TW201835704A - Apparatus for connecting a plurality of containers to a single outlet - Google Patents
Apparatus for connecting a plurality of containers to a single outlet Download PDFInfo
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- TW201835704A TW201835704A TW107101741A TW107101741A TW201835704A TW 201835704 A TW201835704 A TW 201835704A TW 107101741 A TW107101741 A TW 107101741A TW 107101741 A TW107101741 A TW 107101741A TW 201835704 A TW201835704 A TW 201835704A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/008—Feed or outlet control devices
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2204/00—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices
- B01J2204/005—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices the outlet side being of particular interest
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/1628—Controlling the pressure
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/1642—Controlling the product
- C01B2203/1647—Controlling the amount of the product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
Abstract
Description
本發明係關於用於連接數個容器至一單一出口的裝置,特別是用於連接數個加壓容器至一單一出口的裝置。為了本發明的目的,術語“容器”包含一用於產生在一化學反應中使用之氣體的反應器。 The present invention relates to a device for connecting several containers to a single outlet, and more particularly to a device for connecting several pressurized containers to a single outlet. For the purposes of the present invention, the term "container" includes a reactor for generating a gas for use in a chemical reaction.
在許多領域的多種作業中需要依賴氣體或液化氣體,以用於諸如化學反應、焊接作業,特別是在近期的燃料電池中。 Gas or liquefied gas is required for a variety of operations in many fields for applications such as chemical reactions, welding, especially in recent fuel cells.
許多這類作業需要氣體,當所需氣體不是在廠內製造時,則需要施加高壓,這也是目前普遍的情況。使用廠外製造氣體的主要問題是,當壓縮氣體至一定程度所需的壓力越高時,用於容納該壓縮氣體的容器也必須更強。因此,對於像氫氣這樣重量輕的氣體,用於容納該氣體的氣筒的重量對所容納氣體的重量的比例為使得在一標準氣筒中的氣體量不超過裝滿的氣筒的總重量的5%。這表示在需要長時間使用單一標準氣筒的作業中,例如將氫氣做為燃料供給一燃料電池,在氣筒需要被轉換時,停機時間將會太長。 Many of these operations require gas, and when the required gas is not manufactured in the factory, high pressures need to be applied, which is currently the case. The main problem with using off-site manufacturing gases is that when the pressure required to compress the gas to a certain level is higher, the container used to hold the compressed gas must also be stronger. Therefore, for a light weight gas such as hydrogen, the ratio of the weight of the gas cylinder to the gas contained therein is such that the amount of gas in a standard gas cylinder does not exceed 5% of the total weight of the filled gas cylinder . This means that in operations that require a single standard gas cylinder for a long period of time, such as supplying hydrogen to a fuel cell as a fuel, the downtime will be too long when the gas cylinder needs to be switched.
另人驚訝的是,到目前為止,似乎仍無人想出此一問題的解決方法,且大部分系統倚賴平行排列的容器。這表示流體供應系統變的更加龐大,且帶有易燃流體也在更換氣筒時增加爆炸的風險。 Surprisingly, so far no one seems to have come up with a solution to this problem, and most systems rely on containers arranged in parallel. This means that the fluid supply system has become larger, and flammable fluids also increase the risk of explosion when replacing the gas cylinder.
本發明提供前述問題的一種解決方法,係藉由提供一配置,該配置中的數個容器可被連接到一單一出口,通過該出口,氣體能單獨或同時從每個容器排出。 The present invention provides a solution to the foregoing problem by providing a configuration in which several containers can be connected to a single outlet through which gas can be discharged from each container individually or simultaneously.
依據本發明,提供一種用於連接數個容器至一單一出口的裝置,其包括複數個連接器,每一個容器對應該複數個連接器中的一者,供連接該容器至一進料管,以及一複式連接器,供連接所有的進料管至一單一歧管,其中每一個進料管係與其自身用於測定在其所連接的該容器中的壓力之手段和用於控制在該歧管中的壓力之壓力調節器手段結合。 According to the present invention, a device for connecting a plurality of containers to a single outlet is provided. The device includes a plurality of connectors, and each container corresponds to one of the plurality of connectors for connecting the container to a feeding tube. And a duplex connector for connecting all feed pipes to a single manifold, each of which is connected with its own means for measuring the pressure in the container to which it is connected and for controlling the The pressure in the tube is combined by means of a pressure regulator.
