將飽和運作時的互導率設為gmE,則可如以下的式(2)般示出。再者,如上文所述般,由於E型NMOS電晶體120的閘極與汲極連接,進而該些部件與基準電壓端子100c連接,因此於下述式(2)中,閘極-源極間電壓Vg2
成為基準電壓Vref
。因此,汲極電流Id2
依存於臨限值電壓Vte
及基準電壓Vref
。
Id2
=1/2·gmE·(Vg2
-Vte
)2
=1/2·gmE·(Vref
-Vte
)2
···(2)Next, when the drain current I d2 of the
根據上文所述,由於上述式(1)的Id1 等於上述式(2)的Id2 ,因此基準電壓Vref 成為下述式(3)。 Vref ≒Vte +(gmD/gmE)1/2 ·|Vtd | ···(3)As described above, since I d1 in the above-mentioned formula (1) is equal to I d2 in the above-mentioned formula (2), the reference voltage V ref becomes the following formula (3). V ref ≒V te +(gmD/gmE) 1/2 ·|V td | ···(3)
圖2是表示本發明的第一實施形態的半導體裝置的概略平面圖,且為俯視形成於半導體基板上的ED型基準電壓產生電路的圖。於圖2中,示出半導體裝置100的結構中的N型閘極電極6、P型閘極電極7、兼具金屬配線層的功能的氫阻擋金屬膜10、以及與氫阻擋金屬膜10連接的金屬配線9a~金屬配線9f。又,圖2中的虛線分別表示D型NMOS電晶體110及E型NMOS電晶體120的主動(active)區域。2 is a schematic plan view showing the semiconductor device according to the first embodiment of the present invention, and is a plan view of an ED-type reference voltage generating circuit formed on a semiconductor substrate. In FIG. 2, the N-
再者,所謂俯視下的圖,意指對半導體基板自其法線方向觀察上表面時的圖(俯視圖)。In addition, the figure in the top view means the figure (plan view) when the upper surface of a semiconductor substrate is seen from the normal direction.
在自半導體基板的上方(基板的法線方向)俯視時,E型NMOS電晶體120一側的以虛線表示的主動區域上的氫阻擋金屬膜10大於P型閘極電極7的面積,以覆蓋P型閘極電極7的方式配置。When viewed from above the semiconductor substrate (in the normal direction of the substrate), the hydrogen
此處,參照圖3及圖4對D型NMOS電晶體110及E型NMOS電晶體120的剖面進行說明。Here, the cross-sections of the D-
圖3是表示圖2中的A-A線的剖面的說明圖。圖4是表示圖2中的B-B線的剖面的說明圖。Fig. 3 is an explanatory diagram showing a cross section taken along the line A-A in Fig. 2. Fig. 4 is an explanatory diagram showing a cross section taken along the line B-B in Fig. 2.
如圖3及圖4所示,半導體裝置100包括:半導體基板1、分離用氧化膜2、閘極氧化膜3、P型阱區域4、源極-汲極區域5、N型閘極電極6、P型閘極電極7、添加有磷及硼的矽氧化膜(以下稱為「硼磷矽玻璃(Boro-Phospho Silicate Glass,BPSG)膜」)8、金屬配線9、氫阻擋金屬膜10、以及鈍化膜11。D型NMOS電晶體110及E型NMOS電晶體120藉由在半導體基板1上將分離用氧化膜2、閘極氧化膜3、P型阱區域4、源極-汲極區域5、N型閘極電極6、以及P型閘極電極7結構性地組合而形成。As shown in FIGS. 3 and 4, the
半導體基板1是晶圓狀P型矽半導體基板。The
再者,於本實施形態中,作為半導體基板1而設為晶圓狀P型矽半導體基板,但並不限定於此,半導體基板1的形狀、結構、大小、材質、及極性可根據目的而適當選擇。Furthermore, in this embodiment, the
分離用氧化膜2是形成於半導體基板1上的矽局部氧化(LOCal Oxidation of Silicon,LOCOS)。分離用氧化膜2為了分離D型NMOS電晶體110及E型NMOS電晶體120,而設置於各主動區域的外緣。The
再者,於本實施形態中,為了分離D型NMOS電晶體110及E型NMOS電晶體120而形成LOCOS,但並不限定於此,例如,亦可形成淺溝槽絕緣(Shallow Trench Isolation,STI)等而予以分離。Furthermore, in this embodiment, LOCOS is formed in order to separate the D-
