TW201641963A - Corona method - Google Patents
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- TW201641963A TW201641963A TW104116057A TW104116057A TW201641963A TW 201641963 A TW201641963 A TW 201641963A TW 104116057 A TW104116057 A TW 104116057A TW 104116057 A TW104116057 A TW 104116057A TW 201641963 A TW201641963 A TW 201641963A
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Abstract
Description
本發明是有關於一種電暈方法,且特別是有關於一種偏光板的電暈方法。 This invention relates to a corona method, and more particularly to a corona method for a polarizing plate.
在偏光板與顯示面板的貼合製程中,通常是透過黏膠黏合偏光板與顯示面板。然而,隨著材料應用的創新,許多既有的黏膠已無法緊密地黏合偏光板與顯示面板,導致偏光板與顯示面板之間的密著性(Key force)下降。因此,亟需提出一種新的技術去增加偏光板與顯示面板之間的密著性。 In the bonding process of the polarizing plate and the display panel, the polarizing plate and the display panel are usually bonded through the adhesive. However, with the innovation of material applications, many existing adhesives have been unable to closely bond the polarizing plate and the display panel, resulting in a decrease in the key force between the polarizing plate and the display panel. Therefore, it is urgent to propose a new technique to increase the adhesion between the polarizing plate and the display panel.
因此,本發明提出一種偏光板的電暈方法,可增加偏光板與顯示面板之間的密著性。 Therefore, the present invention proposes a corona method of a polarizing plate, which can increase the adhesion between the polarizing plate and the display panel.
根據本發明之一實施例,提出一種偏光板的電暈方法。電暈方法包括以下步驟。對一偏光板執行一第一電暈處理;以及,對偏光板執行一第二電暈處理。第一電暈處理的電暈功率及第二電暈處理的電暈功率介於800瓦至1200瓦之間。 According to an embodiment of the present invention, a corona method of a polarizing plate is proposed. The corona method includes the following steps. Performing a first corona treatment on a polarizing plate; and performing a second corona treatment on the polarizing plate. The corona power of the first corona treatment and the corona power of the second corona treatment are between 800 watts and 1200 watts.
為了對本發明之上述及其他方面有更佳的瞭解,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下: In order to better understand the above and other aspects of the present invention, the preferred embodiments are described below, and in conjunction with the drawings, the detailed description is as follows:
10‧‧‧偏光板 10‧‧‧Polar plate
11‧‧‧第一保護層 11‧‧‧First protective layer
11s‧‧‧表面 11s‧‧‧ surface
12‧‧‧第二保護層 12‧‧‧Second protective layer
13‧‧‧光學層 13‧‧‧Optical layer
100‧‧‧電暈設備 100‧‧‧Corona equipment
110‧‧‧第一電暈滾輪 110‧‧‧First corona roller
120‧‧‧第二電暈滾輪 120‧‧‧Second corona roller
130‧‧‧傳輸滾輪 130‧‧‧Transport roller
140‧‧‧第一電暈器 140‧‧‧First Corona
150‧‧‧第二電暈器 150‧‧‧Second Corona
S110至S130‧‧‧步驟 S110 to S130‧‧‧ steps
第1圖繪示依照本發明一實施例之電暈方法流程圖。 FIG. 1 is a flow chart of a corona method according to an embodiment of the invention.
第2圖繪示依照本發明一實施例之電暈設備的示意圖。 2 is a schematic view of a corona device in accordance with an embodiment of the present invention.
第1圖繪示依照本發明一實施例之電暈方法流程圖。 FIG. 1 is a flow chart of a corona method according to an embodiment of the invention.
於步驟S110中,提供電暈設備100。請同時參考第2圖,其繪示依照本發明一實施例之電暈設備100的示意圖。電暈設備100包括第一電暈滾輪110、第二電暈滾輪120、數個傳輸滾輪130、第一電暈器140及第二電暈器150。偏光板10可由第一電暈滾輪110、第二電暈滾輪120及數個傳輸滾輪130傳輸,以進行電暈製程。 In step S110, a corona device 100 is provided. Please also refer to FIG. 2, which shows a schematic diagram of a corona device 100 in accordance with an embodiment of the present invention. The corona device 100 includes a first corona roller 110, a second corona roller 120, a plurality of transport rollers 130, a first corona 140, and a second corona 150. The polarizing plate 10 can be transported by the first corona roller 110, the second corona roller 120, and the plurality of transport rollers 130 to perform a corona process.
