TW201912035A - Grease composition - Google Patents

Grease composition Download PDF

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TW201912035A
TW201912035A TW107124062A TW107124062A TW201912035A TW 201912035 A TW201912035 A TW 201912035A TW 107124062 A TW107124062 A TW 107124062A TW 107124062 A TW107124062 A TW 107124062A TW 201912035 A TW201912035 A TW 201912035A
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mass
oil
fatty acids
fat
oils
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TW107124062A
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Chinese (zh)
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TWI776917B (en
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豊島尊
辻野祥伍
生稲淳一
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日商日清奧利友集團股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils

Abstract

The present invention provides a grease composition which can suppress foaming during frying preparation. Alternatively, the present invention provides a grease composition which can suppress foaming during frying preparation and prepare a good mayonnaise. A grease composition, for the fatty acids constituted therein, contains 8 mass%~20 mass% saturated fatty acids having 6~10 carbon atoms and 57 mass%~ 90 mass% oleic acid. In said grease, the triglycerides containing the saturated fatty acids having only 6~10 carbon atoms are less than 2.5 mass%. Preferably, the fatty acids constituted in the grease contain 8 mass%~20 mass% saturated fatty acids having 6~10 carbon atoms and 70 mass%~90 mass% oleic acids. Said grease is the transesterified grease and/or esterified grease. Moreover, the grease composition contains 50 mass%~100 mass% said grease.

Description

油脂組成物Grease composition

本發明是有關於一種油脂組成物。The present invention relates to a fat and oil composition.

自先前以來,食用油脂作為主要用途而用於油炸調理、煎炒調理等中。通常,於使用油脂進行油炸調理的情況下,自油炸物產生蒸氣而起泡,但藉由反覆進行油炸調理,因油脂的劣化及自油炸物的溶出成分的影響而導致起泡變得激烈。於起泡厲害的情況下,不僅因氣泡而看不到油炸物,而且自容器溢出等作業方面的安全性惡化。因此,無法進行一定量以上的油炸調理,特別是若對包含雞蛋或肉的油炸物進行油炸調理,則油脂的劣化快。作為抑制該些油炸調理時的氣泡的方法,進行矽酮油的添加,但矽酮油的效果有限,而且近年來有因其生物分解性的惡化而避免使用的傾向。Edible oils and fats have been mainly used for frying conditioning, frying conditioning, and the like since before. Generally, when frying and conditioning is performed using fats and oils, steam is generated from the fry and foaming occurs. However, by repeatedly frying and conditioning, the foaming is caused by the deterioration of fats and oils and the influence of the dissolved components from the fry. Becomes intense. In the case of severe foaming, not only the fry is not visible due to air bubbles, but also safety in terms of work such as overflow from the container is deteriorated. For this reason, it is not possible to perform a frying condition of a certain amount or more. In particular, if a frying condition including eggs or meat is fried, the deterioration of fats and oils is rapid. Silicone oil is added as a method of suppressing these bubbles during frying and conditioning. However, the effect of silicone oil is limited, and in recent years, it has tended to be avoided due to deterioration of its biodegradability.

另外,椰子油與大豆油的混合油、中鏈脂肪酸三甘油酯與菜籽油等酯交換油等起泡較多,此種構成脂肪酸包含碳數6~10的脂肪酸與碳數14~22的脂肪酸這兩者的三甘油酯中即便添加矽酮,亦無法抑制氣泡。因此,揭示一種如下的發明:藉由向包含中鏈脂肪酸作為構成脂肪酸的油脂中添加特定的乳化劑,抑制油炸調理中的起泡。例如,專利文獻1中揭示有調配甘油或二甘油與脂肪酸的單酯。另外,專利文獻2中揭示有調配特定的蔗糖脂肪酸酯。 [現有技術文獻] [專利文獻]In addition, coconut oil and soybean oil mixed oil, medium-chain fatty acid triglyceride and rapeseed oil and other transesterified oil, etc. are foaming a lot, this kind of constituent fatty acid contains fatty acids with 6-10 carbon atoms and 14-22 Even when silicone is added to the triglyceride of both fatty acids, air bubbles cannot be suppressed. Therefore, an invention has been disclosed that suppresses foaming during frying by adding a specific emulsifier to fats and oils containing medium-chain fatty acids as constituent fatty acids. For example, Patent Document 1 discloses a monoester of glycerin or diglycerin and a fatty acid. In addition, Patent Document 2 discloses the formulation of a specific sucrose fatty acid ester. [Prior Art Literature] [Patent Literature]

[專利文獻1]日本專利第4040204號公報 [專利文獻2]日本專利第4046438號公報[Patent Document 1] Japanese Patent No. 4040204 [Patent Document 2] Japanese Patent No. 4046438

[發明所欲解決之課題] 但是,與油脂相比,乳化劑的原料費更高,且需要添加步驟,因此要求簡單地提供一種更廉價的製品。另外,由含有中鏈脂肪酸作為構成脂肪酸的油脂所製造的蛋黃醬的黏度變低,調配有乳化劑的所述油脂中黏度過低,存在無法保持作為蛋黃醬的保形性的問題。因此,於含有中鏈脂肪酸作為構成脂肪酸的油脂中需要一種用於油炸調理等加熱調理與蛋黃醬等乳化用途的通用油脂。[Problems to be Solved by the Invention] However, since the raw material cost of the emulsifier is higher than that of oils and fats, and an addition step is required, it is required to simply provide a cheaper product. In addition, the viscosity of mayonnaise produced from fats and oils containing a medium-chain fatty acid as a constituent fatty acid is low, and the viscosity of the fats and oils formulated with an emulsifier is too low, and there is a problem that the shape retention of the mayonnaise cannot be maintained. Therefore, among the fats and oils containing a medium-chain fatty acid as a constituent fatty acid, there is a need for a general-purpose fat and oil for heating conditioning such as frying conditioning and emulsifying applications such as mayonnaise.

