TWI776917B - oil composition - Google Patents

oil composition Download PDF

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TWI776917B
TWI776917B TW107124062A TW107124062A TWI776917B TW I776917 B TWI776917 B TW I776917B TW 107124062 A TW107124062 A TW 107124062A TW 107124062 A TW107124062 A TW 107124062A TW I776917 B TWI776917 B TW I776917B
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mass
oil
oils
fats
fatty acids
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TW107124062A
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Chinese (zh)
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TW201912035A (en
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豊島尊
辻野祥伍
生稲淳一
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日商日清奧利友集團股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils

Abstract

本發明提供一種抑制油炸調理中的起泡的油脂組成物。或者本發明提供一種抑制油炸調理中的起泡、且可製備良好的蛋黃醬的油脂組成物。一種油脂組成物,其於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,該油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。較佳為油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、70質量%~90質量%的油酸的油脂為酯交換油脂及/或經酯化的油脂,並於油脂組成物中含有50質量%~100質量%的該油脂。The present invention provides an oil and fat composition that suppresses foaming in deep-frying. Alternatively, the present invention provides an oil and fat composition capable of suppressing foaming in deep-frying and preparing good mayonnaise. An oil and fat composition containing 8 to 20 mass % of saturated fatty acids with 6 to 10 carbon atoms and 57 to 90 mass % of oleic acid in constituent fatty acids of fats and oils, wherein the fats and oils only contain 6 to 6 carbon atoms -10 The triglyceride of saturated fatty acid is 2.5 mass % or less. It is preferable that fats and oils containing 8 to 20 mass% of saturated fatty acids having 6 to 10 carbon atoms and 70 to 90 mass% of oleic acid in the constituent fatty acids of fats and oils are transesterified fats and oils and/or esterified fats and oils , and contains 50% by mass to 100% by mass of the oil and fat in the oil and fat composition.

Description

油脂組成物Fat composition

本發明是有關於一種油脂組成物。 The present invention relates to an oil and fat composition.

自先前以來,食用油脂作為主要用途而用於油炸調理、煎炒調理等中。通常,於使用油脂進行油炸調理的情況下,自油炸物產生蒸氣而起泡,但藉由反覆進行油炸調理,因油脂的劣化及自油炸物的溶出成分的影響而導致起泡變得激烈。於起泡厲害的情況下,不僅因氣泡而看不到油炸物,而且自容器溢出等作業方面的安全性惡化。因此,無法進行一定量以上的油炸調理,特別是若對包含雞蛋或肉的油炸物進行油炸調理,則油脂的劣化快。作為抑制該些油炸調理時的氣泡的方法,進行矽酮油的添加,但矽酮油的效果有限,而且近年來有因其生物分解性的惡化而避免使用的傾向。 Conventionally, edible fats and oils have been used for frying, frying, and the like as a main use. In general, when frying is performed using fats and oils, steam is generated from the fried food to cause foaming. However, when the frying is repeatedly performed, foaming occurs due to the deterioration of the fats and oils and the influence of the eluted components from the fried food. become intense. In the case of strong foaming, not only the fried food cannot be seen due to the bubbles, but also the safety in work such as overflowing from the container is deteriorated. Therefore, it is impossible to perform deep-frying cooking in a certain amount or more, and when frying-conditioning is performed on fried foods including eggs or meat, the deterioration of fats and oils is rapid. Silicone oil is added as a method for suppressing these bubbles during frying, but the effect of silicone oil is limited, and in recent years, the use of silicone oil tends to be avoided due to the deterioration of biodegradability.

另外,椰子油與大豆油的混合油、中鏈脂肪酸三甘油酯與菜籽油等酯交換油等起泡較多,此種構成脂肪酸包含碳數6~10的脂肪酸與碳數14~22的脂肪酸這兩者的三甘油酯中即便添加矽酮,亦無法抑制氣泡。因此,揭示一種如下的發明:藉由向包含中鏈脂肪酸作為構成脂肪酸的油脂中添加特定的乳化劑,抑制油炸調理中的起泡。例如,專利文獻1中揭示有調配甘油或二甘油與脂肪酸的單酯。另外,專利文獻2中揭示有調配特定的蔗糖脂 肪酸酯。 In addition, mixed oils of coconut oil and soybean oil, and transesterified oils such as medium-chain fatty acid triglycerides and rapeseed oil, etc. foam more, and such constituent fatty acids include fatty acids with 6 to 10 carbon atoms and fatty acids with 14 to 22 carbon atoms. Even if silicone is added to triglycerides of both fatty acids, bubbles cannot be suppressed. Therefore, an invention of suppressing foaming in deep-frying is disclosed by adding a specific emulsifier to an oil and fat containing a medium-chain fatty acid as a constituent fatty acid. For example, Patent Document 1 discloses the preparation of monoesters of glycerol or diglycerol and fatty acids. In addition, Patent Document 2 discloses that specific sucrose lipids are formulated fatty acid esters.

[現有技術文獻] [Prior Art Literature]

[專利文獻] [Patent Literature]

[專利文獻1]日本專利第4040204號公報 [Patent Document 1] Japanese Patent No. 4040204

[專利文獻2]日本專利第4046438號公報 [Patent Document 2] Japanese Patent No. 4046438

但是,與油脂相比,乳化劑的原料費更高,且需要添加步驟,因此要求簡單地提供一種更廉價的製品。另外,由含有中鏈脂肪酸作為構成脂肪酸的油脂所製造的蛋黃醬的黏度變低,調配有乳化劑的所述油脂中黏度過低,存在無法保持作為蛋黃醬的保形性的問題。因此,於含有中鏈脂肪酸作為構成脂肪酸的油脂中需要一種用於油炸調理等加熱調理與蛋黃醬等乳化用途的通用油脂。 However, compared with oils and fats, the emulsifier has a higher raw material cost and requires an addition step, so it is required to simply provide a cheaper product. In addition, the viscosity of mayonnaise produced from fats and oils containing medium-chain fatty acids as constituent fatty acids becomes low, and the viscosity of the fats and oils prepared with an emulsifier is too low, and there is a problem that the shape retention properties as mayonnaise cannot be maintained. Therefore, among the oils and fats containing medium-chain fatty acids as constituent fatty acids, general-purpose oils and fats for heat-conditioning such as frying and emulsification such as mayonnaise are required.

