TW201737893A - Cleaning agent composition and method for producing same - Google Patents

Abstract

The present invention provides a cleaning agent composition which contains an N-acyl acidic amino acid having a specific structure and/or a salt thereof (component (A)) and a fatty acid t-butyl ester having a specific structure (component (B)).

Description

Detergent composition and method of producing the same

The present invention relates to a detergent composition and a method of manufacturing the same.

The mercapto amino acid-based surfactant has been particularly emphasized in recent years because it has a weakly acidic formula which is close to the pH of hair or skin. For example, Patent Document 1 discloses a technique for improving the odor or turbidity of a mercapto amino acid-based surfactant. Further, Patent Document 2 discloses a technique for improving the foaming power or feeling of use of a mercapto amino acid-based surfactant. [Prior Art Document] [Patent Document 1] [Patent Document 1] International Publication No. 00/40546 [Patent Document 2] International Publication No. 2005/032509

[Problem to be Solved by the Invention] Here, for a detergent composition for shampoo or body soap, etc., in order to obtain a cleaning effect (using the foam to absorb and wrap the effect of the dirt), or to alleviate the friction between the hair or the skin The effect is that the initial foaming is good. Needless to say, there is also a strong demand for "lasting foaming", "the elasticity of the foam", and the "fine foam". However, according to the prior detergent composition described in Patent Documents 1 and 2, although the quality of the mercapto amino acid-based surfactant or the product having excellent foaming power can be obtained, it is difficult to obtain the sustainability of foaming or Excellent product such as foam (elasticity or fineness). Therefore, an object of the present invention is to provide a detergent composition which is excellent in initial foaming power and excellent in foaming durability (hereinafter also referred to as "foaming sustainability"). [Means for Solving the Problems] The inventors of the present invention have conducted intensive studies in order to achieve the above object, and as a result, have found that by using an N-mercapto acid amino acid having a specific structure and/or a salt thereof, The detergent composition of the fatty acid tert-butyl ester having a specific structure is excellent in initial foaming power and excellent in foaming durability, thereby completing the present invention. That is, the present invention is as follows. [1] A detergent composition comprising the following component (A) and the following component (B), wherein the component (A) is represented by the following general formula (1) and/or the following general formula (2); N-mercapto acid amino acid and / or its salt [Chemical 1] Formula (1) [Chemical 2] Formula (2) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms, and M ₁ and M ₂ each independently represent a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid or a choline , M ₁ and M ₂ may be the same or different), component (B): a fatty acid tert-butyl ester represented by the following formula (3) [Chemical 3] Formula (3) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms). [2] The detergent composition according to [1], wherein the content of the component (B) is 0.01 ppm by mass or more and 1000 ppm by mass or less based on the mass of the component (A). [3] The detergent composition according to [1] or [2] further comprising the following component (C), wherein the content of the component (C) in terms of free fatty acid is relative to the mass of the component (A) , in the range of 0.1% by mass or more and 5% by mass or less, [Chemical 4] Formula (4) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms, and M ₃ represents a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid or a choline). [4] The detergent composition according to any one of [1] to [3] further comprising the following component (D) and/or the following component (E), (D): aliphatic guanamine C Betaine and/or alkylbetaine (E): a nonionic surfactant. [5] A method for producing a detergent composition, comprising the steps of: 1) a first step of causing acidity in the presence of a basic compound in a mixed solvent substantially comprising water and a third butanol; The amino acid is subjected to a condensation reaction with the aliphatic ruthenium chloride for 5.0 to 60 hours to obtain a reaction liquid; 2) a second step of using the acid to obtain a pH of the reaction solution of 1 to 6, at a temperature of 35 to 80 ° C. The lower layer is an organic layer and an aqueous layer to obtain an organic layer containing N-mercapto acid amino acid; 3) a third step of mixing the obtained organic layer with water and/or third butanol And stratifying into an aqueous layer and an organic layer containing N-mercapto acid amino acid at a temperature of 35 to 80 ° C to obtain an organic layer containing N-fluorenyl acid amino acid; and 4) a fourth step, The organic layer obtained is neutralized by 1/20 or more of the carboxyl group of the N-mercapto acid amino acid, and water is added to the organic layer at a temperature of 90 ° C or lower. The concentration of the solid content in the organic layer is maintained at 5.0 to 50% by mass relative to the total amount of the organic layer and is distilled off. Solvent. [6] The method for producing a detergent composition according to [5], wherein the second step is from 0.1 to 10 hours. [7] The method for producing a detergent composition according to [5] or [6] wherein the time of the fourth step is 1.0 to 60 hours. [Effects of the Invention] According to the detergent composition of the present invention, the initial foaming power is excellent and the foaming durability is excellent.

Hereinafter, the form for carrying out the present invention (hereinafter simply referred to as "this embodiment") will be described in detail. The following examples are intended to illustrate the invention and are not intended to limit the invention to the following. The present invention can be carried out with appropriate modifications within the scope of the gist of the invention. [Detergent Composition] The detergent composition of the present embodiment contains the following component (A) (hereinafter also referred to as "component (A)", "(A)"), and the following component (B) (hereinafter also It is abbreviated as "component (B)" and "(B)"): component (A): N-mercapto acid amino acid and/or its salt represented by the following general formula (1) and / or (2) [Chemical 5] Formula (1) [Chem. 6] In the formula (1) and the formula (2), R1 represents an alkyl group having 7 to 23 carbon atoms, M ₁ And M ₂ Respectively represent a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid or a choline, respectively. ₁ And M ₂ The component (B): a fatty acid tert-butyl ester represented by the following formula (3). [Component (A): N-decyl acid amino acid (salt)] The component (A) of the present embodiment is an N-mercapto acid amine group represented by the following formula (1) and/or (2) The acid and/or its salt (hereinafter also referred to as "N-mercapto acid amino acid (salt)"). [Chemistry 7] Formula (1) [Chem. 8] In the formula (1) and the formula (2), R1 represents an alkyl group having 7 to 23 carbon atoms. M ₁ And M ₂ Respectively represent a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid or a choline, respectively. ₁ And M ₂ Can be the same or different. The N-fluorenyl acid amino acid represented by the formula (1) and/or a salt thereof (hereinafter also referred to as "mercapto aspartic acid (salt)") are not particularly limited, and performance or ease of use is not limited. From the viewpoint of the above, N-laurosyl aspartic acid (R1: carbon number 11), N-myristyl aspartic acid (R1: carbon number 13), and N-palm-based day are preferred. Aspartic acid (R1: carbon number 15). More preferably, it is N-lauric acid aspartic acid, and N-myristyl aspartic acid. The salt of the decyl aspartate is not particularly limited, and examples thereof include a metal salt such as a sodium salt, a potassium salt, a lithium salt, a magnesium salt or a calcium salt; an ammonium salt such as an ammonium salt or an alkylammonium salt; An amine salt such as an ethanolamine salt, a diethanolamine salt, a triethanolamine salt or an amine methylpropanolate; a single substance or a mixture of a basic amino acid salt such as an amine salt or a arginine salt, or a choline salt. From the viewpoint of performance or ease of handling, a sodium salt, a potassium salt, and a triethanolamine salt are preferred, and a triethanolamine salt is more preferred. The mercapto aspartic acid (salt) represented by the formula (1) may also be used in combination with N-mercapto aspartic acid and N-mercapto aspartate. In addition, instead of the salt, the N-mercapto aspartic acid and the base may be separately formulated to form a salt in the formulation. The N-fluorenyl acid amino acid represented by the formula (2) and/or a salt thereof (hereinafter also referred to as "mercapto glutamic acid (salt)") are not particularly limited, and performance or ease of use is not limited. From the viewpoint of the above, N-lauroyl glutamic acid (R1: carbon number 11), N-myristyl glutamic acid (R1: carbon number 13), and N-palmitoyl glutamic acid (N-palmityl glutamic acid) are preferred. R1: carbon number 15), and N-coconut oil fatty acid thiol glutamic acid (R1: carbon number 8 to 18). More preferably, it is N-lauric