TW202021662A - Gas-liquid mixing device, and exhaust gas desulfurization device comprising gas-liquid mixing device - Google Patents

Gas-liquid mixing device, and exhaust gas desulfurization device comprising gas-liquid mixing device Download PDF

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TW202021662A
TW202021662A TW108129807A TW108129807A TW202021662A TW 202021662 A TW202021662 A TW 202021662A TW 108129807 A TW108129807 A TW 108129807A TW 108129807 A TW108129807 A TW 108129807A TW 202021662 A TW202021662 A TW 202021662A
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gas
cleaning liquid
liquid
introduction
fastening
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TWI720589B (en
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佐佐木良三
杉田覚
善積直之
宮地剛之
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日商三菱日立電力系統股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/04Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Nozzles (AREA)

Abstract

This spraying nozzle is provided with: a first cylinder part in which there are formed a cleansing liquid introduction opening for introducing a cleansing liquid, a gas introduction opening for introducing a gas along a direction orthogonal to the flow direction of the cleansing liquid, and a discharge opening for discharging a mixed fluid of the cleansing liquid and the gas; a throttling part provided farther upstream in the flow direction of the cleansing liquid than a merge part at which the cleansing liquid and the gas merge; and a second cylinder part in which there is formed a second gas introduction opening for introducing the gas into a second flow path that communicates with the gas introduction opening. This gas-liquid mixing device includes: the spraying nozzle; and an expansion joint that includes a barrel part configured so as to be capable of expanding and contracting, the expansion joint being provided to a cleansing liquid introduction line for sending the cleansing liquid from the cleansing liquid introduction opening into a first flow path and/or to a gas introduction line for sending the gas from the second gas introduction opening into the second flow path.

Description

氣液混合裝置及具備氣液混合裝置之排氣脫硫裝置Gas-liquid mixing device and exhaust desulfurization device with gas-liquid mixing device

本揭示係關於一種用以朝使清洗液與自燃燒裝置排出之排氣接觸之、吸收塔中之用於儲存清洗液之集液部噴射含氧之氣體及清洗液的氣液混合裝置、及具備該氣液混合裝置之排氣脫硫裝置。The present disclosure relates to a gas-liquid mixing device for spraying oxygen-containing gas and cleaning liquid toward the liquid collecting part of the absorption tower for storing the cleaning liquid in contact with the exhaust gas discharged from the combustion device, and An exhaust gas desulfurization device equipped with the gas-liquid mixing device.

自例如鍋爐等燃燒機排出之排氣中含有SOx (硫磺氧化物)等大氣污染物質。用以降低排氣中所含之SOx 之方法,有以鹼性水溶液或吸收劑漿料等吸收液將SO2 等吸收去除之濕式脫硫方法等。An exhaust gas discharged from a boiler and the like, for example, combustion engine containing SO x (sulfur oxides) and other air pollutants. The method used to reduce the SO x contained in the exhaust gas includes a wet desulfurization method in which SO 2 etc. are absorbed and removed with an absorbent such as alkaline aqueous solution or absorbent slurry.

使用上述濕式脫硫方法之排氣脫硫裝置中,有具備如下之吸收塔者,該吸收塔於內部劃定氣液接觸部及集液部,該氣液接觸部藉由將清洗液朝吸收塔內流動之排氣噴霧,而使排氣與清洗液接觸;該集液部位於氣液接觸部之下方,用以儲存噴霧後之清洗液(例如,參照專利文獻1)。因排氣與清洗液接觸,從而排氣中所含之SO2 被清洗液吸收。將吸收SO2 後之清洗液儲存於集液部。Among the exhaust gas desulfurization equipment using the above wet desulfurization method, there are those equipped with an absorption tower which defines a gas-liquid contact part and a liquid collecting part inside, and the gas-liquid contact part is directed to the cleaning liquid by The exhaust gas sprayed in the absorption tower makes the exhaust gas contact with the cleaning liquid; the liquid collecting part is located below the gas-liquid contact part for storing the sprayed cleaning liquid (for example, refer to Patent Document 1). As the exhaust gas contacts the cleaning liquid, the SO 2 contained in the exhaust gas is absorbed by the cleaning liquid. Store the cleaning liquid after absorbing SO 2 in the liquid collecting part.

由於儲存於集液部之清洗液中含有自排氣吸收之SO2 而產生而之亞硫酸鹽等反應生成物,故為了去除該反應生成物,有時會使空氣等含氧之氣體遍佈於儲存於集液部之清洗液而使反應生成物氧化。Since the cleaning liquid stored in the sump contains reaction products such as sulfite generated by the SO 2 absorbed from the exhaust gas, in order to remove the reaction products, oxygen-containing gas such as air may be spread over The cleaning liquid stored in the liquid collecting part oxidizes the reaction product.

於專利文獻1中揭示一種氣液混合裝置,其包含構成為將上述含氧之氣體與清洗液之混合流體自噴出口朝集液部噴射的噴射嘴。上述噴射嘴於清洗液之流道中途設置有限縮部,藉由該限縮部將上述流道中流動之清洗液縮流而產生負壓區域。藉由上述負壓區域中產生之吸引力,將經由分支配管供給之氣體朝較上述流道之限縮部更為下游側吸引。又,噴射嘴藉由上述清洗液之流道中流動之清洗液,將經吸引之氣體截斷、微細化而產生混合流體(包含微細氣泡之清洗液),且自噴出口噴射該混合流體。Patent Document 1 discloses a gas-liquid mixing device including an ejection nozzle configured to eject a mixed fluid of the above-mentioned oxygen-containing gas and cleaning liquid from an ejection port toward a liquid collecting portion. The spray nozzle is provided with a constriction in the middle of the flow path of the cleaning liquid, and the constriction part shrinks the flow of the cleaning liquid flowing in the flow path to generate a negative pressure area. Due to the suction force generated in the negative pressure region, the gas supplied through the branch pipe is sucked toward the downstream side of the constricted portion of the flow channel. In addition, the spray nozzle cuts the sucked gas by the cleaning liquid flowing in the flow channel of the cleaning liquid to produce a mixed fluid (cleaning liquid containing fine bubbles), and sprays the mixed fluid from the ejection port.

上述噴射嘴包含:主配管,其供清洗液(包含混合流體)流動;及上述分支配管(氣體導入管),其將氣體導入至主配管。此處,為效率良好地將氣體截斷、微細化,上述分支配管構成為其軸線沿著與主配管之軸線方向正交的方向延伸,在主配管中,沿著與清洗液之流動方向正交之方向導入氣體。氣液混合裝置除上述噴射嘴外,亦具備清洗液導入線與氣體導入線。清洗液導入線包含連接於主配管之清洗液導入管,且經由形成於主配管之清洗液導入口將清洗液導入至主配管。氣體導入線包含連接於分支配管之氣體導入管,且經由形成於分支配管之氣體導入口將氣體導入至分支配管。 [先前技術文獻] [專利文獻]The injection nozzle includes a main pipe for flowing a cleaning liquid (including a mixed fluid), and the branch pipe (gas introduction pipe) for introducing gas into the main pipe. Here, in order to efficiently cut off and miniaturize the gas, the branch piping is configured such that its axis extends in a direction orthogonal to the axial direction of the main pipe, and in the main pipe, it extends along the direction orthogonal to the flow direction of the cleaning liquid Into the direction of the gas. The gas-liquid mixing device also has a cleaning liquid introduction line and a gas introduction line in addition to the above-mentioned spray nozzle. The cleaning liquid introduction line includes a cleaning liquid introduction pipe connected to the main pipe, and the cleaning liquid is introduced into the main pipe through a cleaning liquid introduction port formed in the main pipe. The gas introduction line includes a gas introduction pipe connected to the branch pipe, and the gas is introduced into the branch pipe through a gas introduction port formed in the branch pipe. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本專利第5046755號公報[Patent Document 1] Japanese Patent No. 5046755

[發明所欲解決之問題][Problems to be solved by the invention]

噴射嘴自清洗液導入線中之清洗液導入管等沿著主配管之軸線方向被傳遞有因振動或熱引起之收縮。又,噴射嘴自氣體導入線中之氣體導入管等沿著正交於主配管之軸線方向之方向被傳遞有因振動或熱引起之收縮。即,由於噴射嘴自相互正交之2個方向各自疊加傳遞因振動或熱引起之收縮,故有噴射嘴磨耗或損傷之虞。The spray nozzle is transferred from the cleaning liquid introduction pipe in the cleaning liquid introduction line along the axial direction of the main pipe and contracted due to vibration or heat. In addition, the injection nozzle is transmitted from the gas introduction pipe in the gas introduction line in a direction orthogonal to the axial direction of the main pipe, and contraction due to vibration or heat is transmitted. That is, since the nozzles are superimposed and transmitted from two directions orthogonal to each other and contracted due to vibration or heat, there is a risk of abrasion or damage of the nozzles.

鑑於上述之事況,本發明之至少一實施形態之目的在於提供一種可防止自清洗液導入線及氣體導入線兩者對噴射嘴傳遞因振動或熱引起之收縮而使得噴射嘴嘴磨耗或損傷的氣液混合裝置。 [解決問題之技術手段]In view of the above-mentioned situation, the purpose of at least one embodiment of the present invention is to provide a method that can prevent both the self-cleaning liquid introduction line and the gas introduction line from transmitting to the injection nozzle due to the contraction caused by vibration or heat, causing the injection nozzle to wear or damage.的gas-liquid mixing device. [Technical means to solve the problem]

(1)本發明之至少一實施形態之氣液混合裝置係包含噴射嘴者,該噴射嘴構成為朝以使清洗液與自燃燒裝置排出之排氣進行氣液接觸之方式構成之吸收塔中之用於儲存上述清洗液的集液部,噴射含氧之氣體及上述清洗液;且 上述噴射嘴具備: 第1筒狀部,其於內部劃定第1流道,且形成有用以將上述清洗液導入至上述第1流道之清洗液導入口、用以沿著相對於自上述清洗液導入口導入而於上述第1流道流動之上述清洗液之流動方向正交之方向將上述氣體導入至上述第1流道的氣體導入口、及噴出自上述清洗液導入口導入之上述清洗液與自上述氣體導入口導入之上述氣體之混合流體的噴出口; 限縮部,其設置於較自上述清洗液導入口導入之上述清洗液與自上述氣體導入口導入之上述氣體合流之合流部更靠上述清洗液之流動方向之上游側;及 第2筒狀部,其於內部劃定連通於上述氣體導入口之第2流道,且形成有用以將上述氣體沿著相對於上述清洗液之流動方向正交之方向導入至上述第2流道的第2氣體導入口; 上述氣液混合裝置進而包含: 伸縮管接頭,其係包含於內部劃定用以輸送上述清洗液或上述氣體之導入流道且至少沿著上述導入流道延伸之方向伸縮自如地構成的主體部者,且設置於用以將上述清洗液自上述清洗液導入口輸送至上述第1流道之清洗液導入線、或用以將上述氣體自上述第2氣體導入口輸送至上述第2流道之氣體導入線中之至少一者。(1) The gas-liquid mixing device of at least one embodiment of the present invention includes an injection nozzle configured to flow into an absorption tower that is configured to make the cleaning liquid and exhaust gas discharged from the combustion device come into gas-liquid contact The liquid collecting part used to store the above-mentioned cleaning liquid, spray oxygen-containing gas and the above-mentioned cleaning liquid; and The above spray nozzle has: The first cylindrical portion defines a first flow path inside, and is formed with a cleaning liquid inlet for introducing the cleaning liquid to the first flow path, and is used to guide the cleaning liquid along the direction relative to the cleaning liquid inlet The gas is introduced into the gas inlet of the first flow channel in a direction orthogonal to the flow direction of the cleaning liquid flowing in the first flow channel, and the cleaning liquid introduced from the cleaning liquid inlet is ejected from the cleaning liquid. The jet port of the mixed fluid of the above gas introduced by the gas inlet; A constriction part, which is arranged on the upstream side of the flow direction of the cleaning liquid than the confluence part where the cleaning liquid introduced from the cleaning liquid inlet and the gas introduced from the gas inlet merge; and The second cylindrical portion defines a second flow passage communicating with the gas inlet and is formed to introduce the gas to the second flow in a direction orthogonal to the flow direction of the cleaning liquid The second gas inlet of the road; The gas-liquid mixing device further includes: The telescopic pipe joint includes a main body that is configured to extend and retract at least along the direction in which the introduction channel extends, and is provided for At least one of the cleaning liquid introduced from the cleaning liquid inlet to the cleaning liquid introduction line of the first flow channel, or the gas introduction line used to transport the gas from the second gas inlet to the second flow channel By.

