TW201917156A - Far infrared ray radiant thermal carbonization equipment capable of using heat and carbides generated during a process as a heating fuel to save energy - Google Patents

Far infrared ray radiant thermal carbonization equipment capable of using heat and carbides generated during a process as a heating fuel to save energy Download PDF

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TW201917156A
TW201917156A TW106136062A TW106136062A TW201917156A TW 201917156 A TW201917156 A TW 201917156A TW 106136062 A TW106136062 A TW 106136062A TW 106136062 A TW106136062 A TW 106136062A TW 201917156 A TW201917156 A TW 201917156A
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container
carbonization
waste
far
smoke
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TW106136062A
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TWI648318B (en
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林秋男
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林秋男
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Priority to CN201711265731.9A priority patent/CN109694716A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8643Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B51/00Destructive distillation of solid carbonaceous materials by combined direct and indirect heating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

A far-infrared radiant thermal carbonization equipment of the present invention is a far-infrared radiant thermal carbonization equipment which utilizes the same objects A and B, wherein the radiant heat generated by a material of the far infrared ray in a carbonization container is used to heat and to form an overall far-infrared radiant heat environment in the container, then waste is put into the container to be heated by the infrared ray in a sealed space, and the exterior is heated by a burner to dry, thermally decompose and finally carbonize the waste in the container by the action of the far-infrared radiant heat, further, in order to save energy (fuel), the heat and carbides generated by drying and thermal decomposition are injected into the external burner as a heating fuel through a pipeline for reuse, so that the formed carbonized matters, flue gas, and the likes generated in the container are reburned to remove residual substances.

Description

遠紅外線輻射熱碳化設備Far infrared radiation heat carbonization equipment

[0001] 本發明是關於碳化設備,尤其是有關利用遠紅外線輻射熱碳化裂解廢棄物的遠紅外線輻射熱碳化設備。[0001] The present invention relates to a carbonization device, and more particularly to a far-infrared radiant heat carbonization device that uses far-infrared radiant heat to carbonize and crack waste.

[0002] 以往,廢棄物的處理是以焚化爐設備為主,其設廠及儲存使用空間大,設備投資及維護成本高,合法地目難尋且昂貴,並在處理過程中容易造成空氣污染及隨時面對民眾抗爭事件等問題。[0002] In the past, waste treatment was mainly based on incinerator equipment, which had a large plant and storage space, high equipment investment and maintenance costs, legally difficult to find and expensive, and easy to cause air pollution during the process. Facing issues such as popular protests.

