TW201433651A - Thin film deposition device - Google Patents

Thin film deposition device Download PDF

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Publication number
TW201433651A
TW201433651A TW102147284A TW102147284A TW201433651A TW 201433651 A TW201433651 A TW 201433651A TW 102147284 A TW102147284 A TW 102147284A TW 102147284 A TW102147284 A TW 102147284A TW 201433651 A TW201433651 A TW 201433651A
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Taiwan
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chamber
vacuum
film forming
container
containers
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TW102147284A
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Chinese (zh)
Inventor
Hiroyuki Ooshima
Keiichi Fujimoto
Hiroyasu Tabuchi
Masaki Nakaya
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Kirin Brewery
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Publication of TW201433651A publication Critical patent/TW201433651A/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04Coating on selected surface areas, e.g. using masks
    • C23C16/045Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/458Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber
    • C23C16/4581Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber characterised by material of construction or surface finish of the means for supporting the substrate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/46Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for heating the substrate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/54Apparatus specially adapted for continuous coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • B65D23/02Linings or internal coatings

Abstract

The present invention provides a film deposition device for depositing a thin film such as DLC (diamond-like carbon) films, etc. with excellent gas barrier properties on the inner surface, the outer surface or both surfaces of a container such as a PET bottle. The film deposition device is provided with: a film deposition chamber (6), the interior of which is kept under vacuum and which performs film deposition on multiple containers using heating elements disposed in the chamber at least one gate chamber (2, 4, 8, 10) that communicates with the film deposition chamber (6) and the interior of which is evacuated and conveyor mechanisms (41 - 45) for passing handling containers (56), which hold multiple containers, through the gate chambers (2, 4, 8, 10) and into the film deposition chamber (6) and transporting same out from the film deposition chamber (6). The film deposition in the film deposition chamber (6) is performed with the multiple containers being held by the handling containers (56).

Description

薄膜之成膜裝置 Film forming device

本發明係關於一種使DLC(Diamond Like Carbon:類鑽碳)膜、SiOx膜、SiOC膜、SiOCN膜、SiNx膜、AlOx膜等之氣體阻隔性高之薄膜成膜於寶特瓶(PET(polyethylene terephthalate:聚對苯二甲酸乙二醇酯)瓶)等容器之內表面、外表面之任一者、或兩者之成膜裝置者。 The present invention relates to a film having a high gas barrier property such as a DLC (Diamond Like Carbon) film, a SiOx film, a SiOC film, a SiOCN film, a SiNx film, or an AlOx film, which is formed into a PET bottle (PET). Any of the inner surface and the outer surface of the container such as terephthalate (polyethylene terephthalate) bottle or the film forming device of both.

先前以來,為了填充清涼飲料等,使用以寶特瓶為首之輕量之塑料製中空容器,且根據便利性及成本方面,於飲料、食品領域中塑料容器使用之擴大係急速發展,如今,寶特瓶已佔據總容器之相當一部分。然而,若與金屬罐或玻璃瓶比較,則塑料容器係氣體阻隔性較低,有時發生氧氣侵入容器內或碳酸氣體放出至容器外等,而內容物之品質保持性能劣化。因此,嘗試使DLC膜等之氣體阻隔性高之薄膜成膜於容器內表面。DLC膜等之氣體阻隔性高之薄膜係可於位於真空減壓下之真空腔室內藉由電漿CVD(Chemical Vapor Deposition:化學氣相沉積)法、金屬蒸鍍法、發熱體CVD法、濺鍍法等形成於容器內表面或外表面,從而可飛躍性地提高對於氧氣流入容器內或碳酸氣體放出至容器外等之氣體阻隔性。 In the past, in order to fill a cool drink, etc., a lightweight plastic hollow container including a PET bottle was used, and the expansion of the use of plastic containers in the field of beverages and foods has been rapidly developed according to convenience and cost. Special bottles have occupied a significant portion of the total container. However, when compared with a metal can or a glass bottle, the plastic container has a low gas barrier property, and oxygen may intrude into the container or the carbon dioxide gas may be released to the outside of the container, and the quality retention property of the contents may deteriorate. Therefore, an attempt has been made to form a film having a high gas barrier property such as a DLC film on the inner surface of the container. A film having a high gas barrier property such as a DLC film can be subjected to plasma CVD (Chemical Vapor Deposition), metal vapor deposition, heating CVD, or sputtering in a vacuum chamber under vacuum decompression. The plating method or the like is formed on the inner surface or the outer surface of the container, so that gas barrier properties such as the flow of oxygen into the container or the release of carbonic acid gas to the outside of the container can be dramatically improved.

[先前技術文獻] [Previous Technical Literature]

[專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2008-127054號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2008-127054

[專利文獻1]日本專利特開2004-107781號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2004-107781

在欲量產於表面成膜有DLC膜等之薄膜之容器之情形時,反復於保持為真空狀態之真空腔室內進行容器之成膜,且在成膜完成後使真空腔室內返回大氣壓並取出處理後之容器後,將下一個容器放入真空腔室進行真空處理而成膜。因此,在進行真空腔室之真空處理時,由於時常自大氣壓進行真空處理,故真空腔室之真空處理時間變長,存在週期時間延遲之問題點。為縮短真空處理時間,謀求週期時間短化,必需大型真空泵,而存在設備成本及使用成本上升之問題。 When it is desired to mass-produce a container in which a film having a DLC film or the like is formed on the surface, the film formation of the container is repeated in a vacuum chamber maintained in a vacuum state, and after the film formation is completed, the vacuum chamber is returned to the atmospheric pressure and taken out. After the treated container, the next container is placed in a vacuum chamber for vacuum treatment to form a film. Therefore, when the vacuum processing of the vacuum chamber is performed, since the vacuum processing is often performed from atmospheric pressure, the vacuum processing time of the vacuum chamber becomes long, and there is a problem that the cycle time is delayed. In order to shorten the vacuum processing time and to shorten the cycle time, a large vacuum pump is required, and there is a problem that equipment cost and use cost increase.

又,發熱體CVD法係亦被稱為熱線CVD法、熱燈絲CVD法、觸媒化學氣相沉積法等之製法,且在將薄膜成膜於容器表面之步驟中,因於容器附近配置發熱體進行成膜處理,故將發熱體設置於真空腔室內。因真空腔室在成膜步驟完成後返回大氣壓,故發熱體定期暴露於空氣中。結果,存在因氧化等使發熱體加速劣化,從而降低成膜功能之問題。 Further, the heating element CVD method is also called a hot-wire CVD method, a hot filament CVD method, or a catalytic chemical vapor deposition method, and in the step of forming a film on the surface of the container, heat is placed in the vicinity of the container. Since the body is subjected to a film forming process, the heat generating body is placed in the vacuum chamber. Since the vacuum chamber returns to atmospheric pressure after the film forming step is completed, the heating element is periodically exposed to the air. As a result, there is a problem that the heating element is accelerated and deteriorated by oxidation or the like, thereby reducing the film forming function.

再者,針對飲料、食品領域之塑料容器之成膜裝置係藉由電漿CVD法於容器表面形成薄膜,在該等先前之成膜裝置之情形時,將容器逐個供給至真空腔室而個別地實施成膜處理,存在無法同時對複數個容器實施成膜處理之問題。 Furthermore, the film forming apparatus for plastic containers in the field of beverages and foods forms a film on the surface of the container by plasma CVD, and in the case of the prior film forming apparatuses, the containers are individually supplied to the vacuum chamber and individually. The film formation treatment is carried out, and there is a problem in that it is impossible to perform film formation treatment on a plurality of containers at the same time.

再者,在先前之薄膜之成膜裝置之情形時,自搬送裝置、例如輸送機將未處理之容器搬入於真空腔室,又,將處理完畢之容器自真空腔室搬出且返回搬送裝置、例如輸送機之情形時,使未處理之容器或處理完畢之容器於多個位置待機,存在瓶處理低效率之問題點。 Further, in the case of the film forming apparatus of the prior film, the unprocessed container is carried into the vacuum chamber from the conveying device, for example, the conveyor, and the processed container is carried out from the vacuum chamber and returned to the conveying device, For example, in the case of a conveyor, the untreated container or the processed container is placed in standby at a plurality of positions, and there is a problem that the bottle processing is inefficient.

本發明之目的係提供一種可防止將薄膜成膜於容器表面時所使用之發熱體之劣化,且可縮短成膜時對腔室內進行真空處理時之真空 處理時間之薄膜之成膜裝置。 SUMMARY OF THE INVENTION An object of the present invention is to provide a vacuum which can prevent deterioration of a heat generating body used when a film is formed on a surface of a container, and can shorten a vacuum when vacuuming a chamber during film formation Film forming apparatus for processing time.

用以解決上述課題之本發明之第1態樣係一種成膜裝置,其特徵在於:其係於容器之表面形成薄膜者,且具備:成膜腔室,其內部保持為真空,且使用配置於內部之發熱體進行複數個容器之成膜;至少1個閘極腔室,其連通於上述成膜腔室,且內部被真空處理;及搬送機構,其經由上述閘極腔室將保持有複數個容器之處理容器搬入於上述成膜腔室,且自上述成膜腔室搬出;上述成膜腔室中之成膜係以將複數個容器保持於上述處理容器之狀態進行。 A first aspect of the present invention for solving the above problems is a film forming apparatus which is formed by forming a film on a surface of a container, and includes a film forming chamber in which a vacuum is maintained and a configuration is used. Forming a plurality of containers in the inner heating element; at least one gate chamber communicating with the film forming chamber and internally vacuum-treated; and a transfer mechanism that is maintained via the gate chamber A processing container of a plurality of containers is carried into the film forming chamber and carried out from the film forming chamber; and a film forming system in the film forming chamber is held in a state in which a plurality of containers are held in the processing container.

本發明較佳之態樣之特徵在於:上述至少1個閘極腔室為複數個閘極腔室。 In a preferred aspect of the invention, the at least one gate chamber is a plurality of gate chambers.

本發明較佳之態樣之特徵在於:進而具備將上述複數個閘極腔室分別獨立地進行真空處理之真空排氣機構。 A preferred aspect of the present invention is characterized in further comprising a vacuum exhausting mechanism that independently vacuum-treats the plurality of gate chambers.

本發明較佳之態樣之特徵在於:將上述成膜腔室配置於上述閘極腔室之上側,且於上述閘極腔室之下端形成開口;上述成膜裝置進而具備密閉上述閘極腔室之上述開口之平板;上述搬送機構係以使上述平板升降之方式構成。 In a preferred aspect of the present invention, the film forming chamber is disposed on an upper side of the gate chamber, and an opening is formed at a lower end of the gate chamber; and the film forming device further includes a gate chamber sealed The flat plate of the opening; the conveying mechanism is configured to elevate and lower the flat plate.

本發明較佳之態樣之特徵在於:上述成膜裝置進而具備配置於上述平板上之與該平板獨立而可升降之升降台;上述搬送裝置藉由使載置有保持有複數個容器之上述處理容器之上述升降台升降,而使複數個容器於上述閘極腔室與上述成膜腔室之間移動。 According to a preferred aspect of the present invention, the film forming apparatus further includes: a lifting platform that is disposed on the flat plate and that is movable independently of the flat plate; and the conveying device that performs the above process of holding a plurality of containers The lifting platform of the container is raised and lowered to move a plurality of containers between the gate chamber and the film forming chamber.

本發明較佳之態樣之特徵在於:上述成膜裝置進而具備用以將保持有複數個容器之上述處理容器搬出入上述閘極腔室之搬出入單元。 In a preferred aspect of the invention, the film forming apparatus further includes a carry-in/out unit for carrying the processing container holding the plurality of containers into the gate chamber.

本發明較佳之態樣之特徵在於:上述搬出入單元具備:鄰接於容器投入用輸送機而配置之供給單元、鄰接於容器排出用輸送機而配 置之排出單元、及配置於上述供給單元與上述排出單元之間之中間單元,上述搬出入單元係於上述供給單元中,將複數個容器自上述容器投入用輸送機裝入上述處理容器,在上述中間單元中,將保持有複數個容器之上述處理容器自上述供給單元搬入於上述閘極腔室,在上述中間單元中,將保持有經形成上述薄膜之複數個容器之上述處理容器自上述閘極腔室搬出至上述排出單元,在上述排出單元中,將經形成上述薄膜之複數個容器排出至上述瓶排出用輸送機。 According to a preferred aspect of the present invention, the loading/unloading unit includes a supply unit disposed adjacent to the container insertion conveyor, and is disposed adjacent to the container discharge conveyor. a discharge unit and an intermediate unit disposed between the supply unit and the discharge unit, wherein the carry-in unit is in the supply unit, and a plurality of containers are loaded into the processing container from the container insertion conveyor. In the intermediate unit, the processing container holding a plurality of containers is carried into the gate chamber from the supply unit, and in the intermediate unit, the processing container holding the plurality of containers forming the film is from the above The gate chamber is carried out to the discharge unit, and a plurality of containers through which the film is formed are discharged to the bottle discharge conveyor in the discharge unit.

本發明之第2態樣之特徵在於:其係於真空壓下使用發熱體使薄膜成膜於容器之內表面及外表面中之一者或兩者之成膜裝置,且具備:第1真空預備腔室,其係於包含自大氣壓到特定之第1真空壓之範圍之壓力區域內予以真空處理;第1加載互鎖腔室,其係於包含自上述第1真空壓到較該第1真空壓要低之特定之第2真空壓之範圍之壓力區域內予以真空處理;及成膜腔室,其用以使用位於上述第2真空壓下之上述發熱體進行上述容器之成膜;上述第1真空預備腔室連接於上述第1加載互鎖腔室,上述第1加載互鎖腔室連接於上述成膜腔室,上述容器依序經由上述第1真空預備腔室及上述第1加載互鎖腔室而被搬送至上述成膜腔室。 A second aspect of the present invention is characterized in that the film forming device is formed by one or both of an inner surface and an outer surface of a container by using a heat generating body under vacuum pressure, and is provided with a first vacuum. The preliminary chamber is vacuum-treated in a pressure region including a range from atmospheric pressure to a specific first vacuum pressure; and the first loading interlock chamber is included in the first vacuum pressure from the first vacuum pressure to the first Vacuum processing is performed in a pressure region of a range of a specific second vacuum pressure at which the vacuum pressure is low; and a film forming chamber for forming a film of the container using the heat generating body located under the second vacuum pressure; a first vacuum preparation chamber is connected to the first load lock chamber, the first load lock chamber is connected to the film forming chamber, and the container sequentially passes through the first vacuum preparation chamber and the first loading The chamber is transferred to the film forming chamber.

