TW201412626A - Film floating apparatus, tenter, solution film-forming equipment and process - Google Patents

Film floating apparatus, tenter, solution film-forming equipment and process Download PDF

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Publication number
TW201412626A
TW201412626A TW102135038A TW102135038A TW201412626A TW 201412626 A TW201412626 A TW 201412626A TW 102135038 A TW102135038 A TW 102135038A TW 102135038 A TW102135038 A TW 102135038A TW 201412626 A TW201412626 A TW 201412626A
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Taiwan
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film
exhaust
pressure
experiment
gas
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TW102135038A
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Chinese (zh)
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Hidetoshi Takayama
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Fujifilm Corp
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Abstract

A floating apparatus which can stably float a film to improve vibration resistance resulting from outer disturbance, a tenter, a solution film-forming equipment and process are provided. A gas flow control exhaust part 60 is disposed on a nozzle plate 55 to construct a blast head 50. A plurality of blow-off holes 55b are formed on the nozzle plate 55. The gas flow control exhaust part 60 is constructed by an exhaust gutter 61. The exhaust gutter 61 is formed with a length equal to a width of the blast head 50 in a width direction of a film 30. A dry air 49 is blown out from the blow-off hole 55b of the blast head 50 to float the film 30. The dry air 49 after hitting the film 30 is exhausted by the exhaust gutter 61 to a side of the film 30. The dry air 49 does not stay near the film 30. Even if the film 30 vibrates because of outer disturbance, the vibration is suppressed so that the vibration resistance is excellent.

Description

膜浮起裝置、拉幅機、溶液製膜設備及方法 Film floating device, tenter, solution film forming device and method

本發明涉及一種使帶狀的膜浮起的膜浮起裝置、拉幅機(tenter)、溶液製膜設備及方法。 The present invention relates to a film floating device, a tenter, a solution film forming apparatus and method for floating a strip-shaped film.

聚合物膜因具有優良的光透過性或柔軟性,且可輕量薄膜化,所以作為光學功能性膜而被用於多個領域。其中,使用了醯化纖維素(Cellulose acylate)等的纖維素酯(cellulosic ester)系膜除所述特性外,還具有強韌性或低雙折射率。該纖維素酯系膜被用作近年來市場不斷擴大的液晶顯示裝置(Liquid Crystal Display,LCD)的構成構件即偏光板的保護膜或光學補償膜。 Since the polymer film has excellent light transmittance or flexibility and can be lightly thinned, it is used in various fields as an optical functional film. Among them, a celluloseulosic ester film such as Cellulose acylate has a toughness or a low birefringence in addition to the above characteristics. The cellulose ester film is used as a protective film or an optical compensation film of a polarizing plate which is a constituent member of a liquid crystal display (LCD) which has been expanding in the market in recent years.

作為聚合物膜的製造方法之一,可列舉溶液製膜方法。溶液製膜方法中,將包含聚合物與溶劑的濃液(dope)從流延模流延於支撐體上而形成流延膜。而且,在流延膜一定程度地凝固而具有自我支撐性後,將流延膜作為濕潤膜而從支撐體剝取。然後,利用拉幅機,握持住濕潤膜的兩側端部而進行搬送,在該搬 送中進行膜的乾燥。之後,利用側縱切機(side slitter)將膜的兩側端部切斷後,膜經過乾燥裝置後被捲繞裝置捲繞。 One of the methods for producing a polymer film is a solution film forming method. In the solution film forming method, a dope containing a polymer and a solvent is cast from a casting die onto a support to form a cast film. Further, after the cast film is solidified to some extent and has self-supporting properties, the cast film is peeled off from the support as a wet film. Then, by using a tenter, the both end portions of the wet film are held and transported, and the transfer is performed. The film was dried during the transfer. Thereafter, the both end portions of the film were cut by a side slitter, and the film was passed through a drying device and then wound by a winding device.

拉幅機、尤其用以將溶劑含有率高的濕潤膜乾燥的針板拉幅機(pin tenter)中,使用具有多個針的針夾具(pin clip)而將針紮入膜的兩側緣部並加以保持,且從配置於膜的下方及上方的送風頭吹出乾燥風,一邊使膜浮起一邊進行搬送,並使膜乾燥(參照專利文獻1)。而且,專利文獻2中,作為膜搬送裝置,使用具有多個吹出孔的多孔板噴嘴,在使膜浮起的狀態下進行搬送。 A tenter, in particular, a pin tenter for drying a wet film having a high solvent content, uses a pin clip having a plurality of needles to puncture the needle into both sides of the film In the air blower, the air is blown out from the air blower, and the film is transported while the film is floated (see Patent Document 1). Furthermore, in the patent document 2, a porous plate nozzle having a plurality of blowing holes is used as the film conveying device, and the film is conveyed while the film is being floated.

[先前技術文獻] [Previous Technical Literature]

[專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2003-260741號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2003-260741

[專利文獻2]日本專利特開2008-247507號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2008-247507

然而,伴隨近年的平板顯示器的大型化或輕量化,製膜而得的膜的寬幅化或薄化進展,現有的膜搬送時的浮起穩定化方法中出現浮起的穩定性不足的情況。例如,如果膜的浮起不穩定,則有時膜與多孔板噴嘴等接觸而產生擦傷或破損。如果產生擦傷,則該部分無法作為產品而使用,從而發生產品損失。而且,在破損嚴重的情況下,會導致製膜生產線的停止,因而之後的啟動處理等要耗費大量的功夫與時間。因此,期望出現應對膜的寬幅化或薄化的新的浮起穩定化方法。 However, with the increase in size and weight of flat-panel displays in recent years, the film is broadened or thinned, and the stability of floating in the conventional film transfer method is insufficient. . For example, if the floating of the film is unstable, the film may come into contact with the perforated plate nozzle or the like to cause scratches or breakage. If a scratch is generated, the part cannot be used as a product, and product loss occurs. Moreover, in the case of severe damage, the film production line is stopped, and thus the startup process and the like take a lot of effort and time. Therefore, it is desired to have a new floating stabilization method that copes with the broadening or thinning of the film.

在使用專利文獻1的多孔板噴嘴的方法中,從多孔板噴嘴的吹出孔均等地吹出空氣,抑製膜的下垂,而穩定地浮起並搬 送。然而,雖使吹出壓力均等,但因膜下的壓力小,所以一旦因外擾而浮起變得不穩定時,存在難以穩定化的問題。而且,專利文獻2的多孔板噴嘴中,通過在搬送方向上形成為凸凹形狀,而降低膜下的靜壓,抑制浮起量。然而,因膜下的壓力低,所以會與專利文獻1同樣地,一旦因外擾而浮起變得不穩定時,存在難以穩定化的問題。 In the method of using the perforated plate nozzle of the patent document 1, air is blown uniformly from the blowing hole of the perforated plate nozzle, and the drooping of the film is suppressed, and it is stably floated and moved. give away. However, although the blowing pressure is equal, since the pressure under the film is small, when floating due to external disturbance becomes unstable, there is a problem that it is difficult to stabilize. Further, in the perforated plate nozzle of Patent Document 2, by forming a convex-concave shape in the conveying direction, the static pressure under the film is reduced, and the amount of floating is suppressed. However, since the pressure under the film is low, in the same manner as in Patent Document 1, when floating due to external disturbance becomes unstable, there is a problem that it is difficult to stabilize.

本發明的目的在於提供一種可抑制因外擾帶來的影響而使膜穩定地浮起的膜浮起裝置、拉幅機、溶液製膜設備及方法。 An object of the present invention is to provide a film floating device, a tenter, and a solution film forming apparatus and method which can suppress a film from being stably floated due to the influence of external disturbance.

為了達成所述目的,本發明的膜浮起裝置包括送風頭、以及氣流控制排氣部。送風頭具有噴嘴面。噴嘴面與膜面相向而配置。噴嘴面上配置多個朝向膜面吹出氣體的吹出孔。氣流控制排氣部在膜的寬度方向上配置於噴嘴面,將來自吹出孔的氣體向膜的側方排出。 In order to achieve the object, the film floating device of the present invention includes a blower head and an air flow control exhaust portion. The air supply head has a nozzle face. The nozzle surface is disposed to face the film surface. A plurality of blowing holes for blowing a gas toward the film surface are disposed on the nozzle surface. The air flow control exhaust portion is disposed on the nozzle surface in the width direction of the film, and discharges the gas from the blow hole to the side of the film.

另外,優選在膜的搬送方向上噴嘴面與氣流控制排氣部交替配置。而且,優選當將膜的搬送方向上的噴嘴面的長度設為W4,膜的搬送方向上的氣流控制排氣部的長度設為W2,氣流控制排氣部的膜的搬送方向上的間距設為P(P=W2+W4)時,比(W2/P)為0.1以上且0.3以下。 Further, it is preferable that the nozzle surface and the air flow control exhaust portion are alternately arranged in the transport direction of the film. Further, it is preferable that the length of the nozzle surface in the transport direction of the film is W4, the length of the airflow control exhaust portion in the transport direction of the film is W2, and the interval in the transport direction of the film of the airflow control exhaust portion is preferably set. When P (P=W2+W4), the ratio (W2/P) is 0.1 or more and 0.3 or less.

氣流控制排氣部優選包括排氣槽、及在該排氣槽的膜寬方向的兩側開口的排氣口。排氣槽優選具有1對隔板。1對隔板朝 向膜面突出,且彼此在膜搬送方向上隔開而配置。在該隔板的前端設置著1對導引板。導引板在1對隔板之間,從其中一個隔板的突出端朝向另一個隔板的基端傾斜地連續。 The air flow control exhaust portion preferably includes an exhaust groove and an exhaust port that is open on both sides in the film width direction of the exhaust groove. The venting groove preferably has a pair of separators. 1 pair of partitions towards The film surface is protruded and arranged to be spaced apart from each other in the film transport direction. A pair of guide plates are provided at the front end of the partition. The guide sheets are obliquely continuous between the pair of partitions from the projecting end of one of the partitions toward the base end of the other of the partitions.

優選在排氣槽上設置堵塞膜寬方向兩端的側板。在該側板上形成著排氣孔。由該排氣孔構成排氣口。 It is preferable to provide a side plate which blocks both ends in the width direction of the film on the exhaust groove. A vent hole is formed in the side plate. The exhaust port constitutes an exhaust port.

優選吹出孔中的氣體的吹出壓力為30Pa以上且150Pa以下,從吹出孔到膜為止的距離為20mm以上且100mm以下。而且,優選噴嘴面附近的壓力P1、更準確地說是從噴嘴面向上方離開20mm的位置的壓力P1,及膜面附近的壓力、更準確地說是從膜面向下方離開5mm的位置的壓力P2為5Pa以上且40Pa以下。而且,優選從噴嘴面離開20mm的位置的壓力P1與從膜面離開5mm位置的壓力P2的壓力差(P2-P1)為2Pa以下。 The blowing pressure of the gas in the blowing hole is preferably 30 Pa or more and 150 Pa or less, and the distance from the blowing hole to the film is 20 mm or more and 100 mm or less. Further, the pressure P1 near the nozzle surface, more specifically, the pressure P1 at a position separated from the nozzle surface by 20 mm, and the pressure near the film surface, more specifically, the pressure P2 at a position separated from the film surface by 5 mm downward is preferable. It is 5 Pa or more and 40 Pa or less. Further, it is preferable that the pressure difference (P2-P1) between the pressure P1 at a position separated from the nozzle surface by 20 mm and the pressure P2 at a position separated from the film surface by 5 mm is 2 Pa or less.

本發明的拉幅機包括所述膜浮起裝置、以及膜搬送裝置。膜搬送裝置利用保持部來保持膜的兩側緣部,使該保持部沿膜的搬送方向循環移動而搬送膜。氣體是為了使膜中的溶劑蒸發而經過溫度調節的乾燥空氣。 The tenter of the present invention includes the film floating device and a film conveying device. The film conveying device holds both side edges of the film by the holding portion, and the holding portion circulates in the conveying direction of the film to convey the film. The gas is a temperature-conditioned dry air for evaporating the solvent in the membrane.

本發明的溶液製膜設備包括流延裝置、保持並搬送從該流延裝置搬送的濕潤膜的所述拉幅機、以及將從該拉幅機搬送的濕潤膜乾燥的乾燥裝置。流延裝置在移行的環形的支撐體之上,流延包含聚合物及溶劑的濃液而形成帶狀的流延膜,並將該流延膜作為濕潤膜而剝取。 The solution film forming apparatus of the present invention includes a casting device, the tenter that holds and conveys the wet film conveyed from the casting device, and a drying device that dries the wet film conveyed from the tenter. The casting device casts a dope containing a polymer and a solvent on the traveling annular support to form a strip-shaped cast film, and the cast film is peeled off as a wet film.

