TW202025224A - Metal halide lamp and ultraviolet ray irradiation device ensures required illuminance characteristics while suppressing deterioration - Google Patents

Metal halide lamp and ultraviolet ray irradiation device ensures required illuminance characteristics while suppressing deterioration Download PDF

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TW202025224A
TW202025224A TW108129389A TW108129389A TW202025224A TW 202025224 A TW202025224 A TW 202025224A TW 108129389 A TW108129389 A TW 108129389A TW 108129389 A TW108129389 A TW 108129389A TW 202025224 A TW202025224 A TW 202025224A
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metal halide
halide lamp
arc tube
enclosed
thallium
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TW108129389A
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Chinese (zh)
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TWI809171B (en
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峯山智行
堀内正和
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日商東芝照明技術股份有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • H01J61/18Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • H01J61/18Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent
    • H01J61/20Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent mercury vapour
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/82Lamps with high-pressure unconstricted discharge having a cold pressure > 400 Torr
    • H01J61/827Metal halide arc lamps

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  • Discharge Lamp (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The invention can ensure illuminance characteristics while suppressing deterioration. In the implementation, a metal halide lamp comprises a light emitting tube and an electrode. In the light emitting tube, halogen, iron and thallium are enclosed. The electrode is disposed inside the light emitting tube. The enclosed quantity for thallium relative to iron is above 0.2 and below 0.3 in terms of mass ratio.

Description

金屬鹵化物燈以及紫外線照射裝置Metal halide lamp and ultraviolet irradiation device

本發明的實施方式涉及一種金屬鹵化物燈(metal halide lamp)以及紫外線照射裝置。The embodiment of the present invention relates to a metal halide lamp and an ultraviolet irradiation device.

例如,在半導體的曝光工序或紫外線(ultraviolet,UV)油墨(ink)或UV塗料的乾燥工序、樹脂的固化工序等中,為了通過紫外線來進行光化學反應,使用金屬鹵化物燈來作為發出紫外線的光源。 [現有技術文獻] [專利文獻]For example, in the semiconductor exposure process, ultraviolet (ultraviolet, UV) ink (ink) or UV coating drying process, resin curing process, etc., in order to carry out a photochemical reaction by ultraviolet rays, a metal halide lamp is used as the emission of ultraviolet rays. Light source. [Prior Art Literature] [Patent Literature]

專利文獻1:日本專利特開平6-275234號公報Patent Document 1: Japanese Patent Laid-Open No. 6-275234

[發明所要解決的問題][The problem to be solved by the invention]

在金屬鹵化物燈中,有時會因發光管黑化而劣化,導致發光管的紫外線透射率下降。而且,若為了抑制發光管的黑化而變更封入發光管內部的金屬或鹵素(halogen)等封入物的成分,則有時發光強度會下降,從而得不到所需的照度。這樣,在既要抑制劣化,又要確保所需的照度特性方面,存在改善的餘地。In a metal halide lamp, sometimes the arc tube is deteriorated due to blackening, resulting in a decrease in the ultraviolet transmittance of the arc tube. In addition, if the composition of the metal or halogen enclosed in the arc tube is changed in order to suppress the blackening of the arc tube, the luminous intensity may decrease and the desired illuminance may not be obtained. In this way, there is room for improvement in terms of both suppressing deterioration and ensuring the required illuminance characteristics.

本發明所要解決的問題在於提供一種既能抑制劣化,又能確保所需的照度特性的金屬鹵化物燈以及紫外線照射裝置。 [解決問題的技術手段]The problem to be solved by the present invention is to provide a metal halide lamp and an ultraviolet irradiation device that can suppress degradation and ensure the required illuminance characteristics. [Technical means to solve the problem]

實施方式的金屬鹵化物燈包括發光管與電極。在發光管中,封入有鹵素、鐵及鉈(thallium)。電極被設在發光管的內部。鉈相對於鐵的封入量以品質比計為0.2以上且0.3以下。 [發明的效果]The metal halide lamp of the embodiment includes an arc tube and an electrode. In the arc tube, halogen, iron and thallium (thallium) are enclosed. The electrodes are arranged inside the arc tube. The enclosed amount of thallium to iron is 0.2 or more and 0.3 or less in terms of mass ratio. [Effects of the invention]

根據本發明,既能抑制劣化,又能確保所需的照度特性。According to the present invention, deterioration can be suppressed while ensuring the required illuminance characteristics.

以下說明的實施方式的金屬鹵化物燈10包括發光管11與電極14。在發光管11中,封入有鹵素、鐵及鉈。電極14被設在發光管11的內部。鉈相對於鐵的封入量以品質比計為0.2以上且0.3以下。The metal halide lamp 10 of the embodiment described below includes an arc tube 11 and an electrode 14. In the arc tube 11, halogen, iron, and thallium are enclosed. The electrode 14 is provided inside the arc tube 11. The enclosed amount of thallium to iron is 0.2 or more and 0.3 or less in terms of mass ratio.

而且,以下說明的實施方式的鉈的封入量以發光管11的每單位容積1[cm3 ]計為0.0050[mg]以上且0.0076[mg]以下。In addition, the enclosed amount of thallium in the embodiment described below is 0.0050 [mg] or more and 0.0076 [mg] or less in terms of 1 [cm 3 ] per unit volume of the arc tube 11.

而且,以下說明的實施方式的鉈是作為以發光管11的每單位容積1[cm3 ]計為0.008[mg]以上且0.012[mg]以下的碘化鉈而封入發光管11的內部。In addition, the thallium of the embodiment described below is enclosed in the arc tube 11 as thallium iodide that is 0.008 [mg] or more and 0.012 [mg] or less per unit volume 1 [cm 3 ] of the arc tube 11.

而且,以下說明的實施方式的鐵的封入量以發光管11的每單位容積1[cm3 ]計為0.010[mg]以上且0.040[mg]以下。In addition, the enclosed amount of iron in the embodiment described below is 0.010 [mg] or more and 0.040 [mg] or less in terms of 1 [cm 3 ] per unit volume of the arc tube 11.