本發明較佳之態樣之特徵在於:進而具備:第2真空預備腔室,其係於包含自大氣壓到上述第1真空壓之範圍之壓力區域內予以真空處理;及第2加載互鎖腔室,其係於包含自上述第1真空壓到上述第2真空壓之範圍之壓力區域內予以真空處理;上述第2真空預備腔室連接於上述第2加載互鎖腔室,上述第2加載互鎖腔室連接於上述成膜腔室,於上述成膜腔室內成膜之上述容器依序經由上述第2加載互鎖腔室及上述第2真空預備腔室而被搬送至大氣空間。 A preferred aspect of the present invention is characterized in further comprising: a second vacuum pre-chamber that is vacuum-treated in a pressure region including a range from atmospheric pressure to the first vacuum pressure; and a second loading interlock chamber The vacuum processing is performed in a pressure region including a range from the first vacuum pressure to the second vacuum pressure; the second vacuum preparation chamber is connected to the second load lock chamber, and the second loading chamber The lock chamber is connected to the film forming chamber, and the container formed in the film forming chamber is sequentially transported to the air space via the second load lock chamber and the second vacuum chamber.

本發明較佳之態樣之特徵在於:上述第1真空預備腔室及上述第1加載互鎖腔室係連接於第1真空排氣機構及第2真空排氣機構,且分 別獨立地予以真空處理。 In a preferred aspect of the present invention, the first vacuum pre-chamber and the first load-lock chamber are connected to the first vacuum exhaust mechanism and the second vacuum exhaust mechanism, and are divided into Do not vacuum it independently.

本發明較佳之態樣之特徵在於:上述第2加載互鎖腔室及上述第2真空預備腔室係連接於第3真空排氣機構及第4真空排氣機構,且分別獨立地予以真空處理。 According to a preferred aspect of the present invention, the second load lock chamber and the second vacuum reserve chamber are connected to the third vacuum exhaust mechanism and the fourth vacuum exhaust mechanism, and are independently vacuum-treated. .

本發明較佳之態樣之特徵在於:上述容器為複數個容器,上述複數個容器係以保持於壓板容器之狀態依序經由上述第1真空預備腔室及上述第1加載互鎖腔室而被搬送至上述成膜腔室。 According to a preferred aspect of the present invention, the container is a plurality of containers, and the plurality of containers are sequentially held in the state of the platen container via the first vacuum preparation chamber and the first load lock chamber. Transfer to the film forming chamber described above.

本發明較佳之態樣之特徵在於:上述壓板容器具有複數個收納空間,上述複數個容器之底部分別收納於上述複數個收納空間。 In a preferred aspect of the invention, the platen container has a plurality of storage spaces, and the bottoms of the plurality of containers are respectively housed in the plurality of storage spaces.

本發明較佳之態樣之特徵在於:進而具備在上述容器之成膜處理後回收上述壓板容器之回收機構。 According to a preferred aspect of the present invention, there is provided a recovery mechanism for recovering the platen container after the film forming process of the container.

本發明之第3態樣之特徵在於:其係將容器置入真空腔室內而進行上述真空腔室之真空處理,且於真空狀態之上述真空腔室內使用發熱體使薄膜成膜於容器表面之成膜裝置,上述真空腔室包含:成膜專用腔室,其用於以真空狀態保持上述發熱體且進行複數個容器之成膜;容器待機用腔室,其用以於上述成膜專用腔室放入取出複數個容器;及真空隔離機構,其配置於上述成膜專用腔室與上述容器待機用腔室之間;將上述成膜專用腔室與上述容器待機用腔室連結於真空排氣機構,且朝上述容器待機用腔室搬出入複數個容器及上述成膜專用腔室中複數個容器之成膜係以將複數個容器收納於處理容器之狀態進行。所謂發熱體係其自身實質上不揮發,且具有可使原料氣體藉由觸媒化學反應及/或因熱而分解成化學物種之主要具有金屬表面之構件,例如,將鉭、碳化鉭、鎢、碳化鎢、鎳-鉻合金、或碳作為表層之主成分之導線。 A third aspect of the present invention is characterized in that the container is placed in a vacuum chamber to perform vacuum processing of the vacuum chamber, and a heat generating body is used in the vacuum chamber to form a film on the surface of the container. a film forming apparatus, wherein the vacuum chamber comprises: a film forming dedicated chamber for holding the heat generating body in a vacuum state and performing film formation of a plurality of containers; and a container standby chamber for use in the film forming special cavity a plurality of containers are placed in the chamber; and a vacuum isolation mechanism is disposed between the film forming dedicated chamber and the container standby chamber; and the film forming dedicated chamber and the container standby chamber are connected to the vacuum row The air mechanism is configured to carry out a film forming system in which a plurality of containers and a plurality of containers in the film forming dedicated chamber are carried out in the container standby chamber to store a plurality of containers in the processing container. The heat-generating system itself is substantially non-volatile, and has a main surface having a metal surface which can be chemically reacted by a catalyst and/or decomposed into chemical species by heat, for example, niobium, tantalum carbide, tungsten, Tungsten carbide, nickel-chromium alloy, or carbon as the main component of the surface layer.

根據本發明,因將真空腔室分割成用於以真空狀態保持發熱體且進行成膜之成膜專用腔室、及用以於成膜專用腔室放入取出容器之 容器待機用腔室,故可使成膜專用腔室內始終維持於真空狀態。因此,可防止發熱體劣化,而不會降低成膜功能。又,因僅使容器待機用腔室反復為真空與大氣開放,並使成膜專用腔室始終為真空狀態,故成膜時僅真空處理容器待機用腔室即可。因此,可縮短成膜時真空腔室整體之真空處理時間,從而可縮短週期時間。 According to the present invention, the vacuum chamber is divided into a dedicated film forming chamber for holding the heat generating body in a vacuum state and film forming, and a film forming special chamber is placed in the take-out container. Since the container is in the standby chamber, the film-forming chamber can be maintained in a vacuum state at all times. Therefore, deterioration of the heat generating body can be prevented without lowering the film forming function. Further, since only the container standby chamber is repeatedly opened to the vacuum and the atmosphere, and the film forming dedicated chamber is always in a vacuum state, only the container standby chamber may be vacuum-processed at the time of film formation. Therefore, the vacuum processing time of the entire vacuum chamber at the time of film formation can be shortened, so that the cycle time can be shortened.

根據本發明,可使複數個容器排列於處理容器,且將收納有所排列之複數個容器之處理容器作為1個單元而進行對真空腔室之搬出入及真空腔室中之成膜處理。藉由如此般使用處理容器對複數個容器進行單元管理,可正確且容易進行複數個容器之定位。又,藉由收納多個容器,可同時對多個容器實施成膜處理,從而可實現高產出量。只要在真空腔室可收納之限度內,處理容器之個數不存在上限,但於典型之500ml寶特瓶之情形時,實際上為150個以下。 According to the present invention, a plurality of containers can be arranged in a processing container, and a processing container that accommodates a plurality of arranged containers can be used as a unit to perform a film forming process for carrying in and out of the vacuum chamber and the vacuum chamber. By unit management of a plurality of containers by using the processing container as described above, positioning of a plurality of containers can be performed accurately and easily. Further, by accommodating a plurality of containers, it is possible to perform a film forming process on a plurality of containers at the same time, thereby achieving high throughput. There is no upper limit to the number of processing containers as long as the vacuum chamber can be accommodated, but in the case of a typical 500 ml bottle, it is actually 150 or less.

根據本發明較佳之態樣,其特徵在於:將上述成膜專用腔室配置於上側,將上述容器待機用腔室配置於下側,使上述容器待機用腔室之下端開口,且由可升降之平板密閉上述容器待機用腔室之下端開口。 According to a preferred aspect of the present invention, the film forming dedicated chamber is disposed on the upper side, the container standby chamber is disposed on the lower side, and the lower end of the container standby chamber is opened, and is movable up and down The flat plate seals the lower end opening of the container standby chamber.

根據本發明,藉由升降平板,可將容器待機用腔室設為密閉狀態或開放狀態。即,因平板自身發揮開關閘之作用,故可抑制無用裝置,而可使成膜裝置小型化,且可降低裝置成本。 According to the present invention, the container standby chamber can be set to a closed state or an open state by lifting the flat plate. In other words, since the flat plate itself functions as a switch gate, the useless device can be suppressed, and the film forming apparatus can be downsized and the device cost can be reduced.

根據本發明較佳之態樣,其特徵在於:將收納有複數個容器之上述處理容器載置於上述平板上,藉由上述平板之升降,於上述容器待機用腔室搬出入上述處理容器。 According to a preferred aspect of the present invention, the processing container in which a plurality of containers are accommodated is placed on the flat plate, and the processing container is carried into the container standby chamber by the lifting and lowering of the flat plate.

根據本發明,藉由利用外部設置之升降機升降平板,可將收納有複數個容器之處理容器搬出入容器待機用腔室。藉由如此般使升降機位於真空腔室之外部,可使真空腔室最小化,而可縮短真空處理時間。 According to the present invention, the processing container in which a plurality of containers are accommodated can be carried out into the container standby chamber by using an elevator lifting plate provided externally. By thus positioning the elevator outside of the vacuum chamber, the vacuum chamber can be minimized and the vacuum processing time can be shortened.

根據本發明較佳之態樣,其特徵在於:於上述平板上配置與該平板獨立而可升降之升降台,且使收納有複數個容器之上述處理容器載置於該升降台上,並藉由上述升降台之升降,使收納於上述處理容器之複數個容器於上述瓶待機用腔室與上述成膜專用腔室之間移動。尤其,若設為可調整升降速度之機構,則因可根據容器形狀、容器耐熱特性、或對容器要求之性能,調整容器各部分之成膜時間,而容易調整阻隔性能或容器外觀,故成為本發明更佳之態樣。 According to a preferred aspect of the present invention, a lifting platform that can be raised and lowered independently of the flat plate is disposed on the flat plate, and the processing container that houses the plurality of containers is placed on the lifting platform. The lifting and lowering of the lifting table causes a plurality of containers housed in the processing container to move between the bottle waiting chamber and the film forming dedicated chamber. In particular, if the mechanism for adjusting the lifting speed is set, the film formation time of each part of the container can be adjusted according to the shape of the container, the heat resistance of the container, or the performance required for the container, and the barrier property or the appearance of the container can be easily adjusted. The present invention is better.

根據本發明,可將用以使收納於處理容器之複數個容器於瓶待機用腔室與成膜專用腔室之間移動之升降機構設置於真空腔室外部,而可使真空腔室最小化,從而可縮短真空處理時間。 According to the present invention, the lifting mechanism for moving the plurality of containers accommodated in the processing container between the bottle standby chamber and the film forming dedicated chamber can be disposed outside the vacuum chamber, thereby minimizing the vacuum chamber. Thus, the vacuum processing time can be shortened.

根據本發明較佳之態樣,其特徵在於:使上述平板升降之第1升降機構及使上述升降台升降之第2升降機構係配置於上述真空腔室之下方。 According to a preferred aspect of the present invention, the first elevating mechanism for elevating and lowering the flat plate and the second elevating mechanism for elevating and lowering the elevating table are disposed below the vacuum chamber.

根據本發明較佳之態樣,其特徵在於:將上述成膜專用腔室與上述容器待機用腔室分別連結於個別之真空排氣機構。 According to a preferred aspect of the present invention, the film forming dedicated chamber and the container standby chamber are respectively coupled to an individual vacuum exhausting mechanism.

根據本發明較佳之態樣,其特徵在於:上述成膜專用腔室始終維持於真空狀態。 According to a preferred aspect of the present invention, the film forming chamber is always maintained in a vacuum state.

根據本發明,由於將成膜專用腔室始終維持於真空狀態,而始終以真空狀態保持發熱體,故可防止發熱體劣化,不會降低成膜功能。 According to the present invention, since the heat-generating body is always maintained in a vacuum state while maintaining the vacuum-imparting chamber, the heat-generating body is prevented from deteriorating, and the film-forming function is not lowered.

根據本發明較佳之態樣,上述容器待機用腔室係於容器之成膜時自大氣壓進行真空處理而成為真空狀態,且於成膜完成後之容器取出時返回大氣壓。 According to a preferred aspect of the present invention, the container standby chamber is vacuum-treated at atmospheric pressure at the time of film formation of the container to be in a vacuum state, and returns to atmospheric pressure when the container is taken out after the film formation is completed.

根據本發明較佳之態樣,其特徵在於:在上述真空腔室之兩側,配置有用以將收納有複數個容器之上述處理容器搬出入上述真空腔室之搬出入單元。 According to a preferred aspect of the present invention, a loading and unloading unit for transporting the processing container in which a plurality of containers are accommodated into the vacuum chamber is disposed on both sides of the vacuum chamber.

根據本發明較佳之態樣,其特徵在於:配置於上述真空腔室之兩側之上述2個搬出入單元係將收納有複數個容器之上述處理容器交替地搬出入上述真空腔室。 According to a preferred aspect of the present invention, the two loading/unloading units disposed on both sides of the vacuum chamber alternately carry the processing containers in which a plurality of containers are accommodated into the vacuum chamber.

根據本發明,藉由於真空腔室之兩側配置搬出入單元,可自2個搬出入單元將收納有複數個容器之處理容器交替地搬出入真空腔室。因此,真空腔室幾乎不存在等待時間,可使真空腔室大致連續地運轉。又,因容器朝處理容器之裝入、抽出及收納有容器之處理容器之移送可於真空腔室之容器之成膜步驟中進行,故真空腔室幾乎不存在等待時間,可使真空腔室大致連續地運轉。 According to the present invention, since the loading and unloading unit is disposed on both sides of the vacuum chamber, the processing containers in which the plurality of containers are accommodated can be alternately carried out into the vacuum chamber from the two loading and unloading units. Therefore, there is almost no waiting time in the vacuum chamber, and the vacuum chamber can be operated substantially continuously. Moreover, since the transfer of the processing container into and out of the processing container by the container can be performed in the film forming step of the container of the vacuum chamber, there is almost no waiting time in the vacuum chamber, and the vacuum chamber can be made. It runs roughly continuously.

根據本發明較佳之態樣,其特徵在於:上述搬出入單元具備:供給單元,其係鄰接於容器投入用輸送機而配置;排出單元,其係鄰接於容器排出用輸送機而配置;及中間單元,其配置於上述供給單元與上述排出單元之間;且在上述供給單元中自上述容器投入用輸送機將複數個容器裝入處理容器,在上述中間單元中自上述供給單元接收收納有複數個容器之上述處理容器且搬入於上述真空腔室,在上述中間單元中自上述真空腔室接收收納有已於上述真空腔室內成膜之複數個容器之上述處理容器且搬出至上述排出單元,在上述排出單元中將上述處理容器內之複數個容器排出至上述容器排出用輸送機。 According to a preferred aspect of the present invention, the loading/unloading unit includes: a supply unit that is disposed adjacent to the container insertion conveyor; and a discharge unit that is disposed adjacent to the container discharge conveyor; and a unit disposed between the supply unit and the discharge unit; and the plurality of containers are loaded into the processing container from the container insertion conveyor in the supply unit, and the plurality of containers are received and received from the supply unit in the intermediate unit The processing container of the plurality of containers is carried into the vacuum chamber, and the processing unit that accommodates a plurality of containers that have been formed in the vacuum chamber is received from the vacuum chamber in the intermediate unit, and is carried out to the discharge unit. In the discharge unit, a plurality of containers in the processing container are discharged to the container discharge conveyor.

