以下，雖對本發明之構成進行了詳細說明，但該等係表示理想之實施態樣之一例，本發明並不特定為該等之內容。 [水性合成樹脂乳液之製造方法] 本發明之水性合成樹脂乳液之製造方法係於聚乙烯醇系樹脂之存在下，使聚合成分(以下，將本發明中所使用之聚合成分稱為[聚合成分[I]])乳化聚合者，其特徵在於一面向水性介質中連續地添加聚合成分[I]之總量一面使其乳化聚合。 作為聚合成分[I]，例如較佳為含有丙烯酸系單體、苯乙烯系單體、乙烯酯系單體之至少1種之單體成分作為主成分。於本發明中，作為主成分係指占整體之50重量%以上，包含整體係僅由主成分構成之情形。 作為上述丙烯酸系單體，例如可列舉：(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸異丁酯、(甲基)丙烯酸第三丁酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸環己酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸辛酯、(甲基)丙烯酸硬脂酯等脂肪族系(甲基)丙烯酸酯、或(甲基)丙烯酸苯氧酯等芳香族系(甲基)丙烯酸酯、(甲基)丙烯酸三氟乙酯等，其中，烷基之碳數為1～18、尤其為1～10之脂肪族系(甲基)丙烯酸酯較佳，又，該等可使用1種或2種以上。 再者，於本發明中，所謂(甲基)丙烯酸酯係指丙烯酸酯或甲基丙烯酸酯。 作為上述苯乙烯系單體，例如可列舉：苯乙烯、α-甲基苯乙烯等。該等可單獨使用或組合2種以上使用。 作為上述乙烯酯系單體，例如可列舉：直鏈狀或分支之碳原子數2～12之單羧酸之乙烯酯，具體而言，例如可列舉：甲酸乙烯酯、乙酸乙烯酯、丙酸乙烯酯、戊酸乙烯酯、丁酸乙烯酯、異丁酸乙烯酯、新戊酸乙烯酯、癸酸乙烯酯、月桂酸乙烯酯、硬脂酸乙烯酯、苯甲酸乙烯酯、特十碳酸乙烯酯、2-乙基己酸乙烯酯等。該等可單獨使用或組合2種以上使用。 又，亦可包括含有官能基之單體等，例如可列舉：含有縮水甘油基之單體、含有烯丙基之單體、含有水解性矽烷基之單體、含有乙醯乙醯基之單體、於分子結構中具有2個以上乙烯基之單體、含有羥基之單體等。 作為上述含有縮水甘油基之單體，例如可列舉：(甲基)丙烯酸縮水甘油酯、縮水甘油基(甲基)烯丙醚、3,4-(甲基)丙烯酸環氧基環己酯等。其中，尤其自物性偏差較少，且濕潤時之接著強度提高等觀點而言，較佳為(甲基)丙烯酸縮水甘油酯。 作為上述含有烯丙基之單體，例如可列舉：三烯丙氧基乙烯、馬來酸二烯丙酯、氰尿酸三烯丙酯、異氰尿酸三烯丙酯、四烯丙氧基乙烷等具有2個以上烯丙基之單體、烯丙基縮水甘油醚、乙酸烯丙酯等。其中，就濕潤時之接著強度之觀點而言，較佳為烯丙基縮水甘油醚。 作為上述含有水解性烯丙基之單體，例如可列舉：乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基三(β-甲氧基乙氧基)矽烷、乙烯基甲基二甲氧基矽烷、γ-甲基丙烯醯氧基丙基三甲基矽烷、γ-甲基丙烯醯氧基丙基二甲氧基矽烷、γ-丙烯醯氧基丙基三甲氧基矽烷、γ丙烯醯氧基丙基甲基二甲氧基矽烷、γ-甲基丙烯醯氧基丙基三乙氧基矽烷、γ-甲基丙烯醯氧基丙基甲基二乙氧基矽烷等。其中，就提高耐水性或提高對基底或舊砂漿面之接著強度之觀點而言，較佳為乙烯基三甲氧基矽烷。 作為上述含有乙醯乙醯基之單體，例如可列舉：乙醯乙酸乙烯酯、乙醯乙酸烯丙酯、二乙醯乙酸烯丙酯、(甲基)丙烯酸乙醯乙醯氧基乙酯、巴豆酸乙醯乙醯氧基乙酯、(甲基)丙烯酸乙醯乙醯氧基丙酯、巴豆酸乙醯乙醯氧基丙酯、(甲基)丙烯酸2-氰基乙醯乙醯氧基乙酯等。其中，尤其就物性偏差較少、且提高耐水性、或提高對基底或舊砂漿面之接著強度等之觀點而言，較佳為(甲基)丙烯酸乙醯乙醯氧基乙酯。 作為於上述分子結構中具有2個以上乙烯基之單體，例如可列舉：二乙烯苯、鄰苯二甲酸二烯丙酯、氰尿酸三烯丙酯、異氰尿酸三烯丙酯、乙二醇二(甲基)丙烯酸酯、1,2-丙二醇二(甲基)丙烯酸酯、1,3-丙二醇二(甲基)丙烯酸酯、1,4-丁二醇二(甲基)丙烯酸酯、1,6-己二醇二(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、三羥甲基丙烷三(甲基)丙烯酸酯、(甲基)丙烯酸烯丙酯等。 作為上述含有羥基之單體，例如可列舉：(甲基)丙烯酸2-羥基乙酯、(甲基)丙烯酸羥基丙酯、(甲基)丙烯酸4-羥基丁酯等(甲基)丙烯酸酯等。其中，就乳化聚合時之保護膠體作用及與水泥漿調配物等之混合性改良之觀點而言，較佳為甲基丙烯酸2-羥基乙酯。 於本發明中，就提高耐水壓縮強度或耐水彎折強度之觀點而言，作為聚合成分[I]，其係含有相對於20℃之水之溶解度為0.1%以下之疏水性單體(以下，有時僅記載為[疏水性單體])作為必須成分者，且其含量必須為相對於聚合成分[I]整體為30重量%以上，較佳為40重量%以上，進而較佳為50重量%以上，尤其較佳為70重量%以上。再者，上限通常為100重量%以下。若疏水性單體之含量過少，則砂漿之耐水壓縮強度或耐水彎折強度降低，故而不佳。 作為上述相對於20℃之水之溶解度為0.1%以下之疏水性單體，具體而言可列舉以下。 丙烯酸系單體：例如可列舉：(甲基)丙烯酸正丁酯、(甲基)丙烯酸異丁酯、(甲基)丙烯酸第三丁酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸環己酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸辛酯、(甲基)丙烯酸硬脂酯等烷基之碳數為4以上、較佳為6～18之(甲基)丙烯酸酯，尤其是脂肪族系(甲基)丙烯酸酯、或苯氧基丙烯酸酯等芳香族系(甲基)丙烯酸酯、甲基丙烯酸三氟乙酯等。 苯乙烯系單體：例如可列舉：苯乙烯、α-甲基苯乙烯等。 乙烯系單體：例如可列舉：月桂酸乙烯酯、硬脂酸乙烯酯、特十碳酸乙烯酯等。 上述疏水性單體中，較佳為使用烷基之碳數為4以上之脂肪族系(甲基)丙烯酸酯系單體、苯乙烯系單體，尤其較佳為使用苯乙烯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸2-乙基己酯。 上述疏水性單體可使用1種或併用2種以上。 於本發明中，尤其，較佳為含有苯乙烯作為疏水性單體，且苯乙烯相對於疏水性單體整體之含有比率為80重量%以下，尤其較佳為70重量%以下，進而較佳為60重量%以下。另一方面，苯乙烯含量之下限尤其較佳為30重量%以上，進而較佳為40重量%以上。 若苯乙烯含有比率大於80重量%，則存在產生紫外線導致之聚合物之劣化或變色、耐候性降低之問題之情形。另一方面，若苯乙烯含有比率為30重量%，則就耐水性更加優異之觀點而言較佳。 本發明中所使用之聚乙烯醇系樹脂(以下，有時記載為[PVA(polyvinyl alcohol，聚乙烯醇)系樹脂])係用於賦予聚合中之預乳液之分散穩定性之目的、及賦予所得之水性合成樹脂乳液穩定性、同時使得對該乳液進行噴霧乾燥所獲得之再乳化性合成樹脂粉末於水中容易再分散之目的者。 作為PVA系樹脂之平均皂化度，較佳為70莫耳%以上，尤其較佳為80莫耳%以上，進而較佳為85莫耳%以上。另一方面，平均皂化度之上限較佳為99.9莫耳%，尤其較佳為99.5莫耳%，進而較佳為99.0莫耳%。 若該平均皂化度過低，則存在難以穩定地進行聚合，且即便完成了聚合，乳液之保存穩定性亦降低之傾向，若過高，則存在再乳化性合成樹脂粉末變得難以再乳化之傾向。 再者，平均皂化度可根據JIS K 6726中記載之皂化度之算出方法而求出。 又，作為PVA系樹脂之平均聚合度，較佳為50以上，尤其較佳為100以上，進而較佳為200以上。另一方面，平均聚合度之上限較佳為3,000，尤其較佳為2,000，進而較佳為1,000。 若該平均聚合度過低，則存在乳化聚合時之保護膠體能力變得不充分，且聚合難以穩定地進行之傾向；若過高，則存在聚合時增黏、反應系統變得不穩定，且分散穩定性降低之傾向。 再者，平均聚合度可根據JIS K 6726中記載之平均聚合度之算出方法而求出。 於本發明中，作為PVA系樹脂，可使用PVA、或利用各種改性種改性而成之改性PVA系樹脂，其改性量通常為20莫耳%以下，較佳為15莫耳%以下，進而較佳為10莫耳%以下。再者，下限值為0.01莫耳%。 作為改性PVA系樹脂，例如可列舉藉由以羧基、磺酸基、磷酸基為首之陰離子性基改性而成之陰離子改性PVA系樹脂、藉由四級銨基等陽離子性基改性而成之陽離子改性PVA系樹脂、藉由以乙醯乙醯基、二丙酮丙烯醯胺基、巰基、矽烷醇基為首之各種官能基等改性而成之改性PVA系樹脂、或於支鏈上具有1,2-二醇鍵之PVA系樹脂等。 於本發明中，PVA系樹脂之使用量相對於上述聚合成分[I]100重量份而言，較佳為20重量份以下，尤其較佳為10重量份以下，進而較佳為7重量份以下。另一方面，PVA系樹脂使用量之上限較佳為0.01重量份，尤其較佳為0.1重量份，進而較佳為0.5重量份。 若該PVA系樹脂之使用量過少，則存在乳化聚合時之乳化力變得不足，聚合成分之分散穩定性降低，且聚合穩定性降低之傾向；若使用量過多，則存在合成樹脂乳液之黏度提高，穩定性降低之傾向。 又，於本發明中，PVA系樹脂通常使用水性介質製成水溶液，並將其用於乳化聚合之過程中。作為該水性介質，例如可列舉：水、或以水為主體之醇性溶劑，較佳為水。 關於上述水溶液中之PVA系樹脂之含有比率(固形物成分)，就處理之容易性之觀點而言，較佳為5～30重量%。 作為乳化聚合之方法，必須於PVA系樹脂之存在下，一面向水性介質中連續地添加聚合成分[I]之總量一面使其乳化聚合，例如可向反應罐中加入水性介質、PVA系樹脂，將其升溫，向其中連續地滴加聚合成分[I]之總量，使其聚合。 作為上述水性介質，例如可列舉：水、或以水為主體之醇性溶劑，較佳為水。 又，於本發明中，預先於PVA系樹脂之存在下使聚合成分[I]之總量乳化分散於水性介質中而製備預乳液，較佳為一面向水性介質中連續地添加該預乳液之總量一面使其乳化聚合。 作為該預乳液之調整方法，例如可列舉一面攪拌PVA系樹脂之水溶液一面滴加聚合成分[I]之方法。作為此時之攪拌裝置，可使用利用攪拌翼進行之攪拌混合、或靜態混合機、搖動式混合機、均質機等眾所周知的分散機，但其中較佳為利用攪拌翼進行之攪拌混合。 本發明中，必須一面向水性介質中連續地添加聚合成分[I](或上述預乳液)之總量一面使其乳化聚合。 此處，一面連續地添加總量一面使其乳化聚合係指不進行初期聚合，一面連續地添加總量一面使其乳化聚合，且係指與先前之方法，即藉由使特定量進行初期聚合後，滴加剩餘成分等方式而使其乳化聚合之方法不同之乳化方法。 作為上述連續之添加方法，例如可列舉使用滴加漏斗或旋轉泵向水性介質中滴加聚合成分[I]之方法。 關於該滴加速度，一般於被視為連續滴加之條件下進行滴加即可，考慮到所使用之聚合成分之反應性或下述聚合起始劑之使用量、反應溫度等進行適當調整即可，但具體而言，例如通常將滴加間隔設為10秒以內，較佳為設為5秒以內，一次之滴加量通常為單體總量之2重量%以下，較佳為1重量%以下即可。 再者，上述滴加間隔及一次之滴加量可均勻亦可不均勻。 又，較佳為滴加總量之聚合成分[I]後，設置固定時間之熟成期間。 作為乳化聚合條件，可根據聚合成分之種類、聚合水垢等適當選擇，但作為反應時之溫度條件，通常為40℃以上，尤其較佳為60℃以上。反應時之溫度條件之上限通常為90℃，尤其較佳為80℃。 又，較佳為於乳化聚合時進行攪拌，作為此時之攪拌裝置，可使用與上述用於預乳液之調整者相同者，其中，較佳為利用攪拌翼進行之攪拌混合。 又，通常較佳為於乳化聚合中使用聚合起始劑，此外，可視需要使用聚合調整劑、輔助乳化劑、塑化劑等。 上述聚合起始劑為可用於通常之乳化聚合者即可，例如可列舉：過硫酸鉀、過硫酸鈉、過硫酸銨等無機過氧化物；有機過氧化物、偶氮系起始劑、過氧化氫、丁基過氧化物等過氧化物；及將該等與酸性亞硫酸鈉或L-抗壞血酸等還原劑組合而成之氧化還原聚合起始劑等。該等可併用2種以上。 於本發明中，其中，就不給皮膜物性或強度增強帶來不良影響且聚合容易之觀點而言，較佳為使用無機過氧化物，尤其較佳為過硫酸銨或過硫酸鉀。 作為聚合起始劑之添加方法，可使用於初期進行一次添加之方法、或隨著聚合之進行分批添加之方法等，於分批添加之方法等中，可使用分多次添加至反應罐中之方法、或與聚合成分一起連續地滴加之方法等。 該聚合起始劑之使用量根據所使用之聚合成分之種類或聚合條件等而有所不同，但通常為相對於聚合成分[I]100重量份為0.01重量份以上，較佳為0.5重量份以上。又，使用量之上限通常為5重量份，較佳為3重量份。 作為上述聚合調整劑，可自眾所周知者中適當選擇。作為此種聚合調整劑，例如可列舉：鏈轉移劑、緩衝劑等。 作為上述鏈轉移劑，例如可列舉：甲醇、乙醇、丙醇、丁醇等醇；乙醛、丙醛、正丁醛、糠醛、苯甲醛等醛類；及十二硫醇、月桂硫醇、正硫醇、硫代乙醇酸、硫代乙醇酸辛酯、硫甘油等硫醇類等。該等可單獨使用亦可併用2種以上。 作為上述緩衝劑，例如可列舉：乙酸鈉、乙酸銨、第二磷酸鈉、檸檬酸鈉等。該等可單獨使用亦可併用2種以上。 作為輔助乳化劑，通常為可用於乳化聚合者即可，例如可列舉：陰離子性、陽離子性、及非離子性之界面活性劑、除PVA系樹脂以外之具有保護膠體能之水溶性高分子、及水溶性低聚物等。 作為上述界面活性劑，例如可列舉：如月桂基硫酸鈉、十二烷基苯磺酸鈉之陰離子性界面活性劑、及具有Pluronic型結構者或具有聚氧乙烯型結構者等的非離子性界面活性劑。又，作為界面活性劑，亦可使用於結構中具有自由基聚合性不飽和鍵之反應性界面活性劑。該等可單獨使用或組合2種以上使用。 上述界面活性劑之使用具有使乳化聚合順利進行且容易控制(作為乳化劑之效果)、或抑制於聚合中產生之粗粒子或塊狀物之產生之效果。然而，若大量使用該等界面活性劑作為乳化劑，則有接枝率降低之傾向。因此，於使用界面活性劑之情形時，其使用量較佳為相對於PVA系樹脂為輔助量，即儘可能減少。 作為除PVA系樹脂以外之具有保護膠體能之水溶性高分子，例如可列舉：羥乙基纖維素、聚乙烯吡咯啶酮、甲基纖維素等。該等可單獨使用或組合2種以上使用。該等具有改變乳液之穩定性或乳液之粒徑，從而改變黏性之效果。然而，根據其使用量，存在皮膜之耐水性降低之情況，故而使用時較理想為使用少量。 作為水溶性低聚物，例如較佳為具有磺酸基、羧基、羥基、伸烷基二醇基等親水性基之聚合物，其中較佳地可列舉具有10～500左右之聚合度之聚合物或共聚物。作為水溶性低聚物之具體例，例如可列舉：2-甲基丙烯醯胺-2-甲基丙磺酸共聚物等醯胺系共聚物、甲基丙烯酸鈉-4-苯乙烯磺酸酯共聚物、苯乙烯/馬來酸共聚物、三聚氰胺磺酸甲醛縮合物、聚(甲基)丙烯酸鹽等。進而，作為具體例，亦可列舉預先使具有磺酸基、羧基、羥基、伸烷基二醇基等之單體或自由基聚合性之反應性乳化劑單獨或與其他單體共聚合而成之水溶性低聚物等。該等可單獨使用或組合2種以上使用。 作為上述塑化劑，可使用己二酸系塑化劑、鄰苯二甲酸系塑化劑、磷酸系塑化劑等。 如此，利用本發明之製造方法，即：於PVA系樹脂之存在下，一面向水性介質中連續地添加聚合成分[I]之總量一面使其乳化聚合之方法，可製造水性合成樹脂乳液。 所得之水性合成樹脂乳液系利用PVA系樹脂將合成樹脂粒子分散穩定化於水性介質中而成者。 於本發明中，利用乳化聚合所獲得之水性合成樹脂乳液典型而為均勻之乳白色，水性合成樹脂乳液中之合成樹脂粒子之平均粒徑較佳為0.2 μm以上，尤其較佳為0.3 μm以上。又，平均粒徑之上限較佳為2 μm，尤其較佳為1.5 μm。若該合成樹脂粒子之平均粒徑過大，則有聚合穩定性降低之傾向，若過小，則有水性合成樹脂乳液之黏度變得過高之傾向。 再者，平均粒徑可利用慣用之方法，例如，利用雷射解析/散射式粒度分佈測定裝置[LA-950S2](HORIBA股份有限公司製造)而測定。 又，利用本發明之製造方法所獲得之水性合成樹脂乳液中之合成樹脂粒子之玻璃轉移溫度(Tg)較佳為-40℃以上，尤其較佳為-30℃以上，進而較佳為-20℃以上。又，玻璃轉移溫度(Tg)之上限較佳為30℃，尤其較佳為20℃，進而較佳為10℃。若該玻璃轉移溫度過高，則有於低溫時不能充分發揮樹脂之作為接著劑之效果之傾向，若過低，則有壓縮強度或彎折強度降低之傾向。 玻璃轉移溫度係利用由下述數學式1所示之Fox之式而算出者。 [數學式1]再者，製成構成合成樹脂之單體之均聚物時之玻璃轉移溫度通常係利用示差掃描熱量計(DSC)而測定者。 利用本發明之製造方法所獲得之水性合成樹脂乳液於23℃時之黏度較佳為100 mPa･s以上，尤其較佳為300 mPa･s以上，進而較佳為500 mPa･s以上。另一方面，黏度之上限較佳為5,000 mPa･s，尤其較佳為3,000 mPa･s，進而較佳為2,000 mPa･s。該黏度過高或過低則有水性合成樹脂乳液變得難以粉末化之傾向。 再者，黏度之測定方法係利用B型黏度計而進行。 又，利用本發明之製造方法所獲得之水性合成樹脂乳液之固形物成分濃度較佳為30重量%以上，尤其較佳為35重量%以上，進而較佳為40重量%以上。另一方面，固形物成分濃度之上限較佳為60重量%，尤其較佳為55重量%，進而較佳為50重量%。若該固形物成分濃度過低，則有將水性合成樹脂乳液粉末化時之製造效率降低之傾向，若過高則有水性合成樹脂乳液變得難以粉末化之傾向。 於本發明中，乳化聚合後之水性合成樹脂乳液亦可視需要進一步加入各種添加劑。作為此類添加劑，例如可列舉：有機顏料、無機顏料、水溶性添加劑、pH調整劑、防腐劑、抗氧化劑等。 如此，利用本發明之製造方法所獲得之水性合成樹脂乳液於直接使用時，通常較佳為將固形物成分濃度調整至40～60重量%。 [再乳化性合成樹脂粉末之製造方法] 藉由對利用上述製造方法所獲得之水性合成樹脂乳液進行乾燥，可獲得本發明之再乳化性合成樹脂粉末。再乳化性合成樹脂粉末藉由與水混合而具有再乳化之功能，例如可有效用作聚合物水泥用途。 水性合成樹脂乳液之乾燥方法例如可列舉：噴霧乾燥、冷凍乾燥、凝集後之溫風乾燥等。該等之中，就生產成本、節能之觀點或連續生產性之觀點而言，較佳為噴霧乾燥。 噴霧乾燥之情形時，其噴霧形式可利用例如碟片式、噴嘴式等形式而實施。