根據上述(1)之構成,氣液混合裝置包含設置於清洗液導入線、或氣體導入線之至少一者之伸縮管接頭、及上述噴射嘴。伸縮管接頭包含主體部,該主體部於內部劃定用以輸送清洗液或氣體之導入流道,且構成為沿著導入流道延伸之方向伸縮自如。此種氣液混合裝置由於由伸縮管接頭吸收因振動或熱引起之收縮,故可防止自清洗液導入線或氣體導入線之至少一者對噴射嘴傳遞因振動或熱引起之收縮。由於可防止自相互正交之2個方向各自對噴射嘴疊加傳遞因振動或熱引起之收縮,故可抑制噴射嘴之磨耗或損傷。According to the above-mentioned configuration (1), the gas-liquid mixing device includes a telescopic tube joint provided in at least one of the cleaning liquid introduction line or the gas introduction line, and the injection nozzle. The telescopic pipe joint includes a main body, and the main body defines an introduction channel for conveying cleaning liquid or gas inside, and is configured to expand and contract freely along the extending direction of the introduction channel. Since this type of gas-liquid mixing device absorbs the contraction caused by vibration or heat by the expansion pipe joint, it can prevent at least one of the self-cleaning liquid introduction line or the gas introduction line from transmitting the contraction caused by vibration or heat to the spray nozzle. Since it can prevent the nozzle from being superimposed and transmitted from the two orthogonal directions to the nozzle due to the shrinkage caused by vibration or heat, it can suppress the abrasion or damage of the nozzle.

(2)若干實施形態中,如上述(1)記載之氣液混合裝置,其中上述伸縮接頭設置於上述清洗液導入線及上述氣體導入線之兩者。(2) In some embodiments, the gas-liquid mixing device as described in (1) above, wherein the expansion joint is provided in both the cleaning liquid introduction line and the gas introduction line.

根據上述(2)之構成,由於將伸縮管接頭設置於清洗液導入線及氣體導入線兩者,故可防止自清洗液導入線及氣體導入線兩者對噴射嘴傳遞因振動或熱引起之收縮。根據上述構成,與將伸縮管接頭設置於清洗液導入線或氣體導入線之至少一者之情形相比,可更確實地防止自相互正交之2個方向各自對噴射嘴疊加傳遞因振動或熱引起之收縮。According to the configuration of (2) above, since the expansion pipe joint is provided in both the cleaning liquid introduction line and the gas introduction line, it is possible to prevent the transmission of vibration or heat from both the cleaning liquid introduction line and the gas introduction line to the spray nozzle. shrink. According to the above configuration, compared to the case where the expansion pipe joint is installed in at least one of the cleaning liquid introduction line or the gas introduction line, it is possible to more reliably prevent the superimposed transmission of vibration or vibration or transmission to the nozzle from two orthogonal directions. Shrinkage caused by heat.

(3)若干實施形態中,如上述(1)或(2)記載之氣液混合裝置,其中上述噴射嘴進而具備:清洗液導入側緊固部,其自上述第1筒狀部之較上述合流部更靠上述清洗液之流動方向之上游側之外周突出設置;且 設置於上述清洗液導入線之上述伸縮管接頭即第1伸縮管接頭進而包含:下游側緊固部,其係沿著與上述第1伸縮管接頭之軸線延伸之方向交叉之方向自上述主體部之外周突出設置者,且於上述第1伸縮管接頭與上述第1筒狀部之間夾著上述限縮部之狀態下,藉由第1緊固裝置固定於上述清洗液導入側緊固部。(3) In some embodiments, the gas-liquid mixing device described in (1) or (2) above, wherein the spray nozzle further includes: a cleaning liquid introduction side fastening portion, which is from the first cylindrical portion than the above The confluence part is arranged protrudingly on the outer periphery of the upstream side of the flow direction of the cleaning liquid; and The first expansion pipe joint, which is the expansion pipe joint provided on the cleaning fluid introduction line, further includes: a downstream side fastening portion from the main body portion in a direction intersecting the direction in which the axis of the first expansion pipe joint extends The outer circumference is protruding, and the constriction is sandwiched between the first telescopic pipe joint and the first cylindrical part, and fixed to the cleaning liquid introduction side fastening part by the first fastening device .

根據上述(3)之構成,於第1伸縮管接頭與第1筒狀部之間夾著限縮部之狀態下,將第1伸縮管接頭之下游側緊固部藉由第1緊固裝置而固定於噴射嘴側緊之清洗液導入側緊固部。According to the configuration of (3) above, the downstream side fastening part of the first expansion pipe joint is passed through the first fastening device with the constriction limiting part sandwiched between the first expansion joint and the first cylindrical part. The cleaning liquid fixed on the side of the spray nozzle is introduced into the fastening part on the side tightly.

(4)本發明之至少一實施形態之排氣脫硫裝置係用以對自燃燒裝置排出之排氣進行脫硫者,且具備: 吸收塔,其構成為使清洗液與導入至內部之上述排氣進行氣液接觸,且於內部劃定用以儲存上述清洗液之集液部;及 如上述(1)~(3)中任一項記載之氣液混合裝置。(4) The exhaust gas desulfurization device of at least one embodiment of the present invention is used to desulfurize exhaust gas discharged from a combustion device, and has: An absorption tower, which is configured to make the cleaning liquid come into gas-liquid contact with the exhaust gas introduced into the interior, and a liquid collecting part for storing the cleaning liquid is defined inside; and The gas-liquid mixing device described in any one of (1) to (3) above.

根據上述(4)之構成,吸收塔構成為使清洗液與導入至內部之排氣進行氣液接觸,且於內部劃定用以儲存清洗液之集液部。氣液混合裝置藉由自噴射嘴之噴出口噴出至吸收塔之集液部之混合流體,可使儲存於吸收塔之集液部之清洗液產生充分之氧化反應。又,根據上述構成,由於可防止自相互正交之2個方向各自對噴射嘴疊加傳遞因振動或熱引起之收縮,故可抑制噴射嘴之磨耗或損傷。According to the configuration of (4) above, the absorption tower is configured such that the cleaning liquid and the exhaust gas introduced into the inside are brought into gas-liquid contact, and a liquid collecting part for storing the cleaning liquid is defined inside. The gas-liquid mixing device sprays the mixed fluid from the nozzle of the spray nozzle to the liquid collecting part of the absorption tower, so that the cleaning liquid stored in the liquid collecting part of the absorption tower can generate sufficient oxidation reaction. In addition, according to the above-mentioned structure, since the shrinkage caused by vibration or heat can be prevented from being superimposed and transmitted to the nozzle from two directions orthogonal to each other, it is possible to suppress abrasion or damage of the nozzle.

(5)若干實施形態中,如上述(4)記載之排氣脫硫裝置,其中上述第1筒狀部沿著上述噴出口之中心軸延伸,上述噴射嘴進而包含:噴出口側緊固部,其自上述第1筒狀部之較上述合流部更靠上述清洗液之流動方向之下游側之外周沿著與上述噴出口之上述中心軸正交的方向突出設置;上述吸收塔進而包含:側壁,其係劃定上述集液部之至少一部分者,且形成有供上述第1筒狀部之包含上述噴出口之末端插通的插通孔;筒狀突出部,其於將上述噴出口之上述中心軸自水平面傾斜之角度設為θ時,沿著自水平面傾斜與上述傾斜角度θ相同角度之方向,自上述側壁之上述插通孔之周緣部朝上述側壁之外側突出設置;及噴射嘴用緊固部,其係自上述筒狀突出部之末端沿著與上述筒狀突出部延伸之方向正交的方向突出設置者,且構成為藉由第2緊固裝置而固定於上述噴出口側緊固部。(5) In some embodiments, the exhaust gas desulfurization device described in (4) above, wherein the first cylindrical portion extends along the central axis of the nozzle, and the nozzle further includes: a nozzle-side fastening portion , Which protrudes from the outer periphery of the first cylindrical portion on the downstream side of the flow direction of the cleaning liquid than the confluence portion and along a direction orthogonal to the central axis of the ejection port; the absorption tower further includes: The side wall defines at least a part of the liquid collecting portion, and is formed with an insertion hole through which the end of the first cylindrical portion including the ejection port is inserted; a cylindrical protrusion that connects the ejection port When the angle at which the central axis is inclined from the horizontal plane is set to θ, along the direction inclined from the horizontal plane at the same angle as the inclination angle θ, protrude from the peripheral edge of the through hole of the side wall toward the outside of the side wall; and spray The nozzle fastening portion is one that protrudes from the end of the cylindrical protrusion in a direction orthogonal to the direction in which the cylindrical protrusion extends, and is configured to be fixed to the nozzle by a second fastening device Outlet side fastening part.

根據上述(5)之構成,於將第1筒狀部之包含噴出口之末端插通至形成於吸收塔之側壁之插通孔之狀態下,藉由第2緊固裝置將氣液混合裝置之噴出口側緊固部固定於吸收塔之噴射嘴用緊固部。由於噴射嘴固定於吸收塔,故假若即便自清洗液導入線及氣體導入線兩者對噴射嘴傳遞因振動或熱引起之收縮,亦可防止噴射嘴之噴出口之位置或角度偏移而使得自噴射嘴噴射之混合流體對清洗液之氧化反應降低。According to the configuration of (5) above, in a state where the end of the first cylindrical portion including the ejection port is inserted into the insertion hole formed in the side wall of the absorption tower, the gas-liquid mixing device is made by the second fastening device The nozzle side fastening part is fixed to the nozzle fastening part of the absorption tower. Since the spray nozzle is fixed to the absorption tower, if the contraction caused by vibration or heat is transmitted to the spray nozzle from both the cleaning liquid introduction line and the gas introduction line, the position or angle of the spray nozzle can be prevented from shifting. The oxidation reaction of the mixed fluid sprayed from the spray nozzle to the cleaning liquid is reduced.

又,根據上述之構成,第1筒狀部沿著噴出口之中心軸延伸。吸收塔之筒狀突出部沿著自水平面傾斜與噴出口之中心軸自水平面傾斜之角度θ相同角度的方向延伸。即,吸收塔之筒狀突出部沿著與設置有第1筒狀部時之噴出口之中心軸相同之方向延伸。第1筒狀部因藉由第2緊固裝置固定沿著與第1筒狀部延伸之方向正交的方向延伸之噴出口側緊固部、與沿著與筒狀突出部延伸之方向正交之方向延伸的噴射嘴用緊固部,從而可將噴出口之中心軸自水平面傾斜之角度θ直接作為設置角度。因此,根據上述構成,無需調整第1筒狀部之設置角度之作業,可使第1筒狀部之安裝作業容易化。 [發明之效果]Furthermore, according to the above configuration, the first cylindrical portion extends along the central axis of the ejection port. The cylindrical protrusion of the absorption tower extends along the direction inclined from the horizontal plane at the same angle as the angle θ at which the central axis of the ejection outlet is inclined from the horizontal plane. That is, the cylindrical protrusion of the absorption tower extends in the same direction as the central axis of the ejection port when the first cylindrical portion is provided. Since the first cylindrical portion is fixed by the second fastening device, the ejection port-side fastening portion extending in the direction orthogonal to the direction in which the first cylindrical portion extends is positively aligned with the direction in which the cylindrical protrusion extends. The fastening part for the spray nozzle extending in the opposite direction can directly use the angle θ at which the center axis of the spray port is inclined from the horizontal plane as the installation angle. Therefore, according to the above-mentioned structure, the work of adjusting the installation angle of the first cylindrical part is not required, and the installation work of the first cylindrical part can be facilitated. [Effect of invention]

根據本發明之至少一實施形態,提供一種可防止自清洗液導入線及氣體導入線兩者對噴射嘴傳遞因振動或熱引起之收縮而使得噴射嘴磨耗或損傷的氣液混合裝置。According to at least one embodiment of the present invention, there is provided a gas-liquid mixing device that can prevent both the self-cleaning liquid introduction line and the gas introduction line from transmitting to the injection nozzle due to the contraction caused by vibration or heat, causing the injection nozzle to wear or damage.