本發明之第1態樣發揮以下所列舉之效果。 The first aspect of the present invention exerts the effects listed below.

(1)因可始終以真空狀態保持發熱體,故可防止發熱體劣化,從而成膜功能不會下降。 (1) Since the heating element can be always kept in a vacuum state, deterioration of the heating element can be prevented, and the film forming function does not decrease.

(2)因僅使閘極腔室反復為真空與大氣開放,並使成膜腔室始終為真空狀態,故成膜時僅對閘極腔室進行真空處理即可。因此,可縮短成膜時成膜腔室整體之真空處理時間,而可縮短週期時間。 (2) Since only the gate chamber is repeatedly opened to the vacuum and the atmosphere, and the film forming chamber is always in a vacuum state, only the gate chamber can be vacuum-treated at the time of film formation. Therefore, the vacuum processing time of the entire film forming chamber at the time of film formation can be shortened, and the cycle time can be shortened.

本發明之第2態樣發揮以下所列舉之效果。 The second aspect of the present invention exerts the effects listed below.

(1)因可始終以真空狀態保持發熱體,故可防止發熱體劣化,從而成膜功能不會下降。 (1) Since the heating element can be always kept in a vacuum state, deterioration of the heating element can be prevented, and the film forming function does not decrease.

(2)藉由將第1真空預備腔室及第1加載互鎖腔室階段性地減壓,可以更短之時間間隔將容器搬送至成膜腔室。因此,可縮短成膜之週期時間而提高產出量。 (2) By gradually decompressing the first vacuum pre-chamber and the first load-lock chamber, the container can be transported to the film forming chamber at a shorter time interval. Therefore, the cycle time of film formation can be shortened to increase the throughput.

(3)藉由使用壓板容器,可將複數個容器作為1個單元進行搬送、成膜。因此,可增加每單位時間之處理個數。 (3) By using a platen container, a plurality of containers can be transported as one unit and formed into a film. Therefore, the number of processes per unit time can be increased.

本發明之第3態樣發揮以下所列舉之效果。 The third aspect of the present invention exerts the effects listed below.

(1)因可始終以真空狀態保持發熱體,故可防止發熱體劣化,從而成膜功能不會下降。 (1) Since the heating element can be always kept in a vacuum state, deterioration of the heating element can be prevented, and the film forming function does not decrease.

(2)因僅使容器待機用腔室反復為真空與大氣開放,並使成膜專用腔室始終為真空狀態,故成膜時僅對容器待機用腔室進行真空處理即可。因此,可縮短成膜時真空腔室整體之真空處理時間,而可縮短週期時間。 (2) Since only the container standby chamber is repeatedly opened to the vacuum and the atmosphere, and the film forming dedicated chamber is always in a vacuum state, only the container standby chamber may be vacuum-treated at the time of film formation. Therefore, the vacuum processing time of the entire vacuum chamber at the time of film formation can be shortened, and the cycle time can be shortened.

(3)可使複數個容器排列於處理容器,且將收納有所排列之複數個容器之處理容器作為1個單元進行對真空腔室之搬出入及真空腔室內之成膜處理。藉由如此般使用處理容器對複數個容器進行單元管理,可正確且容易進行複數個容器之定位。又,可對多個寶特瓶同時實施成膜處理,而可實現高產出量。只要在真空腔室可收納之限度內,處理容器之個數不存在上限,但於典型之500ml寶特瓶之情形時,實際上為150個以下。 (3) A plurality of containers may be arranged in a processing container, and a processing container that accommodates a plurality of arranged containers may be used as a unit to perform a film forming process for carrying in and out of the vacuum chamber and the vacuum chamber. By unit management of a plurality of containers by using the processing container as described above, positioning of a plurality of containers can be performed accurately and easily. In addition, a plurality of PET bottles can be simultaneously subjected to a film forming process, and a high throughput can be achieved. There is no upper limit to the number of processing containers as long as the vacuum chamber can be accommodated, but in the case of a typical 500 ml bottle, it is actually 150 or less.

(4)藉由於真空腔室之兩側配置搬出入單元,可自2個搬出入單元將收納有複數個容器之處理容器交替地搬入、搬出真空腔室。藉此,真空腔室幾乎不存在等待時間,可使真空腔室大致連續地運轉。 (4) By arranging the loading and unloading unit on both sides of the vacuum chamber, the processing containers in which a plurality of containers are accommodated can be alternately carried in and out of the vacuum chamber from the two loading and unloading units. Thereby, there is almost no waiting time in the vacuum chamber, and the vacuum chamber can be operated substantially continuously.

(5)因容器朝處理容器之裝入、抽出及收納有容器之處理容器之移送可於真空腔室之容器之成膜步驟中進行,故真空腔室幾乎不存在 等待時間,可使真空腔室大致連續地運轉。 (5) The transfer of the processing container in which the container is loaded, withdrawn, and stored in the processing container can be performed in the film forming step of the container in the vacuum chamber, so that the vacuum chamber hardly exists. The waiting time allows the vacuum chamber to operate substantially continuously.

(6)收納有容器之處理容器對真空腔室之搬出入可藉由利用外部設置之升降機升降而實現。藉由如此般使升降機位於真空腔室之外部,可使真空腔室最小化,而可縮短真空處理時間。 (6) The handling of the vacuum chamber by the processing container in which the container is housed can be realized by lifting and lowering the lift provided by the outside. By thus positioning the elevator outside of the vacuum chamber, the vacuum chamber can be minimized and the vacuum processing time can be shortened.

(7)藉由使經載置收納有容器之處理容器之平板升降,可使真空腔室成為密閉狀態或開放狀態。即,因平板自身發揮開關閘之作用,故可抑制無用裝置,而可使成膜裝置小型化且可降低裝置成本。 (7) The vacuum chamber can be sealed or opened by raising and lowering the flat plate on which the processing container in which the container is placed. In other words, since the flat plate itself functions as a switch gate, the useless device can be suppressed, and the film forming apparatus can be downsized and the device cost can be reduced.

1‧‧‧成膜裝置 1‧‧‧ film forming device

2‧‧‧第1真空預備腔室 2‧‧‧1st vacuum preparation chamber

4‧‧‧第1加載互鎖腔室 4‧‧‧1st load lock chamber

5‧‧‧箭頭符號 5‧‧‧ arrow symbol

6‧‧‧成膜腔室 6‧‧‧filming chamber

6a‧‧‧連結部 6a‧‧‧Linking Department

7‧‧‧箭頭符號 7‧‧‧ arrow symbol

8‧‧‧第2加載互鎖腔室 8‧‧‧2nd load lock chamber

10‧‧‧第2真空預備腔室 10‧‧‧2nd vacuum preparation chamber

20‧‧‧第1閘閥 20‧‧‧1st gate valve

22‧‧‧第2閘閥 22‧‧‧2nd gate valve

24‧‧‧第3閘閥 24‧‧‧3rd gate valve

26‧‧‧第4閘閥 26‧‧‧4th gate valve

28‧‧‧第5閘閥 28‧‧‧5th gate valve

30‧‧‧第6閘閥 30‧‧‧6th gate valve

32‧‧‧真空管線 32‧‧‧vacuum pipeline

33‧‧‧真空管線 33‧‧‧vacuum pipeline

35‧‧‧真空管線 35‧‧‧vacuum pipeline

36‧‧‧真空管線 36‧‧‧vacuum pipeline

40‧‧‧搬送機構 40‧‧‧Transportation agency

41‧‧‧搬送機構 41‧‧‧Transportation agency

42‧‧‧搬送機構 42‧‧‧Transportation agency

43‧‧‧搬送機構 43‧‧‧Transportation agency

44‧‧‧搬送機構 44‧‧‧Transportation agency

45‧‧‧搬送機構 45‧‧‧Transportation agency

50‧‧‧寶特瓶 50‧‧‧Pet Bottle

55‧‧‧搬入輸送機 55‧‧‧ moving into the conveyor

56‧‧‧壓板容器 56‧‧‧ platen container

56a‧‧‧隔板 56a‧‧‧Baffle

61‧‧‧發熱體 61‧‧‧heating body

62‧‧‧氣體供給管 62‧‧‧ gas supply pipe

65‧‧‧發熱體單元 65‧‧‧heating unit

67‧‧‧支持台 67‧‧‧Support desk

69‧‧‧升降機構 69‧‧‧ Lifting mechanism

70‧‧‧支持軸 70‧‧‧ Support shaft

71‧‧‧升降用馬達 71‧‧‧Moving motor

73‧‧‧大氣開放閥 73‧‧‧Atmospheric open valve

75‧‧‧搬出輸送機 75‧‧‧Removing conveyor

80‧‧‧提升式輸送機 80‧‧‧lift conveyor

82‧‧‧搬送軌道 82‧‧‧Transfer track

85‧‧‧掛鉤 85‧‧‧ hook

87‧‧‧滾筒 87‧‧‧Roller

89‧‧‧擋止件 89‧‧‧stops

90‧‧‧下降輸送機 90‧‧‧Down conveyor

92‧‧‧大氣開放閥 92‧‧‧Atmospheric open valve

101‧‧‧成膜裝置 101‧‧‧ film forming device

103‧‧‧瓶投入用輸送機 103‧‧‧Bottle conveyor

104‧‧‧瓶排出用輸送機 104‧‧‧Bottle Discharge Conveyor

110‧‧‧成膜單元 110‧‧‧ film forming unit

110A‧‧‧成膜單元 110A‧‧‧film forming unit

110B‧‧‧成膜單元 110B‧‧‧film forming unit

110C‧‧‧成膜單元 110C‧‧‧ film forming unit

112‧‧‧瓶待機用腔室 112‧‧‧ bottle standby chamber

112a‧‧‧連結部 112a‧‧‧Connecting Department

113‧‧‧升降機 113‧‧‧ Lifts

114‧‧‧平板 114‧‧‧ tablet

115‧‧‧升降台 115‧‧‧ Lifting table

121‧‧‧第1升降軸 121‧‧‧1st lifting shaft

122‧‧‧第2升降軸 122‧‧‧2nd lifting shaft

123‧‧‧閘閥 123‧‧‧ gate valve

130‧‧‧搬出入單元 130‧‧‧ Moving in and out of the unit

131‧‧‧供給單元 131‧‧‧Supply unit

132‧‧‧中間單元 132‧‧‧Intermediate unit

133‧‧‧排出單元 133‧‧‧Discharge unit

A‧‧‧箭頭符號 A‧‧‧ arrow symbol

B‧‧‧箭頭符號 B‧‧‧arrow symbol

VP1‧‧‧真空泵 VP1‧‧‧ vacuum pump

VP2‧‧‧真空泵 VP2‧‧‧ vacuum pump

VP3‧‧‧真空泵 VP3‧‧‧ vacuum pump

VP4‧‧‧真空泵 VP4‧‧‧ vacuum pump

VP5‧‧‧真空泵 VP5‧‧‧ vacuum pump

VP6‧‧‧真空泵 VP6‧‧‧ vacuum pump

圖1係顯示本發明之第1實施形態之薄膜之成膜裝置之整體構成之模式圖。 Fig. 1 is a schematic view showing the overall configuration of a film forming apparatus for a film according to a first embodiment of the present invention.

圖2係自上方觀察本發明之第1實施形態之成膜裝置之圖。 Fig. 2 is a view of the film forming apparatus according to the first embodiment of the present invention as seen from above.

圖3係壓板容器之上表面圖。 Figure 3 is a top view of the platen container.

圖4係顯示壓板容器之其他例之上表面圖。 Fig. 4 is a top view showing the other example of the platen container.

圖5係顯示第1真空預備腔室及第1加載互鎖腔室內之真空壓變動之圖。 Fig. 5 is a view showing changes in vacuum pressure in the first vacuum chamber and the first load lock chamber.

圖6係顯示第2真空預備腔室及第2加載互鎖腔室內之真空壓變動之圖。 Fig. 6 is a view showing changes in vacuum pressure in the second vacuum pre-chamber and the second load-lock chamber.

圖7係模式性顯示成膜腔室之剖面之圖。 Fig. 7 is a view schematically showing a cross section of a film forming chamber.

圖8係顯示本發明之第2實施形態之薄膜之成膜裝置之整體構成之俯視圖。 Fig. 8 is a plan view showing the overall configuration of a film forming apparatus for a film according to a second embodiment of the present invention.

圖9係圖8之IX-IX線剖面圖。 Figure 9 is a cross-sectional view taken along line IX-IX of Figure 8.

圖10係顯示成膜單元之細節之模式性剖面圖。 Figure 10 is a schematic cross-sectional view showing the details of the film forming unit.

圖11A係顯示圖10所示之成膜單元之動作之圖。 Fig. 11A is a view showing the operation of the film forming unit shown in Fig. 10.

圖11B係顯示圖10所示之成膜單元之動作之圖。 Fig. 11B is a view showing the operation of the film forming unit shown in Fig. 10.

圖11C係顯示圖10所示之成膜單元之動作之圖。 Fig. 11C is a view showing the operation of the film forming unit shown in Fig. 10.

圖12係顯示升降台上升至特定位置且將發熱體插入於收納於壓 板容器之寶特瓶內之狀態之模式性剖面圖。 Figure 12 shows that the lifting platform is raised to a specific position and the heating element is inserted into the receiving pressure. A schematic cross-sectional view of the state of the plate container.

圖13係顯示如圖8至圖12所示般構成之本發明之第2實施形態之薄膜之成膜裝置之整體動作之圖。 Fig. 13 is a view showing the overall operation of the film forming apparatus of the film according to the second embodiment of the present invention, which is constructed as shown in Figs. 8 to 12 .

以下,參照圖1至圖7說明本發明之薄膜之成膜裝置之第1實施形態。 Hereinafter, a first embodiment of a film forming apparatus for a film of the present invention will be described with reference to Figs. 1 to 7 .