本發明的溶液製膜方法包括流延步驟、膜搬送步驟、拉 幅步驟、以及將經過拉幅步驟的膜乾燥的乾燥步驟。流延步驟在移行的環形的支撐體之上,流延包含聚合物及溶劑的濃液而形成帶狀的流延膜,並將流延膜作為濕潤膜而從支撐體剝取。膜搬送步驟利用保持部來保持經過流延步驟的濕潤膜的兩側緣部,並搬送濕潤膜。拉幅步驟利用送風頭將乾燥氣體從具有多個吹出孔的噴嘴面朝向膜搬送步驟中的濕潤膜的膜面吹出,由此使濕潤膜乾燥。該乾燥中,利用氣流控制排氣部,將碰到膜面後的乾燥氣體向膜的側方排出。氣流控制排氣部在濕潤膜的搬送方向上隔開,並沿著膜寬方向配置於送風頭。 The solution film forming method of the present invention comprises a casting step, a film carrying step, and pulling The step of drying, and the drying step of drying the film subjected to the tentering step. The casting step is performed by casting a dope containing a polymer and a solvent onto a traveling annular support to form a strip-shaped cast film, and the cast film is taken as a wet film and peeled off from the support. In the film transporting step, both side edges of the wet film which have passed through the casting step are held by the holding portion, and the wet film is conveyed. In the tentering step, the drying gas is blown from the nozzle surface having the plurality of blowing holes toward the film surface of the wetting film in the film transporting step by the air blowing head, whereby the wet film is dried. In this drying, the exhaust portion is controlled by the air current, and the dry gas that has hit the film surface is discharged to the side of the film. The air flow control exhaust portion is partitioned in the conveying direction of the wet film, and is disposed in the air blowing head along the film width direction.

根據本發明,從噴嘴面的吹出孔吹出氣體,且利用氣流控制排氣部將來自吹出孔的氣體向膜的側方排出,由此可使膜面附近與噴嘴面附近的壓力大致相同。由此,不會因外擾而使浮起變得不穩定,從而可使膜穩定地浮起。而且,在使膜穩定地浮起的狀態下進行乾燥,由此在膜的整個面獲得更均勻的光學特性。 According to the present invention, the gas is blown from the blowing hole of the nozzle surface, and the gas is controlled to discharge the gas from the blowing hole to the side of the film by the air flow, whereby the pressure in the vicinity of the film surface and the vicinity of the nozzle surface can be made substantially the same. Thereby, the floating does not become unstable due to external disturbance, and the film can be stably floated. Moreover, drying is performed in a state where the film is stably floated, whereby more uniform optical characteristics are obtained over the entire surface of the film.

10‧‧‧溶液製膜設備 10‧‧‧solution film making equipment

11‧‧‧流延裝置 11‧‧‧casting device

12‧‧‧過渡輥 12‧‧‧Transition roller

13‧‧‧針板拉幅機 13‧‧‧ Needle plate tenter

14‧‧‧布鋏拉幅機 14‧‧‧布铗拉机

15a、15b‧‧‧側縱切機 15a, 15b‧‧‧ side slitting machine

16‧‧‧乾燥裝置 16‧‧‧Drying device

17‧‧‧捲繞裝置 17‧‧‧Winding device

20‧‧‧濃液 20‧‧‧Liquor

21‧‧‧模 21‧‧

22‧‧‧滾筒 22‧‧‧Roller

23‧‧‧剝取輥 23‧‧‧ Stripping roller

24‧‧‧減壓腔室 24‧‧‧Decompression chamber

25‧‧‧濃液製造設備 25‧‧‧Concentrate manufacturing equipment

26‧‧‧流道 26‧‧‧ flow path

27‧‧‧馬達 27‧‧‧Motor

28‧‧‧流延膜 28‧‧‧cast film

29‧‧‧傳熱介質循環機 29‧‧‧Heat Transfer Medium Circulator

30‧‧‧濕潤膜 30‧‧‧ Wet film

30a‧‧‧膜面 30a‧‧‧film surface

30b‧‧‧基準面 30b‧‧‧ datum

34‧‧‧拉幅室 34‧‧‧Large room

35‧‧‧膜搬送裝置 35‧‧‧film conveying device

36‧‧‧膜浮起裝置 36‧‧‧membrane floating device

37‧‧‧膜 37‧‧‧ film

38、82‧‧‧輥 38, 82‧‧‧ Roll

39‧‧‧輥狀膜 39‧‧‧ Roll film

40‧‧‧環形鏈條 40‧‧‧Circular chain

41‧‧‧軌道 41‧‧‧ Track

42‧‧‧鏈輪 42‧‧‧Sprocket

43‧‧‧針板 43‧‧‧ needle board

44‧‧‧針 44‧‧‧ needle

49‧‧‧乾燥空氣 49‧‧‧ Dry air

50、51、72、76、110、120‧‧‧送風頭 50, 51, 72, 76, 110, 120‧‧‧

52‧‧‧送風管 52‧‧‧Air duct

53‧‧‧送風機 53‧‧‧Air blower

54‧‧‧溫度調節機 54‧‧‧temperature regulator

55、75、100、115‧‧‧噴嘴板 55, 75, 100, 115‧‧‧ nozzle plate

55a‧‧‧噴嘴面 55a‧‧・Nozzle surface

55b、75b、100a、115b‧‧‧吹出孔 55b, 75b, 100a, 115b‧‧‧ blow out holes

55c‧‧‧安裝端緣部 55c‧‧‧Installation edge

56‧‧‧底板 56‧‧‧floor

56a‧‧‧膜搬送方向中央部 56a‧‧‧The central part of the film transport direction

56b‧‧‧連結部 56b‧‧‧Linking Department

57‧‧‧側板 57‧‧‧ side panels

57a‧‧‧管連接筒 57a‧‧‧ tube connector

58‧‧‧端板 58‧‧‧End board

60、75c‧‧‧氣流控制排氣部 60, 75c‧‧‧ airflow control exhaust

61、71、74、77‧‧‧排氣槽 61, 71, 74, 77‧‧ ‧ venting slots

62‧‧‧底板 62‧‧‧floor

63、70‧‧‧隔板 63, 70‧‧ ‧ partition

64、74a、74b、77a、77b‧‧‧導引板 64, 74a, 74b, 77a, 77b‧‧‧ guide boards

65‧‧‧排氣溝 65‧‧‧Exhaust ditch

66‧‧‧排氣間隙 66‧‧‧Exhaust clearance

67‧‧‧側板 67‧‧‧ side panels

68‧‧‧排氣口 68‧‧‧Exhaust port

78‧‧‧試驗機 78‧‧‧Testing machine

79‧‧‧帶狀膜 79‧‧‧Band film

80‧‧‧夾具 80‧‧‧ fixture

81‧‧‧砝碼 81‧‧‧ weight

85‧‧‧應變計 85‧‧‧ strain gauge

86‧‧‧個人電腦 86‧‧‧PC

101‧‧‧多孔送風頭 101‧‧‧Multiple air supply head

105‧‧‧狹縫狀開口 105‧‧‧Slit-like opening

106、116‧‧‧噴嘴 106, 116‧‧‧ nozzle

D1‧‧‧直徑 D1‧‧‧ diameter

H2‧‧‧高度 H2‧‧‧ Height

HF‧‧‧浮起高度 HF‧‧‧Floating height

L1、L2‧‧‧長度 L1, L2‧‧‧ length

P‧‧‧間距 P‧‧‧ spacing

P0‧‧‧吹出壓力 P0‧‧‧blowing pressure

P1、P2‧‧‧壓力 P1, P2‧‧‧ pressure

U1‧‧‧浮起量 U1‧‧‧Float

W1‧‧‧下部送風頭的寬度 W1‧‧‧ width of the lower air supply head

W2‧‧‧排氣槽的寬度 W2‧‧‧ vent width

W3‧‧‧排氣間隙的開口寬度 W3‧‧‧ opening width of the exhaust gap

W4‧‧‧噴嘴面的寬度 W4‧‧·The width of the nozzle face

X‧‧‧方向 X‧‧‧ direction

△U‧‧‧浮起量變動 △U‧‧‧Floating volume change

θ 1、θ 2‧‧‧傾斜角度 θ 1 , θ 2‧‧‧ tilt angle

圖1是表示本發明的溶液製膜設備的一例的概要的側面圖。 Fig. 1 is a side view showing an outline of an example of a solution film forming apparatus of the present invention.

圖2是表示本發明的拉幅機的一例的概要的正面剖面圖。 Fig. 2 is a front cross-sectional view showing an outline of an example of a tenter according to the present invention.

圖3是表示下部送風頭的一例的立體圖。 Fig. 3 is a perspective view showing an example of a lower air blowing head.

圖4是以剖面表示下部送風頭的一部分的側面圖。 Fig. 4 is a side view showing a part of the lower air blowing head in a cross section.

圖5是表示包含1單元的送風頭的膜浮起裝置的一例的立體圖。 Fig. 5 is a perspective view showing an example of a film floating device including a one-unit air blowing head.

圖6是表示來自吹出孔的乾燥空氣的流動的一例的圖,且是圖4中的VI-VI線的剖面圖。 FIG. 6 is a view showing an example of the flow of dry air from the blow hole, and is a cross-sectional view taken along line VI-VI of FIG. 4 .

圖7是表示來自吹出孔的乾燥空氣的流動的一例的圖,且是圖4中的VII-VII線的剖面圖。 FIG. 7 is a view showing an example of the flow of dry air from the blowing holes, and is a cross-sectional view taken along line VII-VII in FIG. 4 .

圖8是用以說明膜的浮起量及浮起量變動的正面圖。 Fig. 8 is a front view for explaining a change in the amount of floating and the amount of floating of the film.

圖9是以剖面表示改變排氣槽的形狀的另一實施方式的送風頭的一例的一部分的側面圖。 Fig. 9 is a side view showing a part of an example of a blower head showing another embodiment of changing the shape of the exhaust groove.

圖10同樣是表示變更了導引板的形狀的另一實施方式的排氣槽的一例的剖面圖。 FIG. 10 is a cross-sectional view showing an example of an exhaust groove of another embodiment in which the shape of the guide plate is changed.

圖11同樣是表示變更了導引板的形狀的另一實施方式的排氣槽的一例的剖面圖。 Fig. 11 is a cross-sectional view showing an example of an exhaust groove of another embodiment in which the shape of the guide plate is changed.

圖12是以剖面表示代替排氣槽而將噴嘴板配置成山形的另一實施方式的送風頭的一例的一部分的側面圖。 FIG. 12 is a side view showing a part of an example of a blower head of another embodiment in which a nozzle plate is arranged in a mountain shape instead of an exhaust groove.

圖13是表示試驗機的概要構成的一例的側面圖。 FIG. 13 is a side view showing an example of a schematic configuration of a testing machine.

圖14是表示實驗6中使用的送風頭的立體圖。 Fig. 14 is a perspective view showing a blower head used in Experiment 6.

圖15是表示實驗7中使用的送風頭的立體圖。 Fig. 15 is a perspective view showing a blower head used in Experiment 7.

圖16是表示實驗8中使用的送風頭的立體圖。 Fig. 16 is a perspective view showing a blower head used in Experiment 8.

圖1表示溶液製膜設備的一例,該溶液製膜設備10包括 流延裝置11、針板拉幅機13、布鋏拉幅機(clip tenter)14、側縱切機15a、側縱切機15b、乾燥裝置16、以及捲繞裝置17。 1 shows an example of a solution film forming apparatus 10, which includes the solution film forming apparatus 10 The casting device 11, the pin tenter 13, the clip tenter 14, the side slitter 15a, the side slitter 15b, the drying device 16, and the winding device 17.

流延裝置11包括模21、滾筒22、剝取輥23、以及減壓腔室(chamber)24。模21將從濃液製造設備25供給的濃液20在滾筒22的周面上流成流道(bead)26。濃液20是例如將醯化纖維素溶解於溶劑中所得。 The casting device 11 includes a die 21, a drum 22, a stripping roller 23, and a decompression chamber 24. The mold 21 flows the dope 20 supplied from the dope manufacturing apparatus 25 into a bead 26 on the circumferential surface of the drum 22. The dope 20 is obtained, for example, by dissolving deuterated cellulose in a solvent.