作為噴霧乾燥之熱源，例如可列舉：熱風、加熱水蒸氣等。作為噴霧乾燥之條件，可根據噴霧乾燥機之大小、種類、合成樹脂乳液之非揮發成分、黏度、流量等適當選擇。噴霧乾燥之溫度通常較佳為80℃以上，更佳為120℃以上。又，噴霧乾燥溫度之上限較佳為180℃，更佳為160℃。 若乾燥溫度過低，則有乾燥需要時間，且生產效率降低之傾向，若過高，則有因熱而導致之樹脂本身之變質變得容易發生之傾向。 具體而言，例如利用噴霧乾燥機之噴嘴連續地供給水性合成樹脂乳液，利用溫風使成為霧狀者乾燥並粉末化。根據情形，亦能夠於噴霧時預先將調整後之噴霧液加溫，並利用噴嘴連續地供給，利用溫風使成為霧狀者乾燥並粉末化。藉由加溫，乾燥速度變快，且隨著噴霧液之黏度降低，噴霧液之非揮發成分能夠變高，亦有助於降低生產成本。 又，為進一步提高再乳化性合成樹脂粉末於水中之再乳化性，可調配水溶性添加劑。通常，水溶性添加劑係調配至乾燥前之水性合成樹脂乳液中。該調配量相對於乾燥前之水性合成樹脂乳液之非揮發成分100重量份為2～50重量份。若調配量過少，則有不能充分謀求於水中之再乳化性之提高之傾向，若過多，則有雖顯著有助於在水中之再乳化性之提高，但皮膜之耐水性降低，變得不能發揮期待之物性之傾向。 作為上述水溶性添加劑，例如可列舉：PVA系樹脂類、羥乙基纖維素類、甲基纖維素類、聚乙烯吡咯啶酮、澱粉類、糊精類、水溶性醇酸樹脂、水溶性胺基樹脂、水溶性丙烯酸樹脂、水溶性多羧酸樹脂、水溶性聚醯胺樹脂等水溶性樹脂。該等可單獨使用或組合2種以上使用。該等之中，較佳為PVA系樹脂類。作為PVA系樹脂類，可使用與上述PVA系樹脂相同者，可使用未改性PVA之部分或完全皂化品、或各種改性PVA之部分或完全皂化品，亦可併用該等。 作為上述PVA系樹脂類，較佳為平均皂化度85莫耳%以上之PVA，尤其較佳為87莫耳%以上之PVA。又，作為平均皂化度之上限值，較佳為99.5莫耳%，更佳為95莫耳%。若平均皂化度過小，則有所得之聚合物水泥漿之耐水性顯著降低之傾向，若過大，則有於水中之再乳化性降低之傾向。 又，該平均聚合度較佳為50以上，更佳為200以上，進而較佳為300以上。又，平均聚合度之上限較佳為3,000，更佳為2,000，進而較佳為600。若平均聚合度過小，則有耐水性降低之傾向，若過大，則有再乳化性降低之傾向。 如此，獲得本發明之再乳化性合成樹脂粉末。 亦可使本發明之再乳化性合成樹脂粉末中進而含有防膠著劑、減水劑、分散劑、砂漿流動化促進劑、撥水劑、抗氧化劑、防銹劑等。 再者，防膠著劑可藉由混合於水性合成樹脂乳液中，或混合於噴霧乾燥後之樹脂乳液粉末中，或於噴霧乾燥時與水性合成樹脂乳液一起自其他噴嘴進行噴霧等而含有。 [再乳化所獲得之水性合成樹脂乳液] 上述再乳化性合成樹脂粉末可藉由加入上述水性介質而使其再乳化，可獲得水性合成樹脂乳液。該再乳化所獲得之水性合成樹脂乳液可發揮與製成再乳化性合成樹脂粉末前之水性合成樹脂乳液相同之效果。 [聚合物水泥組合物、聚合物水泥漿] 如此所獲得之再乳化性合成樹脂粉末可與水泥調配作為聚合物水泥組合物而使用，進而可藉由將水或砂、砂礫進行調配而作為砂漿或混凝土而使用。再者，若於該聚合物水泥組合物中調配有水，則再乳化性合成樹脂粉末被再乳化而重新生成水性合成樹脂乳液。 作為上述水泥，例如可列舉：普通波特蘭水泥、氧化鋁水泥、早強波特蘭水泥、超早強波特蘭水泥、中熱波特蘭水泥、低熱波特蘭水泥、耐硫酸鹽波特蘭水泥、高爐水泥、飛灰水泥、矽石水泥等，其中就作業性之觀點而言，較佳為波特蘭水泥。 上述水泥之調配量較佳為相對於再乳化性合成樹脂粉末100重量份為3重量份以上，進而較佳為30重量份以上。又，上述水泥調配量之上限較佳為500重量份，進而較佳為350重量份。 用作砂漿或混凝土時之水之調配量，較佳為相對於聚合物水泥組合物總量，為50重量%以下，進而較佳為30重量%以下。 又，用作砂漿或混凝土時之砂、砂礫之調配量較佳為相對於聚合物水泥組合物總量為30重量%以上，進而較佳為50重量%以上。上述砂、砂礫之調配量之上限較佳為300重量份，進而較佳為150重量份。 再者，於上述聚合物水泥組合物中，可視需要將水泥之減水劑或塑化劑(例如木質素系、萘系、三聚氰胺系、羧酸系等)、收縮降低劑(例如二醇醚系、聚醚系等)、耐寒劑(例如氯化鈣等)、防水劑(例如硬脂酸等)、防銹劑(例如磷酸鹽等)、黏度調整劑(例如甲基纖維素、羥乙基纖維素、聚乙烯醇等)、分散劑(例如多羧酸系、無機磷系等)、消泡劑(例如矽系、礦物油系等)、防腐劑、補強劑(例如鋼纖維、玻璃纖維、合成纖維、碳纖維等)等單獨使用或併用2種以上。 於使用聚合物水泥組合物製備聚合物水泥漿之情形時，與一般之砂漿相同，可藉由加入必須成分及任意成分，並向其中加入適量水，然後使用混練機等進行混練而製備。 聚合物水泥漿通常係用於根據JIS A 6203之步驟，於JIS R 5201之試驗中，以流值變成170±5mm之方式進行調整者。 若使用利用本發明之製造方法所獲得之再乳化性合成樹脂粉末，則與利用先前之製造方法所獲得之再乳化性合成樹脂粉末相比，可藉由調配少量水而製備為所需之流值，進而可無需添加減水劑等添加劑而調整至所需之流值，故而可謂利用本發明之製造方法所獲得之再乳化性合成樹脂粉末係塗佈性優異者。再者，一般而言，若調配之水之量過多，則硬化速度降低，或所得之硬化物之強度降低，故而不佳。 如此所獲得之聚合物水泥組合物於混合至水泥漿中時，顯示出良好之流動性、作業性，且對舊砂漿面或樹脂塗佈面等之密接性優異。又，起到物性偏差較少，且接著強度提高等優異效果。並且，該等聚合物水泥組合物作為水泥漿混合劑，並作為維護砂漿用、基底調整塗料用、自流平材料、磁磚接著砂漿、砂漿密封材料、底塗劑、砂漿養護劑、及石膏系材料等之改質劑而較為有用，進而，對於土木、建築材料用原料、玻璃纖維收斂劑、阻燃劑用途等亦較為有用。 [實施例] 以下，列舉實施例進一步具體說明本發明，但只要不超出其主旨，則本發明並不限定於以下之實施例。再者，例中「份」、「%」係指重量基準。 ＜實驗例1＞ [預乳液之製備] 向燒瓶中添加聚乙烯醇(日本合成化學工業(股)製造之Gosenol GL-03)5份、水49份，於80℃下充分溶解1小時後，冷卻至室溫，繼而添加苯乙烯46份、丙烯酸丁酯54份，利用渦輪翼繼續攪拌30分鐘並使其乳化，製備出預乳液。 [水性合成樹脂乳液之製造] 向具備槳型攪拌翼、回流冷卻器、滴加漏斗、溫度計之可分離式燒瓶中加入水52份、乙酸鈉1份，一面以150 rpm攪拌一面將燒瓶內之溫度升溫至80℃。其次，向燒瓶中添加過硫酸銨10%水溶液3份，繼而利用滴加漏斗將上述所製備之預乳液154份與過硫酸銨10%水溶液4.6份用5小時滴加，進行聚合反應。接著，於80℃下熟成2小時，在此期間將過硫酸銨10%水溶液3.5份分3次添加，完成反應，冷卻至室溫，獲得非揮發成分48.7%、黏度2,940 mPa.s(布魯克菲爾德型黏度計BM12 rpm、23℃)之水性合成樹脂乳液。 [再乳化性合成樹脂粉末之製造] 向所得之水性合成樹脂乳液100重量份中添加聚乙烯醇(日本合成化學工業(股)製造之Gosenol GL－05)之20%水溶液20份後，於抗黏結劑(商品名INCOMP SE－SUPER、Paltentaler Minerals GmbH＆Co KG)14份之存在下，於140℃之氣流環境下，一面進行噴霧器噴霧一面使其乾燥，獲得樹脂粉末(再乳化性合成樹脂粉末)。 ＜比較例1＞ [預乳液之製備] 與實施例1相同地進行，製備出預乳液。 [水性合成樹脂乳液之製造] 向具備漿型攪拌翼、回流冷卻器、滴加漏斗、溫度計之可分離式燒瓶中加入水52份、乙酸鈉1份，以150 rpm一面攪拌一面將燒瓶內之溫度升溫至80℃。其次，向燒瓶中添加過硫酸銨10%水溶液3份，進而一次添加上述所製備之預乳液15.4份(聚合單體總量之10%)，進行60分鐘初期聚合後，繼而利用滴加漏斗將預乳液138.6份與過硫酸銨10%水溶液4.6份用5小時滴加，進行聚合反應。接著，於80℃下熟成2小時，在此期間將過硫酸銨10%水溶液3.5份分3次添加，完成反應，冷卻至室溫，獲得非揮發成分48.6%、黏度6,390 mPa.s(布魯克菲爾德型黏度計BM12 rpm、23℃)之水性合成樹脂乳液。 [再乳化性合成樹脂粉末之製造] 使用所得之水性合成樹脂乳液，與實施例1相同地進行，獲得樹脂粉末(再乳化性合成樹脂粉末)。 ＜比較例2＞ [預乳液之製備] 與實施例1相同地進行，製備出預乳液。 [水性合成樹脂乳液之製造] 向具備漿型攪拌翼、回流冷卻器、滴加漏斗、溫度計之可分離式燒瓶中加入水52份、乙酸鈉1份，一面以150 rpm攪拌一面將燒瓶內之溫度升溫至80℃。其次，向燒瓶中添加過硫酸銨10%水溶液3份，進而一次添加上述所製備之預乳液3.1份(聚合單體總量之2%)，進行60分鐘初期聚合後，繼而利用滴加漏斗將預乳液150.9份與過硫酸銨10%水溶液4.6份用5小時滴加，進行聚合反應。接著，於80℃下熟成2小時，在此期間將過硫酸銨10%水溶液3.5份分3次添加，完成反應，冷卻至室溫，獲得非揮發成分49.1%、黏度34,600 mPa.s(布魯克菲爾德型黏度計BM12 rpm、23℃)之水性合成樹脂乳液。 [再乳化性合成樹脂粉末之製造] 雖然想要使用所得之水性合成樹脂乳液，與實施例1相同地進行，製造再乳化性合成樹脂粉末，但黏度較高，不能進行噴霧器噴霧。 ＜比較例3＞ [預乳液之製備] 與實施例1相同地進行，製備出預乳液。 [水性合成樹脂乳液之製造] 向具備漿型攪拌翼、回流冷卻器、滴加漏斗、溫度計之可分離式燒瓶中加入水52份、乙酸鈉1份，一面以150 rpm攪拌一面將燒瓶內之溫度升溫至80℃。其次，向燒瓶中添加過硫酸銨10%水溶液3份，進而一次添加上述所製備之預乳液7.7份(聚合單體總量之5%)，進行30分鐘初期聚合後，繼而利用滴加漏斗將預乳液146.3份與過硫酸銨10%水溶液4.6份用5小時滴加，進行聚合反應。接著，於80℃下熟成2小時，在此期間將過硫酸銨10%水溶液3.5份分3次添加，完成反應，冷卻至室溫，獲得非揮發成分49.1%、黏度26,200 mPa.s(布魯克菲爾德型黏度計BM12 rpm、23℃)之水性合成樹脂乳液。 [再乳化性合成樹脂粉末之製造] 雖然想要使用所得之水性合成樹脂乳液，與實施例1相同地進行，製造再乳化性合成樹脂粉末，但黏度較高，不能進行噴霧器噴霧。 ＜比較例4＞ [預乳液之製備] 與實施例1相同地進行，製備出預乳液。 [水性合成樹脂乳液之製造] 向具備漿型攪拌翼、回流冷卻器、滴加漏斗、溫度計之可分離式燒瓶中加入水52份、乙酸鈉1份，一面以150 rpm攪拌一面將燒瓶內之溫度升溫至80℃。其次，向燒瓶中添加過硫酸銨10%水溶液3份，進而一次添加上述所製備之預乳液15.4份(聚合單體總量之10%)，進行10分鐘初期聚合後，繼而利用滴加漏斗將預乳液138.6份與過硫酸銨10%水溶液4.6份用5小時滴加，但中途反應變得不穩定，不能進行良好之聚合反應，無法獲得水性合成樹脂乳液。 使用於上述實施例1及比較例1中所得之再乳化性合成樹脂粉末，利用以下之方法評價再乳化性、聚合物水泥漿之流動性。 ＜樹脂粉末之再乳化性＞ 於去離子水100份中，一面攪拌一面添加再乳化性水性合成樹脂乳液粉末100份，之後以1000轉速攪拌10分鐘，使其再乳化。測定該再乳化液於布魯克菲爾德型黏度計BM12 rpm、23℃時之黏度。評價基準如以下所示。結果示於表2。 (評價基準) ○・・・再乳化後之乳液溶液之黏度為未達3,000 mPa.s △・・・再乳化後之乳液溶液之黏度為3,000 mPa.s以上且未達5,000 mPa.s ×・・・再乳化後之乳液溶液之黏度為5,000 mPa.s以上 ＜聚合物水泥漿之流動性＞ 依據JIS A6203，如下述表1，將再乳化性合成樹脂粉末與各種成分進行調配，加水直至聚合物水泥漿符合規定之流值：170±5 mm，製作出聚合物水泥漿。 各加水量中之聚合物水泥漿之流值示於表1。 [表1]
關於加水直至滿足JIS A6203中規定之流值而成之聚合物水泥漿，求出水/水泥(%)，以下述基準進行評價。結果示於表2。 (評價基準) ○・・・水/水泥為未達80% ×・・・水/水泥為80%以上 [表2]
如表2所示，可知利用本發明之製造方法所獲得之實施例1之合成樹脂乳液的黏度較低，將其乾燥所得之乳化性合成樹脂粉末的再乳化性優異，使用其而成之水泥漿之流動性良好。 另一方面，利用單體之聚合方法與本發明之製造方法不同之製造方法所獲得之比較例1之合成樹脂乳液黏度較高，將其乾燥所獲得之再乳化性合成樹脂粉末再乳化後之黏度亦較高，再乳化性較差。 又，自表1及表2之結果可知，使用將利用比較例1之製造方法所獲得之合成樹脂乳液進行乾燥所獲得之再乳化性合成樹脂粉末之聚合物水泥漿若為與實施例1相同之加水量，則無法符合JIS A 6203中規定之流值，為以符合規定之流值之方式進行調整，必須加入更多水，與將利用實施例1之製造方法所獲得之樹脂乳液進行乾燥所獲得之再乳化性合成樹脂粉末相比，可知其係流動性較差者。若聚合物水泥漿之加水量較多，則聚合物水泥之硬化速度降低，又，所得之硬化物之強度降低，故而實用性較差。 又，由於利用比較例2、3之製造方法所獲得之合成樹脂乳液的黏度較高，故而無法獲得再乳化性合成樹脂粉末，於比較例4之製造方法中，聚合穩定性較差，無法獲得合成樹脂乳液。 [產業上之可利用性] 根據本發明之水性合成樹脂乳液之製造方法，可獲得固形物成分濃度高且黏度低之水性合成樹脂乳液，因此，可生產效率較好地獲得再乳化後之作業性優異之乳液粉末，利用本發明之再乳化性合成樹脂粉末之製造方法所獲得之再乳化性合成樹脂粉末及將其再乳化所獲得之水性合成樹脂乳液於用作水泥漿混合劑時，顯示出良好之流動性、作業性，作為水泥漿用途，作為維護砂漿用、基底調整塗料用、自流平材料、瓷磚接著砂漿、及石膏系材料等之改質劑非常有用。Hereinafter, the configuration of the present invention will be described in detail, but these are examples of preferred embodiments, and the present invention is not intended to be specific. [Method for Producing Aqueous Synthetic Resin Emulsion] The method for producing an aqueous synthetic resin emulsion of the present invention is a polymerization component in the presence of a polyvinyl alcohol-based resin (hereinafter, the polymerization component used in the present invention is referred to as a [polymerization component] [I]]) An emulsion polymerizer characterized in that an emulsion polymerization is carried out while continuously adding the total amount of the polymerization component [I] to an aqueous medium. The polymer component [I] is preferably a monomer component containing at least one of an acrylic monomer, a styrene monomer, and a vinyl ester monomer as a main component. In the present invention, the main component means 50% by weight or more of the whole, and the entire system is composed of only the main component. Examples of the acrylic monomer include methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, and (meth)acrylic acid. Third butyl ester, 2-ethylhexyl (meth)acrylate, cyclohexyl (meth)acrylate, lauryl (meth)acrylate, octyl (meth)acrylate, stearyl (meth)acrylate An aromatic (meth) acrylate such as an aliphatic (meth) acrylate or a phenoxy (meth) acrylate or a trifluoroethyl (meth) acrylate, etc., wherein the carbon number of the alkyl group is The aliphatic (meth) acrylate of 1 to 18, particularly 1 to 10 is preferable, and one or two or more kinds of these may be used. Further, in the present invention, the term "(meth)acrylate" means acrylate or methacrylate. Examples of the styrene-based monomer include styrene and α-methylstyrene. These may be used alone or in combination of two or more. The vinyl