而且,以下說明的實施方式的金屬鹵化物燈10中,從發光管11照射的光的均勻度為5[%]以下。Furthermore, in the metal halide lamp 10 of the embodiment described below, the uniformity of the light irradiated from the arc tube 11 is 5 [%] or less.

而且,以下說明的實施方式的金屬鹵化物燈10中,發光管11的管軸方向的相對照度為90[%]以上。Furthermore, in the metal halide lamp 10 of the embodiment described below, the relative illumination in the tube axis direction of the arc tube 11 is 90 [%] or more.

而且,以下說明的實施方式的金屬鹵化物燈10中,點亮中的發光管11的表面溫度為760[℃]以上且850[℃]以下。In addition, in the metal halide lamp 10 of the embodiment described below, the surface temperature of the arc tube 11 during lighting is 760 [° C.] or more and 850 [° C.] or less.

而且,以下說明的實施方式的紫外線照射裝置100包括金屬鹵化物燈10與安裝部20。安裝部20安裝金屬鹵化物燈10。Furthermore, the ultraviolet irradiation device 100 of the embodiment described below includes a metal halide lamp 10 and a mounting portion 20. The mounting part 20 mounts the metal halide lamp 10.

以下,基於附圖來說明本發明的實施方式。另外,以下所示的各實施方式並不限定本發明所公開的技術。而且,以下所示的各實施方式及各變形例能夠在不矛盾的範圍內適當組合。而且,各實施方式的說明中,對於同一結構標注同一符號並適當省略後文的說明。 [實施方式]Hereinafter, embodiments of the present invention will be described based on the drawings. In addition, each embodiment shown below does not limit the technique disclosed by this invention. In addition, each embodiment and each modification shown below can be appropriately combined within a range that does not contradict each other. In the description of the respective embodiments, the same reference numerals are given to the same configuration, and the following description is appropriately omitted. [Implementation]

首先,使用圖1來說明實施方式的金屬鹵化物燈及紫外線照射裝置的結構例。圖1是實施方式的紫外線照射裝置的側面圖。圖1所示的紫外線照射裝置100具有金屬鹵化物燈10與燈具30。燈具30具有安裝部20、遮風板31與排氣口32,且例如構成為,使紫外線照射裝置100設置於天花板等規定位置。圖1所示的紫外線照射裝置100例如能夠用於半導體的曝光工序、或者紫外線固化型油墨或紫外線固化塗料的乾燥工序、紫外線固化型樹脂的固化工序等借助紫外線進行光化學反應的工序中。First, a configuration example of the metal halide lamp and the ultraviolet irradiation device according to the embodiment will be described using FIG. 1. Fig. 1 is a side view of an ultraviolet irradiation device according to an embodiment. The ultraviolet irradiation device 100 shown in FIG. 1 has a metal halide lamp 10 and a lamp 30. The lamp 30 has an attachment portion 20, a wind shield 31, and an exhaust port 32, and is configured, for example, such that the ultraviolet irradiation device 100 is installed at a predetermined position such as a ceiling. The ultraviolet irradiation device 100 shown in FIG. 1 can be used, for example, in a semiconductor exposure process, a drying process of an ultraviolet curable ink or an ultraviolet curable paint, a curing process of an ultraviolet curable resin, and the like in a process of performing a photochemical reaction by ultraviolet rays.

安裝部20可裝卸地安裝金屬鹵化物燈10。安裝部20具有未圖示的保持構件,所述保持構件保持金屬鹵化物燈10所具有的後述的燈頭構件13。保持構件是由具有導電性的金屬材料所形成,與未圖示的電源裝置電連接。保持構件經由後述的外部導線17來對金屬鹵化物燈10供給電力。而且,為了提高燈頭構件13的散熱性,保持構件也可由導熱率高的材料所形成。The mounting part 20 mounts the metal halide lamp 10 detachably. The attachment portion 20 has a holding member (not shown) that holds a base member 13 described later that the metal halide lamp 10 has. The holding member is formed of a conductive metal material, and is electrically connected to a power supply device not shown. The holding member supplies electric power to the metal halide lamp 10 via an external lead 17 described later. Furthermore, in order to improve the heat dissipation of the base member 13, the holding member may be formed of a material with high thermal conductivity.

遮風板31被配置於安裝部20的上方,通過使因金屬鹵化物燈10的發熱而受熱的空氣逸散至排氣口32側,從而抑制伴隨金屬鹵化物燈10的過熱引起的、後述的發光管11的黑化。遮風板31以沿著金屬鹵化物燈10的管軸方向的方式而配置有多個。The windshield 31 is arranged above the mounting portion 20, and by dissipating the air heated by the heat of the metal halide lamp 10 to the exhaust port 32 side, it suppresses the overheating of the metal halide lamp 10, which will be described later. The blackening of the luminous tube 11. A plurality of wind shields 31 are arranged along the tube axis direction of the metal halide lamp 10.

排氣口32是設在燈具30上部的開口。排氣口32連接於未圖示的外部的排氣鼓風機(blower)。排氣口32將因點亮中的金屬鹵化物燈10的發熱而受熱的空氣從安裝部20強制性地排出,由此,能夠抑制因金屬鹵化物燈10的過熱引起的問題。The exhaust port 32 is an opening provided in the upper part of the lamp 30. The exhaust port 32 is connected to an external exhaust blower (not shown). The exhaust port 32 forcibly exhausts the air heated by the heat generated by the lighting metal halide lamp 10 from the mounting portion 20, thereby suppressing problems caused by overheating of the metal halide lamp 10.

