TW201807082A - Colorant dispersion liquid, colored polymerizable composition, and color filter - Google Patents

Abstract

Provided is a colorant dispersion liquid with which a colored polymerizable composition capable of forming a highly precise pattern having a high light-shielding property and high resistivity can be produced. The colorant dispersion liquid (E) is characterized by containing a polymerizable compound (A) represented by general formula (I), a colorant (B), a dispersant (C), and a dispersion medium (D). In the colorant dispersion liquid (E), the colorant (B) is preferably a black pigment. As the dispersant (C), a polymeric dispersant made from polyurethane having a nitrogen atom as a basic functional group is preferable. The colorant (B) is preferably a black pigment.

Description

Colorant dispersion liquid, colored polymerizable composition, and color filter

The present invention relates to a coloring agent dispersion liquid, a coloring polymerizable composition containing the coloring agent dispersion liquid of the present invention, a hardened material and a black matrix obtained by hardening the colored polymerizable composition, and the hardened material or the black material. Matrix color filters.

Previously, color filters have been widely used for the purpose of colorization of liquid crystal display devices and the like, and red, green, and blue pixels are usually arranged in a mosaic shape. As a method for producing the color filter, a dyeing method, a printing method, an inkjet method, an electrodeposition method, a colorant dispersion method, and the like are known. In particular, a coloring agent dispersion method using a coloring polymerizable composition for a color filter in which a photosensitive polymer and / or a photosensitive monomer is dispersed together with a coloring agent and forming fine pixels by a photolithography method is used. Because of its excellent flatness, it has become the mainstream of color filter manufacturing methods. The coloring composition for a color filter contains a pigment, a solvent, a dispersant, a photopolymerizable unsaturated compound, a photopolymerization initiator, and the like. Since the coloring composition containing a photopolymerization initiator can be polymerized and hardened by irradiating ultraviolet rays or electron beams, it is useful for a filter section and the like constituting a color filter. The filter section is formed by exposing a coating material obtained by coating a photosensitive material on a glass substrate or the like to remove the remaining solvent, and then exposing the coating material to a photomask for forming a pixel by exposing the coating material. The active energy ray is irradiated to harden (negative type) or increase the alkali solubility (positive type), and then after the dissolved part is removed by an alkali solution, etc., a heating of 230 degrees or more called post-baking is performed. When a pigment is used for the said coloring composition for color filters, when preparing a coloring composition, the pigment dispersion liquid in which the pigment was previously disperse | distributed to resin or a dispersion medium is prepared normally. In recent years, in order to improve the quality of color imaging elements and color liquid crystal televisions, high definition of display panels has been strongly demanded. Therefore, the industry is continuously researching a colored polymerizable composition for a color filter that can form a black matrix with high light shielding properties, high resistance, and high definition. However, there is a problem that a black matrix having both light-shielding properties and high resistance cannot be obtained with the conventional colored polymerizable composition for color filters. Patent Document 1 discloses a colored polymerizable composition using an acid-modified novolac epoxy acrylate or an acid-modified bisphenol A epoxy acrylate as a dispersion resin. Patent Document 2 discloses a photocurable composition using a novolak-type bisphenol A epoxy acrylate as a covering material of carbon black; Patent Document 3 discloses a photosensitive composition using a novolak-type double An acid-modified product of phenol A epoxy acrylate is used as an alkali-soluble resin. However, a coloring polymerizable composition for a color filter with high light-shielding properties, high resistance, and high definition has not yet been obtained. Prior Art Literature Patent Literature Patent Literature 1: Japanese Patent Laid-Open No. 2010-014961 Patent Literature 2: Japanese Patent Laid-Open No. 2003-015278 Patent Literature 3: WO2008 / 023675 Specification

Therefore, an object of the present invention is to provide a coloring agent dispersion liquid, a coloring polymerizable composition containing the coloring agent dispersion liquid of the present invention, a hardened body and a black matrix obtained by hardening the colored polymerizable composition, and having the above hardening. Object or the color filter of the black matrix. Another object of the present invention is to provide a colored polymerizable composition capable of forming a pattern with high light-shielding properties, high resistance, and high definition, and in particular, when carbon black is used as a colorant, it can form high-light-shielding properties and high Resistive, high-definition patterned polymerizable composition. The present inventors made diligent research on the above-mentioned problems, and as a result, they found that the polymerizable compound (A), the colorant (B), the dispersant (C), and the dispersion medium (D) were contained. The coloring agent dispersion liquid (E) and the coloring polymerizable composition containing the colorant dispersion liquid (E), the ethylenically unsaturated compound (F), and the polymerization initiator (G) can solve the above problems, thereby completing the present invention. invention. [Chemical 1] When (in the ^{formula, R 1, R 2, R} 3, R 4, R 5 and R ⁶ each independently represent a hydrogen atom or a methyl group, in the case of the presence of a plurality of R ^3, plural R ³ are the same or different is also present In the case where there is a plurality of R ⁴ , the plurality of R ⁴ are the same or different, respectively. Y ¹ , Y ² , Y ³ , Y ⁴ , Y ^5, and Y ⁶ (hereinafter, also referred to as Y ¹ ~ ^{Y. 6)} each independently represent a single bond, carbon atoms or a hydrocarbon group of 1 to 20 carbon atoms of the heterocyclic ring containing from 2 to 20, the time in the presence of a plurality Y of the case ^3, a plurality of Y ³ are the same or There are also different situations. When there is a plurality of Y ⁴ , the plurality of Y ⁴ are the same or different. Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ⁶ (hereinafter, also Described as Z ¹ to Z ⁶ ) each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms substituted with a carboxyl group, or a group containing 1 to 20 carbon atoms containing a heterocyclic ring substituted with a carboxyl group, in the presence of a plurality of Z ³ when the case, a plurality of Z ³ are the same or different situations also exist, in case the presence of a plurality of Z ^4, the plurality of Z ⁴ are the same or different is also present The case, Y ¹ ~ Y ⁶ and Z represents a number of carbon atoms of the hydrocarbon group ^{having 1} to Z ^{1. 6} to 20, and the Y ¹ ~ Y ⁶ and Z ¹ to ^{Z. 6} indicated the number of carbon atoms of the heterocyclic ring containing from 2 to 20 The hydrogen atom of the radical is substituted by a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, a methacryl group, an acryl group, an epoxy group, a vinyl group, a mercapto group, an isocyanate group, or a heterocyclic group. the case group the ring, Y ¹ ~ Y ⁶ and Z ¹ ~ Z ⁶ represents the carbon atoms of the hydrocarbon group having 1 to 20 of the indicated number of carbon atoms contained in the heterocyclic ring and Y ¹ ~ Y ⁶ and Z ¹ ~ Z ⁶ When the methylene group in the 2-20 group is substituted with -O-, -CO-, -COO-, -OCO-, -S-, -SO _2- , -SCO-, or -COS-, M ¹ , M ² and M ³ (hereinafter also referred to as M ¹ to M ³ ) each independently represent an alkanediyl group having 1 to 5 carbon atoms, a cycloalkyldiyl group or sulfofluorenyl group having 3 to 10 carbon atoms, carbon atoms, a hydrogen atom carbon atoms and M ¹ ~ M ³ represented by the alkoxy group having 1 to 5 bis and M ¹ ~ M ³ represented by the two groups of the cycloalkyl group of 3 to 10 substituted by a halogen atom is present, carbon In the case of an alkyl group having 1 to 5 atoms or an aryl group having 6 to 12 carbon atoms, When the number M case ^2, the plurality of M ² are the same or there is also a different case, m represents a positive number of 0 or 10 or less of) further, the present invention provides a method to make the colored polymerizable composition was cured from the cured, A black matrix obtained by curing the colored polymerizable composition, and a color filter having the cured product or the black matrix.

Hereinafter, the coloring agent dispersion liquid (E) and the coloring polymerizable composition of this invention are demonstrated based on a preferable embodiment. The colorant dispersion liquid (E) of the present invention is a colorant dispersion liquid including a polymerizable compound (A), a colorant (B), a dispersant (C), and a polymerizable compound represented by the general formula (I). Dispersion medium (D). <Polymerizable compound (A)> The polymerizable compound (A) used in the toner dispersion liquid (E) of the present invention may be colored as long as it is a compound represented by the general formula (I), and it is colored. In terms of excellent dispersibility of the agent, a compound represented by the following general formula (II) is particularly preferred. [Chemical 2] (Where, R ¹¹ , R ¹² , R ¹³ , R ¹⁴ , R ¹⁵ And R ¹⁶ Each independently represents a hydrogen atom or a methyl group, in the presence of a plurality of R ¹³ In the case of plural R ¹³ The same or different situations exist, in the presence of a plurality of R ¹⁴ In the case of plural R ¹⁴ Respectively the same or different situations, Z ¹ ,Z ² ,Z ³ ,Z ⁴ ,Z ⁵ And Z ⁶ (Hereinafter also referred to as Z ¹ ~ Z ⁶ ) Each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms substituted by a carboxyl group, or a carbon group having 1 to 20 carbon atoms substituted with a carboxyl group, in the presence of a plurality of Z ¹³ In the case of a plurality of Z ³ The same or different situations exist, in the presence of a plurality of Z ¹⁴ In the case of a plurality of Z ⁴ Respectively the same or different situations, Z ¹¹ ~ Z ¹⁶ Represented hydrocarbon group with 1 to 20 carbon atoms and Z ¹¹ ~ Z ¹⁶ The represented hydrogen atom containing a heterocyclic carbon group having 2 to 20 carbon atoms is substituted with a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, a methacryl group, acryl group, epoxy In the case of vinyl, mercapto, isocyanate, or heterocyclic containing groups, Z ¹¹ ~ Z ¹⁶ Represented hydrocarbon group with 1 to 20 carbon atoms and Z ¹¹ ~ Z ¹⁶ The methylene group in the 2 to 20 carbon atom group represented by the heterocyclic ring is substituted with -O-, -CO-, -COO-, -OCO-, -S-, -SO ₂ -, -SCO- or -COS-, n represents a positive number below 0 or 10) Y in the above general formulae (I) and (II) ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ A single bond, a hydrocarbon group having 1 to 20 carbon atoms, or a heterocyclic-containing carbon group having 2 to 20 carbon atoms. In Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ In the case of a hydrocarbon group having 1 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ Hydrogen atom of a hydrocarbon group having 1 to 20 carbon atoms, and Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ The represented hydrogen atom containing a heterocyclic carbon group having 2 to 20 carbon atoms is substituted with a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, a methacryl group, acryl group, epoxy In the case of a group, a vinyl group, a mercapto group, an isocyanate group, or a heterocyclic-containing group. Also, in Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ A hydrocarbon group having 1 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, and a hydrocarbon group having 1 to 20 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms having a methylene group In this case, the methylene group is substituted with -O-, -CO-, -COO-, -OCO-, -S-, -SO ₂ -, -SCO- or -COS-. Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ The hydrocarbon group having 1 to 20 carbon atoms is not particularly limited, but preferably an alkyldiyl group having 1 to 20 carbon atoms, an olefin diyl group having 2 to 20 carbon atoms, and a ring having 3 to 20 carbon atoms Alkyldiyl, cycloalkylalkadiyl having 4 to 20 carbon atoms, aryldiyl having 6 to 20 carbon atoms, arylalkanediyl having 7 to 20 carbon atoms, and the like. Examples of the alkanediyl group having 1 to 20 carbon atoms include methanediyl, ethanediyl, propanediyl, isopropanediyl, butanediyl, isobutanediyl, and second butane. Diyl, third butanediyl, pentanediyl, isopentanediyl, third pentanediyl, hexanediyl, heptanediyl, octanediyl, isooctanediyl, 2 -Ethylhexanediyl, third octanediyl, nonanediyl, isononanediyl, decanediyl, isodecanediyl, undecanediyl, dodecanediyl, ten Tetradanediyl, cetanediyl and octadecyldiyl. Examples of the olefin diyl group having 2 to 20 carbon atoms include ethanediyl, propylenediyl, 3-butenediyl, 2-butenediyl, 4-pentenediyl, and 3-pentene. Alkenyldiyl, 2-hexenediyl, 3-hexenediyl, 5-hexenediyl, 2-heptenediyl, 3-heptenediyl, 4-heptenediyl, 3-octene Diyl, 3-nonenediyl, 4-decenediyl, 3-undecenediyl, 4-dodecenediyl, and 3-cyclohexenediyl. The above-mentioned cycloalkanediyl group having 3 to 20 carbon atoms means a saturated monocyclic or saturated polycyclic alkyl group having 3 to 20 carbon atoms. Examples of the cycloalkanediyl group having 3 to 20 carbon atoms include cyclopropanediyl, cyclobutanediyl, cyclopentanediyl, cyclohexanediyl, cycloheptanediyl, and cyclooctane. Diyl, cyclononanediyl, cyclodecanediyl, adamantanediyl, decalin diyl, octahydropentanediyl, bicyclo [1.1.1] pentanediyl and tetradecahydroanthracene diyl Wait. The above-mentioned cycloalkylalkanediyl group having 4 to 20 carbon atoms refers to a group having 4 to 20 carbon atoms in which a hydrogen atom of the alkanediyl group is replaced with a cycloalkyl group. Examples of the cycloalkylalkyldiyl group having 4 to 20 carbon atoms include cyclopropylmethanediyl, cyclobutylmethanediyl, cyclopentylmethanediyl, cyclohexylmethanediyl, and cycloheptyl. Methanediyl, cyclooctylmethanediyl, cyclononylmethanediyl, cyclodecylmethanediyl, 2-cyclobutylethanediyl, 2-cyclopentylethanediyl, 2-cyclohexylethyl Alkanediyl, 2-cycloheptylethanediyl, 2-cyclooctylethanediyl, 2-cyclononylethanediyl, 2-cyclodecylethanediyl, 3-cyclobutylpropane Diyl, 3-cyclopentylpropanediyl, 3-cyclohexylpropanediyl, 3-cycloheptylpropanediyl, 3-cyclooctylpropanediyl, 3-cyclononylpropanediyl, 3-cyclo Decylpropanediyl, 4-cyclobutylbutanediyl, 4-cyclopentylbutanediyl, 4-cyclohexylbutanediyl, 4-cycloheptylbutanediyl, 4-cyclooctyl Butanediyl, 4-cyclononylbutanediyl, 4-cyclodecylbutanediyl, 3-3-adamantylpropanediyl, decalinylpropanediyl and the like. Examples of the aryldiyl group having 6 to 20 carbon atoms include benzenediyl, toluenediyl, xylenediyl, ethylbenzenediyl, naphthalenediyl, anthracenediyl, phenanthryldiyl, and diphenyl Benzenediyl and so on. The aforementioned arylalkanediyl group having 7 to 30 carbon atoms means a group having 7 to 30 carbon atoms in which a hydrogen atom of the alkanediyl group is substituted with an aryl group. Examples of the arylalkanediyl group having 7 to 30 carbon atoms include benzyl, α-methylbenzyl, α, α-dimethylbenzyl, phenylethyl, and naphthylpropyl. The arylalkyl group having 7 to 20 carbon atoms means a group having 7 to 30 carbon atoms in which a hydrogen atom of an alkyl group is replaced with an aryl group. Examples include benzyl, α-methylbenzyl, α, α-dimethylbenzyl, and phenylethyl. So-called Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ The radical having 2 to 20 carbon atoms containing a heterocyclic ring means a radical containing at least one heterocyclic ring and having 2 to 20 carbon atoms as a whole. Examples of the heterocyclic-containing carbon atom group having 2 to 20 carbon atoms include pyrrolediyl, pyridyldiyl, pyridylethanediyl, pyrimidinediyl, piperidine &#134116; diyl, piperidinediyl, Pyranyl diyl, pyranyl ethane diyl, pyrazoline diyl, tri &#134116; diyl, tri &#134116; methanediyl, quinoline diyl, isoquinoline diyl, imidazoline Diyl, benzimidazolone diyl, furan diyl, benzofuran diyl, thiophene diyl, benzothiophene diyl, thiadiazolyl, thiazolyl, benzothiazolyl, oxazolyl, benzofluorene An oxazolyl, isothiazolyl diyl, isofluorenone diyl, indololinyl diyl, morpholine diyl, thiomorpholine diyl, and the like. When the heterocyclic ring-containing group has a substituent in the heterocyclic group, the number of carbon atoms in the entire group may exceed 20. In the case where the heterocyclic ring has a substituent having 2 to 20 carbon atoms, examples of the substituent include a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, and a methyl group. Acrylic fluorenyl, propylene fluorenyl, epoxy, vinyl, mercapto or isocyanate. As the above M ¹ ~ M ³ Examples of the alkanediyl group having 1 to 5 carbon atoms include methanediyl, ethanediyl, propanediyl, butanediyl, and butanediyl. In terms of good compatibility with the coloring agent (B), the above-mentioned M ¹ ~ M ³ The alkanediyl group having 1 to 5 carbon atoms represented is preferably methanediyl, ethanediyl and propanediyl, and most preferably propanediyl. The above-mentioned M ¹ ~ M ³ The cycloalkyldiyl group having 3 to 10 carbon atoms means a saturated monocyclic or saturated polycyclic alkyldiyl group having 3 to 10 carbon atoms. As the above M ¹ ~ M ³ Examples of the cycloalkyldiyl group having 3 to 10 carbon atoms include cyclopropyldiyl, cyclobutyldiyl, cyclopentyldiyl, cyclohexyldiyl, cycloheptyldiyl, and cyclo Octyldiyl, cyclononyldiyl, cyclodecyldiyl, adamantyldiyl, decahydronaphthyldiyl, octahydrocyclopentadienediyl, and bicyclo [1.1.1] pentyldiyl For example, in terms of good compatibility and dispersibility with the coloring agent of the polymerizable compound (A), bicyclo [1.1.1] pentyldiyl is more preferred. As a substitute for the above M ¹ ~ M ³ Examples of the alkanediyl group having 1 to 5 carbon atoms and the cycloalkyldiyl group having 3 to 10 carbon atoms include the alkyl group having 1 to 5 carbon atoms. Examples include methyl, ethyl, Propyl, isopropyl, butyl, isobutyl, second butyl, third butyl, pentyl, isopentyl and third pentyl. As a substitute for the above M ¹ ~ M ³ Examples of the alkanediyl group having 1 to 5 carbon atoms and the aryl group having 6 to 12 carbon atoms in the hydrogen atom of the cycloalkyldiyl group having 3 to 10 carbon atoms include phenyl, tolyl, Xylyl, ethylphenyl and naphthyl. As replaceable Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ Hydrogen atom of a hydrocarbon group having 1 to 20 carbon atoms, Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ A hydrogen atom containing 2 to 20 carbon atoms containing a heterocyclic ring, M ¹ ~ M ³ Alkanediyl having 1 to 5 carbon atoms, and M ¹ ~ M ³ Examples of the halogen atom represented by a hydrogen atom of a cycloalkyldiyl group having 3 to 10 carbon atoms include fluorine, chlorine, bromine, and iodine. As replaceable Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ Hydrogen atom of a hydrocarbon group having 1 to 20 carbon atoms, and Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ The heterocyclic-containing group containing a hydrogen atom having 2 to 20 carbon atoms in the heterocyclic ring group can be exemplified as Y ¹ ~ Y ⁶ ,Z ¹ ~ Z ⁶ And Z ¹¹ ~ Z ¹⁶ The exemplified is a group containing 2 to 20 carbon atoms containing a heterocyclic ring. In the general formula (I), m is a positive number of 0 or less. In terms of good compatibility in the dispersion medium (D) and good dispersibility of the colorant, m is preferably from 2 to 10. If m is less than 2, the dispersibility of the colorant is poor, and if m is greater than 10, the dispersibility into the dispersant is poor. In the general formula (II), n is a positive number of 0 or less. In terms of good compatibility in the dispersion medium (D) and good dispersibility of the colorant (B), n is preferably from 2 to 10. If n is less than 2, the dispersibility of the colorant (B) is poor, and if n is greater than 10, the dispersibility into the dispersant (C) is poor. The polymerizable compound (A) can be produced according to the following reaction formula [Chemical Formula 3]. That is, the method for producing the polymerizable compound (A) is well known. By reacting a commercially available epoxy compound with an unsaturated monobasic acid such as acrylic acid, the following compound A-1 can be obtained, and the obtained compound A- 1 Further reacted with a polyacid such as phthalic anhydride to obtain the following compound A-2. [Chemical 3] Examples of the unsaturated monobasic acid that reacts with an epoxy compound include acrylic acid, methacrylic acid, 2-propenyloxyethylphthalic acid, and 2-methacryloxyethylphthalic acid. Formic acid, 2-propenyloxyethyl succinic acid, 2-methacryloxyethyl succinic acid, 2-propenyloxyethyl succinate, 2-methacryloxyethyl succinate, 2-propenyloxyethyl-2-hydroxyethyl phthalic acid, 2-methacryloxyethyl-2-hydroxyethyl phthalic acid, 2-propenyloxyethyl hexahydro Phthalic acid, 2-methacryloxyethylhexahydrophthalic acid, pentaerythritol pentaacrylate succinic acid modified product, pentaerythritol pentaacrylate phthalic acid modified product, pentaerythritol pentaerythritol pentaacrylate succinic acid Modified products and pentaerythritol pentaacrylate phthalic acid modified products. In terms of easy handling and high reaction rate, as the unsaturated monobasic acid, acrylic acid and methacrylic acid are preferred, and in terms of the good reactivity of the obtained polymerizable compound (A), the most preferred is acrylic acid. As the unsaturated monobasic acid, a commercially available product can be used. Examples of commercially available products of unsaturated monobasic acids include NK ESTER A-SA, SA, CB-1 (manufactured by Shin Nakamura Chemical Industry Co., Ltd.), Lightester A, HOA-MS, HO-MS, HOA-MPE, HOA- HH, HOA-MPL, DPE6A-MS, PE3A-MS, DPE6A-MP and PE3A-MP (manufactured by Kyoeisha Co., Ltd.) and ARONIX M-5300 (East Asia Synthesis), etc. Examples of the polybasic acid anhydride that reacts with the compound A-1 include biphenyltetracarboxylic dianhydride, tetrahydrophthalic anhydride, succinic anhydride, maleic anhydride, trimellitic anhydride, and homobenzene Tetraformic anhydride, 2,2 ', 3,3'-benzophenonetetracarboxylic dianhydride, hexahydrophthalic anhydride, methyltetrahydrophthalic anhydride, geo-anhydride, methyl Acid anhydride and dodecenyl succinic anhydride. The toner dispersion liquid (E) of the present invention may contain the following ethylenically unsaturated compound (F) in addition to the polymerizable compound (A). The content of the ethylenically unsaturated compound (F) in the toner dispersion liquid (E) of the present invention is not particularly limited, but it is preferably 10 parts by mass or less with respect to 100 parts by mass of the polymerizable compound (A). In the colorant dispersion liquid (E) of the present invention, the content of the polymerizable compound (A) is not particularly limited. The colorant dispersion is contained in 100 parts by mass of the total solid content of the colorant dispersion liquid (E). In terms of good properties, it is preferably 1 to 30 parts by mass, and more preferably 3 to 20 parts by mass. When the content of the polymerizable compound (A) is less than 1 part by mass, the dispersibility of the colorant may be poor, and when it is more than 30 parts by mass, sufficient coloring may not be exhibited. When using a colorant dispersion liquid (E), for example, when manufacturing a coloring composition for black matrices, regarding the content of the polymerizable compound (A) in the colorant dispersion liquid (E), the solid matter in the colorant dispersion liquid (E) Of the total 100 parts by mass of the components, 1 to 30 parts by mass is preferred, and 3 to 20 parts by mass is more preferred. <Colorant (B)> As the colorant (B) used in the colorant dispersion liquid (E) of the present invention, pigments and dyes can be used. As the pigment and dye, an inorganic colorant or an organic colorant can be used separately, and these can be used alone or in combination of two or more. Here, the pigment refers to a coloring agent that is insoluble in the dispersion medium (D) described below, and also includes inorganic or organic colorants or inorganic or organic dyes, especially those that are insoluble in the dispersion medium (D), or to inorganic or organic pigments. The dye is laked. Examples of the pigment include carbon black obtained by a furnace method, a chimney method, or a thermal method, or carbon black such as acetylene black, Ketjen black, or lamp black, and the carbon black adjusted or coated with an epoxy resin. Those who have prepared the carbon black by dispersing the resin in a solvent in advance and coated it with a resin of 20 to 200 mg / g, and those who have acid or alkaline surface treatment on the carbon black. The average particle size is 8 Carbon black with DBP (dibutyl phthalate) above 90 nm and oil absorption of 90 ml / 100 g or less, based on CO and CO in volatile matter at 950 ° C ₂ Calculated total oxygen content per 100 m of surface area ² Carbon black, graphite, graphitized carbon black, activated carbon, carbon fiber, nano carbon tube, spiral carbon fiber, carbon nano angle, carbon aerogel, fullerene, aniline black, perylene black, internal Black pigments represented by fluorene black, pigment black 7, titanium black, etc., chrome oxide green, milori blue, cobalt green, cobalt blue, manganese, ferrocyanide, phosphate ultramarine blue, Prussian blue, sea blue, sky blue , Organic green or inorganic pigments such as chrome green, emerald green, lead sulfate, yellow dan, zinc yellow, iron dan (red iron (III) oxide), cadmium red, synthetic iron black, brown earth, lake pigment, etc. In terms of high light-shielding properties, a black pigment is preferably used, and carbon black is more preferably used. Among the above carbon blacks, in terms of obtaining a colorant dispersion liquid having excellent dispersibility, and obtaining a hardened material having excellent light-shielding properties and good adhesion to substrates such as glass, it is preferable to have a sulfonic acid on the surface of the carbon black. Acid-based carbon black. Examples of the method for imparting a sulfonic acid group to the surface of the carbon black include a method (1) for oxidizing carbon black with peroxodisulfuric acid or a salt thereof, and a method (2) for treating carbon black with a sulfonating agent. The method (1) for oxidizing carbon black by using peroxydisulfuric acid or a salt thereof can be performed by any known method. For example, it