因此,本發明的目的在於提供一種抑制油炸調理中的起泡的油脂組成物。另外,本發明的目的在於提供一種抑制油炸調理中的起泡、且可製備良好的蛋黃醬的油脂組成物。 [解決課題之手段]Therefore, an object of the present invention is to provide a fat and oil composition that suppresses foaming during frying conditioning. Another object of the present invention is to provide a fat and oil composition capable of suppressing foaming during frying and preparing good mayonnaise. [Means for solving problems]

本發明的油脂組成物為如下的油脂組成物:於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,該油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。The fat and oil composition of the present invention is a fat and oil composition that contains 8% to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57% to 90% by mass of oleic acid in the fatty acids constituting the fat. The triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms is 2.5% by mass or less.

較佳為於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、70質量%~90質量%的油酸的油脂為酯交換油脂及/或經酯化的油脂,並於油脂組成物中含有50質量%~100質量%的該油脂。It is preferable that the fatty acid constituting the fat and oil contains 8 to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 70 to 90% by mass of oleic acid is a transesterified fat and / or esterified Oils and fats, and the oil and fat composition contains 50 to 100% by mass of the oils and fats.

較佳為所述油脂為構成脂肪酸的68質量%為油酸的植物油、與碳數6~10的飽和脂肪酸的三甘油酯的酯交換油脂。Preferably, the fats and oils are transesterified fats and oils that comprise 68% by mass of vegetable oils that constitute fatty acids and oleic acid and triglycerides with saturated fatty acids having 6 to 10 carbon atoms.

本發明的油脂組成物較佳為不包含乳化劑。The fat and oil composition of the present invention preferably does not contain an emulsifier.

本發明的油脂組成物較佳為選自油炸用途與蛋黃醬用途中的用途。 [發明的效果]The fat and oil composition of the present invention is preferably selected from the uses of frying applications and mayonnaise applications. [Effect of the invention]

根據本發明,可提供一種儘管酯交換油脂的構成脂肪酸中含有中鏈脂肪酸,但油炸時的起泡得到改善的油脂組成物。另外,可提供一種藉由減少或不包含乳化劑而可獲得具有良好的保形性的蛋黃醬的油脂組成物。According to the present invention, it is possible to provide an oil and fat composition having improved foaming during frying, although the fatty acids constituting the transesterified oil and fat contain a medium-chain fatty acid. In addition, it is possible to provide a fat or oil composition having a good shape retention property by reducing or not including an emulsifier.

本發明者等人發現,藉由使用如下的油脂,可改善油炸時的起泡,所述油脂是於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,使僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。基於該見解,從而完成了本申請案發明的油脂組成物。再者,本發明的實施形態中,A(數值)~B(數值)是指A以上且B以下。The present inventors have found that the use of fats and oils, which are saturated fatty acids containing 6 to 10 carbon atoms in the fatty acids constituting the fats and oils, can be improved by using the following fats and oils And 57% by mass to 90% by mass of oleic acid so that the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms is 2.5% by mass or less. Based on this knowledge, the oil-fat composition of this invention was completed. In the embodiment of the present invention, A (numerical value) to B (numerical value) means A or more and B or less.

<油脂組成物> 以下,對本發明的加熱調理用油脂組成物進行詳細說明。<Fat composition> Hereinafter, the fat composition for heating and conditioning of this invention is demonstrated in detail.

(油脂) 本發明的油脂組成物於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,該油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。(Fats) The fat and oil composition of the present invention contains 8% to 20% by mass of saturated fatty acids with 6 to 10 carbon atoms and 57% to 90% by mass of oleic acid in the fatty acids constituting the fats and oils. The triglyceride of a saturated fatty acid having 6 to 10 carbon atoms is 2.5% by mass or less.

本發明中,藉由碳數6~10的飽和脂肪酸於油脂中存在一定量以上,可獲得營養效果。另外,若碳數6~10的飽和脂肪酸的含量變多,則起泡變得激烈。因此,碳數6~10的飽和脂肪酸於油脂的構成脂肪酸中含有8質量%~20質量%。更佳為含有10質量%~16質量%。 碳數6~10的飽和脂肪酸較佳為直鏈狀飽和脂肪酸,例如可列舉:己酸、辛酸、癸酸、月桂酸。該些可使用源自椰子油、棕櫚仁油的脂肪酸,且可單獨或組合而使用。例如可以例如辛酸/癸酸=80/20~0/100(質量比)、較佳為辛酸/癸酸=60/40~75/25(質量比)來使用。In the present invention, a nutritional effect can be obtained when a saturated fatty acid having 6 to 10 carbon atoms is present in a certain amount or more in fats and oils. When the content of saturated fatty acids having 6 to 10 carbon atoms is increased, foaming becomes intense. Therefore, the saturated fatty acid having 6 to 10 carbon atoms contains 8 to 20% by mass of the constituent fatty acids of the oil and fat. The content is more preferably from 10% by mass to 16% by mass. The saturated fatty acid having 6 to 10 carbon atoms is preferably a linear saturated fatty acid, and examples thereof include hexanoic acid, caprylic acid, capric acid, and lauric acid. These can use fatty acids derived from coconut oil and palm kernel oil, and can be used alone or in combination. For example, octanoic acid / decanoic acid = 80/20 to 0/100 (mass ratio), and preferably octanoic acid / decanoic acid = 60/40 to 75/25 (mass ratio) can be used.

本發明中,油酸於油脂中存在57質量%以上,藉此可抑制由含有碳數6~10的飽和脂肪酸而引起的起泡。油酸含量越高越抑制起泡,故較佳。若考慮可藉由市售而獲取的油酸的純度為98%~99%,於使用8質量%~20質量%的碳數6~10的飽和脂肪酸的情況下,則油酸的上限為90質量%。因此,油酸於油脂的構成脂肪酸中較佳為57質量%~90質量%。更佳為60質量%~95質量%,進而佳為62質量%~75質量%。油酸最佳為於油脂的構成脂肪酸中含有65質量%~75質量%。油酸可使用源自油菜籽、大豆、向日葵、紅花、橄欖等高油酸品種的油酸。另外,可使用將低油酸含量的棕櫚脂肪酸分餾而製成高純度者等。In the present invention, oleic acid is present in the fat and oil in an amount of 57% by mass or more, thereby suppressing foaming caused by containing a saturated fatty acid having 6 to 10 carbon atoms. The higher the oleic acid content, the more it suppresses foaming, so it is preferred. Considering that commercially available oleic acid has a purity of 98% to 99%, and when 8 to 20% by mass of a saturated fatty acid having 6 to 10 carbon atoms is used, the upper limit of oleic acid is 90. quality%. Therefore, oleic acid is preferably 57% by mass to 90% by mass of the constituent fatty acids in fats and oils. It is more preferably 60% by mass to 95% by mass, and even more preferably 62% by mass to 75% by mass. Oleic acid is preferably 65 to 75% by mass in the constituent fatty acids of fats and oils. As oleic acid, oleic acid derived from high oleic acid varieties such as rapeseed, soybean, sunflower, safflower, and olive can be used. In addition, palm fatty acid having a low oleic acid content can be fractionated to obtain high purity.

