TW201629626A - Blue photosensitive resin composition for color filters and uses thereof - Google Patents

Abstract

The invention relates to a blue photosensitive resin composition, and the blue photosensitive resin composition has the advantages of good ITO sputtering adaption and good pigment dispersion. The invention also provides a method for manufacture a color filter, a color filter and a liquid crystal display device.

Description

Blue photosensitive resin composition for color filter and application thereof

The present invention relates to a blue photosensitive resin composition for a color filter of a liquid crystal display and a color filter formed therefor. In particular, a blue photosensitive resin composition for a color filter excellent in sputtering suitability and pigment dispersibility of indium tin oxide (hereinafter referred to as ITO) is provided.

In recent years, flat panel displays, including liquid crystal displays and organic electroluminescent displays, have been widely used, in which color filters are used in displays, and in order to comply with current energy saving trends, it is necessary to increase the brightness and contrast of liquid crystal displays. The pigments currently used in color filters in photosensitive resin compositions are used to improve brightness and high contrast. For example, Knife Clear "Color Materials Association" (December 1967, 608) reveals a dispersion of color a method of wavelength of a pigment having a wavelength of less than 1/2; however, the blue pigment has a shorter wavelength than other red and green pigments, in which case additional fine dispersion is required, and thus the cost is increased and dispersed. Problems such as poor stability.

On the other hand, a dye as a coloring agent is also under development. For example, Japanese Laid-Open Patent Publication No. 2008-304766 discloses a dye of a triarylmethane derivative, which has disadvantages of insufficient brightness and heat resistance, in order to improve this. Disadvantages, Japanese Patent Laid-Open No. 2011-132492 and No. 2011-133844 disclose molecular modification of a specific structure for an anion of a triarylmethane salt; in addition, in order to improve the heat resistance of the dye, a Japanese patent JP-A-2009-122650 and JP-A-2010-134278 disclose a photosensitive resin composition having an antioxidant.

Although the brightness and contrast of the photosensitive resin composition have been improved in the prior art, the ITO sputtering suitability and pigment dispersibility of the above-mentioned prior art photosensitive resin compositions have not been accepted by the industry. In view of this, how to simultaneously improve the ITO sputtering suitability and pigment dispersibility to meet the requirements of the current industry is an object of diligent research in the technical field to which the present invention pertains.

The present invention provides a blue photosensitive resin composition for a color filter excellent in ITO sputtering suitability and pigment dispersibility by providing a component of a special alkali-soluble resin and a special dye.

Accordingly, the present invention provides a blue photosensitive resin composition for a color filter comprising: an organic pigment (A); a dye (B); an alkali-soluble resin (C); and an ethylenically unsaturated group-based compound (D) a photoinitiator (E); and an organic solvent (F); wherein: the dye (B) comprises a red dye (B-1) having the structure represented by the formula (I):

In the formula (I), B ¹ to B ⁴ each independently represent hydrogen, -B ⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ⁶ , -OH, -OB ⁶ , -SO ₃ ^- , -SO ₃ H, -SO ₃ M, -COOH, -COOB ⁶ , -SO ₃ B ⁶ , -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ substituted C ₆ to C ₁₀ aromatic hydrocarbon group; B ⁵ represents -SO ₃ ^- , -SO ₃ H, -SO ³ M, -COOH, -COOR ⁶ , -SO ₃ R ⁶ , -SO ₂ NHR ⁸ or -SO ₂ NR ⁸ R ⁹ ;s represents an integer from 0 to 5; When s represents 2 to 5, a plurality of B ⁵ are the same or different; T represents a halogen atom; a represents 0 or 1; B ⁶ represents a C ₁ to C ₁₀ alkyl group or a halogen atom substituted C ₁ to C ₁₀ the alkyl group, wherein the C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of the in -CH ₂ - not based substitution or replaced by -O-, or a carbonyl group -NB ⁷ -; B ⁷ represents C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of; B ⁸ and B ⁹ represent each independently a straight chain of C ₁ to C ₁₀ -alkyl, C ₁ a branched alkyl group to C ₁₀ , a C ₃ to C ₃₀ cycloalkyl group, or -Q; wherein, a C ₁ to C ₁₀ linear alkyl group, a C ₁ to C ₁₀ branched alkyl group or C ₃ to based hydrogen atom of the C ₃₀ cycloalkyl group without taking the Or substituted by a substituent, the substituent group selected from the group consisting of a hydroxyl group, a halogen atom, -Q, -CH = CH ₂ and -CH = CH-B consisting of ^6; C straight chain alkyl of ₁ to C ₁₀ The -CH ₂ - in the C ₁ to C ₁₀ branched alkyl group or the C ₃ to C ₃₀ cycloalkyl group is unsubstituted or substituted with -O-, carbonyl or -NB ⁷ -; or B ⁸ and B ⁹ combined to form a C ₁ to C ₁₀ heterocyclic group, the heterocyclic group wherein the C ₁ to C ₁₀ of a hydrogen atom in the unsubstituted or line B ^6, -OH, substituted or -Q; Q represents C ₆ to C ₁₀ aromatic hydrocarbon group, the hetero-aromatic C ₅ to C ₁₀ group, the halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 or -CH = CH-B ^{6-substituted} the C ₆ to C ₁₀ aromatic hydrocarbon group of, or a halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 and -CH = CH-B of the substituted C ⁶ to C _{10. 5} a heteroaromatic group; and M represents potassium or sodium; and the alkali-soluble resin (C) comprises a first alkali-soluble resin (C-1) having the formula (II) Structure:

Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ .

The present invention also provides a method of producing a color filter, which comprises forming a pixel layer using a blue photosensitive resin composition using the color filter described above.

The present invention further provides a color filter which is produced by the aforementioned method.

The present invention further provides a liquid crystal display device comprising the above-described color filter.

1‧‧‧Photosensitive resin layer

2‧‧‧Polar plate

3‧‧‧Polar plate

4‧‧‧Light source

5‧‧‧luminometer

Fig. 1 is a schematic view showing a comparative measurement state (1) of a photosensitive resin layer.

Fig. 2 is a schematic view showing the comparative measurement state (2) of the photosensitive resin layer.

The present invention provides a blue photosensitive resin composition for a color filter comprising: an organic pigment (A); a dye (B); an alkali-soluble resin (C); an ethylenically unsaturated group-based compound (D); An initiator (E); and an organic solvent (F); wherein: the dye (B) comprises a red dye (B-1) having the structure represented by the formula (I):

In the formula (I), B ¹ to B ⁴ each independently represent hydrogen, -B ⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ⁶ , -OH, -OB ⁶ , -SO ₃ ^- , -SO ₃ H, -SO ₃ M, -COOH, -COOB ⁶ , -SO ₃ B ⁶ , -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ substituted C ₆ to C ₁₀ aromatic hydrocarbon group; B ⁵ represents -SO ₃ ^- , -SO ₃ H, -SO ³ M, -COOH, -COOR ⁶ , -SO ₃ R ⁶ , -SO ₂ NHR ⁸ or -SO ₂ NR ⁸ R ⁹ ;s represents an integer from 0 to 5; When s represents 2 to 5, a plurality of B ⁵ are the same or different; T represents a halogen atom; a represents 0 or 1; B ⁶ represents a C ₁ to C ₁₀ alkyl group or a halogen atom substituted C ₁ to C ₁₀ the alkyl group, wherein the C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of the in -CH ₂ - not based substitution or replaced by -O-, or a carbonyl group -NB ⁷ -; B ⁷ represents C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of; B ⁸ and B ⁹ represent each independently a straight chain of C ₁ to C ₁₀ -alkyl, C ₁ a branched alkyl group to C ₁₀ , a C ₃ to C ₃₀ cycloalkyl group, or -Q; wherein, a C ₁ to C ₁₀ linear alkyl group, a C ₁ to C ₁₀ branched alkyl group or C ₃ to based hydrogen atom of the C ₃₀ cycloalkyl group without taking the Or substituted by a substituent, the substituent group selected from the group consisting of a hydroxyl group, a halogen atom, -Q, -CH = CH ₂ and -CH = CH-B consisting of ^6; C straight chain alkyl of ₁ to C ₁₀ The -CH ₂ - in the C ₁ to C ₁₀ branched alkyl group or the C ₃ to C ₃₀ cycloalkyl group is unsubstituted or substituted with -O-, carbonyl or -NB ⁷ -; or B ⁸ and B ⁹ combined to form a C ₁ to C ₁₀ heterocyclic group, the heterocyclic group wherein the C ₁ to C ₁₀ of a hydrogen atom in the unsubstituted or line B ^6, -OH, substituted or -Q; Q represents C ₆ to C ₁₀ aromatic hydrocarbon group, the hetero-aromatic C ₅ to C ₁₀ group, the halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 or -CH = CH-B ^{6-substituted} the C ₆ to C ₁₀ aromatic hydrocarbon group of, or a halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 and -CH = CH-B of the substituted C ⁶ to C _{10. 5} a heteroaromatic group; and M represents potassium or sodium; and the alkali-soluble resin (C) comprises a first alkali-soluble resin (C-1) having the formula (II) Structure:

Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ .

The organic pigment (A) according to the present invention provides a blue pigment.

In one embodiment of the present invention, the organic pigment (A) is used in an amount of 50 parts by weight to 450 parts by weight, based on 100 parts by weight of the total amount of the alkali-soluble resin (C); preferably 60 parts by weight. Up to 400 parts by weight; more preferably 70 parts by weight to 350 parts by weight.

Preferably, the organic pigment (A) comprises a blue organic pigment (A-1) mainly composed of a copper phthalocyanine structure. The blue pigment (A-1) mainly composed of a copper phthalocyanine structure may be used singly or in combination, and the blue pigment (A-1) mainly composed of a copper phthalocyanine structure includes, but is not limited to, CI Pigment Blue 15: 1 (CIPB 15:1), CI Pigment Blue 15:2 (CIPB 15:2), CI Pigment Blue 15:3 (CIPB 15:3), CI Pigment Blue 15:4 (CIPB 15:4), CI Pigment Blue 15:5 (CIPB 15:5), or CI Pigment Blue 15:6 (CIPB 15:6).

In a specific example of the present invention, the total amount of the alkali-soluble resin (C) used is 100 parts by weight, and the amount of the blue organic pigment (A-1) mainly composed of the copper phthalocyanine structure is 30 parts by weight. A portion to 300 parts by weight; preferably 40 parts by weight to 270 parts by weight; more preferably 50 parts by weight to 250 parts by weight.

Preferably, the organic pigment (A) further comprises a purple organic pigment (A-2). The purple pigment (A-2) may be used singly or in combination, and the purple pigment (A-2) includes, but is not limited to, CI Pigment Violet 14 (CIPV14), CI Pigment Violet 19 (CIPV19), CI Pigment Violet 23 ( CIPV23), CI Pigment Violet 29 (CIPV29), CI Pigment Violet 32 (CIPV32), CI Pigment Violet 33 (CIPV33), CI Pigment Violet 36 (CIPV36), CI Pigment Violet 37 (CIPV37), CI Pigment Violet 38 (CIPV38), CI Pigment Violet 40 (CIPV40), or CI Pigment Violet 50 (CIPV50).

In one embodiment of the present invention, the purple organic pigment (A-2) is used in an amount of from 0 part by weight to 150 parts by weight based on 100 parts by weight of the total amount of the alkali-soluble resin (C); preferably 5 parts by weight to 120 parts by weight; more preferably 10 parts by weight to 100 parts by weight.

The organic pigment (A) may contain a blue pigment (A-3) other than (A-1).

The blue pigment (A-3) other than the (A-1) includes, but is not limited to, CI Pigment Blue 1, CI Pigment Blue 21, CI Pigment Blue 22, CI Pigment Blue 60, CI Pigment Blue 61, CI Pigment Blue 64, Or such a combination. The blue pigment (A-3) other than the (A-1) may be used singly or in combination.

In another embodiment of the present invention, in order to adjust the chromaticity, the organic pigment (A) may comprise a green pigment mainly composed of a halogenated phthalocyanine structure.

Preferably, the green pigment mainly composed of a halogenated phthalocyanine structure includes, but not limited to, C.I. Pigment Green 07, C.I. Pigment Green 36, C.I. Pigment Green 37, C.I. Pigment Green 42, or C.I. Pigment Green 58. More preferably, the green pigment component mainly composed of a halogenated phthalocyanine structure is C.I. Pigment Green 07, C.I. Pigment Green 36, C.I. Pigment Green 37, C.I. Pigment Green 42, C.I. Pigment Green 58, or such combinations. The green pigment mainly composed of a halogenated phthalocyanine structure may be used singly or in combination.

The dye (B) according to the present invention contributes to the improvement of the brightness of the blue photosensitive resin composition for the color filter, and at the same time assists in adjusting the chromaticity of the blue photosensitive resin composition for the color filter.

Preferably, the dye (B) comprises a red dye (B-1) having the structure of the formula (I):

In the formula (I), B ¹ to B ⁴ each independently represent hydrogen, -B ⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ⁶ , -OH, -OB ⁶ , -SO ₃ ^- , -SO ₃ H, -SO ₃ M, -COOH, -COOB ⁶ , -SO ₃ B ⁶ , -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ substituted C ₆ to C ₁₀ aromatic hydrocarbon group; B ⁵ represents -SO ₃ ^- , -SO ₃ H, -SO ³ M, -COOH, -COOR ⁶ , -SO ₃ R ⁶ , -SO ₂ NHR ⁸ or -SO ₂ NR ⁸ R ⁹ ;s represents an integer from 0 to 5; When s represents 2 to 5, a plurality of B ⁵ are the same or different; T represents a halogen atom; a represents 0 or 1; B ⁶ represents a C ₁ to C ₁₀ alkyl group or a halogen atom substituted C ₁ to C ₁₀ the alkyl group, wherein the C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of the in -CH ₂ - not based substitution or replaced by -O-, or a carbonyl group -NB ⁷ -; B ⁷ represents C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of; B ⁸ and B ⁹ represent each independently a straight chain of C ₁ to C ₁₀ -alkyl, C ₁ a branched alkyl group to C ₁₀ , a C ₃ to C ₃₀ cycloalkyl group, or -Q; wherein, a C ₁ to C ₁₀ linear alkyl group, a C ₁ to C ₁₀ branched alkyl group or C ₃ to based hydrogen atom of the C ₃₀ cycloalkyl group without taking the Or substituted by a substituent, the substituent group selected from the group consisting of a hydroxyl group, a halogen atom, -Q, -CH = CH ₂ and -CH = CH-B consisting of ^6; C straight chain alkyl of ₁ to C ₁₀ The -CH ₂ - in the C ₁ to C ₁₀ branched alkyl group or the C ₃ to C ₃₀ cycloalkyl group is unsubstituted or substituted with -O-, carbonyl or -NB ⁷ -; or B ⁸ and B ⁹ combined to form a C ₁ to C ₁₀ heterocyclic group, the heterocyclic group wherein the C ₁ to C ₁₀ of a hydrogen atom in the unsubstituted or line B ^6, -OH, substituted or -Q; Q represents C ₆ to C ₁₀ aromatic hydrocarbon group, the hetero-aromatic C ₅ to C ₁₀ group, the halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 or -CH = CH-B ^{6-substituted} the C ₆ to C ₁₀ aromatic hydrocarbon group of, or a halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 and -CH = CH-B of the substituted C ⁶ to C _{10. 5} a heteroaromatic group; and M represents potassium or sodium.

Preferably, B ⁶ includes, but is not limited to, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, cyclopentyl, hexyl, Cyclohexyl, heptyl, cycloheptane, octyl, cyclooctyl, 2-ethylhexyl, decyl, decyl, tricyclo [5.3.0.0 ^3,10 ] fluorenyl [tricycle (5.3.0.0 ^3,10) Decanyl], methoxypropyl, hexyloxypropyl, 2-ethylhexyloxypropyl, methoxyhexyl, or epoxypropyl.

Preferably, the C ₆ to C ₁₀ aromatic hydrocarbon group includes, but is not limited to, a phenyl group or a naphthyl group and the like.

Preferably, -SO ₃ B ⁶ includes, but is not limited to, methanesulfonyl, ethanesulfonyl, hexanesulfonyl, or decanesulfonyl.

Preferably, -COOB ⁶ includes, but is not limited to, methyloxycarbonyl, ethyloxycarbonyl, propoxycarbonyl, isopropoxycarbonyl, butoxycarbonyl, isobutoxycarbonyl, pentyl Oxycarbonyl, isopentyloxycarbonyl, neopentyloxycarbonyl, cyclopentyloxycarbonyl, hexyloxycarbonyl, cyclohexyloxycarbonyl, heptyloxycarbonyl, cycloheptyloxycarbonyl, octyloxycarbonyl, ring Octyloxycarbonyl, 2-ethylhexyloxycarbonyl, decyloxycarbonyl, decyloxycarbonyl, tricyclo[5.3.0.0 ^3,10 ]decylcarbonyl, methoxypropoxycarbonyl, hexyloxypropyl Oxycarbonyl, 2-ethylhexyloxypropoxycarbonyl, or methoxyhexyloxycarbonyl.

Preferably, -SO ₂ NHB ⁸ includes, but is not limited to, sulfamoyl, methylamine sulfonyl, ethylamine sulfonyl, propylamine sulfonyl, isopropylamine sulfonyl, Butylamine sulfonyl, isobutylamine sulfonyl, amylamine sulfonyl, isoamylamine sulfonyl, neopentylamine sulfonyl, cyclopentylamine sulfonyl, hexylamine sulfonate Base, cyclohexylamine sulfonyl, heptylamine sulfonyl, cycloheptylamine sulfonyl, octylamine sulfonyl, cyclooctylamine sulfonyl, 2-ethylhexylamine sulfonyl, hydrazine Amidoxime, decylamine sulfonyl, tricyclo [5.3.0.0 ^3,10 ] decylamine sulfonyl, methoxypropylamine sulfonyl, hexyloxypropyl sulfonyl, 2-ethylhexyloxypropylamine sulfonyl, methoxyhexylamine sulfonyl, epoxy propyl sulfonyl, 1,5-dimethylhexylamine sulfonyl, propoxy Amidoxime, isopropoxypropylamine sulfonyl, 3-phenyl-1-methylpropylamine sulfonyl, , , , , (R ^a represents a substituted alkyl group of C ₁ to C _3, the C ₁ to C ₃ alkoxy group, the substituted alkyl group or a halogen atom of the halogen atom C ₁ to C ₃ of the C ₁ to C ₃ alkyl-oxy base), , , , (R ^b represents a substituted alkyl group of C ₁ to C _3, the C ₁ to C ₃ alkoxy group, the substituted alkyl group or a halogen atom of the halogen atom C ₁ to C ₃ of the C ₁ to C ₃ alkyl-oxy base), ,

Preferably, -SO ₂ NB ⁸ B ⁹ includes but is not limited to , , , (R ^b represents a substituted alkyl group of C ₁ to C _3, the C ₁ to C ₃ alkoxy group, the substituted alkyl group or a halogen atom of the halogen atom C ₁ to C ₃ of the C ₁ to C ₃ alkyl-oxy base), , , ,

Preferably, the dye (B) comprises a red dye having the structure of the formula (I-1):

In the formula (I-1), B ¹¹ to B ¹⁴ each independently represent hydrogen, -B ⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ⁶ , -OH, -OB ⁶ , -SO _a C ₆ to C ₁₀ aromatic hydrocarbon group substituted with ₃ ^- , -SO ₃ H, -SO ₃ Na, -COOH, -COOB ⁶ , -SO ₃ B ⁶ , -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ ; B ¹⁵ represents hydrogen, -SO ₃ ^- , -SO ₃ H, -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ ; B ¹⁶ represents -SO ₃ ^- , -SO ₃ H, -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ ; T ¹ represents a halogen atom; a ¹ represents 0 or 1.

Preferably, the dye (B) comprises a red dye having the structure of the formula (I-2):

In the formula (I-2), B ²¹ to B ²⁴ each independently represent hydrogen, -B ²⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ²⁶ , -OH, -OB ²⁶ , -SO ₃ ^- , -SO ₃ H, -SO ₃ Na, -COOH, -COOB ²⁶ , -SO ₃ B ²⁶ , or -SO ₂ NHB ²⁸ substituted C ₆ to C ₁₀ aromatic hydrocarbon group; B ²⁵ represents -SO ₃ ^- , -SO ₃ Na, -COOH, -COOB ²⁶ , -SO ₃ H, or -SO ₂ NHB ²⁸ ; s ¹ represents an integer from 0 to 5; when s ¹ represents 2 to 5, a plurality of B ²⁵ are the same or Different; T ² represents a halogen atom; a ² represents 0 or 1; B ²⁶ represents a C ₁ to C ₁₀ alkyl group; or a C ₁ to C ₁₀ alkyl group substituted by a halogen atom or -OB ²⁷ ; B ²⁷ represents C ₁ to C ₁₀ alkyl; and B ²⁸ represents hydrogen, -B ²⁶ , -COOB ²⁶ , C ₆ to C ₁₀ aromatic hydrocarbon group, or C ₆ to C ₁₀ aromatic hydrocarbon group substituted by -B ²⁶ or -OB ²⁶ .

Preferably, the dye (B) comprises a red dye having the structure of formula (I-3):

In the formula (I-3), B ³¹ and B ³² each independently represent a phenyl group, or are substituted by a halogen atom, -B ²⁶ , -OB ²⁶ , -COOB ²⁶ , -SO ₃ B ²⁶ or -SO ₂ NHB ²⁸ Phenyl group; B ³³ represents -SO ₃ ^- or -SO ₂ NHB ²⁸ ; B ³⁴ represents hydrogen, -SO ₃ ^- or -SO ₂ NHB ²⁸ ; T ³ represents a halogen atom; a ³ represents 0 or 1; ²⁶ represents a C ₁ to C ₁₀ alkyl group, the halogen atom or a substituted or -OB ²⁷ of the C ₁ to C ₁₀ alkyl group of; B ²⁷ represents a C ₁ to C ₁₀ alkyl group of; represents hydrogen and B ^28, -B ^{26, -COOB 26,} C ₆ to C ₁₀ aromatic hydrocarbon group, the -B ^26, or by a substituted or -OB ²⁶ of C ₆ to C ₁₀ aromatic hydrocarbon group of.

Preferably, the dye (B) comprises a red dye having the structure of formula (I-4):

In the formula (I-4), B ⁴¹ and B ⁴² each independently represent a phenyl group or a phenyl group substituted with -B ²⁶ or -SO ₂ NHB ²⁸ ; and B ⁴³ represents -SO ₃ ^- or -SO ₂ NHB ²⁸ ; T ⁴ represents a halogen atom; a ⁴ represents 0 or 1; B ²⁶ represents a C ₁ to C ₁₀ alkyl group; or a C ₁ to C ₁₀ alkyl group substituted by a halogen atom or -OB ²⁷ ; B ²⁷ represents C ₁ the alkyl to C _10; and B ²⁸ represents a hydrogen, -B ^26, -COOB ^26, C ₆ to C ₁₀ aromatic hydrocarbon group, the -B ^26, or by a substituted or -OB ²⁶ of C ₆ to C ₁₀ aromatic hydrocarbon group of.

In a specific example of the present invention, the dye (B) includes, but is not limited to, the following formulas (1) to (31):

R ^c and R ^d each independently represent hydrogen, -SO ₃ ^- , -COOH or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl; T represents a halogen atom; and a represents 0 or 1.

R ^e represents hydrogen, -SO ₃ ^- , -COOH or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl; T represents a halogen atom; and a represents 0 or 1.

R ^e represents hydrogen, -SO ₃ ^- , -COOH or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl; T represents a halogen atom; and a represents 0 or 1.

R ^f , R ^g and R ^h each independently represent -SO ₃ ^- , -SO ₃ Na or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ^f , R ^g and R ^h each independently represent -SO ₃ ^- , -SO ₃ Na or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ⁱ , R ^j and R ^k each independently represent hydrogen, -SO ₃ ^- , -SO ₃ H or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ⁱ , R ^j and R ^k each independently represent hydrogen, -SO ₃ ^- , -SO ₃ H or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ^l , R ^m and R ⁿ each independently represent -SO ₃ ^- , -SO ₃ Na or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ^l , R ^m and R ⁿ each independently represent -SO ₃ ^- , -SO ₃ Na or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ^p , R ^q and R ^r each independently represent hydrogen, -SO ₃ ^- , -SO ₃ H or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

R ^p , R ^q and R ^r each independently represent hydrogen, -SO ₃ ^- , -SO ₃ H or -SO ₂ NHB ⁸¹ ; B ⁸¹ represents 2-ethylhexyl.

A preferred specific example of the dye (B) of the present invention is a formula (1) (R ^c and R ^d are -SO ₃ ^- , a is 0) [CI acid red dye 52], formula (22) [CI acid red dye 289], formula (28), formula (31), or a combination of these.

In a specific example of the present invention, the dye (B-1) is used in an amount of 10 parts by weight to 90 parts by weight, based on 100 parts by weight of the total amount of the alkali-soluble resin (C); preferably 13 parts by weight. To 80 parts by weight; more preferably 15 parts by weight to 70 parts by weight. When the dye (B-1) is not used, the pigment dispersibility and contrast of the pixel layer produced by the blue photosensitive resin composition are not good.

In a preferred embodiment of the invention, the dye (B) may further comprise other dyes (B-2).

Preferably, the other dye (B-2) comprises an azo dye or an anthraquinone dye, wherein the azo dye includes, but is not limited to, acid red 37, acid red 180, direct red 28, direct red 83, Reactive Red 17, Reactive Red 120, Disperse Red 58, Alkaline Red 18 or Morden Red 7, etc.; the lanthanide dyes include, but are not limited to, Disperse Red 60 and the like. The above other dyes may generally be used singly or in combination of two or more.

In a specific example of the present invention, the dye (B) is used in an amount of 10 parts by weight to 90 parts by weight based on 100 parts by weight of the total amount of the alkali-soluble resin (C); preferably 13 parts by weight to 80 parts by weight. Parts by weight; more preferably 15 parts by weight to 70 parts by weight.

The alkali-soluble resin (C) according to the present invention comprises a first alkali-soluble resin (C-1) having a structure represented by the formula (II):

Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ .

In the above formula (II), specific examples of L include, but are not limited to, hydrogen atoms; chain-like saturated hydrocarbon groups include, but are not limited to, methyl, ethyl, n-propyl, i-propyl, n-butyl, s-butyl Base, t-butyl, n-pentyl, s-pentyl, t-pentyl, n-hexyl, s-hexyl, n-heptyl, n-octyl, s-octyl, t-octyl, 2-ethylhexyl, octanoic acid, decyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, ten An octaalkyl group, a nonadecyl group, an eicosyl group, a seryl group or a melissyl group; an alkoxy group substituted with a part of a hydrogen atom of a chain saturated hydrocarbon group by an alkoxy group a hydrocarbyl group, wherein the alkoxy group includes, but is not limited to, methoxyethyl, methoxyethoxyethyl, methoxyethoxyethoxyethyl, 3-methoxy-butyl, ethoxyethyl, Ethoxyethoxyethyl, phenoxyethyl or phenoxyethoxyethyl; a hydrocarbyl group substituted with a hydrocarbyl group substituted with a part of a hydrogen atom of a chain saturated hydrocarbon group, wherein the hydrocarbyl group includes but not Limited to hydroxyethyl, hydroxypropyl or hydroxybutyl; saturated with halogen a halogen-substituted chain saturated hydrocarbon group substituted with a partial hydrogen atom of a hydrocarbon group, wherein the halogen includes, but is not limited to, a fluoroethyl group, a difluoroethyl group, a chloroethyl group, a dichloroethyl group, a bromoethyl group or a dibromoethyl group; The chain unsaturated hydrocarbon group includes, but is not limited to, a vinyl group, an allyl group, a methallyl group, a butenyl group or a propynyl group, and a chain having a part of hydrogen atoms substituted by an alkoxy group, a hydrocarbon group or a halogen. An unsaturated hydrocarbon group; the alicyclic hydrocarbon group includes, but is not limited to, a cyclopentyl group, a cyclohexyl group, a 4-methylcyclohexyl group, a 4-tert-butylcyclohexyl group, a tricyclodecyl group, an isobornyl group, an adamantyl group or a bicyclic ring. a pentadienyl group, and an alicyclic hydrocarbon group substituted with a part of hydrogen atoms thereof by an alkoxy group, a hydrocarbon group or a halogen; and an aromatic hydrocarbon group including, but not limited to, a phenyl group, a methylphenyl group, a dimethylphenyl group, Trimethylphenyl, 4-tert-butylphenyl, benzyl, diphenylmethyl, diphenylethyl, triphenylmethyl, cinnamyl, A naphthyl or an anthracenyl group, and an aromatic hydrocarbon group substituted with a part of hydrogen atoms thereof by an alkoxy group, a hydrocarbon group or a halogen. Wherein, the above organic group may further bond a substituent. In the formula (II), L may be the same or two or more different types.