因此,本發明的目的在於提供一種抑制油炸調理中的起泡的油脂組成物。另外,本發明的目的在於提供一種抑制油炸調理中的起泡、且可製備良好的蛋黃醬的油脂組成物。 Then, the objective of this invention is to provide the oil-fat composition which suppresses foaming in deep-frying. Moreover, the objective of this invention is to provide the oil-fat composition which suppresses foaming in deep-frying and can prepare a good mayonnaise.

本發明的油脂組成物為如下的油脂組成物:於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,該油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。 The oil and fat composition of the present invention is an oil and fat composition containing 8% by mass to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57% by mass to 90% by mass of oleic acid in constituent fatty acids of fats and oils. Among them, the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms is 2.5 mass % or less.

較佳為於油脂的構成脂肪酸中含有8質量%~20質量% 的碳數6~10的飽和脂肪酸、70質量%~90質量%的油酸的油脂為酯交換油脂及/或經酯化的油脂,並於油脂組成物中含有50質量%~100質量%的該油脂。 It is preferable to contain 8% by mass to 20% by mass in the constituent fatty acids of fats and oils The fats and oils containing saturated fatty acids with 6 to 10 carbon atoms and 70% by mass to 90% by mass of oleic acid are transesterified fats and oils and/or esterified fats and oils, and the oil and fat composition contains 50% by mass to 100% by mass of the grease.

較佳為所述油脂為構成脂肪酸的68質量%以上為油酸的植物油、與碳數6~10的飽和脂肪酸的三甘油酯的酯交換油脂。 Preferably, the fat is a vegetable oil whose constituent fatty acids are oleic acid in an amount of 68 mass % or more, and a fat and oil transesterified with a triglyceride of a saturated fatty acid having 6 to 10 carbon atoms.

本發明的油脂組成物較佳為不包含乳化劑。 It is preferable that the oil-fat composition of this invention does not contain an emulsifier.

本發明的油脂組成物較佳為選自油炸用途與蛋黃醬用途中的用途。 The oil and fat composition of the present invention is preferably a use selected from a frying use and a mayonnaise use.

根據本發明,可提供一種儘管酯交換油脂的構成脂肪酸中含有中鏈脂肪酸,但油炸時的起泡得到改善的油脂組成物。另外,可提供一種藉由減少或不包含乳化劑而可獲得具有良好的保形性的蛋黃醬的油脂組成物。 According to the present invention, it is possible to provide an oil and fat composition in which foaming during frying is improved, although a medium-chain fatty acid is contained in the constituent fatty acids of the transesterified fat and oil. In addition, it is possible to provide an oil and fat composition which can obtain mayonnaise having good shape retention by reducing or not including an emulsifier.

本發明者等人發現,藉由使用如下的油脂,可改善油炸時的起泡,所述油脂是於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,使僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。基於該見解,從而完成了本申請案發明的油脂組成物。再者,本發明的實施形態中,A(數值)~B(數值)是指A以上且B以下。 The inventors of the present invention found that foaming during frying can be improved by using fats and oils containing 8 to 20 mass% of saturated fatty acids having 6 to 10 carbon atoms in the constituent fatty acids of fats and oils , 57% by mass to 90% by mass of oleic acid, and 2.5% by mass or less of triglycerides containing only saturated fatty acids having 6 to 10 carbon atoms. Based on this finding, the oil and fat composition of the present invention has been completed. In addition, in embodiment of this invention, A (numerical value) - B (numerical value) mean A or more and B or less.

<油脂組成物> <Oil composition>

以下,對本發明的加熱調理用油脂組成物進行詳細說明。 Hereinafter, the oil-fat composition for heat conditioning of this invention is demonstrated in detail.

(油脂) (grease)

本發明的油脂組成物於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸,該油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。 The oil and fat composition of the present invention contains 8% by mass to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57% by mass to 90% by mass of oleic acid in the constituent fatty acids of fats and oils, and the fats and oils only contain 6% by mass of carbon atoms. The triglyceride of the saturated fatty acid of ~10 is 2.5 mass % or less.

本發明中,藉由碳數6~10的飽和脂肪酸於油脂中存在一定量以上,可獲得營養效果。另外,若碳數6~10的飽和脂肪酸的含量變多,則起泡變得激烈。因此,碳數6~10的飽和脂肪酸於油脂的構成脂肪酸中含有8質量%~20質量%。更佳為含有10質量%~16質量%。 In the present invention, a nutritional effect can be obtained by the presence of a certain amount or more of saturated fatty acid having a carbon number of 6 to 10 in the oil. In addition, when the content of saturated fatty acids having 6 to 10 carbon atoms increases, foaming becomes intense. Therefore, the saturated fatty acid having 6 to 10 carbon atoms is contained in 8% by mass to 20% by mass in the constituent fatty acid of the fat and oil. More preferably, it contains 10 mass % - 16 mass %.

碳數6~10的飽和脂肪酸較佳為直鏈狀飽和脂肪酸,例如可列舉:己酸、辛酸、癸酸、月桂酸。該些可使用源自椰子油、棕櫚仁油的脂肪酸,且可單獨或組合而使用。例如可以例如辛酸/癸酸=80/20~0/100(質量比)、較佳為辛酸/癸酸=60/40~75/25(質量比)來使用。 The saturated fatty acid having 6 to 10 carbon atoms is preferably a linear saturated fatty acid, and examples thereof include caproic acid, caprylic acid, capric acid, and lauric acid. These may use fatty acids derived from coconut oil, palm kernel oil, and may be used alone or in combination. For example, caprylic acid/capric acid=80/20 to 0/100 (mass ratio), preferably caprylic acid/capric acid=60/40 to 75/25 (mass ratio), can be used.

