TW201617649A - Polarizing plate roll - Google Patents

Polarizing plate roll Download PDF

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Publication number
TW201617649A
TW201617649A TW104132059A TW104132059A TW201617649A TW 201617649 A TW201617649 A TW 201617649A TW 104132059 A TW104132059 A TW 104132059A TW 104132059 A TW104132059 A TW 104132059A TW 201617649 A TW201617649 A TW 201617649A
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polarizing plate
convex portion
protective film
core
film
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TW104132059A
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Chinese (zh)
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TWI676828B (en
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塩田裕一
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住友化學股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • B32B1/08Tubular products
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • B32B7/023Optical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H75/00Storing webs, tapes, or filamentary material, e.g. on reels
    • B65H75/02Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
    • B65H75/04Kinds or types
    • B65H75/08Kinds or types of circular or polygonal cross-section
    • B65H75/10Kinds or types of circular or polygonal cross-section without flanges, e.g. cop tubes
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/42Polarizing, birefringent, filtering

Abstract

The present invention provides a polarizing plate roll containing a rolling core having a first convex part and a second convex part extending in a circumferential direction on the outer surface thereof, and a polarizing plate rolled on the rolling core. The polarizing plate contains a polarizer and a protective film laminated on at least one surface of the polarizer, and rolled on the core roll such that one end part in a width direction of the protective film rests on the first convex part, and the other end part rests on the second convex part.

Description

偏光板捲筒 Polarizer reel

本發明係關於將長條之偏光板捲繞於捲芯而成之偏光板捲筒。 The present invention relates to a polarizing plate roll in which a long polarizing plate is wound around a winding core.

偏光板被廣泛使用於液晶顯示裝置等顯示裝置、尤其近年如智慧型手機之各種行動機器。偏光板一般係於偏光片之單面或兩面貼合保護膜而構成者,但隨著朝行動機器發展,逐漸要求構成偏光板之偏光片或保護膜的薄膜化。 Polarizers are widely used in display devices such as liquid crystal display devices, and in particular, various mobile devices such as smart phones in recent years. The polarizing plate is generally formed by laminating a protective film on one surface or both surfaces of a polarizing plate. However, as the mobile device progresses, the polarizing plate or the protective film constituting the polarizing plate is gradually required to be thinned.

偏光板之製造係使用長條(帶狀)之原料薄膜,從在捲芯(捲附芯核)已捲繞原料薄膜之捲筒捲出原料薄膜,同時對捲出之原料薄膜進行加工而成為長條(帶狀)之偏光板,再將所得之偏光板捲繞於捲芯作成捲筒,亦即一般以所謂捲筒至捲筒之方式進行。因此,一般係以將長條之偏光板捲繞於捲芯之偏光板捲筒取得偏光板〔例如特開2013-029754號公報(專利文獻1)〕。 In the production of a polarizing plate, a raw material film of a long strip (belt shape) is used, and a raw material film is wound up from a roll in which a raw material film is wound around a winding core (a core), and the raw material film which is wound up is processed. The strip (belt) polarizing plate is wound around the core to form a reel, that is, generally in the form of a so-called reel to reel. For this reason, a polarizing plate is generally obtained by winding a long polarizing plate around a core of a polarizing plate (for example, JP-A-2013-029754 (Patent Document 1)).

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開2013-029754號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2013-029754

如上述,偏光板一般係以偏光板捲筒之形態製造。例如若舉出偏光板之薄膜長為2000m、捲芯之直徑為150mm 之情形為例,偏光板之捲繞數亦達4000次左右。 As described above, the polarizing plate is generally manufactured in the form of a polarizing plate roll. For example, if the polarizing plate has a film length of 2000 m and the core diameter is 150 mm. For example, the number of windings of the polarizing plate is about 4,000 times.

製成偏光板捲筒之偏光板,在供給進一步貼合其他薄膜或形成塗佈層等後續步驟為止之間、或輸送至供給對象之間的某些連續期間,常以捲筒狀態保持。 The polarizing plate which is used to form the polarizing plate reel is often held in a reel state during some continuous periods between the supply of further films or subsequent steps of forming a coating layer, or between the supply objects.

然而,某些連續期間、以捲筒狀態保持後被捲出之偏光板,有易伴隨稱為「捲痕缺陷」之不妥適的問題。構成偏光板之偏光片或保護膜愈薄此問題愈顯著。參照第7圖,所謂「捲痕缺陷」係因偏光板之捲繞起始端與捲芯外周面之間產生之高低差、亦即於落差部分壓住捲繞之偏光板造成朝偏光板的寬度方向延伸之條紋狀凹部缺陷。使用如兩面膠帶之固定構件將偏光板之捲繞起始端固定於捲芯後捲取偏光板之情形,捲痕缺陷特別顯著。如第7圖所示,捲痕缺陷係包含源自於偏光板捲繞起始端之角部(端部之短邊角)的缺陷K1(因壓住偏光板之捲繞起始端之角部而產生的缺陷),使用上述固定構件時,更包含源自該固定構件之角部的缺陷K2(壓住固定構件之角部所產生之缺陷)。 However, in some continuous periods, the polarizing plate which is wound up after being held in a roll state is liable to be accompanied by an unsuitable problem called "winding defect". The thinner the polarizer or the protective film constituting the polarizing plate, the more remarkable the problem. Referring to Fig. 7, the "cricket defect" is caused by the difference in height between the winding start end of the polarizing plate and the outer peripheral surface of the core, that is, the width of the polarizing plate is caused by the drop portion being pressed against the wound polarizing plate. A stripe-shaped recess defect extending in the direction. The use of a fixing member such as a double-sided tape fixes the winding start end of the polarizing plate to the winding core and winds up the polarizing plate, and the curl defect is particularly remarkable. As shown in Fig. 7, the defect of the winding includes the defect K 1 derived from the corner portion (the short corner of the end portion) at the winding start end of the polarizing plate (because the corner portion of the winding start end of the polarizing plate is pressed Further, when the fixing member is used, the defect K 2 derived from the corner portion of the fixing member (the defect generated by pressing the corner portion of the fixing member) is further included.

捲痕缺陷係在偏光板捲筒內側的偏光板(開 始捲繞初期之偏光板)強烈產生,愈朝偏光板捲筒之外側愈弱,但可發生在從偏光板開始捲繞處到長度方向數十公尺處。含有捲痕缺陷之偏光板適用於液晶顯示裝置般之圖像顯示裝置時,有辨識性降低之顧慮,若除去具有該缺陷之偏光板部分作為不良品時,偏光板之製品收率大幅降低。 The curl defect is a polarizing plate on the inside of the polarizing plate reel (open The polarizing plate at the beginning of the initial winding is strongly generated, and the weaker the outer side of the polarizing plate is, but it may occur at a position of several tens of meters from the start of winding of the polarizing plate to the length direction. When the polarizing plate containing the curl defect is suitable for an image display device such as a liquid crystal display device, there is a concern that the visibility is lowered. When the polarizing plate portion having the defect is removed as a defective product, the product yield of the polarizing plate is greatly lowered.

因此,本發明之目的在於提供一種將偏光板捲繞於捲芯而成之偏光板捲筒,從該捲筒捲出偏光板時可抑制能確認之「捲痕缺陷」的偏光板捲筒。 Therefore, an object of the present invention is to provide a polarizing plate roll in which a polarizing plate is wound around a winding core, and a polarizing plate roll capable of confirming a "winding defect" can be suppressed when the polarizing plate is taken out from the winding.

本發明係提供以下所示之偏光板捲筒。 The present invention provides a polarizing plate reel shown below.

[1]一種偏光板捲筒,含有:於外周面具備朝周方向延伸之第1凸部及第2凸部的捲芯、及捲繞於前述捲芯之偏光板,前述偏光板具備偏光片及積層於其至少一方的面上之保護膜,前述偏光板係以前述保護膜之寬度方向之一方的端部區域位於前述第1凸部上、另一方之端部區域位於前述第2凸部上之方式捲繞於前述捲芯。 [1] A polarizing plate roll comprising: a winding core having a first convex portion and a second convex portion extending in a circumferential direction on an outer peripheral surface; and a polarizing plate wound around the winding core, wherein the polarizing plate is provided with a polarizing plate And a protective film laminated on at least one of the surfaces of the polarizing plate, wherein one end region of one of the width directions of the protective film is located on the first convex portion, and the other end region is located at the second convex portion The above method is wound around the aforementioned core.