如第2圖的放大圖所示,偏光板10包括第一保護層11、第二保護層12及光學層13,其中光學層13位於第一保護層11與第二保護層12之間。 As shown in the enlarged view of FIG. 2, the polarizing plate 10 includes a first protective layer 11, a second protective layer 12, and an optical layer 13, wherein the optical layer 13 is located between the first protective layer 11 and the second protective layer 12.
光學層13是指對光學之增益、配向、補償、轉向、直交、擴散、保護、防黏、耐刮、抗眩、反射抑制、高折射率等有所助益的層,可例如為具有控制視角補償或雙折射(birefraction)等特性的配向液晶層、易接合處理層、硬塗層、抗反射層、防黏層、擴散層、防眩層等各種表面處理層。 The optical layer 13 refers to a layer that contributes to optical gain, alignment, compensation, steering, orthogonal, diffusion, protection, anti-sticking, scratch resistance, anti-glare, reflection suppression, high refractive index, etc., and can be controlled, for example. Various surface treatment layers such as alignment liquid crystal layer, easy-bonding treatment layer, hard coat layer, anti-reflection layer, anti-adhesion layer, diffusion layer, and anti-glare layer, such as viewing angle compensation or birefracting.
第一保護層11及/或第二保護層12的材料例如是三乙醯纖維素等纖維素樹脂、聚酯樹脂、聚醚碸樹脂、聚碸樹脂、聚碳酸酯樹脂、聚醯胺樹脂、聚醯亞胺樹脂、聚烯烴樹脂、(甲基)丙烯酸系樹脂、環 狀聚烯烴樹脂(降烯系樹脂)、聚芳酯樹脂、聚苯乙烯樹脂、聚乙烯醇樹脂、聚對苯二甲酸乙二酯(PET)層或其組合。在一實施例中,上述第一保護層11及/或第二保護層12也可為多層組合。 The material of the first protective layer 11 and/or the second protective layer 12 is, for example, a cellulose resin such as triacetyl cellulose, a polyester resin, a polyether oxime resin, a polyfluorene resin, a polycarbonate resin, a polyamide resin, Polyimine resin, polyolefin resin, (meth)acrylic resin, ring Polyolefin resin (decene-based resin), polyarylate resin, polystyrene resin, polyvinyl alcohol resin, polyethylene terephthalate (PET) layer or a combination thereof. In an embodiment, the first protective layer 11 and/or the second protective layer 12 may also be a combination of multiple layers.
在一實施例中,也可形成一黏膠層(圖未示)以及一表面保護層(圖未示)於第一保護層11及/或第二保護層12之上。在一實施例中,黏膠層可例如在丙烯酸系聚合物中調配丙烯酸寡聚物與矽烷偶合劑而形成,或在丙烯酸系聚合物中添加光聚合起始劑,並經照射紫外線而形成。 In an embodiment, an adhesive layer (not shown) and a surface protective layer (not shown) may be formed on the first protective layer 11 and/or the second protective layer 12. In one embodiment, the adhesive layer may be formed, for example, by dissolving an acrylic oligomer and a decane coupling agent in an acrylic polymer, or by adding a photopolymerization initiator to the acrylic polymer and irradiating with ultraviolet rays.
在一實施例中,表面保護層可例如為聚乙烯、聚丙烯、聚對苯二甲酸乙二酯等合成樹脂薄膜,或橡膠片、紙、布、不織布、網狀物、發泡片、金屬箔等層積體。 In an embodiment, the surface protective layer may be, for example, a synthetic resin film such as polyethylene, polypropylene, polyethylene terephthalate, or a rubber sheet, paper, cloth, non-woven fabric, mesh, foamed sheet, metal. A laminate such as foil.