本發明中,油酸於油脂中存在57質量%以上,藉此可抑制由含有碳數6~10的飽和脂肪酸而引起的起泡。油酸含量越高越抑制起泡,故較佳。若考慮可藉由市售而獲取的油酸的純度為98%~99%,於使用8質量%~20質量%的碳數6~10的飽和脂肪酸的情況下,則油酸的上限為90質量%。因此,油酸於油脂的構 成脂肪酸中較佳為57質量%~90質量%。更佳為60質量%~95質量%,進而佳為62質量%~75質量%。油酸最佳為於油脂的構成脂肪酸中含有65質量%~75質量%。油酸可使用源自油菜籽、大豆、向日葵、紅花、橄欖等高油酸品種的油酸。另外,可使用將低油酸含量的棕櫚脂肪酸分餾而製成高純度者等。 In the present invention, oleic acid is present in fats and oils in an amount of 57% by mass or more, whereby foaming caused by the saturated fatty acid containing 6 to 10 carbon atoms can be suppressed. The higher the content of oleic acid, the more suppressing foaming, and it is preferable. Considering that the purity of commercially available oleic acid is 98% to 99%, when 8% by mass to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms are used, the upper limit of oleic acid is 90%. quality%. Therefore, the structure of oleic acid in oils The content of the fatty acid is preferably 57% by mass to 90% by mass. More preferably, it is 60 mass % - 95 mass %, More preferably, it is 62 mass % - 75 mass %. The oleic acid is preferably contained in an amount of 65% by mass to 75% by mass in the constituent fatty acids of fats and oils. As the oleic acid, oleic acid derived from high oleic acid varieties such as rapeseed, soybean, sunflower, safflower, and olive can be used. In addition, a palm fatty acid with a low oleic acid content can be fractionated to obtain a high-purity one or the like.

本發明中,油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.5質量%以下。若僅包含碳數6~10的飽和脂肪酸的三甘油酯的量多於2.5質量%,則油炸時的起泡變得激烈,故欠佳。更佳為油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為2.0質量%以下,進而佳為1.6質量%以下,最佳為1.0質量%以下。 In the present invention, the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms in the oil and fat is 2.5% by mass or less. When the amount of triglycerides containing only saturated fatty acids having 6 to 10 carbon atoms exceeds 2.5 mass %, foaming during frying becomes intense, which is not preferable. More preferably, the triglyceride containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils is 2.0 mass % or less, more preferably 1.6 mass % or less, and most preferably 1.0 mass % or less.

本發明中,油脂中的僅包含碳數6~10的飽和脂肪酸的甘油酯以外的三甘油酯並無特別限定。例如,於使用後述的酯交換油脂或經酯化的油脂的情況下,構成脂肪酸中包含兩個碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為5質量%~25質量%,更佳為6質量%~15質量%。另外,構成脂肪酸中包含一個碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為20質量%~50質量%,更佳為成為25質量%~40質量%。另外,構成脂肪酸中不包含碳數6~10的飽和脂肪酸的三甘油酯的量較佳為成為30質量%~65質量%,更佳為成為45質量%~65質量%。再者,碳數6~10的飽和脂肪酸以外的構成脂肪酸較佳為存在於植物油中的碳數16~22的脂肪酸。 In the present invention, triglycerides other than glycerides containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils are not particularly limited. For example, in the case of using the later-described transesterified fats and oils or esterified fats and oils, the amount of the triglyceride containing two saturated fatty acids having 6 to 10 carbon atoms in the constituent fatty acids is preferably 5 to 25 mass % , more preferably 6% by mass to 15% by mass. In addition, the amount of triglyceride containing a saturated fatty acid having 6 to 10 carbon atoms in the constituent fatty acid is preferably 20 to 50 mass %, more preferably 25 to 40 mass %. In addition, the amount of triglyceride that does not contain saturated fatty acids having 6 to 10 carbon atoms in the fatty acid is preferably 30 to 65 mass %, more preferably 45 to 65 mass %. Further, the constituent fatty acids other than the saturated fatty acids having 6 to 10 carbon atoms are preferably those having 16 to 22 carbon atoms present in vegetable oils.

油脂的構成脂肪酸中含有8質量%~20質量%的碳數6 ~10的飽和脂肪酸以及57質量%~90質量%的油酸的油脂可自酯交換或酯化而獲得。因此,該些油脂較佳為酯交換油脂及/或經酯化的油脂。該些油脂較佳為於油脂組成物中含有50質量%~100質量%,更佳為80質量%~100質量%。最佳為於油脂組成物中含有95質量%~100質量%的該些油脂。再者,將來可期待使用藉由品種改良而獲得的由植物獲得的油脂來代替酯交換油脂及/或經酯化的油脂。 The constituent fatty acids of fats and oils contain 8 to 20 mass % of carbon number 6 Fats and oils of ~10% by mass of saturated fatty acids and 57% by mass to 90% by mass of oleic acid can be obtained from transesterification or esterification. Therefore, these fats and oils are preferably transesterified fats and oils and/or esterified fats and oils. These oils and fats are preferably contained in the oil and fat composition in an amount of 50% by mass to 100% by mass, more preferably 80% by mass to 100% by mass. These oils and fats are preferably contained in an amount of 95% by mass to 100% by mass in the oil and fat composition. In addition, in the future, it can be expected to use plant-derived fats and oils obtained by variety improvement in place of transesterified fats and oils and/or esterified fats and oils.

如所述般,本發明中作為於油脂的構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、70質量%~90質量%的油酸的油脂,可使用酯交換油脂及/或經酯化的油脂。作為除該些油脂以外調配的油脂,就不使油炸時的起泡惡化的方面而言,較佳為油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂。作為油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂,可列舉:大豆油、菜籽油、紅花油、玉米油、葵花油、芝麻油、橄欖油等植物油。油脂的構成脂肪酸中不包含碳數12以下的脂肪酸的油脂較佳為於油脂組成物中含有0質量%~50質量%。更佳為含有0質量%~20質量%,最佳為含有0質量%~5質量%。 As described above, in the present invention, transesterification can be used as the fat and oil containing 8% by mass to 20% by mass of saturated fatty acid having 6 to 10 carbon atoms and 70% by mass to 90% by mass of oleic acid in the constituent fatty acid of fat and oil. Grease and/or Esterified Grease. The fats and oils prepared other than these fats and oils are preferably those which do not contain fatty acids having 12 or less carbon atoms in the constituent fatty acids of the fats and oils from the viewpoint of not deteriorating foaming during frying. Examples of fats and oils that do not contain fatty acids having 12 or less carbon atoms in their constituent fatty acids include vegetable oils such as soybean oil, rapeseed oil, safflower oil, corn oil, sunflower oil, sesame oil, and olive oil. It is preferable to contain 0 mass % - 50 mass % in the oil-fat composition as for fats and oils that do not contain fatty acids having 12 or less carbon atoms in the constituent fatty acids of fats and oils. It is more preferable to contain 0 mass % - 20 mass %, and it is most preferable to contain 0 mass % - 5 mass %.