glutamic acid, and N-coconut oil fatty acid glutamic acid. The salt of the thiol glutamate is not particularly limited, and examples thereof include metal salts such as sodium salts, potassium salts, lithium salts, magnesium salts, and calcium salts; ammonium salts such as ammonium salts and alkyl ammonium salts; and monoethanolamine. An amine salt such as a salt, a diethanolamine salt, a triethanolamine salt or an amine methylpropanolate; or a single substance or a mixture of a basic amino acid salt such as an amine salt or a arginine salt or a choline salt. From the viewpoint of performance or ease of handling, a sodium salt, a potassium salt, and a triethanolamine salt are preferred, and a triethanolamine salt is more preferred. The mercapto glutamic acid (salt) represented by the formula (2) may be used in combination with N-mercapto glutamic acid and N-mercapto glutamate. Further, instead of the salt, the N-mercapto glutamic acid and the base may be separately formulated to form a salt in the formulation. The component (A) is not particularly limited, but is preferably decyl aspartate sodium salt, decyl aspartic acid potassium salt, decyl aspartic acid triethanolamine salt, decyl glutamine sodium salt , thioglycolate potassium salt, and mercapto glutamic acid triethanolamine salt. More preferred are decyl aspartate triethanolamine salt and decyl glutamic acid triethanolamine salt, and further preferably decyl aspartate triethanolamine salt. The N-mercapto acid amino acid and/or its salt as the component (A) of the present embodiment can be produced by a known method described in WO00/40546 or the like, and is preferably produced by the following method. The content of the component (A) is not particularly limited, and is preferably 0.01 by mass relative to the total amount (100% by mass) of the detergent composition from the viewpoints of performance and economy such as foaming power and foaming durability. % or more and 80% by mass or less. It is more preferably 0.3% by mass or more and 60% by mass or less, and still more preferably 1.0% by mass or more and 40% by mass or less. [Component (B): Fatty acid tert-butyl ester] The component (B) of the present embodiment is a fatty acid tert-butyl ester represented by the following formula (3). [化8] In the formula (3), R1 represents an alkyl group having 7 to 23 carbon atoms. The third butyl ester of the fatty acid represented by the formula (3) is not particularly limited, and from the viewpoint of performance or ease of use, it is preferably a capric acid t-butyl ester or a sheep. Decanoic acid t-butyl ester, butyl laurate, and tert-butyl myristate. More preferred is butyl laurate. The method for producing the fatty acid tributyl acrylate of the formula (3) is not limited, and may be carried out by a known method. For example, a method of reacting fat ruthenium chloride with third butanol, or using 4,6-dimethoxy-1,3,5-tris&#134116;-2-yl)-4-methyl A condensing agent such as morpholine hydrochloride is a method of condensing a fatty acid with a third butanol, but a method using a condensing agent is preferred because of a high yield. The content of the component (B) is not particularly limited, and is preferably 0.01 ppm by mass or more and 1000 ppm by mass or less based on the mass of the component (A) from the viewpoint of foaming sustainability and economy. More preferably, it is 0.5 mass ppm or more and 500 mass ppm or less, More preferably, it is 1.0 mass ppm or more and 400 mass ppm or less. When the content is 1000 ppm by mass or less, changes in the foam quality as the detergent composition are imparted, and the elastic force of the foam is imparted to the foam. [Component (C): Fatty Acid] The detergent composition of the present embodiment may further contain a fatty acid or a fatty acid salt represented by the following formula (4) (hereinafter also referred to as "component (C)" and "(C)"). , [Chemistry 9] Formula (4) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms, M ₃ Represents a hydrogen atom, an alkali or alkaline earth metal, an organic or inorganic ammonium, a basic amino acid, or a choline). The component (C) represented by the formula (4) is not particularly limited as long as it is a fatty acid having 1 to 23 carbon atoms or a salt thereof, and is preferably lauric acid or laurate from the viewpoint of performance or ease of handling. Myristic acid, myristate, palmitic acid, palmitate, stearic acid, and stearate. Among these, it is more preferable to be a salt of those in terms of foaming performance. M in formula (4) ₃ It is not particularly limited as long as it is a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid, or a choline, and is preferably an alkali metal and a viewpoint of each performance of the detergent composition. Organic ammonium. The alkali metal is more preferably Na and K. Further, the organic ammonium is more preferably ammonium derived from triethanolamine, ammonium derived from diethanolamine, and ammonium derived from ethanolamine. The content of the component (C) represented by the formula (4) in terms of the free fatty acid is preferably from 0 to the mass of the component (A) from the viewpoint of maintaining excellent foaming property. In the range of 1% by mass or more and 5% by mass or less, more preferably 1% by mass or more and 5% by mass or less. By containing the content in such a range, the foam as a detergent composition is imparted with a change, and the foam is imparted with a strong elastic force to become a finer foam. The detergent composition of the present embodiment may further contain the following component (D) (hereinafter also referred to as "component (D)", "(D)"), and/or the following component (E) (hereinafter also referred to as "Component (E)" and "(E)"): Component (D): Aliphatic propylaminoglycine and/or alkylbetaine component (E): a nonionic surfactant. [Component (D): Betaine] The component (D) of the present embodiment is a betaine of a fatty acid guanamine propyl betaine and/or an alkylbetaine. The fatty acid guanamine propyl betaine is not particularly limited, and examples thereof include lauric acid propyl betaine, myristyl propyl betaine, stearyl propyl betaine, and decyl propyl beet. Alkali, and coconut amidinopropyl betaine. Among them, lauric acid propyl betaine and coconut amidinopropyl betaine are preferred, and lauric acid propyl betaine is more preferred. The alkylbetaine is not particularly limited, and examples thereof include lauryl betaine, myristyl betaine, palmityl betaine, stearyl betaine, oleyl betaine, and cocobetaine. Among them, preferred are cocobetaine and lauryl betaine, and more preferably cocobetaine. The content of the component (D) is not particularly limited, and the mass ratio of the component (D) to the component (A) in terms of foaming power, viscosity-increasing effect, and economy ((A)/(D) )) is preferably 0. 1 or more and 3. 0 or less, more preferably 0. 2 or more and 2. 0 or less. [Component (E): Nonionic surfactant] The component (E) of the present embodiment is a nonionic surfactant. The nonionic surfactant is not particularly limited, and examples thereof include POE (polyoxyethylene) octyl ether, POE lauryl ether, POE myristyl ether, POE cetyl ether, POE stearyl ether, and POE oil base. Polyoxyethylene alkyl ether such as ether, POE isostearyl ether, POE behenyl ether, POE octyl (2-ethyl-hexyl) ether; POE, POP (polyoxypropylene) butyl ether, POE, POE laurel Polyoxyethylene polyoxypropylene glycol type such as ether, POE, POP cetyl ether POE, POP diol; POE octyl phenyl ether, POE nonyl phenyl ether, POE chlorophenyl ether, naphthol polyoxyethylene Polyoxyethylene aryl ether such as ether; POE hydrogenated castor oil ether, POE castor oil ether; other POE lanolin ether, POE phytosterol and other ether systems; POE glyceryl monostearate, POE oleic acid glyceride Ethylene glycerol fatty acid ester; POE sorbitan monolaurate, POE sorbitan monostearate, POE sorbitan tristearate, POE sorbitan monoisostearate, etc. Alkyd fatty acid ester; POE sorbitol hexa-stearate, POE sorbitan tetrastearate, POE sorbitol tetraoleate, POE sorbitol monolaurate, polyoxyethylene sorbitol Fatty acid esters. Further, examples thereof include polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol monooleate, polyethylene glycol distearate, and polyethylene glycol dioleate. Polyethylene glycol fatty acid esters such as esters and polyethylene glycol diisostearate; other ether esters such as polyethylene glycol lanolin fatty acid ester; glyceryl monostearate, self-emulsifying monostearic acid Fatty acid glycerides such as glycerides, glyceryl monohydroxystearate, glyceryl distearate; diglyceryl monostearate, diglyceryl monooleate, diglyceryl dioleate, monoisostearic acid Glyceryl ester, tetraglyceryl monostearate, tetraglyceryl tristearate, tetraglyceryl pentate, hexaglyceryl monolaurate, hexaglyceryl monomyristate, decaglyceryl distearate, Polyglycerol fatty acid esters such as decaglyceryl diisostearate; sorbitan monolaurate, sorbitan monostearate, sorbitan monooleate, sorbitan trioleate, sorbitol A sorbitan fatty acid ester such as anhydride tristearate or sorbitan monoisostearate; ethylene glycol fatty acid ester such as ethylene glycol monolaurate; propylene glycol Stearate, self-emulsifying propylene glycol monostearate and other propylene glycol fatty acid esters. Further, pentaerythritol fatty acid esters such as pentaerythritol monostearate and pentaerythritol monooleate; sugar derivatives such as maltitol hydroxy fatty acid ester, alkylated polysaccharide, alkyl (poly) glucoside, and sugar ester; - an alkyl glyceryl ether such as monoisostearyl glyceryl ether; an organic acid monoglyceride such as acetamidine monoglyceride, lactic acid monoglyceride or citric acid monoglyceride; coconut oil fatty acid monoethanol decylamine, salicylic acid monoethanol Indamine, nutmeg monoethanolamine, lauryl diethanolamine, coconut oil fatty acid diethanolamine, lauryl isopropanolamine, myristylisopropanolamine, coconut oil fatty acid isopropanol Amine, POE, Laurel, monoethanolamine, and other fatty acid alkanolamine; POE laurylamine, POE stearylamine and other POE alkylamine; lauryl dimethyl amine oxide, coco dimethyl amine oxide, coconut oil An amine oxide such as aminopropyl dimethyl amine oxide. Among them, preferred are fatty acid alkanolamines, more preferably coconut oil fatty acid monoethanolamine, coconut oil fatty acid diethanolamine, lauryl monoethanolamine, and lauryl diethanolamine, lauryl isopropanol Guanamine. The content of the component (E) is not particularly limited, and the mass ratio of the component (E) to the total of the component (A) and the component (D) in terms of foaming power, viscosity increasing effect, and economy. ((E)/((A)+(D)))) is preferably 0. 