can be carried out by mixing carbon black, peroxydisulfuric acid or a salt thereof, and an aqueous medium (water or a mixture of water and a water-soluble solvent) with a surfactant or a dispersant as needed, and mixing the mixture in The temperature is lowered to 100 ° C, preferably 40 to 90 ° C, and stirred and heated for less than 24 hours, preferably 2 to 20 hours, and neutralized to pH ≧ 7 if necessary. Examples of the salt of peroxydisulfuric acid include metal salts or ammonium salts of lithium, sodium, potassium, and aluminum. The usage-amount of peroxodisulfuric acid or its salt is used in the range of 0.5-5 mass parts with respect to 1 mass part of carbon black. The method (2) for treating carbon black by using a sulfonating agent can be performed by any known method. For example, carbon black and the sulfonating agent can be mixed or dissolved in a solvent at a temperature of 200 ° C or lower, preferably at Stir at 0-100 ° C. Examples of the sulfonating agent include concentrated sulfuric acid, oleum, sulfur trioxide, halogenated sulfuric acid, amidosulfonic acid, bisulfite, sulfite, and SO ₃ -Dioxane complex, SO ₃ -Ketone complexes, sulfamic acid, sulfonated pyridine salts, and the like. As the solvent, water can be used; acidic solvents such as sulfuric acid, oleum, formic acid, acetic acid, propionic acid, and acetic anhydride; basic solvents such as pyridine, triethylamine, and trimethylamine; ethers such as tetrahydrofuran, dioxane, and diethyl ether Class; dimethylformamide, dimethylacetamide, N-methylpyrrolidone, cyclobutane, nitromethane, acetone, acetonitrile, benzonitrile and other polar solvents; ethyl acetate, butyl acetate Esters; aromatic solvents such as benzene, toluene, xylene, nitrobenzene; alcohol solvents such as methanol, ethanol, isopropanol; chloroform, trichlorofluoromethane, dichloromethane, chlorobenzene, etc. There are also situations where such mixed solvents are used. The use amount of the sulfonating agent is preferably within a range of 0.5 to 20 parts by mass relative to 1 part by mass of carbon black. When a plurality of types of sulfonating agents are used, the total amount thereof is preferably within the above range. In addition, in order to suppress the formation of a known tritium produced as a side reaction of the sulfonation reaction, there is a known tritium inhibitor that is added in an amount of 0.01 to 5 parts by mass relative to 1 part by mass of carbon black within a range that does not hinder the reaction. In the case of fatty acids, organic peracids, anhydrides, acetic acid, ketones, etc. As the inorganic colorant or organic colorant, a known dye may be used. Examples of known dyes include azo dyes, anthraquinone dyes, indigo dyes, triarylmethane dyes, &#134079; Dyes, Alizarin Dyes, Acridine Dyes, Perylene Dyes, Thiazole Dyes, Naphthol Dyes, Quinoline Dyes, Nitro Dyes, Indamine Dyes, Dyes, Dyes, Phthalocyanine Dyes, Cyanine Dyes, etc. . Examples of the inorganic or organic colorant include: a nitroso compound, a nitro compound, an azo compound, a diazo compound, &#134079; Compounds, quinoline compounds, anthraquinone compounds, coumarin compounds, cyanine compounds, phthalocyanine compounds, isoindolinone compounds, isoindolin compounds, quinacridone compounds, anthracenone compounds, purple rings Ketone compounds, fluorene compounds, diketopyrrolopyrrole compounds, thioindigo compounds, difluorene &#134116; compounds, triphenylmethane compounds, quinophthalone compounds, naphthalene tetracarboxylic acid, azo dyes, cyanine dyes Metal complex compounds and the like. As the above-mentioned inorganic colorant or organic colorant, commercially available pigments can also be used, and examples thereof include pigment red 1, 2, 3, 9, 10, 14, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 254, 228, 240 and 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, and 71; Pigment Yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180 and 185; Pigment Green 7, 10, 36, and 58; Pigment Blue 15, 15: 1, 15: 2, 15: 3, 15: 4, 15: 5, 15: 6, 22, 24, 56, 60, 61, 62, and 64; pigment violet 1, 19, 23, 27, 29, 30, 32, 37, 40, and 50, etc. In the coloring agent dispersion liquid (E) of the present invention, the content of the coloring agent (B) is not particularly limited, and it is in terms of good colorability in 100 parts by mass of the total solid content of the coloring agent dispersion (E). In other words, it is preferably 30 to 90 parts by mass, and more preferably 50 to 90 parts by mass. When the content of the colorant (B) is less than 30 parts by mass, a colored polymerizable composition having a sufficient colorant concentration may not be formed. When it is more than 90 parts by mass, the colorant (B) may not be sufficiently made. When dispersed in the colorant dispersion (E). In the case where a coloring polymerizable composition for a color filter is produced using the colorant dispersion liquid (E), the content of the coloring agent (B) in the colorant dispersion liquid (E) is used in the colorant dispersion liquid (E). ) Of the total 100 parts by mass of the solid component, 30 to 90 parts by mass is preferred, and 50 to 90 parts by mass is more preferred. <Dispersant (C)> The dispersant (C) used in the colorant dispersion liquid (E) of the present invention and the coloring polymerizable composition described below is not particularly limited as long as the colorant (B) is used It is sufficient to disperse and stabilize. A polymer dispersant containing a polyester, polyether, or polyurethane having a basic functional group, and a functional group having a nitrogen atom as a basic functional group and a nitrogen atom can be used. It is an amine and / or a quaternary salt thereof, and the amine value is 1 to 100 mgKOH / g. In terms of excellent dispersibility of carbon black, the dispersant (C) is particularly preferably a polymer dispersant containing a polyurethane having a nitrogen atom as a basic functional group. As the dispersant (C), a commercially available dispersant can also be used, and examples include: DISPERBYK-130, DISPERBYK-161, DISPERBYK-162, DISPERBYK-163, DISPERBYK-164, DISPERBYK-167, DISPERBYK-168, DISPERBYK -170, DISPERBYK-171, DISPERBYK-174, DISPERBYK-180, DISPERBYK-182, DISPERBYK-183, DISPERBYK-184, DISPERBYK-185, DISPERBYK-2000, DISPERBYK-2001, DISPERBYK-2020, DISPERBYK-2050, DISPERBYK-2070 , DISPERBYK-2096, DISPERBYK-2150, DISPERBYK-LPN21116, DISPERBYK-LPN6919 (manufactured by BYK-Chemie), Ajisper PB711, Ajisper PB821, Ajisper PB822, Ajisper PB814, Ajisper PN411 and Ajisper PA111 (Ajino Motor Corporation). In the colorant dispersion liquid (E) of the present invention, the content of the dispersant (C) is not particularly limited. The colorant dispersion liquid (E) is contained in 100 parts by mass of the total solid content of the colorant dispersion liquid (E). In terms of dispersibility of the coloring agent in), 5 to 40 parts by mass is preferred, and 5 to 20 parts by mass is more preferred. If the content of the dispersant (C) is less than 5 parts by mass, the dispersibility of the colorant may be poor, and if it is more than 40 parts by mass, a colorant dispersion liquid having a sufficient colorant concentration may not be prepared. When manufacturing a coloring polymerizable composition for a color filter using the colorant dispersion liquid (E), the content of the dispersant (C) in the colorant dispersion liquid (E) is used in the colorant dispersion liquid (E). ) Of the total 100 parts by mass of the solid component, 5 to 40 parts by mass is preferred, and 5 to 20 parts by mass is more preferred. <Dispersion medium (D)> As the dispersion medium (D) used in the toner dispersion liquid (E) of the present invention, generally, any solvent may be used as long as it can dissolve or disperse the above-mentioned components as needed, and examples thereof include: Ketones such as methyl ethyl ketone, methyl amyl ketone, diethyl ketone, acetone, methyl isopropyl ketone, methyl isobutyl ketone, cyclohexanone, and 2-heptanone; ether, dioxane , Tetrahydrofuran, 1,2-dimethoxyethane, 1,2-diethoxyethane, and dipropylene glycol dimethyl ether; ether solvents; methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate Ester solvents such as propyl ester, n-butyl acetate, cyclohexyl acetate, ethyl lactate, dimethyl succinate and TEXANOL; cellulosic solvents such as ethylene glycol monomethyl ether and ethylene glycol monoethyl ether; methanol, Alcohol solvents such as ethanol, iso-or-n-propanol, iso-or-n-butanol, and pentanol; ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, propylene glycol-1-monomethyl ether-2- Ester-based solvents such as acetate (PGMEA), dipropylene glycol monomethyl ether acetate, 3-methoxybutyl acetate, and ethoxyethyl propionate; BTX (Benzene-Tolu, such as benzene, toluene, and xylene) ene-Xylene (benzene-toluene-xylene) series solvents; aliphatic hydrocarbon solvents such as hexane, heptane, octane, and cyclohexane; terpene hydrocarbon oils such as turpentine, D-limonene, and pinene; mineral oil Fine, Swazol # 310 (manufactured by Cosmo Matsuyama Oil) and Solvesso # 100 (manufactured by Exxon Chemical); carbon tetrachloride, chloroform, trichloroethylene, dichloromethane, and 1,2-dichloroethane Isohalogenated aliphatic hydrocarbon solvents; Halogenated aromatic hydrocarbon solvents such as chlorobenzene; Carbitol solvents, aniline, triethylamine, pyridine, acetic acid, acetonitrile, carbon disulfide, N, N-dimethylformamide, N , N-dimethylacetamidamine, N-methylpyrrolidone, dimethylsulfinium, water, etc. These solvents can be used in one or more mixed solvents. Among these, ketones, ether ester solvents, etc., especially PGMEA, cyclohexanone, etc., are dispersing with the colorant in the colorant dispersion liquid (E) and the coloring polymerizable composition or with the inhibitor and the polymerization initiator. The compatibility is good, so it is preferable. In the colorant dispersion liquid (E) of the present invention, the content of the dispersion medium (D) is not particularly limited, and the colorant dispersion liquid (E) is based on 100 parts by mass of the total solid content of the colorant dispersion liquid (E). From the viewpoint of improving the rationality, it is preferably 100 to 1900 parts by mass, and more preferably 200 to 900 parts by mass. When it is more than 1900 parts by mass, it is conceivable that a colored polymerizable composition having a sufficient coloring agent concentration cannot be obtained, and if it is less than 100 parts by mass, there is a possibility that sufficient dispersibility of the coloring agent cannot be obtained. When the coloring agent dispersion liquid (E) is used to form a colored polymerizable composition for a color filter, for example, the content of the dispersion medium (D) in the coloring agent dispersion liquid (E) is not particularly limited, and it is relative to the coloring agent. The total content of the solid content of the dispersion liquid (E) is 100 parts by mass. From the viewpoint of improving the rationality of the colorant dispersion (E), it is preferably 100 to 1900 parts by mass, and more preferably 200 to 900 parts by mass. Serving. The colorant dispersion liquid (E) of the present invention can be prepared by mixing a polymerizable compound (A), a dispersant (C), a dispersion medium (D), etc., and using a horizontal sand mill, a vertical sand mill, and an annular bead. It is obtained by dispersing the colorant (B) with a mill, a mill, or the like. The colorant dispersion liquid (E) of the present invention can be used for various general coatings such as gravure ink, offset ink, ink for inkjet printer, color polymerizable composition for color filter, automobile, wood, metal, etc. , Coatings for back coatings of magnetic tapes, radiation-curable inks, and other uses, and their uses are not particularly limited. When the colorant dispersion liquid (E) of the present invention uses a black pigment typified by carbon black as the colorant (B), it can be used for a coloring composition for a black matrix for a color filter. The coloring composition for a matrix for a color filter is particularly useful for a color filter for a display device for an image display device such as a liquid crystal display panel. <Coloring polymerizable composition> The coloring polymerizable composition of the present invention can be prepared by adding an ethylenically unsaturated compound (F) and a polymerization initiator (G) to the colorant dispersion liquid (E). In the coloring polymerizable composition of the present invention, the content of the colorant dispersion liquid (E) is not particularly limited. For example, in the production of the coloring polymerizable composition, a coloring agent dispersion liquid (E) having a solid content of 25% by mass is used. In this case, from the viewpoint of good colorability, the total amount of the colored polymerizable composition is preferably 10 to 80 parts by mass, and more preferably 30 to 80 parts by mass. If the content of the above-mentioned 25% by mass solid coloring agent dispersion liquid (E) is less than 10 parts by mass, sufficient coloring may not be obtained. If it is more than 80 parts by mass, the following chemical resistance of the hardened substance is present. Reduced situation. When the colored polymerizable composition is, for example, a colored polymerizable composition for a color filter, the content of the coloring agent dispersion (E) of 25% by mass of the solid content is used for the colored polymerizable combination for the color filter Of the total 100 parts by mass, 10 to 80 parts by mass is preferred, and 30 to 80 parts by