The unit content of the first alkali-soluble resin (C-1) having the structure represented by the formula (II) of the present invention can be appropriately adjusted depending on the purpose, the use or the molecular weight of the first alkali-soluble resin of the present invention, in general, The repeating structural unit content is from 5 to 80 mole%, preferably from 10 to 70 mol%, more preferably from 15 to 60 mol%.

Although it is not intended to be limited by theory, it is presumed that the first alkali-soluble resin (C-1) has a tetrahydrofuran ring in its main chain and is methylene on both sides, so it is presumed that it has excellent dispersing of colored materials. Stability, because the tetrahydrofuran ring acts with a Lewis base (donor pair of donors), and the strong base can prevent the colored material from dispersing with the dispersant; further, since the tetrahydrofuran ring has Lewis Bases, therefore, easily interact with functional groups on the surface of other substrates to exhibit good adhesion. Further, since the tetrahydrofuran ring has oxygen trapping property, it is possible to reduce the suppression of radical hardening by oxygen in the radical hardening using heat or active energy rays, and has an advantage of improving surface hardenability and film hardenability.

Further, since tetrahydrofuran has a very broad ability to dissolve substances, it is often used for industrial analysis or research, so the alkali-soluble resin of the present invention has excellent compatibility and dry resolubility.

The first alkali-soluble resin (C-1) of the present invention is obtained by polymerizing the monomer (c-1) represented by the formula (III), and when it is polymerized, the above formula (II) is produced at a high ratio. The structure shown is such that it is less likely to cause abnormal polymerization or gelation.

Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ .

In the above formula (III), the definition of L is the same as the definition of L in the formula (II), and will not be further described herein.

Specific examples of the monomer (c-1) represented by the above formula (III) include α-allyloxymethacrylic acid, α-allyloxymethyl methacrylate, and α-allyl. Ethyl methacrylate, α-allyloxymethacrylate-n-propyl ester, α-allyloxymethacrylic acid-i-propyl ester, α-allyloxymethyl methacrylate-n- Butyl ester, α-allyloxymethacrylic acid-s-butyl ester, α-allyloxymethyl methacrylate-t-butyl ester, α-allyloxymethyl acrylate-n-pentyl ester, α- Allyloxymethacrylic acid-s-pentyl ester, α-allyloxymethyl methacrylate-t-amyl ester, α-allyloxymethyl methacrylate-n-hexyl ester, α-allyloxymethyl Acrylic acid-s-hexyl ester, α-allyloxymethyl methacrylate-n-heptyl ester, α-allyloxy methacrylic acid-n-octyl ester, α-allyloxy methacrylic acid-s- Octyl ester, α-allyloxymethyl methacrylate-t-octyl ester, α-allyloxymethyl methacrylate 2-ethylhexyl ester, α-allyloxymethyl acrylate octanoic acid, α-allyl Oxyl methacrylate, α-allyloxymethyl methacrylate, α-allyloxymethyl undecyl methacrylate, α-allyloxymethyl Dodecyl acrylate, tridecyl α-allyloxymethacrylate, tetradecyl α-allyloxymethacrylate, pentadecyl α-allyloxymethacrylate, α- Allyloxy hexadecane methacrylate, heptadecyl α-allyloxymethyl methacrylate, octadecyl α-allyloxymethyl methacrylate, α-allyloxy methacrylic acid Nonaalkyl ester, α-allyloxymethyl methacrylate, α-allyloxymethyl acrylic acid seryl, α-allyloxy methacrylic acid Decamate, methoxyethyl α-allyloxymethacrylate, methoxyethoxyethyl α-allyloxymethacrylate, methoxyethyl α-allyloxymethacrylate Oxyethoxyethyl ester, α-allyloxymethyl methacrylate-3-methoxybutyl ester, α-allyloxyethyl methacrylate ethoxyethyl ester, α-allyloxy methacrylic acid Ethoxyethoxyethyl ester, phenoxyethyl α-allyloxy methacrylate, phenoxyethoxyethyl α-allyloxy methacrylate, hydroxy group α-allyloxymethyl methacrylate Ethyl ester, α-allyloxymethyl Hydroxypropyl acrylate, α- allyloxy Hydroxybutyl methacrylate, fluoroethyl α-allyloxy methacrylate, difluoroethyl α-allyloxy methacrylate, chloroethyl α-allyloxy methacrylate, α-ene Diethyl ethyl propyl methacrylate, bromoethyl α-allyloxy methacrylate, dibromoethyl α-allyloxy methacrylate, vinyl α-allyloxy methacrylate, Allyl α-allyloxymethacrylate, methyl allyl α-allyloxymethacrylate, butenyl α-allyloxymethacrylate, α-allyloxymethacrylic acid Propargyl propyl ester, cyclopentyl α-allyloxymethyl methacrylate, cyclohexyl α-allyloxymethacrylate, α-allyloxy methacrylate-4-methylcyclohexyl ester, α- Allyloxymethacrylate 4-t-butylcyclohexyl ester, α-allyloxy methacrylate tricyclodecyl ester, α-allyloxy isoamyl methacrylate, α-allyloxy Adamantyl methacrylate, dicyclopentadienyl α-allyloxymethyl methacrylate, phenyl α-allyloxy methacrylate, methyl phenyl acrylate α-allyloxymethyl methacrylate Alpha-allyloxymethyl methacrylate Phenyl ester, trimethylphenyl α-allyloxymethacrylate, 4-t-butylphenyl α-allyloxymethacrylate, benzyl α-allyloxymethyl methacrylate, Diphenylmethyl α-allyloxymethacrylate, diphenylethyl α-allyloxymethacrylate, triphenylmethyl α-allyloxymethacrylate, α-allyloxy Cyanyl methacrylate, naphthyl α-allyloxymethacrylate, and α-allyloxymethacrylate. The monomer (c-1) represented by the above formula (III) can be generally used singly or in combination of two or more.

The content of the monomer (c-1) represented by the formula (III) can be appropriately adjusted depending on the purpose, use, or molecular weight of the alkali-soluble resin of the present invention. Generally, the content of the monomer is 5 to 80 mole%. It is preferably from 10 to 70 mol%, more preferably from 15 to 60 mol%.

When the first alkali-soluble resin of the present invention has a high molecular weight, even if the content of the structural unit represented by the formula (II) is small, there is a tendency to exhibit performance (excellent pigment dispersibility), and when it is a low molecular weight, the content is increased. It is easy to show a tendency to performance. This reason is related to the number of structural units represented by the formula (II) contained in each main chain (hereinafter referred to as the average number of functional groups), and the number of the average functional groups is preferably 0.5 or more, more preferably 1.0 or more. , especially good for 2.0 or more. Wherein, the average functional group number is expressed as follows: Average functional group number = A / PA: Moir number of the structural unit represented by the formula (II) contained per unit mass [mol/g]; P: contained in the unit mass The molar number of the first alkali-soluble resin (C-1) [mol/g]; if there are two or more types of structural units represented by the formula (II), A can be calculated by the following formula; A=ΣA _X ( X = 1, 2, 3, ...); A _X = unit mass × (C _X / 100) / F _X ; A _X : the Xth of the unit mass (X = 1, 2, 3, .. .) Moir number of structural unit represented by formula (II) [mol/g]; C _X : X (X = 1, 2, 3, ...) of formula (II) contained in unit mass Mass ratio of the structural unit shown [% by mass]; F _X : molecular weight [g/mol] of the structural unit represented by the formula (II) of X (X = 1, 2, 3, ...); The number average molecular weight (Mn) of the first alkali-soluble resin (C-1) is represented by the following formula: P = unit mass / Mn; and Mn: the number average molecular weight of the first alkali-soluble resin (C-1).

Therefore, the average functional group number is expressed as follows: average functional group number = Mn × Σ {(C _X / 100) × (1/F _X )} (X = 1, 2, 3, ...)

Further, if the cyclization ratio of the monomer represented by the formula (III) (the ratio of the monomer represented by the formula (III) to the structural unit represented by the formula (II)) is high, C _X and F _X As shown below: C _X : mass ratio of the monomer represented by the formula (III) of the reaction formula (III) to all monomers of the reaction [% by mass]; F _X : molecular weight [g/mol] of the monomer represented by the formula (III) of X (X = 1, 2, 3, ...).

When the reaction rate (conversion ratio) of each monomer used in the polymerization is high (for example, the reaction rate is 90 mol% or more), C _{X is} as follows: C _X : the Xth in the monomer component (X=1, 2, 3, ...) The mass ratio [% by mass] of the monomer represented by the formula (III).

The monomer (c-1) represented by the formula (III) is used in an amount of 5 based on 100 parts by weight of the total of the monomers (c-1), (c-2) and (c-3). The parts by weight to 80 parts by weight; preferably 10 parts by weight to 70 parts by weight; more preferably 15 parts by weight to 60 parts by weight.

In a specific example of the present invention, the first alkali-soluble resin (C-1) is a monomer (c-1) represented by the formula (III), and an ethylenically unsaturated monomer having one or more carboxylic acid groups. The compound (c-2) is obtained by polymerization with another copolymerizable ethylenically unsaturated monomer (c-3).

The ethylenically unsaturated monomer (c-2) having one or more carboxylic acid groups may include, but is not limited to, an unsaturated monocarboxylic acid monomer, an unsaturated polycarboxylic acid monomer, an unsaturated group, and a carboxylic acid. a polycyclic monomer, or a polycyclic monomer having an unsaturated group and a plurality of carboxylic acid groups.

The unsaturated monocarboxylic acid monomer may include, but is not limited to, (meth)acrylic acid, crotonic acid, α-chloroacrylic acid, ethacrylic acid, cinnamic acid, 2-(methyl)acrylic acid ethoxylated succinate (2-methacryloyloxyethyl succinate monoester), 2-(meth) propylene oxime ethoxy hexahydrophthalate, 2-(meth) propylene ethoxy ethoxylate or omega-carboxy condensate Ester polyol monoacrylate and the like. The omega-carboxypolycaprolactone polyol monoacrylate can be manufactured by East Asia Synthetic, model ARONIX M-5300.

The unsaturated polycarboxylic acid monomer may include, but is not limited to, maleic acid, fumaric acid, methyl fumaric acid, itaconic acid or citraconic acid, and the like.

The polycyclic monomer having an unsaturated group and a carboxylic acid group may include, but is not limited to, 5-carboxybicyclo[2.2.1]hept-2-ene, 5-carboxy-5-methylbicyclo[2.2.1]g 2-ene, 5-carboxy-5-ethylbicyclo[2.2.1]hept-2-ene, 5-carboxy-6-methylbicyclo [2.2.1] Hept-2-ene or 5-carboxy-6-ethylbicyclo[2.2.1]hept-2-ene and the like.

The polycyclic monomer having an unsaturated group and a plurality of carboxyl groups may be, for example, 5,6-dicarboxybicyclo[2.2.1]hept-2-ene or the like.

The above unsaturated carboxylic acid monomers may be used singly or in combination of plural kinds.

Preferably, the unsaturated carboxylic acid monomer is selected from the group consisting of acrylic acid, methacrylic acid, 2-methylpropenyl ethoxy succinate, 2-methylpropenyl ethoxy hexahydro phthalate An acid ester, or any combination of the above monomers.

The unsaturated carboxylic anhydride monomer may include, but is not limited to, an unsaturated carboxylic anhydride monomer or a polycyclic monomer having an unsaturated group and a carboxylic anhydride.

The unsaturated carboxylic anhydride monomer may include, but is not limited to, maleic anhydride, fumaric anhydride, methyl fumaric anhydride, itaconic anhydride or citraconic anhydride, and the like. The polycyclic monomer having an unsaturated group and a carboxylic anhydride may include, but is not limited to, 5,6-dicarboxylic anhydride bicyclo[2.2.1]hept-2-ene and the like.

The unsaturated carboxylic anhydride monomer may be used singly or in combination of plural kinds.

Preferably, the unsaturated carboxylic anhydride monomer is maleic anhydride.

The ethylenically unsaturated monomer having one or more carboxylic acid groups (c-2) based on 100 parts by weight of the total of the monomers (c-1), (c-2) and (c-3) used. The amount used is 5 parts by weight to 50 parts by weight; preferably 7 parts by weight to 45 parts by weight; more preferably 10 parts by weight to 40 parts by weight.

The other copolymerizable ethylenically unsaturated monomer (c-3) may include, but is not limited to, an alkyl (meth)acrylate, an alicyclic (meth)acrylate, an aryl (meth)acrylate, An unsaturated dicarboxylic acid ester, a hydroxyalkyl (meth)acrylate, a polyether having a (meth) acrylate group, a styrene monomer or an unsaturated monomer other than the above monomers.

The above alkyl (meth)acrylate may include, but is not limited to, methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, ( N-butyl acrylate, isobutyl (meth)acrylate, second butyl (meth)acrylate or t-butyl (meth)acrylate.

The above (meth) acrylate cycloaliphatic ester may include, but is not limited to, cyclohexyl (meth) acrylate, 2-methylcyclohexyl (meth) acrylate, dicyclopentyl (meth) acrylate {or Tricyclo [5.2.1.0 ^2,6 ]癸-8-yl (meth) acrylate}, dicyclopentyloxy (meth) acrylate, isobornyl (meth) acrylate or (meth) acrylate Tetrahydrofuran ester and the like.

The above aryl (meth)acrylate may include, but is not limited to, phenyl (meth)acrylate or benzyl methacrylate.

The unsaturated dicarboxylic acid ester may include, but is not limited to, diethyl maleate, diethyl fumarate or diethyl itaconate, and the like.

The hydroxyalkyl (meth)acrylate may include, but is not limited to, 2-hydroxyethyl (meth)acrylate or 2-hydroxypropyl (meth)acrylate, and the like.

The (meth) acrylate group-containing polyether may include, but is not limited to, polyethylene glycol mono(meth) acrylate or polypropylene glycol mono (meth) acrylate, and the like.

The styrene monomer may include, but is not limited to, styrene, α-methylstyrene, m-methylstyrene, p-methylstyrene or p-methoxystyrene.

The unsaturated monomer other than the above monomers may include, but not limited to, acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, acrylamide, methacrylamide, vinyl ethyl ester, 1,3-butyl Alkene, isoprene, 2,3-dimethyl1,3-butadiene, N-cyclohexylmaleimide, N-phenylmaleimide, N-benzylmalayiya Amine, N-butyl succinimide-3-maleimide benzoate, N-butyl succinimide-4-maleimide butyrate, N-butylimine -6-maleimide caproate, N-butylenediamine-3-maleimide propionate or N-(9-acridinyl) mala 醯imine and so on.

The other copolymerizable ethylenically unsaturated monomer (c-3) may be used singly or in combination of plural kinds.

Preferably, the other copolymerizable ethylenically unsaturated monomer (c-3) is selected from the group consisting of methyl (meth)acrylate, butyl (meth)acrylate, and 2-hydroxyethyl (meth)acrylate. Ester, tert-butyl (meth)acrylate, benzyl (meth)acrylate, dicyclopentanyl (meth)acrylate, isobornyl methacrylate, dicyclopentyloxyethyl (meth)acrylate , styrene, p-methoxystyrene or any combination of the above monomers.

The amount of the other copolymerizable ethylenically unsaturated monomer (c-3) used based on the total amount of the monomers (c-1), (c-2), and (c-3) used is 100 parts by weight. It is 10 parts by weight to 90 parts by weight; preferably 15 parts by weight to 80 parts by weight; more preferably 20 parts by weight to 70 parts by weight.

The above polymerization method can be appropriately selected depending on the purpose or use, for example, a conventional polymerization method such as bulk polymerization, solution polymerization, or emulsion polymerization, preferably solution polymerization, and the structural adjustment of the molecular weight or the like is easy, so that it is advantageous for industrial use; Further, the polymerization mechanism includes a conventional polymerization method using a radical polymerization initiator, an anionic polymerization initiator, a cationic polymerization initiator initiator, a coordination polymerization initiator, etc., wherein a radical polymerization is used. In the case of the initiator, the higher the cyclization rate (the ratio of the monomer represented by the formula (III) to the structural unit represented by the formula (II)), the more advantageous it is to industrial use.

The polymerization initiation method of the above monomer component can be carried out by a conventional method, for example, self-heating, electromagnetic waves (infrared rays, ultraviolet rays, X-rays, etc.) or electron beams and the like to supply the desired energy for polymerization to the monomer component. Preferably, a polymerization initiator is preferably used in combination, whereby the energy required for the initiation of polymerization can be reduced and the reaction can be controlled more easily.

The method for controlling the above molecular weight can be adjusted by a conventional method such as controlling a polymerization initiator, a polymerization temperature, and a chain transfer agent.

When the monomer is subjected to the solution polymerization method, the solvent to be used in the polymerization is not particularly limited as long as it is appropriately set depending on the polymerization conditions such as the kind or amount of the monomer to be used, the polymerization temperature, and the polymerization concentration.

Specific examples of the solvent may include, but are not limited to, monoalcohols such as methanol, ethanol, isopropanol, n-butanol, s-butanol, etc.; alcohols such as ethylene glycol, propylene glycol, etc.; cyclic ethers For example: tetrahydrofuran, dioxane, etc.; ethylene glycol monoethyl ether, such as: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol single Ethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, 3-methoxybutanol, etc.; glycol ethers, for example: ethylene glycol dimethyl ether , ethylene glycol diethyl ether, ethylene glycol ethyl methyl ether, diglyme, diethylene glycol diethyl ether, diethylene glycol ethyl methyl ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, etc.; Glycol monomethyl ether esters, for example: ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, diethylene glycol monomethyl ether acetate, two Glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, dipropylene glycol Methyl ether acetate, dipropylene glycol monoethyl ether acetate, dipropylene glycol monomethyl ether acetate, 3-methoxybutyrate, etc.; alkyl esters, such as methyl acetate, ethyl acetate, Propyl acetate, isopropyl ester, butyl acetate, methyl propionate, ethyl propionate, butyl propionate, methyl lactate, ethyl lactate, butyl lactate, methyl 3-methoxypropionate, 3 - ethyl methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl acetoacetate, ethyl acetoacetate, etc.; ketones, for example: acetone, methyl Ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.; aromatic hydrocarbons such as benzene, toluene, xylene, ethylbenzene, etc.; aliphatic hydrocarbons such as n-hexane, cyclohexane, octane, etc.; Amides such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like. The above solvents may be used singly or in combination of plural kinds.

The solvent is used in an amount of 40 parts by weight to 1000 parts by weight, based on 100 parts by weight of the total of the monomers (c-1), (c-2) and (c-3); preferably 100 parts by weight. to 400 parts by weight.

The radical polymerization initiator is not particularly limited as long as it can supply heat energy to generate a radical, and a polymerization initiator which generates a radical by heat is advantageous for industrial use.

Specific examples of the radical polymerization initiator may include, but are not limited to, cumene hydroperoxide, diisopropylbenzene hydroperoxide, 2-t-butyl peroxide, lauroyl peroxide, and benzoyl peroxide. Formyl, t-butylperoxyisopropyl carbonate, t-butylperoxy-2-hexanoate ethyl ester, azobisisobutyronitrile, 1,1'-azobis(cyclohexanecarbonitrile) 2,2'-azobis(2,4-dimethyl), 2,2'-azobis(2-methylpropionate), hydrogen peroxide, persulfate, and the like. The above-mentioned radical polymerization initiators may be used singly or in combination of plural kinds. Meanwhile, the radical polymerization initiator may be used in combination with an excessive metal salt or an amine.

The amount of the radical polymerization initiator to be used is not particularly limited as long as it is appropriately set depending on the polymerization conditions such as the type or amount of the monomer to be used, the polymerization temperature, and the polymerization concentration. However, in order to obtain a polymer having a weight average molecular weight of several thousands to several tens of thousands, the radical polymerization is based on the total amount of the monomers (c-1), (c-2) and (c-3) used in an amount of 100 parts by weight. The starting agent is preferably used in an amount of from 0.05 part by weight to 20 parts by weight; more preferably from 0.1 part by weight to 15 parts by weight.

A chain transfer agent may be used in combination during the polymerization, wherein when a chain transfer agent is used, there is a tendency to suppress the molecular weight distribution of the polymer in the reaction to prevent gelation. Specific examples of the chain transfer agent may include, but are not limited to, mercaptocarboxylic acids such as mercaptoacetic acid and 3-mercaptopropionic acid; methyl mercaptoacetate, methyl 3-mercaptopropionate, 2-ethylhexyl propionate-2-ethylhexyl ester , 3-mercaptopropionic acid-n-octyl ester, 3-mercaptopropionic acid methoxybutyl ester, 3-mercaptopropionic acid stearyl ester, trimethylolpropane tris(3-mercaptopropionate), pentaerythritol tetra ( Mercaptocarboxylic acid esters such as 3-mercaptopropionate, dipentaerythritol hexa(3-mercaptopropionate); ethanethiol, t-butyl mercaptan, n-dodecyl mercaptan, 1,2- Alkyl mercaptans such as dimercaptoethane; mercapto alcohols such as 2-mercaptoethanol and 4-mercapto-1-butanol; phenyl mercaptan, m-toluene mercaptan, p-toluene mercaptan, An aromatic thiol such as 2-naphthylthiol or a fluorenyl isocyanurate such as tris[(3-mercaptopropionyloxy)-ethyl]isocyanurate.

As the chain transfer agent, a chain transfer agent other than a compound having a sulfur group, for example, a disulfide such as 2-hydroxyethyl disulfide or tetraethyl thiuram disulfide; Dithiocarbamate such as diethyldibenzyl; monomeric dimers such as α-methylstyrene dimer; and halogenated alkane such as carbon tetrabromide. The chain transfer agent is preferably a mercaptocarboxylic acid, a mercaptocarboxylic acid ester, an alkyl mercaptan, a mercapto alcohol, or an aromatic sulfur in terms of availability, anti-crosslinking ability, and a low degree of polymerization. A compound having a mercapto group such as an alcohol or a mercapto isocyanurate. The above chain transfer agents may be used singly or in combination of plural kinds.

The amount of the chain transfer agent used is not particularly limited as long as it is appropriately set depending on the polymerization conditions such as the type or amount of the monomer to be used, the polymerization temperature, and the polymerization concentration. However, in order to obtain a polymer having a weight average molecular weight of several thousands to several tens of thousands, the chain transfer agent is based on the total amount of the monomers (c-1), (c-2) and (c-3) used in an amount of 100 parts by weight. The amount used is preferably from 0.1 part by weight to 20 parts by weight; more preferably from 0.5 part by weight to 15 parts by weight.

The temperature at which the polymerization reaction is carried out may be appropriately set depending on the type or amount of the monomer to be used and the polymerization conditions such as a polymerization initiator, and is preferably from 50 to 200 ° C, more preferably from 70 to 150 ° C.

In another embodiment of the present invention, the first alkali-soluble resin (C-1) may be copolymerized by the monomers (c-1), (c-2) and (c-3). It is obtained by carrying out polymerization reaction with an ethylenically unsaturated monomer (c-4) having an epoxy group.

The epoxy group-containing ethylenically unsaturated monomer (c-4) may include, but is not limited to, a (meth) acrylate monomer having an epoxy group, an α-alkyl acrylate compound having an epoxy group or a ring. Oxypropyl ether monomer and the like.

The epoxy group-containing (meth) acrylate monomer may include, but is not limited to, glycidyl (meth) acrylate, 2-methyl epoxypropyl (meth) acrylate, (A) 3,4-epoxybutyl acrylate, 6,7-epoxyheptyl (meth)acrylate, 3,4-epoxycyclohexyl (meth)acrylate or 3,4-(meth)acrylate Epoxycyclohexylmethyl ester and the like.

The epoxy group-containing α-alkyl acrylate monomer may include, but is not limited to, α-ethyl methacrylate, propylene propyl α-n-propyl acrylate, and glycidyl α-n-butyl acrylate. Or α-ethyl acrylate-6,7-epoxyheptyl ester and the like.

The propylene glycol ether monomer may include, but is not limited to, o-vinylbenzylglycidylether, m-vinylbenzylglycidylether or p-vinyl. P-vinylbenzylglycidylether or the like.

The epoxy group-containing ethylenically unsaturated monomer (c-4) may be used singly or in combination of plural kinds.

Preferably, the epoxy group-containing ethylenically unsaturated monomer (c-4) is selected from the group consisting of glycidyl methacrylate, 3,4-epoxycyclohexylmethyl methacrylate, and methacrylic acid. 6,7-epoxyheptyl ester, o-vinylbenzyl glycidyl ether, m-vinylbenzyl glycidyl ether, p-vinylbenzyl glycidyl ether or any of the above monomers combination.

The amount of the epoxy group-containing ethylenically unsaturated monomer (c-4) used based on 100 parts by weight of the total of the monomers (c-1), (c-2), and (c-3) It is from 3 parts by weight to 40 parts by weight; preferably from 5 parts by weight to 35 parts by weight; more preferably from 10 parts by weight to 30 parts by weight.

When the first alkali-soluble resin (C-1) is a monomer (c-1) represented by the above formula (III), an ethylenically unsaturated monomer (c-2) having one or more carboxylic acid groups, and the like When the copolymerizable ethylenically unsaturated monomer (c-3) is polymerized and the ethylenic unsaturated monomer (c-4) having an epoxy group is polymerized, it reacts to form A resin having an ethylenically unsaturated group, for example, a structure represented by the formula (IV):

Wherein L ¹ represents a hydrogen atom or a methyl group. The average molecular weight of the first alkali-soluble resin (C-1) of the present invention may be appropriately set according to the purpose and use, and the average molecular weight is 2,000 to 250,000 in order to obtain good ITO sputtering suitability and pigment dispersibility. It is preferably from 3,000 to 200,000, more preferably from 400 to 150,000.

In a specific example of the present invention, the first alkali-soluble resin (C-1) is used in an amount of 5 parts by weight to 100 parts by weight based on 100 parts by weight of the total amount of the alkali-soluble resin (C); It is from 7 parts by weight to 80 parts by weight; more preferably from 10 parts by weight to 60 parts by weight. When the first alkali-soluble resin (C-1) is not used in the synthesis of the monomer (c-1) represented by the formula (III), the ITO of the pixel layer is obtained from the blue photosensitive resin composition. The sputtering suitability and the pigment dispersibility are not good; when the first alkali-soluble resin (C-1) has an ethylenically unsaturated group, the ITO sputtering suitability can be further improved.

The alkali-soluble resin (C) according to the present invention may further comprise a second alkali-soluble resin (C-2) which is obtained by polymerization of a mixture, and the mixture contains An epoxy resin (c1) having at least two epoxy groups, and a compound (c2) having at least one carboxylic acid group and at least one ethylenically unsaturated group. Besides, the above mixture may more optionally contain a carboxylic anhydride compound (c3) and/or an epoxy group-containing compound (c4).