1 or more and 1. 0 or less, more preferably 0. 1 or more and 0. 8 or less. The pH of the detergent composition of the present embodiment is not particularly limited, and is preferably 4. 0~8. 0. More preferably 4. 5~7. 5, and further preferably 5. 0 to 7. 0. The detergent composition of the present embodiment may further contain an anionic surfactant in addition to the component (A). The anionic surfactant is not particularly limited, and examples thereof include sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, potassium myristyl sulfate, sodium cetyl sulfate, and sodium stearyl sulfate. Alkyl sulphate such as sodium oleate or triethanolamine lauryl sulfate; and polyoxyethylene lauryl ether sulfate, polyoxyethylene cetyl ether sodium sulfate, polyoxyethylene oleyl ether sulfate, polyoxyethylene lauryl ether Alkyl ether sulfates such as triethanolamine sulfate and salts thereof; alkyl aryl ether sulfates such as polyoxyethylene octylphenyl ether sulfate; and salts thereof; polyoxyethylene laurate decyl ether sulfate, polyoxyethylene laurate laurate Amine ether triethanolamine sulfate, polyoxyethylene myristate sodium decyl ether sulfate, polyoxyethylene oleic acid decyl ether sulfate, polyoxyethylene coconut oil fatty acid guanamine ether sulfate, oleic acid guanamine ether sulfate and the like Base amine sulfuric acid and its salts; hydrogenated coconut oil fatty acid glycerol sodium sulfate and other mercapto ester sulfuric acid and its salts; alkyl lauryl sulfate such as sodium lauryl sulfonate, sodium myristyl sulfonate, sodium coconut sulfonate Its salt; linear dodecylbenzene sulfonic acid , alkylbenzene sulfonic acid and its salts such as linear dodecylbenzenesulfonic acid triethanolamine; alkylnaphthalenesulfonic acid and its salt; fumarin polycondensate of naphthalenesulfonate, etc. Sulfhydryl groups such as disodium lauryl sulfosuccinate, sodium di-2-ethylhexylsulfosuccinate, disodium polyoxyethylene lauryl sulfosuccinate, disodium oleate sulfosuccinate Succinic acid and its salts. Further, examples thereof include α-olefin sulfonic acid such as sodium dodecenesulfonate, sodium tetradecenesulfonate, potassium dodecensulfonate, and potassium tetradecenesulfonate, and salts thereof; and α-sulfomethyl laurate , α-sulfo myristate methyl ester, α-sulfo lauric acid (EO) n methyl ester and other α-sulfo fatty acid esters and salts thereof; coconut oil fatty acid sulfhydryl-N methyl taurine potassium, laurel Sodium-N-methyl taurate, lauryl-N-methyl taurine, lauryl-N-methyl taurine triethanolamine, myristyl-N-methyl taurate, meat N-Methyl sulphate, such as N-methyl-methyl taurine triethanolamine, coconut oil fatty acid sulfhydryl-N methyl taurate, coconut oil fatty acid sulfhydryl-N methyl taurine triethanolamine Acid and its salt; sodium lauryl isethionate, sodium myristate, sodium hydroxyethanesulfonate, coconut oil fatty acid, sodium isethionate and its salts; alkyl sulfoacetate; Alkyl ether phosphates such as oxyethylene lauryl ether sodium phosphate, polyoxyethylene cetyl ether sodium phosphate, polyoxyethylene myristyl ether potassium phosphate, polyoxyethylene oleate sodium phosphate, dimerized oxyethylene ether ether sodium phosphate, and the like Alkyl aryl ether phosphate Salts thereof; polyoxyethylene lauryl ether sodium phosphate Amides Amides fatty ether phosphoric acid and salts thereof. Further, examples thereof include alkyl ammonium phosphate such as sodium lauryl phosphate, sodium myristate sodium phosphate, sodium coconut fatty acid sodium phosphate, potassium myristyl phosphate, triethanolamine lauryl phosphate, and diethanolamine oleate; and N-laurel Sodium glutamate, sodium N-myristyl glutamate, sodium N-cocoate fat glutamate, potassium N-lauric acid glutamate, potassium N-myristyl glutamate, N-coconut oil fat thiol glutamate, N-lauryl glutamic acid triethanolamine, N-myristyl glutamic acid triethanolamine, N-coconut oil fat thiol glutamic acid triethanolamine, N- Laurel sodium glycinate, N-myristyl glycine triethanolamine, N-laurel-β-alanine potassium, N-laurel sulphate triethanolamine, N-lauric acid sodium creatinine, N -N-mercaptoamino acid such as sodium lauryl-N-methyl-β-alanine, N-lauroside-N-methyl-β-alanine triethanolamine and its salt; lauryl iminodiacetic acid Sodium, lauryl iminodiacetate triethanolamine, coconut oil fatty acid sodium iminodiacetate, disodium lauryl iminodiacetic acid, palm kernel fatty acid iminodiacetic acid Iminodiacetic acid and its salts; polyoxyethylene lauryl ether acetate, polyoxyethylene myristyl ether acetate, polyoxyethylene palmityl ether triethanolamine, polyoxyethylene stearyl ether acetate, polyglyceryl lauryl ether Ether carboxylic acid such as sodium acetate and its salt; deuterated peptide such as coconut oil fatty acid silk peptide; polyoxyethylene sodium laurate decyl ether carboxylate, polyoxyethylene myristate sodium decyl ether carboxylate, polyoxyethylene coconut oil Fatty acid ether carboxylic acid such as fatty acid guanamine ether carboxylic acid triethanolamine; and mercapto lactate; alkenyl succinic acid and salts thereof. Further, the detergent composition of the present embodiment may further contain a cationic surfactant. The cationic surfactant is not particularly limited, and examples thereof include lauryl trimethyl ammonium chloride, myristyl trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, and stearyl trimethyl chloride. Ammonium, oil-based trimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, coconut oil alkyltrimethylammonium chloride, tallow alkyltrimethyl chloride Monoalkyl quaternary ammonium salts such as ammonium, stearyl trimethyl ammonium bromide, coconut oil alkyl trimethyl ammonium bromide, cetyl trimethyl ammonium methyl sulfate; dioctyl dimethyl chloride a dialkyl quaternary ammonium salt such as ammonium, dilauryl dimethyl ammonium chloride or distearyl dimethyl ammonium chloride; ethyl lanolin fatty acid aminopropyl propyl dimethyl ammonium, methyl Amidinoalkyl quaternary ammonium salt such as lauryl ammonium methyl diethylammonium sulfate; dipalmityl polyethoxyethyl ammonium chloride, distearyl polyethoxymethyl ammonium chloride Alkyl ethoxy quaternary ammonium salt; alkyl isoquinoline salt such as lauryl isoquinoline; benzyl benzyl benzyl benzyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride Alkyl ammonium salt Benzoyl chloride ammonium salt such as {2-[2-(p-1,1,3,3,-tetramethylbutylphenoxy)ethoxy]ethyl}ammonium chloride; Pyridinium salt such as pyridinium; imidazolinium salt; N-cocoyl arginine pyrrolidone carboxylate, N-lauric acid ethylamine ethyl ester hydrochloride Alkyl acid salt; primary amine salt such as laurylamine hydrochloride; secondary amine salt such as dilaurin acetate; tertiary amine salt; fatty acid amidoxime salt; lauryl triethylene glycol ammonium hydroxide, etc. Alkyltrialkylalkylammonium salt. The content of each of the surfactants other than the component (A) and the component (D) is not particularly limited, and the component (A) and the component (A) and the component are more effectively exhibited from the viewpoint of the action and effect of the present invention. The mass ratio of each surfactant other than (D) is preferably a component (A): each surfactant: 1:1000 to 300:1, more preferably 1:200 to 100:1, Further preferably, it is in the range of 1:10 to 10:1. The detergent composition of the present embodiment may further contain a cationized polymer in a range that does not impair the effect. The cationized polymer is not particularly limited, and examples thereof include O-[2-hydroxy-3-(trimethylamino)propyl]hydroxyethylcellulose chloride (manufactured by LION Corporation, trade name, Leogard LP; manufactured by Union Carbide, trade name, polymer JR-400; manufactured by Toho Chemical Co., Ltd., trade name, Catinal LC-100, LC-200, HC-100, HC-200, etc.), O-chlorinated O-[2 -Hydroxy-3-(lauryldimethylamino)propyl]hydroxyethylcellulose (manufactured by Union Carbide, trade name, Polymer LM-200, etc.), hydroxyethylcellulose dimethyl diallyl A cationized cellulose such as ammonium chloride or the like, O-[2-hydroxy-3-(trimethylamino)propyl] guar chloride (manufactured by Nikko Chemicals, trade name, Jaguar C-13S; Cellulose-derived guar, such as cationized guar gum, dextran chloride hydroxypropyltrimethylammonium ether, etc., manufactured by Henkel Japan Co., Ltd., COSMEDIA GUAR C261, etc. a cationized polysaccharide obtained by cationization