mass is more preferred. The preferable content of the polymerizable compound (A), a coloring agent (B), and a dispersing agent (C) in the said coloring polymerizable composition is shown below. In the colored polymerizable composition of the present invention, the content of the polymerizable compound (A) is not particularly limited, and the dispersibility of the colorant is good in 100 parts by mass of the total solid components of the colored polymerizable composition. It is preferable that it is 1-20 mass parts, and it is more preferable that it is 1-10 mass parts. If the content of the polymerizable compound (A) is less than 1 part by mass, the dispersibility of the colorant may be poor. If it is more than 20 parts by mass, sufficient coloring may not be exhibited. When the coloring polymerizable composition is, for example, a coloring composition for a color filter, the content of the polymerizable compound (A) in the coloring polymerizable composition for a color filter is used in a coloring composition for a color filter Of the total 100 parts by mass of the solid component of the substance, 1 to 20 parts by mass is preferred, and 1 to 10 parts by mass is more preferred. In the coloring polymerizable composition of the present invention, the content of the colorant (B) is not particularly limited. In terms of 100 parts by mass of the total solid components of the coloring polymerizable composition, in terms of good colorability, It is preferably 20 to 80 parts by mass, and more preferably 30 to 70 parts by mass. If the content of the colorant (B) is less than 20 parts by mass, sufficient light-shielding properties may not be obtained, and if it is more than 80 parts by mass, the chemical resistance of the cured product described below may be reduced. When the colored polymerizable composition is, for example, a colored polymerizable composition for a color filter, the content of the coloring agent (B) in the colored polymerizable composition for a color filter is colored for the color filter. Out of a total of 100 parts by mass of the solid content of the polymerizable composition, it is preferably 20 to 80 parts by mass, and more preferably 30 to 70 parts by mass. In the colored polymerizable composition of the present invention, the content of the dispersant (C) is not particularly limited, and it is preferably from 0.1 to 20 parts by mass, out of 100 parts by mass of the total solid content of the colored polymerizable composition, more preferably It is preferably 0.5 to 15 parts by mass. If the content of the dispersant (C) is less than 0.1 parts by mass, the dispersibility of the colorant may be poor, and if it is more than 20 parts by mass, the chemical resistance may be reduced. When the colored polymerizable composition is, for example, a colored polymerizable composition for a color filter, the content of the dispersant (C) in the colored polymerizable composition for a color filter is colored for the color filter. Out of a total of 100 parts by mass of the solid content of the polymerizable composition, it is preferably 0.1 to 20 parts by mass, and more preferably 1 to 10 parts by mass. <Ethylene Unsaturated Compound (F)> As the ethylenically unsaturated compound (F) used in the colored polymerizable composition of the present invention, any compound having a carbon-carbon double bond in the compound is not required. It is particularly limited and can be used by previous users. The polymerizable compound (A) may be further added as an ethylenically unsaturated compound (F) when preparing a colored polymerizable composition. Examples of the ethylenically unsaturated compound (F) include unsaturated aliphatic hydrocarbons such as ethylene, propylene, butene, isobutylene, vinyl chloride, vinylidene chloride, vinylidene fluoride, and tetrafluoroethylene; (methyl ) Acrylic acid, α-chloroacrylic acid, itaconic acid, maleic acid, citraconic acid, fumaric acid, dicycloheptenedioic acid, butenoic acid, methacrylic acid, vinylacetic acid, allylacetic acid, Cinnamic acid, sorbic acid, mesaconic acid, mono [2- (meth) acryloxyethyl] succinate, mono [2- (meth) acryloxyethyl] phthalate, and ω-carboxy polycaprolactone mono (meth) acrylate is equal to the mono (meth) acrylate of a polymer having a carboxyl group and a hydroxyl group at both ends; hydroxyethyl (meth) acrylate-maleate, ( (Meth) hydroxypropyl acrylate-maleate, dicyclopentadiene-maleate, and polyfunctional (methyl) groups having one carboxyl group and two or more (meth) acrylfluorenyl groups Unsaturated monobasic acids such as acrylate; 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, glycidyl (meth) acrylate, No.A1 to No.A4, methyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, third butyl (meth) acrylate, (meth) acrylic ring Hexyl ester, n-octyl (meth) acrylate, isooctyl (meth) acrylate, isononyl (meth) acrylate, stearyl (meth) acrylate, lauryl (meth) acrylate, (meth) ) Methoxyethyl acrylate, dimethylaminomethyl (meth) acrylate, dimethylaminoethyl (meth) acrylate, aminopropyl (meth) acrylate, dimethylamine (meth) acrylate Propyl ester, ethoxyethyl (meth) acrylate, poly (ethoxy) ethyl (meth) acrylate, butoxyethoxyethyl (meth) acrylate, ethyl (meth) acrylate Hexyl ester, phenoxyethyl (meth) acrylate, tetrahydrofuran (meth) acrylate, vinyl (meth) acrylate, allyl (meth) acrylate, benzyl (meth) acrylate, ethylene glycol Di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, propylene glycol di (meth) Acrylate, 1,4-butanediol di (methyl ) Acrylate, 1,6-hexanediol di (meth) acrylate, trimethylolethane tri (meth) acrylate, trimethylolpropane tri (meth) acrylate, dipentaerythritol hexa ( (Meth) acrylate, dipentaerythritol penta (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, tricyclodecane dimethylol di (meth) acrylate, and Esters of unsaturated monobasic acids such as tris ((meth) acrylethylethyl) isocyanurate and polyester (meth) acrylate oligomers with polyols or polyphenols; zinc (meth) acrylate and ( Metal salts of unsaturated polybasic acids, such as magnesium methacrylate; maleic anhydride, itaconic anhydride, citraconic anhydride, methyltetrahydrophthalic anhydride, tetrahydrophthalic anhydride, trialkyl tetra Hydrophthalic anhydride, 5- (2,5-dioxo-tetrahydrofuranyl) -3-methyl-3-cyclohexene-1,2-dicarboxylic dianhydride, trialkyltetrahydrophthalic acid Formic anhydride-maleic anhydride adduct, dodecenyl succinic anhydride, and methyl polycycloheptene dicarboxylic anhydride, unsaturated polybasic acid anhydrides; (meth) acrylamide, methylenebis- ( (Meth) acrylic acid , Diethylene triamine tri (meth) acrylamide, xylylene bis (meth) acrylamide, α-chloroacrylamide, and N-2-hydroxyethyl (meth) acrylamide Unsaturated monoacids and polyamines, such as ammonium amines; unsaturated aldehydes such as acrolein; (meth) acrylonitrile, α-chloroacrylonitrile, dicyanethylene, and allyl cyanide; and other unsaturated nitriles; styrene, 4 -Methylstyrene, 4-ethylstyrene, 4-methoxystyrene, 4-hydroxystyrene, 4-chlorostyrene, divinylbenzene, vinyltoluene, vinylbenzoic acid, vinylphenol Unsaturated aromatic compounds such as vinyl sulfonic acid, 4-vinylbenzenesulfonic acid, vinyl benzyl methyl ether and vinyl benzyl glycidyl ether; unsaturated ketones such as methyl vinyl ketone; vinylamine, allylamine , N-vinyl pyrrolidone and vinyl piperidine and other unsaturated amine compounds; vinyl alcohols such as allyl alcohol and crotyl alcohol; vinyl methyl ether, vinyl ether, n-butyl vinyl ether, isobutyl vinyl ether and Vinyl ethers such as allyl glycidyl ether; unsaturated fluorenes such as maleimide diimide, N-phenyl maleimide diimide, and N-cyclohexyl maleimide diimide Imines; indines such as indene and 1-methylindene; aliphatic conjugated diene such as 1,3-butadiene, isoprene, and chloroprene; polystyrene, poly (methyl) Methyl acrylate, poly (meth) acrylate and polysiloxane are equivalent to macromonomers with a mono (meth) acrylfluorenyl group at the end of the polymer molecular chain; vinyl chloride, vinylidene chloride, succinic acid Divinyl ester, diallyl phthalate, triallyl phosphate, triallyl isocyanurate, vinyl sulfide, vinyl imidazole, vinyl oxazoline, vinyl carbazole, vinyl pyrrole Pyridones, vinylpyridines, hydroxyl-containing vinyl monomers, vinylurethane compounds of polyisocyanate compounds, hydroxyl-containing vinyl monomers, and vinyl epoxy compounds of polyepoxides, etc. As the ethylenically unsaturated compound (F), commercially available products can be used, and examples thereof include Kayarad DPHA, DPEA-12, PEG400DA, THE-330, RP-1040, NPGDA, PET30 (manufactured by Nippon Kayaku), and SPC- 1000, SPC-3000 (manufactured by Showa Denko), ARONIX M-140, M-215, M-350, M-450 (manufactured by Toa Kosei), NK ESTER A-DPHA-TMPT, A-DCP, A-HD-N , A-9300, TMPT, DCP, NPG and HD-N (manufactured by Shin Nakamura Chemical Industry). [Chemical 4] [Chemical 5] [Chemical 6] [Chemical 7] In addition, as the ethylenically unsaturated compound (F), a copolymer of acrylate, or a phenol and / or cresol novolac epoxy resin and an unsaturated monobasic acid may be used to have a polyfunctional ring. Polyphenylmethane type epoxy resin based on oxygen and unsaturated monobasic acid. Among the aforementioned ethylenically unsaturated compounds (F), when a compound having an acid value is used, alkali-developability can be imparted to the colored polymerizable composition of the present invention. When using the said compound which has an acid value, it is preferable that the usage-amount is 50-99 mass% of the whole polymerizable compound which has an ethylenically unsaturated bond including an ethylenically unsaturated compound (F). The compound having an acid value may be used after further adjusting the acid value by reacting a monofunctional or polyfunctional epoxy compound. By adjusting the acid value of the compound having an acid value, the alkali developability of the curable resin can be improved. The compound having an acid value (that is, a polymerizable compound having an ethylenically unsaturated bond that imparts alkali developability) is preferably in the range of 5 to 120 mgKOH / g of the solid content, and is a monofunctional or polyfunctional epoxy. The amount of the compound used is preferably selected in such a way as to satisfy the above-mentioned acid value. Examples of the monofunctional epoxy compound include glycidyl methacrylate, methyl glycidyl ether, ethyl glycidyl ether, propyl glycidyl ether, isopropyl glycidyl ether, butyl glycidyl ether, and isopropyl ether. Butyl glycidyl ether, third butyl glycidyl ether, pentyl glycidyl ether, hexyl glycidyl ether, heptyl glycidyl ether, octyl glycidyl ether, nonyl glycidyl ether, decyl glycidyl ether, ten Monoalkyl glycidyl ether, dodecyl glycidyl ether, tridecyl glycidyl ether, tetradecyl glycidyl ether, pentadecyl glycidyl ether, cetyl glycidyl ether, 2-ethyl Hexyl glycidyl ether, allyl glycidyl ether, propargyl glycidyl ether, p-methoxyethyl glycidyl ether, phenyl glycidyl ether, p-methoxy glycidyl ether, p-butylphenol glycidyl ether Ether, cresol glycidyl ether, 2-methylcresol glycidyl ether, 4-nonylphenyl glycidyl ether, benzyl glycidyl ether, p-cumylphenyl glycidyl ether, triphenylmethyl ether Glycidyl ether, methacrylic acid 2 , 3-epoxypropyl ester, epoxidized soybean oil, epoxidized linseed oil, glycidyl butyrate, vinyl cyclohexane monoxide, 1,2-epoxy-4-vinyl cyclohexane, epoxy Benzene oxide, pinene oxide, methyl phenylene oxide, cyclohexane, propylene oxide, the above-mentioned compounds No. A2 and No. A3, and the like. As the polyfunctional epoxy compound, if one or more compounds selected from the group consisting of a bisphenol-type epoxy compound and glycidyl ethers are used, a colored hardening resin composition having better characteristics can be obtained, so good. As the bisphenol-type epoxy compound, in addition to the epoxy compound represented by the general formula (I), for example, a bisphenol-type epoxy compound such as a hydrogenated bisphenol-type epoxy compound can be used. As the glycidyl ethers, ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether, 1,4-butanediol diglycidyl ether, 1,6-hexanediol diglycidyl ether, 1 , 8-octanediol diglycidyl ether, 1,10-decanediol diglycidyl ether, 2,2-dimethyl-1,3-propanediol diglycidyl ether, diethylene glycol diglycidyl ether, Triethylene glycol diglycidyl ether, tetraethylene glycol diglycidyl ether, hexaethylene glycol diglycidyl ether, 1,4-cyclohexanedimethanol diglycidyl ether, 1,1,1-tri (glycidyl Glyceryloxymethyl) propane, 1,1,1-tris (glycidyloxymethyl) ethane, 1,1,1-tris (glycidyloxymethyl) methane, and 1,1,1,1 -Tetrakis (glycidyloxymethyl) methane and the like. In addition, phenol novolac epoxy compounds, biphenol novolac epoxy compounds, cresol novolac epoxy compounds, bisphenol A novolac epoxy compounds, and dicyclopentadiene novolacs can also be used. Type epoxy compounds and other novolac type epoxy compounds; 3,4-epoxy-6-methylcyclohexanecarboxylic acid 3,4-epoxy-6-methylcyclohexyl methyl ester, 3,4-epoxy Cyclohexanecarboxylic acid 3,4-epoxycyclohexyl methyl ester and 1-epoxyethyl-3,4-epoxy cyclohexane and other alicyclic epoxy compounds; diglycidyl phthalate, Glycidyl esters such as diglycidyl hydrophthalate and glycidyl dimer; tetraglycidyl diamino diphenylmethane, triglycidyl p-aminophenol and N, N-diglycidyl Glycidylamines such as aniline; heterocyclic epoxy compounds such as 1,3-diglycidyl-5,5-dimethylhydantoin and triglycidyl isocyanurate; dicyclopentanedioxide Dioxide compounds such as olefins; naphthalene type epoxy compounds; triphenylmethane type epoxy compounds; dicyclopentadiene type epoxy compounds and the like. Examples of the ethylenically unsaturated