TW201832755A - Composition with thermochromic coating, method for producing composition with thermochromic coating, and thermochromic facial mask made by using composition with thermochromic coating for providing skin care and thermochromic function - Google Patents

Composition with thermochromic coating, method for producing composition with thermochromic coating, and thermochromic facial mask made by using composition with thermochromic coating for providing skin care and thermochromic function Download PDF

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TW201832755A
TW201832755A TW106107967A TW106107967A TW201832755A TW 201832755 A TW201832755 A TW 201832755A TW 106107967 A TW106107967 A TW 106107967A TW 106107967 A TW106107967 A TW 106107967A TW 201832755 A TW201832755 A TW 201832755A
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thermochromic
composition
fiber
coating
thermochromic coating
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TW106107967A
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張璽
鄭博元
張意君
陳美卿
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趙莉惠
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Abstract

Provided is a composition with thermochromic coating, which comprises a thermochromic coating, a water and a cosmetic, wherein the thermochromic coating includes a methoxy polyoxymethylene melamine, a coloring agent, a 4,4'-isopropyl diphenyl and a potassium stearate fat, and the cosmetic includes a moisturizer and a preservative bacteriostatic agent. The moisturizer is selected from the group consisting of propylene glycol, dipropylene glycol, ethylhexyl glycerol, polypropylene glycol, polyethylene glycol, sorbitol, hydroxypropyl sorbitol, trehalose, hexanediol, 1,3-butanediol , 1',2,6-hexanetriol, glycerol, 1,2-hexanediol, pentanediol, octyl glycol, ethoxylated glycerin, propoxylated glycerin or a combination thereof.

Description

具感溫變色塗料的組成物、具感溫變色塗料的組成物之製造方法及使用感溫變色塗料的組成物所製成之感溫變色面膜Composition for thermochromic paint, method for producing composition with thermochromic paint, and thermochromic mask made of composition using thermochromic paint

本發明與化妝品有關,特別是指一種具感溫變色塗料的組成物、具感溫變色塗料的組成物之製造方法及使用感溫變色塗料的組成物所製成之感溫變色面膜。The present invention relates to cosmetics, and in particular to a composition having a thermochromic paint, a method for producing a composition having a thermochromic paint, and a thermochromic mask made of a composition using a thermochromic paint.

習用的面膜大多以不織布為基材,再將數種保養成分與水混合而成組成物,並將基材浸泡於組成物中以讓保養成分吸附於基材內,之後再將面膜密封於包裝中,以延緩面膜中的水分流失,而當欲使用面膜時,使用者僅須將面膜由包裝中取出並貼敷於使用者的皮膚上,經由面膜與皮膚接觸,使用者的皮膚即會吸收面膜中的保養成分,進而達到保養皮膚之功效。Most of the conventional masks are made of non-woven fabric, and then several kinds of maintenance ingredients are mixed with water to form a composition, and the substrate is immersed in the composition to allow the maintenance component to be adsorbed in the substrate, and then the mask is sealed in the package. In order to delay the loss of moisture in the mask, when the mask is to be used, the user only needs to take the mask out of the package and apply it to the skin of the user, and the skin of the user is absorbed through the mask. The maintenance ingredients in the mask, in order to maintain the skin's effectiveness.

本發明之主要目的在於提供一種具感溫變色塗料的組成物,該組成物具有皮膚保養以及感溫變色之功效。The main object of the present invention is to provide a composition having a thermochromic coating which has the effects of skin care and temperature change.

為了達成上述目的,本發明之具感溫變色塗料的組成物包含有一感溫變色塗料、一水以及一化妝品,其中感溫變色塗料包括有一甲氧基聚氧亞甲基蜜胺、一呈色劑、一4,4'-亞異丙基二苯以及一硬脂酸鉀脂,而化妝品包括有一保濕劑以及一防腐抑菌劑。In order to achieve the above object, the composition of the thermochromic coating of the present invention comprises a thermochromic coating, a water and a cosmetic, wherein the thermochromic coating comprises a methoxy polyoxymethylene melamine, a color The agent, a 4,4'-isopropylidene diphenyl and a potassium stearate, and the cosmetic comprises a moisturizer and a preservative bacteriostatic agent.

在本發明中,保濕劑選自於丙二醇、雙丙甘醇、乙基己基甘油、聚丙二醇、聚乙二醇、山梨醇、羥丙基山梨醇、海藻糖、己二醇、1,3-丁二醇、1,2,6-己三醇、甘油、1,2-己二醇、戊二醇、辛甘醇、乙氧基化甘油、丙氧基化甘油或該等之一組合。In the present invention, the humectant is selected from the group consisting of propylene glycol, dipropylene glycol, ethylhexyl glycerol, polypropylene glycol, polyethylene glycol, sorbitol, hydroxypropyl sorbitol, trehalose, hexanediol, 1,3- Butylene glycol, 1,2,6-hexanetriol, glycerin, 1,2-hexanediol, pentanediol, octyl glycol, ethoxylated glycerin, propoxylated glycerin or a combination of these.

在本發明中,保濕劑選自於多元醇、甘油、丁二醇、丙二醇、雙丙甘醇、乙基己基甘油、辛甘醇或該等之一組合。In the present invention, the humectant is selected from the group consisting of polyhydric alcohol, glycerin, butylene glycol, propylene glycol, dipropylene glycol, ethylhexyl glycerol, octyl glycol, or a combination thereof.