圖1係顯示本發明之薄膜之成膜裝置1之整體構成之模式圖。圖2係自上方觀察成膜裝置1之圖。如圖1所示,成膜裝置1具備第1真空預備腔室2、第1加載互鎖腔室4、成膜腔室6、第2加載互鎖腔室8、及第2真空預備腔室10。該等之第1真空預備腔室2、第1加載互鎖腔室4、成膜腔室6、第2加載互鎖腔室8、及第2真空預備腔室10係依該序串聯連接。第1真空預備腔室2及第1加載互鎖腔室4構成連通於成膜腔室6,且內部被真空處理之閘極腔室。第2真空預備腔室10及第2加載互鎖腔室8亦相同,構成連通於成膜腔室6,且內部被真空處理之閘極腔室。 Fig. 1 is a schematic view showing the overall configuration of a film forming apparatus 1 of the film of the present invention. Fig. 2 is a view of the film forming apparatus 1 as viewed from above. As shown in FIG. 1, the film forming apparatus 1 includes a first vacuum pre-chamber 2, a first load lock chamber 4, a film forming chamber 6, a second load lock chamber 8, and a second vacuum pre-chamber. 10. The first vacuum pre-chamber 2, the first load-lock chamber 4, the film-forming chamber 6, the second load-lock chamber 8, and the second vacuum-preparation chamber 10 are connected in series in this order. The first vacuum pre-chamber 2 and the first load-lock chamber 4 constitute a gate chamber that communicates with the film forming chamber 6 and is internally vacuum-treated. The second vacuum pre-chamber 10 and the second load-lock chamber 8 are also identical, and constitute a gate chamber that communicates with the film forming chamber 6 and is internally vacuum-treated.

如圖2所示,作為容器之寶特瓶50係由搬入輸送機55搬入於成膜裝置1。進而,寶特瓶50依序通過第1真空預備腔室2、第1加載互鎖腔室4、成膜腔室6、第2加載互鎖腔室8、及第2真空預備腔室10,接著由搬出輸送機75搬出。第1真空預備腔室2及第1加載互鎖腔室4係配置於寶特瓶50之流動方向上成膜腔室6之上游側,第2加載互鎖腔室8及第2真空預備腔室10配置於成膜腔室6之下游側。 As shown in FIG. 2, the PET bottle 50 as a container is carried into the film forming apparatus 1 by the carry-in conveyor 55. Further, the PET bottle 50 sequentially passes through the first vacuum preparation chamber 2, the first load lock chamber 4, the film formation chamber 6, the second load lock chamber 8, and the second vacuum preparation chamber 10, Then, it is carried out by the carry-out conveyor 75. The first vacuum pre-chamber 2 and the first load-lock chamber 4 are disposed on the upstream side of the film forming chamber 6 in the flow direction of the PET bottle 50, and the second loading interlock chamber 8 and the second vacuum chamber The chamber 10 is disposed on the downstream side of the film forming chamber 6.

於第1真空預備腔室2與大氣空間(周圍空間)之間,設置有作為第1真空隔離機構之第1閘閥20,藉由開啟第1閘閥20,將寶特瓶50搬入於第1真空預備腔室2內。第1真空預備腔室2係鄰接於第1加載互鎖腔室4而配置。於第1真空預備腔室2與第1加載互鎖腔室4之間,設置有作為第2真空隔離機構之第2閘閥22,藉由開啟第2閘閥22,而使第1真 空預備腔室2與第1加載互鎖腔室4連通。第1加載互鎖腔室4係鄰接於成膜腔室6而配置。於第1加載互鎖腔室4與成膜腔室6之間,設置有作為第3真空隔離機構之第3閘閥24,藉由開啟第3閘閥24,而使第1加載互鎖腔室4與成膜腔室6連通。 A first gate valve 20 as a first vacuum isolation mechanism is provided between the first vacuum chamber 2 and the air space (surrounding space), and the first gate valve 20 is opened to carry the PET bottle 50 into the first vacuum. Prepared in the chamber 2. The first vacuum preparation chamber 2 is disposed adjacent to the first load lock chamber 4 . Between the first vacuum preparation chamber 2 and the first load lock chamber 4, a second gate valve 22 as a second vacuum isolation mechanism is provided, and the first gate valve 22 is opened to make the first true The empty preparation chamber 2 is in communication with the first load lock chamber 4. The first load lock chamber 4 is disposed adjacent to the film forming chamber 6. A third gate valve 24 as a third vacuum isolation mechanism is disposed between the first load lock chamber 4 and the film formation chamber 6, and the first load lock chamber 4 is opened by opening the third gate valve 24. It is in communication with the film forming chamber 6.

第2加載互鎖腔室8係鄰接於成膜腔室6而配置。於成膜腔室6與第2加載互鎖腔室8之間,設置有作為第4真空隔離機構之第4閘閥26,藉由開啟第4閘閥26,而使成膜腔室6與第2加載互鎖腔室8連通。第2真空預備腔室10係鄰接於第2加載互鎖腔室8而配置。於第2加載互鎖腔室8與第2真空預備腔室10之間,設置有作為第5真空隔離機構之第5閘閥28,藉由開啟第5閘閥28,而使第2加載互鎖腔室8與第2真空預備腔室10連通。於第2真空預備腔室10與大氣空間之間,設置有第6閘閥30,藉由開啟第6閘閥30,將寶特瓶50自第2真空預備腔室10搬出至大氣空間。 The second load lock chamber 8 is disposed adjacent to the film formation chamber 6. Between the film forming chamber 6 and the second load lock chamber 8, a fourth gate valve 26 as a fourth vacuum isolating mechanism is provided, and by opening the fourth gate valve 26, the film forming chamber 6 and the second chamber are provided. The load lock chamber 8 is in communication. The second vacuum preparation chamber 10 is disposed adjacent to the second load lock chamber 8 . Between the second load lock chamber 8 and the second vacuum reserve chamber 10, a fifth gate valve 28 as a fifth vacuum isolation mechanism is provided, and the second load lock chamber is opened by opening the fifth gate valve 28. The chamber 8 is in communication with the second vacuum preparation chamber 10. A sixth gate valve 30 is provided between the second vacuum preparation chamber 10 and the air space, and the sixth gate valve 30 is opened to carry the PET bottle 50 out of the second vacuum preparation chamber 10 to the air space.

第1真空預備腔室2經由真空管線32連接於作為真空排氣機構之真空泵VP1,藉由真空泵VP1,於第1真空預備腔室2內形成真空。同樣,第1加載互鎖腔室4、第2加載互鎖腔室8、及第2真空預備腔室10經由真空管線33、35、36分別連接於作為真空排氣機構之真空泵VP2、VP3、VP4,且藉由真空泵VP2、VP3、VP4,於第1加載互鎖腔室4、成膜腔室6、第2加載互鎖腔室8、及第2真空預備腔室10之內部形成真空。藉由此種構成,各個腔室2、4、8、10係藉由真空泵VP1、VP2、VP3、VP4分別獨立地予以真空排氣。再者,藉由以開啟第3閘閥24之狀態驅動真空泵VP2,可同時對第1加載互鎖腔室4及成膜腔室6進行真空處理。 The first vacuum pre-chamber 2 is connected to a vacuum pump VP1 as a vacuum exhaust mechanism via a vacuum line 32, and a vacuum is formed in the first vacuum pre-chamber 2 by the vacuum pump VP1. Similarly, the first load lock chamber 4, the second load lock chamber 8, and the second vacuum reserve chamber 10 are respectively connected to vacuum pumps VP2, VP3, which are vacuum exhaust mechanisms, via vacuum lines 33, 35, 36, VP4, and vacuum is formed in the first load lock chamber 4, the film forming chamber 6, the second load lock chamber 8, and the second vacuum reserve chamber 10 by the vacuum pumps VP2, VP3, and VP4. With this configuration, each of the chambers 2, 4, 8, and 10 is independently evacuated by the vacuum pumps VP1, VP2, VP3, and VP4. Further, by driving the vacuum pump VP2 in a state where the third gate valve 24 is opened, the first load lock chamber 4 and the film forming chamber 6 can be vacuum-processed simultaneously.

於第1真空預備腔室2內安裝有大氣開放閥92,藉由開啟該大氣開放閥92,而將第1真空預備腔室2內大氣開放。同樣,於第2真空預備腔室10內安裝有大氣開放閥73,藉由開啟該大氣開放閥73,而將第 2真空預備腔室10內大氣開放。 An atmosphere opening valve 92 is attached to the first vacuum chamber 2, and the atmosphere in the first vacuum chamber 2 is opened by opening the atmosphere opening valve 92. Similarly, an atmosphere opening valve 73 is installed in the second vacuum chamber 10, and the atmosphere opening valve 73 is opened. 2 The atmosphere in the vacuum preparation chamber 10 is open.

於第1真空預備腔室2與搬入輸送機55之間,配置有包含帶式輸送機等之搬送機構40。再者,於第1真空預備腔室2、第1加載互鎖腔室4、成膜腔室6、第2互鎖加壓腔室8、及第2真空預備腔室10內,分別設置有包含帶式輸送機等之搬送機構41、42、43、44、45。藉由驅動搬送機構40、41、42、43、44、45,寶特瓶50係依序於第1真空預備腔室2、第1加載互鎖腔室4、成膜腔室6、第2加載互鎖腔室8、及第2真空預備腔室10內搬送。 A conveyance mechanism 40 including a belt conveyor or the like is disposed between the first vacuum preparation chamber 2 and the carry-in conveyor 55. Further, in the first vacuum preparation chamber 2, the first load lock chamber 4, the film formation chamber 6, the second interlock pressure chamber 8, and the second vacuum preparation chamber 10, respectively, The conveying mechanisms 41, 42, 43, 44, and 45 including a belt conveyor are included. By driving the transport mechanisms 40, 41, 42, 43, 44, 45, the PET bottle 50 is sequentially arranged in the first vacuum preparation chamber 2, the first load lock chamber 4, the film forming chamber 6, and the second The loading lock chamber 8 and the second vacuum preparation chamber 10 are transported.

如圖1所示,由搬入輸送機55所搬入之寶特瓶50係藉由未圖示之夾具而載置於預先所準備之壓板容器56上。圖3係壓板容器56之上表面圖。如圖3所示,壓板容器56具有複數片隔板56a。於由該等隔板56a所形成之複數個收納空間內,逐個收納寶特瓶50之底部。藉由使用此種壓板容器56,可將寶特瓶50作為1個單元進行管理,進而可正確且容易進行寶特瓶50之定位。收納空間未限定於該例,例如亦可由形成於壓板容器56底部之圓形凹部構成。又,雖然於圖示之例中,係將16個寶特瓶50作為1個單元載置於壓板容器56上而進行搬送,但本發明並未限定於圖示之例,亦可使用能基於成膜腔室6之容量保持更多寶特瓶之壓板容器。例如,如圖4所示,亦可使用可保持56個寶特瓶50之壓板容器56。 As shown in Fig. 1, the PET bottle 50 carried by the carry-in conveyor 55 is placed on a platen container 56 prepared in advance by a jig (not shown). Figure 3 is a top plan view of the platen container 56. As shown in Fig. 3, the platen container 56 has a plurality of separators 56a. The bottom of the PET bottle 50 is stored one by one in a plurality of storage spaces formed by the partitions 56a. By using such a platen container 56, the PET bottle 50 can be managed as one unit, and the positioning of the PET bottle 50 can be performed accurately and easily. The storage space is not limited to this example, and may be constituted, for example, by a circular recess formed in the bottom of the platen container 56. Further, in the illustrated example, the 16 PET bottles 50 are placed on the platen container 56 as one unit and transported. However, the present invention is not limited to the illustrated example, and the present invention can be used based on The capacity of the film forming chamber 6 maintains more of the platen container of the PET bottle. For example, as shown in FIG. 4, a platen container 56 that holds 56 PET bottles 50 can also be used.

未處理之寶特瓶50係自大氣空間經由第1真空預備腔室2及第1加載互鎖腔室4被搬送至形成有真空壓之成膜腔室6。又,所處理之寶特瓶50係自成膜腔室6經由第2加載互鎖腔室8及第2真空預備腔室10被搬送至大氣空間。為實現於大氣空間與成膜腔室6之間搬送寶特瓶50,腔室2、4、8、10內之壓力係隨著寶特瓶50之移動而變動。 The untreated PET bottle 50 is transferred from the atmospheric space to the film forming chamber 6 where the vacuum pressure is formed, via the first vacuum pre-chamber 2 and the first load-lock chamber 4. Further, the processed bottle 50 is transported from the film forming chamber 6 to the atmosphere through the second load lock chamber 8 and the second vacuum reserve chamber 10. In order to realize the transfer of the PET bottle 50 between the atmospheric space and the film forming chamber 6, the pressure in the chambers 2, 4, 8, 10 varies with the movement of the PET bottle 50.

圖5係顯示第1真空預備腔室2及第1加載互鎖腔室4內之真空壓之變動之圖,圖6係顯示第2真空預備腔室10及第2加載互鎖腔室8內之真 空壓之變動之圖。如圖5及圖6所示,第1真空預備腔室2及第2真空預備腔室10係在自大氣壓到至少第1特定真空壓之壓力區域內予以真空處理,第1加載互鎖腔室4及第2加載互鎖腔室8係在自第1真空壓到較該第1真空壓要低之特定之第2真空壓之壓力區域內予以真空處理。成膜腔室6始終維持於特定之目標真空壓(該例中為第2真空壓)。 5 is a view showing changes in the vacuum pressure in the first vacuum chamber 2 and the first load lock chamber 4, and FIG. 6 is a view showing the second vacuum chamber 10 and the second load lock chamber 8 True A diagram of the change in air pressure. As shown in FIGS. 5 and 6, the first vacuum pre-chamber 2 and the second vacuum pre-chamber 10 are vacuum-treated in a pressure region from atmospheric pressure to at least a first specific vacuum pressure, and the first loading interlock chamber 4 and the second load lock chamber 8 are vacuum-treated in a pressure region from a first vacuum pressure to a specific second vacuum pressure lower than the first vacuum pressure. The film forming chamber 6 is always maintained at a specific target vacuum pressure (in this example, the second vacuum pressure).

以下,詳細說明隨著寶特瓶50之搬送而發生之各腔室內之真空壓之變動。當開啟第1閘閥20時,驅動搬送機構40、41而將寶特瓶50連同壓板容器56一起被搬送於第1真空預備腔室2。寶特瓶50被搬送於第1真空預備腔室2內後,封閉第1閘閥20,而使第1真空預備腔室2內成為氣密狀態。於該狀態下,藉由驅動連接於真空管線32之真空泵VP1,將第1真空預備腔室2真空處理至特定之第3真空壓。該第3真空壓係高於第1真空壓之壓力。 Hereinafter, the fluctuation of the vacuum pressure in each chamber which occurs as the transfer of the PET bottle 50 is described in detail. When the first gate valve 20 is opened, the transfer mechanisms 40 and 41 are driven to transport the PET bottle 50 together with the platen container 56 to the first vacuum chamber 2 . After the PET bottle 50 is transferred into the first vacuum pre-chamber 2, the first gate valve 20 is closed, and the inside of the first vacuum pre-chamber 2 is made airtight. In this state, the first vacuum pre-chamber 2 is vacuum-treated to a specific third vacuum pressure by driving the vacuum pump VP1 connected to the vacuum line 32. The third vacuum pressure system is higher than the pressure of the first vacuum pressure.