本發明中,油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。若僅包含碳數6~10的飽和脂肪酸的三甘油酯的量多於2.5質量%,則油炸時的起泡變得激烈,故欠佳。更佳為油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.0質量%以下,進而佳為1.6質量%以下,最佳為1.0質量%以下。In the present invention, the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils is 2.5% by mass or less. If the amount of triglyceride containing only saturated fatty acids having 6 to 10 carbons is more than 2.5% by mass, foaming during frying becomes intense, which is not preferable. More preferably, the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms is 2.0% by mass or less, more preferably 1.6% by mass or less, and most preferably 1.0% by mass or less.

本發明中,油脂中的僅包含碳數6~10的飽和脂肪酸的甘油酯以外的三甘油酯並無特別限定。例如,於使用後述的酯交換油脂或經酯化的油脂的情況下,構成脂肪酸中包含兩個碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為5質量%~25質量%,更佳為6質量%~15質量%。另外,構成脂肪酸中包含一個碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為20質量%~50質量%,更佳為成為25質量%~40質量%。另外,構成脂肪酸中不包含碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為30質量%~65質量%,更佳為成為45質量%~65質量%。再者,碳數6~10的飽和脂肪酸以外的構成脂肪酸較佳為存在於植物油中的碳數16~22的脂肪酸。In the present invention, triglycerides other than glycerides containing only saturated fatty acids having 6 to 10 carbon atoms are not particularly limited. For example, when a transesterified fat or an esterified fat described later is used, the amount of triglyceride containing two saturated fatty acids having 6 to 10 carbon atoms in the fatty acid is preferably 5 to 25% by mass. , More preferably from 6% by mass to 15% by mass. The amount of triglyceride containing 6 to 10 saturated fatty acids in the constituent fatty acid is preferably 20% to 50% by mass, and more preferably 25% to 40% by mass. The amount of triglyceride that does not contain saturated fatty acids having 6 to 10 carbon atoms in the constituent fatty acid is preferably 30% to 65% by mass, and more preferably 45% to 65% by mass. The constituent fatty acids other than the saturated fatty acids having 6 to 10 carbon atoms are preferably fatty acids having 16 to 22 carbon atoms that are present in vegetable oils.

油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸以及57質量%~90質量%的油酸的油脂可自酯交換或酯化而獲得。因此,該些油脂較佳為酯交換油脂及/或經酯化的油脂。該些油脂較佳為於油脂組成物中含有50質量%~100質量%,更佳為80質量%~100質量%。最佳為於油脂組成物中含有95質量%~100質量%的該些油脂。再者,將來可期待使用藉由品種改良而獲得的由植物獲得的油脂來代替酯交換油脂及/或經酯化的油脂。Fats and oils containing 8 to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57 to 90% by mass of oleic acid in the fatty acids constituting the fats and oils can be obtained by transesterification or esterification. Therefore, these fats and oils are preferably transesterified fats and / or esterified fats and oils. These fats and oils are preferably contained in the fat and oil composition in an amount of 50% by mass to 100% by mass, and more preferably 80% by mass to 100% by mass. Most preferably, these fats and oils are contained in the fats and oils composition at 95 mass%-100 mass%. In addition, it is expected that the use of plant-derived oils and fats obtained by improving varieties will replace transesterified oils and / or esterified oils and fats in the future.

如所述般,本發明中作為於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、70質量%~90質量%的油酸的油脂,可使用酯交換油脂及/或經酯化的油脂。作為除該些油脂以外調配的油脂,就不使油炸時的起泡惡化的方面而言,較佳為油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂。作為油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂,可列舉:大豆油、菜籽油、紅花油、玉米油、葵花油、芝麻油、橄欖油等植物油。油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂較佳為於油脂組成物中含有0質量%~50質量%。更佳為含有0質量%~20質量%,最佳為含有0質量%~5質量%。As described above, in the present invention, as a constituent fatty acid in fats and oils, 8 to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 70 to 90% by mass of oleic acid can be used for transesterification. Grease and / or esterified grease. As the fats and oils prepared in addition to these fats and oils, fats and oils that do not contain fatty acids having a carbon number of 12 or less are preferred in terms of not deteriorating foaming during frying. Examples of fats and oils that do not contain fatty acids having a carbon number of 12 or less as the constituent fatty acids of fats and oils include vegetable oils such as soybean oil, rapeseed oil, safflower oil, corn oil, sunflower oil, sesame oil, and olive oil. Fats and oils that do not contain fatty acids having a carbon number of 12 or less in the fatty acids constituting the fats and oils preferably contain 0% to 50% by mass in the fats and oils composition. The content is more preferably 0 to 20% by mass, and the most preferably 0 to 5% by mass.

本發明中使用的油脂較佳為純化油脂。本發明的油脂可藉由純化來製造,所述純化是視榨油需要,經過脫膠步驟、脫酸步驟、脫色步驟,進而視需要經過脫蠟步驟後經過除臭步驟。所述脫膠步驟、脫酸步驟、及脫蠟步驟是根據可對應於提煉油之前的油料原料而變動的粗油的品質來適宜選擇。The fats and oils used in the present invention are preferably purified fats and oils. The fats and oils of the present invention can be produced by purification. The purification is performed according to the needs of oil extraction, through a degumming step, a deacidification step, a decoloring step, and further, if necessary, a dewaxing step and then a deodorizing step. The degumming step, deacidifying step, and dewaxing step are appropriately selected depending on the quality of the crude oil that can be changed according to the oil feedstock before the oil is refined.

