TW201544162A - Gas-liquid-solid separator, gas-liquid separator and plasma desulphuration and denitration apparatus comprising same - Google Patents
Gas-liquid-solid separator, gas-liquid separator and plasma desulphuration and denitration apparatus comprising same Download PDFInfo
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
- B01D45/12—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
- B01D50/20—Combinations of devices covered by groups B01D45/00 and B01D46/00
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
本發明涉及工業廢氣淨化領域,特別涉及一種氣液固分離器、氣液分離器及其電漿除硫脫硝設備。 The invention relates to the field of industrial exhaust gas purification, in particular to a gas-liquid solid separator, a gas-liquid separator and a plasma sulfur removal and denitration device.
硫化物與氮氧化物的排放是造成大氣污染及酸雨不斷加劇的主要原因。 Sulfide and nitrogen oxide emissions are the main causes of air pollution and acid rain.
據國家統計,燃煤電廠的二氧化硫排放量約占二氧化硫總排放量的50%,因此,對硫化物與氮氧化物排放的控制關係到節能減排目標的實現。 According to national statistics, the sulfur dioxide emissions of coal-fired power plants account for about 50% of the total emissions of sulfur dioxide. Therefore, the control of sulfide and nitrogen oxide emissions is related to the realization of energy-saving emission reduction targets.
為了脫硫脫硝,工業上依然採用傳統的濕法石灰石-石膏法煙氣脫硫技術(CA-WFGD)和氨選擇性催化還原法(NH3-SCR),兩種工藝聯合使用可實現同時脫硫脫硝,但兩個系統簡單疊加造成工藝流程和系統複雜,佔用面積大,投資和運行成本高,難以大規模推廣應用,在濕法煙氣脫硫脫硝的過程中,NOX中含有90%的以上難溶於水的NO,NO在室溫(25℃)下的亨利常數僅為1.94×10-8mol/L‧Pa,比SO2低三個數量級,僅通過調控pH和溫度的方法難以顯著提高NO在液相的溶解度,因此嚴重制約著脫硫脫硝的效率。 For the purpose of desulfurization and denitrification, the traditional wet limestone-gypsum flue gas desulfurization technology (CA-WFGD) and ammonia selective catalytic reduction (NH 3 -SCR) are still used in the industry. Desulfurization and denitrification, but the simple superposition of the two systems results in complex process and system, large occupied area, high investment and operating costs, and difficult to promote and apply on a large scale. In the process of wet flue gas desulfurization and denitrification, NO X The Henry's constant of 90% or more of water-insoluble NO and NO at room temperature (25 ° C) is only 1.94 × 10 -8 mol / L ‧ Pa, three orders of magnitude lower than SO 2 , only by regulating pH and The method of temperature is difficult to significantly increase the solubility of NO in the liquid phase, thus seriously restricting the efficiency of desulfurization and denitrification.
為了解決上述技術問題,申請公佈號CN101940871A的中國專利公開了一種基於光化學高級氧化的同時脫硫脫硝系統,請結合圖1予以理解,該脫硫脫硝系統(1)包括燃燒器(11)、靜電除塵器(12)、 換熱器(13)、噴淋器(14)、霧化噴嘴(15)、紫外燈(16)、循環泵(17)、自添液塔(18)、分離塔(19)和煙囪(110)。 In order to solve the above technical problem, the Chinese patent of the publication No. CN101940871A discloses a simultaneous desulfurization and denitration system based on photochemical advanced oxidation, which is understood in conjunction with Fig. 1, the desulfurization and denitration system (1) includes a burner (11) ), electrostatic precipitator (12), Heat exchanger (13), shower (14), atomizing nozzle (15), ultraviolet lamp (16), circulation pump (17), self-adding liquid column (18), separation tower (19) and chimney (110) ).
使用時,通過自添液塔(18)的進氣管(111)輸入H2O2溶液,利用紫外燈(16)激發的紫外光激發分解H2O2,產生具有強氧化性的羥基自由基(OH-),進而氧化脫除煙氣中的NOX與SO2,反應產物為可資源化利用的硫酸與硝酸溶液,添加氨水後即可生成農業肥料。 In use, the H 2 O 2 solution is input through the intake pipe (111) of the liquid addition tower (18), and the ultraviolet light excited by the ultraviolet lamp (16) is used to excite and decompose H 2 O 2 to generate a hydroxyl group having strong oxidizing property. group (OH -), and further oxidation of NO X in the flue gas removal and SO 2, the reaction product of sulfuric acid and nitric acid solution to be resource utilization, to generate the ammonia is added agricultural fertilizer.
為了保證輻射光功率,上述脫硫脫硝系統(1)需要設置多根紫外燈(16),一方面會在噴淋器(14)內形成風阻,需要多個循環泵(17)抽送氣體,另一方面存在光電轉換效率和吸收效率低的問題,即電能轉化成光能會有能量的損失,光能在穿透含有大量顆粒物的灰黑煙氣被H2O2吸收時,又存在光能衰減和吸收不完全的問題,經過光電轉換損耗和吸收時的光能衰減,電能的實際利用率仍較低,並且難以提高。 In order to ensure the radiated light power, the above-mentioned desulfurization and denitration system (1) needs to be provided with a plurality of ultraviolet lamps (16), on the one hand, a wind resistance is formed in the shower (14), and a plurality of circulating pumps (17) are required to pump gas. On the other hand, there is a problem that the photoelectric conversion efficiency and the absorption efficiency are low, that is, the conversion of electric energy into light energy has a loss of energy, and when light energy is absorbed by H 2 O 2 through the ash black smoke containing a large amount of particulate matter, light is present again. The problem of incomplete attenuation and absorption, the photoelectric energy loss after photoelectric conversion loss and absorption, the actual utilization of electric energy is still low, and it is difficult to improve.
此外,在熱電廠燃煤過程中,採用不同種類和品質的煤炭(例如褐煤、煙煤或煤粉)以及不同的燃燒條件(是否過氧氣燃燒和燃燒溫度高低)會產生不同中心粒徑的煙灰顆粒。 In addition, in the coal-fired process of thermal power plants, different types and qualities of coal (such as lignite, bituminous coal or pulverized coal) and different combustion conditions (whether or not the oxygen combustion and combustion temperature) can produce soot particles with different center particle sizes.
因此,對不同粒徑煙灰顆粒的篩選也成為脫硫脫硝領域中面臨的技術難題,經過對現有市場調查,發現市場銷售的氣液分離器不能夠依據熱電廠燃煤狀況篩選不同中心粒徑的煙灰顆粒。 Therefore, the screening of different particle size soot particles has become a technical problem in the field of desulfurization and denitrification. After investigation of the existing market, it is found that the gas-liquid separators sold in the market cannot screen different central particle sizes according to the coal-fired conditions of thermal power plants. Soot particles.
本發明人有鑑於上述習知脫硫脫硝系統之實用困難及有待改善之缺失,盼能提供一突破性之設計,以增進實用效果,乃潛心研思、設計組製,綜集其多年從事相關產品設計產銷之專業技術知識與實務經驗及研思設計所得之成果,終研究出本創作一種氣液固分離器、氣液分離器及其電漿除 硫脫硝設備,以提供使用者。 The present inventors have in view of the practical difficulties of the above-mentioned conventional desulfurization and denitration system and the lack of improvement, and hope to provide a breakthrough design to enhance the practical effect, which is devoted to research and design, and has been engaged for many years. The professional technical knowledge and practical experience of related product design and production, and the results obtained from the research and design, finally developed a gas-liquid-solid separator, gas-liquid separator and plasma removal. Sulfur denitration equipment to provide users.
本發明要解決的技術問題是為了克服現有技術的氣液分離器不能夠依據燃煤狀況篩選不同中心粒徑的煙灰顆粒的缺陷,提供一種氣液固分離器、氣液分離器及其電漿除硫脫硝設備,該氣液固分離器能夠依據燃煤狀況篩選不同中心粒徑的煙灰顆粒。 The technical problem to be solved by the present invention is to overcome the defects that the prior art gas-liquid separator can not screen the soot particles of different central particle sizes according to the coal burning condition, and provide a gas-liquid solid separator, a gas-liquid separator and a plasma thereof. In addition to the sulfur denitration equipment, the gas-liquid-solid separator can screen soot particles of different center sizes according to the coal-burning condition.
本發明是通過下述技術方案來解決上述技術問題:一種氣液固分離器,其特點在於,該氣液固分離器包括一個圓筒狀的殼體,一個嵌置於該殼體內的濾芯和一個排水閥,該殼體的側面上設置有一個具有法蘭的進氣口和一個具有法蘭的排氣口,該殼體和該濾芯之間形成有旋流風道,該進氣口的軸線和該排氣口的軸線均偏離該殼體的軸心,該進氣口、該旋流風道和該排氣口依次相互連通,該排水閥設置於該殼體的底面且與該旋流風道相互連通,該濾芯包括三個同軸嵌套的柱狀過濾桶,該些柱狀過濾桶從內至外依次為燒結過濾器、內過濾桶和外過濾桶,該內過濾桶和該外過濾桶上均陣列有多個過濾孔,該些過濾孔能夠在該內過濾桶和該外過濾桶相對旋轉時相互對正或錯開。 The present invention solves the above technical problem by the following technical solution: a gas-liquid-solid separator, characterized in that the gas-liquid-solid separator comprises a cylindrical casing, a filter element embedded in the casing and a drain valve, the side of the casing is provided with a flanged air inlet and a flanged exhaust port, and a swirling air duct is formed between the casing and the filter core, the axis of the air inlet And the axis of the exhaust port is offset from the axis of the housing, the air inlet, the swirling air channel and the exhaust port are in communication with each other, and the drain valve is disposed on a bottom surface of the housing and the swirling air passage Interconnected, the filter element comprises three coaxially nested column filter barrels, which are a sintered filter, an inner filter barrel and an outer filter barrel from the inside to the outside, the inner filter barrel and the outer filter barrel The upper average array has a plurality of filter holes that are aligned or offset from each other when the inner filter barrel and the outer filter barrel rotate relative to each other.
較佳地,該進氣口設置於該殼體的下部,該排氣口設置於該殼體的上部,該進氣口上設置有測試該進氣口內流體壓力的第一壓力錶,該排氣口上設置有測試該排氣口內流體壓力的第二壓力錶,該內過濾桶上設置有托板,該內過濾桶通過該托板與該燒結過濾器固定連接。 Preferably, the air inlet is disposed at a lower portion of the housing, and the air outlet is disposed at an upper portion of the housing, and the air inlet is provided with a first pressure gauge for testing fluid pressure in the air inlet, the row A second pressure gauge for testing fluid pressure in the exhaust port is disposed on the air port, and the inner filter bucket is provided with a pallet, and the inner filter bucket is fixedly connected to the sintered filter through the pallet.
