TW201823438A - Burning apparatus and biomass fuel - Google Patents
Burning apparatus and biomass fuel Download PDFInfo
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- TW201823438A TW201823438A TW106120343A TW106120343A TW201823438A TW 201823438 A TW201823438 A TW 201823438A TW 106120343 A TW106120343 A TW 106120343A TW 106120343 A TW106120343 A TW 106120343A TW 201823438 A TW201823438 A TW 201823438A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
Description
本發明係有關燃燒裝置及生質燃料者,尤其是,作為燃燒裝置中使用之生質燃料係使用竹材料中混合有樹皮(bark)者。 The present invention relates to a combustion apparatus and a raw fuel, and in particular, a raw material used in a combustion apparatus is a bamboo material in which a bark is mixed.
竹子會大量生長且成長快速,在廢棄的竹林中,竹子朝周邊蔓延,侵蝕到毗鄰的杉、檜等森林,產生該生態系受到破壞等問題。 Bamboo grows in large quantities and grows rapidly. In abandoned bamboo forests, bamboo spreads around and erodes the adjacent forests such as cedar and alfalfa, causing problems such as damage to the ecosystem.
因此,近年來,對於廢棄的竹林,地方政府等進行砍伐對應之例雖增加,然而,所砍伐的竹子卻成為產業廢棄物,要處置的話亦需要費用,而在成本方面成為一大負擔。 Therefore, in recent years, there has been an increase in the number of felled bamboo forests, local governments, etc. However, the bamboo that has been felled has become industrial waste, and it requires a fee to be disposed of, and it is a burden on costs.
因此,嘗試將砍伐的竹子作為生質燃料使用。 Therefore, attempts were made to use felled bamboo as a biomass fuel.
將竹子作為燃料燃燒之燃燒裝置之一例係如第1圖所示。如第1圖所示,使燃燒室1的底部通氣,並保持作為生質燃料之竹材料21,同時裝設使焚燒之灰燼掉落的爐條(grate)11。以未圖式之送風機等送出之空氣由吸氣口14通過爐條11之複數個孔11a供給至燃燒室1內。 An example of a burning device that burns bamboo as a fuel is shown in Fig. 1. As shown in Fig. 1, the bottom of the combustion chamber 1 is ventilated, and the bamboo material 21 as a raw fuel is held, and a grate 11 for dropping the incinerated ash is installed. The air sent out by the blower or the like of the unillustrated type is supplied into the combustion chamber 1 through the plurality of holes 11a of the grate 11 through the intake port 14.
在燃燒室1之上部設置排氣管13,從該排氣 管13排出的高溫廢氣由鍋爐等進行熱利用。 An exhaust pipe 13 is provided above the combustion chamber 1, and the high-temperature exhaust gas discharged from the exhaust pipe 13 is utilized by a boiler or the like.
燃燒室1中,設置用以供給生質燃料之投入口12a,該投入口12a除了供給生質燃料以外係以蓋子12堵塞。 In the combustion chamber 1, an input port 12a for supplying raw fuel is provided, and the inlet port 12a is closed by a lid 12 in addition to the raw fuel.
將保持在爐條11上之竹材料21以未圖式之點火裝置點火,使竹材料21燃燒。由燃燒所產生的灰燼係經爐條11之孔11a掉落。 The bamboo material 21 held on the grate 11 is ignited by an ignition device of the same type to burn the bamboo material 21. The ash produced by the combustion is dropped through the hole 11a of the grate 11.
然而,竹子中係包含矽(Si)成分與鉀(K)成分,當竹子燃燒時,發生竹灰中之氧化鉀(K2O)與氧化矽(SiO2)的共晶反應。通過該共晶反應所產生的物質之融點低至800℃以下。竹子的燃燒中,燃燒室1內變成1000℃左右之溫度,通過共晶所產生的物質熔融,產生熔岩狀的熔渣塊(熔融灰)X。特別是,相較於其它的生質,竹子的鉀較多,而鉀多則熔渣塊的產生變多。 However, the bamboo contains a bismuth (Si) component and a potassium (K) component, and when the bamboo is burned, a eutectic reaction of potassium oxide (K 2 O) and cerium oxide (SiO 2 ) in the bamboo ash occurs. The melting point of the substance produced by the eutectic reaction is as low as 800 ° C or less. In the combustion of bamboo, the inside of the combustion chamber 1 becomes a temperature of about 1000 ° C, and the substance produced by the eutectic is melted to produce a lava-like slag block (molten ash) X. In particular, bamboo has more potassium than other biomass, while potassium has more slag mass.