本發明中使用的油脂較佳為純化油脂。本發明的油脂可藉由純化來製造,所述純化是視榨油需要,經過脫膠步驟、脫酸步驟、脫色步驟,進而視需要經過脫蠟步驟後經過除臭步驟。所述脫膠步驟、脫酸步驟、及脫蠟步驟是根據可對應於提煉油之前的油料原料而變動的粗油的品質來適宜選擇。 The fats and oils used in the present invention are preferably purified fats and oils. The oil and fat of the present invention can be produced by purifying, according to the needs of oil extraction, going through a degumming step, a deacidifying step, a decolorizing step, and then a dewaxing step and then a deodorizing step as needed. The degumming step, the deacidification step, and the dewaxing step are appropriately selected according to the quality of the crude oil, which can vary in accordance with the oil feedstock before refining the oil.

(酯交換油脂) (Transesterified Grease)

本發明的油脂組成物可對選自碳數6~10的飽和脂肪酸的甘油酯、碳數6~10的飽和脂肪酸的低級醇酯、碳數6~10的飽和脂肪酸中的一種以上、以及油脂的構成脂肪酸為高油酸的油脂進行酯交換而獲得。或者可對選自油酸的低級醇酯、油酸中的一種以上、以及碳數6~10的飽和脂肪酸的甘油酯進行酯交換而獲得。 The oil and fat composition of the present invention can treat at least one selected from the group consisting of glycerides of saturated fatty acids having 6 to 10 carbon atoms, lower alcohol esters of saturated fatty acids having 6 to 10 carbon atoms, saturated fatty acids having 6 to 10 carbon atoms, and oils and fats. The constituent fatty acids are obtained by transesterification of oils and fats with high oleic acid. Alternatively, it can be obtained by transesterification of a lower alcohol ester of oleic acid, one or more selected from oleic acid, and a glyceride of a saturated fatty acid having 6 to 10 carbon atoms.

碳數6~10的飽和脂肪酸的甘油酯較佳為三甘油酯。例如可使用作為市售的中鏈脂肪酸三甘油酯而販賣者。 The glycerides of saturated fatty acids having 6 to 10 carbon atoms are preferably triglycerides. For example, a commercially available medium-chain fatty acid triglyceride can be used.

油脂的構成脂肪酸為高油酸的油脂較佳為構成脂肪酸中油酸為68質量%以上的油脂,更佳為構成脂肪酸中油酸為70質量%以上的油脂,進而佳為構成脂肪酸中油酸為75質量%以上的油脂,最佳為構成脂肪酸中油酸為80質量%以上的油脂。作為該些油脂,可使用高油酸菜籽油、高油酸葵花油、高油酸紅花油、橄欖油等。 Fats and oils whose constituent fatty acids are high oleic acid are preferably fats and oils whose constituent fatty acids are oleic acid in an amount of 68% by mass or more, more preferably those whose constituent fatty acids are oleic acid in an amount of 70% by mass or more, and more preferably 75% by mass of oleic acid in constituent fatty acids % or more of fats and oils, preferably fats and oils containing 80% by mass or more of oleic acid in the constituent fatty acids. As these oils and fats, high oleic acid rapeseed oil, high oleic acid sunflower oil, high oleic acid safflower oil, olive oil, etc. can be used.

另外,碳數6~10的飽和脂肪酸的低級醇酯、碳數6~10的飽和脂肪酸、油酸的低級醇酯、油酸可使用市售者。再者,就容易去除副產物的醇而言,低級醇酯的低級醇較佳為甲醇、乙醇、1-丙醇、2-丙醇等碳數1~3的低級醇。 In addition, commercially available ones can be used as lower alcohol esters of saturated fatty acids having 6 to 10 carbon atoms, saturated fatty acids having 6 to 10 carbon atoms, lower alcohol esters of oleic acid, and oleic acid. In addition, the lower alcohol of the lower alcohol ester is preferably a lower alcohol having 1 to 3 carbon atoms, such as methanol, ethanol, 1-propanol, and 2-propanol, in terms of an alcohol that can easily remove by-products.

本發明的油脂組成物為構成脂肪酸的68質量%以上為油酸的植物油、以及碳數6~10的飽和脂肪酸的三甘油酯的酯交換油脂時,在酯交換的過程中不會副產生低級醇或水分,故較佳。 When the oil and fat composition of the present invention is a transesterified oil and fat comprising a vegetable oil in which 68% by mass or more of fatty acids are oleic acid and a triglyceride of a saturated fatty acid having 6 to 10 carbon atoms, low-grade by-products are not produced during the transesterification process. Alcohol or moisture, so it is better.

酯交換可使用甲醇鈉之類的鹼觸媒或脂肪酶等酶來進 行。所使用的原料的比例是以最終的製造油脂於構成脂肪酸中含有8質量%~20質量%的碳數6~10的飽和脂肪酸、57質量%~90質量%的油酸的方式進行調整。 Transesterification can be carried out using alkali catalysts such as sodium methoxide or enzymes such as lipase. Row. The ratio of the raw material to be used is adjusted so that 8-20 mass % of saturated fatty acids having 6 to 10 carbon atoms and 57-90 mass % of oleic acid are contained in the final produced fat and oil in the constituent fatty acids.

例如,於進行將甲醇鈉作為觸媒的酯交換反應的情況下,混合原料,於100mmHg以下的減壓下且80℃~100℃下將混合物加熱,並去除原料混合物中所含的氣體成分及水分。向其中添加0.02質量%~0.5質量%的甲醇鈉,於常壓.氮氣流下或10mmHg以下的減壓下,在80℃~100℃下攪拌10分鐘~60分鐘,藉此進行酯交換反應。藉由利用氣相層析法測定反應產物的三甘油酯組成來確認反應的結束。藉由向反應產物中添加水或添加磷酸等酸來進行反應的停止。之後,進行充分的水洗以去除觸媒及過量的酸,於乾燥後利用常法對反應產物進行脫色、除臭。 For example, in the case of performing a transesterification reaction using sodium methoxide as a catalyst, the raw materials are mixed, and the mixture is heated at 80°C to 100°C under a reduced pressure of 100 mmHg or less to remove gas components and gas components contained in the raw material mixture. moisture. To which was added 0.02% by mass to 0.5% by mass of sodium methoxide, at normal pressure. The transesterification reaction is performed by stirring at 80° C. to 100° C. for 10 minutes to 60 minutes under a nitrogen stream or under a reduced pressure of 10 mmHg or less. The completion of the reaction was confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction is stopped by adding water or an acid such as phosphoric acid to the reaction product. After that, sufficient water washing was performed to remove the catalyst and excess acid, and after drying, the reaction product was decolorized and deodorized by an ordinary method.