一種氣液分離器,其特點在於,該氣液分離器包括一個圓筒狀的殼體,一個嵌置於該殼體內的濾芯和一個排水閥,該殼體的側面上設置有一個具有法蘭的進氣口和一個具有法蘭的排氣口,該殼體和該濾芯之間形成有旋流風道,該進氣口的軸線和該排氣口的軸線均偏離該殼體的軸 心,該進氣口、該旋流風道和該排氣口依次相互連通,該排水閥設置於該殼體的底面且與該旋流風道相互連通,該濾芯包括兩個同軸嵌套的柱狀過濾桶,該些柱狀過濾桶上均陣列有多個過濾孔,該些過濾孔能夠在相對旋轉時相互對正或錯開。 A gas-liquid separator, characterized in that the gas-liquid separator comprises a cylindrical casing, a filter element embedded in the casing and a drain valve, and a flange is arranged on a side of the casing An air inlet and a flanged exhaust port, a swirling air duct is formed between the housing and the filter element, and an axis of the air inlet and an axis of the air outlet are offset from an axis of the housing The air inlet, the swirling air passage and the exhaust port are in communication with each other in sequence. The drain valve is disposed on a bottom surface of the housing and communicates with the swirling air duct. The filter element comprises two coaxially nested columns. Filter barrels are arranged on the column filter barrels with a plurality of filter holes, which can be aligned or offset with each other when rotated relative to each other.
較佳地,該兩個同軸嵌套的柱狀過濾桶分別為一外過濾桶和一個內過濾桶,該內過濾桶嵌套於該外過濾桶內,該外過濾桶上設置有一個螺旋狀的引流板,該引流板用於引導旋流風道內的氣體螺旋運動。 Preferably, the two coaxially nested column filter buckets are respectively an outer filter bucket and an inner filter bucket, and the inner filter bucket is nested in the outer filter bucket, and the outer filter bucket is provided with a spiral A drain plate for guiding the helical movement of gas within the swirling air passage.
較佳地,該進氣口和該排氣口均設置於該殼體的上部,該外過濾桶的上部設置有擋流板,該擋流板用於將從該進氣口流入的氣體阻擋向該引流板,以便使得該引流板引導該氣體螺旋撞向該濾芯的底部。 Preferably, the air inlet and the air outlet are both disposed at an upper portion of the housing, and an upper portion of the outer filter bucket is provided with a baffle for blocking gas flowing in from the air inlet The drain plate is directed such that the drain plate directs the gas spiral into the bottom of the filter element.
較佳地,該內過濾桶內設置有多個環形固定架和多個旋流器,該些旋流器通過該些環形固定架固定於該內過濾桶內,該些旋流器的旋轉方向與該引流板的引流方向相同。 Preferably, the inner filter bucket is provided with a plurality of annular fixing brackets and a plurality of swirlers, and the swirlers are fixed in the inner filter buckets by the annular fixing brackets, and the swirling directions of the swirlers The direction of drainage is the same as that of the drain plate.
較佳地,該氣液分離器還包括一個碟形的集液過濾器和一個導液管,該殼體、該集液過濾器、該導液管和該排水閥依次相互連通,該集液過濾器上陣列有多個集液過濾孔,該集液過濾器的碟形腔體用於收集煙灰顆粒。 Preferably, the gas-liquid separator further comprises a dish-shaped liquid collecting filter and a liquid guiding tube, and the casing, the liquid collecting filter, the liquid guiding tube and the drain valve are in communication with each other in sequence, and the collecting liquid The array on the filter has a plurality of collection filter holes, and the dish-shaped cavity of the liquid collection filter is used to collect soot particles.
一種電漿除硫脫硝設備,其特點在於,該電漿除硫脫硝設備包括一個供氨系統、如上所述的氣液固分離器和如上所述的氣液分離器,該電漿除硫脫硝設備還包括一個第一氣固分離器、一個氣液分離器、一個第一介質電漿、一個反應罐和一個第二氣固分離器,該氣液固分離器、該第一氣固分離器、該氣液分離器、該第一介質電漿、該反應罐和該第二氣固分離器依次相互連通,該供氨系統與該反應罐相互連通。 A plasma desulfurization and denitration device, characterized in that the plasma desulfurization and denitration device comprises an ammonia supply system, a gas liquid solid separator as described above and a gas liquid separator as described above, the plasma removal The sulfur denitration apparatus further includes a first gas-solid separator, a gas-liquid separator, a first medium plasma, a reaction tank and a second gas-solid separator, the gas-liquid-solid separator, the first gas The solid separator, the gas-liquid separator, the first medium plasma, the reaction tank, and the second gas-solid separator are in communication with each other, and the ammonia supply system and the reaction tank are in communication with each other.
較佳地,該電漿除硫脫硝設備還包括一個納米電漿,該氣液 分離器、該納米電漿和該第一介質電漿依次相互連通,納米電漿主要起增強自由基濃度的作用,對於排放指標要求較高的工況,可以使用納米電漿。 Preferably, the plasma sulfur removal and denitration device further comprises a nano plasma, the gas liquid The separator, the nano-plasma and the first dielectric plasma are connected to each other in turn, and the nano-plasma mainly functions to enhance the concentration of the radical. For the working condition requiring high emission index, the nano-plasma can be used.
較佳地,該第一氣固分離器包括第一進氣管道、第二進氣管道、第一排氣管道、第二排氣管道、一個過濾芯子和一個過濾腔,該過濾芯子設置於該過濾腔內,該第一進氣管道用於通過該過濾芯子將流體通向該第一排氣管道,該第二進氣管道用於通過該過濾芯子將流體通向該第二排氣管道,該第一進氣管道和該第二進氣管道相對設置且能夠保持流體的方向相對。 Preferably, the first gas-solid separator comprises a first intake duct, a second intake duct, a first exhaust duct, a second exhaust duct, a filter core and a filter chamber, and the filter core is arranged In the filter chamber, the first intake duct is configured to pass fluid to the first exhaust duct through the filter core, and the second intake duct is configured to pass fluid to the second through the filter core An exhaust duct, the first intake duct and the second intake duct are oppositely disposed and capable of maintaining a direction of fluid relative to each other.
較佳地,該過濾芯子為折疊狀,該過濾腔內設置有多個固定杆,該些固定杆支撐於該過濾芯子的折疊拐角處,以分隔相鄰兩個折疊層。 Preferably, the filter core is folded, and the filter chamber is provided with a plurality of fixing rods supported at the folded corners of the filter core to separate adjacent two folded layers.
較佳地,該第一進氣管道、該第二進氣管道、該第一排氣管道和該第二排氣管道均通過一個漸擴部與該過濾腔相互連通,該第一進氣管道的漸擴部和該第二進氣管道的漸擴部用於均布流體和緩解流速,該第一排氣管道的漸擴部和該第二排氣管道的漸擴部用於彙集過濾後的流體,該過濾芯子的相鄰兩個折疊層的夾角為5°至15°。 Preferably, the first intake duct, the second intake duct, the first exhaust duct and the second exhaust duct communicate with the filter chamber through a diverging portion, the first intake duct The diverging portion and the diverging portion of the second intake duct are for distributing fluid and mitigating the flow rate, and the diverging portion of the first exhaust duct and the diverging portion of the second exhaust duct are used for collecting and filtering The fluid, the adjacent two folded layers of the filter core have an angle of 5° to 15°.
較佳地,該第一氣固分離器還包括一個具有旋轉分隔板和閘門開關的煙灰暫存腔,該煙灰暫存腔和該過濾腔之間設置有分隔板,該分隔板與該第一氣固分離器的內壁面之間設置有夾縫,該煙灰暫存腔和該過濾腔通過該夾縫相互連通,該閘門開關用於控制該旋轉分隔板轉動以便釋放該煙灰暫存腔內的煙灰顆粒。 Preferably, the first gas-solid separator further comprises a soot temporary storage chamber having a rotating partition plate and a gate switch, and a partition plate is disposed between the soot temporary storage chamber and the filter chamber, the partition plate and the partition plate a gap is disposed between the inner wall surfaces of the first gas-solid separator, and the soot temporary storage chamber and the filter chamber communicate with each other through the nip, the gate switch is configured to control the rotation of the rotating partition plate to release the soot temporary storage chamber Soot particles inside.
較佳地,該第一氣固分離器還包括一個煙灰輸運車,該煙灰輸運車包括一個箱體和設置於該箱體端部的輪子,該煙灰暫存腔通過一個輸料管道與該箱體相互連通。 Preferably, the first gas-solid separator further comprises a soot conveying vehicle, the soot conveying vehicle comprises a box body and a wheel disposed at an end of the box body, the soot temporary storage chamber is passed through a conveying pipe and The cabinets are connected to each other.
較佳地,該第一氣固分離器上設置有具有換熱器的第一控溫 設備,該換熱器為表面式換熱器或直接接觸式換熱器。 Preferably, the first gas-solid separator is provided with a first temperature control unit having a heat exchanger Equipment, the heat exchanger is a surface heat exchanger or a direct contact heat exchanger.
較佳地,該納米電漿的兩側均設置有恒溫控制系統並且形成夾持該納米電漿的結構,該第一介質電漿的兩側均設置有恒溫控制系統並且形成夾持該第一介質電漿的結構。 Preferably, both sides of the nano-plasma are provided with a thermostatic control system and form a structure for clamping the nano-plasma, and both sides of the first dielectric plasma are provided with a thermostatic control system and form a clamping first The structure of the dielectric plasma.
較佳地,該些恒溫控制系統均包括一個通風罩,該些通風罩均由一個轉接管、一個漸擴管和一個矩形的轉接頭組成。 Preferably, the thermostatic control systems each include a hood that is comprised of a transfer tube, a diverging tube, and a rectangular adapter.
較佳地,該些轉接頭均包括一個環形的通氣隙,每一通氣隙包括依次相互連通的一個上通氣環道、一個中通氣環道和一個下通氣環道,該些通氣隙用於循環加熱氣體。 Preferably, the adapters each include an annular venting gap, and each venting gap includes an upper venting loop, a middle venting loop, and a lower venting loop that are in communication with each other. Circulating heating gas.
較佳地,該些恒溫控制系統還均包括一個溫度控制箱和一個鼓風機,該下通氣環道的排氣口、該鼓風機、該溫度控制箱和該上通氣環道的進氣口依次相互連通。 Preferably, the thermostatic control systems further comprise a temperature control box and a blower, wherein the exhaust port of the lower venting ring, the blower, the temperature control box and the air inlet of the upper venting ring are sequentially connected to each other. .