[2]如[1]項所述之偏光板捲筒,其中,前述偏光板係以前述偏光片之寬度方向之一方的端部位於較前述第1凸部之內側端部更內側處、另一方之端部位於較前述第2凸部之內側端部更內側處之方式捲繞於前述捲芯。 [2] The polarizing plate roll according to the above aspect, wherein the polarizing plate is located at an inner side of one of the width direction of the polarizer, and is located further inward than an inner end of the first convex portion, and One end portion is wound around the winding core so as to be located further inside than the inner end portion of the second convex portion.

[3]如[1]或[2]項所述之偏光板捲筒,其中,前述偏光板之捲繞起始端係使用固定構件固定於前述 外周面。 [3] The polarizing plate reel according to [1], wherein the winding start end of the polarizing plate is fixed to the foregoing by using a fixing member. The outer perimeter.

[4]如[1]至[3]項中任一項所述之偏光板捲筒,其中,前述第1凸部及前述第2凸部之高度分別為50μm以上。 [4] The polarizing plate reel according to any one of [1], wherein the height of each of the first convex portion and the second convex portion is 50 μm or more.

[5]如[1]至[4]項中任一項所述之偏光板捲筒,其中,前述第1凸部及前述第2凸部係以貼黏於前述外周面之樹脂薄膜構成。 [5] The polarizing plate roll according to any one of [1], wherein the first convex portion and the second convex portion are formed of a resin film adhered to the outer peripheral surface.

若依本發明,可提供能抑制捲痕缺陷之偏光板捲筒。藉由抑制捲痕缺陷,可改善偏光板之製品品質或製品收率。 According to the present invention, it is possible to provide a polarizing plate reel capable of suppressing curl defects. By suppressing the curl defect, the product quality or product yield of the polarizing plate can be improved.

10‧‧‧附凸部之捲芯 10‧‧‧With the core of the convex part

10a‧‧‧第1凸部 10a‧‧‧1st convex

10b‧‧‧第2凸部 10b‧‧‧2nd convex

20‧‧‧偏光板 20‧‧‧Polar plate

21‧‧‧偏光片 21‧‧‧ polarizer

22‧‧‧第1保護膜 22‧‧‧1st protective film

23‧‧‧第2保護膜 23‧‧‧2nd protective film

30‧‧‧固定構件 30‧‧‧Fixed components

第1圖係表示使用於本發明之偏光板捲筒的附凸部之捲芯的一例之模式圖。 Fig. 1 is a schematic view showing an example of a winding core used in a convex portion of a polarizing plate roll of the present invention.

第2圖係表示具有第1圖所示之附凸部的捲芯之第1凸部之部分中之剖面圖。 Fig. 2 is a cross-sectional view showing a portion of a first convex portion of a winding core having a convex portion shown in Fig. 1.

第3圖係示意性表示附凸部之捲芯的凸部與捲繞之偏光板之間的寬度方向相關之位置關係的一例之剖面圖。 Fig. 3 is a cross-sectional view schematically showing an example of a positional relationship between a convex portion of a winding core of a convex portion and a width direction of a wound polarizing plate.

第4圖係示意性表示附凸部之捲芯的凸部與捲繞之偏光板之間的寬度方向相關之位置關係的另一例之剖面圖。 Fig. 4 is a cross-sectional view schematically showing another example of the positional relationship between the convex portion of the winding core of the convex portion and the width direction of the wound polarizing plate.

第5圖係表示附凸部之捲芯的另一例之剖面圖。 Fig. 5 is a cross-sectional view showing another example of the core of the convex portion.

第6圖係表示將偏光板之捲繞起始端部使用固定構件固定於附凸部之捲芯的狀態之概略圖。 Fig. 6 is a schematic view showing a state in which the winding start end portion of the polarizing plate is fixed to the winding core of the convex portion by using a fixing member.

第7圖係用以說明捲痕缺陷之概略圖。 Figure 7 is a schematic diagram for explaining the defects of the curl.

本發明之偏光板捲筒,其一例表示於第1圖及第2圖,係使用於外周面具備朝周方向延伸之第1凸部10a及第2凸部10b的附凸部之捲芯10作為捲芯,再將長條之偏光板捲繞於捲芯而成之捲筒形態的偏光板。在本發明中,為抑制上述「捲痕缺陷」之發生,偏光板係以構成其之保護膜的寬度方向之一方之端部區域位於第1凸部10a上、另一方之端部區域位於第2凸部10b上之方式被捲繞於附凸部之捲芯10。附凸部之捲芯10的凸部10a、10b與捲繞之偏光板之間的寬度方向相關之位置關係以下述(3)項詳細說明。 An example of the polarizing plate roll of the present invention is shown in Figs. 1 and 2, and is a winding core 10 having a convex portion for the first convex portion 10a and the second convex portion 10b extending in the circumferential direction on the outer peripheral surface. As a winding core, a long polarizing plate is wound around a winding core to form a polarizing plate in the form of a roll. In the present invention, in order to suppress the occurrence of the above-mentioned "winding defect", the polarizing plate is located on the first convex portion 10a and the other end portion in the end portion of one of the width directions of the protective film. The manner of the convex portion 10b is wound around the winding core 10 of the convex portion. The positional relationship between the convex portions 10a and 10b of the core 10 with the convex portion and the width direction of the wound polarizing plate will be described in detail in the following item (3).

(1)附凸部之捲芯 (1) The core of the convex part

附凸部之捲芯10除具有第1凸部10a及第2凸部10b以外,可具有與習知之捲芯同樣的形狀,除了此等凸部以外,捲芯的本體部分例如可為圓柱狀或圓筒狀。材質亦無特別限制,可使用金屬、合金、樹脂(熱塑性樹脂等)。附凸部之捲芯10的寬度方向(旋轉軸方向)之長度係與捲繞之偏光板的寬度相同程度、或較其長。附凸部之捲芯10為圓柱狀或圓筒狀時,其直徑可為捲芯之一般直徑,例如為100至200mm 左右。 The winding core 10 having the convex portion may have the same shape as the conventional winding core except for the first convex portion 10a and the second convex portion 10b. The body portion of the winding core may be cylindrical, for example, in addition to the convex portions. Or cylindrical. The material is not particularly limited, and metals, alloys, and resins (thermoplastic resins, etc.) can be used. The length of the winding core 10 with the convex portion in the width direction (the direction of the rotation axis) is equal to or longer than the width of the wound polarizing plate. When the core 10 of the convex portion is cylindrical or cylindrical, the diameter thereof may be a general diameter of the core, for example, 100 to 200 mm. about.

設置於附凸部之捲芯10的外周面之第1凸部10a及第2凸部10b之設置位置,係依存於所捲繞之偏光板的寬度。具體上,第1凸部10a及第2凸部10b在上 述外周面為互異之位置,且以構成偏光板之保護膜的寬度方向之一方之端部區域位於第1凸部10a上、另一方之端部區域位於第2凸部10b上之方式設置。如第1圖所示,第1凸部10a及第2凸部10b一般係設置於附凸部之捲芯10的寬度方向(旋轉軸方向)之端部區域(包含端部)或靠近端部。 The position where the first convex portion 10a and the second convex portion 10b provided on the outer circumferential surface of the winding core 10 having the convex portion are disposed depends on the width of the wound polarizing plate. Specifically, the first convex portion 10a and the second convex portion 10b are on The outer peripheral surface is at a position different from each other, and the end portion of one of the width directions of the protective film constituting the polarizing plate is located on the first convex portion 10a, and the other end portion is located on the second convex portion 10b. . As shown in Fig. 1, the first convex portion 10a and the second convex portion 10b are generally provided at an end portion (including an end portion) in the width direction (rotational axis direction) of the winding core 10 of the convex portion or near the end portion. .

