TW202103970A - Method for producing cutting-processed laminated film - Google Patents

Method for producing cutting-processed laminated film Download PDF

Info

Publication number
TW202103970A
TW202103970A TW109106912A TW109106912A TW202103970A TW 202103970 A TW202103970 A TW 202103970A TW 109106912 A TW109106912 A TW 109106912A TW 109106912 A TW109106912 A TW 109106912A TW 202103970 A TW202103970 A TW 202103970A
Authority
TW
Taiwan
Prior art keywords
laminated film
cutting
film
manufacturing
cutting tool
Prior art date
Application number
TW109106912A
Other languages
Chinese (zh)
Inventor
芦田丈行
高橋政仁
内藤達也
Original Assignee
日商住友化學股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商住友化學股份有限公司 filed Critical 日商住友化學股份有限公司
Publication of TW202103970A publication Critical patent/TW202103970A/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C3/00Milling particular work; Special milling operations; Machines therefor
    • B23C3/13Surface milling of plates, sheets or strips
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C1/00Milling machines not designed for particular work or special operations
    • B23C1/06Milling machines not designed for particular work or special operations with one vertical working-spindle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0004Cutting, tearing or severing, e.g. bursting; Cutter details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • B32B7/023Optical properties
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C2220/00Details of milling processes
    • B23C2220/16Chamferring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C2220/00Details of milling processes
    • B23C2220/52Orbital drilling, i.e. use of a milling cutter moved in a spiral path to produce a hole

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polarising Elements (AREA)
  • Laminated Bodies (AREA)
  • Milling Processes (AREA)
  • Liquid Crystal (AREA)

Abstract

This invention provides a method for producing cutting-processed laminated film capable of suppressing delamination of the laminated film due to cutting process.
A method for producing cutting-processed laminated film including a first cutting step of cutting the laminated film by performing an operation of relatively moving a cutting tool in a spiral shape when viewed from a direction perpendicular to a main surface of the laminated film.

Description

經切削加工之積層膜的製造方法 Manufacturing method of machined laminated film

本發明係有關於經切削加工之積層膜的製造方法。 The present invention relates to a method for manufacturing a laminated film processed by cutting.

近年來,被使用在各式各樣的領域的積層膜,逐漸被期望照著其使用目的、設計性等來加工形狀。但是,在加工積層膜之際,已知道在積層膜中會產生有破裂、層間剝離等缺陷(例如,JP2009-037228號公報及JP2016-030331號公報)。 In recent years, laminated films used in various fields are increasingly expected to be processed in shape according to their purpose of use, design, and the like. However, when processing a laminated film, it is known that defects such as cracks and delamination between layers occur in the laminated film (for example, JP2009-037228 and JP2016-030331).

本發明的目的係提供一種經切削加工之積層膜的製造方法,該經切削加工之積層膜的製造方法可抑制因切削加工所致之積層膜的層間剝離。 The object of the present invention is to provide a method for manufacturing a cut-processed laminated film that can suppress delamination of the laminated film due to cutting.

本發明提供下列所示之經切削加工之積層膜的製造方法。 The present invention provides a method for manufacturing a laminated film that has been machined by cutting as shown below.

〔1〕一種經切削加工之積層膜的製造方法,係包含:第1切削步驟,係從相對於積層膜的主面為垂直的方向觀看,進行使切削工具螺線狀地相對移動的操作,藉此切削前述積層膜。 [1] A method of manufacturing a cut-processed laminated film, comprising: a first cutting step, which is an operation of relatively moving a cutting tool in a helical shape when viewed from a direction perpendicular to the main surface of the laminated film, This cuts the aforementioned laminated film.

〔2〕如〔1〕所述之製造方法,其中,前述切削工具具有可旋轉的柄與外周刃, [2] The manufacturing method described in [1], wherein the cutting tool has a rotatable shank and a peripheral edge,

前述外周刃與前述柄成為一體。 The outer peripheral blade is integrated with the shank.

〔3〕如〔2〕所述之製造方法,其中,於前述第1切削步驟中,以前述柄係相對於前述積層膜的主面成為垂直的狀態進行使前述切削工具相對移動的操作。 [3] The manufacturing method according to [2], wherein in the first cutting step, the operation of relatively moving the cutting tool is performed in a state where the shank system is perpendicular to the main surface of the laminated film.

〔4〕如〔1〕至〔3〕中任一者所述之製造方法,其中,於前述第1切削步驟中,使前述切削工具相對移動的操作,係以相對於前述積層膜的主面為平行的方向進行。 [4] The manufacturing method according to any one of [1] to [3], wherein, in the first cutting step, the operation of moving the cutting tool relative to the main surface of the laminated film Performed in parallel directions.

〔5〕如〔1〕至〔4〕中任一者所述之製造方法,更包含: [5] The manufacturing method as described in any one of [1] to [4], further comprising:

貫通孔形成步驟,係於前述第1切削步驟之前形成貫通孔,該貫通孔係在相對於前述積層膜的主面為垂直的方向貫通;以及 The through hole forming step is to form a through hole before the first cutting step, and the through hole penetrates in a direction perpendicular to the main surface of the laminated film; and

配置步驟,係以貫通前述貫通孔的方式配置前述切削工具。 The arrangement step is to arrange the cutting tool so as to penetrate the through hole.

〔6〕如〔5〕所述之製造方法,其中,於前述貫通孔形成步驟中,藉由使前述切削工具於相對於前述積層膜的主面為垂直的方向相對移動,而形成前述貫通孔。 [6] The manufacturing method according to [5], wherein in the through hole forming step, the through hole is formed by relatively moving the cutting tool in a direction perpendicular to the main surface of the laminated film .

〔7〕如〔6〕所述之製造方法,其中,前述切削工具具有可旋轉的柄、外周刃及底刃, [7] The manufacturing method according to [6], wherein the cutting tool has a rotatable shank, a peripheral edge, and a bottom edge,

前述外周刃及前述底刃係各別與前述柄成為一體。 The outer peripheral blade and the bottom blade are respectively integrated with the shank.

〔8〕如〔1〕至〔7〕中任一者所述之製造方法,其中,於前述第1切削步驟中,螺線的螺距為0.01mm以上0.5mm以下。 [8] The manufacturing method according to any one of [1] to [7], wherein in the first cutting step, the pitch of the spiral is 0.01 mm or more and 0.5 mm or less.

〔9〕如〔1〕至〔8〕中任一者所述之製造方法,更包含研磨步驟,係研磨藉由前述第1切削步驟形成之切削部分。 [9] The manufacturing method as described in any one of [1] to [8], further including a grinding step of grinding the cut portion formed by the aforementioned first cutting step.

〔10〕如〔1〕至〔9〕中任一者所述之製造方法,更包含第2切削步驟,係於藉由前述第1切削步驟所得之積層膜中,在相對於前述積層膜的主面為平行的方向使前述切削工具相對移動,進行更進一步的切削。 [10] The manufacturing method as described in any one of [1] to [9], further comprising a second cutting step, in which the laminated film obtained by the aforementioned first cutting step has an The main surface is in a parallel direction, so that the cutting tool is relatively moved, and further cutting is performed.

〔11〕如〔1〕至〔10〕中任一者所述之製造方法,其中,前述積層膜為顯示裝置用膜。 [11] The manufacturing method according to any one of [1] to [10], wherein the laminated film is a film for a display device.

〔12〕如〔1〕至〔11〕中任一者所述之製造方法,其中,前述積層膜包含偏光板。 [12] The manufacturing method according to any one of [1] to [11], wherein the laminated film includes a polarizing plate.

〔13〕如〔1〕至〔12〕中任一者所述之製造方法,其中,於前述第1切削步驟中,將前述積層膜重疊複數片並切削。 [13] The manufacturing method according to any one of [1] to [12], wherein in the first cutting step, a plurality of pieces of the laminated film are stacked and cut.

依據本發明,於經切削加工之積層膜的製造中,可抑制因切削加工所致之積層膜的層間剝離。 According to the present invention, it is possible to suppress interlayer peeling of the laminated film due to the cutting process in the production of the laminated film that has undergone cutting processing.

100:積層膜 100: Laminated film

10:偏光板 10: Polarizing plate

11:偏光片 11: Polarizer

12,13:保護膜 12, 13: Protective film

20:第1黏著劑層 20: The first adhesive layer

21:第2黏著劑層 21: The second adhesive layer

30,31:光學機能層 30, 31: Optical function layer

40:接著劑層 40: Adhesive layer

圖1 為顯示藉由本發明的製造方法所得之經切削之積層膜的一例之示意圖。(a)、(b)及(c)所示之積層膜中,各別形成有圓形、U字形狀及Omega形狀的洞穴部。 Fig. 1 is a schematic diagram showing an example of a cut laminated film obtained by the manufacturing method of the present invention. In the laminated films shown in (a), (b), and (c), a circular, U-shaped, and Omega-shaped cavity are respectively formed.

圖2 為(A)顯示於第1切削步驟中,相對於積層膜,切削工具螺線狀地相對移動之樣子之一例之平面圖。(B)顯示作為比較例,相對於積層膜,切削工具相對移動之樣子之平面圖。圖中附箭頭的線,係顯示從對積層膜的主面為垂直的方向來觀看,切削工具相對移動的路線。 Fig. 2 is (A) a plan view showing an example of the relative movement of the cutting tool relative to the laminated film in a spiral shape in the first cutting step. (B) A plan view showing how the cutting tool moves relative to the laminated film as a comparative example. The line with arrows in the figure shows the path of the relative movement of the cutting tool when viewed from the direction perpendicular to the main surface of the laminated film.

圖3 為將於先前技術中因切削所產生之積層膜的缺陷之一部,從相對於積層膜的主面為垂直的方向攝影之顯微鏡照片。圖中的左上部為經切削之洞穴部,右下部為積層膜。 Fig. 3 is a micrograph of a defect of the laminated film produced by cutting in the prior art, taken from a direction perpendicular to the main surface of the laminated film. The upper left part of the picture is the cut cave part, and the lower right part is the laminated film.

圖4 為顯示本發明之積層膜的一例之示意剖面圖。 Fig. 4 is a schematic cross-sectional view showing an example of the laminated film of the present invention.

圖5 為顯示本發明之積層膜的另一例之示意剖面圖。 Fig. 5 is a schematic cross-sectional view showing another example of the laminated film of the present invention.

圖6 為顯示於實施例中,因切削所產生之層間剝離的深入值之圖表(graph)。 Fig. 6 is a graph showing the depth value of delamination caused by cutting in the embodiment.

<經切削加工之積層膜> <Cutting Laminated Film>

經切削加工之積層膜具有在相對於積層膜的主面為垂直的方向貫通之洞穴部。該洞穴部係藉由上述切削加工而形成者。參照圖1,洞穴部例如可為圓形(圖1之(a))、楕圓形、圓角型方形狀等,洞穴部亦可為與端面結合之U字形狀(圖1之(b))或Omega(Ω)形狀(圖1之(c))等缺口部。 The cut-processed laminated film has a cavity part penetrating in a direction perpendicular to the main surface of the laminated film. The cave is formed by the above-mentioned cutting process. Referring to Figure 1, the cave part can be round (Figure 1(a)), ellipse round, rounded square shape, etc., and the cave part can also be U-shaped combined with the end surface (Figure 1(b)) ) Or Omega (Ω) shape (Figure 1(c)) and other notches.

洞穴部為圓形的情況,其直徑例如可為1.5mm以上15mm以下,較佳為2mm以上10mm以下。洞穴部為楕圓形或圓角形方形狀的情況,楕圓或圓角的曲率半徑例如可為1mm以上10mm以下,較佳為2mm以上10 mm以下。洞穴部為缺口部的情況,缺口部的深度例如可為1.5mm以上15mm以下,較佳為2mm以上10mm以下。 When the cavity is circular, the diameter may be, for example, 1.5 mm or more and 15 mm or less, and preferably 2 mm or more and 10 mm or less. When the cave is in an elliptical or rounded square shape, the radius of curvature of the elliptical or rounded corner may be, for example, 1 mm or more and 10 mm or less, preferably 2 mm or more. mm or less. When the cave is a notch, the depth of the notch may be, for example, 1.5 mm or more and 15 mm or less, and preferably 2 mm or more and 10 mm or less.

<積層膜> <Laminated Film>

積層膜係積層有2個以上之層者。構成積層膜之層可舉例如偏光片、保護膜、光學機能層、接著劑層、黏著劑層、間隔膜、表面保護膜(遮護膜)等。積層膜的層構成之例係顯示於圖4及圖5,但積層膜不限定於此。於圖4之例中,積層膜100係依序具有偏光板10、第1黏著劑層20、光學機能層30、接著劑層40、光學機能層31及第2黏著劑層21,偏光板10係具有偏光片11與保護膜12。如圖5所示,偏光板10可具有偏光片11以及積層於其兩面之保護膜12及13。積層膜較佳為包含偏光板。 Laminated film has more than 2 layers. Examples of the layer constituting the laminated film include a polarizer, a protective film, an optical function layer, an adhesive layer, an adhesive layer, a spacer film, a surface protective film (shielding film), and the like. The example of the layer structure of the laminated film is shown in FIGS. 4 and 5, but the laminated film is not limited to this. In the example of FIG. 4, the laminated film 100 has a polarizing plate 10, a first adhesive layer 20, an optical function layer 30, an adhesive layer 40, an optical function layer 31, and a second adhesive layer 21 in this order, and the polarizing plate 10 The system has a polarizer 11 and a protective film 12. As shown in FIG. 5, the polarizing plate 10 may have a polarizer 11 and protective films 12 and 13 laminated on both sides thereof. The laminated film preferably includes a polarizing plate.