較佳地,該溫度控制箱內設置有一個加熱器,該溫度控制箱包括有一個具有保溫層的外殼,該保溫層內設置有溫度感測器。 Preferably, the temperature control box is provided with a heater, and the temperature control box comprises a casing having an insulation layer, and the temperature sensor is provided with a temperature sensor.
較佳地,該反應罐包括依次相互連通的第一反應腔、顆粒暫存腔和第二反應腔體,該第一反應腔和該第二反應腔體內均設置有多個導流板,該些導流板用於阻擋流體和改變流向,使得流體均勻混合,該反應罐上還設置有與該顆粒暫存腔相互連通的排料閥。 Preferably, the reaction tank comprises a first reaction chamber, a particle temporary storage chamber and a second reaction chamber which are sequentially connected to each other, and a plurality of baffles are disposed in the first reaction chamber and the second reaction chamber. The baffles are used to block the fluid and change the flow direction so that the fluid is uniformly mixed, and the reaction tank is further provided with a discharge valve that communicates with the particle temporary storage chamber.
較佳地,該第一反應腔、該顆粒暫存腔和該第二反應腔體的內壁面覆蓋有聚氨基甲酸酯塗層或聚四氟乙烯塗層。 Preferably, the first reaction chamber, the particle temporary storage chamber and the inner wall surface of the second reaction chamber are covered with a polyurethane coating or a polytetrafluoroethylene coating.
本發明的積極進步效果在於:本發明的氣液固分離器能夠依據燃煤狀況篩選不同中心粒徑的煙灰顆粒,另外,介質電漿和納米電漿對濕度要求較高,況且燃煤電廠的排煙管路均較長,煙道廢氣在管道內輸送的過程中 存在吸濕和結露現象,這種現象在冬季尤為明顯,因此對煙道廢氣的乾燥和除濕尤為必要,本發明的氣液固分離器能夠除濕,防止電漿洩露。 The positive progressive effect of the invention is that the gas-liquid-solid separator of the invention can screen the soot particles of different central particle sizes according to the coal-burning condition, and the medium plasma and the nano-plasma have higher requirements on humidity, and the coal-fired power plant The exhaust pipe is long, and the flue gas is transported in the pipeline. There is moisture absorption and condensation phenomenon, which is particularly obvious in winter, so it is especially necessary for drying and dehumidifying the flue gas. The gas-liquid solid separator of the present invention can dehumidify and prevent plasma leakage.
為使 貴審查委員能更了解本發明之特徵及其功效,茲配合圖式並詳細說明於后。 In order to enable the reviewing committee to better understand the features of the present invention and its efficacy, it is described in detail with reference to the drawings.
(1)‧‧‧脫硫脫硝系統 (1)‧‧‧Desulfurization and denitration system
(10)‧‧‧氨氣源 (10) ‧ ‧ ammonia source
(11)‧‧‧燃燒器 (11)‧‧‧ Burners
(12)‧‧‧靜電除塵器 (12)‧‧‧Electrostatic precipitator
(13)‧‧‧換熱器 (13)‧‧‧ Heat exchanger
(14)‧‧‧噴淋器 (14)‧‧‧Sprinkler
(15)‧‧‧霧化噴嘴 (15)‧‧‧Atomizing nozzle
(16)‧‧‧紫外燈 (16)‧‧‧UV lamp
(17)‧‧‧循環泵 (17) ‧ ‧ Circulating pump
(18)‧‧‧自添液塔 (18)‧‧‧ Self-adding liquid tower
(19)‧‧‧分離塔 (19) ‧‧ ‧ separation tower
(110)‧‧‧煙囪 (110)‧‧‧ chimney
(111)‧‧‧進氣管 (111)‧‧‧Air intake pipe
(2)‧‧‧鍋爐 (2) ‧ ‧ boiler
(20)‧‧‧第二介質電漿 (20)‧‧‧Second medium plasma
(3)‧‧‧氣液固分離器 (3) ‧ ‧ gas-liquid-solid separator
(31)‧‧‧桶蓋 (31) ‧ ‧ barrel lid
(32)‧‧‧緊固螺釘 (32)‧‧‧ fastening screws
(33)‧‧‧燒結過濾器 (33)‧‧‧Sintering filter
(34)‧‧‧內過濾桶 (34) ‧ ‧ inner filter barrel
(35)‧‧‧殼體 (35) ‧‧‧Shell
(36)‧‧‧外過濾桶 (36) ‧‧‧External filter bucket
(37)‧‧‧第二壓力錶 (37) ‧‧‧Second pressure gauge
(38)‧‧‧排水閥 (38)‧‧‧Drain valve
(351)‧‧‧進氣口 (351)‧‧‧ Air intake
(352)‧‧‧排氣口 (352) ‧ ‧ vents
(4)‧‧‧第一氣固分離器 (4) ‧‧‧First gas-solid separator
(41)‧‧‧過濾芯子 (41) ‧‧‧Filter core
(42)‧‧‧固定杆 (42) ‧ ‧ fixed rod
(43)‧‧‧過濾腔 (43) ‧‧‧Filter chamber
(44)‧‧‧折疊層 (44)‧‧‧Folding layer
(45)‧‧‧煙灰暫存腔 (45) ‧ ‧ ash temporary storage chamber
(46)‧‧‧旋轉分隔板 (46)‧‧‧Rotating partition
(47)‧‧‧閘門開關 (47)‧‧‧gate switch
(48)‧‧‧輸料管道 (48)‧‧‧Transport pipeline
(49)‧‧‧煙灰輸運車 (49)‧‧‧ Ash truck
(410)‧‧‧第一進氣管道 (410) ‧‧‧First intake duct
(420)‧‧‧第一排氣管道 (420)‧‧‧First exhaust duct
(430)‧‧‧第二進氣管道 (430)‧‧‧Second intake duct
(440)‧‧‧第二排氣管道 (440) ‧‧‧Second exhaust duct
(450)‧‧‧分隔板 (450)‧‧‧ partition board
(460)‧‧‧漸擴部 (460) ‧ ‧ gradual expansion
(5)‧‧‧氣液分離器 (5) ‧‧‧ gas-liquid separator
(51)‧‧‧殼體蓋 (51)‧‧‧ housing cover
(52)‧‧‧內過濾桶 (52) ‧ ‧ inner filter barrel
(53)‧‧‧外過濾桶 (53) ‧‧‧External filter bucket
(54)‧‧‧導液管 (54)‧‧‧ catheter
(55)‧‧‧殼體 (55) ‧‧‧Shell
(56)‧‧‧集液過濾器 (56) ‧ ‧ sump filter
(57)‧‧‧排水閥 (57)‧‧‧Drain valve
(58)‧‧‧固定支腳 (58) ‧‧‧Fixed feet
(511)‧‧‧連杆 (511)‧‧‧ linkage
(520)‧‧‧環形固定架 (520) ‧ ‧ ring holder
(531)‧‧‧擋流板 (531)‧‧‧Baffles
(532)‧‧‧引流板 (532)‧‧‧ Drainage board
(551)‧‧‧進氣口 (551)‧‧‧ Air inlet
(552)‧‧‧排氣口 (552)‧‧‧Exhaust port
(560)‧‧‧碟形腔體 (560)‧‧‧ dish-shaped cavity
(570)‧‧‧蓄水罐 (570)‧‧‧Water tank
(6)‧‧‧納米電漿 (6) ‧‧‧ nano plasma
(60)‧‧‧第二恒溫控制系統 (60) ‧‧‧Second thermostat control system
(61)‧‧‧通風罩 (61) ‧ ‧ hood
(62)‧‧‧鼓風機 (62) ‧‧‧Blowers
(63)‧‧‧溫度控制箱 (63) ‧‧‧temperature control box
(611)‧‧‧轉接管 (611)‧‧‧Transfer tube
(612)‧‧‧漸擴管 (612) ‧ ‧ gradual expansion
(613)‧‧‧轉接頭 (613)‧‧‧Transfer
(614)‧‧‧上通氣環道 (614) ‧ ‧ upper ventilation loop
(615)‧‧‧中通氣環道 (615) ‧ ‧ venting loop
(616)‧‧‧下通氣環道 (616) ‧‧‧ ventilation loop
(661)‧‧‧外殼 (661)‧‧‧ Shell
(65)‧‧‧鼓風機 (65) ‧‧‧Blowers
(66)‧‧‧溫度控制箱 (66) ‧‧‧temperature control box
(662)‧‧‧溫度感測器 (662)‧‧‧Temperature Sensor
(663)‧‧‧電阻絲式加熱器 (663)‧‧‧Resistive wire heater
(7)‧‧‧第一介質電漿 (7) ‧‧‧First dielectric plasma
(70)‧‧‧恒溫控制系統 (70) ‧ ‧ Constant Temperature Control System
(8)‧‧‧反應罐 (8) ‧‧‧Reaction tank
(81)‧‧‧進氣管口 (81)‧‧‧ intake manifold
(82)‧‧‧排氣管口 (82)‧‧‧Exhaust nozzle
(83)‧‧‧第一反應腔 (83)‧‧‧First reaction chamber
(84)‧‧‧第二反應腔體 (84) ‧‧‧Second reaction chamber
(85)‧‧‧導流板 (85)‧‧‧Baffle
(86)‧‧‧圓形通孔 (86)‧‧‧Circular through holes
(87)‧‧‧排料閥 (87)‧‧‧Dumping valve
(88)‧‧‧顆粒暫存腔 (88) ‧ ‧ granule temporary storage chamber
(89)‧‧‧集料盒 (89)‧‧‧Collection box
(9)‧‧‧第二氣固分離器 (9) ‧‧‧Second gas-solid separator
(90)‧‧‧煙囪 (90) ‧ ‧ chimney
圖1為現有的脫硫脫硝系統的結構示意圖。 Figure 1 is a schematic view showing the structure of a conventional desulfurization and denitration system.
圖2為本發明較佳實施例的氣液固分離器的結構示意圖。 2 is a schematic structural view of a gas-liquid-solid separator according to a preferred embodiment of the present invention.
圖3為本發明較佳實施例的氣液分離器的結構示意圖。 3 is a schematic structural view of a gas-liquid separator according to a preferred embodiment of the present invention.
圖4為圖3的氣液分離器的濾芯的結構示意圖。 4 is a schematic structural view of a filter element of the gas-liquid separator of FIG. 3.
圖5為圖3的氣液分離器的內過濾桶的結構示意圖。 FIG. 5 is a schematic structural view of an inner filter barrel of the gas-liquid separator of FIG. 3. FIG.