當所述容器為簡單的流體容器時,所述裝置較佳具有用於確保在每個進料管中的壓力為大致相同之手段。 When the container is a simple fluid container, the device preferably has means for ensuring that the pressure in each feed tube is approximately the same.
所述用於測定壓力之手段較佳為電子壓力計,而所述壓力調節器手段較佳為與一中央控制單元結合之電子閥,該中央控制單元較佳為一用於控制該電子閥的運作及其他電子特性之微控制器。 The means for measuring the pressure is preferably an electronic pressure gauge, and the pressure regulator means is preferably an electronic valve combined with a central control unit, and the central control unit is preferably an electronic valve for controlling the electronic valve. Microcontroller for operation and other electronic characteristics.
所述裝置亦較佳具有用於檢測並隔離任何變空或多餘的容器之手段,使得該容器能被置換而無需關閉整個系統。 The device also preferably has means for detecting and isolating any empty or excess containers so that the containers can be replaced without having to shut down the entire system.
當所述容器為用於產生供燃料電池應用的氫氣之反應器時,所述裝置特別有用,因其提供系統設計者許多尚不可得的選項。所 述裝置將允許例如較高的燃料儲存容量而不使增加儲存重量的負擔加大,並將減少或消除任何常見於加壓氫氣系統的爆炸的風險。 The device is particularly useful when the vessel is a reactor for generating hydrogen for fuel cell applications, as it provides many options not yet available to system designers. The device will allow, for example, higher fuel storage capacity without increasing the burden of increasing stored weight, and will reduce or eliminate the risk of any explosions commonly found in pressurized hydrogen systems.
在這個例子中,所述容器為複數個單個氫氣產生器,其具有用於控制從每個氫氣產生器通過所述歧管到燃料電池的壓力及氣體流動的閥手段,且該閥手段較佳為調節器。氫氣產生器係與連接於燃料電池的歧管連接。一中央控制單元係用於決定在氫氣產生器叢集中的多個氣閥何時該被開啟和關閉,且優選地亦可用於指示各個氣體調節器在作業壓力中和氫氣流入每個燃料電池的流速中以及在該燃料電池運作中確保效率峰值的其他必要參數中產生任何必要的改變。 In this example, the container is a plurality of single hydrogen generators having valve means for controlling the pressure and gas flow from each hydrogen generator through the manifold to the fuel cell, and the valve means is preferably For the regulator. The hydrogen generator is connected to a manifold connected to a fuel cell. A central control unit is used to determine when multiple gas valves in the hydrogen generator cluster should be opened and closed, and preferably also used to indicate the gas regulators at operating pressure and the flow rate of hydrogen into each fuel cell Any necessary changes in the fuel cell operation and other necessary parameters to ensure efficiency peaks.
優選地,所述中央控制單元亦可用於檢測是否有任何氫氣產生器的運作是不規律的,尤其是且危險的,並關閉該檢測出的氫氣產生器,而不影響剩下的氫氣產生器產生氫氣,以使供應燃料到燃料電池不被中斷。 Preferably, the central control unit can also be used to detect whether any hydrogen generator is operating irregularly, especially and dangerously, and shut down the detected hydrogen generator without affecting the remaining hydrogen generators. Hydrogen is generated so that the supply of fuel to the fuel cell is not interrupted.
對氫氣產生器的供水可以多種方式安排,例如,可以一個以多管連接氫氣產生器的單一大容器的形式,或由多個較小的容器組成,每個容器對應一個氫氣產生器。對一個靜態燃料電池,甚至能從一水的主管路直接以管輸送。 The water supply to the hydrogen generator can be arranged in various ways, for example, it can be in the form of a single large container connected to the hydrogen generator with multiple pipes, or it can be composed of multiple smaller containers, each container corresponding to a hydrogen generator. For a static fuel cell, it can even be piped directly from a water main.