ester-based monomer may, for example, be a linear or branched vinyl ester of a monocarboxylic acid having 2 to 12 carbon atoms, and specific examples thereof include vinyl formate, vinyl acetate, and propionic acid. Vinyl ester, vinyl valerate, vinyl butyrate, vinyl isobutyrate, vinyl pivalate, vinyl decanoate, vinyl laurate, vinyl stearate, vinyl benzoate, tetraethylene carbonate Ester, vinyl 2-ethylhexanoate, and the like. These may be used alone or in combination of two or more. Further, a monomer having a functional group or the like may be included, and examples thereof include a monomer containing a glycidyl group, a monomer containing an allyl group, a monomer having a hydrolyzable alkylene group, and a monomer containing an ethylidene group. A monomer having two or more vinyl groups, a monomer having a hydroxyl group, or the like in a molecular structure. Examples of the glycidyl group-containing monomer include glycidyl (meth)acrylate, glycidyl (meth)allyl ether, and 3,4-(meth)acrylic acid epoxycyclohexyl ester. . Among them, in particular, glycidyl (meth)acrylate is preferred from the viewpoints of less variation in physical properties and improvement in adhesion strength at the time of wetting. Examples of the allyl group-containing monomer include triallyloxyethylene, diallyl maleate, triallyl cyanurate, triallyl isocyanurate, and tetraallyloxy B. A monomer having two or more allyl groups such as an alkane, allyl glycidyl ether, allyl acetate, or the like. Among them, allyl glycidyl ether is preferred from the viewpoint of the strength at the time of wetting. Examples of the hydrolyzable allyl group-containing monomer include vinyl trimethoxy decane, vinyl triethoxy decane, vinyl tris (β-methoxyethoxy) decane, and vinyl methyl group. Dimethoxydecane, γ-methacryloxypropyltrimethyldecane, γ-methylpropenyloxypropyldimethoxydecane, γ-propyleneoxypropyltrimethoxydecane, γ propylene methoxy propyl methyl dimethoxy decane, γ-methyl propylene methoxy propyl triethoxy decane, γ-methyl propylene methoxy propyl methyl diethoxy decane, and the like. Among them, vinyltrimethoxydecane is preferred from the viewpoint of improving water resistance or improving the adhesion strength to the substrate or the old mortar surface. Examples of the monomer containing an ethyl oxime group include ethyl acetate, vinyl acetate, allyl acetate, and ethyl (meth) acrylate. , acetophenic acid ethyl ethoxylate, (meth) acrylate ethoxypropyl propylate, acetophenoxy propyl propyl methacrylate, 2-cyanoacetamido (meth) acrylate Oxyethyl ester and the like. Among them, in particular, from the viewpoint of less variation in physical properties, improvement in water resistance, or improvement in adhesion strength to a substrate or an old mortar surface, etc., ethyl acetoxyethyl (meth)acrylate is preferred. Examples of the monomer having two or more vinyl groups in the above molecular structure include divinylbenzene, diallyl phthalate, triallyl cyanurate, triallyl isocyanurate, and ethylene. Alcohol di(meth)acrylate, 1,2-propanediol di(meth)acrylate, 1,3-propanediol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, allyl (meth)acrylate, and the like. Examples of the hydroxyl group-containing monomer include (meth)acrylate such as 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, and 4-hydroxybutyl (meth)acrylate. . Among them, 2-hydroxyethyl methacrylate is preferred from the viewpoint of the protective colloid action during emulsion polymerization and the improvement of the mixing property with the cement slurry preparation and the like. In the present invention, the polymerizable component [I] contains a hydrophobic monomer having a solubility of 0.1% or less with respect to water at 20 ° C from the viewpoint of improving the water-resistant compressive strength or the water-resistant bending strength (hereinafter, In some cases, it is described as a "hydrophobic monomer" as an essential component, and the content thereof is required to be 30% by weight or more, preferably 40% by weight or more, and more preferably 50% by weight based on the entire polymerization component [I]. More than %, particularly preferably 70% by weight or more. Further, the upper limit is usually 100% by weight or less. If the content of the hydrophobic monomer is too small, the water-resistant compressive strength or the water-resistant bending strength of the mortar is lowered, which is not preferable. Specific examples of the hydrophobic monomer having a solubility of water of 0.1% or less with respect to 20 ° C are as follows. Examples of the acrylic monomer include n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, and 2-ethylhexyl (meth)acrylate. The number of carbon atoms of the alkyl group such as cyclohexyl (meth)acrylate, lauryl (meth)acrylate, octyl (meth)acrylate or stearyl (meth)acrylate is 4 or more, preferably 6 to 18 ( Methyl) acrylate, in particular, an aromatic (meth) acrylate such as an aliphatic (meth) acrylate or a phenoxy acrylate, or a trifluoroethyl methacrylate. Examples of the styrene monomer include styrene and α-methylstyrene. Examples of the vinyl monomer include vinyl laurate, vinyl stearate, and tetradecene carbonate. Among the above hydrophobic monomers, an aliphatic (meth) acrylate monomer having a carbon number of 4 or more and a styrene monomer are preferably used, and styrene or (methyl) is particularly preferably used. ) n-butyl acrylate, 2-ethylhexyl (meth) acrylate. These hydrophobic monomers may be used alone or in combination of two or more. In the present invention, in particular, styrene is preferably contained as a hydrophobic monomer, and the content ratio of styrene to the entire hydrophobic monomer is 80% by weight or less, particularly preferably 70% by weight or less, and further preferably. It is 60% by weight or less. On the other hand, the lower limit of the styrene content is particularly preferably 30% by weight or more, and further preferably 40% by weight or more. When the styrene content ratio is more than 80% by weight, there is a problem in that deterioration or discoloration of the polymer due to ultraviolet rays is caused, and weather resistance is lowered. On the other hand, when the styrene content ratio is 30% by weight, it is preferable from the viewpoint of further excellent water resistance. The polyvinyl alcohol-based resin (hereinafter, referred to as [PVA (polyvinyl alcohol) resin] used in the present invention) is used for the purpose of imparting dispersion stability to a pre-emulsion during polymerization, and imparting The obtained aqueous synthetic resin emulsion is stable, and the re-emulsifiable synthetic resin powder obtained by spray-drying the emulsion is easily redispersed in water. The average saponification degree of the PVA-based resin is preferably 70 mol% or more, particularly preferably 80 mol% or more, and further preferably 85 mol% or more. On the other hand, the upper limit of the average degree of saponification is preferably 99.9 mol%, particularly preferably 99.5 mol%, and further preferably 99.0 mol%. When the average degree of saponification is too low, it is difficult to carry out the polymerization stably, and even if the polymerization is completed, the storage stability of the emulsion tends to be lowered. If the average degree of saponification is too high, the re-emulsifiable synthetic resin powder becomes difficult to be re-emulsified. tendency. Further, the average degree of saponification can be determined by a method for calculating the degree of saponification described in JIS K 6726. Moreover, the average degree of polymerization of the PVA-based resin is preferably 50 or more, particularly