compound (F) include ethylenically unsaturated compounds having a dihydroindene skeleton. Examples of the ethylenically unsaturated compound having a dihydroindene skeleton include those obtained by epoxidizing a bisphenol compound having a dihydroindene skeleton and then reacting the bisphenol compound with an unsaturated monobasic acid. An indolin skeleton novolak compound is epoxidized and reacted with an unsaturated monobasic acid; after a bisphenol compound having a dihydroindene skeleton is added with an alkylene oxide, epoxidized and made A product obtained by reacting with an unsaturated monobasic acid; a product obtained by adding an alkylene oxide to a novolak compound having a dihydroindene skeleton, followed by epoxidation, and reacting with an unsaturated monobasic acid. Specifically, as the ethylenically unsaturated compound having a dihydroindene skeleton, for example, 1,1-bis [4-[(4-ethylethylphenyl) methoxy] phenyl] -2, 3-dihydro-3-phenyl-1H-indene, diacrylic acid (3-phenyl-2,3-dihydro-1H-indene-1,1-diyl) bis (4,1-phenylene) Esters and (3,5-phenyl-2,3-dihydro-1H-indene-1,1-diyl) bis (4,1-phenylene) diacrylate and the like. As the above ethylenically unsaturated compound having a dihydroindene skeleton, an epoxy adduct obtained by reacting an epoxy compound represented by the following general formula (III) with an ethylenically unsaturated monobasic acid, and as an borrow The ethylenically unsaturated compound of the reaction product obtained by the esterification reaction with the polybasic acid anhydride is preferred because of its good colorant dispersibility and hardenability. [Chemical 8] (In the formula, Y represents a substituent selected from the group represented by the following formulae (a) and (b), and R ^{twenty one} ~ R ²⁸ Each independently represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, and k is a number of 0 to 10; when k is a number of 1 to 10 , There are a plurality of R in the compound ^{twenty one} ~ R ²⁸ And Y are the same or different) [化 9] (Where, R ²⁹ ~ R ⁴⁴ Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, and carbon, respectively A heterocyclic group having 2 to 20 atoms or a halogen atom, and the alkylene part of the above alkyl and arylalkyl groups may be interrupted by an unsaturated bond, -O- or -S-, R ²⁹ With R ³⁰ , R ³⁰ With R ³¹ , R ³¹ With R ³² , R ³⁷ With R ³⁸ , R ³⁸ With R ³⁹ And R ³⁹ With R ⁴⁰ In some cases, a bond is formed to form a ring) In the above general formula (III), R is ^{twenty one} ~ R ²⁸ Examples of the alkyl group having 1 to 10 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, second butyl, third butyl, isobutyl, pentyl, and iso. Pentyl, third pentyl, hexyl, heptyl, isoheptyl, third heptyl, n-octyl, isooctyl, third octyl, 2-ethylhexyl, n-nonyl, trifluoromethyl, Difluoromethyl, monofluoromethyl, pentafluoroethyl, tetrafluoroethyl, trifluoroethyl, difluoroethyl, heptafluoropropyl, hexafluoropropyl, pentafluoropropyl, tetrafluoropropyl, Trifluoropropyl, perfluorobutyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl and cyclodecyl. In the general formula (III), as R ^{twenty one} ~ R ²⁸ Examples of the alkoxy group having 1 to 10 carbon atoms include methoxy, ethoxy, isopropoxy, propoxy, butoxy, pentoxy, isopentyloxy, and hexyloxy. , Heptyloxy, octyloxy, 2-ethylhexyloxy, trifluoromethoxy, difluoromethoxy, monofluoromethoxy, pentafluoroethoxy, tetrafluoroethoxy, trifluoroethyl Oxy, difluoroethoxy, heptafluoropropoxy, hexafluoropropoxy, pentafluoropropoxy, tetrafluoropropoxy, trifluoropropoxy, perfluorobutoxy, cyclopropoxy, Cyclobutoxy, cyclopentyloxy, cyclohexyloxy, cycloheptyloxy, cyclooctyloxy, cyclononyloxy, cyclodecyloxy and the like. In the general formula (III), as R ^{twenty one} ~ R ²⁸ Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ ~ R ⁴⁴ Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, second butyl, third butyl, isobutyl, pentyl, and iso. Amyl, third pentyl, hexyl, heptyl, isoheptyl, third heptyl, n-octyl, isooctyl, third octyl, 2-ethylhexyl, n-nonyl, n-decyl, ten Monoalkyl, dodecyl, tridecyl, isotridecyl, myristyl, palmityl, stearyl, trifluoromethyl, difluoromethyl, monofluoromethyl, pentafluoroethyl , Tetrafluoroethyl, trifluoroethyl, difluoroethyl, heptafluoropropyl, hexafluoropropyl, pentafluoropropyl, tetrafluoropropyl, trifluoropropyl, perfluorobutyl, cyclopropyl, Cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl and cyclodecyl. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ ~ R ⁴⁴ Examples of the alkoxy group having 1 to 20 carbon atoms include methoxy, ethoxy, isopropoxy, propoxy, butoxy, pentoxy, isopentyloxy, and hexyloxy. , Heptyloxy, octyloxy, 2-ethylhexyloxy, n-nonyloxy, n-decyloxy, undecyloxy, dodecyloxy, tridecyloxy, isotridecyloxy Base, myristyloxy, palmoxy, stearyloxy, trifluoromethoxy, difluoromethoxy, monofluoromethoxy, pentafluoroethoxy, tetrafluoroethoxy, trifluoroethoxy Base, difluoroethoxy, heptafluoropropoxy, hexafluoropropoxy, pentafluoropropoxy, tetrafluoropropoxy, trifluoropropoxy, perfluorobutoxy, cyclopropoxy, cyclo Butoxy, cyclopentyloxy, cyclohexyloxy, cycloheptyloxy, cyclooctyloxy, cyclononyloxy and cyclodecyloxy. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ ~ R ⁴⁴ Examples of the aryl group having 6 to 20 carbon atoms include phenyl, naphthyl, anthracen-1-yl, phenanthrene-1-yl, o-tolyl, m-tolyl, p-tolyl, 4-vinyl Phenyl, 3-isopropylphenyl, 4-isopropylphenyl, 4-butylphenyl, 4-isobutylphenyl, 4-thirdbutylphenyl, 4-hexylphenyl, 4 -Cyclohexylphenyl, 4-octylphenyl, 4- (2-ethylhexyl) phenyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl, 2,5-di Methylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl, 2,4-di-tert-butylphenyl, 2,5 -Tertiary butylphenyl, 2,6-tertiary butylphenyl, 2,4-tertiary pentylphenyl, 2,5-tertiary pentylphenyl, cyclohexylphenyl, Biphenyl, 2,4,5-trimethylphenyl, 4-chlorophenyl, 3,4-dichlorophenyl, 4-trichlorophenyl, 4-trifluorophenyl, perfluorophenyl, etc. As R ²⁹ ~ R ⁴⁴ Examples of the arylalkyl group having 7 to 20 carbon atoms include benzyl, phenethyl, 2-phenylpropyl, diphenylmethyl, triphenylmethyl, styryl, and phenene. Propyl and 4-chlorophenylmethyl. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ ~ R ⁴⁴ Examples of the heterocyclic group having 2 to 20 carbon atoms include: pyrrolyl, pyridyl, pyrimidinyl, da &#134116; yl, piperidinyl, pyranyl, pyrazolyl , Tris #, pyrrolidinyl, quinolinyl, isoquinolinyl, imidazolyl, benzimidazolyl, triazolyl, furyl, furanyl, benzofuranyl, Thienyl, thiophenyl, benzophenylthio, thiadiazolyl, thiazolyl, benzothiazolyl, oxazolyl, benzoxazolyl, isothiazolyl, iso Oxazolyl, indolyl, pyrrolidyl, morpholinyl, thiomorpholinyl, 2-pyrrolidinone-1-yl, 2-piperidone-1-yl, 2,4- Dioximidazol-3-yl and 2,4-dioxazosidazol-3-yl and the like. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ ~ R ⁴⁴ Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. In the general formula (III), Y is selected from among the substituents selected from the group represented by the above formulae (a) and (b), and R is ²⁹ With R ³⁰ , R ³⁰ With R ³¹ , R ³¹ With R ³² , R ³⁷ With R ³⁸ , R ³⁸ With R ³⁹ And R ³⁹ With R ⁴⁰ Examples of the ring formed by bonding include cyclopentane, cyclohexane, cyclopentene, benzene, pyrrolidine, pyrrole, piperazine, morpholine, thiomorpholine, tetrahydropyridine, internal 5- to 7-membered rings such as ester ring and lactam ring, and condensed rings such as naphthalene and anthracene. The above-mentioned ethylenically unsaturated monobasic acid which reacts with an epoxy compound represented by the general formula (III) refers to an unsaturated bond in the structure, and each molecule has one hydrogen atom that can be ionized to become a hydrogen ion. acid. Examples of the ethylenically unsaturated monobasic acid include acrylic acid, methacrylic acid, butenoic acid, cinnamic acid, sorbic acid, and hydroxyethyl methacrylate-maleate, and hydroxypropyl methacrylate- Maleic acid ester, hydroxypropyl acrylate-maleic acid ester, dicyclopentadiene-maleic acid ester, and the like, in terms of higher polymerizability, acrylic acid and methyl are preferred. acrylic acid. Examples of the polybasic acid anhydride that undergoes an esterification reaction with an epoxy adduct obtained by reacting an epoxy compound represented by the general formula (III) and an ethylenically unsaturated monobasic acid include biphenyltetracarboxylic acid di Anhydride, tetrahydrophthalic anhydride, succinic anhydride, maleic anhydride, trimellitic anhydride, pyromellitic anhydride, 2,2 ', 3,3'-benzophenonetetracarboxylic dianhydride, Ethylene glycol dianhydrotrimellitic acid ester, glycerol dianhydrotrimellitic acid ester, hexahydrophthalic anhydride, methyltetrahydrophthalic anhydride, terracidic anhydride, methyltetrahydrophthalic anhydride, trioxane Tetrahydrophthalic anhydride, hexahydrophthalic anhydride, 5- (2,5-dioxotetrahydrofuranyl) -3-methyl-3-cyclohexene-1,2-dicarboxylic acid di Anhydride, trialkyltetrahydrophthalic anhydride-maleic anhydride adduct, dodecenyl succinic anhydride, methylbicycloheptene dicarboxylic anhydride, and the like. The reaction between the epoxy compound represented by the general formula (III) and the ethylenically unsaturated monobasic acid and the polybasic acid anhydride is preferably as follows. That is, in an epoxy adduct having a structure in which 0.1 to 1.0 of the carboxyl group of the ethylenically unsaturated monobasic acid is added to the epoxy group of one of the epoxy compounds, it is preferably set to 1 with respect to 1 For each hydroxyl group of the epoxy adduct, the polybasic acid anhydride structure of the polybasic acid anhydride is in a ratio of 0.1 to 1.0. Although the reaction example of the said epoxy compound, the said ethylenically unsaturated monobasic acid, and the said polybasic acid anhydride is shown below, it is not limited to the following reaction scheme 1. [Chemical 10] As the ethylenically unsaturated compound (F), from the viewpoint of further improving the availability and the effect of the present invention, among the above reaction products, an epoxy compound represented by the general formula (III) is preferred, Use R ^{twenty one} ~ R ²⁶ Those who are hydrogen atoms. From the same viewpoint, it is also preferable to use Y as a base represented by (a) and R ²⁹ ~ R ³⁶ Is a hydrogen atom or a phenyl group, or Y is a group represented by (b) and R ³⁷ ~ R ⁴⁴ A hydrogen atom or a phenyl group. From the viewpoint of increasing the polymerizability of the colored polymerizable composition, it is preferable to use one having 5 or less carbon atoms as the ethylenically unsaturated monobasic acid, and particularly preferable to use acrylic acid, methacrylic acid, or the like. In terms of excellent dispersibility of the colorant, those having a benzene ring or a saturated aliphatic ring as the polybasic acid anhydride are preferred, and biphenyltetracarboxylic dianhydride, phthalic anhydride, and tetrahydroortho Phthalic anhydride, biphenyltetracarboxylic dianhydride, etc. As the ethylenically unsaturated compound (F) used in the present invention, in terms of good dispersibility and hardenability of the colorant, among the above reaction products, the following compounds are particularly preferably obtained by using the following compounds as raw materials: Products, but not limited to these. Specifically, for example, 1,1-bis [4- (2,3-glycidoxy) phenyl] dihydroindene is selected as the epoxy compound represented by the general formula (III), and acrylic acid is selected. As a product of ethylenically unsaturated monobasic acid and biphenyltetracarboxylic dianhydride selected as polybasic acid anhydride; 1,1-bis [4- (2,3-glycidoxy) phenyl] dihydroindene As the epoxy compound represented by the above general formula (I), a product obtained by using acrylic acid as an unsaturated monobasic acid and using tetrahydrophthalic anhydride as a polybasic acid anhydride; using 1,1-bis [4- (2 , 3-glycidoxy) phenyl] indane as the epoxy compound represented by the general formula (I) above, using acrylic acid as the unsaturated monobasic acid and phthalic anhydride as the polybasic acid. Product; using 1,1-bis [4- (2,3-glycidoxy) phenyl] dihydroindene as the epoxy compound represented by the above general formula (I), using acrylic acid as the unsaturated monobasic acid, A product obtained by using biphenyltetracarboxylic dianhydride and tetrahydrophthalic anhydride as polybasic acid anhydride; and 1,1-bis [4- (2,3-glycidoxy) phenyl] -3 -Phenyldihydroindene as Said epoxy compound of formula (I) represented by the use of acrylic acid as unsaturated monocarboxylic acids, and biphenyl tetracarboxylic dianhydride and tetrahydrophthalic anhydride as a polybasic acid anhydride to obtain a product of the like. In the coloring polymerizable composition of the present invention, the content of the ethylenically unsaturated compound (F) is not particularly limited, and the chemical resistance of the following hardened materials to 100 parts by mass of the solid components of the colored polymerizable composition is as follows: In terms of improving the properties, 5 to 60 parts by mass is preferred, and 5 to 50 parts by mass is more preferred. When the content of the ethylenically unsaturated compound (F) is less than 5 parts by mass, the chemical resistance of the following hardened material may be inferior, and when it is more than 60 parts by mass, sufficient coloring may not be obtained. When the colored polymerizable composition is, for example, a colored polymerizable composition for a color filter, the content of the ethylenically unsaturated compound (F) in the colored polymerizable composition for a color filter