D型NMOS電晶體110包括:閘極氧化膜3、P型阱區域4、源極-汲極區域5、以及於多晶矽膜注入有磷而成的N型閘極電極6。The D-
D型NMOS電晶體110中,基於以P型阱區域4與N型閘極電極6的工作函數的差變大的方式調整雜質濃度,而對P型的半導體基板1的表面施加有反轉方向的電場,因此成為低臨限值電壓。進而,基於可藉由N型通道摻雜區域降低臨限值電壓,因此對於N型閘極電極6及通道摻雜區域的雜質注入以D型NMOS電晶體110成為耗盡型的方式適當控制,而可將臨限值電壓Vtd
設為0 V以下。藉此,即便閘極的電位為0 V,亦可藉由施加汲極電壓而經由通道流動汲極電流。In the D-
又,背閘極經由包含高濃度的P型雜質的區域(未圖示)連接於P型阱區域4,且連接於源極。In addition, the back gate is connected to the P-
E型NMOS電晶體120具有注入BF2
而形成的P型閘極電極7,以臨限值電壓Vte
成為0 V以上的方式,調整P型閘極電極7及通道摻雜區域的雜質濃度。又,於所述P型閘極電極7的上方配置有氫阻擋金屬膜10。除此以外,E型NMOS電晶體120與D型NMOS電晶體110相同。The
再者,P型閘極電極7的形狀、結構、大小、材質、以及雜質的種類及濃度並無特別限制,可根據目的而適當選擇。In addition, the shape, structure, size, material, and type and concentration of impurities of the P-
於D型NMOS電晶體110及E型NMOS電晶體120的上表面,將表面平坦化而形成作為層間絕緣膜的BPSG膜8。於所述BPSG膜8,以貫通至源極-汲極區域5的方式將金屬配線9a~金屬配線9d分別埋入於分別形成的接觸孔(contact hole),而形成來自源極-汲極區域5的導通路徑。On the upper surfaces of the D-
再者,於本實施形態中,將層間絕緣膜設為BPSG膜8,但並不限定於此,例如亦可設為非摻雜矽酸鹽玻璃(Non-doped Silicate Glass,NSG)膜與BPSG膜的積層結構、正矽酸乙酯(Tetra-Ethyl-Ortho-Silicate,TEOS)膜與BPSG膜的積層結構等。Furthermore, in this embodiment, the interlayer insulating film is set as the
與金屬配線9a~金屬配線9d的上部電性連接的氫阻擋金屬膜10包含AlSiCu。由於所述氫阻擋金屬膜10位於P型閘極電極7的上方,因此阻礙以鈍化膜11等為產生源的氫自上方移動,而可以不使氫侵入具有P型閘極電極7的E型NMOS電晶體120的附近的方式進行阻擋。即,本實施形態的半導體裝置100藉由在P型閘極電極7的上方具有兼具金屬配線層的功能的氫阻擋金屬膜10,而可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況。The hydrogen
作為氫阻擋金屬膜10的材質並無特別限制,可根據目的而適當選擇,但在氫阻擋金屬膜10兼為金屬配線層的方面而言,較佳為鋁合金。作為鋁合金,例如,除了AlSiCu以外,還可舉出AlNd、AlCu、AlSi等。又,亦可設為於基底的鈦上膜狀地形成鎢的態樣。若為與所述基底的鈦上膜狀地形成鎢的態樣,則在下述方面有利,即:不僅藉由鎢阻擋氫侵入,而且可藉由基底的鈦吸收氫。The material of the hydrogen
再者,於本實施形態中,將氫阻擋金屬膜10設為大於P型閘極電極7的主動區域的面積,但只要可阻擋擴散至P型閘極電極7的主動區域的氫,則不限定於此,氫阻擋金屬膜10的面積亦可等同於或窄於P型閘極電極7的主動區域。Furthermore, in this embodiment, the hydrogen
作為氫阻擋金屬膜10的厚度並無特別限制,可根據目的而適當選擇,但基於可確保能夠阻擋氫的厚度的觀點,較佳為300 nm以上且500 nm以下。The thickness of the hydrogen
作為氫阻擋金屬膜10的大小並無特別限制,可根據目的而適當選擇,較佳為在俯視下於主動區域內大於P型閘極電極7。The size of the hydrogen
於半導體裝置100的最上表面,設置有鈍化膜11。On the uppermost surface of the
作為鈍化膜11,較佳為矽氮化膜。作為矽氮化膜的形成方法,當使用減壓化學氣相沈積(Chemical Vaper Deposition,CVD)時,有金屬配線9a~金屬配線9d融解的情形,因此較佳為使用電漿CVD。As the
再者,於本實施形態中,將鈍化膜11設為矽氮化膜的單層結構,但並不限定於此,例如,亦可設為矽氧化膜與矽氮化膜的雙層結構。又,作為鈍化膜11的形狀、結構、及大小並無特別限制,可根據目的而適當選擇。In addition, in this embodiment, the