圖6為圖3的氣液分離器的集液過濾和排水閥的結構示意圖。 Figure 6 is a schematic view showing the structure of the liquid collecting filter and the drain valve of the gas-liquid separator of Figure 3.
圖7為本發明較佳實施例的第一氣固分離器的結構示意圖。 Figure 7 is a schematic view showing the structure of a first gas-solid separator according to a preferred embodiment of the present invention.
圖8為本發明較佳實施例的反應罐的結構示意圖。 Figure 8 is a schematic view showing the structure of a reaction tank according to a preferred embodiment of the present invention.
圖9為本發明較佳實施例的電漿除硫脫硝設備的結構示意圖。 FIG. 9 is a schematic structural view of a plasma sulfur removal and denitration apparatus according to a preferred embodiment of the present invention.
圖10為圖9的電漿除硫脫硝設備的局部結構示意圖。 FIG. 10 is a partial structural schematic view of the plasma sulfur removal and denitration apparatus of FIG. 9. FIG.
圖11為圖10中的電漿除硫脫硝設備的通風罩和溫度控制箱的結構示意圖。 11 is a schematic structural view of a hood and a temperature control box of the plasma desulfurization and denitration apparatus of FIG.
圖12為圖11中的溫度控制箱的結構示意圖。 Figure 12 is a schematic view showing the structure of the temperature control box of Figure 11;
圖13為圖9的電漿除硫脫硝設備的脫硫脫硝效果圖。 Figure 13 is a graph showing the effect of desulfurization and denitration of the plasma desulfurization and denitration equipment of Figure 9.
下面舉個較佳實施例,並結合附圖來更清楚完整地說明本發明。 The invention will be described more clearly and fully hereinafter with reference to the accompanying drawings.
本實施例的氣液固分離器的結構如下: 請結合圖2予以理解,本實施例的氣液固分離器(3)包括一個桶蓋(31)、多個緊固螺釘(32)、一個圓筒狀的殼體(35),一個嵌置於該殼體(35)內的濾芯和一個排水閥(38),該殼體(35)的側面上設置有一個具有法蘭的進氣口(351)和一個具有法蘭的排氣口(352),該殼體(35)和該濾芯之間形成有旋流風道,該進氣口(351)的軸線和該排氣口(352)的軸線均偏離該殼體(35)的軸心,該進氣口(351)、該旋流風道和該排氣口(352)依次相互連通,該排水閥(38)設置於該殼體(35)的底部且與該旋流風道相互連通,該濾芯包括三個同軸嵌套的柱狀過濾桶,該些柱狀過濾桶從內至外依次為燒結過濾器(33)、內過濾桶(34)和外過濾桶(36),該內過濾桶(34)和該外過濾桶(36)上均陣列有多個過濾孔,該些過濾孔能夠在該內過濾桶(34)和該外過濾桶(36)相對旋轉時相互對正或錯開,以便改變過濾孔的有效面積,進而對不同中心粒徑的液滴精細篩選。 The structure of the gas-liquid-solid separator of this embodiment is as follows: 2, the gas-liquid-solid separator (3) of the present embodiment includes a bucket cover (31), a plurality of fastening screws (32), and a cylindrical casing (35), one embedded. a filter element in the housing (35) and a drain valve (38), the side of the housing (35) is provided with a flanged air inlet (351) and a flanged exhaust port ( 352), a swirling air duct is formed between the casing (35) and the filter element, and an axis of the air inlet (351) and an axis of the exhaust port (352) are both offset from an axis of the casing (35). The air inlet (351), the swirling air passage and the air outlet (352) are in communication with each other in sequence, and the drain valve (38) is disposed at a bottom of the housing (35) and communicates with the swirling air passage. The filter element comprises three coaxially nested column filter barrels, which are sintered filter (33), inner filter barrel (34) and outer filter barrel (36) from the inside to the outside, the inner filter A plurality of filter holes are arranged on the barrel (34) and the outer filter barrel (36), and the filter holes can be aligned or staggered when the inner filter barrel (34) and the outer filter barrel (36) rotate relative to each other. In order to change the effective area of the filter hole, Fine screening of droplets of different center particle diameter.
該進氣口(351)可以設置於該殼體(35)的下部,該排氣口(352)設置於該殼體(35)的上部,該進氣口(351)上設置有測試其內部流體壓力的第一壓力錶,該排氣口(352)上設置有測試其內部流體壓力的第二壓力錶(37),該內過濾桶(34)上設置有托板,該內過濾桶(34)通過該托板與該燒結過濾器(33)固定連接,以便於保持兩者相對靜止,進而相對地旋轉該內過濾桶(34)和該外過濾桶(36),以使得該內過濾桶(34)上的過濾孔和該外過濾桶(36)上的過濾孔相互對正或錯開。 The air inlet (351) may be disposed at a lower portion of the casing (35), the exhaust port (352) is disposed at an upper portion of the casing (35), and the air inlet (351) is provided with a test interior thereof a first pressure gauge of fluid pressure, the exhaust port (352) is provided with a second pressure gauge (37) for testing the internal fluid pressure thereof, and the inner filter bucket (34) is provided with a pallet, the inner filter bucket ( 34) being fixedly coupled to the sintered filter (33) by the pallet so as to keep the two relatively stationary, thereby relatively rotating the inner filter bucket (34) and the outer filter bucket (36) to cause the inner filter The filter holes on the tub (34) and the filter holes on the outer filter bucket (36) are aligned or offset from each other.
本實施例的氣液分離器的結構如下:請結合圖3予以理解,本實施例還提供一種氣液分離器(5),該氣液分離器(5)包括一個具有連杆(511)的殼體蓋(51)、 一個內過濾桶(52)、一個外過濾桶(53)、一個導液管(54)、一個圓筒狀的殼體(55)、一個碟形的集液過濾器(56)、一個排水閥(57)和三個固定支腳(58),該殼體(55)、該集液過濾器(56)、該導液管(54)和該排水閥(57)依次相互連通。 The structure of the gas-liquid separator of the present embodiment is as follows: Please understand with reference to FIG. 3, the embodiment further provides a gas-liquid separator (5) including a connecting rod (511). Housing cover (51), An inner filter barrel (52), an outer filter barrel (53), a liquid guiding tube (54), a cylindrical casing (55), a dish-shaped liquid collecting filter (56), and a drain valve (57) and three fixed legs (58), the housing (55), the liquid collection filter (56), the liquid guiding tube (54) and the drain valve (57) are in turn in communication with each other.
請結合圖3和圖4予以理解,該內過濾桶(52)和該外過濾桶(53)均為表面陣列有多個過濾孔的柱狀過濾桶,該內過濾桶(52)嵌套於該外過濾桶(53)內並且形成濾芯,該些過濾孔能夠在該內過濾桶(52)和該外過濾桶(53)相對旋轉時相互對正或錯開,以便改變過濾孔的有效面積,進而對不同中心粒徑的液滴精細篩選,採用可調孔隙式分離水氣結構,可以使相對濕度降低30%-60%以上,該外過濾桶(53)上設置有一個螺旋狀的引流板(532),該引流板(532)用於引導旋流風道內的氣體螺旋運動。 3 and FIG. 4, the inner filter barrel (52) and the outer filter barrel (53) are column filter barrels having a plurality of filter holes in a surface array, and the inner filter barrel (52) is nested in The outer filter barrel (53) is formed with a filter element, and the filter holes can be aligned or offset with each other when the inner filter barrel (52) and the outer filter barrel (53) are relatively rotated, so as to change the effective area of the filter hole. Furthermore, fine screening of droplets of different center particle sizes, using an adjustable pore separation water and gas structure, can reduce the relative humidity by 30%-60%, and the outer filter barrel (53) is provided with a spiral drain plate. (532), the drain plate (532) is for guiding the helical movement of the gas within the swirling air passage.
請結合圖3予以理解,該殼體(55)的側面上設置有一個具有法蘭的進氣口(551)和一個具有法蘭的排氣口(552),該進氣口(551)和該排氣口(552)均設置於該殼體(55)的上部,該殼體(55)和該濾芯之間形成有旋流風道,該進氣口(551)的軸線和該排氣口(552)的軸線均偏離該殼體(55)的軸心,該進氣口(551)、該旋流風道和該排氣口(552)依次相互連通。 As understood with reference to Figure 3, the side of the housing (55) is provided with a flanged air inlet (551) and a flanged exhaust port (552), the air inlet (551) and The exhaust port (552) is disposed at an upper portion of the casing (55), and a swirling air passage is formed between the casing (55) and the filter element, an axis of the air inlet (551) and the exhaust port The axes of (552) are all offset from the axis of the housing (55), and the intake port (551), the swirling air passage, and the exhaust port (552) are in communication with each other in sequence.
該外過濾桶(53)的上部設置有擋流板(531),該擋流板(531)用於將從該進氣口(551)流入的氣體阻擋向該引流板(532),以便使得該引流板(532)引導該氣體螺旋撞向該濾芯的底部。 An upper portion of the outer filter bucket (53) is provided with a baffle (531) for blocking gas flowing in from the air inlet (551) toward the drain plate (532) so as to The drain plate (532) directs the gas spiral into the bottom of the filter element.
請結合圖5予以理解,該內過濾桶(52)內設置有多個環形固定架(520)和多個旋流器(圖中未示出),該些旋流器通過該些環 形固定架(520)固定於該內過濾桶內,該些旋流器的旋轉方向與該引流板(532)的引流方向相同。 As understood from FIG. 5, the inner filter barrel (52) is provided with a plurality of annular fixing frames (520) and a plurality of swirlers (not shown) through which the cyclones pass. The fixing brackets (520) are fixed in the inner filter barrel, and the swirling directions of the swirlers are the same as the drainage direction of the draining plate (532).
請結合圖6予以理解,該集液過濾器(56)上陣列有多個集液過濾孔,該集液過濾器(56)的碟形腔體(560)用於收集煙灰顆粒,該排水閥(57)的蓄水罐(570)能夠儲存過濾後的廢水。 As understood with reference to Figure 6, the liquid collection filter (56) has a plurality of liquid collection filter holes in the array, and the dish-shaped cavity (560) of the liquid collection filter (56) is used to collect soot particles, the drainage valve The water storage tank (570) of (57) is capable of storing the filtered wastewater.
