TW201630225A - Resistive random access memory and method for manufacturing the same - Google Patents

Resistive random access memory and method for manufacturing the same Download PDF

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TW201630225A
TW201630225A TW104103712A TW104103712A TW201630225A TW 201630225 A TW201630225 A TW 201630225A TW 104103712 A TW104103712 A TW 104103712A TW 104103712 A TW104103712 A TW 104103712A TW 201630225 A TW201630225 A TW 201630225A
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layer
random access
access memory
conductive type
resistive random
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TWI572074B (en
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陳啟明
林勝結
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力晶科技股份有限公司
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Abstract

A resistive random access memory (RRAM) including a resistive random access memory cell string. The resistive random access memory cell string includes a substrate, a first conductive type conductor layer and a plurality of stacked structures. The first conductive type conductor layer is disposed on the substrate. The stacked structures are separately disposed on the first conductive type conductor layer. Each of the stacked structures includes a second conductive type deposition layer, a RRAM cell and a first conductive line. The second conductive type deposition layer is disposed on the first conductive type conductor layer. The RRAM cell is disposed on the second conductive type deposition layer. The first conductive line is disposed on the RRAM cell.

Description

電阻式隨機存取記憶體及其製造方法 Resistive random access memory and manufacturing method thereof

本發明是有關於一種記憶體及其製造方法,且特別是有關於一種電阻式隨機存取記憶體及其製造方法。 The present invention relates to a memory and a method of fabricating the same, and more particularly to a resistive random access memory and a method of fabricating the same.

由於,非揮發性記憶體具有資料在斷電後也不會消失的優點,因此許多電器產品中必須具備此類記憶體,以維持電器產品開機時的正常操作。目前,業界積極發展的一種非揮發性記憶體元件是電阻式隨機存取記憶體(resistive random access memory,RRAM),其具有寫入操作電壓低、寫入抹除時間短、記憶時間長、非破壞性讀取、多狀態記憶、結構簡單以及所需面積小等優點,因此在未來將可成為個人電腦和電子設備所廣泛採用的非揮發性記憶體元件之一。 Since non-volatile memory has the advantage that the data will not disappear after power-off, many such electrical products must have such memory to maintain the normal operation of the electrical product when it is turned on. At present, a non-volatile memory component actively developed in the industry is a resistive random access memory (RRAM), which has a low write operation voltage, a short write erase time, a long memory time, and a non-volatile memory. Destructive reading, multi-state memory, simple structure and small required area make it one of the non-volatile memory components widely used in personal computers and electronic devices in the future.

然而,目前的電阻式隨機存取記憶體在操作時存在會產生漏電流(sneak current)的問題,進而造成記憶體元件的可靠度降低。 However, current resistive random access memories have a problem of sneak current during operation, which in turn causes a decrease in reliability of the memory device.

本發明提供一種電阻式隨機存取記憶體及其製造方法,其可有效地提升記憶體元件的可靠度。 The invention provides a resistive random access memory and a manufacturing method thereof, which can effectively improve the reliability of a memory component.

本發明提出一種電阻式隨機存取記憶體,包括電阻式隨機存取記憶胞串。電阻式隨機存取記憶胞串包括基底、第一導電型導體層與多個堆疊結構。第一導電型導體層設置於基底上。堆疊結構分離設置於第一導電型導體層上。各個堆疊結構包括第二導電型沉積層、電阻式隨機存取記憶胞與第一導線。第二導電型沉積層設置於第一導電型導體層上。電阻式隨機存取記憶胞設置於第二導電型沉積層上。第一導線設置於電阻式隨機存取記憶胞上。 The invention provides a resistive random access memory comprising a resistive random access memory cell string. The resistive random access memory cell string includes a substrate, a first conductive type conductor layer, and a plurality of stacked structures. The first conductive type conductor layer is disposed on the substrate. The stacked structure is separately disposed on the first conductive type conductor layer. Each of the stacked structures includes a second conductive type deposition layer, a resistive random access memory cell, and a first wire. The second conductive type deposition layer is disposed on the first conductive type conductor layer. The resistive random access memory cell is disposed on the second conductive type deposition layer. The first wire is disposed on the resistive random access memory cell.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,各個電阻式隨機存取記憶胞包括可變電阻層。可變電阻層設置於第二導電型沉積層上。 According to an embodiment of the invention, in the resistive random access memory, each of the resistive random access memory cells includes a variable resistance layer. The variable resistance layer is disposed on the second conductive type deposition layer.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,各個電阻式隨機存取記憶胞更包括第一電極層與第二電極層。第一電極層設置於可變電阻層與第二導電型沉積層之間。第二電極層設置於可變電阻層與第一導線之間。 According to an embodiment of the present invention, in the resistive random access memory, each of the resistive random access memory cells further includes a first electrode layer and a second electrode layer. The first electrode layer is disposed between the variable resistance layer and the second conductive type deposition layer. The second electrode layer is disposed between the variable resistance layer and the first wire.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,電阻式隨機存取記憶胞串更包括二個第二導電型摻雜區,設置於電阻式隨機存取記憶胞串兩末端的第一導電型導體層中。 According to an embodiment of the present invention, in the resistive random access memory, the resistive random access memory cell string further includes two second conductive type doped regions, which are disposed in the resistive random access memory. The first conductive type conductor layer at both ends of the cell string.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,電阻式隨機存取記憶胞串更包括第二導線。第二導線設置於堆疊結構上,且與堆疊結構隔離設置。第二導線電性連接至第一導電型導體層。 According to an embodiment of the invention, in the resistive random access memory, the resistive random access memory cell string further includes a second wire. The second wire is disposed on the stacked structure and disposed apart from the stacked structure. The second wire is electrically connected to the first conductive type conductor layer.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,第二導線與第一導電型導體層例如是不在電阻式隨機存取記憶胞串中最末端的相鄰兩個堆疊結構之間進行連接。 According to an embodiment of the present invention, in the resistive random access memory, the second conductive line and the first conductive type conductor layer are, for example, not adjacent to the last end of the resistive random access memory cell string. Connect between the stacked structures.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體中,位於第二導電型沉積層之間的第一導電型導體層的上表面例如是低於第二導電型沉積層的下表面。 According to an embodiment of the present invention, in the resistive random access memory, the upper surface of the first conductive type conductor layer located between the second conductive type deposition layers is, for example, lower than the second conductive type sink. The lower surface of the laminate.

