TW201313592A - Control device of moving direction of circular belt, casting apparatus, and solution casting method - Google Patents
Control device of moving direction of circular belt, casting apparatus, and solution casting method Download PDFInfo
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- TW201313592A TW201313592A TW101131216A TW101131216A TW201313592A TW 201313592 A TW201313592 A TW 201313592A TW 101131216 A TW101131216 A TW 101131216A TW 101131216 A TW101131216 A TW 101131216A TW 201313592 A TW201313592 A TW 201313592A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/24—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
- B29C41/28—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length by depositing flowable material on an endless belt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
- B29C41/52—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/0074—Production of other optical elements not provided for in B29D11/00009- B29D11/0073
- B29D11/00788—Producing optical films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2001/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
- B29K2001/08—Cellulose derivatives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2011/00—Optical elements, e.g. lenses, prisms
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
本發明係有關一種環狀帶的移動方向控制裝置、流延設備及溶液製膜方法。 The present invention relates to a moving direction control device for an endless belt, a casting device, and a solution film forming method.
具有透光性之聚合物薄膜(以下稱為薄膜)為輕質且易成型,所以作為光學薄膜被廣泛利用。其中,利用纖維素醯化物等之纖維素酯類薄膜除了用作照片感光用薄膜之外,還用作液晶顯示裝置的光學薄膜。作為液晶顯示裝置的光學薄膜,有偏光板保護薄膜或相位差薄膜等。 A translucent polymer film (hereinafter referred to as a film) is lightweight and easy to mold, and thus is widely used as an optical film. Among them, a cellulose ester film using a cellulose halide or the like is used as an optical film of a liquid crystal display device in addition to a film for photo-sensing. As the optical film of the liquid crystal display device, there are a polarizing plate protective film or a retardation film.
藉由溶液製膜方法製造薄膜。溶液製膜方法為具有如下各製程之方法。首先,使用配設於流延室內之流延模,朝向已進行溫度調節之移動之支撐體流出聚合物溶液(以下稱為濃液(dope)),並在支撐體上形成帶狀流延膜(以下稱為膜形成製程)。濃液包括聚合物和溶劑。接著,從流延膜蒸發溶劑直至能夠傳送流延膜(以下稱為膜乾燥製程)。之後,從支撐體剝下能夠傳送之流延膜作為濕潤薄膜(以下稱為剝離製程)。並且,從該濕潤薄膜蒸發溶劑作為薄膜(以下稱為薄膜乾燥製程)。 A film is produced by a solution film forming method. The solution film forming method is a method having the following processes. First, using a casting die disposed in a casting chamber, a polymer solution (hereinafter referred to as a dope) is discharged toward a support that has undergone temperature adjustment, and a tape cast film is formed on the support. (hereinafter referred to as a film formation process). The dope includes a polymer and a solvent. Next, the solvent is evaporated from the casting film until a cast film can be transferred (hereinafter referred to as a film drying process). Thereafter, the cast film which can be conveyed is peeled off from the support as a wet film (hereinafter referred to as a peeling process). Further, the solvent is evaporated from the wet film as a film (hereinafter referred to as a film drying process).
作為用於該溶液製膜方法之支撐體,已知有架設於複數個輥並循環移動之環狀帶。由於能夠藉由使用該環狀帶來反覆進行膜形成製程、膜乾燥製程及剝離製程,因此作為結果能夠提高薄膜的生產效率。 As a support for the solution forming method of the solution, an endless belt which is stretched over a plurality of rolls and circulated and moved is known. Since the film formation process, the film drying process, and the peeling process can be repeatedly performed by using the annular band, the production efficiency of the film can be improved as a result.
但是,若長時間進行溶液製膜方法,則有時導致環狀 帶偏離預定環狀路(環狀移動路)。若在環狀帶偏離環狀路之狀態下進行溶液製膜方法,則導致所獲得之薄膜的均勻性受損。薄膜的均勻性中尤其是寬度方向上的厚度、表面狀態、光學特性的均勻性受損。 However, if the solution film forming method is carried out for a long period of time, it may cause a ring shape. The belt is offset from the predetermined annular path (annular moving path). When the solution film forming method is performed in a state where the endless belt is deviated from the annular path, the uniformity of the obtained film is impaired. Among the uniformity of the film, in particular, the thickness in the width direction, the surface state, and the uniformity of optical characteristics are impaired.
作為調節環狀帶的移動方向之方法,例如已知有如日本專利公開2002-254452號公報或日本專利公開平10-202722號公報中記載使捲繞有環狀帶之驅動滾筒或從動滾筒移變之發明。 As a method of adjusting the moving direction of the endless belt, for example, it is known that the driving roller or the driven roller wound with the endless belt is moved as disclosed in Japanese Patent Laid-Open Publication No. 2002-254452 or Japanese Patent Laid-Open No. Hei 10-202722. Change the invention.
然而,日本專利公開2002-254452號公報、日本專利公開平10-202722號公報的環狀帶的移動方向的控制方法中,在以下(1)~(3)情況下導致環狀帶的移動方向的控制精確度下降。其結果不僅導致環狀帶難以返回到環狀路,而且還導致環狀帶更大幅偏離環狀路。 In the method of controlling the moving direction of the endless belt of the Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei 10-202722, the movement direction of the endless belt is caused by the following (1) to (3). The accuracy of the control is reduced. As a result, not only is the endless belt difficult to return to the annular path, but also the annular band is more deviated from the annular path.
(1)以提高溶液製膜方法的生產效率等為目的,提高環狀帶的移動速度之情況。 (1) For the purpose of improving the production efficiency of the solution film forming method, the moving speed of the endless belt is increased.
(2)產生環狀帶的移動速度的變動之情況。 (2) A case where a change in the moving speed of the endless belt occurs.
(3)反覆進行膜形成製程、膜乾燥製程及剝離製程期間的環狀帶的溫度的變動量較大之情況。 (3) The amount of change in the temperature of the endless belt during the film formation process, the film drying process, and the peeling process is repeated.
如此,要求一種能夠更可靠地將移動之環狀帶限制於環狀路之環狀帶的移動方向控制方法。 Thus, a moving direction control method capable of more reliably restricting a moving endless belt to an endless belt of an annular path is required.
本發明之目的在於提供一種與環狀帶的移動速度的大小、環狀帶的移動速度的變動及環狀帶的溫度的變動量等無關,能夠將移動之環狀帶更可靠地限制於環狀路之環狀 帶的移動方向控制裝置、流延設備及溶液製膜方法。 An object of the present invention is to provide a ring-shaped belt that can be moved more reliably to the ring regardless of the magnitude of the moving speed of the endless belt, the fluctuation of the moving speed of the endless belt, and the amount of fluctuation in the temperature of the endless belt. Ring of the road Belt movement direction control device, casting device and solution film forming method.
本發明的環狀帶的移動方向控制裝置為具備導引機構且控制環狀帶的移動方向之環狀帶的移動方向控制裝置。環狀帶捲繞於以水平且相互平行地配設之驅動滾筒及從動滾筒,並藉由驅動滾筒的旋轉來移動。導引機構導引環狀帶的寬度方向端面。導引機構配設於環狀帶所移動之環狀移動路中下方部份的寬度方向兩外側。 The moving direction control device for the endless belt of the present invention is a moving direction control device that includes a guide mechanism and controls an endless belt in a moving direction of the endless belt. The endless belt is wound around a driving roller and a driven roller which are disposed horizontally and in parallel with each other, and are moved by the rotation of the driving roller. The guiding mechanism guides the end surface in the width direction of the endless belt. The guiding mechanism is disposed on both outer sides in the width direction of the lower portion of the annular moving path in which the endless belt moves.
導引機構設置成在與移動路靠近之靠近位置與遠離前述靠近位置之退避位置之間移動自如為較佳。導引機構為具備輥主體和輥軸之導引輥更為佳。輥主體在周面上導引環狀帶的寬度方向端面。輥軸對輥主體進行軸支撐。在輥主體的周面形成導引環狀帶的寬度方向端面之支撐槽為進一步較佳。 It is preferable that the guiding mechanism is disposed to be movable between a position close to the moving path and a retracted position away from the approaching position. The guiding mechanism is preferably a guide roller having a roller body and a roller shaft. The roller body guides the end surface in the width direction of the endless belt on the circumferential surface. The roller shaft axially supports the roller body. It is further preferable to form a support groove for guiding the end surface in the width direction of the endless belt on the circumferential surface of the roller main body.
導引機構向移動路的寬度方向上的中央側被施力為較佳。導引機構為具備輥主體與輥軸之導引輥更為佳。輥主體在周面上導引環狀帶的寬度方向端面。輥軸對輥主體進行軸支撐。在輥主體的周面形成導引環狀帶的寬度方向端面之支撐槽為進一步較佳。 It is preferable that the guiding mechanism is biased toward the center side in the width direction of the moving path. The guiding mechanism is preferably a guide roller having a roller body and a roller shaft. The roller body guides the end surface in the width direction of the endless belt on the circumferential surface. The roller shaft axially supports the roller body. It is further preferable to form a support groove for guiding the end surface in the width direction of the endless belt on the circumferential surface of the roller main body.
導引機構具備一端側導引件與另一端側導引件為較佳。一端側導引件配設於移動路的寬度方向的一端側。另一端側導引件配設於移動路的寬度方向的另一端側。一端側導引件與另一端側導引件在環狀帶的移動方向上交替配設。 The guiding mechanism is preferably provided with one end side guide and the other end side guide. The one end side guide is disposed on one end side in the width direction of the moving path. The other end side guide is disposed on the other end side in the width direction of the moving path. The one end side guide and the other end side guide are alternately arranged in the moving direction of the endless belt.
一端側導引件及另一端側導引件排列成隨著從從動滾 筒朝向驅動滾筒而向移動路的寬度方向中央部靠近為較佳。 One end side guide and the other end side guide are arranged to follow the slave roll It is preferable that the cylinder approaches the drive roller and approaches the center portion in the width direction of the movement path.
環狀帶的移動方向控制裝置進一步具備從動滾筒移變部、偏離方向檢測部及從動滾筒姿勢控制部為較佳。從動滾筒移變部使從動滾筒在第1姿勢與第2姿勢之間移變。第1姿勢為從動滾筒的一端比另一端更接近驅動滾筒之姿勢。第2姿勢為從動滾筒的另一端比一端更接近前述驅動滾筒之姿勢。偏離方向檢測部檢測環狀帶偏離移動路之方向。從動滾筒姿勢控制部依據偏離方向檢測部檢測之偏離方向控制從動滾筒移變部。 The moving direction control device for the endless belt further preferably includes a driven roller shifting portion, an off-direction detecting portion, and a driven roller posture controlling portion. The driven roller shifting portion shifts the driven roller between the first posture and the second posture. The first posture is a posture in which one end of the driven roller is closer to the driving roller than the other end. The second posture is a posture in which the other end of the driven roller is closer to the driving roller than the one end. The deviation direction detecting unit detects the direction in which the endless belt deviates from the movement path. The driven drum posture control unit controls the driven drum shifting unit in accordance with the deviation direction detected by the deviation direction detecting unit.
驅動滾筒具備驅動滾筒主體和滾筒驅動軸為較佳。驅動滾筒主體由周面支撐環狀帶的背面。滾筒驅動軸對驅動滾筒主體進行軸支撐。驅動滾筒主體具有設置於寬度方向中央部之小徑滾筒部和設置於寬度方向兩端部之大徑滾筒部。移動路設定於小徑滾筒部的周面上。 The drive roller is preferably provided with a drive roller body and a drum drive shaft. The driving roller body supports the back surface of the endless belt by the circumferential surface. The drum drive shaft axially supports the drive drum body. The drive roller main body has a small-diameter roller portion provided at a central portion in the width direction and a large-diameter roller portion provided at both end portions in the width direction. The moving path is set on the circumferential surface of the small diameter roller portion.