於步驟S120中,如第2圖所示,偏光板10經過第一電暈器140時,第一電暈器140對偏光板10的第一保護層11的表面11s進行第一次的電暈處理。第2圖中,第一電暈器140正對著被第一電暈滾輪110捲繞的偏光板10(如第2圖的放大區域2’所示)進行第一次的電暈處理,然其它實施例中,亦可對著呈平直狀的偏光板10(尚未被第一電暈滾輪110捲繞或已脫離第一電暈滾輪110的捲繞)進行第一次的電暈處理。 In step S120, as shown in FIG. 2, when the polarizing plate 10 passes through the first corona 140, the first corona 140 performs the first corona on the surface 11s of the first protective layer 11 of the polarizing plate 10. deal with. In Fig. 2, the first corona 140 is facing the polarizing plate 10 wound by the first corona roller 110 (as shown in the enlarged area 2' of Fig. 2) for the first corona treatment, In other embodiments, the first corona treatment may be performed against the flat polarizing plate 10 (the winding that has not been wound by the first corona roller 110 or has been detached from the first corona roller 110).
經過電暈處理後,表面11s的材料會發生化學變化(例如,表面11s氧化而產生具有反應性的官能基),此化學變化有助於增加於偏光板10與顯示面板(未繪示)在後續貼合製程中黏膠(未繪示)與偏光板10的密著性。本步驟中,第一次的電暈處理的功率例如是介於800瓦(Watt)至1200 瓦之間。實際上的功率可視第一保護層11的材料而定,本發明實施例不加以限制。本實施例中,第一電暈器140包括二個子電暈器,然本發明實施例不限制第一電暈器140的形式,另一實施例之第一電暈器140可只有一個電暈器。 After corona treatment, the material of the surface 11s undergoes chemical changes (for example, the surface is oxidized to produce a reactive functional group), and this chemical change is added to the polarizing plate 10 and the display panel (not shown). Adhesion of the adhesive (not shown) to the polarizing plate 10 in the subsequent bonding process. In this step, the power of the first corona treatment is, for example, between 800 watts (Watt) and 1200. Between the tiles. The actual power may be determined by the material of the first protective layer 11, and is not limited by the embodiment of the present invention. In this embodiment, the first corona 140 includes two sub-coronas. However, the embodiment of the present invention does not limit the form of the first corona 140. The first corona 140 of another embodiment may have only one corona. Device.
於步驟S130中,如第2圖所示,偏光板10經過第二電暈器150時,第二電暈器150對偏光板10的第一保護層11的同一表面11s進行第二次的電暈處理。第二電暈器150可正對被第二電暈滾輪120捲繞的偏光板10(如第2圖的放大區域2”所示)進行第二次的電暈處理;另一實施例中,亦可對著呈平直狀的偏光板10(尚未被第二電暈滾輪120捲繞或已脫離第二電暈滾輪120的捲繞)進行第二次的電暈處理。 In step S130, as shown in FIG. 2, when the polarizing plate 10 passes through the second corona 150, the second corona 150 performs the second electric power on the same surface 11s of the first protective layer 11 of the polarizing plate 10. Halo treatment. The second corona 150 can perform a second corona treatment on the polarizing plate 10 (shown as the enlarged area 2 of FIG. 2) wound by the second corona roller 120; in another embodiment, A second corona treatment may also be performed against the flat polarizing plate 10 (which has not been wound by the second corona roller 120 or has been detached from the second corona roller 120).
經過電暈處理後,表面11s的材料會發生化學變化,此化學變化有助於增加於偏光板10與顯示面板(未繪示)在後續貼合製程中黏膠(未繪示)與偏光板10的密著性。第二次的電暈處理的功率可介於800瓦至1200瓦之間。本實施例中,第二電暈器150包括二個子電暈器,然本發明實施例不限制第二電暈器150的形式,另一實施例之第二電暈器150可只有一個電暈器。 After the corona treatment, the material of the surface 11s will undergo a chemical change, which may be added to the polarizing plate 10 and the display panel (not shown) in the subsequent bonding process (not shown) and the polarizing plate. 10 closeness. The power of the second corona treatment can be between 800 watts and 1200 watts. In this embodiment, the second corona 150 includes two sub-coronas. However, the embodiment of the present invention does not limit the form of the second corona 150. In another embodiment, the second corona 150 can have only one corona. Device.