本發明提出一種電阻式隨機存取記憶體的製造方法,包括形成電阻式隨機存取記憶胞串。電阻式隨機存取記憶胞串的形成方法包括下列步驟。於基底上形成第一導電型導體層。於第一導電型導體層上分離形成多個堆疊結構。各個堆疊結構包括第二導電型沉積層、電阻式隨機存取記憶胞與第一導線。第二導電型沉積層設置於第一導電型導體層上。電阻式隨機存取記憶胞設置於第二導電型沉積層上。第一導線設置於電阻式隨機存取記憶胞上。 The invention provides a method for manufacturing a resistive random access memory, comprising forming a resistive random access memory cell string. The method of forming a resistive random access memory cell string includes the following steps. A first conductive type conductor layer is formed on the substrate. A plurality of stacked structures are separated on the first conductive type conductor layer. Each of the stacked structures includes a second conductive type deposition layer, a resistive random access memory cell, and a first wire. The second conductive type deposition layer is disposed on the first conductive type conductor layer. The resistive random access memory cell is disposed on the second conductive type deposition layer. The first wire is disposed on the resistive random access memory cell.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,第一導電型導體層的形成方法包括對基底進行離子植入製程而形成或藉由臨場摻雜的沉積法所形成。 According to an embodiment of the present invention, in the method of fabricating a resistive random access memory, the method of forming the first conductive type conductor layer includes forming an ion implantation process on the substrate or by performing field doping. The deposition method is formed.

依照本發明的一實施例所述,在上述之電阻式隨機存取 記憶體的製造方法中,堆疊結構的形成方法包括下列步驟。於第一導電型導體層上沉積第二導電型沉積材料層。於第二導電型沉積材料層上形成電阻式隨機存取記憶胞層。於電阻式隨機存取記憶胞層上形成第一導線材料層。對第一導線材料層、電阻式隨機存取記憶胞層與第二導電型沉積材料層進行圖案化製程。 According to an embodiment of the invention, in the above resistive random access In the method of manufacturing a memory, the method of forming the stacked structure includes the following steps. A second conductive type deposition material layer is deposited on the first conductive type conductor layer. A resistive random access memory cell layer is formed on the second conductive type deposition material layer. Forming a first layer of conductive material on the resistive random access memory cell layer. The first conductive material layer, the resistive random access memory cell layer and the second conductive type deposition material layer are patterned.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,第二導電型沉積材料層的沉積方法包括藉由臨場摻雜的沉積法直接形成或藉由以下方法所形成。於第一導電型導體層上沉積未摻雜半導體層。於未摻雜半導體層上沉積第二導電型摻雜半導體層。將第二導電型摻雜半導體層中的多個第二導電型摻質擴散到未摻雜半導體層中。 According to an embodiment of the invention, in the method for fabricating a resistive random access memory, the method for depositing a second conductive type deposition material layer comprises directly forming by a field doping deposition method or by the following The method is formed. An undoped semiconductor layer is deposited on the first conductive type conductor layer. A second conductive type doped semiconductor layer is deposited on the undoped semiconductor layer. A plurality of second conductivity type dopants in the second conductivity type doped semiconductor layer are diffused into the undoped semiconductor layer.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,電阻式隨機存取記憶胞層的形成方法包括下列步驟。於第二導電型沉積材料層上形成第一電極材料層。於第一電極材料層上形成可變電阻材料層。於可變電阻材料層上形成第二電極材料層。 According to an embodiment of the invention, in the method for fabricating a resistive random access memory, the method for forming a resistive random access memory cell layer includes the following steps. A first electrode material layer is formed on the second conductive type deposition material layer. A layer of variable resistance material is formed on the first electrode material layer. A second electrode material layer is formed on the variable resistance material layer.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,更包括於電阻式隨機存取記憶胞串兩末端的第一導電型導體層中形成二個第二導電型摻雜區。 According to an embodiment of the invention, in the method for manufacturing a resistive random access memory, the method further includes forming two in the first conductive type conductor layer at both ends of the resistive random access memory cell string. Two conductivity type doped regions.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,更包括於堆疊結構上形成電性連接至第一導電型導體層的第二導線。第二導線與堆疊結構隔離設置。 According to an embodiment of the invention, in the method of manufacturing a resistive random access memory, the method further includes forming a second wire electrically connected to the first conductive type conductor layer on the stacked structure. The second wire is disposed apart from the stacked structure.

依照本發明的一實施例所述,在上述之電阻式隨機存取記憶體的製造方法中,第二導線與第一導電型導體層例如是不在電阻式隨機存取記憶胞串中最末端的相鄰兩個堆疊結構之間進行連接。 According to an embodiment of the invention, in the manufacturing method of the resistive random access memory, the second conductive line and the first conductive type conductor layer are not at the end of the resistive random access memory cell string, for example. A connection is made between two adjacent stacked structures.

基於上述,在本發明所提出的電阻式隨機存取記憶體及其製造方法中,由於第二導電型沉積層是使用沉積的方式形成,所以在製造過程中可使得相鄰的堆疊結構中的第二導電型沉積層完全分離,以避免產生電性干擾,進而有效地提升記憶體元件的可靠度。此外,第二導電型沉積層與第一導電型導體層可形成二極體,所以能夠抑制記憶體元件的漏電流,進而防止誤動作產生,因此可有效地提升記憶體元件的可靠度。 Based on the above, in the resistive random access memory and the manufacturing method thereof according to the present invention, since the second conductive type deposition layer is formed by deposition, the adjacent stacked structure can be made in the manufacturing process. The second conductive type deposition layer is completely separated to avoid electrical interference, thereby effectively improving the reliability of the memory element. Further, since the second conductive type deposition layer and the first conductive type conductor layer can form a diode, leakage current of the memory element can be suppressed, and malfunction can be prevented, so that the reliability of the memory element can be effectively improved.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。 The above described features and advantages of the invention will be apparent from the following description.