本發明的流延設備為在環狀帶上形成由濃液構成之膜之流延設備。流延設備具備流延模、驅動滾筒、從動滾筒、環狀帶、膜乾燥裝置、剝離裝置及移動方向控制裝置。流延模流出濃液。濃液包括聚合物及溶劑。驅動滾筒以水平配設。從動滾筒以水平配設。從動滾筒配設成與驅動滾筒平行。環狀帶捲繞於驅動滾筒及從動滾筒,並藉由驅動滾筒的旋轉來移動。環狀帶具有支撐從流延模流出之濃液之支撐面。濃液從流延模朝向環狀帶中捲繞於驅動滾筒之部份流出。膜形成於支撐面上。膜乾燥裝置對膜吹送乾燥風 並從膜蒸發溶劑。剝離裝置從環狀帶剝離膜。移動方向控制裝置控制環狀帶的移動方向。移動方向控制裝置具備導引環狀帶的寬度方向端面之導引機構。導引機構配設於環狀帶所移動之環狀移動路中下方部份的寬度方向兩外側。 The casting apparatus of the present invention is a casting apparatus which forms a film composed of a dope on an endless belt. The casting apparatus includes a casting die, a driving roller, a driven roller, an endless belt, a film drying device, a peeling device, and a moving direction control device. The casting die flows out of the dope. The dope includes a polymer and a solvent. The drive rollers are arranged horizontally. The driven roller is horizontally arranged. The driven roller is disposed in parallel with the drive roller. The endless belt is wound around the drive roller and the driven roller and is moved by the rotation of the drive roller. The endless belt has a support surface that supports the concentrated liquid flowing out of the casting die. The dope flows out from the casting die toward the portion of the endless belt wound around the drive roller. The film is formed on the support surface. Membrane drying device blows dry air to the membrane And evaporate the solvent from the membrane. The peeling device peels off the film from the endless belt. The moving direction control device controls the moving direction of the endless belt. The movement direction control device includes a guide mechanism that guides the end surface in the width direction of the endless belt. The guiding mechanism is disposed on both outer sides in the width direction of the lower portion of the annular moving path in which the endless belt moves.
本發明的溶液製膜方法為由濃液製造薄膜之溶液製膜方法。溶液製膜方法具備膜形成步驟、膜乾燥步驟、剝離步驟及移動控制步驟。膜形成步驟在環狀帶上形成由濃液構成之膜。濃液包含聚合物及溶劑。環狀帶捲繞於驅動滾筒與從動滾筒並藉由驅動滾筒的旋轉來移動。驅動滾筒與從動滾筒以水平且相互平行地配設。環狀帶具有支撐從流延模流出之濃液之支撐面。濃液從流延模朝向環狀帶中捲繞於驅動滾筒之部份流出。膜乾燥步驟對支撐面上的膜吹送乾燥風並從膜蒸發溶劑。剝離步驟從環狀帶剝離經膜乾燥製程之膜。移動控制步驟利用移動方向控制裝置進行環狀帶的移動方向的控制。移動方向控制裝置具有導引環狀帶的寬度方向端面之導引機構。導引機構配設於環狀帶所移動之環狀移動路中下方部份的寬度方向兩外側。 The solution film forming method of the present invention is a film forming method of producing a film from a dope. The solution film forming method includes a film forming step, a film drying step, a peeling step, and a movement control step. The film forming step forms a film composed of a dope on the endless belt. The dope contains the polymer and solvent. The endless belt is wound around the drive roller and the driven roller and is moved by the rotation of the drive roller. The drive roller and the driven roller are disposed horizontally and in parallel with each other. The endless belt has a support surface that supports the concentrated liquid flowing out of the casting die. The dope flows out from the casting die toward the portion of the endless belt wound around the drive roller. The film drying step blows dry air to the film on the support surface and evaporates the solvent from the film. The stripping step strips the film of the film drying process from the endless belt. The movement control step controls the movement direction of the endless belt by the movement direction control means. The moving direction control device has a guiding mechanism that guides the end surface in the width direction of the endless belt. The guiding mechanism is disposed on both outer sides in the width direction of the lower portion of the annular moving path in which the endless belt moves.
依據本發明,與環狀帶的移動速度的大小、環狀帶的移動速度的變動、環狀帶的溫度的變動量等無關,能夠更可靠地將移動之環狀帶限制於環狀路。 According to the present invention, regardless of the magnitude of the moving speed of the endless belt, the fluctuation of the moving speed of the endless belt, the amount of fluctuation in the temperature of the endless belt, or the like, the moving endless belt can be more reliably restricted to the annular passage.
如圖1所示,溶液製膜設備10具有流延裝置15、夾子拉幅機17、乾燥裝置18及捲取裝置19。流延裝置15 由濃液12製作濕潤薄膜13。夾子拉幅機17藉由乾燥濕潤薄膜13來得到薄膜16。乾燥裝置18進一步乾燥薄膜16。捲取裝置19將薄膜16捲取在卷芯上。 As shown in FIG. 1, the solution film forming apparatus 10 has a casting device 15, a clip tenter 17, a drying device 18, and a winding device 19. Casting device 15 The wet film 13 is made of the dope 12. The clip tenter 17 obtains the film 16 by drying the wet film 13. Drying device 18 further dries film 16. The take-up device 19 winds the film 16 onto the core.
如圖2所示,流延裝置15具有殼體23、配設於殼體23內之流延裝置主體。流延裝置主體具有流延支撐單元、隔板單元、流延單元、膜乾燥單元及剝離構件。 As shown in FIG. 2, the casting apparatus 15 has a casing 23 and a casting apparatus main body disposed in the casing 23. The casting device main body has a casting support unit, a separator unit, a casting unit, a film drying unit, and a peeling member.
流延支撐單元具備:水平滾筒24、水平滾筒25,其在殼體23內以水平且相互平行地排列;流延帶26,其架設於水平滾筒24、水平滾筒25;及帶移動單元27(參閱圖3、圖4)。 The casting support unit includes: a horizontal drum 24 and a horizontal drum 25 which are horizontally and parallel to each other in the casing 23; the casting belt 26 is mounted on the horizontal drum 24, the horizontal drum 25, and the belt moving unit 27 ( See Figure 3, Figure 4).
如圖3所示,水平滾筒24具備驅動軸24A、固定於驅動軸24A之不銹鋼製滾筒主體24B及驅動軸的軸承(未圖示)。水平滾筒25具備轉動軸25A、固定於轉動軸25A之不銹鋼製滾筒主體25B及設置於轉動軸25A兩端之軸承25AS。水平滾筒24、水平滾筒25上捲繞環狀流延帶26。流延帶26藉由連結帶狀片材的兩端而獲得。 As shown in FIG. 3, the horizontal drum 24 is provided with a drive shaft 24A, a stainless steel drum main body 24B fixed to the drive shaft 24A, and a bearing (not shown) of the drive shaft. The horizontal drum 25 includes a rotating shaft 25A, a stainless steel drum main body 25B fixed to the rotating shaft 25A, and a bearing 25AS provided at both ends of the rotating shaft 25A. The annular casting belt 26 is wound around the horizontal drum 24 and the horizontal drum 25. The casting tape 26 is obtained by joining both ends of the strip-shaped sheet.
其中,水平是指水平滾筒24、水平滾筒25相對水平面之交叉角度分別為0°以上且0.05°以下。並且,平行是指水平滾筒24、水平滾筒25的交叉角度為0°以上且0.05°以下。 Here, the horizontal means that the angle of intersection of the horizontal drum 24 and the horizontal drum 25 with respect to the horizontal plane is 0° or more and 0.05° or less, respectively. Further, the parallel means that the intersection angle of the horizontal drum 24 and the horizontal drum 25 is 0° or more and 0.05° or less.
流延帶26為具有充份的耐腐蝕性與強度之不銹鋼(例如SUS316)製為較佳。流延帶26的寬度例如為濃液12 的流延寬度的1.1倍以上且2.0倍以下為較佳。流延帶26的長度例如為20m以上且200m以下為較佳。流延帶26的厚度例如為0.5mm以上~2.5mm以下為較佳。另外,關於流延帶26的厚度不均,使用相對於整體的厚度為0.5%以下者為較佳。並且,形成流延膜之表面(以下稱為流延面)26A和與滾筒主體24B、滾筒主體25B相接觸之背面26B平坦地形成。尤其是流延面26A被研磨為較佳,流延面26A的表面粗糙度為0.05μm以下為較佳。 The casting tape 26 is preferably made of stainless steel (for example, SUS316) having sufficient corrosion resistance and strength. The width of the casting belt 26 is, for example, a dope 12 It is preferable that the casting width is 1.1 times or more and 2.0 times or less. The length of the casting belt 26 is preferably 20 m or more and 200 m or less, for example. The thickness of the casting belt 26 is preferably 0.5 mm or more to 2.5 mm or less. Further, it is preferable that the thickness of the casting tape 26 is not uniform, and the thickness is 0.5% or less with respect to the entire thickness. Further, a surface (hereinafter referred to as a casting surface) 26A on which the casting film is formed and a back surface 26B which is in contact with the drum main body 24B and the drum main body 25B are formed flat. In particular, the casting surface 26A is preferably polished, and the surface roughness of the casting surface 26A is preferably 0.05 μm or less.
如圖3及圖4所示,帶移動單元27具備使捲繞於水平滾筒24、水平滾筒25之流延帶26移動之帶移動部28、限制流延帶26的移動方向之帶移動方向控制部29及控制部30。 As shown in FIGS. 3 and 4, the belt moving unit 27 includes a belt moving portion 28 for moving the casting belt 26 wound around the horizontal drum 24 and the horizontal drum 25, and a belt moving direction control for restricting the moving direction of the casting belt 26. The unit 29 and the control unit 30.
帶移動部28具備驅動用馬達28M、軸位移部28AS及力量感測器28LC。 The belt moving unit 28 includes a drive motor 28M, a shaft displacement unit 28AS, and a force sensor 28LC.
驅動用馬達28M與驅動軸24A連接。控制部30控制驅動用馬達28M,以預定的速度旋轉滾筒主體24B。流延帶26隨著滾筒主體24B的旋轉向預定的方向循環移動,滾筒主體25B隨著流延帶26的移動而旋轉。以下,將流延帶26的移動方向稱為X方向,將流延帶26的寬度方向稱為Y方向,將垂直方向稱為Z方向。 The drive motor 28M is connected to the drive shaft 24A. The control unit 30 controls the drive motor 28M to rotate the drum main body 24B at a predetermined speed. The casting belt 26 is cyclically moved in a predetermined direction as the drum main body 24B rotates, and the drum main body 25B rotates as the casting belt 26 moves. Hereinafter, the moving direction of the casting tape 26 is referred to as the X direction, the width direction of the casting tape 26 is referred to as the Y direction, and the vertical direction is referred to as the Z direction.
流延帶26的流延面26A的移動速度V26A為150m/分鐘以下為較佳。若移動速度V26A超過150m/分鐘,則難以穩定形成液珠。關於移動速度V26A的下限值,考慮目標薄膜的生產率即可。移動速度V26A的下限值例如為10m/分 鐘。 The moving speed V 26A of the casting surface 26A of the casting belt 26 is preferably 150 m/min or less. If the moving speed V 26A exceeds 150 m/min, it is difficult to stably form the bead. Regarding the lower limit of the moving speed V 26A , the productivity of the target film may be considered. The lower limit of the moving speed V 26A is, for example, 10 m/min.