of a polysaccharide such as a natural rubber, a starch, or a dextran; for example, N-[2-hydroxy-3-(trimethylamino)propyl]hydrochlorinated casein White, N-[2-hydroxy-3-(trimethylamino)propyl]hydrolyzed collagen, N-[2-hydroxy-3-(trimethylamino)propyl]hydrogenated chloride Protein, N-[2-hydroxy-3-(trimethylamino)propyl]hydrogenated keratin, N-[2-hydroxy-3-(trimethylamino)propyl]hydrochloride Protein, N-[2-hydroxy-3-(trimethylamino)propyl]hydrolyzed pearlin, N-[2-hydroxy-3-(stearyldimethylamino)propyl chloride Hydrolyzed keratin, N-[2-hydroxy-3-(stearyldimethylamino)propyl] chlorinated collagen, N-[2-hydroxy-3-(stearyl) Amino]propyl]hydrolyzed silk protein, N-[2-hydroxy-3-(stearyldimethylamino)propyl] chloride hydrolyzed casein, N-[2-hydroxy-3-chloride (stearyl dimethylamino)propyl]hydrolyzed wheat protein, N-[2-hydroxy-3-(stearyldimethylamino)propyl]hydrolyzed pearlin, chlorinated N-[ 2-hydroxy-3-(lauryldimethylamino)propyl]hydrolyzed keratin, N-[2-hydroxy-3-(lauryldimethylamino)propyl]hydrochloride collagen, chlorine N-[2-hydroxy-3-(lauryldimethylamino)propyl]hydrolyzed silk protein, N-[2-hydroxy-3-(chlorinated) Citrine dimethylamino)propyl]hydrolyzed casein, N-[2-hydroxy-3-(lauryldimethylamino)propyl]hydrolyzed wheat protein, N-[2-hydroxyl chloride -3-(lauryl dimethylamino)propyl]hydrolyzed pearl protein, N-[2-hydroxy-3-(coconut oil alkyldimethylamino)propyl]hydrolyzed soy protein, chlorinated N-[2-hydroxy-3-(coconut oil alkyldimethylamino)propyl]hydrolyzed casein, N-[2-hydroxy-3-(coconut oil alkyldimethylamino)propyl chloride Hydrolyzed collagen, N-[2-hydroxy-3-(coconutylalkyldimethylamino)propyl]hydrogenated silk protein, N-[2-hydroxy-3-(cocoline) Hydrolyzed protein cationized by dimethyl dimethylamino)propyl]hydrolyzed keratin, N-[2-hydroxy-3-(coconutyl alkyldimethylamino)propyl]hydrolyzed pearlin The obtained cationized hydrolyzed protein; dimethyl diallyl ammonium chloride-acrylamide copolymer (manufactured by Nalco Japan, trade name, Merquat 550; manufactured by LION Corporation, trade name, Ripofuro MN, etc.), β-methyl Acryloxyethyltrimethylammonium-acrylamide copolymer (for example, Retin220 manufactured by Hercules), Dimethyldiallyl ammonium-acrylic acid copolymer, dimethyldiallyl ammonium chloride-acrylic acid-acrylamide copolymer, vinyl pyrrolidone-N,N-dimethylaminoethyl A cationized vinyl or cation such as a methacrylic acid copolymer, diethyl sulphate, or dimethylmethylene piperidine (manufactured by Nalco Japan, trade name, Merquat 100; manufactured by LION Corporation, trade name, Ripofuro KY, etc.) Acrylic polymer; in addition, a copolymer of adipic acid and dimethylamino hydroxypropyl diethylamine (for example, manufactured by SANDOZ, trade name, Cartaretin F4), polyethylenimine (Japan) Manufactured by Catalyst Industries, Inc., trade name, EPOMIN P-100), condensate of polyamine and polyglycol, dimethyl adipate-amino hydroxypropyldiethyltriamine copolymer, aminoethylamine a propyl-methyl polyoxyalkylene copolymer, and mixtures thereof and the like. Further, for example, polytetra-ammonium salt-4, polytetra-quaternary ammonium salt-5, polytetra-quaternary ammonium salt as described in Japanese Cosmetics Raw Materials Collection 2007 (edited by the Japan Cosmetic Industry Association, June 28, 2007) can also be cited. -6, poly quaternary ammonium salt-7, poly quaternary ammonium salt-10, poly quaternary ammonium salt -11, poly quaternary ammonium salt-16, poly quaternary ammonium salt-22, poly quaternary ammonium salt-28 , poly quaternary ammonium salt-32, poly quaternary ammonium salt-33, poly quaternary ammonium salt-37, polyquaternary ammonium salt-39, polyquaternary ammonium salt-43, polyquaternary ammonium salt-44, poly Quaternary ammonium salt-46, polyquaternary ammonium salt-47, polyquaternary ammonium salt-49, polyquaternary ammonium salt-51, polyquaternary ammonium salt-52, polyquaternary ammonium salt-53, poly quaternary Ammonium salt-55, polyquaternary ammonium salt-57, polyquaternary ammonium salt-61, polyquaternary ammonium salt-64, polyquaternary ammonium salt-65, polyquaternary ammonium salt-68, fenugreek hydroxypropyl A compound of trimethylammonium chloride, starch hydroxypropyltrimonium chloride, guar hydroxypropyltrimonium chloride. Among the above, as the cationized polymer, a cationized ethylene-based and a cationized acrylic polymer, a cationized polysaccharide, and a cationized guar gum are preferable, and a cationized ethylene-based or acrylic-based polymer is more preferable. In the detergent composition of the present embodiment, phosphorylcholine, bipyridinium quaternary ammonium salt, double-chain dicarboxylate, and dilauroyl glutamic acid may be further contained within a range that does not impair the effect. A Gemini-type compound such as sodium amide. The detergent composition of the present embodiment can appropriately contain various components which are generally used as a detergent or a cosmetic, within the range which does not impair the effects thereof, depending on the purpose. Examples of the components thereof include powder components such as calcium carbonate, talc, mica, kaolin, titanium dioxide, and zinc dioxide; jojoba oil, macadamia oil, avocado oil, evening primrose oil, eucalyptus oil, and rapeseed oil. , castor oil, sunflower oil, corn oil, cocoa butter, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, camellia oil, peach kernel oil, castor oil, eucalyptus oil, cottonseed oil, wood Natural animal and vegetable oils such as wax, palm oil, palm kernel oil, egg butter, lanolin, squalene; synthetic triglyceride; squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax, isoparaffin and other hydrocarbons Type; wax of carnauba wax, paraffin wax, cetyl wax, beeswax, candelilla wax, lanolin; cetyl alcohol, stearyl alcohol, lauryl alcohol, cetearyl alcohol, oleyl alcohol, behenyl alcohol Higher alcohols such as lanolin alcohol, hydrogenated lanolin alcohol, hexyl decyl alcohol, octyldodecanol; cholesterol and its derivatives such as cholesteryl-octyldodecyl-behenyl; isopropyl myristate , isopropyl palmitate, isopropyl stearate, 2 B An ester such as hexanoic acid glyceride, butyl stearate or ethyl linoleic acid; a polar oil such as diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether or polyoxypropylene butyl ether; The oily ingredients described in 2007 (edited by the Japan Cosmetic Industry Association, June 28, 2007). Further, examples thereof include methylphenyl polyoxyalkylene, methyl polyoxyalkylene, octamethylcyclotetraoxane, decamethylcyclopentaoxane, and dodecamethylcyclohexaoxane. , methylcyclopolyoxyalkylene, octamethyltrioxane, decamethyltetraoxane, polyoxyethylene-methyl polyoxyalkylene copolymer, polyoxypropylene-methyl polyoxyalkylene copolymer , poly(oxyethylene/oxypropylene) methyl polyoxyalkylene copolymer, methyl hydrogen polyoxyalkylene oxide, tetrahydrotetramethylcyclotetraoxane, stearyloxymethyl polyoxyalkylene, acetamidine Oxymethylmethyl polyoxyalkylene, methyl polyoxyalkylene emulsion, high polymerization methyl polyoxyalkylene, trimethyl alkoxy decanoic acid, crosslinked methyl polyoxyalkylene, crosslinked methyl Phenyl polyoxane, etc., further comprising an amine-modified anthrone, an epoxy-modified anthrone, a carboxyl-modified anthrone, a methanol-modified anthrone, a methacryl-modified anthrone, a mercapto-modified oxime Ketone, phenol modified anthrone, single-end reactive anthrone, heterofunctional functionally modified anthrone, polyether modified anthrone, methylstyryl modified anthrone, alkyl modified anthrone, higher fatty acid Ester-modified anthrone, hydrophilic Modified anthrone, higher alkoxy-modified anthrone, anthrone containing various derivatives such as higher fatty acid anthrone, fluorine-modified anthrone, etc.; amino-aminobenzoic acid and its derivative, homomethyl-7N-acetylalantoylanylate , butyl methoxy benzhydryl methane, di-p-methoxy cinnamic acid-mono-2-ethylhexanoic acid glyceride, octyl cinnamate, p-methoxy cinnamic acid derivatives, amyl salicylate, etc. Salicylic acid derivatives, benzophenone derivatives such as 2,4-dihydroxybenzophenone, dimethoxybenzylidene oxazolidinium propionate ethylhexyl acetate, acetic acid liquid lanolin, and scutellaria root Extract, triphenylamine-p-carboxyethylhexyloxy-tri-[134116; and other ultraviolet absorbers. Further, ascorbic acid and derivatives thereof such as arbutin, kojic acid, magnesium ascorbyl phosphate, glutathione, licorice extract, clove extract, tea extract, astaxanthin, bovine placenta extract, vitamin E and Its derivatives, tranexamic acid and its salts, chamomile blue, γ-hydroxybutyric acid and other whitening ingredients; maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol, glycol, etc. Organic acids and salts thereof such as polyhydric alcohol, sodium pyrrolidonecarboxylate, sodium lactate or sodium citrate, hyaluronic acid such as sodium hyaluronate and salts thereof, hydrolyzate of yeast and yeast extract, yeast culture solution, lactic acid bacteria culture solution Such as fermented metabolites, collagen, elastin, keratin, sericin and other water-soluble proteins, collagen hydrolysates, casein hydrolysates, silk protein hydrolysates, polyaspartate and other peptides and salts thereof, Trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, plant-based mucopolysaccharide and other sugars, crystalline cellulose, amorphous cellulose, xylan, mannan, polyhalf Lactose, polyarabinose, arabian wood Polysaccharides and derivatives thereof such as sugar, water-soluble chitin, polyglucosamine, pectin, chondroitin sulfate and its salts, such as glycosaminoglycan and its