以下參照隨附圖式,對本發明之若干實施形態進行說明。惟作為實施形態而記載或圖式所示之構成零件之尺寸、材質、形狀、其相對配置等並非旨在將本發明之範圍加以限定,僅為單純之說明例。 例如,表示「朝某方向」、「沿著某方向」、「平行」、「正交」、「中心」、「同心」或「同軸」等相對或絕對之配置之表述不僅嚴格地表示該種配置,亦表示具有公差或可獲得相同功能之程度之角度或距離而相對移位之狀態。 例如,「同一」、「相等」及「均質」等表示事物相等之狀態之表述不僅嚴格地表示相等之狀態,亦表示存在公差或可獲得相同功能之程度之差異的狀態。 例如,表示四角形狀或圓筒形狀等形狀之表述不僅表示幾何學上嚴嚴格意義之四角形狀或圓筒形狀等形狀,亦表示於可獲得相同效果之範圍內包含凹凸部或倒角部等之形狀。 另一方面,將一構成要素稱為「配備」、「具有」、「具備」、「包含」、「含有」之表述並非排除其他構成要素之存在之表述。 另,對於同樣之構成,有時標註相同符號省略說明。Several embodiments of the present invention will be described below with reference to the accompanying drawings. However, the dimensions, materials, shapes, and relative arrangements of the constituent parts described as embodiments or shown in the drawings are not intended to limit the scope of the present invention, but are merely illustrative examples. For example, expressions representing relative or absolute arrangements such as "toward a certain direction", "along a certain direction", "parallel", "orthogonal", "center", "concentric" or "coaxial" not only strictly refer to that kind of Configuration also means the state of relative displacement with tolerance or angle or distance to the extent that the same function can be obtained. For example, expressions such as "identical", "equal", and "homogeneous" that indicate the state of things being equal not only strictly indicate the state of equality, but also indicate the state of tolerance or difference in the degree to which the same function can be obtained. For example, the expressions representing shapes such as quadrangular shapes or cylindrical shapes not only refer to shapes such as quadrangular shapes or cylindrical shapes in a geometrically strict sense, but also include concave and convex portions or chamfered portions within the range where the same effect can be obtained. shape. On the other hand, the expression of a component as “equipped”, “have”, “have”, “include”, or “contain” does not exclude the existence of other components. In addition, for the same configuration, the same reference numerals are sometimes attached to omit the description.

圖1係顯示一實施形態之排氣脫硫裝置之概略構成之剖視圖。排氣脫硫裝置係用以將自燃燒裝置排出之排氣進行脫硫之裝置。作為上述燃燒裝置,舉出柴油發動機、燃氣渦輪發動機或蒸汽渦輪發動機等發動機或鍋爐等。如圖1所示,排氣脫硫裝置1具備吸收塔2與氣液混合裝置4。Fig. 1 is a cross-sectional view showing a schematic configuration of an exhaust gas desulfurization device according to an embodiment. The exhaust gas desulfurization device is a device used to desulfurize the exhaust gas discharged from the combustion device. Examples of the aforementioned combustion device include engines such as diesel engines, gas turbine engines, or steam turbine engines, boilers, and the like. As shown in FIG. 1, the exhaust gas desulfurization device 1 includes an absorption tower 2 and a gas-liquid mixing device 4.

吸收塔2構成為使清洗液與導入至內部之排氣進行氣液接觸。圖示之實施形態中,吸收塔2如圖1所示,構成為於內部劃定:氣液接觸部21A,其構成為對導入至內部之排氣進行清洗液噴霧,使排氣與清洗液氣液接觸;及集液部21B,其位於較氣液接觸部更為下方,供儲存在氣液接觸部21A中吸收到排氣中之SOx 之清洗液。此處,作為清洗液,舉出包含鹼性劑之液體或海水等。又,作為鹼性劑,舉出例如CaCO3 、NaOH、Ca(OH)2 、NaHCO3 、Na2 CO3 等,亦可使用減容為高濃度之鹼。The absorption tower 2 is configured to make gas-liquid contact between the cleaning liquid and the exhaust gas introduced into the inside. In the embodiment shown in the figure, the absorption tower 2 is as shown in FIG. 1, and is configured to be internally defined: a gas-liquid contact portion 21A, which is configured to spray the exhaust gas introduced into the interior with a cleaning liquid to make the exhaust gas and the cleaning liquid Gas-liquid contact; and the liquid collection part 21B, which is located below the gas-liquid contact part, for storing the cleaning liquid of SO x absorbed in the exhaust gas in the gas-liquid contact part 21A. Here, as the cleaning liquid, a liquid containing an alkaline agent, seawater, and the like are mentioned. In addition, as the alkaline agent, for example, CaCO 3 , NaOH, Ca(OH) 2 , NaHCO 3 , Na 2 CO 3, etc., and alkali whose volume is reduced to a high concentration can also be used.

更詳細而言,吸收塔2如圖1所示,具備吸收塔本體部22,其於內部劃定出包含上述之氣液接觸部21A及上述之集液部21B之內部空間21;排氣導入部23,其用以將排氣導入至吸收塔本體部22;及排氣排出部24,其用以自吸收塔本體部22排出排氣。如圖1所示,將吸收塔本體部22與排氣導入部23相鄰之方向定義為第1方向,將第1方向上之排氣導入部23側定義為一側,將第1方向上之排氣排出部24側定義為另一側。In more detail, the absorption tower 2 as shown in FIG. 1 is provided with an absorption tower main body 22, which defines an internal space 21 including the above-mentioned gas-liquid contact part 21A and the above-mentioned liquid collecting part 21B; The part 23 is used to introduce the exhaust gas to the absorption tower main body 22; and the exhaust gas discharge part 24 is used to discharge the exhaust gas from the absorption tower main body 22. As shown in Figure 1, the direction in which the absorption tower main body 22 and the exhaust gas introduction portion 23 are adjacent is defined as the first direction, and the exhaust gas introduction portion 23 side in the first direction is defined as one side, and the first direction The side of the exhaust discharge portion 24 is defined as the other side.

如圖1所示,於吸收塔本體部22之上述第1方向上之一側側壁即第1側壁25,形成有與內部空間21(下方側內部空間21C)連通之排氣導入口251。於吸收塔本體部22之上述第1方向上之另一側側壁即第2側壁26,於高於排氣導入口251之位置,形成有與內部空間21(上方側內部空間21D)連通之排氣排出口261。第1側壁25及第2側壁26各者於俯視時沿著與第1方向正交之第2方向延伸,且劃定包含集液部21B之內部空間21之至少一部分。As shown in FIG. 1, the first side wall 25, which is one of the side walls in the first direction of the absorption tower main body 22, is formed with an exhaust inlet 251 communicating with the internal space 21 (lower internal space 21C). The second side wall 26, which is the other side wall in the first direction of the absorption tower body 22, is formed at a position higher than the exhaust inlet 251 to communicate with the inner space 21 (upper inner space 21D)气出口261。 Air exhaust port 261. Each of the first side wall 25 and the second side wall 26 extends along a second direction orthogonal to the first direction in a plan view, and defines at least a part of the internal space 21 including the liquid collecting portion 21B.

自燃燒裝置(未圖示)導入至排氣導入部23之排氣通過排氣導入部23後,經由排氣導入口251導入至內部空間21(下方側內部空間21C)。經導入至內部空間21之排氣於下方側內部空間21C自位於一側之第1側壁25流向位於另一側之第2側壁26後,於內部空間21一面上升一面流動。上升至上方側內部空間21D之排氣自第1側壁25流向第2側壁26後,經由排氣排出口261朝排氣排出部24排出。The exhaust gas introduced from the combustion device (not shown) to the exhaust gas introduction portion 23 passes through the exhaust gas introduction portion 23 and then is introduced into the internal space 21 (lower internal space 21C) through the exhaust gas introduction port 251. The exhaust gas introduced into the internal space 21 flows in the lower internal space 21C from the first side wall 25 on one side to the second side wall 26 on the other side, and then flows in the internal space 21 while rising. The exhaust gas that rises to the upper internal space 21D flows from the first side wall 25 to the second side wall 26, and then is discharged to the exhaust gas discharge portion 24 through the exhaust gas discharge port 261.

如圖1所示,在吸收塔本體部22之位於較下方側內部空間21C更上方且較上方側內部空間21D更下方之氣液接觸部21A,配置有用以將上述之清洗液散佈於內部空間21之散佈裝置28。散佈裝置28構成為對通過氣液接觸部21A之排氣散佈清洗液,使排氣與清洗液氣液接觸,從而將排氣中所含之SOx (包含SO2 )吸收去除。As shown in Figure 1, the gas-liquid contact portion 21A of the absorption tower main body 22 located above the lower internal space 21C and below the upper internal space 21D is arranged to spread the above-mentioned cleaning liquid in the internal space 21 of the spreading device 28. The spreading device 28 is configured to spread the cleaning liquid to the exhaust gas passing through the gas-liquid contact portion 21A, and contact the exhaust gas with the cleaning liquid to absorb and remove SO x (including SO 2 ) contained in the exhaust gas.

散佈裝置28如圖1所示,包含灑水管281,其於吸收塔本體部22之內部空間21中沿著上述第1方向延伸;及複數個灑水噴嘴282,其等設置於灑水管281。灑水噴嘴282構成為朝向排氣之流動方向上之下游側、即朝向鉛直方向上之上方散佈清洗液。圖示之實施形態中,灑水噴嘴282液柱狀地噴射清洗液。即,圖示之吸收塔2為液柱式之吸收塔。As shown in FIG. 1, the spreading device 28 includes a sprinkler pipe 281 that extends in the inner space 21 of the absorption tower main body 22 along the above-mentioned first direction; and a plurality of sprinkler nozzles 282 which are provided in the sprinkler pipe 281. The sprinkler nozzle 282 is configured to spread the washing liquid toward the downstream side in the flow direction of the exhaust gas, that is, toward the upper side in the vertical direction. In the embodiment shown in the figure, the sprinkler nozzle 282 sprays the cleaning liquid in a liquid column. That is, the absorption tower 2 shown in the figure is a liquid column absorption tower.

另,吸收塔2只要以使清洗液與導入至內部之排氣氣液接觸之方式構成即可,不限定於上述之液柱式。例如,吸收塔2可為具備將用以促進氣液接觸之填充材填充於內部空間21之填充層的格柵式吸收塔,或具備將清洗液放射狀地噴霧之灑水噴嘴282之噴灑式吸收塔等。又,灑水管281可沿著俯視時與上述第1方向正交之方向延伸。又,灑水噴嘴282可構成為朝向鉛直方向上之下方散佈清洗液。In addition, the absorption tower 2 is not limited to the above-mentioned liquid column type as long as it is configured such that the cleaning liquid is brought into contact with the exhaust gas liquid introduced into the inside. For example, the absorption tower 2 may be a grid type absorption tower equipped with a packing layer for filling the internal space 21 with a packing material for promoting gas-liquid contact, or a spray type equipped with a sprinkler nozzle 282 that sprays the cleaning liquid radially Absorption tower etc. In addition, the sprinkler pipe 281 may extend in a direction orthogonal to the first direction in a plan view. In addition, the sprinkler nozzle 282 may be configured to spread the cleaning liquid downward in the vertical direction.

通過氣液接觸部21A之排氣中含有大量水分。於排氣之流動方向上較氣液接觸部21A更為下游側,配置有除霧器27。除霧器27構成為將水分自通過除霧器27之排氣去除。將通過除霧器27之排氣排出至吸收塔2之外部。The exhaust gas passing through the gas-liquid contact portion 21A contains a large amount of moisture. A demister 27 is arranged on the downstream side of the gas-liquid contact portion 21A in the flow direction of the exhaust gas. The mist eliminator 27 is configured to remove moisture from the exhaust gas passing through the mist eliminator 27. The exhaust gas passing through the mist eliminator 27 is discharged to the outside of the absorption tower 2.

圖示之實施形態中,除霧器27配置於排氣排出部24,且以分隔排氣排出部24中排氣流動方向之上游側與下游側之方式沿著鉛直方向延伸。另,除霧器27可配置於上方側內部空間21D,且沿著水平方向延伸。又,除霧器27可為多段構成。In the illustrated embodiment, the mist eliminator 27 is disposed in the exhaust gas discharge portion 24 and extends in the vertical direction to partition the upstream and downstream sides of the exhaust gas flow direction in the exhaust gas discharge portion 24. In addition, the mist eliminator 27 may be arranged in the upper internal space 21D and extend in the horizontal direction. In addition, the mist eliminator 27 may be configured in multiple stages.