is used in the color filter. Of 100 parts by mass of the total solid content of the colored polymerizable composition for tablets, 10 to 60 parts by mass is preferred, and 5 to 50 parts by mass is more preferred. <Polymerization initiator (G)> As the polymerization initiator (G) used in the colored polymerizable composition of the present invention, a conventionally known radical polymerization initiator can be used. Examples of the previously known radical polymerization initiator include a photopolymerization initiator and a thermal polymerization initiator. Examples of the photopolymerization initiator include benzophenone, phenylbiphenyl ketone, 1-hydroxy-1-benzylcyclohexane, benzoin, benzoin dimethyl ketal, and 1-benzyl Methyl-1-dimethylamino-1- (4'-morpholinylbenzyl) propane, 2-morpholinyl-2- (4'-methylmercapto) benzylpropylpropane, 9- Oxygen &#134079; , 1-chloro-4-propoxy9-oxysulfur &#134079; , Isopropyl 9-oxysulfur &#134079; , Diethyl 9-oxysulfur &#134079; , Ethyl anthraquinone, 4-benzylidene-4'-methyldiphenyl sulfide, benzoin butyl ether, 2-hydroxy-2-benzylidenepropane, 2-hydroxy-2- (4'-iso (Propyl) benzamylpropane, 4-butyl benzamyl chloroform, 4-phenoxy benzamyl dichloromethane, methyl benzamyl formate, 1,7-bis (9 ' -Acridineyl) heptane, 9-n-butyl-3,6-bis (2'-morpholinylisobutylamidino) carbazole, 2-methyl-4,6-bis (trichloromethyl) &#134116;, 2-phenyl-4,6-bis (trichloromethyl) trimes &#134116;, 2-naphthyl-4,6-bis (trichloromethyl) trimes &#134116; , 2,2-bis (2-chlorophenyl) -4,5,4 ', 5'-tetraphenyl-1-2'-biimidazole, 4,4-azobisisobutyronitrile, triphenyl Phosphine, camphorquinone, N-1414, N-1717, N-1919, NCI-831, NCI-930 (made by ADEKA), IRGACURE369, IRGACURE907, IRGACURE OXE 01 and IRGACURE OXE 02 (made by BASF), etc .; as heat Examples of the polymerization initiator include 2,2'-azobisisobutyronitrile, 2,2'-azobis (isobutyric acid methyl ester), 2,2'-azobis-2,4-di Azo-based initiators such as methylvaleronitrile, 1,1'-azobis (1-acetamido-1-phenylethane); benzamidine peroxide, di-tert-butylbenzene A Peroxide-based initiators such as tert-butyl pervalerate, bis (4-tert-butylcyclohexyl) peroxydicarbonate, persulfuric acid such as ammonium persulfate, sodium persulfate and potassium persulfate Salt, etc. The polymerization initiator (G) used in the colored polymerizable composition of the present invention is particularly preferable in terms of the sensitivity of the colored polymerizable composition and the heat resistance of the cured product obtained from the colored polymerizable composition. It is preferable to use a compound represented by the following general formula (IV). [Chemical 11] (Where, R ⁵¹ And R ⁵² Existence of a hydrogen atom, a nitro group, a halogen atom, a cyano group, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, or a carbon atom, respectively In the case of a heterocyclic group of 2 to 20, or R ⁵¹ Or R ⁵² There are also bonds to adjacent benzene rings to form X ¹ Case of the ring, R ⁵³ And R ⁵⁴ Each independently represents a hydrogen atom, a halogen atom, a nitro group, a cyano group, a hydroxyl group, a carboxyl group, a cycloalkyl group having 3 to 20 carbon atoms, a cycloalkylalkyl group having 4 to 20 carbon atoms, and R ⁵⁵ , OR ⁵⁵ , SR ⁵⁵ , NR ⁵⁶ R ⁵⁷ COR ⁵⁵ SOR ⁵⁵ , SO ₂ R ⁵⁵ Or CONR ⁵⁶ R ⁵⁷ , R ⁵⁵ ~ R ⁵⁷ Each independently represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms or a heterocyclic group having 2 to 20 carbon atoms, X ¹ Represents oxygen atom, sulfur atom, selenium atom, CR ⁵⁸ R ⁵⁹ , CO, NR ⁶⁰ Or PR ⁶⁰ , X ² For single bond or CO, R ⁵⁸ ~ R ⁶⁰ Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an arylalkyl group having 7 to 20 carbon atoms, and the methylene group in the above alkyl group or arylalkyl group In the case where the group is substituted with a halogen atom, a nitro group, a cyano group, a hydroxyl group, a carboxyl group, or a heterocyclic group, and there is a case where it is interrupted by -O-, R ⁵⁸ With R ⁵⁹ There may be cases where a bond is formed to form a ring, a represents an integer of 0 to 4, and b represents an integer of 0 to 5) As an alkyl group, an aryl group, an arylalkyl group, and a heterocyclic group represented by each symbol of the general formula (IV) Examples of the ring group include the same as the above-mentioned R ²⁹ ~ R ⁴⁴ Examples of the alkyl group, aryl group, arylalkyl group and heterocyclic group shown are the same. In the compound represented by the general formula (IV), the so-called R ⁵³ And R ⁵⁴ The above-mentioned cycloalkyl group having 3 to 20 carbon atoms means a saturated monocyclic or saturated polycyclic alkyl group having 3 to 20 carbon atoms. Examples include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, adamantyl, decalinyl, octahydrocyclopentane Examples of the cycloalkyl group having 3 to 10 carbon atoms, such as olefin, bicyclo [1.1.1] pentyl group and tetradecahydroanthryl group, include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, Cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, adamantyl, decalinyl, octahydrocyclopentadiene, and bicyclo [1.1.1] pentyl, etc. In the compound represented by the general formula (IV), the so-called R ⁵³ And R ⁵⁴ The above-mentioned cycloalkylalkyl group having 4 to 20 carbon atoms means a group having 4 to 20 carbon atoms in which a hydrogen atom of an alkyl group is replaced with a cycloalkyl group. Examples include cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cycloheptylmethyl, cyclooctylmethyl, cyclononylmethyl, cyclodecylmethyl, 2 -Cyclobutylethyl, 2-cyclopentylethyl, 2-cyclohexylethyl, 2-cycloheptylethyl, 2-cyclooctylethyl, 2-cyclononylethyl, 2-cyclodecyl Ethyl, 3-cyclobutylpropyl, 3-cyclopentylpropyl, 3-cyclohexylpropyl, 3-cycloheptylpropyl, 3-cyclooctylpropyl, 3-cyclononylpropyl , 3-cyclodecylpropyl, 4-cyclobutylbutyl, 4-cyclopentylbutyl, 4-cyclohexylbutyl, 4-cycloheptylbutyl, 4-cyclooctylbutyl, 4- Cyclononylbutyl, 4-cyclodecylbutyl, 3-3-adamantylpropyl, decahydronaphthylpropyl, etc. Examples of the cycloalkylalkyl group having 4 to 10 carbon atoms include, for example, : Cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cycloheptylmethyl, cyclooctylmethyl, cyclononylmethyl, 2-cyclobutylethyl, 2- Cyclopentylethyl, 2-cyclohexylethyl, 2-cycloheptylethyl, 2-cyclooctylethyl, 3-cyclobutylpropyl, 3-cyclopentylpropyl, 3-cyclohexylpropyl Base, 3-cycloheptyl Propyl, 4-cyclobutylbutyl, 4-cyclopentylbutyl and 4-cyclohexylbutyl. As R ⁵¹ Or R ⁵² Contains X formed by bonding to adjacent benzene rings ¹ Examples of rings include: carbazole, &#134079; , Dibenzofuran and dibenzothiophene. As R ⁵⁸ With R ⁵⁹ Examples of the ring formed by bonding include cyclopentane, cyclohexane, cyclopentene, benzene, pyrrolidine, pyrrole, piperazine, morpholine, thiomorpholine, tetrahydropyridine, internal 5- to 7-membered rings such as ester ring and lactam ring, and condensed rings such as naphthalene and anthracene. These polymerization initiators can be used by mixing one or two or more kinds according to the required performance. In the colored polymerizable composition of the present invention, the content of the polymerization initiator (G) is not particularly limited, and the hardenability is improved in 100 parts by mass of the total solid components of the colored polymerizable composition. Specifically, it is preferably 0.1 to 20 parts by mass, and more preferably 1 to 10 parts by mass. If the content of the polymerization initiator (G) is less than 0.1 parts by mass, the curability may be poor, and if it is more than 20 parts by mass, the initiator may be precipitated in the resin composition. When the colored polymerizable composition is, for example, a colored polymerizable composition for a color filter, the content of the polymerization initiator (G) in the colored polymerizable composition for a color filter described above is used in a color filter. Of 100 parts by mass of the total solid components of the colored polymerizable composition for tablets, 0.1 to 20 parts by mass is preferred, and 1 to 10 parts by mass is more preferred. In addition, in the colored polymerizable composition of the present invention, a solvent may be contained in order to improve handleability, control the thickness of a cured product, and the like. As such a compound, as long as it is a colorant having good dispersibility and an ethylenically unsaturated compound, Those having excellent solubility in (F) and the polymerization initiator (G) are not particularly limited, and those listed in the dispersion medium (D) can be preferably used. In the colored polymerizable composition of the present invention, the content of the solvent is preferably an amount in which the concentration of the composition other than the solvent is 5 to 30% by mass. When the concentration of the composition other than the solvent is less than 5% by mass, there is a case where it is difficult to thicken the hardened material and sufficient coloring properties cannot be obtained. When it exceeds 30% by mass, the combination is caused by the precipitation of the composition The preservation of the material is reduced, or the viscosity is increased, so the handling is reduced, which is not good. In the colored polymerizable composition of the present invention, a polymerizable compound (A), a colorant (B), a dispersant (C), a dispersion medium (D), Any component other than the ethylenically unsaturated compound (F) and the polymerization initiator (G). The arbitrary components are described below. The colored polymerizable composition of the present invention may contain a compound that does not have an ethylenically unsaturated bond and imparts alkali developability as the above-mentioned optional component. As such a compound, as long as it has an acid value, it is soluble in an alkaline aqueous solution. The compound is not particularly limited, and a representative example thereof is an alkali-soluble novolak resin (hereinafter, simply referred to as "novolak resin"). Novolac resin can be obtained by polycondensation of phenols and aldehydes in the presence of an acid catalyst. Examples of the phenols include phenol, o-cresol, m-cresol, p-cresol, o-ethylphenol, m-ethylphenol, p-ethylphenol, o-butylphenol, m-butylphenol, and p-butylphenol. Phenol, 2,3-xylenol, 2,4-xylenol, 2,5-xylenol, 3,4-xylenol, 3,5-xylenol, 2,3,5-trimethylphenol Phenol, p-phenylphenol, hydroquinone, catechol, resorcinol, 2-methylresorcinol, catechol, α-naphthol, bisphenol A, and dihydroxybenzene Esters and gallates, among these phenols, phenol, o-cresol, m-cresol, p-cresol, 2,5-xylenol, 3,5-xylenol, 2,3,5-trimethylphenol, resorcinol, 2-methylresorcinol and bisphenol A. These phenols can be used individually or in mixture of 2 or more types. Examples of the aldehydes include formaldehyde, paraformaldehyde, acetaldehyde, propionaldehyde, benzaldehyde, phenylacetaldehyde, α-phenylpropanal, β-phenylpropanal, o-hydroxybenzaldehyde, and m-hydroxybenzene Formaldehyde, p-hydroxybenzaldehyde, o-chlorobenzaldehyde, m-chlorobenzaldehyde, p-chlorobenzaldehyde, o-nitrobenzaldehyde, m-nitrobenzaldehyde, p-nitrobenzaldehyde, o-methylbenzaldehyde, m-methylbenzene Formaldehyde, p-methylbenzaldehyde, p-ethylbenzaldehyde and p-n-butylbenzaldehyde. Among these compounds, formaldehyde, acetaldehyde and benzaldehyde are preferred. These aldehydes can be used individually or in mixture of 2 or more types. The aldehydes are used at a ratio of preferably 0.7 to 3 moles, and more preferably 0.7 to 2 moles per mol of phenols. Examples of the acid catalyst include inorganic acids such as hydrochloric acid, nitric acid, and sulfuric acid, and organic acids such as formic acid, oxalic acid, and acetic acid. The amount of these acid catalysts is preferably 1 × 10 per mole of phenols ^-4 ～ 5 × 10 ^-1 Mor. In the condensation reaction, water can generally be used as the reaction medium. When the phenols used in the condensation reaction are not dissolved in the aqueous solution of aldehydes, and when the system becomes a heterogeneous system from the beginning of the reaction, a hydrophilic solvent can also be used. Reaction medium. Examples of such hydrophilic solvents include alcohols such as methanol, ethanol, propanol, and butanol, and cyclic ethers such as tetrahydrofuran and dioxane. The amount of these reaction media used is usually 20 to 1,000 parts by mass per 100 parts by mass of the reaction raw materials. The reaction temperature of the condensation reaction can be appropriately adjusted according to the reactivity of the reaction raw materials, and is usually 10 to 200 ° C, preferably 70 to 150 ° C. After the condensation reaction is completed, in order to remove unreacted raw materials, acid catalysts, and reaction media present in the system, the internal temperature is usually raised to 130-230 ° C, the volatiles are distilled off under reduced pressure, and then the molten novolac is removed. The resin is salivated on a steel belt or the like and recovered. After the condensation reaction is completed, the reaction mixture may be dissolved in the above-mentioned hydrophilic solvent and added to a precipitant such as water, n-hexane, and n-heptane to precipitate the novolak resin, and isolate the precipitate, and It collects by heat-drying. As an example of an arbitrary component other than the said novolak resin, the resin shown below is mentioned. The resin used in the colored polymerizable composition includes a non-photosensitive resin such as a thermoplastic resin and a thermosetting resin, and a photosensitive resin. The binder resin can be used alone or as a mixture of two or more monomers or oligomers, which are precursors, which are hardened by radiation irradiation to produce a binder resin. Examples of the thermoplastic resin include butyraldehyde resin, styrene-maleic acid copolymer, chlorinated polyethylene, chlorinated polypropylene, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, and polyvinyl acetate. Polyurethane resin, polyester resin, acrylic resin, alkyd resin, polystyrene resin, polyamide resin, rubber resin, cyclized rubber resin, cellulose, polybutadiene , Polyethylene, polypropylene, polyimide resin, etc. Examples of the thermosetting resin include epoxy resin, benzoguanamine resin, rosin-modified maleic acid resin, rosin-modified fumaric resin, melamine resin, urea resin, and phenol resin. As the photosensitive resin, a linear polymer having a reactive substituent such as a hydroxyl group, a carboxyl group, or an amine group, and a (meth) acrylic compound having a reactive substituent such as an isocyanate group, an aldehyde group, or an epoxy group, or A resin obtained by reacting cinnamic acid and introducing a photocrosslinkable group such as a (meth) acrylfluorenyl group or a styryl group into the linear polymer. Alternatively, a linear polymer containing an acid anhydride, such as a styrene-maleic anhydride copolymer or an α-olefin-maleic anhydride copolymer, may be used by a hydroxyl-containing polymer such as a hydroxyalkyl (meth) acrylate. A (meth) acrylic compound is semi-esterified. In addition, to the colorant dispersion liquid (E) and the coloring polymerizable composition of the present invention, p-anisole, hydroquinone, catechol, third butylcatechol, and phenanthrene can be added as necessary. 