如此般,本實施形態的半導體裝置100於半導體基板1上具有:E型NMOS電晶體120,用於ED型基準電壓產生電路中,並包括P型閘極電極7;BPSG膜8,配置於E型NMOS電晶體120上;以及氫阻擋金屬膜10,配置於BPSG膜8上且為P型閘極電極7的上方附近,阻擋氫。藉此,半導體裝置100可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況。In this way, the
接著,參照圖5A至圖5C對本實施形態的半導體裝置100的製造方法進行說明。Next, a method of manufacturing the
首先,準備半導體基板1並進行LOCOS形成處理,而於半導體基板1上形成分離用氧化膜2。First, the
接著,如圖5A所示,藉由閘極氧化膜形成處理、源極-汲極區域形成處理、多晶矽的閘極電極形成處理等現有的金屬氧化物半導體場效電晶體(Metal-Oxide-Semiconductor Field-Effect Transistor,MOSFET)製造技術,於半導體基板1上形成閘極氧化膜3、P型阱區域4、源極-汲極區域5、N型閘極電極6、以及P型閘極電極7。藉此,形成D型NMOS電晶體110及E型NMOS電晶體120。Next, as shown in FIG. 5A, the conventional metal-oxide-semiconductor field-effect transistors (Metal-Oxide-Semiconductor transistors) such as gate oxide film formation processing, source-drain region formation processing, polysilicon gate electrode formation processing, etc. Field-Effect Transistor (MOSFET) manufacturing technology to form a
具體而言,為了形成D型NMOS電晶體110,首先於各主動區域的一部分注入硼而形成P型阱區域4,於P型阱區域4的表面的一部分形成N型通道摻雜區域。接著,當於所述通道摻雜區域上形成閘極氧化膜3之後,於形成於閘極氧化膜3上的多晶矽膜注入5×1016
/cm3
以上且1×1018
/cm3
以下的低濃度的磷而形成N型閘極電極6。然後,於閘極氧化膜3之下的夾著通道摻雜區域的位置,將1×1019
/cm3
以上的高濃度的N型的源極-汲極區域5形成於P型阱區域4的表面。Specifically, in order to form the D-
再者,該些部件藉由在必要的部分進行光罩(photo mask)處理而形成。Furthermore, these components are formed by performing photo mask processing on necessary parts.
又,作為多晶矽膜的厚度並無特別限制,可根據目的而適當選擇,較佳為100 nm以上且500 nm以下。In addition, the thickness of the polysilicon film is not particularly limited, and can be appropriately selected according to the purpose, and it is preferably 100 nm or more and 500 nm or less.
接著,如圖5B所示,將BPSG膜8形成於表面整個區域並予以平坦化。Next, as shown in FIG. 5B, the
作為BPSG膜8的形成方法,並無特別限制,可根據目的而適當選擇。The method of forming the
作為BPSG膜8的平坦化方法,並無特別限制,可根據目的而適當選擇,例如可舉出回流焊(reflow)法、回蝕(etch back)法、化學機械研磨(Chemical Mechanical Polishing,CMP)法等。具體而言,回流焊法可在形成含有磷或硼的氧化膜之後,以850℃以上的熱處理予以平坦化。The method for planarizing the
接著,藉由光微影術(photolithography)及乾式蝕刻(dry etching)於BPSG膜8開製接觸孔並以鈦為基底而將鎢埋入,而形成金屬配線9a~金屬配線9d。然後,藉由光微影術及蝕刻而形成氫阻擋金屬膜10。由於所述氫阻擋金屬膜10兼為金屬配線層,故存在與金屬配線9a~金屬配線9d的上部電性連接的部位。Next, contact holes are formed in the
接著,在形成BPSG膜8而予以平坦化之後,於BPSG膜8及氫阻擋金屬膜10上,藉由電漿CVD形成矽氮化膜即鈍化膜11。Next, after the
如此般,本實施形態的半導體裝置100的製造方法包括:形成E型NMOS電晶體120的步驟,所述E型NMOS電晶體120配置於半導體基板1上,且用於ED型基準電壓產生電路中,並包括P型閘極電極7;於E型NMOS電晶體120上形成BPSG膜8的步驟;以及於BPSG膜8上且為P型閘極電極7的上方附近,形成阻擋氫的氫阻擋金屬膜10的步驟。藉此,所製造的半導體裝置100可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況。In this way, the manufacturing method of the