集液部21B構成為儲存已對導入至內部空間21之排氣散佈之散佈後之清洗液。圖示之實施形態中,集液部21B以液面位於下方側內部空間21C之下方且低於排氣導入口251之位置之方式設置。儲存於集液部21B之清洗液中含有由自排氣吸收之SOx 所產生之反應生成物。此處,作為反應生成物,舉出因於清洗液中吸收SO2 而生成之亞硫酸鹽等。The liquid collecting part 21B is configured to store the cleaning liquid after the spraying of the exhaust gas introduced into the internal space 21 has been dispersed. In the illustrated embodiment, the liquid collecting portion 21B is provided such that the liquid surface is located below the lower internal space 21C and lower than the position of the exhaust gas inlet 251. The cleaning liquid stored in the liquid collecting part 21B contains the reaction product generated by the SO x absorbed from the exhaust gas. Here, as a reaction product, exemplified by sulfite in the absorption of SO 2 generated in the cleaning liquid.

如圖1所示,於第2側壁26,於鉛直方向上集液部21B之底面211附近之位置,開口出用以將儲存於集液部21B之清洗液引出至外部之清洗液引出口262。清洗液引出口262連通於集液部21B。As shown in FIG. 1, in the second side wall 26, at a position near the bottom surface 211 of the liquid collecting portion 21B in the vertical direction, an opening is opened to guide the cleaning liquid stored in the liquid collecting portion 21B to the outside. . The cleaning liquid outlet 262 communicates with the liquid collecting part 21B.

圖示之實施形態中,排氣脫硫裝置1如圖1所示進而具備:清洗液循環線7,其構成為將儲存於集液部21B之清洗液輸送至散佈裝置28;及清洗液供給線8,其構成為自吸收塔2之外部將清洗液供給至集液部21B。In the illustrated embodiment, the exhaust gas desulfurization device 1 as shown in FIG. 1 is further provided with: a cleaning liquid circulation line 7 configured to transport the cleaning liquid stored in the liquid collecting portion 21B to the spreading device 28; and cleaning liquid supply The line 8 is configured to supply the cleaning liquid to the liquid collection part 21B from the outside of the absorption tower 2.

清洗液循環線7包含:至少一條配管71,其連接上述之清洗液引出口262及上述之灑水管281;及清洗液循環泵72,其設置於清洗液循環線7之中途,用以自清洗液引出口262將清洗液輸送至灑水管281。即,將自散佈裝置28散佈而儲存於集液部21B之清洗液之至少一部分由清洗液循環泵72壓送,通過清洗液循環線7而輸送至散佈裝置28。The cleaning fluid circulation line 7 includes: at least one piping 71 connected to the above-mentioned cleaning fluid outlet 262 and the above-mentioned sprinkler pipe 281; and a cleaning fluid circulation pump 72, which is arranged in the middle of the cleaning fluid circulation line 7 for self-cleaning The liquid introduction port 262 conveys the cleaning liquid to the sprinkler pipe 281. That is, at least a part of the cleaning liquid dispersed from the spreading device 28 and stored in the liquid collecting portion 21B is pressure-fed by the cleaning liquid circulation pump 72, and is sent to the spreading device 28 through the cleaning liquid circulation line 7.

清洗液供給線8包含:清洗液儲存槽81,其設置於吸收塔2之外部;及至少一條配管82,其連接清洗液儲存槽81與集液部21B。清洗液自清洗液儲存槽81通過清洗液供給線8輸送至集液部21B。The cleaning liquid supply line 8 includes: a cleaning liquid storage tank 81 which is provided outside the absorption tower 2; and at least one pipe 82 which connects the cleaning liquid storage tank 81 and the liquid collection part 21B. The cleaning liquid is transported from the cleaning liquid storage tank 81 to the liquid collection part 21B through the cleaning liquid supply line 8.

氣液混合裝置4如圖1所示,包含:噴射嘴5,其構成為將例如空氣等含氧之氣體與清洗液之混合流體MF噴射至吸收塔2之集液部21B;清洗液導入線41,其構成為將清洗液輸送至噴射嘴5;及氣體導入線42,其構成為將含氧之氣體輸送至噴射嘴5。氣液混合裝置4自噴射嘴5朝集液部21B噴射混合流體MF,使混合流體MF遍佈於儲存於集液部21B之清洗液,從而藉由混合流體MF使上述反應生成物氧化,產生氧化生成物。作為氧化生成物,舉出石膏等。As shown in FIG. 1, the gas-liquid mixing device 4 includes an injection nozzle 5 configured to inject a mixed fluid MF of an oxygen-containing gas such as air and a cleaning liquid to the liquid collecting part 21B of the absorption tower 2; and a cleaning liquid introduction line 41, which is configured to deliver cleaning liquid to the spray nozzle 5; and a gas introduction line 42 which is configured to deliver oxygen-containing gas to the spray nozzle 5. The gas-liquid mixing device 4 injects the mixed fluid MF from the spray nozzle 5 toward the liquid collecting part 21B, so that the mixed fluid MF is spread over the cleaning liquid stored in the liquid collecting part 21B, and the above-mentioned reaction product is oxidized by the mixed fluid MF to produce oxidation Product. As an oxidation product, gypsum etc. are mentioned.

圖示之實施形態中,排氣脫硫裝置1如圖1所示,進而具備清洗液排出線9,其構成為排出儲存於集液部21B之包含氧化生成物(石膏等)之清洗液。圖1所示之實施形態中,清洗液排出線9構成為經由連接於集液部21B之清洗液循環線7而排出清洗液。更詳細而言,清洗液排出線9自清洗液循環線7之分支部73分支,連接於設置在吸收塔2之外部之裝置91,自清洗液循環線7之分支部73將包含氧化生成物之清洗液輸送至裝置91。作為裝置91,舉出自包含氧化生成物之清洗液將水分脫水之脫水機(分離機)或用以暫時儲存清洗液之儲存槽等。In the illustrated embodiment, as shown in FIG. 1, the exhaust gas desulfurization device 1 further includes a cleaning liquid discharge line 9 configured to discharge the cleaning liquid containing oxidation products (gypsum etc.) stored in the liquid collecting part 21B. In the embodiment shown in FIG. 1, the cleaning liquid discharge line 9 is configured to discharge the cleaning liquid through the cleaning liquid circulation line 7 connected to the liquid collecting portion 21B. In more detail, the cleaning fluid discharge line 9 branches from the branch 73 of the cleaning fluid circulation line 7 and is connected to the device 91 provided outside the absorption tower 2. The branch 73 of the self-cleaning fluid circulation line 7 will contain oxidation products The cleaning liquid is delivered to the device 91. Examples of the device 91 include a dehydrator (separator) for dehydrating water from a cleaning liquid containing oxidation products, a storage tank for temporarily storing the cleaning liquid, and the like.

圖1所示之實施形態中,清洗液導入線41在位於清洗液之流動方向上較分支部73更為下游側之分支部44處,自清洗液循環線7分支。上述之清洗液循環泵72將清洗液之一部分自清洗液引出口262經由分支部44輸送至噴射嘴5。In the embodiment shown in FIG. 1, the cleaning liquid introduction line 41 is branched from the cleaning liquid circulation line 7 at the branch portion 44 located downstream of the branch portion 73 in the flow direction of the cleaning liquid. The above-mentioned cleaning liquid circulation pump 72 transports a part of the cleaning liquid from the cleaning liquid outlet 262 to the spray nozzle 5 via the branch portion 44.

圖示之實施形態中,氣體導入線42之一端連接於噴射嘴5,另一端於較集液部21B之液面更上方之位置大氣開放。In the illustrated embodiment, one end of the gas introduction line 42 is connected to the injection nozzle 5, and the other end is open to the atmosphere at a position higher than the liquid level of the liquid collecting portion 21B.

圖2係用以說明一實施形態之噴射嘴之功能之噴射嘴的概略剖視圖。圖3係顯示一實施形態之噴射嘴之概略構成之剖視圖。噴射嘴5如圖2、3所示,包含第1筒狀部52、限縮部53及第2筒狀部54。Fig. 2 is a schematic cross-sectional view of a spray nozzle for explaining the function of the spray nozzle of an embodiment. Fig. 3 is a cross-sectional view showing the schematic configuration of an injection nozzle according to an embodiment. As shown in FIGS. 2 and 3, the spray nozzle 5 includes a first cylindrical portion 52, a constriction restricting portion 53, and a second cylindrical portion 54.

第1筒狀部52如圖2、3所示,形成為於內部劃定第1流道55之筒狀。於第1筒狀部52,形成有用以將清洗液導入至第1流道55之清洗液導入口56、用以沿著相對於自清洗液導入口56導入且於第1流道55中流動之清洗液之流動方向正交的方向將上述氣體導入至第1流道55之氣體導入口57及上述之噴出口51。噴出口51係用以噴出自清洗液導入口56導入之清洗液與自氣體導入口57導入之氣體之混合流體MF而設置。As shown in FIGS. 2 and 3, the first cylindrical portion 52 is formed in a cylindrical shape that defines the first flow passage 55 inside. The first cylindrical portion 52 is formed with a cleaning liquid introduction port 56 for introducing the cleaning liquid into the first flow passage 55, so as to be introduced along with respect to the self-cleaning liquid introduction port 56 and flow in the first flow passage 55 The gas is introduced into the gas inlet 57 of the first flow path 55 and the ejection outlet 51 described above in a direction orthogonal to the flow direction of the cleaning liquid. The ejection port 51 is provided for ejecting the mixed fluid MF of the cleaning liquid introduced from the cleaning liquid inlet 56 and the gas introduced from the gas inlet 57.

圖2、3所示之實施形態中,第1筒狀部52沿著噴出口51之中心軸CA之延伸方向具有長度方向。於第1筒狀部52之長度方向之一端開口為上述之清洗液導入口56,於第1筒狀部52之長度方向之另一端開口為上述之噴出口51。於第1筒狀部52之外周開口為上述之氣體導入口57。自清洗液導入線41經由清洗液導入口56被輸送至第1流道55內之清洗液,於第1流道55中朝沿著中心軸CA延伸方向之方向,自清洗液導入口56流向噴出口51。In the embodiment shown in FIGS. 2 and 3, the first cylindrical portion 52 has a longitudinal direction along the extending direction of the central axis CA of the ejection port 51. The opening at one end in the longitudinal direction of the first cylindrical portion 52 is the above-mentioned cleaning liquid introduction port 56, and the other opening in the longitudinal direction of the first cylindrical portion 52 is the above-mentioned ejection port 51. The gas inlet 57 described above is opened on the outer periphery of the first cylindrical portion 52. The self-cleaning liquid introduction line 41 is sent to the cleaning liquid in the first flow channel 55 through the cleaning liquid introduction port 56, and flows in the direction along the extending direction of the central axis CA in the first flow channel 55 from the cleaning liquid introduction port 56 Ejection outlet 51.

第2筒狀部54如圖2、3所示,於內部劃定連通於氣體導入口57之第2流道58,沿著氣體導入口57之氣體導入方向(相對於清洗液之流動方向正交之方向)延伸,且形成有用以將氣體導入至第2流道58的第2氣體導入口59。As shown in FIGS. 2 and 3, the second cylindrical portion 54 defines a second flow path 58 communicating with the gas inlet 57 along the gas inlet direction of the gas inlet 57 (positive relative to the flow direction of the cleaning liquid). It extends in the opposite direction) and forms a second gas introduction port 59 for introducing gas into the second flow channel 58.

圖2、3所示之實施形態中,第2筒狀部54沿著氣體導入口57之中心軸CA2延伸之方向、即與噴出口51之中心軸CA延伸之方向正交之方向具有長度方向。第2筒狀部54之長度方向上之一端一體連接於第1筒狀部52之外周。即,第1筒狀部52與第2筒狀部54一體形成。於第2筒狀部54之長度方向上之另一端開口為上述之第2氣體導入口59。自氣體導入線42經由第2氣體導入口59被輸送至第2流道58內之氣體通過第2流道58後,經由氣體導入口57被輸送至第1流道55內。經輸送至第1流道55內之氣體於合流部60中與清洗液合流。In the embodiment shown in FIGS. 2 and 3, the second cylindrical portion 54 has a longitudinal direction along the direction in which the central axis CA2 of the gas inlet 57 extends, that is, the direction orthogonal to the direction in which the central axis CA of the ejection port 51 extends. . One end in the longitudinal direction of the second cylindrical portion 54 is integrally connected to the outer circumference of the first cylindrical portion 52. That is, the first cylindrical portion 52 and the second cylindrical portion 54 are integrally formed. The opening at the other end of the second cylindrical portion 54 in the longitudinal direction is the second gas introduction port 59 described above. The gas sent from the gas introduction line 42 into the second flow channel 58 through the second gas introduction port 59 passes through the second flow channel 58 and then is sent into the first flow channel 55 through the gas introduction port 57. The gas sent into the first flow channel 55 merges with the cleaning liquid in the merging part 60.