〔偏光板〕 〔Polarizing plate〕

偏光板10通常由偏光片11與保護膜所構成。 The polarizer 10 is usually composed of a polarizer 11 and a protective film.

偏光片11可為具備吸收具有與吸收軸平行的振動面之直線偏光且讓具有與吸收軸正交(與穿透軸平行)的振動面之直線偏光穿透之性質之吸收型的偏光片。偏光片11可舉出吸附有具有吸收異向性之色素之延伸膜或延伸層、塗佈具有吸收異向性之色素並使其硬化而成之層等。具有吸收異向性之色素可舉例如二色性色素。二色性色素具體而言可使用碘或二色性的有機染料。二色性有機染料包含C.I.DIRECT RED39等雙偶氮化合物所構成之二色性直接染料,三偶氮、四偶氮等化合物所構成之二色性直接染料。偏光片11可在其一面或兩面隔著接著劑或黏著劑貼合保護膜而使用作為偏光板10。 The polarizer 11 may be an absorption type polarizer that absorbs linearly polarized light having a vibration surface parallel to the absorption axis and transmits linearly polarized light having a vibration surface orthogonal to the absorption axis (parallel to the penetration axis). Examples of the polarizer 11 include a stretched film or stretched layer on which a pigment having absorption anisotropy is adsorbed, a layer formed by coating and curing a pigment having an absorption anisotropy, and the like. Examples of pigments having absorption anisotropy include dichroic pigments. Specifically, dichroic dyes can be iodine or dichroic organic dyes. Dichroic organic dyes include dichroic direct dyes composed of C.I.DIRECT RED39 and other bisazo compounds, and dichroic direct dyes composed of compounds such as trisazo and tetrasazo. The polarizer 11 can be used as the polarizer 10 by pasting a protective film on one or both surfaces of the polarizer 11 via an adhesive or adhesive.

(屬於延伸膜或延伸層之偏光片) (Polarizer belonging to stretched film or stretched layer)

屬於吸附有具有吸收異向性之色素的延伸膜之偏光片11通常可經由下列步驟製造:將聚乙烯醇系樹脂膜單軸延伸之步驟;將聚乙烯醇系樹脂膜以二色性色素染色,藉此使其吸附二色性色素之步驟;以硼酸水溶液處理吸附有二色性色素之聚乙烯醇系樹脂膜之步驟;以及在藉由硼酸水溶液而處理後進行水洗之步驟。 The polarizer 11, which belongs to the stretched film to which the pigment with absorption anisotropy is adsorbed, can usually be manufactured through the following steps: the step of uniaxially stretching the polyvinyl alcohol-based resin film; dyeing the polyvinyl alcohol-based resin film with dichroic pigments , The step of making it adsorb the dichroic pigment; the step of treating the polyvinyl alcohol resin film adsorbing the dichroic pigment with the boric acid aqueous solution; and the step of washing with water after the treatment with the boric acid aqueous solution.

偏光片11之厚度通常為30μm以下,較佳為18μm以下,更佳為15μm以下。使偏光片11之厚度變薄,有利於偏光板10的薄膜化。偏光片11之厚度通常為1μm以上,例如可為5μm以上。偏光片11之厚度例如可藉由聚乙烯醇系樹脂膜的選定、延伸倍率的調節等來控制。 The thickness of the polarizer 11 is usually 30 μm or less, preferably 18 μm or less, and more preferably 15 μm or less. Making the thickness of the polarizer 11 thinner is beneficial to the thinning of the polarizer 10. The thickness of the polarizer 11 is usually 1 μm or more, for example, 5 μm or more. The thickness of the polarizer 11 can be controlled by, for example, selection of a polyvinyl alcohol-based resin film, adjustment of a stretching ratio, and the like.

聚乙烯醇系樹脂係藉由將聚乙酸乙烯酯系樹脂皂化所得者。聚乙酸乙烯酯系樹脂除了屬於乙酸乙烯酯之均聚物之聚乙酸乙烯酯之外,亦可用乙酸乙烯酯和可與其共聚合之其他的單體的共聚物。可與乙酸乙烯酯共聚合之其他的單體可舉例如不飽和羧酸系化合物、烯烴系化合物、乙烯基醚系化合物、不飽和碸系化合物、具有銨基之(甲基)丙烯醯胺系化合物等。 The polyvinyl alcohol-based resin is obtained by saponifying a polyvinyl acetate-based resin. In addition to polyvinyl acetate, which is a homopolymer of vinyl acetate, polyvinyl acetate resins can also be copolymers of vinyl acetate and other monomers copolymerizable therewith. Other monomers that can be copolymerized with vinyl acetate include, for example, unsaturated carboxylic acid-based compounds, olefin-based compounds, vinyl ether-based compounds, unsaturated turpentine-based compounds, and (meth)acrylamide-based compounds having an ammonium group. Compound etc.

聚乙烯醇系樹脂之皂化度通常為85莫耳%以上100莫耳%以下程度,較佳為98莫耳%以上。聚乙烯醇系樹脂可使用經改質者,例如可使用經醛類改質之聚乙烯醇縮甲醛或聚乙烯醇縮乙醛。聚乙烯醇系樹脂之聚合度通常為1,000以上10,000以下,較佳為1,500以上5,000以下。 The degree of saponification of the polyvinyl alcohol resin is usually 85 mol% or more and 100 mol% or less, preferably 98 mol% or more. The polyvinyl alcohol-based resin can be modified, for example, polyvinyl formal or polyvinyl acetal modified with aldehydes can be used. The degree of polymerization of the polyvinyl alcohol-based resin is usually 1,000 or more and 10,000 or less, preferably 1,500 or more and 5,000 or less.

屬於吸附有具有吸收異向性之色素的延伸層之偏光片,通常可經由下列步驟製造:將包含上述聚乙烯醇系樹脂之塗佈液塗佈在基材膜上之步驟;將所得之積層膜單軸延伸之步驟;將經單軸延伸之積層膜的聚乙烯醇系樹脂層以二色性色素染色,藉此使其吸附二色性色素而成為偏光片之步驟;將吸 附有二色性色素之膜以硼酸水溶液處理之步驟;以及在藉由硼酸水溶液而處理後進行水洗之步驟。 Polarizers that belong to the extended layer adsorbed with pigments with absorption anisotropy can usually be manufactured through the following steps: the step of coating the coating solution containing the above-mentioned polyvinyl alcohol-based resin on the base film; and the resulting laminate The step of uniaxial stretching of the film; the step of dyeing the polyvinyl alcohol resin layer of the uniaxially stretched laminated film with dichroic pigments so that it can adsorb the dichroic pigments and become a polarizer; The step of treating the film with the dichroic pigment with an aqueous solution of boric acid; and the step of washing with water after being treated with the aqueous solution of boric acid.

視需要,可將基材膜從偏光片剝離除去。基材膜的材料及厚度可與後述之保護膜的材料及厚度相同。 If necessary, the base film can be peeled and removed from the polarizer. The material and thickness of the base film may be the same as the material and thickness of the protective film described later.

保護膜12可舉例如熱塑性樹脂膜。 The protective film 12 may be, for example, a thermoplastic resin film.

熱塑性樹脂膜可舉例如環狀聚烯烴系樹脂膜;三乙醯纖維素、二乙醯纖維素等樹脂所構成之乙酸纖維素系樹脂膜;聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚對苯二甲酸丁二酯等樹脂所構成之聚酯系樹脂膜;聚碳酸酯系樹脂膜;(甲基)丙烯酸系樹脂膜;聚丙烯系樹脂膜等本領域中公知的膜。 Examples of thermoplastic resin films include cyclic polyolefin resin films; cellulose acetate resin films composed of resins such as triacetyl cellulose and diacetyl cellulose; polyethylene terephthalate, polyethylene naphthalate Polyester resin films composed of resins such as ethylene glycol and polybutylene terephthalate; polycarbonate resin films; (meth)acrylic resin films; polypropylene resin films, etc., which are well known in the art membrane.

從偏光板的薄型化的觀點來看,保護膜12之厚度較佳為薄者,但太薄時有強度低落、加工性差的傾向,故較佳為5μm以上150μm以下,更佳為5μm以上100μm以下,再佳為10μm以上50μm以下。 From the viewpoint of thinning of the polarizing plate, the thickness of the protective film 12 is preferably thinner, but if it is too thin, the strength tends to be low and the workability tends to be poor. Therefore, it is preferably 5 μm or more and 150 μm or less, more preferably 5 μm or more and 100 μm. Hereinafter, it is more preferably 10 μm or more and 50 μm or less.

保護膜12例如可為兼具有相位差膜及增亮膜等的光學機能的保護膜。例如,可為藉由將上述材料所構成之透明樹脂膜延伸(單軸延伸或雙軸延伸等)、或於該膜上形成液晶層等而賦予任意的相位差值之相位差膜。 The protective film 12 may be, for example, a protective film having both optical functions such as a retardation film and a brightness enhancement film. For example, it may be a retardation film to which an arbitrary retardation value is given by stretching a transparent resin film composed of the above-mentioned materials (uniaxial stretching, biaxial stretching, etc.), or forming a liquid crystal layer on the film.

將積層膜100配置於圖像顯示裝置的情況,積層膜100能夠以使保護膜12成為圖像顯示裝置側的方式貼合於圖像顯示裝置。 When the laminated film 100 is arranged in an image display device, the laminated film 100 can be bonded to the image display device so that the protective film 12 is on the side of the image display device.

保護膜12上亦可形成硬塗層。硬塗層可形成在保護膜的一面,亦可形成在兩面。藉由設有硬塗層,可成為讓硬度及耐刮性提升之保護膜12。硬塗層例如為紫外線硬化型樹脂之硬化層。紫外線硬化型樹脂可舉例如丙烯酸系樹脂、聚矽氧系樹脂、聚酯系樹脂、胺酯系樹脂、醯胺系樹脂、環氧系樹脂等。為了使強度提升,硬塗層亦可含有添加劑。添加劑並無限定,可舉出無機 系微粒子、有機系微粒子、或此等之混合物。保護膜13係引用保護膜12之記載。 A hard coat layer may also be formed on the protective film 12. The hard coat layer can be formed on one side of the protective film or on both sides. By providing a hard coating, it can become a protective film 12 that improves hardness and scratch resistance. The hard coat layer is, for example, a cured layer of ultraviolet curable resin. Examples of ultraviolet curable resins include acrylic resins, silicone resins, polyester resins, urethane resins, amide resins, and epoxy resins. In order to increase the strength, the hard coat layer may also contain additives. The additives are not limited, but inorganic It is fine particles, organic fine particles, or a mixture of these. The protective film 13 refers to the description of the protective film 12.

(塗佈具有吸收異向性之色素並使其硬化而成之偏光片) (Polarizer made by coating and hardening pigment with absorption anisotropy)

塗佈具有吸收異向性之色素並使其硬化而成之偏光片11可舉出於基材膜塗佈包含具有液晶性之聚合性的二色性色素之組成物、或包含二色性色素與聚合性液晶之組成物並使其硬化而得之層等包含聚合性液晶化合物之硬化物的偏光片。 The polarizer 11 formed by coating and hardening a pigment with absorption anisotropy can be exemplified by coating a composition containing a polymerizable dichroic pigment with liquid crystallinity on a base film, or containing a dichroic pigment A polarizer containing a cured product of a polymerizable liquid crystal compound, such as a layer obtained by curing a composition with a polymerizable liquid crystal.

於積層膜中,視需要,可將基材膜從偏光片剝離除去。基材膜的材料及厚度可為與上述之保護膜的材料及厚度相同。 In the laminated film, if necessary, the base film can be peeled and removed from the polarizer. The material and thickness of the base film can be the same as the material and thickness of the above-mentioned protective film.

於積層膜中,塗佈具有吸收異向性之色素並使其硬化而成之偏光片11亦可於其單面或兩面貼合上述之保護膜。 In the laminated film, the polarizer 11 formed by coating and hardening a pigment with absorption anisotropy can also be laminated with the above-mentioned protective film on one or both sides.

塗佈具有吸收異向性之色素並使其硬化而成之偏光片11之厚度通常為10μm以下,較佳為0.5μm以上8μm以下,更佳為1μm以上5μm以下。 The thickness of the polarizer 11 formed by coating and hardening a pigment having absorption anisotropy is generally 10 μm or less, preferably 0.5 μm or more and 8 μm or less, and more preferably 1 μm or more and 5 μm or less.

〔第1黏著劑層〕 〔1st Adhesive Layer〕

第1黏著劑層20係介入而存在於偏光板10與光學機能層30之間並將此等接合之層。第1黏著劑層20可由以(甲基)丙烯酸系樹脂、橡膠系樹脂、胺酯系樹脂、酯系樹脂、聚矽氧系樹脂、聚乙烯基醚系樹脂等作為主成分之黏著劑組成物所構成。其中,適合為以透明性、耐候性、耐熱性等優異之(甲基)丙烯酸系樹脂作為基質聚合物之黏著劑組成物。黏著劑組成物可為活性能量線硬化型或熱硬化型者。 The first adhesive layer 20 is a layer that intervenes and exists between the polarizing plate 10 and the optical function layer 30 and joins these layers. The first adhesive layer 20 may be an adhesive composition with (meth)acrylic resin, rubber resin, urethane resin, ester resin, silicone resin, polyvinyl ether resin, etc. as main components. Constituted. Among them, it is suitable as an adhesive composition using a (meth)acrylic resin excellent in transparency, weather resistance, heat resistance, etc., as a matrix polymer. The adhesive composition can be an active energy ray hardening type or a heat hardening type.