第1凸部10a及第2凸部10b係在附凸部之捲芯10的外周面,以朝附凸部之捲芯10的周方向延伸之方式設置,較佳係相對於附凸部之捲芯10的周方向平行(相對於附凸部之捲芯10的旋轉軸方向為垂直之方向)延伸。如第2圖所示,第1凸部10a及第2凸部10b以帶狀為較佳,且以涵蓋附凸部之捲芯10的外周面之全周或約略全周呈環狀設置為較佳。 The first convex portion 10a and the second convex portion 10b are provided on the outer circumferential surface of the winding core 10 of the convex portion, and are provided to extend in the circumferential direction of the winding core 10 of the convex portion, preferably with respect to the convex portion. The circumferential direction of the core 10 extends in parallel (in a direction perpendicular to the direction of the rotation axis of the winding core 10 of the convex portion). As shown in Fig. 2, the first convex portion 10a and the second convex portion 10b are preferably belt-shaped, and are preferably provided in a ring shape over the entire circumference or about the entire circumference of the outer circumferential surface of the winding core 10 covering the convex portion. .

第1凸部10a及第2凸部10b,亦可與附凸部之捲芯10的本體部分形成一體,亦可使用與該本體部分相異之另外構件形成。使用另外構件形成凸部之方法,可舉例如在作為附凸部之捲芯10的本體部分之圓柱狀或圓筒狀的捲芯之外周面,貼黏形成第1凸部10a及第2凸部10b之樹脂薄膜(例如由熱塑性樹脂所構成之薄膜膠帶)之方法。此樹脂薄膜為了貼黏於捲芯之外周面,亦可為於單面具有黏著劑層者。使用黏著劑貼黏樹脂薄膜之方法,因可重複貼黏,故凸部之位置調整或位置變更變容易。藉樹脂薄膜之貼黏形成凸部之方法,在附凸部之捲芯10的製造成本方面及製造之簡便性方面均為有利,又可得到具有充 分強度之附凸部之捲芯10。樹脂薄膜亦可使用接著劑貼黏於捲芯之外周面。 The first convex portion 10a and the second convex portion 10b may be integrally formed with the main body portion of the winding core 10 of the convex portion, or may be formed of another member different from the main body portion. In the method of forming the convex portion by using another member, for example, the first convex portion 10a and the second convex portion are adhered to each other on the outer circumferential surface of the cylindrical or cylindrical core of the main body portion of the winding core 10 as the convex portion. A method of a resin film of the portion 10b (for example, a film tape composed of a thermoplastic resin). The resin film may be an adhesive layer on one side in order to adhere to the outer surface of the core. The method of using an adhesive to stick a resin film is reproducible, so that the positional adjustment or positional change of the convex portion becomes easy. The method of forming the convex portion by the adhesion of the resin film is advantageous in terms of the manufacturing cost of the core 10 with the convex portion and the simplicity of manufacture, and can be obtained by charging. The core 10 of the convex portion with a partial intensity. The resin film may also be adhered to the outer surface of the core by using an adhesive.

(2)偏光板 (2) Polarizer

捲繞於附凸部之捲芯10的偏光板,係具備偏光片與積層於其至少一方之面上的保護膜者。亦可於偏光片之兩面積層保護膜。保護膜通常透過接著劑層貼合於偏光片。接著劑可使用如紫外線硬化性接著劑之活性能量線硬化性接著劑,或如聚乙烯醇系樹脂水溶液之水性接著劑。偏光板之全體厚度一般為30至300μm左右。 The polarizing plate wound around the winding core 10 of the convex portion is provided with a polarizer and a protective film laminated on at least one of the faces. The film can also be protected on the two layers of the polarizer. The protective film is usually attached to the polarizer through the adhesive layer. As the subsequent agent, an active energy ray-curable adhesive such as an ultraviolet curable adhesive or an aqueous adhesive such as an aqueous solution of a polyvinyl alcohol-based resin can be used. The total thickness of the polarizing plate is generally about 30 to 300 μm.

偏光片可妥適使用二色性色素被吸著配向於經一軸延伸之聚乙烯醇系樹脂者。二色性色素可使用碘或二色性染料。構成偏光片之聚乙烯醇系樹脂可使用將聚醋酸乙烯酯系樹脂皂化者。聚醋酸乙烯酯系樹脂除了醋酸乙烯酯均聚物的聚醋酸乙烯酯之外,尚可例示醋酸乙烯酯與可與其共聚合之其他單體之共聚物。可共聚合於醋酸乙烯酯之其他單體的例子,包含不飽和羧酸類、烯烴類、乙烯基醚類、不飽和磺酸類及具有銨基之(甲基)丙烯醯胺類。在本說明書中,「(甲基)丙烯酸基」係意指由丙烯酸基及甲基丙烯酸基選出之至少一方。有關「(甲基)丙烯醯基」亦同樣。 The polarizer can be suitably used to align a dichroic dye to a polyvinyl alcohol-based resin which is stretched by one axis. As the dichroic dye, iodine or a dichroic dye can be used. As the polyvinyl alcohol-based resin constituting the polarizer, those obtained by saponifying a polyvinyl acetate-based resin can be used. Polyvinyl acetate-based resin In addition to polyvinyl acetate of a vinyl acetate homopolymer, a copolymer of vinyl acetate and another monomer copolymerizable therewith can be exemplified. Examples of other monomers copolymerizable with vinyl acetate include unsaturated carboxylic acids, olefins, vinyl ethers, unsaturated sulfonic acids, and (meth) acrylamides having an ammonium group. In the present specification, "(meth)acrylic group" means at least one selected from the group consisting of an acryl group and a methacryl group. The same applies to "(meth)acrylonitrile".

聚乙烯醇系樹脂之皂化度一般為85至100mol%左右,以98mol%以上為較佳。聚乙烯醇系樹脂亦可被改質,例如亦可使用以醛類改質之聚乙烯甲醛及聚乙烯乙醛等。聚乙烯醇系樹脂之聚合度一般為1000至10000 左右,以1500至5000左右為較佳。 The degree of saponification of the polyvinyl alcohol-based resin is generally from about 85 to 100 mol%, preferably from 98 mol% or more. The polyvinyl alcohol-based resin may be modified, and for example, polyethylene formaldehyde modified with an aldehyde and polyvinyl acetaldehyde may be used. The degree of polymerization of the polyvinyl alcohol-based resin is generally from 1,000 to 10,000. Around 1500 to 5000 is preferred.

偏光片可藉由包含如下步驟方法製造:將由上述聚乙烯醇系樹脂構成之胚膜進行一軸延伸(典型上係朝薄膜長度方向之縱一軸延伸)之步驟;將聚乙烯醇系樹脂薄膜以二色性色素染色使該二色性色素吸附之步驟;將吸附二色性色素之聚乙烯醇系樹脂薄膜以硼酸水溶液處理之步驟;及以硼酸水溶液進行處理後進行水洗之步驟。染色處理之前亦可設置對水實施浸漬處理之膨潤步驟。 The polarizer can be produced by a method comprising the steps of: stretching a matrix film composed of the above polyvinyl alcohol-based resin on one axis (typically extending toward a longitudinal axis of the film length direction); and using a polyvinyl alcohol-based resin film as two The step of adsorbing the dichroic dye by the dyeing of the coloring matter; the step of treating the polyvinyl alcohol resin film adsorbing the dichroic dye with a boric acid aqueous solution; and the step of washing with a boric acid aqueous solution and then washing with water. A swelling step of subjecting the water to an immersion treatment may also be provided before the dyeing treatment.

聚乙烯醇系樹脂薄膜之一軸延伸,可於二色性色素之染色前、與染色同時、或染色之後進行。於染色之後進行一軸延伸時,該一軸延伸亦可於硼酸處理之前或硼酸處理中進行。又,亦可於此等之複數段階進行一軸延伸。 One of the polyvinyl alcohol-based resin films is axially stretched, and can be carried out before dyeing of the dichroic dye, simultaneously with dyeing, or after dyeing. When a shaft extension is performed after dyeing, the one-axis extension can also be carried out before boric acid treatment or boric acid treatment. Moreover, one-axis extension can also be performed in the plural steps of the order.

偏光片之厚度(全寬度之平均厚度)例如為40μm以下,較佳係25μm以下,更佳係20μm以下,特別在行動機器用之偏光板中,從偏光板薄型化的觀點以10μm以下為更佳。偏光片之厚度一般為2μm以上。使用如此之薄膜偏光片時,藉由本發明,可有效抑制捲痕缺陷。 The thickness of the polarizer (the average thickness of the full width) is, for example, 40 μm or less, preferably 25 μm or less, more preferably 20 μm or less, and particularly in a polarizing plate for a mobile device, from the viewpoint of reducing the thickness of the polarizing plate to 10 μm or less. good. The thickness of the polarizer is generally 2 μm or more. When such a film polarizer is used, the present invention can effectively suppress curl defects.