134116; Isothermal polymerization inhibitors; plasticizers; then accelerators; fillers; defoamers; leveling agents; surface conditioners; antioxidants; ultraviolet absorbers; dispersion aids; anticoagulants; catalysts; effects Accelerators; conventional additives such as cross-linking agents and tackifiers. In the coloring agent dispersion liquid (E) and the coloring polymerizable composition of the present invention, a chain transfer agent, a sensitizer, a surfactant, a melamine, and the like may be used in combination. As said chain transfer agent and sensitizer, the compound containing a sulfur atom can be used normally. Examples include: thioglycolic acid, thiomalic acid, thiosalicylic acid, 2-mercaptopropionic acid, 3-mercaptopropionic acid, 3-mercaptobutyric acid, N- (2-mercaptopropionyl) glycine Acid, 2-mercaptonicotinic acid, 3- [N- (2-mercaptoethyl) aminomethane] propionic acid, 3- [N- (2-mercaptoethyl) amino] propionic acid, N- ( 3-mercaptopropionyl) alanine, 2-mercaptoethanesulfonic acid, 3-mercaptopropanesulfonic acid, 4-mercaptobutanesulfonic acid, dodecyl (4-methylthio) phenyl ether, 2-mercaptoethanol, 3-mercapto-1,2-propanediol, 1-mercapto-2-propanol, 3-mercapto-2-butanol, mercaptophenol, 2-mercaptoethylamine, 2-mercaptoimidazole, 2-mercaptobenzimidazole, Thiol compounds such as 2-mercapto-3-pyridinol, 2-mercaptobenzothiazole, thioglycolic acid, trimethylolpropane tris (3-mercaptopropionate), and pentaerythritol tetrakis (3-mercaptopropionate); Disulfide compounds obtained by oxidation of mercapto compounds, iodoacetic acid, iodopropionic acid, 2-iodoethanol, 2-iodoethanesulfonic acid, 3-iodopropanesulfonic acid and other iodinated alkyl compounds, trimethylolpropane tri ( (3-mercaptoisobutyrate), butanediol bis (3-mercaptoisobutyrate), hexanedithiol, sebacylthiol, 1,4-dimethylmercaptobenzene, succinic acid Dithiopropionate, butanediol dimercaptoacetate, ethylene glycol bismercaptoacetate, trimethylolpropane trimercaptoacetate, butanediol dithiopropionate, trimethylol Propane trithiopropionate, trimethylolpropane trimercaptoacetate, pentaerythritol tetrathiopropionate, pentaerythritol tetramercaptoacetate, trihydroxyethyl trithiopropionate, the following compound No.C1 , Karenz PE1 and NR1 manufactured by Showa Denko Corporation. [Chemical 12] Specific examples of the sensitizer include benzophenone, p, p'-tetramethyldiaminobenzophenone, p, p'-tetraethylaminobenzophenone, 2- Chlorine 9-oxysulfur &#134079; , Anthrone, 9-ethoxyanthracene, anthracene, pyrene, pyrene, phenanthrene, diphenylethylenedione, acridine orange, benzoflavin, thioflavin-T, 9,10 -Diphenylanthracene, 9-fluorenone, acetophenone, phenanthrene, 2-nitrofluorene, 5-nitrofluorene, benzoquinone, 2-chloro-4-nitroaniline, N-ethylfluorenyl p-nitro Aniline, p-nitroaniline, N-ethylamido-4-nitro-1-naphthylamine, 2,4,6-trinitrochlorobenzene, anthraquinone, 2-ethylanthraquinone, 2-third Butylanthraquinone, 1,2-benzoanthraquinone, 3-methyl-1,3-diaza-1,9-benzoanthrone, dibenzylideneacetone, 1,2-naphthoquinone, 3 , 3'-carbonyl-bis (5,7-dimethoxycarbonylcoumarin) and succinyl. As the surfactant, a fluorine surfactant such as a perfluoroalkyl phosphate, a perfluoroalkyl carboxylate, an anionic surfactant such as a higher fatty acid base salt, an alkyl sulfonate, or an alkyl sulfate can be used. , Cationic surfactants such as higher amine halide salts, quaternary ammonium salts, non-ionic interface activities such as polyethylene glycol alkyl ethers, polyethylene glycol fatty acid esters, sorbitan fatty acid esters, and fatty acid monoglycerides Surfactants such as agents, amphoteric surfactants, and polysiloxane surfactants may also be used in combination. Examples of the melamine compound include active methylol among nitrogen compounds such as (poly) methylol melamine, (poly) methylol glycoluril, (poly) methylol benzoguanamine, and (poly) methylol urea. Base (CH ₂ OH group) A compound in which all or a part (at least 2) is alkyl-etherified. Here, as an alkyl group which comprises an alkyl ether, a methyl group, an ethyl group, a butyl group, etc. are mentioned, and they may be the same as each other, and may be different. In addition, the methylol group which is not alkyl-etherified may exist in one molecule to perform self-condensation, or it may condense in two molecules to form an oligomer component as a result. Specifically, hexamethoxymethyl melamine, hexabutoxymethyl melamine, tetramethoxymethyl glycoluril, tetrabutoxymethyl glycoluril, and the like can be used. Among these, melamine obtained by alkyl etherification of hexamethoxymethylmelamine, hexabutoxymethylmelamine, or the like is preferred. In the colored polymerizable composition of the present invention, except for the polymerizable compound (A), the colorant (B), the dispersant (C), the dispersion medium (D), the ethylenically unsaturated compound (F), and the polymerization initiator The content of any component other than (G) is appropriately selected depending on the purpose for which it is used, and is not particularly limited. It is preferably set to 20 parts by mass or less based on 100 parts by mass of the solid component of the colored polymerizable composition. The cured product obtained by curing the colored polymerizable composition of the present invention refers to a product obtained by polymerizing and curing the colorable composition using heat, light, or the like. The method for hardening the colored polymerizable composition is described below, but the hardening method of the present invention is not limited to these. The colored polymerizable composition of the present invention can be obtained by a known method such as a spin coater, a roll coater, a rod coater, a die coater, a curtain coater, various printing, dipping, etc. It is applied to the supporting substrate of soda glass, quartz glass, semiconductor substrate, metal, paper and plastic. In addition, after being temporarily formed on a supporting substrate such as a film, it may be transferred to another supporting substrate, and the application method is not limited. In addition, as the light source of the active light used for curing the colored polymerizable composition of the present invention, one that emits light having a wavelength of 300 to 450 nm can be used. For example, ultra-high pressure mercury, mercury vapor arc, carbon arc, and xenon arc can be used. Wait. Furthermore, the direct laser drawing method, which uses laser light instead of a mask as the exposure light source to directly form an image based on digital information from a computer or the like, can not only improve productivity, but also achieve resolution or position accuracy. It is useful to improve the laser beam. As the laser light, light having a wavelength of 340 to 430 nm can be used favorably. Argon ion laser, helium neon laser, and YAG (Yttrium Aluminum Garnet) laser can also be used. , And semiconductor lasers that emit light from the visible region to the infrared region. In the case of using such lasers, a sensitizing pigment that absorbs visible light to the infrared region can be added. The colored polymerizable composition of the present invention can be used to repeatedly perform the following steps (1) to (4) and combine patterns of two or more colors to produce a color filter used in a liquid crystal display panel or the like. (1) a step of forming a coating film of the colored polymerizable composition of the present invention on a substrate (2) a step of irradiating active light with a patterned photomask through the coating film (3) using a developing solution (especially Alkali developer) Step of developing a cured film (4) Step of heating the film after development The colored polymerizable composition (or its cured product) of the present invention can be used for a curable coating or varnish, an adhesive, Color filters in printed substrates, color televisions, color display liquid crystal display panels of PC (Personal Computer) displays, portable information terminals, digital cameras, etc. Black columnar spacers, color filters for CCD (Charge Coupled Device) image sensors, black columnar spacers for CCD image sensors, black spaces for organic EL (Electroluminescence, electroluminescence) Partition materials, electrode materials for touch panels, plasma display panels, powder coatings, printing inks, printing plates, adhesives, gel coatings, photoresists for electronics, plating resists, Both resists, liquid and dry films, solder resists, insulating films, color filters used in the manufacture of various display applications or used in the manufacturing steps of plasma display panels, electroluminescent display devices, and LCDs Structure forming resists, compositions for encapsulating electrical and electronic parts, solder resists, magnetic recording materials, micro mechanical parts, waveguides, optical switches, plating masks, etching masks, color test systems, glass fibers Cable coatings, stencils for screen printing, materials for producing three-dimensional objects by stereolithography, materials for holographic recording, image recording materials, fine electronic circuits, decoloring materials, image recording materials Decoloring materials for microcapsules, decoloring materials for image recording materials using microcapsules, photoresist materials for printed wiring boards, UV (Ultra Violet, ultraviolet) and visible light laser direct image systems, photoresist materials for printed circuit boards There are no particular restrictions on the uses of the photoresist material and the protective film used for the formation of the dielectric layer in the successive lamination. When the coloring polymerizable composition of the present invention can use a black pigment as the colorant (B), it is preferably used for forming a black matrix for a color filter. The black matrix for a color filter is particularly useful for a color filter for a display device used in an image display device such as a liquid crystal display panel. Examples Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. [Production Example 1] Production of Polymerizable Compound No. 1 50 g (0.036 mol) of bisphenol A type phenol novolac epoxy compound, 31.0 g (0.36 mol) of methacrylic acid, manufactured by Japan Chemtex Co., Ltd., 0.5 g of pyridinium p-toluenesulfonate and 100 g of THF (Tetrahydrofuran, tetrahydrofuran) as a solvent were mixed, and the reaction was performed by stirring at room temperature for one night. After the reaction solution was neutralized with sodium carbonate, the organic solvent-soluble matter in the reaction solution was extracted with ethyl acetate. After the solvent in the extract was distilled off by an evaporator, recrystallization was performed using a mixed solvent of ethyl acetate / hexane to obtain the following polymerizable compound No. 1. [Chemical 13] [Production Example 2] Production of polymerizable compound No. 2 231.6 g of polymerizable compound No. 1 was dissolved in 230 g of PGMEA, and 50 g of tetrahydrophthalic anhydride and 0.35 g of tetra-n-butylammonium bromide were added. And stirred at 100 ° C. for 5 hours for reaction. Thereafter, PGMEA was added so that the solid content concentration of the obtained PGMEA solution became 45% by mass, and a PGMEA solution of the polymerizable compound No. 2 was obtained. [Production Example 3] Production of polymerizable compound No. 3 231.6 g of polymerizable compound No. 1 was dissolved in 270 g of PGMEA, and 80 g of tetrahydrophthalic anhydride and 0.57 g of tetra-n-butylammonium bromide were added. And stirred at 100 ° C for 8 hours for reaction. Then, PGMEA was added so that the solid content concentration of the obtained PGMEA solution became 45 mass%, and the PGMEA solution of the polymerizable compound No. 3 was obtained. [Manufacturing Example 4] 150 g of MA100 (carbon black manufactured by Mitsubishi Chemical Corporation) and 3000 ml of a deionized aqueous solution of sodium peroxodisulfate (concentration 2.0 N) were mixed, and stirred at 60 ° C for 10 hours. . Thereafter, the mixed solution was filtered, and