黏著劑組成物中所使用之(甲基)丙烯酸系樹脂(基質聚合物)適合使用(甲基)丙烯酸丁酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸異辛酯、(甲基)丙烯酸2-乙基己酯等(甲基)丙烯酸酯的1種或2種以上作為單體之聚合物或共聚物。基質聚合物較佳為使極性單體共聚合。極性單體可舉出(甲基)丙烯酸化合物、(甲基)丙烯酸2-羥基丙酯化合物、(甲基)丙烯酸羥基乙酯化合物、(甲基)丙烯醯胺化合物、(甲基)丙烯酸N,N-二甲基胺基乙酯化合物、(甲基)丙烯酸縮水甘油酯化合物等具有羧基、羥基、醯胺基、胺基、環氧基等之單體。 For the (meth)acrylic resin (matrix polymer) used in the adhesive composition, butyl (meth)acrylate, ethyl (meth)acrylate, isooctyl (meth)acrylate, (methyl) ) Polymers or copolymers in which one or more of (meth)acrylates such as 2-ethylhexyl acrylate are used as monomers. The matrix polymer preferably copolymerizes polar monomers. Examples of polar monomers include (meth)acrylic acid compounds, 2-hydroxypropyl (meth)acrylate compounds, hydroxyethyl (meth)acrylate compounds, (meth)acrylamide compounds, and (meth)acrylic acid N , N-dimethylamino ethyl compounds, glycidyl (meth)acrylate compounds and other monomers having carboxyl groups, hydroxyl groups, amide groups, amine groups, epoxy groups, etc.

黏著劑組成物可僅包含上述基質聚合物,但通常進一步含有交聯劑。交聯劑例示如:會與羧基之間形成羧酸金屬鹽之2價以上的金屬離子;會與羧基之間形成醯胺鍵之多胺化合物;會與羧基之間形成酯鍵之聚環氧化合物或多元醇;會與羧基之間形成醯胺鍵之聚異氰酸酯化合物。其中,較佳為聚異氰酸酯化合物。 The adhesive composition may only contain the above-mentioned matrix polymer, but usually further contains a crosslinking agent. Examples of crosslinking agents are: metal ions with more than two valences that form carboxylic acid metal salts with carboxyl groups; polyamine compounds that form amide bonds with carboxyl groups; and polyepoxides that form ester bonds with carboxyl groups Compounds or polyols; polyisocyanate compounds that form amide bonds with carboxyl groups. Among them, polyisocyanate compounds are preferred.

第1黏著劑層20的形成,可藉由下列方式進行:使黏著劑組成物溶解或分散於甲苯或乙酸乙酯等有機溶劑中而調製黏著劑液,將該黏著劑液直接塗佈於積層膜的對象面而形成黏著劑層的方式;或先在施有離型處理的間隔膜上形成片狀的黏著劑層,並將此轉移到偏光板的對象面的方式等。 The formation of the first adhesive layer 20 can be performed by the following method: the adhesive composition is dissolved or dispersed in an organic solvent such as toluene or ethyl acetate to prepare an adhesive liquid, and the adhesive liquid is directly applied to the build-up layer A method of forming an adhesive layer on the target surface of the film; or a method of first forming a sheet-shaped adhesive layer on the spacer film with a release process and transferring this to the target surface of the polarizing plate.

第1黏著劑層20的厚度係因應接著力等決定,例如可為1μm以上50μm以下的範圍,較佳為2μm以上40μm以下,更佳為3μm以上30μm以下,再佳為3μm以上25μm以下。 The thickness of the first adhesive layer 20 is determined in accordance with the adhesive force and the like. For example, it may be in the range of 1 μm or more and 50 μm or less, preferably 2 μm or more and 40 μm or less, more preferably 3 μm or more and 30 μm or less, and still more preferably 3 μm or more and 25 μm or less.

積層膜100可含有上述的間隔膜。間隔膜可為由聚乙烯等聚乙烯系樹脂、聚丙烯等聚丙烯系樹脂、聚對苯二甲酸乙二酯等聚酯系樹脂等所構成之膜。其中,較佳為聚對苯二甲酸乙二酯的延伸膜。 The laminated film 100 may contain the aforementioned spacer film. The spacer film may be a film composed of a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, and a polyester resin such as polyethylene terephthalate. Among them, a stretched film of polyethylene terephthalate is preferred.

第1黏著劑層20可包含玻璃纖維、玻璃珠、樹脂珠、金屬粉或其他的無機粉末所構成之填充劑;顏料;著色劑;抗氧化劑;紫外線吸收劑;抗靜電劑等作為任意成分。 The first adhesive layer 20 may include fillers composed of glass fibers, glass beads, resin beads, metal powder or other inorganic powders; pigments; colorants; antioxidants; ultraviolet absorbers; antistatic agents, etc., as optional components.

抗靜電劑可舉出離子性化合物、導電性微粒子、導電性高分子等,較佳為使用離子性化合物。 Examples of the antistatic agent include ionic compounds, conductive fine particles, and conductive polymers, and ionic compounds are preferably used.

構成離子性化合物之陽離子成分可為無機陽離子,亦可為有機陽離子。 The cationic component constituting the ionic compound may be an inorganic cation or an organic cation.

有機陽離子可舉出吡啶鎓陽離子、咪唑鎓陽離子、銨陽離子、鋶陽離子、鏻陽離子、哌啶鎓陽離子、吡咯啶鎓陽離子等,無機陽離子可舉出鋰離子、鉀離子等。 Examples of organic cations include pyridinium cations, imidazolium cations, ammonium cations, sulfonium cations, phosphonium cations, piperidinium cations, and pyrrolidinium cations. Examples of inorganic cations include lithium ion and potassium ion.

另一方面,構成離子性化合物之陰離子成分可為無機陰離子,亦可為有機陰離子,但從提供抗靜電性能優異之離子性化合物的觀點來看,較佳為包含氟原子之陰離子成分。包含氟原子之陰離子成分可舉出六氟膦酸鹽陰離子〔(PF6 -)〕、雙(三氟甲烷磺醯基)亞胺陰離子〔(CF3SO2)2N-〕陰離子、雙(氟磺醯基)亞胺陰離子〔(FSO2)2N-〕陰離子等。 On the other hand, the anion component constituting the ionic compound may be an inorganic anion or an organic anion, but from the viewpoint of providing an ionic compound with excellent antistatic properties, an anion component containing a fluorine atom is preferred. The anionic component containing a fluorine atom include hexafluorophosphate [phosphonate anion (PF 6 -)], bis (trifluoromethane sulfonic acyl) imide anion [(CF 3 SO 2) 2 N - ] anion, bis ( sulfo acyl-fluoro) imide anion [(FSO 2) 2 N -] anion.

〔光學機能層〕 〔Optical Function Layer〕

光學機能層30、31可為用以賦予所期望的光學機能之偏光片11以外的其他的具有光學機能之層。光學機能層的合適的一例為相位差層。相位差層可舉例如賦予λ/2之相位差之層、賦予λ/4之相位差之層(正A板)及正C板等。光學機能層可含有配向層及基材,亦可各別具有2個以上的液晶層、配向層及基材。積層膜100具有偏光層與賦予λ/4之相位差之膜的情況,積層膜100可為圓偏光板。 The optical function layers 30 and 31 may be layers having optical functions other than the polarizer 11 for imparting desired optical functions. A suitable example of the optical function layer is a retardation layer. Examples of the retardation layer include a layer giving a phase difference of λ/2, a layer giving a phase difference of λ/4 (positive A plate), a positive C plate, and the like. The optical function layer may include an alignment layer and a substrate, or may have two or more liquid crystal layers, alignment layers, and substrates each. When the laminated film 100 has a polarizing layer and a film providing a phase difference of λ/4, the laminated film 100 may be a circular polarizing plate.

保護膜12可兼任相位差層,但亦可除了該等膜以外另外積層相位差層。後者的情況,相位差層可隔著黏著劑層或接著劑層而積層於偏光板10。 The protective film 12 may also serve as a retardation layer, but a retardation layer may be laminated in addition to these films. In the latter case, the retardation layer may be laminated on the polarizing plate 10 via an adhesive layer or an adhesive layer.

相位差層可舉出由具有透光性之熱塑性樹脂之延伸膜所構成之雙折射性膜、形成在基材膜上之上述液晶層等。 Examples of the retardation layer include a birefringent film composed of a stretched film of a thermoplastic resin having translucency, the above-mentioned liquid crystal layer formed on a base film, and the like.

基材膜通常為由熱塑性樹脂所構成之膜,熱塑性樹脂之一例為三乙醯纖維素等纖維素酯系樹脂。 The base film is usually a film made of a thermoplastic resin, and an example of the thermoplastic resin is a cellulose ester resin such as triacetyl cellulose.

積層膜100中可含有的其他的光學機能性膜(光學構件)之例有集光板、增亮膜、反射層(反射膜)、半穿透反射層(半穿透反射膜)、光擴散層(光擴散膜)等。 Examples of other optically functional films (optical members) that can be contained in the laminated film 100 include a light-collecting plate, a brightness enhancement film, a reflective layer (reflective film), a semi-transmissive reflective layer (semi-transmissive reflective film), and a light diffusion layer. (Light diffusion film) and so on.

〔接著劑層〕 〔Adhesive layer〕

光學機能層30與光學機能層31可隔著黏著劑層或接著劑層40而接合。接著劑層40係由水中溶解或分散有硬化性的樹脂成分之公知的水系組成物(包含水系接著劑)及含有活性能量線硬化性化合物之公知的活性能量線硬化性組成物(包含活性能量線硬化性接著劑)等所構成。 The optical function layer 30 and the optical function layer 31 may be joined via an adhesive layer or an adhesive layer 40. Adhesive layer 40 is composed of a known water-based composition (including water-based adhesive) in which a curable resin component is dissolved or dispersed in water and a known active energy ray curable composition (including active energy ray curable compound). Linear hardening adhesive) and so on.

水系組成物中所含有之樹脂成分可舉出聚乙烯醇系樹脂或胺酯樹脂等。 Examples of the resin component contained in the water-based composition include polyvinyl alcohol-based resins, urethane resins, and the like.

為了提升密著性或接著性,包含聚乙烯醇系樹脂之水系組成物可進一步含有多元醛、三聚氰胺系化合物、氧化鋯化合物、鋅化合物、乙二醛、乙二醛衍生物、水溶性環氧樹脂等硬化性成分或交聯劑。 In order to improve adhesion or adhesion, the water-based composition containing polyvinyl alcohol-based resin may further contain polyaldehyde, melamine-based compound, zirconium oxide compound, zinc compound, glyoxal, glyoxal derivative, water-soluble epoxy Curable components such as resins or crosslinking agents.

包含胺酯樹脂之水系組成物可舉出包含聚酯系離子聚合物型胺酯樹脂與具有縮水甘油基氧基的化合物之水系組成物。聚酯系離子聚合物型胺酯樹脂係指具有聚酯骨架之胺酯樹脂中導入有少量的離子性成分(親水成分)者。 The water-based composition containing the urethane resin includes an aqueous composition containing a polyester-based ionomer type urethane resin and a compound having a glycidyloxy group. Polyester ionomer type urethane resin refers to a urethane resin having a polyester skeleton with a small amount of ionic components (hydrophilic components) introduced.

活性能量線硬化性組成物係藉由紫外線、可見光、電子射線、X射線等活性能量線的照射而進行硬化之組成物。 The active energy ray curable composition is a composition that is cured by irradiation of active energy rays such as ultraviolet rays, visible light, electron beams, and X-rays.

活性能量線硬化性組成物可為含有藉由陽離子聚合而進行硬化之環氧系化合物作為硬化性成分之組成物,較佳為含有該環氧系化合物作為硬化性成分之紫外線硬化性組成物。環氧系化合物係意指在分子內平均具有1個以上,較佳為2個以上之環氧基之化合物。環氧系化合物可僅使用1種,亦可併用2種以上。 The active energy ray curable composition may be a composition containing an epoxy-based compound that is cured by cationic polymerization as a curable component, and is preferably an ultraviolet-curable composition containing the epoxy-based compound as a curable component. The epoxy-based compound means a compound having one or more epoxy groups, preferably two or more epoxy groups on average in the molecule. The epoxy compound may use only 1 type, and may use 2 or more types together.

環氧系化合物可舉出藉由使芳香族多元醇的芳香環進行氫化反應而得之脂環式多元醇、與表氯醇進行反應所得之氫化環氧系化合物(具有脂環式環之多元醇的縮水甘油基醚);脂肪族多元醇或其伸烷基氧化物加成物的聚縮水甘油基醚等脂肪族環氧系化合物;屬於分子內有1個以上與脂環式環鍵結之環氧基之環氧系化合物的脂環式環氧系化合物等。 Examples of epoxy compounds include alicyclic polyols obtained by hydrogenating the aromatic ring of aromatic polyols, and hydrogenated epoxy compounds obtained by reacting with epichlorohydrin (polybasic polyols having alicyclic rings). Glycidyl ether of alcohol); aliphatic epoxy compounds such as polyglycidyl ether of aliphatic polyhydric alcohol or its alkylene oxide adduct; belonging to one or more alicyclic ring bonds in the molecule The epoxy-based epoxy compounds, alicyclic epoxy compounds, etc.

活性能量線硬化性組成物可含有自由基聚合性的(甲基)丙烯酸系化合物作為硬化性成分,以取代上述環氧系化合物;或可同時含有上述環氧系化合物與自由基聚合性的(甲基)丙烯酸系化合物作為硬化性成分。(甲基)丙烯酸系化合物可舉出分子內具有1個以上之(甲基)丙烯醯基氧基之(甲基)丙烯酸酯單體;使兩種以上的含官能基之化合物反應而得之分子內至少具有2個(甲基)丙烯醯基氧基之(甲基)丙烯酸酯寡聚物等含(甲基)丙烯醯基氧基之化合物。 The active energy ray curable composition may contain a radical polymerizable (meth)acrylic compound as a curable component instead of the epoxy compound; or may contain both the epoxy compound and the radical polymerizable ( A meth)acrylic compound is used as a curable component. The (meth)acrylic compound includes a (meth)acrylate monomer having one or more (meth)acryloxy groups in the molecule; it is obtained by reacting two or more functional group-containing compounds Compounds containing (meth)acryloxy groups such as (meth)acrylate oligomers having at least two (meth)acryloxy groups in the molecule.