貼合於偏光片之保護膜,可為具有透光性(較佳係光學上透明之)熱塑性樹脂,例如鏈狀聚烯烴系樹脂(聚丙烯系樹脂等)、環狀聚烯烴系樹脂(降茨烯系樹脂等)等聚烯烴系樹脂;纖維素三乙酸酯、纖維素二乙酸酯等纖維素酯系樹脂;聚酯系樹脂;聚碳酸酯系樹脂;(甲基)丙 烯酸系樹脂;聚苯乙烯系樹脂;或由此等之混合物、共聚合物等構成之薄膜。於偏光片之兩面貼合保護膜時,此等可為由同種之樹脂構成之保護膜,亦可為由異種之樹脂構成之保護膜。 The protective film to be bonded to the polarizer may be a translucent (preferably optically transparent) thermoplastic resin such as a chain polyolefin resin (such as a polypropylene resin) or a cyclic polyolefin resin. A polyolefin resin such as a benzylene resin; a cellulose ester resin such as cellulose triacetate or cellulose diacetate; a polyester resin; a polycarbonate resin; A olefinic resin; a polystyrene resin; or a film composed of a mixture such as a copolymer or the like. When the protective film is bonded to both surfaces of the polarizer, these may be a protective film made of the same kind of resin, or may be a protective film made of a different kind of resin.

保護膜亦可為一併具有位相差膜、增亮膜等光學機能的保護膜。例如,將由上述熱塑性樹脂所構成之薄膜延伸(一軸延伸或二軸延伸等),或於該薄膜上形成液晶層等,藉此可作成賦予任意位相差值之位相差膜。 The protective film may also be a protective film having an optical function such as a phase difference film or a brightness enhancement film. For example, a film made of the above thermoplastic resin may be stretched (one-axis stretching or biaxial stretching or the like), or a liquid crystal layer or the like may be formed on the film, whereby a phase difference film imparting an arbitrary phase difference value may be formed.

鏈狀聚烯烴系樹脂除了聚乙烯樹脂、聚丙烯樹脂等鏈狀烯烴的均聚物之外,可舉例如由2種以上之鏈狀烯烴所構成之共聚物。 In addition to a homopolymer of a chain olefin such as a polyethylene resin or a polypropylene resin, the chain polyolefin resin may, for example, be a copolymer composed of two or more kinds of chain olefins.

環狀聚烯烴系樹脂係以環狀烯烴作為聚合單元進行聚合之樹脂的總稱。舉出環狀聚烯烴系樹脂之具體例,包括環狀烯烴之開環(共)聚合物、環狀烯烴之加成聚合物、環狀烯烴與乙烯、丙烯等鏈狀烯烴之共聚物(代表性者係隨機共聚物)、及將此等以不飽和羧酸或其衍生物改質之接枝聚合物、以及此等之氫化物等。其中,以使用降茨烯或多環降茨烯系單體等降茨烯系單體作為環狀烯烴之降茨烯系樹脂為較佳。 The cyclic polyolefin resin is a general term for a resin obtained by polymerizing a cyclic olefin as a polymerization unit. Specific examples of the cyclic polyolefin-based resin include a ring-opened (co)polymer of a cyclic olefin, an addition polymer of a cyclic olefin, a copolymer of a cyclic olefin and a chain olefin such as ethylene or propylene (representative The same is a random copolymer), a graft polymer which is modified with an unsaturated carboxylic acid or a derivative thereof, and a hydride or the like. Among them, a decylene-based resin having a nordene-based monomer such as a norbornene or a polycyclic nordzene-based monomer as a cyclic olefin is preferred.

纖維素酯系樹脂係纖維素與脂肪酸之酯。纖維素酯系樹脂之具體例包含纖維素三乙酸酯、纖維素二乙酸酯、纖維素三丙酸酯、纖維素二丙酸酯。又,亦可使用此等之共聚物或羥基之一部份以其他取代基修飾者。此等之中,以纖維素三乙酸酯(三乙醯基纖維素:TAC)為特 佳。 The cellulose ester resin is an ester of cellulose and a fatty acid. Specific examples of the cellulose ester-based resin include cellulose triacetate, cellulose diacetate, cellulose tripropionate, and cellulose dipropionate. Further, it is also possible to use one of these copolymers or a part of a hydroxyl group to be modified with other substituents. Among these, cellulose triacetate (triethyl fluorenyl cellulose: TAC) is special. good.

聚酯系樹脂係具有酯鍵結之上述纖維素酯系樹脂以外的樹脂,以多元羧酸或其衍生物與多元醇之聚縮合物構成者為一般。多元羧酸或其衍生物可使用二羧酸或其衍生物,可舉例如對苯二甲酸、間苯二甲酸、對苯二甲酸二甲酯、萘二羧酸二甲酯等。多元醇可使用二元醇,可舉例如乙二醇、丙二醇、丁二醇、新戊二醇、環己烷二甲醇等。 The polyester-based resin is a resin other than the cellulose ester-based resin having an ester bond, and is generally composed of a polycondensate of a polyvalent carboxylic acid or a derivative thereof and a polyhydric alcohol. As the polyvalent carboxylic acid or a derivative thereof, a dicarboxylic acid or a derivative thereof can be used, and examples thereof include terephthalic acid, isophthalic acid, dimethyl terephthalate, and dimethyl naphthalene dicarboxylate. As the polyhydric alcohol, a glycol may be used, and examples thereof include ethylene glycol, propylene glycol, butanediol, neopentyl glycol, and cyclohexane dimethanol.

聚酯系樹脂之具體例包含聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二酯、聚萘二甲酸丁二酯、聚對苯二甲酸丙二酯、聚萘二甲酸丙二酯、聚對苯二甲酸環己烷二甲酯、聚萘二甲酸環己烷二甲酯。 Specific examples of the polyester resin include polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, and polytrimethylene terephthalate. , propylene naphthalate, dimethyl dimethyl terephthalate, cyclohexane dimethyl phthalate.

聚碳酸酯系樹脂由透過碳酸酯基鍵結單體單元之聚合物所構成。聚碳酸酯系樹脂亦可為被稱為改質聚碳酸酯之聚合物骨架經修飾之樹脂、或共聚合聚碳酸酯等。 The polycarbonate resin is composed of a polymer that transmits a monomer unit through a carbonate group. The polycarbonate resin may be a resin modified with a polymer skeleton called modified polycarbonate, or a copolymerized polycarbonate.

(甲基)丙烯酸系樹脂係以具有(甲基)丙烯醯基之化合物作為主要構成單體之樹脂。(甲基)丙烯酸系樹脂之具體例,例如包括聚甲基丙烯酸甲酯等聚(甲基)丙烯酸酯;甲基丙烯酸甲酯-(甲基)丙烯酸共聚合物;甲基丙烯酸甲酯-(甲基)丙烯酸酯共聚合物;甲基丙烯酸甲酯-丙烯酸酯-(甲基)丙烯酸共聚物;(甲基)丙烯酸甲酯-苯乙烯共聚合物(MS樹脂等);甲基丙烯酸甲酯與具有脂環族烴基之化合物之共聚物(例如甲基丙烯酸甲酯-甲基丙烯酸 環己酯共聚物、甲基丙烯酸甲酯-(甲基)丙烯酸降茨烷酯共聚物等)。較佳可使用以聚(甲基)丙烯酸甲酯等聚(甲基)丙烯酸C1-6烷基酯作為主成分之聚合物,更佳可使用以甲基丙烯酸甲酯作為主成分(50至100重量%、較佳係70至100重量%)之甲基丙烯酸甲酯系樹脂。 The (meth)acrylic resin is a resin having a compound having a (meth)acryl fluorenyl group as a main constituent monomer. Specific examples of the (meth)acrylic resin include, for example, poly(meth)acrylate such as polymethyl methacrylate; methyl methacrylate-(meth)acrylic acid copolymer; methyl methacrylate-( Methyl) acrylate copolymer; methyl methacrylate-acrylate-(meth)acrylic acid copolymer; methyl (meth) acrylate-styrene copolymer (MS resin, etc.); methyl methacrylate Copolymer with a compound having an alicyclic hydrocarbon group (for example, methyl methacrylate-cyclohexyl methacrylate copolymer, methyl methacrylate-(meth)acrylic acid reduced alkyl ester copolymer, etc.). It is preferable to use a polymer having a poly(meth)acrylic acid C 1-6 alkyl ester such as poly(methyl) acrylate as a main component, and it is more preferable to use methyl methacrylate as a main component (50 to 100% by weight, preferably 70 to 100% by weight, based on the methyl methacrylate resin.