The epoxy resin (c1) having at least two epoxy groups according to the present invention may have a structure represented by the following formula (V) or the following formula (VI). Here, the description "the epoxy resin (c1) may have a structure represented by the following formula (V) or the following formula (VI)" also encompasses a compound having a structure represented by the following formula (V) and has the following formula The compound of the structure shown by (VI) exists at the same time as the case of the epoxy resin (c1). Specifically, the epoxy resin (c1) having at least two epoxy groups described above has, for example, a structure represented by the following formula (V):

Wherein: R ⁶¹ , R ⁶² , R ⁶³ and R ⁶⁴ are independently selected from the group consisting of hydrogen, halogen and C ₁ to C ₅ alkyl; the epoxy of the above formula (V) having at least two epoxy groups The resin (c1) may include an epoxy group-containing bisphenol quinone type compound obtained by reacting a bisphenol fluorene with a halogenated propylene oxide (epihalohydrin), but is not limited thereto.

Specific examples of the above bisphenol quinoid type compound include 9,9-bis(4-hydroxyphenyl)fluorene, 9,9-bis(4-hydroxyl group). -3-methylphenyl)fluorene [9,9-bis(4-hydroxy-3-methylphenyl)fluorene], 9,9-bis(4-hydroxy-3-chlorophenyl)fluorene [9,9-bis (4-hydroxy-3-chlorophenyl)fluorene], 9,9-bis(4-hydroxy-3-bromophenyl)fluorene, 9,9 - bis(4-hydroxy-3-fluorophenyl)fluorene, 9,9-bis(4-hydroxy-3-methoxyphenyl) [9,9-bis(4-hydroxy-3-methoxyphenyl)fluorene], 9,9-bis(4-hydroxy-3,5-dimethylphenyl)anthracene [9,9-bis(4-hydroxy) -3,5-dimethylphenyl)fluorene], 9,9-bis(4-hydroxy-3,5-dichlorophenyl)fluorene, a compound such as 9,9-bis(4-hydroxy-3,5-dibromophenyl)fluorene.

The above-mentioned epihalohydrin may include, but is not limited to, 3-chloro- 1,2-propylene oxide (epichlorohydrin) or 3-bromo-1,2-epoxypropane (epibromohydrin).

The epoxy group-containing bisphenol quinone type compound obtained by reacting the bisphenol quinoid compound with the halogenated propylene oxide includes, but is not limited to: (1) a product manufactured by Nippon Steel Chemical Co., Ltd. : for example, ESF-300, etc.; (2) goods manufactured by Osaka Gas Co., Ltd.: for example, PG-100, EG-210, etc.; (3) manufactured by SMS Technology Co., Ltd. Goods such as SMS-F9PhPG, SMS-F9CrG, SMS-F914PG, and the like.

Next, the epoxy resin (c1) having at least two epoxy groups may have a structure represented by the following formula (VI):

Wherein R ⁶⁵ to R ⁷⁸ are independently selected from the group consisting of hydrogen, halogen, C ₁ to C ₈ alkyl and C ₆ to C ₁₅ aromatic groups; and n represents an integer of 0 to 10.

The epoxy resin (c1) having at least two epoxy groups of the above formula (VI) is, for example, a compound having a structure of the following formula (VI-1) and a halogenated propylene oxide in the presence of an alkali metal hydroxide. Take the reaction and get:

In the above formula (VI-1), R ⁶⁵ to R ⁷⁸ and n are as defined to R ⁶⁵ are the same as in ^78, and the formula (Vl) R n are as defined, which is not repeated herein.

Further, the epoxy resin (c1) having at least two epoxy groups of the above formula (VI) is, for example, a compound having a structure of the following formula (VI-2) and a phenol in the presence of an acid catalyst. After the condensation reaction, a compound having the structure of the formula (VI-1) is formed. Next, a dehydrohalogenation reaction is carried out by adding an excess of halogenated propylene oxide to obtain an epoxy resin (c1) having at least two epoxy groups as shown in the formula (VI):

In the above formula (VI-2), R ⁷⁹ and R ⁸⁰ are each the same or different hydrogen atom, a halogen atom, a C ₁ to C ₈ alkyl group or a C ₆ to C ₁₅ aromatic group; X ⁵ and X ⁶ They are the same or different halogen atoms, C ₁ to C ₆ alkyl groups or C ₁ to C ₆ alkoxy groups, respectively. Preferably, the above halogen atom may be, for example, chlorine or bromine, and the above alkyl group may be, for example, a methyl group, an ethyl group or a third butyl group, and the above alkoxy group may be, for example, a methoxy group or an ethoxy group.

Specific examples of the phenols include phenol, cresol, ethylphenol, n-propylphenol, isobutylphenol, and t-butyl phenol. (t-butylphenol), octylphenol, nonylphenol, xylenol, methylbutylphenol, di-t-butylphenol, vinylphenol (vinylphenol), propenylphenol, ethinylphenol, cyclopentylphenol, cyclohexylphenol or cyclohexylcresol. The above phenols can be generally used singly or in combination of two or more.

The compound having the structure of the above formula (VI-2) is used in an amount of 1 mol, and the phenol is used in an amount of from 0.5 mol to 20 mol, preferably from 2 mol to 15 mol.

Specific examples of the acid catalyst include hydrochloric acid, sulfuric acid, p-toluenesulfonic acid, oxalic acid, boron trifluoride, and anhydrous chloride anhydrous. ), zinc chloride or the like, wherein p-toluenesulfonic acid, sulfuric acid or hydrochloric acid is preferred. The above acid catalysts may be used singly or in combination of two or more.

Further, the amount of the acid catalyst used is not particularly limited, but the amount of the acid catalyst used is preferably 0.1 based on the amount of the compound having the structure of the formula (VI-2) used in an amount of 100% by weight (% by weight). Wt% to 30wt%.

The above condensation reaction can be carried out in the absence of a solvent or in the presence of an organic solvent. Specific examples of the organic solvent include toluene, xylene, and methyl isobutyl ketone. The above organic solvents may be used singly or in combination of two or more.

The total amount of the compound and the phenol used based on the structure of the formula (VI-2) is 100% by weight, and the above organic solvent is used in an amount of 50% by weight to 300% by weight, preferably 100% by weight to 250% by weight. Further, the above condensation reaction has an operation temperature of 40 ° C to 180 ° C, and the operation time of the condensation reaction is 1 hour to 8 hours.

After completion of the above condensation reaction, a neutralization treatment or a water washing treatment may be carried out. The above neutralization treatment is to adjust the pH of the solution after the reaction to pH 3 to pH 7, preferably pH 5 to pH 7. The water washing treatment may be carried out using a neutralizing agent, and the neutralizing agent is an alkaline substance, and specific examples thereof include alkali metal hydroxides such as sodium hydroxide and potassium hydroxide; and hydrogen; Alkaline earth metal hydroxides such as calcium hydroxide and magnesium hydroxide; diethylene triamine, triethylenetetramine, aniline, phenylenediamine (diethyltetramine) Organic amines such as phenylene diamine; and ammonia, sodium dihydrogen phosphate, and the like. The above washing treatment can be carried out by a known method, for example, in the solution after the reaction, An aqueous solution containing a neutralizing agent is added and extraction is repeated. After the neutralization treatment or the water washing treatment, the unreacted phenols and the solvent are distilled off by heating under reduced pressure, and concentrated to obtain a compound having the structure of the formula (VI-1).

Specific examples of the above halogenated propylene oxide include 3-chloro-1,2-epoxypropane and 3-bromo-1,2-epoxypropane (3). -bromo-1, 2-epoxypropane) or any combination of the above. An alkali metal hydroxide such as sodium hydroxide or potassium hydroxide may be added in advance or added to the reaction before the dehydrohalogenation reaction. The above dehydrohalogenation reaction has an operating temperature of from 20 ° C to 120 ° C and an operation time ranging from 1 hour to 10 hours.

In a specific example of the present invention, an aqueous solution of the alkali metal hydroxide added to the dehydrohalogenation reaction may be used. In this specific example, while the aqueous alkali metal hydroxide solution is continuously added to the dehydrohalogenation reaction system, water and halogenated propylene oxide can be continuously distilled off under reduced pressure or normal pressure, thereby separating and removing water. At the same time, the halogenated propylene oxide can be continuously refluxed into the reaction system.

Before the dehydrohalogenation reaction is carried out, tetramethyl ammonium chloride, tetramethyl ammonium bromide, trimethyl benzyl ammonium chloride or the like may be added. The ammonium salt is used as a catalyst, and reacted at 50 ° C to 150 ° C for 1 hour to 5 hours, and then an alkali metal hydroxide or an aqueous solution thereof is added thereto, and the reaction is carried out at a temperature of 20 ° C to 120 ° C for 1 hour. 10 hours for the dehydrohalogenation reaction.

The halogenated propylene oxide may be used in an amount of from 1 equivalent to 20 equivalents, preferably from 2 equivalents to 10 equivalents, based on 1 equivalent of the total hydroxyl group in the compound of the above formula (VI-1). The alkali metal hydroxide added in the above dehydrohalogenation reaction may be used in an amount of from 0.8 equivalents to 15 equivalents, wherein from 0.9 equivalents, based on 1 equivalent of the total hydroxyl group in the compound having the structure of the formula (VI-1). 11 equivalents are preferred.

In addition, in order to make the above dehydrohalogenation reaction proceed smoothly, in addition to being added In addition to an alcohol such as methanol or ethanol, a reaction may be carried out by adding an aprotic polar solvent such as dimethyl sulfone or dimethyl sulfoxide. In the case of using an alcohol, the alcohol may be used in an amount of 2% by weight to 20% by weight, preferably 4% by weight to 15% by weight based on the total amount of the above-mentioned halogenated propylene oxide being 100% by weight. In the case of using an aprotic polar solvent, the total amount of the aprotic polar solvent may be from 5 wt% to 100 wt%, wherein 10 wt% to 90 wt%, based on the total amount of the halogenated propylene oxide, is 100 wt%. good.

After completion of the dehydrohalogenation reaction, a water washing treatment can be selectively performed. Thereafter, the halogenated propylene oxide, the alcohol, and the aprotic polar solvent are removed by heating and decompression. The heating and depressing is performed, for example, in an environment having a temperature of 110 ° C to 250 ° C and a pressure of 1.3 kPa (10 mmHg) or less.

In order to prevent the formed epoxy resin from containing a hydrolyzable halogen, the solution after the dehydrohalogenation reaction may be added to a solvent such as toluene or methyl isobutyl ketone, and a base such as sodium hydroxide or potassium hydroxide may be added. The metal hydroxide aqueous solution is again subjected to a dehydrohalogenation reaction. In the dehydrohalogenation reaction, the total equivalent weight of the hydroxyl group in the compound having the structure of the above formula (VI-1) is 1 equivalent, and the alkali metal hydroxide is used in an amount of 0.01 mol to 0.3 mol, wherein 0.05 mol is used. The ear is preferably 0.2 mu. Further, the above dehydrohalogenation reaction has an operating temperature in the range of 50 ° C to 120 ° C and an operation time ranging from 0.5 hour to 2 hours.

After completion of the dehydrohalogenation reaction, the salts are removed by filtration, washing, and the like. Further, a solvent such as toluene or methyl isobutyl ketone may be distilled off by heating and decompression to obtain an epoxy resin having at least two epoxy groups as shown in the formula (VI) (c1). ). The epoxy resin (c1) having at least two epoxy groups of the above formula (VI) may include, but is not limited to, Nippon Chemicals (Nippon) such as the trade names NC-3000, NC-3000H, NC-3000S, and NC-3000P. A product manufactured by Kayaku Co. Ltd.).

The foregoing having at least one carboxylic acid group and at least one ethylenically unsaturated group The compound (c2) is, for example, selected from the group consisting of (1) to (3): (1) acrylic acid, methacrylic acid, 2-methacryloyloxyethylbutanedioic acid (2-methacryloyloxyethylbutanedioic acid) ), 2-methylpropenyloxybutyl succinic acid, 2-methylpropenyl oxyethyl adipate, 2-methylpropenyloxybutyl adipate, 2-methylpropenyloxyethyl Hexahydrophthalic acid, 2-methylpropenyloxyethyl maleic acid, 2-methylpropenyloxypropyl maleic acid, 2-methylpropenyloxybutyl maleic acid, 2-methyl Propylene oxypropyl succinic acid, 2-methyl propylene sulfoxypropyl adipate, 2-methyl propylene oxypropyl tetrahydrophthalic acid, 2-methyl propylene oxypropyl phthalate Formic acid, 2-methylpropenyloxybutylphthalic acid, or 2-methylpropenyloxybutylphthalic acid; (2) Hydroxyl-containing (meth) acrylate and dicarboxylic acid a compound obtained by reacting a compound, wherein the dicarboxylic acid compound includes, but is not limited to, adipic acid, succinic acid, maleic acid, phthalic acid; (3) a hydroxyl group-containing (meth) acrylate and a carboxylic acid anhydride Semi-esterification of compound (c3) The hydroxyl group-containing (meth) acrylate includes, but is not limited to, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate or pentaerythritol trimethacrylate. Further, the carboxylic anhydride compound described herein may be the same as the carboxylic anhydride compound (c3) contained in the mixture of the second alkali-soluble resin (C-2) described below, and thus will not be described herein.

The mixture of the above second alkali-soluble resin (C-2) may more optionally contain a carboxylic anhydride compound (c3) and/or an epoxy group-containing compound (c4). The above carboxylic anhydride compound (c3) may be selected from the group consisting of (1) to (2): (1) butanedioic anhydride, maleic anhydride, itaconic anhydride (Itaconic) Anhydride), phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride Anhydride), methyltetrahydrophthalic anhydride, methylhexahydrophthalic anhydride, methyl endo-methylene tetrahydrophthalic anhydride, chlorinated anhydride Chlorinic anhydride), dimethyl carboxylic acid anhydride (1,3-dioxoisobenzofuran-5-carboxylic anhydride) and the like; and (2) benzophenone tetracarboxylic dianhydride (abbreviated as benzophenone tetracarboxylic dianhydride) A quaternary carboxylic anhydride compound such as BTDA), bisbenzenetetracarboxylic dianhydride or diphenyl ether tetracarboxylic dianhydride.

The epoxy group-containing compound (c4) is, for example, selected from the group consisting of glycidyl methacrylate, 3,4-epoxycyclohexyl methacrylate, an unsaturated group-containing glycidyl ether compound, and an epoxy group-containing compound. A group of unsaturated compounds or any combination of the above. The unsaturated group-containing glycidyl ether compound includes, but is not limited to, the trade names Denacol EX-111, EX-121 Denacol, Denacol EX-141, Denacol EX-145, Denacol EX-146, Denacol EX-171, and Denacol EX-192. Compound (the above is a product of Nagase Chemical Industry Co., Ltd.).

The second alkali-soluble resin (C-2) may be an epoxy resin (c1) having at least two epoxy groups of the formula (V) and a compound having at least one carboxylic acid group and at least one ethylenically unsaturated group (c2) The polymerization reaction is carried out to form a hydroxyl group-containing reaction product, followed by addition of a carboxylic anhydride compound (c3) to carry out a reaction. The equivalent weight of the hydroxyl group-based reaction product is 1 equivalent, and the equivalent weight of the acid anhydride group contained in the carboxylic anhydride compound (c3) is preferably from 0.4 equivalents to 1 equivalent, more preferably from 0.75 equivalents to 1 equivalent. When a plurality of carboxylic anhydride compounds (c3) are used, they may be added sequentially or simultaneously in the reaction. When a dicarboxylic anhydride compound and a tetracarboxylic anhydride compound are used as the carboxylic anhydride compound (c3), the molar ratio of the dicarboxylic anhydride compound and the tetracarboxylic anhydride compound is preferably from 1/99 to 90/10, more preferably It is from 5/95 to 80/20. Further, the operating temperature range of the above reaction is, for example, in the range of 50 ° C to 130 ° C.

The second alkali-soluble resin (C-2) may have at least two of formula (VI) The epoxy group epoxy resin (c1) is reacted with a compound (c2) having at least one carboxylic acid group and at least one ethylenically unsaturated group to form a hydroxyl group-containing reaction product, followed by addition of a carboxylic anhydride compound ( The c3) and/or the epoxy group-containing compound (c4) is obtained by a polymerization reaction. The epoxy group (c1) having at least two epoxy groups has a total equivalent weight of 1 equivalent based on the formula (VI), and the above compound having at least one carboxylic acid group and at least one ethylenically unsaturated group (c2) The acid value equivalent is preferably from 0.8 equivalents to 1.5 equivalents, more preferably from 0.9 equivalents to 1.1 equivalents. The total amount of hydroxyl groups based on the above hydroxyl group-containing reaction product is 100 mol% (mol%), and the carboxylic anhydride compound (c3) is preferably used in an amount of 10 mol% to 100 mol%, more preferably 20 mol%. % to 100% by mole, particularly preferably 30% by mole to 100% by mole.

In the preparation of the second alkali-soluble resin (C-2), in order to accelerate the reaction, a basic compound is usually added as a reaction catalyst to the reaction solution. The above reaction catalysts may be used singly or in combination, and the above reaction catalysts include, but are not limited to, triphenyl phosphine, triphenyl stibine, triethylamine, triethanolamine. , tetramethylammonium chloride, benzyltriethylammonium chloride, and the like. The use amount of the reaction catalyst is based on the total amount of the epoxy resin (c1) having at least two epoxy groups and the compound (c2) having at least one carboxylic acid group and at least one ethylenically unsaturated group in an amount of 100 parts by weight. The amount is preferably from 0.01 part by weight to 10 parts by weight, more preferably from 0.3 part by weight to 5 parts by weight.

Further, in order to control the degree of polymerization, a polymerization inhibitor is usually added to the reaction solution. The above polymerization inhibitor may include, but is not limited to, methoxyphenol, methylhydroquinone, hydroquinone, 2,6-di-t-butyl-p-cresol (2,6-di) -t-butyl-p-cresol) or phenothiazine. In general, the above polymerization inhibitors may be used singly or in combination of two or more. The total amount of use of the epoxy resin (c1) having at least two epoxy groups and the compound (c2) having at least one carboxylic acid group and at least one ethylenically unsaturated group is 100 The polymerization inhibitor is preferably used in an amount of from 0.01 part by weight to 10 parts by weight, more preferably from 0.1 part by weight to 5 parts by weight, per part by weight.

In the preparation of the second alkali-soluble resin (C-2), a polymerization solvent can be used as necessary. Specific examples of the polymerization reaction solvent include alcohol compounds such as ethanol, propanol, isopropanol, butanol, isobutanol, 2-butanol, hexanol or ethylene glycol; methyl ethyl ketone or cyclohexanone; Ketone compounds; aromatic hydrocarbon compounds such as toluene or xylene; celecin compounds such as cellosolve or butyl cellosolve; carbitol or butyl carbene a carbaryl compound such as butyl carbitol; a propylene glycol alkyl ether compound such as propylene glycol monomethyl ether; and a polypropylene glycol alkyl ether such as di(propylene glycol) methyl ether [poly(propylene glycol) alkyl ether] compound; acetate such as ethyl acetate, butyl acetate, ethylene glycol monoethyl ether acetate or propylene glycol methyl ether acetate a compound; an alkyl lactate compound such as ethyl lactate or butyl lactate; or a dialkyl glycol ether. The above polymerization solvent can be generally used singly or in combination of two or more. Further, the acid value of the above first alkali-soluble resin (C-1) is preferably from 50 mgKOH/g to 200 mgKOH/g, more preferably from 60 mgKOH/g to 150 mgKOH/g.

Further, the second alkali-soluble resin (C-2) has a polystyrene-equivalent number average molecular weight of from 800 to 8,000, more preferably from 1,000 to 6,000, as measured by Gel Permeation Chromatography (GPC). .

In a specific example of the present invention, the total amount of the alkali-soluble resin (C) used is 100 parts by weight, and the second alkali-soluble resin (C-2) is used in an amount of 0 parts by weight to 95 parts by weight; preferably. It is 20 parts by weight to 93 parts by weight; more preferably 40 parts by weight to 90 parts by weight. When the second alkali-soluble resin (C-2) is used, the pigment dispersibility of the pixel layer produced by the blue photosensitive resin composition is preferred.

Preferably, the alkali-soluble resin (C) according to the present invention may further comprise a third alkali-soluble resin (C-3) containing one or more carboxylic acid groups. The ethylenically unsaturated monomer is obtained by copolymerization with other copolymerizable ethylenically unsaturated monomers. Preferably, the second alkali-soluble resin (C-3) is from 50 parts by weight to 95 parts by weight of the ethylenically unsaturated monomer having one or more carboxylic acid groups, based on 100 parts by weight of the monomer for copolymerization. It is obtained by copolymerizing 5 parts by weight to 50 parts by weight of other copolymerizable ethylenically unsaturated monomers.

The ethylenically unsaturated monomer having one or more carboxylic acid groups may be used singly or in combination, and the carboxylic acid group-containing ethylenically unsaturated monomer includes, but is not limited to, methacrylic acid (MAA). ), crotonic acid, α-chloroacrylic acid, ethacrylic acid, cinnamic acid, 2-propenyl ethoxylated succinate, or 2-methacryloyloxyethyl succinate monoester , referred to as HOMS), unsaturated monocarboxylic acids; maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, etc. a class of unsaturated polycarboxylic acids (anhydrides) having three or more carboxylic acid groups. Preferably, the carboxylic acid group-containing ethylenically unsaturated monomer is selected from the group consisting of acrylic acid, methacrylic acid, 2-propenyl ethoxy succinate, or 2-methyl propylene ethoxy ethoxylate Acid ester. More preferably, the carboxylic acid group-containing ethylenically unsaturated monomer is selected from 2-propenyl ethoxy succinate or 2-methyl propylene ethoxy succinate to enhance the pigment. Dispersibility and increase development speed and reduce residue.

The other copolymerizable ethylenically unsaturated monomers may be used singly or in combination, and the other copolymerizable ethylenically unsaturated monomers include, but are not limited to, styrene (SM), α-methyl styrene. , an aromatic vinyl compound such as vinyl toluene, p-chlorostyrene, methoxystyrene, etc.; N-phenylmaleimide (PMI), nitrogen-o-hydroxyphenyl Malay Yttrium imine, nitrogen-m-hydroxyphenyl maleimide, nitrogen-p-hydroxyphenyl maleimide, nitrogen-o-methylphenyl horse Iridium imine, nitrogen-m-methylphenylmaleimide, nitrogen-p-methylphenylmaleimide, nitrogen-o-methoxyphenylmaleimide, nitrogen- M-mercaptoimine of m-methoxyphenylmaleimide, nitrogen-p-methoxyphenylmaleimide, nitrogen-cyclohexylmaleimide, etc.; methyl acrylate ( Methyl acrylate (MA), methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, butyl acrylate Ester, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, second butyl acrylate, second butyl methacrylate, third butyl acrylate, third butyl methacrylate, acrylic acid 2-hydroxyethyl ester, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, acrylic acid 2- Hydroxybutyl ester, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, A 4-hydroxybutyl acrylate, allyl acrylate, allyl methacrylate, benzyl methacrylate, benzyl methacrylate (BzMA), phenyl acrylate, phenyl methacrylate, acrylic acid Triethylene glycol methoxylate, triethylene glycol methacrylate methacrylate, dodecyl methacrylate, tetradecyl methacrylate, cetyl methacrylate, methacrylic acid An octaalkyl ester, an eicosyl methacrylate, a behenyl methacrylate, an unsaturated carboxylic acid ester such as dicyclopentenyloxyethyl acrylate (DCPOA); Nitrogen, nitrogen-dimethylaminoethyl ester, methacrylic acid-nitrogen, nitrogen-dimethylaminoethyl ester, acrylic acid-nitrogen, nitrogen-diethylaminopropyl methacrylate, methacrylic acid-nitrogen, nitrogen- Dimethylaminopropyl acrylate, nitrogen acrylate, nitrogen-dibutylaminopropyl propyl ester, nitrogen-isobutylaminoethyl methacrylate; glycidyl acrylate, glycidyl methacrylate Equivalent carboxylic acid glycidyl esters; vinyl acetate, vinyl propionate, Vinyl carboxylates such as vinyl acetate; unsaturated ethers such as vinyl methyl ether, vinyl ethyl ether, allyl epoxypropyl ether, methallyl epoxypropyl ether; acrylonitrile, A Nitrile vinyl compound such as acrylonitrile, α-chloroacrylonitrile, vinyl cyanide, etc.; acrylamide, A Alkyl amide, α-chloropropenylamine, nitrogen-hydroxyethyl acrylamide, nitrogen-hydroxyethyl methacrylamide, etc., unsaturated decylamine; 1,3-butadiene, isoprene An aliphatic conjugated diene such as chlorinated butadiene.

Preferably, the other copolymerizable ethylenically unsaturated monomer is selected from the group consisting of styrene, nitrogen-phenyl maleimide, methyl acrylate, methyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, benzyl acrylate, benzyl methacrylate, dicyclopentenyl acrylate, or combinations thereof.

In the preparation of the third alkali-soluble resin (C-3), a solvent may be used, which may be used singly or in combination, and the solvent includes, but is not limited to, ethylene glycol methyl ether, ethylene glycol diethyl ether, diethylene glycol methyl ether. , diethylene glycol ethyl ether, diethylene glycol n-propyl ether, diethylene glycol n-butyl ether, triethylene glycol methyl ether, triethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, one (poly)alkylene glycol monoalkyl ethers such as dipropylene glycol n-propyl ether, dipropylene glycol n-butyl ether, tripropylene glycol methyl ether, and tripropylene glycol ethyl ether; ethylene glycol methyl ether acetate, (poly)alkylene glycol monoalkyl ether acetates such as ethylene glycol ethyl ether acetate, propylene glycol methyl ether acetate (PGMEA), propylene glycol ethyl ether acetate, etc.; diglyme , other ethers such as diethylene glycol methyl ether, diethylene glycol diethyl ether, tetrahydrofuran; ketones such as methyl ethyl ketone, cyclohexanone, 2-heptanone, 3-heptanone; methyl 2-hydroxypropionate An alkyl lactate such as ethyl 2-hydroxypropionate; methyl 2-hydroxy-2-methylpropionate, 2-hydroxy-2- Ethyl propyl propionate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate , referred to as EEP), ethyl ethoxylate, ethyl hydroxyacetate, methyl 2-hydroxy-3-methylbutanoate, 3-methyl-3-methoxybutyl acetate, 3-methyl 3-methoxybutylpropionate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl acetate, isoamyl acetate, n-butyl propionate Ester, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate, methyl acetate, ethyl acetate Ethyl ester, 2-methoxybutyl Other esters such as ethyl acetate; aromatic hydrocarbons such as toluene and xylene; nitrogen-methylpyrrolidone, nitrogen, nitrogen-dimethylformamide, or nitrogen, nitrogen-dimethylacetamide Such as guanamines and the like. Preferably, the solvent is selected from the group consisting of propylene glycol methyl ether acetate, ethyl 3-ethoxypropionate, or combinations thereof. The (poly)alkylene glycol monoalkyl ethers are referred to as alkylene glycol monoalkyl ethers or polyalkylene glycol monoalkyl ethers. The (poly)alkylene glycol monoalkyl ether acetates are referred to as alkylene glycol monoalkyl ether acetates or polyalkylene glycol monoalkyl ether acetates.

The initiator used in the preparation of the third alkali-soluble resin (C-3) is generally a radical polymerization initiator, specifically, for example, 2,2'-azobisisobutyronitrile, 2,2'-couple Nitrogen bis(2,4-dimethylvaleronitrile), 2,2'-azobis(4-methoxy-2,4-dimethylvaleronitrile), 2,2'-azobis-2 An azo compound such as 2,2'-azobis-2-methyl butyronitrile (abbreviated as AMBN); or a peroxy compound such as dibenzoguanidine peroxide.

Further, the third alkali-soluble resin (C-3) preferably has a polystyrene-equivalent number average molecular weight of 3,000 to 30,000, more preferably 5,000 to 25,000, as measured by a gel permeation chromatography (GPC). .

The ethylenically unsaturated group-containing compound (D) of the present invention is a compound (D-1) selected from a first ethylenically unsaturated group, a second ethylenically unsaturated group-containing compound (D-2) or the like. One of the combinations.