滾筒22利用馬達27而旋轉。由此,在滾筒周面上流道26被拉長,從而形成流延膜28。也就是說,滾筒22是支撐體的一形態。減壓腔室24對流道26的背面側(滾筒22的旋轉方向上游側)進行減壓,以消除流道26的不穩定的晃動。 The drum 22 is rotated by the motor 27. Thereby, the flow path 26 is elongated on the circumferential surface of the drum, thereby forming the casting film 28. That is, the drum 22 is a form of the support. The decompression chamber 24 decompresses the back side of the flow path 26 (the upstream side in the rotation direction of the drum 22) to eliminate unstable sway of the flow path 26.

滾筒22上連接著傳熱介質循環機29。傳熱介質循環機29將經冷卻的傳熱介質向滾筒22的內部傳送,將滾筒22的周面維持為固定溫度。利用該冷卻,固化成如下程度:流延膜28在滾筒22旋轉約3/4周的期間內,即便剝離也具有自我支撐性。 A heat transfer medium circulation machine 29 is connected to the drum 22. The heat transfer medium circulation machine 29 conveys the cooled heat transfer medium to the inside of the drum 22 to maintain the circumferential surface of the drum 22 at a fixed temperature. By this cooling, the curing is carried out to such an extent that the casting film 28 is self-supporting even when peeled off during the period in which the drum 22 is rotated for about 3/4 of a week.

相對於模21,在滾筒22的旋轉方向上游側且在滾筒22的周面附近,設置著剝取輥23。剝取輥23對由冷卻而固化的流延膜28進行支撐,並從滾筒22剝取流延膜28。經剝取的流延膜28作為濕潤膜30而經由過渡輥12被送至針板拉幅機13。 The stripping roller 23 is provided on the upstream side in the rotation direction of the drum 22 and in the vicinity of the circumferential surface of the drum 22 with respect to the mold 21. The stripping roller 23 supports the casting film 28 which is solidified by cooling, and the casting film 28 is peeled off from the drum 22. The stripped cast film 28 is sent as a wet film 30 to the pin tenter 13 via the transition roller 12.

針板拉幅機13包括膜搬送裝置35、以及膜浮起裝置36。針板拉幅機13中,一邊利用膜搬送裝置35搬送濕潤膜30,一邊利用由膜浮起裝置36帶來的乾燥風進行乾燥。也就是,針板拉幅機13為拉幅機的一形態。 The pin tenter 13 includes a film transport device 35 and a film floating device 36. In the needle card tenter 13, the wet film 30 is conveyed by the film transport device 35, and dried by the dry air by the film floating device 36. That is, the pin tenter 13 is a form of a tenter.

進行了乾燥的膜30被送至側縱切機15a。側縱切機15a將包含由針板拉幅機13的針44造成的保持痕跡的膜30的兩側部切除。 The dried film 30 is sent to the side slitter 15a. The side slitter 15a cuts both side portions of the film 30 including the holding marks caused by the needles 44 of the pin tenter 13.

布鋏拉幅機14中,握持住在針板拉幅機13進行了乾燥的膜30的兩側緣部,並向膜寬方向及膜搬送方向將膜30延伸。利用該延伸,形成具有所需的光學特性的膜37。膜37在利用側縱切機15b將兩側部切除後,被送至乾燥裝置16。另外,根據膜37的光學特性,也有時不使用布鋏拉幅機14,而迂回地直接送至乾燥裝置16。 In the fabric tenter 14, the both side edges of the film 30 dried by the pin tenter 13 are held, and the film 30 is extended in the film width direction and the film conveyance direction. With this extension, a film 37 having the desired optical properties is formed. The film 37 is cut off at both sides by the side slitter 15b, and then sent to the drying device 16. Further, depending on the optical characteristics of the film 37, the fabric tenter 14 may not be used, and may be sent directly to the drying device 16 in a meandering manner.

乾燥裝置16中,將膜37卷掛在多個輥38上進行搬送。乾燥裝置16的內部的環境氣體是由未圖示的溫調機來調節溫度或濕度等。在膜37被搬送期間,溶劑蒸發而得以乾燥。然後,膜37利用捲繞裝置17而捲繞成卷狀。由本發明而獲得的卷狀膜39例如被用於相位差膜或偏光板保護膜。 In the drying device 16, the film 37 is wound around a plurality of rollers 38 and conveyed. The ambient gas inside the drying device 16 is adjusted by temperature or humidity or the like by a thermostat (not shown). During the transport of the film 37, the solvent evaporates and is dried. Then, the film 37 is wound into a roll shape by the winding device 17. The roll film 39 obtained by the present invention is used, for example, for a retardation film or a polarizing plate protective film.

本發明的針板拉幅機13包括拉幅室34、膜搬送裝置35、以及膜浮起裝置36。拉幅室34氣密地構成,經乾燥的溶劑等不會從濕潤膜30向外部洩露。而且,從流延裝置11到針板拉幅機13的過渡部或從針板拉幅機13到布鋏拉幅機14的連接部、從布鋏拉幅機14到乾燥裝置16的連接部,也均成為氣密構造,從而溶劑不會向外部洩露。 The needle card tenter 13 of the present invention includes a tenter chamber 34, a film transporting device 35, and a film floating device 36. The tenter chamber 34 is airtight, and the dried solvent or the like does not leak from the wet film 30 to the outside. Further, a transition portion from the casting device 11 to the pin tenter 13 or a connection portion from the pin tenter 13 to the fabric tenter 14 and a connection portion from the fabric tenter 14 to the drying device 16 They also become airtight structures so that the solvent does not leak to the outside.

如圖2所示,膜搬送裝置35包括環形鏈條40、軌道41、鏈輪42(參照圖1)、以及針板(pin plate)43。環形鏈條40沿著 濕潤膜30的移行路徑的兩側部而配置,且設置有1對。這些環形鏈條40架設在鏈輪42上。在一個鏈輪42上連結著馬達。馬達使鏈輪42旋轉,從而使環形鏈條40循環移行。 As shown in FIG. 2, the film conveying device 35 includes an endless chain 40, a rail 41, a sprocket 42 (refer to FIG. 1), and a pin plate 43. Circular chain 40 along The wet film 30 is disposed on both sides of the traveling path, and is provided in a pair. These endless chains 40 are mounted on the sprocket 42. A motor is coupled to a sprocket 42. The motor rotates the sprocket 42 to circulate the endless chain 40.

各鏈輪42間的環形鏈條40是由軌道41支撐。環形鏈條40上以固定間距而安裝有針板43。針板43上突出形成有多個針44。針44紮入濕潤膜30的兩側緣部,而對濕潤膜30進行支撐。也就是說,針44為保持部的一形態。 The endless chain 40 between the sprockets 42 is supported by the rails 41. A needle plate 43 is attached to the endless chain 40 at a fixed pitch. A plurality of needles 44 are protruded from the needle plate 43. The needle 44 is inserted into both side edges of the wet film 30 to support the wet film 30. That is, the needle 44 is one form of the holding portion.

如圖1所示,在本實施方式中,就設備效率的觀點而言,膜搬送路以例如成為3段的方式在中途折返。伴隨於此,環形鏈條40也在鏈輪42處折返。 As shown in FIG. 1, in the present embodiment, the film transport path is folded back halfway, for example, in a three-stage manner from the viewpoint of equipment efficiency. Along with this, the endless chain 40 is also folded back at the sprocket 42.

針板拉幅機13的膜導入部配置著未圖示的膜按壓刷。膜按壓刷將膜側緣部按壓至針44的根部側,從而針44確實地刺入濕潤膜30。由針44保持了兩側緣部的濕潤膜30利用環形鏈條40的循環移行而送往X方向。 A film pressing brush (not shown) is disposed in the film introduction portion of the needle card tenter 13. The film pressing brush presses the side edge portion of the film to the root side of the needle 44, so that the needle 44 surely penetrates the wet film 30. The wet film 30, which is held by the needles 44 at both side edges, is transferred to the X direction by the cyclic movement of the endless chain 40.

如圖2所示,膜浮起裝置36包括下部送風頭50、上部送風頭51、送風管52、送風機53、以及溫度調節機54。下部送風頭50以夾著膜30的方式配置在膜30的下方,上部送風頭51配置在膜30的上方。 As shown in FIG. 2, the film floating device 36 includes a lower air blowing head 50, an upper air blowing head 51, a blow pipe 52, a blower 53, and a temperature adjuster 54. The lower air blowing head 50 is disposed below the film 30 so as to sandwich the film 30, and the upper air blowing head 51 is disposed above the film 30.

如圖3及圖4所示,下部送風頭50包括噴嘴板55、底板56、兩側板57、以及兩端板58,且構成為大致箱狀。噴嘴板55以與濕潤膜30的搬送路徑相向的方式配置。噴嘴面55a上形成著多個吹出孔55b。噴嘴板55的兩端從兩端板58稍微延伸出。由該 延伸設置部分形成安裝端緣部55c。該安裝端緣部55c的吹出孔55b不與下部送風頭50的內部連通,因而無助於吹出。另外,也可省略該安裝端緣部55c。 As shown in FIGS. 3 and 4, the lower air blowing head 50 includes a nozzle plate 55, a bottom plate 56, two side plates 57, and two end plates 58, and is formed in a substantially box shape. The nozzle plate 55 is disposed to face the transport path of the wet film 30. A plurality of blowing holes 55b are formed in the nozzle surface 55a. Both ends of the nozzle plate 55 slightly extend from the both end plates 58. By this The extended portion forms a mounting end edge portion 55c. The blowing hole 55b of the mounting end edge portion 55c does not communicate with the inside of the lower air blowing head 50, and thus does not contribute to blowing. In addition, the mounting end edge portion 55c may be omitted.

如圖4所示,底板56的膜搬送方向中央部56a相對於噴嘴面55a平行。而且,將膜搬送方向中央部56a與兩端板58予以連結的連結部56b以隨著朝向端板58而與噴嘴面55a的距離減小的方式傾斜。 As shown in FIG. 4, the film conveyance direction center part 56a of the bottom plate 56 is parallel with respect to the nozzle surface 55a. In addition, the connection portion 56b that connects the film conveyance direction center portion 56a and the both end plates 58 is inclined so as to decrease in distance from the nozzle face 55a toward the end plate 58.

其中一個側板57上形成著管連接筒57a。經由該管連接筒57a而連結著送風管52(參照圖2)。另外,視需要在上部送風頭51內配置著整流板。該整流板使來自各吹出孔55b的空氣吹出壓力大致為固定。 A pipe connecting cylinder 57a is formed on one of the side plates 57. The air supply duct 52 is connected via the tube connection cylinder 57a (see FIG. 2). Further, a rectifying plate is disposed in the upper air blowing head 51 as needed. The rectifying plate has a substantially constant air blowing pressure from each of the blowing holes 55b.

噴嘴面55a上,沿膜寬方向配置著排氣槽61。該排氣槽61在膜搬送方向上以固定間距而例如配置4個。由此,噴嘴板55與排氣槽61在膜搬送方向上交替配置著。 An exhaust groove 61 is disposed on the nozzle surface 55a in the film width direction. For example, four exhaust grooves 61 are arranged at a fixed pitch in the film transport direction. Thereby, the nozzle plate 55 and the exhaust groove 61 are alternately arranged in the film conveying direction.

如圖3所示,排氣槽61由底板62及1對隔板63而構成為大致U字形。隔板63在底板62的膜搬送方向兩端緣連續,並朝向膜面30a突出。該排氣槽61構成吹出氣體的氣流控制排氣部60,該氣流控制排氣部60用以將來自吹出孔55b的氣體在碰到膜面30a後,向膜30的兩側方排出。 As shown in FIG. 3, the exhaust groove 61 is formed in a substantially U shape by the bottom plate 62 and the pair of partition plates 63. The separator 63 is continuous at both end edges of the bottom plate 62 in the film transport direction, and protrudes toward the film surface 30a. The exhaust groove 61 constitutes an air flow control exhaust unit 60 for blowing a gas, and the air flow control exhaust unit 60 is for discharging the gas from the blowing hole 55b to the both sides of the film 30 after hitting the film surface 30a.