第1加載互鎖腔室4係藉由真空泵VP2而被真空處理至第2真空壓,於第1加載互鎖腔室4內形成有比第1真空預備腔室2高之真空度。若於該狀態下開啟第2閘閥22,則第1真空預備腔室2與第1加載互鎖腔室4連通,該等腔室2、4內之壓力成為第3真空壓與第2真空壓之中間壓力即第1真空壓。 The first load lock chamber 4 is vacuum-treated to the second vacuum pressure by the vacuum pump VP2, and a vacuum higher than the first vacuum reserve chamber 2 is formed in the first load lock chamber 4. When the second gate valve 22 is opened in this state, the first vacuum reserve chamber 2 communicates with the first load lock chamber 4, and the pressures in the chambers 2, 4 become the third vacuum pressure and the second vacuum pressure. The intermediate pressure is the first vacuum pressure.

在開啟第2閘閥22之期間,驅動搬送機構41、42而將寶特瓶50連同壓板容器56一起自第1真空預備腔室2搬送於第1加載互鎖腔室4。寶特瓶50之搬送中,真空泵VP1、VP2繼續真空排氣動作,藉此,第1真空預備腔室2及第1加載互鎖腔室4內之壓力自第1真空壓進而降低。當寶特瓶50之搬送完成時,封閉第2閘閥22。真空泵VP2將第1加載互鎖腔室4內真空處理至第2真空壓。 While the second gate valve 22 is being opened, the transfer mechanisms 41 and 42 are driven to transport the PET bottle 50 together with the platen container 56 from the first vacuum supply chamber 2 to the first load lock chamber 4. During the transfer of the PET bottle 50, the vacuum pumps VP1 and VP2 continue the vacuum exhaust operation, whereby the pressure in the first vacuum reserve chamber 2 and the first load lock chamber 4 is further lowered from the first vacuum pressure. When the transfer of the PET bottle 50 is completed, the second gate valve 22 is closed. The vacuum pump VP2 vacuum-treats the first load lock chamber 4 to the second vacuum pressure.

成膜腔室6內係藉由真空泵VP2預先進行真空處理,且於成膜腔室6內形成有第2真空壓。在第1加載互鎖腔室4及成膜腔室6內之真空壓實質上相同之狀態下開啟第3閘閥24,且藉由搬送機構42、43將寶 特瓶50連同壓板容器56一起自第1加載互鎖腔室4搬送於成膜腔室6。在寶特瓶50朝成膜腔室6之搬送完成後,封閉第3閘閥24。接著,寶特瓶50係如後述般在成膜腔室6內於真空壓下進行成膜處理。 The inside of the film forming chamber 6 is vacuum-treated in advance by the vacuum pump VP2, and a second vacuum pressure is formed in the film forming chamber 6. The third gate valve 24 is opened in a state where the vacuum pressures in the first load lock chamber 4 and the film forming chamber 6 are substantially the same, and the treasures are transferred by the transfer mechanisms 42 and 43. The special bottle 50 is carried together with the platen container 56 from the first loading lock chamber 4 to the film forming chamber 6. After the transfer of the PET bottle 50 to the film forming chamber 6 is completed, the third gate valve 24 is closed. Next, the PET bottle 50 is subjected to a film forming process under vacuum pressure in the film forming chamber 6 as will be described later.

經成膜處理之寶特瓶50係自成膜腔室6被搬送至第2加載互鎖腔室8。更具體而言,係藉由真空泵VP3將第2加載互鎖腔室8真空處理至上述第2真空壓,且於第2加載互鎖腔室8內形成與成膜腔室6實質上相同之真空度。於該狀態下開啟第4閘閥26,寶特瓶50係與壓板容器56一同藉由搬送機構43、44自成膜腔室6被移送至第2加載互鎖腔室8。此時,第2真空預備腔室10係藉由真空泵VP4真空處理至上述第3真空壓(第3真空壓>第1真空壓>第2真空壓)。當寶特瓶50朝第2加載互鎖腔室8之搬送完成時,封閉第4閘閥26,其後開啟第5閘閥28。其結果,使第2加載互鎖腔室8與第2真空預備腔室10連通,該等腔室8、10內之壓力成為第3真空壓與第2真空壓之中間壓力即第1真空壓。 The film-forming PET bottle 50 is transferred from the film forming chamber 6 to the second load lock chamber 8. More specifically, the second load lock chamber 8 is vacuum-treated to the second vacuum pressure by the vacuum pump VP3, and substantially the same as the film formation chamber 6 is formed in the second load lock chamber 8. Vacuum degree. When the fourth gate valve 26 is opened in this state, the PET bottle 50 is transferred from the film forming chamber 6 to the second load lock chamber 8 by the transfer mechanisms 43 and 44 together with the platen container 56. At this time, the second vacuum pre-chamber 10 is vacuum-treated by the vacuum pump VP4 to the third vacuum pressure (third vacuum pressure > first vacuum pressure > second vacuum pressure). When the transfer of the PET bottle 50 to the second load lock chamber 8 is completed, the fourth gate valve 26 is closed, and thereafter the fifth gate valve 28 is opened. As a result, the second load lock chamber 8 communicates with the second vacuum reserve chamber 10, and the pressure in the chambers 8 and 10 becomes the first vacuum pressure which is the intermediate pressure between the third vacuum pressure and the second vacuum pressure. .

在開啟第5閘閥28之期間,驅動搬送機構44、45而將寶特瓶50連同壓板容器56一起自第2加載互鎖腔室8搬送至第2真空預備腔室10。當寶特瓶50之搬送完成時,封閉第5閘閥28。其次,開啟大氣開放閥73,藉此將第2真空預備腔室10大氣開放。其後,開啟第6閘閥30,將寶特瓶50與壓板容器56一同自第2真空預備腔室10搬送至大氣空間。 While the fifth gate valve 28 is being opened, the transfer mechanisms 44 and 45 are driven to transport the PET bottle 50 together with the platen container 56 from the second load lock chamber 8 to the second vacuum reserve chamber 10. When the transfer of the PET bottle 50 is completed, the fifth gate valve 28 is closed. Next, the atmosphere opening valve 73 is opened, whereby the second vacuum pre-chamber 10 is opened to the atmosphere. Thereafter, the sixth gate valve 30 is opened, and the PET bottle 50 is transferred from the second vacuum preparation chamber 10 to the atmospheric space together with the platen container 56.

搬送至大氣空間之處理完畢之寶特瓶50係由未圖示之夾具搬送至搬出輸送機75。取出寶特瓶50後之壓板容器56係藉由提升式輸送機80而上升至搬送軌道82。提升式輸送機80具備固定於帶式輸送機之複數個掛鉤85,可將複數個壓板容器56連續地掛上掛鉤85且提升至搬送軌道82。 The processed bottle 50 that has been transported to the atmospheric space is transported to the carry-out conveyor 75 by a jig (not shown). The platen container 56 after the bottle 50 is taken out is raised to the transfer rail 82 by the lift conveyor 80. The lift conveyor 80 includes a plurality of hooks 85 fixed to the belt conveyor, and the plurality of platen containers 56 can be continuously hung on the hooks 85 and lifted to the transport rails 82.

搬送軌道82係一方面朝下方傾斜一方面自提升式輸送機80延伸至下降輸送機90。搬送軌道82具有複數個自由旋轉之滾筒87,壓板容器56係藉由其自身重量於複數個滾筒87上向下降輸送機90移動。於下 降輸送機90之前配置有擋止件89,藉由擋止件89使壓板容器56停止向下降輸送機90移動。擋止件89係以特定間隔將壓板容器56逐個抽出至下降輸送機90之方式構成。因此,複數個壓板容器56係以特定間隔藉由下降輸送機90下降,且載置於搬送機構40上。接著,將由搬入輸送機55搬送而來之下一個寶特瓶50載置於壓板容器56上。如此,在寶特瓶50之成膜後回收壓板容器56,且使用於後續之寶特瓶50之成膜步驟中。在本實施形態中,由提升式輸送機80、搬送軌道82、及下降輸送機90構成回收壓板容器56之回收機構。 The transport rail 82 is inclined downward on the one hand and extends from the lift conveyor 80 to the lower conveyor 90 on the one hand. The transport rail 82 has a plurality of freely rotatable drums 87 that are moved toward the descending conveyor 90 by a plurality of rollers 87 by their own weight. Under Before the down conveyor 90, a stopper 89 is disposed, and the stopper container 89 stops the movement of the platen container 56 toward the descending conveyor 90. The stopper 89 is configured to draw the platen containers 56 one by one to the lowering conveyor 90 at a specific interval. Therefore, the plurality of platen containers 56 are lowered by the descending conveyor 90 at a predetermined interval, and are placed on the conveying mechanism 40. Next, the next PET bottle 50 is carried by the carry-in conveyor 55 and placed on the platen container 56. Thus, the platen container 56 is recovered after the film formation of the PET bottle 50, and is used in the film forming step of the subsequent PET bottle 50. In the present embodiment, the lift conveyor 80, the conveyance rail 82, and the down conveyor 90 constitute a recovery mechanism for collecting the platen container 56.

先行之寶特瓶50係自第1真空預備腔室2被移送至第1加載互鎖腔室4,且在封閉第2閘閥22後,開啟大氣開放閥92,藉此將第1真空預備腔室2大氣開放。接著,將後續之寶特瓶50與壓板容器56一同搬入於第1真空預備腔室2內,重複上述步驟。 The first treasure special bottle 50 is transferred from the first vacuum preparation chamber 2 to the first load lock chamber 4, and after closing the second gate valve 22, the atmosphere open valve 92 is opened, thereby the first vacuum preparation chamber Room 2 is open to the atmosphere. Next, the subsequent PET bottle 50 is carried into the first vacuum preparation chamber 2 together with the platen container 56, and the above steps are repeated.

如圖5所示,第1真空預備腔室2係於自大氣壓到至少第1真空壓之壓力區域內予以真空處理,且第1加載互鎖腔室4係在自第1真空壓到第2真空壓(<第1真空壓)之壓力區域內予以真空處理。成膜腔室6始終維持於第2真空壓。如此般,藉由將第1真空預備腔室2及第1加載互鎖腔室4階段性地減壓,與將1個加載互鎖腔室設置於成膜腔室6之上游側之情形相比,可以更短之時間間隔將寶特瓶50搬送至成膜腔室6。因此,可縮短成膜之週期時間,而可提高產出量。 As shown in FIG. 5, the first vacuum pre-chamber 2 is vacuum-treated in a pressure region from atmospheric pressure to at least the first vacuum pressure, and the first load-lock chamber 4 is from the first vacuum to the second. Vacuum treatment is performed in the pressure region of the vacuum pressure (<1st vacuum pressure). The film forming chamber 6 is always maintained at the second vacuum pressure. In this manner, the first vacuum chamber 2 and the first load lock chamber 4 are stepped down in a stepwise manner, and the one load lock chamber is disposed on the upstream side of the film forming chamber 6. The PET bottle 50 can be transported to the film forming chamber 6 at a shorter time interval. Therefore, the cycle time of film formation can be shortened, and the throughput can be increased.

如圖6所示,第2真空預備腔室10係自大氣壓到至少第1真空壓之壓力區域內予以真空處理,且第2加載互鎖腔室8係在自第1真空壓到第2真空壓(<第1真空壓)之壓力區域內予以真空處理。如此般,藉由將第2加載互鎖腔室8及第2真空預備腔室10階段性地減壓,與將1個加載互鎖腔室設置於成膜腔室6之下游側之情形相比,可以更短之時間間隔將寶特瓶50自成膜腔室6搬出。因此,可縮短成膜之週期時間,而可提高產出量。 As shown in FIG. 6, the second vacuum pre-chamber 10 is vacuum-treated from atmospheric pressure to at least the first vacuum pressure, and the second load-lock chamber 8 is from the first vacuum to the second vacuum. Vacuum treatment is performed in the pressure region of the pressure (<1st vacuum pressure). In this manner, by gradually depressurizing the second load lock chamber 8 and the second vacuum reserve chamber 10, and placing one load lock chamber on the downstream side of the film forming chamber 6, In comparison, the PET bottle 50 can be carried out from the film forming chamber 6 at a shorter time interval. Therefore, the cycle time of film formation can be shortened, and the throughput can be increased.

其次,參照圖7說明成膜腔室6之構造。圖7係模式性顯示成膜腔室6之剖面之圖。如圖7所示,於成膜腔室6內配置有具備發熱體61及將原料氣體供給至寶特瓶50內之氣體供給管62之發熱體單元65。於發熱體單元65中自未圖示之電源供給電力,藉此使發熱體61發熱。另,發熱體之加熱係以通電加熱較為容易,因此,可使用較如電漿CVD法所使用之高頻電源及整合器之組合更為低價之交流或直流之電源。 Next, the configuration of the film forming chamber 6 will be described with reference to FIG. Fig. 7 is a view schematically showing a cross section of the film forming chamber 6. As shown in FIG. 7, a heating element unit 61 including a heating element 61 and a gas supply pipe 62 for supplying a material gas into the PET bottle 50 is disposed in the film forming chamber 6. Electric power is supplied from a power source (not shown) in the heating unit 65, whereby the heating element 61 generates heat. Further, since the heating of the heating element is facilitated by electric conduction, it is possible to use a combination of a high-frequency power source and an integrator used in the plasma CVD method to supply a lower-cost AC or DC power source.

所謂發熱體係其自身實質上不揮發,且可使原料氣體藉由觸媒化學反應及/或因熱而分解成化學物種之構件,例如,將鉭、碳化鉭、鎢、碳化鎢、鎳-鉻合金、或碳作為表層之主成分之導線。雖然在本實施形態中,針對16個寶特瓶50,配置有16組發熱體單元65(圖7中僅圖示有4組發熱體單元65),但發熱體單元65之配置數係可根據壓板容器56上之寶特瓶50之個數而適當變更。 The so-called heating system itself is substantially non-volatile, and the raw material gas can be decomposed into chemical species by chemical reaction of the catalyst and/or by heat, for example, niobium, tantalum carbide, tungsten, tungsten carbide, nickel-chromium. A wire that is an alloy or carbon as the main component of the surface layer. In the present embodiment, 16 sets of heating element units 65 are arranged for the 16 PET bottles 50 (only four sets of heating elements 65 are illustrated in FIG. 7), but the number of the heating elements 65 can be configured according to The number of the PET bottles 50 on the platen container 56 is appropriately changed.