The first ethylenically unsaturated group-containing compound (D-1) is a (meth) acrylate-based compound obtained by reacting a caprolactone-modified polyol with (meth)acrylic acid.

The caprolactone-modified polyol is obtained by reacting the caprolactone with a polyol having four or more functional groups, wherein the caprolactone may be γ-caprolactone or δ-caprolactone. Or ε-caprolactone, and preferably ε-caprolactone. The polyol having four or more functional groups may be pentaerythritol, ditrimethylolpropane or dipentaerythritol. Preferably, the content of the caprolactone ranges from 1 to 12 moles based on the content of the polyol having 4 functional groups or more.

The first ethylenically unsaturated group compound (D-1) is selected from the group consisting of pentaerythritol The modification of the tetrakis (meth) acrylate compound modified by the alcohol caprolactone, the tetrakis (meth) acrylate compound modified by ditrimethylolpropane caprolactone, and the dipentaerythritol caprolactone (A An acrylate compound or the like, wherein the dipentaerythritol caprolactone modified poly(meth) acrylate compound may be dipentaerythritol caprolactone modified di(meth) acrylate compound, dipentaerythritol Caprolactone modified tris(meth)acrylate compound, dipentaerythritol caprolactone modified tetra(meth)acrylate compound, dipentaerythritol caprolactone modified penta(meth)acrylate A hexa (meth) acrylate compound modified with a compound or dipentaerythritol caprolactone.

The above first ethylenically unsaturated group-containing compound (D-1) has a structure represented by the formula (VII):

Wherein: Z ¹ and Z ² each independently represent hydrogen or methyl; t represents an integer from 1 to 2; and b represents an integer from 1 to 6; c represents from 0 to 5 to an integer, wherein the sum of b and c is 2 An integer of up to 6.

The first ethylenically unsaturated group compound (D-1) is used in an amount of 10 parts by weight to 50 parts by weight, preferably 13 parts by weight, based on 100 parts by weight of the total amount of the alkali-soluble resin (C). To 45 parts by weight, more preferably 15 parts by weight to 40 parts by weight. When the first ethylenically unsaturated group-containing compound (D-1) is used, the ITO sputtering suitability of the pixel layer obtained from the blue photosensitive resin composition is preferable.

The second ethylenically unsaturated group-containing compound (D-2) has a functional group represented by the formula (IX):

In the formula (IX), Z ³ represents hydrogen or a methyl group.

The second ethylenically unsaturated group-containing compound (D-2) may be selected from the group consisting of acrylamide, (meth) propylene morpholine, (meth) acrylate-7-amino-3,7-dimethyl octyl Ester, isobutoxymethyl (meth) acrylamide, isobornyl oxyethyl (meth) acrylate, isobornyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, Ethyl diglycol (meth) acrylate, third octyl (meth) acrylamide, diacetone (meth) acrylamide, dimethyl amino (meth) acrylate, (meth) acrylate Dialkyl ester, dicyclopentenyloxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, nitrogen, nitrogen-dimethyl(meth)acrylamide, (meth)acrylic acid Chlorophenyl ester, 2-tetrachlorophenoxyethyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, tetrabromophenyl (meth)acrylate,-2-tetrabromo(meth)acrylate Phenoxyethyl ester, 2-trichlorophenoxyethyl (meth)acrylate, tribromophenyl (meth)acrylate, 2-tribromophenoxyethyl (meth)acrylate, (A) 2-hydroxyethyl acrylate, 2-hydroxypropyl (meth)acrylate, vinyl caprolactam, nitrogen-vinyl leather Alkanone, phenoxyethyl (meth)acrylate, pentachlorophenyl (meth)acrylate, pentabromophenyl (meth)acrylate, polyethylene glycol mono(meth)acrylate, poly (a) Base) propylene glycol acrylate, borneol (meth)acrylate, ethylene glycol di(meth)acrylate, dicyclopentenyl di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraganyl Alcohol di(meth)acrylate, tris(2-hydroxyethyl)isocyanate di(meth)acrylate, tris(2-hydroxyethyl)isocyanate tri(meth)acrylate, caprolactone modified three (2-Hydroxyethyl)isocyanate tri(meth)acrylate, trimethylolpropyl tri(meth)acrylate, ethylene oxide (hereinafter referred to as EO) modified tris(meth)acrylic acid Propyl propyl acrylate, propylene oxide (hereinafter referred to as PO) modified tris (meth) acrylate trimethylol propyl Ester, neopentyl glycol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, pentaerythritol tris(methyl) Acrylate, pentaerythritol tetra(meth)acrylate, polyester di(meth)acrylate, polyethylene glycol di(meth)acrylate, dipentaerythritol hexa(meth)acrylate, dipentaerythritol penta (methyl) Acrylate (trade name: TO-1382, manufactured by Japan East Asia Synthetic Co., Ltd.), dipentaerythritol tetra(meth)acrylate, caprolactone-modified dipentaerythritol hexa(meth)acrylate, EO modification Dipentaerythritol hexaacrylate, caprolactone modified dipentaerythritol penta (meth) acrylate, tetrakis (meth) acrylate ditrimethylol propyl ester, EO modified bisphenol A di(meth) acrylate Ester, PO modified bisphenol A di(meth) acrylate, EO modified hydrogenated bisphenol A di(meth) acrylate, PO modified hydrogenated bisphenol A di(meth) acrylate, PO Modified triglyceride, EO modified bisphenol F di(meth) acrylate, phenolic polyglycidyl ether (meth) acrylate, trishydroxy methacrylate Propyl ester, EO modified trimethylol propyl triacrylate, PO modified trimethylol propyl triacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol hexaacrylate, dipentaerythritol pentaacrylate Dipentaerythritol tetraacrylate, caprolactone modified dipentaerythritol hexaacrylate, ditrimethylolpropyl methacrylate.

Preferably, the second ethylenically unsaturated group compound (D-2) is selected from trimethylol propyl triacrylate, EO modified trimethylol propyl triacrylate, and PO modified three. Trimethylolpropyl acrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol hexaacrylate, dipentaerythritol pentaacrylate, dipentaerythritol tetraacrylate, caprolactone modified dipentaerythritol hexaacrylate, tetraacrylic acid Ditrimethylolpropyl propyl ester, PO-modified triglyceride, a product of the trade name TO-1382 manufactured by Japan East Asia Synthetic Co., Ltd., or a combination thereof.

The second ethylenically unsaturated group compound (D-2) is used in an amount of 40 parts by weight to 400 parts by weight, preferably 45 parts by weight, based on 100 parts by weight of the total amount of the alkali-soluble resin (C). It is preferably from 50 parts by weight to 300 parts by weight to 350 parts by weight.

The ethylenically unsaturated group-based compound (D) is used in an amount of 50 parts by weight to 450 parts by weight, preferably 55 parts by weight to 400 parts by weight, based on 100 parts by weight of the total amount of the alkali-soluble resin (C). More preferably, it is 60 parts by weight to 350 parts by weight.

The photoinitiator (E) according to the invention comprises a photoinitiator (E-1) having the structure of formula (VIII):

Wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, C ₁ -C ₂₀ alkyl, , COR ₁₆ , OR ₁₇ , halogen, NO ₂ or Or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are each independently Substituted C ₂ -C ₁₀ alkenyl or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are independently of each other -(CH ₂ ) _P -Y-(CH ₂ ) _q -; or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R _{8 is} independent of each other However, the condition is at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R _{8 ; R 9, R 10, R} 11 and R ₁₂ are independently hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of each other the following groups: halo, Phenyl, CN, OH, SH, C ₁ -C ₄ -alkoxy, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ Independent of each other, an unsubstituted phenyl group or a phenyl group substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, CN, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₉ And R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, halogen, CN, OR ₁₇ , SR ₁₈ , SOR ₁₈ , SO ₂ R ₁₈ or NR ₁₉ R ₂₀ , wherein the substituents OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ optionally forming a 5- or 6-membered ring with a carbon atom in the naphthyl ring via the group R ₁₇ , R ₁₈ , R ₁₉ and/or R ₂₀ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ independently of each other for , COR ₁₆ or NO ₂ ; Y series O, S, NR ₂₆ or direct bond; p is an integer 0, 1, 2 or 3; q is an integer 1, 2 or 3; X is CO or direct bond; R ₁₃ is C _{a 1-} C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , COOR ₁₇ , OR ₁₇ , SR ₁₈ , CONR ₁₉ R ₂₀ , NR ₁₉ R ₂₀ , PO (OC _k H _2k+1 ) ₂ or Or R ₁₃ is a C ₂ -C ₂₀ alkyl group in which one or more of O, S, SO, SO ₂ , NR ₂₆ or CO, or a C ₂ -C ₁₂ alkenyl group, which has no inter Or a plurality of O, CO or NR ₂₆ wherein the C ₂ -C ₂₀ alkyl group and the unintervening or interstitial C ₂ -C ₁₂ alkenyl group are unsubstituted or substituted by one or more halogens; or R _{a 13-} series C ₄ -C ₈ cycloalkenyl group, a C ₂ -C ₁₂ alkynyl group or a C ₃ -C ₁₀ cycloalkyl group having one or more O, S, CO or NR ₂₆ without inter or hetero-hetero; or R ₁₃ a phenyl or naphthyl group, each of which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , _{, COR 16, CN, NO 2} , halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, interrupted by one or more O, S, CO or NR C ₂₆ of ₂ -C ₂₀ alkyl group; or via their respective C ₃ -C ₁₀ cycloalkyl, or interrupted by one or more O, S, CO or NR ₂₆ of the C ₃ -C ₁₀ cycloalkyl; based integer k 1 to 10; R ₁₄ type hydrogen, C ₃ -C ₈ cycloalkyl, C ₂ -C ₅ alkenyl, C ₁ -C ₂₀ alkoxy or C ₁ -C ₂₀ alkyl, unsubstituted or via one or more halogens, phenyl, C ₁ - C ₂₀ alkylphenyl or CN substituted; or R ₁₄ phenyl or naphthyl, each unsubstituted or substituted by one or more of the following groups: C ₁ -C ₆ alkyl, C ₁ -C ₄ haloalkane a group, a halogen, CN, OR ₁₇ , SR ₁₈ and/or NR ₁₉ R ₂₀ ; or R ₁₄ C ₃ -C ₂₀ heteroaryl, C ₁ -C ₈ alkoxy, benzyloxy or phenoxy, Benzyloxy and phenoxy are unsubstituted or substituted by one or more C ₁ -C ₆ alkyl, C ₁ -C ₄ haloalkyl and/or halogen; R ₁₅ C ₆ -C ₂₀ aryl or C ₃ a -C ₂₀ heteroaryl group, each unsubstituted or substituted by one or more of the following groups: phenyl, halo, C ₁ -C ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , SO-C ₁ -C ₁₀ alkyl, SO ₂ -C ₁ -C ₁₀ alkyl, inter-hetero- or one or more C ₂ -C ₂₀ alkyl groups of O, S or NR ₂₆ ; or each of C ₁ - C ₂₀ alkyl substituted, the C ₁ -C ₂₀ alkyl group is unsubstituted or substituted with one or more of the following groups: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ hydrogen, C ₂ - a C ₁₂ alkenyl group, a C ₃ -C ₈ cycloalkyl group having one or more O, CO or NR ₂₆ unsubstituted or inter-hetero; or an R ₁₅ -C ₁ -C ₂₀ alkyl group which is unsubstituted or subjected to one or Substituted by a plurality of groups: halogen, OR ₁₇ , SR ₁₈ , C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ -C ₂₀ heteroaryl Oxycarbonyl group, NR ₁₉ R ₂₀ , COOR ₁₇ , CONR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , , Or a phenyl group; or the C ₁ -C ₂₀ alkyl group substituted by a phenyl group, which is halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ Substituting; or R ₁₅ is a C ₂ -C ₂₀ alkyl group, interspersed with one or more O, SO or SO ₂ , and the interstitial C ₂ -C ₂₀ alkyl group is unsubstituted or substituted by one or more of the following groups Group substitution: halogen, OR ₁₇ , COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl or phenyl substituted by OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ C ₂ -C ₂₀ alkanoyl or benzoyl A thiol group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is unsubstituted or a naphthylmethyl group substituted by one or more OR ₁₇ or a C ₃ -C ₁₄ heteroarylcarbonyl group; or an R ₁₅ C ₂ -C ₁₂ alkoxycarbonyl group, which has no or a heterogeneous one or more O And the inter- or non-hetero-C ₂ -C ₁₂ alkoxycarbonyl group is unsubstituted or substituted with one or more hydroxy groups; or the R ₁₅ phenoxycarbonyl group is unsubstituted or one or more of the following Group substitution: C ₁ -C ₆ alkyl, halogen, C ₁ -C ₄ haloalkyl, phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is CN, CONR ₁₉ R ₂₀ , NO ₂ , C ₁ -C ₄ haloalkyl, S(O) _m -C ₁ -C ₆ alkyl, unsubstituted or via C ₁ -C ₁₂ alkyl or SO ₂ -C ₁ -C ₆ alkyl substituted S(O) _m -phenyl; or R ₁₅ -based SO ₂ O-phenyl, unsubstituted or C ₁ -C ₁₂ alkane Substituent; or a diphenylphosphonium or di(C ₁ -C ₄ alkoxy)-phosphonium; m system 1 or 2; R' ₁₄ has one of the meanings given for R ₁₄ ; R _'15 R ₁₅ having the meanings Suo were given for one; X ₁ Department of O, S, SO, or SO _2; X _2-based O, CO, S or a direct bond; R ₁₆ C ₆ -C ₂₀ aryl-based group Or a C ₃ -C ₂₀ heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or interrupted by one or more O, S or NR C ₂₆ of ₁ -C ₂₀ alkyl group; or each with one or more C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl group which Substituted or substituted with one or more of the following groups: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ Aryloxycarbonyl, C ₃ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₆ is hydrogen, C ₁ -C ₂₀ alkyl, the C ₁ -C ₂₀ alkyl group is unsubstituted or substituted with one or more of the following groups: halogen, phenyl , OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₁₆ C ₂ -C ₁₂ alkyl, one or more O, S or NR ₂₆ ; or R ₁₆ (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₁₂ Alkenyl or C ₃ -C ₈ cycloalkyl; or R ₁₆ is phenyl substituted by SR ₁₈ wherein the group R ₁₈ represents a phenyl or naphthyl ring bonded to the oxazole moiety to which COR ₁₆ is attached Direct bond; n is 1 to 20; R ₁₇ is hydrogen, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with one or more of the following groups: halogen , OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C _4- alkyl), OCO)-(C ₂ -C ₄ )alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C ₁ -C ₄ alkyl), C ₃ -C ₂₀ Cycloalkyl, SO ₂ -(C ₁ -C ₄ haloalkyl), O(C ₁ - C ₄ haloalkyl) or a C ₃ -C ₂₀ cycloalkyl group having one or more O; or an R ₁₇ C ₂ -C ₂₀ alkyl group having one or more O, S or NR _{26 in between} ; or R ₁₇ (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₁ -C ₈ alkanoyl, C ₂ -C ₁₂ olefin a C ₃ -C ₆ olefinic group or a C ₃ -C ₂₀ cycloalkyl group having one or more O, S, CO or NR ₂₆ undoped or inter-hetero; or R ₁₇ C ₁ -C ₈ alkyl- a C ₃ -C ₁₀ cycloalkyl group which has no or a hetero or one or more O; or an R ₁₇ benzylidene group which is unsubstituted or has one or more C ₁ -C ₆ alkyl groups, halogens, OH or C ₁ -C ₃ alkoxy substituted; or R ₁₇ is phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or substituted by one or more of the following groups: halogen, OH , C ₁ -C ₁₂ alkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl-C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, benzene Thiothio, N(C ₁ -C ₁₂ alkyl) ₂ , diphenyl-amine or Or R ₁₇ forms a bond to have a group thereon or a direct bond of one carbon atom of a phenyl or naphthyl ring; R ₁₈ is hydrogen, C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl or phenyl-C ₁ -C ₃ alkyl, wherein C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl or phenyl-C ₁ -C ₃ alkyl without inter or hetero-have one or more O, S, CO, NR ₂₆ or COOR ₁₇ ; or R ₁₈ Is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ ( CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl Or (CO)OR ₁₇ ; or R ₁₈ C ₂ -C ₂₀ alkyl with one or more O, S, CO, NR ₂₆ or COOR _{17 in between} ; or R ₁₈ (CH ₂ CH ₂ O) _n H , (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₈ alkanoyl or C ₃ -C ₆ alkenyl; or R ₁₈ benzhydryl, It is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OH, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio; or R ₁₈ Phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or substituted by one or more of the following groups: halogen, C ₁ -C ₁₂ alkyl, C ₁ -C ₄ Haloalkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl-C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N ( C ₁ -C ₁₂ alkyl) ₂ , diphenylamino, (CO)O(C ₁ -C ₈ alkyl), (CO)-C ₁ -C ₈ alkyl, (CO)N (C ₁ - C ₈ alkyl) ₂ or R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₂ -C ₁₀ alkoxyalkyl, C ₂ -C ₅ alkenyl, C ₃ - C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₈ alkanoyl, C ₁ -C ₈ alkenyloxy, C ₃ -C ₁₂ alkenyl, SO ₂ -( C ₁ -C ₄ haloalkyl) or benzylidene; or R ₁₉ and R ₂₀ are phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or via one or more of the following groups Substituted: halogen, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, C ₁ -C ₁₂ alkyl, benzhydryl or C ₁ -C ₁₂ alkoxy; or R ₁₉ and R ₂₀ The attached N atoms together form a 5- or 6-membered saturated or unsaturated ring which is not intermixed or interspersed with O, S or NR ₁₇ , and the 5 or 6 member saturated or unsaturated ring is unsubstituted or Or substituted with a plurality of groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkoxy, =0, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , NO ₂ , halogen, C ₁ -C ₄ -haloalkyl, CN, phenyl, Or a C ₃ -C ₂₀ cycloalkyl group, the C ₃ -C ₂₀ cycloalkyl group having no or hetero or one or more O, S, CO or NR ₁₇ ; or R ₁₉ and R ₂₀ and the N atom to which it is attached Together forming a heteroaromatic ring system, the ring system is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, =O, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , , Halogen, NO _2, CN, phenyl or C ₃ -C ₂₀ cycloalkyl group, the C ₃ -C ₂₀ cycloalkyl interrupted or not interrupted with one or more O, S, CO or NR _17; R ₂₁ and R ₂₂ independently of one another hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₃ -C ₁₀ cycloalkyl or phenyl; or R ₂₁ and R _{22 together} with the attached N atom Forming a 5- or 6-membered saturated or unsaturated ring without interstitial or interstitial with O, S or NR ₂₆ , and the 5 or 6 member saturated or unsaturated ring is not fused or the 5 or 6 members are saturated or not The saturated ring system is fused to a benzene ring; R ₂₃ is hydrogen, OH, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, intervening one or more O, CO or NR ₂₆ C ₂ -C ₂₀ alkane a C ₃ -C ₂₀ cycloalkyl group having an O, S, CO or NR ₂₆ or an R ₂₃ phenyl group, a naphthyl group, a phenyl-C ₁ -C ₄ alkyl group, OR ₁₇ , SR ₁₈ or NR ₂₁ R ₂₂ ; R ₂₄ system (CO)OR ₁₇ , CONR ₁₉ R ₂₀ , (CO)R ₁₇ ; or R ₂₄ having one of the meanings given for R ₁₉ and R ₂₀ ; R ₂₅ system COOR ₁₇ , CONR ₁₉ R ₂₀ , (CO)R ₁₇ ; or R ₂₅ have one of the meanings given for R ₁₇ ; R ₂₆ is hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl ,between a C ₂ -C ₂₀ alkyl group having one or more O or CO; or a phenyl-C ₁ -C ₄ alkyl group, a C ₃ -C ₈ naphthene having no or hetero or one or more O or CO Or a group (CO)R ₁₉ ; or a phenyl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, halogen, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or But the condition is that at least one group is present in the molecule or

The photoinitiator (E-1) having the structure represented by the formula (VIII) is characterized in that it contains one or more annelated unsaturated rings on the carbazole moiety. In other words, at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈

In one embodiment, having the formula (VIII) as shown in the optical configuration of initiator (E-1), the C ₁ -C ₂₀ straight or branched alkyl chain line and lines (e.g.) C ₁ -C ₁₈ -, C ₁ -C ₄ -, C ₁ -C ₁₂ -, C ₁ -C ₈ -, C ₁ -C ₈ - or C ₁ -C ₄ alkyl or C ₄ -C ₁₂ - or C ₄ -C ₈ alkyl. Examples are methyl, ethyl, propyl, isopropyl, n-butyl, t-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, 2,4,4-trimethyl Amyl, 2-ethylhexyl, octyl, decyl, decyl, dodecyl, tetradecyl, fifteen, hexadecyl, octadecyl and decyl. The C ₁ -C ₆ alkyl group has the same meaning as given above for the C ₁ -C ₂₀ alkyl group and has the highest corresponding number of C atoms.

The unsubstituted or substituted C ₁ -C ₂₀ alkyl group containing one or more CC multiple bonds means an alkenyl group as explained below.

The C ₁ -C ₄ haloalkyl group as defined below, based substituted with halogen or as hereinbefore defined C ₁ -C ₄ alkyl. The alkyl group is, for example, mono- or polyhalogenated until all H-atoms are replaced by halogen. It is, for example, C _n H _x Hal _y , wherein x+y=2n+1 and Hal is halogen, preferably F. Specific examples are chloromethyl, trichloromethyl, trifluoromethyl or 2-bromopropyl, especially trifluoromethyl or trichloromethyl. C ₂ -C ₄ hydroxyalkyl means a C ₂ -C ₄ alkyl group substituted with one or two O atoms. The alkyl group is straight or branched. Examples are 2-hydroxyethyl, 1-hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 1-hydroxybutyl, 4-hydroxybutyl, 2-hydroxybutyl, 3-hydroxybutyl, 2,3-dihydroxypropyl or 2,4-dihydroxybutyl. C ₂ -C ₁₀ alkoxyalkyl lines interrupted by one O C ₂ -C ₁₀ alkyl group atoms. The C ₂ -C ₁₀ alkyl group has the same meaning as given above for the C ₁ -C ₂₀ alkyl group and has the highest corresponding number of C atoms. Examples are methoxymethyl, methoxyethyl, methoxypropyl, ethoxymethyl, ethoxyethyl, ethoxypropyl, propoxymethyl, propoxyethyl, Propoxypropyl.

a C ₂ -C ₂₀ alkyl group having one or more O, S, NR ₂₆ or CO intermixed with O, S, NR ₂₆ or CO (for example) 1 to 9 times, 1 to 5 times, 1 to 3 times or 1 or 2 times. If more than one meta-group is present, it is the same species or different. The two O atoms are separated by at least one methylene group, preferably at least two methylene groups (ie, an extended ethyl group). These alkyl groups are linear or branched. For example, the following structural units will be present: -CH ₂ -CH ₂ -O-CH ₂ CH ₃ , -[CH ₂ CH ₂ O] _y -CH ₃ (where y = 1 to 9), -(CH ₂ - CH ₂ O) ₇ -CH ₂ CH ₃ , -CH ₂ -CH(CH ₃ )-O-CH ₂ -CH ₂ CH ₃ , -CH ₂ -CH(CH ₃ )-O-CH ₂ -CH ₃ ,- CH ₂ -CH ₂ -S-CH ₂ CH ₃ , -CH ₂ -CH(CH ₃ )-NR ₂₆ -CH ₂ -CH ₃ , -CH ₂ -CH ₂ -COO-CH ₂ CH ₃ or -CH ₂ - CH(CH ₃ )-OCO-CH ₂ -CH ₂ CH ₃ .

The C ₃ -C ₁₀ cycloalkyl, C ₃ -C ₁₀ cycloalkyl and C ₃ -C ₈ cycloalkyl are understood in the context of the present application to mean an alkyl group containing at least one ring. It is, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclooctyl, pentylcyclopentyl and cyclohexyl. C ₃ -C ₁₀ cycloalkyl is also intended to encompass a bicyclic ring in the context of the present invention, in other words, a bridging ring, for example , , And the corresponding ring. Other examples are such as , , (E.g )or Such structures, as well as bridging or fused ring systems, for example, the term is also intended to cover , Wait.

The C ₃ -C ₂₀ cycloalkyl group interspersed with O, S, CO, NR ₂₆ has the meaning given above wherein at least one CH ₂ - group in the alkyl group is replaced by O, S, CO or NR ₂₆ . Examples are such as , , (E.g ), , , , , or And other structures.

The C ₁ -C ₈ alkyl-C ₃ -C ₁₀ cycloalkyl group is a C ₃ -C ₁₀ cycloalkyl group as defined above substituted with one or more alkyl groups having up to 8 carbon atoms. Instance system , Wait.

a C ₁ -C ₈ alkyl-C ₃ -C ₁₀ cycloalkyl group having one or more O groups substituted by one or more alkyl groups having up to 8 carbon atoms, as defined above, O interstitial C ₃ - C ₁₀ cycloalkyl. Instance system , Wait.

The C ₁ -C ₁₂ alkoxy substituted with the system via a O atom C ₁ -C ₁₂ alkyl. The C ₁ -C ₁₂ alkyl group has the same meaning as given above for the C ₁ -C ₂₀ alkyl group and has the highest corresponding number of C atoms. The C ₁ -C ₄ alkoxy is straight or branched, such as methoxy, ethoxy, propoxy, isopropoxy, n-butoxy, second butoxy, isobutoxy or Third butoxy. The C ₁ -C ₈ alkoxy group and the C ₁ -C ₄ -alkoxy group have the same meanings as described above and have the highest corresponding number of C atoms.

The C ₁ -C ₁₂ substituted alkylthio system S atom of a C ₁ -C ₁₂ alkyl. The C ₁ -C ₂₀ alkyl group has the same meaning as given above for the C ₁ -C ₂₀ alkyl group and has the highest corresponding number of C atoms. The C ₁ -C ₄ alkylthio group is linear or branched, such as methylthio, ethylthio, propylthio, isopropylthio, n-butylthio, and second butyl sulfide. Base, isobutylthio, tert-butylthio.

The phenyl-C ₁ -C ₃ alkyl group is, for example, benzyl, phenylethyl, α-methylbenzyl or α,α-dimethyl-benzyl, especially benzyl.

The phenyl-C ₁ -C ₃ alkoxy is, for example, a benzyloxy group, a phenylethoxy group, an α-methylbenzyloxy group or an α,α-dimethylbenzyloxy group, especially a benzyloxy group. .

The C ₂ -C ₁₂ alkenyl group is mono- or polyunsaturated and is, for example, C ₂ -C ₁₀ -, C ₂ -C ₈ -, C ₂ -C ₅ -alkenyl, such as vinyl, allyl , methallyl, 1,1-dimethylallyl, 1-butenyl, 3-butenyl, 2-butenyl, 1,3-pentadienyl, 5-hexenyl , 7-octenyl or dodecenyl, especially allyl. The C ₂ -C ₅ alkenyl group has the same meaning as given above for the C ₂ -C ₁₂ alkenyl group and has the highest corresponding number of C atoms.

The C ₂ -C ₁₂ alkenyl group having one or more O, CO or NR ₂₆ is heterogeneous (for example) 1 to 9 times, 1 to 5 times, 1 to 3 times or 1 time by O, S, NR ₂₆ or CO. Or 2 times. If more than one meta-group is present, it is the same species or different. The two O atoms are separated by at least one methylene group, preferably at least two methylene groups (ie, an extended ethyl group). The alkenyl group is straight or branched and is as defined above. For example, the following structural units can be formed: -CH=CH-O-CH ₂ CH ₃ , -CH=CH-O-CH=CH ₂ and the like.

The C ₄ -C ₈ cycloalkenyl group has one or more double bonds and is, for example, a C ₄ -C ₆ -cycloalkenyl group or a C ₆ -C ₈ -cycloalkenyl group. Examples are cyclobutenyl, cyclopentenyl, cyclohexenyl or cyclooctenyl, especially cyclopentenyl and cyclohexenyl, preferably cyclohexenyl.