(酯交換油脂) 本發明的油脂組成物可對選自碳數6~10的飽和脂肪酸的甘油酯、碳數6~10的飽和脂肪酸的低級醇酯、碳數6~10的飽和脂肪酸中的一種以上、以及油脂的構成脂肪酸為高油酸的油脂進行酯交換而獲得。或者可對選自油酸的低級醇酯、油酸中的一種以上、以及碳數6~10的飽和脂肪酸的甘油酯進行酯交換而獲得。 碳數6~10的飽和脂肪酸的甘油酯較佳為三甘油酯。例如可使用作為市售的中鏈脂肪酸三甘油酯而販賣者。 油脂的構成脂肪酸為高油酸的油脂較佳為構成脂肪酸中油酸為68質量%以上的油脂,更佳為構成脂肪酸中油酸為70質量%的油脂,進而佳為構成脂肪酸中油酸為75質量%以上的油脂,最佳為構成脂肪酸中油酸為80質量%以上的油脂。作為該些油脂,可使用高油酸菜籽油、高油酸葵花油、高油酸紅花油、橄欖油等。 另外,碳數6~10的飽和脂肪酸的低級醇酯、碳數6~10的飽和脂肪酸、油酸的低級醇酯、油酸可使用市售者。再者,就容易去除副產物的醇而言,低級醇酯的低級醇較佳為甲醇、乙醇、1-丙醇、2-丙醇等碳數1~3的低級醇。(Ester-exchange fats and oils) The fat and oil composition of the present invention can be selected from glycerides of saturated fatty acids with 6 to 10 carbon atoms, lower alcohol esters of saturated fatty acids with 6 to 10 carbon atoms, and saturated fatty acids with 6 to 10 carbon atoms. One or more types of fats and oils whose fatty acids are high oleic acid are transesterified. Alternatively, it can be obtained by transesterifying a lower alcohol ester selected from oleic acid, one or more of oleic acid, and a glyceride of a saturated fatty acid having 6 to 10 carbon atoms. The glyceride of a saturated fatty acid having 6 to 10 carbon atoms is preferably a triglyceride. For example, it can be sold as a commercially available medium-chain fatty acid triglyceride. Fats and oils whose constituent fatty acids are high oleic acid are preferably fats and oils containing 68% by mass or more of oleic acid in fatty acids, more preferably 70% by mass of oils and fats containing oleic acid in fatty acids, and more preferably 75% by mass of oleic acids in fatty acids. The above fats and oils are preferably fats and oils having an oleic acid content of 80% by mass or more. As these fats and oils, high oleic rapeseed oil, high oleic sunflower oil, high oleic safflower oil, olive oil, and the like can be used. As the lower alcohol ester of a saturated fatty acid having 6 to 10 carbon atoms, the lower alcohol ester of a saturated fatty acid having 6 to 10 carbon atoms, a lower alcohol ester of oleic acid, and oleic acid can be used commercially. Furthermore, in terms of alcohols that are easy to remove by-products, the lower alcohol of the lower alcohol ester is preferably a lower alcohol having 1 to 3 carbon atoms such as methanol, ethanol, 1-propanol, and 2-propanol.

本發明的油脂組成物為構成脂肪酸的68質量%以上為油酸的植物油、以及碳數6~10的飽和脂肪酸的三甘油酯的酯交換油脂時,在酯交換的過程中不會副產生低級醇或水分,故較佳。When the fat and oil composition of the present invention is a transesterified fat oil comprising 68% by mass or more of oleic acid vegetable oil and triglyceride of saturated fatty acids having 6 to 10 carbon atoms, lower grades will not be produced in the transesterification process. Alcohol or water is preferred.

酯交換可使用甲醇鈉之類的鹼觸媒或脂肪酶等酶來進行。所使用的原料的比例是以最終的製造油脂於構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸的方式進行調整。The transesterification can be performed using an alkali catalyst such as sodium methoxide or an enzyme such as lipase. The proportion of the raw materials used is adjusted so that the final fatty oil contains 8% to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57% to 90% by mass of oleic acid.

例如,於進行將甲醇鈉作為觸媒的酯交換反應的情況下,混合原料,於100 mmHg以下的減壓下且80℃~100℃下將混合物加熱,並去除原料混合物中所含的氣體成分及水分。向其中添加0.02質量%~0.5質量%的甲醇鈉,於常壓·氮氣流下或10 mmHg以下的減壓下,在80℃~100℃下攪拌10分鐘~60分鐘,藉此進行酯交換反應。藉由利用氣相層析法測定反應產物的三甘油酯組成來確認反應的結束。藉由向反應產物中添加水或添加磷酸等酸來進行反應的停止。之後,進行充分的水洗以去除觸媒及過量的酸,於乾燥後利用常法對反應產物進行脫色、除臭。For example, in the case of a transesterification reaction using sodium methoxide as a catalyst, the raw materials are mixed, the mixture is heated under a reduced pressure of 100 mmHg or less and at 80 ° C to 100 ° C, and gas components contained in the raw material mixture are removed. And moisture. 0.02 to 0.5% by mass of sodium methoxide was added thereto, and the transesterification reaction was performed by stirring at 80 ° C to 100 ° C for 10 to 60 minutes under a normal pressure and nitrogen flow or a reduced pressure of 10 mmHg or less. The end of the reaction was confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction is stopped by adding water or an acid such as phosphoric acid to the reaction product. After that, sufficient water was washed to remove the catalyst and excess acid, and after drying, the reaction product was decolorized and deodorized by a conventional method.