活性能量線硬化性組成物含有藉由陽離子聚合而進行硬化之環氧系化合物作為硬化性成分的情況,較佳為含有光陽離子聚合起始劑。光陽離子聚合起始劑可舉出芳香族重氮鹽;芳香族錪鹽或芳香族鋶鹽等鎓鹽;鐵-丙二烯錯合物等。 When the active energy ray curable composition contains an epoxy-based compound that is cured by cationic polymerization as a curable component, it preferably contains a photocationic polymerization initiator. The photocationic polymerization initiator includes aromatic diazonium salts; onium salts such as aromatic iodonium salts and aromatic sulfonium salts; iron-allene complexes and the like.

活性能量線硬化性組成物包含(甲基)丙烯酸系化合物等自由基聚合性成分的情況,較佳為含有光自由基聚合起始劑。光自由基聚合起始劑可舉出苯乙酮系起始劑、二苯基酮系起始劑、安息香醚系起始劑、硫雜蒽酮系起始劑、氧雜蒽酮、茀酮、樟腦醌、苯甲醛、蔥醌等。 When the active energy ray-curable composition contains a radical polymerizable component such as a (meth)acrylic compound, it preferably contains a photo-radical polymerization initiator. The photo-radical polymerization initiators include acetophenone-based initiators, benzophenone-based initiators, benzoin ether-based initiators, thioxanthone-based initiators, xanthones, and quinones. , Camphorquinone, benzaldehyde, onionquinone, etc.

光學機能層30與光學機能層31可隔著黏著劑層而接合。在此使用之黏著劑層可引用第1黏著劑層的記載。 The optical function layer 30 and the optical function layer 31 may be joined via an adhesive layer. For the adhesive layer used here, the description of the first adhesive layer can be cited.

〔第2黏著劑層〕 [Second Adhesive Layer]

積層膜100在光學機能層31側具有第2黏著劑層21。第2黏著劑層21可將積層膜100與圖像顯示元件或其他的光學構件貼合。 The laminated film 100 has the second adhesive layer 21 on the optical function layer 31 side. The second adhesive layer 21 can bond the laminated film 100 to an image display element or other optical members.

第2黏著劑層21中所使用之黏著劑、黏著劑組成物、厚度及製作方法係引用第1黏著劑層20的項目中所述的說明。第2黏著劑層21中所使用之間隔膜與可含有之任意成分亦引用第1黏著劑層20的說明。 The adhesive, adhesive composition, thickness, and production method used in the second adhesive layer 21 refer to the descriptions described in the item of the first adhesive layer 20. The separator used in the second adhesive layer 21 and optional components that may be contained also refer to the description of the first adhesive layer 20.

〔表面保護膜(遮護膜)〕 〔Surface protection film (shielding film)〕

積層膜100可包含用以保護其表面(典型而言為偏光板的保護膜的表面)之表面保護膜。表面保護膜例如在圖像顯示元件或其他的光學構件貼合偏光板後,連同其所具有之黏著劑層一起被剝離除去。 The laminated film 100 may include a surface protective film for protecting the surface thereof (typically, the surface of the protective film of the polarizing plate). The surface protection film is peeled off and removed, for example, after the image display element or other optical member is bonded to the polarizing plate, together with the adhesive layer it has.

表面保護膜例如藉由基材膜與積層於其上之黏著劑層所構成。黏著劑層係引用上述之記載。 The surface protection film is composed of, for example, a base film and an adhesive layer laminated thereon. The adhesive layer refers to the above-mentioned description.

構成基材膜之樹脂例如可為聚乙烯等聚乙烯系樹脂;聚丙烯等聚丙烯系樹脂;聚對苯二甲酸乙二酯或聚萘二甲酸乙二酯等聚酯系樹脂;聚碳酸酯系樹脂;等的熱塑性樹脂。較佳為聚對苯二甲酸乙二酯等聚酯系樹脂。 The resin constituting the base film may be, for example, polyethylene resins such as polyethylene; polypropylene resins such as polypropylene; polyester resins such as polyethylene terephthalate or polyethylene naphthalate; and polycarbonate. Department of resin; and other thermoplastic resins. It is preferably a polyester resin such as polyethylene terephthalate.

表面保護膜的厚度並無特別限定,但較佳設為20μm以上200μm以下的範圍。基材膜的厚度為20μm以上時,有變得易於對積層膜100賦予強度之傾向。 The thickness of the surface protection film is not particularly limited, but is preferably set to a range of 20 μm or more and 200 μm or less. When the thickness of the base film is 20 μm or more, it tends to be easier to impart strength to the laminated film 100.

<經切削加工之積層膜的製造方法> <Manufacturing Method of Laminated Film by Cutting Process>

本發明之經切削加工之積層膜的製造方法(以下,亦稱為本發明的製造方法)包含第1切削步驟,係從相對於積層膜的主面為垂直的方向觀看,進行使切削工具螺線狀地相對移動的操作,藉此切削前述積層膜。積層膜的主面係指與積層膜的厚度方向垂直的面。 The manufacturing method of the cut-processed laminated film of the present invention (hereinafter, also referred to as the manufacturing method of the present invention) includes a first cutting step, which is viewed from a direction perpendicular to the main surface of the laminated film, and the cutting tool is screwed. The operation of linear relative movement cuts the aforementioned laminated film. The main surface of the laminate film refers to a surface perpendicular to the thickness direction of the laminate film.

〔切削工具〕 〔Cutting Tools〕

本發明的製造方法中所使用之切削工具若為可切削加工積層膜者則並無特別限定,可舉例如具有可旋轉的柄與外周刃,且外周刃與柄成為一體之切削工具。亦可使用具有可旋轉的柄、外周刃及底刃,且外周刃及底刃各別與柄成為一體之切削工具。外周刃與底刃可成為一體。這樣的切削工具可舉出端銑刀(endmill)等。 The cutting tool used in the manufacturing method of the present invention is not particularly limited as long as it is capable of cutting a laminated film. For example, a cutting tool having a rotatable shank and a peripheral edge, and the peripheral edge and the shank are integrated. It is also possible to use a cutting tool with a rotatable shank, a peripheral edge and a bottom edge, and the peripheral edge and the bottom edge are respectively integrated with the shank. The outer edge and the bottom edge can be integrated. Examples of such cutting tools include end mills and the like.

切削工具的外周刃及底刃的數量並無特別限定,例如可為1片以上6片以下,亦可為2片、3片或4片。刃數少時有易於排出切削屑之傾向,但切削工具的剛性容易減低。 The number of the peripheral edge and the bottom edge of the cutting tool is not particularly limited, and for example, it may be one or more and six or less, or two, three, or four. When the number of blades is small, there is a tendency to easily discharge the cutting chips, but the rigidity of the cutting tool is likely to decrease.

切削工具的外周刃及底刃的傾角(rake angle)通常為0°以上未達20°,亦可為3°以上未達15°。傾角太大時刃有變得容易缺損的傾向。 The rake angle of the peripheral edge and the bottom edge of the cutting tool is usually 0° or more and less than 20°, and may also be 3° or more and less than 15°. When the angle of inclination is too large, the blade tends to become easily chipped.

切削工具的外周刃及底刃的餘隙角(clearance angle)例如為比0°大且未達20°,亦可設為3°以上15°以下。餘隙角為0°時積層膜與刃會磨擦,餘隙角太大時刃有變得容易缺損的傾向。 The clearance angle (clearance angle) of the outer peripheral edge and the bottom edge of the cutting tool is, for example, greater than 0° and less than 20°, and may be 3° or more and 15° or less. When the clearance angle is 0°, the laminated film will rub against the blade, and when the clearance angle is too large, the blade tends to be easily chipped.

外周刃亦可沿著柄扭轉。切削工具的外周刃的扭轉角(torsion angle)可為-75°以上75°以下,亦可為-65°以上65°以下。扭轉角過大時有難以排出切削屑的傾向。 The peripheral edge can also be twisted along the shank. The torsion angle of the peripheral edge of the cutting tool may be -75° or more and 75° or less, or -65° or more and 65° or less. When the torsion angle is too large, it tends to be difficult to discharge chips.

切削工具的外周刃較佳為構成切削工具的旋轉部分的最大徑。切削工具的外周刃的直徑(與柄正交之方向的最大徑)例如為1.0mm以上10mm以下,較佳為1.5mm以上8mm以下。直徑過小時端銑刀有容易折損的傾向,過大時細微的切削加工會變得困難。 The outer peripheral edge of the cutting tool is preferably the largest diameter constituting the rotating part of the cutting tool. The diameter (the maximum diameter in the direction orthogonal to the shank) of the outer peripheral edge of the cutting tool is, for example, 1.0 mm or more and 10 mm or less, preferably 1.5 mm or more and 8 mm or less. If the diameter is too small, the end mill tends to break easily. If the diameter is too large, it will be difficult to perform fine cutting.

切削工具的進給速度通常為50mm/分鐘以上5000mm/分鐘以下,可為100mm/分鐘以上,較佳為200mm/分鐘以上3000mm/分鐘以下。 The feed rate of the cutting tool is usually 50 mm/min or more and 5000 mm/min or less, and may be 100 mm/min or more, preferably 200 mm/min or more and 3000 mm/min or less.

此外,端銑刀的外周刃及底刃的旋轉速度可為5000rpm以上100000rpm以下,可為10000rpm以上80000rpm以下,亦可為30000rpm以上60000rpm以下。旋轉速度變慢時有變得容易產生積層膜的層間剝離之傾向,旋轉速度過快時則有發熱並對積層膜造成傷害的可能性。 In addition, the rotation speed of the peripheral edge and the bottom edge of the end mill can be from 5000 rpm to 100,000 rpm, from 10,000 rpm to 80,000 rpm, or from 30,000 rpm to 60,000 rpm. When the rotation speed is slow, the interlayer peeling of the laminated film tends to occur easily, and when the rotation speed is too fast, it may generate heat and cause damage to the laminated film.

〔第1切削步驟〕 [The first cutting step]

第1切削步驟中,例如圖2之(A)所示般,從相對於積層膜的主面為垂直的方向觀看,進行使切削工具螺線狀地相對移動的操作,藉此切削積層膜。 In the first cutting step, for example, as shown in FIG. 2(A), when viewed from a direction perpendicular to the main surface of the laminated film, an operation of relatively moving the cutting tool in a spiral shape is performed to cut the laminated film.

螺線係指一邊向外側遠離一邊旋轉的曲線。螺線可舉例如:螺線的間隔(亦即螺線的螺距)為等間隔的螺線(阿基米德螺線(Archimedes spiral)等)、螺線的螺距愈向外側變得愈寬的螺線(對數螺線(logarithmic spiral)等)、螺線的螺距愈向外側變得愈窄的螺線(拋物螺線(parabolic spiral)等)等。螺線的螺距為等間隔的螺線可為半徑以每隔一圈以下的一定間隔(例如半圈、1/4圈等)變大的螺線。螺線的一圈中的一部分可有螺線的螺距為0,亦即並未從已經切削之部分 重新切削的部分。使切削工具螺線狀地相對移動的操作,係指於已經切削之切削部分的至少一部分中,使切削工具在僅螺線的螺距寬度之程度的外側相對移動的操作。藉此,於已經切削之切削部分的至少一部分中,只切削螺線的螺距寬度之程度的外側的積層膜。 A spiral refers to a curve that rotates while moving away from the outside. Examples of spirals include: spirals in which the interval of the spirals (that is, the pitch of the spirals) is equally spaced (Archimedes spiral, etc.), and the pitch of the spirals becomes wider toward the outside. A spiral (logarithmic spiral, etc.), a spiral whose pitch becomes narrower toward the outside (parabolic spiral, etc.), etc. A spiral whose pitch is equally spaced may be a spiral whose radius increases at a certain interval (for example, half turn, quarter turn, etc.) below every other turn. A part of the spiral can have a spiral pitch of 0, that is, it has not been cut from the part Recut part. The operation of relatively moving the cutting tool in a helical shape refers to an operation of relatively moving the cutting tool to the outside of only the pitch width of the spiral in at least a part of the cut portion that has been cut. Thereby, in at least a part of the cut portion that has been cut, only the laminated film on the outer side of the pitch width of the spiral is cut.

於第1切削步驟中的螺線若為一圈以上即可,較佳為進行積層膜的切削時至少最外周因螺線狀之相對移動而被切削。 The spiral in the first cutting step may be one or more turns, and it is preferable that at least the outermost periphery is cut due to spiral relative movement when cutting the laminated film.

依據本發明,從相對於積層膜的主面為垂直的方向觀看,進行使切削工具螺線狀地相對移動的操作來切削積層膜之情況,與藉由直線與圓周運動的組合來相對移動而切削的情況(圖2之(B)等)相比,可抑制積層膜的層間剝離。例如積層膜具有相位差膜與接著劑層或黏著劑層的情況,可抑制相位差膜與接著劑層或黏著劑層之間的層間剝離。進一步地,若是螺線狀地相對移動而進行切削,則可縮短形成目的大小的切削部分為止所要花費的時間。 According to the present invention, when viewed from a direction perpendicular to the main surface of the laminated film, the operation of relatively moving the cutting tool in a spiral shape to cut the laminated film is different from the relative movement by a combination of linear and circular motions. Compared with the case of cutting (Fig. 2(B), etc.), the interlayer peeling of the laminated film can be suppressed. For example, when the laminated film has a retardation film and an adhesive layer or an adhesive layer, peeling between a retardation film and an adhesive layer or an adhesive layer can be suppressed. Furthermore, if cutting is performed by relative movement in a spiral shape, the time required to form a cut portion of a target size can be shortened.