各遮風板31相對於金屬鹵化物燈10的角度或排氣口32是配置成,點亮中的金屬鹵化物燈10所具有的發光管11的表面溫度處於規定範圍,例如760[℃]以上且850[℃]以下。而且,也可在夾著金屬鹵化物燈10而與遮風板31及排氣口32相對的位置設置風扇(fan),以朝向金屬鹵化物燈10送氣。另外,遮風板31及排氣口32是對安裝於安裝部20的金屬鹵化物燈10進行冷卻的冷卻機構的一例,也可未必為圖示的結構。The angle of each windshield 31 with respect to the metal halide lamp 10 or the exhaust port 32 is arranged so that the surface temperature of the arc tube 11 of the metal halide lamp 10 that is lighting is within a predetermined range, for example, 760 [°C] Above and below 850[°C]. In addition, a fan may be provided at a position facing the wind shield 31 and the exhaust port 32 with the metal halide lamp 10 sandwiched therebetween to blow air toward the metal halide lamp 10. In addition, the wind shield 31 and the exhaust port 32 are an example of a cooling mechanism that cools the metal halide lamp 10 attached to the mounting portion 20, and they may not necessarily have the structure shown in the figure.

(金屬鹵化物燈的結構) 如圖1所示,實施方式的金屬鹵化物燈10包括發光管11、密封部12、燈頭構件13、電極14、金屬箔15、內部引線16與外部引線17。(Structure of metal halide lamp) As shown in FIG. 1, the metal halide lamp 10 of the embodiment includes an arc tube 11, a sealing portion 12, a base member 13, an electrode 14, a metal foil 15, an inner lead 16 and an outer lead 17.

發光管11形成為管狀,由設在管軸方向兩端的密封部12予以密封。發光管11例如為石英玻璃,使紫外線透過。而且,發光管11在內部具有空間11a,在空間11a內,至少封入有金屬鹵化物(metal halide)、鐵與水銀。作為封入空間11a內的金屬鹵化物,例如使用碘化鉈(TlI)。若將蒸汽壓比鐵高的鉈封入發光管11的內部,則具有下述效果,即:在金屬鹵化物燈10的點亮中,在發光管11的內壁附近蒸氣化的鉈起到緩衝材的作用,以抑制鐵向發光管11的附著或滲入。另外,作為封入空間11a內的金屬鹵化物的鹵素,例如也可使用氯、溴等。另外,關於封入空間11a內的封入物的成分或封入量的詳細將後述。The arc tube 11 is formed in a tube shape, and is sealed by sealing portions 12 provided at both ends in the tube axis direction. The arc tube 11 is, for example, quartz glass, and transmits ultraviolet rays. Furthermore, the arc tube 11 has a space 11a inside, and at least a metal halide, iron, and mercury are enclosed in the space 11a. As the metal halide enclosed in the space 11a, for example, thallium iodide (TlI) is used. If thallium, which has a higher vapor pressure than iron, is enclosed in the arc tube 11, there is an effect that the thallium vaporized near the inner wall of the arc tube 11 acts as a buffer during the lighting of the metal halide lamp 10 The role of the material to inhibit the adhesion or penetration of iron to the arc tube 11. In addition, as the halogen of the metal halide enclosed in the space 11a, for example, chlorine, bromine, etc. may be used. In addition, the details of the components and the enclosed amount of the enclosed material in the enclosed space 11a will be described later.

密封部12通過收縮(shrink)密封而形成為圓柱狀。另外,密封部12也可通過箍縮(pinch)密封而形成為板狀。The sealing part 12 is formed in a cylindrical shape by shrink sealing. In addition, the sealing portion 12 may be formed in a plate shape by pinch sealing.

燈頭構件13是以對在發光管11的管軸方向兩端部形成的密封部12的外周進行覆蓋的方式而分別配置,支撐發光管11。The base members 13 are respectively arranged so as to cover the outer periphery of the sealing portion 12 formed at both ends of the arc tube 11 in the tube axis direction, and support the arc tube 11.

電極14是以在管軸方向上以規定間隔L1彼此相對的方式而配置在空間11a的內部。電極14為內部引線16的一端部,內部引線16的另一端與金屬箔15電連接。電極14例如為包含作為電子放射性物質的氧化釷的鍍釷鎢(thoriated tungsten)。內部引線16例如是由與電極14相同的鍍釷鎢而一體地形成。另外,電極14或內部導線16並不限定於所述,例如內部導線16也可與電極14獨立地構成,例如也可為在鎢中摻雜(dope)有鉀或矽的摻雜鎢。The electrodes 14 are arranged in the space 11a so as to face each other at a predetermined interval L1 in the tube axis direction. The electrode 14 is one end of the inner lead 16, and the other end of the inner lead 16 is electrically connected to the metal foil 15. The electrode 14 is, for example, a thoriated tungsten containing thorium oxide as an electron radioactive substance. The inner lead 16 is integrally formed of, for example, the same thoriated tungsten plated as the electrode 14. In addition, the electrode 14 or the internal lead 16 is not limited to the above. For example, the internal lead 16 may be formed separately from the electrode 14, for example, tungsten doped with potassium or silicon doped with tungsten.

金屬箔15的一端與內部引線16連接,另一端與外部引線17連接。金屬箔15被分別嵌設於密封部12的內部。金屬箔15例如為鉬箔。One end of the metal foil 15 is connected to the inner lead 16 and the other end is connected to the outer lead 17. The metal foil 15 is embedded in the inside of the sealing part 12, respectively. The metal foil 15 is, for example, a molybdenum foil.

外部引線17連接金屬箔15與外部的未圖示的電源裝置。外部引線17例如為鉬棒。外部引線17的一端分別連接於金屬箔15,另一端露出至發光管11的外部。外部引線17的另一端經由未圖示的連接器而與未圖示的纜線(cable)電連接。即,實施方式的金屬鹵化物燈10對應於經由與外部的未圖示的電源裝置連接的連接器、纜線、外部引線17、金屬箔15、內部引線16而從電源裝置供給至電極14的電力來放電,以放射紫外光。The external lead 17 connects the metal foil 15 to an external power supply device not shown. The external lead 17 is, for example, a molybdenum rod. One end of the external lead 17 is connected to the metal foil 15 respectively, and the other end is exposed to the outside of the arc tube 11. The other end of the external lead 17 is electrically connected to a cable (not shown) via a connector (not shown). That is, the metal halide lamp 10 of the embodiment corresponds to the power supply from the power supply device to the electrode 14 via the connector, cable, external lead 17, metal foil 15, and internal lead 16 connected to an external power supply device not shown. Electricity discharges to emit ultraviolet light.