保護膜之厚度,從偏光板薄型化的觀點,較佳係90μm以下,更佳係50μm以下,又更佳係30μm以下。保護膜之厚度從強度及處理性之觀點,通常為5μm以上。即使使用如此薄膜的保護膜時,若依據本發明,可有效抑制捲痕缺陷。 The thickness of the protective film is preferably 90 μm or less, more preferably 50 μm or less, and still more preferably 30 μm or less from the viewpoint of reducing the thickness of the polarizing plate. The thickness of the protective film is usually 5 μm or more from the viewpoint of strength and handleability. Even when a protective film of such a film is used, according to the present invention, curl defects can be effectively suppressed.

偏光板亦可為含有保護膜以外之薄膜或層者。保護膜以外之薄膜或層之具體例,包括:黏著劑層;保護黏著劑層之外面的分離薄膜(剝離薄膜);保護保護膜之表面的保護薄膜(表面保護膜);用以對偏光板賦予各種機能之表面處理層(塗佈層);各種光學機能薄膜。 The polarizing plate may also be a film or layer other than the protective film. Specific examples of the film or layer other than the protective film include: an adhesive layer; a separation film (peeling film) protecting the outer surface of the adhesive layer; a protective film (surface protective film) for protecting the surface of the protective film; A surface treatment layer (coating layer) imparting various functions; various optical functional films.

可使用於黏著劑層之黏著劑,可使用以往公知之適宜的黏著劑,可舉例如(甲基)丙烯酸系黏著劑、胺基甲酸酯系黏著劑、聚矽氧系黏著劑、聚酯系黏著劑、聚醯胺系黏著劑、聚醚系黏著劑、氟系黏著劑、橡膠系黏著劑等。其中,從透明性、黏著力、信頼性、重工性等之觀點,較佳使用(甲基)丙烯酸系黏著劑。黏著劑層之厚度一般可為1至40μm(例如3至25μm)。 As the adhesive for the adhesive layer, a conventionally known suitable adhesive can be used, and examples thereof include a (meth)acrylic adhesive, an urethane adhesive, a polyoxygen adhesive, and a polyester. An adhesive, a polyamide-based adhesive, a polyether adhesive, a fluorine-based adhesive, a rubber-based adhesive, or the like. Among them, a (meth)acrylic adhesive is preferably used from the viewpoints of transparency, adhesion, letterability, and reworkability. The thickness of the adhesive layer may generally be from 1 to 40 μm (for example, from 3 to 25 μm).

分離薄膜之構成材料可為聚乙烯等聚乙烯系樹脂、聚丙烯等聚丙烯系樹脂、聚對苯二甲酸乙二酯等 聚酯系樹脂等。其中,以聚對苯二甲酸乙二酯之延伸薄膜為較佳。 The constituent material of the separation film may be a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, or polyethylene terephthalate. Polyester resin, etc. Among them, an extended film of polyethylene terephthalate is preferred.

保護薄膜之構成材料可舉例如聚乙烯等聚乙烯系樹脂、聚丙烯等聚丙烯系樹脂、聚對苯二甲酸乙二酯等聚酯系樹脂等,其中,從透濕性或機械強度之觀點,以聚對苯二甲酸乙二酯之延伸薄膜為較佳。 The constituent material of the protective film may, for example, be a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, or a polyester resin such as polyethylene terephthalate. From the viewpoint of moisture permeability or mechanical strength, An extended film of polyethylene terephthalate is preferred.

表面處理層可舉例如硬塗層、防眩層、抗反射層、抗靜電層、防汚層。 The surface treatment layer may, for example, be a hard coat layer, an antiglare layer, an antireflection layer, an antistatic layer, or an antifouling layer.

光學機能薄膜可舉例如透過某種偏光之光、使顯示與其相反性質的偏光之光反射之反射型偏光薄膜;於表面具有凹凸形狀之附防眩機能的薄膜;附表面抗反射機能之薄膜;於表面具有反射機能之反射薄膜;一併具有反射機能與透過機能之半透過反射薄膜;視角補償薄膜。 The optical functional film may be, for example, a reflective polarizing film that transmits light of a certain polarized light and reflects polarized light having opposite properties; a film with an anti-glare function having a concave-convex shape on the surface; and a film with a surface anti-reflective function; a reflective film having a reflective function on the surface; a semi-transmissive reflective film having a reflective function and a transmissive function; and a viewing angle compensation film.

捲繞於附凸部之捲芯10之偏光板的寬度並無特別限制,但通常為300至2500mm左右,較典型者係500至2000mm左右。又,偏光板之長度亦無特別限制,但通常為數百m至3000m左右(例如2000m左右),較典型者係1500至2500m左右。偏光片之寬度與貼合於此之保護膜的寬度可為相同,亦可為相異,但一般以更增大保護膜之寬度、使保護膜之寬度方向兩端部(兩端面)位於較偏光片之寬度方向兩端部(兩端面)的更外側之方式貼合保護膜。 The width of the polarizing plate wound around the winding core 10 of the convex portion is not particularly limited, but is usually about 300 to 2,500 mm, more typically about 500 to 2,000 mm. Further, the length of the polarizing plate is not particularly limited, but is usually about several hundred m to about 3,000 m (for example, about 2000 m), and more typically about 1,500 to 2,500 m. The width of the polarizer and the width of the protective film attached thereto may be the same or different, but generally, the width of the protective film is further increased, and both ends (both ends) of the protective film are located at the opposite ends. The protective film is bonded to the outer side of both ends (both ends) of the polarizer in the width direction.

(3)附凸部之捲芯之凸部與捲繞之偏光板之間的寬度方向相關的位置關係 (3) Positional relationship between the convex portion of the core of the convex portion and the width direction of the wound polarizing plate

第3圖係示意性表示有關附凸部之捲芯10的凸部與捲繞之偏光板20之間的寬度方向之位置關係的一例之剖面圖。第3圖係表示使用由偏光片21與貼合於其一方之面的第1保護膜22及貼合於另一方之面的第2保護膜23所構成之偏光板20的情形作為一例,但如上述,偏光板之層構成不限定於此。又,第3圖係只採取附凸部之捲芯10的第1凸部10a,但說明於以下之內容對與第2凸部10b之位置關係亦同樣適用。 Fig. 3 is a cross-sectional view showing an example of a positional relationship between the convex portion of the winding core 10 and the wound polarizing plate 20 in the convex portion. 3 is a view showing a case where the polarizing plate 20 including the polarizing film 21 and the first protective film 22 bonded to one surface and the second protective film 23 bonded to the other surface is used as an example, but As described above, the layer configuration of the polarizing plate is not limited thereto. In addition, in the third drawing, only the first convex portion 10a of the winding core 10 having the convex portion is used. However, the positional relationship with the second convex portion 10b will be similarly applied to the following description.

本發明之偏光板捲筒中之偏光板20,係使保護膜之寬度方向之一方的端部區域位於第1凸部10a上,在第3圖中雖未圖示,但係以另一方之端部區域位於第2凸部10b上之方式捲繞於附凸部之捲芯10。如第3圖之例,於偏光片21之兩面具備保護膜(第1及第2保護膜22、23)時,係以兩面之保護膜滿足上述位置關係之方式捲繞為較佳。 In the polarizing plate 20 of the polarizing plate roll of the present invention, one end region of the protective film in the width direction is located on the first convex portion 10a, and in the third drawing, although not shown, the other end is used. The portion of the portion is located on the second convex portion 10b so as to be wound around the winding core 10 of the convex portion. In the case of the protective film (the first and second protective films 22 and 23) provided on both surfaces of the polarizer 21, it is preferable to wind the protective film on both sides so as to satisfy the above-described positional relationship.

