TW201328607A - Thickening composition improved dispersibility and starch hydrolysate containing metal salt used therefor - Google Patents

Thickening composition improved dispersibility and starch hydrolysate containing metal salt used therefor Download PDF

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TW201328607A
TW201328607A TW101142127A TW101142127A TW201328607A TW 201328607 A TW201328607 A TW 201328607A TW 101142127 A TW101142127 A TW 101142127A TW 101142127 A TW101142127 A TW 101142127A TW 201328607 A TW201328607 A TW 201328607A
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metal salt
starch
composition
salt
viscosity
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TW101142127A
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TWI589230B (en
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Maki Imaoka
Motonobu Sasakawa
Nobumasa Tanaka
Junko Tsuchiya
Hiroshi Tokuyama
Masahiro Nishida
Toru Nakajima
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Mitsubishi Shoji Foodtech Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/50Polysaccharides, gums

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Molecular Biology (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Grain Derivatives (AREA)
  • Medicinal Preparation (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Cosmetics (AREA)

Abstract

The problem to be solved is to provide a thickening composition with improved dispersity, wherein the thickening composition with more improved dispersity than traditional things is used in a thickening agent and so on, and can inhibit the formation of lumps. When producing the thickening composition, if the granulation is necessary, there is no need to consider the influence of the dosage of binder on the composition, and the operation becomes easier. The solution is the thickening composition with improved dispersity which comprises metal salt containing starch hydrolysate and polysaccharide thickener, wherein the content of metal salt is 0.5 to 40 parts by mass relative to 100 parts by mass of the starch hydrolysate.

Description

提升分散性之增黏組成物及使用於其之含金屬鹽之澱粉分解物 a viscosity-enhancing composition for enhancing dispersibility and a starch-decomposing product containing the metal salt thereof

本發明係有關於一種藉由使用含金屬鹽之澱粉分解物改善分散性之增黏組成物。 The present invention relates to a viscosity-increasing composition for improving dispersibility by using a metal salt-containing starch decomposition product.

伴隨著高齡化的進展,以調整適合吞嚥困難者的飲食品黏度為目的而使用的增黏組成物,亦即所謂稠度(thickness)調整劑的需要係增加中。但是,稠度調整劑的主劑之三仙膠(xanthan gum)分散性非常低,被添加至水後之粉體的聚集物係從與水接觸的部分開始產生膨潤,且將聚集物的表面覆蓋,遮蔽水往聚集物的內部滲透,並且形成所謂「疙瘩」。欲使此種疙瘩完全溶解係非常困難的,在稠度調整劑的使用上成為問題。 With the progress of aging, the viscosity-increasing composition used for the purpose of adjusting the viscosity of foods and drinks for those who have difficulty in swallowing, that is, the need for a so-called thickness adjuster is increasing. However, the dispersibility of the xanthan gum, which is the main component of the consistency adjuster, is very low, and the aggregate of the powder added to the water starts to swell from the portion in contact with water, and covers the surface of the aggregate. The shadow water penetrates into the interior of the aggregate and forms a so-called "疙瘩". It is very difficult to completely dissolve such hydrazine, and it becomes a problem in the use of a consistency adjuster.

以柱,藉由改良在三仙膠粉末造粒時所使用的黏合劑液來使分散性改善之專利,已提出了許多申請。 A number of applications have been made by using a column to improve the dispersibility by modifying the binder liquid used in the granulation of the Sanxian gum powder.

例如,在日本特聞2004-49225號公報(專利文獻1)揭示一種技術,其係藉由將三仙膠等的溶膠化劑及糊精(dextrin)等的水溶性分散劑進行造粒,來實現對液狀食品之分散性、溶解性良好,以及凝膠化或溶膠化後的食品之低黏附性、高凝集性。 For example, Japanese Patent Publication No. 2004-49225 (Patent Document 1) discloses a technique of granulating a solifying agent such as Sanxian gum or a water-soluble dispersing agent such as dextrin. It achieves good dispersibility and solubility in liquid foods, and low adhesion and high agglutination of foods after gelation or solification.