The C ₃ -C ₆ alkenyloxy group is mono- or polyunsaturated and has one of the meanings given above for an alkenyl group, and the attached oxy group has the highest corresponding number of C atoms. Examples are allyloxy, methylallyloxy, butenyloxy, pentenyloxy, 1,3-pentadienyloxy, 5-hexenyloxy.

The C ₂ -C ₁₂ alkynyl group is mono- or polyunsaturated linear or branched and is, for example, a C ₂ -C ₈ -, C ₂ -C ₆ - or C ₂ -C ₄ alkynyl group. Examples are ethynyl, propynyl, butynyl, 1-butynyl, 3-butynyl, 2-butynyl, pentynylhexynyl, 2-hexynyl, 5-hexynyl, Octyl group and the like.

The C ₂ -C ₂₀ alkenyl group is linear or branched and is, for example, C ₂ -C ₁₈ -, C ₂ -C ₁₄ -, C ₂ -C ₁₂ -, C ₂ -C ₈ -, C ₂ -C ₆ - or C ₂ -C ₄ alkyl fluorenyl or C ₄ -C ₁₂ - or C ₄ -C ₈ alkyl fluorenyl. Examples are ethyl acetyl, propyl, butyl, isobutyl, pentylene, hexyl, decyl, octyl, fluorenyl, fluorenyl, fluorenyl, tetradecyl, fifteen Base, hexadecanyl, octadecyl, and decyl, preferably acetyl. The C ₁ -C ₈ alkano group has the same meaning as given above for the C ₂ -C ₂₀ alkano group and has the highest corresponding number of C atoms.

The C ₂ -C ₁₂ alkoxycarbonyl group is straight or branched and is, for example, a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a n-butoxycarbonyl group, an isobutoxycarbonyl group, 1, 1-Dimethylpropoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, decyloxycarbonyl or dodecyloxycarbonyl, especially methoxy A carbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a n-butoxycarbonyl group or an isobutoxycarbonyl group is preferably a methoxycarbonyl group.

The C ₂ -C ₁₂ alkoxycarbonyl group having one or more O is linear or branched. The two O atoms are separated by at least two methylene groups (ie, an extended ethyl group). The meta-alkyloxycarbonyl group is unsubstituted or substituted with one or more hydroxyl groups. The C ₆ -C ₂₀ aryloxycarbonyl group is, for example, a phenyloxycarbonyl group [=phenyl-O-(CO)-], a naphthyloxycarbonyl group, a decyloxycarbonyl group or the like. C ₅ -C ₂₀ heteroaryloxycarbonyl C ₅ -C ₂₀ heteroaryl-O-CO-.

The C ₃ -C ₁₀ cycloalkylcarbonyl system is C ₃ -C ₁₀ cycloalkyl-CO-, wherein the cycloalkyl group has one of the meanings indicated above and has the highest corresponding number of C atoms. The C ₃ -C ₁₀ cycloalkylcarbonyl group having one or more of O, S, CO, NR ₂₆ refers to a heterocycloalkylene group-CO-, wherein the meta-heterocycloalkylene group is as defined above.

The C ₃ -C ₁₀ cycloalkoxycarbonyl group is C ₃ -C ₁₀ cycloalkyl-O-(CO)-, wherein the cycloalkyl group has one of the meanings indicated above and has the highest corresponding number of C atoms. The C ₃ -C ₁₀ cycloalkoxycarbonyl group having one or more O, S, CO, NR ₂₆ refers to a heterocycloalkylene-O-(CO)- group, wherein the meta-heterocycloalkyl group is as described above Defined.

The C ₁ -C ₂₀ alkylphenyl group means a phenyl group substituted by one or more alkyl groups, wherein the sum of C atoms is at most 20.

The C ₆ -C ₂₀ aryl group (for example) phenyl, naphthyl, anthracenyl, phenanthryl, fluorenyl, A tetraphenyl, a triphenyl or the like, especially a phenyl or naphthyl group, preferably a phenyl group. Naphthyl 1-naphthyl or 2-naphthyl.

In the context of the present invention, the C ₃ -C ₂₀ heteroaryl is intended to include monocyclic or polycyclic systems, such as fused ring systems. Examples are thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thioxyl, furyl, dibenzofuranyl, Sulfhydryl, xanthenyl, thioxanthyl, phenothiphenyl, pyrrolyl, imidazolyl, pyrazolyl, pyrazinyl, pyrimidinyl, pyridazinyl, carbazinyl, isodecyl, fluorenyl , carbazolyl, fluorenyl, quinazolyl, isoquinolyl, quinolyl, pyridazinyl, naphthyridinyl, quinoxalinyl, quinazolinyl, Polinyl, acridinyl, oxazolyl, β-carbolinyl, phenanthryl, acridinyl, naphthyldiazophenyl, phenanthroline, phenazinyl, isothiazolyl, phenothiazine , isoxazolyl, furazolyl, phenomethoxy, 7-phenanthryl, inden-2-yl (=9,10-di-oxy-9,10-dihydroindol-2-yl), 3 -benzo[b]thienyl, 5-benzo[b]thienyl, 2-benzo[b]thienyl, 4-dibenzofuranyl, 4,7-dibenzofuranyl, 4-methyl Base-7-dibenzofuranyl, 2-xanthene, 8-methyl-2-indenyl, 3-indolyl, 2-morphothinyl, 2,7-morphothinyl, 2 -pyrrolyl, 3-pyrrolyl, 5-methyl-3-pyrrolyl, 2-imidazolyl, 4-imidazolyl, 5-imidazolyl, 2-methyl-4-imidazolyl, 2-ethyl-4 -Imidazolyl, 2-ethyl-5-imidazolyl, 1H-tetrazol-5-yl, 3-pyrazolyl, 1-methyl-3-pyrazolyl, 1-propyl-4-pyrazolyl , 2-pyrazinyl, 5,6-dimethyl-2-pyrazinyl, 2-indolizinyl, 2-methyl-3-isoindolyl, 2-methyl-1-isoindole , 1-methyl-2-indenyl, 1-methyl-3-indolyl, 1,5-dimethyl-2-indenyl, 1-methyl-3-oxazolyl, 2 ,7-dimethyl-8-fluorenyl, 2-methoxy-7-methyl-8-fluorene , 2-quinazinyl, 3-isoquinolinyl, 6-isoquinolinyl, 7-isoquinolyl, 3-methoxy-6-isoquinolinyl, 2-quinolinyl, 6- Quinolinyl, 7-quinolyl, 2-methoxy-3-quinolyl, 2-methoxy-6-quinolinyl, 6-pyridazinyl, 7-pyridazinyl, 1-methoxy -6-oxazinyl, 1,4-dimethoxy-6-pyridazinyl, 1,8-naphthyridin-2-yl, 2-quinoxalinyl, 6-quinoxalinyl, 2, 3-Dimethyl-6-quinoxalinyl, 2,3-dimethoxy-6-quinoxalinyl, 2-quinazolinyl, 7-quinazolinyl, 2-dimethylamino -6-quinazolinyl, 3- Lolinyl, 6- Olinyl group, 7- Lolinyl, 3-methoxy-7- Lolinyl, 2-acridinyl, 6-acridinyl, 7-acridinyl, 6,7-dimethoxy-2-acridinyl, 2-oxazolyl, 3-oxazolyl, 9- Methyl-2-oxazolyl, 9-methyl-3-oxazolyl, β-carboline-3-yl, 1-methyl-β-carboline-3-yl, 1-methyl-β- Porphyrin-6-yl, 3-phenanthryl, 2-acridinyl, 3-acridinyl, 2-naphthyldiazophenyl, 1-methyl-5-naphthyldiazophenyl, 5-phenanthroline, 6-phenanthroline, 1-phenazinyl, 2-phenazinyl, 3-isothiazolyl, 4-isothiazolyl, 5-isothiazolyl, 2-phenothiazine , 3-phenothiazine, 10-methyl-3-phenothiazinyl, 3-isoxazolyl, 4-isoxazolyl, 5-isoxazolyl, 4-methyl-3-furazan Base, 2-oxo group, 10-methyl-2-phenoxy group, and the like.

The C ₃ -C ₂₀ heteroaryl is especially thienyl, benzo[b]thienyl, thioxyl, thioxanthyl, 1-methyl-2-indenyl or 1-methyl-3-indole a base; especially a thienyl group.

The C ₄ -C ₂₀ heteroarylcarbonyl group is attached to the remainder of the molecule via a CO group as defined above for a C ₃ -C ₂₀ heteroaryl group.

The substituted aryl (phenyl, naphthyl, C ₆ -C ₂₀ aryl or C ₅ -C ₂₀ heteroaryl) is 1 to 7 times, 1 to 6 times or 1 to 4 times, especially 1 Sub, 2 or 3 substitutions. It will be apparent that the defined aryl group cannot have more substituents than the free position at the aryl ring.

The substituent on the phenyl ring is preferably in position 4 on the phenyl ring or in the 3,4-, 3,4,5-, 2,6-, 2,4- or 2,4,6-group. state.

1 or 19 times, 1 to 15 times, 1 to 12 times, 1 to 9 times, 1 to 7 times, 1 to 5 times, 1 to 4 times, such as 1 to 19 times, 1 to 15 times, 1 to 12 times, 1 to 9 times, 1 to 7 times, 1 to 5 times, 1 to 4 times 1, 1 to 3 or 1 or 2 times (obviously, the number of heteroatoms depends on the number of C atoms in the interstitial). The substituted group substituted by one or more times has, for example, 1 to 7, 1 to 5, 1 to 4, 1 to 3 or 1 or 2 identical or different substituents.

The group substituted with one or more of the defined substituents is intended to have one substituent or a plurality of substituents as defined or differently given. Halogen is fluorine, chlorine, bromine and iodine, especially fluorine, chlorine and bromine, preferably fluorine and chlorine. When R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ or R ₅ and Re, R ₆ and R ₇ , R ₇ and R ₈ are independently of each other ; then form (for example) the following structure (Ia)-I(i): Or (for example) structures such as (Id)-(Ih):

The preferred structure is (Ia).

The photoinitiator (E-1) having the structure represented by the formula (VIII) is characterized in that at least one phenyl ring is partially fused with a carbazole to form a "naphthyl" ring. That is, one of the above structures is given by the structure shown in the formula (VIII).

If R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are each independently taken to be -(CH ₂ ) _P -Y- (CH ₂ ) _q -, forming, for example, such as And other structures.

If the substituent OR ₁₇ , SR ₁₈ , SOR ₁₈ , SO ₂ R ₁₈ or NR ₁₉ R ₂₀ on the phenyl or naphthyl ring is via the radicals R ₁₇ , R ₁₈ , R ₁₉ and/or R ₂₀ and the naphthyl ring When a carbon atom forms a 5- or 6-membered ring, a structure comprising 3 or more rings including a naphthyl ring is obtained.

Instance system Wait.

If R ₁₇ forms a bond to have a group thereon or a direct bond of a carbon atom of a phenyl or naphthyl ring, for example, such as And other structures.

If R ₁₆ is a phenyl group substituted by SR ₁₈ , wherein the group R ₁₉ represents a direct bond bonded to a phenyl or naphthyl ring to which a carbazole moiety of the COR ₁₆ group is attached, for example, such as And other structures. That is, if R ₁₆ is a phenyl group substituted by SR ₁₈ , wherein the group R ₁₈ represents a direct bond bonded to a phenyl or naphthyl ring to which a carbazole moiety of the COR ₁₆ group is attached, the thioxanthene The base moiety is formed together with a phenyl or naphthyl ring of the carbazole moiety.

If R ₁₉ and R ₂₀ together with the N atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring, optionally mixed with O, S or NR ₁₇ , a saturated or unsaturated ring, such as aziridine, is formed. Pyrrole, thiazole, pyrrolidine, oxazole, pyridine, 1,3-diazine, 1,2-diazine, hexahydropyridine or morpholine. Preferably, if R ₁₉ and R ₂₀ together with the N atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring of O, S or NR ₁₇ as appropriate, an inter- or inter-molecular O is formed. Or NR ₁₇ , especially the 5- or 6-member saturated ring of O.

If R ₂₁ and R ₂₂ together with the N atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring, optionally mixed with O, S or NR ₂₆ , and the benzene ring is optionally fused to the saturated or unsaturated ring. , forming a saturated or unsaturated ring, such as aziridine, pyrrole, thiazole, pyrrolidine, oxazole, pyridine, 1,3-diazine, 1,2-diazine, hexahydropyridine or morpholine or corresponding ring Ring (for example )Wait.

If R ₁₉ and R ₂₀ together with the N atom to which they are attached form a heteroaromatic ring system, the ring system is intended to contain more than one ring (eg 2 or 3 rings) and one or one from the same or different species. Above heteroatoms. Suitable hetero atomic systems are, for example, N, S, O or P, especially N, S or O. Examples are carbazole, indole, isoindole, carbazole, anthracene, isoquinoline, quinoline, porphyrin, phenothiazine and the like.

The term "and/or" or "or/and" is intended to mean in the context of the present invention that not only one of the defined substitutes (substituents) but also a plurality of defined substitutes (substituents) may be present, ie A mixture of different substitutes (substituents).

The term "at least" is intended to define one or more, such as one or both or three, preferably one or both.

The term "optionally substituted" means that the group to which it is referred is unsubstituted or substituted.

The term "as appropriate" means that the group to which it is referred is not miscellaneous or interstitial.

Throughout this specification and the claims below, the words "comprise" or variant (eg, "comprises" or "comprising") are understood to include the integer or A step or integer group or group of steps, but does not exclude any other integer or step or integer group or group of steps. The term "(meth)acrylate" is intended in the context of the present application to mean acrylate and the corresponding methacrylate.

The preferred embodiments shown in the text for the compounds of the present invention in the context of the present invention are intended to refer to all categories of patent applications, i.e., the scope of application for compositions, uses, methods, color filters, and the like.

The photoinitiator (E-1) having the structure represented by the formula (VIII) is produced by a method described in the literature, for example, by reacting a corresponding hydrazine with a hydrazine halide, particularly a chloride or an acid anhydride, under the following conditions. : in an inert solvent such as tert-butyl methyl ether, tetrahydrofuran (THF) or dimethylformamide, in the presence of a base such as triethylamine or pyridine, or in a basic solvent such as pyridine. In the following, as an example, the preparation of the compound of the formula Ia, wherein R ₇ is an oxime ester group and the X-based direct bond system [the reaction of the compound (Ib)-(Ih) from the appropriate oxime] is explained:

R ₁ , R ₂ , R ₅ , R ₆ , R ₈ , R ₁₃ , R ₁₄ and R ₁₅ are as defined above, and Hal means a halogen atom, especially Cl.

R _{14 is} preferably a methyl group.

Such reactions are well known to those skilled in the art and are typically carried out at a temperature of from -15 ° C to +50 ° C, preferably from 0 to 25 ° C.

When X is CO, the corresponding lanthanide is obtained by using alkyl nitrite (such as methyl nitrite, ethyl nitrite, propyl nitrite, butyl nitrite or isoamyl nitrite). Nitrification to synthesize. The esterification is then carried out under the same conditions as described above:

Thus, the subject matter of the invention is also prepared by reacting the corresponding hydrazine compound with an hydrazine halide of formula (a) or an anhydride of formula (b) in the presence of a mixture of bases or bases, as defined above, having formula (VIII) A method of the photoinitiator (E-1) of the structure shown.

Wherein Hal is halogen, especially Cl, and R ₁₄ is as defined above.

The desired material for the starting material can be obtained by standard chemistry textbooks (eg J. March, Advanced Organic Chemistry, 4th edition, Wiley Interscience, 1992) or monographs (eg S.R. Sandler & W.Karo, Organic functional group). Various methods are described in Preparations, Vol. 3, Academic Press.

One of the most convenient methods is, for example, reacting an aldehyde or a ketone with hydroxylamine or a salt thereof in a polar solvent such as dimethylacetamide (DMA), aqueous DMA, ethanol or an aqueous ethanol solution. In this case, a base such as sodium acetate or pyridine is added to control the pH of the reaction mixture. It is well known that the reaction rate is pH dependent and the base can be added continuously at the beginning or during the reaction. An alkaline solvent such as pyridine can also be used as the base and/or solvent or co-solvent. The reaction temperature is usually from room temperature to the reflux temperature of the mixture, and is usually from about 20 ° C to 120 ° C.

The corresponding ketone intermediate system, for example, is prepared by methods described in the literature (e.g., standard chemistry textbooks, e.g., J. March, Advanced Organic Chemistry, 4th Ed., Wiley Interscience, 1992). In addition, the continuous Friedel-Crafts reaction can be effectively used to synthesize intermediates. Such reactions are well known to those skilled in the art.

Another convenient synthesis of hydrazine is the nitrosation of "active" methylene groups with nitrous acid or alkyl nitrite. Basic conditions (as described, for example, in Organic Syntheses coll., Volume VI (J. Wiley & Sons, New York, 1988), pages 199 and 840) and acidic conditions (e.g., for example) Organic Synthesis coll Volume V, pages 32 and 373, coll. Volume III, pages 191 and 513, coll. Volume II, pages 202, 204 and 363) It is suitable for the preparation of hydrazine used as a starting material in the present invention. Nitrous acid is generally produced from sodium nitrite. The alkyl nitrite can be, for example, methyl nitrite, ethyl nitrite, propyl nitrite, butyl nitrite or isoamyl nitrite.

Another embodiment of the present invention is a photoinitiator (E-1) having a structure of the formula (IA):

Wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, C ₁ -C ₂₀ alkyl, , COR ₁₆ , OR ₁₇ , halogen, NO ₂ or Or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are each independently Substituted C ₂ -C ₁₀ alkenyl; or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are independently of each other Is -(CH ₂ ) _P -Y-(CH ₂ ) _q -; or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ And R ₈ are mutually independent However, the condition is at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R _{8 , R 9, R 10, R} 11 and R ₁₂ independently of one another hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following groups: halo, Phenyl, CN, OH, SH, C ₁ -C ₄ -alkoxy, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ Independently from each other, an unsubstituted phenyl group or a phenyl group substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, CN, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₉ And R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, halogen, CN, OR ₁₇ , SR ₁₈ , SOR ₁₈ , SO ₂ R ₁₈ or NR ₁₉ R ₂₀ , wherein the substituents OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ optionally forming a 5- or 6-membered ring with a carbon atom in the naphthyl ring via the group R ₁₇ , R ₁₈ , R ₁₉ and/or R ₂₀ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ independently of each other for , COR ₁₆ or NO ₂ ; Y series O, S, NR ₂₆ or direct bond; p is an integer 0, 1, 2 or 3; q is an integer 1, 2 or 3; X is CO or direct bond; R ₁₃ is C _{a 1-} C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , COOR ₁₇ , OR ₁₇ , SR ₁₈ , CONR ₁₉ R ₂₀ , NR ₁₉ R ₂₀ , PO (OC _k H _2k+1 ) ₂ or Or R ₁₃ is a C ₂ -C ₂₀ alkyl group in which one or more of O, S, SO, SO ₂ , NR ₂₆ or CO, or a C ₂ -C ₁₂ alkenyl group, which has no inter Or a plurality of O, CO or NR ₂₆ wherein the C ₂ -C ₂₀ alkyl group and the unintervening or interstitial C ₂ -C ₁₂ alkenyl group are unsubstituted or substituted by one or more halogens; or R _{a 13-} C ₄ -C ₈ cycloalkenyl group, a C ₂ -C ₁₂ alkynyl group or a C ₃ -C ₁₀ cycloalkyl group which has no or hetero or one or more O, s, CO or NR ₂₆ ; or R ₁₃ A phenyl or naphthyl group, each unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , , COR ₁₆ , CN, NO ₂ , halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₂ -C ₂₀ alkyl, interspersed with one or more O, S, CO or NR ₂₆ ; each warp or C ₃ -C ₁₀ cycloalkyl, or interrupted by one or more O, S, CO or NR ₂₆ of the C ₃ -C ₁₀ cycloalkyl; K-based integer from 1 to 10; R ₁₅ lines C ₆ - C ₂₀ aryl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or substituted by one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , SO-C ₁ -C ₁₀ alkyl, SO ₂ -C ₁ -C ₁₀ alkyl, hetero or one or more O, S or NR C ₂₆ of ₂ -C ₂₀ alkyl group; or each warp substituted C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following radicals: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is hydrogen, C ₂ -C ₁₂ alkenyl, C ₃ -C ₈ cycloalkyl, which has no or hetero or one or more O, CO or NR ₂₆ ; R ₁₅ C ₁ -C ₂₀ alkyl-based, which was used without A substituted or by one or more of the following groups: _{halo, OR 17, SR 18, C} 3 -C 8 cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl group, C ₃ -C ₂₀ heteroaryloxycarbonyl, NR ₁₉ R ₂₀ , COOR ₁₇ , CONR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , , Or a phenyl group; or the C ₁ -C ₂₀ alkyl group substituted by a phenyl group, which is halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ Substituting; or R ₁₅ is a C ₂ -C ₂₀ alkyl group, interspersed with one or more O, SO or SO ₂ , and the interstitial C ₂ -C ₂₀ alkyl group is unsubstituted or substituted by one or more of the following groups Group substitution: halogen, OR ₁₇ , COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl or phenyl substituted by OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ C ₂ -C ₂₀ alkanoyl or benzoyl A thiol group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is unsubstituted or a naphthylmethyl group substituted by one or more OR ₁₇ or a C ₃ -C ₁₄ heteroarylcarbonyl group; or an R ₁₅ C ₂ -C ₁₂ alkoxycarbonyl group, which has no or a heterogeneous one or more O And the inter- or non-hetero-C ₂ -C ₁₂ alkoxycarbonyl group is unsubstituted or substituted with one or more hydroxy groups; or the R ₁₅ phenoxycarbonyl group is unsubstituted or one or more of the following Group substitution: C ₁ -C ₆ alkyl, halogen, C ₁ -C ₄ haloalkyl, phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is CN, CONR ₁₉ R ₂₀ , NO ₂ , C ₁ -C ₄ haloalkyl, S(O) _m -C ₁ -C ₆ alkyl, unsubstituted or via C ₁ -C ₁₂ alkyl or SO ₂ -C ₁ -C ₆ alkyl substituted S(O) _m -phenyl; or R ₁₅ -based SO ₂ O-phenyl, unsubstituted or C ₁ -C ₁₂ alkane Substituent; or a diphenylphosphinium or di(C ₁ -C ₄ alkoxy)-phosphonium; m system 1 or 2; R' ₁₅ has one of the meanings given for R ₁₅ ; X ₁ is O, S, SO or SO ₂ ; X ₂ is O, CO, S or a direct bond; R ₁₆ is a C ₆ -C ₂₀ aryl or C ₃ -C ₂₀ heteroaryl group, each of which is not Substituted or substituted with one or more of the following groups: phenyl, halo, C ₁ -C ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or miscellaneous one or more O, S or NR C ₂₆ of ₁ -C ₂₀ alkyl group; or each substituted by one or more C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following groups Substitution: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ -C ₂₀ heteroaryl butoxycarbonyl, oR _17, SR ₁₈ or NR ₁₉ R _20; or R ₁₆ lines , Unsubstituted or substituted with one or more of the following radicals C ₁ -C ₂₀ alkyl group: halogen, phenyl, OH, SH, CN, C 3 -C 6 alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl, (CO)OH or (CO)O ( C ₁ -C ₄ alkyl); or R ₁₆ interstitial with one or more C ₂ -C ₁₂ alkyl groups of O, S or NR ₂₆ ; or R ₁₆ system (CH ₂ CH ₂ O) _n+1 H, ( CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₁₂ alkenyl or C ₃ -C ₈ cycloalkyl; or R ₁₆ is a phenyl substituted by SR ₁₈ , Wherein the group R ₁₈ represents a direct bond bonded to a phenyl or naphthyl ring to which a carbazole moiety of a COR ₁₆ group is attached; n is 1 to 20; R ₁₇ is hydrogen, phenyl-C ₁ -C _{a 3-} alkyl, C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O ( CO)-phenyl, (CO)OH, (CO)O(C ₁ -C ₄ alkyl), SO ₂ -(C ₁ -C ₄ haloalkyl), O(C ₁ -C ₄ haloalkyl), C or ₃ -C ₂₀ cycloalkyl interrupted by one or more of C ₃ -C ₂₀ O Alkyl group; R _17, or C ₂ -C ₂₀ alkyl-based, have therebetween one or more heteroatoms O, S or NR _26; or R ₁₇ lines _{(CH 2 CH 2 O) n} + 1 H, (CH 2 CH 2 O _n (CO)-(C ₁ -C ₈ alkyl), C ₁ -C ₈ alkanoyl, C ₂ -C ₁₂ alkenyl, C ₃ -C ₆ alkenyl or C ₃ -C ₂₀ cycloalkyl , having no or hetero or one or more O, S, CO or NR ₂₆ ; or R ₁₇ C ₁ -C ₈ alkyl-C ₃ -C ₁₀ cycloalkyl, which has one or more Or R ₁₇ is a benzhydryl group which is unsubstituted or substituted by one or more C ₁ -C ₆ alkyl, halogen, OH or C ₁ -C ₃ alkoxy groups; or R ₁₇ phenyl group , naphthyl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or substituted by one or more of the following groups: halogen, OH, C ₁ -C ₁₂ alkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl-C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N(C ₁ -C ₁₂ alkyl) ₂ , diphenyl Amino-amino group or Or R ₁₇ forms a bond to have a group thereon or a direct bond of one carbon atom of a phenyl or naphthyl ring; R ₁₈ is hydrogen, C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl or phenyl-C ₁ -C ₃ alkyl, wherein C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl or phenyl-C ₁ -C ₃ alkyl without inter or hetero-have one or more O, S, CO, NR ₂₆ or COOR ₁₇ ; or R ₁₈ Is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ ( CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl Or (CO)OR ₁₇ ; or R ₁₈ C ₂ -C ₂₀ alkyl with one or more O, S, CO, NR ₂₆ or °COOR ₁₇ ; or R ₁₈ (CH ₂ CH ₂ O) _n H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₈ alkanoyl or C ₃ -C ₆ olefin; or R ₁₈ benzyl fluorenyl , which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OH, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkylthio; or R ₁₈ A phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl group, each unsubstituted or substituted with one or more of the following groups: halogen, C ₁ -C ₁₂ alkyl, C ₁ -C _4- haloalkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl-C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N (C ₁ -C ₁₂ alkyl) ₂ , diphenylamino, (CO)O(C ₁ -C ₈ alkyl), (CO)-C ₁ -C ₈ alkyl, (CO)N (C ₁ -C ₈ alkyl) ₂ or R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₂ -C ₁₀ alkoxyalkyl, C ₂ -C ₅ alkenyl, C ₃ - C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkyl, SO ₂ -(C ₁ -C ₄ haloalkyl), C ₁ -C ₈ alkanoyl, C ₁ -C ₈ alkenyloxy, a C ₃ -C ₁₂ olefinic group or a benzhydryl group; or R ₁₉ and R ₂₀ are a phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl group, each unsubstituted or having one or more of the following groups Substituted: halogen, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, C ₁ -C ₁₂ alkyl, benzhydryl or C ₁ -C ₁₂ alkoxy; or R ₁₉ and R ₂₀ The attached N atoms together form a 5- or 6-membered saturated or unsaturated ring which is not intermixed or interspersed with O, S or NR ₁₇ , and the 5 or 6 member saturated or unsaturated ring is unsubstituted or Or substituted with a plurality of groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkoxy, =0, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , NO ₂ , halogen, C ₁ -C ₄ -haloalkyl, CN, phenyl, Or a C ₃ -C ₂₀ cycloalkyl group, the C ₃ -C ₂₀ cycloalkyl group having no or hetero or one or more O, S, CO or NR ₁₇ ; or R ₁₉ and R ₂₀ and the N atom to which it is attached Together forming a heteroaromatic ring system, the ring system is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, =O, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , , Halogen, NO _2, CN, phenyl or C ₃ -C ₂₀ cycloalkyl group, the C ₃ -C ₂₀ cycloalkyl interrupted or not interrupted with one or more O, S, CO or NR _17; R ₂₁ and R ₂₂ independently of one another hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₃ -C ₁₀ cycloalkyl or phenyl; or R ₂₁ and R _{22 together} with the attached N atom Forming a 5- or 6-membered saturated or unsaturated ring without interstitial or interstitial with O, S or NR ₂₆ , and the 5 or 6 member saturated or unsaturated ring is not fused or the 5 or 6 members are saturated or not The saturated ring system is fused to a benzene ring; R ₂₃ is hydrogen, OH, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, intervening one or more O, CO or NR ₂₆ C ₂ -C ₂₀ alkane a C ₃ -C ₂₀ cycloalkyl group having an O, S, CO or NR ₂₆ or an R ₂₃ phenyl group, a naphthyl group, a phenyl-C ₁ -C ₄ alkyl group, OR ₁₇ , SR ₁₈ or NR ₂₁ R ₂₂ ; R ₂₄ system (CO)OR ₁₇ , CONR ₁₉ R ₂₀ , (CO)R ₁₇ ; or R ₂₄ having one of the meanings given for R ₁₉ and R ₂₀ ; R ₂₅ system COOR ₁₇ , CONR ₁₉ R ₂₀ , (CO)R ₁₇ ; or R ₂₅ have one of the meanings given for R ₁₇ ; R ₂₆ is hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl , C ₂ a C ₂₀ alkyl group in which one or more O or CO are heterogeneous; or a phenyl-C ₁ -C ₄ alkyl group, a C ₃ -C ₈ cycloalkyl group, which has one or more O or CO; or a series of (CO)R ₁₉ ; or a phenyl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, halogen, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or But the condition is that at least one group is present in the molecule or .