以往,切削積層膜時,容易產生如圖3所示之層間剝離,此外,容易產生缺糊、破裂等缺陷。在此,缺糊係指於積層膜中的黏著劑層中,欠缺靠近切削面之部分的黏著劑的狀態。破裂係指在積層膜的層產生的龜裂,且容易在偏光板或光學機能層產生。層間剝離、缺糊、破裂等缺陷的種類及產生缺陷的層可藉由光學顯微鏡下的觀察來判別。 In the past, when cutting a laminated film, the interlayer peeling as shown in FIG. 3 was easy to occur, and defects such as lack of paste and cracking were easy to occur. Here, the lack of paste refers to a state where the adhesive layer near the cutting surface is lacking in the adhesive layer in the laminated film. Cracks refer to cracks that occur in the layer of the laminated film, and are likely to occur in the polarizing plate or the optical function layer. The types of defects such as delamination, lack of paste, and cracking, and the layer in which the defect occurs can be distinguished by observation under an optical microscope.

藉由第1切削步驟而形成之切削部分具有曲線部。將積層膜切削為圓形的情況,例如若是一邊增大從中心開始的半徑一邊使切削工具螺線狀地相對移動後,直到與已經切削之部分相接為止不改變半徑而維持最大半徑使切削工具圓形地相對移動,則經切削之部分會變成圓形。例如若是以畫出每半圈半徑就變大的圓的方式螺線狀地相對移動切削工具的情況,以最後的半圈不改 變半徑地畫圓的方式使切削工具相對移動,則可於積層膜形成圓形的切削部分。 The cutting portion formed by the first cutting step has a curved portion. When cutting the laminated film into a circular shape, for example, if the cutting tool is relatively moved spirally while increasing the radius from the center, the radius is not changed until it comes into contact with the cut part, and the maximum radius is maintained for cutting. The relative movement of the tool circularly, the cut part will become circular. For example, if the cutting tool is relatively moved spirally in such a way that the radius of each half circle becomes larger, the last half circle does not change. The cutting tool is relatively moved by drawing a circle with a variable radius, and a circular cutting part can be formed in the laminated film.

切削工具螺線狀地相對移動的軌跡與積層膜的端面相接時,切削部分可設為U字形狀、Omega形狀等的缺口部。螺線的螺距於1圈中可具有寬的部分以及窄的部分,藉由這樣的反覆,亦可將切削部分設為圓形以外的形狀(例如楕圓等)。 When the trajectory of the relative movement of the cutting tool in a spiral shape is in contact with the end surface of the laminated film, the cut portion can be a U-shaped, Omega-shaped cutout. The pitch of the spiral may have a wide part and a narrow part in one turn, and by such repetition, the cut part may be formed into a shape other than a circle (for example, an ellipse circle, etc.).

於第1切削步驟中,較佳為藉由切削工具的外周刃與積層膜相接來切削積層膜。切削工具具有可旋轉的柄的情況,該可旋轉的柄相對於積層膜的主面可為垂直,亦可為傾斜,較佳為以相對於積層膜的主面為垂直的狀態進行使切削工具相對移動的操作。藉此,經切削之面相對於積層膜的主面成為垂直。 In the first cutting step, it is preferable to cut the laminated film by contacting the outer peripheral edge of the cutting tool with the laminated film. When the cutting tool has a rotatable shank, the rotatable shank may be vertical or inclined with respect to the main surface of the laminated film. It is preferable to make the cutting tool perpendicular to the main surface of the laminated film. Relative movement operation. Thereby, the cut surface becomes perpendicular to the main surface of the laminated film.

於第1切削步驟中,使切削工具相對移動的操作,通常在相對於積層膜的主面為平行的方向進行。該操作亦可進一步伴隨相對於積層膜的主面為垂直的移動。伴隨相對於積層膜的主面為垂直的移動的情況,可舉例如使切削工具螺旋狀地相對移動的操作。使切削工具螺旋狀相對移動來進行的切削,亦可兼任後述之貫通孔的形成。 In the first cutting step, the operation of relatively moving the cutting tool is usually performed in a direction parallel to the main surface of the laminated film. This operation may be further accompanied by a vertical movement with respect to the main surface of the laminated film. When the movement is perpendicular to the main surface of the laminated film, for example, an operation of relatively moving the cutting tool in a spiral shape can be mentioned. The cutting performed by relatively moving the cutting tool in a spiral shape may also serve as the formation of the through hole described later.

於第1切削步驟中,螺線的螺距例如為0.01mm以上0.5mm以下,較佳為0.02mm以上0.3mm以下,更佳為0.03mm以上0.2mm以下。螺線的螺距於上述之範圍內的情況,可不過度需要時間就將積層膜切削成目的的大小。另外,螺線的螺距過大時經切削之積層膜有變得容易產生缺陷的傾向。 In the first cutting step, the pitch of the spiral is, for example, 0.01 mm or more and 0.5 mm or less, preferably 0.02 mm or more and 0.3 mm or less, and more preferably 0.03 mm or more and 0.2 mm or less. When the pitch of the spiral is within the above range, the laminated film can be cut to the desired size without excessively requiring time. In addition, when the pitch of the spiral is too large, the cut laminated film tends to be easily defective.

於第1切削步驟中,積層膜可一片一片地進行切削,亦可對重疊複數片積層膜所製成的積層體進行切削。於第1切削步驟中,將積層膜重疊複 數片並切削的情況,從相對於積層體的主面為垂直的方向來看進行使切削工具螺線狀地相對移動的操作,藉此可切削構成積層體之各積層膜。構成積層體之積層膜的片數例如可為10片以上500片以下。於積層膜的積層方向,積層體的厚度例如可為1mm以上50mm以下。 In the first cutting step, the laminated film can be cut one by one, or a laminated body formed by stacking a plurality of laminated films can be cut. In the first cutting step, overlap the laminated film When several pieces are cut together, when viewed from a direction perpendicular to the main surface of the laminated body, an operation of relatively moving the cutting tool in a spiral shape is performed, whereby each laminated film constituting the laminated body can be cut. The number of laminate films constituting the laminate may be, for example, 10 or more and 500 or less. In the lamination direction of the lamination film, the thickness of the lamination body may be, for example, 1 mm or more and 50 mm or less.

〔貫通孔形成步驟〕 [Through hole formation step]

本發明的製造方法較佳為更包含形成在相對於積層膜的主面為垂直的方向貫通之貫通孔之貫通孔形成步驟。貫通孔形成步驟及下述之配置步驟通常係在第1切削步驟之前進行。為了可在貫通孔內配置切削工具,貫通孔的大小係與切削工具的正交於柄之最大徑相同或比該最大徑大。 The manufacturing method of the present invention preferably further includes a through hole forming step of forming a through hole penetrating in a direction perpendicular to the main surface of the laminated film. The through hole forming step and the following arrangement step are usually performed before the first cutting step. In order to be able to arrange the cutting tool in the through hole, the size of the through hole is the same as or larger than the maximum diameter of the cutting tool orthogonal to the shank.

貫通孔較佳為藉由使切削工具在相對於積層膜的主面為垂直的方向相對移動來形成。例如切削工具具有可旋轉的柄、及與該柄成為一體之底刃的情況,藉由使切削工具朝向積層膜的主面在垂直的方向相對移動,而能夠以底刃切削積層膜,形成與切削工具的正交於柄之最大徑相同直徑的貫通孔。於貫通孔形成步驟中,在相對於積層膜的主面為平行的方向使切削工具相對移動的操作,可和朝與積層膜的主面垂直的方向之相對移動同時或獨立進行。藉由該操作,可形成比切削工具的正交於柄之最大徑大的貫通孔。在相對於積層膜的主面為平行的方向之相對移動的操作,可舉出從垂直於積層膜的主面的方向來看,切削工具為圓周運動之操作、直線運動之操作等。 The through hole is preferably formed by relatively moving the cutting tool in a direction perpendicular to the main surface of the laminated film. For example, when a cutting tool has a rotatable shank and a bottom edge integrated with the shank, by moving the cutting tool in a vertical direction toward the main surface of the laminated film, the laminated film can be cut with the bottom edge to form a A through hole with the same diameter orthogonal to the largest diameter of the shank of a cutting tool. In the through hole forming step, the relative movement of the cutting tool in a direction parallel to the main surface of the laminated film can be performed simultaneously or independently of the relative movement in the direction perpendicular to the main surface of the laminated film. By this operation, a through hole larger than the maximum diameter of the cutting tool orthogonal to the shank can be formed. The operation of relative movement in a direction parallel to the main surface of the laminated film may include circular motion operations or linear motion operations of the cutting tool when viewed from the direction perpendicular to the main surface of the laminated film.

亦可將積層膜重疊複數片而作成積層體,並進行貫通孔形成步驟。於貫通孔形成步驟中,可藉由使切削工具在相對於積層體的主面為垂直的方向相對移動,於構成積層體之各積層膜形成貫通孔。將積層膜作成積層體並 進行貫通孔形成步驟的情況,可對形成有貫通孔之該積層體進行此後之配置步驟及第1切削步驟。 It is also possible to stack a plurality of laminated films to form a laminated body, and perform the through hole forming step. In the through hole forming step, by relatively moving the cutting tool in a direction perpendicular to the main surface of the laminated body, a through hole can be formed in each laminated film constituting the laminated body. The laminated film is made into a laminated body and In the case of performing the through-hole forming step, the subsequent arranging step and the first cutting step may be performed on the laminated body in which the through-hole is formed.

貫通孔可藉由衝壓法、雷射法等公知的方法形成。藉由上述方法形成之貫通孔較佳為比切削工具的正交於柄之最大徑還大。 The through hole can be formed by a known method such as a punching method and a laser method. The through hole formed by the above method is preferably larger than the maximum diameter of the cutting tool orthogonal to the shank.

〔配置步驟〕 [Configuration steps]

本發明的製造方法較佳為更包含以貫通前述貫通孔的方式配置切削工具之配置步驟。亦可由貫通貫通孔,且切削工具的外周刃相接到貫通孔的內側的方式來配置。具體而言,形成貫通孔後,以貫通前述貫通孔的方式配置切削工具即可。形成U字形狀、Omega形狀的缺口部的情況,可在與積層膜的主面平行的方向,一邊切削積層膜,一邊使切削工具相對移動,在螺線的開始地點配置切削工具。 The manufacturing method of the present invention preferably further includes an arrangement step of arranging the cutting tool so as to penetrate the through hole. It can also be arranged in such a way that the through hole penetrates and the outer peripheral edge of the cutting tool contacts the inside of the through hole. Specifically, after the through hole is formed, the cutting tool may be arranged so as to penetrate the through hole. When a U-shaped or Omega-shaped notch is formed, the cutting tool can be relatively moved while cutting the laminated film in a direction parallel to the main surface of the laminated film, and the cutting tool can be placed at the starting point of the spiral.

藉由切削工具形成貫通孔的情況,可藉由不將已在相對於積層膜的主面為垂直的方向相對移動過之切削工具拔出,而以貫通前述貫通孔的方式配置切削工具。亦可在相對於積層膜的主面為垂直的方向使切削工具相對移動而形成貫通孔後,從貫通孔在垂直方向拔出切削工具,除去研磨渣,再次於貫通孔配置切削工具。 When the through hole is formed by the cutting tool, the cutting tool can be arranged so as to penetrate the through hole without pulling out the cutting tool that has relatively moved in a direction perpendicular to the main surface of the laminated film. After the cutting tool is relatively moved in a direction perpendicular to the main surface of the laminated film to form a through hole, the cutting tool may be pulled out in the vertical direction from the through hole to remove the grinding slag, and the cutting tool may be placed in the through hole again.

亦可將積層膜重疊複數片而作成積層體並進行配置步驟。此時,以將形成於構成積層體之各積層膜之貫通孔貫通的方式配置切削工具。對積層體進行配置步驟的情況,可直接對該積層體進行第1切削步驟。 It is also possible to stack a plurality of laminated films to form a laminated body and perform the arrangement step. At this time, the cutting tool is arranged so as to penetrate through the through holes formed in the respective laminated films constituting the laminated body. When performing the arrangement step on the layered body, the first cutting step can be directly performed on the layered body.

〔研磨步驟〕 〔Grinding Step〕

本發明的製造方法較佳為更包含研磨藉由第1切削步驟或下述第2切削步驟所形成之切削部分的研磨步驟。 The manufacturing method of the present invention preferably further includes a polishing step of polishing the cut portion formed by the first cutting step or the second cutting step described below.

亦可將積層膜重疊複數片而作成積層體並進行研磨步驟。於研磨步驟中,藉由研磨積層體,可研磨構成積層體之各積層膜的切削部分。對積層體進行第1切削步驟或第2切削步驟後,可直接研磨該積層體。 It is also possible to stack a plurality of laminated films to form a laminated body and perform a polishing step. In the polishing step, by polishing the laminated body, the cut portions of each laminated film constituting the laminated body can be polished. After the layered body is subjected to the first cutting step or the second cutting step, the layered body can be directly polished.

研磨的方法若為可讓經切削之面平滑的方法則並無特別限定,可舉出以研磨紙(砂紙)、研磨布、微粒子研磨劑、磨石等磨擦的研磨法、電氣研磨法、使用溶劑的化學研磨法等。亦可藉由使用第1切削步驟所使用之端銑刀等切削工具,且減慢進給速度、減少研磨量、或這兩者來研磨切削面。此外,亦可藉由研磨來除去至此為止的步驟沾附的髒汙、灰塵等。 The method of polishing is not particularly limited as long as it is a method that can smooth the cut surface. Examples include polishing methods such as abrasive paper (sandpaper), abrasive cloth, fine particle abrasives, and grindstones, electric abrasive methods, and use Chemical polishing of solvents, etc. It is also possible to grind the cutting surface by using a cutting tool such as an end mill used in the first cutting step and slowing down the feed rate, reducing the amount of grinding, or both. In addition, the dirt, dust, etc. attached to the steps up to this point can also be removed by grinding.