驅動軸24A在張力外加位置與鬆弛位置之間移動自如。張力外加位置為對架設於滾筒主體24B、滾筒主體25B之流延帶26外加預定移動張力之位置。鬆弛位置為架設於滾筒主體24B、滾筒主體25B之流延帶26鬆弛之位置。軸位移部28AS在控制部30的控制下在張力外加位置與鬆弛位置之間對驅動軸24A進行移變。軸位移部28AS為維持與轉動軸25A平行之狀態的同時使驅動軸24A移變為較佳。 The drive shaft 24A is freely movable between a tension applied position and a relaxed position. The tension applied position is a position at which a predetermined moving tension is applied to the casting belt 26 which is mounted on the drum main body 24B and the drum main body 25B. The slack position is a position where the casting belt 26 that is stretched over the drum main body 24B and the drum main body 25B is slack. The shaft displacement portion 28AS shifts the drive shaft 24A between the tension applied position and the slack position under the control of the control unit 30. The shaft displacement portion 28AS preferably moves the drive shaft 24A while maintaining the state parallel to the rotation shaft 25A.
力量感測器28LC安裝於驅動軸24A。力量感測器28LC檢測驅動軸24A所承受之外力。控制部30從力量感測器28LC讀取驅動軸24A所承受之外力。接著,控制部30依據讀取之外力及內置之流延帶26的截面積值控制軸位移部28AS,以便施加於流延帶26之移動張力成為預定者。如此,能夠在Y方向上對流延帶26外加相同的移動張力。 The force sensor 28LC is mounted to the drive shaft 24A. The force sensor 28LC detects the external force that the drive shaft 24A is subjected to. The control unit 30 reads the force received by the drive shaft 24A from the force sensor 28LC. Next, the control unit 30 controls the shaft displacement portion 28AS in accordance with the external force of reading and the cross-sectional area value of the built-in casting tape 26 so that the moving tension applied to the casting tape 26 becomes a predetermined one. In this way, the same moving tension can be applied to the casting belt 26 in the Y direction.
帶移動方向控制部29具有滾筒擺動機構35和帶導引機構36。滾筒擺動機構35按照流延帶26偏離移動路26R之方向擺動水平滾筒25。帶導引機構36導引流延帶26的Y方向兩端面。 The belt movement direction control unit 29 has a drum swing mechanism 35 and a belt guide mechanism 36. The drum swinging mechanism 35 swings the horizontal drum 25 in a direction in which the casting belt 26 is displaced from the moving path 26R. The tape guiding mechanism 36 guides both end faces of the casting tape 26 in the Y direction.
滾筒擺動機構35具備偏離檢測部35K和軸承位移部35S。偏離檢測部35K感測流延帶26已偏離移動路26R。 軸承位移部35S使1對軸承25AS分別獨立向X方向移動。 The drum swinging mechanism 35 is provided with an offset detecting portion 35K and a bearing displacement portion 35S. The deviation detecting portion 35K senses that the casting tape 26 has deviated from the moving path 26R. The bearing displacement portion 35S moves the pair of bearings 25AS independently in the X direction.
偏離檢測部35K設置於乾燥室23B。偏離檢測部35K具備設置於流延帶26的一端側之一端偏離檢測部35KP和設置於流延帶26的另一端側之另一端偏離檢測部35KQ。 The deviation detecting unit 35K is provided in the drying chamber 23B. The deviation detecting unit 35K includes one end deviation detecting unit 35KP provided on one end side of the casting belt 26 and the other end detecting unit 35KQ provided on the other end side of the casting belt 26.
如圖5所示,一端偏離檢測部35KP具備發光部40PA和受光部40PB。發光部40PA內置光源,向外部射出來自光源的檢查光。受光部40PB內置能夠對檢查光進行受光之光感測器,光感測器判斷是否已檢測來自發光部40PA的檢查光。當受光部40PB感測到檢查光時,受光部40PB輸出檢測信號。發光部40PA及受光部40PB設置成從發光部40PA到受光部40PB的檢查光的光路40PX通過預先設定之流延帶26的移動路26R的Y方向的一端。 As shown in FIG. 5, the one end deviation detecting portion 35KP includes a light emitting portion 40PA and a light receiving portion 40PB. The light emitting unit 40PA has a built-in light source and emits inspection light from the light source to the outside. The light receiving unit 40PB incorporates a photosensor capable of receiving the inspection light, and the photo sensor determines whether or not the inspection light from the light emitting unit 40PA has been detected. When the light receiving unit 40PB senses the inspection light, the light receiving unit 40PB outputs a detection signal. The light-emitting portion 40PA and the light-receiving portion 40PB are provided so that the optical path 40PX of the inspection light from the light-emitting portion 40PA to the light-receiving portion 40PB passes through one end of the movement path 26R of the casting tape 26 set in advance in the Y direction.
另一端偏離檢測部35KQ與一端偏離檢測部35KP相同地具備發光部40QA和受光部40QB。發光部40QA內置光源,向外部射出來自光源的檢查光。受光部40QB內置能夠對檢查光進行受光之光感測器,光感測器判斷是否已檢測到來自發光部40QA的檢查光。當受光部40QB檢測到檢查光時,受光部40QB輸出檢測信號。發光部40QA及受光部40QB設置成從發光部40QA到受光部40QB的檢查光的光路40QX通過預先設定之流延帶26的移動路26R的Y方向的另一端。 The other end deviation detecting unit 35KQ includes the light emitting unit 40QA and the light receiving unit 40QB in the same manner as the one end deviation detecting unit 35KP. The light-emitting unit 40QA has a built-in light source and emits inspection light from the light source to the outside. The light receiving unit 40QB incorporates a photo sensor capable of receiving the inspection light, and the photo sensor determines whether or not the inspection light from the light emitting unit 40QA has been detected. When the light receiving unit 40QB detects the inspection light, the light receiving unit 40QB outputs a detection signal. The light-emitting unit 40QA and the light-receiving unit 40QB are provided so that the optical path 40QX of the inspection light from the light-emitting unit 40QA to the light-receiving unit 40QB passes through the other end of the movement path 26R of the casting belt 26 set in advance in the Y direction.
移動路26R為在Y方向上預先設定且捲繞於水平滾筒24、水平滾筒25之流延帶26的基準路徑,其形成為環狀。移動路26R的寬度係流延帶26的寬度加上預定的游隙寬 度者。 The movement path 26R is a reference path which is set in advance in the Y direction and is wound around the casting belt 26 of the horizontal drum 24 and the horizontal drum 25, and is formed in a ring shape. The width of the moving path 26R is the width of the casting tape 26 plus a predetermined clearance width. Degree.
返回圖3及圖4,軸承位移部35S具備使一端側的軸承25AS移動之一端側軸承位移部35SP和使另一端側的軸承25AS移動之另一端側軸承位移部35SQ。一端側軸承位移部35SP及另一端側軸承位移部35SQ在控制部30的控制下分別獨立向預定方向移動軸承25AS。 Referring back to FIG. 3 and FIG. 4, the bearing displacement portion 35S includes one end side bearing displacement portion 35SP for moving the one end side bearing 25AS and the other end side bearing displacement portion 35SQ for moving the other end side bearing 25AS. The one end side bearing displacement portion 35SP and the other end side bearing displacement portion 35SQ independently move the bearing 25AS in a predetermined direction under the control of the control unit 30.
控制部30進行偏離方向判斷處理。偏離方向判斷處理中,首先,控制部30判斷是否從受光部40PB、受光部40QB(參閱圖5)輸出檢測信號。並且,當判斷為從受光部40PB、受光部40QB(參閱圖5)雙方輸出檢測信號時,控制部30判斷流延帶26處於移動路26R上。另一方面,當判斷為從受光部40QB(參閱圖5)輸出檢測信號且未從受光部40PB(參閱圖5)輸出檢測信號時,控制部30判斷流延帶26從移動路26R向一端側偏離。並且,當判斷為從受光部40PB(參閱圖5)輸出檢測信號且未從受光部40QB(參閱圖5)輸出檢測信號時,控制部30判斷流延帶26從移動路26R向另一端側偏離。 The control unit 30 performs a deviation direction determination process. In the deviation direction determination processing, first, the control unit 30 determines whether or not the detection signal is output from the light receiving unit 40PB and the light receiving unit 40QB (see FIG. 5). When it is determined that the detection signals are output from both the light receiving unit 40PB and the light receiving unit 40QB (see FIG. 5), the control unit 30 determines that the casting tape 26 is on the movement path 26R. On the other hand, when it is determined that the detection signal is output from the light receiving unit 40QB (see FIG. 5) and the detection signal is not output from the light receiving unit 40PB (see FIG. 5), the control unit 30 determines that the casting tape 26 is from the movement path 26R to the one end side. Deviation. When it is determined that the detection signal is output from the light receiving unit 40PB (see FIG. 5) and the detection signal is not output from the light receiving unit 40QB (see FIG. 5), the control unit 30 determines that the casting tape 26 is deviated from the movement path 26R toward the other end side. .
並且,控制部30依據偏離方向判斷處理的結果進行對水平滾筒25的姿勢進行調節之從動滾筒移變處理。從動滾筒移變處理中,控制部30依據偏離方向判斷處理的結果控制軸承位移部35S。例如,判斷為流延帶26處於移動路26R內時,控制部30以轉動軸25A與驅動軸24A平行之方式控制一端側軸承位移部35SP及另一端側軸承位移部35SQ。將與驅動軸24A平行之位置設為基準位置(參閱圖 6)。另一方面,當判斷流延帶26從移動路26R向一端側偏離時,以轉動軸25A的一端側比轉動軸25A的另一端側更遠離驅動軸24A之方式控制一端側軸承位移部35SP及另一端側軸承位移部35SQ(參閱圖7)。相反,當判斷流延帶26從移動路26R向另一端側偏離時,以轉動軸25A的另一端側比轉動軸25A的一端側更遠離驅動軸24A之方式控制一端側軸承位移部35SP及另一端側軸承位移部35SQ(參閱圖8)。 Further, the control unit 30 performs a slave drum shifting process for adjusting the posture of the horizontal drum 25 in accordance with the result of the deviation direction determining process. In the driven drum shifting process, the control unit 30 controls the bearing displacement portion 35S in accordance with the result of the deviation direction determining process. For example, when it is determined that the casting belt 26 is in the moving path 26R, the control unit 30 controls the one end side bearing displacement portion 35SP and the other end side bearing displacement portion 35SQ such that the rotation shaft 25A is parallel to the drive shaft 24A. The position parallel to the drive shaft 24A is set as the reference position (see the figure). 6). On the other hand, when it is determined that the casting belt 26 is displaced from the movement path 26R toward the one end side, the one end side bearing displacement portion 35SP and the one end side of the rotation shaft 25A are further away from the drive shaft 24A than the other end side of the rotation shaft 25A. The other end side bearing displacement portion 35SQ (see Fig. 7). On the other hand, when it is judged that the casting belt 26 is displaced from the moving path 26R to the other end side, the one end side bearing displacement portion 35SP and the other are controlled such that the other end side of the rotating shaft 25A is farther from the driving shaft 24A than the one end side of the rotating shaft 25A. One end side bearing displacement portion 35SQ (see Fig. 8).
如圖9及圖10所示,帶導引機構36配設於移動路26R的Y方向兩外側。帶導引機構36具有一端側導引輥36PA~36PB和另一端側導引輥36QA~36QC。一端側導引輥36PA~36PB為配設於移動路26R中下方部份的Y方向一端側之一端側導引件。另一端側導引輥36QA~36QC為配設於移動路26R中下方部份的Y方向另一端側之另一端側導引件。其中,移動路26R中下方部份是指從捲繞於滾筒主體25B之流延帶26遠離滾筒主體25B之位置P25(參閱圖2)到朝向滾筒主體24B移動之流延帶26與滾筒主體24B接觸之位置P24(參閱圖2)之間。一端側導引輥36PA、一端側導引輥36PB從X方向上游側依次朝向下游側配設。相同道理,另一端側導引輥36QA、另一端側導引輥36QB、另一端側導引輥36QC從X方向上游側依次朝向下游側配設。 As shown in FIGS. 9 and 10, the tape guiding mechanism 36 is disposed on both outer sides in the Y direction of the moving path 26R. The tape guiding mechanism 36 has one end side guide rollers 36PA to 36PB and the other end side guide rollers 36QA to 36QC. The one end side guide rollers 36PA to 36PB are one end side guides disposed on one end side in the Y direction of the lower portion of the movement path 26R. The other end side guide rollers 36QA to 36QC are the other end side guides disposed on the other end side in the Y direction of the lower portion of the movement path 26R. Here, the lower portion of the moving path 26R refers to the casting belt 26 and the drum main body 24B which are moved from the position P25 (refer to FIG. 2) of the casting belt 26 wound around the drum main body 25B away from the drum main body 25B to the drum main body 24B. Contact position P24 (see Figure 2). The one end side guide roller 36PA and the one end side guide roller 36PB are disposed in order from the upstream side in the X direction toward the downstream side. In the same manner, the other end side guide roller 36QA, the other end side guide roller 36QB, and the other end side guide roller 36QC are disposed in order from the upstream side in the X direction toward the downstream side.