隔板63的前端連續地連接著導引板64。導引板64在排氣槽61的內側,前端朝向斜下方。由該1對導引板64形成V字形的排氣溝65。而且,1對導引板64的前端緣彼此不密接而形成 排氣間隙66。 The front end of the partition 63 is continuously connected to the guide plate 64. The guide plate 64 is inside the exhaust groove 61, and the front end faces obliquely downward. A V-shaped exhaust groove 65 is formed by the pair of guide plates 64. Moreover, the front end edges of the pair of guiding plates 64 are not closely connected to each other to form Exhaust clearance 66.

如圖6及圖7所示,排氣槽61的膜寬方向兩端部是由側板67封閉。如圖3所示,側板67連結於底板62、隔板63及導引板64的側緣。排氣口68在側板67的下部開口。排氣口68形成為在水平方向上長的長方形。從吹出孔55b吹出並碰到膜30的空氣通過排氣槽61的排氣溝65或排氣口68,而被送至送風頭51的兩側方。由此,從吹出孔55b吹出並碰到膜30的空氣不會在膜30附近滯留。 As shown in FIGS. 6 and 7, the end portions of the exhaust groove 61 in the film width direction are closed by the side plates 67. As shown in FIG. 3, the side plate 67 is coupled to the side edges of the bottom plate 62, the partition plate 63, and the guide plate 64. The exhaust port 68 is open at a lower portion of the side plate 67. The exhaust port 68 is formed in a rectangular shape that is long in the horizontal direction. The air blown from the blowing hole 55b and hitting the film 30 passes through the exhaust groove 65 or the exhaust port 68 of the exhaust groove 61, and is sent to both sides of the air blowing head 51. Thereby, the air blown out from the blowing hole 55b and hitting the film 30 does not stay in the vicinity of the film 30.

另外,排氣口68上也可設置開口面積調節閥或排氣風扇等流量調整機構。該流量調整機構對來自排氣口68的排氣量進行微調。藉此,調節從吹出孔55b吹出並碰到膜30的空氣的排出量。而且,本第一實施方式中,將排氣口68設置於排氣溝65的兩側,但也可僅在單側設置排氣口68。該情況下,以使未形成排氣口側的排氣間隙66的開口寬度W3相比於排氣口側的排氣間隙66的開口寬度W3而漸增的方式,逐漸擴大寬度W3,由此可在寬度方向上無不均地進行排氣。 Further, a flow rate adjusting mechanism such as an opening area adjusting valve or an exhaust fan may be provided in the exhaust port 68. The flow rate adjustment mechanism finely adjusts the amount of exhaust gas from the exhaust port 68. Thereby, the discharge amount of the air blown out from the blowing hole 55b and hitting the film 30 is adjusted. Further, in the first embodiment, the exhaust ports 68 are provided on both sides of the exhaust groove 65, but the exhaust port 68 may be provided only on one side. In this case, the width W3 is gradually increased so that the opening width W3 of the exhaust gap 66 where the exhaust port side is not formed is gradually increased compared to the opening width W3 of the exhaust gap 66 on the exhaust port side. Exhaust can be performed without unevenness in the width direction.

吹出孔55b中的乾燥空氣49的吹出壓力P0優選為20Pa以上且155Pa以下。特別優選為20Pa以上且120Pa以下。如果吹出壓力P0為30Pa以上,則膜30不會經不住自重,從而穩定地浮起。如果為150Pa以下,則膜30的正下方的壓力不會變得過大。而且,即便引起由外擾造成的振動而增大了振動,也可抑制振動,從而浮起穩定。從吹出孔55b到膜30為止的距離即浮起高度HF 優選為20mm以上且100mm以下,特別優選為40mm以上且100mm以下。如果該浮起高度HF為20mm以上且100mm以下,則膜下的壓力變得均勻,浮起中的振動減少。 The blowing pressure P0 of the dry air 49 in the blowing hole 55b is preferably 20 Pa or more and 155 Pa or less. It is particularly preferably 20 Pa or more and 120 Pa or less. If the blowing pressure P0 is 30 Pa or more, the film 30 does not pass through its own weight, and thus floats stably. If it is 150 Pa or less, the pressure immediately below the film 30 does not become excessive. Further, even if the vibration caused by the external disturbance is caused to increase the vibration, the vibration can be suppressed and the floating stability can be achieved. The distance from the blowing hole 55b to the film 30 is the floating height HF It is preferably 20 mm or more and 100 mm or less, and particularly preferably 40 mm or more and 100 mm or less. When the floating height HF is 20 mm or more and 100 mm or less, the pressure under the film becomes uniform, and the vibration during floating is reduced.

從噴嘴面55a向上方離開20mm的位置的壓力P1及從膜面30a向下方離開5mm的位置的壓力P2優選為5Pa以上且40Pa以下。特別優選為10Pa以上且25Pa以下。如果這些壓力P1、壓力P2為5Pa以上,則膜30不會經不住自重,從而可浮起搬送。而且,如果這些壓力P1、壓力P2為40Pa以下,則膜30不會在寬度方向上鼓起成平緩的凸形狀,從而不會導致浮起量過多或外擾耐受性不足。 The pressure P1 at a position separated from the nozzle surface 55a by 20 mm upward and the pressure P2 at a position separated from the film surface 30a by 5 mm are preferably 5 Pa or more and 40 Pa or less. It is particularly preferably 10 Pa or more and 25 Pa or less. If the pressure P1 and the pressure P2 are 5 Pa or more, the film 30 does not pass through the self-weight, and can be floated and transported. Further, if these pressures P1 and P2 are 40 Pa or less, the film 30 does not bulge in a gentle convex shape in the width direction, so that the amount of floating is not excessive or the external disturbance resistance is insufficient.

這些壓力P1、壓力P2的壓力差(P2-P1)優選為2Pa以下。如果該壓力差(P2-P1)為2Pa以下,則壓力變得大致均勻,從而也不會因由外擾引起的振動而使得膜30的浮起變得不穩定。 The pressure difference (P2-P1) between the pressure P1 and the pressure P2 is preferably 2 Pa or less. If the pressure difference (P2-P1) is 2 Pa or less, the pressure becomes substantially uniform, and the floating of the film 30 is not unstable due to the vibration caused by the external disturbance.

如圖8所示,膜30因來自吹出孔的氣體的吹出,而成為向氣體吹出方向突出地鼓起的形狀。因此,如果以膜面30a為基準來測定壓力P2則變成在其每次變動的位置進行測定。為了避免該情況的發生,在以膜面30a為基準的情況下,實際上將由針板43的針44造成的膜的保持面(以下稱作基準面)30b作為膜面30a,以從該基準面30b算起的距離來確定壓力P2的測定點。另外,圖8中,為了說明膜30的浮起量U1及浮起量變動△U,而將膜30的鼓起形狀描繪得比實際形狀還誇張。而且,省略上側的送風頭的圖示。 As shown in FIG. 8, the film 30 has a shape which bulges in the gas blowing direction by the gas from the blowing hole. Therefore, when the pressure P2 is measured based on the film surface 30a, it is measured at the position where it changes every time. In order to avoid this, when the film surface 30a is used as a reference, the film holding surface (hereinafter referred to as a reference surface) 30b by the needle 44 of the needle plate 43 is actually used as the film surface 30a from the reference. The distance from the face 30b determines the measurement point of the pressure P2. In addition, in FIG. 8, in order to explain the floating amount U1 of the film 30 and the floating amount fluctuation ΔU, the bulging shape of the film 30 is drawn more than the actual shape. Moreover, the illustration of the air blowing head on the upper side is omitted.

膜30的浮起量U1是指,因氣體的吹出而膜30浮起時的膜30的寬度方向中央的從基準面30b算起的高度的平均值。該浮起量U1是例如10秒以上且60秒以下的時間內的高度的平均值。浮起量變動△U是指求出浮起量U1時的膜30的寬度方向中央的浮起量U1的變動幅度的最大值。膜振動的頻率與浮起量變動△U的頻率彼此不同,膜振動依存於吹出空氣的頻率,為15Hz以上且200Hz以下左右,浮起量變動△U的頻率為0.01Hz以上且5Hz以下左右。 The floating amount U1 of the film 30 is an average value of the height from the reference surface 30b at the center in the width direction of the film 30 when the film 30 is floated by the gas blowing. The floating amount U1 is an average value of the heights in a time period of, for example, 10 seconds or more and 60 seconds or less. The fluctuation amount ΔU is the maximum value of the fluctuation range of the floating amount U1 in the center in the width direction of the film 30 when the floating amount U1 is obtained. The frequency of the film vibration and the fluctuation of the floating amount fluctuation ΔU are different from each other, and the film vibration is 15 Hz or more and 200 Hz or less depending on the frequency of the blown air, and the frequency of the floating amount fluctuation ΔU is 0.01 Hz or more and 5 Hz or less.

如圖4所示,排氣槽61的寬度W2與排氣槽61的間距P之比(W2/P)優選為0.1以上且0.3以下。另外,間距P是指在下部送風頭50的噴嘴面上沿膜搬送方向將排氣槽61隔開而排列時的各排氣槽61間的間隔。當將各排氣槽61間的噴嘴面55a的寬度(噴嘴面55a的膜搬送方向上的長度)設為W4時,間距P為(W2+W4)。如果排氣槽61的寬度相對於該間距P所占的比例即比(W2/P)為0.1以上,則排氣的效果增加,外擾耐受性比後述實驗1的多孔板強。而且,如果比(W2/P)為0.3以下,則不會導致供氣風量不足,從而使浮起穩定化。另外,為了圖示出作為氣流控制排氣部60的排氣槽61,在圖2~圖9中,將排氣槽61的尺寸相比於噴嘴面55a而進行放大,並誇張圖示排氣槽61。因此,這些圖2~圖9中,並非為滿足所述W2/P的關係的尺寸。 As shown in FIG. 4, the ratio (W2/P) of the width W2 of the exhaust groove 61 to the pitch P of the exhaust groove 61 is preferably 0.1 or more and 0.3 or less. In addition, the pitch P is an interval between the exhaust grooves 61 when the exhaust grooves 61 are arranged in the film transport direction on the nozzle surface of the lower air blowing head 50. When the width of the nozzle surface 55a between the respective exhaust grooves 61 (the length of the nozzle surface 55a in the film transport direction) is W4, the pitch P is (W2+W4). When the ratio of the width of the exhaust groove 61 to the pitch P, that is, the ratio (W2/P) is 0.1 or more, the effect of the exhaust gas is increased, and the external disturbance resistance is stronger than that of the porous plate of Experiment 1 to be described later. Further, if the ratio (W2/P) is 0.3 or less, the amount of supply air is not insufficient, and the floating is stabilized. In addition, in order to illustrate the exhaust groove 61 as the airflow control exhaust unit 60, in FIGS. 2 to 9, the size of the exhaust groove 61 is enlarged compared to the nozzle surface 55a, and the exhaust is exaggerated. Slot 61. Therefore, in these FIGS. 2 to 9, it is not the size that satisfies the relationship of W2/P.

而且,當將導引板64的前端彼此的間隙即排氣間隙66的寬度設為W3時,其相對於排氣槽61的上端的寬度W2的比即 W3/W2優選為0.02以上且0.05以下。如果為0.02以上,則因排氣的效果而外擾耐受性增大。而且,如果為0.05以下,則排氣的效果不會增大,膜下的壓力大致均勻。 Further, when the gap between the tips of the guide plates 64, that is, the width of the exhaust gap 66 is W3, the ratio of the width W2 of the upper end of the exhaust groove 61 is W3/W2 is preferably 0.02 or more and 0.05 or less. If it is 0.02 or more, the external disturbance tolerance increases due to the effect of the exhaust gas. Further, if it is 0.05 or less, the effect of the exhaust gas does not increase, and the pressure under the film is substantially uniform.

如圖3所示,排氣槽61的長度L2優選與下部送風頭50的寬度W1相同。該情況下,在膜30的浮起區域內可利用排氣槽61使碰到膜面30a的乾燥空氣49高效率地向膜寬方向兩側排放。 As shown in FIG. 3, the length L2 of the exhaust groove 61 is preferably the same as the width W1 of the lower air blowing head 50. In this case, the dry air 49 that hits the film surface 30a can be efficiently discharged to both sides in the film width direction by the exhaust groove 61 in the floating region of the film 30.