於使用脂肪酶進行酯交換反應的情況下,混合原料並調整溫度至脂肪酶的活性可充分地發揮的反應溫度即40℃~100℃的範圍。之後,相對於原料混合物而以0.005質量%~10質量%的比例添加脂肪酶,以2小時~48小時的範圍進行酯交換反應。該反應理想的是於常壓下在氮氣流中進行。藉由利用氣相層析法測定反應產物的三甘油酯組成來確認反應的結束。藉由利用過濾將酶去除來進行反應的停止。反應產物是於水洗、乾燥後利用常法來進行脫色、除臭。再者,於使用中鏈脂肪酸的情況下,於反應停止後利用薄膜式蒸發器來預先去除游離脂肪酸。 若使用脂肪酶的酯交換反應不充分,則於分子內具有三個中鏈脂肪酸殘基的三甘油酯的比例變多。於分子內具有三個中鏈脂肪酸殘基的三甘油酯的比例多的油脂組成物於連續的油炸調理時,冒煙或起泡變得激烈,故欠佳。 作為脂肪酶,可列舉源自產鹼菌(alcaligenes)屬、念珠菌屬、根黴菌(rhizopus)屬、毛黴菌(mucor)屬或假單胞菌(pseudomonas)屬的脂肪酶,或源自肝臟的磷脂酶A等,特佳為源自念珠菌屬或根黴菌屬的脂肪酶。In the case of performing a transesterification reaction using a lipase, the raw materials are mixed and the temperature is adjusted to a range of 40 ° C to 100 ° C, which is a reaction temperature at which the activity of the lipase can be sufficiently exhibited. Thereafter, lipase is added at a ratio of 0.005 mass% to 10 mass% with respect to the raw material mixture, and a transesterification reaction is performed within a range of 2 hours to 48 hours. The reaction is desirably carried out under a nitrogen stream at normal pressure. The end of the reaction was confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction was stopped by removing the enzyme by filtration. After the reaction product is washed with water and dried, it is decolorized and deodorized by a conventional method. When a medium-chain fatty acid is used, after the reaction is stopped, the free fatty acid is removed in advance by a thin-film evaporator. If the transesterification reaction using a lipase is insufficient, the proportion of triglyceride having three medium-chain fatty acid residues in the molecule increases. An oil and fat composition having a large proportion of triglycerides having three medium-chain fatty acid residues in the molecule during continuous frying and conditioning causes intense smoke and foaming, which is not satisfactory. Examples of the lipase include lipases derived from the genus alcaligenes, Candida, rhizopus, mucor, or pseudomonas, or liver-derived The phospholipase A and the like are particularly preferably a lipase derived from Candida or Rhizopus.

(經酯化的油脂) 本發明的油脂組成物可混合碳數6~10的飽和脂肪酸、油酸、甘油,並藉由無觸媒或鹼中的利用加熱的酯化、或者利用脂肪酶的酯化而獲得。於酯化反應中,副產生水分,為了推進反應而需要去除水分,因此較佳為利用加熱的酯化。所使用的原料的比例是以最終的製造油脂於構成脂肪酸中使碳數6~10的飽和脂肪酸成為8質量%~20質量%、使油酸成為57質量%~90質量%的方式進行調整。(Esterified Fats and Oils) The fats and oils composition of the present invention can be mixed with saturated fatty acids, oleic acid, and glycerin having 6 to 10 carbon atoms, and esterified by heating with no catalyst or alkali, or using lipase. Obtained by esterification. In the esterification reaction, water is produced as a by-product, and it is necessary to remove water in order to advance the reaction. Therefore, it is preferable to use heat for esterification. The proportion of the raw materials used is adjusted such that the final fatty acid is composed of saturated fatty acids having 6 to 10 carbon atoms to 8 to 20% by mass and oleic acid is 57 to 90% by mass in the constituent fatty acids.

例如,於無觸媒下進行酯化反應的情況下,混合原料,並於常溫或者100 mmHg以下的減壓下將混合物加熱至200℃以上,使其進行3小時~20小時酯化。此時,就防止著色的方面而言,較佳為於氮氣流下進行。藉由利用酸價測定游離脂肪酸量來確認反應的結束。利用常法來對反應產物進行脫酸、脫色、除臭。再者,於殘存脂肪酸多的情況下,較佳為自反應產物利用薄膜式蒸發器等來預先去除脂肪酸。For example, when the esterification reaction is performed without a catalyst, the raw materials are mixed, and the mixture is heated to 200 ° C or higher under normal temperature or a reduced pressure of 100 mmHg or less, and the esterification is performed for 3 to 20 hours. In this case, in terms of preventing coloration, it is preferably performed under a nitrogen stream. The end of the reaction was confirmed by measuring the amount of free fatty acid using an acid value. The reaction product is deacidified, decolored, and deodorized by a conventional method. When there are many residual fatty acids, it is preferable to remove the fatty acids in advance from a reaction product using a thin-film evaporator or the like.

於使用脂肪酶進行酯化反應的情況下,混合原料並調整溫度至脂肪酶的活性可充分地發揮的反應溫度即40℃~100℃的範圍。之後,相對於原料混合物而以0.005質量%~10質量%的比例添加脂肪酶,以5小時~200小時的範圍進行酯化反應。該反應理想的是於常壓下在氮氣流中、或微減壓下進行。藉由利用酸價測定游離脂肪酸量來確認反應的結束。藉由利用過濾將酶去除來進行反應的停止。反應產物是於水洗、乾燥後利用常法來進行脫酸、脫色、除臭。再者,於殘存脂肪酸多的情況下,較佳為自反應產物利用薄膜式蒸發器等來預先去除脂肪酸。 作為脂肪酶,可列舉源自產鹼菌屬、念珠菌屬、根黴菌屬、毛黴菌屬或假單胞菌屬的脂肪酶,或源自肝臟的磷脂酶A等,特佳為源自念珠菌屬或根黴菌屬的脂肪酶。When an esterification reaction is performed using a lipase, the raw materials are mixed and the temperature is adjusted to a range of 40 ° C to 100 ° C, which is a reaction temperature at which the activity of the lipase can be sufficiently exhibited. Thereafter, lipase is added at a ratio of 0.005 mass% to 10 mass% with respect to the raw material mixture, and an esterification reaction is performed within a range of 5 hours to 200 hours. This reaction is desirably carried out under a nitrogen stream at a normal pressure, or under a slight reduced pressure. The end of the reaction was confirmed by measuring the amount of free fatty acid using an acid value. The reaction was stopped by removing the enzyme by filtration. After the reaction product is washed with water and dried, it is deacidified, decolored, and deodorized by a common method. When there are many residual fatty acids, it is preferable to remove the fatty acids in advance from a reaction product using a thin-film evaporator or the like. Examples of the lipase include lipases derived from Alcaligenes, Candida, Rhizopus, Mucor or Pseudomonas, or phospholipase A derived from the liver. Particularly preferred are Candida-derived candida. Lipase from Mycobacterium or Rhizopus.