並且,各導引輥36PA~36PB、各導引輥36QA~36QC 在X方向上交替配設為較佳。藉此,能夠使施加於流延帶26之力成為最小限度的同時,以限制於移動路26R的方式導引流延帶26。 Moreover, each of the guide rollers 36PA~36PB and each guide roller 36QA~36QC It is preferable to alternately arrange in the X direction. Thereby, the casting belt 26 can be guided so as to be limited to the movement path 26R while minimizing the force applied to the casting belt 26.
如圖10及圖11所示,另一端側導引輥36QA具備導引輥主體51和導引輥軸52。導引輥主體51在周面51S上導引流延帶26的Y方向的帶端面26E。導引輥軸52對導引輥主體51進行軸支撐。導引輥軸52向Z方向延設。導引輥主體51或導引輥主體51的周面部由鐵氟龍(註冊商標)等材料形成為較佳。在導引輥主體51的周面51S上形成有對流延帶26的Y方向的帶端面26E進行導引之支撐槽51D為較佳。支撐槽51D向周向延設,且形成為環狀。支撐槽51D包括對流延帶26的Y方向的帶端面26E進行導引之底面51DD與側面51DS。 As shown in FIGS. 10 and 11, the other end side guide roller 36QA is provided with a guide roller main body 51 and a guide roller shaft 52. The guide roller main body 51 guides the belt end surface 26E of the casting belt 26 in the Y direction on the circumferential surface 51S. The guide roller shaft 52 axially supports the guide roller main body 51. The guide roller shaft 52 extends in the Z direction. The circumferential surface of the guide roller main body 51 or the guide roller main body 51 is preferably formed of a material such as Teflon (registered trademark). It is preferable that the support groove 51D for guiding the belt end surface 26E of the casting belt 26 in the Y direction is formed on the circumferential surface 51S of the guide roller main body 51. The support groove 51D is extended in the circumferential direction and formed in a ring shape. The support groove 51D includes a bottom surface 51DD and a side surface 51DS that guide the belt end surface 26E of the casting belt 26 in the Y direction.
並且,另一端側導引輥36QA可具備與導引輥軸52平行配設之擺動軸55和連結導引輥軸52及擺動軸55之連結臂56。連結臂56的一端部固設於導引輥軸52,另一端部軸支撐於擺動軸55。導引輥主體51藉由連結臂56在移動路26R中與Y方向的端部26RE靠近之靠近位置P1與從靠近位置P1退避之退避位置P2~P3之間擺動自如(參閱圖12)。退避位置P2為比靠近位置P1更靠X方向上游側,退避位置P3為比靠近位置P1更靠X方向下游側。能夠藉由擺動軸55及連結臂56使施加於流延帶26之力成為最小限度的同時,以限制於移動路26R內之方式對流延帶26進行導引。另外,可設置為了成為靠近位置P1而對導 引輥主體51進行施力之施力構件。 Further, the other end side guide roller 36QA may include a swing shaft 55 disposed in parallel with the guide roller shaft 52, and a coupling arm 56 that connects the guide roller shaft 52 and the swing shaft 55. One end of the connecting arm 56 is fixed to the guide roller shaft 52, and the other end is axially supported by the swing shaft 55. The guide roller main body 51 is swingable between the approaching position P1 in the moving path 26R and the retracted position P2 to P3 which is retracted from the approaching position P1 by the connecting arm 56 (see FIG. 12). The retracted position P2 is on the upstream side in the X direction from the approach position P1, and the retracted position P3 is on the downstream side in the X direction from the approach position P1. The casting belt 26 can be guided by the swing shaft 55 and the connecting arm 56 to minimize the force applied to the casting belt 26 while being restricted to the inside of the moving path 26R. In addition, it can be set to be close to the position P1 The ejector main body 51 performs a biasing force applying member.
另外,另一端側導引輥36QA可具有軸位移部61(參閱圖9及圖10)或彈簧62(參閱圖11)。軸位移部61使擺動軸55在Z方向上位移移動。彈簧62使導引輥主體51向Y方向中央側施力。控制部30控制軸位移部61,以便導引輥主體51成為如能夠由周面51S支撐流延帶26的Y方向的帶端面26E之位置(參閱圖4)。控制部30以防止流延帶26與側面51DS接觸的方式控制軸位移部61為較佳。彈簧62中,例如一端固著於擺動軸55,另一端固著於殼體23的內壁面23S。能夠藉由彈簧62使施加於流延帶26之力成為最小限度的同時,以限制於移動路26R內的方式對流延帶26進行導引。 Further, the other end side guide roller 36QA may have a shaft displacement portion 61 (see FIGS. 9 and 10) or a spring 62 (see FIG. 11). The shaft displacement portion 61 moves the swing shaft 55 in the Z direction. The spring 62 biases the guide roller main body 51 toward the center side in the Y direction. The control unit 30 controls the shaft displacement portion 61 so that the guide roller main body 51 is positioned to support the belt end surface 26E of the casting belt 26 in the Y direction by the circumferential surface 51S (see FIG. 4). The control unit 30 preferably controls the shaft displacement portion 61 so as to prevent the casting tape 26 from coming into contact with the side surface 51DS. In the spring 62, for example, one end is fixed to the swing shaft 55, and the other end is fixed to the inner wall surface 23S of the casing 23. The force applied to the casting tape 26 can be minimized by the spring 62, and the casting tape 26 can be guided to be restricted to the inside of the moving path 26R.
另外,由於一端側導引輥36PA~36PB及另一端側導引輥36QB~36QC具有與另一端側導引輥36QA相同的結構,所以省略詳細說明。 In addition, since the one end side guide rollers 36PA to 36PB and the other end side guide rollers 36QB to 36QC have the same configuration as the other end side guide roller 36QA, detailed description thereof will be omitted.
與導引輥主體51係配設於一端側者或者係配設於另一端側者無關,靠近位置P1處的導引輥主體51的支撐槽51D的底面51DD與移動路26R的Y方向端部26RE的間隔CL(參閱圖11)隨著從X方向上游側朝向下游側遞減為較佳。另外,間隔CL(參閱圖11)例如為0mm以上且20mm以下。例如關於圖9所示之另一端側導引輥36QA的間隔CLQA、關於一端側導引輥36PA的間隔CLPA、關於另一端側導引輥36QB的間隔CLQB、關於一端側導引輥36PB的間隔CLPB、及關於另一端側導引輥36QC的間隔 CLQC滿足關係式(1)為較佳。 Regardless of whether the guide roller main body 51 is disposed on one end side or is disposed on the other end side, the bottom surface 51DD of the support groove 51D of the guide roller main body 51 at the position P1 and the Y-direction end portion of the movement path 26R are not provided. The interval CL of the 26RE (see FIG. 11) is preferably decreased as it goes from the upstream side toward the downstream side in the X direction. Further, the interval CL (see FIG. 11) is, for example, 0 mm or more and 20 mm or less. For example, the interval CL QA of the other end side guide roller 36QA shown in Fig. 9, the interval CL PA with respect to the one end side guide roller 36PA, the interval CL QB with respect to the other end side guide roller 36QB, and the one end side guide roller It is preferable that the interval CL PB of 36 PB and the interval CL QC of the other end side guide roller 36QC satisfy the relational expression (1).
CLQA>CLPA>CLQB>CLPB>CLQC………關係式(1) CL QA >CL PA >CL QB >CL PB >CL QC .........Relationship (1)
返回圖2,隔板單元具備第1密封構件71~第3密封構件73。第1密封構件71~第3密封構件73在殼體23內從X方向上游側依次朝向下游側配設。第1密封構件71~第3密封構件73分別設置成從殼體23的內壁面突出且突端與流延帶26的流延面26A靠近。殼體23內亦即由殼體23的內壁面與流延面26A包圍之區段藉由第1密封構件71~第3密封構件73從X方向上游側朝向下游側隔成流延室23A、乾燥室23B及剝離室23C。並且,流延室23A的氣密性藉由第1密封構件71~第2密封構件72維持。並且,乾燥室23B的氣密性藉由第2密封構件72~第3密封構件73維持。第1密封構件71~第3密封構件73與流延面26A的間隔例如為1.5mm以上且2.0mm以下。 Referring back to FIG. 2 , the separator unit includes the first to third sealing members 71 to 73 . The first to third sealing members 71 to 73 are disposed in the casing 23 from the upstream side in the X direction toward the downstream side. Each of the first to third sealing members 71 to 73 is provided so as to protrude from the inner wall surface of the casing 23, and the projecting end is close to the casting surface 26A of the casting belt 26. In the casing 23, the section surrounded by the inner wall surface of the casing 23 and the casting surface 26A is separated into a casting chamber 23A from the upstream side toward the downstream side in the X direction by the first to third sealing members 71 to 73, Drying chamber 23B and peeling chamber 23C. Further, the airtightness of the casting chamber 23A is maintained by the first sealing member 71 to the second sealing member 72. Further, the airtightness of the drying chamber 23B is maintained by the second sealing member 72 to the third sealing member 73. The distance between the first sealing member 71 to the third sealing member 73 and the casting surface 26A is, for example, 1.5 mm or more and 2.0 mm or less.
在流延室23A內配設由濃液12(參閱圖1)形成流延膜76之流延單元。流延單元具備流延模77與減壓機78。流延模77具有流出濃液12(參閱圖1)之濃液流出口77A。流延模77配設於水平滾筒24的上方,以便流延帶26中捲繞於滾筒主體24B之部份與濃液流出口77A靠近。 A casting unit that forms the casting film 76 from the dope 12 (see FIG. 1) is disposed in the casting chamber 23A. The casting unit includes a casting die 77 and a pressure reducing machine 78. The casting die 77 has a dope outflow port 77A that flows out of the dope 12 (see Fig. 1). The casting die 77 is disposed above the horizontal drum 24 so that the portion of the casting belt 26 wound around the drum main body 24B is close to the dope outlet 77A.
流延模77從濃液流出口77A朝向流延帶26流出濃液12(參閱圖1)。從濃液流出口77A流出並到達流延面26A為止的濃液12(參閱圖1)形成液珠。到達流延面26A之 濃液12在X方向流延之結果形成帶狀的流延膜76。 The casting die 77 flows out of the dope 12 from the dope outlet 77A toward the casting belt 26 (see Fig. 1). The dope 12 (see FIG. 1) which flows out from the dope outlet 77A and reaches the casting surface 26A forms a bead. Reaching the casting surface 26A The dope 12 is cast in the X direction to form a strip-shaped cast film 76.
減壓機78係用於對液珠的X方向的上游側進行減壓者。減壓機78具有減壓室78A、減壓扇78B及吸引管78C。減壓室78A配置於比流延模77的濃液流出口77A更靠X方向上游側。減壓扇78B係用於吸引減壓室78A內的氣體者。吸引管78C連接減壓扇78B與減壓室78A。 The pressure reducer 78 is for decompressing the upstream side of the liquid droplet in the X direction. The pressure reducer 78 has a decompression chamber 78A, a decompression fan 78B, and a suction pipe 78C. The decompression chamber 78A is disposed on the upstream side in the X direction from the dope outlet 77A of the casting die 77. The decompression fan 78B is used to attract the gas in the decompression chamber 78A. The suction pipe 78C is connected to the pressure reducing fan 78B and the decompression chamber 78A.