the obtained slurry was neutralized with sodium hydroxide, and a solid was obtained by diafiltration, and the obtained solid was dried at 75 ° C. for a day, Carbon black No. 1 was obtained as a black powder. [Manufacturing Example 5] 150 g of MA100 (carbon black manufactured by Mitsubishi Chemical Corporation) and 400 ml of cyclobutane were added to manufacture carbon black No. 2, and 15 g of sulfonamide was added and stirred at 140 to 150 ° C. for 10 hours. Thereafter, the obtained slurry was neutralized with lithium hydroxide, and treated by diafiltration, and the obtained solid was dried overnight at 75 ° C. to obtain carbon black No. 2 as a black powder. [Production Example 6] Preparation of ethylenically unsaturated compound No. 1 having a dihydroindene skeleton, 1,1-bis [4- (2,3-glycidoxy) phenyl] -3-phenyldi was added 184 g of indene, 58 g of acrylic acid, 0.26 g of 2,6-di-tert-butyl-p-cresol, 0.11 g of tetra-n-butylammonium bromide, and 105 g of PGMEA were stirred at 120 ° C. for 16 hours. The reaction liquid was cooled to room temperature, 160 g of PGMEA, 59 g of biphenyltetracarboxylic dianhydride, and 0.24 g of tetra-n-butylammonium bromide were added, and stirred at 120 ° C. for 4 hours. Furthermore, 20 g of tetrahydrophthalic anhydride was added and stirred at 120 ° C for 4 hours, at 100 ° C for 3 hours, at 80 ° C for 4 hours, at 60 ° C for 6 hours, and at 40 ° C. After stirring for 11 hours, 128 g of PGMEA was added, and a polymerizable compound No. 1 was obtained as a PGMEA solution. [Production Example 7] Preparation of ethylenically unsaturated compound No. 2 having a dihydroindene skeleton, 1,1-bis [4- (2,3-glycidoxy) phenyl] -3-phenyldi was added 43 g of indene, 11 g of acrylic acid, 0.05 g of 2,6-di-tert-butyl-p-cresol, 0.11 g of tetrabutylammonium acetate, and 23 g of PGMEA were stirred at 120 ° C. for 16 hours. After cooling to room temperature, 35 g of PGMEA and 9.4 g of biphenyltetracarboxylic dianhydride were added, and the mixture was stirred at 120 ° C. for 8 hours. Further, 6.0 g of tetrahydrophthalic anhydride was added, and the mixture was stirred at 120 ° C for 4 hours, at 100 ° C for 3 hours, at 80 ° C for 4 hours, at 60 ° C for 6 hours, and at 40 ° C for 11 hours. After hours, 27 g of PGMEA was added, and a polymerizable compound No. 2 was obtained as a PGMEA solution. [Comparative Production Example 1] Production of Comparative Polymerizable Compound No. 1 Added 9,9-bis (4-glycidyloxyphenyl) 茀 75.0 g, 23.8 g of acrylic acid, and 2,6-di-tert-butyl p-formyl 0.273 g of phenol, 0.585 g of tetrabutylammonium chloride, and 65.9 g of PGMEA, and stirred at 90 ° C for 1 hour, at 100 ° C for 1 hour, at 110 ° C for 1 hour, and at 120 ° C for 14 hours . After cooling to room temperature, 25.9 g of succinic anhydride, 0.427 g of tetrabutylammonium chloride, and 1.37 g of PGMEA were added and stirred at 100 ° C. for 5 hours. Furthermore, 30.0 g of 9,9-bis (4-glycidyloxyphenyl) fluorene, 0.269 g of 2,6-di-tert-butyl-p-cresol, and 1.50 g of PGMEA were added, and it stirred at 90 degreeC for 90 minutes After stirring at 120 ° C for 4 hours, 122.2 g of PGMEA was added, and a comparative polymerizable compound No. 1 was obtained as a target using a PGMEA solution. [Examples 1 to 9 and Comparative Examples 1 to 4] Preparation of colorant dispersion liquid Each component was adjusted according to the composition of [Table 1] to [Table 3], and processed with a bead mill to obtain a colorant dispersion liquid ( Colorant dispersion liquids No. 1 to 9 and comparative colorant dispersion liquids No. 1 to 4). The numbers in the table indicate parts by mass. The symbols of the components in the table indicate the following components. A-1 Polymerizable compound No.1 A-2 Polymerizable compound No.2 A-3 Polymerizable compound No.3 B-1 Carbon black No.1 B-2 Carbon black No.2 C-1 DISPERBYK-161 ( (By BYK-Chemie) D-1 PGMEA D-2 cyclohexanone F-1 VR-60 (Bisphenol A epoxy acrylate manufactured by Showa Denko) F-2 PR-300PG (Novolac epoxy manufactured by Showa Denko Acrylate) [Table 1] [Table 2] [table 3] [Examples 10 to 29 and Comparative Examples 5 to 8] Preparation of colored polymerizable composition According to the composition of [Table 4] to [Table 8], each component was mixed to obtain a colored polymerizable composition (colored polymerizable composition No. .1 to 20 and Comparative Colored Polymerizable Compositions Nos. 1 to 4). The numbers in the table indicate parts by mass. The symbols of the components in the table indicate the following components. [Colorant Dispersion Liquid (E)] [Colorant Dispersion Nos. 1 to 9] was used. As a comparative colorant dispersion liquid, [Comparative colorant dispersion liquids No. 1 to 4] was used. D-1 PGMEA D-2 Cyclohexanone F-3 Kayarad DPHA (manufactured by Nippon Kayaku Co., Ltd.) F-4 Ethylene unsaturated compound having a dihydroindene skeleton No. 1 F-5 Ethylene unsaturated compound No. 2 G-1 NCI-831 (manufactured by ADEKA) G-2 PBG-304 (manufactured by Tronly) H-1 EP-4100L (epoxy compound: ADEKA company) [Table 4] [table 5] [TABLE 6] [TABLE 7] [TABLE 8] [Evaluation Examples 10 to 29 and Comparative Evaluation Examples 5 to 8] The polymerizable composition Nos. 1 to 20 and the comparative colored polymerizable composition Nos. 1 to 4 were subjected to the following evaluations. The results are shown in [Table 9] and [Table 10]. The polymerizable composition Nos. 1 to 20 and the comparative colored polymerizable composition Nos. 1 to 4 were spin-coated (1300 rpm, 50 seconds) on a glass substrate and dried. After pre-baking at 70 ° C for 20 minutes, an 5% aqueous solution of polyvinyl alcohol was applied to prepare an oxygen barrier film. After drying at 70 ° C for 20 minutes, using a specific mask, exposure with an ultra-high pressure mercury lamp, immersion in a 2.5% sodium carbonate aqueous solution at 25 ° C for 30 seconds for development, and sufficient water washing. After washing with water and drying, baking was performed at 230 ° C for 1 hour to fix the pattern. About the obtained pattern, the following OD (Optical Density, optical density) value, volume resistivity, and sensitivity were measured. (OD value) The OD value of the obtained film was measured using a Macbeth transmission density meter, and the OD value was divided by the film thickness after baking to calculate the OD value per 1 μm of the film thickness. (Volume resistivity) Spin coating was performed on a chromium substrate so that the film thickness of the coloring composition became 4 μm. As pre-baking, firing was performed at 110 ° C. for 2 minutes at 100 mJ / cm. ² Exposure was performed using a high-pressure mercury lamp, and as a post-baking, 230 ° C. × 180 minutes was fired to produce a cured film of the coloring composition. A platinum electrode was produced on the cured film by a sputtering process. A lead was attached to the chromium part and the platinum electrode, and a resistance measuring device was connected to measure the volume resistivity. The unit is Ω · cm. (Sensitivity) from 20 mJ / cm ² At 10 mJ / cm ² Increasing the exposure amount at intervals, confirm the minimum exposure amount where the pattern fixing after development becomes good. [TABLE 9] [TABLE 10] Based on the above results, the cured product of the colored polymerizable composition using the coloring agent dispersion liquid (E) of the present invention has a higher sensitivity than the cured product of the colored polymerizable composition using the coloring agent dispersion liquid of the comparative example. The result of higher OD value and volume resistance. Therefore, the coloring agent dispersion liquid (E) of the present invention and the coloring polymerizable composition of the present invention using the same are particularly useful as a coloring polymerizable composition for a color filter and a color filter having excellent display quality. [Industrial Applicability] Since the colored dispersion liquid of the present invention can provide a colored polymerizable composition capable of forming a pattern with high light-shielding properties, high resistance, and high definition, it is used as a colored polymer for forming a color filter and the like. The raw material of the sexual composition is useful.

no

Claims (7)

A colorant dispersion liquid comprising a polymerizable compound (A), a colorant (B), a dispersant (C), and a dispersion medium (D) represented by the following general formula (I), When (in the ^{formula, R 1, R 2, R} 3, R 4, R 5 and R ⁶ each independently represent a hydrogen atom or a methyl group, in the case of the presence of a plurality of R ^3, plural R ³ are the same or different is also present In the case where there is a plurality of R ⁴ , the plurality of R ⁴ are the same or different, respectively. Y ¹ , Y ² , Y ³ , Y ⁴ , Y ^5, and Y ⁶ (hereinafter, also referred to as Y ¹ ~ ^{Y. 6)} each independently represent a single bond, carbon atoms or a hydrocarbon group of 1 to 20 carbon atoms of the heterocyclic ring containing from 2 to 20, the time in the presence of a plurality Y of the case ^3, a plurality of Y ³ are the same or There are also different situations. When there is a plurality of Y ⁴ , the plurality of Y ⁴ are the same or different. Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ⁶ (hereinafter, also Described as Z ¹ to Z ⁶ ) each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms substituted with a carboxyl group, or a group containing 1 to 20 carbon atoms containing a heterocyclic ring substituted with a carboxyl group, in the presence of a plurality of Z ³ when the case, a plurality of Z ³ are the same or different situations also exist, in case the presence of a plurality of Z ^4, the plurality of Z ⁴ are the same or different is also present The case, Y ¹ ~ Y ⁶ and Z represents a number of carbon atoms of the hydrocarbon group ^{having 1} to Z ^{1. 6} to 20, and the Y ¹ ~ Y ⁶ and Z ¹ to ^{Z. 6} indicated the number of carbon atoms of the heterocyclic ring containing from 2 to 20 The hydrogen atom of the radical is substituted by a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, a methacryl group, an acryl group, an epoxy group, a vinyl group, a mercapto group, an isocyanate group, or a heterocyclic group. the case group the ring, Y ¹ ~ Y ⁶ and Z ¹ ~ Z ⁶ represents the carbon atoms of the hydrocarbon group having 1 to 20 of the indicated number of carbon atoms contained in the heterocyclic ring and Y ¹ ~ Y ⁶ and Z ¹ ~ Z ⁶ When the methylene group in the 2-20 group is substituted with -O-, -CO-, -COO-, -OCO-, -S-, -SO _2- , -SCO-, or -COS-, M ¹ , M ² and M ³ (hereinafter also referred to as M ¹ to M ³ ) each independently represent an alkanediyl group having 1 to 5 carbon atoms, a cycloalkyldiyl group or sulfofluorenyl group having 3 to 10 carbon atoms, carbon atoms, a hydrogen atom carbon atoms and M ¹ ~ M ³ represented by the alkoxy group having 1 to 5 bis and M ¹ ~ M ³ represented by the two groups of the cycloalkyl group of 3 to 10 substituted by a halogen atom is present, carbon In the case of an alkyl group having 1 to 5 atoms or an aryl group having 6 to 12 carbon atoms, When the number M ² of the case, a plurality of M ² are the same or different is also present case, m represents 0 or a positive number of 10 or less). The toner dispersion liquid of claim 1, wherein the polymerizable compound (A) is a compound represented by the following general formula (II), When (in the ^{formula, R 11, R 12, R} 13, R 14, R 15 and R ¹⁶ each independently represent a hydrogen atom or a methyl group, in the case of the presence of a plurality of R ^13, R ¹³ are a plurality of the same or different is also present In the case where there is a plurality of R ¹⁴ , the plurality of R ¹⁴ are the same or different, respectively. Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ⁶ (hereinafter, also referred to as Z ¹ to Z ⁶ ) each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms substituted by a carboxyl group, or a carbon group having 1 to 20 carbon atoms substituted with a carboxyl group, when a plurality of Z ¹³ are present When multiple Z ³ are the same or different, when multiple Z ¹⁴ is present, multiple Z ⁴ are the same or different, and the number of carbon atoms represented by Z ¹¹ to Z ¹⁶ is 1 to A hydrocarbon group of 20 and a hydrogen atom having a heterocyclic carbon group of 2 to 20 represented by Z ¹¹ to Z ¹⁶ are substituted with a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amine group, a carboxyl group, and methacrylic acid. In the case of fluorenyl, acrylfluorenyl, epoxy, vinyl, mercapto, isocyanate, or heterocyclic containing groups Carbon atoms, Z ¹¹ ~ Z ¹⁶ hydrocarbon group and represented by the Z ¹¹ ~ Z ¹⁶ 1 ~ 20 of the group containing the indicated number of carbon atoms of the heterocyclic ring of 2 to 20 in the presence of a methylene group is replaced by -O-, In the case of -CO-, -COO-, -OCO-, -S-, -SO _2- , -SCO-, or -COS-, n represents a positive number of 0 or less). The colorant dispersion liquid according to claim 1 or 2, wherein the colorant (B) is a black pigment. A coloring polymerizable composition comprising the coloring agent dispersion liquid (E) as claimed in claim 1, an ethylenically unsaturated compound (F), and a polymerization initiator (G). A cured product obtained by curing the colored polymerizable composition according to claim 4. A black matrix is obtained by curing a colored polymerizable composition containing the colored dispersion liquid (E), the ethylenically unsaturated compound (F), and the polymerization initiator (G) according to claim 3. A color filter having a hardened body as claimed in claim 5 or a black matrix as claimed in claim 6.