(發光管中的鐵及鉈的封入量) 圖2是表示對相對於碘化鉈封入量的365nm相對照度進行比較的結果的圖。另外,作為金屬鹵化物燈10,使用發光管徑26[mm]、壁厚1.5[mm]、發光長L1(參照圖1)1200[mm]、全長L2(參照圖1)1300[mm]者。而且,只要未特別說明,則在圖3以後的說明中,也分別使用相同的金屬鹵化物燈10。(The amount of iron and thallium enclosed in the arc tube) Fig. 2 is a graph showing the results of comparing the 365 nm phase contrast with the amount of thallium iodide enclosed. In addition, as the metal halide lamp 10, a luminous tube diameter of 26 [mm], a wall thickness of 1.5 [mm], a luminous length L1 (refer to Fig. 1) 1200 [mm], and a total length L2 (refer to Fig. 1) of 1300 [mm] . In addition, unless otherwise specified, the same metal halide lamp 10 is also used in the description after FIG. 3.

而且,對於封入有以空間11a的每單位容積1[cm3 ]計為0.025[mg]的鐵,進而封入有以空間11a的每單位容積1[cm3 ]計為0.004[mg]、0.008[mg]、0.012[mg]、0.018[mg]的碘化鉈的金屬鹵化物燈10,在發光管11的表面溫度800[℃]時分別測定以燈功率18000[Wrms]點亮時的波長365[nm]下的照度,將TlI0.004[mg/cm3 ]時的實測值作為100[%]而進行標準化。此處,所謂“發光管11的表面溫度”,是指如下所述的值,即,基於通過燈點亮中的管內蒸氣的對流而放電弧柱位於上側的情況,對發光管上表面的管壁溫度進行測定所得的值。發光管上表面的管壁溫度例如是通過K熱電偶而測定。而且,照度是在從位於發光管11的管軸方向中央的發光管11的表面朝發光管11的徑方向隔開1[m]的位置配置作為被照射體的感測器(ORC製作所制:UV-SD35-M10),使用照度計(ORC製作所制:UV-M03A)而測定。Further, for the enclosed per unit space 11a volume 1 [cm 3] calculated as 0.025 [mg] of the iron, and thus is enclosed per unit space 11a volume 1 [cm 3] calculated as 0.004 [mg], 0.008 [ mg], 0.012[mg], 0.018[mg] thallium iodide metal halide lamp 10, when the surface temperature of the arc tube 11 is 800[℃], the wavelength when lit with the lamp power of 18000[Wrms] is measured 365 The illuminance in [nm] is standardized with the actual measurement value at TlI0.004 [mg/cm 3 ] as 100 [%]. Here, the "surface temperature of the arc tube 11" refers to a value based on the situation where the arc column is located on the upper side by the convection of the vapor in the tube while the lamp is on. The tube wall temperature is the value obtained by measuring. The tube wall temperature on the upper surface of the arc tube is measured by a K thermocouple, for example. In addition, the illuminance is that a sensor (manufactured by ORC Manufacturing Co., Ltd.: UV-SD35-M10), measured using an illuminance meter (ORC Manufacturing Co., Ltd.: UV-M03A).

如圖2所示,在碘化鉈封入量為0.018[mg/cm3 ]的情況下,相對強度低至90[%],無法確保所需的照度特性。與此相對,在碘化鉈封入量為0.012[mg/cm3 ]以下的金屬鹵化物燈10中,相對強度呈現95[%]以上的高的值。即,表示了:通過將碘化鉈封入量設為0.012[mg/cm3 ]以下,能夠確保所需的照度特性。As shown in Fig. 2, when the enclosed thallium iodide amount is 0.018 [mg/cm 3 ], the relative strength is as low as 90 [%], and the required illuminance characteristics cannot be ensured. In contrast, in the metal halide lamp 10 in which the enclosed thallium iodide amount is 0.012 [mg/cm 3 ] or less, the relative intensity exhibits a high value of 95 [%] or more. That is, it is shown that by setting the enclosed amount of thallium iodide to 0.012 [mg/cm 3 ] or less, the required illuminance characteristics can be secured.

圖3是表示對應於每種碘化鉈封入量而對發光管溫度與365nm相對照度的關係進行比較的結果的圖。圖3是對於封入有以空間11a的每單位容積1[cm3 ]計為0.025[mg]的鐵,進而分別封入有以空間11a的每單位容積1[cm3 ]計為0.012[mg]、0.008[mg]、0.004[mg]的碘化鉈的金屬鹵化物燈10,在發光管11的表面溫度765[℃]、773[℃]、780[℃]、800[℃]時,分別測定以燈功率18000[Wrms]點亮時的波長365[nm]下的照度,並將發光管11的表面溫度800[℃]時的實測值作為100[%]來進行標準化,並圖示者。Fig. 3 is a graph showing the result of comparing the relationship between the temperature of the arc tube and the illuminance at 365 nm for each type of thallium iodide enclosed amount. 3 is a graph enclosed per unit space 11a volume 1 [cm 3] calculated as 0.025 [mg] of the iron, and thus are enclosed per unit space 11a volume 1 [cm 3] calculated as 0.012 [mg], The metal halide lamp 10 of thallium iodide of 0.008[mg] and 0.004[mg] is measured at the surface temperature of the arc tube 11 at 765[℃], 773[℃], 780[℃], 800[℃] The illuminance at a wavelength of 365 [nm] when the lamp power is 18000 [Wrms] is used for lighting, and the actual measurement value at the surface temperature of the arc tube 11 at 800 [°C] is normalized as 100 [%], and the figure is shown.

如圖3所示,伴隨發光管11的表面溫度的下降,照度也下降。尤其,在封入有0.004[mg/cm3 ]的碘化鉈的金屬鹵化物燈10中,發光管11的表面溫度765[℃]時的照度下降至85[%]左右(85.8[%])。As shown in FIG. 3, as the surface temperature of the arc tube 11 decreases, the illuminance also decreases. In particular, in the metal halide lamp 10 containing 0.004 [mg/cm 3 ] thallium iodide, the illuminance at the surface temperature of the arc tube 11 at 765 [°C] drops to about 85 [%] (85.8 [%]) .