在乾燥室23B內配設進行流延膜的乾燥之膜乾燥單元。膜乾燥單元具備向流延膜76供給預定乾燥風之第1乾燥機81~第2乾燥機82及乾燥控制機(未圖示)。第1乾燥機81~第2乾燥機82在乾燥室23B中從X方向上游側依次朝向下游側設置。第1乾燥機81配設於架設在水平滾筒24、水平滾筒25之流延帶26的上方。第2乾燥機82配設於架設在水平滾筒24、水平滾筒25之流延帶26的下方。 A film drying unit that performs drying of the cast film is disposed in the drying chamber 23B. The film drying unit includes a first dryer 81 to a second dryer 82 and a drying controller (not shown) that supply predetermined drying air to the casting film 76. The first dryer 81 to the second dryer 82 are disposed in order from the upstream side in the X direction toward the downstream side in the drying chamber 23B. The first dryer 81 is disposed above the casting belt 26 that is stretched over the horizontal drum 24 and the horizontal drum 25. The second dryer 82 is disposed below the casting belt 26 that is stretched over the horizontal drum 24 and the horizontal drum 25.
第1乾燥機81具備第1進氣導管81A和第1排氣導管81B。第1進氣導管81A與第1排氣導管81B從X方向上游側依次朝向下游側設置。第1進氣導管81A與第1排氣導管81B分別與流延帶26隔離而配設。第1進氣導管81A上設置送出第1乾燥風81DA之第1進氣口81AO。朝向X方向下游側開口之第1進氣口81AO從流延膜76的一端延設至另一端。第1排氣導管81B上設置排出第1乾燥風81DA之第1排氣口81BO。朝向X方向上游側開口之第1排氣口81BO從流延膜76的一端延設至另一端。 The first dryer 81 includes a first intake duct 81A and a first exhaust duct 81B. The first intake duct 81A and the first exhaust duct 81B are disposed in order from the upstream side in the X direction toward the downstream side. The first intake duct 81A and the first exhaust duct 81B are disposed apart from the casting belt 26, respectively. The first intake port 81A that sends out the first dry air 81DA is provided in the first intake duct 81A. The first intake port 81AO that opens toward the downstream side in the X direction extends from one end of the cast film 76 to the other end. The first exhaust port 81B that discharges the first dry air 81DA is provided in the first exhaust duct 81B. The first exhaust port 81BO that opens toward the upstream side in the X direction extends from one end of the casting film 76 to the other end.
第2乾燥機82具備第2排氣導管82A和第2進氣導管82B。第2排氣導管82A與第2進氣導管82B從X方向上游側依次朝向下游側設置。第2排氣導管82A及第2進氣導管82B分別與流延帶26隔離而配設。第2排氣導管82A上設置排出第2乾燥風82DA之第2排氣口82AO。朝向X方向下游側開口之第2排氣口82AO從流延膜76的一端延設至另一端。第2進氣導管82B上設置送出第2乾燥風82DA之第2進氣口82BO。朝向X方向上游側開口之第2進氣口82BO從流延膜76的一端延設至另一端。 The second dryer 82 includes a second exhaust duct 82A and a second intake duct 82B. The second exhaust duct 82A and the second intake duct 82B are provided in order from the upstream side in the X direction toward the downstream side. The second exhaust duct 82A and the second intake duct 82B are disposed apart from the casting belt 26, respectively. The second exhaust duct 82A is provided with a second exhaust port 82AO through which the second dry air 82DA is discharged. The second exhaust port 82AO that opens toward the downstream side in the X direction extends from one end of the casting film 76 to the other end. The second intake port 82BO that sends out the second dry air 82DA is provided in the second intake duct 82B. The second intake port 82BO that opens toward the upstream side in the X direction extends from one end of the cast film 76 to the other end.
乾燥控制機係獨立調節第1乾燥風81DA及第2乾燥風82DA的溫度或風速者。乾燥控制機具備第1調溫機~第2調溫機(未圖示)、調節第1乾燥風81DA及第2乾燥風82DA的風量之第1送風扇~第2送風扇(未圖示)及控制器(未圖示)。第1調溫機~第2調溫機調節第1乾燥風81DA及第2乾燥風82DA的溫度。第1調溫機~第2調溫機及第1送風扇~第2送風扇設置於第1乾燥機81~第2乾燥機82的各導管內。控制器控制第1調溫機~第2調溫機及第1送風扇~第2送風扇,並獨立調節關於第1乾燥風81DA及第2乾燥風82DA的溫度或風速。 The drying controller independently adjusts the temperature or wind speed of the first dry air 81DA and the second dry air 82DA. The first control fan to the second temperature control unit (not shown) and the first to fourth air fans (not shown) that adjust the air volume of the first dry air 81DA and the second dry air 82DA are provided. And controller (not shown). The first temperature control machine to the second temperature control unit adjust the temperatures of the first dry air 81DA and the second dry air 82DA. The first thermostat to the second thermostat and the first to second fan are provided in the respective ducts of the first dryer 81 to the second dryer 82. The controller controls the first temperature control unit to the second temperature control unit and the first to second power supply fans, and independently adjusts the temperature or the wind speed of the first dry air 81DA and the second dry air 82DA.
剝離室23C內配設作為剝離構件之剝離輥86。剝離輥86從流延帶26上剝離已成為能夠剝離狀態之流延膜76作為濕潤薄膜13,並從設置於剝離室23C之出口23CO送出濕潤薄膜13。 A peeling roller 86 as a peeling member is disposed in the peeling chamber 23C. The peeling roller 86 peels the cast film 76 which has been peeled off from the casting tape 26 as the wet film 13, and feeds the wet film 13 from the outlet 23CO provided in the peeling chamber 23C.
可將對殼體23內的氣氛中所含之溶劑進行冷凝之冷凝裝置、回收冷凝之溶劑之回收裝置設置於流延裝置15。藉此能夠將殼體23內的氣氛中所含之溶劑的濃度保持在恆定範圍內。 A condensing device that condenses the solvent contained in the atmosphere in the casing 23 and a recovery device that recovers the condensed solvent can be placed in the casting device 15. Thereby, the concentration of the solvent contained in the atmosphere in the casing 23 can be maintained within a constant range.
返回到圖1,流延裝置15與夾子拉幅機17之間的轉送部上排列有複數個對濕潤薄膜13進行支撐之支撐輥87。支撐輥87藉由未圖示之馬達以軸為中心旋轉。支撐輥87支撐從流延裝置15送出之濕潤薄膜13並向夾子拉幅機17導引。另外,圖1中示出在轉送部排列2個支撐輥87之情況,但是本發明不限於此,亦可在轉送部排列1個或3個以上的支撐輥87。並且,支撐輥87亦可以為自由輥。 Returning to Fig. 1, a plurality of support rollers 87 for supporting the wet film 13 are arranged on the transfer portion between the casting device 15 and the clip tenter 17. The support roller 87 rotates around the shaft by a motor (not shown). The support roller 87 supports the wet film 13 fed from the casting device 15 and is guided to the clip tenter 17. In addition, FIG. 1 shows a case where two support rollers 87 are arranged in the transfer portion. However, the present invention is not limited thereto, and one or three or more support rollers 87 may be arranged in the transfer portion. Also, the support roller 87 may be a free roller.
夾子拉幅機17具有對濕潤薄膜13的幅度方向的兩個側緣部進行把持之複數個夾子,該夾子在拉伸軌道上移動。相對藉由夾子把持之濕潤薄膜13送入乾燥風,對濕潤薄膜13實施向寬度方向的拉伸處理和乾燥處理。 The clip tenter 17 has a plurality of clips that grip the two side edge portions of the wet film 13 in the width direction, and the clip moves on the stretching rail. The wet film 13 is sent to the dry air with respect to the wet film 13 held by the clip, and the wet film 13 is subjected to stretching treatment and drying treatment in the width direction.
夾子拉幅機17與乾燥裝置18之間設置有切邊裝置88。送出於切邊裝置88之薄膜16的幅度方向的兩端形成有藉由夾子形成之把持痕跡。切邊裝置88切掉具有該把持痕跡之兩端部份。該切掉之部份藉由送風依次向截斷風機(未圖示)及破碎機(未圖示)送入而被切碎並作為濃液等的原料再利用。 A trimming device 88 is disposed between the clip tenter 17 and the drying device 18. Both ends of the film 16 sent out of the trimming device 88 in the amplitude direction are formed with gripping traces formed by the clips. The trimming device 88 cuts off the ends having the grip marks. The cut portion is sent to the cutting fan (not shown) and the crusher (not shown) in order, and is shredded and reused as a raw material such as a dope.
乾燥裝置18具備殼體、複數個輥18A及空調機(未圖示)。殼體具備薄膜16的傳送路。複數個輥18A形成薄膜16的傳送路。空調機對殼體內的氣氛的溫度或濕度進行 調節。導入於殼體內之薄膜16捲繞於複數個輥18A的同時被傳送。藉由調節該氣氛的溫度或濕度,從在殼體內傳送之薄膜16蒸發殘留之溶劑。另外,乾燥裝置18上連接藉由吸附回收從薄膜16蒸發之溶劑之吸附回收裝置。 The drying device 18 includes a casing, a plurality of rollers 18A, and an air conditioner (not shown). The housing is provided with a conveying path of the film 16. A plurality of rollers 18A form a transport path for the film 16. The air conditioner performs temperature or humidity on the atmosphere inside the casing Adjustment. The film 16 introduced into the casing is wound while being wound around a plurality of rolls 18A. The residual solvent is evaporated from the film 16 conveyed in the casing by adjusting the temperature or humidity of the atmosphere. Further, the drying device 18 is connected to an adsorption recovery device that recovers the solvent evaporated from the film 16 by adsorption.
乾燥裝置18與捲取裝置19之間從上游側依次設置冷卻室89、除電棒(未圖示)、帶有滾花的輥輪90及切邊裝置(未圖示)。冷卻室89對薄膜16進行冷卻直至薄膜16的溫度成為大致室溫。除電棒進行從自冷卻室89送出並帶電之薄膜16除電之除電處理。帶有滾花的輥輪90對薄膜16的寬度方向兩端賦予捲取用滾花。切邊裝置以在切斷後的薄膜16的寬度方向兩端殘留滾花的方式切斷薄膜16的寬度方向兩端。 A cooling chamber 89, a static eliminating rod (not shown), a knurled roller 90, and a trimming device (not shown) are disposed between the drying device 18 and the winding device 19 in this order from the upstream side. The film 16 is cooled by the cooling chamber 89 until the temperature of the film 16 becomes substantially room temperature. The static eliminating rod performs a static elimination treatment of the thin film 16 which is sent out from the cooling chamber 89 and charged. The roller 90 with knurling imparts a knurling for winding to both ends in the width direction of the film 16. The trimming device cuts both ends in the width direction of the film 16 so that knurls remain at both ends in the width direction of the cut film 16 .
捲取裝置19具有壓輥19A和卷芯19B。送入捲取裝置19之薄膜16藉由壓輥19A按壓的同時捲取於卷芯19B而呈輥狀。 The take-up device 19 has a pressure roller 19A and a winding core 19B. The film 16 fed to the take-up device 19 is wound in the roll core 19B while being pressed by the press roller 19A to be in a roll shape.
接著,對本發明的作用進行說明。如圖3及圖4所示,藉由軸位移部28AS、力量感測器28LC及控制部30,向流延帶26外加預定的移動張力。並且,藉由驅動用馬達28M與控制部30旋轉水平滾筒24。藉此,流延帶26在移動路26R上移動,亦即在殼體23內的移動路26R中依次在各室23A~室23C循環移動。 Next, the action of the present invention will be described. As shown in FIGS. 3 and 4, a predetermined movement tension is applied to the casting belt 26 by the shaft displacement portion 28AS, the force sensor 28LC, and the control portion 30. Then, the horizontal roller 24 is rotated by the drive motor 28M and the control unit 30. Thereby, the casting belt 26 moves on the movement path 26R, that is, the movement path 26R in the casing 23 sequentially circulates in each of the chambers 23A to 23C.