搬送至成膜腔室6內之寶特瓶50係藉由升降機構69與壓板容器56一同上升。升降機構69具備載置壓板容器56之支持台67、對支持台67進行支持之支持軸70、及連結於支持軸70之升降用馬達71。於支持軸70貫通成膜腔室6之部分,配置有未圖示之密封構件。藉由驅動升降用馬達71,而使支持台67升降,且使載置於支持台67上之壓板容器56及保持於壓板容器56之寶特瓶50升降。 The PET bottle 50 conveyed into the film forming chamber 6 is lifted together with the platen container 56 by the elevating mechanism 69. The elevating mechanism 69 includes a support base 67 on which the platen container 56 is placed, a support shaft 70 that supports the support base 67, and a lift motor 71 that is coupled to the support shaft 70. A sealing member (not shown) is disposed in a portion of the support shaft 70 that penetrates the film forming chamber 6. By driving the lifting motor 71, the support table 67 is moved up and down, and the platen container 56 placed on the support table 67 and the PET bottle 50 held by the platen container 56 are lifted and lowered.

對寶特瓶50之成膜進行說明。與開始封閉第3閘閥24同時,利用升降機構69使壓板容器56及寶特瓶50上升,且如圖7所示,將發熱體61及氣體供給管62插入於載置於壓板容器56上之寶特瓶50內。接著,自氣體供給管62於寶特瓶50內供給原料氣體,且於發熱體61中流通電流。藉此,發熱體61成為高溫,從而發熱體61成為熱觸媒體。自氣體供給管62吹出之原料氣體與成為熱觸媒體之發熱體61接觸,且藉由觸媒化學反應及/或因熱而分解成化學物種。該化學物種到達寶特瓶50之內表面,且於寶特瓶50之內表面形成薄膜。特定膜厚之薄膜成膜於 寶特瓶50之內表面後,藉由升降機構69使壓板容器56及寶特瓶50下降。 The film formation of the PET bottle 50 will be described. At the same time as the closing of the third gate valve 24, the platen container 56 and the PET bottle 50 are raised by the elevating mechanism 69, and as shown in Fig. 7, the heating element 61 and the gas supply pipe 62 are inserted into the platen container 56. Baote bottle 50 inside. Next, the material gas is supplied from the gas supply pipe 62 in the PET bottle 50, and an electric current flows through the heating element 61. Thereby, the heating element 61 becomes a high temperature, and the heating element 61 becomes a thermal contact medium. The material gas blown from the gas supply pipe 62 is in contact with the heat generating body 61 serving as a heat contact medium, and is decomposed into chemical species by catalytic reaction of the catalyst and/or by heat. The chemical species reaches the inner surface of the PET bottle 50 and forms a film on the inner surface of the PET bottle 50. a film of a specific film thickness is formed on the film After the inner surface of the bottle 50, the platen container 56 and the PET bottle 50 are lowered by the lifting mechanism 69.

各寶特瓶50係藉由利用升降機構69,以預先設定之速度上升、下降,而將各發熱體61於各寶特瓶50內插入、拔出。成膜時,亦可調整使寶特瓶50升降之升降速度。藉由此種構成,可根據容器形狀、容器耐熱特性、或對容器所要求之性能,調整容器各部分之成膜時間,從而容易調整阻隔性能或容器外觀。亦可代替寶特瓶50,利用未圖示之升降機構使發熱體61升降,藉此將發熱體61針對寶特瓶50進行插入及拔出。 Each of the PET bottles 50 is inserted into and removed from each of the PET bottles 50 by the elevating mechanism 69 at a predetermined speed. At the time of film formation, the lifting speed of the lifting and lowering of the bottle 50 can also be adjusted. According to this configuration, the film formation time of each part of the container can be adjusted according to the shape of the container, the heat resistance of the container, or the performance required for the container, so that the barrier property or the appearance of the container can be easily adjusted. Instead of the PET bottle 50, the heating element 61 can be moved up and down by a lifting mechanism (not shown), whereby the heating element 61 can be inserted and removed for the PET bottle 50.

藉由將發熱體61配置於寶特瓶50之外側,亦可同樣於寶特瓶50之外表面形成薄膜。再者,藉由將發熱體61配置於寶特瓶50之內側及外側,亦可於寶特瓶50之內表面及外表面之兩者形成薄膜。 By disposing the heating element 61 on the outer side of the PET bottle 50, a film can be formed on the outer surface of the PET bottle 50 as well. Further, by disposing the heating element 61 inside and outside the PET bottle 50, a film can be formed on both the inner surface and the outer surface of the PET bottle 50.

根據本發明,配置有發熱體61之成膜腔室6內始終保持為真空壓。因此,可防止發熱體61劣化,從而發熱體61之成膜功能不會降低。 According to the present invention, the inside of the film forming chamber 6 in which the heat generating body 61 is disposed is always maintained at a vacuum pressure. Therefore, deterioration of the heat generating body 61 can be prevented, and the film forming function of the heat generating body 61 is not lowered.

以下,參照圖8至圖13說明本發明之第2實施形態之薄膜之成膜裝置之實施形態。另,在圖8至圖13中,對相同或相當之構成要件標註相同符號且省略重複說明。 Hereinafter, an embodiment of a film forming apparatus for a film according to a second embodiment of the present invention will be described with reference to Figs. 8 to 13 . In the drawings, the same or corresponding components are denoted by the same reference numerals and the description thereof will not be repeated.

圖8係顯示本發明之第2實施形態之薄膜之成膜裝置之整體構成之俯視圖。圖9係圖8之IX-IX線剖面圖。如圖8所示,薄膜之成膜裝置101設置於投入寶特瓶50作為處理對象之容器之瓶投入用輸送機(搬入輸送機)103、與排出處理完畢之寶特瓶50之瓶排出用輸送機(搬出輸送機)104之間。 Fig. 8 is a plan view showing the overall configuration of a film forming apparatus for a film according to a second embodiment of the present invention. Figure 9 is a cross-sectional view taken along line IX-IX of Figure 8. As shown in Fig. 8, the film forming apparatus 101 for a film is placed in a bottle-input conveyor (loading conveyor) 103 into which the container 50 is to be processed, and a bottle for discharge of the bottle 50 which has been discharged. Between the conveyors (out of the conveyor) 104.

為達成較高之處理能力,例如每分鐘600個之處理能力,薄膜之成膜裝置101構成為使用可收納多個寶特瓶50、例如8個~64個寶特瓶之壓板容器56,且使收納有多個寶特瓶50之壓板容器56於裝置內移動 而進行成膜處理。在本實施形態中,壓板容器56可收納28個(4行×7列)寶特瓶50。壓板容器56構成用以將複數個寶特瓶50搬出入真空腔室且對複數個寶特瓶50實施成膜處理之處理容器。 In order to achieve a higher processing capacity, for example, a processing capacity of 600 per minute, the film forming apparatus 101 of the film is configured to use a platen container 56 that can accommodate a plurality of PET bottles 50, for example, 8 to 64 PET bottles, and The platen container 56 containing the plurality of PET bottles 50 is moved inside the device The film formation process is performed. In the present embodiment, the platen container 56 can accommodate 28 (4 rows x 7 columns) PET bottles 50. The platen container 56 constitutes a processing container for carrying out a plurality of PET bottles 50 into the vacuum chamber and performing a film forming process on the plurality of PET bottles 50.

如圖8及圖9所示,薄膜之成膜裝置101包含:成膜單元110,其配置於中央部且用以對寶特瓶50實施成膜處理;與搬出入單元130、130,其配置於成膜單元110左右,用以將未處理之寶特瓶50搬入於成膜單元110,且自成膜單元110搬出處理完畢之寶特瓶50。因左右之搬出入單元130、130為相同構成,故以下僅說明右側之搬出入單元130。 As shown in FIGS. 8 and 9, the film forming apparatus 101 includes a film forming unit 110 disposed at a central portion and configured to perform a film forming process on the PET bottle 50, and a loading/unloading unit 130 and 130. To the left and right of the film forming unit 110, the untreated PET bottle 50 is carried into the film forming unit 110, and the processed PET bottle 50 is carried out from the film forming unit 110. Since the left and right loading and unloading units 130 and 130 have the same configuration, only the right loading and unloading unit 130 will be described below.

如圖8所示,搬出入單元130包含鄰接於瓶投入用輸送機103所配置之供給單元131、鄰接於瓶排出用輸送機104所配置之排出單元133、及配置於供給單元131與排出單元133之間之中間單元132。供給單元131可載置並列之複數個壓板容器56。在本實施形態中,於供給單元131上載置3個壓板容器56。於供給單元131上之複數個壓板容器56中,藉由投入機構(未圖示)依序裝入瓶投入用輸送機103上之寶特瓶50。當於供給單元131上之全部壓板容器56中裝入特定數量(28個)之寶特瓶50時,供給單元131將複數個壓板容器56交付於中間單元132。 As shown in FIG. 8, the carry-in/out unit 130 includes a supply unit 131 disposed adjacent to the bottle insertion conveyor 103, a discharge unit 133 disposed adjacent to the bottle discharge conveyor 104, and a supply unit 131 and a discharge unit. Intermediate unit 132 between 133. The supply unit 131 can mount a plurality of platen containers 56 juxtaposed. In the present embodiment, three platen containers 56 are placed on the supply unit 131. The plurality of platen containers 56 on the supply unit 131 are sequentially loaded into the bottle 50 of the bottle feeding conveyor 103 by an input mechanism (not shown). When a specific number (28) of PET bottles 50 are loaded into all of the platen containers 56 on the supply unit 131, the supply unit 131 delivers a plurality of platen containers 56 to the intermediate unit 132.

上述中間單元132可載置並列之複數個壓板容器56,在本實施形態中,於中間單元132上載置3個壓板容器56。中間單元132係將自供給單元131所接收之複數個壓板容器56供給至成膜單元110。又,中間單元132係自成膜單元110接收收納有成膜單元110中所成膜之處理完畢之寶特瓶50之複數個壓板容器56,且將所接收之複數個壓板容器56交付於排出單元133。排出單元133可載置並列之複數個壓板容器56,在本實施形態中,於排出單元133上載置3個壓板容器56。收納於載置於排出單元133之壓板容器56中之特定數量(28個)之處理完畢之寶特 瓶50係藉由排出機構(未圖示)依序排出至瓶排出用輸送機104。另,瓶投入用輸送機103(搬入輸送機)與瓶排出用輸送機(搬出輸送機)104較佳為分別包含對應於左側之搬出入單元130之輸送機、及對應於右側之搬出入單元130之輸送機之2個輸送機。 The intermediate unit 132 can mount a plurality of platen containers 56 arranged in parallel. In the present embodiment, three platen containers 56 are placed on the intermediate unit 132. The intermediate unit 132 supplies a plurality of platen containers 56 received from the supply unit 131 to the film forming unit 110. Further, the intermediate unit 132 receives a plurality of platen containers 56 containing the processed PET bottles 50 formed in the film forming unit 110 from the film forming unit 110, and delivers the received plurality of platen containers 56 to the discharge. Unit 133. The discharge unit 133 can mount a plurality of platen containers 56 arranged in parallel. In the present embodiment, three platen containers 56 are placed on the discharge unit 133. The specified number (28) of the processed pouches contained in the platen container 56 placed in the discharge unit 133 The bottle 50 is sequentially discharged to the bottle discharge conveyor 104 by a discharge mechanism (not shown). Further, the bottle insertion conveyor 103 (loading conveyor) and the bottle discharging conveyor (loading conveyor) 104 preferably include a conveyor corresponding to the left loading and unloading unit 130 and a loading and unloading unit corresponding to the right side. Two conveyors for the 130 conveyor.

如圖8及圖9所示,成膜單元110包含複數個成膜單元,在本實施形態中,為可將自供給單元131所接收之3個壓板容器56內所收納之各28個寶特瓶50同時進行成膜處理,而包含3組成膜單元110A、110B、110C。因3組成膜單元110A、110B、110C包含相同構成之真空腔室,故以下僅說明成膜單元110B(圖9中虛線所包圍之單元)。 As shown in FIGS. 8 and 9, the film forming unit 110 includes a plurality of film forming units. In the present embodiment, each of the 28 platen containers 56 received in the three platen containers 56 received from the supply unit 131 can be accommodated. The bottle 50 is simultaneously subjected to a film forming process, and includes three constituent film units 110A, 110B, and 110C. Since the three constituent film units 110A, 110B, and 110C include the vacuum chamber having the same configuration, only the film forming unit 110B (the unit surrounded by the broken line in Fig. 9) will be described below.

圖10係顯示成膜單元110B之細節之模式性剖面圖。如圖10所示,成膜單元110B具備成膜腔室6與瓶待機用腔室112之2個腔室。成膜腔室6配置於上側,瓶待機用腔室112配置於下側。成膜腔室6與瓶待機用腔室112係經由閘閥123連結。瓶待機用腔室112構成連通於成膜腔室6,且內部被真空處理之閘極腔室。 Fig. 10 is a schematic cross-sectional view showing the details of the film forming unit 110B. As shown in FIG. 10, the film forming unit 110B includes two chambers of the film forming chamber 6 and the bottle standby chamber 112. The film forming chamber 6 is disposed on the upper side, and the bottle standby chamber 112 is disposed on the lower side. The film forming chamber 6 and the bottle standby chamber 112 are coupled via a gate valve 123. The bottle standby chamber 112 constitutes a gate chamber that communicates with the film forming chamber 6 and is internally vacuum-treated.

成膜腔室6經由連結部6a而連結於作為真空排氣機構之真空泵VP5,成膜腔室6內係由真空泵VP5進行真空處理。於成膜腔室6內,為了可同時對收納於壓板容器56之多個寶特瓶50進行成膜處理,而配置有多個具備線狀之發熱體61之發熱體單元65。線狀之發熱體之基部包含未圖示之銅製棒狀構件,採用在發熱體61發熱時實質上不會被加熱之構成。於發熱體單元65中自未圖示之電源供給電力,藉此使發熱體61發熱。另,發熱體之加熱係以通電加熱較為容易,因此,可使用較電漿CVD法所使用之高頻電源及整合器之組合更為低價之交流或直流電源。各發熱體61係插入於成膜腔室6內保持為直立狀態之各寶特瓶50內。在本實施形態中,配置有28個發熱體單元65,於成膜腔室6內,可進行收納於壓板容器56之總計28個寶特瓶50之成膜處理。 The film forming chamber 6 is connected to a vacuum pump VP5 as a vacuum exhausting mechanism via a connecting portion 6a, and the inside of the film forming chamber 6 is vacuum-treated by a vacuum pump VP5. In the film forming chamber 6, in order to simultaneously form a film forming process on the plurality of PET bottles 50 accommodated in the platen container 56, a plurality of heat generating units 65 including the linear heating elements 61 are disposed. The base of the linear heating element includes a copper rod-shaped member (not shown), and is configured to be substantially not heated when the heating element 61 generates heat. Electric power is supplied from a power source (not shown) in the heating unit 65, whereby the heating element 61 generates heat. Further, since the heating of the heating element is facilitated by electric conduction, it is possible to use a combination of a high-frequency power source and an integrator used in the plasma CVD method, and a lower-cost AC or DC power source. Each of the heating elements 61 is inserted into each of the PET bottles 50 which are held in the film forming chamber 6 in an upright state. In the present embodiment, 28 heat generating unit 65s are disposed, and in the film forming chamber 6, a total of 28 PET bottles 50 accommodated in the platen container 56 can be formed.