salts, glycine, serine, threonine, Amino acid such as alanine, aspartic acid, tyrosine, lysine, leucine, arginine, glutamic acid, lysine, glycosyl acid compounds such as aminocarbonyl reactants, aloe vera, Plant extracts such as horse chestnut, trimethylglycine, urea, uric acid, ammonia, lecithin, lanolin, squalane, squalene, glucosamine, creatinine, DNA, RNA and other nucleic acid related substances, etc. Humectant; carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl trimethyl ammonium chloride ether, ethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, starch, soluble starch, Carboxymethyl starch, methyl starch, propylene glycol alginate, methyl cellulose, gum arabic, sambag, guar gum, locust bean gum, medlar seed, carrageenan, polygalactose, pectin, Mannan, dextran, amber xylan, cadmium, gelatin, casein, albumin, collagen, methoxy b Alkenyl maleic anhydride copolymer, amphoteric methacrylate copolymer, poly(dimethylmethylene piperidinium), polyacrylate copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone Polyvinylethylene fatty acid ester such as polyvinyl methyl ether, carboxyvinyl polymer, polyacrylic acid, nitrocellulose, polyethylene glycol fatty acid ester, polyethylene glycol distearate, methyl glucoside polyoxyl Emulsifiers such as ethylene dioleate such as methyl glucoside polyoxyethylene fatty acid ester; ethylenediaminetetraacetic acid and its salts, hydroxyethylenediamine triacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, gluconic acid , metal phosphate blockers such as polyphosphates and metaphosphates. Further, examples thereof include organic solvents such as ethanol, propylene glycol, and 1,3-butylene glycol; antioxidants such as butylhydroxytoluene, vitamin E, and phytic acid; and citric acid, malic acid, tartaric acid, lactic acid, adipic acid, and bran Organic acids such as aminic acid, aspartic acid, maleic acid; vitamin A and its derivatives; vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives Class B; ascorbic acid, ascorbyl sulfate, ascorbyl phosphate and other vitamin C, alpha vitamin E, beta vitamin E, gamma vitamin E and other vitamin E, vitamin D, vitamin H, pantothenic acid and other vitamins; nicotine guanamine, Benzyl nicotinic acid, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, eugenol, mucidin, sweet bisabolol, eucalyptol, thymol Inositol, saponin (saponin, red bean saponin, loofah saponin, etc.) tranexamic acid, panthenol ethyl ether, ethinyl estradiol, cephalosporin, placenta extract, surimi extract, gold wire Turbotine, vitamin E and its derivatives, γ-谷维Such as blood flow promoter; pepper sputum, ginger sputum, cantharidin, niacin phthalate and other local irritants, various vitamins or amino acids and other nutrients, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, An anti-inflammatory agent such as chamomile blue, aminocaproic acid or hydrocortisone. Further, examples thereof include an astringent such as zinc oxide, zinc sulfite, allantoin hydroxyaluminum, aluminum chloride, zinc phenolsulfonate, and citric acid; a cooling agent such as menthol and camphor; an antihistamine; and a vitamin E , BHA (Butyl hydroxy anisd, butyl hydroxyanisole), BHT (butylated hydroxytoluene, butylated hydroxytoluene), gallic acid, NDGA (nordihydroguaiaretic acid, n-dihydroguaiac acid), ubiquinone and other antioxidants Medicament; yeasts such as yeast, filamentous bacteria, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, protein from milk, wheat, soybean, bovine blood, pig blood, cockscomb, chamomile, cucumber, Rice, shea butter, white birch, tea, tomato, garlic, witch hazel, rose, loofah, hop, peach, apricot, lemon, vicus, houttuynia, pepper, Sophora flavescens, sheepshoe, Pampas grass , sage, saw palm, mallow, Chuanxiong, surimi, thyme, angelica, spruce, birch, thief, loofah, horse chestnut, saxifrage, arnica, lily, wormwood, peony, Aloe, true aloe, scutellaria, cork, Flowers, safflower, hawthorn, purple root, jujube, dried tangerine peel, ginseng, coix seed, medlar, medlar, blue-spotted horses and other animals and plants, microorganisms and some of them are extracted with organic solvents, alcohols, polyols, water, aqueous alcohols, etc. Natural extract obtained by hydrolysis; pigment; perfume; natural surfactant such as lanolin, cholesterol, saponin; polymer interface activity such as sodium alginate, starch derivative, and tragacanth; Among them, when the powder component is further contained, the cleaning force is increased by the physical friction effect, and the dirt is adsorbed on the surface of the particles, which is effective. Further, when the oil component is further contained, there is an effect of dissolving the oily dirt by the solvent effect of the oil component, and therefore it is suitable for improvement of the cleaning power. When the oily component further contains an anthrone, it gives a refreshing touch after use, and is therefore particularly effective. Further, when the humectant is further contained, there is a tendency that the skin roughness caused by excessive degreasing can be suppressed, and the feeling of use can be improved. Further, in combination with a metal ion blocking agent or an antioxidant, the change in the product under long-term or severe use conditions is suppressed, and it is effective in continuously providing a good feeling of use. The detergent composition of the present embodiment is not particularly limited, and is preferably used for cosmetic applications such as shampoo, body soap, facial cleansing foam, cleansing oil, cleansing cream, cleansing lotion, cleansing lotion, toothpaste, and the like. Moreover, the detergent composition of the present embodiment can be used for kitchen utensils, tableware, bath tubs, dining tables, desks, furniture, stationery and other daily necessities, clothes, accessories, watches, bags, shoes and the like, photocopying machines, printers, etc. Office equipment, umbrellas, raincoats and other rain gear, bicycles, locomotives, airplanes, ships and other means of transportation, rockets, satellites and other aerospace engineering equipment, MRI (Magnetic Resonance Imaging), ultrasonic devices and other medical equipment, electronic substrates, Display, solar cells, lithium-ion batteries, electrodes and other electronic materials, televisions, telephones, mobile phones, smart phones, computers and other electronic devices. The container of the detergent composition of the present embodiment is not particularly limited, and for example, a general-purpose container such as a tube, a pump bottle or a cream bottle can be used. [Method for Producing Detergent Composition] The method for producing a detergent composition according to the present embodiment includes the following steps: (1) A first step (hereinafter also referred to as "deuteration reaction step"), which substantially contains water And a mixed solvent of the third butanol, in the presence of a basic compound, the acid amino acid is condensed with the aliphatic ruthenium chloride. 0 to 60 hours to obtain a reaction liquid; (2) a second step (hereinafter also referred to as "acid precipitation step"), which uses an acid to obtain a pH of from 1 to 6, at 35 to 80 ° C The organic layer and the aqueous layer were layered at a temperature to obtain an organic layer containing an N-fluorenyl acid amino acid. (3) a third step (hereinafter also referred to as "water washing step"), which mixes the obtained organic layer with water and/or third butanol, and layers into a water layer at a temperature of 35 to 80 ° C and An organic layer containing N-mercapto acid amino acid is obtained, and an organic layer containing N-mercapto acid amino acid having impurities removed is obtained. (4) The fourth step (hereinafter also referred to as "solvent distillation removal step"), which neutralizes 1/20 or more of the carboxyl group of the N-mercapto acid amino acid from the obtained organic layer in the organic layer When the temperature is 90 ° C or lower and water is added during the distillation, the concentration of the solid content in the organic layer is maintained at 5. The total amount (100% by mass) of the organic layer is maintained at 5. 0 to 50% by mass and the organic solvent is distilled off. [First Step: Deuteration Reaction Step] The deuteration reaction step of the present embodiment is carried out by condensing an acidic amino acid with a fat ruthenium chloride in the presence of a basic compound in a mixed solvent of water and a third butanol. The step of reacting, and by the condensation reaction (deuteration reaction), a crude N-fluorenyl acid amino acid is formed. Further, the reaction liquid obtained by the condensation reaction is also referred to as "deuteration reaction liquid". In the present embodiment, the time of the deuteration reaction step means that the time from the start of the coexistence of the acid amino acid, the aliphatic hydrazine chlorine, and the basic compound in the solvent is started until the next acid precipitation step. The time until the acid is added. By setting the time of the deuteration reaction step to 5. More than 0 hours, and substantially formed fatty acid tert-butyl ester. Further, by the time of the deuteration reaction step being 60 hours or shorter, the decomposition of the temporarily formed fatty acid tert-butyl ester is suppressed, so that the obtained detergent composition substantially contains the fatty acid tert-butyl ester. The time for the deuteration reaction step is preferably from 10 to 40 hours. In the hydrazine reaction step, the fat bismuth chloride is preferably 1. Below 05, more preferably 1. 