如圖2所示,流延室23A中進行在流延帶26上形成由濃液12構成之流延膜76之流延製程。流延模77從濃液 流出口40A連續流出濃液12。流出之濃液12從流延模77遍及流延帶26而形成液珠,並在流延帶26上流延。這樣在流延帶26上形成由濃液12構成之流延膜76。 As shown in FIG. 2, in the casting chamber 23A, a casting process in which the casting film 76 composed of the dope 12 is formed on the casting tape 26 is performed. Casting die 77 from the dope The outflow port 40A continuously flows out of the dope 12. The concentrated dope 12 flows from the casting die 77 over the casting tape 26 to form a bead, and is cast on the casting tape 26. Thus, a casting film 76 composed of the dope 12 is formed on the casting belt 26.
乾燥室23B中進行向流延膜76吹送預定的乾燥風並使溶劑從流延膜76蒸發之膜乾燥製程。膜乾燥製程進行至流延膜76成為能夠獨立傳送之狀態。膜乾燥製程中依次進行向流延膜76吹送第1乾燥風81DA之第1膜乾燥製程和向流延膜76吹送第2乾燥風82DA之第2膜乾燥製程。 In the drying chamber 23B, a film drying process in which a predetermined dry air is blown to the casting film 76 and the solvent is evaporated from the casting film 76 is performed. The film drying process proceeds to a state in which the casting film 76 can be independently transferred. In the film drying process, the first film drying process of blowing the first dry air 81DA to the casting film 76 and the second film drying process of blowing the second drying wind 82DA to the casting film 76 are sequentially performed.
第1膜乾燥製程相對溶劑的含有率為250質量%以上且400質量%以下的流延膜76進行為較佳,相對溶劑的含有率為300質量%以上且350質量%以下的流延膜76進行更為佳。第1乾燥風81DA的溫度為30℃以上且80℃以下為較佳。並且,第1乾燥風81DA的風速為5m/秒以上且25m/秒以下為較佳。 The casting film 76 in which the content of the first film drying process is 250% by mass or more and 400% by mass or less, and the content of the solvent is preferably 300% by mass or more and 350% by mass or less. It is better to do it. The temperature of the first dry air 81DA is preferably 30° C. or higher and 80° C. or lower. Further, the wind speed of the first dry air 81DA is preferably 5 m/sec or more and 25 m/sec or less.
第2膜乾燥製程中,第2乾燥風82DA的溫度為30℃以上且80℃以下為較佳。並且,第2乾燥風82DA的風速為5m/秒以上且25m/秒以下為較佳。 In the second film drying process, the temperature of the second dry air 82DA is preferably 30° C. or higher and 80° C. or lower. Further, the wind speed of the second dry air 82DA is preferably 5 m/sec or more and 25 m/sec or less.
其中,溶劑的含有率係以乾量基準表示流延膜或各薄膜中所含之溶劑的量者,當從對象薄膜採取樣品並將該樣品的重量設為x、乾燥樣品後的重量設為y時,表示為{(x-y)/y}×100。 In addition, the content rate of the solvent is the amount of the solvent contained in the casting film or each film on a dry basis, and when the sample is taken from the target film, the weight of the sample is x, and the weight after drying the sample is set. When y, it is expressed as {(xy)/y}×100.
在剝離室23C中,進行從流延帶26剝離成為能夠剝 離狀態之流延膜76之剝離製程。剝離輥86從流延帶26剝離成為能夠剝離狀態之流延膜76作為濕潤薄膜13,並從設置於剝離室23C之出口23CO送出濕潤薄膜13。剝離製程相對溶劑的含有率為20質量%以上且80質量%以下的流延膜76進行為較佳。 In the peeling chamber 23C, peeling from the casting tape 26 is performed to be peelable The stripping process of the cast film 76 from the state. The peeling roller 86 is peeled from the casting tape 26 into a peelable state of the casting film 76 as the wet film 13, and the wet film 13 is sent out from the outlet 23CO provided in the peeling chamber 23C. It is preferable that the casting film 76 having a content of the peeling process to the solvent is 20% by mass or more and 80% by mass or less.
並且,剝離製程之後在流延帶26上再次進行膜形成製程。如此,流延裝置15中反覆進行膜形成製程、膜乾燥製程及剝離製程。能夠藉由流延裝置15由濃液12連續生產濕潤薄膜13。 Further, after the stripping process, the film forming process is again performed on the casting tape 26. In this manner, the film forming process, the film drying process, and the peeling process are repeatedly performed in the casting device 15. The wet film 13 can be continuously produced from the dope 12 by the casting device 15.
其中,當控制部30檢測到流延帶26偏離移動路26R的情況下,控制部30進行依據偏離方向判斷處理的結果控制軸承位移部35S之從動滾筒移變處理(參閱圖6~圖8)。能夠使流延帶26藉由從動滾筒移變處理返回到移動路26R。但是,流延帶26的移動速度較大時(例如為50m/分鐘以上)或者流延帶26的移動速度產生較大的變動(例如為2m/分鐘2以上)時或者反覆進行膜形成製程、膜乾燥製程及剝離製程期間的流延帶26的溫度的變動量較大(例如為30℃以上)時,僅由偏離方向判斷處理不但很難使流延帶26返回到移動路26R,而且導致流延帶26更偏離移動路26R。 When the control unit 30 detects that the casting belt 26 is displaced from the movement path 26R, the control unit 30 controls the slave drum shifting process of the bearing displacement portion 35S according to the result of the deviation direction determination processing (see FIGS. 6 to 8). ). The casting belt 26 can be returned to the moving path 26R by the driven drum shifting process. However, when the moving speed of the casting belt 26 is large (for example, 50 m/min or more) or the moving speed of the casting belt 26 is largely changed (for example, 2 m/min 2 or more) or the film forming process is repeated, When the amount of fluctuation in the temperature of the casting belt 26 during the film drying process and the peeling process is large (for example, 30 ° C or higher), it is difficult to return the casting tape 26 to the moving path 26R only by the deviation direction determining process, and The casting belt 26 is further offset from the moving path 26R.
流延裝置15中能夠藉由帶導引機構36在移動路26R的寬度加上恆定游隙量之範圍內維持流延帶26。因此,能夠避免流延帶26大幅偏離移動路26R。並且,能夠藉由在如此狀態下進行從動滾筒移變處理,避免流延帶26偏離移 動路26R。如此,能夠在從流延模77流出之濃液12(參閱圖1)著落於流延面26A之流延位置CP(參閱圖8)處,將流延帶26限制於移動路26R。 The casting device 15 can maintain the casting tape 26 in the casting device 15 within the range of the width of the moving path 26R plus the amount of constant play by the tape guiding mechanism 36. Therefore, it is possible to prevent the casting belt 26 from largely deviating from the moving path 26R. Moreover, the shifting of the casting belt 26 can be avoided by performing the driven drum shifting process in such a state. Drive 26R. In this manner, the dope 12 (see FIG. 1) flowing out from the casting die 77 can be placed at the casting position CP (see FIG. 8) of the casting surface 26A, and the casting tape 26 can be restricted to the moving path 26R.
滾筒擺動機構35可省略。省略滾筒擺動機構35時,底面51DD與移動路26R的Y方向端部26RE的間隔CL設為0即可(參閱圖13)。 The drum swinging mechanism 35 can be omitted. When the drum swing mechanism 35 is omitted, the interval CL between the bottom surface 51DD and the Y-direction end portion 26RE of the movement path 26R may be set to 0 (see FIG. 13).
當利用滾筒擺動機構35(參閱圖4)時,最接近水平滾筒25之導引輥需要以不與擺動之水平滾筒25接觸之程度遠離水平滾筒25。但是,省略滾筒擺動機構35時,能夠使最接近水平滾筒25之導引輥更靠近水平滾筒25。 When the drum swing mechanism 35 (see FIG. 4) is utilized, the guide roller closest to the horizontal drum 25 needs to be away from the horizontal drum 25 to such an extent that it does not come into contact with the swinging horizontal drum 25. However, when the drum swing mechanism 35 is omitted, the guide roller closest to the horizontal drum 25 can be brought closer to the horizontal drum 25.
並且,可使用圖14及圖15所示之帶台階狀滾筒124代替水平滾筒24。帶台階狀滾筒124在殼體23內以水平且與水平滾筒25平行地配設,並具備驅動軸124A與固定於驅動軸124A之不銹鋼製滾筒主體124B。滾筒主體124B在Y方向中央部具備小徑滾筒部124BC,在Y方向兩端部具備大徑滾筒部124BE。Y方向上的小徑滾筒部124BC的長度與移動路26R的寬度相等。移動路26R設定在小徑滾筒部124BC的周面上。藉由大徑滾筒部124BE及小徑滾筒部124BC形成之流延帶26的支撐槽124M的深度D124M、亦即從大徑滾筒部124BE的半徑減去小徑滾筒部124BC的半徑之差係捲繞於小徑滾筒部124BC的周面之流延帶26不跨到大徑滾筒部124BE之程度者即可,例如為流延帶26的厚度D26的0.5倍以上且5倍以下即可。能夠藉由帶台階狀滾筒124避免流延帶26偏離移動路26R。 Further, instead of the horizontal drum 24, the stepped drum 124 shown in Figs. 14 and 15 can be used. The stepped drum 124 is disposed horizontally in the casing 23 in parallel with the horizontal drum 25, and includes a drive shaft 124A and a stainless steel drum main body 124B fixed to the drive shaft 124A. The drum main body 124B includes a small-diameter roller portion 124BC at a central portion in the Y direction, and a large-diameter roller portion 124BE at both end portions in the Y direction. The length of the small diameter roller portion 124BC in the Y direction is equal to the width of the movement path 26R. The movement path 26R is set on the circumferential surface of the small diameter roller portion 124BC. The depth D 124M of the support groove 124M of the casting tape 26 formed by the large diameter roller portion 124BE and the small diameter roller portion 124BC, that is, the difference between the radius of the large diameter roller portion 124BE and the radius of the small diameter roller portion 124BC is The casting tape 26 wound around the circumferential surface of the small-diameter roller portion 124BC may not extend to the extent of the large-diameter roller portion 124BE, and may be, for example, 0.5 times or more and 5 times or less the thickness D 26 of the casting tape 26. . The casting tape 26 can be prevented from deviating from the moving path 26R by the stepped roller 124.
利用帶台階狀滾筒124時,可省略滾筒擺動機構35或帶導引機構36。 When the stepped drum 124 is used, the drum swinging mechanism 35 or the belt guiding mechanism 36 can be omitted.
藉由本發明獲得之薄膜16尤其能夠使用於相位差薄膜或偏光板保護薄膜。 The film 16 obtained by the present invention can be used particularly for a retardation film or a polarizing plate protective film.
薄膜16的寬度為600mm以上為較佳,為1400mm以上且2500mm以下更為佳。並且,當薄膜16的寬度大於2500mm時,本發明亦有效果。並且,薄膜16的膜厚為20μm以上且80μm以下為較佳。 The width of the film 16 is preferably 600 mm or more, and more preferably 1400 mm or more and 2500 mm or less. Further, the present invention also has an effect when the width of the film 16 is more than 2,500 mm. Further, the film thickness of the film 16 is preferably 20 μm or more and 80 μm or less.
並且,薄膜16的面內延遲Re為20nm以上且300nm以下為較佳,薄膜16的厚度方向延遲Rth為-100nm以上且300nm以下為較佳。 Further, the in-plane retardation Re of the film 16 is preferably 20 nm or more and 300 nm or less, and the film thickness retardation Rth of the film 16 is preferably -100 nm or more and 300 nm or less.