排氣槽61的隔板63的高度H2優選為吹出孔55b的直徑D1的2倍以上且25倍以下。如果為2倍以上則氣流向排氣溝65流動,而獲得排氣的效果。而且,如果為25倍以下,則來自噴嘴板55的噴出風的衰減減小,浮起穩定。 The height H2 of the partition plate 63 of the exhaust groove 61 is preferably twice or more and 25 times or less the diameter D1 of the blow-out hole 55b. If it is 2 times or more, the airflow flows to the exhaust groove 65, and the effect of the exhaust gas is obtained. Further, if it is 25 times or less, the attenuation of the discharged air from the nozzle plate 55 is reduced, and the floating is stabilized.

如圖4所示,導引板64的相對於噴嘴面55a的傾斜角度θ 1優選為5°以上且30°以下。如果傾斜角度θ 1為5°以上則氣流容易進入排氣溝65。而且,如果為30°以下則排氣槽61的周邊的壓力變得均勻。 As shown in FIG. 4, the inclination angle θ1 of the guide plate 64 with respect to the nozzle surface 55a is preferably 5° or more and 30° or less. If the inclination angle θ 1 is 5° or more, the airflow easily enters the exhaust groove 65. Moreover, if it is 30 degrees or less, the pressure of the periphery of the exhaust groove 61 becomes uniform.

如圖2所示,上部送風頭51也與下部送風頭50為相同構成,對相同構成構件附上相同符號,並省略重複的說明。如圖5所示,本實施方式中,將下部送風頭50與上部送風頭51作為1組,並將3組送風頭排列而作為1個單元。而且,根據膜搬送裝置35的膜搬送長度,僅設置必要的單元數,由此構成膜浮起裝置36。 As shown in Fig. 2, the upper air blowing head 51 is also configured in the same manner as the lower air blowing head 50, and the same components are denoted by the same reference numerals, and the overlapping description will be omitted. As shown in FIG. 5, in the present embodiment, the lower air blowing head 50 and the upper air blowing head 51 are set as one set, and the three sets of air blowing heads are arranged as one unit. Further, the film floating device 36 is configured by providing only the necessary number of cells in accordance with the film transport length of the film transport device 35.

其次,對本實施方式的作用進行說明。如圖2所示,針板拉幅機13中,濕潤膜30通過將針44紮入其兩側緣部,而兩側 緣部得到保持。針44保持於針板43,針板43固定於旋轉移行的環形鏈條40上。環形鏈條40在由軌道41支撐的狀態下利用鏈輪42(參照圖1)而旋轉。由此,濕潤膜30在針板拉幅機13內沿X方向移行。 Next, the action of this embodiment will be described. As shown in Fig. 2, in the pin tenter 13, the wet film 30 is inserted into the side edges of the needles 44, and both sides are The edge is kept. The needle 44 is held on the needle plate 43, and the needle plate 43 is fixed to the rotationally moving endless chain 40. The endless chain 40 is rotated by the sprocket 42 (refer to FIG. 1) in a state of being supported by the rail 41. Thereby, the wet film 30 travels in the X direction in the pin tenter 13.

從下部送風頭50及上部送風頭51的吹出孔55b向移行的濕潤膜30通入乾燥空氣49。該乾燥空氣49在如圖6所示碰到膜面30a之後,如圖7所示,從排氣槽61向膜30的兩側方排出。因此,吹出孔55b附近的靜壓與膜面30a附近的靜壓的壓力差消失,即便膜30因外擾而擾動,擾動也會立即被抑制,從而不會向大的擾動發展。因此,膜面30a也不會晃動,從而可使膜30穩定地浮起。由此,下部送風頭50及上部送風頭51不會與膜面30a接觸而發生擦傷或破損。而且,因膜30在穩定地浮起的狀態下進行乾燥,所以在膜30的整個面獲得更均勻的光學特性。 Dry air 49 is introduced into the traveling wet film 30 from the lower air blowing head 50 and the blowing hole 55b of the upper air blowing head 51. After the dry air 49 hits the film surface 30a as shown in FIG. 6, as shown in FIG. 7, it is discharged from the exhaust groove 61 to both sides of the film 30. Therefore, the pressure difference between the static pressure in the vicinity of the blowing hole 55b and the static pressure in the vicinity of the film surface 30a disappears, and even if the film 30 is disturbed by the external disturbance, the disturbance is immediately suppressed, and the large disturbance is not developed. Therefore, the film surface 30a does not shake, so that the film 30 can be stably floated. Thereby, the lower air blowing head 50 and the upper air blowing head 51 are not in contact with the film surface 30a, and are scratched or damaged. Further, since the film 30 is dried in a state of being stably floated, more uniform optical characteristics are obtained over the entire surface of the film 30.

特別是,氣流控制排氣部60沿膜寬方向配置得長,其排氣口68位於膜寬方向兩端部,因而可高效地將為了使膜30浮起而吹出的乾燥空氣49從膜浮起範圍區域向膜兩側方送出。由此,可進一步減小形成有吹出孔55b的噴嘴面55a附近的壓力與膜面30a附近的壓力之差。因此,針對由外擾引起的膜30的振動,可將振動抑制得不大,從而振動耐受性提高。 In particular, the airflow control exhaust portion 60 is disposed long in the film width direction, and the exhaust port 68 is located at both end portions in the film width direction, so that the dry air 49 blown out for the film 30 to float can be efficiently floated from the film. The range area is sent to both sides of the film. Thereby, the difference between the pressure in the vicinity of the nozzle surface 55a in which the blowing hole 55b is formed and the pressure in the vicinity of the film surface 30a can be further reduced. Therefore, with respect to the vibration of the film 30 caused by the external disturbance, the vibration can be suppressed little, and the vibration resistance is improved.

另外,所述實施方式中,如圖4所示,使排氣槽61的隔板63與噴嘴面55a正交配置,但不限於此,也可如圖9所示,使用將隔板70朝向排氣槽71的內側以傾斜角度θ 2傾斜而配置的 送風頭72。另外,各實施方式中,對於與圖1~圖7所示的實施方式相同的構成構件附上相同符號,並省略重複的說明。 Further, in the above-described embodiment, as shown in FIG. 4, the partition plate 63 of the exhaust groove 61 is disposed to be orthogonal to the nozzle surface 55a. However, the present invention is not limited thereto, and as shown in FIG. 9, the partition plate 70 may be used. The inside of the exhaust groove 71 is disposed at an inclination angle θ 2 The air head 72 is supplied. In the respective embodiments, the same components as those in the embodiment shown in FIGS. 1 to 7 are denoted by the same reference numerals, and the description thereof will not be repeated.

圖10表示將1對導引板74a、導引板74b中的一個形成得比另一個長的另一實施方式的排氣槽74。圖11表示使1對導引板77a、導引板77b朝向下方彎曲的另一實施方式的排氣槽77。排氣間隙66的開口寬度W3在圖10的情況下,為從短的導引板74a的前端到長的導引板74b為止的間隙。在圖11的情況下,導引板77a、導引板77b的前端彼此的間隙為排氣間隙66的開口寬度W3。 Fig. 10 shows an exhaust groove 74 of another embodiment in which one of the pair of guide plates 74a and 74b is formed longer than the other. FIG. 11 shows an exhaust groove 77 of another embodiment in which one pair of the guide sheets 77a and the guide sheets 77b are bent downward. The opening width W3 of the exhaust gap 66 is a gap from the front end of the short guide plate 74a to the long guide plate 74b in the case of FIG. In the case of FIG. 11, the gap between the front ends of the guide sheets 77a and the guide sheets 77b is the opening width W3 of the exhaust gap 66.

圖12表示代替個別的排氣槽61、排氣槽71,而將具有多個吹出孔75b的噴嘴板75配置成山形的另一實施方式的送風頭76。該情況下,消除山形彼此之間的谷部分的吹出孔75b,由該谷部分構成氣流控制排氣部75c。另外,也可通過使谷部分的吹出孔75b的每單位面積的開口率比山頂部分小,而減弱吹出風,並將該減弱部分作為氣流控制排氣部。 FIG. 12 shows a blower head 76 of another embodiment in which a nozzle plate 75 having a plurality of blow holes 75b is disposed in a mountain shape instead of the individual exhaust grooves 61 and the exhaust grooves 71. In this case, the blowing holes 75b of the valley portions between the mountain shapes are eliminated, and the air flow control exhausting portion 75c is constituted by the valley portions. In addition, the blowing rate per unit area of the blowing hole 75b of the valley portion may be made smaller than that of the top portion, and the blowing wind may be weakened, and the weakened portion may be used as the air flow to control the exhaust portion.

所述實施方式中,與膜30相向來配置下部送風頭50及上部送風頭51,但也可省略上部送風頭51而僅利用下部送風頭50進行浮起搬送。然而,如果考慮對外擾的振動耐受性,則優選在上下設置送風頭。 In the above embodiment, the lower air blowing head 50 and the upper air blowing head 51 are disposed to face the film 30. However, the upper air blowing head 51 may be omitted and the lower air blowing head 50 may be used for floating transportation. However, if the vibration resistance of the external disturbance is considered, it is preferable to provide the air blowing head up and down.

所述實施方式中,是作為針板拉幅機13的膜浮起裝置36而進行了說明,但不限於此,也可用於布鋏拉幅機14或其他膜搬送裝置。而且,不限於膜搬送,也可用於其他帶狀材料的浮起搬 送。 In the above embodiment, the film floating device 36 of the pin tenter 13 has been described. However, the present invention is not limited thereto, and may be used for the fabric tenter 14 or other film transporting device. Moreover, it is not limited to film transport, and can also be used for floating of other strip materials. give away.

本發明的溶液製膜設備10中,作為產品的膜的寬度優選為600mm以上,更優選為1400mm以上且2500mm以下。另外,在膜的寬度大於2500mm的情況下也有效。而且,膜的膜厚優選為15μm以上且80μm以下。作為聚合物膜的原料的聚合物不作特別限定,例如醯化纖維素或環狀聚烯烴等。 In the solution film forming apparatus 10 of the present invention, the width of the film as a product is preferably 600 mm or more, and more preferably 1400 mm or more and 2500 mm or less. In addition, it is also effective in the case where the width of the film is more than 2,500 mm. Further, the film thickness of the film is preferably 15 μm or more and 80 μm or less. The polymer which is a raw material of the polymer film is not particularly limited, and examples thereof include deuterated cellulose or cyclic polyolefin.

本發明的醯化纖維素中使用的醯基可僅為1種,或者也可使用2種以上的醯基。當使用2種以上的醯基時,優選其中之一為乙醯基。以羧酸將纖維素的羥基酯化的比例,也就是醯基的取代度優選滿足下述式(I)~式(III)的全部。另外,以下的式(I)~式(III)中,A及B表示醯基的取代度,A為乙醯基的取代度,而且B為碳原子數3~22的醯基的取代度。而且,三醋酸纖維素(Triacetyl Cellulose,TAC)的90重量%以上優選為0.1mm以上且4mm以下的粒子。 The mercapto group used in the deuterated cellulose of the present invention may be only one type, or two or more types of mercapto groups may be used. When two or more kinds of anthracenyl groups are used, one of them is preferably an ethyl group. The ratio of the esterification of the hydroxy group of the cellulose with a carboxylic acid, that is, the degree of substitution of the thiol group preferably satisfies all of the following formulas (I) to (III). Further, in the following formulae (I) to (III), A and B represent the degree of substitution of a mercapto group, A is a degree of substitution of an ethylidene group, and B is a degree of substitution of a mercapto group having 3 to 22 carbon atoms. Further, 90% by weight or more of Triacetyl Cellulose (TAC) is preferably 0.1 mm or more and 4 mm or less.

(I)2.0≦A+B≦3.0 (I) 2.0≦A+B≦3.0

(II)1.0≦A≦3.0 (II) 1.0≦A≦3.0

(III)0≦B≦2.9 (III)0≦B≦2.9

醯基的總取代度A+B更優選為2.20以上且2.90以下,特別優選為2.40以上且2.88以下。而且,碳原子數3~22的醯基的取代度B更優選為0.30以上,特別優選為0.5以上。 The total substitution degree A+B of the fluorenyl group is more preferably 2.20 or more and 2.90 or less, and particularly preferably 2.40 or more and 2.88 or less. Further, the degree of substitution B of the fluorenyl group having 3 to 22 carbon atoms is more preferably 0.30 or more, and particularly preferably 0.5 or more.