日本特開2010-81943號公報(專利文獻2)、日本特開2008-61608號公報(專利文獻3)、日本特許第3930897號說明書(專利文獻4)係開發一種技術,其係藉由將鉀鹽、海藻酸鹽、羧甲基纖維素(CMC)或金屬鹽溶液作為黏合劑而對三仙膠的粉末表面噴霧且造粒,使其實現不 產生疙瘩而分散、溶解,且在添加後2分鐘達到尖鋒黏度的90%以上。 JP-A-2010-81943 (Patent Document 2), JP-A-2008-61608 (Patent Document 3), and Japanese Patent No. 3930897 (Patent Document 4) develop a technique in which potassium is used. Salt, alginate, carboxymethyl cellulose (CMC) or metal salt solution as a binder to spray and granulate the powder surface of Sanxian gum, so that it does not It is produced by dispersing, dissolving, and dissolving, and reaches more than 90% of the sharp viscosity 2 minutes after the addition.

日本特開2008-68194號公報(專利文獻5)係揭示一種技術,其係藉由將由包含氯化鈣、乳酸鈣、及泛酸鈣之群組中選擇1種以上之水溶液作為黏合劑而將水溶性高分子的粉末進行造粒,使其實現即便在使用刮鏟(spatula)等手攪拌之較弱的攪拌條件下,水溶性高分子等的粉末亦不產生疙瘩而容易分散、溶解。 Japanese Laid-Open Patent Publication No. 2008-68194 (Patent Document 5) discloses a technique in which a water-soluble solution is selected by using one or more aqueous solutions selected from the group consisting of calcium chloride, calcium lactate, and calcium pantothenate as a binder. The powder of the polymer is granulated so that the powder of a water-soluble polymer or the like is easily dispersed and dissolved without causing enthalpy even under a weak stirring condition by hand stirring using a spatula or the like.

日本特開2011-120538號公報(專利文獻6)係開發一種技術,其係藉由在將含有18~35重量%的糊精之水溶液作為黏合劑液而對含有增黏多糖類及糊精的粉末原料進行噴霧、造粒之同時,使粉末原料含有CMC鈉鹽,藉此能夠得到不會損害飲食品的風味而黏度的上升及持續性良好,而且分散性良好且能夠抑制產生疙瘩之增黏劑造粒物。 Japanese Laid-Open Patent Publication No. 2011-120538 (Patent Document 6) is a technique for developing a technique comprising a thickening polysaccharide and a dextrin by using an aqueous solution containing 18 to 35% by weight of dextrin as a binder liquid. The powder raw material is sprayed and granulated, and the powder raw material contains the CMC sodium salt, whereby the viscosity and the sustainability of the food and beverage are not impaired, and the viscosity is improved and the dispersibility is good, and the visbreaking of the enamel can be suppressed. Granules.

又,除了三仙膠的改良以外,亦有藉由限定添加作為分散劑之糊精的種類來使分散性改善之專利提出申請。日本特閒2006-6252號公報(專利文獻7)係開發一種技術,其係藉由將含有具有凝膠化及/或增黏的性質之水溶性高分子及DE值5以下的糊精之混合物顆粒化,來防止水溶性高分子的成塊(lumping)。 Further, in addition to the improvement of the Sanxian gum, there is also a patent for improving the dispersibility by limiting the type of dextrin added as a dispersing agent. Japanese Patent Publication No. 2006-6252 (Patent Document 7) is a technique for developing a technique comprising a water-soluble polymer having gelation and/or viscosity-increasing properties and a dextrin having a DE value of 5 or less. Granular to prevent lumping of water-soluble polymers.

但是,就稠度調整劑而言,上述的先前技術之防止產生疙瘩係難以達到能夠容許程度,特別是改良使用於噴霧造粒的黏合劑液之方法,為了使所製造之組成物的組成為一定,必須調整黏合劑液的噴霧量,而且因為黏 合劑溶液的溶質會造成噴霧旋轉器的孔眼堵塞致使作業性差,而要求進一步改良造粒方法。 However, in the case of the consistency adjuster, the above-mentioned prior art method for preventing the occurrence of a lanthanoid system is difficult to achieve an allowable degree, in particular, a method for improving the binder liquid used for spray granulation, in order to make the composition of the manufactured composition constant. , the amount of spray of the binder must be adjusted, and because of the stickiness The solute of the mixture solution causes clogging of the orifice of the spray rotator to cause poor workability, and further improvement of the granulation method is required.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開2004-49225號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2004-49225

[專利文獻2]日本特開2010-81943號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2010-81943

[專利文獻3]日本特開2008-61608號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2008-61608

[專利文獻4]日本特許第3930897號說明書 [Patent Document 4] Japanese Patent No. 3930897

[專利文獻5]日本特開2008-68194號公報 [Patent Document 5] Japanese Patent Laid-Open Publication No. 2008-68194

[專利文獻6]日本特開2011-120538號公報 [Patent Document 6] Japanese Patent Laid-Open Publication No. 2011-120538

[專利文獻7]日本特開2006-6252號公報 [Patent Document 7] Japanese Patent Laid-Open Publication No. 2006-6252

鑒於上述的問題,本發明之目的係提供一種能夠抑制疙瘩的形成之經改善分散性之增黏組成物。 In view of the above problems, it is an object of the present invention to provide an adhesion-enhancing composition capable of suppressing the formation of bismuth and having improved dispersibility.