面內延遲Re的測定方法為如下。關於面內延遲Re,利用在溫度25℃、濕度60%RH下對樣品薄膜進行2小時調濕,並由自動雙折射儀(KOBRA21DH王子計量設備株式會社製)從632.8nm處的垂直方向測定之延遲值。另外,Re由以下公式表示。 The method of measuring the in-plane retardation Re is as follows. For the in-plane retardation Re, the sample film was conditioned for 2 hours at a temperature of 25 ° C and a humidity of 60% RH, and was measured from the vertical direction at 632.8 nm by an automatic birefringence meter (manufactured by KOBRA 21 DH Prince Metering Co., Ltd.). Delay value. In addition, Re is represented by the following formula.
Re=| n1-n2 |×d Re=| n1-n2 |×d
n1表示慢軸的折射率,n2表示進相軸2的折射率,d表示薄膜的厚度(膜厚)。 N1 represents the refractive index of the slow axis, n2 represents the refractive index of the phase axis 2, and d represents the thickness (film thickness) of the film.
厚度方向延遲Rth的測定方法為如下。由在溫度25℃、濕度60%RH下對樣品薄膜進行2小時調濕,並用橢圓偏振計(M150日本分光株式會社製)依據632.8nm從垂直方向測定之值和使薄膜面傾斜的同時相同地測定之延遲值的外插值,依據下述公式計算。 The method of measuring the thickness direction retardation Rth is as follows. The sample film was conditioned for 2 hours at a temperature of 25 ° C and a humidity of 60% RH, and the value measured from the vertical direction at 632.8 nm and the film surface were inclined by the ellipsometer (M150, manufactured by JASCO Corporation). The extrapolated value of the measured delay value is calculated according to the following formula.
Rth={(n1+n2)/2-n3}×d Rth={(n1+n2)/2-n3}×d
n3表示厚度方向的折射率。 N3 represents the refractive index in the thickness direction.
上述實施方式中,成為聚合物薄膜的原料之聚合物無特別限定,例如有纖維素醯化物或環狀聚烯烴等。 In the above embodiment, the polymer which is a raw material of the polymer film is not particularly limited, and examples thereof include cellulose halides and cyclic polyolefins.
用於本發明的纖維素醯化物之醯基可以僅為1種,或者亦可使用2種以上的醯基。使用2種以上的醯基時,其中1個為乙醯基為較佳。用羧酸對纖維素的羥基進行酯化的比例,亦即醯基的取代度滿足所有下述公式(I)~(III)為較佳。另外,以下公式(I)~(III)中,A及B表示醯基的取代度,A為乙醯基的取代度,並且,B為碳原子數3~22的醯基的取代度。另外,三醋酸纖維素(TAC)的90質量%以上為0.1mm~4mm的顆粒為較佳。 The thiol group used for the cellulose oxime of the present invention may be used alone or in combination of two or more kinds. When two or more kinds of mercapto groups are used, one of them is preferably an ethylidene group. The ratio of the esterification of the hydroxyl group of the cellulose with a carboxylic acid, that is, the degree of substitution of the thiol group, satisfies all of the following formulas (I) to (III). Further, in the following formulas (I) to (III), A and B represent the degree of substitution of a mercapto group, A is a degree of substitution of an ethylidene group, and B is a degree of substitution of a mercapto group having 3 to 22 carbon atoms. Further, it is preferred that 90% by mass or more of triacetylcellulose (TAC) is 0.1 mm to 4 mm.
醯基的總取代度A+B為2.20以上且2.90以下更為佳,為2.40以上且2.88以下尤為佳。並且,碳原子數3~22的醯基的取代度B為0.30以上更為佳,0.5以上尤為佳。 The total substitution degree A+B of the fluorenyl group is preferably 2.20 or more and 2.90 or less, and more preferably 2.40 or more and 2.88 or less. Further, the substitution degree B of the fluorenyl group having 3 to 22 carbon atoms is more preferably 0.30 or more, and particularly preferably 0.5 or more.
作為纖維素醯化物的原料之纖維素可以係由棉絨纖維、漿料中的任一種得到者。 The cellulose which is a raw material of the cellulose oxime may be obtained from any one of cotton linters and pulp.
作為本發明的纖維素醯化物的碳數2以上的醯基,可 以是脂肪族基,亦可以是芳基,無特別限定。這些例如為纖維素的烷羰基酯、烯羰基酯或芳香族羰基酯、芳香族烷羰基酯等,亦可以分別具有進一步被取代之基團。作為這些較佳例子,能夠列舉出丙醯基、丁醯基、戊醯基、己醯基、辛醯基、癸醯基、十二烷醯基、十三烷醯基、十四烷醯基、十六烷醯基、十八烷醯基、異丁醯基、叔丁醯基、環己烷基羰基、油醯基、苯甲醯基、萘羰基及肉桂醯基等。其中,丙醯基、丁醯基、十二烷醯基、十八烷醯基、叔丁醯基、油醯基、苯甲醯基、萘羰基及肉桂醯基等更為佳,丙醯基及丁醯基尤為佳。 The fluorenyl group having a carbon number of 2 or more as the cellulose halide of the present invention It may be an aliphatic group or an aryl group, and is not particularly limited. These may be, for example, an alkylcarbonyl ester of cellulose, an olefinic carbonyl ester or an aromatic carbonyl ester, an aromatic alkylcarbonyl ester or the like, and may each have a further substituted group. As such a preferable example, a propyl fluorenyl group, a butyl fluorenyl group, a pentyl fluorenyl group, a hexyl fluorenyl group, a octyl decyl group, a decyl group, a dodecyl fluorenyl group, a tridecyl fluorenyl group, a tetradecyl fluorenyl group, and a hexadecane Anthracenyl, octadecylfluorenyl, isobutylhydrazine, tert-butylhydrazine, cyclohexanecarbonylcarbonyl, anthracenyl, benzamyl, naphthalenecarbonyl and cinnamyl. Among them, propyl sulfonyl, butyl fluorenyl, dodecyl fluorenyl, octadecyl fluorenyl, tert-butyl fluorenyl, anthracenyl, benzhydryl, naphthalenecarbonyl and cinnamyl are preferred, and propyl sulfhydryl and butyl sulfhydryl are particularly preferred. .
作為製備濃液之溶劑,可以列舉出芳香族烴(例如,苯及甲苯等)、鹵代烴(例如,二氯甲烷及氯苯等)、醇(例如,甲醇、乙醇、正丙醇、正丁醇及二甘醇等)、酮(例如,丙酮及甲乙酮等)、酯(例如,醋酸甲酯、醋酸乙酯及醋酸丙酯等)及醚(例如,四氫呋喃及甲基溶纖劑等)等。另外,本發明中濃液是指將聚合物溶解或分散於溶劑而獲得之聚合物溶液及分散液。 Examples of the solvent for preparing the dope include aromatic hydrocarbons (for example, benzene and toluene), halogenated hydrocarbons (for example, dichloromethane and chlorobenzene, etc.), and alcohols (for example, methanol, ethanol, n-propanol, and positive). Butanol and diethylene glycol, etc., ketones (for example, acetone and methyl ethyl ketone), esters (for example, methyl acetate, ethyl acetate, and propyl acetate) and ethers (for example, tetrahydrofuran and methyl cellosolve, etc.) Wait. Further, in the present invention, the dope refers to a polymer solution and a dispersion obtained by dissolving or dispersing a polymer in a solvent.
其中,使用碳原子數1~7的鹵代烴為較佳,使用二氯甲烷為最佳。從聚合物的溶解性、流延膜從支撐體的剝離性、薄膜的機械強度等及薄膜的光學特性等物性觀點考慮,除了二氯甲烷以外,混合1種乃至數種碳原子數1~5的醇為較佳。醇的含量相對所有溶劑為2質量%~25質量%為較佳,為5質量%~20質量%更為佳。作為醇的具體 例子,可以列舉出甲醇、乙醇、正丙醇、異丙醇及正丁醇等,但是使用甲醇、乙醇、正丁醇或它們的混合物為較佳。 Among them, a halogenated hydrocarbon having 1 to 7 carbon atoms is preferably used, and dichloromethane is most preferred. From the viewpoint of physical properties such as the solubility of the polymer, the peelability of the cast film from the support, the mechanical strength of the film, and the optical properties of the film, one or several kinds of carbon atoms are mixed in addition to methylene chloride. The alcohol is preferred. The content of the alcohol is preferably 2% by mass to 25% by mass based on the total amount of the solvent, and more preferably 5% by mass to 20% by mass. Specific as alcohol Examples thereof include methanol, ethanol, n-propanol, isopropanol, n-butanol and the like, but methanol, ethanol, n-butanol or a mixture thereof is preferred.
但是,最近以將對環境的影響抑制到最小限度為目的,亦對不使用二氯甲烷時的溶劑組成進行了檢討。針對該目的,使用碳原子數為4~12的醚、碳原子數為3~12的酮、碳原子數為3~12的酯、碳原子數為1~12的醇為較佳。有時適當混合這些來使用。例如,可以列舉出醋酸甲酯、丙酮、乙醇及正丁醇的混合溶劑。這些醚、酮、酯及醇可以係具有環狀結構者。並且,具有2個以上醚、酮、酯及醇的官能團(亦即,-O-、-CO-、-COO-及-OH)中的任意一種之化合物亦能夠用作溶劑。 However, in order to minimize the influence on the environment, the solvent composition in the case where methylene chloride is not used has been reviewed recently. For this purpose, an ether having 4 to 12 carbon atoms, a ketone having 3 to 12 carbon atoms, an ester having 3 to 12 carbon atoms, or an alcohol having 1 to 12 carbon atoms is preferred. Sometimes mix these to use. For example, a mixed solvent of methyl acetate, acetone, ethanol, and n-butanol can be mentioned. These ethers, ketones, esters and alcohols may be those having a cyclic structure. Further, a compound having two or more functional groups of an ether, a ketone, an ester, and an alcohol (that is, -O-, -CO-, -COO-, and -OH) can also be used as a solvent.
另外,在日本專利公開2005-104148號的[0140]段落到[0195]段落中對纖維素醯化物的詳細內容進行了記載。這些記載亦能夠適用於本發明。並且,同樣在日本專利公開2005-104148號的[0196]段落到[0516]段落中亦對溶劑及增塑劑、劣化抑制劑、紫外線吸收劑(UV劑)、光學各向異性控制劑、延遲抑制劑、染料、去光劑、剝離劑、剝離促進劑等添加劑進行了詳細記載。 Further, the details of the cellulose halide are described in paragraphs [0140] to [0195] of Japanese Patent Laid-Open Publication No. 2005-104148. These descriptions can also be applied to the present invention. Also, in the paragraphs [0196] to [0516] of Japanese Patent Laid-Open Publication No. 2005-104148, solvents and plasticizers, deterioration inhibitors, ultraviolet absorbers (UV agents), optical anisotropy control agents, and delays are also used. Additives such as inhibitors, dyes, matting agents, release agents, and release accelerators are described in detail.