本實施例的第一氣固分離器的結構如下:請結合圖7予以理解,本實施例還提供一種第一氣固分離器(4),該第一氣固分離器(4)包括第一進氣管道(410)、第二進氣管道(430)、第一排氣管道(420)、第二排氣管道(440)、一個過濾芯子(41)和一個過濾腔(43),該過濾芯子(41)設置於該過濾腔(43)內,該第一進氣管道(410)用於通過該過濾芯子(41)將流體通向該第一排氣管道(420),該第二進氣管道(430)用於通過該過濾芯子(41)將流體通向該第二排氣管道(440),該第一進氣管道(410)和該第二進氣管道(430)相對設置且能夠保持流體的流動方向相對。 The structure of the first gas-solid separator of the present embodiment is as follows: Please understand with reference to FIG. 7 , the embodiment further provides a first gas-solid separator (4), the first gas-solid separator (4) includes the first An intake duct (410), a second intake duct (430), a first exhaust duct (420), a second exhaust duct (440), a filter core (41), and a filter chamber (43), a filter cartridge (41) is disposed in the filter chamber (43) for passing fluid to the first exhaust conduit (420) through the filter cartridge (41), a second intake duct (430) for passing fluid through the filter core (41) to the second exhaust duct (440), the first intake duct (410) and the second intake duct (430) Relatively arranged and capable of keeping the flow direction of the fluid opposite.
該過濾芯子(41)為折疊狀,該過濾腔(43)內設置有多個固定杆(42),該些固定杆(42)支撐於該過濾芯子(41)的折疊拐角處,以分隔相鄰兩個折疊層(44),製作時,相鄰兩個折疊層(44)之間最好形成5°至15°的夾角。 The filter core (41) is folded, and a plurality of fixing rods (42) are disposed in the filter chamber (43), and the fixing rods (42) are supported at the folded corners of the filter core (41) to The two adjacent folded layers (44) are separated, and an angle of between 5 and 15 is preferably formed between adjacent two folded layers (44).
該第一進氣管道(410)、該第二進氣管道(430)、該第一排氣管道(420)和該第二排氣管道(440)均通過一個漸擴部(460)與該過濾腔(43)相互連通,漸擴部(460)的外輪廓可以為圓臺狀或喇叭狀,該第一進氣管道(410)的漸擴部(460)和該第二進氣管道(430)的漸擴部(460)用於均布流體和緩解流速, 該第一排氣管道(420)的漸擴部(460)和該第二排氣管道(440)的漸擴部(460)用於彙集過濾後的流體。 The first intake duct (410), the second intake duct (430), the first exhaust duct (420) and the second exhaust duct (440) each pass through a diverging portion (460) and the The filter chambers (43) are in communication with each other, and the outer contour of the diverging portion (460) may be a truncated cone or a trumpet shape, the diverging portion (460) of the first intake duct (410) and the second intake duct ( The diverging portion (460) of 430) is used to evenly distribute fluid and relieve flow rate, The diverging portion (460) of the first exhaust conduit (420) and the diverging portion (460) of the second exhaust conduit (440) are used to collect the filtered fluid.
該第一氣固分離器(4)還包括一個具有旋轉分隔板(46)和閘門開關(47)的煙灰暫存腔(45),該煙灰暫存腔(45)和該過濾腔(43)之間設置有分隔板(450),該分隔板(450)與該第一氣固分離器(4)的內壁面之間設置有夾縫,該煙灰暫存腔(45)和該過濾腔(43)通過該夾縫相互連通,該閘門開關(47)用於控制該旋轉分隔板(46)轉動以便釋放該煙灰暫存腔(45)內的煙灰顆粒。 The first gas-solid separator (4) further includes a soot temporary storage chamber (45) having a rotating partition plate (46) and a gate switch (47), the soot temporary storage chamber (45) and the filter chamber (43) Between the partition plate (450), a gap between the partition plate (450) and the inner wall surface of the first gas-solid separator (4) is provided, the soot temporary storage chamber (45) and the filter The chambers (43) are in communication with each other through the nip, and the gate switch (47) is for controlling the rotation of the rotating partition plate (46) to release the soot particles in the soot temporary storage chamber (45).
該第一氣固分離器(4)還包括一個煙灰輸運車(49),該煙灰輸運車(49)包括一個箱體和設置於該箱體端部的輪子,該煙灰暫存腔(45)通過一個輸料管道(48)與該箱體相互連通,以便將煙灰顆粒輸送至該煙灰輸運車(49),避免了直接向塑膠袋灌裝煙灰過程中引起煙灰飛揚,對清潔人員眼睛造成損傷以及對外界環境造成污染,收集的煙灰顆粒可以作為化工原料應用(例如,製作黑色鞋油或橡膠輪胎)。 The first gas-solid separator (4) further includes a soot transport truck (49) including a tank body and wheels disposed at the end of the tank body, the soot temporary storage chamber ( 45) communicating with the tank through a conveying pipe (48) to transport the soot particles to the soot conveying vehicle (49), thereby avoiding the soot flying during the process of directly filling the plastic bag with the soot, to the cleaning personnel Eye damage and contamination of the external environment, the collected soot particles can be used as a chemical raw material (for example, making black shoe polish or rubber tires).
另外,該第一氣固分離器(4)上設置有具有換熱器(13)的第一控溫設備,該換熱器(13)為表面式換熱器或直接接觸式換熱器,以便降低煙道廢氣的溫度。 In addition, the first gas-solid separator (4) is provided with a first temperature control device having a heat exchanger (13), and the heat exchanger (13) is a surface heat exchanger or a direct contact heat exchanger. In order to reduce the temperature of the flue gas.
本實施例的反應罐的結構如下:請結合圖8予以理解,本實施例還提供一種反應罐(8),該反應罐(8)包括依次相互連通的進氣管口(81)、第一反應腔(83)、顆粒暫存腔(88)和第二反應腔體(84)和排氣管口(82),具體上可以在第一反應腔(83)和第二反應腔體(84)的下分隔板上開設圓形通孔(86),該第一反應腔(83)和該第二反應腔體(84)內均設置有多個導流板(85),該些導流板(85)用於阻擋流體和改變流向, 使得流體均勻混合,該反應罐(8)上還設置有與該顆粒暫存腔(88)相互連通的排料閥(87),該反應罐(8)還包括一個集料盒(89),該集料盒(89)用於收集該排料閥(87)排出的化肥顆粒。 The structure of the reaction tank of this embodiment is as follows: Please understand with reference to Fig. 8, this embodiment further provides a reaction tank (8) including an intake nozzle (81) which is in communication with each other in sequence, first The reaction chamber (83), the particle temporary chamber (88) and the second reaction chamber (84) and the exhaust nozzle (82), specifically in the first reaction chamber (83) and the second reaction chamber (84) a circular through hole (86) is formed in the lower partition plate, and a plurality of baffles (85) are disposed in the first reaction chamber (83) and the second reaction chamber (84), and the guides are provided The flow plate (85) is used to block fluids and change the flow direction, The fluid is uniformly mixed, and the reaction tank (8) is further provided with a discharge valve (87) communicating with the particle temporary storage chamber (88), the reaction tank (8) further comprising a collecting box (89). The collection box (89) is used to collect fertilizer particles discharged from the discharge valve (87).
該第一反應腔(83)、該顆粒暫存腔(88)和該第二反應腔體(84)的內壁面均塗覆有聚氨基甲酸酯(簡稱聚氨酯,polyurethane)塗層或聚四氟乙烯(polytetrafluoroethylene,PTFE)塗層,研發人員發現反應腔的內壁面塗覆聚氨酯或聚四氟乙烯後,合成的化肥顆粒不會與反應腔的內壁面吸附或粘連,並且容易結晶形成0.2-5毫米粒徑的化肥顆粒,大顆粒的化肥顆粒會自動掉落到顆粒暫存腔(88),方便收集,較小顆粒硫酸銨與硝酸銨可以使用第二氣固分離器(9)予以分離收集。 The first reaction chamber (83), the particle temporary storage chamber (88) and the inner wall surface of the second reaction chamber (84) are coated with a polyurethane coating (polyurethane) or polytetra Polytetrafluoroethylene (PTFE) coating, the researchers found that after the inner wall of the reaction chamber is coated with polyurethane or polytetrafluoroethylene, the synthetic fertilizer particles will not adsorb or adhere to the inner wall surface of the reaction chamber, and will easily crystallize to form 0.2- 5mm particle size fertilizer particles, large particles of fertilizer particles will automatically fall into the particle temporary storage cavity (88) for easy collection, smaller particles of ammonium sulfate and ammonium nitrate can be separated using a second gas-solid separator (9) collect.
本實施例的電漿除硫脫硝設備的結構如下:請結合圖9予以理解,本實施例的電漿除硫脫硝設備包括一個供氨系統、如上所述的氣液固分離器(3)、如上所述的第一氣固分離器(4)、如上所述的氣液分離器(5)以及如上所述的反應罐(8),該電漿除硫脫硝設備還包括一個納米電漿(6)、一個第一介質電漿(7)、一個第二氣固分離器(9)和一個煙囪(90),該氣液固分離器(3)、該第一氣固分離器(4)、該氣液分離器(5),該納米電漿(6)、該第一介質電漿(7)、該反應罐(8)、該第二氣固分離器(9)和該煙囪(90)依次相互連通,該供氨系統與該反應罐(8)相互連通,以便向該反應罐(8)內通入氨氣,圖9僅示意性地給出了燃煤電廠鍋爐(2),實際上的鍋爐(2)體積較為龐大,圖10給出了第一氣固分離器(4)與氣液固分離器(3)和氣液分離器(5)的管道連接結構。 The structure of the plasma sulfur removal and denitration device of the present embodiment is as follows: Please understand that the plasma sulfur removal and denitration device of the present embodiment includes an ammonia supply system, a gas-liquid-solid separator as described above (3). a first gas-solid separator (4) as described above, a gas-liquid separator (5) as described above, and a reaction tank (8) as described above, the plasma sulfur removal and denitration device further comprising a nanometer a plasma (6), a first dielectric plasma (7), a second gas-solid separator (9) and a chimney (90), the gas-liquid-solid separator (3), the first gas-solid separator (4) the gas-liquid separator (5), the nano-plasma (6), the first dielectric plasma (7), the reaction tank (8), the second gas-solid separator (9), and the The chimneys (90) are in communication with each other in sequence, and the ammonia supply system and the reaction tank (8) are in communication with each other to introduce ammonia into the reaction tank (8), and FIG. 9 only schematically shows a coal-fired power plant boiler ( 2) The actual boiler (2) is relatively bulky. Figure 10 shows the pipe connection structure of the first gas-solid separator (4) and the gas-liquid-solid separator (3) and the gas-liquid separator (5).