[發明所欲解決之課題]   [0003] 有鑑於上述已知的諸多問題,本發明人提出一種可置放於一般室內方便使用之廢棄物的遠紅外線輻射熱碳化設備,該碳化設備是利用遠紅外線的輻射熱及碳化容器以及循環水幫浦等特殊構造提供高性能的碳化裝置。 [用於解決課題的手段]   [0004] 為解決以上的問題,本發明提供一種碳化裂解廢棄物的設備,係利用遠紅外線幅射熱的碳化裂解廢棄物之相同個體A與B的設備,其特徵為:在本體碳化容器內利用遠紅線材料產生的輻射熱進行加熱,使該本體碳化容器內形成整體遠紅外線輻射熱,將廢棄物等投入該本體碳化容器內,在密閉的空間內以紅外線加熱,外部則利用燃燒器加溫使上述容器內的廢棄物等在上述遠紅外線輻射熱的作用下乾燥、熱分解最終碳化,並節省能源(燃料)再利用上述乾燥、熱分解所產生的熱量、碳化物作為加熱燃料經由通道注入本體外部燃燒裝置中,對上述容器內產生的碳化物質、煙氣等進行二次燃燒以燒除殘餘的物質。   [0005] 並且,本發明中,在上述本體碳化容器內形成整體遠紅外線輻射熱,該容器位於封閉的本體內空間,使用遠紅外線陶瓷加熱層由外部燃燒器加熱該碳化容器,利用燃料加熱所產生的熱及遠紅外線輻射熱,將投入上述碳化容器內的廢棄物等乾燥、熱分解,最後碳化,並將上述碳化容器產生的碳化物質、煙氣、臭味等再經導管導入上述外部加熱裝置中燃燒,形成二次燃燒以減少上述容器內所產生的碳化物質、煙氣等,以節省能源並利用上述碳化物質(可燃性氣體)為燃料快速加溫達到碳化容器內廢棄物的碳化。   [0006] 又,本發明中,利用上述乾燥、熱分解所產生的熱量、碳化物質等經控制器並導入氣體緩衝部並作為加熱燃料注入外部燃燒裝置中燃燒,形成二次燃燒將其碳化所產生的碳化物質、煙、臭味減至最少,並再利用尾器處理燃燒裝置將上述二次燃燒未完成的剩餘物質再次燃燒,將碳化所產生的物質完全燃燒,最終由催化觸媒對廢棄物等所產生的氣化物進行消煙、除臭。   [0007] 另外,本發明中,投入上述碳化容器內的廢棄物等,經加熱產生的煙及熱分解的氣化物作為燃燒燃料經導管導入上述外部熱燒器內,以減少上述容器內所產生的碳化物質,再利用一組或二組以上的水循環裝置(水幫浦),將熱分解後的煙及氣化物冷卻使其含有油、氣之氣化物和水混合儲存於循環水箱,所含的油氣經冷卻水中凝結形成浮油存浮於裝置內,在裝置內利用臭氧機(O3 )注入臭氧以分解浮於水面上之浮油以及有機物質。   [0008] 又,本發明中,至少包括一個或一個以上水循環裝置(水幫浦),使用於裝置內由上述容器內廢棄物所產生的裂解油氣進行分解以及至少包括一個或一個以上高溫燃燒處理器以及催化觸媒的消煙除臭器,使用於裝置內由碳化容器廢棄物所產生的煙氣進行消煙、除臭。   [0009] 又,本發明中,利用上述一組或二組以上的水循環裝置(水幫浦)抽取碳化裝置本體內的煙及氣化物,使上述碳化裝置內形成負壓,避免裝置本體內漏出煙氣及臭味。   [0010] 並且,本發明中,碳化容器內置攪拌器可將廢棄物於碳化過程中加以攪拌使碳化物受熱均勻加速碳化,以節省碳化時間。   [0011] 又,本發明中,上述碳化容器所產生的碳化物質、煙、臭味等經導管導入上述外部加熱裝置中燃燒以消煙、除臭,最後利用含貴金屬及氧化鈦的主要催化劑及遠紅外線層所形成的消煙、除臭器。   [0012] 進一步說明本發明如下:   1. 用於加熱處理的碳化容器內部置放遠紅外線加熱材料,外部設置燃料加熱器,將廢棄物投入容器內,在密閉的空間內以外部燃燒加熱遠紅外線的輻射熱的加熱方法將上述容器加熱,並且利用碳化容器蒸發的物質經控制器導至外部燃燒器中燃燒,形成二次燃燒,為提升熱值及節省燃料達快速處理及量產之需求,上述該容器特殊結構將容器內廢棄物攪拌粉碎加速碳化及上述方法所產生的熱量及遠紅外線輻射熱將廢棄物加熱乾燥、熱分解最後達到碳化的目的。   [0013] 利用遠紅外線輻射熱的加熱方法,熱輻射是一種電磁波,其傳導的熱量T14 -T24 成正比,一般加熱的方法物體間的傳熱有熱傳導、對流需靠傳熱介質,則傳導的熱量與二個物體間的溫度差T1-T2成正比。   遠紅外線加熱就是將輻射熱直接對物質的加熱,乾燥,利用遠紅外線的輻射熱進行加熱乾燥等可減少空氣等介質上的能量損失,於熱授受時易使特性匹配,所謂熱是指以分子觀點看儲存於物體內部的原子間震動等動能,以紅外線加熱時,若使用有助於受熱體原子間運動的能量波段(即紅外線活性基準振動波)的輻射,則可更有效地進行加熱。例如水(H2 O)為3原子分子其基準振動數為3個,亦即OH的對稱伸縮振動為3652cm-1 (2.7um)、逆對稱伸縮振動為3756cm-1 (2.66um)、變角振動為1595cm(6.27um),水分子為輕分子結合力強,其基本吸收帶在2.7um,接近有效吸收紅外線,任何物體只要在非零度都會放射紅外線,在使用於加熱、乾燥時紅外線放射體必須形成可有效促進被加熱原子間運動的紅外線放射特性。   [0014] 一般加熱大都採用把熱風送入乾燥室的對流方式進行乾燥加熱,是把空氣加熱成對流的熱,將熱傳導到被加熱體上,如果被加熱物質產生水蒸氣其蒸氣壓高時,即使增高溫度也不易乾燥,須將有能量的水蒸氣迅速放出外部,則損失未用於乾燥的熱能,若利用紅外線加熱不會對空氣進行不必要的加熱,直接將要加熱的物質加熱,使蒸發的水蒸氣迅速煇散,有效地進行加熱。   [0015] 本發明利用外部燃燒器加熱上述紅外線的特性,用於本體內部使形成整體遠紅外線輻射熱的加熱、乾燥方法,直接加熱被加熱物體,使蒸發的水蒸氣迅速飛散,經由循環水幫抽離加速熱分解效能,使被加熱的物質迅速碳化,熱分解中蒸發的氣化物被直接導入外部燃燒器燃燒,形成二次燃燒,再經由循環水幫浦吸引冷卻,將所含有的油氣凝結浮儲於水面經臭氧機於水中注入臭氧(O3 )分解浮儲物質。   [0016] 2. 利用遠紅外線的輻射熱加熱催化觸媒,對於廢棄物所產生的氣化物進行消煙、除臭。   [0017] 使用催化觸媒可降低廢氣的處理溫度並與一般常見的VOC廢氣處理之比較如下。   使用催化觸媒加熱碳化處理的主要反應如下:   VOC + O2 觸媒CO2 + H2 O   使用催化觸媒加熱及無催化劑觸媒加熱對一般VOC之比較如下: [0018] 3. 外部設置燃料燃燒加熱器在密閉的空間內利用外部加熱使遠紅線輻射熱得以加熱,碳化裝置製容器本體,其所述碳化裝置容器本體內部裝設陶瓷發熱材料形成內部整體遠紅外線輻射熱,將容器內碳化物加熱通過遠紅外線陶瓷輻射熱投射於上述碳化容器內的碳化物加以乾燥、熱分解的同時容器內特殊結構將容器內碳化物攪拌、粉碎加速碳化。   [0019] 4. 利用二次燃燒器將上述碳化容器內產生的氣化分解物及煙等蒸發物,其蒸發物為高熱值的碳氫化合物,將它直接導入氣體緩衝部再注入燃燒器中燃燒,使上述氣化分解物質經高溫燃燒碳化,將剩餘物質減至最少,同時提高碳化容器內物質碳化,再利用尾氣處理燃燒設備將二次燃燒未完全之煙及碳化物進行再次燃燒消煙、除臭並由含有催化觸媒的尾氣處理設備消煙除臭處理。   [0020] 5. 利用水循環水幫浦吸引碳化設備本體內碳化物所產生的煙及氣化物,使碳化設備本體內形成負壓以避免裝置本體內洩漏出煙及臭味,同時將氣化物冷卻凝結浮儲於水面,利用臭氧機注入(O3 )將浮儲於水面上之凝結油及有機物等氧化分解。   [0021] 6. 消煙除臭器可分二次燃燒及尾氣處理燃燒及臭氧消煙除、臭器,最終觸媒消煙除臭器其主要的成分是填充的鉑、鈀及氧化鈦等氧化劑,並注入臭氧以分解有害物質之成分。   [0022] 本發明碳化設備,係利用輸送帶或昇降機將廢棄物投入絞碎機經絞碎的廢棄物由輸送帶輸送,於輸送過程中的同時將廢棄物去除水分後風乾並投入碳化容器內,推壓旋轉門開關關閉碳化容器,外部燃燒器加熱並利用遠紅外線陶瓷材料產生的輻射熱將容器內碳化物加熱,本碳化設備的特點在於採用全自動的PLC控制下進行碳化,不會因過熱高溫而發生燃燒,碳化容器內的廢棄物是利用來自遠紅外線輻射熱的熱量加熱及外部燃料燃燒器的加熱而乾燥、熱分解。將蒸發氣化後的煙及氣化物經導管導至緩衝部再注入外部燃燒器中燃燒,形成二次燃燒的消煙、除臭、滅菌後的氣化物質經冷卻水洗浮儲於水面,經由臭氧機注入(O3 )分解氧化,剩餘氣化物質再經尾氣燃燒器再次燃燒,最終觸媒消煙除臭器再予以消煙、除臭分解其有害物質後排放於大氣。碳化容器內之碳化剩餘物質含微量的碳化物可作為一般處理過後的廢棄物處理,也可置放於一般土壤中。   [0023] 並且,說明本發明遠紅外線碳化裝置對於廢棄物的碳化方法如下:   [0024] 空氣污染中危害最深遠為戴奧辛(二噁英),戴奧辛(Dioxin)是一種化合物(如燃燒塑膠、塑膠袋含有戴奧辛),由兩個氧原子連接一對苯環類化合物所組成,當使用一般燃燒焚化分解方式時,燃燒材料中氯原子會形成化合物。本發明方法是在密封狀態下利用遠紅外線輻射熱加熱使上述廢棄物乾燥、熱分解、蒸發、碳化,它與一般燃燒方式在原理上完全不同,因不供給氧原子時,氧原子結合產生戴奧辛的量與燃燒方式比較減少許多。   [0025] 一般事業廢棄物及家庭廢棄物具有感染性及危險性以及處理時效之迫切性,廢棄物中大部份含有塑膠類如聚乙烯(Polyethlene)或有機矽(Silicon)樹脂等,以上述遠紅外線輻射熱的碳化方法將其熱分解成為低分子化後,氯化合物不能在與其結合並且由於聚乙烯為同類的分子物質因此實際反應也部會結合為戴奧辛。   [0026]   遠紅外線之作用    H-H-H-H   聚乙烯之結構 C-C-C-C    H-H-H-H   化學式:C-C、C-H之結合   [0027] 聚乙烯的C-C鍵吸收遠紅外線輻射中的特定波長,它的C-H鍵吸收遠紅外線輻射中的另一個特定波長後,分解成為活性自由基,當聚乙烯的C-C鍵及C-H鍵吸收遠紅外線而斷裂分解成為低分子自由基並在水中反應時,因聚乙烯自由基屬低分子物質,它與氫自由基反應時形成穩定的低分子物質。所形成的低分子中的C-C、C-H鍵再經遠紅外線輻射,形成更低分子的活性物質,它與氫原子反應形成氧化氣體,其帶有油脂氣體經水洗冷切於水中,利用臭氧產生器(O3 )氧化處理浮儲於水面之物質及油氣等最終可將有機物全部氧化還原。   [0028] 遠紅外線輻射碳化程序如下: 聚乙烯(Polyethylene)熱輻射、遠紅外線輻射(熱分解) 低分子、有機物熱輻射、遠紅外線輻射    (熱分解) 低分子化、有機物碳原子(C)    (熱分解、熱氧化分解、氧化) 無機物、碳酸氣體CO2 、H2 O   [0029] 臭氧之氧化反應機制:   臭氧為一強氧化劑,溶於水中後會維持臭氧分子形態或經過一串反應機制,行成氧化能力更高的氫氧自由基,因此不論是臭氧或氫氧自由基,均能以其強大的氧化能力對水中有機物加以破壞。臭氧在水中發生的反應如下:   O3 → O + O2 ,O + H2 O → 2HO,再鹼性介質中O3 可以OH- 反應,產生自由基的速度很快,即O3 + OH- → HO2 + O- 2 ,O3 + HO2 → HO +2O2 ,2HO2 → O3 + H2 O 產生的HO比O3 更強的氧化能力,能使有機物(RH)發生反應:   HO + RH → R + H2 O   R + O2 → RO2 RO2 + RH → ROOH + R   ROOH + HO → CO2 + H2 O + ……其他氧化產物 [發明效果]   [0030] 1. 碳化容器內使用遠紅外線陶瓷層經外部加熱器加熱形成整體遠紅外線的輻射熱的加熱,因此可透過整體遠紅外線輻射熱的加熱,碳化容器內的事業廢棄物或一般廢棄物,可獲得良好且均勻的熱貫穿效果,碳化容器為密閉以水幫浦吸引形成負壓因此不會產生過熱而燃燒,尤其處理事業廢棄物時,大部分為聚乙烯或樹脂類的物質,可利用遠紅外線輻射熱碳化可促進其穩定熱分解來缩短處理時間,以熱分解形成低分子化合物後,不再反應成為有害物質。   [0031] 2. 碳化容器的內壁裝設遠紅外線的陶瓷層,廢棄物除了可利用遠紅外線陶瓷層加熱,並利用外部燃燒裝置燃燒器具加熱於碳化容器,藉由外部的加熱使遠紅外線陶瓷層形成遠紅外線輻射熱,其可補助遠紅外線陶瓷加熱的加熱更能縮短處理時間,並可節省電費燃料費,碳化容器內形成遠紅外線的陶瓷層,不會有碳化物附著在內表面上之虞。   [0032] 3. 容器內置攪拌器經由控制器(A/B-1a)帶動馬達將攪拌器連桿升至170度後放開控制器由旋轉器旋轉將容器內廢棄物轉動,可使廢棄物獲得均熱加速碳化,可節省處理時間及費用。   [0033] 4. 利用水幫浦將容器內氣化物吸引使容器內行成負壓,不會有煙惡臭等洩漏之虞,更可加速碳化時間,其結構简單可長期使用。由水幫浦吸引容器內所產生的氣化物水洗冷卻含有油脂成分物質浮儲於水槽中由臭氧機(O3 )注入臭氧分解有害物質並於消煙除臭。   [0034] 5. 本裝置由於第1至第5消煙、除臭器應用多重方法具有高效果,不會造成公害。[Problems to be Solved by the Invention] [0003] In view of the above-mentioned known problems, the present inventor proposes a far-infrared radiant heat carbonization device that can be placed in wastes convenient for general indoor use. The carbonization device uses far-infrared The special structure of radiant heat and carbonization container and circulating water pump provides high-performance carbonization device. [Means for Solving the Problems] [0004] In order to solve the above problems, the present invention provides a device for carbonizing and cracking waste, which is a device for the same individuals A and B of carbonizing and cracking waste using far-infrared radiation heat. It is characterized by heating in the body carbonization container by the radiant heat generated by the far red wire material, so that the body carbonization container forms an overall far-infrared radiant heat, putting waste and the like into the body carbonization container, and heating with infrared rays in a closed space. The outside uses a burner to heat the waste in the container to dry and thermally decompose under the action of the far-infrared radiant heat, and finally saves energy (fuel) and reuses the heat and carbides generated by the drying and thermal decomposition. The heated fuel is injected into the external combustion device of the main body through the passage, and the carbonized materials, smoke, and the like generated in the container are subjected to secondary combustion to burn out the remaining materials. [0005] In the present invention, the entire far-infrared radiant heat is formed in the above-mentioned carbonized container. The container is located in a closed body space. The far-infrared ceramic heating layer is used to heat the carbonized container by an external burner, and the fuel is generated by heating. The heat and far-infrared radiant heat will dry and thermally decompose the waste and other materials put into the carbonization container, and finally carbonize, and then introduce the carbonized substances, smoke, odor, etc. generated by the carbonization container into the external heating device through a duct. Combustion to form secondary combustion to reduce carbonized materials, smoke, etc. generated in the container, to save energy and use the carbonized material (flammable gas) as a fuel to quickly warm up to carbonize the waste in the carbonized container. [0006] In the present invention, the heat generated by the above-mentioned drying and thermal decomposition, carbonized substances, etc. are introduced into a gas buffer section by a controller and injected into an external combustion device as a heating fuel for combustion, forming a secondary combustion to carbonize the carbonization chamber. The carbonized materials, smoke and odor generated are minimized, and the tailing treatment combustion device is used to reburn the remaining material that is not completed in the above secondary combustion. The carbonized materials are completely burned. The gaseous substances generated by the products are used for smoke