保護膜之一方的端部區域位於第1凸部10a上,係如第3圖所示之例,除了保護膜之端部(端面、第3圖中之T1)位於第1凸部10a上之情形外,尚包含保護膜之端部T1位於較第1凸部10a之外側端部T2更外側,但保護膜之端部T1附近的端部區域被置於第1凸部10a上之情形。保護膜之端部T1附近的端部區域,係指各端部至偏光板之寬度的15%之區域。藉此,可得到捲痕缺陷抑制效果。保護膜之端部T1位於第1凸部10a上,係謂端部T1位於第1凸部10a之外側端部T2與內側端部T3之間(包含T1與T2 或T3一致之情形)。保護膜之端部T1位於較第1凸部10a之內側端部(端面)T3更內側時,難以得到捲痕缺陷抑制效果。 The end portion of one of the protective films is located on the first convex portion 10a, as in the example shown in Fig. 3, except that the end portion (end surface, T 1 in Fig. 3) of the protective film is located on the first convex portion 10a. In addition, the end portion T 1 including the protective film is located outside the outer end portion T 2 of the first convex portion 10a, but the end portion near the end portion T 1 of the protective film is placed in the first convex portion 10a. The situation on the top. The end region near the end portion T 1 of the protective film refers to a region where each end portion is 15% of the width of the polarizing plate. Thereby, the curl defect suppressing effect can be obtained. The end portion T 1 of the protective film is located on the first convex portion 10a, and the end portion T 1 is located between the outer end portion T 2 and the inner end portion T 3 of the first convex portion 10a (including T 1 and T 2 or T). 3 consistent situation). When the end portion T 1 of the protective film is located further inside than the inner end portion (end surface) T 3 of the first convex portion 10a, it is difficult to obtain the curl defect suppressing effect.

可得到捲痕缺陷抑制效果之偏光板20,可以如第3圖所示,以使偏光片21之寬度方向之端部T4位於較第1凸部10a之內側端部T3更內側之方式被捲繞於附凸部之捲芯10,亦可如第4圖所示,以使偏光片21之端部T4位於第1凸部10a上之方式,亦即以使偏光片21之端部T4位於第1凸部10a之外側端部T2與內側端部T3之間(包含T1與T2或T3一致之情形。)之方式捲繞於附凸部之捲芯10。較佳係前者。 The polarizing plate 20 which can obtain the effect of suppressing the curling defect can be such that the end portion T 4 in the width direction of the polarizing plate 21 is located further inside than the inner end portion T 3 of the first convex portion 10a as shown in Fig. 3 The winding core 10 wound around the convex portion may have the end portion T 4 of the polarizing plate 21 positioned on the first convex portion 10a as shown in Fig. 4 , that is, the end of the polarizing plate 21 The portion T 4 is located between the outer end portion T 2 of the first convex portion 10a and the inner end portion T 3 (including the case where T 1 coincides with T 2 or T 3 ). The winding core 10 is wound around the convex portion 10 . . It is better to be the former.

參照第3圖及第4圖,位於(搭載於)第1凸部10a上之保護膜的端部區域之寬度W2(保護膜與第1凸部10a之重疊寬度)以5mm以上為較佳,以10mm以上為更佳。若重疊寬度W2太小,難以獲得充分之捲痕缺陷抑制效果。重疊寬度W2之上限並無特別限制,但可設為例如30mm左右。第1凸部10a之寬度W1,為了能夠得到上述較佳的重疊寬度W2,以設為5mm以上為較佳。寬度W1之上限並無特別限制,例如為100mm。 With reference to Fig. 3 and Fig. 4, the width W 2 (the overlapping width of the protective film and the first convex portion 10a) of the end portion of the protective film (mounted on the first convex portion 10a) is preferably 5 mm or more. More preferably 10mm or more. If the overlap width W 2 is too small, it is difficult to obtain a sufficient curl defect suppressing effect. The upper limit of the overlapping width W 2 is not particularly limited, but may be, for example, about 30 mm. The width W 1 of the first convex portion 10a is preferably 5 mm or more in order to obtain the above-described preferable overlapping width W 2 . The upper limit of the width W 1 is not particularly limited and is, for example, 100 mm.

為了更有效獲得捲痕缺陷抑制效果,第1凸部10a之高度H以設為50μm以上為較佳。高度H之上限可為1500μm(例如1000μm)。例如藉由樹脂薄膜之貼著形成凸部時,如第5圖所示,為增大高度H,亦可使樹脂薄膜重疊捲繞複數層。第5圖係於第1樹脂薄膜t1之上藉 由重疊捲繞第2樹脂薄膜t2而形成第1凸部10a之例。使樹脂薄膜重疊捲繞複數層時,彼等之連接點如第5圖所示,以不使其一致而互相偏離為較佳。若使其一致,其連繫之連接點可成為捲痕缺陷之要因。 In order to obtain the curl defect suppressing effect more effectively, the height H of the first convex portion 10a is preferably 50 μm or more. The upper limit of the height H may be 1500 μm (for example, 1000 μm). For example, when the convex portion is formed by the adhesion of the resin film, as shown in Fig. 5, in order to increase the height H, the resin film may be wound and wound in a plurality of layers. Fig. 5 shows an example in which the first convex portion 10a is formed by superposing and winding the second resin film t 2 on the first resin film t 1 . When the resin film is wound around a plurality of layers, the connection points thereof are preferably shifted from each other without being uniform as shown in Fig. 5. If they are consistent, the connection point of the connection can be the cause of the defect of the wound.

如第4圖所示,偏光片21之端部T4位於第1凸部10a上時,為了更有效獲得捲痕缺陷抑制效果,相較於端部T4位於較第1凸部10a之內側端部T3更內側之情形,以使第1凸部10a之高度H較低為較佳。亦即,位於第1凸部10a上之偏光片21的厚度,使成為捲痕缺陷因素之偏光板的捲繞起始端與捲芯外周面之間產生之高低差(落差部分)增大,故若使第1凸部10a之高度H成為例如400μm以下、更進一步為200μm以下,較低者於捲痕缺陷抑制上較有利。 As shown in Fig. 4, when the end portion T 4 of the polarizer 21 is positioned on the first convex portion 10a, the curl portion defect suppressing effect is more effectively obtained, and the end portion T 4 is located on the inner side of the first convex portion 10a. It is preferable that the end portion T 3 is further inside so that the height H of the first convex portion 10a is lower. In other words, the thickness of the polarizer 21 located on the first convex portion 10a increases the height difference (falling portion) between the winding start end of the polarizing plate which is a factor of the curl defect and the outer peripheral surface of the core, so that the thickness is increased. When the height H of the first convex portion 10a is, for example, 400 μm or less, and further 200 μm or less, the lower one is advantageous in suppressing the curl defect.

另一方面,偏光片21之端部T4位於較第1凸部10a之內側端部T3更內側時,為了更有效獲得捲痕缺陷抑制效果,使第1凸部10a之高度H比較提高為較佳,例如以設為150μm以上、更進一步設為300μm以上為較佳。 On the other hand, when the end portion T 4 of the polarizer 21 is located inside the inner end portion T 3 of the first convex portion 10a, the height H of the first convex portion 10a is improved in order to more effectively obtain the curl defect suppressing effect. Preferably, it is preferably 150 μm or more, and more preferably 300 μm or more.

如上述,一般以更增大保護膜之寬度、使保護膜之寬度方向兩端部位於較偏光片之寬度方向兩端部更外側之方式貼合保護膜,參照第3圖,保護膜(第1保護膜22及第2保護膜23)之超出寬度W3(從保護膜22、23之端部T1至偏光片21之端部T4的距離)可設為1至100mm左右(例如5至60mm左右)。 As described above, the protective film is bonded so as to increase the width of the protective film so that both end portions in the width direction of the protective film are located outside the both end portions in the width direction of the polarizer. Referring to FIG. 3, the protective film (No. The excess width W 3 (the distance from the end portion T 1 of the protective films 22 and 23 to the end portion T 4 of the polarizing film 21) of the protective film 22 and the second protective film 23) can be set to about 1 to 100 mm (for example, 5) Up to 60mm).