在本發明中,防腐抑菌劑選自於氯苯甘醚、碘代丙炔基丁基甲氨酸酯、對羥基苯甲酸的烷基酯、乙內酰脲衍生物、丙酸鹽和各種季銨化合物、EDTA二鈉、苯氧基乙醇、對羥基苯甲酸甲酯、對羥基苯甲酸丙酯、咪唑烷基脲、脫氫乙酸鈉和芐醇、苯甲酸鈉、溴硝丙二醇、脫氫乙酸鈉、聚六亞甲基雙胍鹽酸鹽、異噻唑酮和重氮烷基脲、甲醇、甲基氯異噻唑啉酮、甲基異噻唑啉酮、脫氫乙酸、鄰苯基苯酚、亞硫酸氫鈉、二氯苯,任何上述化合物的鹽或該等之衍生物。In the present invention, the antiseptic bacteriostatic agent is selected from the group consisting of chlorophenyl glycol ether, iodopropynyl butyl carbamate, alkyl ester of p-hydroxybenzoic acid, hydantoin derivative, propionate and various quaternary ammonium salts. a compound, disodium EDTA, phenoxyethanol, methyl p-hydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea, sodium dehydroacetate and benzyl alcohol, sodium benzoate, bromide, sodium dehydroacetate, Polyhexamethylene biguanide hydrochloride, isothiazolone and diazolidinyl urea, methanol, methyl chloroisothiazolinone, methyl isothiazolinone, dehydroacetic acid, o-phenylphenol, sodium hydrogen sulfite Dichlorobenzene, a salt of any of the above compounds or a derivative thereof.

在本發明中,防腐抑菌劑選自於羥苯甲脂、o-傘花烴-5-醇、苯氧基乙醇、氯苯甘醚、碘代丙炔基丁基甲氨酸酯或該等之衍生物。In the present invention, the preservative bacteriostatic agent is selected from the group consisting of hydroxybenzene methyl ester, o-cymene-5-ol, phenoxyethanol, chlorophenylglycol, iodopropynyl butyl carbamate or the like. derivative.

在本發明中,具感溫變色塗料的組成物更包含有一皮膚調理劑,皮膚調理劑選自於植物萃取、透明質酸鈉、維他命類、卵磷脂、尿素、羥乙基尿素、菸鹼胺、甘草酸鉀、尿囊素、咯烷酮羧酸鈉、海藻醣或該等之衍生物。In the present invention, the composition of the thermochromic coating further comprises a skin conditioning agent selected from the group consisting of plant extract, sodium hyaluronate, vitamins, lecithin, urea, hydroxyethyl urea, nicotine amine. , potassium glycyrrhizinate, allantoin, sodium pyrrolidone carboxylate, trehalose or such derivatives.

在本發明中,化妝品係選自於化妝水、凝膠、洗劑、乳膏、敷膏、乳液、粉底、口紅、洗面乳、美髮水或該等一組合,藉以讓組成物具有潤澤髮膚、刺激嗅覺、掩飾體臭或修飾容貌等效果。In the present invention, the cosmetic is selected from the group consisting of a lotion, a gel, a lotion, a cream, an ointment, an emulsion, a foundation, a lipstick, a facial cleanser, a hair lotion, or the like, whereby the composition is moisturized and scented. , stimulate the sense of smell, cover up body odor or modify the appearance of the effect.

在本發明中,具感溫變色塗料的組成物更包含有一增稠劑,該增稠劑選自於卡波姆、三仙膠、羥乙基纖維素、澎潤土或該等之衍生物。In the present invention, the composition of the thermochromic coating further comprises a thickener selected from the group consisting of carbomer, trisin, hydroxyethyl cellulose, strontium or such derivatives. .

在本發明中,甲氧基聚氧亞甲基蜜胺的含量為1~20wt%;該呈色劑的含量為1~20wt%;該4,4'-異亞丙基二苯酚的含量為1~20wt%;以及該硬脂酸甲脂的含量為50~80wt%10~80wt%,藉以讓感溫變色塗料具有較佳的感溫變色效果。In the present invention, the content of methoxy polyoxymethylene melamine is 1 to 20% by weight; the content of the coloring agent is 1 to 20% by weight; and the content of the 4,4'-isopropylidenediphenol is 1~20wt%; and the content of the methyl stearate is 50-80wt% 10~80wt%, so that the thermochromic paint has better temperature-changing effect.

本發明之次一目的在於提供一種具感溫變色塗料的組成物之製造方法,藉以能製造出兼具保養皮膚及感溫變色效果的組成物。A second object of the present invention is to provide a method for producing a composition having a thermochromic paint, whereby a composition having both skin care and thermochromic effects can be produced.

為達成上述之次要目的,本發明之具感溫變色塗料的組成物之製造方法包含有下列步驟:首先將甲氧基聚氧亞甲基蜜胺、呈色劑、4,4'-亞異丙基二苯以及硬脂酸鉀脂加入一第一容器內,再將水加入第一容器並進行攪拌,以形成感溫變色塗料,接著將保濕劑、防腐抑菌劑以及水加入一第二容器內後進行攪拌,以形成化妝品,之後將感溫變色塗料加入化妝品,以形成組成物。In order to achieve the above secondary object, the method for producing a composition for a thermochromic coating of the present invention comprises the following steps: first, methoxypolyoxymethylene melamine, coloring agent, 4, 4'-Asia Add isopropyl diphenyl and potassium stearate to a first container, add water to the first container and stir to form a thermochromic coating, then add a moisturizer, antiseptic and water to the first The second container is then stirred to form a cosmetic, and then the thermochromic coating is added to the cosmetic to form a composition.