(其他成分) 於不損及本發明的效果的程度內,可向本發明的油脂組成物中加入油脂以外的成分。該些成分例如是用於一般的油脂中的成分(食品添加物等)。作為該些成分,例如可列舉:抗氧化劑、乳化劑、矽酮油、結晶調整劑、口感改良劑等,較佳為於除臭後且填充前添加。(Other components) To the extent that the effects of the present invention are not impaired, components other than oil and fat may be added to the oil and fat composition of the present invention. These components are, for example, components (food additives, etc.) used in general fats and oils. Examples of these components include antioxidants, emulsifiers, silicone oils, crystal modifiers, and texture improvers, and they are preferably added after deodorization and before filling.

作為抗氧化劑,例如可列舉:生育酚類、抗壞血酸類、黃酮衍生物、麴酸、沒食子酸衍生物、兒茶素及其酯、蜂鬥菜酸、棉酚(gossypol)、芝麻酚(sesamol)、萜烯類等。Examples of the antioxidant include tocopherols, ascorbic acids, flavonoid derivatives, gallic acid, gallic acid derivatives, catechins and their esters, butteric acid, gossypol, and sesaminol ( sesamol), terpenes, etc.

作為乳化劑,可列舉:蔗糖脂肪酸酯、聚甘油脂肪酸酯、有機酸單甘油酯、單甘油酯、二甘油酯、山梨糖醇脂肪酸酯、山梨糖醇酐脂肪酸酯、聚山梨醇酯、丙二醇脂肪酸酯、卵磷脂等。藉由含有一部分乳化劑,可進一步提高油炸適應性、特別是起泡抑制。但是,藉由含有乳化劑,產生蛋黃醬的黏度下降的問題,因此乳化劑添加較佳為少量或不添加。例如,於進行添加的本發明中可選擇所述乳化劑的至少一種,對油脂組成物的添加量較佳為以乳化劑整體計而未滿0.5質量%,進而佳為0.01質量%~0.2質量%。最佳為不含有乳化劑。Examples of the emulsifier include sucrose fatty acid ester, polyglycerol fatty acid ester, organic acid monoglyceride, monoglyceride, diglyceride, sorbitol fatty acid ester, sorbitan fatty acid ester, and polysorbitol. Esters, propylene glycol fatty acid esters, lecithin, and the like. By including a part of the emulsifier, the frying adaptability, especially the suds suppression, can be further improved. However, since the emulsifier contains a problem that the viscosity of the mayonnaise decreases, the emulsifier is preferably added in a small amount or not. For example, in the present invention to be added, at least one kind of the emulsifier may be selected, and the amount of the fat and oil composition added is preferably less than 0.5% by mass based on the entire emulsifier, and more preferably 0.01% by mass to 0.2% by mass. %. Most preferably, it does not contain an emulsifier.

作為矽酮油,可使用於食品用途中市售者,並無特別限定,例如可列舉具有二甲基聚矽氧烷結構且動態黏度於25℃下為800 mm2 /s~5000 mm2 /s者。矽酮油的動態黏度特佳為800 mm2 /s~2000 mm2 /s,進而佳為900 mm2 /s~1100 mm2 /s。此處,所謂「動態黏度」,設為是指依據JIS K 2283(2000)而測定的值。關於矽酮油,除矽酮油以外亦可包含微粒子二氧化矽。The silicone oil can be used in food applications without any particular limitation, and examples thereof include a dimethylpolysiloxane structure and a dynamic viscosity of 800 mm 2 / s to 5000 mm 2 / at 25 ° C. s person. The dynamic viscosity of the silicone oil is particularly preferably 800 mm 2 / s to 2000 mm 2 / s, and further preferably 900 mm 2 / s to 1100 mm 2 / s. Here, the "dynamic viscosity" is a value measured based on JIS K 2283 (2000). As for the silicone oil, fine particles of silicon dioxide may be contained in addition to the silicone oil.

<油脂組成物的用途> 本發明的加熱調理用油脂組成物可用於所有的加熱調理用途,但油炸時的起泡得到抑制,故適於油炸用途。另外,乳化劑的添加為少量或未添加的油脂組成物適於油炸用途及蛋黃醬用途。<Uses of oil and fat composition> The oil and fat composition for heating and conditioning of the present invention can be used for all heating and conditioning applications, but foaming during frying is suppressed, and therefore it is suitable for frying applications. In addition, the addition of an emulsifier in a small amount or no added fat and oil composition is suitable for frying applications and mayonnaise applications.

<脂肪酸及三甘油酯的分析> 本發明中,構成油脂的脂肪酸的分析可依照美國油脂化學協會(The American Oil Chemists Society,AOCS)官方方法(Official Method)Ce 1f-96並利用氣相層析法來測定。油脂中的三甘油酯量可依照氣相層析法(JAOCS, Vol. 70, no.11, 1111-1114)(1993)來測定。 [實施例]<Analysis of fatty acids and triglycerides> In the present invention, the analysis of fatty acids constituting oils and fats can be performed according to the Official Method Ce 1f-96 of The American Oil Chemists Society (AOCS) and by gas chromatography Method to determine. The amount of triglyceride in fats and oils can be measured by gas chromatography (JAOCS, Vol. 70, no. 11, 1111-1114) (1993). [Example]

以下,基於實施例來對本發明進行具體說明,但本發明並不限定於該些實施例。Hereinafter, the present invention will be specifically described based on examples, but the present invention is not limited to these examples.