(4)偏光板捲繞起始端固定於附凸部之捲芯 (4) The winding end of the polarizing plate is fixed to the core of the convex portion

藉由使附凸部之捲芯10以其旋轉軸為中心旋轉,可捲取偏光板20。此時,如第6圖所示,開始捲取之前,以使用固定構件30〔第6圖(a)〕將偏光板20之捲繞起始端(長度方向始端)固定於附凸部之捲芯10的外周面為較佳〔第6圖(b)〕。由於可簡便地固定偏光板20,固定構件30以使用雙面膠帶較佳。例如,使作為固定構件30之雙面膠帶與附凸部之捲芯10的旋轉軸平行,貼黏於附凸部之捲芯10之外周面,於其上使偏光板20之捲繞起始端以偏光板20之短邊方向與附凸部之捲芯10的旋轉軸平行之方式貼黏。藉由將偏光板20之捲繞起始端固定於附凸部之捲芯10,可順利進行尤其在初期之偏光板20的捲取。使用固定構件將偏光板20之捲繞起始端固定於附凸部之捲芯10時,於偏光板20之捲繞起始端與附凸部之捲芯10的外周面之間產生高低差(落差)而易產生捲痕缺陷,若依據本發明,即使在如此之情形,亦可有效抑制捲痕缺陷。 The polarizing plate 20 can be wound up by rotating the winding core 10 of the convex portion around the rotation axis thereof. At this time, as shown in Fig. 6, before the start of winding, the winding start end (length direction start end) of the polarizing plate 20 is fixed to the core of the convex portion by using the fixing member 30 [Fig. 6 (a)]. The outer peripheral surface of 10 is preferable (Fig. 6(b)). Since the polarizing plate 20 can be easily fixed, it is preferable to use the double-sided tape for the fixing member 30. For example, the double-sided tape as the fixing member 30 is parallel to the rotation axis of the core 10 of the convex portion, and is adhered to the outer circumferential surface of the core 10 of the convex portion, and the winding start end of the polarizing plate 20 is made thereon. The short side direction of the polarizing plate 20 is adhered in parallel with the rotation axis of the winding core 10 of the convex portion. By fixing the winding start end of the polarizing plate 20 to the winding core 10 of the convex portion, the winding of the polarizing plate 20, particularly in the initial stage, can be smoothly performed. When the winding start end of the polarizing plate 20 is fixed to the winding core 10 of the convex portion by using the fixing member, a height difference (fall) is generated between the winding start end of the polarizing plate 20 and the outer peripheral surface of the winding core 10 of the convex portion. However, it is easy to cause a curl defect, and according to the present invention, even in such a case, the curl defect can be effectively suppressed.

[實施例] [Examples]

以下,表示實施例及比較例更具體說明本發明,但本發明係不受此等例所限定。 Hereinafter, the present invention will be specifically described by way of examples and comparative examples, but the present invention is not limited by these examples.

<比較例1> <Comparative Example 1>

將由三乙醯基纖維素(TAC)構成之第1保護膜〔厚度40μm〕/接著劑層/縱一軸延伸之聚乙烯醇系樹脂薄膜吸附配向二色性色素而成之偏光片〔厚度28μm〕/接著 劑層/由TAC構成之第2保護膜〔厚度40μm〕/由延伸聚對苯二甲酸乙二酯構成之保護薄膜〔厚度62μm〕之層構造所構成之長條偏光板以捲筒至捲筒之方式連續製作,同時捲繞於圓柱狀捲芯(無凸部),獲得偏光板捲筒。偏光板捲筒製作之具體條件如下。又,偏光板之捲繞起始端(長度方向起始端),係使用厚度176μm之兩面膠帶,固定於捲芯之外周面。 A polarizing film (thickness: 28 μm) obtained by adsorbing a dichroic dye to a first protective film (thickness: 40 μm)/adhesive layer/longitudinal axis-extending polyvinyl alcohol-based resin film made of triethylenesulfonyl cellulose (TAC) /then Coating layer / second protective film (thickness 40 μm) composed of TAC / long polarizing plate composed of a layer structure of a protective film (thickness 62 μm) composed of extended polyethylene terephthalate, from reel to reel The method is continuously produced, and is wound around a cylindrical core (without a convex portion) to obtain a polarizing plate roll. The specific conditions for the production of the polarizing plate reel are as follows. Further, the winding start end (starting end in the longitudinal direction) of the polarizing plate was fixed to the outer peripheral surface of the core by using a double-sided tape having a thickness of 176 μm.

〔1〕圓柱狀捲芯(無凸部).材質:FRP(纖維強化塑膠)、.寬度方向(旋轉軸方向)長度:1480mm、.直徑:167mm 、〔2〕偏光板.保護膜之寬度:1330mm、.偏光片之寬度:1270mm、.第3圖中之W3:30mm(兩端皆是)、.偏光板長度:約2000m、.偏光板捲取時之張力:60N。 [1] cylindrical core (no convex). Material: FRP (fiber reinforced plastic),. Width direction (rotation axis direction) length: 1480mm,. Diameter: 167mm , [2] polarizing plate. The width of the protective film: 1330mm, The width of the polarizer: 1270mm,. In the third figure, W 3 : 30mm (both ends are). Polarizer length: about 2000m. Tension when the polarizing plate is taken up: 60N.

<比較例2至4> <Comparative Examples 2 to 4>

除了將偏光板捲取時之張力分別設為100N(比較例2)、150N(比較例3)、250N(比較例4)以外,其餘與比較例1同樣製作偏光板捲筒。 A polarizing plate reel was produced in the same manner as in Comparative Example 1, except that the tension at the time of winding the polarizing plate was 100 N (Comparative Example 2), 150 N (Comparative Example 3), and 250 N (Comparative Example 4).

<實施例1> <Example 1>

使用與第1圖同樣之附凸部之捲芯,除使偏光板捲筒製作之具體條件如下述以外,其餘與比較例1同樣製作偏 光板捲筒。偏光板係以使貼合於偏光片之兩面的保護膜之寬度方向之一方的端部區域位於第1凸部上、另一方之端部區域位於第2凸部上之方式捲繞。但,如第3圖所示,係以偏光片21之端部T4位於較第1凸部10a及第2凸部10b之內側端部T3更內側之方式(以偏光片與凸部不重複之方式)捲繞。附凸部之捲芯的第1及第2凸部係如第5圖所示,將於單面具有黏著劑層之一定寬度的樹脂薄膜膠帶大致涵蓋全周貼黏於捲芯本體部分之外周面,進而於其外周面將於單面具有黏著劑層之相同寬度的樹脂薄膜膠帶從偏離連接點約15mm貼黏大致涵蓋全周而形成。 A polarizing plate reel was produced in the same manner as in Comparative Example 1, except that the specific conditions for the production of the polarizing plate reel were as follows, using the same winding core as in the first embodiment. The polarizing plate is wound such that one end region of one of the width directions of the protective film bonded to both surfaces of the polarizer is positioned on the first convex portion and the other end portion is located on the second convex portion. However, as shown in Fig. 3, the end portion T 4 of the polarizer 21 is located further inside than the inner end portion T 3 of the first convex portion 10a and the second convex portion 10b (the polarizer and the convex portion are not Repeatedly) winding. The first and second convex portions of the core of the convex portion are as shown in Fig. 5, and the resin film tape having a certain width of the adhesive layer on one side substantially covers the periphery of the core portion of the core. The surface of the resin film tape having the same width of the adhesive layer on one side of the outer peripheral surface is formed by sticking approximately 15 mm from the joint point to cover the entire circumference.

〔1〕附凸部之捲芯(本體部分:圓柱狀).材質:FRP(纖維強化塑膠)、.寬度方向(旋轉軸方向)長度:1480mm、.本體部分之直徑:167mm 、.第1及第2凸部之寬度(第3圖中之W1):10mm、.第1及第2凸部之高度(第3圖中之H):360μm、〔2〕偏光板.保護膜之寬度:1330mm、.偏光片之寬度:1270mm、.保護膜之超出寬度(第3圖中之W3):30mm(兩端皆是)、.偏光板長度:約2000m、.偏光板捲取時之張力:60N、〔3〕偏光板與附凸部之捲芯之位置關係.兩面之保護膜與第1及第2凸部之重疊寬度(第3圖中之 W2):10mm、.偏光片與第1及第2凸部之重疊寬度:0mm。 [1] The core of the convex part (body part: cylindrical). Material: FRP (fiber reinforced plastic),. Width direction (rotation axis direction) length: 1480mm,. The diameter of the body part: 167mm , The width of the first and second convex portions (W 1 in Fig. 3): 10 mm, The height of the first and second convex portions (H in Fig. 3): 360 μm, [2] polarizing plate. The width of the protective film: 1330mm, The width of the polarizer: 1270mm,. The excess width of the protective film (W 3 in Fig. 3 ): 30mm (both ends are). Polarizer length: about 2000m. The tension when the polarizing plate is taken up: 60N, [3] the positional relationship between the polarizing plate and the core of the convex portion. The overlapping width of the protective film on both sides and the first and second convex portions (W 2 in Fig. 3): 10 mm. The overlap width between the polarizer and the first and second convex portions is 0 mm.