elimination and deodorization. [0007] In addition, in the present invention, the waste and the like put into the carbonization container, the smoke and the thermally decomposed gaseous matter generated by the heating are introduced into the external thermal burner through a duct as a combustion fuel, so as to reduce the amount of the generated in the container. Carbonized materials, and then use one or two or more water circulation devices (water pumps) to cool the thermally decomposed smoke and gaseous materials so that the gaseous materials containing oil, gas, and water are mixed and stored in the circulating water tank. The oil and gas condensed in the cooling water to form slick oil and float in the device. In the device, an ozone machine (O 3 ) is used to inject ozone to decompose the slick oil and organic substances floating on the water surface. [0008] Furthermore, the present invention includes at least one or more water circulation devices (water pumps), which are used in the device to decompose the cracked oil and gas generated by the waste in the container and include at least one or more high temperature combustion treatments Device and catalytic catalyst smoke and deodorizer are used for smoke and deodorization in the device. [0009] In the present invention, the above-mentioned one or two or more sets of water circulation devices (water pumps) are used to extract smoke and gaseous substances in the body of the carbonization device, so that a negative pressure is formed in the carbonization device to prevent leakage from the body of the device. Smoke and odor. [0010] Moreover, in the present invention, the agitator built in the carbonization container can agitate the waste during the carbonization process to uniformly accelerate the carbonization by heating the carbide, so as to save the carbonization time. [0011] In the present invention, carbonized substances, smoke, and odors generated by the carbonization container are introduced into the external heating device through a duct to be burned to eliminate smoke and deodorization. Finally, a main catalyst containing precious metals and titanium oxide and Smoke and deodorizer formed by the far-infrared layer. [0012] The present invention is further explained as follows: 1. A far-infrared heating material is placed inside the carbonized container for heat treatment, a fuel heater is provided externally, the waste is put into the container, and the far-infrared is heated by external combustion in a closed space. The radiant heat heating method heats the above-mentioned container, and the material evaporated by the carbonized container is guided to the external burner for combustion by the controller to form a secondary combustion. In order to increase the heating value and save fuel for the needs of rapid processing and mass production, the above The special structure of the container stirs and pulverizes the waste in the container to accelerate the carbonization, and the heat and far-infrared radiation heat generated by the above method heat the waste to dry, thermally decompose, and finally achieve the purpose of carbonization. [0013] The heating method using far-infrared radiant heat, thermal radiation is an electromagnetic wave, and the conductive heat T1 4 -T2 4 is directly proportional. In general heating methods, the heat transfer between objects has thermal conduction, and convection depends on the heat transfer medium. The heat is proportional to the temperature difference T1-T2 between the two objects. Far-infrared heating is the direct heating and drying of material by radiant heat. Heating and drying using far-infrared radiation can reduce energy loss on media such as air, and it is easy to match characteristics when heat is received. The so-called heat refers to a molecular point of view. Kinetic energy such as inter-atomic vibration stored in an object can be heated more efficiently if it is irradiated with energy in a band of energy that contributes to the inter-atomic motion of the heated body (ie, the infrared active reference vibration wave). For example, water (H 2 O) is a three-atom molecule, and its reference vibration number is three, that is, the symmetrical stretching vibration of OH is 3652cm -1 (2.7um), the reverse symmetrical stretching vibration is 3756cm -1 (2.66um), and the variable angle The vibration is 1595cm (6.27um). Water molecules are light molecules with strong binding force. Its basic absorption band is 2.7um, which is close to effectively absorbing infrared rays. Any object emits infrared rays as long as it is not zero. Infrared radiators are used when heating and drying. It is necessary to form infrared radiation characteristics that can effectively promote the movement between heated atoms. [0014] Generally, heating is performed by convection in which hot air is sent into a drying chamber. Drying heating is performed by heating air into convective heat and transmitting heat to the heated body. If the heated substance generates water vapor and its vapor pressure is high, Even if the temperature is increased, it is not easy to dry. The energy water vapor must be quickly released to the outside, and the heat energy not used for drying is lost. If infrared heating is used, the air to be heated will not be heated unnecessarily, and the substance to be heated is directly heated to evaporate. The water vapor quickly dissipates and is effectively heated. [0015] The present invention utilizes the characteristics of heating the infrared rays by an external burner, and is used in the body for heating and drying methods that form the overall far-infrared radiant heat, directly heating the object to be heated, so that the evaporated water vapor is quickly scattered, and the circulating water helps Extraction accelerates the thermal decomposition efficiency, so that the heated material is quickly carbonized, and the vaporized vapors during thermal decomposition are directly introduced into the external burner for combustion, forming secondary combustion, and then attracted and cooled by the circulating water pump to condense the contained oil and gas Floating stored on the water surface, ozone (O 3 ) is injected into the water through an ozone machine to decompose floating storage materials. [0016] 2. The far-infrared radiant heat is used to heat the catalytic catalyst, and the smoke generated from the waste is deodorized and deodorized. [0017] The use of a catalytic catalyst can reduce the treatment temperature of the exhaust gas and compare it with the general VOC exhaust gas treatment as follows. The main reactions of carbonization treatment with catalytic catalyst are as follows: VOC + O 2 catalyst The comparison of CO 2 + H 2 O with catalytic catalyst heating and catalystless catalyst heating for general VOC is as follows: [0018] 3. An externally installed fuel combustion heater uses external heating to heat the far-red line radiation in a closed space. The container body is made of a carbonization device, and a ceramic heating material is installed inside the container body of the carbonization device to form an internal whole. Infrared radiant heat, the carbides in the container are heated through far-infrared ceramic radiant heat, and the carbides projected in the carbonized container are dried and thermally decomposed. At the same time, the special structure in the container stirs and pulverizes the carbides in the container to accelerate carbonization. [0019] 4. Use a secondary burner to vaporize the vaporized decomposition products and smoke and other vapors generated in the carbonization container, and the vapors are high-calorie hydrocarbons, which are directly introduced into the gas buffer section and then injected into the burner. Combustion, carbonizing the above-mentioned gasification and decomposition materials through high-temperature combustion, minimizing the remaining materials, and at the same time increasing the carbonization of the materials in the carbonization container, and then using the exhaust gas treatment combustion equipment to re-burn the incomplete smoke and carbides after the second combustion to eliminate the smoke Deodorization and deodorization by tail gas treatment equipment containing catalytic catalyst. [0020] 5. The water circulating water pump is used to attract the smoke and vapors generated by the carbides in the body of the carbonization device, so that a negative pressure is formed in the body of the carbonization device to