preferably 100 or more, and further preferably 200 or more. On the other hand, the upper limit of the average degree of polymerization is preferably 3,000, particularly preferably 2,000, and still more preferably 1,000. When the average degree of polymerization is too low, the protective colloidal ability at the time of emulsion polymerization is insufficient, and the polymerization tends to be difficult to proceed stably; if it is too high, the viscosity is increased during polymerization, and the reaction system becomes unstable, and The tendency to reduce dispersion stability. Further, the average degree of polymerization can be determined by a method for calculating the average degree of polymerization described in JIS K 6726. In the present invention, as the PVA-based resin, PVA or a modified PVA-based resin modified with various modified species can be used, and the amount of modification is usually 20 mol% or less, preferably 15 mol%. Hereinafter, it is more preferably 10 mol% or less. Further, the lower limit value is 0.01 mol%. Examples of the modified PVA-based resin include an anion-modified PVA-based resin modified with an anionic group including a carboxyl group, a sulfonic acid group, and a phosphoric acid group, and a cationic group such as a quaternary ammonium group. a modified PVA-based resin obtained by modifying a cationically modified PVA-based resin with various functional groups such as an ethyl acetonate, a diacetone acrylamide group, a mercapto group or a stanol group, or A PVA-based resin having a 1,2-glycol bond on the branch. In the present invention, the amount of the PVA-based resin to be used is preferably 20 parts by weight or less, more preferably 10 parts by weight or less, and still more preferably 7 parts by weight or less based on 100 parts by weight of the polymerization component [I]. . On the other hand, the upper limit of the amount of use of the PVA-based resin is preferably 0.01 part by weight, particularly preferably 0.1 part by weight, and still more preferably 0.5 part by weight. When the amount of the PVA-based resin used is too small, the emulsifying power at the time of emulsion polymerization is insufficient, the dispersion stability of the polymer component is lowered, and the polymerization stability tends to be lowered. When the amount used is too large, the viscosity of the synthetic resin emulsion is present. Increased, the tendency to reduce stability. Further, in the present invention, the PVA-based resin is usually made into an aqueous solution using an aqueous medium, and is used in the process of emulsion polymerization. The aqueous medium may, for example, be water or an alcoholic solvent mainly composed of water, and is preferably water. The content ratio (solid content) of the PVA-based resin in the aqueous solution is preferably from 5 to 30% by weight from the viewpoint of easiness of handling. As a method of emulsion polymerization, it is necessary to carry out emulsion polymerization by continuously adding the total amount of the polymerization component [I] to an aqueous medium in the presence of a PVA resin, for example, an aqueous medium or a PVA resin can be added to the reaction tank. The temperature was raised, and the total amount of the polymerization component [I] was continuously dropped thereto to be polymerized. The aqueous medium may, for example, be water or an alcoholic solvent mainly composed of water, and is preferably water. Further, in the present invention, a pre-emulsion is prepared by previously emulsifying and dispersing a total amount of the polymerization component [I] in an aqueous medium in the presence of a PVA-based resin, and preferably, the pre-emulsion is continuously added to an aqueous medium. The total amount is emulsified and polymerized on one side. The method of adjusting the pre-emulsion is, for example, a method in which the polymerization component [I] is added dropwise while stirring the aqueous solution of the PVA-based resin. As the stirring device at this time, a known mixing machine such as a stirring mixing by a stirring blade or a static mixer, a rocking mixer, or a homogenizer can be used, but among them, stirring and mixing by a stirring blade are preferable. In the present invention, it is necessary to carry out emulsion polymerization by continuously adding the total amount of the polymerization component [I] (or the above pre-emulsion) to the aqueous medium. Here, the continuous addition of the total amount is carried out, and the emulsion polymerization means that the initial polymerization is not carried out, and the total amount is continuously added to carry out emulsion polymerization, and the method is the same as the prior method, that is, by subjecting a specific amount to initial polymerization. Thereafter, the emulsification method differs from the method of emulsifying and polymerizing the remaining components. As a method of adding the above-mentioned continuous method, for example, a method of dropping a polymerization component [I] into an aqueous medium using a dropping funnel or a rotary pump can be mentioned. The dropping rate is generally carried out under the conditions of continuous dropping, and may be appropriately adjusted in consideration of the reactivity of the polymerization component to be used, the amount of the polymerization initiator to be used, the reaction temperature, and the like. Specifically, for example, the dropping interval is usually set to be within 10 seconds, preferably within 5 seconds, and the amount of dropwise addition is usually 2% by weight or less, preferably 1% by weight based on the total amount of the monomers. The following can be. Furthermore, the above-mentioned dropping interval and the amount of dropping in one time may be uniform or uneven. Further, it is preferred to set a ripening period for a fixed period of time after the total amount of the polymerization component [I] is added dropwise. The emulsion polymerization conditions can be appropriately selected depending on the type of the polymerization component, the polymerization scale, and the like. However, the temperature conditions at the time of the reaction are usually 40 ° C or higher, and particularly preferably 60 ° C or higher. The upper limit of the temperature condition at the time of the reaction is usually 90 ° C, and particularly preferably 80 ° C. Moreover, it is preferable to stir at the time of emulsion-polymerization, and the stirring apparatus at this time can use the same as the above-mentioned adjustment of the pre-emulsion, and it is preferable to carry out stirring-mixing by stirring-wing. Further, it is generally preferred to use a polymerization initiator in the emulsion polymerization, and a polymerization regulator, a co-emulsifier, a plasticizer or the like may be used as needed. The above-mentioned polymerization initiator may be used for ordinary emulsion polymerization, and examples thereof include inorganic peroxides such as potassium persulfate, sodium persulfate and ammonium persulfate; organic peroxides and azo initiators; a peroxide such as hydrogen peroxide or butyl peroxide; and a redox polymerization initiator which is combined with a reducing agent such as sodium sulfite or L-ascorbic acid. These may be used in combination of two or more types. In the present invention, it is preferred to use an inorganic peroxide, and particularly preferably ammonium persulfate or potassium persulfate, from the viewpoint of not adversely affecting the physical properties or the strength of the film and facilitating the polymerization. The method of adding the polymerization initiator can be