接下來,使用圖4~圖6來說明鉈的封入量對於鐵的發光強度的影響。圖4~圖6是表示對應於每種發光管表面溫度而對使碘化鉈封入量發生變化時的分光分佈進行比較的結果的圖。與圖2、圖3同樣,在發光管11的表面溫度800[℃]、765[℃]時,分別測定將鐵的封入量固定為0.025[mg/cm3 ],另一方面,將碘化鉈封入量設為0.012[mg/cm3 ](圖4)、0.008[mg/cm3 ](圖5)、0.004[mg/cm3 ](圖6)的金屬鹵化物燈10的分光分佈。另外,關於分光分佈,是對於使用在從位於發光管11的管軸方向中央的發光管11的表面朝發光管11的徑方向隔開1[m]的位置處配置的MCPD-9800(大塚電子股份有限公司制)而測定出的實測值,將鐵的發光輝線即375[nm]的光譜值設為100[%]來進行標準化,進而,將在碘化鉈封入量0.004[mg/cm3 ]、發光管11的表面溫度800[℃]的條件下測定出的照度值作為基準來乘以各光譜資料,以進行標準化並予以圖示,由此使得能夠與圖4~圖6所示的照度值直接進行比較。Next, the influence of the enclosed amount of thallium on the luminescence intensity of iron will be explained using FIGS. 4 to 6. 4 to 6 are graphs showing the results of comparison of the spectral distribution when the amount of thallium iodide enclosed is changed in accordance with the surface temperature of each arc tube. As with Figures 2 and 3, when the surface temperature of the arc tube 11 is 800 [℃] and 765 [℃], the enclosed amount of iron is measured and fixed to 0.025 [mg/cm 3 ]. On the other hand, the iodide is The amount of thallium enclosed is the spectral distribution of the metal halide lamp 10 of 0.012 [mg/cm 3 ] (Figure 4), 0.008 [mg/cm 3 ] (Figure 5), and 0.004 [mg/cm 3 ] (Figure 6). In addition, regarding the spectral distribution, the MCPD-9800 (Otsuka Electronics Co., Ltd.) is used at a position spaced 1 [m] away from the surface of the arc tube 11 located at the center of the tube axis of the arc tube 11 in the radial direction of the arc tube 11. Co., Ltd.) and the measured value is standardized by setting the spectrum value of 375 [nm], which is the luminescence line of iron, to 100 [%]. Furthermore, the amount of thallium iodide enclosed is 0.004 [mg/cm 3 ], the illuminance value measured under the condition of the surface temperature of the arc tube 11 at 800 [°C] is used as a reference to multiply each spectrum data to standardize and graph it, so that it can be compared with those shown in FIGS. 4 to 6 The illuminance values are directly compared.

如圖5、圖6所示,在碘化鉈封入量為0.008[mg/cm3 ]、0.004[mg/cm3 ]的情況下,維持了主發光即來源於鐵的輝線(波長375[nm]、383[nm])的相對強度高的狀態。尤其,在碘化鉈封入量為0.004[mg/cm3 ]的情況下,碘化鉈封入量不足,難以抑制發光管11的黑化。另一方面,如圖4所示,在碘化鉈封入量為0.012[mg/cm3 ]的情況下,與來源於鉈的輝線(波長353[nm]、378[nm])的相對強度相比,來源於鐵的輝線的相對強度較低。這樣,若碘化鉈封入量過度增加,則鐵的發光效率下降,成為紫外光發光強度指標的365[nm]照度下降。所述鐵的發光效率的下降在發光管11的表面溫度高的800[℃]時變得更為顯著。As shown in Figure 5 and Figure 6, when the enclosed thallium iodide amount is 0.008 [mg/cm 3 ] and 0.004 [mg/cm 3 ], the main luminescence, that is, the glow line derived from iron (wavelength 375 [nm ], 383[nm]) in a state of high relative intensity. In particular, when the enclosed thallium iodide amount is 0.004 [mg/cm 3 ], the enclosed thallium iodide amount is insufficient, and it is difficult to suppress the blackening of the arc tube 11. On the other hand, as shown in Figure 4, when the amount of thallium iodide enclosed is 0.012 [mg/cm 3 ], the relative intensity of the glow line (wavelength 353 [nm], 378 [nm]) derived from thallium is comparable to Compared with, the relative strength of the glow wire derived from iron is lower. In this way, if the amount of thallium iodide enclosed is excessively increased, the luminous efficiency of iron decreases, and the illuminance of 365 [nm], which is an index of the intensity of ultraviolet light, decreases. The decrease in the luminous efficiency of the iron becomes more remarkable when the surface temperature of the arc tube 11 is high at 800 [°C].

接下來,使用圖7~圖9來說明鉈的封入量對於從發光管照射的光的均勻度的影響。圖7是表示對各測定點的發光管的表面溫度進行比較的結果的圖。圖8是表示對應於每種碘化鉈封入量而對各測定點的UV-35照度進行比較的結果的圖。另外,圖7中,是對將鐵的封入量及碘化鉈的封入量分別設為0.025[mg/cm3 ]、0.012[mg/cm3 ]者進行測定。而且,圖8中,分別製作將鐵的封入量固定為0.025[mg/cm3 ],另一方面,將碘化鉈封入量設為0.012[mg/cm3 ]、0.008[mg/cm3 ]、0.004[mg/cm3 ]的金屬鹵化物燈10,並進行測定。Next, the influence of the enclosed amount of thallium on the uniformity of light irradiated from the arc tube will be explained using FIGS. 7 to 9. Fig. 7 is a graph showing the result of comparing the surface temperature of the arc tube at each measurement point. Fig. 8 is a graph showing the result of comparing the UV-35 illuminance at each measurement point for each type of thallium iodide enclosed amount. In addition, in FIG. 7, the enclosed amount of iron and the enclosed amount of thallium iodide were measured as 0.025 [mg/cm 3 ] and 0.012 [mg/cm 3 ], respectively. In addition, in Fig. 8, the enclosed amount of iron is fixed to 0.025 [mg/cm 3 ], while the enclosed amount of thallium iodide is set to 0.012 [mg/cm 3 ] and 0.008 [mg/cm 3 ]. , 0.004 [mg/cm 3 ] metal halide lamp 10, and perform the measurement.