The preferred group of the group defined by the photoinitiator (E-1) of the structure represented by the formula (IA) corresponds to a photoinitiator (E- as defined for the structure of the formula (VIII) given below. 1) given, just for each defined oxime ester group (eg Are replaced by corresponding free sulfonium groups .

Each oxime ester group can exist in two configurations (Z) or (E). The isomers can be separated by conventional methods, but a mixture of isomers can also be used as, for example, a photoinitiator. Accordingly, the present invention is also a mixture of configurational isomers of the photoinitiator (E-1) of the structure represented by the formula (VIII).

Preferred is a photoinitiator (E-1) of the structure represented by the formula (VIII) as defined above, wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R _{8 is} independently of each other hydrogen, C ₁ -C ₂₀ alkyl, , COR ₁₆ or NO ₂ , or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are independently of each other However, the condition is at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ X is a CO or a direct bond; R ₁₃ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, OR ₁₇ , SR ₁₈ , COOR ₁₇ , CONR ₁₉ R ₂₀ or PO(OC _k H _2k+1 ) ₂ ; or R ₁₃ is a C ₂ -C ₂₀ alkyl group in which one or more O, S, NR ₂₆ or CO are mixed; or R ₁₃ is a phenyl or naphthyl group. Unsubstituted or one or more Or substituted by COR ₁₆ ; R ₁₄ is C ₁ -C ₂₀ alkyl, phenyl or C ₁ -C ₈ alkoxy; R ₁₅ is phenyl, naphthyl, C ₃ -C ₂₀ heteroaryl, each of which is not Substituted or substituted with one or more of the following: phenyl, halo, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ or C ₂ -C ₂₀ alkyl, interspersed with one or more O or S; each of which is substituted with one or more C ₁ - C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following radicals: _{halogen, COOR 17, CONR 19 R 20} , phenyl , C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₄ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ Or PO(OC _k H _2k+1 ) ₂ ; or R ₁₅ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , C ₃ -C ₈ a cycloalkyl group, a C ₃ -C ₂₀ heteroaryl group, NR ₁₉ R ₂₀ , COOR ₁₇ , CONR ₁₉ R ₂₀ or PO(OC _k H _2k+1 ) ₂ ; R' ₁₄ has the meaning given for R ₁₄ one; R _'15 has the meanings for R ₁₅ Suo one of those given; R ₁₆ lines phenyl, which is unsubstituted or substituted with one or more of the following _{groups: oR 17, SR 18, NR} 19 R 20 Or intermixed with one or more C ₂ -C ₂₀ alkyl groups of O, S or NR ₂₆ , or an R ₁₆ -type phenyl group substituted by one or more C ₁ -C ₂₀ alkyl groups, the C ₁ -C ₂₀ alkane Substituent substituted or substituted with one or more of the following groups: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₄ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₆ C ₁ -C ₂₀ alkyl, unsubstituted or substituted by : halogen, phenyl, OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ Alkyl) or (CO)O(C ₁ -C ₄ alkyl); R ₁₇ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(C ₁ -C ₄ alkyl), (CO)O(C ₁ -C ₄ alkyl), C ₃ -C ₂₀ cycloalkyl or hetero Or a plurality of C ₃ -C ₂₀ cycloalkyl groups of O; or R ₁₇ C ₂ -C ₂₀ alkyl groups with one or more O interstitials; R ₁₈ is a methyl group substituted by (CO)OR ₁₇ ; R ₁₉ and R ₂₀ independently of one another hydrogen, phenyl, C ₁ -C ₂₀ alkyl, C ₁ -C ₈ alkanoyl group or a C ₁ -C ₈ alkanoyl-yloxy ; Or R ₁₉ and R ₂₀ appended thereto the N atom to form a heteroaromatic ring system with the ring system is unsubstituted or Substituting; but the condition is that at least one group is present in the molecule or

It is necessary to pay attention to the photoinitiator (E-1) of the structure represented by the formula (VIII) as defined above, wherein R ₁ , R ₂ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, COR ₁₆ or NO ₂ , R ₃ and R ₄ together ; R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are hydrogen; X is a direct bond; R ₁₃ is a C ₁ -C ₂₀ alkyl group; R ₁₄ is a C ₁ -C ₂₀ alkyl group; and R ₁₅ is a C ₁ -C ₂₀ group; An alkyl or phenyl group substituted with one or more OR ₁₇ or C ₁ -C ₂₀ alkyl groups; R ₁₆ is a phenyl group substituted with one or more C ₁ -C ₂₀ alkyl groups or OR ₁₇ ; and R ₁₇ based unsubstituted or substituted with one or more of halogen or C ₁ -C ₂₀ alkyl interrupted by one or more lines of C ₂ -C ₂₀ O-alkyl; with the proviso that there is in the molecule at least one group .

The subject matter of the present invention is further a photoinitiator (E-1) of the structure represented by the formula (VIII) as defined above, wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, or R ₁ and R ₂ , R ₃ and R ₄ or R ₅ and R ₆ are independently of each other However, the condition is that at least one of R ₁ and R ₂ , R ₃ and R ₄ or R ₅ and R ₆ is Or R ₂ , COR ₁₆ , NO ₂ or ; or R ₇ series Or COR _16; R _9, R ₁₁ and R ₁₂ hydrogen system; R _10-based hydrogen, OR ₁₇ or COR _16; X based CO or a direct bond; R ₁₃ C ₁ -C ₂₀ alkyl-based, which is unsubstituted or Substituted by one or more of the following groups: halogen, R ₁₇ , OR ₁₇ , SR ₁₈ or PO(OC _k H _2k+1 ) ₂ ; or R ₁₃ C ₂ -C ₂₀ alkyl, with one or more O inter Or R ₁₃ is a phenyl group; k is an integer 2; R ₁₄ is a C ₁ -C ₂₀ alkyl or thienyl group; R ₁₅ is a phenyl or naphthyl group, each unsubstituted or via one or more OR ₁₇ or C ₁ -C ₂₀ alkyl substituted; or R ₁₅ is thienyl, hydrogen, C ₁ -C ₂₀ alkyl, the C ₁ -C ₂₀ alkyl group is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , C ₃ -C ₈ cycloalkyl, NR ₁₉ R ₂₀ or COOR ₁₇ ; or R ₁₅ C ₂ -C ₂₀ alkyl, interspersed with SO ₂ ; R ₁₆ phenyl or naphthyl, each of which Substituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or C ₁ -C ₂₀ alkyl; or R ₁₆ thienyl; R ₁₇ hydrogen, C ₁ -C ₈ An alkanoyl group, a C ₁ -C ₂₀ alkyl group, which is unsubstituted or has one or more of the following groups: halogen, O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄₎ alkenyl group or interrupted by one or O of a C ₃ -C ₂₀ cycloalkyl; R _17, or C ₂ -C ₂₀ alkyl-based, have therebetween one or more heteroatoms O; R ₁₈ lines C ₃ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ alkyl a group which is unsubstituted or substituted by one or more OH, O(CO)-(C ₂ -C ₄ )alkenyl or (CO)OR ₁₇ ; or an R ₁₈ phenyl group which is unsubstituted or or more halo substituents; R ₁₉ and R ₂₀ independently of one another C ₁ -C ₈ alkanoyl group or a C ₁ -C ₈ alkoxy group, acyl; or R ₁₉ and R ₂₀ appended thereto together with the N atom to a 5- or 6-membered saturated ring of O; however, the condition is that at least one group is present in the molecule .

Examples of compounds of the invention are the compounds of formula (Ia)-(Ig) as defined above. Compounds of formula (Ia), (Ib), (Ic), especially formula (Ia) or (Ic), or formula (Ia), (Ic) or (Id), especially formula (Ia) are of interest.

For example, R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, Or COR ₁₆ , or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ or R ₅ and R ₆ , R ₆ and R ₇ , R ₇ and R ₈ are independently of each other .

For example, R ₃ and R ₄ or R ₁ and R ₂ are Or R ₃ and R ₄ and R ₅ and R ₆ are ; R ₃ and R _{4 are} especially common .

For example, R ₁ , R ₅ , R ₆ and R ₈ are hydrogen.

R _{7 is} especially hydrogen, Or COR ₁₆ . Or R ₇ series Or COR ₁₆ , especially .

R _{2 is} especially , COR ₁₆ or Or R ₂ together with R ₁ . R _{2 is} especially COR ₁₆ .

X is preferably a direct bond.

For example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or phenyl substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OR ₁₇ or SR ₁₈ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently halogen, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ wherein the substituent OR ₁₇ SR ₁₈ or NR ₁₉ R ₂₀ optionally via a group R _17, R _18, R ₁₉ and / or R ₂₀ form a 5 or 6-membered ring with a carbon atom naphthyl ring; or R _9, R _10, R ₁₁ And R ₁₂ are independent of each other Or COR ₁₆ .

Specifically, for example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or substituted by one or more of the following groups Phenyl group: C ₁ -C ₆ alkyl group, halogen, OR ₁₇ or SR ₁₈ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently halogen, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are independent of each other Or COR ₁₆ .

For example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or substituted by one or more C ₁ -C ₆ alkyl groups. Phenyl; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are independently of each other Or COR ₁₆ .

In another embodiment, for example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or one or more of the following groups a substituted phenyl group: C ₁ -C ₆ alkyl, halogen, OR ₁₇ or SR ₁₈ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently halogen, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ Wherein the substituent OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ optionally forms a 5- or 6-membered ring via a group R ₁₇ , R ₁₈ , R ₁₉ and/or R ₂₀ with one carbon atom of the naphthyl ring.

Further, for example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or phenyl substituted with one or more of the following groups C ₁ -C ₆ alkyl, halogen, OR ₁₇ or SR ₁₈ , or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently halogen, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or COR ₁₆ .

Or by way of example, R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, hydrogen, C ₁ -C ₂₀ alkyl, unsubstituted phenyl or phenyl substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OR ₁₇ or SR ₁₈ , or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are each independently halogen, OR ₁₇ , COR ₁₆ or NR ₁₉ R ₂₀ .

Preferably, R ₉ , R ₁₁ and R ₁₂ are hydrogen and R ₁₀ is hydrogen, OR ₁₇ or COR ₁₆ .

R ₁₃ is, for example, a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, COOR ₁₇ or CONR ₁₉ R ₂₀ ; or R ₁₃ C ₂ -C ₂₀ alkyl In the meantime, one or more of O, S, SO, SO ₂ , NR ₂₆ or CO, or a C ₂ -C ₁₂ alkenyl group, optionally having one or more O, CO or NR ₂₆ or R ₁₃ systems a C ₃ -C ₁₀ cycloalkyl group optionally having one or more O, S, CO, NR ₂₆ or R ₁₃ phenyl or naphthyl groups, either unsubstituted or having one or more of the following groups Group replacement: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , , COR _16, NO _2, halogen, alkyl C ₁ -C _20, C ₁ -C ₄ haloalkyl, C ₂ -C _20-alkyl, heteroalkyl have therebetween one or more O; or C ₁ -C ₂₀ alkyl-based , which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , COOR ₁₇ , OR ₁₇ , SR ₁₈ , CONR ₁₉ R ₂₀ or PO(OC _k H _2k+1 ) ₂ ; or C ₂ -C ₂₀ alkyl group with one or more O in between.

Further, R ₁₃ is, for example, a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , COOR ₁₇ , OR ₁₇ , SR ₁₈ , CONR ₁₉ R ₂₀ or PO(OC _k H _2k+1 ) ₂ ; or a C ₂ -C ₂₀ alkyl group with one or more O; or a C ₂ -C ₁₂ alkenyl group, a C ₃ -C ₁₀ cycloalkyl group; or R _{a 13} -phenyl or naphthyl group which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , And COR ₁₆ , NO ₂ , halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₂ -C ₂₀ alkyl, with one or more O intervening.

In another embodiment, R ₁₃ lines (e.g.) C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with one or more of the following radicals: _{halogen, R 17, OR 17, SR} 18 or PO (OC _k H _2k+1 ) ₂ ; or a C ₂ -C ₂₀ alkyl group in which one or more O is hetero; or a C ₂ -C ₁₂ alkenyl group, a C ₃ -C ₁₀ cycloalkyl group, a phenyl group or a naphthyl group; .

Or R ₁₃ is, for example, a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , OR ₁₇ , SR ₁₈ or PO(OC _k H2 _k+1 ) _2; or C ₂ -C ₂₀ alkyl-based, or more therebetween O mixed with a; or a phenyl-based, C ₂ -C ₁₂ alkenyl or C ₃ -C ₁₀ cycloalkyl.

Or R ₁₃ lines (e.g.) C ₁ -C ₂₀ alkyl, phenyl, C ₂ -C ₁₂ alkenyl or C ₃ -C ₁₀ cycloalkyl.

Or R ₁₃ is, for example, a C ₁ -C ₂₀ alkyl group, a C ₂ -C ₁₂ alkenyl group or a C ₃ -C ₁₀ cycloalkyl group.

Preferably, R ₁₃ is C ₁ -C ₂₀ alkyl, especially C ₁ -C ₈ alkyl, such as 2-ethylhexyl.

R ₁₄ is, for example, hydrogen, C ₃ -C ₈ cycloalkyl, C ₂ -C ₅ alkenyl, C ₁ -C ₂₀ alkoxy or C ₁ -C ₂₀ alkyl, unsubstituted or via one or a plurality of halogen or phenyl substitutions; or R ₁₄ phenyl or naphthyl, both unsubstituted or substituted by one or more of the following groups: C ₁ -C ₆ alkyl, C ₁ -C ₄ haloalkyl , halogen, OR ₁₇ , SR ₁₈ and/or NR ₁₉ R ₂₀ ; or R ₁₄ C ₃ -C ₅ heteroaryl, such as thienyl, or C ₁ -C ₈ alkoxy, benzyloxy or phenoxy base.

Or R ₁₄ is, for example, a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more halogen or phenyl groups; or an R ₁₄ C ₃ -C ₅ heteroaryl group (e.g., thienyl) or a system a phenyl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, C ₁ -C ₄ haloalkyl, halogen, OR ₁₇ , SR ₁₈ and/or NR ₁₉ R ₂₀ ; R ₁₄ is a C ₁ -C ₈ alkoxy group, a benzyloxy group or a phenoxy group.

In another embodiment, R ₁₄ represents C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with phenyl; or R ₁₄ is phenyl, unsubstituted or via one or more C ₁ -C ₆ Alkyl substitution.

Preferably, R ₁₄ is C ₁ -C ₂₀ alkyl, C ₃ -C ₅ heteroaryl (such as thienyl), or phenyl, especially C ₁ -C ₂₀ alkyl or thienyl, especially C _1- C ₈ alkyl.

R ₁₅ is, for example, a C ₆ -C ₂₀ aryl group or a C ₅ -C ₂₀ heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkane Base, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , C ₁ -C ₂₀ alkyl; or R ₁₅ hydrogen, C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ cycloalkyl Depending on the case, one or more O, CO or NR ₂₆ ; or R ₁₅ C ₁ -C ₂₀ alkyl groups which are unsubstituted or substituted by one or more of the following groups: halogen, OR ₁₇ , C ₃ -C ₈ cycloalkyl, C ₅ -C ₂₀ heteroaryl, C ₈ -C ₂₀ phenoxycarbonyl, C ₅ -C ₂₀ heteroaryloxy group - _{carbonyl, NR 19 R 20, COOR 17} , CONR 19 R 20, PO (OC _k H _2k+1 ) ₂ , Phenyl or phenyl substituted by the following groups: halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, OR ₁₇ or NR ₁₉ R ₂₀ ; or R ₁₅ C ₂ -C ₂₀ alkyl In between, one or more of O, S or SO ₂ , or R ₁₅ C ₂ -C ₂₀ alkyl fluorenyl, benzhydryl, C ₂ -C ₁₂ alkoxycarbonyl, phenoxycarbonyl, CONR ₁₉ R ₂₀ , NO ₂ or C ₁ -C ₄ haloalkyl.

Further, R ₁₅ is, for example, hydrogen, C ₆ -C ₂₀ aryl, especially phenyl or naphthyl, each unsubstituted or substituted by C ₁ -C ₁₂ alkyl; or C ₃ -C ₅ hetero An aryl group, such as a thienyl group; or a C ₃ -C ₈ cycloalkyl group, a C ₁ -C ₂₀ alkyl group, which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₇ , C ₃ - C ₈ -cycloalkyl, NR ₁₉ R ₂₀ or COOR ₁₇ ; or R ₁₅ C ₂ -C ₂₀ alkyl, heterogeneously having one or more O or SO ₂ .

The photoinitiator (E-1) having the structure of the formula (VIII) is interesting, wherein R ₁₅ is, for example, hydrogen, phenyl, naphthyl, each unsubstituted or via C ₁ -C ₈ An alkyl group substituted; or an R ₁₅ -based thienyl group, a C ₁ -C ₂₀ alkyl group, which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₇ , C ₃ -C ₈ -cycloalkyl, NR ₁₉ R ₂₀ or COOR ₁₇ ; or R ₁₅ is a C ₂ - C ₂₀ alkyl group in which one or more O or SO ₂ are heterogeneous.

R _{15 is} especially, for example, C ₃ -C ₈ cycloalkyl or C ₁ -C ₂₀ alkyl, especially C ₁ -C ₂₀ alkyl, especially C ₁ -C ₁₂ alkyl.

The preferred ones of R' ₁₄ and R' ₁₅ are as set forth above for R ₁₄ and R ₁₅ , respectively.

X ₁ is, for example, O, S or SO, such as O or S, especially O.

R ₁₆ is, for example, a C ₆ -C ₂₀ aryl group (especially phenyl or naphthyl, especially phenyl) or a C ₅ -C ₂₀ heteroaryl (especially thienyl), each unsubstituted or one or more Substituted for: phenyl, halogen, C ₁ -G ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or a C ₁ -C ₂₀ alkyl group having one or more O; or each with one or more C ₁ -C ₂₀ substituted alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following radicals: _{halogen, COOR 17, CONR 19 R 20} , benzyl , C ₃ -C ₈ cycloalkyl, C ₅ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₅ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R _20; or R ₁₆ based hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one or more of the following groups: halogen, phenyl, OH, SH, C ₃ - C ₆ alkenyloxy, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl, (CO) OH or (CO)O(C ₁ -C ₄ alkyl); or R ₁₆ C ₂ -C ₁₂ alkyl, heterogeneously having one or more O; or (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₁₂ alkenyl or C ₃ -C ₈ naphthenic And n is 1 to 20, such as 1 to 12 or 1 to 8, especially 1 or 2.

Furthermore, R ₁₆ is, for example, phenyl or naphthyl, especially phenyl, thienyl or oxazole, each unsubstituted or substituted by one or more of the following groups: phenyl, halogen, C ₁ -C _{a 4-} haloalkyl group, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or C ₁ -C ₂₀ alkyl; or an R ₁₆ C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: Halogen, phenyl, OH, SH, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl) , O(CO)-phenyl, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₁₆ C ₂ -C ₁₂ alkyl, in which one or more O; or (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₁₂ alkenyl or C ₃ -C ₈ cycloalkyl And n is from 1 to 20, such as from 1 to 12 or from 1 to 8, especially 1 or 2.

Further, R ₁₆ is, for example, phenyl or naphthyl, especially phenyl, each unsubstituted or substituted with one or more of the following groups: phenyl, halo, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or C ₁ -C ₂₀ alkyl; or R ₁₆ C ₃ -C ₃ heteroaryl, especially thienyl.

In particular, R ₁₆ is (e.g.) phenyl, which is unsubstituted or substituted with one or more of the following _{groups: OR 17, SR 18, NR} 19 R 20 or C ₁ -C ₂₀ alkyl group, or R ₁₆ based thienyl .

Preferably, R ₁₆ is, for example, phenyl or naphthyl, each unsubstituted or substituted with one or more C ₁ -C ₂₀ alkyl groups.

R _{16 is} especially phenyl which is substituted by one or more C ₁ -C ₂₀ alkyl groups.

R ₁₇ is, for example, hydrogen, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with one or more of the following groups: halogen, OH, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-benzene a C ₃ -C ₂₀ cycloalkyl group; or a R ₁₇ system having one or more O groups; or (CO)OH, (CO)O(C ₁ -C ₄ alkyl), C ₃ -C ₂₀ cycloalkyl or inter-hetero a C ₂ -C ₂₀ alkyl group in which one or more O is hetero; a system of (CH ₂ CH ₂ O) _n+1 H, (GH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl) a C ₁ -C ₈ alkanoyl group, a C ₂ -C ₁₂ alkenyl group, a C ₃ -C ₆ olefinic group or a C ₃ -C ₂₀ cycloalkyl group optionally having one or more O; or an R ₁₇ system a benzhydryl group which is unsubstituted or substituted by one or more C ₁ -C ₆ alkyl, halogen, OH or C ₁ -C ₃ alkoxy groups; or R ₁₇ phenyl, naphthyl or C5-C _{a 20} heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: halogen, OH, C ₁ -C ₁₂ alkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl- C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N(C ₁ -C ₁₂ alkyl) ₂ , diphenyl-amine or .

In another embodiment, R ₁₇ is, for example, hydrogen, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with one or more of the following groups: halogen , O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ alkenyl) or a C ₂ -C ₂₀ alkyl group having one or more O; or a C ₁ -C ₈ alkyl fluorenyl, C ₂ -C ₁₂ alkenyl, C ₃ -C ₆ olefinic group, heterochromic one or more C ₂ -C ₂₀ alkyl groups, optionally with one or more C ₃ a -C ₂₀ cycloalkyl group; or a benzhydryl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OH or C ₁ -C ₃ alkoxy; Or a phenyl or naphthyl group, each unsubstituted or substituted with one or more of the following groups: halogen, C ₁ -C ₁₂ alkyl or C ₁ -C ₁₂ alkoxy.

R ₁₇ is also, for example, hydrogen, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₈ alkanoyl, C ₁ -C ₂₀ alkyl, unsubstituted or via one or more of the following groups Substitution: halogen, C ₃ -C ₂₀ cycloalkyl, O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ alkenyl) or miscellaneous one or more O C ₂ -C ₂₀ alkyl, or R ₁₇ C ₂ -C ₂₀ alkyl, heterogeneous with one or more O.

R _{17 is} especially hydrogen, C ₁ -C ₈ alkanoyl, C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted by one or more of the following groups: O(CO)-(C ₁ -C ₄ alkane a group of O(CO)-(C ₂ -C ₄ alkenyl) or a C ₂ -C ₂₀ alkyl group having one or more O, or an R ₁₇ C ₂ -C ₂₀ alkyl group, having one or more O.

R ₁₈ is, for example, a C ₃ -C ₂₀ cycloalkyl group which has no or a hetero or one or more O; or an R ₁₈ C ₁ -C ₂₀ alkyl group which is unsubstituted or one or more Group substitution: OH, O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl) or (CO)OR ₁₇ ; or R ₁₈ C ₂ -C _{a 20} alkyl group having one or more of O, S, CO, NR ₂₆ or COOR _{17 in between} ; or an R ₁₈ C ₂ -C ₈ alkanoyl group or a C ₃ -C ₆ alkenyl group or a benzamidine group; R ₁₈ is phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl, each unsubstituted or substituted by one or more of the following groups: halogen, C ₁ -C ₁₂ alkyl, C ₁ -C ₄ haloalkane Base, C ₁ -C ₁₂ alkoxy or NO ₂ .

In another embodiment, R ₁₈ is, for example, C ₃ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ alkyl, which is unsubstituted or substituted with one or more of the following groups: OH, O (CO )-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl) or (CO)OR ₁₇ ; or R ₁₈ phenyl or naphthyl, each unsubstituted or via One or more halogen or C ₁ -C ₁₂ alkyl groups, especially halogen.

R ₁₈ is, for example, C ₁ -C ₂₀ alkyl, C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkyl, C ₂ -C ₈ alkanoyl , benzylidene, phenyl or naphthyl.

For example, R ₁₈ is a C ₁ -C ₂₀ alkyl group substituted with one or more of the following groups: OH, O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl) or (CO)OR ₁₇ , or R ₁₈ -phenyl, substituted by one or more halogens.

Preferably, R ₁₈ is C ₁ -C ₈ alkyl, which is substituted as defined above.

For example, R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₃ -C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkane a phenyl or naphthyl group, a C ₁ -C ₈ alkanoyl group, a C ₁ -C ₈ alkenyloxy group, a C ₃ -C ₁₂ alkenyl group or a benzhydryl group; or R ₁₉ and R ₂₀ The attached N atoms together form a 5- or 6-membered saturated or unsaturated ring heterogeneously interspersed with O, S or NR ₁₇ ; or R ₁₉ and R ₂₀ together with the N atom to which they are attached form a heteroaromatic ring system, The ring system is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, or .

Further, for example, R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₃ -C ₂₀ cycloalkyl, phenyl-C ₁ -C _{a 3} alkyl group, a C ₁ -C ₈ alkyl fluorenyl group, a C ₁ -C ₈ alkyl fluorenyloxy group, a C ₃ -C ₁₂ olefinic fluorenyl group or a benzhydryl group; or R ₁₉ and R ₂₀ are attached thereto The atoms together form a 5- or 6-membered saturated ring, optionally mixed with O or NR ₁₇ ; or R ₁₉ and R ₂₀ together with the N atom to which they are attached form an indazole ring.

For example, R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₃ -C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkane a C ₁ -C ₈ alkanoyl group, a C ₁ -C ₈ alkanoyloxy group, a C ₃ -C ₁₂ alkenyl group or a benzhydryl group; or R ₁₉ and R ₂₀ together with the N atom to which it is attached Form a 5- or 6-membered saturated ring with O or NR ₁₇ as appropriate.

Preferably, R ₁₉ and R ₂₀ are, independently of each other, a C ₁ -C ₈ alkanoyl group, a C ₁ -C ₈ alkenyloxy group; or R ₁₉ and R ₂₀ together with the N atom to which they are attached form a morpholine ring.

For example, R ₂₁ and R ₂₂ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₃ -C ₁₀ cycloalkyl or phenyl; or R ₂₁ and R ₂₂ The attached N atoms together form a morpholine ring. R ₂₁ and R _{22 are, in} particular, independently of one another hydrogen or C ₁ -C ₂₀ alkyl.