0 or less, and further preferably 0. 98 or less. The molar ratio of the fat lanthanum halide to the acidic amino acid is 1. Below 05, there is a tendency to easily reduce the amount of free fatty acid produced. As a composition of the mixed solvent of the deuteration reaction step, the capacity ratio of water to the third butanol (water/third butanol) is preferably in the range of 90/10 to 20/80, more preferably 85/15 to 50. /50 range. The acid amino acid, the fat ruthenium chloride, and the basic compound are easily dissolved by the range of 90/10 to 20/80, and the reaction rate can be increased, which is preferable. The concentration of the acidic amino acid to be added in the deuteration reaction step is not particularly limited. However, since the viscosity of the reaction liquid rises with time during the reaction, it is preferably adjusted to such an extent that it can be stirred and mixed near the end of the reaction. Add concentration. The reaction temperature in the deuteration reaction step is not particularly limited, and from the viewpoint of promoting the main reaction and suppressing the side reaction, it is preferably in the range of -10 to 70 ° C, more preferably in the range of -10 to 20 ° C, and further preferably. For -5. 0 to 10 ° C range. The basic compound used in the deuteration reaction step is not particularly limited, and examples thereof include inorganic bases such as sodium hydroxide, potassium hydroxide, calcium hydroxide, and barium hydroxide. Regarding the pH value in the deuteration reaction step, the pH value is preferably maintained at 9 to 13. from the viewpoint of promoting the main reaction and suppressing the side reaction. 5, more preferably maintained in the range of 10 to 13. [Second Step: Acid Sinking Step] The acid precipitation step of the present embodiment is carried out by, for example, using an acid such as hydrochloric acid or sulfuric acid (preferably a mineral acid) to separate the pH of the hydrazine reaction liquid into an organic layer. And the steps of obtaining the organic layer in two layers of the water layer. In the deuterated reaction solution, the N-decyl acidic amino acid formed is present in the form of an alkali salt. The organic layer and the aqueous layer are layered by partially or completely adding one of the carboxyl groups in the N-mercapto acid amino acid to the free acid by adding an acid thereto. Depending on the pH of the acid precipitation, the dissociation state of the carboxyl group changes, and the stratified state, that is, the mass ratio of the organic layer to the aqueous layer or the removal of the inorganic salt slightly changes, so it is preferably at a pH of 1 to 3 implementation, more preferably pH 1 ~ 2. 5. The temperature in the acid precipitation step is preferably from 35 to 80 °C. More preferably 40 to 70 ° C. When it is 35 ° C or more, the time until the stratification equilibrium is shortened can be shortened, and the tendency of the residual amount of the inorganic salt in the organic layer at the time of equilibrium can be reduced. Since the azeotropic composition of water/t-butanol is at a boiling point of 80 ° C under normal pressure, boiling is prevented by being 80 ° C or less without delamination under pressure, and in terms of simplification of the apparatus. It is beneficial. The time of the acid precipitation step refers to the standing time at a specific pH value and temperature. The standing time is not limited, and is preferably stratified into an organic layer and an aqueous layer and inhibits decomposition of the fatty acid tert-butyl ester. 1 to 10 hours. More preferably 0. 2 to 5. 0 hours. [Third Step: Water Washing Step] The water washing step of the present embodiment is a step of transferring the water-soluble impurities in the organic layer obtained in the acid precipitation step to the water layer by liquid-liquid extraction to reduce it. Specifically, water and/or third butanol is added to the organic layer after the acid precipitation step to adjust the composition of the N-mercapto acid amino acid/third butanol/water, and the organic layer is extracted by liquid-liquid extraction. The water-soluble impurities, mainly the deuteration reaction step and the inorganic salts formed in the acid precipitation step, are transferred to the aqueous layer. In the water washing step, the water washing temperature is preferably from 35 to 80 ° C, more preferably from 40 to 70 ° C. By setting the water washing temperature to 35 ° C or higher, the time until the stratified equilibrium is reached does not become long, and even if the equilibrium is reached, the inorganic salt remains in the organic layer, regardless of the type of the N-mercapto acid amino acid or The concentration in the liquid tends to be easily delaminated. Further, since the boiling point of the azeotropic composition of water/t-butanol is around 80 ° C, it is difficult to cause boiling by setting the water washing temperature to 80 ° C or less, and it is necessary to carry out stratification under pressure or use a special device. The tendency to be less sexual. [Fourth step: solvent distillation removal step] In the solvent distillation removal step of the present embodiment, the distillation operation is carried out in the form of an N-mercapto acid amino acid salt, and the salt is not particularly limited, and examples thereof include sodium. , alkali metal salts such as potassium and lithium, alkaline earth metal salts such as calcium and magnesium, aluminum salts, zinc salts, ammonium salts, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine and other organic amine salts, arginine, and A basic amino acid salt such as aminic acid. From the viewpoint of the performance and ease of handling of the detergent composition, an alkali metal salt and a triethanolamine salt are preferred. When the N-mercapto acid amino acid is used as an amine salt or an alkali metal salt, for example, a base or an aqueous solution thereof may be added. When the N-mercapto acid amino acid salt is formed, it is preferably added so that the carboxyl group content of the N-mercapto acid amino acid is 1/20 or more and becomes an alkali salt. When the ratio of the alkali salt is 1/20 or more of the carboxyl group content, the effect of adding a base can be sufficiently obtained, and the fluidity of the mixed liquid tends to be improved. The ratio of the alkali salt is preferably added so as to be 1/10 or more of the carboxyl group content, and more preferably added to be 1/3 or more. The temperature in the solvent distillation removal step is preferably 90 ° C or lower. When the temperature is 90° C. or lower, the decomposition reaction of the N-fluorenyl acid amino acid or a salt thereof can be suppressed, and the product quality tends to be favorably maintained. More preferably, it is 80 ° C or less, and further preferably 70 ° C or less. In the present embodiment, the time in the solvent distillation removal step refers to the time from when the solvent starts to be distilled off at a specific temperature until the third butanol in the product reaches a certain concentration or lower and the solvent distillation removal operation is stopped. The solvent distillation removal time is not particularly limited, and is preferably 1. from the viewpoint of suppressing foaming of the detergent composition and inhibiting decomposition of fatty acid tert-butyl ester. 0 to 60 hours. More preferably 5. 0 to 40 hours. In the solvent distillation removal step, water is also lost together with the third butanol, so distillation is carried out while adding water. A method of adding water, warm water or water vapor intermittently or continuously can be mentioned. In the solvent distillation removal step, the concentration of the solid content in the liquid at the time of distillation is maintained at 5. The total amount of the liquid (100% by mass) is maintained at 5. 0 to 50% by mass. When the solid content concentration is 50% by mass or less, it is possible to suppress the high viscosity of the liquid, the curing, and the like, and it is possible to suppress the decomposition reaction of the N-mercapto acid amino acid or a salt thereof due to excessive heating. By the solid content concentration of 5. When the concentration is 0% by mass or more, the concentration of the third butanol is excessively lowered, the distillation efficiency is lowered, and the concentration of the solid content component required for the final product is not required to be further concentrated, which is preferable. The solid content concentration is more preferably 20 to 40% by mass, still more preferably 25 to 35% by mass. In the solvent distillation removal step, it is preferred to remove the third butanol to such an extent that it does not affect the aroma of the product. In this regard, the third butanol content is preferably 0. relative to the N-mercapto acid amino acid. 1 mass ppm or more and 750 mass ppm or less, more preferably 0. 1 mass ppm or more and 300 mass ppm or less, and further preferably 0. 