圖7、圖8中,對於“測定點[mm]”,是將發光長L1=1200[mm]的發光管11的管軸方向的中央規定為600[mm],將沿著發光管11的管軸方向隔開300[mm]的部位分別規定為300[mm]、900[mm]。而且,圖8中,所謂“UV-35照度”,是指使用在波長310[nm]~700[nm]處具備靈敏度曲線的感測器(ORC製作所制:UV-SD35-M10)、照度計(ORC製作所制:UV-M03A)而測定所得的值。並且,在圖7中,圖示了各測定點(300[mm]、600[mm]、900[mm])處的表面溫度,在圖8中,對於在從圖7中的各測定點朝發光管11的徑方向隔開1[m]的位置分別配置作為被照射體的感測器(ORC製作所制:UV-SD35-M10),並使用照度計(ORC製作所制:UV-M03A)而測定出的UV-35照度的值,將測定點600[mm]處的值作為100[%]來進行標準化並予以圖示。In FIGS. 7 and 8, for the "measurement point [mm]", the center of the tube axis direction of the arc tube 11 with the light emission length L1=1200 [mm] is defined as 600 [mm], and the distance along the arc tube 11 The positions separated by 300 [mm] in the pipe axis direction are respectively specified as 300 [mm] and 900 [mm]. In addition, in Fig. 8, the "UV-35 illuminance" refers to the use of a sensor (manufactured by ORC Manufacturing Co., Ltd.: UV-SD35-M10) and an illuminance meter with a sensitivity curve at a wavelength of 310 [nm] to 700 [nm] (ORC Manufacturing Co., Ltd.: UV-M03A) and measured the obtained value. In addition, in FIG. 7, the surface temperature at each measurement point (300 [mm], 600 [mm], 900 [mm]) is illustrated. In FIG. 8, the Sensors (UV-SD35-M10, manufactured by ORC Manufacturing Co., Ltd.) are arranged at positions separated by 1 [m] in the radial direction of the arc tube 11, and an illuminance meter (manufactured by ORC Manufacturing Co., Ltd.: UV-M03A) is used. The measured UV-35 illuminance value is normalized and graphed with the value at the measurement point 600 [mm] as 100 [%].

如圖7所示可知,發光管11的表面溫度在中央部分(600[mm])為最高,且隨著從中央部分朝管軸方向遠離而變低。而且,在圖7所示的示例中,測定點300[mm]、900[mm]處的發光管11的表面溫度根據環境條件而不同,如圖8所示,追隨於所述表面溫度的不同,UV-35照度也不同。尤其可知,在碘化鉈封入量為0.004[mg/cm3 ]的情況下,發光管11的表面溫度對UV-35照度的影響變得顯著。As shown in FIG. 7, it can be seen that the surface temperature of the arc tube 11 is highest in the central part (600 [mm]), and becomes lower as it moves away from the central part in the tube axis direction. Furthermore, in the example shown in FIG. 7, the surface temperature of the arc tube 11 at the measurement points 300 [mm] and 900 [mm] differs according to environmental conditions, as shown in FIG. 8, following the difference in the surface temperature , UV-35 illumination is also different. In particular, when the enclosed thallium iodide amount is 0.004 [mg/cm 3 ], the influence of the surface temperature of the arc tube 11 on the UV-35 illuminance becomes significant.

圖9是表示對應於每種碘化鉈封入量而對均勻度進行比較的結果的圖。圖9中,“均勻度[%]”是作為(最大照度-最小照度)/(最大照度+最小照度)×100而算出。若舉碘化鉈封入量為0.004[mg/cm3 ]的情況為例,則為(100-85.8)/(100+85.8)=7.64[%]。Fig. 9 is a graph showing the results of comparing the uniformity for each type of thallium iodide enclosed amount. In Fig. 9, "uniformity [%]" is calculated as (maximum illuminance-minimum illuminance)/(maximum illuminance + minimum illuminance)×100. Taking a case where the amount of thallium iodide enclosed is 0.004 [mg/cm 3 ] as an example, it is (100-85.8)/(100+85.8)=7.64[%].

從發光管11照射的光的均勻度是成為對紫外光相對於被照射面的照射不均進行判定的指標的值,可設定為5[%]以下。The uniformity of the light irradiated from the arc tube 11 is a value used as an index for judging the unevenness of the irradiation of ultraviolet light with respect to the irradiated surface, and can be set to 5 [%] or less.

而且,作為用於對紫外光相對於被照射面的照射不均進行判定的其他指標,可使用發光管11的管軸方向的相對照度。此處,所謂“發光管11的管軸方向的相對照度”,是指如圖8所示,將發光管11的管軸方向的中央(600[mm])的值作為100[%]而對UV-35照度的值進行標準化時的、各測定點處的相對照度的最小值。發光管11的管軸方向的相對照度為90[%]以上的金屬鹵化物燈10中,紫外光相對於被照射面的照射不均少,可以說適合於實際使用。Moreover, as another index for determining the unevenness of the irradiation of ultraviolet light with respect to the irradiated surface, the relative illuminance in the tube axis direction of the arc tube 11 can be used. Here, the "relative illuminance in the tube axis direction of the arc tube 11" refers to the value of the center (600 [mm]) of the tube axis direction of the arc tube 11 as 100 [%] as shown in FIG. The minimum value of relative illuminance at each measurement point when the value of UV-35 illuminance is normalized. In the metal halide lamp 10 in which the relative illuminance in the tube axis direction of the arc tube 11 is 90 [%] or more, there is little unevenness in the irradiation of ultraviolet light to the irradiated surface, and it can be said that it is suitable for practical use.