關於醯化纖維素的詳情,記載於日本專利特開2005-104148號的〔0140〕段落至〔0195〕段落。這些記載也適用 於本發明。而且,關於溶劑及增塑劑、劣化防止劑、紫外線吸收劑(UV劑)、光學異向性控制劑、延遲(retardation)控制劑、染料、消光劑、剝離劑、剝離促進劑等添加劑,也同樣詳細地記載於日本專利特開2005-104148號的〔0196〕段落至〔0516〕段落中。 The details of the deuterated cellulose are described in paragraphs [0140] to [0195] of JP-A-2005-104148. These records also apply In the present invention. Further, additives such as a solvent, a plasticizer, a deterioration preventive agent, an ultraviolet absorber (UV agent), an optical anisotropy control agent, a retardation control agent, a dye, a matting agent, a release agent, and a peeling accelerator are also used. Also described in detail in paragraphs [0196] to [0516] of Japanese Patent Laid-Open No. 2005-104148.

為了確認本發明的膜浮起裝置36造成的效果,而如圖13所示使用試驗機78進行試驗。首先,將帶狀膜79的一端固定於夾具80,另一端上安裝著砝碼81,以輥82水平支撐帶狀膜79。以夾著該帶狀膜79的方式,在帶狀膜79的下方配置下部送風頭50,在帶狀膜79的上方配置上部送風頭51,將下部送風頭50及上部送風頭51作為一組而在膜搬送方向(長邊方向)上排列3組來作為1個單元。向該1個單元的各下部送風頭50及上部送風頭51通入空氣,而使帶狀膜79浮起。帶狀膜79使用厚度25μm、寬度1800mm的TAC膜。 In order to confirm the effect by the film floating device 36 of the present invention, the test was performed using the testing machine 78 as shown in FIG. First, one end of the strip film 79 is fixed to the jig 80, and the weight 81 is attached to the other end, and the strip film 79 is horizontally supported by the roller 82. The lower air blowing head 50 is disposed below the belt-shaped film 79 so that the upper air blowing head 51 is disposed above the belt-shaped film 79, and the lower air blowing head 50 and the upper air blowing head 51 are grouped as a group. In the film transport direction (longitudinal direction), three groups are arranged as one unit. Air is supplied to the lower air blowing head 50 and the upper air blowing head 51 of the one unit, and the belt-shaped film 79 is floated. As the strip film 79, a TAC film having a thickness of 25 μm and a width of 1800 mm was used.

[實施例] [Examples]

(實驗1) (Experiment 1)

實驗1中,使用具有噴嘴板55的圖3所示的下部送風頭50及上部送風頭51,該噴嘴板55包含排列有多個直徑D1為2.5mm的吹出孔55b且將每單位面積的開口率設為10%的沖孔板。於噴嘴板55上且沿膜搬送方向以間距P為500mm而設置4個排氣槽61。將排氣槽61的長度L2配合帶狀膜79的寬度而設為1800mm,排氣槽61的寬度W2設為150mm,高度H2設為45mm。 比(W2/P)為0.3。導引板64的相對於噴嘴面55a的傾斜角度θ 1設為6°。排氣間隙66的開口寬度W3設為4mm,其開口面積設為7200mm2。氣體吹出壓力P0設為90Pa,從噴嘴面55a到帶狀膜79為止的距離即浮起高度HF設為90mm。 In Experiment 1, the lower air blowing head 50 and the upper air blowing head 51 shown in Fig. 3 having the nozzle plate 55 including a plurality of blowing holes 55b having a diameter D1 of 2.5 mm and openings per unit area were used. The rate is set to 10% punching plate. Four exhaust grooves 61 are provided on the nozzle plate 55 in the film conveying direction at a pitch P of 500 mm. The length L2 of the exhaust groove 61 was set to 1800 mm in accordance with the width of the strip film 79, the width W2 of the exhaust groove 61 was 150 mm, and the height H2 was set to 45 mm. The ratio (W2/P) is 0.3. The inclination angle θ 1 of the guide plate 64 with respect to the nozzle face 55a is set to 6°. The opening width W3 of the exhaust gap 66 was set to 4 mm, and the opening area was set to 7200 mm 2 . The gas discharge pressure P0 was set to 90 Pa, and the distance from the nozzle surface 55a to the strip film 79, that is, the floating height HF was set to 90 mm.

向下部送風頭50及上部送風頭51供給乾燥風。首先,利用來自下部送風頭50的乾燥風的吹出,而使帶狀膜79浮起。而且,利用來自上部送風頭51的乾燥風的吹出,抑制帶狀膜79向上方的鼓起,而減小浮起量U1。因此,考慮帶狀膜79的自重而將下部送風頭50的送風量設定成可使帶狀膜79浮起的風量。而且,上部送風頭51的送風量中吹出壓力為5Pa左右。而且,在浮起量U1大的情況下,緩慢提高上部送風頭51的送風量(例如,為下部送風頭50的送風量的1/5左右)。另外,以浮起量U1與浮起量變動△U相加所得的量(U1+△U)處於小於下部送風頭50及上部送風頭51的間隙{2×(HF-H2)}的範圍內的方式,來設定送風量。由此,帶狀膜79不會接觸到下部送風頭50及上部送風頭51。 Dry air is supplied to the lower air blowing head 50 and the upper air blowing head 51. First, the strip film 79 is floated by the blowing of the dry air from the lower air blowing head 50. Then, by the blowing of the dry air from the upper air blowing head 51, the upward movement of the belt-shaped film 79 is suppressed, and the floating amount U1 is reduced. Therefore, the amount of air blown from the lower air blowing head 50 is set to the amount of air that can float the belt-shaped film 79 in consideration of the own weight of the strip-shaped film 79. Further, the blowing pressure of the air blowing amount of the upper air blowing head 51 is about 5 Pa. Further, when the floating amount U1 is large, the air blowing amount of the upper air blowing head 51 is gradually increased (for example, about 1/5 of the air blowing amount of the lower air blowing head 50). Further, the amount (U1 + ΔU) obtained by adding the floating amount U1 and the floating amount variation ΔU is smaller than the gap {2 × (HF - H2)} of the lower air blowing head 50 and the upper air blowing head 51. Way to set the air supply volume. Thereby, the strip film 79 does not come into contact with the lower air blowing head 50 and the upper air blowing head 51.

以從噴嘴面55a噴出的氣流充分衰減後的距離(從噴嘴面55a離開20mm的位置),使用長野計器(股)製造的壓力感測器GC30測定噴嘴面55a附近的風壓。同樣地,在帶狀膜79的附近(從圖8所示的基準面30b離開5mm的位置)配置感測器來測定帶狀膜79下的風壓。 The air pressure in the vicinity of the nozzle surface 55a is measured by a pressure sensor GC30 manufactured by a Nagano meter (a), which is sufficiently attenuated by the airflow ejected from the nozzle surface 55a (a position separated by 20 mm from the nozzle surface 55a). Similarly, a sensor was placed in the vicinity of the strip film 79 (a position separated from the reference surface 30b shown in FIG. 8 by 5 mm) to measure the wind pressure under the strip film 79.

帶狀膜79的振動試驗使用應變計(strain gauge)85與個 人電腦86來進行測定。個人電腦86中安裝有應用程式,該應用程式用以根據來自應變計85的信號,將應變振動高速傅裏葉變換(Fast Fourier Transform,FFT)而進行頻率解析,並測定振動的波峰。應變計85貼附於帶狀膜79的長度方向及寬度方向的中央部。使用該應變計85,測定因風壓變動而振動的帶狀膜79的振動數,根據其振動波峰的大小,分4個等級進行評價。應變計85使用東京測器研究所(股)製造的YEFLA-2。而且,作為利用應變振動而求出振動波峰的應用程式,使用利用FFT對應變變動值進行頻率解析的巨集(macro)。而且,圖8中的浮起量U1及浮起量變動△U使用基恩斯(KEYENCE)股份有限公司製造的雷射位移計LKG-3000進行測定 The vibration test of the strip film 79 uses a strain gauge 85 and a The human computer 86 performs the measurement. An application program is installed in the personal computer 86 for performing frequency analysis based on a signal from the strain gauge 85 by means of a Fourier Transform (FFT), and measuring the peak of the vibration. The strain gauge 85 is attached to the center portion of the strip film 79 in the longitudinal direction and the width direction. Using the strain gauge 85, the number of vibrations of the strip-shaped film 79 vibrated by the fluctuation of the wind pressure was measured, and the vibration peaks were evaluated in four levels. The strain gauge 85 used YEFLA-2 manufactured by Tokyo Institute of Testing Instruments. Further, as an application for obtaining a vibration peak by strain vibration, a macro that performs frequency analysis using an FFT corresponding variable value is used. Further, the floating amount U1 and the floating amount variation ΔU in Fig. 8 were measured using a laser displacement meter LKG-3000 manufactured by KEYENCE Co., Ltd.

外擾耐受性試驗在帶狀膜79的長度方向中央位置,根據在與膜面30a正交的鉛垂方向上,將作為下部送風頭50及上部送風頭51的間隙的90mm的振幅施加一次時的到膜振動衰減為止的時間s(秒),來分等級進行評價。 The external disturbance tolerance test is applied to the center position in the longitudinal direction of the strip film 79, and the amplitude of 90 mm which is the gap between the lower air blowing head 50 and the upper air blowing head 51 is applied once in the vertical direction orthogonal to the film surface 30a. The time s (seconds) until the film vibration was attenuated was evaluated in stages.

(實驗2) (Experiment 2)

實驗2除使用如圖9所示將排氣槽71的隔板70向內側傾斜的送風頭72以外,設為與實驗1相同的條件。隔板70相對於鉛垂線的傾斜角度θ 2設為10°,排氣溝65的排氣間隙66的開口寬度W3設為4mm。 In the experiment 2, the same conditions as in Experiment 1 were used except that the air blowing head 72 in which the partition plate 70 of the exhaust groove 71 was inclined inward was used as shown in FIG. The inclination angle θ 2 of the partition plate 70 with respect to the vertical line is set to 10°, and the opening width W3 of the exhaust gap 66 of the exhaust groove 65 is set to 4 mm.

(實驗3) (Experiment 3)

實驗3除使用如圖10所示的具有長度不同的導引板 74a、導引板74b的排氣槽74以外,設為與實驗1相同的條件。 Experiment 3 except that the guide plates having different lengths as shown in FIG. 10 were used. 74a and the exhaust groove 74 of the guide plate 74b were set to the same conditions as the experiment 1.

(實驗4) (Experiment 4)

實驗4除使用如圖11所示具有以向內側凸出的方式彎曲的導引板77a、導引板77b的排氣槽77以外,設為與實驗1相同的條件。 In the experiment 4, the same conditions as in Experiment 1 were used except that the guide groove 77a and the guide groove 77b which were bent so as to protrude inward as shown in Fig. 11 were used.

(實驗5) (Experiment 5)

實驗5除使用如圖12所示將具有吹出孔75b的噴嘴板75相對於水平線傾斜而設為山形的送風頭76以外,設為與實驗1相同的條件。吹出孔75b的直徑為2.5mm,每單位面積的開口率為10%,噴嘴板75的相對於水平線的傾斜角度設為30°。 In the experiment 5, the same conditions as those in Experiment 1 were used except that the nozzle plate 75 having the blowing holes 75b was inclined with respect to the horizontal line to form a mountain-shaped air blowing head 76 as shown in FIG. The diameter of the blow hole 75b is 2.5 mm, the aperture ratio per unit area is 10%, and the inclination angle of the nozzle plate 75 with respect to the horizontal line is set to 30°.

(實驗6) (Experiment 6)

實驗6使用如圖14所示具有噴嘴板100的多孔送風頭101,該噴嘴板100是從圖3的下部送風頭50及上部送風頭51去除排氣槽61並於整個面形成多個吹出孔100a。除此以外設為與實驗1相同的條件。噴嘴板100的吹出孔100a的直徑D1為2.5mm,其每單位面積的開口率設為10%。 In Experiment 6, a porous air blowing head 101 having a nozzle plate 100 as shown in Fig. 14 was used, and the nozzle plate 100 was removed from the lower air blowing head 50 and the upper air blowing head 51 of Fig. 3, and a plurality of blowing holes were formed on the entire surface. 100a. Other than the above, the same conditions as in Experiment 1 were set. The diameter D1 of the blowing hole 100a of the nozzle plate 100 was 2.5 mm, and the aperture ratio per unit area was set to 10%.

(實驗7) (Experiment 7)

實驗7使用如圖15所示將噴嘴106沿膜搬送方向以間距P為500mm而配置4列所得的送風頭110,該噴嘴106在膜寬方向上具有狹縫狀開口105。除此以外設為與實驗1相同的條件。 In the experiment 7, the air blowing head 110 obtained by arranging four rows of the nozzles 106 in the film conveying direction at a pitch P of 500 mm as shown in Fig. 15 having the slit-like opening 105 in the film width direction was used. Other than the above, the same conditions as in Experiment 1 were set.