R ₂₃ is, for example, hydrogen, OH, phenyl or C ₁ -C ₂₀ alkyl. R _{23 is} especially hydrogen, OH or C ₁ -C ₄ alkyl.

The preferred of R ₂₄ is as given for R ₁₉ and R ₂₀ . The preferred of R ₂₅ is as given for R ₁₇ .

R ₂₆ is, for example, hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₂ -C ₂₀ alkyl, heterogeneously having one or more O or CO; or phenyl-C ₁ - a C ₄ alkyl group, a C ₃ -C ₈ cycloalkyl group optionally having one or more O or CO; or a (CO)R ₁₉ or phenyl group which is unsubstituted or has one or more of the following groups Substitution: C ₁ -C ₂₀ alkyl, halogen, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ .

Or R ₂₆ represents, for example, hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl; phenyl-C ₁ -C ₄ alkyl, C ₃ -C ₈ cycloalkyl, (CO)R ₁₉ or a phenyl group which is unsubstituted or substituted by one or more C ₁ -C ₂₀ alkyl groups. Further, R ₂₆ is, for example, hydrogen or a C ₁ -C ₂₀ alkyl group, especially a C ₁ -C ₄ alkyl group.

An example of the photoinitiator (E-1) having the structure of the formula (VIII) of the present invention is as follows:

The photoinitiator (E-1) having the structure represented by the formula (VIII) is used for photopolymerization of a composition comprising at least one ethylenically unsaturated photopolymerizable compound.

In a specific example of the present invention, the total amount of the alkali-soluble resin (C) used is 100 parts by weight, and the photoinitiator (E-1) having the structure represented by the formula (VIII) is used in an amount of 2 parts by weight. The portion is 20 parts by weight, preferably 2 parts by weight to 15 parts by weight, more preferably 2 parts by weight to 10 parts by weight. When the photoinitiator (E-1) having the structure represented by the formula (VIII) is used, the ITO sputtering suitability of the pixel layer produced by the blue photosensitive resin composition is preferable.

The photoinitiator (E) may further comprise other radical type photoinitiators (E-2).

The other radical type photoinitiator (E-2) may be selected from the group consisting of an acetophenone compound, a biimidazole compound, an acyl oxime compound, or a combination thereof.

The above acetophenone-based compound is selected from the group consisting of p-dimethylamino-acetophenone, α,α'-dimethoxyoxo acetophenone (α,α'-dimethoxyazoxy-acetophenone). , 2,2'-dimethyl-2-phenyl-acetophenone, p-methoxy-acetophenone, 2- Methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone, 2- Benzyl-2-nitrogen, nitrogen-dimethylamine-1-(4-morpholinophenyl)-1-butanone [2-benzyl-2-N, N-dimethylamino-1-(4-morpholinophenyl)- 1-butanone].

The above diimidazole-based compound is selected from 2,2'-bis(o-chlorophenyl)- 4,4',5,5'-o-chlorophenyl-4,4',5,5'-tetraphenyl-biimidazole], 2,2'-double ( O-fluorophenyl)-4,4,5,5'-tetraphenyl-biimidazole, 2,2'-bis(o-fluorophenyl)-4,4',5,5'-tetraphenyl-biimidazole , 2'-bis(o-methylphenyl)-4,4',5,5'-tetraphenyldiimidazole [2,2'-bis(o-methyl phenyl)-4,4',5, 5'-tetraphenyl-biimidazole], 2,2'-bis(o-methoxyphenyl)-4,4',5,5'-tetraphenyldiimidazole [2,2'-bis(o-methoxyphenyl) -4,4',5,5'-tetraphenyl-biimidazole], 2,2'-bis(o-ethylphenyl)-4,4',5,5'-tetraphenyldiimidazole [2, 2'-bis(o-ethylphenyl)-4,4',5,5'-tetraphenyl-biimidazole], 2,2'-bis(p-methoxyphenyl)-4,4',5,5'- 2,2'-bis(p-methoxyphenyl)-4,4',5,5'-tetraphenyl-biimidazole], 2,2'-bis(2,2',4,4'- Tetramethoxyphenyl)-4,4',5,5'-tetraphenyldiimidazole [2,2'-bis(2,2',4,4'-tetramethoxyphenyl)-4,4',5 , 5'-tetraphenyl-biimidazole], 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-biimidazole], 2,2'-bis(2,4-dichlorophenyl)-4,4' , 5,5'-tetraphenyl-biimidazole [2,2'-bis(2,4-dichlorophenyl)-4,4',5,5'-tetraphenyl-biimidazole].

The above lanthanide compound is selected from the group consisting of ethane ketone, 1-[9-ethyl-6-(2-methylbenzylidenyl)-9hydro-oxazol-3- substituent]-, 1- (Ethanone, 1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazole-3-yl]-, 1-(O-acetyl oxime), for example, manufactured by Ciba Specialty Chemicals The product name is CGI-242, and its structure is as shown in the following formula (32)], 1-[4-(phenylthio)phenyl]-octane-1,2-dione 2-(O-benzoinyl) [1-[4-(benzoyl)phenyl]-heptane-1,2-dione 2-(O-benzoyloxime), for example, a product of the trade name CGI-124 manufactured by Ciba Specialty Chemicals, having the following structure (33) ), ethane ketone, 1-[9-ethyl-6-(2-chloro-4-benzyl-thio-benzhydryl)-9hydro-indazole-3-substituent] -, 1-(9-ethyl-6-(2-cholro-4-benzyl-thio-benzoyl)-9H-carbazole-3-yl]-, 1-((Ethone) O-acetyl oxime), for example, manufactured by Asahi Kasei Co., Ltd., has the structure shown in the following formula (34):

Preferably, the other radical photoinitiator (E-2) is 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-propanone, 2-benzyl Base-2-nitrogen, nitrogen-dimethylamine-1-(4-morpholinophenyl)-1-butanone, 2,2'-bis(o-chlorophenyl)-4,4',5, 5'-tetraphenyldiimidazole, ethyl ketone, 1-[9-ethyl-6-(2-methylbenzylidenyl)-9hydro-oxazol-3-substituted group]-, 1-( Oxygen-acetamidine) or a combination of these.

The other radical type photoinitiator (E-2) of the present invention may further contain the following compounds: thioxanthone, 2,4-diethyl-thioxanthanone, Thioxanthone-4-sulfone, benzophenone, 4,4'-bis(dimethylamino)benzophenone a benzophenone compound such as 4,4'-diethylaminobenzophenone; benzil or acetamidine Alpha-diketone compound (acetyl) a acyloin compound such as benzoin; benzoin methylether, benzoin ethylether, benzoin isopropyl Ethyl ether ether acyloin ether compound; 2,4,6-trimethyl-benzoyl-diphenyl-phosphine oxide, bis-( 2,6-dimethoxybenzoquinone-2,4,4-trimethoxy-benzoyl-2,4,4-trimethyl-benzyl-phosphineoxide And other acylphosphine oxide compounds; quinone compounds such as anthraquinone, 1,4-naphthoquinone, etc.; phenacyl chloride; , a halide of tribromomethyl-phenylsulfone, tris(trichloromethyl)-s-triazine, etc.; and di-tertiary butyl peroxide (di-tertbutylperoxide) and the like. Among them, a benzophenone-based compound is preferred, and 4,4'-bis(diethylamine)benzophenone is particularly preferred.

When the photoinitiator (E-1) having the structure of the formula (VIII) and other radical photoinitiator (E-2) are used in combination, the blue photosensitive resin composition is used. The ITO sputtering of the pixel layer is more suitable.

In the preparation of the blue photosensitive resin composition for a color filter of the present invention, usually, each component other than the organic pigment (A) is first dissolved in an organic solvent (F) to prepare a liquid composition, and then added. The organic pigment (A) is uniformly mixed. The organic solvent (F) is selected to dissolve the dye (B), the alkali-soluble resin (C), the ethylenically unsaturated group (D), and the photoinitiator (E), and is not required to interact with the components. The reaction is carried out with appropriate volatility.

In a specific example of the present invention, the total amount of the alkali-soluble resin (C) used is 100 parts by weight, and the organic solvent (F) is used in an amount ranging from 500 parts by weight to 5,000 parts by weight; preferably 550. The parts by weight are 4,500 parts by weight; more preferably 600 parts by weight to 4,000 parts by weight.

Further, the organic solvent (F) can be prepared by preparing the alkali-soluble resin (C) The solvent used is the same and will not be described here. Preferably, the organic solvent (F) is selected from propylene glycol methyl ether acetate or ethyl 3-ethoxypropionate.

Preferably, the blue photosensitive resin composition for a color filter according to the present invention may further contain a functional additive (G).

The functional additive (G) may be used singly or in combination, and the functional additive (G) includes, but is not limited to, a filler such as glass or aluminum; polyvinyl alcohol, polyethylene glycol monoalkyl ether, polyfluoroacrylic acid Alkali-soluble resin such as alkyl ester (polymer compound other than C; vinyl trimethoxy decane, vinyl triethoxy decane, vinyl tris(2-methoxyethoxy) decane, nitrogen-(2-amino group) Ethyl)-3-aminopropylmethyldimethoxydecane, nitrogen-(2-aminoethyl)-3-aminopropyltrimethoxydecane, 3-aminopropyltriethoxylate Decane, 3-glycidylpropyltrimethoxydecane, 3-glycidylpropylmethyldimethoxydecane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, 3-chloropropylmethyldimethoxydecane, 3-chloropropyltrimethoxydecane, 3-methylpropoxypropyltrimethoxydecane, 3-thiolpropyltrimethoxydecane, etc. Promoter; 2,2-thiobis(4-methyl-6-tert-butylphenol), 2,6-di-tert-butylphenol and other antioxidants; 2-(3-tert-butyl a UV absorber such as -5-methyl-2-hydroxyphenyl)-5-chlorophenyl azide or alkoxyphenone; Anti-aggregating agent and sodium methacrylate.

The present invention also provides a method of producing a color filter, which comprises forming a pixel layer using a blue photosensitive resin composition using the color filter described above.

The present invention further provides a color filter which is produced by the aforementioned method.

Preferably, the color filter includes a pixel layer, and the pixel layer is formed using the photosensitive resin composition for the color filter.

The method for forming a color filter of the present invention is mainly a method of mixing into a solution state by a coating method such as rotary coating, cast coating, ink-jet coating or roll coating. The color filter is coated on the substrate with a photosensitive composition. After coating, Most of the solvent is removed by drying under reduced pressure, and the solvent is removed by pre-bake to form a pre-baked film. The conditions for drying under reduced pressure and pre-baking vary depending on the type of each component and the blending ratio. Usually, the drying under reduced pressure is carried out at a pressure of 0 to 200 mmHg for 1 second to 60 seconds, and the pre-baking is It is carried out at a temperature of 70 to 110 ° C for 1 minute to 15 minutes. After prebaking, the prebaked coating film is exposed to a designated mask, immersed in a developing solution at a temperature of 23 ± 2 ° C for 15 seconds to 5 minutes for development, and the unnecessary portion is removed to form a pattern. The light used for exposure is preferably ultraviolet rays such as g-line, b-line, and i-line, and the ultraviolet device may be a (ultra) high-pressure mercury lamp or a metal halide lamp.

Specific examples of the substrate include: alkali-free glass, soda-lime glass, hard glass (Pyrus glass), quartz glass, and the like, and a transparent conductive film attached to the glass; or a solid-state imaging device; A photoelectric conversion device substrate (such as a germanium substrate) or the like. These substrates generally form a black matrix that separates the colored layers of each pixel.

Further, specific examples of the developer include: sodium hydroxide, potassium hydroxide, sodium carbonate, sodium hydrogencarbonate, potassium carbonate, potassium hydrogencarbonate, sodium citrate, sodium methyl citrate, ammonia, ethylamine, diethylamine, Dimethylethanolamine, tetramethylammonium hydroxide, tetraethylammonium hydroxide, choline, pyrrole, acridine, 1,8-diazabicyclo-(5,4,0)-7-undecene The alkaline aqueous solution of the compound is generally present in a concentration of from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, more preferably from 0.01 to 1% by weight.

When the developer composed of the alkaline aqueous solution is used, it is usually washed with water after development, and then air-dried with compressed air or compressed nitrogen.

After drying, the substrate having the photo-curing coating layer is heated by a heating means such as a hot plate or an oven at a temperature of 100 to 280 ° C for 1 to 15 minutes to remove volatile components in the coating film, and the coating film is not The reacted ethylenically unsaturated double bond undergoes a thermosetting reaction. The photosensitive resin composition of each color (mainly including red, green, and blue colors) is repeatedly operated in the same step on the predetermined pixel three times to obtain red, green, and blue colors. Light hardened pixel coloring layer.

Next, on the pixel colored layer, an ITO (indium tin oxide) deposited film is formed under vacuum at a temperature of 220 ° C to 250 ° C, and if necessary, after etching and wiring the ITO deposited film, the liquid crystal alignment film is coated. The quinone imine, which is then fired, can be used as a color filter for liquid crystal displays.

It is still another object of the present invention to provide a liquid crystal display device comprising the aforementioned color filter.

The liquid crystal display device of the present invention is mainly composed of a color filter substrate formed by the above-described color filter forming method and a driving substrate provided with a thin film transistor (TFT), wherein The inter-substrate gap (cell gap) is arranged in the opposite direction, and the peripheral portions of the two substrates are bonded together with a sealing agent, and the liquid crystal is filled in the gap between the surface of the substrate and the sealing agent to seal the injection. The holes constitute a liquid crystal cell. Then, a polarizing plate is bonded to the outer surface of the liquid crystal cell, that is, the other side surface of each of the substrates constituting the liquid crystal cell, to obtain a liquid crystal display element.

The invention is illustrated by the following examples, which are not intended to be limited to the scope of the invention.

Preparation Examples 1 to 5: Synthesis of a monomer represented by the formula (III)

According to Japanese Patent Laid-Open No. Hei 10-226669, 1,4-diazabicyclo[2.2.2]octane is used as a catalyst, as shown in Table 1, from allyl alcohol and corresponding α-hydroxymethyl groups. Acrylate (HMA-R) to synthesize the monomer of formula (III).

Synthesis Example 1: Method for Producing First Alkali Soluble Resin (C-1-1)

A stirrer, thermometer, condenser, and nitrogen inlet were placed on a four-necked flask and nitrogen was introduced. Then, 100 parts by weight of propylene glycol monomethyl ether acetate was added, and the temperature was raised to 100 °C. Next, 5 parts by weight of α-allyloxymethyl methacrylate (AMA-M) obtained in Preparation Example 1, 40 parts by weight of methacrylic acid (abbreviated as MAA), and 10 parts by weight of methacrylic acid 2 were added. -hydroxyethyl ester (abbreviated as HEMA), 40 parts by weight of benzyl methacrylate (abbreviated as BzMA) and 5 parts by weight of isobornyl methacrylate (abbreviated as IBOMA) and 4 parts by weight of azobis The valeronitrile was dissolved in 100 parts by weight of propylene glycol monomethyl ether acetate, and the mixed solution was dropwise added to a four-necked flask over 2 hours. After reacting at 100 ° C for 6.5 hours, 15 parts by weight of glycidyl methacrylate (abbreviated as GMA) and 10 parts by weight of -6,7-epoxyheptyl methacrylate (abbreviated as EP-MA) were added. In a four-necked flask filled with nitrogen, the temperature was raised to 110 °C. After reacting for 6 hours, the first alkali-soluble resin (C-1-1) of Synthesis Example 1 was obtained.

Synthesis Examples 2 to 6: Method for Producing First Alkali Soluble Resin (C-1-2) to (C-1-6)

Synthesis Examples C-1-2 to C-1-6 The first alkali-soluble resin (C-1) was prepared in the same manner as in Synthesis Example C-1-1 except that the kind of the component was changed, The amount used and the reaction conditions are detailed in Table 2.

Synthesis Example 7: Method for Producing Second Alkali Soluble Resin (C-2-1)

100 parts by weight of an antimony epoxy compound (Model ESF-300, manufactured by Nippon Steel Chemical Co., Ltd.; epoxy equivalent 231), 30 parts by weight of acrylic acid, 0.3 parts by weight of benzyltriethylammonium chloride, 0.1 part by weight 2,6-di-t-butyl-p-cresol and 130 parts by weight of propylene glycol methyl ether acetate were continuously added to a 500-mL four-necked flask, and the feed rate was controlled at 25 parts by weight/min, and the temperature was maintained at 100 ° C. After reacting for 15 hours in the range of 110 ° C, a pale yellow transparent mixture having a solid concentration of 50% by weight was obtained.

Next, 100 parts by weight of the above mixture was dissolved in 25 parts by weight of ethylene glycol ethyl ether acetate, while 6 parts by weight of tetrahydrophthalic anhydride and 13 parts by weight of benzophenone tetracarboxylic dianhydride were added. And heating to 110 ° C to 115 ° C, after reacting for 2 hours, a second alkali-soluble resin (C-2-1) having an acid value of 98.0 mgKOH/g and a number average molecular weight of 1,623 was obtained.

Synthesis Example 8: Method for Producing Second Alkali Soluble Resin (C-2-2)

100 parts by weight of an antimony epoxy compound (Model ESF-300, manufactured by Nippon Steel Chemical Co., Ltd.; epoxy equivalent 231), 30 parts by weight of acrylic acid, 0.3 parts by weight of benzyltriethylammonium chloride, 0.1 part by weight 2,6-di-t-butyl-p-cresol and 130 parts by weight of propylene glycol methyl ether acetate were continuously added to a 500-mL four-necked flask, and the feed rate was controlled at 25 parts by weight/min, and the temperature was maintained at 100 ° C. After reacting for 15 hours in the range of 110 ° C, a pale yellow transparent mixture having a solid concentration of 50% by weight was obtained.

Next, 100 parts by weight of the above mixture was dissolved in 25 parts by weight of ethylene glycol ethyl ether acetate, while 13 parts by weight of benzophenone tetracarboxylic dianhydride was added, and the reaction was carried out at 90 ° C to 95 ° C for 2 hours. Next, 6 parts by weight of tetrahydrophthalic anhydride is added and reacted at 90 ° C to 95 ° C for 4 hours to obtain a second alkali-soluble resin having an acid value of 99.0 mgKOH/g and a number average molecular weight of 2,162. (C-2-2).

Synthesis Example 9: Method for Producing Second Alkali Soluble Resin (C-2-3)

400 parts by weight of epoxy compound (Model NC-3000, Nippon Chemical Manufactured by the company; epoxy equivalent 288), 102 parts by weight of acrylic acid, 0.3 parts by weight of methoxyphenol, 5 parts by weight of triphenylphosphine, and 264 parts by weight of propylene glycol methyl ether acetate. In the bottle, the temperature was maintained at 95 ° C, and after 9 hours of reaction, an intermediate product having an acid value of 2.2 mg KOH / g was obtained. Next, 151 parts by weight of tetrahydrophthalic anhydride was added and reacted at 95 ° C for 4 hours to obtain a second alkali-soluble resin having an acid value of 102 mgKOH/g and a number average molecular weight of 2,589 ( C-2-3).

Synthesis Example 10: Method for Producing Third Alkali Soluble Resin (C-3-1)

1 part by weight of 2,2'-azobisisobutyronitrile, 240 parts by weight of propylene glycol methyl ether acetate, 30 parts by weight of 2-methylpropenyl ethoxy succinate (referred to as HOMS), 10 parts by weight of 2-hydroxyethyl methacrylate (abbreviated as HEMA), 30 parts by weight of isobornyl methacrylate (abbreviated as IBOMA), 10 parts by weight of butadiene, 20 parts by weight of styrene In a round bottom flask equipped with a stirrer and a condenser, the inside of the flask was filled with nitrogen. Then, the mixture was slowly stirred and heated to 80 ° C, and the respective reactants were uniformly mixed and subjected to polymerization for 4 hours. Then, it was further heated to 100 ° C, and 0.5 part by weight of 2,2'-azobisisobutyronitrile was added. After the polymerization reaction was carried out for 1 hour, a third alkali-soluble resin (C-3-1) was obtained.

Synthesis Example 11: Method for producing third alkali-soluble resin (C-3-2)

A stirrer, thermometer, condenser, and nitrogen inlet were placed on a four-necked flask and nitrogen was introduced. Then, 135 parts by weight of propylene glycol monomethyl ether acetate was added, and the temperature was raised to 100 °C. Next, 15 parts by weight of methacrylic acid (abbreviated as MAA), 15 parts by weight of 2-methylpropenyl ethoxy succinate (referred to as HOMS), and 30 parts by weight of benzyl methacrylate ( Abbreviated as BzMA), 20 parts by weight of isobornyl methacrylate (abbreviated as IBOMA), 20 parts by weight of styrene and 2.6 parts by weight of azobisisobutyronitrile dissolved in 100 parts by weight of propylene glycol monomethyl ether acetate. And the mixed solution was dropped into a four-necked flask in 2 hours. After reacting at 100 ° C for 5 hours, 10 parts by weight of A Glycidyl acrylate (abbreviated as GMA) and 5 parts by weight of -6,7-epoxyheptyl methacrylate were added to a four-necked flask filled with nitrogen and the temperature was raised to 110 °C. After reacting for 6 hours, a third alkali-soluble resin (C-3-2) was obtained.

Example 1:

100 parts by weight of the first alkali-soluble resin (C-1-1) obtained in the above Synthesis Example, 50 parts by weight of the organic pigment (A-1), 10 parts by weight of the dye (B-1), and the formula (VII) a compound (wherein t is 1, b is 3, c is 3, and both Z ¹ and Z ² are hydrogen) (hereinafter referred to as D-1-1) 10 parts by weight, dipentaerythritol hexaacrylate (hereinafter referred to as D-2-1) 40 parts by weight, E-1-1 1 part by weight, 1-[4-(phenylthio)phenyl]-1,2-octanedione 2-(O-benzohydrazide) (hereinafter referred to as E -2-1) 15 parts by weight, 500 parts by weight of an organic solvent 3-ethoxypropionate ethyl ester (hereinafter referred to as F-1) was added, and then dissolved and mixed by a shaking stirrer to prepare a color filter. The photosensitive resin composition for a light sheet was used, and the blue photosensitive resin composition of this color filter was evaluated by the following measurement evaluation methods, and the results are shown in Table 3.

Examples 2 to 13 and Comparative Examples 1 to 7:

Examples 2 to 13 and Comparative Examples 1 to 7 used the same operation method as the method for producing a blue photosensitive resin composition for a color filter of Example 1, except that Examples 2 to 13 and Comparative Example 1 were used. The type and amount of the raw materials in the blue photosensitive resin composition for the color filter were changed, and the formulation and the following evaluation results are shown in Tables 3 and 4.

In Tables 3 and 4:

Evaluation method:

Compared:

The photosensitive resin composition was applied by spin coating to a glass substrate of 100 mm × 100 mm, and dried under reduced pressure at a pressure of 100 mmHg for 30 seconds, and then pre-baked at a temperature of 80 ° C and time 2 In a minute, a pre-baked film having a film thickness of 2.5 μm can be formed. Further, the prebaked coating film was irradiated with ultraviolet light (exposure machine Canon PLA-501F) at a light amount of 100 mJ/cm ² , and then the prebaked coating film was further immersed in a developing solution at 23 ° C for 1 minute, and washed with pure water.

Next, after baking at 235 ° C for 30 minutes, a photosensitive resin layer having a film thickness of 2.0 μm was formed on the glass substrate.

From the obtained photosensitive resin layer, the luminance measured by the method shown in FIGS. 1 and 2 is calculated and compared; wherein the obtained photosensitive resin layer 1 is placed between the two polarizing plates 2 and 3, and the light source is obtained from the light source. The light emitted by the fourth light is sequentially transmitted through the polarizing plate 2, the photosensitive resin layer 1, and the polarizing plate 3, and finally the luminance (cd/cm ² ) transmitted through the polarizing plate 3 is measured by a luminance meter 5 (manufactured by Japan Topcon Co., Ltd., model BM). -5A) Take measurements.

As shown in FIG. 1, when the polarizing direction of the polarizing plate 3 and the polarizing direction of the polarizing plate 2 are parallel to each other, the measured luminance is A (cd/cm ² ); in addition, as shown in FIG. 2, when the polarizing plate 3 is used When the polarization direction is perpendicular to the polarization direction of the polarizing plate 2, the measured luminance is B (cd/cm ² ); the contrast can be obtained by the ratio of luminance A to luminance B (luminance A/luminance B). The evaluation criteria are as follows.

◎: (luminance A / luminance B) ≧ 3500

○: 3300 ≦ (luminance A / luminance B) < 3500

△: 3000 ≦ (luminance A / luminance B) < 3300

×: (luminance A/luminance B) <3000

Pigment dispersion:

A photosensitive resin composition containing no photopolymerization initiator was prepared, and after completion of the preparation, it was allowed to stand in a thermostat at 40 ° C for 7 days, and then measured by an E-type viscosity meter, and the evaluation criteria were as follows.

◎: viscosity change rate <15%

○: 15% < viscosity change rate <20%

△: 20% < viscosity change rate <25%

×: 25% <viscosity change rate

ITO sputtering suitability:

The ITO was subjected to vapor deposition (film thickness: 1400 Å; vapor deposition temperature: 200 ° C) according to a conventional method, and then Ra value was measured by an atomic force microscope (SPA-400 AFM, manufactured by Seiko Instruments Inc.), and the evaluation criteria were as follows.

◎: Ra<3nm

○: 3 nm < Ra < 8 nm

△: 8 nm < Ra < 10 nm

×: 10 nm < Ra

The above-described embodiments are merely illustrative of the principles and effects of the invention, and are not intended to limit the invention. Modifications and variations of the embodiments described above will be apparent to those skilled in the art without departing from the spirit of the invention. The scope of the invention should be as set forth in the appended claims.