(實施例1:樣品製備) 按照表1的配方(質量比例)混合HOLL菜籽脫色油(高油酸菜籽脫色油 構成脂肪酸中的油酸:73.4質量% 日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、構成脂肪酸以質量比計為辛酸:癸酸=75:25的MCT(中鏈脂肪酸三甘油酯 日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)。相對於該混合物100質量份而添加0.3質量份的脂肪酶QLM(名糖產業股份有限公司製造),於攪拌下以45℃進行16小時酯交換反應。自反應產物過濾分離酶,對濾液進行脫酸、脫色、除臭(250℃、3托(Torr)、60分鐘)而獲得組成物(實施例1)。 組成物的碳數6~10的飽和脂肪酸為13.7%,油酸為63.1%。另外,油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為1.5質量%,包含兩個碳數6~10的飽和脂肪酸的三甘油酯的量為10.8質量%,構成脂肪酸中包含一個碳數6~10的飽和脂肪酸的三甘油酯的量為37.8質量%。(Example 1: Sample preparation) According to the formula (mass ratio) in Table 1, HOLL rapeseed decolorized oil (high oleic rapeseed decolorized oil constitutes oleic acid in fatty acids: 73.4% by mass of Nisshin OilliO Group) (Group) Co., Ltd.), MCT (mass chain fatty acid triglyceride, manufactured by Nisshin OilliO Group Co., Ltd.) is the caprylic acid: capric acid = 75: 25 in mass ratio of constituent fatty acids. 0.3 mass parts of lipase QLM (made by Mingsu Industry Co., Ltd.) was added to 100 mass parts of this mixture, and transesterification reaction was performed at 45 degreeC for 16 hours with stirring. The enzyme was filtered and separated from the reaction product, and the filtrate was deacidified, decolored, and deodorized (250 ° C, 3 Torr, 60 minutes) to obtain a composition (Example 1). The composition has 13.7% saturated fatty acids having 6 to 10 carbon atoms, and 63.1% oleic acid. In addition, the amount of triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils is 1.5% by mass, and the amount of triglyceride containing two saturated fatty acids having 6 to 10 carbon atoms is 10.8% by mass. The amount of triglyceride of a saturated fatty acid having 6 to 10 carbon atoms was 37.8% by mass.

(實施例2~實施例5、比較例1:樣品製備) 按照表1的配方(質量比例)混合菜籽脫色油(構成脂肪酸中的油酸:61.4質量%、日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、HOLL菜籽脫色油(高油酸菜籽脫色油 構成脂肪酸中的油酸:73.4質量% 日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、高油酸葵花脫色油(構成脂肪酸中的油酸:81.8質量%、日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、構成脂肪酸以質量比計為辛酸:癸酸=75:25的MCT(中鏈脂肪酸三甘油酯 日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)。相對於該混合物100質量份而添加0.3質量份的脂肪酶QLM(名糖產業股份有限公司製造),於攪拌下以45℃進行16小時酯交換反應。自反應產物過濾分離酶,對濾液進行脫酸、脫色、除臭(250℃、3 Torr、60分鐘)而獲得組成物(實施例2~實施例5、比較例1)。(Example 2 to Example 5, Comparative Example 1: Sample preparation) According to the formula (mass ratio) in Table 1, mixed rapeseed decolorized oil (oleic acid in fatty acids: 61.4% by mass, Nisshin Oriyu Group (Nisshin (Manufactured by OilliO Group) Co., Ltd.), HOLL rapeseed decolorized oil (high oleic rapeseed decolorized oil constitutes oleic acid in fatty acids: 73.4% by mass manufactured by Nisshin OilliO Group), high Oleic acid sunflower decolorizing oil (oleic acid in fatty acids: 81.8% by mass, manufactured by Nisshin OilliO Group Co., Ltd.), fatty acids in terms of mass ratio are caprylic acid: capric acid = 75: 25 MCT (Mid-chain fatty acid triglyceride manufactured by Nisshin OilliO Group Co., Ltd.). 0.3 mass parts of lipase QLM (made by Mingsu Industry Co., Ltd.) was added to 100 mass parts of this mixture, and transesterification reaction was performed at 45 degreeC for 16 hours with stirring. The enzyme was filtered and separated from the reaction product, and the filtrate was deacidified, decolored, and deodorized (250 ° C, 3 Torr, 60 minutes) to obtain a composition (Example 2 to Example 5, Comparative Example 1).

(分析) 油脂的脂肪酸的分析是依照AOCS Ce 1f-96並利用氣相層析法來測定。油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯量是依照氣相層析法(JAOCS, vol. 70, 11, 1111-1114)(1993)來測定。 將組成物(比較例1、實施例1~實施例5)的分析值[油脂的構成脂肪酸中的碳數6~10的飽和脂肪酸量(質量比例)、油脂的構成脂肪酸中的油酸量(質量比例)、僅包含碳數6~10的飽和脂肪酸的三甘油酯量(質量比例)]示於表1中。(Analysis) Analysis of fatty acids in oils and fats was measured by gas chromatography in accordance with AOCS Ce 1f-96. The amount of triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils was measured in accordance with gas chromatography (JAOCS, vol. 70, 11, 1111-1114) (1993). The analysis value of the composition (Comparative Example 1, Examples 1 to 5) was [the amount of saturated fatty acids having a carbon number of 6 to 10 (mass ratio) in the constituent fatty acids of fats and oils, and the amount of oleic acid in the constituent fatty acids of fats and oils ( Mass ratio) and triglyceride amount (mass ratio) containing only saturated fatty acids having 6 to 10 carbon atoms are shown in Table 1.