(實驗8) (Experiment 8)

實驗8代替實驗7的具有狹縫狀開口105的噴嘴106,而 使用如圖16所示將噴嘴116沿膜搬送方向以間距P為500mm而配置4列所得的凹凸狀的送風頭120,該噴嘴116在開口位置具有多個吹出孔115b的直徑D1為2.5mm且每單位面積的開口率為10%的噴嘴板115。除此以外設為與實驗1相同的條件。 Experiment 8 replaces the nozzle 106 of the slit 7 having the slit-like opening 105, and As shown in FIG. 16 , the nozzles 116 are arranged in four rows in the film transport direction at a pitch P of 500 mm, and the nozzles 116 have a plurality of blow holes 115 b having a diameter D1 of 2.5 mm at the opening position. The nozzle plate 115 having an opening ratio per unit area of 10%. Other than the above, the same conditions as in Experiment 1 were set.

將實施結果表示於下述的表1中。 The results of the implementation are shown in Table 1 below.

膜振動試驗的評價基準設為,“A”為超過0με且為100με以下,“B”為超過100με且為250με以下,“C”為超過250με且為400με以下,“D”為超過400με。該膜振動試驗的結果在實驗1中為50με,為優(A)。而且,在實驗2中為110με,為良(B)。在實驗3中為60με,為優(A)。在實驗4中為45με,為優(A)。在實驗5中為200με,為良(B)。在實驗6中為300με,為不合格(C),在實驗7中為550με,為不合格(D),在實驗8中為300με,為不合格(C)。另外,實驗6、實驗8的評價(C)是對膜厚25μm且膜寬1800mm的薄且寬的膜的評價,隨著膜厚變厚且膜寬也變窄,對於例如膜厚60μm、膜寬1800mm這樣的有一些厚度的膜,則有符合標準的可能性,從而成為與實驗7的不合格(D)的評價不同的評價。 The evaluation criteria of the membrane vibration test are such that "A" is more than 0 με and is 100 με or less, "B" is more than 100 με and is 250 με or less, "C" is more than 250 με and is 400 με or less, and "D" is more than 400 με. The results of the film vibration test were 50 με in Experiment 1, which was excellent (A). Further, in Experiment 2, it was 110 με, which was good (B). In Experiment 3, it was 60 με, which was excellent (A). In Experiment 4, it was 45 με, which was excellent (A). In Experiment 5, it was 200 με, which was good (B). In Experiment 6, it was 300 με, which was unacceptable (C), and in Experiment 7, it was 550 με, which was unacceptable (D), and in Experiment 8, it was 300 με, which was unacceptable (C). Further, the evaluation (C) of Experiments 6 and 8 is an evaluation of a thin and wide film having a film thickness of 25 μm and a film width of 1800 mm, and the film thickness is also narrowed as the film thickness is increased, for example, a film thickness of 60 μm or a film. A film having a thickness of 1800 mm and having a certain thickness has a possibility of conforming to the standard, and thus is different from the evaluation of the failure (D) of Experiment 7.

外擾耐受性試驗的評價基準設為A為超過0且為20s(秒)以下,B為超過20s且為50s以下,C為超過50s且為120s以下,D為超過120s或振動不會衰減。該外擾耐受性試驗的結果為,在實驗1中為10s,為優(A)。而且,在實驗2中為30s,為良(B)。在實驗3、實驗4中為10s,為優(A)。在實驗5中為30s,為良(B)。在實驗6中為65s,為不合格(C),在實驗7中為振動增大而不衰減的結果,為不合格(D),在實驗8中為180s,為不合格(D)。另外,實驗6的評價(C)是對於膜厚25μm、膜寬1800mm的薄且寬的膜的評價,隨著膜厚例如厚至60μm左右,而且隨著膜寬變窄,在實用級別上有符合標準的可能性,從 而成為與實驗7、實驗8的不合格(D)的評價不同的評價。 The evaluation criteria of the external disturbance tolerance test are such that A is more than 0 and is less than 20 s (seconds), B is more than 20 s and is 50 s or less, C is more than 50 s and is 120 s or less, D is more than 120 s or vibration is not attenuated. . The result of the external disturbance tolerance test was 10 s in Experiment 1, which was excellent (A). Moreover, in Experiment 2, it was 30 s, which was good (B). In Experiment 3 and Experiment 4, it was 10 s, which was excellent (A). In Experiment 5, it was 30 s, which was good (B). In Experiment 6, it was 65 s, which was unacceptable (C), and in Experiment 7, the vibration was increased without attenuating, and it was unsatisfactory (D), and in Experiment 8, it was 180 s, which was unacceptable (D). Further, the evaluation (C) of Experiment 6 is an evaluation of a thin and wide film having a film thickness of 25 μm and a film width of 1800 mm, and the film thickness is, for example, as thick as about 60 μm, and as the film width is narrowed, there is a practical level. The possibility of meeting the standard, from On the other hand, it was evaluated differently from the evaluation of the failure (D) of Experiment 7 and Experiment 8.

根據所述實驗1~實驗8,獲得排氣槽的形狀不同的情況下的評價。而且,膜振動試驗及外擾耐受性試驗中,將評價均為良(B)以上的實驗或其中一個試驗的評價為不合格(C)而另一個試驗的評價為良(B)的實驗綜合評價為良,除此以外為不合格。該結果,實驗1~實驗5為良,實驗6~實驗8為不合格。 According to Experiments 1 to 8, the evaluations in the case where the shapes of the exhaust grooves were different were obtained. Further, in the membrane vibration test and the external disturbance tolerance test, an experiment in which the evaluation is good (B) or more or the evaluation of one of the tests is unqualified (C) and the evaluation of the other test is good (B) The overall evaluation was good, and otherwise it was unqualified. As a result, Experiments 1 to 5 were good, and Experiments 6 to 8 were unqualified.

(實驗11~實驗13) (Experiment 11 ~ Experiment 13)

實驗11~實驗13中,使用實驗1的下部送風頭50來確認氣體吹出壓力P0的適當範圍。改變氣體吹出壓力P0而進行所述膜振動試驗及外擾耐受性試驗。實驗11除將氣體吹出壓力P0變為30Pa以外設為與實驗1大致相同的條件。如果氣體吹出壓力P0變化則噴嘴附近壓力P1、膜下壓力P2、及他們的差(P2-P1)發生變化,因而難以說與實驗1為完全相同的條件,從而使用大致相同的條件這樣的表達。以下的各實驗也同樣。實驗12除將氣體吹出壓力P0變為150Pa以外設為與實驗1大致相同的條件。實驗13除將氣體吹出壓力P0變為155Pa以外,設為與實驗1大致相同的條件。將實驗結果表示於下述表2中。根據這些實驗11~實驗13而判明氣體吹出壓力P0的適當範圍為30Pa以上且150Pa以下。 In Experiments 11 to 13, the lower range of the gas blowing pressure P0 was confirmed using the lower air blowing head 50 of Experiment 1. The film vibration test and the external disturbance tolerance test were carried out by changing the gas blowing pressure P0. In the experiment 11, the conditions similar to those of the experiment 1 were set except that the gas blowing pressure P0 was changed to 30 Pa. If the gas discharge pressure P0 changes, the pressure near the nozzle P1, the sub-membrane pressure P2, and their difference (P2-P1) change, so it is difficult to say that the conditions are exactly the same as those in Experiment 1, and the expressions using substantially the same conditions are used. . The following experiments are also the same. In the experiment 12, the conditions similar to those of the experiment 1 were set except that the gas blowing pressure P0 was changed to 150 Pa. In the experiment 13, the conditions similar to those in Experiment 1 were set except that the gas blowing pressure P0 was changed to 155 Pa. The experimental results are shown in Table 2 below. From these experiments 11 to 13, it was found that the appropriate range of the gas blowing pressure P0 is 30 Pa or more and 150 Pa or less.

(實驗21~實驗23) (Experiment 21 ~ Experiment 23)

實驗21~實驗23中,使用實驗1的下部送風頭50,改變噴嘴附近壓力P1而進行膜振動試驗及外擾耐受性試驗,並確認 噴嘴附近壓力P1的適當範圍。實驗21除將噴嘴附近壓力P1變為5Pa以外設為與實驗1大致相同的條件。然而,為了改變噴嘴附近壓力P1,而變更氣體吹出壓力P0。伴隨該變更,膜下壓力P2、他們的差(P2-P1)相對於實驗1發生了變化。實驗22除將噴嘴附近壓力P1設為40Pa,並為此改變氣體吹出壓力P0以外設為與實驗1大致相同的條件。同樣地,實驗23除將噴嘴附近壓力P1設為45Pa,並為此也改變氣體吹出壓力P0以外,設為與實驗1大致相同。將實驗結果表示於下述表2。根據這些實驗21~實驗23而判明,噴嘴附近壓力P1的適當範圍為5Pa以上且40Pa以下。 In Experiments 21 to 23, the lower air blowing head 50 of Experiment 1 was used to change the pressure P1 near the nozzle to perform a membrane vibration test and an external disturbance tolerance test, and confirmed The appropriate range of pressure P1 near the nozzle. In Experiment 21, the conditions similar to those of Experiment 1 were set except that the pressure P1 near the nozzle was changed to 5 Pa. However, in order to change the pressure P1 near the nozzle, the gas blowing pressure P0 is changed. With this change, the sub-film pressure P2 and their difference (P2-P1) changed with respect to Experiment 1. In Experiment 22, except that the pressure P1 in the vicinity of the nozzle was set to 40 Pa, and the gas blowing pressure P0 was changed for this purpose, substantially the same conditions as in Experiment 1 were employed. Similarly, Experiment 23 was set to be substantially the same as Experiment 1 except that the pressure P1 in the vicinity of the nozzle was set to 45 Pa, and the gas blowing pressure P0 was also changed for this purpose. The experimental results are shown in Table 2 below. From these experiments 21 to 23, it was found that the appropriate range of the pressure P1 near the nozzle was 5 Pa or more and 40 Pa or less.

(實驗31~實驗33) (Experiment 31 ~ Experiment 33)

實驗31~實驗33中,使用實驗1的下部送風頭50,改變膜下壓力P2而進行膜振動試驗及外擾耐受性試驗,並確認膜下壓力P2的適當範圍。實驗31除將膜下壓力P2變為5Pa以外設為與實驗1大致相同的條件。然而,為了改變膜下壓力P2,而要變更氣體吹出壓力P0。伴隨該變更,噴嘴附近壓力P1、他們的差(P2-P1)相對於實驗1發生了變化。實驗32除將膜下壓力P2設為40Pa,並為此改變氣體吹出壓力P0以外,設為與實驗1大致相同的條件。同樣地,實驗33除將膜下壓力P2設為45Pa,並為此也改變了氣體吹出壓力P0以外,設為與實驗1大致相同。將實驗結果表示於下述表2中。根據這些實驗31~實驗33而判明膜下壓力P2的適當範圍為5Pa以上且40Pa以下。 In Experiments 31 to 33, the lower air blowing head 50 of Experiment 1 was used, and the film pressure test and the external disturbance resistance test were performed by changing the film pressure P2, and the appropriate range of the film pressure P2 was confirmed. In the experiment 31, substantially the same conditions as in Experiment 1 were carried out except that the sub-film pressure P2 was changed to 5 Pa. However, in order to change the sub-film pressure P2, the gas blowing pressure P0 is changed. With this change, the pressure P1 near the nozzle and their difference (P2-P1) changed with respect to Experiment 1. In the experiment 32, except that the film lower pressure P2 was set to 40 Pa, and the gas blowing pressure P0 was changed for this purpose, substantially the same conditions as in Experiment 1 were employed. Similarly, Experiment 33 was set to be substantially the same as Experiment 1 except that the film lower pressure P2 was set to 45 Pa, and the gas blowing pressure P0 was also changed for this purpose. The experimental results are shown in Table 2 below. From these experiments 31 to 33, it was found that the appropriate range of the sub-film pressure P2 was 5 Pa or more and 40 Pa or less.