〔第2切削步驟〕 [Second cutting step]

本發明的製造方法可進一步含有第2切削步驟,係於從第1切削步驟所得之積層膜中,在相對於積層膜的主面為平行的方向使切削工具相對移動,更進一步地進行切削。 The manufacturing method of the present invention may further include a second cutting step in which, in the laminated film obtained from the first cutting step, the cutting tool is relatively moved in a direction parallel to the main surface of the laminated film to further perform cutting.

亦可將積層膜重疊複數片而作成積層體,並進行第2切削步驟。於第2切削步驟中,藉由進行在相對於積層體的主面為平行的方向使切削工具相對移動的操作,更進一步地切削構成積層體之各積層膜。亦可對積層體進行第1切削步驟,並直接對該積層體進行第2切削步驟。 It is also possible to stack a plurality of laminated films to form a laminated body, and perform the second cutting step. In the second cutting step, by performing an operation of relatively moving the cutting tool in a direction parallel to the main surface of the laminated body, each laminated film constituting the laminated body is further cut. It is also possible to perform the first cutting step on the layered body and directly perform the second cutting step on the layered body.

藉由從第1切削步驟形成之切削部分進一步繼續進行第2切削步驟,可獲得經切削為目的的形狀之積層膜。例如藉由第1切削步驟而形成有圓形的洞穴部的情況,藉由從洞穴部向積層膜的端面進行曲線或直線的切削,可形成U字形狀、Omega形狀等的缺口部。 By proceeding to the second cutting step from the cut portion formed in the first cutting step, a laminated film of the desired shape after cutting can be obtained. For example, when a circular cavity is formed in the first cutting step, a U-shaped, Omega, etc. notch can be formed by cutting a curve or a straight line from the cavity to the end surface of the laminated film.

<經切削加工之積層膜的用途> <Uses of Laminated Films Processed by Cutting>

由本發明的製造方法所得之經切削加工之積層膜可使用於各式各樣的顯示裝置中。顯示裝置係指具有顯示元件之裝置,且含有發光元件或發光裝置作為發光源。顯示裝置可舉例如液晶顯示裝置、有機EL顯示裝置、無機電致發光(以下亦稱為無機EL)顯示裝置、電子發射顯示裝置(例如電場發射顯示裝置(亦稱為FED)、表面電場發射顯示裝置(亦稱為SED))、電子紙(使用電子印墨或電泳元件之顯示裝置)、電漿顯示裝置、投射型顯示裝置(例如柵狀光閥(亦稱為GLV)顯示裝置、具有數位微鏡裝置(亦稱為DMD)之顯示裝置)及壓電陶瓷顯示器等。液晶顯示裝置亦包含穿透型液晶顯示裝置、半穿透型液晶顯示裝置等之任一者。該等顯示裝置可為顯示2維圖像之顯示裝置,亦可為顯示3維圖像之立體顯示裝置。 The machined laminated film obtained by the manufacturing method of the present invention can be used in various display devices. The display device refers to a device with a display element and contains a light-emitting element or a light-emitting device as a light-emitting source. The display device can include, for example, a liquid crystal display device, an organic EL display device, an inorganic electroluminescence (hereinafter also referred to as inorganic EL) display device, an electron emission display device (such as a field emission display device (also referred to as FED), a surface electric field emission display) Device (also known as SED), electronic paper (display device using electronic printing ink or electrophoresis element), plasma display device, projection display device (such as grating light valve (also called GLV) display device, with digital Micromirror devices (also known as DMD display devices) and piezoelectric ceramic displays, etc. The liquid crystal display device also includes any one of a transmissive liquid crystal display device, a semi-transmissive liquid crystal display device, and the like. These display devices may be display devices that display 2-dimensional images, or may be stereoscopic display devices that display 3-dimensional images.

上述經切削加工之積層膜可進一步設有前面板、觸感測器面板、背面板等,而應用於顯示裝置。 The above-mentioned machined laminated film can be further provided with a front panel, a touch sensor panel, a back panel, etc., and applied to a display device.

〔前面板〕 〔Front Panel〕

前面板較佳為光可穿透的板狀體。前面板可僅由1層所構成,亦可由2層以上所構成。 The front panel is preferably a light-permeable plate-shaped body. The front panel may be composed of only one layer, or may be composed of two or more layers.

前面板可舉例如玻璃製的板狀體(玻璃板、可撓性薄型玻璃等)、樹脂製的板狀體(樹脂板、樹脂片、樹脂膜(有時亦稱為窗膜)等),較佳為顯示可撓性之板狀體。上述者中,較佳為樹脂膜等樹脂製的板狀體。可撓性係指可重覆彎曲或彎折者。 Examples of the front panel include glass plates (glass plates, flexible thin glass, etc.), resin plates (resin plates, resin sheets, resin films (also called window films), etc.), It is preferably a plate-shaped body exhibiting flexibility. Among the above, a plate-shaped body made of resin such as a resin film is preferred. Flexibility refers to those that can bend or bend repeatedly.

樹脂製的板狀體可舉出熱塑性樹脂所構成之樹脂膜。熱塑性樹脂可舉出鏈狀聚烯烴系樹脂(聚乙烯系樹脂、聚丙烯系樹脂、聚甲基戊烯系樹脂等)、環狀聚烯烴系樹脂(降莰烯系樹脂等)等聚烯烴系樹脂;三乙醯纖維素等纖 維素系樹脂;聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚對苯二甲酸丁二酯等聚酯系樹脂;聚碳酸酯系樹脂;乙烯-乙酸乙烯酯系樹脂;聚苯乙烯系樹脂;聚醯胺系樹脂;聚醚醯亞胺系樹脂;聚(甲基)丙烯酸甲酯樹脂等(甲基)丙烯酸系樹脂;聚醯亞胺系樹脂;聚醚碸系樹脂;聚碸系樹脂;聚氯乙烯系樹脂;聚偏二氯乙烯系樹脂;聚乙烯醇系樹脂;聚乙烯醇縮乙醛系樹脂;聚醚酮系樹脂;聚醚醚酮系樹脂;聚醚碸系樹脂;聚醯胺醯亞胺系樹脂等。 Examples of the resin-made plate-shaped body include a resin film composed of a thermoplastic resin. Thermoplastic resins include polyolefin resins such as chain polyolefin resins (polyethylene resins, polypropylene resins, polymethylpentene resins, etc.), cyclic polyolefin resins (norbornene resins, etc.) Resin; Triacetyl cellulose and other fibers Vitamin resins; polyester resins such as polyethylene terephthalate, polyethylene naphthalate, and polybutylene terephthalate; polycarbonate resins; ethylene-vinyl acetate resins; Polystyrene resins; polyamide resins; polyether imine resins; (meth)acrylic resins such as polymethyl (meth)acrylate resin; polyimide resins; polyether imide resins ;Polyether resins; polyvinyl chloride resins; polyvinylidene chloride resins; polyvinyl alcohol resins; polyvinyl acetal resins; polyether ketone resins; polyether ether ketone resins; polyethers Chloride-based resins; polyimide-based resins, etc.

熱塑性樹脂可單獨使用或混合2種以上使用。 The thermoplastic resin can be used alone or in combination of two or more kinds.

其中,從可撓性、強度及透明性的觀點來看,構成前面板之熱塑性樹脂適合使用聚醯亞胺系樹脂、聚醯胺系樹脂、聚醯胺醯亞胺系樹脂。 Among them, from the viewpoint of flexibility, strength, and transparency, the thermoplastic resin constituting the front panel is preferably polyimide resin, polyimide resin, and polyimide resin.

前面板可為在基材膜的至少一面設有硬塗層而提升了硬度之膜。基材膜可使用上述的樹脂膜。 The front panel may be a film with a hard coat layer provided on at least one surface of the base film to increase the hardness. The above-mentioned resin film can be used for the base film.

硬塗層可形成在基材膜的一面,亦可形成在兩面。藉由設置硬塗層,可提升硬度及耐刮性。硬塗層的厚度例如可為0.1μm以上30μm以下,較佳為1μm以上20μm以下,更佳為5μm以上15μm以下。 The hard coat layer may be formed on one side of the base film or on both sides. By installing a hard coat, the hardness and scratch resistance can be improved. The thickness of the hard coat layer may be, for example, 0.1 μm or more and 30 μm or less, preferably 1 μm or more and 20 μm or less, and more preferably 5 μm or more and 15 μm or less.

硬塗層可舉例如為紫外線硬化型樹脂之硬化層。紫外線硬化型樹脂可舉出(甲基)丙烯酸系樹脂、聚矽氧系樹脂、聚酯系樹脂、胺酯系樹脂、醯胺系樹脂、環氧系樹脂等。為了提升強度,硬塗層亦可含有添加劑。添加劑並無限定,可舉出無機系微粒子、有機系微粒子、及此等之混合物等。 The hard coat layer may be, for example, a cured layer of ultraviolet curable resin. Examples of ultraviolet curable resins include (meth)acrylic resins, silicone resins, polyester resins, urethane resins, amide resins, epoxy resins, and the like. In order to increase the strength, the hard coat layer may also contain additives. The additives are not limited, and examples include inorganic fine particles, organic fine particles, and mixtures thereof.

前面板不僅具有保護顯示裝置的前面(畫面)之功能,亦可為具有作為觸感測器之功能、抗藍光功能、視野角調整功能等者。 The front panel not only has the function of protecting the front face (screen) of the display device, but also has the function of being a touch sensor, anti-blue light function, viewing angle adjustment function, etc.

前面板的厚度例如可為20μm以上2000μm以下,較佳為25μm以上1500μm以下,更佳為30μm以上1000μm以下,再佳為40μm以 上500μm以下,特佳為40μm以上200μm以下,又更較佳為40μm以上100μm以下。 The thickness of the front panel can be, for example, 20 μm or more and 2000 μm or less, preferably 25 μm or more and 1500 μm or less, more preferably 30 μm or more and 1000 μm or less, and still more preferably 40 μm or less. The upper limit is 500 μm or less, particularly preferably 40 μm or more and 200 μm or less, and more preferably 40 μm or more and 100 μm or less.

〔觸感測器面板〕 〔Touch sensor panel〕

觸感測器面板若為具有可檢測出經觸碰位置之感測器(亦即觸感測器)的面板即可,無限定。觸感測器的檢測方式並無限定,例示有電阻膜式、電容耦合式、光感測器式、超音波式、電磁感應耦合式、表面彈性波方式等的觸感測器面板。由低成本而言,適合使用電阻膜式、電容耦合式的觸感測器面板。 If the touch sensor panel is a panel with a sensor (that is, a touch sensor) that can detect the touched position, it is not limited. The detection method of the touch sensor is not limited, and examples of touch sensor panels such as resistive film type, capacitive coupling type, photo sensor type, ultrasonic type, electromagnetic induction coupling type, surface elastic wave type, and the like are exemplified. In terms of low cost, it is suitable to use resistive film type and capacitive coupling type touch sensor panels.

作為電阻膜式的觸感測器之一例,可舉出由彼此對向配置之一對基板、被夾持在該一對基板之間的絕緣性間隔件、在各基板的內側的整面設置之作為電阻膜之透明導電膜、及觸碰位置偵測電路所構成之構件。 As an example of a resistive film type touch sensor, a pair of substrates arranged to face each other, an insulating spacer sandwiched between the pair of substrates, are provided on the entire inner surface of each substrate It is a component composed of the transparent conductive film of the resistive film and the touch position detection circuit.

於設有電阻膜式的觸感測器之圖像顯示裝置中,若觸碰前面板的表面,則對向之電阻膜會短路,於電阻膜流通電流。觸碰位置偵測電路係偵測此時的電壓變化,檢測出經觸碰的位置。 In an image display device equipped with a resistive film type touch sensor, if the surface of the front panel is touched, the opposing resistive film will be short-circuited, and current will flow through the resistive film. The touch position detection circuit detects the voltage change at this time and detects the touched position.

作為電容耦合式之觸感測器之一例,可舉出由基板、設於基板整面之位置檢測用透明電極、以及觸碰位置偵測電路所構成之構件。於設有電容耦合式之觸感測器之圖像顯示裝置中,若觸碰前面板的表面,則在經觸碰之點,透明電極會經由人體的電容而接地。觸碰位置偵測電路會偵測透明電極的接地,檢測出經觸碰的位置。 As an example of a capacitive coupling type touch sensor, a component composed of a substrate, a transparent electrode for position detection provided on the entire surface of the substrate, and a touch position detection circuit can be cited. In an image display device equipped with a capacitively coupled touch sensor, if the surface of the front panel is touched, the transparent electrode will be grounded via the capacitance of the human body at the touched point. The touch position detection circuit detects the grounding of the transparent electrode and detects the touched position.

觸感測器面板的厚度例如可為5μm以上2000μm以下,較佳為5μm以上100μm以下,再佳為5μm以上50μm以下。 The thickness of the touch sensor panel may be, for example, 5 μm or more and 2000 μm or less, preferably 5 μm or more and 100 μm or less, and more preferably 5 μm or more and 50 μm or less.

觸感測器面板可為在基材膜上形成有觸感測器的圖案之構件。基材膜的例示能夠與上述保護膜的說明中的例示相同。觸感測器圖案的厚度例如可為1μm以上20μm以下。 The touch sensor panel may be a member in which a pattern of the touch sensor is formed on the base film. The example of the base film can be the same as the example in the description of the above-mentioned protective film. The thickness of the touch sensor pattern may be, for example, 1 μm or more and 20 μm or less.