10‧‧‧電阻式隨機存取記憶體 10‧‧‧Resistive random access memory

100‧‧‧基底 100‧‧‧Base

102‧‧‧第二導電型井區 102‧‧‧Second Conductive Well Area

104‧‧‧第一導電型導體層 104‧‧‧First Conductive Conductor Layer

106‧‧‧第二導電型沉積材料層 106‧‧‧Second conductive deposition material layer

106a‧‧‧第二導電型沉積層 106a‧‧‧Second conductive deposit

108、112‧‧‧電極材料層 108, 112‧‧‧ electrode material layer

108a、112a‧‧‧電極層 108a, 112a‧‧‧electrode layer

110‧‧‧可變電阻材料層 110‧‧‧Variable resistance material layer

110a‧‧‧可變電阻層 110a‧‧‧variable resistance layer

113‧‧‧硬罩幕層 113‧‧‧hard mask layer

113a‧‧‧圖案化硬罩幕層 113a‧‧‧ patterned hard mask layer

114‧‧‧電阻式隨機存取記憶胞層 114‧‧‧Resistive random access memory cell layer

114a‧‧‧電阻式隨機存取記憶胞 114a‧‧‧Resistive random access memory cells

115、118、122‧‧‧圖案化光阻層 115, 118, 122‧‧‧ patterned photoresist layer

116‧‧‧導線材料層 116‧‧‧Wire material layer

116a‧‧‧導線 116a‧‧‧Wire

117、124‧‧‧開口 117, 124‧‧‧ openings

119‧‧‧隔離結構 119‧‧‧Isolation structure

120‧‧‧堆疊結構 120‧‧‧Stack structure

126‧‧‧第二導電型摻雜區 126‧‧‧Second conductive doped region

128‧‧‧介電層 128‧‧‧ dielectric layer

130‧‧‧接觸窗 130‧‧‧Contact window

132‧‧‧導線 132‧‧‧Wire

134‧‧‧電阻式隨機存取記憶胞串 134‧‧‧Resistive random access memory cell string

圖1為本發明一實施例的電阻式隨機存取記憶體的上視圖。 1 is a top view of a resistive random access memory according to an embodiment of the present invention.

圖2A至圖2D為沿著圖1中的I-I’剖面線的電阻式隨機存取記憶體的製造流程剖面圖。 2A to 2D are cross-sectional views showing the manufacturing process of the resistive random access memory along the line I-I' in Fig. 1.

圖3A至圖3D為沿著圖1中的II-II’剖面線的電阻式隨機存取記憶體的製造流程剖面圖。 3A to 3D are cross-sectional views showing the manufacturing flow of the resistive random access memory along the line II-II' in Fig. 1.

圖1為本發明一實施例的電阻式隨機存取記憶體的上視圖。為了清楚地進行說明,在圖1中省略介電層的繪示。圖2A至圖2D為沿著圖1中的I-I’剖面線的電阻式隨機存取記憶體的製造流程剖面圖。圖3A至圖3D為沿著圖1中的II-II’剖面線的電阻式隨機存取記憶體的製造流程剖面圖。 1 is a top view of a resistive random access memory according to an embodiment of the present invention. For the sake of clarity, the depiction of the dielectric layer is omitted in FIG. 2A to 2D are cross-sectional views showing the manufacturing process of the resistive random access memory along the line I-I' in Fig. 1. 3A to 3D are cross-sectional views showing the manufacturing flow of the resistive random access memory along the line II-II' in Fig. 1.

在此實施例中,所指的「第一導電型」與「第二導電型」為不同的導電型態。當第一導電型為N型時,第二導電型為P型。當第一導電型為P型時,第二導電型為N型。 In this embodiment, the "first conductivity type" and the "second conductivity type" referred to are different conductivity types. When the first conductivity type is an N type, the second conductivity type is a P type. When the first conductivity type is a P type, the second conductivity type is an N type.

首先,請同時參照圖1與圖2A,可選擇性地於基底100中形成第二導電型井區102。基底100例如是矽基底。第二導電型井區102例如是P型井區或N型井區。在此實施例中,第二導電型井區102是以P型井區為例進行說明。第二導電型井區102的形成方法例如是離子植入法。 First, referring to FIG. 1 and FIG. 2A simultaneously, the second conductive type well region 102 can be selectively formed in the substrate 100. The substrate 100 is, for example, a crucible substrate. The second conductive well region 102 is, for example, a P-type well region or an N-type well region. In this embodiment, the second conductive type well region 102 is described by taking a P-type well region as an example. The method of forming the second conductive type well region 102 is, for example, an ion implantation method.

接著,於基底100上形成第一導電型導體層104。第一導電型導體層104可用以作為埋入式位元線。第一導電型導體層104例如是N型導體層或P型導體層。在此實施例中,第一導電型導體層104是以N型導體層為例進行說明。第一導電型導體層104的形成方法可藉由對基底100進行離子植入製程而形成。此外,第一導電型導體層104亦可藉由臨場摻雜的沉積法所形成,如臨場摻雜的化學氣相沉積法。藉由臨場摻雜的沉積法所形成的第一導電型導體層104的材料例如是摻雜半導體,如摻雜多晶矽。 Next, a first conductive type conductor layer 104 is formed on the substrate 100. The first conductive type conductor layer 104 can be used as a buried bit line. The first conductive type conductor layer 104 is, for example, an N-type conductor layer or a P-type conductor layer. In this embodiment, the first conductive type conductor layer 104 is described by taking an N-type conductor layer as an example. The method of forming the first conductive type conductor layer 104 can be formed by performing an ion implantation process on the substrate 100. In addition, the first conductive type conductor layer 104 can also be formed by a deposition method of field doping, such as a field doped chemical vapor deposition method. The material of the first conductive type conductor layer 104 formed by the deposition method of the field doping is, for example, a doped semiconductor such as doped polysilicon.

然後,請同時參照圖1與圖2B,於第一導電型導體層104上沉積第二導電型沉積材料層106。第二導電型沉積材料層106例如是P型沉積材料層或N型沉積材料層。在此實施例中,第二導電型沉積材料層106是以P型沉積材料層為例進行說明。第二導電型沉積材料層106的沉積方法可藉由臨場摻雜的沉積法直接形成,如臨場摻雜的化學氣相沉積法。第二導電型沉積材料層106的材料例如是摻雜半導體,如摻雜多晶矽。 Then, referring to FIG. 1 and FIG. 2B, a second conductive type deposition material layer 106 is deposited on the first conductive type conductor layer 104. The second conductive type deposition material layer 106 is, for example, a P-type deposition material layer or an N-type deposition material layer. In this embodiment, the second conductive type deposition material layer 106 is exemplified by a P-type deposition material layer. The deposition method of the second conductive type deposition material layer 106 can be directly formed by a deposition method of on-site doping, such as a field-doped chemical vapor deposition method. The material of the second conductive type deposition material layer 106 is, for example, a doped semiconductor such as doped polysilicon.