於使用脂肪酶進行酯交換反應的情況下,混合原料並調整溫度至脂肪酶的活性可充分地發揮的反應溫度即40℃~100℃的範圍。之後,相對於原料混合物而以0.005質量%~10質量%的比例添加脂肪酶,以2小時~48小時的範圍進行酯交換反應。該反應理想的是於常壓下在氮氣流中進行。藉由利用氣相層析法測定反應產物的三甘油酯組成來確認反應的結束。藉由利用過濾將酶去除來進行反應的停止。反應產物是於水洗、乾燥後利用常法來進行脫色、除臭。再者,於使用中鏈脂肪酸的情況下,於反應停止後利用薄膜式蒸發器來預先去除游離脂肪酸。 In the case of performing the transesterification reaction using lipase, the raw materials are mixed and the temperature is adjusted within the range of 40°C to 100°C, which is a reaction temperature at which the activity of the lipase can be sufficiently exhibited. Then, lipase is added in a ratio of 0.005 mass % to 10 mass % with respect to the raw material mixture, and the transesterification reaction is performed in the range of 2 hours to 48 hours. The reaction is ideally carried out under normal pressure in a nitrogen stream. The completion of the reaction was confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction was stopped by removing the enzyme by filtration. The reaction product is decolorized and deodorized by a conventional method after washing with water and drying. In addition, when a medium chain fatty acid is used, the free fatty acid is removed in advance by a thin-film evaporator after the reaction is stopped.

若使用脂肪酶的酯交換反應不充分,則於分子內具有三個中 鏈脂肪酸殘基的三甘油酯的比例變多。於分子內具有三個中鏈脂肪酸殘基的三甘油酯的比例多的油脂組成物於連續的油炸調理時,冒煙或起泡變得激烈,故欠佳。 If the transesterification reaction using lipase is insufficient, there are three molecules in the molecule. The ratio of triglycerides of chain fatty acid residues increases. An oil and fat composition having a large proportion of triglycerides having three medium-chain fatty acid residues in the molecule is not preferable because smoking or foaming becomes intense during continuous frying.

作為脂肪酶,可列舉源自產鹼菌(alcaligenes)屬、念珠菌屬、根黴菌(rhizopus)屬、毛黴菌(mucor)屬或假單胞菌(pseudomonas)屬的脂肪酶,或源自肝臟的磷脂酶A等,特佳為源自念珠菌屬或根黴菌屬的脂肪酶。 Examples of the lipase include those derived from the genus Alcaligenes, Candida, Rhizopus, Mucor, or Pseudomonas, or those derived from liver phospholipase A, etc., particularly preferably a lipase derived from Candida or Rhizopus.

(經酯化的油脂) (esterified fats and oils)

本發明的油脂組成物可混合碳數6~10的飽和脂肪酸、油酸、甘油,並藉由無觸媒或鹼中的利用加熱的酯化、或者利用脂肪酶的酯化而獲得。於酯化反應中,副產生水分,為了推進反應而需要去除水分,因此較佳為利用加熱的酯化。所使用的原料的比例是以最終的製造油脂於構成脂肪酸中使碳數6~10的飽和脂肪酸成為8質量%~20質量%、使油酸成為57質量%~90質量%的方式進行調整。 The oil-fat composition of the present invention can be obtained by mixing saturated fatty acids having 6 to 10 carbon atoms, oleic acid, and glycerin, and by esterification by heating without catalyst or in alkali, or by esterification by lipase. In the esterification reaction, water is by-produced, and it is necessary to remove water in order to advance the reaction, so esterification by heating is preferable. The ratio of the raw material used is adjusted so that the saturated fatty acid of carbon number 6-10 may become 8-20 mass %, and the oleic acid may become 57-90 mass % in the constituent fatty acid of the final produced fats and oils.

例如,於無觸媒下進行酯化反應的情況下,混合原料,並於常溫或者100mmHg以下的減壓下將混合物加熱至200℃以上,使其進行3小時~20小時酯化。此時,就防止著色的方面而言,較佳為於氮氣流下進行。藉由利用酸價測定游離脂肪酸量來確認反應的結束。利用常法來對反應產物進行脫酸、脫色、除臭。再者,於殘存脂肪酸多的情況下,較佳為自反應產物利用薄膜式蒸發器等來預先去除脂肪酸。 For example, in the case of performing the esterification reaction without a catalyst, the raw materials are mixed, and the mixture is heated to 200° C. or higher at normal temperature or under a reduced pressure of 100 mmHg or less, and the esterification is performed for 3 to 20 hours. At this time, it is preferable to carry out under a nitrogen gas flow from the viewpoint of preventing coloration. The completion of the reaction was confirmed by measuring the amount of free fatty acid using the acid value. The reaction product is deacidified, decolorized and deodorized by conventional methods. Furthermore, when there are many remaining fatty acids, it is preferable to remove fatty acids from the reaction product in advance by a thin film evaporator or the like.

於使用脂肪酶進行酯化反應的情況下,混合原料並調整溫度至脂肪酶的活性可充分地發揮的反應溫度即40℃~100℃的範圍。之後,相對於原料混合物而以0.005質量%~10質量%的比例添加脂肪酶,以5小時~200小時的範圍進行酯化反應。該反應理想的是於常壓下在氮氣流中、或微減壓下進行。藉由利用酸價測定游離脂肪酸量來確認反應的結束。藉由利用過濾將酶去除來進行反應的停止。反應產物是於水洗、乾燥後利用常法來進行脫酸、脫色、除臭。再者,於殘存脂肪酸多的情況下,較佳為自反應產物利用薄膜式蒸發器等來預先去除脂肪酸。 In the case of performing the esterification reaction using lipase, the raw materials are mixed and the temperature is adjusted within the range of 40°C to 100°C, which is a reaction temperature at which the activity of the lipase can be sufficiently exhibited. Then, lipase is added in a ratio of 0.005 mass % to 10 mass % with respect to the raw material mixture, and the esterification reaction is performed in the range of 5 hours to 200 hours. The reaction is desirably carried out under normal pressure in a nitrogen stream, or under slightly reduced pressure. The completion of the reaction was confirmed by measuring the amount of free fatty acid using the acid value. The reaction was stopped by removing the enzyme by filtration. The reaction product is deacidified, decolorized and deodorized by conventional methods after washing with water and drying. Furthermore, when there are many remaining fatty acids, it is preferable to remove fatty acids from the reaction product in advance by a thin film evaporator or the like.