carried out in a batch addition method or the like in a batch addition method, or a method of adding it to the reaction tank in multiple portions. The method of the method, or the method of continuously dropping together with the polymerization component, and the like. The amount of the polymerization initiator to be used varies depending on the type of the polymerization component to be used, the polymerization conditions, and the like, but is usually 0.01 parts by weight or more, preferably 0.5 parts by weight, per 100 parts by weight of the polymerization component [I]. the above. Further, the upper limit of the amount used is usually 5 parts by weight, preferably 3 parts by weight. The above polymerization regulator can be appropriately selected from those skilled in the art. As such a polymerization regulator, a chain transfer agent, a buffer, etc. are mentioned, for example. Examples of the chain transfer agent include alcohols such as methanol, ethanol, propanol, and butanol; aldehydes such as acetaldehyde, propionaldehyde, n-butyraldehyde, furfural, and benzaldehyde; and dodecyl mercaptan and lauryl mercaptan. A mercaptan such as a thiol, a thioglycolic acid, an octyl thioglycolate or a thioglycerol. These may be used alone or in combination of two or more. Examples of the buffering agent include sodium acetate, ammonium acetate, sodium diphosphate, and sodium citrate. These may be used alone or in combination of two or more. The auxiliary emulsifier is usually used for the emulsion polymerization, and examples thereof include an anionic, cationic, and nonionic surfactant, and a water-soluble polymer having a protective colloidal energy other than the PVA resin. And water-soluble oligomers and the like. Examples of the surfactant include non-ionic surfactants such as sodium lauryl sulfate and sodium dodecylbenzenesulfonate, and those having a Pluronic structure or a polyoxyethylene structure. Surfactant. Further, as the surfactant, a reactive surfactant having a radical polymerizable unsaturated bond in the structure can also be used. These may be used alone or in combination of two or more. The use of the above surfactant has an effect of allowing the emulsion polymerization to proceed smoothly and easily controlling (the effect as an emulsifier) or suppressing the generation of coarse particles or chunks generated during the polymerization. However, when such a surfactant is used in a large amount as an emulsifier, the graft ratio tends to decrease. Therefore, in the case of using a surfactant, the amount thereof is preferably an auxiliary amount with respect to the PVA-based resin, that is, as much as possible. Examples of the water-soluble polymer having a protective colloidal energy other than the PVA-based resin include hydroxyethyl cellulose, polyvinylpyrrolidone, and methyl cellulose. These may be used alone or in combination of two or more. These have the effect of changing the stability of the emulsion or the particle size of the emulsion, thereby changing the viscosity. However, depending on the amount of use, there is a case where the water resistance of the film is lowered, so that it is preferably used in a small amount when used. As the water-soluble oligomer, for example, a polymer having a hydrophilic group such as a sulfonic acid group, a carboxyl group, a hydroxyl group or an alkylene glycol group is preferable, and among them, a polymerization having a polymerization degree of about 10 to 500 is preferably exemplified. Or a copolymer. Specific examples of the water-soluble oligomer include a guanamine copolymer such as 2-methacrylamide-2-methylpropanesulfonic acid copolymer, and sodium methacrylate-4-styrenesulfonate. Copolymer, styrene/maleic acid copolymer, melamine sulfonic acid formaldehyde condensate, poly(meth) acrylate, and the like. Further, as a specific example, a monomer having a sulfonic acid group, a carboxyl group, a hydroxyl group, an alkylene glycol group, or the like, or a radically polymerizable reactive emulsifier, may be used alone or copolymerized with another monomer. Water soluble oligomers and the like. These may be used alone or in combination of two or more. As the plasticizer, an adipic acid plasticizer, a phthalic acid plasticizer, a phosphoric acid plasticizer, or the like can be used. In the production method of the present invention, an aqueous synthetic resin emulsion can be produced by continuously adding a polymerization component [I] to an aqueous medium in the presence of a PVA resin. The obtained aqueous synthetic resin emulsion is obtained by dispersing and stabilizing synthetic resin particles in an aqueous medium using a PVA-based resin. In the present invention, the aqueous synthetic resin emulsion obtained by emulsion polymerization is typically uniform milky white, and the average particle diameter of the synthetic resin particles in the aqueous synthetic resin emulsion is preferably 0.2 μm or more, and particularly preferably 0.3 μm or more. Further, the upper limit of the average particle diameter is preferably 2 μm, and particularly preferably 1.5 μm. When the average particle diameter of the synthetic resin particles is too large, the polymerization stability tends to be lowered, and if it is too small, the viscosity of the aqueous synthetic resin emulsion tends to be too high. In addition, the average particle diameter can be measured by a conventional method, for example, by a laser analysis/scattering type particle size distribution measuring apparatus [LA-950S2] (manufactured by HORIBA Co., Ltd.). Further, the glass transition temperature (Tg) of the synthetic resin particles in the aqueous synthetic resin emulsion obtained by the production method of the present invention is preferably -40 ° C or higher, particularly preferably -30 ° C or higher, and further preferably -20 Above °C. Further, the upper limit of the glass transition temperature (Tg) is preferably 30 ° C, particularly preferably 20 ° C, and further preferably 10 ° C. When the glass transition temperature is too high, the effect of the resin as an adhesive may not be sufficiently exhibited at a low temperature, and if it is too low, the compressive strength or the bending strength tends to decrease. The glass transition temperature is calculated by the formula of Fox shown in the following Math. [Math 1] Further, the glass transition temperature at the time of producing a homopolymer of a monomer constituting the synthetic resin is usually measured by a differential scanning calorimeter (DSC). The viscosity of the aqueous synthetic resin emulsion obtained by the production method of the present invention at 23 ° C is preferably 100 mPa·s or more, particularly preferably 300 mPa·s or more, and more preferably 500 mPa·s or more. On the other hand, the upper limit of the viscosity is preferably 5,000 mPa·s, particularly preferably 3,000 mPa·s, and further preferably 2,000 mPa·s. When the viscosity is too high or too low, the aqueous synthetic resin emulsion tends to be difficult to be powdered. Further, the method of measuring the viscosity is carried out using a B-type viscometer. Moreover, the solid content of the aqueous synthetic resin emulsion obtained by the production method of the present invention is preferably 30% by weight or more, particularly preferably 35% by weight or more, and still more preferably 40% by weight or more. On the other hand, the upper limit of the solid content concentration is preferably 60% by weight, particularly preferably 55% by weight, and still more preferably 50% by weight. When the concentration of the solid content component is too low, the production efficiency when the aqueous