此外,第二導電型沉積材料層106亦可藉由以下方法所形成。於第一導電型導體層104上沉積未摻雜半導體層(未繪示)。於未摻雜半導體層上沉積第二導電型摻雜半導體層(未繪示)。將第二導電型摻雜半導體層中的第二導電型摻質擴散到未摻雜半導體層中,使得未摻雜半導體層亦成為第二導電型摻雜半導體層,而藉由此兩層第二導電型摻雜半導體層形成第二導電型沉積材料層106。將第二導電型摻雜半導體層中的第二導電型摻質擴散到未摻雜半導體層中的方法例如是對第二導電型摻雜半導體層進行回火製程。 Further, the second conductive type deposition material layer 106 can also be formed by the following method. An undoped semiconductor layer (not shown) is deposited on the first conductive type conductor layer 104. A second conductive type doped semiconductor layer (not shown) is deposited on the undoped semiconductor layer. Diffusion of the second conductivity type dopant in the second conductivity type doped semiconductor layer into the undoped semiconductor layer, so that the undoped semiconductor layer also becomes the second conductivity type doped semiconductor layer, thereby The second conductive type doped semiconductor layer forms the second conductive type deposition material layer 106. The method of diffusing the second conductivity type dopant in the second conductivity type doped semiconductor layer into the undoped semiconductor layer is, for example, a tempering process of the second conductivity type doped semiconductor layer.

接下來,於第二導電型沉積材料層106上形成電極材料層108。電極材料層108的材料例如是鈦、鎳、鉭或銅等金屬材料。電極材料層108的形成方法例如是物理氣相沉積法。 Next, an electrode material layer 108 is formed on the second conductive type deposition material layer 106. The material of the electrode material layer 108 is, for example, a metal material such as titanium, nickel, ruthenium or copper. The method of forming the electrode material layer 108 is, for example, a physical vapor deposition method.

之後,於電極材料層108上形成可變電阻材料層110。可變電阻材料層110的材料例如是金屬氧化物,如氧化鉿、氧化鎂、氧化鎳、氧化鈮、氧化鈦、氧化鋁、氧化釩、氧化鎢、氧化鋅或 氧化鈷。可變電阻材料層110的形成方法例如是化學氣相沉積法。 Thereafter, a variable resistance material layer 110 is formed on the electrode material layer 108. The material of the variable resistance material layer 110 is, for example, a metal oxide such as cerium oxide, magnesium oxide, nickel oxide, cerium oxide, titanium oxide, aluminum oxide, vanadium oxide, tungsten oxide, zinc oxide or Cobalt oxide. The method of forming the variable resistance material layer 110 is, for example, a chemical vapor deposition method.

再者,於可變電阻材料層110上形成電極材料層112。電極材料層112的材料例如是鈦、鎳、鉭或銅等金屬材料。電極材料層112的形成方法例如是物理氣相沉積法。此外,由電極材料層108、可變電阻材料層110與電極材料層112形成位於第二導電型沉積材料層106上的電阻式隨機存取記憶胞層114。 Further, an electrode material layer 112 is formed on the variable resistance material layer 110. The material of the electrode material layer 112 is, for example, a metal material such as titanium, nickel, tantalum or copper. The method of forming the electrode material layer 112 is, for example, a physical vapor deposition method. Further, a resistive random access memory cell layer 114 on the second conductive type deposition material layer 106 is formed by the electrode material layer 108, the variable resistance material layer 110, and the electrode material layer 112.

隨後,可選擇性地於電極材料層112上形成硬罩幕層113。硬罩幕層113的材料例如是氮化矽或氧化矽。硬罩幕層113的形成方法例如是化學氣相沉積法。 Subsequently, a hard mask layer 113 may be selectively formed on the electrode material layer 112. The material of the hard mask layer 113 is, for example, tantalum nitride or tantalum oxide. The method of forming the hard mask layer 113 is, for example, a chemical vapor deposition method.

繼之,於硬罩幕層113上形成圖案化光阻層115。圖案化光阻層115的形成方法例如是藉由進行微影製程而形成。 Next, a patterned photoresist layer 115 is formed on the hard mask layer 113. The method of forming the patterned photoresist layer 115 is formed, for example, by performing a lithography process.

接著,請同時參照圖1與圖2C,以圖案化光阻層115為罩幕,移除部分硬罩幕層113,而形成圖案化硬罩幕層113a。部分硬罩幕層113的移除方法例如是乾式蝕刻法。 Next, referring to FIG. 1 and FIG. 2C simultaneously, the patterned photoresist layer 115 is used as a mask to remove a portion of the hard mask layer 113 to form a patterned hard mask layer 113a. The method of removing the partial hard mask layer 113 is, for example, a dry etching method.

然後,可選擇性地移除圖案化光阻層115。圖案化光阻層115的移除方法例如是乾式去光阻法。 The patterned photoresist layer 115 can then be selectively removed. The method of removing the patterned photoresist layer 115 is, for example, a dry de-resisting method.

接下來,以圖案化硬罩幕層113a為罩幕,移除部分電阻式隨機存取記憶胞層114、部分第二導電型沉積材料層106、部分第一導電型導體層104與部分第二導電型井區102,而於上述膜層中形成開口117。上述移除步驟所使用的移除方法例如是乾式蝕刻法。 Next, using the patterned hard mask layer 113a as a mask, a portion of the resistive random access memory cell layer 114, a portion of the second conductive type deposition material layer 106, a portion of the first conductive type conductor layer 104, and a portion of the second portion are removed. The conductive well region 102 forms an opening 117 in the above-mentioned film layer. The removal method used in the above removal step is, for example, a dry etching method.

之後,請同時參照圖1與圖2D,於開口117中形成隔離 結構119。隔離結構119例如是淺溝渠隔離結構(STI)。隔離結構119的材料例如是氧化矽。隔離結構119的形成方法例如是先形成填滿開口117的隔離結構材料層(未繪示),再移除開口117以外的隔離結構材料層而形成。其中,開口117以外的隔離結構材料層的移除方法例如是化學機械研磨法。 After that, please refer to FIG. 1 and FIG. 2D simultaneously to form isolation in the opening 117. Structure 119. The isolation structure 119 is, for example, a shallow trench isolation structure (STI). The material of the isolation structure 119 is, for example, ruthenium oxide. The forming method of the isolation structure 119 is formed, for example, by forming a layer of an insulating structural material (not shown) filling the opening 117 and then removing a layer of the insulating structural material other than the opening 117. The method for removing the layer of the isolation structural material other than the opening 117 is, for example, a chemical mechanical polishing method.

再者,移除圖案化硬罩幕層113a。圖案化硬罩幕層113a的移除方法例如是乾式蝕刻法。 Furthermore, the patterned hard mask layer 113a is removed. The method of removing the patterned hard mask layer 113a is, for example, a dry etching method.