所產生的熔渣塊X在爐條11之上擴延而堵塞爐條11之孔11a,在連續燃燒中會發生障礙。 The generated slag block X is spread over the grate 11 to block the hole 11a of the grate 11, and an obstacle occurs in continuous combustion.
如上所述,一旦產生熔渣塊X時,將阻礙燃燒室1內的燃燒空氣的流入及排出而無法持續燃燒。而且,為了去除所產生之熔渣塊X,除了需要以鎚子敲打等作業,同時亦發生爐條11等受損等問題。 As described above, when the slag block X is generated, the inflow and discharge of the combustion air in the combustion chamber 1 are hindered, and the combustion cannot be continued. Further, in order to remove the generated slag block X, in addition to the work such as hammering, it is also problematic that the grate 11 or the like is damaged.
在此,專利文獻1中揭示一種將竹子改質,並將自竹子去除鉀者作為燃料使用。在該專利文獻1中,將竹子微粒化至粒徑6mm以下,並將微粒化之竹子浸漬在常壓之水中,使鉀及氯溶出,從竹子將鉀及氯去除。然後, 將浸漬在常壓之水的竹子脫水,並將經脫水之竹子作為燃料使用。 Here, Patent Document 1 discloses a method of modifying bamboo and removing potassium from bamboo as a fuel. In Patent Document 1, the bamboo is micronized to a particle diameter of 6 mm or less, and the micronized bamboo is immersed in water at normal pressure to dissolve potassium and chlorine, and potassium and chlorine are removed from the bamboo. Then, the bamboo immersed in water at normal pressure is dehydrated, and the dehydrated bamboo is used as a fuel.
在上述專利文獻1中記載者,通過竹子的改質,將鉀自竹子去除,即可防止在作為燃料使用時熔渣塊的產生。然而,為了竹子的改質而需要在水中浸漬之步驟、將竹脫水之步驟,直到作成燃料為止之作業步驟增加,產生成本的增加等問題。 According to the above Patent Document 1, it is possible to prevent the generation of slag blocks when used as a fuel by removing the potassium from the bamboo by modifying the bamboo. However, in order to modify the bamboo, the step of immersing in water and the step of dehydrating the bamboo are required until the operation step of preparing the fuel is increased, resulting in an increase in cost and the like.
[專利文獻1]日本特開2016-125030號公報 [Patent Document 1] Japanese Laid-Open Patent Publication No. 2016-125030
本發明之課題係提供:不使成本增加並防止熔渣塊產生之燃燒裝置以及生質燃料。 An object of the present invention is to provide a combustion apparatus and a raw fuel which do not increase the cost and prevent the generation of a slag block.
本發明之燃燒裝置中,為了解決如上述之問題而將生質燃料導入燃燒室內並使上述生質燃料燃燒,其中,上述生質燃料係使用竹材料中混合有樹皮者。然後,上述樹皮係可使用針葉樹或闊葉樹之樹皮。 In the combustion apparatus of the present invention, in order to solve the above problems, the raw fuel is introduced into the combustion chamber to burn the raw fuel, and the raw material is a bamboo material in which the bark is mixed. Then, the bark system may use a bark of a conifer or a broadleaf tree.
上述燃燒裝置中,只要以燃燒後之灰燼中的氧化鈣之重量百分比大於氧化鉀的重量百分比之方式,設定上述生質燃料的竹材料與樹皮的混合比率即可。然後,以混合20重量%以上之上述樹皮者為佳。如此地設定生質 燃料之竹材料與樹皮的混合比率時,燃燒灰的融點不會降低,可防止熔渣塊的產生。 In the above combustion apparatus, the mixing ratio of the bamboo material of the raw fuel to the bark may be set so that the weight percentage of calcium oxide in the ash after combustion is greater than the weight percentage of potassium oxide. Then, it is preferred to mix 20% by weight or more of the above bark. When the mixing ratio of the bamboo material of the biomass fuel and the bark is set in this way, the melting point of the burning ash does not decrease, and the generation of the slag block can be prevented.
上述記載的燃燒裝置中,可在上述燃燒室的底面設置進行空氣供給的爐條。 In the combustion apparatus described above, a grate for supplying air can be provided on the bottom surface of the combustion chamber.
此外,本發明為,在燃燒裝置中使用作為燃料之生質燃料,上述生質燃料係在竹材料中混合有樹皮者。 Further, in the present invention, a biomass fuel as a fuel is used in the combustion apparatus, and the biomass fuel is a body in which a bark is mixed with a bamboo material.