如圖2、3所示,限縮部53設置於較合流部60更靠清洗液之流動方向之上游側。限縮部53於內部流動清洗液,且開口出與清洗液之流動方向之上游側及下游側相比剖面積急劇縮小之縮流形成口61。限縮部53構成為藉由以縮流形成口61將清洗液縮流,而於清洗液之流動方向上較限縮部53更靠下游側產生負壓區域62(參照圖2)。噴射嘴5藉由負壓區域62中產生之吸引力,自氣流導入口57吸引氣體。另,若僅以上述吸引力輸送至第1流道55之氣體量不足之情形時,可於氣體導入線42設置用以將氣體輸送至第1流道55之未圖示之泵,藉由該泵增加輸送至第1流道55之氣體量。As shown in FIGS. 2 and 3, the constriction portion 53 is provided on the upstream side of the flow direction of the cleaning liquid more than the confluence portion 60. The constriction portion 53 flows the cleaning fluid inside, and opens out a constriction flow forming port 61 whose cross-sectional area is sharply reduced compared to the upstream and downstream sides of the flow direction of the cleaning fluid. The constriction part 53 is configured to contract the cleaning liquid with the constriction flow forming port 61 to generate a negative pressure area 62 on the downstream side of the constriction part 53 in the flow direction of the cleaning liquid (refer to FIG. 2 ). The injection nozzle 5 sucks gas from the airflow inlet 57 by the suction force generated in the negative pressure area 62. In addition, if the amount of gas delivered to the first flow channel 55 by the above-mentioned suction force is insufficient, a pump not shown in the figure can be installed in the gas introduction line 42 to deliver the gas to the first flow channel 55. The pump increases the amount of gas delivered to the first flow channel 55.

圖2、3所示之實施形態中,限縮部53與第1筒狀部52分開構成。另一實施形態中,限縮部53可與第1筒狀部52一體形成。例如,限縮部53可自第1筒狀部52之劃定第1流道55之內周面突出設置。In the embodiment shown in FIGS. 2 and 3, the constriction portion 53 and the first cylindrical portion 52 are formed separately. In another embodiment, the constriction restricting portion 53 may be integrally formed with the first cylindrical portion 52. For example, the constriction portion 53 may protrude from the inner peripheral surface of the first cylindrical portion 52 defining the first flow passage 55.

噴射嘴5藉由第1流道55中流動之清洗液,將輸送至第1流道55之氣體截斷、微細化而產生混合流體MF(於內部包含微細氣泡之清洗液)。又,噴射嘴5將噴射嘴5內產生之混合流體MF自噴出口51噴射。The spray nozzle 5 cuts off and miniaturizes the gas delivered to the first flow channel 55 by the cleaning liquid flowing in the first flow channel 55 to generate a mixed fluid MF (cleaning liquid containing fine bubbles in the inside). In addition, the spray nozzle 5 sprays the mixed fluid MF generated in the spray nozzle 5 from the spray port 51.

圖4係概略性顯示吸收塔中之固定噴射嘴之部分附近之圖,且係用以說明第1伸縮管接頭及第2伸縮管接頭的圖。Fig. 4 is a diagram schematically showing the vicinity of the part where the spray nozzle is fixed in the absorption tower, and is a diagram for explaining the first expansion joint and the second expansion joint.

若干實施形態中,上述之氣液混合裝置4如圖2、3所示,具備上述之第1筒狀部52、上述之限縮部53及上述之第2筒狀部54。且,上述之氣液混合裝置4進而具備如圖4所示之設置於上述之清洗液導入線41、或上述之氣液導入線42中之至少一者的伸縮管接頭45。In some embodiments, the above-mentioned gas-liquid mixing device 4 is provided with the above-mentioned first cylindrical part 52, the above-mentioned constriction part 53 and the above-mentioned second cylindrical part 54 as shown in FIGS. 2 and 3. In addition, the above-mentioned gas-liquid mixing device 4 further includes an expansion pipe joint 45 provided in at least one of the above-mentioned cleaning liquid introduction line 41 and the above-mentioned gas-liquid introduction line 42 as shown in FIG. 4.

如圖4所示,伸縮管接頭45包含主體部451,其於內部劃定用以輸送清洗液或氣體之導入流道455,且構成為至少沿著導入流道455延伸之方向伸縮自如。As shown in FIG. 4, the telescopic pipe joint 45 includes a main body 451, which defines an introduction channel 455 for transporting cleaning liquid or gas inside, and is configured to be flexible at least along the direction in which the introduction channel 455 extends.

圖示之實施形態中,如圖4所示,伸縮管接頭45之導入流道455及主體部451沿著軸線CE1、CE2延伸之方向延伸。且,伸縮管接頭45包含:下游側緊固部453,其自主體部451之延伸方向上之一側端部(下游側端部)之外周,沿著與主體部451之延伸方向正交的方向突出設置;及上游側緊固部454,其自主體部451之延伸方向之另一端部(上游側端部)之外周,沿著與主體部451之延伸方向正交的方向突出設置。伸縮管接頭45於主體部451之中途設置有具有伸縮性或彎折性之伸縮囊452。於主體部451設置有伸縮囊452之伸縮管接頭45沿著導入流道455延伸之方向伸縮自如,且沿著與導入流道455延伸之方向正交的方向伸縮自如。In the illustrated embodiment, as shown in FIG. 4, the introduction channel 455 and the main body 451 of the telescopic pipe joint 45 extend along the direction in which the axes CE1 and CE2 extend. In addition, the telescopic pipe joint 45 includes a downstream fastening portion 453 which extends from the outer periphery of one side end (downstream end) in the extension direction of the main body 451 along a direction perpendicular to the extension direction of the main body 451 And the upstream fastening portion 454, which protrudes from the outer periphery of the other end (upstream end) in the extension direction of the main body 451 along the direction orthogonal to the extension direction of the main body 451. The expansion tube joint 45 is provided with an expansion bladder 452 having elasticity or flexibility in the middle of the main body 451. The telescopic tube joint 45 provided with the bellows 452 in the main body 451 is stretchable along the direction in which the introduction channel 455 extends, and is freely stretchable along the direction orthogonal to the direction in which the introduction channel 455 extends.

根據上述構成,氣液混合裝置4具備設置於清洗液導入線41、或氣體導入線42之至少一者之伸縮管接頭45與上述噴射嘴5。伸縮管接頭45包含主體部451,其於內部劃定用以輸送清洗液或氣體之導入流道455,且構成為至少沿著導入流道455延伸之方向伸縮自如。此種氣液混合裝置4係於由伸縮管接頭45吸收因振動或熱引起之收縮,故可防止自清洗液導入線41或氣體導入線42之至少一者對噴射嘴5傳遞因振動或熱引起之收縮。由於可防止自相互正交之2個方向(中心軸CA延伸之方向、中心軸CA2延伸之方向)各自對噴射嘴5疊加傳遞因振動或熱引起之收縮,故可抑制噴射嘴5之磨耗或損傷。 又,根據上述構成,因自清洗液導入線41拆卸伸縮管接頭45,無需拆卸清洗液導入線41之較伸縮管接頭45更靠上游側之配管即可執行限縮部53之檢點作業,因此,可迅速地進行上述檢點作業。According to the above configuration, the gas-liquid mixing device 4 includes the expansion pipe joint 45 provided in at least one of the cleaning liquid introduction line 41 or the gas introduction line 42 and the injection nozzle 5. The telescopic pipe joint 45 includes a main body 451, which defines an introduction channel 455 for transporting cleaning liquid or gas inside, and is configured to be flexible at least along the extending direction of the introduction channel 455. The gas-liquid mixing device 4 is designed to absorb the contraction caused by vibration or heat by the expansion pipe joint 45, so that at least one of the self-cleaning liquid introduction line 41 or the gas introduction line 42 can be prevented from transmitting the vibration or heat to the spray nozzle 5. Caused to shrink. Since the two orthogonal directions (the direction in which the central axis CA extends and the direction in which the central axis CA2 extends) can be prevented from being superimposed and transmitted to the injection nozzle 5 from contraction caused by vibration or heat, it is possible to suppress the wear and tear of the injection nozzle 5 damage. In addition, according to the above configuration, since the expansion pipe joint 45 is removed from the cleaning fluid introduction line 41, the inspection of the constriction section 53 can be performed without disassembling the piping of the cleaning solution introduction line 41 on the upstream side of the expansion pipe joint 45. Therefore, , The above-mentioned inspection work can be carried out quickly.

若干實施形態中,如圖4所示,上述之伸縮管接頭45設置於清洗液導入線41及氣體導入線42兩者。換言之,上述之伸縮管接頭45包含設置於清洗液導入線41之第1伸縮管接頭45A與設置於氣體導入線之第2伸縮接頭45B。於該情形時,由於將伸縮管接頭45設置於清洗液導入線41及氣體導入線42兩者,故可防止自清洗液導入線41及氣體導入線42兩者對噴射嘴5傳遞因振動或熱引起之收縮。根據上述構成,與將伸縮管接頭45設置於清洗液導入線41或氣體導入線42之至少一者之情形相比,可更確實地防止自相互正交之2個方向各自對噴射嘴5疊加傳遞因振動或熱引起之收縮,又,因自清洗液導入線41拆卸第1伸縮管接頭45A,且自氣體導入線42拆卸第2伸縮管接頭45B,故可迅速地進行自吸收塔2拆除噴射嘴5之作業。In some embodiments, as shown in FIG. 4, the aforementioned telescopic pipe joint 45 is provided in both the cleaning liquid introduction line 41 and the gas introduction line 42. In other words, the aforementioned expansion joint 45 includes a first expansion joint 45A provided on the cleaning liquid introduction line 41 and a second expansion joint 45B provided on the gas introduction line. In this case, since the telescopic pipe joint 45 is provided on both the cleaning liquid introduction line 41 and the gas introduction line 42, it is possible to prevent the transmission of vibration or vibration from both the cleaning liquid introduction line 41 and the gas introduction line 42 to the spray nozzle 5 Shrinkage caused by heat. According to the above configuration, compared with the case where the telescopic pipe joint 45 is provided in at least one of the cleaning liquid introduction line 41 or the gas introduction line 42, it is possible to more reliably prevent the injection nozzle 5 from being superimposed on each of the two orthogonal directions. The contraction caused by vibration or heat is transmitted, and since the first expansion pipe joint 45A is removed from the cleaning fluid introduction line 41, and the second expansion pipe joint 45B is removed from the gas introduction line 42, the self-absorption tower 2 can be removed quickly Operation of spray nozzle 5.

圖5係概略性顯示吸收塔中之固定噴射嘴之部分附近之局部剖視圖。以下基於圖5,說明噴射嘴5之安裝方法。Figure 5 is a partial cross-sectional view schematically showing the vicinity of the fixed spray nozzle in the absorption tower. Hereinafter, based on FIG. 5, the installation method of the spray nozzle 5 will be described.

首先,將形成有噴射嘴5之噴出口51之第1筒狀部52之末端插通至以貫通第1側壁25之方式形成之插通孔252。First, the end of the first cylindrical portion 52 in which the ejection port 51 of the ejection nozzle 5 is formed is inserted into the insertion hole 252 formed so as to penetrate the first side wall 25.

如圖5所示,噴射嘴5包含噴出口側緊固部63。第1筒狀部52沿著噴出口51之中心軸CA延伸,且於延伸方向上之一端形成有噴出口51。噴出口側緊固部63自第1筒狀部52之外周沿著與噴出口51之中心軸CA正交之方向突出設置。噴出口側緊固部63設置於第1筒狀部52之、較與第2筒狀部54之連接部或合流部60更靠清洗液之流動方向之下游側之外周。As shown in FIG. 5, the spray nozzle 5 includes a discharge port side fastening portion 63. The first cylindrical portion 52 extends along the central axis CA of the ejection port 51, and the ejection port 51 is formed at one end in the extending direction. The ejection port side fastening portion 63 protrudes from the outer periphery of the first cylindrical portion 52 in a direction orthogonal to the center axis CA of the ejection port 51. The ejection port-side fastening portion 63 is provided on the outer periphery of the first cylindrical portion 52 on the downstream side in the flow direction of the cleaning liquid than the connection portion with the second cylindrical portion 54 or the merging portion 60.