在一實施例中,第一次電暈及/或第二次的電暈的各別放電量可介於20W/m2/min至55W/m2/min之間,其中m指的是電暈設備幅寬(公尺),m/nin指的是前進速度(公尺/分鐘),而W指的是瓦特。在一實施例中,第一次電暈及/或第二次電暈的各別放電量可相同或相異。在一實施例中,第一次電暈及第二次電暈的累積放電量可介於40W/m2/min至110W/m2/min。 In an embodiment, the respective discharge amount of the first corona and/or the second corona may be between 20 W/m 2 /min and 55 W/m 2 /min, wherein m refers to electricity The halo device width (meters), m/nin refers to the forward speed (meters per minute), and W refers to the watts. In one embodiment, the respective amounts of discharge of the first corona and/or the second corona may be the same or different. In an embodiment, the cumulative discharge of the first corona and the second corona may range from 40 W/m 2 /min to 110 W/m 2 /min.
相較於一次的電暈處理,由於本發明實施例之偏光板10係經過二次電暈處理,因此可增加表面11s與黏膠的密著性。另一實施例中,偏光板10可受到二次以上的電暈處理,只要可增加表面11s與黏膠的密著性即可,本發明實施例不限制偏光板10受到電暈處理的次數。 Compared with the one-time corona treatment, since the polarizing plate 10 of the embodiment of the present invention is subjected to secondary corona treatment, the adhesion of the surface 11s to the adhesive can be increased. In another embodiment, the polarizing plate 10 can be subjected to two or more corona treatments, as long as the adhesion of the surface 11s to the adhesive can be increased, and the embodiment of the present invention does not limit the number of times the polarizing plate 10 is subjected to the corona treatment.
此外,當偏光板10受到過高功率的電暈處理時,其表面會產生影響光學品質的粒子,如草酸根粒子(然不同保護層材料可能析出不同粒子)。相較於一次較高功率的電暈處理,由於本發明實施例之偏光板10係受到二次較低功率的電暈處理,因此不致產生過多的粒子。進一步地說,以表面11s達到相同的電暈效果而言,一次的電暈處理需要更高的功率,如1800瓦或以上,如此高的功率會導致表面11s析出過多的粒子。反觀本發明實施例,偏光板10受到二次較低功率的電暈處理,因此可減少或甚至避免粒子析出,進而避免偏光板10與顯示面板的密著性及/或光學品質降低。 In addition, when the polarizing plate 10 is subjected to a high-power corona treatment, particles having an influence on optical quality such as oxalate particles may be generated on the surface (other protective layer materials may precipitate different particles). Compared to the one-time higher power corona treatment, since the polarizing plate 10 of the embodiment of the present invention is subjected to the second lower power corona treatment, excessive particles are not generated. Further, in the case where the surface 11s achieves the same corona effect, the primary corona treatment requires higher power, such as 1800 watts or more, and such high power causes the surface 11s to precipitate excessive particles. In contrast, in the embodiment of the present invention, the polarizing plate 10 is subjected to a second lower power corona treatment, thereby reducing or even avoiding particle precipitation, thereby preventing the adhesion of the polarizing plate 10 and the display panel and/or the optical quality from being lowered.
在一實施例中,第一次電暈處理的功率與第二次電暈處理的功率可大致上相等或相異。就功率相異而言,第一次電暈處理的功率與第二次電暈處理的功率的比值可介於例如是0.1至3之間。此外,由於電暈處理後的表面11s溫度會升高,為避免負面地影響下一次電暈處理的品質,二次電暈處理之間的行程(如偏光板10的傳輸長度)可介於5公尺至15公尺之間,然實際行程可視電暈功率、保護層材料及/或黏膠種類而定,本發明實施例不加以限制。在一實施例中,第一電暈滾輪110與第二電暈滾輪120係相鄰,即第一電暈滾輪110與第二電暈滾輪120之間無其它電暈滾輪。 In an embodiment, the power of the first corona treatment may be substantially equal or different from the power of the second corona treatment. In terms of power difference, the ratio of the power of the first corona treatment to the power of the second corona treatment may be, for example, between 0.1 and 3. In addition, since the temperature of the surface 11s after the corona treatment is increased, in order to avoid adversely affecting the quality of the next corona treatment, the stroke between the secondary corona treatments (such as the transmission length of the polarizing plate 10) may be between 5. The embodiment of the present invention is not limited, and the actual stroke may be determined by the corona power, the protective layer material, and/or the type of the adhesive. In one embodiment, the first corona roller 110 is adjacent to the second corona roller 120, that is, there is no other corona roller between the first corona roller 110 and the second corona roller 120.