基於所述的多個實驗結果,得到下述結果,即,在金屬鹵化物燈10中,理想的是,封入發光管11內部的碘化鉈以發光管11的每單位容積1[cm3 ]計為0.008[mg]以上且0.012[mg]以下。通過像這樣向發光管11的內部封入適量的碘化鉈,既能抑制劣化,又能確保所需的照度特性。Based on the aforementioned experimental results, the following results were obtained. That is, in the metal halide lamp 10, it is desirable that the thallium iodide enclosed in the arc tube 11 is 1 [cm 3 ] per unit volume of the arc tube 11 It is 0.008 [mg] or more and 0.012 [mg] or less. By enclosing an appropriate amount of thallium iodide into the arc tube 11 in this way, deterioration can be suppressed and the required illuminance characteristics can be ensured.

另外,所述實施方式中,表示了封入有碘化鉈作為金屬鹵化物的示例,但並不限於此,只要封入以發光管11的每單位容積1[cm3 ]計為0.005[mg]以上且0.0076[mg]以下的鉈即可。In addition, in the above embodiment, an example is shown in which thallium iodide is enclosed as a metal halide, but it is not limited to this, as long as the enclosure is 0.005 [mg] or more per unit volume 1 [cm 3 ] of the arc tube 11 Thallium less than 0.0076 [mg] is sufficient.

而且,所述實施方式中,將鐵的封入量固定為0.025[mg/cm3 ]而進行了說明,但並不限於此,只要封入以發光管11的每單位容積1[cm3 ]計為0.010[mg]以上且0.040[mg]以下的鐵即可。此時,通過將鉈相對於鐵的封入量以品質比計設為0.2以上且0.3以下,既能抑制劣化,又能確保所需的照度特性。In addition, in the above-mentioned embodiment, the enclosed amount of iron is fixed to 0.025 [mg/cm 3 ], but it is not limited to this, as long as the enclosed amount is calculated as 1 [cm 3 ] per unit volume of the arc tube 11 Iron of 0.010 [mg] or more and 0.040 [mg] or less is sufficient. At this time, by setting the enclosed amount of thallium with respect to iron to be 0.2 or more and 0.3 or less in terms of mass ratio, deterioration can be suppressed and the required illuminance characteristics can be ensured.

如上所述,實施方式的金屬鹵化物燈10包括發光管11與電極14。在發光管11中,封入有鹵素、鐵及鉈。電極14被設在發光管11的內部。鉈相對於鐵的封入量以品質比計為0.2以上且0.3以下。由此,既能抑制發光管11的劣化,又能確保所需的照度特性。As described above, the metal halide lamp 10 of the embodiment includes the arc tube 11 and the electrode 14. In the arc tube 11, halogen, iron, and thallium are enclosed. The electrode 14 is provided inside the arc tube 11. The enclosed amount of thallium to iron is 0.2 or more and 0.3 or less in terms of mass ratio. As a result, the deterioration of the arc tube 11 can be suppressed, and the required illuminance characteristics can be ensured.

而且,實施方式的金屬鹵化物燈10中,從發光管11照射的光的均勻度為5[%]以下。由此,能夠減少紫外光相對於被照射面的照射不均。Furthermore, in the metal halide lamp 10 of the embodiment, the uniformity of the light irradiated from the arc tube 11 is 5 [%] or less. Thereby, it is possible to reduce the unevenness in the irradiation of ultraviolet light with respect to the irradiated surface.

而且,實施方式的金屬鹵化物燈10中,發光管11的管軸方向的相對照度為90[%]以上。由此,能夠減少紫外光相對於被照射面的照射不均。In addition, in the metal halide lamp 10 of the embodiment, the relative illuminance in the tube axis direction of the arc tube 11 is 90 [%] or more. Thereby, it is possible to reduce the unevenness in the irradiation of ultraviolet light with respect to the irradiated surface.

而且,實施方式的金屬鹵化物燈10中,點亮中的發光管11的表面溫度為760[℃]以上且850[℃]以下。由此,能夠減少紫外光相對於被照射面的照射不均。Furthermore, in the metal halide lamp 10 of the embodiment, the surface temperature of the arc tube 11 during lighting is 760 [°C] or more and 850 [°C] or less. Thereby, it is possible to reduce the unevenness in the irradiation of ultraviolet light with respect to the irradiated surface.

而且,實施方式的紫外線照射裝置100包括金屬鹵化物燈10與安裝部20。安裝部20安裝金屬鹵化物燈10。由此,既能抑制發光管11的劣化,又能確保所需的照度特性。進而,能夠減少紫外光相對於被照射面的照射不均。Furthermore, the ultraviolet irradiation device 100 of the embodiment includes a metal halide lamp 10 and a mounting part 20. The mounting part 20 mounts the metal halide lamp 10. As a result, the deterioration of the arc tube 11 can be suppressed, and the required illuminance characteristics can be ensured. Furthermore, it is possible to reduce the unevenness in the irradiation of ultraviolet light with respect to the irradiated surface.

對本發明的實施方式進行了說明,但實施方式僅為例示,並不意圖限定發明的範圍。這些實施方式能夠以其他的各種形態來實施,能夠在不脫離發明主旨的範圍內進行各種省略、替換、變更。這些實施方式或其變形包含在發明的範圍或主旨中,同樣包含在權利要求書所記載的發明及其均等的範圍內。The embodiments of the present invention have been described, but the embodiments are only examples and are not intended to limit the scope of the invention. These embodiments can be implemented in other various forms, and various omissions, substitutions, and changes can be made without departing from the scope of the invention. These embodiments and their modifications are included in the scope or spirit of the invention, and are also included in the invention described in the claims and their equivalent scope.