又,瓶待機用腔室112係經由連結部112a而連結於作為真空排氣 機構之真空泵VP6,瓶待機用腔室112內係由真空泵VP6進行真空處理。 Further, the bottle standby chamber 112 is connected to the vacuum exhaust via the connecting portion 112a. The vacuum pump VP6 of the mechanism and the chamber standby chamber 112 are vacuum-treated by a vacuum pump VP6.

在圖10所示之狀態下,瓶待機用腔室112之下表面係開放,於瓶待機用腔室112之下方設置有構成為可藉由升降機113升降之平板114。藉由利用升降機113使平板114上升來封閉瓶待機用腔室112之下端開口,可密閉瓶待機用腔室112內,平板114成為腔室下表面。另,於平板114之上表面設置有O型環等之密封構件(未圖示),在平板114封閉瓶待機用腔室112內之下端開口時,氣密地保持瓶待機用腔室112。 In the state shown in FIG. 10, the lower surface of the bottle standby chamber 112 is opened, and a flat plate 114 configured to be lifted and lowered by the elevator 113 is provided below the bottle standby chamber 112. By opening the lower end of the bottle standby chamber 112 by raising the flat plate 114 by the lifter 113, the inside of the bottle standby chamber 112 can be sealed, and the flat plate 114 becomes the lower surface of the chamber. Further, a sealing member (not shown) such as an O-ring is provided on the upper surface of the flat plate 114, and when the flat plate 114 closes the lower end opening in the bottle standby chamber 112, the bottle standby chamber 112 is hermetically held.

於成為上述腔室下表面之平板114之上表面設置有升降台115,於升降台115上載置有收納有寶特瓶50之壓板容器56。升降台115藉由利用升降機113使平板114升降,而可與平板114一體化升降,又,升降台115構成為與平板114獨立而可單獨升降。即,升降機113具備二重升降機構,藉由使第1升降機構作動,可使平板114與升降台115一同升降,藉由使第2升降機構作動,可使升降台115單獨升降。另,雖然第2升降機構之升降軸貫通平板114,但於該貫通部分設置有密封機構,故平板114可氣密地維持瓶待機用腔室112。 A lifting table 115 is provided on the upper surface of the flat plate 114 which is the lower surface of the chamber, and a platen container 56 in which the PET bottle 50 is housed is placed on the lifting table 115. The elevating table 115 can be lifted and lowered integrally with the flat plate 114 by lifting and lowering the flat plate 114 by the lifter 113. Further, the elevating table 115 can be independently moved up and down independently of the flat plate 114. In other words, the lifter 113 is provided with a double lifting mechanism. By actuating the first elevating mechanism, the flat plate 114 can be moved up and down together with the elevating table 115, and the elevating table 115 can be moved up and down by the second elevating mechanism. Further, although the elevating shaft of the second elevating mechanism passes through the flat plate 114, a sealing mechanism is provided in the penetrating portion, so that the flat plate 114 can airtightly maintain the bottle standby chamber 112.

參照圖11A至圖11C說明如圖10所示般構成之成膜單元之動作。 The operation of the film forming unit configured as shown in Fig. 10 will be described with reference to Figs. 11A to 11C.

如圖11A所示,成膜腔室6內始終為真空狀態,且位於成膜腔室6內之發熱體61始終以真空狀態予以保持。此時,將作為成膜腔室6與瓶待機用腔室112間之真空隔離機構之閘閥123設為閉合狀態,切斷成膜腔室6與瓶待機用腔室112之連通。收納有多個寶特瓶50之壓板容器56係自中間單元132被供給至成膜單元110B之升降台115上。此時,瓶待機用腔室112之下表面係開放。 As shown in Fig. 11A, the inside of the film forming chamber 6 is always in a vacuum state, and the heat generating body 61 located in the film forming chamber 6 is always held in a vacuum state. At this time, the gate valve 123, which is a vacuum isolation mechanism between the film forming chamber 6 and the bottle standby chamber 112, is closed, and the film forming chamber 6 is disconnected from the bottle standby chamber 112. The platen container 56 in which the plurality of PET bottles 50 are housed is supplied from the intermediate unit 132 to the lifting table 115 of the film forming unit 110B. At this time, the lower surface of the bottle standby chamber 112 is open.

其次,使升降機113之第1升降機構作動而使第1升降軸121上升,且使平板114與載置有壓板容器56之升降台115一同上升,並如圖11B 所示,藉由利用平板114閉塞瓶待機用腔室112之下端開口而密封瓶待機用腔室112內。藉此,將位於升降台115上且收納有多個寶特瓶50之壓板容器56配置於瓶待機用腔室112內。於該狀態下,使真空泵VP6作動而開始瓶待機用腔室112內之真空處理。 Next, the first elevating mechanism of the elevator 113 is actuated to raise the first elevating shaft 121, and the flat plate 114 is raised together with the elevating table 115 on which the platen container 56 is placed, as shown in Fig. 11B. As shown, the inside of the bottle standby chamber 112 is sealed by closing the lower end opening of the bottle standby chamber 112 by the flat plate 114. Thereby, the platen container 56 which is located in the elevating table 115 and accommodates the plurality of PET bottles 50 is placed in the bottle standby chamber 112. In this state, the vacuum pump VP6 is actuated to start the vacuum processing in the bottle standby chamber 112.

藉由真空泵VP6之作動,瓶待機用腔室112內較成膜腔室6內之真空壓要低,在成為特定真空壓時,開啟閘閥123,使成膜腔室6與瓶待機用腔室112連通。藉此,瓶待機用腔室112內之真空壓上升,成為與成膜腔室6內之真空壓相等。因此,可縮短瓶待機用腔室112之真空處理時間。 By the action of the vacuum pump VP6, the vacuum pressure in the bottle standby chamber 112 is lower than that in the film forming chamber 6. When the specific vacuum pressure is reached, the gate valve 123 is opened to make the film forming chamber 6 and the bottle standby chamber. 112 connected. Thereby, the vacuum pressure in the bottle standby chamber 112 rises to be equal to the vacuum pressure in the film forming chamber 6. Therefore, the vacuum processing time of the bottle standby chamber 112 can be shortened.

其次,如圖11C所示,使升降機113之第2升降機構作動而使第2升降軸122上升,且使載置有壓板容器56之升降台115單獨上升,而將收納有多個寶特瓶50之壓板容器56供給至成膜腔室6內。當升降台115上升至特定位置時,各發熱體61成為插入於各寶特瓶50內之狀態。各寶特瓶50藉由利用升降台115以預先設定之速度上升、下降,而將各發熱體61於各寶特瓶50內插入、拔出。 Next, as shown in FIG. 11C, the second elevating mechanism of the elevator 113 is actuated to raise the second elevating shaft 122, and the elevating table 115 on which the platen container 56 is placed is separately raised, and a plurality of PET bottles are accommodated. A platen container 56 of 50 is supplied into the film forming chamber 6. When the elevating table 115 is raised to a specific position, each of the heating elements 61 is inserted into each of the PET bottles 50. Each of the PET bottles 50 is inserted and removed in each of the PET bottles 50 by raising and lowering at a predetermined speed by the lifting table 115.

圖12係顯示升降台115上升至特定位置且將發熱體61插入於收納於壓板容器56之寶特瓶50內之狀態之模式性剖面圖。在圖12中,藉由升降台115之上升、下降,發熱體單元65之發熱體61及氣體供給管62成為插入於寶特瓶50內之狀態。在上述之插入、拔出步驟之期間,成膜腔室6內達到可成膜之真空壓,自氣體供給管62朝寶特瓶50內供給原料氣體且於發熱體61中流通電流。藉此,發熱體61成為高溫,發熱體61成為熱觸媒體。自氣體供給管62吹出之原料氣體與成為熱觸媒體之發熱體61接觸,藉由觸媒化學反應及/或因熱而分解成化學物種。該化學物種到達寶特瓶50之內表面,且於寶特瓶50之內表面形成薄膜。特定膜厚之薄膜成膜於寶特瓶50之內表面後,完成成膜。 FIG. 12 is a schematic cross-sectional view showing a state in which the elevating table 115 is raised to a specific position and the heating element 61 is inserted into the PET bottle 50 housed in the platen container 56. In FIG. 12, the heating element 61 and the gas supply pipe 62 of the heating unit 65 are inserted into the PET bottle 50 by the raising and lowering of the lifting table 115. During the above-described insertion and extraction steps, the film forming chamber 6 reaches a vacuum pressure at which film formation is possible, and the material gas is supplied from the gas supply pipe 62 into the PET bottle 50, and a current flows through the heating element 61. Thereby, the heating element 61 becomes a high temperature, and the heating element 61 becomes a thermal contact medium. The material gas blown from the gas supply pipe 62 is brought into contact with the heat generating body 61 serving as a heat contact medium, and is decomposed into chemical species by catalytic reaction of the catalyst and/or by heat. The chemical species reaches the inner surface of the PET bottle 50 and forms a film on the inner surface of the PET bottle 50. After a film having a specific film thickness is formed on the inner surface of the PET bottle 50, film formation is completed.

根據本發明,藉由設為可調整使寶特瓶50升降之升降速度之構 成,可根據容器形狀、容器耐熱特性、或對容器所要求之性能,調整容器各部分之成膜時間,從而容易調整阻隔性能或容器外觀。 According to the present invention, it is set to adjust the height of the lifting and lowering of the PET bottle 50 The film formation time of each part of the container can be adjusted according to the shape of the container, the heat resistance of the container, or the performance required for the container, so that the barrier property or the appearance of the container can be easily adjusted.

其次,使升降機113之第2升降機構作動而使第2升降軸122下降,自成膜腔室6取出收納有處理完畢之寶特瓶50之壓板容器56且返回瓶待機用腔室112後,封閉閘閥123。該狀態係除了未處理之寶特瓶50變為處理完畢之寶特瓶50之點外,與圖11B所示之狀態相同。其後,使設置於瓶待機用腔室112之未圖示之真空破壞閥(大氣開放閥)作動而將瓶待機用腔室112內大氣開放。此時,成膜腔室6內始終為真空狀態,且位於成膜腔室6內之發熱體61始終以真空狀態予以保持。 Then, the second elevating mechanism 122 of the elevator 113 is actuated to lower the second elevating shaft 122, and the platen container 56 containing the processed PET bottle 50 is taken out from the film forming chamber 6 and returned to the bottle standby chamber 112. The gate valve 123 is closed. This state is the same as that shown in Fig. 11B except that the untreated PET bottle 50 becomes the treated PET bottle 50. Thereafter, a vacuum break valve (atmospheric open valve) (not shown) provided in the bottle standby chamber 112 is actuated to open the atmosphere in the bottle standby chamber 112. At this time, the inside of the film forming chamber 6 is always in a vacuum state, and the heat generating body 61 located in the film forming chamber 6 is always held in a vacuum state.

其次,使升降機113之第1升降機構作動而使第1升降軸121下降,且使平板114與載置有壓板容器56之升降台115一同下降,並自瓶待機用腔室112取出處理完畢之寶特瓶50。該狀態係除了未處理之寶特瓶50變為處理完畢之寶特瓶50之點外,與圖11A所示之狀態相同。其次,將收納有處理完畢之寶特瓶50之壓板容器56自升降台115抽出至搬出入單元130之中間單元132。接著,將收納有新寶特瓶50之壓板容器56自中間單元132供給至升降台115上。在將壓板容器56供給至升降台115上之後,重複進行上述之寶特瓶50之朝成膜腔室6之搬入步驟及寶特瓶50之成膜步驟。 Then, the first elevating mechanism of the lifter 113 is actuated to lower the first elevating shaft 121, and the flat plate 114 is lowered together with the elevating table 115 on which the platen container 56 is placed, and is taken out from the bottle standby chamber 112. Baote bottle 50. This state is the same as that shown in Fig. 11A except that the untreated PET bottle 50 becomes the treated PET bottle 50. Next, the platen container 56 containing the processed PET bottle 50 is taken out from the lifting table 115 to the intermediate unit 132 of the loading and unloading unit 130. Next, the platen container 56 containing the new PET bottle 50 is supplied from the intermediate unit 132 to the lifting table 115. After the platen container 56 is supplied onto the elevating table 115, the step of carrying in the film forming chamber 6 of the above-described PET bottle 50 and the film forming step of the PET bottle 50 are repeated.

其次,參照圖13說明如圖8至圖12所示般構成之薄膜之成膜裝置之整體動作。 Next, the overall operation of the film forming apparatus of the film configured as shown in Figs. 8 to 12 will be described with reference to Fig. 13 .

圖13係顯示薄膜之成膜裝置101中之處理對象之寶特瓶50之流動之模式性俯視圖。因左右之搬出入單元130、130進行相同之動作,故以下主要說明右側之搬出入單元130之動作。如圖13所示,處理對象之寶特瓶50係由瓶投入用輸送機103朝箭頭符號A方向列狀地搬送。此時,於供給單元131上載置有3個空的壓板容器56。瓶投入用輸送機103上之寶特瓶50係如箭頭符號1所示,由投入機構(未圖示)依序裝入 於供給單元131上之壓板容器56。 Fig. 13 is a schematic plan view showing the flow of the PET bottle 50 to be processed in the film forming apparatus 101 of the film. Since the left and right loading and unloading units 130 and 130 perform the same operation, the operation of the loading/unloading unit 130 on the right side will be mainly described below. As shown in FIG. 13, the bottle 50 to be processed is conveyed in the direction of the arrow symbol A by the bottle insertion conveyor 103. At this time, three empty platen containers 56 are placed on the supply unit 131. The bottle 50 on the bottle feeding conveyor 103 is sequentially loaded by an input mechanism (not shown) as indicated by an arrow symbol 1 The platen container 56 on the supply unit 131.

當於供給單元131上之全部壓板容器56中裝入特定數量(28個)之寶特瓶50時,供給單元131係如箭頭符號2所示,將3個壓板容器56交付於中間單元132。中間單元132係如箭頭符號3所示,將自供給單元131所接收之3個壓板容器56搬入於成膜單元110A、110B、110C。在成膜單元110A、110B、110C中,實施圖11A~圖11C所示之成膜步驟,將特定膜厚之薄膜成膜於分別收納於3個壓板容器56之28個寶特瓶50之內表面。 When a specific number (28) of PET bottles 50 are loaded into all of the platen containers 56 on the supply unit 131, the supply unit 131 delivers the three platen containers 56 to the intermediate unit 132 as indicated by the arrow 2. The intermediate unit 132 carries the three platen containers 56 received from the supply unit 131 into the film forming units 110A, 110B, and 110C as indicated by an arrow symbol 3. In the film forming units 110A, 110B, and 110C, the film forming steps shown in FIGS. 11A to 11C are performed, and a film having a specific film thickness is formed into 28 pieces of the PET bottles 50 housed in the three platen containers 56, respectively. surface.