在本發明中,感溫變色塗料係可在0~150℃加入化妝品中,以降低製作具感溫變色的組成物之難易度,及增加其實用範圍。In the present invention, the thermochromic paint can be added to the cosmetic at 0 to 150 ° C to reduce the difficulty of producing a composition having thermochromic properties and to increase its practical range.

在本發明中,具感溫變色塗料的組成物之製造方法更包含將一皮膚調理劑,皮膚調理劑係先以50~11000rmp攪拌2~20min,待完全溶解再添加入該第二容器內。In the present invention, the method for manufacturing a composition having a thermochromic coating further comprises: stirring a skin conditioning agent and a skin conditioning agent at 50 to 11,000 rpm for 2 to 20 minutes, and then completely dissolving and adding to the second container.

在本發明中,感溫變色塗料以噴塗、膠版印刷、絲印、平版印刷、無版印刷、膠印、凹版印刷、網版印刷、油印等工藝與一基材結合,藉此能有較高之效率來完成感溫變色面膜之製作。In the present invention, the thermochromic coating is combined with a substrate by spraying, offset printing, silk screen printing, lithography, offset printing, offset printing, gravure printing, screen printing, stencil printing, etc., thereby achieving higher efficiency. To complete the production of the thermochromic mask.

在本發明中,防腐抑菌劑與保濕劑係待完全溶解後且呈現透明狀時,再將水加入並進行攪拌,藉以加快反應速度。In the present invention, when the antiseptic bacteriostatic agent and the humectant are completely dissolved and appear transparent, water is added and stirred to accelerate the reaction rate.

在本發明中,具感溫變色塗料的組成物之製造方法更包含將保濕劑加水進行攪拌,待完全溶解且呈透明狀。In the present invention, the method for producing a composition having a thermochromic paint further comprises stirring the humectant with water, and is completely dissolved and transparent.

本發明之另一目的在於提供一種使用感溫變色塗料的組成物所製成之感溫變色面膜,其主要是在一基材的表面或裡面或表面與裡面同時形成有前述感溫變色塗料,而基材選自於不織布、棉布、木漿、蠶絲、泥膏、果凍膠、乳霜、生物纖維、羽纖織布、木漿珍珠、淨炭、純棉、有機棉、羽絲縷、天絲棉纖維、黑布膜、純棉、各色微導面膜、凝水纖維、凝水蠶絲、竹炭纖維、天然纖維、仿生材料(Aqpar)、Rayron嫘縈纖維、木漿纖維(Viscose)與彈性纖維混編而成的廣角材料、彈性纖維與木漿纖維針織而成的拉提材料、聚丙烯材料(Polypropylene)、木漿纖維與聚酯纖維(PET)混編而成的水織布、天然棉與木棉組成的絮纖布、木樹之纖維編織而成的綠纖布,使面膜具有感溫變色且兼具保養皮膚的效果。Another object of the present invention is to provide a thermochromic facial mask made of a composition using a thermochromic coating, which is mainly formed by forming the aforementioned thermochromic coating on the surface or inside or on the surface of a substrate. The substrate is selected from the group consisting of non-woven fabrics, cotton fabrics, wood pulp, silk, mud paste, jelly gel, cream, bio-fiber, feather fiber woven fabric, wood pulp pearl, net charcoal, pure cotton, organic cotton, feather silk, day Silk cotton fiber, black cloth film, pure cotton, various color micro-conductive mask, condensed fiber, condensed silk, bamboo charcoal fiber, natural fiber, biomimetic material (Aqpar), Rayron® fiber, wood pulp fiber (Viscose) and elastic fiber Mixed wide-angle material, stretch fabric made of elastic fiber and wood pulp fiber, polypropylene fabric, water-weaved fabric made of wood pulp fiber and polyester fiber, natural cotton The green fiber cloth woven with the fiber cloth composed of kapok and the fiber of the wood tree makes the mask have a temperature-sensitive discoloration and has the effect of maintaining the skin.

有關本發明所提供之水性塗料的詳細構造、特點、組裝或使用方式,將於後續的實施方式詳細說明中予以描述。然而,在本發明領域中具有通常知識者應能瞭解,該等詳細說明以及實施本發明所列舉的特定實施例,僅係用於說明本發明,並非用以限制本發明之專利申請範圍。Detailed construction, features, assembly or use of the aqueous coatings provided by the present invention will be described in the detailed description of the subsequent embodiments. However, it should be understood by those of ordinary skill in the art that the present invention is not limited by the scope of the invention.