prevent the smoke and odor from leaking out of the device body, while cooling the gas The condensed oil is stored on the water surface, and the ozone oil is injected (O 3 ) to oxidatively decompose the condensed oil and organic matter floating on the water surface. [0021] 6. The smoke and deodorizer can be divided into secondary combustion and exhaust gas treatment combustion and ozone smoke and deodorizer, and the final catalyst smoke and deodorizer is mainly composed of platinum, palladium and titanium oxide. An oxidant, and ozone is injected to break down the components of harmful substances. [0022] The carbonization equipment of the present invention uses a conveyor belt or a lift to put waste into a crusher. The crushed waste is transported by the conveyor belt. During the transportation process, the waste is removed from the water and air-dried and put into a carbonization container. , Push the revolving door switch to close the carbonization container, the external burner heats and uses the radiant heat generated by the far-infrared ceramic material to heat the carbide in the container. The feature of this carbonization equipment is that it adopts full-automatic PLC control to perform carbonization without overheating. Combustion occurs at high temperatures, and the waste in the carbonization container is dried and thermally decomposed by heating with heat from far-infrared radiation heat and heating by an external fuel burner. The vaporized vapors and vapors are guided to the buffer section through a duct and then injected into an external burner for combustion to form a secondary combustion to eliminate smoke, deodorize, and sterilize the vaporized material. They are washed, floated and stored on the water surface with cooling water. The ozone machine is injected (O 3 ) to decompose and oxidize, and the remaining gasified material is reburned by the exhaust gas burner. Finally, the catalyst smoke deodorizer will de-smoke, deodorize and decompose its harmful substances, and then discharge it to the atmosphere. The carbonized residue in the carbonization container contains a small amount of carbides, which can be treated as waste after general treatment or placed in general soil. [0023] Furthermore, the method for carbonizing waste by the far-infrared carbonization device of the present invention is described as follows: [0024] Dioxin (dioxin) is the most harmful in air pollution. Dioxin is a compound (such as burning plastic, plastic The bag contains dioxin), which is composed of two oxygen atoms connected to a pair of benzene ring compounds. When the general combustion incineration decomposition method is used, the chlorine atoms in the combustion material will form compounds. The method of the present invention uses far-infrared radiant heating to dry, thermally decompose, evaporate, and carbonize the above-mentioned waste in a sealed state. It is completely different from the general combustion method in principle. When oxygen atoms are not supplied, the oxygen atoms combine to generate dioxin. The amount is much reduced compared to the combustion method. [0025] General business wastes and household wastes are infectious and dangerous, as well as the urgency of processing time. Most of the wastes contain plastics such as polyethylene (Polyethlene) or silicone resins. After the far-infrared radiant carbonization method thermally decomposes it into a low-molecular weight compound, chlorine compounds cannot be combined with it, and since polyethylene is a similar molecular substance, the actual reaction will also be combined into dioxin. [0026] The role of far-infrared HHHH polyethylene structure CCCC HHHH Chemical formula: combination of CC and CH [0027] The CC bond of polyethylene absorbs a specific wavelength in far-infrared radiation, and its CH bond absorbs another of the far-infrared radiation After a specific wavelength, it decomposes into active radicals. When the CC bond and CH bond of polyethylene absorb far-infrared rays, they break down and decompose into low-molecular free radicals and react in water. Because polyethylene free radicals are low-molecular substances, they are free of hydrogen. The radical reaction forms a stable low-molecular substance. The low-molecular CC and CH bonds formed are irradiated with far-infrared rays to form a lower-molecular active substance. It reacts with hydrogen atoms to form an oxidizing gas, which carries a grease gas and is cold-cut into water after washing with water. An ozone generator is used. (O 3 ) Oxidation treatment of substances and oil and gas floating on the water surface can finally oxidize and reduce all organic matter. [0028] The far-infrared radiation carbonization procedure is as follows: Polyethylene Thermal radiation, far-infrared radiation (Thermal decomposition) low-molecular, organic matter Thermal radiation, far-infrared radiation (thermal decomposition), low molecular weight, organic matter Carbon atom (C) (thermal decomposition, thermal oxidative decomposition, oxidation) Inorganic substances, carbon dioxide gas CO 2 , H 2 O [0029] Ozone oxidation reaction mechanism: Ozone is a strong oxidant, which will maintain the molecular form of ozone when dissolved in water or After a series of reaction mechanisms, hydroxyl radicals with higher oxidation capacity are formed. Therefore, whether it is ozone or hydroxide radicals, it can destroy organic matter in water with its strong oxidation ability. Reaction of ozone in water as follows: O 3 → O + O 2 , O + H 2 O → 2HO, alkaline medium and then O 3 may OH - reaction, a radical generation rate quickly, i.e., O 3 + OH - → HO 2 + O - 2, , HO O 3 greater than the oxidation O 3 + HO 2 → HO + 2O 2, 2HO 2 → O 3 + H 2 O generated can organics (RH) reaction: HO + RH → R + H 2 O R + O 2 → RO 2 RO 2 + RH → ROOH + R ROOH + HO → CO 2 + H 2 O + ... Other oxidation products [Inventive effect] [0030] 1. Carbonization container The far-infrared ceramic layer is used inside to be heated by the external heater to form the whole far-infrared radiant heat heating. Therefore, the overall far-infrared radiant heat can be heated, and the business waste or general waste in the carbonization container can obtain a good and uniform heat penetration. The effect is that the carbonized container is hermetically sealed and attracted by the water pump to form a negative pressure so that it does not overheat and burn. Especially when processing business waste, most of the materials are polyethylene or resin. Far-infrared radiation heat can be used for carbonization to promote its stability. Thermal decomposition to shorten processing time to thermal decomposition After the formation of low-molecular compounds, they no longer react to become harmful substances. [0031] 2. The far-infrared ceramic layer is installed on the inner wall of the carbonization container. In addition to the waste, the far-infrared ceramic layer can be used for heating and the carbonization container can be heated by using an external combustion device combustion device. The far-infrared ceramic can be made by external heating. The layer forms far-infrared radiant heat, which can subsidize the heating of far-infrared ceramic heating, which can shorten the processing time and save electricity and fuel costs. The far-infrared ceramic layer is formed in the carbonization container, and there is no risk of carbides adhering to the inner surface. . [0032] 3. The built-in agitator in the container drives the motor to raise the agitator link to 170 degrees via the controller (A / B-1a), then release the controller and rotate the spinner to rotate the waste in the container to make the waste Get soaking to accelerate carbonization, which can save processing time and costs. [0033] 4. The water pump is used to attract the gaseous substances in the container to create a negative pressure inside the container, so there is no risk of leakage of smoke, foul odor, etc. It can also accelerate the carbonization time, and its structure is simple and can be used for a long time. The gaseous substances generated in the water pump suction container are washed and cooled, and the substances containing oil and fat components are floated and stored in the water tank. The ozone machine (O 3 ) is injected into the ozone to decompose the harmful substances, and the smoke is deodorized. [0034] 5. This device has a high effect due to the multiple methods of the first to fifth smoke and deodorizers, and will not cause pollution.