本發明係可提供將生質燃料導入燃燒室內使上述生質燃料燃燒之燃燒裝置,上述生質燃料係在竹材料中混合有樹皮,藉此,不施行竹的改質即可防止熔渣塊的產生者,不使成本增加而使用竹材料即可使燃燒室之持續運行成為可能。 The present invention provides a combustion apparatus for introducing a raw fuel into a combustion chamber to burn the raw fuel, wherein the raw fuel is mixed with a bark in a bamboo material, thereby preventing the slag block from being modified without performing bamboo. The producer of bamboo can make the continuous operation of the combustion chamber possible without increasing the cost.
1‧‧‧燃燒室 1‧‧‧ combustion chamber
2‧‧‧生質燃料 2‧‧‧Biomass fuel
21‧‧‧竹材料 21‧‧‧Bamboo materials
22‧‧‧樹皮 22‧‧‧ bark
11‧‧‧爐條 11‧‧‧Flange
11a‧‧‧孔 11a‧‧‧ hole
12‧‧‧蓋子 12‧‧‧ cover
12a‧‧‧投入口 12a‧‧‧ Input
13‧‧‧排氣管 13‧‧‧Exhaust pipe
14‧‧‧吸氣口 14‧‧‧Intake port
第1圖係呈示在使用作為傳統生質燃料之竹材料的燃燒裝置中,產生熔渣塊之狀態的概略圖。 Fig. 1 is a schematic view showing a state in which a slag block is produced in a combustion apparatus using a bamboo material as a conventional raw material fuel.
第2圖係呈示使用作為本發明之實施型態的生質燃料之竹材料中混合有樹皮者的燃燒裝置之概略圖。 Fig. 2 is a schematic view showing a combustion apparatus in which a bark is mixed with a bamboo material which is a biomass fuel of an embodiment of the present invention.
第3圖係呈示竹材料與樹皮之混合比與生成之灰燼中的金屬氧化物之比率圖。 Figure 3 is a graph showing the ratio of the mixing ratio of bamboo material to bark to the metal oxide in the resulting ash.
以下,根據附圖,具體說明本發明之實施型態的燃燒裝置。而且,本發明之燃燒裝置並不限於下述實施型態中所示者。在不改變本發明之主旨的範圍內,可適 當變化實施。 Hereinafter, a combustion apparatus according to an embodiment of the present invention will be specifically described with reference to the accompanying drawings. Moreover, the combustion apparatus of the present invention is not limited to those shown in the following embodiments. Modifications may be made as appropriate within the scope of the gist of the invention.
本案發明者等著眼於在竹子燃燒時產生之熔渣塊的生成,經由實驗研討在竹子中混合其它生質材料時是否可抑制熔渣塊的產生。 The inventors of the present invention have focused on the generation of a slag block generated during the burning of bamboo, and have experimentally investigated whether the generation of the slag block can be suppressed when the other raw materials are mixed in the bamboo.
作為生質原料係杉木、檜木之疏伐材等之樹皮。該樹皮成為產業廢棄物,目前僅利用作為樹皮堆肥的程度,可考慮將樹皮作為生質燃料使用。 As a raw material for raw materials, it is a bark of pine and eucalyptus. The bark becomes an industrial waste, and currently only the degree of composting of the bark is utilized, and the bark can be considered as a raw material fuel.
樹皮中含有大量的鈣成分,在使樹皮燃燒時,會在灰燼中產生氧化鈣(CaO)。本案發明者等發現:該氧化鈣(CaO)於灰燼中存在時,即使燃燒竹子使氧化鉀(K2O)在灰燼中存在,亦不降低灰燼的融點,而可防止熔渣塊產生。 The bark contains a large amount of calcium, which produces calcium oxide (CaO) in the ash when the bark is burned. The inventors of the present invention found that when the calcium oxide (CaO) is present in the ash, even if the bamboo is burned to cause potassium oxide (K 2 O) to be present in the ash, the melting point of the ash is not lowered, and the slag block can be prevented from being generated.
因此,本發明係將竹材料中混合樹皮者作為生質燃料使用,使在燃燒室1內燃燒者。參照第2圖說明本發明之實施型態。 Therefore, in the present invention, a person who mixes bark in a bamboo material is used as a biomass fuel to burn in the combustion chamber 1. An embodiment of the present invention will be described with reference to Fig. 2.
呈示本發明之實施型態的第2圖中,燃燒裝置係與第1圖所示者為相同構成,在相同部分附上相同符號,為了避免重複說明,在此省略說明。 In the second embodiment of the present invention, the same components as those in the first embodiment are denoted by the same reference numerals, and the same reference numerals will be given to the same parts, and the description thereof will be omitted.