此外,另一實施例中,在稍加修改電暈設備100後, 二次電暈處理可由同一個電暈器(如第一電暈器140或第二電暈器150)完成,在此設計下,可省略第一電暈器140或第二電暈器150。 Moreover, in another embodiment, after slightly modifying the corona device 100, The secondary corona treatment may be performed by the same corona device (such as the first corona 140 or the second corona 150), and in this design, the first corona 140 or the second corona 150 may be omitted.
請參照下列表一,第1至5組係依照本發明實施例之實施二次電暈處理的實驗組別,而第6至9組實施一次電暈處理的實驗組別。 Referring to Table 1 below, Groups 1 to 5 are experimental groups that perform secondary corona treatment according to an embodiment of the present invention, and Groups 6 to 9 perform a corona treatment experimental group.
以第3組舉例說明,第一次電暈處理使用35W/m2/min,其中m指的是電暈設備幅寬(公尺),m/min指的是前進速度(公尺/分鐘),而W指的是瓦特。第二次電暈處理同樣使用35W/m2/min。由對應的測試結果可知,無論是異物析出或密著性皆符合預期(以”OK”表示)。第1、2及4至5組由於都採用二次電暈處理,因此具有相似的效果,容此不再贅述。 Taking the example of Group 3 as an example, the first corona treatment uses 35 W/m 2 /min, where m refers to the width of the corona device (meter) and m/min refers to the forward speed (meters per minute). And W refers to Watt. The second corona treatment also used 35 W/m 2 /min. It can be seen from the corresponding test results that both foreign matter precipitation and adhesion are in line with expectations (indicated by "OK"). Groups 1, 2, and 4 to 5 have similar effects because they are subjected to secondary corona treatment, and will not be described again.
以第6及7組舉例來說,由於電暈功率不足(只有27 W/m2/min),因此密著性未通過(以”NG”表示)。以第8及9組舉例來說,由於單次的電暈功率過高,雖然密著性通過,但卻有異物析出的問題。 In the case of Groups 6 and 7, for example, since the corona power is insufficient (only 27 W/m 2 /min), the adhesion is not passed (indicated by "NG"). In the eighth and ninth groups, for example, since the single corona power is too high, although the adhesion is passed, there is a problem that foreign matter is precipitated.
總歸,由於本發明實施例的電暈方法係採用二次較低功率的電暈處理,因此可減少或甚至避免異物析出,可增加偏光板10與黏膠之間的密著性。 In summary, since the corona method of the embodiment of the present invention adopts a second lower power corona treatment, the foreign matter precipitation can be reduced or even prevented, and the adhesion between the polarizing plate 10 and the adhesive can be increased.
綜上所述,雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 In conclusion, the present invention has been disclosed in the above preferred embodiments, and is not intended to limit the present invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
S110至S130‧‧‧步驟 S110 to S130‧‧‧ steps
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TW104116057A TWI618953B (en) | 2015-05-20 | 2015-05-20 | Corona method |
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TWI702426B (en) * | 2018-11-20 | 2020-08-21 | 住華科技股份有限公司 | Manufacturing methods of polarizer and display device comprising the same |
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JP2008122502A (en) * | 2006-11-09 | 2008-05-29 | Sumitomo Chemical Co Ltd | Method of manufacturing polarizing plate |
JP5986831B2 (en) * | 2012-07-11 | 2016-09-06 | 大倉工業株式会社 | Film conveying method and optical film manufacturing method |
JP6066707B2 (en) * | 2012-12-13 | 2017-01-25 | 日東電工株式会社 | Manufacturing method of polarizing film |
WO2015008741A1 (en) * | 2013-07-17 | 2015-01-22 | コニカミノルタ株式会社 | Polarizing plate and liquid crystal display device |
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TWI702426B (en) * | 2018-11-20 | 2020-08-21 | 住華科技股份有限公司 | Manufacturing methods of polarizer and display device comprising the same |
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