如圖5所示,吸收塔2進而包含筒狀突出部29與噴射嘴用緊固部30。如圖5所示,於將噴出口51之中心軸CA與水平面之傾斜角度設為θ時,筒狀突出部29沿著自水平面傾斜該傾斜角度θ之方向,自第1側壁25之插通孔252之周緣部朝外側突出設置。噴射嘴用緊固部30自筒狀突出部29之末端沿著與筒狀突出部29延伸之方向正交的方向突出設置。As shown in FIG. 5, the absorption tower 2 further contains the cylindrical protrusion part 29 and the fastening part 30 for injection nozzles. As shown in FIG. 5, when the inclination angle between the central axis CA of the ejection port 51 and the horizontal plane is set to θ, the cylindrical protrusion 29 penetrates from the first side wall 25 along the direction inclined by the inclination angle θ from the horizontal plane. The peripheral edge of the hole 252 protrudes outward. The fastening portion 30 for the spray nozzle protrudes from the end of the cylindrical protrusion 29 in a direction orthogonal to the direction in which the cylindrical protrusion 29 extends.

接著,將噴射嘴5固定於第1側壁25。噴射嘴5之噴出口側緊固部63藉由緊固裝置66(66A)固定於吸收塔2之噴射嘴用緊固部30。圖示之實施形態中,緊固裝置66A(第2緊固裝置)包含螺栓67(67A)與螺母68(68A)。Next, the spray nozzle 5 is fixed to the first side wall 25. The ejection outlet side fastening portion 63 of the ejection nozzle 5 is fixed to the ejection nozzle fastening portion 30 of the absorption tower 2 by a fastening device 66 (66A). In the illustrated embodiment, the fastening device 66A (second fastening device) includes a bolt 67 (67A) and a nut 68 (68A).

螺栓67(67A)具備:軸部671,其至少於外周面之一部分形成有螺紋部;及頭部672,其於軸部671之基端部形成為較軸部671更大徑。於噴出口側緊固部63與噴射嘴用緊固部30,沿著筒狀突出部29延伸之方向形成有可供螺栓67A之軸部671插通的貫通孔631、301。螺栓67A中,軸部671自筒狀突出部29延伸之方向之一側插通至形成於噴出口側緊固部63及噴射嘴用緊固部30之貫通孔631、301,且插通至筒狀突出部29延伸之方向之另一側之軸部671之末端與螺母68A螺合,藉此將噴射嘴5固定於第1側壁25。The bolt 67 (67A) includes a shaft portion 671 in which a threaded portion is formed on at least a part of the outer peripheral surface, and a head portion 672 in which the base end of the shaft portion 671 is formed to have a larger diameter than the shaft portion 671. The ejection port side fastening portion 63 and the ejection nozzle fastening portion 30 are formed with through holes 631 and 301 along the direction in which the cylindrical protrusion 29 extends, through which the shaft portion 671 of the bolt 67A can be inserted. In the bolt 67A, the shaft portion 671 is inserted from one side of the direction in which the cylindrical protrusion 29 extends to the through holes 631, 301 formed in the ejection port-side fastening portion 63 and the ejection nozzle fastening portion 30, and is inserted to The end of the shaft 671 on the other side of the direction in which the cylindrical protrusion 29 extends is screwed with the nut 68A, thereby fixing the spray nozzle 5 to the first side wall 25.

將噴射嘴5固定於第1側壁25後,將氣體導入線42連接於噴射嘴5。圖示之實施形態中,噴射嘴5如圖5所示,進而包含自第2筒狀部54之形成有第2氣體導入口59之端部外周突出設置之氣體導入側緊固部64。如圖4所示,氣體導入線42包含:氣體導入管47,其連接於第2筒狀部54之上游側;上述之第2伸縮管接頭45B,其連接於氣體導入管47之上游側;及第2氣體導入管49,其連接於第2伸縮管接頭45B之上游側。After fixing the spray nozzle 5 to the first side wall 25, the gas introduction line 42 is connected to the spray nozzle 5. In the illustrated embodiment, as shown in FIG. 5, the injection nozzle 5 further includes a gas introduction side fastening portion 64 protruding from the outer periphery of the end of the second cylindrical portion 54 where the second gas introduction port 59 is formed. As shown in Fig. 4, the gas introduction line 42 includes: a gas introduction pipe 47 connected to the upstream side of the second cylindrical portion 54; the aforementioned second expansion pipe joint 45B, which is connected to the upstream side of the gas introduction pipe 47; And the second gas introduction pipe 49 is connected to the upstream side of the second expansion pipe joint 45B.

如圖4所示,氣體導入管47包含:氣體下游側緊固部48(參照圖5),其自形成有連通於第2氣體導入口59之開口之下游側端部之外周突出設置;及氣體上游側緊固部472,其自上游側端部之外周突出設置。第2氣體導入管49包含自下游側端部之外周突出設置之第2氣體下游側緊固部491。As shown in FIG. 4, the gas introduction pipe 47 includes: a gas downstream side fastening portion 48 (refer to FIG. 5), which protrudes from the outer periphery of the downstream side end where the opening communicating with the second gas introduction port 59 is formed; and The gas upstream side fastening portion 472 is provided to protrude from the outer periphery of the upstream side end portion. The second gas introduction pipe 49 includes a second gas downstream side fastening portion 491 protrudingly provided from the outer periphery of the downstream side end portion.

氣體導入管47之氣體下游側緊固部48藉由緊固裝置66(66B)而固定於噴射嘴5之氣體導入側緊固部64。圖示之實施形態中,緊固裝置66B包含:螺栓67B,其具備與螺栓67A同樣之構成;及螺母68B,其具備與螺母68A同樣之構成。螺栓67B在插通至形成於氣體導入側緊固部64及氣體下游側緊固部48之貫通孔641、481的軸部671之末端與螺母68B螺合,而將氣體導入管47固定於噴射嘴5之第2筒狀部54。The gas downstream side fastening portion 48 of the gas introduction pipe 47 is fixed to the gas introduction side fastening portion 64 of the injection nozzle 5 by the fastening device 66 (66B). In the illustrated embodiment, the fastening device 66B includes a bolt 67B, which has the same structure as the bolt 67A, and a nut 68B, which has the same structure as the nut 68A. The bolt 67B is inserted into the through holes 641 and 481 formed in the gas introduction side fastening portion 64 and the gas downstream side fastening portion 48 at the end of the shaft portion 671 and screwed with the nut 68B to fix the gas introduction tube 47 to the jet The second cylindrical portion 54 of the mouth 5.

如圖4所示,第2伸縮管接頭45B藉由緊固裝置66(66E)將下游側緊固部453(453B)固定於氣體導入管47之氣體上游側緊固部472,藉由緊固裝置66(66F)將上游側緊固部454(454B)固定於第2氣體導入管49之第2氣體下游側緊固部491。圖示之實施形態中,緊固裝置66E、66F與緊固裝置66B同樣地包含螺栓與螺母。As shown in FIG. 4, the second expansion pipe joint 45B fixes the downstream side fastening portion 453 (453B) to the gas upstream side fastening portion 472 of the gas introduction pipe 47 by the fastening device 66 (66E). The device 66 (66F) fixes the upstream fastening portion 454 (454B) to the second gas downstream fastening portion 491 of the second gas introduction pipe 49. In the illustrated embodiment, the fastening devices 66E and 66F include bolts and nuts similarly to the fastening device 66B.

將噴射嘴5固定於第1側壁25後,將清洗液導入線41連接於噴射嘴5。清洗液導入線41與噴射嘴5之連接可與氣體導入線42與噴射嘴5之連接同時進行,亦可在氣體導入線42與噴射嘴5之連接之前或之後進行。After fixing the spray nozzle 5 to the first side wall 25, the cleaning liquid introduction line 41 is connected to the spray nozzle 5. The connection between the cleaning liquid introduction line 41 and the spray nozzle 5 can be performed at the same time as the connection between the gas introduction line 42 and the spray nozzle 5, or before or after the connection between the gas introduction line 42 and the spray nozzle 5.

噴射嘴5如圖5所示,進而包含自第1筒狀部52之形成有清洗液導入口56之端部外周突出設置之清洗液導入側緊固部65。如圖4所示,清洗液導入線41包含連接於第1筒狀部52之上游側之上述之第1伸縮管接頭45A、及連接於第1伸縮管接頭45A之上游側之清洗液導入管46。清洗液導入管46包含自下游側端部之外周突出設置之清洗液下游側緊固部461。As shown in FIG. 5, the spray nozzle 5 further includes a cleaning liquid introduction side fastening portion 65 protruding from the outer periphery of the end of the first cylindrical portion 52 where the cleaning liquid introduction port 56 is formed. As shown in FIG. 4, the cleaning liquid introduction line 41 includes the above-mentioned first expansion pipe joint 45A connected to the upstream side of the first cylindrical portion 52, and a cleaning liquid introduction pipe connected to the upstream side of the first expansion pipe joint 45A 46. The cleaning liquid introduction pipe 46 includes a cleaning liquid downstream side fastening portion 461 protruding from the outer periphery of the downstream end portion.

如圖5所示,第1伸縮管接頭45A藉由緊固裝置66C(第1緊固裝置)將下游側緊固部453(453A)固定於噴射嘴5之清洗液導入側緊固部65。圖示之實施形態中,緊固裝置66C包含:螺栓67C,其具備與螺栓67A同樣之構成;及螺母68C,其具備與螺母68A同樣之構成。螺栓67C在插通至形成於清洗液導入側緊固部65及下游側緊固部453(453A)之貫通孔651、456的軸部671之末端與螺母68C螺合,而以於第1筒狀部52與第1伸縮管接頭45A之間夾著限縮部53之狀態,將第1伸縮管接頭45A固定於噴射嘴5之第1筒狀部52。As shown in FIG. 5, the 1st expansion pipe joint 45A fixes the downstream side fastening part 453 (453A) to the cleaning liquid introduction side fastening part 65 of the spray nozzle 5 by the fastening device 66C (1st fastening device). In the illustrated embodiment, the fastening device 66C includes a bolt 67C, which has the same structure as the bolt 67A, and a nut 68C, which has the same structure as the nut 68A. The bolt 67C is inserted into the through holes 651, 456 formed in the cleaning fluid introduction side fastening portion 65 and the downstream side fastening portion 453 (453A) at the end of the shaft portion 671 and the nut 68C is screwed to the first cylinder The first telescopic tube joint 45A is fixed to the first cylindrical part 52 of the spray nozzle 5 in a state where the constriction restricting part 53 is sandwiched between the shaped part 52 and the first telescopic tube joint 45A.

如圖4所示,第1伸縮管接頭45A藉由緊固裝置66(66D)將上游側緊固部454(454A)固定於清洗液導入管46之清洗液下游側緊固部461。圖示之實施形態中,緊固裝置66D與緊固裝置66C同樣地包含螺栓與螺母。As shown in FIG. 4, the first expansion pipe joint 45A fixes the upstream fastening portion 454 (454A) to the cleaning liquid downstream fastening portion 461 of the cleaning liquid introduction pipe 46 by the fastening device 66 (66D). In the illustrated embodiment, the fastening device 66D includes bolts and nuts similarly to the fastening device 66C.

圖示之實施形態中,如圖4所示,將噴出口51之中心軸CA自水平面傾斜之角度設為θ,將第1伸縮管接頭45A之軸線CE1自水平面傾斜之角度設為θ1之情形時,傾斜角度θ1為θ±5°之範圍內。即,第1伸縮管接頭45A之軸線CE1沿著平行於噴出口51之中心軸CA之方向延伸。於該情形時,可減少自第1伸縮管接頭45A向第1筒狀部52輸送清洗液時之阻力。此外,另一實施形態中,上述之θ1亦可為上述之θ±5°之範圍外。 又,圖示之實施形態中,如圖4所示,第2伸縮管接頭45B位於較第1伸縮管接頭45A更上方。In the illustrated embodiment, as shown in FIG. 4, the angle at which the central axis CA of the ejection port 51 is inclined from the horizontal plane is set to θ, and the angle at which the axis CE1 of the first expansion joint 45A is inclined from the horizontal plane is set to θ1 When the inclination angle θ1 is within the range of θ±5°. That is, the axis CE1 of the first telescopic pipe joint 45A extends in a direction parallel to the central axis CA of the ejection port 51. In this case, it is possible to reduce the resistance when the cleaning liquid is sent from the first expansion joint 45A to the first cylindrical portion 52. In addition, in another embodiment, the aforementioned θ1 may be outside the aforementioned range of θ±5°. Moreover, in the illustrated embodiment, as shown in FIG. 4, the second expansion joint 45B is located above the first expansion joint 45A.