1‧‧‧Photosensitive resin layer

2‧‧‧Polar plate

3‧‧‧Polar plate

4‧‧‧Light source

5‧‧‧luminometer

Claims (17)

A blue photosensitive resin composition for a color filter comprising: an organic pigment (A); a dye (B); an alkali-soluble resin (C); an ethylenically unsaturated group-based compound (D); a photoinitiator (E); and an organic solvent (F); wherein: the dye (B) comprises a red dye (B-1) having the structure represented by the formula (I): In the formula (I), B ¹ to B ⁴ each independently represent hydrogen, -B ⁶ , a C ₆ to C ₁₀ aromatic hydrocarbon group, or a halogen atom, -B ⁶ , -OH, -OB ⁶ , -SO ₃ ^- , -SO ₃ H, -SO ₃ M, -COOH, -COOB ⁶ , -SO ₃ B ⁶ , -SO ₂ NHB ⁸ or -SO ₂ NB ⁸ B ⁹ substituted C ₆ to C ₁₀ aromatic hydrocarbon group; B ⁵ represents -SO ₃ ^- , -SO ₃ H, -SO ³ M, -COOH, -COOR ⁶ , -SO ₃ R ⁶ , -SO ₂ NHR ⁸ or -SO ₂ NR ⁸ R ⁹ ;s represents an integer from 0 to 5; When s represents 2 to 5, plural B ⁵ are the same or different; T represents a halogen atom; a represents 0 or 1; B ⁶ represents a C ₁ to C ₁₀ alkyl group or a halogen atom substituted C ₁ to C ₁₀ the alkyl group, wherein the C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of the in -CH ₂ - not based substitution or replaced by -O-, or a carbonyl group -NB ⁷ -; B ⁷ represents C ₁ to C ₁₀ alkyl group of the halogen atom or substituted C ₁ to C ₁₀ alkyl group of; B ⁸ and B ⁹ represent each independently a straight chain of C ₁ to C ₁₀ -alkyl, C ₁ a branched alkyl group to C ₁₀ , a C ₃ to C ₃₀ cycloalkyl group, or -Q; wherein, a C ₁ to C ₁₀ linear alkyl group, a C ₁ to C ₁₀ branched alkyl group or C ₃ to based hydrogen atom of the C ₃₀ cycloalkyl group without taking the Or substituted by a substituent, the substituent group selected from the group consisting of a hydroxyl group, a halogen atom, -Q, -CH = CH ₂ and -CH = CH-B consisting of ^6; C straight chain alkyl of ₁ to C ₁₀ The -CH ₂ - in the C ₁ to C ₁₀ branched alkyl group or the C ₃ to C ₃₀ cycloalkyl group is unsubstituted or substituted with -O-, carbonyl or -NB ⁷ -; or B ⁸ and B ⁹ combined to form a C ₁ to C ₁₀ heterocyclic group, the heterocyclic group wherein the C ₁ to C ₁₀ of a hydrogen atom in the unsubstituted or line B ^6, -OH, substituted or -Q; Q represents C ₆ to C ₁₀ aromatic hydrocarbon group, the hetero-aromatic C ₅ to C ₁₀ group, the halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 or -CH = CH-B ^{6-substituted} the C ₆ to C ₁₀ aromatic hydrocarbon group of, or a halogen ^{atom, -B 6, -OH, -OB 6} , -NO 2, -CH = CH 2 and -CH = CH-B of the substituted C ⁶ to C _{10. 5} a heteroaromatic group; and M represents potassium or sodium; and the alkali-soluble resin (C) comprises a first alkali-soluble resin (C-1) having the formula (II) Structure: Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ . The blue photosensitive resin composition for a color filter according to claim 1, wherein the first alkali-soluble resin (C-1) is polymerized by the monomer (c-1) represented by the formula (III). Have Wherein L represents a hydrogen atom or an organic group of C ₁ to C ₃₀ . The blue photosensitive resin composition for a color filter according to claim 2, wherein the first alkali-soluble resin (C-1) contains an ethylenically unsaturated group, and the first alkali-soluble resin (C-1) is From the monomer (c-1) represented by the formula (III), the ethylenically unsaturated monomer (c-2) having one or more carboxylic acid groups, and other copolymerizable ethylenically unsaturated monomers ( C-3) A copolymer obtained by copolymerization is obtained by reacting an ethylenically unsaturated monomer (c-4) having an epoxy group. The blue photosensitive resin composition for a color filter according to claim 1, wherein the first alkali-soluble resin (C-1) is used based on the total amount of the alkali-soluble resin (C) used in an amount of 100 parts by weight. The amount is from 5 parts by weight to 100 parts by weight. A blue photosensitive resin composition for a color filter according to claim 1, wherein the alkali-soluble resin (C) further comprises a second alkali-soluble resin (C-2), the second alkali-soluble resin (C- 2) obtained by polymerizing a mixture of an epoxy resin (c1) having at least two epoxy groups and a compound (c2) having at least one carboxylic acid group and at least one ethylenically unsaturated group, A blue photosensitive resin composition for a color filter according to claim 5, wherein the epoxy resin (c1) having at least two epoxy groups has a structure represented by the following formula (V) or formula (VI): Wherein: R ⁶¹ , R ⁶² , R ⁶³ and R ⁶⁴ are independently selected from the group consisting of hydrogen, halogen and C ₁ to C ₅ alkyl; Wherein R ⁶⁵ to R ⁷⁸ are independently selected from the group consisting of hydrogen, halogen, C ₁ to C ₈ alkyl and C ₆ to C ₁₅ aromatic groups; and n represents an integer of 0 to 10. The blue photosensitive resin composition for a color filter according to claim 6, wherein the second alkali-soluble resin (C-2) is used based on the total amount of the alkali-soluble resin (C) used in an amount of 100 parts by weight. The amount is from 0 part by weight to 95 parts by weight. A blue photosensitive resin composition for a color filter according to claim 1, wherein the ethylenically unsaturated group-containing compound (D) comprises a first ethylenically unsaturated group-containing compound (D-1), the first The ethylenically unsaturated group compound (D-1) has a structure represented by the formula (VII): Wherein: Z ¹ and Z ² each independently represent hydrogen or methyl; t represents an integer from 1 to 2; and b represents an integer from 1 to 6; c represents from 0 to 5 to an integer, wherein the sum of b and c is 2 An integer of up to 6. The blue photosensitive resin composition for a color filter according to claim 8, wherein the first ethylenically unsaturated group-based compound (D- based on the total amount of the alkali-soluble resin (C) used is 100 parts by weight. 1) The amount used is from 10 parts by weight to 50 parts by weight. A blue photosensitive resin composition for a color filter according to claim 1, wherein the photoinitiator (E) comprises a photoinitiator (E-1) having a structure represented by the formula (VIII): Wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, C ₁ -C ₂₀ alkyl, , COR ₁₆ , OR ₁₇ , halogen, NO ₂ or Or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are each independently Substituted C ₂ -C ₁₀ alkenyl; or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are independently of each other Is -(CH ₂ ) _p -Y-(CH ₂ ) _q -; or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ And R ₈ are mutually independent However, the condition is at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R _{8 , R 9, R 10, R} 11 and R ₁₂ are independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂₀ alkyl group which is unsubstituted or line ₁ -C one another by one or more of the following radicals: halogen , phenyl, CN, OH, SH, C ₁ -C ₄ -alkoxy, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ independently of each other as an unsubstituted phenyl group or a phenyl group substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, CN, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ are, independently of each other, halogen, CN, OR ₁₇ , SR ₁₈ , SOR ₁₈ , SO ₂ R ₁₈ or NR ₁₉ R ₂₀ , wherein the substituents OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ optionally forms a 5- or 6-membered ring with one of the carbon atoms of the naphthyl ring via the groups R ₁₇ , R ₁₈ , R ₁₉ and/or R ₂₀ ; or R ₉ , R ₁₀ , R ₁₁ and R ₁₂ Independent of each other , COR ₁₆ or NO ₂ ; Y series O, S, NR ₂₆ or direct bond; p is an integer 0, 1, 2 or 3; q is an integer 1, 2 or 3; X is CO or direct bond; R ₁₃ is C _{a 1-} C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, R ₁₇ , COOR ₁₇ , OR ₁₇ , SR ₁₈ , CONR ₁₉ R ₂₀ , NR ₁₉ R ₂₀ , PO (OC _k H _2k+1 ) ₂ or Or R ₁₃ is a C ₂ -C ₂₀ alkyl group with one or more of O, S, SO, SO ₂ , NR ₂₆ or CO, or a C ₂ -C ₁₂ alkenyl group, which is unintercalated or heterozygous One or more O, CO or NR ₂₆ , wherein the inter-hetero C ₂ -C ₂₀ alkyl group and the uninter or hetero-hetero C ₂ -C ₁₂ alkenyl group are unsubstituted or have one or more halogens Substituted; or R ₁₃ is a C ₄ -C ₈ cycloalkenyl group, a C ₂ -C ₁₂ alkynyl group or a C ₃ -C ₁₀ cycloalkyl group having one or more O, S, CO or NR ₂₆ without inter or hetero-hetero; Or R ₁₃ is a phenyl or naphthyl group, each of which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ , _{, COR 16, CN, NO 2} , halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, interrupted by one or more O, S, CO or NR C ₂₆ of ₂ -C ₂₀ alkyl group; or via their respective C ₃ -C ₁₀ cycloalkyl, or interrupted by one or more O, S, CO or NR ₂₆ of the C ₃ -C ₁₀ cycloalkyl; based integer k 1 to 10; R ₁₄ type hydrogen, C ₃ a -C ₈ cycloalkyl, C ₂ -C ₅ alkenyl, C ₁ -C ₂₀ alkoxy or C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, Phenyl, C ₁ -C ₂₀ alkylphenyl or CN; or R ₁₄ -phenyl or naphthyl, each unsubstituted or substituted by one or more of the following groups: C ₁ -C ₆ alkyl, C _1- C ₄ haloalkyl, halogen, CN, OR ₁₇ , SR ₁₈ and/or NR ₁₉ R ₂₀ ; or R ₁₄ C ₃ -C ₂₀ heteroaryl, C ₁ -C ₈ alkoxy, benzyloxy or phenoxy, benzyloxy and phenoxy which is unsubstituted or substituted with one line or more of the following groups: C ₁ -C ₆ alkyl, C ₁ -C ₄ haloalkyl and / or halogen; R ₁₅ lines a C ₆ -C ₂₀ aryl or C ₃ -C ₂₀ heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkyl, CN, NO ₂ , OR ₁₇ , S R ₁₈ , NR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , SO-C ₁ -C ₁₀ alkyl, SO ₂ -C ₁ -C ₁₀ alkyl, hetero or one or more O, S or NR the ₂ -C ₂₀ C ₂₆ alkyl group; or each warp substituted C ₁ -C ₂₀ alkyl, C ₂₀ alkyl group which line ₁ -C unsubstituted or substituted by one or more of the following radicals: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ is hydrogen, C ₂ -C ₁₂ alkenyl, unmixed or heterozygous with one or more O, CO or NR ₂₆ C ₃ -C ₈ cycloalkyl; or R _{a 15} series C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, OR ₁₇ , SR ₁₈ , C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl a C ₆ -C ₂₀ aryloxycarbonyl group, a C ₃ -C ₂₀ heteroaryloxycarbonyl group, NR ₁₉ R ₂₀ , COOR ₁₇ , CONR ₁₉ R ₂₀ , PO(OC _k H _2k+1 ) ₂ , , Or a phenyl group; or the C ₁ -C ₂₀ alkyl group is substituted by a phenyl group which is halogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R _{20 is} substituted; or R ₁₅ is a C ₂ -C ₂₀ alkyl group in which one or more O, SO or SO ₂ are heterogeneous, and the interstitial C ₂ -C ₂₀ alkyl group is unsubstituted or one or more Substituted by: halogen, OR ₁₇ , COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl or phenyl substituted with OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ C ₂ -C ₂₀ alkyl fluorenyl Or benzhydryl, which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ a naphthylmethyl group or a C ₃ -C ₁₄ heteroarylcarbonyl group which is unsubstituted or substituted with one or more OR ₁₇ ; or an R ₁₅ C ₂ -C ₁₂ alkoxycarbonyl group which is uninterfering or heterozygous One or more O and the inter- or un-doped C ₂ -C ₁₂ alkoxycarbonyl group is unsubstituted or substituted with one or more hydroxyl groups; or the R ₁₅ -based phenoxycarbonyl group is unsubstituted Or substituted by one or more of the following groups: C ₁ -C ₆ alkyl, halogen, C ₁ -C ₄ haloalkyl, Phenyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₅ based CN, CONR ₁₉ R ₂₀ , NO ₂ , C ₁ -C ₄ haloalkyl, S(O) _m -C ₁ -C ₆ alkyl, S(O) _m -phenyl unsubstituted or substituted with C ₁ -C ₁₂ alkyl or SO ₂ -C ₁ -C ₆ alkyl; or R ₁₅ -based SO ₂ O-phenyl, which is unsubstituted or by C ₁ -C ₁₂ substituted alkyl; or based diphenylphosphino acyl or di (C ₁ -C ₄ alkoxy) - phosphino acyl; m lines 1 or 2; R _'14 R ₁₄ having the targeted Give one of the meanings; R' ₁₅ has one of the meanings given for R15; X ₁ is O, S, SO or SO ₂ ; X ₂ is O, CO, S or direct bond; R ₁₆ a C ₆ -C ₂₀ aryl or C ₃ -C ₂₀ heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkyl, CN, NO _{2, oR 17, SR 18,} NR 19 R 20 or interrupted by one or more O, S or NR C ₂₆ of ₁ -C ₂₀ alkyl group; or each with one or more C ₁ -C ₂₀ alkyl, The C ₁ -C ₂₀ alkyl group is unsubstituted or substituted with one or more of the following groups: halogen, COOR ₁₇ , CONR ₁₉ R ₂₀ , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ Heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₃ - C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or R ₁₆ hydrogen, C ₁ -C ₂₀ alkyl, the C ₁ -C ₂₀ alkyl is unsubstituted or one or more Substituted by the following groups: halogen, phenyl, OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O (C ₁ -C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-phenyl, (CO)OH or (CO)O(C ₁ -C ₄ alkyl); or R ₁₆ C ₂ -C ₁₂ alkyl group with one or more O, S or NR _{26 in between} ; or R ₁₆ system (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₁₂ alkenyl or C ₃ -C ₈ cycloalkyl; or R ₁₆ is a phenyl substituted by SR ₁₈ , wherein the group R ₁₈ represents a bond to the COR ₁₆ group a direct bond of the phenyl or naphthyl ring to which the carbazole moiety is attached; n is 1 to 20; R ₁₇ is hydrogen, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₂₀ alkyl, Unsubstituted or substituted with one or more of the following groups: halogen, OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN, OCH ₂ CH ₂ (CO)O (C ₁ - C ₄ alkyl), O(CO)-(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-phenyl, (CO)OH, ( CO) O (C ₁ -C ₄ alkyl), C ₃ -C _{20 Alkyl, SO 2 - (C 1 -C} 4 haloalkyl), O (C ₁ -C ₄ haloalkyl) or interrupted by one or more O of C ₃ -C ₂₀ cycloalkyl; or R ₁₇ based C ₂ - a C ₂₀ alkyl group having one or more O, S or NR _{26 in between} ; or R ₁₇ (CH ₂ CH ₂ O) _n+1 H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ - C ₈ alkyl), C ₁ -C ₈ alkanoyl, C ₂ -C ₁₂ alkenyl, C ₃ -C ₆ alkenyl or uninter or hetero or one or more O, S, CO or NR ₂₆ a C ₃ -C ₂₀ cycloalkyl group; or an R ₁₇ system C ₁ -C ₈ alkyl-C ₃ -C ₁₀ cycloalkyl group, which is undoped or heterozygous with one or more O; or R ₁₇ is benzamidine a group which is unsubstituted or substituted by one or more C ₁ -C ₆ alkyl, halogen, OH or C ₁ -C ₃ alkoxy groups; or R ₁₇ phenyl, naphthyl or C ₃ -C ₂₀ a heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: halogen, OH, C ₁ -C ₁₂ alkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl- C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N(C ₁ -C ₁₂ alkyl) ₂ , diphenyl-amine or Or R ₁₇ forms a bond to the group or a direct bond of one of the carbon atoms of the phenyl or naphthyl ring; R ₁₈ is hydrogen, C ₂ -C ₁₂ alkenyl, C ₃ -C ₂₀ cycloalkyl or phenyl-C ₁ -C ₃ alkyl Wherein the C ₂ -C ₁₂ alkenyl group, the C ₃ -C ₂₀ cycloalkyl group or the phenyl-C ₁ -C ₃ alkyl group is uninter or hetero- or one or more O, S, CO, NR ₂₆ or COOR ₁₇ ; or R ₁₈ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ CN , OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO)-(C ₂ -C ₄ )alkenyl, O(CO)-(C ₁ -C ₄ alkyl), O (CO)-phenyl or (CO)OR ₁₇ ; or R ₁₈ C ₂ -C ₂₀ alkyl with one or more O, S, CO, NR ₂₆ or COOR ₁₇ ; or R ₁₈ (CH _{2 )} CH ₂ O) _n H, (CH ₂ CH ₂ O) _n (CO)-(C ₁ -C ₈ alkyl), C ₂ -C ₈ alkanoyl or C ₃ -C ₆ olefin; or R ₁₈ Is a benzinyl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₆ alkyl, halogen, OH, C ₁ -C ₄ alkoxy or C ₁ -C ₄ alkyl a thio group; or an R ₁₈ phenyl, naphthyl or C ₃ -C ₂₀ heteroaryl group, each of which is unsubstituted or substituted with one or more of the following groups: halogen, C ₁ -C ₁₂ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₁₂ alkoxy, CN, NO ₂ , phenyl-C ₁ -C ₃ alkoxy, phenoxy, C ₁ -C ₁₂ alkylthio, phenylthio, N(C ₁ -C ₁₂ alkyl) ₂ , diphenylamino, (CO)O(C ₁ -C ₈ alkyl), (CO)-C ₁ - C ₈ alkyl, (CO) N(C ₁ -C ₈ alkyl) ₂ or R ₁₉ and R ₂₀ are each independently hydrogen, C ₁ -C ₂₀ alkyl, C ₂ -C ₄ hydroxyalkyl, C ₂ -C ₁₀ alkoxyalkyl, C ₂ -C ₅ alkenyl, C ₃ - C ₂₀ cycloalkyl, phenyl-C ₁ -C ₃ alkyl, C ₁ -C ₈ alkanoyl, C ₁ -C ₈ alkenyloxy, C ₃ -C ₁₂ alkenyl, SO ₂ -( a C ₁ -C ₄ haloalkyl group or a benzylidene group; or R ₁₉ and R ₂₀ are a phenyl group, a naphthyl group or a C ₃ -C ₂₀ heteroaryl group, each of which is unsubstituted or has one or more of the following groups; Substituted: halogen, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, C ₁ -C ₁₂ alkyl, benzhydryl or C ₁ -C ₁₂ alkoxy; or R ₁₉ and R ₂₀ Together with the N atom to which it is attached, it forms a 5- or 6-membered saturated or unsaturated ring which is not intermixed or interspersed with O, S or NR ₁₇ , and the 5 or 6 member saturated or unsaturated ring system is unsubstituted or Substituted by one or more of the following groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkoxy, =0, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , NO ₂ , Halogen, C ₁ -C ₄ -haloalkyl, CN, phenyl, Or a C ₃ -C ₂₀ cycloalkyl group having one or more O, S, CO or NR ₁₇ without intermixing or intermixing; or R ₁₉ and R ₂₀ together with the N atom to which they are attached form a heteroaromatic ring system, The ring system is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₂₀ alkoxy, =0, OR ₁₇ , SR ₁₈ , NR ₂₁ R ₂₂ , (CO)R ₂₃ , , halogen, NO ₂ , CN, phenyl or a C ₃ -C ₂₀ cycloalkyl group having one or more O, S, CO or NR ₁₇ without inter or hetero or hetero; R ₂₁ and R ₂₂ are each independently hydrogen, C _{a 1-} C ₂₀ alkyl group, a C ₁ -C ₄ haloalkyl group, a C ₃ -C ₁₀ cycloalkyl group or a phenyl group; or R ₂₁ and R ₂₂ together with the N atom to which they are attached form an unintermixed or intervening O, a 5- or 6-membered saturated or unsaturated ring of S or NR26, and the 5- or 6-membered saturated or unsaturated ring system is not fused or the 5- or 6-membered saturated or unsaturated ring is fused to the benzene ring; ₂₃ is hydrogen, OH, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, hetero or one or more O, CO or C ₂ -C ₂₀ alkyl of NR ₂₆ , unintermixed or intervening O, C ₃ -C ₂₀ cycloalkyl of S, CO or NR ₂₆ or R ₂₃ phenyl, naphthyl, phenyl-C ₁ -C ₄ alkyl, OR ₁₇ , SR ₁₈ or NR ₂₁ R ₂₂ ; R ₂₄ (CO)OR ₁₇ , CONR ₁₉ R ₂₀ , (CO)R ₁₇ ; or R ₂₄ having one of the meanings given for R ₁₉ and R ₂₀ ; R ₂₅ is COOR ₁₇ , CONR ₁₉ R ₂₀ , (CO ) R _17; or R ₂₅ R ₁₇ Suo for having one of the meanings given by; R ₂₆ type hydrogen, C ₁ -C ₂₀ alkyl, C ₁ -C ₄ haloalkyl, C ₂ -C ₂₀ alkyl, therebetween One or more O or CO; or a phenyl-based -C ₁ -C ₄ alkyl, C ₃ -C ₈ cycloalkyl, which is based not interrupted or is interrupted by one or more O or CO; or tie (CO) R ₁₉ ; or a phenyl group which is unsubstituted or substituted with one or more of the following groups: C ₁ -C ₂₀ alkyl, halogen, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or But the condition is that at least one group is present in the molecule or A blue photosensitive resin composition for a color filter according to claim 10, wherein the photoinitiator (E) comprises a photoinitiator (E-1) having a structure represented by the formula (VIII), wherein R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, C ₁ - C ₂₀ alkyl, , COR ₁₆ or NO ₂ , or R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ are independently of each other However, the condition is at least one of R ₁ and R ₂ , R ₂ and R ₃ , R ₃ and R ₄ , R ₅ and R ₆ , R ₆ and R ₇ or R ₇ and R ₈ X is a CO or a direct bond; R ₁₃ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: halogen, OR ₁₇ , SR ₁₈ , COOR ₁₇ , CONR ₁₉ R ₂₀ Or PO(OC _k H _2k+1 ) ₂ ; or R ₁₃ C ₂ -C ₂₀ alkyl, in which one or more of O, S, NR ₂₆ or CO are mixed; or R ₁₃ is phenyl or naphthyl, Both are unsubstituted or one or more Or substituted by COR ₁₆ ; R ₁₄ is C ₁ -C ₂₀ alkyl, phenyl or C ₁ -C ₈ alkoxy; R ₁₅ is phenyl, naphthyl, C ₃ -C ₂₀ heteroaryl, each of which is not Substituted or substituted with one or more of the following groups: phenyl, halogen, C ₁ -C ₄ haloalkyl, OR ₁₇ , SR ₁₈ or C ₂ -C ₂₀ alkyl, with one or more O or S in between; or each with one or more C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one line or more of the following radicals: _{halogen, COOR 17, CONR 19 R 20} , Phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl, C ₆ -C ₂₀ aryloxycarbonyl, C ₄ -C ₂₀ heteroaryloxycarbonyl, OR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or PO(OC _k H _2k+1 ) ₂ ; or R ₁₅ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or substituted with one or more of the following groups: OR ₁₇ , SR ₁₈ , C ₃ -C ₈ cycloalkyl, C ₃ -C _{20 heteroaryl, NR 19 R 20, COOR 17} , CONR 19 R 20 or _{PO (OC k H 2k + 1} ) 2; R '14 has given for R ₁₄ one of those meanings; R _'15 has the meanings for R ₁₅ Suo one of those given; R ₁₆ lines phenyl, which is unsubstituted or substituted with one line or more of the following groups: oR _17, SR ₁₈ NR ₁₉ R ₂₀ or interrupted by one or more O, S or NR ₂₆ of C ₂ -C ₂₀ alkyl, phenyl or R ₁₆ lines, which lines with one or more C ₁ -C ₂₀ substituted alkyl, said C line ₁ -C ₂₀ alkyl unsubstituted or substituted with one or more of the following radicals: _{halogen, COOR 17, CONR 19 R 20} , phenyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₂₀ heteroaryl a C ₆ -C ₂₀ aryloxycarbonyl group, a C ₄ -C ₂₀ heteroaryloxycarbonyl group, OR ₁₇ , SR ₁₈ or NR ₁₉ R ₂₀ ; or an R ₁₆ C ₁ -C ₂₀ alkyl group, which is not Substituted or substituted by halogen, phenyl, OH, SH, CN, C ₃ -C ₆ alkenyloxy, OCH ₂ CH ₂ (CO)O(C ₁ -C ₄ alkyl), O(CO) -(C ₁ -C ₄ alkyl) or (CO)O(C ₁ -C ₄ alkyl); R ₁₇ is a C ₁ -C ₂₀ alkyl group which is unsubstituted or has one or more of the following groups Substitution: halogen, OCH ₂ CH ₂ (CO) O (C ₁ -C ₄ alkyl), O(C ₁ -C ₄ alkyl), (CO)O(C ₁ -C ₄ alkyl), C ₃ - C ₂₀ alkyl or cycloalkyl interrupted by one or more O of C ₃ -C ₂₀ cycloalkyl; R _17, or C ₂ -C ₂₀ alkyl-based, have therebetween one or more heteroatoms O; R ₁₈ through lines (CO) oR _{a 17-} substituted methyl group; R ₁₉ and R ₂₀ are each independently hydrogen, phenyl, C ₁ -C ₂₀ alkyl, C ₁ -C ₈ alkanoyl Or a C ₁ -C ₈ alkenyloxy group; or R ₁₉ and R ₂₀ together with the N atom to which they are attached form a heteroaromatic ring system which is unsubstituted or Substituting; but the condition is that at least one group is present in the molecule or A blue photosensitive resin composition for a color filter according to claim 10, wherein the photoinitiator (E) comprises a photoinitiator (E-1) having a structure represented by the formula (VIII), wherein , R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ and R ₈ are each independently hydrogen, or R ₁ and R ₂ , R ₃ and R ₄ or R ₅ and R ₆ are independent of each other Common ground However, the condition is that at least one of R ₁ and R ₂ , R ₃ and R ₄ or R ₅ and R ₆ is Or R ₂ , COR ₁₆ , NO ₂ or ; or R ₇ series Or COR ₁₆ ; R ₉ , R ₁₁ and R ₁₂ are hydrogen; R ₁₀ is hydrogen, OR ₁₇ or COR ₁₆ ; X is CO or a direct bond; R ₁₃ is a C ₁ - C ₂₀ alkyl group which is unsubstituted or Substituted by one or more of the following groups: halogen, R ₁₇ , OR ₁₇ , SR ₁₈ or PO(OC _k H _2k+1 ) ₂ ; or R ₁₃ C ₂ -C ₂₀ alkyl, with one or more O; or R ₁₃ is a phenyl group; k is an integer 2; R ₁₄ is a C ₁ -C ₂₀ alkyl or thienyl group; R ₁₅ is a phenyl or naphthyl group, each of which is unsubstituted or has one or more ORs ₁₇ or C ₁ -C ₂₀ alkyl substituted; or R ₁₅ is thienyl, hydrogen, C ₁ -C ₂₀ alkyl, the C ₁ -C ₂₀ alkyl is unsubstituted or substituted with one or more of the following groups :OR ₁₇ , SR ₁₈ , C ₃ -C ₈ cycloalkyl, NR ₁₉ R ₂₀ or COOR ₁₇ ; or R ₁₅ C ₂ -C ₂₀ alkyl, interspersed with SO ₂ ; R ₁₆ phenyl or naphthyl , each of which is unsubstituted or substituted with one or more of the following groups: CR ₁₇ , SR ₁₈ , NR ₁₉ R ₂₀ or C ₁ -C ₂₀ alkyl; or R ₁₆ thienyl; R ₁₇ hydrogen, C acyl ₁ -C ₈ alkoxy, C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or substituted with one line or more of the following groups: halo, O (CO) - (C 1 - C ₄ alkyl), O(CO)- (C ₂ -C ₄ )alkenyl or hetero-C ₃ -C ₂₀ cycloalkyl having one or more O; or R ₁₇ C ₂ -C ₂₀ alkyl, heterogeneous one or more O; R ₁₈ C ₃ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ alkyl which is unsubstituted or system with one or more OH, O (CO) - ( C 2 -C 4) alkenyl or (CO) oR ₁₇ substituents Or R ₁₈ is a phenyl group which is unsubstituted or substituted by one or more halogens; R ₁₉ and R ₂₀ are each independently C ₁ -C ₈ alkanoyl or C ₁ -C ₈ alkanoyloxy Or R ₁₉ and R ₂₀ together with the N atom to which they are attached form a 5- or 6-membered saturated ring interspersed with O; provided that at least one group is present in the molecule . The blue photosensitive resin composition for a color filter according to claim 10, wherein the light having the structure represented by the formula (VIII) is based on a total amount of the alkali-soluble resin (C) used in an amount of 100 parts by weight. The agent (E-1) is used in an amount of 2 parts by weight to 20 parts by weight. Share. The blue photosensitive resin composition for a color filter according to claim 1, wherein the total amount of the alkali-soluble resin (C) used is 100 parts by weight, and the organic pigment (A) is used in an amount of 50 parts by weight. To 450 parts by weight; the dye (B) is used in an amount of 10 parts by weight to 90 parts by weight; the ethylenically unsaturated group compound (D) is used in an amount of 50 parts by weight to 450 parts by weight; the photoinitiator (E) is used in an amount of from 17 parts by weight to 170 parts by weight; the organic solvent (F) is used in an amount of from 500 parts by weight to 5,000 parts by weight. A method of producing a color filter using the color filter according to any one of claims 1 to 14 to form a pixel layer with a blue photosensitive resin composition. A color filter produced by the method of claim 15. A liquid crystal display device comprising a color filter according to claim 16.