如第1圖所示,本案發明之具感溫變色塗料的組成物10包含有一感溫變色塗料20、一水30、一化妝品40。其中感溫變色塗料20包括有一含量為1~20wt%的甲氧基聚氧亞甲基蜜胺、一含量為1~20wt%的呈色劑、一含量為1~20wt%的4,4'-異亞丙基二苯酚,以及一含量為50~80wt%的硬脂酸甲脂,而化妝品40係定義為一種能清潔及提升人體外貌之用品,更為一種調理人體膚質且不改變生理結構之用品,此化妝品40包括有一保濕劑、一防腐抑菌劑以及一皮膚調理劑,舉例來說,保濕劑選自於丙二醇、雙丙甘醇、乙基己基甘油、聚丙二醇、聚乙二醇、山梨醇、羥丙基山梨醇、海藻糖、己二醇、1,3-丁二醇、1,2,6-己三醇、甘油、1,2-己二醇、戊二醇、辛甘醇、乙氧基化甘油、丙氧基化甘油或該等之一組合,防腐抑菌劑選自於氯苯甘醚、碘代丙炔基丁基甲氨酸酯、對羥基苯甲酸的烷基酯、乙內酰脲衍生物、丙酸鹽和各種季銨化合物、EDTA二鈉、苯氧基乙醇、對羥基苯甲酸甲酯、對羥基苯甲酸丙酯、咪唑烷基脲、脫氫乙酸鈉和芐醇、苯甲酸鈉、溴硝丙二醇、脫氫乙酸鈉、聚六亞甲基雙胍鹽酸鹽、異噻唑酮和重氮烷基脲、甲醇、甲基氯異噻唑啉酮、甲基異噻唑啉酮、脫氫乙酸、鄰苯基苯酚、亞硫酸氫鈉、二氯苯,任何上述化合物的鹽或該等之衍生物,或者羥苯甲脂、o-傘花烴-5-醇、苯氧基乙醇、氯苯甘醚、碘代丙炔基丁基甲氨酸酯或該等之衍生物,而皮膚調理劑選自於植物萃取、透明質酸鈉、維他命類、卵磷脂、尿素、羥乙基尿素、菸鹼胺、甘草酸鉀、尿囊素、咯烷酮羧酸鈉、海藻醣或該等之衍生物。而為了增加具感溫變色塗料的組成物之黏稠性,更可於組成物中添加一增稠劑,增稠劑選自於卡波姆、三仙膠、羥乙基纖維素、澎潤土或該等之衍生物。此外,本發明為了讓組成物具有潤澤髮膚、刺激嗅覺、掩飾體臭或修飾容貌等效果,故化妝品將選自於化妝水、凝膠、洗劑、乳膏、敷膏、乳液、粉底、口紅、洗面乳、美髮水或該等一組合。As shown in Fig. 1, the composition 10 of the thermochromic coating of the present invention comprises a thermochromic coating 20, a water 30, and a cosmetic 40. The thermochromic coating 20 comprises a methoxypolyoxymethylene melamine in an amount of 1 to 20% by weight, a coloring agent in an amount of 1 to 20% by weight, and a 4, 4' content in an amount of 1 to 20% by weight. - isopropylidene diphenol, and a content of 50 to 80% by weight of methyl stearate, while Cosmetic 40 is defined as a product that can clean and enhance the appearance of the human body, and is a kind of conditioning of the human skin without changing the physiological The cosmetic article 40 comprises a moisturizer, a preservative bacteriostatic agent and a skin conditioning agent. For example, the humectant is selected from the group consisting of propylene glycol, dipropylene glycol, ethylhexyl glycerol, polypropylene glycol, polyethylene glycol Alcohol, sorbitol, hydroxypropyl sorbitol, trehalose, hexanediol, 1,3-butanediol, 1,2,6-hexanetriol, glycerin, 1,2-hexanediol, pentanediol, Succinol, ethoxylated glycerin, propoxylated glycerin or a combination thereof, the antiseptic bacteriostatic agent is selected from the group consisting of chlorophenylglycol, iodopropynyl butyl carbamate, and parabens of p-hydroxybenzoic acid Base ester, hydantoin derivative, propionate and various quaternary ammonium compounds, disodium EDTA, phenoxyethanol, methyl p-hydroxybenzoate, p-hydroxyl Propyl benzoate, imidazolidinyl urea, sodium dehydroacetate and benzyl alcohol, sodium benzoate, bromide, sodium dehydroacetate, polyhexamethylene biguanide hydrochloride, isothiazolone and diazolidinyl urea, Methanol, methyl chloroisothiazolinone, methyl isothiazolinone, dehydroacetic acid, o-phenylphenol, sodium hydrogen sulfite, dichlorobenzene, salts of any of the above compounds or derivatives thereof, or hydroxybenzene Methyl ester, o-cymene-5-ol, phenoxyethanol, chlorophenylglycol, iodopropynyl butyl carbamate or derivatives thereof, and the skin conditioning agent is selected from plant extracts, transparent Sodium carbonate, vitamins, lecithin, urea, hydroxyethyl urea, nicotinic amine, potassium glycyrrhizinate, allantoin, sodium sulphonate, trehalose or derivatives thereof. In order to increase the viscosity of the composition of the thermochromic coating, a thickener may be added to the composition, and the thickener is selected from the group consisting of carbomer, trisin, hydroxyethyl cellulose, and strontium. Or such derivatives. In addition, the present invention is selected from the group consisting of lotions, gels, lotions, creams, creams, lotions, foundations, etc. in order to impart a moisturizing, stimulating, odor, or cosmetic appearance to the composition. Lipstick, facial cleanser, hair lotion or a combination of these.

請參酌第1圖及第2圖,本發明第1較佳實施例之具感溫變色塗料的組成物之製造方法包含有下列步驟:Referring to Figures 1 and 2, the method for manufacturing a composition having a thermochromic paint according to a first preferred embodiment of the present invention comprises the following steps:

步驟a:將含量為1~20wt%的甲氧基聚氧亞甲基蜜胺、含量為1~20wt%的呈色劑、含量為1~20wt%的4,4'-亞異丙基二苯以及含量為50~80wt%10~80wt%的硬脂酸鉀脂加入一第一容器內,接著將水加入第一容器並進行攪拌,以形成感溫變色塗料。Step a: a methoxypolyoxymethylene melamine having a content of 1 to 20% by weight, a coloring agent having a content of 1 to 20% by weight, and a 4,4'-isopropylidene group having a content of 1 to 20% by weight. Benzene and potassium stearate in an amount of 50 to 80% by weight and 10 to 80% by weight are added to a first container, and then water is added to the first container and stirred to form a thermochromic coating.