如第2圖所示,在燃燒室1中設置用以供給生質燃料之投入口12a,從該投入口12a投入在竹材料21中混合樹皮22之生質燃料2。然後,使在竹材料21中混合樹皮22之生質燃料2燃燒。第2圖中,生質燃料2中之樹皮22塗成黑點。 As shown in Fig. 2, the combustion chamber 1 is provided with an input port 12a for supplying raw fuel, and the raw material fuel 2 for mixing the bark 22 in the bamboo material 21 is introduced from the input port 12a. Then, the biomass fuel 2 in which the bark 22 is mixed in the bamboo material 21 is burned. In Fig. 2, the bark 22 in the raw fuel 2 is painted as a black spot.
如上所述,將適量的杉木、檜木等之針葉樹 的樹皮22混合在竹材料21中,可防止熔渣塊的產生。其結果,不會因熔渣塊而堵塞爐條11之孔11a,燃燒用的空氣可由爐條11之孔11a供給,可持續連續燃燒。樹皮22亦可使用針葉樹以外之闊葉樹樹皮。 As described above, an appropriate amount of the bark 22 of the coniferous tree such as Chinese fir or eucalyptus is mixed in the bamboo material 21 to prevent the generation of the slag block. As a result, the hole 11a of the grate 11 is not blocked by the slag block, and the air for combustion can be supplied from the hole 11a of the grate 11, and continuous combustion can be continued. The bark 22 can also use the broad-leaved tree bark other than the conifer.
而且,竹材料係可直接將竹切斷或作成碎片狀等,以加工成易於燃燒者為佳。 Further, the bamboo material can be directly cut into bamboo or formed into a chip shape, etc., and it is preferable to process it into a person who is easy to burn.
表1係呈示依據JIS M8801「灰燼的熔融特性溫度測定」測定使竹材料與樹皮混合並改變其混合比率使其燃燒時之燃燒灰燼的軟化點、融點及熔流點之熔融特性的結果。將在竹材料30重量%與樹皮70重量%、竹材料50重量%與樹皮50重量%、竹材料80重量%與樹皮20重量%之3種狀態燃燒而成之灰燼進行回收。使用該灰燼製作試驗錐,在爐內連續加熱,測定試驗錐之形狀發生特定變化時之溫度。此處,軟化點係試驗錐之頂點部開始融化變圓之溫度、融點係試驗錐熔融,其高度成為表觀底部寬度的1/2時之溫度、熔流點係熔融物在支撐台流動,成為融點時高度的1/3高度時的溫度。 Table 1 shows the results of measuring the melting characteristics of the softening point, the melting point, and the melting point of the burning ash when the bamboo material is mixed with the bark and the mixing ratio thereof is changed in accordance with JIS M8801 "Measurement of the melting characteristic temperature of the ash". The ash was burned in three states of 30% by weight of bamboo material and 70% by weight of bark, 50% by weight of bamboo material and 50% by weight of bark, 80% by weight of bamboo material, and 20% by weight of bark. A test cone was produced using the ash, and heating was continuously performed in the furnace to measure the temperature at which the shape of the test cone was specifically changed. Here, the softening point is the temperature at which the apex portion of the test cone starts to melt and round, the melting point test cone is melted, the height becomes the temperature of 1/2 of the apparent bottom width, and the melt point melt flows on the support table. It becomes the temperature at the height of 1/3 of the height of the melting point.
如表1所示,在竹材料中混合樹皮使其燃燒時,即使在竹材料80重量%與樹皮20重量%之混合比率時的燃燒灰燼中,融點亦為1250℃。可知因燃燒室1內之溫度為1000℃左右,故燃燒灰燼不會熔融而可防止熔渣塊的產生。 As shown in Table 1, when the bark was mixed and burned in the bamboo material, the melting point was 1,250 ° C even in the combustion ash at a mixing ratio of 80% by weight of the bamboo material to 20% by weight of the bark. It can be seen that since the temperature in the combustion chamber 1 is about 1000 ° C, the combustion ash does not melt and the generation of the slag block can be prevented.
接著,在竹材料中使樹皮混合,改變其混合比率使其燃燒時,測定所產生的氧化鉀(K2O)、氧化鈣(CaO)、氧化矽(SiO2)等金屬氧化物的重量,並將測定其重量%比率的結果呈示於第3圖。第3圖中,黑點為氧化矽(SiO2)、黑三角為氧化鉀(K2O)、黑四角為氧化鈣(CaO)。 Next, when the bark is mixed in the bamboo material and the mixing ratio is changed to burn, the weight of the metal oxide such as potassium oxide (K 2 O), calcium oxide (CaO), or cerium oxide (SiO 2 ) is measured. The result of measuring the weight % ratio is shown in Fig. 3. In Fig. 3, the black dots are cerium oxide (SiO 2 ), the black triangles are potassium oxide (K 2 O), and the black squares are calcium oxide (CaO).