synthetic resin emulsion is powdered tends to be lowered, and if it is too high, the aqueous synthetic resin emulsion tends to be difficult to be powdered. In the present invention, the aqueous synthetic resin emulsion after the emulsion polymerization may further be added with various additives as needed. As such an additive, an organic pigment, an inorganic pigment, a water-soluble additive, a pH adjuster, a preservative, an antioxidant, etc. are mentioned, for example. As described above, when the aqueous synthetic resin emulsion obtained by the production method of the present invention is used as it is, it is usually preferred to adjust the solid content concentration to 40 to 60% by weight. [Method for Producing Re-Emulsifying Synthetic Resin Powder] The re-emulsifiable synthetic resin powder of the present invention can be obtained by drying the aqueous synthetic resin emulsion obtained by the above production method. The re-emulsifiable synthetic resin powder has a function of re-emulsification by mixing with water, and can be effectively used, for example, as a polymer cement. Examples of the drying method of the aqueous synthetic resin emulsion include spray drying, freeze drying, and warm air drying after aggregation. Among these, spray drying is preferred from the viewpoint of production cost, energy saving viewpoint, or continuous productivity. In the case of spray drying, the spray form can be carried out using, for example, a disc type, a nozzle type or the like. Examples of the heat source for spray drying include hot air, heated water vapor, and the like. The conditions for the spray drying can be appropriately selected depending on the size and type of the spray dryer, the nonvolatile component of the synthetic resin emulsion, the viscosity, the flow rate, and the like. The temperature of the spray drying is usually preferably 80 ° C or higher, more preferably 120 ° C or higher. Further, the upper limit of the spray drying temperature is preferably 180 ° C, more preferably 160 ° C. When the drying temperature is too low, drying takes time and the production efficiency tends to decrease. If the drying temperature is too high, the deterioration of the resin itself due to heat tends to occur. Specifically, for example, the aqueous synthetic resin emulsion is continuously supplied by a nozzle of a spray dryer, and the mist is dried and powdered by warm air. In some cases, the adjusted spray liquid can be heated in advance at the time of spraying, and can be continuously supplied by a nozzle, and the mist can be dried and powdered by warm air. By heating, the drying speed becomes faster, and as the viscosity of the spray liquid is lowered, the non-volatile content of the spray liquid can be increased, which also contributes to lowering the production cost. Further, in order to further improve the re-emulsifiability of the re-emulsifiable synthetic resin powder in water, a water-soluble additive can be formulated. Usually, the water-soluble additive is formulated into an aqueous synthetic resin emulsion before drying. The blending amount is 2 to 50 parts by weight based on 100 parts by weight of the nonvolatile component of the aqueous synthetic resin emulsion before drying. If the amount is too small, the re-emulsifiability in water may not be sufficiently improved. If the amount is too large, the re-emulsifiability in water may be significantly improved, but the water resistance of the film may be lowered. The tendency to look forward to the materiality of expectation. Examples of the water-soluble additive include PVA-based resins, hydroxyethylcelluloses, methylcelluloses, polyvinylpyrrolidone, starches, dextrins, water-soluble alkyd resins, and water-soluble amines. A water-soluble resin such as a base resin, a water-soluble acrylic resin, a water-soluble polycarboxylic acid resin, or a water-soluble polyamide resin. These may be used alone or in combination of two or more. Among these, PVA resin is preferable. As the PVA-based resin, the same as the above PVA-based resin may be used, and a partially or completely saponified product of the unmodified PVA or a partially or completely saponified product of various modified PVA may be used, or these may be used in combination. The PVA-based resin is preferably a PVA having an average degree of saponification of 85 mol% or more, and particularly preferably a PVA of 87 mol% or more. Further, the upper limit of the average degree of saponification is preferably 99.5 mol%, more preferably 95 mol%. When the average degree of saponification is too small, the water resistance of the obtained polymer cement slurry tends to be remarkably lowered, and if it is too large, the re-emulsifiability in water tends to decrease. Further, the average degree of polymerization is preferably 50 or more, more preferably 200 or more, still more preferably 300 or more. Further, the upper limit of the average degree of polymerization is preferably 3,000, more preferably 2,000, still more preferably 600. When the average degree of polymerization is too small, the water resistance tends to decrease, and if it is too large, the re-emulsifiability tends to decrease. Thus, the re-emulsifiable synthetic resin powder of the present invention is obtained. Further, the re-emulsifiable synthetic resin powder of the present invention may further contain an anti-adhesive agent, a water reducing agent, a dispersing agent, a mortar fluidization accelerator, a water repellent, an antioxidant, a rust preventive agent, and the like. Further, the anti-adhesive agent may be contained by mixing it in an aqueous synthetic resin emulsion, or by mixing it in a spray-dried resin emulsion powder, or by spraying with an aqueous synthetic resin emulsion from another nozzle during spray drying. [Aqueous synthetic resin emulsion obtained by re-emulsification] The above-described re-emulsifiable synthetic resin powder can be re-emulsified by adding the above aqueous medium to obtain an aqueous synthetic resin emulsion. The aqueous synthetic resin emulsion obtained by the re-emulsification can exhibit the same effect as the aqueous synthetic resin emulsion before the re-emulsifiable synthetic resin powder. [Polymer cement composition, polymer cement slurry] The re-emulsifiable synthetic resin powder thus obtained can be used as a polymer cement composition in combination with cement, and can be used as a mortar by blending water or sand or gravel. Or use concrete. Further, when water is blended in the polymer cement composition, the re-emulsifiable synthetic resin powder is re-emulsified to regenerate the aqueous synthetic resin emulsion. Examples of the cement include ordinary Portland cement, alumina cement, early strength Portland cement, super early strong Portland cement, medium heat Portland cement, low heat Portland cement, and sulfate resistant waves. Portland cement, blast furnace cement, fly ash cement, vermiculite cement, etc., among which Portland cement is preferred from the viewpoint of workability. The amount of the cement is preferably 3 parts by weight or more, and more preferably 30 parts by weight or more based on 100 parts by weight of the re-emulsifiable synthetic resin powder. Further, the upper limit of the amount of the above-mentioned cement is preferably 500 parts by weight, and more preferably 350 parts by weight. The amount of water used as the mortar or concrete is preferably 50% by weight or less, and more preferably 30% by weight or less based on the total amount of the polymer cement composition. Further, the amount of the sand and the gravel to be used as the mortar or concrete is preferably 30% by weight or more, and