步驟b:將保濕劑、防腐抑菌劑、皮膚調理劑以及水加入一第二容器內後進行攪拌,以形成化妝品。Step b: adding a moisturizer, an antiseptic bacteriostatic agent, a skin conditioning agent, and water to a second container, followed by stirring to form a cosmetic.

在步驟a~b的製作過程中,本案發明為了加快反應速度,故可透過對感溫變色塗料預先加熱來達成,而溫度介於0~150℃,再詳述之,在防腐抑菌劑的部分係先加熱至60℃,待防腐抑菌劑完全溶解且呈現透明液體後再將其降溫至45℃,而皮膚調理劑的部分則是先以50~11000rmp攪拌2~20min,待皮膚調理劑完全溶解且呈半透明的霧狀液體,而保濕劑的部分則須透過多次的加水及攪拌,待保濕劑完全溶解且呈透明狀的稠狀物。In the production process of steps a~b, the invention of the present invention can achieve the reaction speed by preheating the thermochromic paint, and the temperature is between 0 and 150 ° C, and in detail, in the antiseptic bacteriostatic agent. The part is first heated to 60 ° C, after the antiseptic bacteriostatic agent is completely dissolved and the transparent liquid is presented, then the temperature is lowered to 45 ° C, and the skin conditioning agent is first stirred at 50 ~ 11000 rpm for 2 ~ 20 min, until the skin conditioning agent A completely soluble and translucent misty liquid, and a portion of the humectant is required to pass through multiple additions and agitation, and the humectant is completely dissolved and transparent.

步驟c:將感溫變色塗料20加入化妝品40,以形成具感溫變色塗料的組成物10。Step c: The thermochromic coating 20 is added to the cosmetic 40 to form a composition 10 having a thermochromic coating.

在步驟c的製作過程中,本案發明為了降低製作具感溫變色的組成物之難易度以及增加其實用範圍,感溫變色塗料係容許溫度在0~150℃之間加入化妝品。In the production process of the step c, in order to reduce the difficulty of producing a composition having temperature-sensing discoloration and to increase the practical range thereof, the thermochromic paint allows the temperature to be added between 0 and 150 ° C.

除前述之外,如第2圖、第6圖及第7圖所示,本發明第2較佳實施例之製造方法,第2較佳實施例之製法與第1較佳實施例之製法相似,其差異在於第2較佳實施例更包含有將上述之化妝品30填入一基材50中,藉以製作成為一感溫變色面膜,但並不以面膜為限,也可眼膜或其他與化妝保養相關之基材,其中基材50選自於不織布、棉布、木漿、蠶絲、泥膏、果凍膠、乳霜、生物纖維、羽纖織布、木漿珍珠、淨炭、純棉、有機棉、羽絲縷、天絲棉纖維、黑布膜、純棉、各色微導面膜、凝水纖維、凝水蠶絲、竹炭纖維、天然纖維、仿生材料(Aqpar)、Rayron嫘縈纖維、木漿纖維(Viscose)與彈性纖維混編而成的廣角材料、彈性纖維與木漿纖維針織而成的拉提材料、聚丙烯材料(Polypropylene)、木漿纖維與聚酯纖維(PET)混編而成的水織布、天然棉與木棉組成的絮纖布、木樹之纖維編織而成的綠纖布。In addition to the foregoing, as shown in FIGS. 2, 6 and 7, the manufacturing method of the second preferred embodiment of the present invention is similar to the method of the first preferred embodiment. The difference is that the second preferred embodiment further comprises filling the above-mentioned cosmetic 30 into a substrate 50, thereby forming a thermochromic mask, but not limited to the mask, but also an eye mask or the like. A substrate related to cosmetic maintenance, wherein the substrate 50 is selected from the group consisting of non-woven fabrics, cotton fabrics, wood pulp, silk, mud paste, jelly gel, cream, biofiber, feather fiber woven fabric, wood pulp pearl, net charcoal, pure cotton, Organic cotton, feather silk, Tencel cotton fiber, black cloth film, pure cotton, various micro-conductive mask, condensed fiber, condensed silk, bamboo charcoal fiber, natural fiber, biomimetic material (Aqpar), Rayron 嫘萦 fiber, wood Wide-angle material made of Viscose and elastic fiber, drawn material made of elastic fiber and wood pulp fiber, polypropylene, wood pulp fiber and polyester fiber (PET) Flock fabric made of water-weaved fabric, natural cotton and kapok, and fiber of wood tree Woven green fiber cloth.

在此值得一提的是,本發明為了能以較高之效率來完成感溫變色面膜之製作,故感溫變色塗料20採用噴塗、膠版印刷、絲印、平版印刷、無版印刷、膠印、凹版印刷、網版印刷、油印等工藝與基材50結合。此外,若是以本發明第1較佳實施例之製造方法所製成的組成物10再與基材50結合,此時組成物10將可形成於基材50的表面或裡面,或者是同時形成基材的表面與裡面。It is worth mentioning that, in order to complete the production of the temperature-sensitive color-changing mask with high efficiency, the thermo-sensitive color-changing coating 20 adopts spraying, offset printing, silk screen printing, lithography, non-printing, offset printing, gravure printing. Printing, screen printing, mime printing and the like are combined with the substrate 50. Further, if the composition 10 produced by the manufacturing method of the first preferred embodiment of the present invention is further bonded to the substrate 50, the composition 10 may be formed on the surface or inside of the substrate 50, or may be simultaneously formed. The surface and inside of the substrate.