<實施例2至3> <Examples 2 to 3>

除了將偏光板捲取時之張力分別設為150N(實施例2)、250N(實施例3)以外,其餘與實施例1同樣製作偏光板捲筒。 A polarizing plate reel was produced in the same manner as in Example 1 except that the tension when the polarizing plate was taken up was 150 N (Example 2) and 250 N (Example 3).

<實施例4> <Example 4>

除了將偏光板捲取時之張力設為150N,使樹脂薄膜膠帶重疊捲繞3層,並使第1及第2凸部之高度(第3圖中之H)設為540μm以外,其餘與實施例1同樣製作偏光板捲筒。 In addition to the tension when the polarizing plate was taken up, the tension was 150 N, and the resin film tape was wound and wound in three layers, and the heights of the first and second convex portions (H in FIG. 3) were set to 540 μm. In Example 1, a polarizing plate reel was also produced.

<實施例5> <Example 5>

使用與第1圖同樣之附凸部之捲芯,除了使偏光板捲筒製作之具體條件如下述以外,其餘與比較例1同樣製作偏光板捲筒。偏光板係以使貼合於偏光片之兩面的保護膜之寬度方向之一方的端部區域位於第1凸部上、另一方之端部區域位於第2凸部上之方式捲繞。在本實施例中,如第4圖所示,係以偏光片21之寬度方向之一方的端部T4位於第1凸部10a上、另一方之端部T4位於第2凸部10b部上之方式捲繞。附凸部之捲芯的第1及第2凸部,係將於單面具有黏著劑層之一定寬度的樹脂薄膜膠帶,如第2圖般大致涵蓋全周貼黏於捲芯本體部分之外周面而形成。 A core of a polarizing plate was produced in the same manner as in Comparative Example 1, except that the specific conditions for producing the polarizing plate were the same as in the first embodiment. The polarizing plate is wound such that one end region of one of the width directions of the protective film bonded to both surfaces of the polarizer is positioned on the first convex portion and the other end portion is located on the second convex portion. In the present embodiment, as shown in Fig. 4, the end portion T 4 in which one of the width directions of the polarizing plate 21 is located on the first convex portion 10a, and the other end portion T 4 is located in the second convex portion 10b. Winding on the way. The first and second convex portions of the core of the convex portion are resin film tapes having a certain width of the adhesive layer on one side, and as shown in FIG. 2, the periphery of the core portion is substantially covered for the entire circumference. Formed in the face.

〔1〕附凸部之捲芯(本體部分:圓柱狀).材質:FRP(纖維強化塑膠)、 .寬度方向(旋轉軸方向)長度:1480mm、.本體部分之直徑:167mm 、.第1及第2凸部之寬度(第4圖中之W1):10mm、.第1及第2凸部之高度(第圖4中之H):360μm、〔2〕偏光板.保護膜之寬度:1330mm、.偏光片之寬度:1270mm、.保護膜之超出寬度(第3圖中之W3):30mm(兩端皆是)、.偏光板長度:約2000m、.偏光板捲取時之張力:250N、〔3〕偏光板與附凸部之捲芯之位置關係.兩面之保護膜與第1及第2凸部之重疊寬度(第圖4中之W2):10mm、.偏光片與第1及第2凸部之重疊寬度(從第4圖中之端部T4至凸部之內側端部T3之距離):10mm。 [1] The core of the convex part (body part: cylindrical). Material: FRP (fiber reinforced plastic), . Width direction (rotation axis direction) length: 1480mm,. The diameter of the body part: 167mm , The width of the first and second convex portions (W1 in Fig. 4): 10 mm, The height of the first and second convex portions (H in Fig. 4): 360 μm, [2] polarizing plate. The width of the protective film: 1330mm, The width of the polarizer: 1270mm,. The excess width of the protective film (W3 in Fig. 3): 30mm (both ends are). Polarizer length: about 2000m. The tension when the polarizing plate is taken up: 250N, [3] the positional relationship between the polarizing plate and the core of the convex portion. The overlapping width of the protective film on both sides and the first and second convex portions (W2 in Fig. 4): 10 mm. The overlapping width of the polarizer and the first and second convex portions (the distance from the end portion T4 in Fig. 4 to the inner end portion T3 of the convex portion): 10 mm.

<實施例6> <Example 6>

除了將第1及第2凸部之高度(第4圖中之H)設為180μm以外,其餘與實施例5同樣製作偏光板捲筒。 A polarizing plate reel was produced in the same manner as in Example 5 except that the heights of the first and second convex portions (H in Fig. 4) were 180 μm.

將實施例1至6及比較例1至4中之偏光板捲筒的主要製造條件彙總於第1表。製成之偏光板捲筒在25℃ 50%RH之環境下保管15日後,捲出偏光板捲筒,測定從偏光板之開始捲繞處的捲痕缺陷之發生長度。將結果表示於第1表中。 The main manufacturing conditions of the polarizing plate reels of Examples 1 to 6 and Comparative Examples 1 to 4 are summarized in Table 1. The prepared polarizing plate roll was stored in an environment of 25 ° C and 50% RH for 15 days, and then the polarizing plate roll was taken up, and the length of occurrence of the curl defect at the winding from the start of the polarizing plate was measured. The results are shown in the first table.

10‧‧‧附凸部之捲芯 10‧‧‧With the core of the convex part

10a‧‧‧第1凸部 10a‧‧‧1st convex

20‧‧‧偏光板 20‧‧‧Polar plate

21‧‧‧偏光片 21‧‧‧ polarizer

22‧‧‧第1保護膜 22‧‧‧1st protective film

23‧‧‧第2保護膜 23‧‧‧2nd protective film

Claims (5)

一種偏光板捲筒,含有:於外周面具備朝周方向延伸之第1凸部及第2凸部的捲芯、及捲繞於前述捲芯之偏光板,前述偏光板具備偏光片及積層於其至少一方的面上之保護膜,前述偏光板係以前述保護膜之寬度方向之一方的端部區域位於前述第1凸部上、另一方之端部區域位於前述第2凸部上之方式捲繞於前述捲芯。 A polarizing plate roll includes: a winding core having a first convex portion and a second convex portion extending in a circumferential direction on an outer circumferential surface; and a polarizing plate wound around the winding core, wherein the polarizing plate includes a polarizing plate and a laminate The protective film on the surface of at least one of the polarizing plates is such that one end region of the protective film in the width direction is located on the first convex portion and the other end region is located on the second convex portion. Winding on the aforementioned core. 如申請專利範圍第1項所述之偏光板捲筒,其中,前述偏光板係以前述偏光片之寬度方向之一方的端部位於較前述第1凸部之內側端部更內側處、另一方之端部位於較前述第2凸部之內側端部更內側處之方式捲繞於前述捲芯。 The polarizing plate roll according to the first aspect of the invention, wherein the polarizing plate has one end portion in a width direction of the polarizing plate located further inward than an inner end portion of the first convex portion, and the other side The end portion is wound around the winding core so as to be located further inside than the inner end portion of the second convex portion. 如申請專利範圍第1或2項所述之偏光板捲筒,其中,前述偏光板之捲繞起始端係為使用固定構件固定於前述外周面。 The polarizing plate reel according to claim 1 or 2, wherein the winding start end of the polarizing plate is fixed to the outer peripheral surface by using a fixing member. 如申請專利範圍第1至3項中任一項所述之偏光板捲筒,其中,前述第1凸部及前述第2凸部之高度分別為50μm以上。 The polarizing plate roll according to any one of claims 1 to 3, wherein the height of each of the first convex portion and the second convex portion is 50 μm or more. 如申請專利範圍第1至4項中任一項所述之偏光板捲筒,其中,前述第1凸部及前述第2凸部係以貼黏於前述外周面之樹脂薄膜構成。 The polarizing plate roll according to any one of claims 1 to 4, wherein the first convex portion and the second convex portion are formed of a resin film adhered to the outer peripheral surface.
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