再者,於本實施形態中,如圖6所示,可將E型NMOS電晶體120的源極端子與氫阻擋金屬膜10一體化。藉此,可擴大氫阻擋金屬膜10的面積,且於源極端子與氫阻擋金屬膜10之間不產生間隙,因此氫更不易擴散至包括P型閘極電極7的E型NMOS電晶體120中,就該方面而言較佳。Furthermore, in this embodiment, as shown in FIG. 6, the source terminal of the
[第二實施形態]
圖7是表示本發明的第二實施形態的半導體裝置的剖面的說明圖。如圖7所示,第二實施形態除了圖3所示的第一實施形態以外,還於氫阻擋金屬膜10上隔著BPSG膜12配置有廣域氫阻擋金屬膜13。[Second Embodiment]
Fig. 7 is an explanatory diagram showing a cross section of a semiconductor device according to a second embodiment of the present invention. As shown in FIG. 7, in the second embodiment, in addition to the first embodiment shown in FIG. 3, a wide-area hydrogen
廣域氫阻擋金屬膜13與氫阻擋金屬膜10同樣地包含AlSiCu。由於所述廣域氫阻擋金屬膜13位於P型閘極電極7及氫阻擋金屬膜10的上方,因此除了藉由氫阻擋金屬膜10以外亦可藉由廣域氫阻擋金屬膜13阻擋氫對於具有P型閘極電極7的E型NMOS電晶體120的侵入,故可進一步抑制產生由氫引起的不良狀況。The wide-area hydrogen
又,於本實施形態的半導體裝置100中,在具有多個場效電晶體的情況下,廣域氫阻擋金屬膜13較佳的是以覆蓋多個場效電晶體整體的方式配置於氫阻擋金屬膜10的上方。In addition, in the
[第三實施形態] 圖8是表示本發明的第三實施形態的半導體裝置的剖面的說明圖。[Third Embodiment] FIG. 8 is an explanatory diagram showing a cross-section of a semiconductor device according to a third embodiment of the present invention.
如圖8所示,第三實施形態除了圖3所示的第一實施形態以外,還於P型閘極電極7的上部及源極-汲極區域5的上部,形成有CoSi的金屬矽化物膜14、金屬矽化物膜15。藉此,本實施形態的半導體裝置100除了藉由氫阻擋金屬膜10以外亦藉由金屬矽化物膜14、金屬矽化物膜15阻擋氫在具有P型閘極電極7的E型NMOS電晶體120的附近的侵入,因此可進一步抑制產生由氫引起的不良狀況。As shown in FIG. 8, in addition to the first embodiment shown in FIG. 3, in the third embodiment, a metal silicide of CoSi is formed on the upper part of the P-
再者,於本實施形態中,將金屬矽化物膜14、金屬矽化物膜15設為CoSi,但並不限定於此,例如亦可設為WSi、TiSi、NiSi等。Furthermore, in this embodiment, the
如以上所說明般,本發明的一實施形態的半導體裝置包括:半導體基板;場效電晶體,配置於半導體基板上,且用於類比電路中,並包括P型閘極電極;層間絕緣膜,配置於場效電晶體上;以及氫阻擋金屬膜,配置於層間絕緣膜上且為P型閘極電極的上方附近,阻擋氫。As described above, the semiconductor device of one embodiment of the present invention includes: a semiconductor substrate; a field-effect transistor, which is arranged on the semiconductor substrate and used in an analog circuit, and includes a P-type gate electrode; an interlayer insulating film, It is arranged on the field effect transistor; and a hydrogen barrier metal film is arranged on the interlayer insulating film and is near the upper side of the P-type gate electrode to block hydrogen.
藉此,本發明的一實施形態的半導體裝置可在不增加所形成的膜的情況下抑制產生由氫引起的不良狀況。Thereby, the semiconductor device of one embodiment of the present invention can suppress the occurrence of defects caused by hydrogen without increasing the film formed.