請再次結合圖9予以理解,具體上,該供氨系統包括一個氨氣源(10)和第二介質電漿(20),該氨氣源(10)可以為氨氣瓶或 合成氨氣的裝置,該第二介質電漿(20)用於使得氨氣分子吸附電荷,並且將吸附有電荷的氨氣分子供應至該反應罐(8)內。 Please understand again in conjunction with FIG. 9. Specifically, the ammonia supply system includes an ammonia gas source (10) and a second dielectric plasma (20), and the ammonia gas source (10) may be an ammonia gas cylinder or A device for synthesizing ammonia gas, the second dielectric plasma (20) is for causing an ammonia gas molecule to adsorb a charge, and supplying an adsorbed ammonia gas molecule into the reaction tank (8).
該納米電漿(6)的兩側均設置有恒溫控制系統(70)並且形成夾持該納米電漿(6)的結構,該第一介質電漿(7)的兩側均設置有恒溫控制系統(70)並且形成夾持該第一介質電漿(7)的結構,夾層結構在龐大的電漿系統中的採用,使得升溫速度加快並且控溫更加精確,便於將反應溫度維持在65℃至70℃範圍內,提高了電離效率。 The nano plasma (6) is provided with a constant temperature control system (70) on both sides thereof and forms a structure for holding the nano plasma (6), and the first dielectric plasma (7) is provided with constant temperature control on both sides thereof. System (70) and forming a structure for holding the first dielectric plasma (7), the use of a sandwich structure in a bulky plasma system, such that the heating rate is increased and the temperature control is more precise, and the reaction temperature is maintained at 65 ° C. The ionization efficiency is improved up to 70 °C.
上述四個恒溫控制系統(70)結構相同,故僅以第二恒溫控制系統(60)為例講解,請結合圖11予以理解,實際製作時,第二恒溫控制系統(60)包括一個通風罩(61)、一個鼓風機(62)和一個溫度控制箱(63)。 The above four constant temperature control systems (70) have the same structure, so only the second constant temperature control system (60) is taken as an example. Please understand with reference to FIG. 11. In actual production, the second constant temperature control system (60) includes a ventilation cover. (61), a blower (62) and a temperature control box (63).
該通風罩(61)由一個轉接管(611)、一個漸擴管(612)和一個矩形的轉接頭(613)組成,該轉接頭(613)均包括一個環形的通氣隙,通氣隙包括依次相互連通的一個上通氣環道(614)、一個中通氣環道(615)和一個下通氣環道(616),該通氣隙用於循環加熱氣體。該下通氣環道(616)的進氣口、該鼓風機(62)、該溫度控制箱(63)和該上通氣環道(614)的排氣口依次相互連通。 The venting cover (61) is composed of an adapter tube (611), a diverging tube (612) and a rectangular adapter (613). The adapter (613) includes an annular ventilation gap for ventilation. The gap includes an upper venting loop (614), a middle venting loop (615), and a lower venting loop (616) that are in communication with each other, the venting gap being used to circulate the heated gas. The intake port of the lower venting ring (616), the blower (62), the temperature control box (63), and the exhaust port of the upper venting ring (614) are in turn in communication with each other.
請結合圖12予以理解,該溫度控制箱(66)包括有一個具有保溫層的外殼(661),該外殼(661)內設置有一個電阻絲式加熱器(663),該保溫層內設置有溫度感測器(662),該鼓風機(65)用於向該外殼(661)的內腔體抽送氣體。 As will be understood from FIG. 12, the temperature control box (66) includes a housing (661) having an insulating layer, and a resistor wire heater (663) is disposed in the housing (661), and the insulating layer is provided with A temperature sensor (662) for pumping gas into the inner cavity of the outer casing (661).
本實施例的氣液固分離器和電漿除硫脫硝設備的工作原理如下:請結合圖9予以理解,使用時,鍋爐(2)廢氣依次流經該 氣液固分離器(3)、該第一氣固分離器(4)、該氣液分離器(5),該納米電漿(6)、該第一介質電漿(7)、該反應罐(8)、該第二氣固分離器(9)和該煙囪(90)而排放至外界環境。 The working principle of the gas-liquid-solid separator and the plasma desulfurization and denitration device of the present embodiment is as follows: Please understand that, in use, the boiler (2) exhaust gas flows through the system in sequence. a gas-liquid-solid separator (3), the first gas-solid separator (4), the gas-liquid separator (5), the nano-plasma (6), the first dielectric slurry (7), the reaction tank (8) The second gas-solid separator (9) and the chimney (90) are discharged to the external environment.
在該氣液固分離器(3)內,對鍋爐(2)廢氣中的水分和煙灰顆粒進行初次過濾,表1給出了氣液固分離器(3)對不同粒徑顆粒的捕獲效率。 In the gas-liquid-solid separator (3), the moisture and soot particles in the exhaust gas of the boiler (2) are initially filtered. Table 1 shows the gas-liquid-solid separator (3) for the capture efficiency of particles of different particle sizes.
由上表1的數據可知:該氣液固分離器(3)對粒徑為10微米以上的灰塵顆粒靜電除塵效果明顯。 It can be seen from the data in Table 1 that the gas-liquid-solid separator (3) has an electrostatic precipitating effect on dust particles having a particle diameter of 10 μm or more.
在該第一氣固分離器(4)內,對鍋爐(2)廢氣中的水分和煙灰顆粒進行再次過濾,該第一氣固分離器(4)(亦稱為不銹鋼網過濾器)採用2.5微米的不銹鋼過濾網作為濾芯,取得了較高的分離效果,不銹鋼網過濾器經設計可以每天反覆沖洗,不怕熱,每半年保養一次,節能省電,徹底解決PM2.5不達標問題,表2給出了第一氣固分離器(4)對不同粒徑顆粒的捕獲效率。 In the first gas-solid separator (4), the moisture and soot particles in the exhaust gas of the boiler (2) are filtered again, and the first gas-solid separator (4) (also referred to as a stainless steel mesh filter) adopts 2.5. The micron stainless steel filter is used as the filter element to achieve high separation effect. The stainless steel mesh filter is designed to be washed repeatedly every day, not afraid of heat, once every six months, saving energy and completely solving the problem of PM2.5 failure to meet the standard. Table 2 The capture efficiency of the first gas-solid separator (4) for particles of different particle sizes is given.
由上表2的數據可知:該第一氣固分離器(4)對粒徑為2.5微米以上的灰塵顆粒靜電除塵效果明顯。 It can be seen from the data in the above Table 2 that the first gas-solid separator (4) has an effect of electrostatically removing dust particles having a particle diameter of 2.5 μm or more.
工業實施結果表明,依據該氣液固分離器(3)和該第一氣固分離器(4)對不同粒徑灰塵顆粒的處理優勢,通過級聯該氣液固分離器(3)和該第一氣固分離器(4),粒徑大於10um的顆粒分離率幾乎達到100%,粒徑大於2.5um的顆粒分離率達到80%以上,雙重過濾處理方式能夠將煙灰顆粒的含量控制在PM2.5的排放標準(低於0.075毫克/立方米)範圍內。 Industrial implementation results show that, according to the gas liquid-solid separator (3) and the first gas-solid separator (4), the treatment advantages of different particle size dust particles are achieved by cascading the gas-liquid-solid separator (3) and the The first gas-solid separator (4), the particle separation rate of particle size greater than 10um is almost 100%, the particle separation rate of particle size greater than 2.5um is more than 80%, and the double filtration treatment method can control the content of soot particles in PM2. .5 emission standards (less than 0.075 mg / cubic meter).
因此,經過氣液固分離器(3)和第一氣固分離器(4)雙重除塵處理後的廢氣體,在粉塵含量方面,完全能夠滿足蘇州旺德科技有限公司生產的納米電漿(6)和第一介質電漿(7)對相對濕度(RH)不能高於65%的要求,因此不會對電漿造成損壞。 Therefore, the exhaust gas body after the double dust removal treatment by the gas-liquid-solid separator (3) and the first gas-solid separator (4) can completely satisfy the nano-plasma produced by Suzhou Wangde Technology Co., Ltd. in terms of dust content (6) And the first dielectric plasma (7) does not require a relative humidity (RH) higher than 65%, so there is no damage to the plasma.
另外,該第一氣固分離器(4)中換熱器(13)還能夠將鍋爐(2)廢氣(100℃至200℃)降溫至45℃至80℃,以避免氣體溫度過 高會對該納米電漿(6)和該第一介質電漿(7)造成損傷,以及影響除硫脫硝的效率(除硫、脫硝熱化學反應對溫度要求嚴格)。 In addition, the heat exchanger (13) in the first gas-solid separator (4) can also cool the boiler (2) exhaust gas (100 ° C to 200 ° C) to 45 ° C to 80 ° C to avoid gas temperature over The high-level damage to the nano-plasma (6) and the first dielectric plasma (7), as well as the efficiency of desulfurization and denitrification (the sulfur removal, denitrification thermochemical reaction is temperature-critical).
在該氣液分離器(5)內,請同時結合圖3予以理解,含有水汽的鍋爐(2)廢氣依次通過該進氣口(551)、該旋流風道後、該內過濾桶(52)的腔體後,由該排氣口(552)排出,由於該進氣口(551)的軸線偏離該殼體(55)的軸心,因此鍋爐(2)廢氣會在該旋流風道內形成渦流,水汽凝結成水珠並在離心力的作用下甩向該殼體(55)的內壁面,在打開排水閥(57)後可以將積水放掉,乾燥的鍋爐(2)廢氣透過該濾芯,並經該排氣口(552)排出。 In the gas-liquid separator (5), it should be understood in conjunction with FIG. 3 that the boiler (2) containing water vapor sequentially passes through the intake port (551), the swirling air passage, and the inner filter barrel (52). After the cavity is discharged from the exhaust port (552), since the axis of the air inlet (551) deviates from the axis of the casing (55), the exhaust gas of the boiler (2) forms a vortex in the swirling air passage. The water vapor condenses into water droplets and slams into the inner wall surface of the casing (55) under the action of centrifugal force. After opening the drain valve (57), the water can be drained, and the dry boiler (2) exhaust gas passes through the filter element, and Discharged through the exhaust port (552).
該擋流板(531)起到反射流體的作用,將從該進氣口流入的氣體阻擋向該引流板(532),以便使得該引流板(532)引導該氣體螺旋運動並撞向該濾芯的底部。雖然進氣口(551)和排氣口(552)均設置於該殼體(55)的上部,然而經過擋流板(531)和引流板(532)的協同作用後,鍋爐(2)廢氣能夠在濾芯的軸向上得到均布,因此濾芯的過濾功能得以有效地使用。 The baffle (531) functions as a reflective fluid, and the gas flowing from the air inlet is blocked toward the drainage plate (532), so that the drainage plate (532) guides the gas spiral motion and collides with the filter element. bottom of. Although the intake port (551) and the exhaust port (552) are both disposed at the upper portion of the casing (55), after the synergy of the baffle (531) and the deflector (532), the boiler (2) exhaust gas It is possible to obtain a uniform distribution in the axial direction of the filter element, so that the filter function of the filter element can be effectively used.