隨後,請同時參照圖1與圖3A,於電阻式隨機存取記憶胞層114上形成導線材料層116。導線材料層116的材料例如是摻雜多晶矽或金屬等導體材料。電極材料層112的形成方法例如是化學氣相沉積法或物理氣相沉積法。 Subsequently, referring to FIG. 1 and FIG. 3A, a conductive material layer 116 is formed on the resistive random access memory cell layer 114. The material of the wire material layer 116 is, for example, a conductive material such as doped polysilicon or metal. The method of forming the electrode material layer 112 is, for example, a chemical vapor deposition method or a physical vapor deposition method.

繼之,請同時參照圖1與圖3B,於導線材料層116上形成圖案化光阻層118。圖案化光阻層118的形成方法例如是藉由進行微影製程而形成。 Next, please refer to FIG. 1 and FIG. 3B simultaneously to form a patterned photoresist layer 118 on the conductive material layer 116. The method of forming the patterned photoresist layer 118 is formed, for example, by performing a lithography process.

接著,以圖案化光阻層118為罩幕,移除部分導線材料層116、部分電阻式隨機存取記憶胞層114與部分第二導電型沉積材料層106,而暴露出第一導電型導體層104,並於第一導電型導體層104上形成堆疊結構120。在此實施例中,堆疊結構120例如是藉由對導線材料層116、電阻式隨機存取記憶胞層114與第二導電型沉積材料層106進行上述自對準的圖案化製程而形成。上述移除步驟所使用的移除方法例如是乾式蝕刻法。 Then, the patterned photoresist layer 118 is used as a mask to remove a portion of the conductive material layer 116, the partial resistive random access memory cell layer 114 and a portion of the second conductive type deposition material layer 106, thereby exposing the first conductive type conductor. The layer 104 and the stacked structure 120 are formed on the first conductive type conductor layer 104. In this embodiment, the stacked structure 120 is formed, for example, by performing the above self-aligned patterning process on the conductive material layer 116, the resistive random access memory cell layer 114, and the second conductive type deposition material layer 106. The removal method used in the above removal step is, for example, a dry etching method.

各個堆疊結構120包括第二導電型沉積層106a、電阻式 隨機存取記憶胞114a與導線116a。第二導電型沉積層106a設置於第一導電型導體層104上。電阻式隨機存取記憶胞114a設置於第二導電型沉積層106a上。各個電阻式隨機存取記憶胞114a包括電極層108a、可變電阻層110a、電極層112a。電極層108a設置於第二導電型沉積層106a上。可變電阻層110a設置於電極層108a上。電極層112a設置於可變電阻層110a上。導線116a設置於電阻式隨機存取記憶胞114a上,且可做為字元線使用。 Each of the stacked structures 120 includes a second conductive type deposition layer 106a, and a resistive type The memory cell 114a is randomly accessed with the wire 116a. The second conductive type deposition layer 106a is disposed on the first conductive type conductor layer 104. The resistive random access memory cell 114a is disposed on the second conductive type deposition layer 106a. Each of the resistive random access memory cells 114a includes an electrode layer 108a, a variable resistance layer 110a, and an electrode layer 112a. The electrode layer 108a is disposed on the second conductive type deposition layer 106a. The variable resistance layer 110a is provided on the electrode layer 108a. The electrode layer 112a is provided on the variable resistance layer 110a. The wire 116a is disposed on the resistive random access memory cell 114a and can be used as a word line.

在上述移除步驟中,由於第二導電型沉積材料層106是使用沉積的方式形成,所以可輕易地將位於堆疊結構120之間的第二導電型沉積材料層106移除。因此,可使得相鄰的堆疊結構120中的第二導電型沉積層106a完全分離,以避免產生電性干擾,進而提升記憶體元件的可靠度。 In the above removal step, since the second conductive type deposition material layer 106 is formed using deposition, the second conductive type deposition material layer 106 located between the stacked structures 120 can be easily removed. Therefore, the second conductive type deposition layer 106a in the adjacent stacked structure 120 can be completely separated to avoid electrical interference, thereby improving the reliability of the memory element.

為了確保完全移除位於堆疊結構120之間的第二導電型沉積材料層106,更可選擇性地移除所暴露出的部分第一導電型導體層104。如此一來,位於第二導電型沉積層106a之間的第一導電型導體層104的上表面例如是低於第二導電型沉積層106a的下表面。 In order to ensure complete removal of the second conductive type deposition material layer 106 between the stacked structures 120, the exposed portion of the first conductive type conductor layer 104 is more selectively removed. As a result, the upper surface of the first conductive type conductor layer 104 located between the second conductive type deposition layers 106a is, for example, lower than the lower surface of the second conductive type deposition layer 106a.

此外,由於第二導電型沉積層106a與第一導電型導體層104可形成二極體,所以能夠抑制記憶體元件的漏電流,進而防止誤動作產生,因此可有效地提升記憶體元件的可靠度。 In addition, since the second conductive type deposition layer 106a and the first conductive type conductor layer 104 can form a diode, leakage current of the memory element can be suppressed, thereby preventing malfunction, thereby effectively improving the reliability of the memory element. .

然後,請同時參照圖1與圖3C,移除圖案化光阻層118。圖案化光阻層118的移除方法例如是乾式去光阻法。 Then, referring to FIG. 1 and FIG. 3C simultaneously, the patterned photoresist layer 118 is removed. The method of removing the patterned photoresist layer 118 is, for example, a dry de-resist method.

接下來,形成圖案化光阻層122。圖案化光阻層122中的開口124暴露出第一導電型導體層104。圖案化光阻層122的形成方法例如是藉由進行微影製程而形成。 Next, a patterned photoresist layer 122 is formed. The opening 124 in the patterned photoresist layer 122 exposes the first conductive type conductor layer 104. The method of forming the patterned photoresist layer 122 is formed, for example, by performing a lithography process.