[0036] 圖1及圖2為本碳化裝置本體兩個相同個體A與B的遠紅外線輻射熱碳化設備,其內外壁係由耐久金屬材料製成,該內外殼之間填充輕質隔熱材料,如磁化纖維或矽酸鈣等,在該本體碳化容器(A/B-1)內部形成遠紅線陶磁發熱層(A/B-2d),利用旋轉門關閉(A/B-2),本體密封蓋(A/B-2a)卡鈎上下移動再進入利用油壓缸旋轉進入轉軸(A/B-2b),形成內部密閉空間A/B-2c)置放廢棄物。遠紅外線陶瓷層(A/B-2d)置放於上述本體內部,本發明使用遠紅外線陶瓷層,藉由外部燃燒裝置燃燒其補助燃料燃燒機(A/B-5b)可使用瓦斯或柴油燃燒機補助加熱碳化容器,使碳化容器內部陶瓷層(A/B-2e)產生遠紅外線輻射熱,使碳化容器內部空間(A/B-2c)形成整體遠紅外線的輻射熱。   [0037] 碳化容器(A/B-1)的俯視圖及透視圖如圖3表示。遠紅外線陶瓷層(A/B-2d)塗裝於碳化容器(A/B-1)的內壁,旋轉門(A/B-2)利用油壓缸經PLC (13)自動控制可將門控制開或關,將廢棄物投入容器空間內(A/B-2c),當碳化容器門關閉後,啟動外部燃燒裝置將遠紅外線層加熱(A/B-2d)透過燃燒裝置燃燒將遠紅外線陶瓷加熱(A/B-2d),將容器內廢棄物加熱至400℃,另外利用遠紅外線陶瓷層(A/B-2d)所產生的輻射熱加熱碳化容器內廢棄物,經乾燥、熱分解步驟促使氣化蒸發。利用熱效應原理加熱經(A/B-2e)煙道口進入螺旋式煙道加熱,尾氣經空冷裝置(A/B-3a)降溫進入氣體緩衝器(A/B-6),本體碳化容器所產生的蒸發物經控制器(A/B-4)控制導向,其裝置設有A與B兩個相同的個體,經導入自動替換器接頭,轉換A或B容器所產生的碳化蒸發物質再經外部燃燒裝置中燃燒,當A容器達到設定溫度時,可將A容器所產生的碳化物質及熱導入B外部燃燒裝置中燃燒,或則直接切換導入A或B經緩衝器緩衝注入燃燒裝置中燃燒(A/B-5)。將碳化容器所蒸發物質與煙道產生的煙氣等注入緩衝器(A/B-6)管道(A/B-6a)連接排氣通道(7a)連至消煙、除臭器以及尾氣處理,當容器內溫度達280度時啟動攪拌器(A/B-1a)攪拌碳化容器內廢棄物加速碳化,容器內溫度達300度時啟動撒水裝置(A/B-2f)並控制撒水量及間隔加速裂解及氧化,容器內氣壓安全閥(A/B-5c)設置當容器內氣壓超過外部燃燒裝置設定值時洩氣並警報。   [0038] 第一消煙、除臭器(A/B-5)利用碳化容器內所產生蒸發物回流至外部燃燒裝置燃燒,使蒸發物再次燃燒消煙、除臭把剩餘物質減至最少,碳化容器內所產生的蒸發物為高燃值的碳氫化合物容易燃燒當為燃燒燃料可減少燃料使用量並提升碳化速度及產能。   [0039] 第二消煙、除臭器利用第一水泵(7))將上述煙氣中的碳化合物吸引,應用恆吸原理將水滴落之力量吸引煙氣跌落水槽中冷卻含有油脂成分物質浮儲於水槽中由臭氧裝置(O3 )分解並於消煙除臭。   [0040] 第三消煙、除臭器利用第二水幫浦(6)將煙氣中的碳化合物吸引,應用恆吸原理將水滴落之利量吸引煙氣跌落水槽中冷卻其冷水(10)提供冰水使含有輕分子之化合物及短鏈之物質浮儲於水槽中(9b)第二臭氧裝置(O3 )將之溶解並於消煙、除臭。   [0041] 第四尾氣燃燒裝置(12)將上述消煙、除臭剩餘物質利用燃燒器(12-a)再次將上述處理殘留物質與於燃燒使煙氣、臭氣等不良物質消失,其燃燒裝置特殊結構熱風(S)提供熱氧使碳化物容易完全燃燒並可節省燃料。   [0042] 第五消煙、除臭器(12)之作用,由內置催化觸媒催化劑(12-e),以化學方式及物理方法將容器內熱分解後的汽化物以加熱器(12-i)加熱催化,將氧化觸媒(12-e)加熱至320℃使氣化物及煙氣分解成為低分子氣化物,將微量殘留輕分子及臭味除去後排放大氣。   [0043] 以下,說明第一消煙、除臭器(A/B-5)燃燒裝置燃燒器(A/B-5a)燃燒熱分解其碳化容器內所產生的蒸發物其作用為熱分解。   [0044] 例如:塑膠類PE、PVC、矽膠等 CmHn + O2 催化劑CO2 + H2 O (CH3 )3 N + O2 催化劑CO2 + H2 O + N2 VOC + O2 催化劑CO2 + H2 O OH- 自解作用O3 + OH- → HO2 + O- 2 O3 + OH- → HO- 2 + O2 HCO- 3 + HO → CO- 3 + H2 O NH3 氧化作用 NH3 + 4O3 → NO- 3 + H3 O Br- 氧化作用 Br- + O3 → BrO- + O2 HCO- 3 氧自由基捕捉劑 HCO- 3 +HO → HCO3 + OH- CI- 氧自由基捕捉劑 CI- + OH → HOCI- SO2 -4 氧自由基捕捉劑 SOI2- 4 + OH → HSO- 4 +H2 O   [0045] 其次,如上所述,第二、三消煙、除臭器(7)內之臭氧裝置(O3 )的主要為氧化還原劑,將有機成分氧化或還原其化學反應如下。   [0046] 首先,將催化觸媒(12-e)及氧化觸媒以加熱器(12-i)加熱至320℃使氣化物完全氧化分解,同時(7及9)臭氧裝置注入O3 分解有害物質如下化學反應。 O3 直接反應:污染物 + O3 → 產物或中間物 O3 間接反映:污染物 + HO →產物或中間物 O3 + H2 O +hv H2 O2 + hv 2HO O3 (HO2 - ) HO- CO + 1/2O2 催化劑 CO2 Hydrocarbons + O2 催化劑 CO + H2 O H2 +1/2 O2 催化劑 H2 O NO + H2 催化劑 1/2N2 + H2 O Hydrocarbons + NO 催化劑 N2 +H2 O + CO2 CO + H2 O 催化劑 CO2 + H2 2NO + 2CO 催化劑 N2 + 2CO2 CH2 COOH + O3 (CO2 )n + (H2 O)m H2 CCHCl + O3 H2 O + CO2 + ClCl + H2 O + NaOH NaCl+ H2 O   [0047] 容器內廢棄物碳化後剩餘微量碳化物經排灰裝置(4)及排灰控制閥(4a)排入灰渣儲存桶儲存定量控制由控制閥(4b)控制排灰,利用塑膠袋或麻袋接至出灰口(4e)裝填,其灰渣經過完全碳化可當一般廢棄物處理或當土壤混合物。1 and FIG. 2 are far-infrared radiant heat carbonization equipment of two identical entities A and B of the carbonization device body, the inner and outer walls of which are made of durable metal materials, and the inner and outer shells are filled with lightweight heat-insulating materials. Such as magnetized fiber or calcium silicate, etc., a far-red line ceramic magnetic heating layer (A / B-2d) is formed inside the carbonized container (A / B-1), and the body is sealed by a revolving door (A / B-2), and the body is sealed. The hook of the cover (A / B-2a) moves up and down and then enters the rotating shaft (A / B-2b) by the rotation of the hydraulic cylinder to form an internal closed space A / B-2c) to place waste. The far-infrared ceramic layer (A / B-2d) is placed inside the above-mentioned body. The present invention uses a far-infrared ceramic layer, and its auxiliary fuel burner (A / B-5b) is burned by an external combustion device. Gas or diesel can be used. The burner assists in heating the carbonization container, so that the ceramic layer (A / B-2e) inside the carbonization container generates far-infrared radiant heat, and the internal space (A / B-2c) of the carbonization container forms the entire far-infrared radiant heat. [0037] A plan view and a perspective view of the carbonization container (A / B-1) are shown in FIG. 3. The far-infrared ceramic layer (A / B-2d) is coated on the inner wall of the carbonized container (A / B-1). The revolving door (A / B-2) can be controlled by the hydraulic cylinder through PLC (13) automatic control. Open or close, put waste into the container space (A / B-2c), when the carbonization container door is closed, start the external combustion device to heat the far-infrared layer (A / B-2d) and burn the far-infrared ceramic through the combustion device Heating (A / B-2d) to heat the waste in the container to 400 ° C. In addition, the radiant heat generated by the far-infrared ceramic layer (A / B-2d) is used to heat the waste in the carbonized container, which is promoted by the drying and thermal decomposition steps. Evaporation. The heat effect principle is used to heat the spiral flue through the (A / B-2e) flue port, and the exhaust gas is cooled by the air cooling device (A / B-3a) into the gas buffer (A / B-6). The evaporate is controlled and guided by the controller (A / B-4). Its device is equipped with two identical entities A and B. After the introduction of the automatic replacer connector, the carbonized evaporative material produced by the A or B container is converted to the outside. Combustion in the combustion device. When the A container reaches the set temperature, the carbonized material and heat generated by the A container can be introduced into the B external combustion device