如第4圖、第6圖及第7圖所示,為本發明第3較佳實施例之製造方法,此製法包含以下步驟:As shown in FIG. 4, FIG. 6, and FIG. 7, a manufacturing method according to a third preferred embodiment of the present invention includes the following steps:

步驟a:該步驟與第1較佳實施例之步驟a相似。Step a: This step is similar to step a of the first preferred embodiment.

步驟b:將基材原料以裁切之成形加工方式來獲得基材50。Step b: The substrate 50 is obtained by cutting the substrate material into a forming process.

步驟c:將感溫變色塗料20以前述噴塗、印刷等方式形成於基材50的表面。Step c: The thermochromic paint 20 is formed on the surface of the substrate 50 by the aforementioned spraying, printing or the like.

步驟d:將具有感溫變色塗料20的基材以浸泡或添加的方式加入化妝品40,以形成感溫變色面膜。Step d: The substrate having the thermochromic coating 20 is added to the cosmetic 40 in a manner of soaking or adding to form a thermochromic mask.

如第5圖至第7圖所示,為本發明第4較佳實施例之製造方法,第4較佳實施例之製法與第3較佳實施例之製法相似,其差異在於第4較佳實施例的製造方法係將感溫變色塗料20先以前述之噴塗、印刷等方法形成於基材原料的表面,接著再對具有感溫變色塗料20的基板原料進行裁切之成形加工,以成為具感溫變色塗料20的基材,最後再將具感溫變色塗料的基材浸泡於化妝品40中,使化妝品40與基材50結合而形成感溫變色面膜。As shown in FIG. 5 to FIG. 7, the manufacturing method of the fourth preferred embodiment of the present invention is similar to the method of the third preferred embodiment, and the difference is that the fourth preferred embodiment is the fourth preferred embodiment. In the manufacturing method of the embodiment, the thermochromic paint 20 is first formed on the surface of the substrate raw material by the above-described spraying, printing or the like, and then the substrate material having the thermosensitive color change coating material 20 is cut and formed to be formed. The substrate having the thermochromic coating 20 is finally immersed in the cosmetic 40 in the substrate 40, and the cosmetic 40 is bonded to the substrate 50 to form a thermochromic mask.

從上述可知,由於本發明之製造方法所製得的組成物10及面膜皆含有感溫變色塗料的成分,因而兼具感溫變色以及保養皮膚之效果,特別是透過本發明的製造方法,不僅加快了感溫變色塗料20與化妝品40之間的反應速度,更是大大地降低製作具感溫變色的組成物之難易度,以提高完成感溫變色面膜製作之效率及增加其實用範圍。As described above, since both the composition 10 and the mask obtained by the production method of the present invention contain a component of a thermochromic paint, they have both a thermochromic effect and an effect of skin care, particularly through the production method of the present invention. The reaction speed between the thermochromic paint 20 and the cosmetic 40 is accelerated, and the difficulty of fabricating the composition with temperature and discoloration is greatly reduced, so as to improve the efficiency of completing the thermochromic mask and increase the practical range thereof.

10‧‧‧組成物10‧‧‧Composition

20‧‧‧感溫變色塗料20‧‧‧temperature sensitive color coating

30‧‧‧水30‧‧‧ water

40‧‧‧化妝品40‧‧‧ Cosmetics

50‧‧‧基材50‧‧‧Substrate

第1圖為本發明具感溫變色塗料之組成物的示意圖。 第2圖為本發明第1較佳實施例之製造方法的流程圖。 第3圖為本發明第2較佳實施例之製造方法的流程圖。 第4圖為本發明第3較佳實施例之製造方法的流程圖。 第5圖為本發明第4較佳實施例之製造方法的流程圖。 第6圖及第7圖為本發明感溫變色面膜的剖視圖。Fig. 1 is a schematic view showing the composition of a thermochromic paint of the present invention. Fig. 2 is a flow chart showing a manufacturing method of the first preferred embodiment of the present invention. Figure 3 is a flow chart showing a manufacturing method of a second preferred embodiment of the present invention. Figure 4 is a flow chart showing a manufacturing method of a third preferred embodiment of the present invention. Figure 5 is a flow chart showing a manufacturing method of a fourth preferred embodiment of the present invention. 6 and 7 are cross-sectional views of the thermochromic mask of the present invention.

Claims (19)