在其他有利的功能中,本發明之氫氣產生器能在低於目前常態使用的壓力下儲存所產生的氫氣,以直接供應氫氣給燃料電池,例如,產生電能以供電給電動車的傳動系統。對此類電動車,也可配置成延距式(range extender)電力系統。 Among other advantageous functions, the hydrogen generator of the present invention can store the generated hydrogen at a pressure lower than the current normal use to directly supply hydrogen to a fuel cell, for example, to generate electricity to power an electric vehicle drive system. This type of electric vehicle can also be configured as a range extender power system.
2‧‧‧水容器 2‧‧‧ water container
3‧‧‧控制單元 3‧‧‧control unit
4‧‧‧泵 4‧‧‧ pump
5‧‧‧反應器 5‧‧‧ Reactor
6‧‧‧氣閥 6‧‧‧Air valve
7‧‧‧燃料電池系統 7‧‧‧ fuel cell system
8‧‧‧水加熱器 8‧‧‧ water heater
9‧‧‧中央控制單元 9‧‧‧ Central Control Unit
10‧‧‧氣體歧管 10‧‧‧ Gas Manifold
11‧‧‧氣體調節器 11‧‧‧Gas Regulator
12‧‧‧外殼 12‧‧‧ shell
13‧‧‧水源 13‧‧‧ Water source
14‧‧‧出口 14‧‧‧ exit
15‧‧‧閥 15‧‧‧ valve
16‧‧‧燃料匣 16‧‧‧ fuel tank
17‧‧‧結構 17‧‧‧ Structure
18‧‧‧泵 18‧‧‧ pump
19‧‧‧加熱器 19‧‧‧ heater
第1圖顯示依據先前技術之氫氣產生器的一種形式之方塊圖;第2圖顯示如第1圖所示之氫氣產生器的一叢集的一種配置之方塊圖;第3圖顯示如第2圖所示之氫氣產生器的一變體之方塊圖;第4圖顯示用於第2圖或第3圖之氫氣產生器的一氫氣產生器之改良隔室叢集燃料防護桶之示意圖。 Fig. 1 shows a block diagram of a form of a hydrogen generator according to the prior art; Fig. 2 shows a block diagram of a cluster and a configuration of the hydrogen generator shown in Fig. 1; Fig. 3 shows a diagram of Fig. 2 A block diagram of a variant of the hydrogen generator shown; Figure 4 shows a schematic diagram of a modified hydrogen-generating compartment cluster fuel protection barrel for the hydrogen generator of Figure 2 or Figure 3.
如第1圖所示,一種用於提供氫氣到一氫氣燃料電池系統之昔知單一氫氣產生器,其包括通過管路與一泵4連接的一水容器2。泵4從水容器2輸送水,作為用於將一氫化物燃料轉換為氫氣的液態反應物。在反應器5中,由所述反應產生的氫氣被儲存在反應器5中。氣閥6控制氫氣釋放到燃料電池系統7中。所有的程序由一控制單元3監測及控制,控制單元3從所述系統的每一個構件接收訊號並傳送訊號到系統的每一個構件。 As shown in FIG. 1, a conventional single hydrogen generator for supplying hydrogen to a hydrogen fuel cell system includes a water container 2 connected to a pump 4 through a pipeline. The pump 4 transports water from the water container 2 as a liquid reactant for converting a hydride fuel into hydrogen. In the reactor 5, the hydrogen generated by the reaction is stored in the reactor 5. The gas valve 6 controls the release of hydrogen into the fuel cell system 7. All programs are monitored and controlled by a control unit 3, which receives signals from each component of the system and sends signals to each component of the system.
如第2圖所示,四個如第1圖所示類型的氫氣產生器係平行連接,惟具有一水加熱器8位於泵4和反應器5之間。所述系統的每一個構件交叉連接於一中央控制單元9,以使叢集的每一個構件能從中央控制單元9接收訊號並傳送訊號到中央控制單元9。氣閥6饋入一單一氣體歧管10,並從氣體歧管10將所產生的氫氣係供入燃料電池7。 As shown in FIG. 2, four hydrogen generators of the type shown in FIG. 1 are connected in parallel, except that a water heater 8 is located between the pump 4 and the reactor 5. Each component of the system is cross-connected to a central control unit 9 so that each component of the cluster can receive signals from the central control unit 9 and transmit signals to the central control unit 9. The gas valve 6 is fed into a single gas manifold 10, and the generated hydrogen system is supplied to the fuel cell 7 from the gas manifold 10.