之後,在開口所暴露出的第一導電型導體層104中形成第二導電型摻雜區126,而在預定形成的電阻式隨機存取記憶胞串的兩末端的第一導電型導體層104中形成二個第二導電型摻雜區126。第二導電型摻雜區126例如是P型摻雜區或N型摻雜區。在此實施例中,第二導電型摻雜區126是以P型摻雜區為例進行說明。第二導電型摻雜區126的形成方法例如是離子植入法。此外,第二導電型摻雜區126與第一導電型導體層104可形成二極體,所以能夠進一步地抑制記憶體元件的漏電流,進而有效地提升記憶體元件的可靠度。 Thereafter, a second conductive type doped region 126 is formed in the first conductive type conductor layer 104 exposed by the opening, and the first conductive type conductor layer 104 at both ends of the predetermined formed resistive random access memory cell string is formed. Two second conductivity type doping regions 126 are formed in the middle. The second conductive type doped region 126 is, for example, a P-type doped region or an N-type doped region. In this embodiment, the second conductive type doped region 126 is exemplified by a P-type doped region. The method of forming the second conductive type doped region 126 is, for example, an ion implantation method. In addition, the second conductive type doping region 126 and the first conductive type conductor layer 104 can form a diode, so that the leakage current of the memory device can be further suppressed, thereby effectively improving the reliability of the memory device.

再者,請同時參照圖1與圖3D,移除圖案化光阻層122。圖案化光阻層122的移除方法例如是乾式去光阻法。 Furthermore, please refer to FIG. 1 and FIG. 3D simultaneously to remove the patterned photoresist layer 122. The method of removing the patterned photoresist layer 122 is, for example, a dry photoresist removal method.

隨後,形成覆蓋堆疊結構120的介電層128。介電層128的材料例如是氧化矽等介電材料。介電層128的形成方法例如是化學氣相沉積法。 Subsequently, a dielectric layer 128 covering the stacked structure 120 is formed. The material of the dielectric layer 128 is, for example, a dielectric material such as ruthenium oxide. The method of forming the dielectric layer 128 is, for example, a chemical vapor deposition method.

繼之,於介電層128中形成接觸窗130。接觸窗130的材料例如是銅或鎢。介電層128可組合使用微影製程、蝕刻製程與沉積製程而形成或藉由金屬鑲嵌法而形成,如單重金屬鑲嵌法。 Next, a contact window 130 is formed in the dielectric layer 128. The material of the contact window 130 is, for example, copper or tungsten. The dielectric layer 128 can be formed by using a lithography process, an etching process, and a deposition process in combination or by a damascene process, such as a single damascene process.

接著,於堆疊結構120上形成電性連接至第一導電型導體層104的導線132。導線132可藉由接觸窗130而電性連接至第 一導電型導體層104。導線132與堆疊結構120可藉由介電層128而隔離設置。導線132的材料例如是銅或鋁等金屬材料。導線132的形成方法例如是先利用物理氣相沉積法形成導線材料層(未繪示),再對導線材料層進行圖案化製程而形成。 Next, a wire 132 electrically connected to the first conductive type conductor layer 104 is formed on the stacked structure 120. The wire 132 can be electrically connected to the first through the contact window 130 A conductive type conductor layer 104. The wires 132 and the stacked structure 120 may be disposed apart by the dielectric layer 128. The material of the wire 132 is, for example, a metal material such as copper or aluminum. The method for forming the wire 132 is formed by first forming a wire material layer (not shown) by physical vapor deposition, and then patterning the wire material layer.

藉由上述製造方法已完成電阻式隨機存取記憶體10的製作。電阻式隨機存取記憶體10包括電阻式隨機存取記憶胞串134。在此實施例中,繪示出電阻式隨機存取記憶體10中的一串電阻式隨機存取記憶胞串134為例進行說明,但本發明並不以此為限。只要電阻式隨機存取記憶體10包括一串以上電阻式隨機存取記憶胞串134即屬於本發明所保護的範圍。 The fabrication of the resistive random access memory 10 has been completed by the above manufacturing method. The resistive random access memory 10 includes a resistive random access memory cell string 134. In this embodiment, a series of resistive random access memory cell strings 134 in the resistive random access memory 10 are illustrated as an example, but the invention is not limited thereto. As long as the resistive random access memory 10 includes a string or more of the resistive random access memory cell strings 134, it is within the scope of the present invention.

在此實施例中,導線132與第一導電型導體層104例如是不在電阻式隨機存取記憶胞串134中最末端的相鄰兩個堆疊結構120之間進行連接,而可具有較佳的操作效能,但本發明並不以此為限。所屬技術領域具有通常知識者可依照產品設計需求來對導線132與第一導電型導體層104的電性連接位置進行調整。 In this embodiment, the wires 132 and the first conductive type conductor layer 104 are, for example, not connected between the two adjacent stacked structures 120 at the end of the resistive random access memory cell string 134, but may have better Operational efficiency, but the invention is not limited thereto. Those skilled in the art can adjust the electrical connection position of the wire 132 and the first conductive type conductor layer 104 according to product design requirements.

以下,藉由圖3D來說明本實施例的電阻式隨機存取記憶體10的結構。 Hereinafter, the configuration of the resistive random access memory 10 of the present embodiment will be described with reference to Fig. 3D.

請參照圖3D,電阻式隨機存取記憶體10包括電阻式隨機存取記憶胞串134。電阻式隨機存取記憶胞串134包括基底100、第一導電型導體層104與多個堆疊結構120。第一導電型導體層104設置於基底100上。堆疊結構120分離設置於第一導電型導體層104上。各個堆疊結構120包括第二導電型沉積層106a、 電阻式隨機存取記憶胞114a與導線116a。第二導電型沉積層106a設置於第一導電型導體層104上。位於第二導電型沉積層106a之間的第一導電型導體層104的上表面例如是低於第二導電型沉積層106a的下表面。電阻式隨機存取記憶胞114a設置於第二導電型沉積層106a上。各個電阻式隨機存取記憶胞114a包括可變電阻層110a。可變電阻層110a設置於第二導電型沉積層106a上。各個電阻式隨機存取記憶胞114a更可包括電極層108a與電極層112a。電極層108a設置於可變電阻層110a與第二導電型沉積層106a之間。電極層112a設置於可變電阻層110a與導線116a之間。導線116a設置於電阻式隨機存取記憶胞114a上。 Referring to FIG. 3D, the resistive random access memory 10 includes a resistive random access memory cell string 134. The resistive random access memory cell string 134 includes a substrate 100, a first conductive type conductor layer 104, and a plurality of stacked structures 120. The first conductive type conductor layer 104 is disposed on the substrate 100. The stacked structure 120 is separately disposed on the first conductive type conductor layer 104. Each of the stacked structures 120 includes a second conductive type deposition layer 106a, The resistive random access memory cell 114a is connected to the wire 116a. The second conductive type deposition layer 106a is disposed on the first conductive type conductor layer 104. The upper surface of the first conductive type conductor layer 104 located between the second conductive type deposition layers 106a is, for example, lower than the lower surface of the second conductive type deposition layer 106a. The resistive random access memory cell 114a is disposed on the second conductive type deposition layer 106a. Each of the resistive random access memory cells 114a includes a variable resistance layer 110a. The variable resistance layer 110a is disposed on the second conductive type deposition layer 106a. Each of the resistive random access memory cells 114a may further include an electrode layer 108a and an electrode layer 112a. The electrode layer 108a is disposed between the variable resistance layer 110a and the second conductive type deposition layer 106a. The electrode layer 112a is disposed between the variable resistance layer 110a and the wire 116a. The wire 116a is disposed on the resistive random access memory cell 114a.