more preferably 50% by weight or more based on the total amount of the polymer cement composition. The upper limit of the amount of the sand and gravel is preferably 300 parts by weight, and more preferably 150 parts by weight. Further, in the above polymer cement composition, a cement water reducing agent or a plasticizer (for example, lignin, naphthalene, melamine, carboxylic acid, etc.) and a shrinkage reducing agent (for example, a glycol ether system) may be used as needed. , polyether, etc.), cold resistant agents (such as calcium chloride, etc.), water repellents (such as stearic acid, etc.), rust inhibitors (such as phosphates, etc.), viscosity modifiers (such as methyl cellulose, hydroxyethyl) Cellulose, polyvinyl alcohol, etc., dispersant (for example, polycarboxylic acid type, inorganic phosphorus type, etc.), antifoaming agent (for example, lanthanum series, mineral oil type, etc.), preservative, reinforcing agent (for example, steel fiber, glass fiber) , synthetic fibers, carbon fibers, etc.) may be used alone or in combination of two or more. In the case of preparing a polymer cement slurry using a polymer cement composition, it can be prepared by adding an essential component and an optional component, adding an appropriate amount of water thereto, and then kneading using a kneading machine or the like, in the same manner as a general mortar. The polymer cement slurry is usually used in the test of JIS R 5201 in accordance with the procedure of JIS A 6203, and the flow rate is changed to 170 ± 5 mm. When the re-emulsifiable synthetic resin powder obtained by the production method of the present invention is used, it can be prepared into a desired stream by blending a small amount of water as compared with the re-emulsifiable synthetic resin powder obtained by the prior production method. Further, the value can be adjusted to a desired flow value without adding an additive such as a water reducing agent. Therefore, the re-emulsifiable synthetic resin powder obtained by the production method of the present invention is excellent in coatability. Further, in general, if the amount of water to be blended is too large, the curing rate is lowered, or the strength of the obtained cured product is lowered, which is not preferable. When the polymer cement composition obtained in this manner is mixed into a cement slurry, it exhibits good fluidity and workability, and is excellent in adhesion to an old mortar surface or a resin-coated surface. Further, it has an excellent effect of less variation in physical properties and subsequent strength improvement. Moreover, the polymer cement composition is used as a cement slurry mixture, and is used as a maintenance mortar, a substrate adjustment coating, a self-leveling material, a tile followed by a mortar, a mortar sealing material, a primer, a mortar curing agent, and a gypsum system. It is useful as a modifier for materials and the like, and is also useful for materials for civil engineering and building materials, glass fiber astringents, and flame retardants. [Examples] Hereinafter, the present invention will be specifically described by way of examples, but the present invention is not limited to the following examples as long as the scope of the invention is not exceeded. In the examples, "parts" and "%" refer to the weight basis. <Experimental Example 1> [Preparation of pre-emulsion] 5 parts of polyvinyl alcohol (Gosenol GL-03 manufactured by Nippon Synthetic Chemical Co., Ltd.) and 49 parts of water were added to the flask, and after fully dissolving at 80 ° C for 1 hour, After cooling to room temperature, 46 parts of styrene and 54 parts of butyl acrylate were added, and stirring was continued for 30 minutes using a turbine blade to emulsify, thereby preparing a pre-emulsion. [Production of Aqueous Synthetic Resin Emulsion] To a separable flask equipped with a paddle type stirring blade, a reflux condenser, a dropping funnel, and a thermometer, 52 parts of water and 1 part of sodium acetate were added, and the inside of the flask was stirred while stirring at 150 rpm. The temperature was raised to 80 °C. Next, 3 parts of a 10% aqueous solution of ammonium persulfate was added to the flask, and then 154 parts of the pre-emulsion prepared above and 4.6 parts of a 10% aqueous solution of ammonium persulfate were added dropwise over 5 hours using a dropping funnel to carry out a polymerization reaction. Next, the mixture was aged at 80 ° C for 2 hours, during which time 3.5 parts of an ammonium persulfate 10% aqueous solution was added three times to complete the reaction, and cooled to room temperature to obtain a nonvolatile content of 48.7% and a viscosity of 2,940 mPa.s (Brookfield A water-based synthetic resin emulsion of a viscous meter BM12 rpm, 23 ° C). [Production of Re-Emulsifying Synthetic Resin Powder] After adding 20 parts of a 20% aqueous solution of polyvinyl alcohol (Gosenol GL-05, manufactured by Nippon Synthetic Chemical Co., Ltd.) to 100 parts by weight of the obtained aqueous synthetic resin emulsion, In the presence of 14 parts of a binder (trade name INCOMP SE-SUPER, Paltentaler Minerals GmbH & Co KG), the spray was sprayed while being sprayed in a 140 ° C atmosphere to obtain a resin powder (re-emulsifiable synthetic resin powder). <Comparative Example 1> [Preparation of pre-emulsion] A pre-emulsion was prepared in the same manner as in Example 1. [Production of a water-based synthetic resin emulsion] To a separable flask equipped with a slurry type stirring blade, a reflux condenser, a dropping funnel, and a thermometer, 52 parts of water and 1 part of sodium acetate were added, and the flask was stirred at 150 rpm. The temperature was raised to 80 °C. Next, 3 parts of a 10% aqueous solution of ammonium persulfate was added to the flask, and 15.4 parts of the pre-emulsion prepared above (10% of the total amount of the polymerization monomers) was further added thereto, and the initial polymerization was carried out for 60 minutes, followed by a dropping funnel. 138.6 parts of the pre-emulsion and 4.6 parts of a 10% aqueous solution of ammonium persulfate were added dropwise over 5 hours to carry out a polymerization reaction. Next, it was aged at 80 ° C for 2 hours, during which 3.5 parts of ammonium persulfate 10% aqueous solution was added three times to complete the reaction, and cooled to room temperature to obtain a nonvolatile content of 48.6% and a viscosity of 6,390 mPa.s (Brookfield A water-based synthetic resin emulsion of a viscous meter BM12 rpm, 23 ° C). [Production of Re-Emulsifying Synthetic Resin Powder] The obtained aqueous synthetic resin emulsion was used in the same manner as in Example 1 to obtain a resin powder (re-emulsifiable synthetic resin powder). <Comparative Example 2> [Preparation of pre-emulsion] A pre-emulsion was prepared in the same manner as in Example 1. [Production of a water-based synthetic resin emulsion] To a separable flask equipped with a slurry type stirring blade, a reflux condenser, a dropping funnel, and a thermometer, 52 parts of water and 1 part of sodium acetate were added, and the flask was stirred while stirring at 150 rpm. The temperature was raised to 80 °C. Next, 3 parts of a 10% aqueous solution of ammonium persulfate was added to the flask, and 3.1 parts of the pre-emulsion prepared above (2% of the total amount of the polymerization monomers) was added at a time, and the initial polymerization was carried out for 60 minutes, followed by a dropping funnel. 