1 mass ppm or more and 150 mass ppm or less. [Foaming Sustainability of Detergent Composition] By using the detergent composition of the present embodiment, not only the foaming power is excellent, but also the generated foaming is continued and stable for a long period of time. The detergent composition of the present embodiment preferably maintains a height of 60% or more of the height of the foam at the time of foam generation after 5 minutes of foaming under a specific condition, and more preferably maintains a height of 80% or more. Such a property is exhibited when the detergent composition contains at least the component (A) and the component (B), and is contained in the detergent composition containing the component (A), the component (B), and the component (C). Detergent composition of component (A) component (B), component (C), and component (D), and detergent composition containing component (A), component (B), component (C), and component (E) Any of the detergent compositions including the component (A), the component (B), the component (C), the component (D), and the component (E) can be used. The detergent composition of the present embodiment further imparts a change in the foam quality as the detergent composition by the height of the foaming durability, and imparts a strong elastic force to the foam to become a fine foam. Hereinafter, the present embodiment will be specifically described by way of specific examples and comparative examples. However, the present embodiment is not limited to the examples and comparative examples as long as the gist of the present invention is not exceeded. <Analysis of fatty acid tert-butyl ester (GC/MS analysis)> The fatty acid tert-butyl ester was analyzed by the following GC/MS analysis using a gas chromatograph and a mass spectrometer.・Gas Chromatograph (GC) Unit: Agilent Technology 7890B Column: SUPELCO Equity-1 (30 m×0. 25 mmΦ) film thickness 0. 25 μm Temperature conditions: 40 ° C (5 min) → 10 ° C / min → 320 ° C Flow rate: 1 mL / min Injection volume: 1 μL Injection inlet: 320 ° C Split ratio 1: 10 • Mass spectrometer (MS) Device: Agilent Technology 7000 ionization: EI 70 eV Scanning mode: TIC method (m/z = 10 to 800) Ion source temperature: 250 ° C <Evaluation method of foaming power and foaming persistence> For the examples and comparative examples Each of the detergent compositions has a solid content of 0. 33% by mass of the aqueous solution obtained by diluting with water was added to the juice blender and stirred for 30 seconds, and the foaming height immediately after stirring and after 5 minutes was measured, and the foaming height immediately after stirring and after 5 minutes was measured. Set to foaming force. Further, the ratio (%) of the foaming height after 5 minutes to the foaming height immediately after the stirring was calculated, and the foaming sustainability was evaluated in accordance with the following criteria. ◎: 80% or more ○: less than 60 to 80% Δ: 60% or less <Evaluation method of the fineness of the foam> For each of the detergent compositions shown in the examples and the comparative examples, the solid content was 0. The aqueous solution was diluted with water in a manner of 33% by mass, and the appearance of the foam obtained by treating the aqueous solution by the Ross-Miles method was visually confirmed, and the fineness of the foam was evaluated in accordance with the following criteria. ◎: There is no coarse foam and more fine foam. ○: The coarse foam is less, but the slightly thick foam is mixed with the fine foam. △: Although the coarse foam is not large but has a considerable amount, the coarse foam is mixed with the fine foam. ×: There are many coarse foams. <Evaluation Method of Elasticity of Foam> For each of the detergent compositions shown in the examples and the comparative examples, the solid content was 0. A 33% by mass method was used to obtain an aqueous solution by dilution with water, and the foam obtained by treating the aqueous solution by the Ross-Miles method was touched by hand, and the elastic force of the foam was evaluated in accordance with the following criteria. ◎: The foam has a considerable elasticity, and the foam also has a strong sense of strength. ○: The foam has considerable elasticity, but the foam has less sensation. △: The foam has elasticity, but its elasticity is weak. ×: The foam has no elasticity. <Evaluation method of cleaning power> 1 g of commercially available butter was applied to the plate, and each of the detergent compositions shown in the examples and the comparative examples was used to have a solid content of 0. After cleaning the liquid obtained by diluting with water in a manner of 1% by mass, the state of the dish was observed, and the cleaning power was evaluated in accordance with the following criteria. ◎: The oil of butter did not remain on the plate. ○: The oil of butter is slightly left. <Analysis Method of Free Fatty Acid (HPLC Analysis)> The free fatty acid was measured based on the peak area obtained by the following analysis using HPLC. Detector: Differential Refractometer (RI) Separation tube: A stainless steel tube with an inner diameter of 6 mm and a length of 150 mm is filled with a cyanoacrylate having a particle size of 5 μm and a pore diameter of 12 nm modified with octadecyldecyl. Separation tube temperature: fixed temperature around 40 °C mobile phase: methanol / water / dioxane / phosphoric acid = 2000 / 400 / 49 / 0. 62 Flow: 0 per minute. More specifically, a fixed amount of about 8 mL is more specifically calculated based on the peak area of each of the mercaptoamine acid salt and the fatty acid obtained by HPLC analysis, and the free fatty acid (%) is calculated using the following formula. Free fatty acid (%) = peak area of fatty acid / peak area of mercaptoamine acid salt × 100 <viscosity> For each of the detergent compositions shown in the examples and the comparative examples, a B-type viscometer was used to measure at 25 ° C. Viscosity. <Synthesis of fatty acid tert-butyl ester> [Synthesis Example 1] Synthesis of butyl laurate to make lauric acid (5. 2 g, 0. 026 mol), 4,6-dimethoxy-1,3,5-tri &#134116;-2-yl)-4-methylmorpholine hydrochloride (14. 4 g, 0. 052 mol) and N-methylmorpholine (3. 2 g, 0. 032 mol) was dissolved in tert-butanol (228 g) and reacted at 50 ° C for 20 hours. The reaction liquid was analyzed by the above analysis to confirm the formation of butyl laurate (yield 73%). <Synthesis of N-decyl acid amino acid salt> [Comparative Example 1] (Sulphide step) 860 g of L-aspartate monosodium (5. 55 mol), pure water 2978 g, sodium hydroxide 222 g (5. 1049 g of an 80% by mass aqueous solution of a third butanol was added to the mixed solution of 55 mol), the solution was maintained at 3 ° C, and the pH was adjusted to 12 while using 25% by mass of sodium hydroxide, and the laurel was added dropwise with stirring. Chlorine 1210 g (about 5. 2 mol). The time for the simmering step is 2. 5 hours. (Shenic acid precipitation step) After adding 1136 g of an 80% by mass aqueous solution of third butanol, 75% sulfuric acid was added dropwise, the pH of the liquid was adjusted to 2, and the temperature of the liquid was adjusted to 45 ° C, and allowed to stand 1. After layering into an organic layer and a water bath for 0 hours, the organic layer was taken. (Water washing step) To the organic layer to be separated, a 20% by mass aqueous solution of a third butanol having the same mass as the organic layer was added and stirred, and the mixture was allowed to stand at 45 ° C for 1 hour to be layered into an organic layer and an aqueous layer. (Solvent Distillation Removal Step) Sodium hydroxide is added to the organic layer in such a manner that 83% of the carboxyl group of N-lauroside-L-aspartic acid in the organic layer obtained is in the form of a salt, thereby further solidifying Pure water was added so that the content of the component was 25% by mass. Then, using a spray evaporator, pure water was added while maintaining the solid content of 25% by mass, and vacuum distillation was carried out at 70 ° C for 20 hours to obtain N-lauroside-L-aspartate. Aqueous sodium salt solution (yield 98%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Examples 1 to 6 and 12] A detergent was prepared by mixing the butyl laurate to the N-lauroside-L-aspartic acid aqueous solution obtained in Comparative Example 1 in such a manner as to have the composition of Table 1. combination. Further, the foaming power and foaming durability of the obtained detergent composition are shown in Table 1. Since Examples 1 to 6 contained the fatty acid tert-butyl ester, it was confirmed that at least the foaming durability was obtained as compared with Comparative Example 1 containing no such ester. [Example 7] (deuteration step) 1444 g of L-glutamic acid monosodium monohydrate (7. 72 mol), pure water 3070 g, 25% sodium hydroxide aqueous solution 1235 g (sodium hydroxide 7. 1647 mL of an 80% by mass aqueous solution of a third butanol was added to the mixed solution of 72 mol), the solution was maintained at 3 ° C, and the pH was adjusted to 12 while using 25% sodium hydroxide, and coconut oil was added dropwise with stirring. Chlorine 1760 g (7. 56 mol). The time for the simmering step is 6. 0 hours. (acid precipitation step) The pH of the liquid is adjusted to 2 by adding 75% sulfuric acid, and the temperature of the liquid is adjusted to 65 ° C. After standing for 1 hour and layering into an organic layer and an aqueous layer, the organic layer is separated. . (water washing step) adding third butanol and water to the organic layer to be combined to form N-cocoyl-L-glutamic acid/third butanol/water=33/25/42% by mass The preparation was carried out in such a manner that it was allowed to stand at 65 ° C. Layered into an organic layer and an aqueous layer at 0 hours. (Solvent Distillation Removal Step) Triethanolamine is added to the organic layer in such a manner that 50% of the carboxyl group of the N-cocoyl-L-glutamic acid in the organic layer is added to the organic layer, thereby further solidifying Pure water was added so that the content of the component was 30% by mass. Then, using a spray evaporator, the solid content was maintained at 30% by mass, and pure water was added thereto at 70 ° C for 20 hours under reduced pressure to obtain N-cocoyl-L-glutamine. An aqueous solution of triethanolamine salt (yield 97%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 8] An aqueous solution containing 30% by mass of N-cocoyl-L-glutamic acid was obtained under the same conditions as in Example 7 except that the time of the deuteration step was 30 hours. Rate 98%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 9] An aqueous solution containing 30% by mass of N-cocoyl mercapto-L-glutamic acid was obtained under the same conditions as in Example 7 except that the time of the deuteration step was 55 hours. The rate is 97%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 10] (Deuteration step) L-aspartate monosodium 860 g (5. 