具有觸感測器面板之積層膜100,可舉例如依序具有基材(較佳為前面板,更佳為顯示可撓性之前面板)、觸感測器及偏光層之積層膜,或依序具有基材(較佳為前面板,更佳為顯示可撓性之前面板)、偏光層及觸感測器之積層膜。 The laminated film 100 with a touch sensor panel may be, for example, a laminated film having a substrate (preferably a front panel, more preferably a display flexible front panel), a touch sensor and a polarizing layer in sequence, or The sequence has a laminate film of a substrate (preferably a front panel, more preferably a display flexible front panel), a polarizing layer and a touch sensor.

〔背面板〕 〔Back panel〕

背面板可具有例如光可穿透之板狀體。背面板可僅由1層所構成,亦可由2層以上所構成。 The back plate may have, for example, a plate-shaped body that can penetrate light. The back panel may be composed of only one layer, or may be composed of two or more layers.

背面板與前面板相同地,可舉例如玻璃製的板狀體(例如,玻璃板、玻璃膜等)、樹脂製的板狀體(例如,樹脂板、樹脂片、樹脂膜等)。 Like the front panel, the back panel includes, for example, a plate-shaped body made of glass (for example, a glass plate, glass film, etc.) and a plate-shaped body made of resin (for example, a resin plate, a resin sheet, a resin film, etc.).

上述者中,從積層體100及包含該積層體100之顯示裝置的可撓性的觀點來看,較佳為顯示可撓性者,較佳為顯示可撓性之樹脂製的板狀體。 Among the above, from the viewpoint of flexibility of the laminated body 100 and the display device including the laminated body 100, it is preferably one that exhibits flexibility, and more preferably a resin-made plate-shaped body that exhibits flexibility.

樹脂製的板狀體可舉出熱塑性樹脂所構成之樹脂膜。熱塑性樹脂之具體例係引用關於前面板之記載。熱塑性樹脂較佳為纖維素系樹脂、(甲基)丙烯酸系樹脂、環狀聚烯烴系樹脂、聚酯系樹脂、聚碳酸酯系樹脂等。 Examples of the resin-made plate-shaped body include a resin film composed of a thermoplastic resin. The specific example of the thermoplastic resin refers to the description on the front panel. The thermoplastic resin is preferably a cellulose resin, (meth)acrylic resin, cyclic polyolefin resin, polyester resin, polycarbonate resin, or the like.

背面板可為塗佈有聚合性液晶化合物之基材膜。 The back plate may be a base film coated with a polymerizable liquid crystal compound.

背面板為光可穿透之板狀體的情況,從積層膜100的薄型化之觀點來看,其厚度較佳為15μm以上200μm以下,更佳為20μm以上150μm以下,再佳為30μm以上130μm以下。 When the back plate is a light-permeable plate-shaped body, from the viewpoint of making the laminated film 100 thinner, the thickness is preferably 15 μm or more and 200 μm or less, more preferably 20 μm or more and 150 μm or less, and still more preferably 30 μm or more and 130 μm the following.

積層膜的厚度係因應積層膜所要求的機能及積層膜的用途等而異,故並無特別限定,但例如可為25μm以上1000μm以下,較佳為100μm以上500μm以下,更佳為100μm以上300μm以下。 The thickness of the laminated film varies depending on the required function of the laminated film and the purpose of the laminated film, so it is not particularly limited, but for example, it can be 25 μm or more and 1000 μm or less, preferably 100 μm or more and 500 μm or less, more preferably 100 μm or more and 300 μm. the following.

[實施例] [Example]

以下,列舉實施例而更詳細地說明本發明,但本發明不限定於此。 Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited to these.

(製造例1) (Manufacturing example 1)

將平均聚合度約2400、皂化度99.9莫耳%以上、厚度20μm之聚乙烯醇膜以乾式單軸延伸到約4倍,進一步保持在緊繃狀態,在40℃之純水中浸漬1分鐘後,在28℃於碘/碘化鉀/水之重量比為0.1/5/100的水溶液中浸漬60秒鐘。之後,在68℃於碘化鉀/硼酸/水之重量比為10.5/7.5/100的水溶液中浸漬300秒鐘。接著,以5℃之純水洗淨5秒鐘後,在70℃乾燥180秒鐘,獲得於經單軸延伸之聚乙烯醇膜中吸附配向有碘之偏光片。偏光片的厚度為7μm。 A polyvinyl alcohol film with an average degree of polymerization of about 2400, a degree of saponification of 99.9 mol% or more, and a thickness of 20 μm was stretched to about 4 times in a dry uniaxial manner, and kept in a tight state. After immersing in pure water at 40°C for 1 minute , Immerse in an aqueous solution with a weight ratio of iodine/potassium iodide/water of 0.1/5/100 at 28°C for 60 seconds. After that, it was immersed in an aqueous solution with a weight ratio of potassium iodide/boric acid/water of 10.5/7.5/100 at 68°C for 300 seconds. Then, after washing with pure water at 5°C for 5 seconds, it was dried at 70°C for 180 seconds to obtain a polarizer in which iodine was adsorbed and aligned in a uniaxially stretched polyvinyl alcohol film. The thickness of the polarizer is 7 μm.

將厚度50μm之環狀烯烴系樹脂所構成之熱塑性樹脂膜,各別於其貼合面施以電暈處理後,隔著光硬化型接著劑(環氧系的光硬化性接著劑)接著於所得之偏光片之一面,而獲得偏光板。 A thermoplastic resin film composed of a cyclic olefin resin with a thickness of 50μm is subjected to corona treatment on each of the bonding surfaces, and then bonded to the surface via a photo-curing adhesive (epoxy-based photo-curing adhesive) One side of the obtained polarizer is obtained, and a polarizing plate is obtained.

在該偏光板所具有之偏光片中的與熱塑性樹脂膜為相反側的面,貼合下列的層,獲得具有「除了不具有第2黏著劑層21以外,其餘與圖4所述之構成相同的構成」之厚度16μm之積層膜。 On the surface of the polarizer that the polarizer has on the opposite side to the thermoplastic resin film, the following layers are bonded to obtain the structure having the same structure as that described in FIG. 4 except that it does not have the second adhesive layer 21 The constitution" is a build-up film with a thickness of 16μm.

第1黏著劑層20:厚度5μm The first adhesive layer 20: thickness 5μm

光學機能層30:液晶化合物經硬化而成之層及配向膜所構成之λ/2板,厚度3μm Optical function layer 30: a λ/2 plate composed of a hardened liquid crystal compound layer and an alignment film, with a thickness of 3μm

接著劑層40:厚度5μm Adhesive layer 40: thickness 5μm

光學機能層31:液晶化合物經硬化而成之層及配向膜所構成之λ/4板,厚度3μm Optical function layer 31: A λ/4 plate composed of a hardened liquid crystal compound layer and an alignment film, with a thickness of 3μm

(製造例2) (Manufacturing example 2)

除了在偏光片的兩面接著熱塑性樹脂膜、及在一熱塑性樹脂膜貼合光學機能層以外,其餘與製造例1相同地操作,獲得具有「除了不具有第2黏著劑層21以外,其餘與圖5所述之構成相同的構成」之積層膜。 Except for bonding the thermoplastic resin film on both sides of the polarizer and laminating the optical function layer on a thermoplastic resin film, the rest is the same as in Manufacturing Example 1, and obtained with "except that the second adhesive layer 21 is not provided, the rest is as shown in the figure 5 "The same structure as the above-mentioned laminated film."

<實施例1> <Example 1>

積層50片積層膜,形成積層體。切削係使用直徑2mm、刃數2片的端銑刀。首先,在相對於積層體的面為垂直的方向移動端銑刀,以端銑刀的底刃形成貫通孔,以貫通前述貫通孔的方式配置端銑刀(貫通孔形成步驟及配置步驟)。之後,如圖2之(A)所示般,使端銑刀以從相對於積層體的面為垂直的方向來看成為螺線的方式相對移動,進行積層膜的切削(第1切削步驟),形成直徑3mm的圓形的洞穴部。此時,以使端銑刀的可旋轉的柄相對於積層膜的主面為垂直的方式,並且,一邊進行使端銑刀在相對於積層膜的主面為平行的方向相對移動的操作,一邊進行切削。螺線設定為以每半圈半徑就增大0.05mm的方式的圓周運動,螺線的螺距為0.10mm。端銑刀的進給速度為500mm/分鐘,旋轉速度為50000rpm。 50 laminated films are laminated to form a laminated body. The cutting system uses an end mill with a diameter of 2 mm and two blades. First, the end mill is moved in a direction perpendicular to the surface of the layered body, a through hole is formed with the bottom edge of the end mill, and the end mill is arranged so as to penetrate the through hole (through hole forming step and arrangement step). After that, as shown in FIG. 2(A), the end mill is relatively moved so as to be spiral when viewed from the direction perpendicular to the surface of the laminate, and the laminate film is cut (first cutting step) , Forming a circular cave with a diameter of 3mm. At this time, so that the rotatable shank of the end mill is perpendicular to the main surface of the laminated film, and while the end mill is relatively moved in a direction parallel to the main surface of the laminated film, While cutting. The spiral is set to a circular motion in a manner that the radius of each half turn increases by 0.05 mm, and the pitch of the spiral is 0.10 mm. The feed speed of the end mill is 500 mm/min, and the rotation speed is 50,000 rpm.

<實施例2> <Example 2>

於第1切削步驟中,除了端銑刀的進給速度為300mm/分鐘以外,其餘與實施例1相同地進行積層體的切削。 In the first cutting step, the laminated body was cut in the same manner as in Example 1, except that the feed rate of the end mill was 300 mm/min.

<實施例3> <Example 3>

於第1切削步驟中,除了端銑刀的進給速度為500mm/分鐘,且旋轉數為40000rpm以外,其餘與實施例1相同地進行積層體的切削。 In the first cutting step, except that the feed rate of the end mill was 500 mm/min and the number of revolutions was 40,000 rpm, the cutting of the laminate was performed in the same manner as in Example 1.

<實施例4> <Example 4>

於第1切削步驟中,端銑刀的進給速度為500mm/分鐘,且旋轉數為30000rpm以外,其餘與實施例1相同地進行積層體的切削。 In the first cutting step, except that the feed speed of the end mill was 500 mm/min and the number of revolutions was 30,000 rpm, the cutting of the laminate was performed in the same manner as in Example 1.

<比較例1> <Comparative Example 1>

除了端銑刀的移動路線與實施例1不同以外,其餘與實施例1相同地進行積層體的切削。首先,在相對於積層體的面為垂直的方向移動端銑刀,以端銑刀的底刃形成貫通孔。之後,如圖2之(B)所示般重覆進行0.10mm之直線運動與半徑逐次增大0.10mm的圓周運動,以螺距成為0.10mm的方式進行切削,形成直徑3mm之圓形的洞穴部。 Except that the movement path of the end mill is different from that of the first embodiment, the cutting of the laminated body is performed in the same manner as that of the first embodiment. First, the end mill is moved in a direction perpendicular to the surface of the layered body, and a through hole is formed with the bottom edge of the end mill. After that, repeat the linear motion of 0.10mm and the circular motion of increasing the radius by 0.10mm as shown in Figure 2(B), cutting so that the pitch becomes 0.10mm, forming a circular cavity with a diameter of 3mm .

<比較例2> <Comparative Example 2>

除了直線運動的距離設為0.05mm,圓周運動的半徑逐次增大0.05mm,螺距設為0.05mm的方式以外,其餘與比較例1相同地進行切削。 The cutting was performed in the same manner as in Comparative Example 1, except that the distance of linear motion was set to 0.05 mm, the radius of circular motion was gradually increased by 0.05 mm, and the thread pitch was set to 0.05 mm.

<比較例3> <Comparative Example 3>

除了直線運動的距離設為0.15mm,圓周運動的半徑逐次增大0.15mm,螺距設為0.15mm的方式以外,其餘與比較例1相同地進行切削。 Except that the distance of linear motion is set to 0.15mm, the radius of circular motion is gradually increased by 0.15mm, and the thread pitch is set to 0.15mm, the cutting is performed in the same manner as in Comparative Example 1.

〔層間剝離的測定〕 [Measurement of delamination]

將積層體在積層方向約略分為三份,各別作為上層、中層、下層,從各別的層的約中央部選擇1片,在光學顯微鏡下觀察經切削之積層膜的切削部分。將所生成的層間剝離量(在積層膜的主面方向所產生之層間剝離之長度)的最大 值為80μm以下者評估為「A」,81μm以上150μm以下者評估為「B」,151μm以上者評估為「C」。 The laminate was roughly divided into three parts in the lamination direction, each as the upper layer, the middle layer, and the lower layer. One sheet was selected from about the center of each layer, and the cut part of the cut laminate film was observed under an optical microscope. The maximum amount of interlayer peeling (the length of the interlayer peeling generated in the direction of the main surface of the laminated film) Those with a value of 80 μm or less are evaluated as "A", those with a value of 81 μm or more and 150 μm or less are evaluated as "B", and those with 151 μm or more are evaluated as "C".

將製造例1之積層膜藉由實施例1至4及比較例1及2之方法切削之結果顯示於表1。 The results of cutting the laminated film of Production Example 1 by the methods of Examples 1 to 4 and Comparative Examples 1 and 2 are shown in Table 1.

Figure 109106912-A0202-12-0028-1
Figure 109106912-A0202-12-0028-1

將製造例2之積層膜藉由實施例1及比較例1及2之方法切削之結果顯示於表2。 Table 2 shows the results of cutting the laminated film of Production Example 2 by the method of Example 1 and Comparative Examples 1 and 2.