150.9 parts of the pre-emulsion and 4.6 parts of a 10% aqueous solution of ammonium persulfate were added dropwise over 5 hours to carry out a polymerization reaction. Next, the mixture was aged at 80 ° C for 2 hours, during which time 3.5 parts of an ammonium persulfate 10% aqueous solution was added three times to complete the reaction, and cooled to room temperature to obtain a nonvolatile content of 49.1% and a viscosity of 34,600 mPa.s (Brookfield A water-based synthetic resin emulsion of a viscous meter BM12 rpm, 23 ° C). [Production of Re-Emulsifying Synthetic Resin Powder] Although the obtained aqueous synthetic resin emulsion was used, the re-emulsifiable synthetic resin powder was produced in the same manner as in Example 1, but the viscosity was high, and the sprayer spray could not be performed. <Comparative Example 3> [Preparation of pre-emulsion] A pre-emulsion was prepared in the same manner as in Example 1. [Production of a water-based synthetic resin emulsion] To a separable flask equipped with a slurry type stirring blade, a reflux condenser, a dropping funnel, and a thermometer, 52 parts of water and 1 part of sodium acetate were added, and the flask was stirred while stirring at 150 rpm. The temperature was raised to 80 °C. Next, 3 parts of a 10% aqueous solution of ammonium persulfate was added to the flask, and 7.7 parts of the pre-emulsion prepared above (5% of the total amount of the polymerization monomers) was added at a time, and initial polymerization was carried out for 30 minutes, followed by a dropping funnel. 146.3 parts of the pre-emulsion and 4.6 parts of a 10% aqueous solution of ammonium persulfate were added dropwise over 5 hours to carry out a polymerization reaction. Next, the mixture was aged at 80 ° C for 2 hours, during which time 3.5 parts of an ammonium persulfate 10% aqueous solution was added three times to complete the reaction, and cooled to room temperature to obtain a nonvolatile content of 49.1% and a viscosity of 26,200 mPa.s (Brookfield A water-based synthetic resin emulsion of a viscous meter BM12 rpm, 23 ° C). [Production of Re-Emulsifying Synthetic Resin Powder] Although the obtained aqueous synthetic resin emulsion was used, the re-emulsifiable synthetic resin powder was produced in the same manner as in Example 1, but the viscosity was high, and the sprayer spray could not be performed. <Comparative Example 4> [Preparation of pre-emulsion] A pre-emulsion was prepared in the same manner as in Example 1. [Production of a water-based synthetic resin emulsion] To a separable flask equipped with a slurry type stirring blade, a reflux condenser, a dropping funnel, and a thermometer, 52 parts of water and 1 part of sodium acetate were added, and the flask was stirred while stirring at 150 rpm. The temperature was raised to 80 °C. Next, 3 parts of a 10% aqueous solution of ammonium persulfate was added to the flask, and 15.4 parts of the pre-emulsion prepared above (10% of the total amount of the polymerization monomers) was further added thereto, and initial polymerization was carried out for 10 minutes, followed by a dropping funnel. 138.6 parts of the pre-emulsion and 4.6 parts of a 10% aqueous solution of ammonium persulfate were added dropwise over 5 hours, but the reaction became unstable in the middle, and a good polymerization reaction could not be performed, and the aqueous synthetic resin emulsion could not be obtained. The re-emulsifiability and the fluidity of the polymer cement slurry were evaluated by the following methods using the re-emulsifiable synthetic resin powder obtained in the above Example 1 and Comparative Example 1. <Re-Emulsifying Property of Resin Powder> 100 parts of the re-emulsifiable aqueous synthetic resin emulsion powder was added to 100 parts of deionized water while stirring, and then stirred at 1000 rpm for 10 minutes to re-emulsifie. The viscosity of the re-emulsified emulsion at a Brookfield-type viscometer BM12 rpm and 23 ° C was measured. The evaluation criteria are as follows. The results are shown in Table 2. (Evaluation criteria) ○・・・The viscosity of the emulsion solution after re-emulsification is less than 3,000 mPa·s △・・・The viscosity of the emulsion solution after re-emulsification is 3,000 mPa·s or more and less than 5,000 mPa·s ×・・The viscosity of the emulsion solution after re-emulsification is 5,000 mPa·s or more <The fluidity of the polymer cement slurry> According to JIS A6203, the re-emulsifiable synthetic resin powder is mixed with various components as shown in Table 1 below, and water is added until polymerization. The cement slurry meets the specified flow value: 170±5 mm, and a polymer cement slurry is produced. The flow values of the polymer cement slurry in each water addition amount are shown in Table 1. [Table 1] The polymer cement slurry obtained by adding water until the flow value specified in JIS A6203 was obtained, and water/cement (%) was determined and evaluated based on the following criteria. The results are shown in Table 2. (Evaluation criteria) ○・・・Water/cement is less than 80% ×・・・Water/cement is 80% or more [Table 2] As shown in Table 2, it is understood that the synthetic resin emulsion of Example 1 obtained by the production method of the present invention has a low viscosity, and the emulsified synthetic resin powder obtained by drying is excellent in re-emulsifiability, and the cement is used. The fluidity of the pulp is good. On the other hand, the synthetic resin emulsion of Comparative Example 1 obtained by the production method different from the polymerization method of the present invention has a high viscosity, and the emulsified synthetic resin powder obtained by drying it is re-emulsified. The viscosity is also high and the re-emulsifiability is poor. Moreover, it is understood from the results of Tables 1 and 2 that the polymer cement slurry obtained by drying the synthetic resin emulsion obtained by the production method of Comparative Example 1 is the same as in Example 1. The amount of water added does not conform to the flow value specified in JIS A 6203, and is adjusted in such a manner as to conform to the prescribed flow value, more water must be added, and the resin emulsion obtained by the production method of Example 1 is dried. Compared with the obtained re-emulsifiable synthetic resin powder, it was found to be inferior in fluidity. If the amount of water added to the polymer cement slurry is large, the curing speed of the polymer cement is lowered, and the strength of the obtained cured product is lowered, so that the practicability is poor. In addition, since the viscosity of the synthetic resin emulsion obtained by the production methods of Comparative Examples 2 and 3 was high, the re-emulsifiable synthetic resin powder could not be obtained, and in the production method of Comparative Example 4, the polymerization stability was poor, and synthesis could not be obtained. Resin emulsion. [Industrial Applicability] According to the method for producing an aqueous synthetic resin emulsion of the present invention, an aqueous synthetic resin emulsion having a high solid content concentration and a low viscosity can be obtained, and therefore, the operation after re-emulsification can be obtained with good production efficiency. The emulsion powder having excellent properties, the re-emulsifiable synthetic resin powder obtained by the method for producing a re-emulsifiable synthetic resin powder of the present invention, and the aqueous synthetic resin emulsion obtained by re-emulsification thereof are used as a cement slurry mixture, and are displayed. Good fluidity and workability. It is very useful as a cement slurry for use as a modifier for maintenance of mortars, base-adjusting coatings, self-leveling materials, ceramic tile, mortar, and gypsum-based materials.