一種具感溫變色塗料的組成物,包含有: 一感溫變色塗料,其包括有一甲氧基聚氧亞甲基蜜胺、一呈色劑、一4,4'-亞異丙基二苯以及一硬脂酸鉀脂; 一水;以及 一化妝品,其包括有一保濕劑以及一防腐抑菌劑。A composition for a thermochromic coating comprising: a thermochromic coating comprising a methoxy polyoxymethylene melamine, a color former, a 4,4'-isopropylidene diphenyl And a potassium stearate; a water; and a cosmetic comprising a moisturizer and a preservative bacteriostatic agent. 如請求項1所述之具感溫變色塗料的組成物,其中該保濕劑選自於丙二醇、雙丙甘醇、乙基己基甘油、聚丙二醇、聚乙二醇、山梨醇、羥丙基山梨醇、海藻糖、己二醇、1,3-丁二醇、1,2,6-己三醇、甘油、1,2-己二醇、戊二醇、辛甘醇、乙氧基化甘油、丙氧基化甘油或該等之一組合。The composition of the thermochromic coating according to claim 1, wherein the humectant is selected from the group consisting of propylene glycol, dipropylene glycol, ethylhexyl glycerol, polypropylene glycol, polyethylene glycol, sorbitol, and hydroxypropyl sorbitol. Alcohol, trehalose, hexanediol, 1,3-butanediol, 1,2,6-hexanetriol, glycerin, 1,2-hexanediol, pentanediol, octyl glycol, ethoxylated glycerol , propoxylated glycerol or a combination of these. 如請求項1所述之具感溫變色塗料的組成物,其中該保濕劑選自於多元醇、甘油、丁二醇、丙二醇、雙丙甘醇、乙基己基甘油、辛甘醇或該等之一組合。The composition of the thermochromic coating according to claim 1, wherein the humectant is selected from the group consisting of polyhydric alcohol, glycerin, butylene glycol, propylene glycol, dipropylene glycol, ethylhexyl glycerol, octyl glycol or the like. One combination. 如請求項1所述之具感溫變色塗料的組成物,其中該防腐抑菌劑選自於氯苯甘醚碘代丙炔基丁基甲氨酸酯、對羥基苯甲酸的烷基酯、乙內酰脲、衍生物、丙酸鹽和各種季銨化合物、EDTA二鈉、苯氧基乙醇、對羥基苯甲酸甲酯、對羥基苯甲酸丙酯、咪唑烷基脲、脫氫乙酸鈉和芐醇、苯甲酸鈉、溴硝丙二醇、脫氫乙酸鈉、聚六亞甲基雙胍鹽酸鹽、異噻唑酮和重氮烷基脲、甲醇、甲基氯異噻唑啉酮、甲基異噻唑啉酮、脫氫乙酸、鄰苯基苯酚、亞硫酸氫鈉、二氯苯,任何上述化合物的鹽或該等之衍生物。The composition of the thermochromic paint according to claim 1, wherein the antiseptic bacteriostatic agent is selected from the group consisting of chlorophenylglycol iodopropynyl butyl carbamate, alkyl ester of p-hydroxybenzoic acid, and B. Acyl ureas, derivatives, propionates and various quaternary ammonium compounds, disodium EDTA, phenoxyethanol, methyl p-hydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea, sodium dehydroacetate and benzyl alcohol , sodium benzoate, bromide, sodium dehydroacetate, polyhexamethylene biguanide hydrochloride, isothiazolone and diazolidinyl urea, methanol, methyl chloroisothiazolinone, methyl isothiazolinone, Dehydroacetic acid, o-phenylphenol, sodium hydrogen sulfite, dichlorobenzene, salts of any of the above compounds or derivatives thereof. 如請求項1所述之具感溫變色塗料的組成物,其中該防腐抑菌劑選自於羥苯甲脂、o-傘花烴-5-醇、苯氧基乙醇、氯苯甘醚、碘代丙炔基丁基甲氨酸酯或該等之衍生物。The composition of the thermochromic paint according to claim 1, wherein the antiseptic bacteriostatic agent is selected from the group consisting of hydroxybenzene methyl ester, o-cymene-5-alcohol, phenoxyethanol, chlorpheniramine, Iodopropynyl butyl carbamate or such derivatives. 如請求項1或請求項2或請求項4所述之具感溫變色塗料的組成物,其更包含有一皮膚調理劑,該皮膚調理劑選自於植物萃取、透明質酸鈉、維他命類、卵磷脂、尿素、羥乙基尿素、菸鹼胺、甘草酸鉀、尿囊素、咯烷酮羧酸鈉、海藻醣或該等之衍生物。The composition of the thermochromic coating according to claim 1 or claim 2 or claim 4, further comprising a skin conditioning agent selected from the group consisting of plant extracting, sodium hyaluronate, vitamins, Lecithin, urea, hydroxyethyl urea, nicotinic amine, potassium glycyrrhizinate, allantoin, sodium sulovidone carboxylate, trehalose or derivatives thereof. 如請求項1所述之具感溫變色塗料的組成物,其中該化妝品係選自於化妝水、凝膠、洗劑、乳膏、敷膏、乳液、粉底、口紅、洗面乳、美髮水或該等一組合。The composition of the thermochromic paint according to claim 1, wherein the cosmetic is selected from the group consisting of a lotion, a gel, a lotion, a cream, an ointment, an emulsion, a foundation, a lipstick, a facial cleanser, a hair lotion or One such combination. 如請求項1所述之具感溫變色塗料的組成物,其更包含有一增稠劑,該增稠劑選自於卡波姆、三仙膠、羥乙基纖維素、澎潤土或該等之衍生物。The composition of the thermochromic coating according to claim 1, further comprising a thickener selected from the group consisting of carbomer, trisin, hydroxyethyl cellulose, strontium or the like And other derivatives. 如請求項1所述之具感溫變色塗料的組成物,其中該甲氧基聚氧亞甲基蜜胺的含量為1~20wt%;該呈色劑的含量為1~20wt%;該4,4'-異亞丙基二苯酚的含量為1~20wt%;以及該硬脂酸甲脂的含量為50~80wt%10~80wt%。The composition of the thermochromic paint according to claim 1, wherein the content of the methoxy polyoxymethylene melamine is 1 to 20% by weight; and the content of the coloring agent is 1 to 20% by weight; The content of 4'-isopropylidenediphenol is 1 to 20% by weight; and the content of the methyl stearate is 50 to 80% by weight and 10 to 80% by weight. 一種如請求項1所述具感溫變色塗料的組成物之製造方法,包含有下列步驟: 將該甲氧基聚氧亞甲基蜜胺、該呈色劑、該4,4'-異亞丙基二苯酚以及該硬脂酸甲脂加入一第一容器內; 將該水加入該第一容器並進行攪拌,以形成該感溫變色塗料; 將該保濕劑、該防腐抑菌劑以及該水加入一第二容器內後進行攪拌,以形成該化妝品;以及 將該感溫變色塗料加入該化妝品,以形成該組成物。