55 mol), pure water 2978 g, sodium hydroxide 222 g (5. 1049 g of an 80% by mass aqueous solution of a third butanol was added to the mixed solution of 55 mol), the solution was maintained at 3 ° C, and the pH was adjusted to 12 while using 25% by mass of sodium hydroxide, and the laurel was added dropwise with stirring. Chlorine 1210 g (about 5. 2 mol). The time for the deuteration step is 32 hours. (Shenic acid precipitation step) After adding 1136 g of an 80% by mass aqueous solution of third butanol, 75% sulfuric acid was added dropwise, the pH of the solution was adjusted to 2, and the temperature of the solution was adjusted to 45 ° C, and allowed to stand 1. After layering into an organic layer and a water bath for 0 hours, the organic layer was taken. (Water washing step) A 20% by mass aqueous solution of a third butanol having the same mass as the organic layer was added to the organic layer to be separated and stirred, and allowed to stand at 45 ° C. Layered into an organic layer and an aqueous layer at 0 hours. (Solvent Distillation Removal Step) Sodium hydroxide is added to the organic layer in such a manner that 83% of the carboxyl group of N-lauroside-L-aspartic acid in the organic layer obtained is in the form of a salt, thereby further solidifying Pure water was added so that the content of the component was 25% by mass. Then, using a spray evaporator, the solid content was maintained at 25% by mass, and pure water was added thereto at 70 ° C for 20 hours under reduced pressure to obtain N-lauroside-L-aspartate. Aqueous sodium salt solution (yield 98%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 11] N-Lauryl-L- was obtained under the same conditions as in Example 10 except that the time of the acid precipitation step was set to 15 hours, and the time of the solvent distillation removal step was set to 80 hours. An aqueous solution of aspartate sodium salt (yield 95%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 12] N-lauric was obtained under the same conditions as in Example 10 except that the time of the acid precipitation step of the deuteration step was set to 15 hours, and the time of the solvent distillation removal step was set to 80 hours.醯-L-aspartic acid sodium salt aqueous solution (yield 95%). The composition of the aqueous solution (detergent composition) is shown in Table 1. [Example 13] The composition obtained in Example 12 was added in such a manner that the free fatty acid of lauric acid was 5% by mass to obtain an aqueous solution. The composition of the aqueous solution (detergent composition) is shown in Table 1. [Comparative Example 2] The time of the deuteration step was set to 2. An aqueous solution containing 30% by mass of N-cocoyl-L-glutamic acid (yield 96%) was obtained under the same conditions as in Example 7 except for the mixture. The composition of the aqueous solution (detergent composition) is shown in Table 1. [Comparative Example 3] An aqueous solution containing 30% by mass of N-cocoyl mercapto-L-glutamic acid was obtained under the same conditions as in Example 7 except that the time of the deuteration step was 68 hours. Rate 96%). The composition of the aqueous solution (detergent composition) is shown in Table 1. In Examples 10 to 13, according to the production method of the present embodiment, a composition containing a fatty acid tert-butyl ester or a fatty acid was obtained, and the foaming durability, the fineness of the foam, the elastic force of the foam, and the cleaning power were good. On the other hand, in Comparative Examples 2 to 3, since the production method of the present embodiment was not obtained, the composition containing the fatty acid tert-butyl ester was not obtained, and the free fatty acid was also large, and the foaming durability and the fineness of the foam were The elastic and cleaning power of the foam were inferior to those of Examples 10 to 13. [Table 1] [Examples 14 to 21, Comparative Examples 4 to 5] A detergent composition having the composition of Table 2 was prepared, and the foaming durability and viscosity were evaluated. Since the cleaning composition of Examples 14 to 21 contains the fatty acid tert-butyl ester, it has excellent foaming durability and a high viscosity. On the other hand, since the cleaning compositions of Comparative Examples 4 to 5 did not contain the fatty acid tert-butyl ester, there was a tendency that the foaming durability was poor and the viscosity was low as compared with the cleaning compositions of Examples 14 to 21. . [Table 2] Hereinafter, the product name and manufacturer corresponding to the components used in (Note 1) to (Note 8) of Table 2 are shown. Note 1) MIYOSHI OIL & FAT (shares) AMPHOREX LB-2 Note 2) MIYOSHI OIL & FAT (shares) AMPHOREX CB-1 Note 3) New Japan Physical and Chemical (shares) RIKANON A-100 Note 4) Toho Chemical Industry Co., Ltd. Obazoline BC Note 5) Kawaken Fine Chemicals (shares) Amisol CME Note 6) Kawaken Fine Chemicals (shares) Amisol CDE Note 7) Kao (shares) AMINON C-11S Note 8) Kawaken Fine Chemicals (shares) VISCOFINE E2S This application is The contents of the Japanese Patent Application No. Hei. No. 2016-081483, filed on Jan. [Industrial Applicability] According to the detergent composition of the present invention and the method for producing the same, it is possible to provide an initial foaming power, and it is not necessary to say that "foaming durability" and "foaming strength" are A good detergent composition such as "fineness of foam".

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Claims (7)

A detergent composition comprising the following component (A) and the following component (B): component (A): N- represented by the following formula (1) and/or the following formula (2) Mercapto acid amino acid and/or its salt [Chemical 1] Formula (1) [Chemical 2] Formula (2) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms, and M ₁ and M ₂ each independently represent a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid, or a cholesterium The base, M ₁ and M ₂ may be the same or different), component (B): a fatty acid tert-butyl ester represented by the following formula (3) [Chemical 3] Formula (3) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms). The detergent composition according to claim 1, wherein the content of the component (B) is 0.01 ppm by mass or more and 1000 ppm by mass or less based on the mass of the component (A). The detergent composition according to claim 1 or 2, further comprising the following component (C), wherein the content of the component (C) in terms of free fatty acid is 0.1% by mass or more based on the mass of the component (A) And within the range of 5 mass% or less, [Chem. 4] Formula (4) (wherein R1 represents an alkyl group having 7 to 23 carbon atoms, and M ₃ represents a hydrogen atom, an alkali metal or an alkaline earth metal, an organic or inorganic ammonium, a basic amino acid, or a choline). The detergent composition according to any one of claims 1 to 3, which further comprises the following component (D) and/or the following component (E), (D): an aliphatic guanamidopropyl betaine and/or Alkyl betaine (E): a nonionic surfactant. A method for producing a detergent composition, comprising the steps of: 1) a first step of causing an acidic amino acid in the presence of a basic compound in a solvent mixture substantially comprising water and a third butanol The fat bismuth chloride is subjected to a condensation reaction for 5.0 to 60 hours to obtain a reaction liquid; and 2) a second step of stratifying the obtained reaction solution with a pH of 1 to 6 by using an acid at a temperature of 35 to 80 ° C. The organic layer and the aqueous layer are obtained to obtain an organic layer containing N-mercapto acid amino acid; 3) a third step of mixing the obtained organic layer with water and/or third butanol at 35~ Layered into an aqueous layer and an organic layer comprising N-mercapto acid amino acid at a temperature of 80 ° C to obtain an organic layer comprising N-mercapto acid amino acid; and 4) a fourth step, which is obtained from The organic layer neutralizes 1/20 or more of the carboxyl group of the N-mercapto acid amino acid, and the water is added to the organic layer at a temperature of 90 ° C or lower. The solid content concentration is maintained at 5.0 to 50% by mass relative to the total amount of the organic layer and the organic solvent is distilled. In addition. The method for producing a detergent composition according to claim 5, wherein the second step is carried out for a period of from 0.1 to 10 hours. A method of producing a detergent composition according to claim 5 or 6, wherein the fourth step is carried out for a period of from 1.0 to 60 hours.