再者,於上文所述的各實施形態中,D型NMOS電晶體110包括N型閘極電極6,E型NMOS電晶體120包括P型閘極電極,但並不限定於此,D型NMOS電晶體110亦可包括P型閘極電極。Furthermore, in each embodiment described above, the D-
又,於本實施形態中,將D型NMOS電晶體110及E型NMOS電晶體120兩者設為NMOS電晶體,但並不限定於此,亦可將兩者設為P通道金屬氧化物半導體(P-channel Metal-Oxide-Semiconductor,PMOS)電晶體。In addition, in this embodiment, both the D-
再者,於上文所述的各實施形態中,將類比電路設為ED型基準電壓產生電路,但並不限定於此,例如,亦可舉出非ED型的基準電壓產生電路、ED型或非ED型的基準電壓產生電路的輸出連接於比較器(comparator)的非反轉輸入端子及反轉輸入端子的至少任一者的電路、以及電流鏡(current mirror)電路等。Furthermore, in each of the above-mentioned embodiments, the analog circuit is set as an ED-type reference voltage generating circuit, but it is not limited to this. For example, non-ED-type reference voltage generating circuits and ED-type reference voltage generating circuits may also be cited. The output of the NOR-ED type reference voltage generating circuit is connected to a circuit of at least one of a non-inverting input terminal and an inverting input terminal of a comparator, a current mirror circuit, and the like.
1:半導體基板
2:分離用氧化膜
3:閘極氧化膜
4:P型阱區域
5:源極-汲極區域
6:N型閘極電極
7:P型閘極電極
8:BPSG膜(層間絕緣膜)
9a~9f:金屬配線
10:氫阻擋金屬膜
11:鈍化膜
12:BPSG膜(層間絕緣膜)
13:廣域氫阻擋金屬膜
14、15:金屬矽化物膜
100:半導體裝置
100a:電源端子
100b:接地端子
100c:基準電壓端子
110:耗盡型NMOS電晶體
120:增強型NMOS電晶體
A-A:線
B-B:線
VDD:電源電壓
VSS:接地電壓
Vref
:基準電壓1: Semiconductor substrate 2: Separation oxide film 3: Gate oxide film 4: P-type well region 5: Source-drain region 6: N-type gate electrode 7: P-type gate electrode 8: BPSG film (interlayer Insulating film) 9a to 9f: Metal wiring 10: Hydrogen barrier metal film 11: Passivation film 12: BPSG film (interlayer insulating film) 13: Wide-area hydrogen
圖1是表示本發明的第一實施形態的半導體裝置的類比電路的電路圖。 圖2是表示本發明的第一實施形態的半導體裝置的概略平面圖。 圖3是表示圖2中的A-A線的剖面的說明圖。 圖4是表示圖2中的B-B線的剖面的說明圖。 圖5A是表示製造本發明的第一實施形態的半導體裝置的方法的說明圖。 圖5B是表示製造本發明的第一實施形態的半導體裝置的方法的說明圖。 圖5C是表示製造本發明的第一實施形態的半導體裝置的方法的說明圖。 圖6是表示本發明的第一實施形態的變形例的概略平面圖。 圖7是表示本發明的第二實施形態的半導體裝置的剖面的說明圖。 圖8是表示本發明的第三實施形態的半導體裝置的剖面的說明圖。Fig. 1 is a circuit diagram showing an analog circuit of a semiconductor device according to a first embodiment of the present invention. Fig. 2 is a schematic plan view showing the semiconductor device according to the first embodiment of the present invention. Fig. 3 is an explanatory diagram showing a cross section taken along the line A-A in Fig. 2. Fig. 4 is an explanatory diagram showing a cross section taken along the line B-B in Fig. 2. 5A is an explanatory diagram showing a method of manufacturing the semiconductor device according to the first embodiment of the present invention. 5B is an explanatory diagram showing the method of manufacturing the semiconductor device according to the first embodiment of the present invention. 5C is an explanatory diagram showing the method of manufacturing the semiconductor device according to the first embodiment of the present invention. Fig. 6 is a schematic plan view showing a modification of the first embodiment of the present invention. Fig. 7 is an explanatory diagram showing a cross section of a semiconductor device according to a second embodiment of the present invention. FIG. 8 is an explanatory diagram showing a cross-section of a semiconductor device according to a third embodiment of the present invention.
100:半導體裝置 100: Semiconductor device
100a:電源端子 100a: power terminal
100b:接地端子 100b: Ground terminal
100c:基準電壓端子 100c: Reference voltage terminal
110:耗盡型NMOS電晶體 110: Depletion NMOS Transistor
120:增強型NMOS電晶體 120: Enhanced NMOS transistor
VDD:電源電壓 VDD: power supply voltage
VSS:接地電壓 VSS: Ground voltage
Vref:基準電壓 V ref : reference voltage
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