10:金屬鹵化物燈 11:發光管 11a:空間 12:密封部 13:燈頭構件 14:電極 15:金屬箔 16:內部引線 17:外部引線 20:安裝部 30:燈具 31:遮風板 32:排氣口 100:紫外線照射裝置 L1:規定間隔、發光長 L2:全長10: Metal halide lamp 11: luminous tube 11a: Space 12: Sealing part 13: Lamp holder components 14: Electrode 15: Metal foil 16: internal lead 17: External lead 20: Installation Department 30: lamps 31: Windshield 32: exhaust port 100: Ultraviolet irradiation device L1: Specified interval, long light emission L2: Full length

圖1是實施方式的紫外線照射裝置的側面圖。 圖2是表示對相對於碘化鉈封入量的365nm相對照度進行比較的結果的圖。 圖3是表示對應於每種碘化鉈封入量而對發光管溫度與365nm相對照度的關係進行比較的結果的圖。 圖4是表示對應於每種發光管表面溫度而對使碘化鉈封入量發生變化時的分光分佈進行比較的結果的圖。 圖5是表示對應於每種發光管表面溫度而對使碘化鉈封入量發生變化時的分光分佈進行比較的結果的圖。 圖6是表示對應於每種發光管表面溫度而對使碘化鉈封入量發生變化時的分光分佈進行比較的結果的圖。 圖7是表示對各測定點的發光管表面溫度進行比較的結果的圖。 圖8是表示對應於每種碘化鉈封入量而對各測定點的UV-35照度進行比較的結果的圖。 圖9是表示對應於每種碘化鉈封入量而對均勻度進行比較的結果的圖。Fig. 1 is a side view of an ultraviolet irradiation device according to an embodiment. Fig. 2 is a graph showing the results of comparing the 365 nm phase contrast with the amount of thallium iodide enclosed. Fig. 3 is a graph showing the result of comparing the relationship between the temperature of the arc tube and the illuminance at 365 nm for each type of thallium iodide enclosed amount. Fig. 4 is a graph showing the results of comparing the spectral distributions when the amount of thallium iodide enclosed is changed for each type of arc tube surface temperature. Fig. 5 is a graph showing the results of comparing the spectral distributions when the amount of thallium iodide enclosed is changed for each type of arc tube surface temperature. Fig. 6 is a graph showing the results of comparing the spectral distributions when the amount of thallium iodide enclosed is changed for each type of arc tube surface temperature. Fig. 7 is a graph showing the result of comparing the surface temperature of the arc tube at each measurement point. Fig. 8 is a graph showing the result of comparing the UV-35 illuminance at each measurement point for each type of thallium iodide enclosed amount. Fig. 9 is a graph showing the results of comparing the uniformity for each type of thallium iodide enclosed amount.

10:金屬鹵化物燈 10: Metal halide lamp

11:發光管 11: luminous tube

11a:空間 11a: Space

12:密封部 12: Sealing part

13:燈頭構件 13: Lamp holder components

14:電極 14: Electrode

15:金屬箔 15: Metal foil

16:內部引線 16: internal lead

17:外部引線 17: External lead

20:安裝部 20: Installation Department

30:燈具 30: lamps

31:遮風板 31: Windshield

32:排氣口 32: exhaust port

100:紫外線照射裝置 100: Ultraviolet irradiation device

L1:規定間隔、發光長 L1: Specified interval, long light emission

L2:全長 L2: Full length

Claims (8)

一種金屬鹵化物燈,其包括: 發光管,封入有鹵素、鐵及鉈;以及 電極,被設在所述發光管的內部, 所述鉈相對於所述鐵的封入量以品質比計為0.2以上且0.3以下。A metal halide lamp, which includes: Light emitting tube, sealed with halogen, iron and thallium; and The electrodes are arranged inside the luminous tube, The enclosed amount of the thallium with respect to the iron is 0.2 or more and 0.3 or less in terms of mass ratio. 如申請專利範圍第1項所述的金屬鹵化物燈,其中 所述鉈的封入量以所述發光管的每單位容積1[cm3 ]計為0.005[mg]以上且0.0076[mg]以下。The metal halide lamp described in the first item of the scope of patent application, wherein the enclosed amount of the thallium is 0.005 [mg] or more and 0.0076 [mg] or less per unit volume 1 [cm 3 ] of the arc tube. 如申請專利範圍第1項或第2項所述的金屬鹵化物燈,其中 所述鉈是作為以所述發光管的每單位容積1[cm3 ]計為0.008[mg]以上且0.012[mg]以下的碘化鉈而封入所述發光管的內部。The metal halide lamp as described in item 1 or item 2 of the scope of patent application, wherein the thallium is calculated as 0.008 [mg] or more and 0.012 [mg per unit volume 1 [cm 3 ] of the arc tube ] The following thallium iodide is enclosed in the arc tube. 如申請專利範圍第1項或第2項所述的金屬鹵化物燈,其中 所述鐵的封入量以所述發光管的每單位容積1[cm3 ]計為0.010[mg]以上且0.040[mg]以下。The metal halide lamp described in item 1 or item 2 of the scope of patent application, wherein the enclosed amount of iron is 0.010 [mg] or more and 0.040 [in terms of 1 [cm 3 ] per unit volume of the arc tube mg] or less. 如申請專利範圍第1項或第2項所述的金屬鹵化物燈,其中 從所述發光管照射的光的均勻度為5[%]以下。Such as the metal halide lamp described in item 1 or item 2 of the scope of patent application, wherein The uniformity of the light irradiated from the arc tube is 5 [%] or less. 如申請專利範圍第1項或第2項所述的金屬鹵化物燈,其中 所述發光管的管軸方向的相對照度為90[%]以上。Such as the metal halide lamp described in item 1 or item 2 of the scope of patent application, wherein The relative illuminance in the tube axis direction of the luminous tube is 90 [%] or more. 如申請專利範圍第1項或第2項所述的金屬鹵化物燈,其中 點亮中的所述發光管的表面溫度為760[℃]以上且850[℃]以下。Such as the metal halide lamp described in item 1 or item 2 of the scope of patent application, wherein The surface temperature of the arc tube during lighting is 760 [°C] or more and 850 [°C] or less. 一種紫外線照射裝置,其包括: 申請專利範圍第1項至第7項中任一項所述的金屬鹵化物燈;以及 安裝部,安裝所述金屬鹵化物燈。An ultraviolet irradiation device, which includes: The metal halide lamp described in any one of items 1 to 7 of the scope of patent application; and The installation part installs the metal halide lamp.
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