for combustion, or directly switched to A or B and injected into the combustion device through the buffer to burn ( A / B-5). Inject the substance evaporated from the carbonization container and the flue gas generated from the flue into the buffer (A / B-6) pipe (A / B-6a). Connect the exhaust channel (7a) to the smoke elimination, deodorizer and exhaust gas treatment. When the temperature in the container reaches 280 degrees, start the agitator (A / B-1a) to agitate the waste in the carbonization container to accelerate the carbonization. When the temperature in the container reaches 300 degrees, start the water sprinkler (A / B-2f) and control the amount of water and Accelerate cracking and oxidation at intervals. The air pressure safety valve (A / B-5c) in the container is set to deflate and alarm when the pressure in the container exceeds the set value of the external combustion device. [0038] The first smoke and deodorizer (A / B-5) uses the vapors generated in the carbonization container to return to the external combustion device for combustion, so that the vapors are reburned to eliminate smoke and deodorization to minimize the remaining substances, The vapors produced in the carbonization container are hydrocarbons with high ignition value and are easy to burn. When used as a combustion fuel, the amount of fuel used can be reduced and the carbonization speed and productivity can be increased. [0039] The second smoke and deodorizer uses the first water pump (7) to attract the carbon compounds in the smoke, and applies the principle of constant suction to attract the power of water droplets to drop the flue gas into the water tank to cool the substances containing oil and fat components. It is stored in the water tank and decomposed by the ozone device (O 3 ), and is used for deodorizing smoke. [0040] The third smoke and deodorizer uses the second water pump (6) to attract carbon compounds in the flue gas, and applies the constant suction principle to attract the profit of water droplets to the flue gas to cool the cold water (10 ) Provide ice water to float the compounds containing light molecules and short-chain substances in the water tank (9b). The second ozone device (O 3 ) will dissolve and dissolve the smoke and deodorize. [0041] The fourth exhaust gas combustion device (12) uses the burner (12-a) to remove the above-mentioned smoke and deodorization residual substances and burns the above-mentioned treatment residual substances with the burned substances to eliminate undesirable substances such as smoke and odor, and burns them. The special structure of the device, hot air (S), provides hot oxygen to make the carbide easily burn completely and save fuel. [0042] The function of the fifth smoke and deodorizer (12) is to use a built-in catalytic catalyst (12-e) to chemically and physically decompose the vaporized substance in the container by a heater (12-i). ) Heating and catalyzing, heating the oxidation catalyst (12-e) to 320 ° C to decompose the gaseous matter and smoke into low-molecular-weight gaseous matter, and remove the traces of residual light molecules and odors and discharge them into the atmosphere. [0043] Hereinafter, the first smoke removal and deodorizer (A / B-5) combustion device burner (A / B-5a) will be thermally decomposed, and the vapor generated in the carbonization container will be thermally decomposed. [0044] For example: CmHn + O 2 catalysts such as plastic PE, PVC, silicone, etc. CO 2 + H 2 O (CH 3 ) 3 N + O 2 catalyst CO 2 + H 2 O + N 2 VOC + O 2 catalyst CO 2 + H 2 O OH- self-decomposition O 3 + OH - → HO 2 + O - 2 O 3 + OH - → HO - 2 + O 2 HCO - 3 + HO → CO - 3 + H 2 O NH 3 oxidation of NH 3 + 4O 3 → NO - 3 + H 3 O Br- oxidation of Br - + O 3 → BrO - + O 2 HCO - 3 oxygen radical scavenger HCO - 3 + HO → HCO 3 + OH - CI- oxygen radical scavenger CI - + OH → HOCI - SO 2 -4 oxygen radical scavenger SOI 2- 4 + OH → HSO - 4 + H 2 O [0045] Second, as described above, the ozone in the second and third smoke elimination and deodorizer (7) The device (O 3 ) is mainly a redox agent, and the chemical reaction of oxidizing or reducing organic components is as follows. [0046] First, the catalytic catalyst (12-e) and the oxidation catalyst are heated to 320 ° C by a heater (12-i) to completely oxidize and decompose the gaseous substances, and (7 and 9) the ozone device is injected with O 3 to decompose and is harmful. The substance reacts chemically as follows. O 3 Direct Reaction: Pollutants + O 3 → O 3 intermediate product or indirectly reflect: + HO → product or contaminant intermediate O 3 + H 2 O + hv H 2 O 2 + hv 2HO O 3 (HO 2 - ) HO-CO + 1 / 2O 2 catalyst CO 2 Hydrocarbons + O 2 catalyst CO + H 2 OH 2 + 1/2 O 2 catalyst H 2 O NO + H 2 catalyst 1 / 2N 2 + H 2 O Hydrocarbons + NO catalyst N 2 + H 2 O + CO 2 CO + H 2 O Catalyst CO 2 + H 2 2NO + 2CO Catalyst N 2 + 2CO 2 CH 2 COOH + O 3 (CO 2 ) n + (H 2 O) m H 2 CCHCl + O 3 H 2 O + CO 2 + Cl Cl + H 2 O + NaOH NaCl + H 2 O [0047] The remaining traces of carbides after the carbonization of the waste in the container are discharged into the ash slag storage barrel through the ash discharge device (4) and the ash discharge control valve (4a). The storage quantitative control is controlled by the control valve (4b). The plastic bag or sack is connected to the ash outlet (4e) for filling, and the ash residue is completely carbonized and can be treated as general waste or as soil mixture.