如第3圖所示,即使改變竹材料與樹皮之混合比率,氧化矽(SiO2)之比率亦無多大變化,增加竹材料之混合比率時,氧化鉀(K2O)增加而氧化鈣(CaO)減少。然後,直到竹材料成為85重量%、樹皮成為15重量%,灰燼中之氧化鈣(CaO)比氧化鉀(K2O)更多。氧化鈣(CaO)多的情況下,灰燼的融點為1127℃以上,不會產生熔渣塊。 As shown in Fig. 3, even if the mixing ratio of bamboo material to bark is changed, the ratio of cerium oxide (SiO 2 ) does not change much. When the mixing ratio of bamboo material is increased, potassium oxide (K 2 O) increases and calcium oxide ( CaO) is reduced. Then, until the bamboo material became 85% by weight and the bark became 15% by weight, the calcium oxide (CaO) in the ash was more than potassium oxide (K 2 O). When there is a large amount of calcium oxide (CaO), the melting point of the ash is 1127 ° C or more, and no slag block is generated.
因此,以燃燒後的灰燼中之氧化鈣(CaO)的重量%比氧化鉀(K2O)的重量%更多之方式,設定生質燃料中之竹材料21與樹皮22之混合比率即可。 Therefore, the mixing ratio of the bamboo material 21 and the bark 22 in the raw fuel can be set such that the weight % of calcium oxide (CaO) in the burned ash is more than the weight % of potassium oxide (K 2 O). .
從第3圖可知,直到竹材料21成為85重量%、樹皮22成為15重量%,灰燼中之氧化鈣(CaO)比氧化鉀(K2O)更多,惟竹或樹皮皆為自然界中生長之物,由於該等之中所存在的鈣、鉀多寡不一,故為了確實使灰燼中之氧化鈣(CaO)比氧化鉀(K2O)更多,期待使用混合有20重量 %以上之樹皮22、與80重量%以下之竹材料21之生質燃料2。 As can be seen from Fig. 3, until the bamboo material 21 is 85% by weight and the bark 22 is 15% by weight, the calcium oxide (CaO) in the ash is more than the potassium oxide (K 2 O), but the bamboo or bark is grown in nature. Since there are many kinds of calcium and potassium present in these, it is expected that the calcium oxide (CaO) in the ash is more than potassium oxide (K 2 O), and it is expected to use 20% by weight or more of the mixture. The bark 22 and the biomass fuel 2 of the bamboo material 21 of 80% by weight or less.
而且,樹皮容易纏繞,只有樹皮將容易形成團聚物而難以作為燃料使用,若使樹皮22與竹材料21混合存在,樹皮22間之纏繞將被竹材料21抑制而可抑制團聚物之形成,亦有所謂容易作為生質燃料2進行處理之優點。如此即可提供一種生質燃料,不用進行竹的改質等,即可將無法使用的產業廢棄物之竹子與樹皮加以利用而不產生熔渣塊者。 Further, the bark is easily entangled, and only the bark is likely to form agglomerates and is difficult to be used as a fuel. If the bark 22 is mixed with the bamboo material 21, the entanglement between the bark 22 is suppressed by the bamboo material 21, and the formation of agglomerates can be suppressed. There is an advantage that it is easy to handle as the raw fuel 2 . In this way, a raw material fuel can be provided, and bamboo and bark of industrial waste that cannot be used can be utilized without generating a slag block without modifying the bamboo.
在燃燒室1之底面設置有爐條11者之中,使用上述本發明之混合竹材料21與樹皮22的生質燃料2使其燃燒時,不會引起熔渣塊的產生,不但可維持燃燒空氣的供給,且灰燼會從爐條11之孔11a往下掉落。 In the case where the grate 11 is provided on the bottom surface of the combustion chamber 1, when the mixed bamboo material 21 of the present invention and the biomass fuel 2 of the bark 22 are burned, the slag block is not generated, and combustion can be maintained. The supply of air, and the ash falls down from the hole 11a of the grate 11.
第2圖所示之燃燒裝置係在燃燒室1之底面設置供給空氣之爐條11,並從底部供給燃燒空氣,惟燃燒室之型態並不限於此,各種燃燒室之本發明都可被應用。 The combustion apparatus shown in Fig. 2 is provided with a furnace strip 11 for supplying air on the bottom surface of the combustion chamber 1, and supplies combustion air from the bottom, but the type of the combustion chamber is not limited thereto, and the present invention of various combustion chambers can be application.
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