使用引流板(532)螺旋導流的另一個好處是,氣流不僅受到徑向的離心力,而且還受到軸向的引導力,使得水汽快速凝結成水珠並斜向下均勻地甩向殼體(55)的內壁面,避免了僅僅甩向殼體(55)的內壁面的上部,而導致受衝擊力不均的問題(噪音過大)。 Another benefit of using the deflector (532) to spiral the flow is that the airflow is not only subjected to radial centrifugal forces, but also to the axial guiding force, so that the water vapor quickly condenses into water droplets and slantes downwardly and evenly toward the casing ( The inner wall surface of 55) avoids the problem of only the upper portion of the inner wall surface of the casing (55), resulting in uneven impact force (too much noise).
依據熱電廠燃煤狀況的不同,可以相對地旋轉該內過濾桶(52)和該外過濾桶(53),以便改變過濾孔的有效面積,進而對不同中心粒徑的液滴精細篩選,實驗發現,在熱電廠使用褐煤時,可以將濾孔的有效半徑設置在10微米至15微米,在旋流速度大於25米/秒的條件下,可以去除廢氣中85%以上的水分,旋流速度的提升可以使用該內過濾桶(52) 內的旋流器,並且要確保該些旋流器的旋轉方向與該引流板(532)的引流方向相同。 According to the coal-fired condition of the thermal power plant, the inner filter barrel (52) and the outer filter barrel (53) can be relatively rotated to change the effective area of the filter hole, thereby finely screening the droplets of different center particle diameters, and experimentally found that When using lignite in a thermal power plant, the effective radius of the filter hole can be set at 10 micrometers to 15 micrometers, and at a swirling speed of more than 25 meters per second, more than 85% of the moisture in the exhaust gas can be removed, and the swirling speed is improved. This inner filter bucket can be used (52) The internal swirlers are to ensure that the swirlers rotate in the same direction as the drain (532).
請結合圖6予以理解,碟形的集液過濾器(56)上陣列的集液過濾孔能夠彙集積液,並將煙灰顆粒收集於碟形腔體(560)內,避免了直接將鍋爐(2)積液排放至外界環境引發水質污染,由排水閥(57)排放的達標的積水。 As can be understood from Fig. 6, the liquid collecting filter holes of the array on the dish-shaped liquid collecting filter (56) can collect the liquid and collect the soot particles in the dish (560), thereby avoiding direct boiler ( 2) The effluent discharged to the external environment causes water pollution, and the water discharged by the drain valve (57) reaches the standard.
請結合圖11予以理解,在該通風罩(61)內,混合氣體通過轉接管(611)甩向漸擴管(612),以便實現氣體均布,該些通氣隙用於循環加熱氣體,通過下通氣環道(616)、中通氣環道(615)和上通氣環道(614)的依次加熱,可以將混合氣體的溫度維持在65℃至70℃。該鼓風機(62)用於給加熱氣體提供循環動力,以便於維持加熱氣體的旋轉,該電阻絲式加熱器(663)用於電加熱循環氣體,以便將加熱氣體的溫度維持在70℃。本實施例給出了電阻絲式加熱器(663),實際生產時,還可以採用氣體換熱器或水加熱器。 As will be understood in conjunction with FIG. 11, in the hood (61), the mixed gas is slid into the diverging tube (612) through the transfer tube (611) to achieve gas uniformity, and the venting grooves are used to circulate the heated gas. The temperature of the mixed gas can be maintained at 65 ° C to 70 ° C by sequential heating of the lower venting loop (616), the intermediate venting loop (615), and the upper venting loop (614). The blower (62) is for providing a circulating power to the heating gas to maintain the rotation of the heating gas, and the resistance wire heater (663) is for electrically heating the circulating gas to maintain the temperature of the heating gas at 70 °C. In this embodiment, a resistance wire heater (663) is provided, and in actual production, a gas heat exchanger or a water heater can also be used.
請結合圖9予以理解,在該納米電漿(6)和該第一介質電漿(7)內,脫硫和脫硝過程的主要化學反應為: Please understand with reference to Figure 9, in the nano-plasma (6) and the first dielectric plasma (7), the main chemical reactions of the desulfurization and denitration processes are:
H2O+e → H++OH- H 2 O+e → H + +OH -
O2+e → 2O- O 2 +e → 2O -
O2+O- → O3 O 2 +O - → O 3
O+H2O → OH-+OH- O+H 2 O → OH - +OH -
H+O2 → HO2 3- H+O 2 → HO 2 3-
經過納米電漿(6)和第一介質電漿(7)的高壓放電反應,產生大量的的O-、O3、OH-、HO2 3-自由基。 After nano plasma (6) and a first plasma medium (7) of the high pressure discharge reaction, a large amount of O -, O 3, OH - , HO 2 3- radical.
SO2+O- → SO3 SO 2 +O - → SO 3
SO3+H2O → H2SO4 SO 3 +H 2 O → H 2 SO 4
SO2+OH- → HSO3 - SO 2 +OH - → HSO 3 -
HSO3 -+OH- → H2SO4 HSO 3 - +OH - → H 2 SO 4
同理,還會產生硝酸,請結合圖9予以理解,該氨氣源(10)和該第二介質電漿(20)能夠將吸附有電荷的氨氣分子供應至該反應罐(8)內,該氨氣源(10)的排氣管道上設置有流量閥,能夠調節氨氣的注入流量接近化學反應的計量,在該反應罐(8)內發生以下化學反應: Similarly, nitric acid is also produced. As understood with reference to Figure 9, the ammonia gas source (10) and the second dielectric plasma (20) are capable of supplying the adsorbed ammonia molecules to the reaction tank (8). The ammonia gas source (10) is provided with a flow valve on the exhaust pipe, which can adjust the injection flow rate of the ammonia gas to be close to the measurement of the chemical reaction, and the following chemical reaction occurs in the reaction tank (8):
H2SO4+2NH3 → (NH4)2SO4 H 2 SO 4 +2NH 3 → (NH 4 ) 2 SO 4
HNO3+NH3 → NH4NO3 HNO 3 +NH 3 → NH 4 NO 3
為了測試NOX的濃度、SO2的濃度、鍋爐(2)廢氣流量、電漿電壓對NOX脫除率、SO2脫除率和能耗的影響,因此進行了除硫脫硝實驗:實驗時控制鍋爐(2)廢氣流量為40L/H,改變納米電漿(6)和第一介質電漿(7)的總功率(電壓控制在36KV),實驗結果如圖13所示,通過實驗可知,NOX和SO2的脫除率和能耗並非為線性關係,在煤化工企業內,電功率控制在50W就可以去除90%以上的NOX和SO2,此時平均能耗僅為1.25W/L,另外還可以將電漿電壓調高至100KV至150KV以便獲得更好的脫硫脫硝效果。 To test the concentration of NO X concentration of SO 2, the boiler (2) exhaust gas flow rate, impact, plasma voltage of NO X removal rate, SO 2 removal rate and the energy consumption, the sulfur removal thus performed denitrification experiments: Experiment When controlling the boiler (2), the exhaust gas flow rate is 40L/H, and the total power of the nano-plasma (6) and the first dielectric plasma (7) is changed (the voltage is controlled at 36KV). The experimental results are shown in Fig. 13, and it is known through experiments. , NO X and SO 2 removal rate and energy consumption is not a linear relationship, in the coal chemical industry, the electric power control 50W can be removed more than 90% of the NO X and SO 2, this time the average power consumption is only 1.25W /L, in addition, the plasma voltage can be adjusted to 100KV to 150KV for better desulfurization and denitration.
本實施例的氣液固分離器和電漿除硫脫硝設備具有以下技術效果: The gas-liquid-solid separator and the plasma desulfurization and denitration device of the present embodiment have the following technical effects:
第一、本發明的氣液固分離器(3)能夠依據燃煤狀況篩選不同中心粒徑的煙灰顆粒,具體上,依據熱電廠燃煤狀況的不同,可以相對地旋轉該內過濾桶(34)和該外過濾桶(36),以便改變過濾孔的有 效面積,進而對不同中心粒徑的液滴精細篩選。 First, the gas-liquid-solid separator (3) of the present invention can screen the soot particles of different center particle sizes according to the coal-burning condition. Specifically, the inner filter barrel can be relatively rotated according to the coal-fired condition of the thermal power plant (34). And the outer filter barrel (36) to change the filter hole Effective area, and then fine screening of droplets of different center particle sizes.
第二、旋流風道利用原有流體的動能,旋轉離心水分,旋流風速可以通過第一壓力錶和第二壓力錶(37)測量,由於該進氣口設置於該殼體(35)的下部,該排氣口設置於該殼體(35)的上部,在旋流的過程中,水珠和煙道廢氣在該外過濾桶(36)的中部分離,水珠在重力和離心力的作用下斜向下甩向該殼體(35)的內壁面,並沿著該殼體(35)的內壁面彙聚到該殼體(35)的底部,煙道廢氣旋流上升並且依次透過該外過濾桶(36)、該內過濾桶(34)和該燒結過濾器(33),該外過濾桶(36)和該內過濾桶(34)形成的過濾孔,能夠對液滴精細篩選,該燒結過濾器(33)能夠吸附煙道廢氣中的煙灰顆粒,實現對煙灰顆粒的粗過濾。 Second, the swirling air passage utilizes the kinetic energy of the original fluid to rotate the centrifugal water, and the swirling wind speed can be measured by the first pressure gauge and the second pressure gauge (37), since the air inlet is disposed in the casing (35) In the lower part, the exhaust port is disposed at an upper portion of the casing (35). During the swirling process, the water droplets and the flue gas are separated in the middle of the outer filter tank (36), and the water droplets are subjected to gravity and centrifugal force. Sliding downwardly downward toward the inner wall surface of the casing (35), and converges along the inner wall surface of the casing (35) to the bottom of the casing (35), the flue gas exhaust gas swirls upwardly and sequentially passes through the outer a filter barrel (36), the inner filter barrel (34) and the sintered filter (33), the filter barrel formed by the outer filter barrel (36) and the inner filter barrel (34), capable of finely screening the droplets, The sintered filter (33) is capable of adsorbing soot particles in the flue gas to achieve coarse filtration of the soot particles.