如上所述,若干實施形態中,如圖5所示,上述之噴射嘴5具備上述之清洗液導入側緊固部65,其自第1筒狀部52之較與第2筒狀部54之連接部或合流部60更靠清洗液流動方向之上游側之、形成有清洗液導入口56的端部外周突出設置。上述之第1伸縮管接頭45A包含上述之下游側緊固部453A,其沿著與上述第1伸縮管接頭45A之軸線CE1延伸之方向交叉的方向自主體部451之端部外周突出設置。下游側緊固部453A構成為於第1伸縮管接頭45A與第1筒狀部52之間夾著限縮部53之狀態下,藉由緊固裝置66C(第1緊固裝置)固定於下游側緊固部453A。As described above, in some embodiments, as shown in FIG. 5, the above-mentioned spray nozzle 5 is provided with the above-mentioned cleaning liquid introduction side fastening portion 65, which is compared with the second cylindrical portion 54 from the first cylindrical portion 52 The connecting portion or the merging portion 60 is protrudingly provided on the upstream side of the flow direction of the cleaning liquid on the outer periphery of the end where the cleaning liquid inlet 56 is formed. The aforementioned first telescopic pipe joint 45A includes the aforementioned downstream side fastening portion 453A, which protrudes from the outer periphery of the end portion of the main body portion 451 in a direction intersecting the direction in which the axis CE1 of the aforementioned first telescopic pipe joint 45A extends. The downstream fastening portion 453A is configured to be fixed downstream by a fastening device 66C (first fastening device) in a state in which the constriction portion 53 is sandwiched between the first telescopic pipe joint 45A and the first cylindrical portion 52 Side fastening part 453A.

根據上述之構成,第1伸縮管接頭45A之下游側緊固部453A於第1伸縮管接頭45A與第1筒狀部52之間夾著限縮部53之狀態下,藉由緊固裝置66C(第1緊固裝置)固定於噴射嘴5之清洗液導入側緊固部65。由於將第1伸縮管接頭45A直接固定於噴射嘴5,故可有效地吸收因來自清洗液導入線41之振動或熱引起之收縮。According to the above-mentioned configuration, the downstream side fastening portion 453A of the first expansion joint 45A is sandwiched between the first expansion joint 45A and the first cylindrical portion 52 by the fastening device 66C. (First fastening device) The cleaning liquid introduction side fastening part 65 fixed to the spray nozzle 5. Since the first telescopic pipe joint 45A is directly fixed to the spray nozzle 5, it can effectively absorb the shrinkage caused by the vibration or heat from the cleaning liquid introduction line 41.

若干實施形態之排氣脫硫裝置1具備上述之吸收塔2與上述之氣液混合裝置4。根據上述構成,吸收塔2構成為使清洗液與導入至內部之排氣進行氣液接觸,且於內部劃定用以儲存清洗液之集液部21B。氣液混合裝置4可藉由自噴射嘴5之噴出口51噴出至吸收塔2之集液部21B之混合流體MF,對儲存於吸收塔2之集液部21B之清洗液產生充分之氧化反應。又,根據上述構成,由於可防止自相互正交之2個方向各自對噴射嘴5疊加傳遞因振動或熱引起之收縮,故可抑制噴射嘴5之磨耗或損傷。The exhaust gas desulfurization device 1 of some embodiments includes the above-mentioned absorption tower 2 and the above-mentioned gas-liquid mixing device 4. According to the above-mentioned configuration, the absorption tower 2 is configured such that the cleaning liquid and the exhaust gas introduced into the inside are brought into gas-liquid contact, and the liquid collecting part 21B for storing the cleaning liquid is defined inside. The gas-liquid mixing device 4 can produce a sufficient oxidation reaction to the cleaning liquid stored in the liquid collecting part 21B of the absorption tower 2 by spraying the mixed fluid MF from the spray outlet 51 of the spray nozzle 5 to the liquid collecting part 21B of the absorption tower 2 . In addition, according to the above-mentioned structure, since the shrinkage caused by vibration or heat can be prevented from being superimposed and transmitted to the injection nozzle 5 from two directions orthogonal to each other, the abrasion or damage of the injection nozzle 5 can be suppressed.

若干實施形態中,上述之噴射嘴5(氣液混合裝置4)包含上述之第1筒狀部52與上述之噴出口側緊固部63。且,上述之吸收塔2包含上述之筒狀突出部29與上述之噴射嘴用緊固部30。In some embodiments, the above-mentioned injection nozzle 5 (gas-liquid mixing device 4) includes the above-mentioned first cylindrical part 52 and the above-mentioned discharge port side fastening part 63. In addition, the aforementioned absorption tower 2 includes the aforementioned cylindrical projection 29 and the aforementioned nozzle fastening portion 30.

根據上述構成,於將第1筒狀部52之包含噴出口51之末端插通至形成於吸收塔2之側壁(第1側壁25等)之插通孔252之狀態下,藉由緊固裝置66A(第2緊固裝置)將噴射嘴5(氣液混合裝置4)之噴出口側緊固部63固定於吸收塔2之噴射嘴用緊固部30。由於噴射嘴5固定於吸收塔2,故假若即便自清洗液導入線41及氣體導入線42兩者對噴射嘴5傳遞因振動或熱引起之收縮,亦可防止噴射嘴5之噴出口51之位置或角度偏移而使得自噴射嘴5噴射之混合流體MF對清洗液之氧化反應降低。According to the above configuration, in a state where the end of the first cylindrical portion 52 including the ejection port 51 is inserted into the insertion hole 252 formed in the side wall (first side wall 25 etc.) of the absorption tower 2, the fastening device 66A (second fastening device) fixes the ejection port side fastening portion 63 of the injection nozzle 5 (gas-liquid mixing device 4) to the injection nozzle fastening portion 30 of the absorption tower 2. Since the injection nozzle 5 is fixed to the absorption tower 2, even if both the cleaning liquid introduction line 41 and the gas introduction line 42 transmit the contraction due to vibration or heat to the injection nozzle 5, it can prevent the ejection port 51 of the injection nozzle 5 from falling The position or angle is shifted to reduce the oxidation reaction of the mixed fluid MF sprayed from the spray nozzle 5 to the cleaning liquid.

又,根據上述之構成,第1筒狀部52沿著噴出口51之中心軸CA延伸。吸收塔2之筒狀突出部29沿著自水平面傾斜與噴出口51之中心軸CA自水平面傾斜之角度θ相同角度之方向延伸。即,吸收塔2之筒狀突出部29沿著與設置有第1筒狀部52時之噴出口51之中心軸CA相同之方向延伸。第1筒狀部52因藉由緊固裝置66A固定沿著與第1筒狀部52延伸之方向正交的方向延伸之噴出口側緊固部63、及沿著與筒狀突出部29延伸之方向正交之方向延伸的噴射嘴用緊固部30,從而可將噴出口51之中心軸CA自水平面傾斜之角度θ直接作為設置角度。因此,根據上述構成,無需調整第1筒狀部52之設置角度之作業,可使第1筒狀部52之安裝作業容易化。Furthermore, according to the above-mentioned configuration, the first cylindrical portion 52 extends along the central axis CA of the ejection port 51. The cylindrical protrusion 29 of the absorption tower 2 extends in a direction inclined from the horizontal plane at the same angle as the angle θ at which the central axis CA of the ejection outlet 51 is inclined from the horizontal plane. That is, the cylindrical protrusion 29 of the absorption tower 2 extends in the same direction as the central axis CA of the ejection port 51 when the first cylindrical portion 52 is provided. The first cylindrical portion 52 is fixed by the fastening device 66A along the ejection port side fastening portion 63 extending in the direction orthogonal to the direction in which the first cylindrical portion 52 extends, and extends along the cylindrical protrusion 29 The fastening portion 30 for the spray nozzle extending in the direction orthogonal to the direction of the spray nozzle can directly use the angle θ at which the central axis CA of the spray port 51 is inclined from the horizontal plane as the installation angle. Therefore, according to the above-mentioned structure, the work of adjusting the installation angle of the first cylindrical portion 52 is unnecessary, and the installation work of the first cylindrical portion 52 can be facilitated.

本發明非限定於上述之實施形態,亦包含對上述之實施形態加以變化之形態或將該等形態適當組合之形態。The present invention is not limited to the above-mentioned embodiment, but also includes a form in which the above-mentioned embodiment is changed or a form in which these forms are appropriately combined.

例如,上述之若干實施形態中,排氣排出部24於第1方向上夾著吸收塔本體部22而設置於與排氣導入部23相反側,但亦可設置於與排氣導入部23相同側。又,排氣排出部24亦可設置為俯視時與第1方向正交之第2方向上與吸收塔本體部22相鄰。For example, in some of the above-mentioned embodiments, the exhaust gas discharge portion 24 is provided on the opposite side of the exhaust gas introduction portion 23 with the absorption tower main body portion 22 interposed in the first direction, but it may be provided in the same manner as the exhaust gas introduction portion 23. side. Moreover, the exhaust gas discharge part 24 may be provided so that it may be adjacent to the absorption tower main body part 22 in the 2nd direction orthogonal to the 1st direction in plan view.

1:排氣脫硫裝置 2:吸收塔 4:氣液混合裝置 5:噴射嘴 7:清洗液循環線 8:清洗液供給線 9:清洗液排出線 21:內部空間 21A:氣液接觸部 21B:集液部 21C:下方側內部空間 21D:上方側內部空間 22:吸收塔本體部 23:排氣導入部 24:排氣排出部 25:第1側壁 26:第2側壁 27:除霧器 28:散佈裝置 29:筒狀突出部 30:噴射嘴用緊固部 41:清洗液導入線 42:氣體導入線 44:分支部 45:伸縮管接頭 45A:第1伸縮管接頭 45B:第2伸縮管接頭 46:清洗液導入管 47:氣體導入管 48:氣體下游側緊固部 49:第2氣體導入管 51:噴出口 52:第1筒狀部 53:限縮部 54:第2筒狀部 55:第1流道 56:清洗液導入口 57:氣體導入口 58:第2流道 59:第2氣體導入口 60:合流部 61:縮流形成口 62:負壓區域 63:噴出口側緊固部 64:氣體導入側緊固部 65:清洗液導入側緊固部 66:緊固裝置 66A~66F:緊固裝置 67A~67C:螺栓 68A~68C:螺母 71:配管 72:清洗液循環泵 73:分支部 81:清洗液儲存槽 82:配管 91:裝置 211:底面 251:排氣導入口 252:插通孔 261:排氣排出口 262:引出口 281:灑水管 282:灑水噴嘴 301:貫通孔 451:主體部 452:伸縮囊 453:下游側緊固部 453A:下游側緊固部 453B:下游側緊固部 454:上游側緊固部 454A:上游側緊固部 454B:上游側緊固部 455:導入流道 456:貫通孔 461:清洗液下游側緊固部 472:氣體上游側緊固部 481:貫通孔 491:第2氣體下游側緊固部 631:貫通孔 641:貫通孔 651:貫通孔 671:軸部 672:頭部 CA:噴出口之中心軸 CA2:氣體導入口之中心軸 CE1:第1伸縮管接頭之軸線 CE2:第2伸縮管接頭之軸線 G:氣體 MF:混合流體 θ:傾斜角度 θ1:傾斜角度1: Exhaust desulfurization device 2: Absorption tower 4: Gas-liquid mixing device 5: Jet nozzle 7: Cleaning fluid circulation line 8: Cleaning fluid supply line 9: Cleaning fluid discharge line 21: Internal space 21A: Gas-liquid contact part 21B: Liquid Collection 21C: Lower inner space 21D: Upper internal space 22: Absorption tower body 23: Exhaust introduction part 24: Exhaust discharge part 25: 1st side wall 26: 2nd side wall 27: Demister 28: Spreading device 29: cylindrical protrusion 30: Fastening part for nozzle 41: Cleaning fluid introduction line 42: Gas introduction line 44: Branch 45: Expansion pipe joint 45A: 1st expansion pipe joint 45B: 2nd expansion pipe joint 46: Cleaning fluid inlet pipe 47: Gas inlet pipe 48: Gas downstream side fastening part 49: The second gas introduction pipe 51: spout 52: The first cylindrical part 53: Restriction 54: The second cylindrical part 55: first runner 56: Cleaning fluid inlet 57: Gas inlet 58: 2nd runner 59: Second gas inlet 60: Confluence Department 61: Contraction flow forming mouth 62: negative pressure area 63: Fastening part on the outlet side 64: Gas inlet side fastening part 65: Washing fluid introduction side fastening part 66: Fastening device 66A~66F: Fastening device 67A~67C: Bolt 68A~68C: Nut 71: Piping 72: Cleaning fluid circulation pump 73: Branch 81: Cleaning fluid storage tank 82: Piping 91: device 211: Bottom 251: Exhaust inlet 252: Through hole 261: Exhaust outlet 262: Secret 281: Sprinkler Pipe 282: Sprinkler nozzle 301: Through hole 451: Main Body 452: bellows 453: Downstream fastening part 453A: Downstream side fastening part 453B: Downstream side fastening part 454: Upstream fastening part 454A: Upstream fastening part 454B: Upstream fastening part 455: Import runner 456: through hole 461: Downstream fastening part of cleaning fluid 472: Gas upstream side fastening part 481: Through hole 491: 2nd gas downstream side fastening part 631: Through hole 641: Through hole 651: Through hole 671: Shaft 672: head CA: The central axis of the nozzle CA2: Central axis of gas inlet CE1: The axis of the first expansion pipe joint CE2: The axis of the second expansion pipe joint G: gas MF: Mixed fluid θ: tilt angle θ1: Tilt angle