成膜完成後,中間單元132係如箭頭符號4所示,自成膜單元110A、110B、110C接收收納有處理完畢之寶特瓶50之3個壓板容器56。自成膜單元110A、110B、110C搬出收納有處理完畢之寶特瓶50之3個壓板容器56後,如箭頭符號5所示,將收納有未處理之寶特瓶50之3個壓板容器56自左側之搬出入單元130之中間單元132搬入於成膜單元110A、110B、110C。收納有於成膜單元110A、110B、110C中經完成成膜處理之寶特瓶50之3個壓板容器56係抽出至左側之搬出入單元130之中間單元132。即,於成膜單元110A、110B、110C中,自左右之搬出入單元130、130交替地搬入收納有未處理之寶特瓶50之3個壓板容器56。 After the film formation is completed, the intermediate unit 132 receives the three platen containers 56 in which the processed PET bottles 50 are housed from the film forming units 110A, 110B, and 110C as indicated by the arrow symbol 4. After the film forming units 110A, 110B, and 110C carry out the three platen containers 56 in which the processed PET bottles 50 are stored, as shown by the arrow 5, the three platen containers 56 in which the untreated PET bottles 50 are accommodated are placed. The intermediate unit 132 from the loading/unloading unit 130 on the left side is carried into the film forming units 110A, 110B, and 110C. The three platen containers 56 that house the PET bottles 50 that have been subjected to the film forming process in the film forming units 110A, 110B, and 110C are taken out to the intermediate unit 132 of the loading/unloading unit 130 on the left side. In other words, in the film forming units 110A, 110B, and 110C, the three platen containers 56 in which the untreated PET bottles 50 are accommodated are alternately carried in from the left and right loading and unloading units 130 and 130.

一方面,右側之搬出入單元130之中間單元132係如箭頭符號6所示,將收納有處理完畢之寶特瓶50之3個壓板容器56交付於排出單元133。收納於載置於排出單元133之3個壓板容器56之寶特瓶50係如箭頭符號7所示,由排出機構(未圖示)依序排出至瓶排出用輸送機104。瓶排出用輸送機104係朝箭頭符號B方向列狀地搬送處理完畢之寶特瓶50。 On the other hand, the intermediate unit 132 of the loading/unloading unit 130 on the right side is delivered to the discharge unit 133 by the three pressure plate containers 56 in which the processed PET bottles 50 are stored, as indicated by the arrow symbol 6. The PET bottle 50 accommodated in the three platen containers 56 placed in the discharge unit 133 is sequentially discharged to the bottle discharge conveyor 104 by a discharge mechanism (not shown) as indicated by an arrow 7 . The bottle discharge conveyor 104 conveys the processed PET bottle 50 in the direction of the arrow symbol B.

如上所述,在圖8至圖13所示之薄膜之成膜裝置101中,可使複數個寶特瓶50排列於壓板容器56,且將收納有所排列之複數個寶特瓶 50之壓板容器56作為1個單元朝成膜單元110A、110B、110C搬入、搬出及進行成膜單元110A、110B、110C中之成膜處理。藉由如此般使用壓板容器56對複數個寶特瓶50進行單元管理,可正確且容易進行複數個寶特瓶50之定位。在本實施形態中,可將收納有28個寶特瓶50之壓板容器56作為1個單元,且將3個單元(=84個)作為一組而進行移送(搬入、搬出)及成膜處理。 As described above, in the film forming apparatus 101 of the film shown in FIGS. 8 to 13, a plurality of PET bottles 50 can be arranged in the platen container 56, and a plurality of PET bottles arranged in a row can be accommodated. The platen container 56 of 50 is carried into and out of the film forming units 110A, 110B, and 110C as one unit, and the film forming process in the film forming units 110A, 110B, and 110C is performed. By unit management of a plurality of PET bottles 50 by using the platen container 56 as described above, the positioning of the plurality of PET bottles 50 can be performed accurately and easily. In the present embodiment, the platen container 56 in which the 28 PET bottles 50 are accommodated can be used as one unit, and three units (=84 units) can be transferred (loaded in and out) and film-formed as a group. .

藉由於成膜單元110A、110B、110C之兩側配置搬出入單元130,可自2個搬出入單元130將上述3個單元(=84個)交替地搬入、搬出成膜單元110A、110B、110C。藉此,成膜單元110A、110B、110C幾乎不存在等待時間,可使成膜單元110A、110B、110C大致連續地運轉。又,因寶特瓶50朝壓板容器56之裝入、抽出及收納有寶特瓶50之壓板容器56之移送可於成膜單元110A、110B、110C內寶特瓶50之成膜步驟中進行,故成膜單元110A、110B、110C幾乎不存在等待時間,可使成膜單元110A、110B、110C大致連續地運轉。 By arranging the carry-in/out unit 130 on both sides of the film forming units 110A, 110B, and 110C, the three units (=84) can be alternately carried in and out of the film forming units 110A, 110B, and 110C from the two loading/unloading units 130. . Thereby, the film forming units 110A, 110B, and 110C have almost no waiting time, and the film forming units 110A, 110B, and 110C can be operated substantially continuously. Further, the transfer of the platen container 56 into which the PET bottle 50 is loaded, withdrawn, and stored with the PET bottle 50 can be carried out in the film forming step of the PET bottle 50 in the film forming units 110A, 110B, and 110C. Therefore, there is almost no waiting time for the film forming units 110A, 110B, and 110C, and the film forming units 110A, 110B, and 110C can be operated substantially continuously.

藉由利用外部設置之升降機升降平板114,可將收納有寶特瓶50之壓板容器56搬出入各成膜單元(真空腔室)110A、110B、110C。藉由如此般使升降機位於真空腔室之外部,可使真空腔室最小化,而可縮短真空處理時間。 The platen container 56 in which the PET bottle 50 is accommodated can be carried out into the respective film forming units (vacuum chambers) 110A, 110B, and 110C by the elevator lifting plate 114 provided outside. By thus positioning the elevator outside of the vacuum chamber, the vacuum chamber can be minimized and the vacuum processing time can be shortened.

又,於真空腔室中,藉由使經載置收納有多個寶特瓶50之壓板容器56之平板114上升,可將真空腔室設為密閉狀態。即,因平板自身發揮開關閘之作用,故可抑制無用裝置,而可使成膜裝置小型化且可降低裝置成本。 Further, in the vacuum chamber, the vacuum chamber can be sealed by raising the flat plate 114 on which the platen container 56 in which the plurality of PET bottles 50 are placed. In other words, since the flat plate itself functions as a switch gate, the useless device can be suppressed, and the film forming apparatus can be downsized and the device cost can be reduced.

至此雖已對本發明之實施形態進行說明,但本發明並未限定於上述實施形態,當然亦可在其技術思想之範圍內以多種不同之形態予以實施。例如,藉由將發熱體配置於容器外部,可使容器外表面成膜。 Although the embodiments of the present invention have been described above, the present invention is not limited to the above-described embodiments, and various modifications may be made without departing from the spirit and scope of the invention. For example, the outer surface of the container can be formed into a film by disposing the heat generating body outside the container.

[產業上之可利用性] [Industrial availability]

本發明可利用於將DLC(Diamond Like Carbon:類鑚碳)膜、SiOx膜、SiOC膜、SiOCN膜、SiNx膜、AlOx膜等之氣體阻隔性高之薄膜成膜於寶特瓶(PET瓶)等容器之內表面、外表面之任一者、或兩者之成膜裝置。 The present invention can be used for forming a film having a high gas barrier property such as a DLC (Diamond Like Carbon) film, a SiOx film, a SiOC film, a SiOCN film, a SiNx film, or an AlOx film in a PET bottle. A film forming apparatus such as either or both of the inner surface and the outer surface of the container.

1‧‧‧成膜裝置 1‧‧‧ film forming device

2‧‧‧第1真空預備腔室 2‧‧‧1st vacuum preparation chamber

4‧‧‧第1加載互鎖腔室 4‧‧‧1st load lock chamber

6‧‧‧成膜腔室 6‧‧‧filming chamber

8‧‧‧第2加載互鎖腔室 8‧‧‧2nd load lock chamber

10‧‧‧第2真空預備腔室 10‧‧‧2nd vacuum preparation chamber

20‧‧‧第1閘閥 20‧‧‧1st gate valve

22‧‧‧第2閘閥 22‧‧‧2nd gate valve

24‧‧‧第3閘閥 24‧‧‧3rd gate valve

26‧‧‧第4閘閥 26‧‧‧4th gate valve

28‧‧‧第5閘閥 28‧‧‧5th gate valve

30‧‧‧第6閘閥 30‧‧‧6th gate valve

32‧‧‧真空管線 32‧‧‧vacuum pipeline

33‧‧‧真空管線 33‧‧‧vacuum pipeline

35‧‧‧真空管線 35‧‧‧vacuum pipeline

36‧‧‧真空管線 36‧‧‧vacuum pipeline

40‧‧‧搬送機構 40‧‧‧Transportation agency

41‧‧‧搬送機構 41‧‧‧Transportation agency

42‧‧‧搬送機構 42‧‧‧Transportation agency

43‧‧‧搬送機構 43‧‧‧Transportation agency

44‧‧‧搬送機構 44‧‧‧Transportation agency

45‧‧‧搬送機構 45‧‧‧Transportation agency

50‧‧‧寶特瓶 50‧‧‧Pet Bottle

55‧‧‧搬入輸送機 55‧‧‧ moving into the conveyor

56‧‧‧壓板容器 56‧‧‧ platen container

71‧‧‧升降用馬達 71‧‧‧Moving motor

73‧‧‧大氣開放閥 73‧‧‧Atmospheric open valve

75‧‧‧搬出輸送機 75‧‧‧Removing conveyor

80‧‧‧提升式輸送機 80‧‧‧lift conveyor

82‧‧‧搬送軌道 82‧‧‧Transfer track

85‧‧‧掛鉤 85‧‧‧ hook

87‧‧‧滾筒 87‧‧‧Roller

89‧‧‧擋止件 89‧‧‧stops

90‧‧‧下降輸送機 90‧‧‧Down conveyor

92‧‧‧大氣開放閥 92‧‧‧Atmospheric open valve

VP1‧‧‧真空泵 VP1‧‧‧ vacuum pump

VP2‧‧‧真空泵 VP2‧‧‧ vacuum pump

VP3‧‧‧真空泵 VP3‧‧‧ vacuum pump

VP4‧‧‧真空泵 VP4‧‧‧ vacuum pump

Claims (7)

一種成膜裝置,其特徵在於:其係於容器之表面形成薄膜者;且包含:成膜腔室,其內部保持為真空,且使用配置於內部之發熱體進行複數個容器之成膜;至少1個閘極腔室,其連通於上述成膜腔室,且內部被真空處理;及搬送機構,其經由上述閘極腔室,將保持有複數個容器之處理容器搬入於上述成膜腔室,且自上述成膜腔室搬出;上述成膜腔室中之成膜係以將複數個容器保持於上述處理容器之狀態進行。 A film forming apparatus characterized in that it is formed on a surface of a container to form a film; and comprises: a film forming chamber in which a vacuum is maintained, and a plurality of containers are formed by using a heat generating body disposed inside; at least a gate chamber connected to the film forming chamber and internally vacuum-treated; and a transfer mechanism for carrying a processing container holding a plurality of containers into the film forming chamber via the gate chamber And ejecting from the film forming chamber; the film forming system in the film forming chamber is carried out in a state in which a plurality of containers are held in the processing container. 如請求項1之成膜裝置,其中上述至少1個閘極腔室為複數個閘極腔室。 The film forming apparatus of claim 1, wherein the at least one gate chamber is a plurality of gate chambers. 如請求項2之成膜裝置,其中進而包含將上述複數個閘極腔室分別獨立地進行真空處理之真空排氣機構。 The film forming apparatus of claim 2, further comprising a vacuum exhausting mechanism that vacuum-processes the plurality of gate chambers independently. 如請求項1之成膜裝置,其中上述成膜腔室配置於上述閘極腔室之上側,且於上述閘極腔室之下端形成開口;上述成膜裝置進而包含密閉上述閘極腔室之上述開口之平板;上述搬送機構係以使上述平板升降之方式構成。 The film forming apparatus of claim 1, wherein the film forming chamber is disposed on an upper side of the gate chamber, and an opening is formed at a lower end of the gate chamber; and the film forming device further comprises a sealing chamber The flat plate of the opening; the conveying mechanism is configured to elevate and lower the flat plate. 如請求項4之成膜裝置,其中上述成膜裝置進而包含配置於上述平板上之與該平板獨立而可升降之升降台;上述搬送裝置藉由使載置有保持有複數個容器之上述處理容器之上述升降台升降,而使複數個容器於上述閘極腔室與上述成膜腔室之間移動。 The film forming apparatus of claim 4, wherein the film forming apparatus further includes an elevating table disposed on the flat plate independently of the flat plate and movable up and down; and the transfer device is configured to carry the above process of holding a plurality of containers The lifting platform of the container is raised and lowered to move a plurality of containers between the gate chamber and the film forming chamber. 如請求項1之成膜裝置,其中進而包含用以將保持有複數個容器之上述處理容器搬出入上述閘極腔室之搬出入單元。 The film forming apparatus of claim 1, further comprising a carry-in/out unit for carrying the processing container holding the plurality of containers into the gate chamber. 如請求項6之成膜裝置,其中上述搬出入單元包含:供給單元,其係鄰接於容器投入用輸送機而配置;排出單元,其係鄰接於容器排出用輸送機而配置;及中間單元,其配置於上述供給單元與上述排出單元之間;上述搬出入單元,於上述供給單元中,將複數個容器自上述容器投入用輸送機裝入上述處理容器;在上述中間單元中,將保持有複數個容器之上述處理容器自上述供給單元搬入於上述閘極腔室;在上述中間單元中,將保持有經形成上述薄膜之複數個容器之上述處理容器自上述閘極腔室搬出至上述排出單元;在上述排出單元中,將經形成上述薄膜之複數個容器排出至上述瓶排出用輸送機。 The film forming apparatus according to claim 6, wherein the carry-in unit includes a supply unit that is disposed adjacent to the container insertion conveyor, and a discharge unit that is disposed adjacent to the container discharge conveyor; and an intermediate unit; The loading/unloading unit is configured to load a plurality of containers from the container insertion conveyor into the processing container in the feeding unit; and to maintain the plurality of containers in the intermediate unit The processing container of the plurality of containers is carried into the gate chamber from the supply unit; and in the intermediate unit, the processing container holding the plurality of containers forming the film is carried out from the gate chamber to the discharge In the above discharge unit, a plurality of containers through which the film is formed are discharged to the bottle discharge conveyor.
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