位於水容器2和反應器5之間的加熱器5在水通過進入反應器5之前將其汽化,以使氫氣產生反應能更容易進行。 The heater 5 located between the water container 2 and the reactor 5 vaporizes the water before it passes into the reactor 5 so that the hydrogen-generating reaction can be more easily performed.
第3圖顯示第2圖所示配置的一變體,其中在每一條線中,一氣體調節器11係位於反應器5和氣閥6之間。在需求出現時,氣體調節器11允許叢集中不同的線在不同的壓力和流速下運作。 FIG. 3 shows a variant of the configuration shown in FIG. 2, in which a gas regulator 11 is located between the reactor 5 and the gas valve 6 in each line. When demand arises, the gas regulator 11 allows different lines in the cluster to operate at different pressures and flow rates.
第4圖顯示一燃料防護桶的外殼12的一種形式,其允許將一水源13連接到數個氫氣產生器,該數個氫氣產生器可被單獨控制但由一單一閥15控制饋入到一共同的出口14。 FIG. 4 shows a form of the casing 12 of a fuel protection barrel, which allows a water source 13 to be connected to several hydrogen generators which can be controlled individually but controlled by a single valve 15 to a Common exit 14.
在外殼12之內設置有數個固體氫氣燃料匣16。每個燃料匣16具有一中央流動引導結構17。數個泵18從源13進水,經加熱器19加熱產生蒸氣後再流經結構17。所述蒸氣和燃料匣16中的燃料劇烈反應以產生可從出口14釋放到燃料電池的非常大量的氫氣。 A plurality of solid hydrogen fuel cartridges 16 are disposed within the casing 12. Each fuel cartridge 16 has a central flow guiding structure 17. Several pumps 18 enter the water from the source 13 and are heated by the heater 19 to generate steam and then flow through the structure 17. The vapor reacts violently with the fuel in the fuel cartridge 16 to produce a very large amount of hydrogen that can be released from the outlet 14 to the fuel cell.
一中央控制系統(未顯示)是用於控制燃料匣並與燃料匣相互作用。 A central control system (not shown) is used to control and interact with the fuel tank.
泵18的每一者可根據一預設的演算法個別或集體被控制,以供應正確量的氫氣到燃料電池。 Each of the pumps 18 can be controlled individually or collectively according to a preset algorithm to supply the correct amount of hydrogen to the fuel cell.
硼氫化鈉通常用作燃料物質並可與適合的催化材料互補。其它氫氣產生化合物為眾所皆知,包括其他金屬氫化物、金屬硼化物,並可使用其他富氫(hydrogen-rich)有機和無機化合物。 Sodium borohydride is commonly used as a fuel substance and can be complementary to suitable catalytic materials. Other hydrogen generating compounds are well known, including other metal hydrides, metal borides, and other hydrogen-rich organic and inorganic compounds can be used.
至於用於產生氫氣的液態反應劑,除了水之外,亦可使用各種有機溶劑和酸性溶液。 As for the liquid reactant for generating hydrogen, various organic solvents and acidic solutions can be used in addition to water.
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---|---|---|---|---|
AU731003B3 (en) * | 1999-11-19 | 2001-03-22 | Water Corporation, The | A system and method for removing a gas from a plurality of vessels |
JP4552399B2 (en) * | 2003-08-07 | 2010-09-29 | トヨタ自動車株式会社 | Tank system comprising multiple tanks and control method thereof |
-
2017
- 2017-11-17 WO PCT/MY2017/050072 patent/WO2018147719A1/en active Application Filing
-
2018
- 2018-01-17 TW TW107101741A patent/TW201835704A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2018147719A1 (en) | 2018-08-16 |
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