作為脂肪酶,可列舉源自產鹼菌屬、念珠菌屬、根黴菌屬、毛黴菌屬或假單胞菌屬的脂肪酶,或源自肝臟的磷脂酶A等,特佳為源自念珠菌屬或根黴菌屬的脂肪酶。 Examples of the lipase include lipases derived from Alcaligenes, Candida, Rhizopus, Mucor, or Pseudomonas, and phospholipase A derived from liver, among which Candida is particularly preferred. Lipases of the genus Rhizopus or Rhizopus.

(其他成分) (other ingredients)

於不損及本發明的效果的程度內,可向本發明的油脂組成物中加入油脂以外的成分。該些成分例如是用於一般的油脂中的成分(食品添加物等)。作為該些成分,例如可列舉:抗氧化劑、乳化劑、矽酮油、結晶調整劑、口感改良劑等,較佳為於除臭後且填充前添加。 Components other than oils and fats may be added to the oil and fat composition of the present invention to the extent that the effects of the present invention are not impaired. These components are, for example, components (food additives, etc.) used in general oils and fats. As these components, an antioxidant, an emulsifier, a silicone oil, a crystallizing agent, a texture improving agent, etc. are mentioned, for example, It is preferable to add after deodorization and before filling.

作為抗氧化劑,例如可列舉:生育酚類、抗壞血酸類、黃酮衍生物、麴酸、沒食子酸衍生物、兒茶素及其酯、蜂鬥菜酸、棉酚(gossypol)、芝麻酚(sesamol)、萜烯類等。 Examples of antioxidants include tocopherols, ascorbic acids, flavonoid derivatives, koji acid, gallic acid derivatives, catechins and their esters, butterbur, gossypol, sesamol ( sesamol), terpenes, etc.

作為乳化劑,可列舉:蔗糖脂肪酸酯、聚甘油脂肪酸酯、 有機酸單甘油酯、單甘油酯、二甘油酯、山梨糖醇脂肪酸酯、山梨糖醇酐脂肪酸酯、聚山梨醇酯、丙二醇脂肪酸酯、卵磷脂等。藉由含有一部分乳化劑,可進一步提高油炸適應性、特別是起泡抑制。但是,藉由含有乳化劑,產生蛋黃醬的黏度下降的問題,因此乳化劑添加較佳為少量或不添加。例如,於進行添加的本發明中可選擇所述乳化劑的至少一種,對油脂組成物的添加量較佳為以乳化劑整體計而未滿0.5質量%,進而佳為0.01質量%~0.2質量%。最佳為不含有乳化劑。 As emulsifiers, sucrose fatty acid esters, polyglycerol fatty acid esters, Organic acid monoglyceride, monoglyceride, diglyceride, sorbitan fatty acid ester, sorbitan fatty acid ester, polysorbate, propylene glycol fatty acid ester, lecithin, etc. By containing a part of an emulsifier, frying suitability, especially foaming suppression can be improved further. However, when an emulsifier is contained, there arises a problem that the viscosity of the mayonnaise decreases, so it is preferable to add the emulsifier in a small amount or not at all. For example, in the present invention to be added, at least one of the emulsifiers may be selected, and the addition amount to the oil and fat composition is preferably less than 0.5% by mass in terms of the entire emulsifier, more preferably 0.01% by mass to 0.2% by mass %. Preferably, it does not contain emulsifiers.

作為矽酮油,可使用於食品用途中市售者,並無特別限定,例如可列舉具有二甲基聚矽氧烷結構且動態黏度於25℃下為800mm2/s~5000mm2/s者。矽酮油的動態黏度特佳為800mm2/s~2000mm2/s,進而佳為900mm2/s~1100mm2/s。此處,所謂「動態黏度」,設為是指依據JIS K 2283(2000)而測定的值。關於矽酮油,除矽酮油以外亦可包含微粒子二氧化矽。 The silicone oil that can be used in food applications and marketed is not particularly limited, and examples include those having a dimethylpolysiloxane structure and a dynamic viscosity of 800 mm 2 /s to 5000 mm 2 /s at 25° C. . The dynamic viscosity of the silicone oil is particularly preferably 800 mm 2 /s to 2000 mm 2 /s, and more preferably 900 mm 2 /s to 1100 mm 2 /s. Here, the "dynamic viscosity" refers to a value measured in accordance with JIS K 2283 (2000). Regarding the silicone oil, fine particle silica may be contained in addition to the silicone oil.

<油脂組成物的用途> <Use of oil and fat composition>

本發明的加熱調理用油脂組成物可用於所有的加熱調理用途,但油炸時的起泡得到抑制,故適於油炸用途。另外,乳化劑的添加為少量或未添加的油脂組成物適於油炸用途及蛋黃醬用途。 The oil and fat composition for heating and conditioning of the present invention can be used for all heating and conditioning applications, but is suitable for frying because foaming during frying is suppressed. In addition, the oil and fat composition in which the emulsifier is added in a small amount or not is suitable for frying and mayonnaise.

<脂肪酸及三甘油酯的分析> <Analysis of fatty acids and triglycerides>

本發明中,構成油脂的脂肪酸的分析可依照美國油脂化學協會(The American Oil Chemists Society,AOCS)官方方法(Official Method)Ce 1f-96並利用氣相層析法來測定。油脂中的三甘油酯量可依照氣相層析法(JAOCS,Vol.70,no.11,1111-1114)(1993)來測定。 In the present invention, the analysis of fatty acids constituting oils and fats can be performed in accordance with the official method (Official Method of The American Oil Chemists Society, AOCS). Method) Ce 1f-96 and measured by gas chromatography. The amount of triglycerides in fats and oils can be measured according to gas chromatography (JAOCS, Vol. 70, no. 11, 1111-1114) (1993).

[實施例] [Example]

以下,基於實施例來對本發明進行具體說明,但本發明並不限定於該些實施例。 Hereinafter, the present invention will be specifically described based on examples, but the present invention is not limited to these examples.