[0048][0048]

A/B‧‧‧本體碳化容器A / B‧‧‧Carbonized container

A/B-1‧‧‧碳化設備本體A / B-1‧‧‧‧Carbonization equipment body

A/B-1a‧‧‧碳化設備本體攪拌裝置A / B-1a‧‧‧Carbonization equipment body stirring device

A/B-1b‧‧‧本體碳化容器碳化蒸發物出口A / B-1b‧‧‧Carbonized Evaporator Outlet

A/B-1c‧‧‧碳化設備本體煙道出口A / B-1c‧‧‧‧Carbonization equipment body flue exit

A/B-1d‧‧‧煙道夾層A / B-1d‧‧‧Layer

A/B-1e‧‧‧碳化設備本體碳化剩餘物出口A / B-1e‧‧‧Carbonization equipment body carbonization residue export

A/B-1f‧‧‧碳化剩餘物儲存桶A / B-1f‧‧‧‧Carbonized Residue Storage Bucket

A/B-2‧‧‧碳化容器密封旋臂A / B-2‧‧‧Carbonized container sealed swing arm

A/B-2a‧‧‧碳化容器密封旋轉門A / B-2a‧‧‧Carbonized container sealed revolving door

A/B-2b‧‧‧油壓缸觸動式碳化容器密封轉動套件A / B-2b‧‧‧Hydraulic Cylinder Tactile Carbonized Container Sealed Rotation Kit

A/B-2c‧‧‧碳化容器空間A / B-2c‧‧‧Carbonization container space

A/B-2d‧‧‧碳化容器內置的遠紅外線陶瓷發熱層A / B-2d‧ far-infrared ceramic heating layer built into the carbonized container

A/B-2e‧‧‧本體碳化容器煙道A / B-2e‧‧‧Body of carbonized container flue

A/B-2f‧‧‧灑水器A / B-2f‧‧‧Sprinkler

A/B-3‧‧‧本體碳化容器煙道通道安全氣壓閥A / B-3‧‧‧ body carbonized container flue channel safety air pressure valve

A/B-3a‧‧‧碳化容器煙道通道氣冷設備A / B-3a‧‧‧Carbonization container flue channel air cooling equipment

A/B-3b‧‧‧碳化容器煙道通道氣冷設備之風扇A / B-3b‧‧‧Fan channel air cooling equipment fan for carbonized container

A/B-3c‧‧‧碳化容器煙道通道氣冷設備內排流管A / B-3c ‧‧‧ Drain pipe in air cooling device of flue channel of carbonized container

A/B-4‧‧‧本體碳化容器蒸發物控制器A / B-4‧‧‧Body Carbonization Vessel Evaporator Controller

A/B-4a‧‧‧控制器第1開關A / B-4a‧‧‧controller first switch

A/B-4b‧‧‧控制器第2開關A / B-4b‧‧‧ Controller 2nd Switch

A/B-5‧‧‧本體外部燃燒裝置A / B-5‧‧‧Body external combustion device

A/B-5a‧‧‧本體外部燃燒器A / B-5a‧‧‧Body External Burner

A/B-5b‧‧‧本體碳化蒸化物緩衝部A / B-5b‧‧‧‧Carbonized vaporized buffer

A/B-5c‧‧‧本體外部燃燒器安全閥A / B-5c‧‧‧External burner safety valve

A/B-5d‧‧‧外部燃燒器內層高溫瓷磚A / B-5d‧‧‧External burner inner high temperature tile

A/B-6‧‧‧碳化蒸發物及煙氣緩衝部A / B-6‧‧‧‧Carbonized Evaporate and Flue Gas Buffer Department

A/B-6a‧‧‧連接水處理裝置管道A / B-6a‧‧‧ Connected to water treatment equipment pipeline

7‧‧‧(利用虹吸原理水的流動動力提供吸引力)第一水循環裝置7‧‧‧ (Using the siphon principle of the power of water to provide attraction) The first water circulation device

7-a‧‧‧進氣口7-a‧‧‧air inlet

7-b‧‧‧水處理循環桶7-b‧‧‧Water Treatment Circulation Bucket

7-c‧‧‧水處理循環桶內置水管7-c‧‧‧Water Treatment Circulation Bucket with Built-in Water Pipe

7-d‧‧‧第一抽水循環幫浦(馬達)7-d‧‧‧The first pumping circulation pump (motor)

7-e‧‧‧第一處理循環水箱7-e‧‧‧The first treatment circulating water tank

7-f‧‧‧臭氧機(O3)7-f‧‧‧Ozone machine (O 3 )

7-g‧‧‧水洗廢氣排出通道7-g‧‧‧washed exhaust gas discharge channel

7-h‧‧‧水位感測器7-h‧‧‧Water Level Sensor

8‧‧‧水塔散熱裝置8‧‧‧ Water Tower Radiator

9‧‧‧第二水循環裝置9‧‧‧Second water circulation device

9-a‧‧‧第二抽水循環幫浦9-a‧‧‧Second pumping circulation pump

9-b‧‧‧第二處理循環水箱9-b‧‧‧Second treatment circulating water tank

9-c‧‧‧臭氧機(O3)9-c‧‧‧Ozone machine (O 3 )

9-d‧‧‧水洗廢氣排出通道9-d‧‧‧washed exhaust gas discharge channel

9-e‧‧‧水位感測器9-e‧‧‧ Water Level Sensor

10‧‧‧冰冷水機10‧‧‧Ice cold water machine

11‧‧‧利用虹吸原理流水通道11‧‧‧Using Siphon Principle

11-a‧‧‧廢氣跌落通道11-a‧‧‧Exhaust gas drop channel

11-b‧‧‧第三抽水循環幫浦11-b‧‧‧Third pumping circulation pump

11-c‧‧‧廢氣排出口11-c‧‧‧Exhaust gas outlet

11-d‧‧‧水位感測器11-d‧‧‧Water Level Sensor

11-e‧‧‧第三處理循環水箱11-e‧‧‧Third treatment circulating water tank

12‧‧‧尾氣燃燒裝置12‧‧‧ tail gas combustion device

12-a‧‧‧燃燒器12-a‧‧‧ burner

12-b‧‧‧冷卻水桶12-b‧‧‧cooling bucket

12-c‧‧‧冷卻水循環幫浦12-c‧‧‧Cooling water circulation pump

12-d‧‧‧水冷卻循環裝置12-d‧‧‧Water cooling circulation device

12-e‧‧‧貴重金屬觸媒床裝置12-e‧‧‧precious metal catalyst bed device

12-f‧‧‧抽氣風扇12-f‧‧‧Exhaust Fan

12-g‧‧‧最終氣體緩衝部12-g‧‧‧Final gas buffer

12-h‧‧‧煙囪對外排氣12-h‧‧‧ chimney exhaust

12-i‧‧‧觸媒床加熱器12-i‧‧‧catalyst bed heater

13‧‧‧PLC自動控制系統13‧‧‧PLC automatic control system

[0035]   圖1表示本發明的遠紅外線輻射熱碳化設備之具體實施例的各構成與流程的詳細說明剖視圖。   圖2表示本發明的遠紅外線輻射熱碳化設備之具體實施例的剖視圖。   圖3是本發明的碳化容器的詳細結構圖。   圖4是本發明的遠紅外線輻射熱碳化設備中循環水(泵)幫浦結構圖。   圖5是本發明兩個相同的碳化容器所產生碳化蒸發物控制器及緩衝器結構圖。   圖6是本發明的遠紅外線輻射熱碳化設備中的煙道氣冷裝置的結構圖。   圖7是本發明的遠紅外線輻射熱碳化設備中的緩衝器的結構圖。   圖8是本發明的遠紅外線輻射熱碳化設備中尾氣觸媒裝置結構圖。   圖9是本發明的遠紅外線輻射熱碳化設備流程圖。[0035] FIG. 1 is a detailed explanatory cross-sectional view of each structure and flow of a specific embodiment of a far-infrared radiant heat carbonization device of the present invention. FIG. 2 shows a cross-sectional view of a specific embodiment of the far-infrared radiant heat carbonization device of the present invention. FIG. 3 is a detailed configuration diagram of the carbonization container of the present invention. FIG. 4 is a structural diagram of a circulating water (pump) pump in a far-infrared radiant heat carbonization device of the present invention. Figure 5 is a structural diagram of a carbonized vapor controller and a buffer produced by two identical carbonized containers of the present invention. Fig. 6 is a structural diagram of a flue gas cooling device in a far-infrared radiant heat carbonization device of the present invention. 7 is a structural diagram of a buffer in a far-infrared radiant heat carbonization device of the present invention. FIG. 8 is a structural diagram of an exhaust gas catalyst device in a far-infrared radiant heat carbonization device of the present invention. FIG. 9 is a flowchart of a far-infrared radiant heat carbonization device of the present invention.