(實驗41~實驗43) (Experiment 41 ~ Experiment 43)

實驗41~實驗43中,使用實驗1的下部送風頭50,改變比(W2/P)而進行膜振動試驗及外擾耐受性試驗,並確認比(W2/P)的適當範圍。實驗41除將比(W2/P)變為0.3以外設為與實驗1相同的條件。然而,改變比(W2/P)但將浮起高度HF設為固定,因而氣體吹出壓力P0或噴嘴附近壓力P1、膜下壓力P2、差(P2-P1)也發生了改變。實驗42除將比(W2/P)變為0.4以外設為與實驗41相同的條件。同樣地實驗43除將比(W2/P)變為0.05以外設為與實驗41相同的條件。然而,以與實驗41同樣的方式改變比(W2/P)但將浮起高度HF設為固定,因而氣體吹出壓力P0或噴嘴附近壓力P1、膜下壓力P2、差(P2-P1)也發生了改變。將實驗結果表示於下述表3中。根據這些實驗1、實驗41~實驗43而判明比(W2/P)的適當範圍為0.1以上且0.3以下。 In the experiment 41 to the experiment 43, the lower air blowing head 50 of the experiment 1 was used, and the film vibration test and the external disturbance resistance test were carried out by changing the ratio (W2/P), and the appropriate range of the ratio (W2/P) was confirmed. In Experiment 41, the same conditions as in Experiment 1 were set except that the ratio (W2/P) was changed to 0.3. However, the ratio (W2/P) is changed but the floating height HF is set to be fixed, and thus the gas blowing pressure P0 or the pressure near the nozzle P1, the sub-film pressure P2, and the difference (P2-P1) are also changed. In the experiment 42, the same conditions as in Experiment 41 were set except that the ratio (W2/P) was changed to 0.4. Similarly, Experiment 43 was set to the same conditions as Experiment 41 except that the ratio (W2/P) was changed to 0.05. However, the ratio (W2/P) was changed in the same manner as in Experiment 41, but the floating height HF was set to be fixed, and thus the gas blowing pressure P0 or the pressure near the nozzle P1, the sub-membrane pressure P2, and the difference (P2-P1) also occurred. Changed. The experimental results are shown in Table 3 below. From the results of Experiment 1 and Experiment 41 to Experiment 43, the appropriate range of the ratio (W2/P) was 0.1 or more and 0.3 or less.

另外,未特別進行確認噴嘴附近壓力P1、膜下壓力P2的壓力差(P2-P1)的適當範圍的實驗。然而,根據所述各實驗的結果判明當壓力差(P2-P1)為2Pa以下時,膜振動或外擾耐受性良。 Further, an experiment for confirming an appropriate range of the pressure difference (P2-P1) between the pressure P1 near the nozzle and the pressure P2 under the membrane was not particularly performed. However, it was found from the results of the respective experiments that when the pressure difference (P2-P1) was 2 Pa or less, the film vibration or external disturbance was well tolerated.

30‧‧‧濕潤膜 30‧‧‧ Wet film

30a‧‧‧膜面 30a‧‧‧film surface

49‧‧‧乾燥空氣 49‧‧‧ Dry air

50‧‧‧送風頭 50‧‧‧Air head

55‧‧‧噴嘴板 55‧‧‧Nozzle plate

55a‧‧‧噴嘴面 55a‧‧・Nozzle surface

55b‧‧‧吹出孔 55b‧‧‧Blow out the hole

55c‧‧‧安裝端緣部 55c‧‧‧Installation edge

56‧‧‧底板 56‧‧‧floor

56a‧‧‧膜搬送方向中央部 56a‧‧‧The central part of the film transport direction

56b‧‧‧連結部 56b‧‧‧Linking Department

57‧‧‧側板 57‧‧‧ side panels

57a‧‧‧管連接筒 57a‧‧‧ tube connector

58‧‧‧端板 58‧‧‧End board

60‧‧‧氣流控制排氣部 60‧‧‧Air control exhaust

61‧‧‧排氣槽 61‧‧‧Exhaust trough

62‧‧‧底板 62‧‧‧floor

63‧‧‧隔板 63‧‧‧Baffle

64‧‧‧導引板 64‧‧‧Guideboard

65‧‧‧排氣溝 65‧‧‧Exhaust ditch

66‧‧‧排氣間隙 66‧‧‧Exhaust clearance

67‧‧‧側板 67‧‧‧ side panels

68‧‧‧排氣口 68‧‧‧Exhaust port

D1‧‧‧直徑 D1‧‧‧ diameter

H2‧‧‧高度 H2‧‧‧ Height

HF‧‧‧浮起高度 HF‧‧‧Floating height

L1‧‧‧長度 L1‧‧‧ length

P‧‧‧間距 P‧‧‧ spacing

W2‧‧‧排氣槽的寬度 W2‧‧‧ vent width

W3‧‧‧排氣間隙的開口寬度 W3‧‧‧ opening width of the exhaust gap

W4‧‧‧噴嘴面的寬度 W4‧‧·The width of the nozzle face

X‧‧‧方向 X‧‧‧ direction

θ 1‧‧‧傾斜角度 θ 1‧‧‧ tilt angle

Claims (11)

一種膜浮起裝置,其特徵在於包括:送風頭,具有噴嘴面,所述噴嘴面與帶狀的膜的膜面相向而配置,且配置有多個可朝向所述膜面吹出氣體的吹出孔;以及氣流控制排氣部,沿著所述膜的寬度方向而配置於所述噴嘴面,且用以將來自所述吹出孔的氣體向所述膜的側方排出。 A film floating device comprising: a blowing head having a nozzle surface, wherein the nozzle surface is disposed to face a film surface of a strip-shaped film, and a plurality of blowing holes for blowing a gas toward the film surface are disposed And a gas flow control exhaust portion disposed on the nozzle surface along a width direction of the film and configured to discharge gas from the blowing hole to a side of the film. 如申請專利範圍第1項所述的膜浮起裝置,其中:在所述膜的搬送方向上,所述噴嘴面與所述氣流控制排氣部交替配置。 The film floating device according to claim 1, wherein the nozzle face and the airflow control exhausting portion are alternately arranged in a conveying direction of the film. 如申請專利範圍第2項所述的膜浮起裝置,其中:當將所述膜的搬送方向上的所述噴嘴面的長度設為W4,所述膜的搬送方向上的所述氣流控制排氣部的長度設為W2,所述氣流控制排氣部的所述膜的搬送方向上的間距設為P時,所述長度W2與所述間距P之比(W2/P)為0.1以上且0.3以下,其中間距P=長度W2+長度W4。 The film floating device according to claim 2, wherein the length of the nozzle surface in the conveying direction of the film is set to W4, and the airflow control row in the conveying direction of the film When the length of the gas portion is W2 and the pitch in the transport direction of the film of the air flow control exhaust portion is P, the ratio (W2/P) of the length W2 to the pitch P is 0.1 or more. 0.3 or less, wherein the pitch P = the length W2 + the length W4. 如申請專利範圍第3項所述的膜浮起裝置,其中:所述氣流控制排氣部包括排氣槽以及排氣口,所述排氣槽包括:1對隔板,朝向所述膜面突出,且彼此在膜搬送方向上隔開而配置;1對導引板,在所述1對隔板之間,從其中一個所述隔板的突出端朝向另一個所述隔板的基端傾斜地連接於所述隔板;以及 排氣間隙,設置於所述1對導引板的前端之間;所述排氣口在所述排氣槽的膜寬方向的兩側開口。 The membrane floating device of claim 3, wherein: the airflow control exhaust portion includes an exhaust slot and an exhaust port, the exhaust slot comprising: a pair of partitions facing the membrane surface Projecting and being spaced apart from each other in the film transport direction; a pair of guide plates between the pair of baffles, from the projecting end of one of the baffles toward the base end of the other of the baffles Tiltly connected to the partition; and An exhaust gap is provided between the front ends of the pair of guide plates; the exhaust ports are open on both sides in the film width direction of the exhaust grooves. 如申請專利範圍第4項所述的膜浮起裝置,其中包括:堵塞所述排氣槽的膜寬方向兩端的側板、以及形成於所述側板的排氣孔,且由所述排氣孔構成所述排氣口。 The film floating device of claim 4, comprising: a side plate that blocks both ends of the exhaust groove in the film width direction, and a vent hole formed in the side plate, and the vent hole The exhaust port is configured. 如申請專利範圍第1項至第5項中任一項所述的膜浮起裝置,其中:所述吹出孔中的氣體的吹出壓力為30Pa以上且150Pa以下,從所述吹出孔到所述膜為止的距離為20mm以上且100mm以下。 The film floating device according to any one of claims 1 to 5, wherein a gas discharge pressure of the gas in the blowing hole is 30 Pa or more and 150 Pa or less, from the blowing hole to the The distance from the film is 20 mm or more and 100 mm or less. 如申請專利範圍第6項所述的膜浮起裝置,其中:從所述噴嘴面離開20mm的位置的壓力及從所述膜面離開5mm的位置的壓力為5Pa以上且40Pa以下。 The film floating device according to claim 6, wherein the pressure at a position separated from the nozzle surface by 20 mm and the pressure at a position separated from the film surface by 5 mm are 5 Pa or more and 40 Pa or less. 如申請專利範圍第7項所述的膜浮起裝置,其中:從所述噴嘴面離開20mm的位置的壓力與從所述膜面離開5mm的位置的壓力之差為2Pa以下。 The film floating device according to claim 7, wherein a difference between a pressure at a position separated from the nozzle surface by 20 mm and a pressure at a position separated from the film surface by 5 mm is 2 Pa or less. 一種拉幅機,其特徵在於包括:如申請專利範圍第1項至第8項中任一項所述的膜浮起裝置;以及膜搬送裝置,利用保持部來保持所述膜的兩側緣部,並使所述保持部沿所述膜的搬送方向循環移動而搬送所述膜,所述氣體是用以使所述膜中的溶劑蒸發的經過溫度調節的乾 燥空氣。 A tenter comprising: the film lifting device according to any one of claims 1 to 8; and a film conveying device for holding both sides of the film by a holding portion And conveying the film by circulating the holding portion in a conveying direction of the film, the gas being a temperature-regulated dry for evaporating a solvent in the film Dry air. 一種溶液製膜設備,其特徵在於包括:流延裝置,在移行的環形的支撐體之上,流延包含聚合物及溶劑的濃液而形成帶狀的流延膜後,將所述流延膜作為濕潤膜而從所述支撐體剝取;如申請專利範圍第9項所述的拉幅機,保持並搬送從所述流延裝置搬送的所述濕潤膜;以及乾燥裝置,將從所述拉幅機搬送的所述濕潤膜乾燥。 A solution film forming apparatus, comprising: a casting device, casting a strip-shaped cast film on a traveling annular support body after casting a dope comprising a polymer and a solvent, and casting the film The film is stripped from the support as a wet film; the tenter according to claim 9 holds and transports the wet film conveyed from the casting device; and a drying device The wet film conveyed by the tenter is dried. 一種溶液製膜方法,其特徵在於包括:流延步驟,在移行的環形的支撐體之上,流延包含聚合物及溶劑的濃液而形成帶狀的流延膜後,將所述流延膜作為濕潤膜而從所述支撐體剝取;膜搬送步驟,利用保持部來保持經過所述流延步驟的所述濕潤膜的兩側緣部,並搬送所述濕潤膜;拉幅步驟,利用送風頭本體將乾燥氣體從具有多個吹出孔的噴嘴面朝向所述膜搬送步驟中的所述濕潤膜的膜面吹出,由此使所述濕潤膜乾燥,在該乾燥中,利用在所述濕潤膜的搬送方向上隔開且沿著所述濕潤膜的寬度方向而配置於所述噴嘴面的氣流控制排氣部,將碰到所述膜面後的所述乾燥氣體向所述濕潤膜的側方排出;以及乾燥步驟,將經過所述拉幅步驟的所述濕潤膜乾燥。 A solution film forming method, comprising: a casting step of casting a dope containing a polymer and a solvent onto a traveling annular support body to form a strip-shaped cast film, and then casting the film The film is peeled off from the support as a wet film; in the film transfer step, both sides of the wet film passing through the casting step are held by the holding portion, and the wet film is conveyed; and the tentering step, The drying gas is blown from the nozzle surface having the plurality of blowing holes toward the film surface of the wet film in the film transporting step by the air blowing head main body, whereby the wet film is dried, and the drying is utilized in the drying. An air flow control exhaust portion that is disposed in the transport direction of the wet film and that is disposed along the width direction of the wet film on the nozzle surface, and the dry gas that has hit the film surface is wetted The side of the film is discharged; and a drying step of drying the wet film through the tentering step.
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