A method for producing a composition having a thermochromic paint according to claim 1, comprising the steps of: methoxypolyoxymethylene melamine, the color former, and the 4,4'- Propyl diphenol and the methyl stearate are added to a first container; the water is added to the first container and stirred to form the thermochromic coating; the humectant, the antiseptic and the bacteriostatic agent Water is added to a second container and stirred to form the cosmetic; and the thermochromic coating is added to the cosmetic to form the composition. 如請求項10所述具感溫變色塗料的組成物之製造方法,其中該感溫變色塗料係可在0~150℃加入該化妝品中。The method for producing a composition having a thermochromic paint according to claim 10, wherein the thermochromic paint is added to the cosmetic at 0 to 150 °C. 如請求項10所述具感溫變色塗料的組成物之製造方法,其更包含將一皮膚調理劑添加入該第二容器內。A method of producing a composition having a thermochromic coating according to claim 10, further comprising adding a skin conditioning agent to the second container. 如請求項12所述具感溫變色塗料的組成物之製造方法,其中該皮膚調理劑係先以50~11000rmp攪拌2~20min,待完全溶解。The method for producing a composition having a thermochromic paint according to claim 12, wherein the skin conditioning agent is first stirred at 50 to 11,000 rpm for 2 to 20 minutes until completely dissolved. 如請求項10所述具感溫變色塗料的組成物之製造方法,其中該感溫變色塗料以噴塗、膠版印刷、絲印、平版印刷、無版印刷、膠印、凹版印刷、網版印刷、油印等工藝與一基材結合。The method for manufacturing a composition having a thermochromic paint according to claim 10, wherein the thermochromic paint is sprayed, offset printed, screen printed, lithographic, non-printed, offset, gravure, screen printing, mimeograph, etc. The process is combined with a substrate. 如請求項10所述具感溫變色塗料的組成物之製造方法,其中該防腐抑菌劑與該保濕劑係待完全溶解後且呈現透明狀時,再將水加入並進行攪拌。The method for producing a composition for a thermochromic paint according to claim 10, wherein the antiseptic bacteriostatic agent and the humectant are added to the mixture and stirred while being completely dissolved. 如請求項10所述具感溫變色塗料的組成物之製造方法,其更包含將該保濕劑加水進行攪拌,待完全溶解且呈透明狀。The method for producing a composition having a thermochromic paint according to claim 10, further comprising adding the humectant to water and stirring, to be completely dissolved and transparent. 一種感溫變色面膜,包含有: 一基材;以及 一如請求項10至16中任一項所述之製造方法所製得之感溫變色塗料的組成物,係形成於該基材。A thermochromic facial mask comprising: a substrate; and a composition of a thermochromic coating prepared by the method of any one of claims 10 to 16, formed on the substrate. 如請求項17所述之感溫變色面膜,其中該基材選自於不織布、棉布、木漿、蠶絲、泥膏、果凍凝膠、乳霜、生物纖維、羽纖織布、木漿珍珠、淨炭、純棉、有機棉、羽絲縷、天絲棉纖維、黑布膜、純棉、各色微導面膜、凝水纖維、凝水蠶絲、竹炭纖維、天然纖維、仿生材料(Aqpar)、Rayron嫘縈纖維、木漿纖維(Viscose)與彈性纖維混編而成的廣角材料、彈性纖維與木漿纖維針織而成的拉提材料、聚丙烯材料(Polypropylene)、木漿纖維與聚酯纖維(PET)混編而成的水織布、天然棉與木棉組成的絮纖布、木樹之纖維編織而成的綠纖布。The thermochromic facial mask according to claim 17, wherein the substrate is selected from the group consisting of non-woven fabric, cotton cloth, wood pulp, silk, mud paste, jelly gel, cream, biofiber, feather fiber woven fabric, wood pulp pearl, Clean carbon, pure cotton, organic cotton, feather silk, tencel cotton fiber, black cloth film, pure cotton, various micro-conductive mask, condensed fiber, condensed silk, bamboo charcoal fiber, natural fiber, biomimetic material (Aqpar), Wide-angle material made of Rayron 嫘萦 fiber, Viscose and elastic fiber, lacquered material made of elastic fiber and wood pulp fiber, Polypropylene, wood pulp fiber and polyester fiber (PET) a water-weaving fabric, a natural cotton and kapok composed of a fiber cloth, and a wood fiber woven green fiber cloth. 如請求項17所述之感溫變色面膜,其中該組成物係形成於該基材的表面或裡面,或者同時形成該基材的表面與裡面。The thermochromic facial mask according to claim 17, wherein the composition is formed on the surface or inside of the substrate or simultaneously forms the surface and the inside of the substrate.
TW106107967A 2017-03-10 2017-03-10 Composition with thermochromic coating, method for producing composition with thermochromic coating, and thermochromic facial mask made by using composition with thermochromic coating for providing skin care and thermochromic function TW201832755A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11958308B1 (en) 2023-05-31 2024-04-16 G13 Innovation In Production Ltd Thermal paper, and methods and systems for forming the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11958308B1 (en) 2023-05-31 2024-04-16 G13 Innovation In Production Ltd Thermal paper, and methods and systems for forming the same

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