Claims (8)

一種碳化裂解廢棄物的設備,係利用遠紅外線幅射熱的碳化裂解廢棄物之相同個體A與B的設備,其特徵為:在本體碳化容器內利用遠紅線材料產生的輻射熱進行加熱,使該本體碳化容器內形成整體遠紅外線輻射熱,將廢棄物等投入該本體碳化容器內,在密閉的空間內以紅外線加熱,外部則利用燃燒器加溫使上述容器內的廢棄物等在上述遠紅外線輻射熱的作用下乾燥、熱分解最終碳化,並節省能源(燃料)再利用上述乾燥、熱分解所產生的熱量、碳化物作為加熱燃料經由通道注入本體外部燃燒裝置中,對上述容器內產生的碳化物質、煙氣等進行二次燃燒以燒除殘餘的物質。A device for carbonizing and cracking waste is a device for the same individual A and B of carbonizing and cracking waste using far-infrared radiation heat, and is characterized in that the radiant heat generated by the far red wire material is used for heating in the bulk carbonization container, so that the The far-infrared radiant heat is formed in the body carbonization container, and waste is put into the body carbonization container, which is heated by infrared in a closed space, and the outside is heated by a burner to heat the waste in the container to the far-infrared radiation. Under the action of carbon dioxide, it is dried and thermally decomposed and finally carbonized, and the energy (fuel) is saved. The heat generated by the above-mentioned drying and thermal decomposition is used, and the carbide is injected into the external combustion device of the body as a heating fuel through the channel to the carbonized substances generated in the container , Smoke, and other secondary combustion to burn away the remaining material. 如申請專利範圍第1項記載的碳化裂解廢棄物的設備,其中,在上述本體碳化容器內形成整體遠紅外線輻射熱,該容器位於封閉的本體內空間,使用遠紅外線陶瓷加熱層由外部燃燒器加熱該碳化容器,利用燃料加熱所產生的熱及遠紅外線輻射熱,將投入上述碳化容器內的廢棄物等乾燥、熱分解,最後碳化,並將上述碳化容器產生的碳化物質、煙氣、臭味等再經導管導入上述外部加熱裝置中燃燒,形成二次燃燒以減少上述容器內所產生的碳化物質、煙氣等,以節省能源並利用上述碳化物質(可燃性氣體)為燃料快速加溫達到碳化容器內廢棄物的碳化。The device for carbonizing and decomposing waste as described in the first item of the patent application scope, wherein the overall far-infrared radiation heat is formed in the above-mentioned carbonized container, which is located in the closed body space and is heated by an external burner using a far-infrared ceramic heating layer This carbonization container uses the heat generated by fuel heating and far-infrared radiant heat to dry, thermally decompose waste and the like put into the carbonization container, and finally carbonize the carbonized material, smoke, and odor generated by the carbonization container. It is then introduced into the external heating device through a duct for combustion to form secondary combustion to reduce carbonized substances, smoke and the like generated in the container, to save energy and use the carbonized substances (flammable gases) as fuel to rapidly heat to carbonize. Carbonization of waste in containers. 如申請專利範圍第2項記載的碳化裂解廢棄物的設備,其中,利用上述乾燥、熱分解所產生的熱量、碳化物質等經控制器並導入氣體緩衝部並作為加熱燃料注入外部燃燒裝置中燃燒,形成二次燃燒將其碳化所產生的碳化物質、煙、臭味減至最少,並再利用尾器處理燃燒裝置將上述二次燃燒未完成的剩餘物質再次燃燒,將碳化所產生的物質完全燃燒,最終由催化觸媒對廢棄物等所產生的氣化物進行消煙、除臭。The equipment for cracking carbonized waste as described in the second item of the patent application, wherein the heat generated by the above-mentioned drying and thermal decomposition, carbonized materials, etc. are introduced into a gas buffer section by a controller and injected into an external combustion device as a heating fuel for combustion. To form a secondary combustion to minimize the carbonized substances, smoke, and odor generated by its carbonization, and then use the tail treatment combustion device to re-burn the remaining material that was not completed in the secondary combustion, and completely complete the carbonization. Combustion, the gaseous substances generated by waste and the like are deodorized and deodorized by a catalytic catalyst. 如申請專利範圍第1項或第2項記載的碳化裂解廢棄物的設備,其中,投入上述碳化容器內的廢棄物等,經加熱產生的煙及熱分解的氣化物作為燃燒燃料經導管導入上述外部熱燒器內,以減少上述容器內所產生的碳化物質,再利用一組或二組以上的水循環裝置(水幫浦),將熱分解後的煙及氣化物冷卻使其含有油、氣之氣化物和水混合儲存於循環水箱,所含的油氣經冷卻水中凝結形成浮油存浮於裝置內,在裝置內利用臭氧機(O3 )注入臭氧以分解浮於水面上之浮油以及有機物質。For example, the equipment for carbonizing and decomposing waste as described in the first or second aspect of the patent application scope, wherein the waste and other wastes put into the carbonization container are heated and the smoke and thermally decomposed gaseous material are introduced into the above as a combustion fuel through a duct. In the external thermal burner, to reduce the carbonized substances generated in the container, one or two or more water circulation devices (water pumps) are used to cool the thermally decomposed smoke and gaseous substances to contain oil and gas. The gaseous material and water are mixed and stored in the circulating water tank. The oil and gas contained in the cooling water is condensed to form a floating oil, which is stored and floated in the device. In the device, an ozone machine (O 3 ) is used to inject ozone to decompose the floating oil floating on the water surface. organic matters. 如申請專利範圍第3項記載的碳化裂解廢棄物的設備,其中,至少包括一個或一個以上水循環裝置(水幫浦),使用於裝置內由上述容器內廢棄物所產生的裂解油氣進行分解以及至少包括一個或一個以上高溫燃燒處理器以及催化觸媒的消煙除臭器,使用於裝置內由碳化容器廢棄物所產生的煙氣進行消煙、除臭。The equipment for cracking carbonized waste as described in item 3 of the scope of patent application, which includes at least one or more water circulation devices (water pumps) for decomposing cracked oil and gas generated by the waste in the container in the device and The smoke and deodorizer including at least one or more high-temperature combustion processors and catalytic catalysts is used for smoke and deodorization in the device from the smoke generated by the carbonized container waste. 如申請專利範圍第2項或第4項記載的碳化裂解廢棄物的設備,其中,利用上述一組或二組以上的水循環裝置(水幫浦)抽取碳化裝置本體內的煙及氣化物,使上述碳化裝置內形成負壓,避免裝置本體內漏出煙氣及臭味。For example, the equipment for carbonizing and cracking wastes described in item 2 or 4 of the scope of patent application, wherein the above-mentioned one or two or more water circulation devices (water pumps) are used to extract the smoke and gas in the body of the carbonization device, A negative pressure is formed in the carbonization device to prevent smoke and odor from leaking out of the device body. 如申請專利範圍第2項或第4項記載的碳化裂解廢棄物的設備,其中,碳化容器內置攪拌器可將廢棄物於碳化過程中加以攪拌使碳化物受熱均勻加速碳化,以節省碳化時間。For example, the equipment for carbonizing and cracking wastes described in the second or fourth aspect of the patent application scope, wherein the agitator with a built-in carbonization container can agitate the waste during the carbonization process to uniformly accelerate the carbonization by heating the carbides to save carbonization time. 如申請專利範圍第2項記載的碳化裂解廢棄物的設備,其中,上述碳化容器所產生的碳化物質、煙、臭味等經導管導入上述外部加熱裝置中燃燒以消煙、除臭,最後利用含貴金屬及氧化鈦的主要催化劑及遠紅外線層所形成的消煙、除臭器。The apparatus for carbonizing and cracking waste as described in the second item of the scope of the patent application, wherein the carbonized substances, smoke, and odor generated by the carbonization container are introduced into the external heating device through a duct to burn and smoke and deodorize, and finally used Main catalyst containing precious metals and titanium oxide, and smoke and deodorizer formed by far-infrared layer.
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