第三、能夠正反輪換過濾煙灰顆粒,請結合圖7予以理解,在第一時間,打開該第一進氣管道(410)和該第一排氣管道(420)上的閥門,關閉該第二進氣管道(430)和該第二排氣管道(440)上的閥門,使得煙道廢氣沿著第一方向吹向該過濾芯子(41),在第二時間,關閉該第一進氣管道(410)和該第一排氣管道(420)上的閥門,打開該第二進氣管道(430)和該第二排氣管道(440)上的閥門,使得煙道廢氣沿著第二方向吹向該過濾芯子(41),正反輪換過濾煙灰顆粒的優點在於,沿著第一方向吹向並且嵌入該過濾芯子(41)的折疊拐角處的煙灰顆粒,在第二方向的風力作用下,被吹出且重新過濾,經過正反方向交互輪回過濾,避免了煙灰顆粒嵌入折疊拐角形成結垢的問題。 Third, the positive and negative rotation of the filtered soot particles, as understood in conjunction with Figure 7, at the first time, open the first intake duct (410) and the valve on the first exhaust duct (420), close the first a valve on the two intake ducts (430) and the second exhaust duct (440), such that the flue gas is blown toward the filter core (41) in a first direction, and the first one is closed at a second time. a gas pipe (410) and a valve on the first exhaust pipe (420) open a valve on the second intake pipe (430) and the second exhaust pipe (440), so that the flue gas flows along the first Blowing the filter core (41) in both directions, the positive and negative rotation of the soot particles is advantageous in that the soot particles are blown in the first direction and embedded in the folded corners of the filter core (41) in the second direction Under the action of the wind, it is blown out and re-filtered, and alternately filtered in the forward and reverse directions to avoid the problem that the soot particles are embedded in the folded corners to form scale.
第四、過濾效果優異且能夠自動檢測,請繼續結合圖7予以理解,鑒於該過濾芯子(41)的相鄰兩個折疊層(44)的夾角為5°至15°,煙道廢氣能夠有效地吹向相鄰兩個折疊層(44)之間的夾縫,並且 具有垂直於折疊層(44)的分力,便於煙灰顆粒的分離,過濾後的煙灰顆粒落入煙灰暫存腔(45),由於煙灰暫存腔(45)分為兩個並列的煙灰暫存區域,在正反輪換過濾煙灰顆粒的工況下,兩個煙灰暫存區域的煤灰量基本保持相等,若存在煤灰量相差較大的情況,則可以判斷煤灰過濾通道出現故障。 Fourth, the filtering effect is excellent and can be automatically detected. Please continue to understand in conjunction with FIG. 7 , in view of the fact that the adjacent two folded layers (44) of the filter core (41) have an angle of 5° to 15°, the flue gas can Effectively blowing a nip between adjacent two folded layers (44), and The component has a component perpendicular to the folded layer (44) to facilitate separation of the soot particles, and the filtered soot particles fall into the soot temporary storage chamber (45), and the soot temporary storage chamber (45) is divided into two juxtaposed soots. In the area, under the condition of positive and negative rotation filtering soot particles, the amount of coal ash in the two soot temporary storage areas remains basically equal. If there is a large difference in the amount of coal ash, it can be judged that the coal ash filtration channel is faulty.
第五、混合均勻且合成反應充分,該些導流板(85)能夠阻擋流體和改變流向,使得流體均勻混合,另外還延長了氣體路徑,以便於合成反應充分進行,化肥顆粒合成後會沿著傾斜設置的導流板(85)滾落並掉入該顆粒暫存腔(88),在使用聚氨基甲酸酯塗層或聚四氟乙烯塗層後發現,化肥顆粒不會吸附或粘連於反應腔體和反應罐(8)的內壁面。 Fifth, the mixture is uniform and the synthesis reaction is sufficient. The baffles (85) can block the fluid and change the flow direction, so that the fluid is uniformly mixed, and the gas path is further extended, so that the synthesis reaction is fully performed, and the chemical fertilizer particles are synthesized. The inclined baffle plate (85) rolls off and falls into the particle temporary storage chamber (88). After using the polyurethane coating or the polytetrafluoroethylene coating, it is found that the fertilizer particles do not adsorb or stick. On the inner wall surface of the reaction chamber and the reaction tank (8).
第六、升溫速度快且控溫精確,該納米電漿(6)的兩側和該第一介質電漿(7)的兩側均設置有恒溫控制系統(70),恒溫控制系統(70)設置於兩側,納米電漿(6)和第一介質電漿(7)夾設于中間,形成夾層結構,升溫速度快且控溫精確,便於將反應溫度維持在65℃至70℃的範圍。 Sixth, the heating rate is fast and the temperature control is precise. The two sides of the nano plasma (6) and the two sides of the first dielectric plasma (7) are provided with a constant temperature control system (70), and the constant temperature control system (70) Set on both sides, the nano-plasma (6) and the first dielectric plasma (7) are sandwiched in the middle to form a sandwich structure, which has a fast heating rate and precise temperature control, and is convenient to maintain the reaction temperature in the range of 65 ° C to 70 ° C. .
第七、該電漿除硫脫硝設備不僅能源利用效率高而且除硫脫硝效率強,鑒於該納米電漿(6)電壓和該第一介質電漿(7)能夠產生10KV-200KV的高壓電,電漿內部的高壓電極能夠瞬間將油煙廢氣中的分子電離成游離狀態的離子,因而能源利用效率高而且除硫脫硝效率強,電漿內部的觸媒塗層能夠引導該些游離狀態的離子發生化學反應,因此沒有臭氧產生,另外,能耗僅為其他除硫脫硝設備的幾十分之一至百分之一。 Seventh, the plasma desulfurization and denitration device has high energy utilization efficiency and high sulfur removal and denitration efficiency, and the nano plasma (6) voltage and the first dielectric plasma (7) can generate a high of 10KV-200KV. Piezoelectric, the high-voltage electrode inside the plasma can instantly ionize the molecules in the soot exhaust gas into ions in the free state, so the energy utilization efficiency is high and the sulfur removal and denitration efficiency is strong, and the catalyst coating inside the plasma can guide the free ions. The state of the ion chemical reaction, so there is no ozone, in addition, the energy consumption is only a few tenths to one percent of other sulfur removal and denitration equipment.
第八、該電漿除硫脫硝設備採用模組化堆疊設計,具有體積較小、結構緊湊和擴展能力強的優點,例如,多個第一介質電漿(7)能 夠橫向堆疊成第一介質電漿單元,多個第一介質電漿單元橫向堆疊成第一介質電漿模組,多個第一介質電漿模組縱向堆疊成電漿除硫脫硝設備,因此具有體積較小、結構緊湊和擴展能力強的優點。 Eighth, the plasma desulfurization and denitration device adopts a modular stacking design, and has the advantages of small volume, compact structure and strong expansion capability, for example, a plurality of first dielectric plasmas (7) can The plurality of first dielectric plasma units are laterally stacked into a first dielectric plasma module, and the plurality of first dielectric plasma modules are vertically stacked into a plasma sulfur removal and denitration device. Therefore, it has the advantages of small volume, compact structure and strong expansion capability.
第九、多層絕緣且防止漏電,每一第一介質電漿(7)的外表面採用聚氯乙烯材料進行絕緣,在第一介質電漿(7)橫向堆疊成第一介質電漿單元後,每一第一介質電漿單元的外表面採用聚氯乙烯材料進行絕緣,在第一介質電漿單元橫向堆疊成第一介質電漿模組後,每一第一介質電漿模組的外表面採用聚氯乙烯材料進行絕緣,因此多層絕緣,能夠防止電漿外漏,達到省電和安全的目的。 Ninth, multi-layer insulation and prevention of leakage, the outer surface of each first dielectric plasma (7) is insulated by a polyvinyl chloride material, after the first dielectric plasma (7) is laterally stacked into a first dielectric plasma unit, The outer surface of each first dielectric plasma unit is insulated by a polyvinyl chloride material, and the outer surface of each first dielectric plasma module is assembled after the first dielectric plasma unit is laterally stacked into the first dielectric plasma module. Insulation is made of polyvinyl chloride material, so multi-layer insulation can prevent leakage of plasma and achieve power saving and safety.
雖然以上描述了本發明的具體實施方式,但是本領域的技術人員應當理解,這些僅是舉例說明,本發明的保護範圍是由所附申請專利範圍限定的。本領域的技術人員在不背離本發明的原理和實質的前提下,可以對這些實施方式做出多種變更或修改,但這些變更和修改均落入本發明的保護範圍。 While the invention has been described with respect to the specific embodiments of the present invention, it should be understood that the scope of the invention is defined by the scope of the appended claims. A person skilled in the art can make various changes or modifications to the embodiments without departing from the spirit and scope of the invention, and such changes and modifications fall within the scope of the invention.
(10)‧‧‧氨氣源 (10) ‧ ‧ ammonia source
(2)‧‧‧鍋爐 (2) ‧ ‧ boiler
(20)‧‧‧第二介質電漿 (20)‧‧‧Second medium plasma
(3)‧‧‧氣液固分離器 (3) ‧ ‧ gas-liquid-solid separator
(4)‧‧‧第一氣固分離器 (4) ‧‧‧First gas-solid separator
(5)‧‧‧氣液分離器 (5) ‧‧‧ gas-liquid separator
(8)‧‧‧反應罐 (8) ‧‧‧Reaction tank
(6)‧‧‧納米電漿 (6) ‧‧‧ nano plasma
(60)‧‧‧第二恒溫控制系統 (60) ‧‧‧Second thermostat control system
(7)‧‧‧第一介質電漿 (7) ‧‧‧First dielectric plasma
(70)‧‧‧恒溫控制系統 (70) ‧ ‧ Constant Temperature Control System
(9)‧‧‧第二氣固分離器 (9) ‧‧‧Second gas-solid separator
(90)‧‧‧煙囪 (90) ‧ ‧ chimney
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CN103695060B (en) * | 2013-12-17 | 2015-05-06 | 成都展望能源机械有限公司 | Cyclone-type natural gas oil-gas separator |
-
2014
- 2014-04-09 CN CN201410140278.9A patent/CN104971575B/en not_active Expired - Fee Related
-
2015
- 2015-04-01 TW TW104110590A patent/TWI584863B/en not_active IP Right Cessation
- 2015-04-09 WO PCT/CN2015/076132 patent/WO2015154687A1/en active Application Filing
Also Published As
Publication number | Publication date |
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TWI584863B (en) | 2017-06-01 |
CN104971575B (en) | 2019-02-01 |
CN104971575A (en) | 2015-10-14 |
WO2015154687A1 (en) | 2015-10-15 |
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