Figure 109106912-A0202-12-0028-9
Figure 109106912-A0202-12-0028-9

無論是於製造例1之積層膜中,或是於製造例2之積層膜中,與比較例1及比較例2相比,實施例1係抑制了層間剝離。於比較例1及比較例2中,特別是進行直線運動的切削部分看到較多的層間剝離。依據本發明的製造法,可製造更加抑制了層間剝離之經切削加工之積層膜。相較於比較例1及2,於實施例1中,亦抑制了破裂及缺糊的發生。 Regardless of whether it is in the laminated film of Production Example 1 or in the laminated film of Production Example 2, compared with Comparative Example 1 and Comparative Example 2, Example 1 suppresses delamination. In Comparative Example 1 and Comparative Example 2, in particular, a large amount of delamination was observed in the cutting portion that performed linear motion. According to the manufacturing method of the present invention, it is possible to manufacture a laminated film that has undergone cutting processing in which delamination is more suppressed. Compared with Comparative Examples 1 and 2, in Example 1, the occurrence of cracking and lack of paste was also suppressed.

將製造例1之積層膜藉由實施例1及比較例1至3所述之方法切削時的層間剝離量之最大值顯示於圖6。積層膜係選擇自積層體的下層。 The maximum value of the delamination amount when the laminated film of Production Example 1 was cut by the method described in Example 1 and Comparative Examples 1 to 3 is shown in FIG. 6. The laminated film is selected from the lower layer of the laminated body.

由比較例1至3之結果,可得知重覆直線運動與圓周運動的切削方法中,隨著螺距變大,層間剝離亦變大。屬於積層體的下層之積層膜容易產生因切削加工所致的層間剝離。為了抑制層間剝離,雖然可減小螺距,但若是螺距減小,則切削到形成目的大小的洞穴部為止所需要的時間會變長。依據本發明的製造方法,即便螺距較大仍可抑制層間剝離,故可縮短切削時間。 From the results of Comparative Examples 1 to 3, it can be seen that in the cutting method that repeats linear motion and circular motion, as the thread pitch increases, the delamination increases. The laminated film belonging to the lower layer of the laminated body is prone to interlayer peeling due to cutting processing. In order to suppress delamination, the thread pitch can be reduced. However, if the thread pitch is reduced, the time required for cutting to form a cavity of the target size becomes longer. According to the manufacturing method of the present invention, delamination can be suppressed even if the thread pitch is large, so the cutting time can be shortened.

Claims (13)

一種經切削加工之積層膜的製造方法,係包含:第1切削步驟,係從相對於積層膜的主面為垂直的方向觀看,進行使切削工具螺線狀地相對移動的操作,藉此切削前述積層膜。 A method for manufacturing a cut-processed laminated film includes: a first cutting step, viewing from a direction perpendicular to the main surface of the laminated film, and performing an operation of relatively moving a cutting tool in a spiral shape, thereby cutting The aforementioned laminated film. 如請求項1所述之製造方法,其中,前述切削工具具有可旋轉的柄與外周刃, The manufacturing method according to claim 1, wherein the cutting tool has a rotatable shank and a peripheral edge, 前述外周刃與前述柄成為一體。 The outer peripheral blade is integrated with the shank. 如請求項2所述之製造方法,其中,於前述第1切削步驟中,以前述柄係相對於前述積層膜的主面成為垂直的狀態,進行使前述切削工具相對移動的操作。 The manufacturing method according to claim 2, wherein in the first cutting step, the operation of relatively moving the cutting tool is performed in a state where the shank system is perpendicular to the main surface of the laminated film. 如請求項1至3中任一項所述之製造方法,其中,於前述第1切削步驟中,使前述切削工具相對移動的操作,係以相對於前述積層膜的主面為平行的方向進行。 The manufacturing method according to any one of claims 1 to 3, wherein, in the first cutting step, the operation of relatively moving the cutting tool is performed in a direction parallel to the main surface of the laminated film . 如請求項1至4中任一項所述之製造方法,更包含: The manufacturing method according to any one of claims 1 to 4, further comprising: 貫通孔形成步驟,係於前述第1切削步驟之前形成貫通孔,該貫通孔係在相對於前述積層膜的主面為垂直的方向貫通;以及 The through hole forming step is to form a through hole before the first cutting step, and the through hole penetrates in a direction perpendicular to the main surface of the laminated film; and 配置步驟,係以貫通前述貫通孔的方式配置前述切削工具。 The arrangement step is to arrange the cutting tool so as to penetrate the through hole. 如請求項5所述之製造方法,其中,於前述貫通孔形成步驟中,藉由使前述切削工具於相對於前述積層膜的主面為垂直的方向相對移動,而形成前述貫通孔。 The manufacturing method according to claim 5, wherein in the through-hole forming step, the through-hole is formed by relatively moving the cutting tool in a direction perpendicular to the main surface of the laminated film. 如請求項6所述之製造方法,其中,前述切削工具具有可旋轉的柄、外周刃及底刃, The manufacturing method according to claim 6, wherein the cutting tool has a rotatable shank, a peripheral edge, and a bottom edge, 前述外周刃及前述底刃係各別與前述柄成為一體。 The outer peripheral blade and the bottom blade are respectively integrated with the shank. 如請求項1至7中任一項所述之製造方法,其中,於前述第1切削步驟中,螺線的螺距為0.01mm以上0.5mm以下。 The manufacturing method according to any one of claims 1 to 7, wherein in the first cutting step, the pitch of the spiral is 0.01 mm or more and 0.5 mm or less. 如請求項1至8中任一項所述之製造方法,更包含研磨步驟,係研磨藉由前述第1切削步驟形成之切削部分。 The manufacturing method according to any one of claims 1 to 8, further comprising a grinding step of grinding the cut part formed by the aforementioned first cutting step. 如請求項1至9中任一項所述之製造方法,更包含第2切削步驟,係於藉由前述第1切削步驟所得之積層膜中,在相對於前述積層膜的主面為平行的方向使前述切削工具相對移動,進行更進一步的切削。 The manufacturing method according to any one of claims 1 to 9, further comprising a second cutting step in which the laminated film obtained by the first cutting step is parallel to the main surface of the laminated film The direction causes the cutting tool to move relatively to perform further cutting. 如請求項1至10中任一項所述之製造方法,其中,前述積層膜為顯示裝置用膜。 The manufacturing method according to any one of claims 1 to 10, wherein the laminated film is a film for a display device. 如請求項1至11中任一項所述之製造方法,其中,前述積層膜包含偏光板。 The manufacturing method according to any one of claims 1 to 11, wherein the laminated film includes a polarizing plate. 如請求項1至12中任一項所述之製造方法,其中,於前述第1切削步驟中,將前述積層膜重疊複數片並切削。 The manufacturing method according to any one of claims 1 to 12, wherein in the first cutting step, a plurality of pieces of the laminated film are stacked and cut.
TW109106912A 2019-03-06 2020-03-03 Method for producing cutting-processed laminated film TW202103970A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2019-040675 2019-03-06
JP2019040675 2019-03-06
JP2019129131A JP6622439B1 (en) 2019-03-06 2019-07-11 Manufacturing method of cut laminated film
JP2019-129131 2019-07-11

Publications (1)

Publication Number Publication Date
TW202103970A true TW202103970A (en) 2021-02-01

Family

ID=68917225

Family Applications (1)

Application Number Title Priority Date Filing Date
TW109106912A TW202103970A (en) 2019-03-06 2020-03-03 Method for producing cutting-processed laminated film

Country Status (4)

Country Link
JP (2) JP6622439B1 (en)
KR (1) KR20200107812A (en)
CN (1) CN111665587A (en)
TW (1) TW202103970A (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6995813B2 (en) * 2019-03-28 2022-01-17 日東電工株式会社 Polarizer
KR20220093160A (en) * 2019-12-11 2022-07-05 닛토덴코 가부시키가이샤 Polarizing plate, set of polarizing plate and image display device
CN114829994A (en) * 2019-12-11 2022-07-29 日东电工株式会社 Polarizing plate, polarizing plate group, and image display device
JP2021128202A (en) * 2020-02-12 2021-09-02 住友化学株式会社 Display device
WO2021192391A1 (en) * 2020-03-25 2021-09-30 日東電工株式会社 Production method for adhesive layer-equipped optical layered body having through-hole
KR20220156554A (en) * 2020-03-25 2022-11-25 닛토덴코 가부시키가이샤 Method for manufacturing an optical laminate with a pressure-sensitive adhesive layer having a through hole, and through hole forming device used in the manufacturing method
CN112091292B (en) * 2020-09-14 2022-09-02 中国航发贵州黎阳航空动力有限公司 Allowance hole reaming method
CN112317883A (en) * 2020-10-30 2021-02-05 共享智能机器(苏州)有限公司 High-precision machining method for machine parts
JP2022148128A (en) * 2021-03-24 2022-10-06 住友化学株式会社 Polarizer and image display device
JP7220764B1 (en) 2021-11-02 2023-02-10 住友化学株式会社 METHOD FOR MANUFACTURING FILM WITH THROUGH HOLE, AND CIRCULAR POLARIZER
CN115057067A (en) * 2022-07-07 2022-09-16 丝艾产品标识(重庆)有限公司 Method for solving peeling of protective film of lens of camera

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4742533Y1 (en) * 1967-03-08 1972-12-22
GB2132276B (en) * 1982-12-23 1986-10-01 Copeland Corp Scroll-type rotary fluid-machine
JPS60106398U (en) * 1983-12-22 1985-07-19 凸版印刷株式会社 Housing with electromagnetic shielding effect
JPS60157848A (en) * 1984-01-26 1985-08-19 神鋼電機株式会社 Implanted sheet and usage thereof
JPH10225814A (en) * 1992-06-17 1998-08-25 Makino Milling Mach Co Ltd Cutting work method
JP3427330B2 (en) * 1994-10-07 2003-07-14 不二商事株式会社 Scroll compressor scroll
JPH09191168A (en) * 1996-01-10 1997-07-22 Yamamoto Seisakusho:Kk Method for making contact hole through printed wiring board
WO1998009758A1 (en) * 1996-09-06 1998-03-12 Masao Kubota Rotary cutting tool having composite cutting edge and machining method using the tool
JP3935927B2 (en) * 2004-12-10 2007-06-27 東邦エンジニアリング株式会社 Bit tool for pad groove machining and method for manufacturing polishing pad using the same
JP4570763B2 (en) * 2000-11-29 2010-10-27 東北リコー株式会社 Method for producing a master for thermal stencil printing
JP3716232B2 (en) * 2001-09-25 2005-11-16 オルファ株式会社 Compass and compass cutter with ratchet mechanism
JP2005246098A (en) * 2001-09-25 2005-09-15 Olfa Corp Compass-cutter
JP2004209559A (en) * 2002-12-27 2004-07-29 Sumitomo Electric Ind Ltd End mill having back taper
US7591072B2 (en) * 2004-10-15 2009-09-22 Stravitz David M Cutting devices
JP2009263408A (en) * 2008-04-22 2009-11-12 Akira Ogawara Releasing sheet for manually applied pressure-sensitive adhesive film and method to apply pressure-sensitive adhesive film provided with the same
JP5474032B2 (en) * 2011-11-29 2014-04-16 ユニオンツール株式会社 Rotary cutting tool
JP5463501B2 (en) * 2012-03-26 2014-04-09 祥二 勝目 Three-dimensional light emitting structure using electroluminescent laminate sheet
US20160291570A1 (en) * 2014-05-28 2016-10-06 Mitsubishi Electric Corporation Tool-path generation apparatus and method
JP2018012182A (en) * 2016-07-22 2018-01-25 日東電工株式会社 Method and apparatus for manufacturing polarization plate
JP2018159911A (en) * 2017-01-27 2018-10-11 住友化学株式会社 Polarizing plate and image display device
TWI628708B (en) * 2017-07-03 2018-07-01 國立臺灣師範大學 Cutting device for round cutting
JP6940071B2 (en) * 2017-07-26 2021-09-22 株式会社ウエノシステック Simple protective cap
CN108062947B (en) * 2017-11-28 2021-06-29 华中科技大学 Method for forming acoustic vortex based on patterned cutting technology

Also Published As

Publication number Publication date
KR20200107812A (en) 2020-09-16
JP2020149034A (en) 2020-09-17
JP6622439B1 (en) 2019-12-18
JP2020146827A (en) 2020-09-17
JP7386674B2 (en) 2023-11-27
CN111665587A (en) 2020-09-15

Similar Documents

Publication Publication Date Title
TW202103970A (en) Method for producing cutting-processed laminated film
TWI830879B (en) Method for producing cutting-processed film
WO2021010114A1 (en) Optical laminate and manufacturing method therefor
JP2024009307A (en) polarizer
JP2021144208A (en) Laminated sheet and manufacturing method therefor
WO2020095579A1 (en) Polarizing plate
WO2021149358A1 (en) Optical stack and production method therefor
WO2021182005A1 (en) Laminate sheet and method for manufacturing same
WO2021177040A1 (en) Optical laminate
KR20210102851A (en) Optical laminate having an adhesive layer and display device
CN112526664A (en) Method for producing polarizing plate and polarizing plate
JP2021167930A (en) Optical laminate and peeling method
TW202028786A (en) Polarizing plate
WO2021220805A1 (en) Flexible laminate and display device
WO2021186986A1 (en) Laminate sheet and method for manufacturing same
TWI838456B (en) Optical laminated film with adhesive layer and method for producing the same
TW202045654A (en) Optical laminated film with adhesive layer and method for producing the same
JP2021149087A (en) Laminated sheet and manufacturing method therefor
CN115136040A (en) Optical laminate and display device provided with same
CN115244438A (en) Optical laminate