10‧‧‧溶液製膜設備 10‧‧‧solution film making equipment
12‧‧‧濃液 12‧‧‧Liquor
13‧‧‧濕潤薄膜 13‧‧‧ Wet film
15‧‧‧流延裝置 15‧‧‧casting device
16‧‧‧乾燥薄膜 16‧‧‧Dry film
17‧‧‧夾子拉幅機 17‧‧‧Clip tenter
18‧‧‧乾燥裝置 18‧‧‧Drying device
18A‧‧‧輥 18A‧‧‧roll
19‧‧‧捲取裝置 19‧‧‧Winding device
19A‧‧‧壓輥 19A‧‧‧Pressure roller
19B‧‧‧卷芯 19B‧‧‧core
23‧‧‧殼體 23‧‧‧ housing
23A‧‧‧流延室 23A‧‧‧Casting room
23B‧‧‧乾燥室 23B‧‧·drying room
23C‧‧‧剝離室 23C‧‧‧ peeling room
23CO‧‧‧出口 23CO‧‧‧Export
23S‧‧‧內壁面 23S‧‧‧ inner wall
24、25‧‧‧水平滾筒 24, 25‧‧‧ horizontal drum
24A、124A‧‧‧驅動軸 24A, 124A‧‧‧ drive shaft
24B、25B、124B‧‧‧不銹鋼製滾筒主體 24B, 25B, 124B‧‧‧ Stainless steel drum body
25A‧‧‧轉動軸 25A‧‧‧Rotary axis
25AS‧‧‧軸承 25AS‧‧‧ bearing
26‧‧‧流延帶 26‧‧‧Casting zone
26A‧‧‧流延面 26A‧‧‧Running surface
26B‧‧‧背面 26B‧‧‧Back
26E‧‧‧帶端面 26E‧‧‧with end face
26R‧‧‧移動路 26R‧‧‧Mobile Road
26RE‧‧‧移動路26R的Y方向端部 26RE‧‧‧Y-direction end of mobile road 26R
27‧‧‧帶移動單元 27‧‧‧With mobile unit
28‧‧‧帶移動部 28‧‧‧With the Ministry of Movement
28AS‧‧‧軸位移部 28AS‧‧‧Axis displacement
28LC‧‧‧力量感測器 28LC‧‧‧Power Sensor
28M‧‧‧驅動用馬達 28M‧‧‧Drive motor
29‧‧‧帶移動方向控制部 29‧‧‧With movement direction control
30‧‧‧控制部 30‧‧‧Control Department
35‧‧‧滾筒擺動機構 35‧‧‧Rolling mechanism
35K‧‧‧偏離檢測部 35K‧‧‧ Deviation Detection Department
35KP‧‧‧一端偏離檢測部 35KP‧‧‧ one end deviation detection department
35KQ‧‧‧另一端偏離檢測部 35KQ‧‧‧The other end of the deviation detection department
35S‧‧‧軸承位移部 35S‧‧‧ bearing displacement
35SP‧‧‧一端側軸承位移部 35SP‧‧‧ one end side bearing displacement
35SQ‧‧‧另一端側軸承位移部 35SQ‧‧‧Other end side bearing displacement
36‧‧‧帶導引機構 36‧‧‧With guiding mechanism
36PA、36PB‧‧‧一端側導引輥 36PA, 36PB‧‧‧ one end side guide roller
36QA、36QB、36QC‧‧‧另一端側導引輥 36QA, 36QB, 36QC‧‧‧ other end side guide rolls
40PA、40QA‧‧‧發光部 40PA, 40QA‧‧‧Lighting Department
40PB、40QB‧‧‧受光部 40PB, 40QB‧‧‧Receiving Department
40PX、40QX‧‧‧光路 40PX, 40QX‧‧‧ light path
51‧‧‧導引輥主體 51‧‧‧ Guide roller body
51D‧‧‧支撐槽 51D‧‧‧Support slot
51DD‧‧‧底面 51DD‧‧‧ bottom surface
51DS‧‧‧側面 51DS‧‧‧ side
51S‧‧‧周面 51S‧‧‧Sun
52‧‧‧導引輥軸 52‧‧‧ Guide roller
55‧‧‧擺動軸 55‧‧‧Swing axis
56‧‧‧連結臂 56‧‧‧Link arm
61‧‧‧軸位移部 61‧‧‧Axis displacement
62‧‧‧彈簧 62‧‧‧ Spring
71‧‧‧第1密封構件 71‧‧‧1st sealing member
72‧‧‧第2密封構件 72‧‧‧2nd sealing member
73‧‧‧第3密封構件 73‧‧‧3rd sealing member
76‧‧‧流延膜 76‧‧‧cast film
77‧‧‧流延模 77‧‧‧casting mode
77A‧‧‧濃液流出口 77A‧‧‧ Concentrated liquid outlet
78‧‧‧減壓機 78‧‧‧Relief machine
78A‧‧‧減壓室 78A‧‧‧ Decompression chamber
78B‧‧‧減壓扇 78B‧‧‧Relief fan
78C‧‧‧吸引管 78C‧‧‧ suction tube
81‧‧‧第1乾燥機 81‧‧‧1st dryer
81A‧‧‧第1進氣導管 81A‧‧‧1st intake duct
81AO‧‧‧第1進氣口 81AO‧‧‧1st air inlet
81B‧‧‧第1排氣導管 81B‧‧‧1st exhaust duct
81BO‧‧‧第1排氣口 81BO‧‧‧1st exhaust port
81DA‧‧‧第1乾燥風 81DA‧‧‧1st dry wind
82‧‧‧第2乾燥機 82‧‧‧2nd dryer
82A‧‧‧第2排氣導管 82A‧‧‧2nd exhaust duct
82AO‧‧‧第2排氣口 82AO‧‧‧2nd exhaust port
82B‧‧‧第2進氣導管 82B‧‧‧2nd intake duct
82BO‧‧‧第2進氣口 82BO‧‧‧2nd air inlet
82DA‧‧‧第2乾燥風 82DA‧‧‧2nd dry wind
86‧‧‧剝離輥 86‧‧‧ peeling roller
87‧‧‧支撐輥 87‧‧‧Support roller
88‧‧‧切邊裝置 88‧‧‧ trimming device
89‧‧‧冷卻室 89‧‧‧Cooling room
90‧‧‧帶有滾花的輥輪 90‧‧‧Roller with knurling
77A‧‧‧濃液流出口 77A‧‧‧ Concentrated liquid outlet
124‧‧‧帶台階狀滾筒 124‧‧‧with stepped roller
124BC‧‧‧小徑滾筒部 124BC‧‧‧ Small diameter roller
124BE‧‧‧大徑滾筒部 124BE‧‧‧ Large Diameter Roller
124M‧‧‧支撐槽 124M‧‧‧ support slot
CL‧‧‧間隔 CL‧‧‧ interval
CP‧‧‧流延位置 CP‧‧‧cast position
D26‧‧‧厚度 D 26 ‧‧‧thickness
D124M‧‧‧深度 D 124M ‧‧‧ Depth
P1‧‧‧靠近位置 P1‧‧‧ close to location
P2、P3‧‧‧退避位置 P2, P3‧‧‧ retreat position
P24‧‧‧流延帶26與滾筒主體24B接觸之位置 P24‧‧‧The position where the casting belt 26 is in contact with the drum main body 24B
P25‧‧‧流延帶26與滾筒主體25B接觸之位置 P25‧‧‧The position where the casting belt 26 is in contact with the drum main body 25B
X、Y、Z‧‧‧方向 X, Y, Z‧‧ Direction
圖1係表示溶液製膜設備的概要之說明圖。 Fig. 1 is an explanatory view showing an outline of a solution film forming apparatus.
圖2係表示流延裝置的概要之側視圖。 Fig. 2 is a side view showing an outline of a casting device.
圖3係表示配設於流延裝置的殼體內之各組件的概要之立體圖。 Fig. 3 is a perspective view showing an outline of each of the components disposed in the casing of the casting device.
圖4係表示帶移動部、帶移動方向控制部及控制部的 概要之塊圖。 4 is a view showing a belt moving portion, a belt moving direction control unit, and a control unit. A block diagram of the outline.
圖5係表示一端偏離檢測部與另一端偏離檢測部的概要之說明圖。 Fig. 5 is an explanatory view showing an outline of one end deviation detecting portion and the other end deviation detecting portion.
圖6係表示轉動軸處於基準位置之水平滾筒的概要之俯視圖。 Fig. 6 is a plan view showing an outline of a horizontal drum in which a rotating shaft is at a reference position.
圖7係表示轉動軸的一端側比轉動軸的另一端側更遠離驅動軸時的水平滾筒的概要之俯視圖。 Fig. 7 is a plan view showing an outline of a horizontal drum when one end side of the rotating shaft is farther from the driving shaft than the other end side of the rotating shaft.
圖8係表示轉動軸的另一端側比轉動軸的一端側更遠離驅動軸時的水平滾筒的概要之俯視圖。 Fig. 8 is a plan view showing an outline of a horizontal drum when the other end side of the rotating shaft is farther from the driving shaft than the one end side of the rotating shaft.
圖9係表示帶導引機構的概要之立體圖。 Fig. 9 is a perspective view showing an outline of a belt guiding mechanism.
圖10係表示另一端側導引輥的概要之立體圖。 Fig. 10 is a perspective view showing the outline of the other end side guide roller.
圖11係表示另一端側導引輥的概要之側視圖。 Fig. 11 is a side view showing the outline of the other end side guide roller.
圖12係表示擺動自如的導引輥主體的概要之頂視圖。 Fig. 12 is a top plan view showing an outline of a swinging guide roller main body.
圖13係表示另一端側導引輥的概要之側視圖。 Fig. 13 is a side view showing the outline of the other end side guide roller.
圖14係表示帶台階狀滾筒的概要之立體圖。 Fig. 14 is a perspective view showing an outline of a stepped drum.
圖15係表示帶台階狀滾筒的概要之側視圖。 Fig. 15 is a side view showing an outline of a stepped drum.
24、25‧‧‧水平滾筒 24, 25‧‧‧ horizontal drum
24A‧‧‧驅動軸 24A‧‧‧ drive shaft
24B、25B‧‧‧不銹鋼製滾筒主體 24B, 25B‧‧‧ Stainless steel drum body
25A‧‧‧轉動軸 25A‧‧‧Rotary axis
25AS‧‧‧軸承 25AS‧‧‧ bearing
26‧‧‧流延帶 26‧‧‧Casting zone
28‧‧‧帶移動部 28‧‧‧With the Ministry of Movement
28AS‧‧‧軸位移部 28AS‧‧‧Axis displacement
28LC‧‧‧力量感測器 28LC‧‧‧Power Sensor
28M‧‧‧驅動用馬達 28M‧‧‧Drive motor
35S‧‧‧軸承位移部 35S‧‧‧ bearing displacement
35SP‧‧‧一端側軸承位移部 35SP‧‧‧ one end side bearing displacement
35SQ‧‧‧另一端側軸承位移部 35SQ‧‧‧Other end side bearing displacement
36‧‧‧帶導引機構 36‧‧‧With guiding mechanism
36PA、36PB‧‧‧一端側導引輥 36PA, 36PB‧‧‧ one end side guide roller
36QA、36QB、36QC‧‧‧另一端側導引輥 36QA, 36QB, 36QC‧‧‧ other end side guide rolls
77‧‧‧流延模 77‧‧‧casting mode
77A‧‧‧濃液流出口 77A‧‧‧ Concentrated liquid outlet
X、Y、Z‧‧‧方向 X, Y, Z‧‧ Direction
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CN101432114B (en) * | 2006-04-28 | 2011-01-12 | 柯尼卡美能达精密光学株式会社 | Method for manufacturing optical film |
JP4860584B2 (en) * | 2007-09-18 | 2012-01-25 | 株式会社神戸製鋼所 | Road surface rectilinear control mechanism and road surface rectilinear control method for running test apparatus |
JP5010002B2 (en) * | 2009-03-19 | 2012-08-29 | 国際計測器株式会社 | Running test device |
-
2011
- 2011-09-30 JP JP2011216686A patent/JP5571637B2/en not_active Expired - Fee Related
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2012
- 2012-08-24 KR KR1020120092882A patent/KR101985543B1/en active IP Right Grant
- 2012-08-28 TW TW101131216A patent/TWI621578B/en not_active IP Right Cessation
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TWI621578B (en) | 2018-04-21 |
CN103030824A (en) | 2013-04-10 |
KR101985543B1 (en) | 2019-06-03 |
JP5571637B2 (en) | 2014-08-13 |
CN103030824B (en) | 2017-04-12 |
KR20130035865A (en) | 2013-04-09 |
JP2013075432A (en) | 2013-04-25 |
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