此外,電阻式隨機存取記憶胞串134更可選擇性地包括第二導電型井區102、二個第二導電型摻雜區126與導線132中的至少一者。第二導電型井區102設置於第一導電型導體層104下方的基底100中。第二導電型摻雜區126設置於電阻式隨機存取記憶胞串134兩末端的第一導電型導體層104中。導線132設置於堆疊結構120上。導線132與堆疊結構120可藉由介電層128而隔離設置。導線132可藉由接觸窗130而電性連接至第一導電型導體層104。導線132與第一導電型導體層104例如是不在電阻式隨機存取記憶胞串134中最末端的相鄰兩個堆疊結構120之間進行連接,而可具有較佳的操作效能,但本發明並不以此為限。 In addition, the resistive random access memory cell string 134 further selectively includes at least one of the second conductive type well region 102, the two second conductive type doped regions 126, and the wires 132. The second conductive type well region 102 is disposed in the substrate 100 below the first conductive type conductor layer 104. The second conductive type doping region 126 is disposed in the first conductive type conductor layer 104 at both ends of the resistive random access memory cell string 134. The wires 132 are disposed on the stacked structure 120. The wires 132 and the stacked structure 120 may be disposed apart by the dielectric layer 128. The wire 132 can be electrically connected to the first conductive type conductor layer 104 by the contact window 130. The wire 132 and the first conductive type conductor layer 104 are not connected between the two adjacent stacked structures 120 at the end of the resistive random access memory cell string 134, but may have better operational efficiency, but the present invention Not limited to this.

基於上述,在上述實施例的電阻式隨機存取記憶體及其製造方法中,由於第二導電型沉積層106a是使用沉積的方式形 成,所以在製造過程中可使得相鄰的堆疊結構120中的第二導電型沉積層106a完全分離,以避免產生電性干擾,進而有效地提升記憶體元件的可靠度。此外,第二導電型沉積層106a與第一導電型導體層104可形成二極體,所以能夠抑制記憶體元件的漏電流,進而防止誤動作產生,因此可有效地提升記憶體元件的可靠度。 Based on the above, in the resistive random access memory of the above embodiment and the method of fabricating the same, since the second conductive type deposition layer 106a is formed by deposition Therefore, the second conductive type deposition layer 106a in the adjacent stacked structure 120 can be completely separated during the manufacturing process to avoid electrical interference, thereby effectively improving the reliability of the memory element. Further, since the second conductive type deposition layer 106a and the first conductive type conductor layer 104 can form a diode, leakage current of the memory element can be suppressed, and malfunction can be prevented, so that the reliability of the memory element can be effectively improved.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.

10‧‧‧電阻式隨機存取記憶體 10‧‧‧Resistive random access memory

100‧‧‧基底 100‧‧‧Base

102‧‧‧第二導電型井區 102‧‧‧Second Conductive Well Area

104‧‧‧第一導電型導體層 104‧‧‧First Conductive Conductor Layer

106a‧‧‧第二導電型沉積層 106a‧‧‧Second conductive deposit

108a、112a‧‧‧電極層 108a, 112a‧‧‧electrode layer

110a‧‧‧可變電阻層 110a‧‧‧variable resistance layer

114a‧‧‧電阻式隨機存取記憶胞 114a‧‧‧Resistive random access memory cells

116a‧‧‧導線 116a‧‧‧Wire

120‧‧‧堆疊結構 120‧‧‧Stack structure

126‧‧‧第二導電型摻雜區 126‧‧‧Second conductive doped region

128‧‧‧介電層 128‧‧‧ dielectric layer

130‧‧‧接觸窗 130‧‧‧Contact window

132‧‧‧導線 132‧‧‧Wire

134‧‧‧電阻式隨機存取記憶胞串 134‧‧‧Resistive random access memory cell string

Claims (15)