[表1] [Table 1]

(油炸時的起泡試驗) 將20 ml的油脂組成物(比較例1、實施例1~實施例5)放入試驗管(內徑28 mm)中,並加熱至160℃。將土豆片(立方體 1 cm×1 cm×1 cm)放入油脂組成物中,測定所產生的氣泡的最高達到距離。 另外,於比較例1中添加0.8質量%的蔗糖脂肪酸酯(料陶蔗糖酯(Ryoto Sugar Ester)O-170 三菱化學食品股份有限公司製造),從而製備參考例1的油脂組成物。參考例1中亦同樣地測定氣泡的最高達到距離。 另外,若進行油炸,則磷脂質等自油炸調理品中溶出,起泡變得厲害。因此,向油脂組成物(比較例1、實施例1~實施例5、參考例1)中添加200 ppm(質量比例)的卵磷脂(日清奧利友集團(Nisshin OilliO Group)股份有限公司製造),如所述般測定所產生的氣泡的最高達到距離。 測定是進行各三次,並將起泡(氣泡的最高達到距離的平均值)示於表2中。(Foaming test during frying) 20 ml of a fat composition (Comparative Example 1, Example 1 to Example 5) were put into a test tube (inner diameter 28 mm) and heated to 160 ° C. Put potato chips (cubic 1 cm × 1 cm × 1 cm) into the oil and fat composition, and measure the maximum reach of the generated air bubbles. In addition, 0.8% by mass of sucrose fatty acid ester (Ryoto Sugar Ester O-170 manufactured by Mitsubishi Chemical Foods Co., Ltd.) was added to Comparative Example 1 to prepare a fat and oil composition of Reference Example 1. In Reference Example 1, the maximum reach of the bubbles was measured in the same manner. In addition, when fried, phospholipids and the like are dissolved from the fried conditioning product, and foaming becomes severe. Therefore, 200 ppm (mass ratio) of lecithin (manufactured by Nisshin OilliO Group) was added to the fat and oil composition (Comparative Example 1, Example 1 to Example 5, Reference Example 1). ), And measure the maximum reach of the generated bubbles as described. The measurement was performed three times each, and bubbling (the average value of the maximum reach distance of the air bubbles) is shown in Table 2.

[表2] [Table 2]

如表2所示般,可確認到實施例1~實施例5中起泡均良好,特別是即便於磷脂質等自油炸調理品中溶出而起泡變得激烈的情況下,亦可充分地抑制起泡。As shown in Table 2, it was confirmed that the foaming was good in Examples 1 to 5, and it was sufficient even when the foaming became fierce when it was dissolved out of the frying conditioning product such as phospholipids. To suppress foaming.

(蛋黃醬評價) 蛋黃醬是利用下述的方法來製作。 向食物加工器中放入3個雞蛋、45 g的米醋、5 g的鹽、2 g的芥末、2 g的砂糖、少量的胡椒並攪拌10秒鐘。繼而,一面持續攪拌一面逐次少量加入360 g的實施例1~實施例5、比較例1的油脂組成物。將油脂組成物加入完成後,進而攪拌約3分鐘,並確認蛋黃醬的保形性。將所述結果示於表3中。(Evaluation of Mayonnaise) Mayonnaise was prepared by the following method. Add 3 eggs, 45 g of rice vinegar, 5 g of salt, 2 g of mustard, 2 g of granulated sugar, a small amount of pepper into the food processor and stir for 10 seconds. Then, while continuously stirring, 360 g of the oil and fat compositions of Examples 1 to 5 and Comparative Example 1 were added in small amounts one by one. After the addition of the fat composition was completed, the mixture was further stirred for about 3 minutes, and the shape retention of the mayonnaise was confirmed. The results are shown in Table 3.

[表3] [table 3]

根據表2、表3,比較例1中起泡厲害,若於比較例1中添加蔗糖脂肪酸酯,則可改善起泡,但蛋黃醬的保形性變差。另一方面,實施例1~實施例5中起泡亦良好,蛋黃醬的保形性亦良好。According to Tables 2 and 3, foaming was severe in Comparative Example 1. When sucrose fatty acid ester was added to Comparative Example 1, foaming was improved, but the shape retention of the mayonnaise was poor. On the other hand, foaming was also good in Examples 1 to 5, and the shape retention of the mayonnaise was also good.

no

no

Claims (5)

一種油脂組成物,其於油脂的構成脂肪酸中包含8質量%~20質量%的碳數6~10的飽和脂肪酸、以及57質量%~90質量%的油酸, 所述油脂包含的三甘油酯為2.5質量%以下,所述三甘油酯僅由碳數6~10的飽和脂肪酸構成。A fat and oil composition comprising 8 to 20% by mass of saturated fatty acids having a carbon number of 6 to 10 and 57 to 90% by mass of oleic acid in constituent fatty acids of the fat and oil, and a triglyceride contained in the fat and oil It is 2.5% by mass or less, and the triglyceride is composed of only saturated fatty acids having 6 to 10 carbon atoms. 如申請專利範圍第1項所述的油脂組成物,其中油脂的構成脂肪酸中包含8質量%~20質量%的碳數6~10的飽和脂肪酸、以及70質量%~90質量%的油酸,所述油脂為酯交換油脂及/或經酯化的油脂,並於油脂組成物中含有50質量%~100質量%的所述油脂。The oil and fat composition according to item 1 of the scope of the patent application, wherein the constituent fatty acids of the oil and fat include 8 to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms, and 70 to 90% by mass of oleic acid, The fat and oil is a transesterified fat and / or an esterified fat and oil, and the fat and oil composition contains the fat and oil in an amount of 50% to 100% by mass. 如申請專利範圍第1項或第2項所述的油脂組成物,其中所述油脂為植物油與三甘油酯的酯交換油脂,所述植物油的構成脂肪酸包含68質量%的油酸,所述三甘油酯為碳數6~10的飽和脂肪酸。The fat or oil composition according to item 1 or 2 of the scope of the patent application, wherein the fat is a transesterified fat of vegetable oil and triglyceride, the constituent fatty acid of the vegetable oil contains 68% by mass of oleic acid, and the three Glyceride is a saturated fatty acid having 6 to 10 carbon atoms. 如申請專利範圍第1項至第3項中任一項所述的油脂組成物,其中所述油脂組成物不包含乳化劑。The fat or oil composition according to any one of claims 1 to 3, wherein the fat or oil composition does not include an emulsifier. 如申請專利範圍第1項至第4項中任一項所述的油脂組成物,其中所述油脂組成物為選自油炸用途與蛋黃醬用途中的用途。The fat or oil composition according to any one of claims 1 to 4 of the scope of application for a patent, wherein the fat or oil composition is an application selected from the group consisting of frying applications and mayonnaise applications.
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