(實施例1:樣品製備) (Example 1: Sample Preparation)

按照表1的配方(質量比例)混合HOLL菜籽脫色油(高油酸菜籽脫色油構成脂肪酸中的油酸:73.4質量%日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、構成脂肪酸以質量比計為辛酸:癸酸=75:25的MCT(中鏈脂肪酸三甘油酯日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)。相對於該混合物100質量份而添加0.3質量份的脂肪酶QLM(名糖產業股份有限公司製造),於攪拌下以45℃進行16小時酯交換反應。自反應產物過濾分離酶,對濾液進行脫酸、脫色、除臭(250℃、3托(Torr)、60分鐘)而獲得組成物(實施例1)。 According to the formula (mass ratio) in Table 1, HOLL rapeseed decolorized oil (high oleic acid rapeseed decolorized oil constitutes oleic acid in fatty acids: 73.4% by mass, manufactured by Nisshin OilliO Group Co., Ltd.), The constituent fatty acid was MCT (Medium Chain Fatty Acid Triglyceride Nisshin OilliO Group Co., Ltd. product) of caprylic acid:capric acid=75:25 in mass ratio. 0.3 mass part of lipase QLM (made by Meisu Sangyo Co., Ltd.) was added with respect to 100 mass parts of this mixture, and the transesterification reaction was performed at 45 degreeC with stirring for 16 hours. The enzyme was separated from the reaction product by filtration, and the filtrate was subjected to deacidification, decolorization, and deodorization (250° C., 3 Torr, 60 minutes) to obtain a composition (Example 1).

組成物的碳數6~10的飽和脂肪酸為13.7%,油酸為63.1%。另外,油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯為1.5質量%,包含兩個碳數6~10的飽和脂肪酸的三甘油酯的量為10.8質量%,構成脂肪酸中包含一個碳數6~10的飽和脂肪酸的三甘油酯的量為37.8質量%。 The saturated fatty acid having 6 to 10 carbon atoms in the composition was 13.7%, and the oleic acid was 63.1%. In addition, the amount of triglycerides containing only saturated fatty acids having 6 to 10 carbon atoms in the fats and oils was 1.5% by mass, the amount of triglycerides containing two saturated fatty acids having 6 to 10 carbon atoms was 10.8% by mass, and the constituent fatty acids contained The amount of triglyceride of saturated fatty acid having 6 to 10 carbon atoms was 37.8 mass %.

(實施例2~實施例5、比較例1:樣品製備) (Examples 2 to 5, Comparative Example 1: sample preparation)

按照表1的配方(質量比例)混合菜籽脫色油(構成脂肪酸中的油酸:61.4質量%、日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、HOLL菜籽脫色油(高油酸菜籽脫色油構成脂肪酸中的油酸:73.4質量%日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、高油酸葵花脫色油(構成脂肪酸中的油酸:81.8質量%、日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)、構成脂肪酸以質量比計為辛酸:癸酸=75:25的MCT(中鏈脂肪酸三甘油酯日清奧利友集團(Nisshin OilliO Group)股份有限公司製造)。相對於該混合物100質量份而添加0.3質量份的脂肪酶QLM(名糖產業股份有限公司製造),於攪拌下以45℃進行16小時酯交換反應。自反應產物過濾分離酶,對濾液進行脫酸、脫色、除臭(250℃、3Torr、60分鐘)而獲得組成物(實施例2~實施例5、比較例1)。 Rapeseed decolorized oil (oleic acid in constituent fatty acids: 61.4 mass %, manufactured by Nisshin OilliO Group Co., Ltd.), HOLL rapeseed decolorized oil (high Oleic acid in rapeseed decolorized oil constituting fatty acid: 73.4% by mass Nisshin OilliO Group Co., Ltd.), high oleic sunflower decolorized oil (oleic acid in constituting fatty acid: 81.8% by mass , manufactured by Nisshin OilliO Group Co., Ltd.), MCT (Medium Chain Fatty Acid Triglyceride Nisshin OilliO Group (Nisshin OilliO Group) in which the constituent fatty acids are caprylic acid: capric acid = 75:25 in mass ratio OilliO Group) Co., Ltd.). 0.3 mass part of lipase QLM (made by Meisu Sangyo Co., Ltd.) was added with respect to 100 mass parts of this mixture, and the transesterification reaction was performed at 45 degreeC with stirring for 16 hours. The enzyme was separated from the reaction product by filtration, and the filtrate was deacidified, decolorized, and deodorized (250° C., 3 Torr, 60 minutes) to obtain compositions (Examples 2 to 5, Comparative Example 1).

(分析) (analyze)

油脂的脂肪酸的分析是依照AOCS Ce 1f-96並利用氣相層析法來測定。油脂中的僅包含碳數6~10的飽和脂肪酸的三甘油酯量是依照氣相層析法(JAOCS,vol.70,11,1111-1114)(1993)來測定。 The fatty acid analysis of fats and oils was measured by gas chromatography in accordance with AOCS Ce 1f-96. The amount of triglycerides containing only saturated fatty acids having 6 to 10 carbon atoms in fats and oils is measured in accordance with gas chromatography (JAOCS, vol. 70, 11, 1111-1114) (1993).

將組成物(比較例1、實施例1~實施例5)的分析值[油脂的構成脂肪酸中的碳數6~10的飽和脂肪酸量(質量比例)、油脂的構成脂肪酸中的油酸量(質量比例)、僅包含碳數6~10的飽和脂肪酸的三甘油酯量(質量比例)]示於表1中。 The analytical values of the compositions (Comparative Example 1, Examples 1 to 5) [the amount of saturated fatty acids with 6 to 10 carbon atoms (mass ratio) in the constituent fatty acids of fats and oils, the amount of oleic acid in the constituent fatty acids of fats and oils ( mass ratio) and the triglyceride amount (mass ratio) containing only saturated fatty acids having 6 to 10 carbon atoms] are shown in Table 1.

Figure 107124062-A0305-02-0015-1
Figure 107124062-A0305-02-0015-1

(油炸時的起泡試驗) (Foam test during frying)

將20ml的油脂組成物(比較例1、實施例1~實施例5)放入試驗管(內徑28mm)中,並加熱至160℃。將土豆片(立方體1cm×1cm×1cm)放入油脂組成物中,測定所產生的氣泡的最高達到距離。 20 ml of oil and fat compositions (Comparative Example 1, Examples 1 to 5) were placed in a test tube (inner diameter of 28 mm), and heated to 160°C. Potato chips (cube 1 cm×1 cm×1 cm) were put into the oil and fat composition, and the maximum reaching distance of the generated air bubbles was measured.