一種電阻式隨機存取記憶體,包括一電阻式隨機存取記憶胞串,其中該電阻式隨機存取記憶胞串包括:一基底;一第一導電型導體層,設置於該基底上;以及多個堆疊結構,分離設置於該第一導電型導體層上,其中各該堆疊結構包括:一第二導電型沉積層,設置於該第一導電型導體層上;一電阻式隨機存取記憶胞,設置於該第二導電型沉積層上;以及一第一導線,設置於該電阻式隨機存取記憶胞上。 A resistive random access memory, comprising a resistive random access memory cell string, wherein the resistive random access memory cell string comprises: a substrate; a first conductive type conductor layer disposed on the substrate; a plurality of stacked structures are disposed on the first conductive type conductor layer, wherein each of the stacked structures comprises: a second conductive type deposition layer disposed on the first conductive type conductor layer; and a resistive random access memory a cell disposed on the second conductivity type deposition layer; and a first wire disposed on the resistive random access memory cell. 如申請專利範圍第1項所述的電阻式隨機存取記憶體,其中各該電阻式隨機存取記憶胞包括一可變電阻層,設置於該第二導電型沉積層上。 The resistive random access memory according to claim 1, wherein each of the resistive random access memory cells comprises a variable resistance layer disposed on the second conductive type deposition layer. 如申請專利範圍第1項所述的電阻式隨機存取記憶體,其中各該電阻式隨機存取記憶胞更包括:一第一電極層,設置於該可變電阻層與該第二導電型沉積層之間;以及一第二電極層,設置於該可變電阻層與該第一導線之間。 The resistive random access memory according to claim 1, wherein each of the resistive random access memory cells further comprises: a first electrode layer disposed on the variable resistance layer and the second conductive type Between the deposited layers; and a second electrode layer disposed between the variable resistance layer and the first conductive line. 如申請專利範圍第1項所述的電阻式隨機存取記憶體,其中該電阻式隨機存取記憶胞串更包括二第二導電型摻雜區,設置於該電阻式隨機存取記憶胞串兩末端的該第一導電型導體層中。 The resistive random access memory of claim 1, wherein the resistive random access memory cell string further comprises two second conductive type doped regions disposed on the resistive random access memory cell string. In the first conductive type conductor layer at both ends. 如申請專利範圍第1項所述的電阻式隨機存取記憶體,其中該電阻式隨機存取記憶胞串更包括一第二導線,設置於該些堆疊結構上,且與該些堆疊結構隔離設置,其中該第二導線電性連接至該第一導電型導體層。 The resistive random access memory of claim 1, wherein the resistive random access memory cell string further comprises a second wire disposed on the stacked structure and isolated from the stacked structures The device is electrically connected to the first conductive type conductor layer. 如申請專利範圍第5項所述的電阻式隨機存取記憶體,其中該第二導線與該第一導電型導體層並非在該電阻式隨機存取記憶胞串中最末端的相鄰兩個堆疊結構之間進行連接。 The resistive random access memory according to claim 5, wherein the second conductive line and the first conductive type conductor layer are not adjacent to the last two of the resistive random access memory cell strings. Connect between the stacked structures. 如申請專利範圍第1項所述的電阻式隨機存取記憶體,其中位於該些第二導電型沉積層之間的該第一導電型導體層的上表面低於該些第二導電型沉積層的下表面。 The resistive random access memory according to claim 1, wherein an upper surface of the first conductive type conductor layer between the second conductive type deposition layers is lower than the second conductive type sinks The lower surface of the laminate. 一種電阻式隨機存取記憶體的製造方法,包括形成一電阻式隨機存取記憶胞串,其中該電阻式隨機存取記憶胞串的形成方法包括:於一基底上形成一第一導電型導體層;以及於該第一導電型導體層上分離形成多個堆疊結構,其中各該堆疊結構包括:一第二導電型沉積層,設置於該第一導電型導體層上;一電阻式隨機存取記憶胞,設置於該第二導電型沉積層上;以及一第一導線,設置於該電阻式隨機存取記憶胞上。 A method of manufacturing a resistive random access memory, comprising forming a resistive random access memory cell string, wherein the resistive random access memory cell string forming method comprises: forming a first conductive type conductor on a substrate And forming a plurality of stacked structures on the first conductive type conductor layer, wherein each of the stacked structures comprises: a second conductive type deposition layer disposed on the first conductive type conductor layer; and a resistive random storage The memory cell is disposed on the second conductive type deposition layer; and a first wire is disposed on the resistive random access memory cell. 如申請專利範圍第8項所述的電阻式隨機存取記憶體的製造方法,其中該第一導電型導體層的形成方法包括對該基底進行 一離子植入製程而形成或藉由一臨場摻雜的沉積法所形成。 The method of manufacturing a resistive random access memory according to claim 8, wherein the method of forming the first conductive type conductor layer comprises performing the substrate An ion implantation process is formed or formed by a deposition method of on-site doping. 如申請專利範圍第8項所述的電阻式隨機存取記憶體的製造方法,其中該些堆疊結構的形成方法包括:於該第一導電型導體層上沉積一第二導電型沉積材料層;於該第二導電型沉積材料層上形成一電阻式隨機存取記憶胞層;於該電阻式隨機存取記憶胞層上形成一第一導線材料層;以及對該第一導線材料層、該電阻式隨機存取記憶胞層與該第二導電型沉積材料層進行一圖案化製程。 The method for fabricating a resistive random access memory according to claim 8, wherein the method for forming the stacked structure comprises: depositing a second conductive type deposition material layer on the first conductive type conductor layer; Forming a resistive random access memory cell layer on the second conductive type deposition material layer; forming a first wire material layer on the resistive random access memory cell layer; and the first wire material layer, the The resistive random access memory cell layer and the second conductive type deposition material layer are subjected to a patterning process. 如申請專利範圍第10項所述的電阻式隨機存取記憶體的製造方法,其中該第二導電型沉積材料層的沉積方法包括藉由一臨場摻雜的沉積法直接形成或藉由以下方法所形成:於該第一導電型導體層上沉積一未摻雜半導體層;於該未摻雜半導體層上沉積一第二導電型摻雜半導體層;以及將該第二導電型摻雜半導體層中的多個第二導電型摻質擴散到該未摻雜半導體層中。 The method for manufacturing a resistive random access memory according to claim 10, wherein the method for depositing the second conductive type deposition material layer comprises directly forming by a field doping deposition method or by the following method Forming: depositing an undoped semiconductor layer on the first conductive type conductor layer; depositing a second conductive type doped semiconductor layer on the undoped semiconductor layer; and doping the second conductive type doped semiconductor layer A plurality of second conductivity type dopants are diffused into the undoped semiconductor layer. 如申請專利範圍第10項所述的電阻式隨機存取記憶體的製造方法,其中該電阻式隨機存取記憶胞層的形成方法包括:於該第二導電型沉積材料層上形成一第一電極材料層;於該第一電極材料層上形成一可變電阻材料層;以及 於該可變電阻材料層上形成一第二電極材料層。 The method for manufacturing a resistive random access memory according to claim 10, wherein the method for forming the resistive random access memory cell layer comprises: forming a first layer on the second conductive type deposition material layer a layer of electrode material; forming a layer of variable resistance material on the first electrode material layer; A second electrode material layer is formed on the variable resistance material layer. 如申請專利範圍第8項所述的電阻式隨機存取記憶體的製造方法,更包括於該電阻式隨機存取記憶胞串兩末端的該第一導電型導體層中形成二第二導電型摻雜區。 The method for manufacturing a resistive random access memory according to claim 8, further comprising forming a second conductivity type in the first conductive type conductor layer at both ends of the resistive random access memory cell string. Doped area. 如申請專利範圍第8項所述的電阻式隨機存取記憶體的製造方法,更包括於該些堆疊結構上形成電性連接至該第一導電型導體層的一第二導線,其中該第二導線與該些堆疊結構隔離設置。 The method for manufacturing a resistive random access memory according to claim 8, further comprising forming a second wire electrically connected to the first conductive type conductor layer on the stacked structures, wherein the The two wires are disposed apart from the stacked structures. 如申請專利範圍第14項所述的電阻式隨機存取記憶體的製造方法,其中該第二導線與該第一導電型導體層並非在該電阻式隨機存取記憶胞串中最末端的相鄰兩個堆疊結構之間進行連接。 The method of manufacturing a resistive random access memory according to claim 14, wherein the second conductive line and the first conductive type conductor layer are not at the end of the resistive random access memory cell string. Connect between two adjacent stack structures.
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