圖1係顯示一實施形態之排氣脫硫裝置之概略構成之剖視圖。 圖2係用以說明一實施形態之噴射嘴之功能之噴射嘴的概略剖視圖。 圖3係顯示一實施形態之噴射嘴之概略構成之剖視圖。 圖4係概略性顯示吸收塔中之固定噴射嘴之部分附近之圖,且係用以說明第1伸縮管接頭及第2伸縮管接頭的圖。 圖5係概略性顯示吸收塔中之固定噴射嘴之部分附近之局部剖視圖。Fig. 1 is a cross-sectional view showing a schematic configuration of an exhaust gas desulfurization device according to an embodiment. Fig. 2 is a schematic cross-sectional view of a spray nozzle for explaining the function of the spray nozzle of an embodiment. Fig. 3 is a cross-sectional view showing the schematic configuration of an injection nozzle according to an embodiment. Fig. 4 is a diagram schematically showing the vicinity of the part where the spray nozzle is fixed in the absorption tower, and is a diagram for explaining the first expansion joint and the second expansion joint. Figure 5 is a partial cross-sectional view schematically showing the vicinity of the fixed spray nozzle in the absorption tower.

4:氣液混合裝置 4: Gas-liquid mixing device

5:噴射嘴 5: Jet nozzle

25:第1側壁 25: 1st side wall

29:筒狀突出部 29: cylindrical protrusion

41:清洗液導入線 41: Cleaning fluid introduction line

42:氣體導入線 42: Gas introduction line

45:伸縮管接頭 45: Expansion pipe joint

45A:第1伸縮管接頭 45A: 1st expansion pipe joint

45B:第2伸縮管接頭 45B: 2nd expansion pipe joint

46:清洗液導入管 46: Cleaning fluid inlet pipe

47:氣體導入管 47: Gas inlet pipe

49:第2氣體導入管 49: The second gas introduction pipe

52:第1筒狀部 52: The first cylindrical part

53:限縮部 53: Restriction

54:第2筒狀部 54: The second cylindrical part

66A~66F:緊固裝置 66A~66F: Fastening device

451:主體部 451: Main Body

452:伸縮囊 452: bellows

453:下游側緊固部 453: Downstream fastening part

453A:下游側緊固部 453A: Downstream side fastening part

453B:下游側緊固部 453B: Downstream side fastening part

454:上游側緊固部 454: Upstream fastening part

454A:上游側緊固部 454A: Upstream fastening part

454B:上游側緊固部 454B: Upstream fastening part

455:導入流道 455: Import runner

461:清洗液下游側緊固部 461: Downstream fastening part of cleaning fluid

472:氣體上游側緊固部 472: Gas upstream side fastening part

491:第2氣體下游側緊固部 491: 2nd gas downstream side fastening part

CA:噴出口之中心軸 CA: The central axis of the nozzle

CE1:第1伸縮管接頭之軸線 CE1: The axis of the first expansion pipe joint

CE2:第2伸縮管接頭之軸線 CE2: The axis of the second expansion pipe joint

θ:傾斜角度 θ: tilt angle

θ1:傾斜角度 θ1: Tilt angle

Claims (5)

一種氣液混合裝置,其係包含噴射嘴者,該噴射嘴構成為朝以使清洗液與自燃燒裝置排出之排氣進行氣液接觸之方式構成之吸收塔中之用於儲存上述清洗液的集液部,噴射含氧之氣體及上述清洗液;且 上述噴射嘴具備: 第1筒狀部,其於內部劃定第1流道,且形成有用以將上述清洗液導入至上述第1流道之清洗液導入口、用以沿著相對於自上述清洗液導入口導入而於上述第1流道流動之上述清洗液之流動方向正交之方向將上述氣體導入至上述第1流道的氣體導入口、及噴出自上述清洗液導入口導入之上述清洗液與自上述氣體導入口導入之上述氣體之混合流體的噴出口; 限縮部,其設置於較自上述清洗液導入口導入之上述清洗液與自上述氣體導入口導入之上述氣體合流之合流部更靠上述清洗液之流動方向之上游側;及 第2筒狀部,其於內部劃定連通於上述氣體導入口之第2流道,且形成有用以將上述氣體沿著相對於上述清洗液之流動方向正交之方向導入至上述第2流道的第2氣體導入口; 上述氣液混合裝置進而包含: 伸縮管接頭,其係包含於內部劃定用以輸送上述清洗液或上述氣體之導入流道且至少沿著上述導入流道延伸之方向伸縮自如地構成的主體部者,且設置於用以將上述清洗液自上述清洗液導入口輸送至上述第1流道之清洗液導入線、或用以將上述氣體自上述第2氣體導入口輸送至上述第2流道之氣體導入線中之至少一者。A gas-liquid mixing device comprising an injection nozzle configured to store the cleaning liquid in an absorption tower constructed in such a way that the cleaning liquid and exhaust gas discharged from the combustion device are in gas-liquid contact The liquid collecting part sprays oxygen-containing gas and the above-mentioned cleaning liquid; and The above spray nozzle has: The first cylindrical portion defines a first flow path inside, and is formed with a cleaning liquid inlet for introducing the cleaning liquid to the first flow path, and is used to guide the cleaning liquid along the direction relative to the cleaning liquid inlet The gas is introduced into the gas inlet of the first flow channel in a direction orthogonal to the flow direction of the cleaning liquid flowing in the first flow channel, and the cleaning liquid introduced from the cleaning liquid inlet is ejected from the cleaning liquid. The jet port of the mixed fluid of the above gas introduced by the gas inlet; A constriction part, which is arranged on the upstream side of the flow direction of the cleaning liquid than the confluence part where the cleaning liquid introduced from the cleaning liquid inlet and the gas introduced from the gas inlet merge; and The second cylindrical portion defines a second flow passage communicating with the gas inlet and is formed to introduce the gas to the second flow in a direction orthogonal to the flow direction of the cleaning liquid The second gas inlet of the road; The gas-liquid mixing device further includes: The telescopic pipe joint includes a main body that is configured to extend and retract at least along the direction in which the introduction channel extends, and is provided for At least one of the cleaning liquid introduced from the cleaning liquid inlet to the cleaning liquid introduction line of the first flow channel, or the gas introduction line used to transport the gas from the second gas inlet to the second flow channel By. 如請求項1之氣液混合裝置,其中 上述伸縮接頭設置於上述清洗液導入線及上述氣體導入線兩者。Such as the gas-liquid mixing device of claim 1, where The expansion joint is provided in both the cleaning liquid introduction line and the gas introduction line. 如請求項1或2之氣液混合裝置,其中 上述噴射嘴進而具備:清洗液導入側緊固部,其自上述第1筒狀部之較上述合流部更靠上述清洗液之流動方向之上游側之外周突出設置;且 設置於上述清洗液導入線之上述伸縮管接頭即第1伸縮管接頭進而包含:下游側緊固部,其係沿著與上述第1伸縮管接頭之軸線延伸之方向交叉之方向自上述主體部之外周突出設置者,且於上述第1伸縮管接頭與上述第1筒狀部之間夾著上述限縮部之狀態下,藉由第1緊固裝置固定於上述清洗液導入側緊固部。Such as the gas-liquid mixing device of claim 1 or 2, where The spray nozzle further includes: a cleaning liquid introduction side fastening portion protruding from the outer periphery of the first cylindrical portion on the upstream side in the flow direction of the cleaning liquid than the confluence portion; and The first expansion pipe joint, which is the expansion pipe joint provided on the cleaning fluid introduction line, further includes: a downstream side fastening portion from the main body portion in a direction intersecting the direction in which the axis of the first expansion pipe joint extends The outer circumference is protruding, and the constriction is sandwiched between the first telescopic pipe joint and the first cylindrical part, and fixed to the cleaning liquid introduction side fastening part by the first fastening device . 一種排氣脫硫裝置,其係用以對自燃燒裝置排出之排氣進行脫硫者,且具備: 吸收塔,其構成為使清洗液與導入至內部之上述排氣進行氣液接觸,且於內部劃定用以儲存上述清洗液之集液部;及 請求項1至3中任一項之氣液混合裝置。An exhaust gas desulfurization device, which is used to desulfurize exhaust gas discharged from a combustion device, and has: An absorption tower, which is configured to make the cleaning liquid come into gas-liquid contact with the exhaust gas introduced into the interior, and a liquid collecting part for storing the cleaning liquid is defined inside; and The gas-liquid mixing device of any one of claims 1 to 3. 如請求項4之排氣脫硫裝置,其中 上述第1筒狀部沿著上述噴出口之中心軸延伸, 上述噴射嘴進而包含:噴出口側緊固部,其自上述第1筒狀部之較上述合流部更靠上述清洗液之流動方向之下游側之外周沿著與上述噴出口之上述中心軸正交的方向突出設置;且 上述吸收塔進而包含: 側壁,其係劃定上述集液部之至少一部分者,且形成有供上述第1筒狀部之包含上述噴出口之末端插通的插通孔; 筒狀突出部,其於將上述噴出口之上述中心軸自水平面傾斜之角度設為θ時,沿著自水平面傾斜與上述傾斜角度θ相同角度之方向,自上述側壁之上述插通孔之周緣部朝上述側壁之外側突出設置;及 噴射嘴用緊固部,其係自上述筒狀突出部之末端沿著與上述筒狀突出部延伸之方向正交的方向突出設置者,且構成為藉由第2緊固裝置而固定於上述噴出口側緊固部。Such as the exhaust gas desulfurization device of claim 4, where The first cylindrical portion extends along the central axis of the ejection port, The injection nozzle further includes: an ejection port side fastening portion that extends from the outer periphery of the first cylindrical portion on the downstream side of the flow direction of the cleaning liquid than the confluence portion and is aligned with the center axis of the ejection port The direction of intersection is prominently set; and The above absorption tower further includes: A side wall, which delimits at least a part of the liquid collecting part, and is formed with an insertion hole through which the end of the first cylindrical part including the ejection port is inserted; Cylindrical projection, when the angle at which the central axis of the ejection port is inclined from the horizontal plane is set to θ, along the direction inclined from the horizontal plane at the same angle as the inclination angle θ, from the peripheral edge of the insertion hole of the side wall The part protrudes toward the outer side of the side wall; and The fastening portion for the injection nozzle is one that protrudes from the end of the cylindrical protrusion in a direction orthogonal to the direction in which the cylindrical protrusion extends, and is configured to be fixed to the above by a second fastening device The fastening part on the ejection port side.
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