另外,於比較例1中添加0.8質量%的蔗糖脂肪酸酯(料陶蔗糖酯(Ryoto Sugar Ester)O-170三菱化學食品股份有限公司製造),從而製備參考例1的油脂組成物。參考例1中亦同樣地測定氣泡的最高達到距離。 Moreover, 0.8 mass % of sucrose fatty acid ester (Ryoto Sugar Ester O-170 Mitsubishi Chemical Foods Co., Ltd. make) was added to the comparative example 1, and the oil-fat composition of the reference example 1 was prepared. Also in Reference Example 1, the maximum reaching distance of the bubbles was measured in the same manner.

另外,若進行油炸,則磷脂質等自油炸調理品中溶出,起泡變得厲害。因此,向油脂組成物(比較例1、實施例1~實施例5、參考例1)中添加200ppm(質量比例)的卵磷脂(日清奧利友集 團(Nisshin OilliO Group)股份有限公司製造),如所述般測定所產生的氣泡的最高達到距離。 In addition, when deep-frying is performed, phospholipids and the like are eluted from the deep-fried preparation, and foaming becomes severe. Therefore, 200 ppm (mass ratio) of lecithin (Nissin Oliver Collection) was added to the oil and fat compositions (Comparative Example 1, Examples 1 to 5, and Reference Example 1). A group (manufactured by Nisshin OilliO Group Co., Ltd.), and the maximum reaching distance of the generated bubbles was measured as described above.

測定是進行各三次,並將起泡(氣泡的最高達到距離的平均值)示於表2中。 The measurement was performed three times each, and the bubbling (the average value of the highest reaching distance of the bubbles) is shown in Table 2.

Figure 107124062-A0305-02-0016-2
Figure 107124062-A0305-02-0016-2

如表2所示般,可確認到實施例1~實施例5中起泡均良好,特別是即便於磷脂質等自油炸調理品中溶出而起泡變得激烈的情況下,亦可充分地抑制起泡。 As shown in Table 2, it was confirmed that foaming was good in all of Examples 1 to 5, and even when foaming became intense due to elution of phospholipids and the like from the fried prepared product, sufficient foaming was obtained. to suppress foaming.

(蛋黃醬評價) (Mayonnaise Evaluation)

蛋黃醬是利用下述的方法來製作。 Mayonnaise was produced by the following method.

向食物加工器中放入3個雞蛋、45g的米醋、5g的鹽、2g的芥末、2g的砂糖、少量的胡椒並攪拌10秒鐘。繼而,一面持續攪拌一面逐次少量加入360g的實施例1~實施例5、比較例1的油脂組成物。將油脂組成物加入完成後,進而攪拌約3分鐘,並確認蛋黃醬的保形性。將所述結果示於表3中。 Put 3 eggs, 45g rice vinegar, 5g salt, 2g mustard, 2g sugar, a pinch of pepper into a food processor and blend for 10 seconds. Next, 360 g of the oil and fat compositions of Examples 1 to 5, and Comparative Example 1 were gradually added in small amounts while continuing to stir. After the addition of the oil and fat composition was completed, the mixture was further stirred for about 3 minutes, and the shape retention of the mayonnaise was confirmed. The results are shown in Table 3.

Figure 107124062-A0305-02-0016-3
Figure 107124062-A0305-02-0016-3
Figure 107124062-A0305-02-0017-4
Figure 107124062-A0305-02-0017-4

根據表2、表3,比較例1中起泡厲害,若於比較例1中添加蔗糖脂肪酸酯,則可改善起泡,但蛋黃醬的保形性變差。另一方面,實施例1~實施例5中起泡亦良好,蛋黃醬的保形性亦良好。 According to Tables 2 and 3, the foaming was strong in Comparative Example 1, and when sucrose fatty acid ester was added to Comparative Example 1, the foaming was improved, but the shape retention of mayonnaise was deteriorated. On the other hand, in Examples 1 to 5, foaming was also good, and the shape retention of mayonnaise was also good.

Claims (5)

一種油脂組成物,其於油脂的構成脂肪酸中包含8質量%~20質量%的碳數6~10的飽和脂肪酸、以及57質量%~90質量%的油酸,所述油脂包含的三甘油酯為2.5質量%以下,所述三甘油酯僅由碳數6~10的飽和脂肪酸構成。 An oil and fat composition comprising 8% by mass to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 57% by mass to 90% by mass of oleic acid in constituent fatty acids of fats and oils, wherein the triglycerides contained in the fats and oils It is 2.5 mass % or less, and the said triglyceride consists only of C6-C10 saturated fatty acid. 如申請專利範圍第1項所述的油脂組成物,其中油脂的構成脂肪酸中包含8質量%~20質量%的碳數6~10的飽和脂肪酸、以及70質量%~90質量%的油酸,所述油脂為酯交換油脂及/或經酯化的油脂,並於油脂組成物中含有50質量%~100質量%的所述油脂。 The oil and fat composition according to claim 1, wherein the constituent fatty acids of the oil and fat comprise 8% to 20% by mass of saturated fatty acids having 6 to 10 carbon atoms and 70% by mass to 90% by mass of oleic acid, The fats and oils are transesterified fats and oils and/or esterified fats and oils, and contain 50% by mass to 100% by mass of the fats and oils in the oil and fat composition. 如申請專利範圍第1項或第2項所述的油脂組成物,其中所述油脂為植物油與三甘油酯的酯交換油脂,所述植物油的構成脂肪酸包含68質量%以上的油酸,所述三甘油酯為碳數6~10的飽和脂肪酸。 The oil and fat composition according to claim 1 or claim 2, wherein the oil and fat is a transesterified oil and fat of vegetable oil and triglyceride, the constituent fatty acid of the vegetable oil contains 68% by mass or more of oleic acid, and the Triglycerides are saturated fatty acids with 6 to 10 carbon atoms. 如申請專利範圍第1項或第2項所述的油脂組成物,其中所述油脂組成物不包含乳化劑。 The oil and fat composition according to claim 1 or claim 2, wherein the oil and fat composition does not contain an emulsifier. 如申請專利範圍第1項或第2項所述的油脂組成物,其中所述油脂組成物為選自油炸用途與蛋黃醬用途中的用途。 The oil and fat composition according to claim 1 or claim 2, wherein the oil and fat composition is a use selected from a frying application and a mayonnaise application.
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