而且,本發明之目的係提供一種經提升分散性之增黏組成物,其在製造增黏組成物時必須造粒之情況,不必考慮黏合劑的添加量對組成的影響,使得作業變為容易。 Further, it is an object of the present invention to provide a tackifying composition which is improved in dispersibility, which must be granulated in the production of a tackifying composition, and it is not necessary to consider the influence of the amount of the binder added on the composition, making the operation easy. .

本發明者等為了達成上述目的而專心研究的結果,發現藉由在製造時調配各種金屬鹽且使用經粉末化之澱粉分解物、及增黏多糖類,具有改善以三仙膠為首之增黏多糖類的分散性之效果,而完成了本發明。 As a result of intensive research in order to achieve the above object, the present inventors have found that by compounding various metal salts at the time of production and using powdered starch decomposition products and polysaccharide-promoting polysaccharides, it is possible to improve the viscosity-enhancing manner of Sanxian gum. The effect of the dispersibility of the polysaccharide is completed, and the present invention has been completed.

亦即,本發明第一是提供一種經改善分散性之增黏 組成物,其係含有含金屬鹽之澱粉分解物及增黏多糖類。 That is, the first aspect of the present invention provides an improved viscosity with improved dispersibility. The composition contains a starch-decomposing product containing a metal salt and a polysaccharide-promoting polysaccharide.

第二是如上述第一之增黏組成物,其中相對於100質量份澱粉分解物,金屬鹽的含量係0.5~40質量份。 The second is the first viscosity-increasing composition as described above, wherein the content of the metal salt is from 0.5 to 40 parts by mass based on 100 parts by mass of the starch decomposition product.

第三是如上述第一或第二之增黏組成物,其中金屬鹽係從鈣鹽、鈉鹽、鉀鹽、鎂鹽選擇之1種以上。 The third aspect is the above-mentioned first or second thickening composition, wherein the metal salt is one or more selected from the group consisting of a calcium salt, a sodium salt, a potassium salt and a magnesium salt.

第四是如上述第一至第三中任一項之增黏組成物,其中在增黏組成物所含有之含金屬鹽之澱粉分解物及增黏多糖類之質量比,係含金屬鹽之澱粉分解物:增黏多糖類=55:45~99:1。 The fourth aspect is the adhesion-promoting composition according to any one of the above-mentioned first to third, wherein the mass ratio of the metal-containing salt-decomposed starch and the polysaccharide-promoting polysaccharide contained in the viscosity-increasing composition is a metal salt-containing Starch decomposition product: Tackified polysaccharide = 55:45~99:1.

第五是一種稠度調整劑,其係含有如上述第一至第四中任一項之增黏組成物。 The fifth is a consistency adjuster comprising the adhesion-promoting composition according to any one of the above first to fourth.

第六是一種含金屬鹽之澱粉分解物,其係如上述第一至第四中任一項之增黏組成物的成分。\ The sixth is a metal salt-containing starch decomposition product which is a component of the adhesion-promoting composition according to any one of the above first to fourth. \

第七是如上述第六之含金屬鹽之澱粉分解物,其中金屬鹽的含量係相對於100質量份之澱粉分解物為0.5~40質量份。 The seventh is a starch decomposition product containing a metal salt as described above, wherein the content of the metal salt is 0.5 to 40 parts by mass based on 100 parts by mass of the starch decomposition product.

第八是如上述第六或第七之含金屬鹽之澱粉分解物,其中金屬鹽係從鈣鹽、鈉鹽、鉀鹽、鎂鹽選擇之1種以上。 The eighth aspect is the starch decomposition product of the metal salt according to the sixth or seventh aspect, wherein the metal salt is one or more selected from the group consisting of a calcium salt, a sodium salt, a potassium salt and a magnesium salt.

第九是如上述第六至第八中任一項之含金屬鹽之澱粉分解物,其中右旋糖(dextrose)當量係6~25。 The ninth is a metal salt-containing starch decomposition product according to any one of the above sixth to eighth invention, wherein the dextrose equivalent is 6 to 25.

第十是如上述第六至第九中任一項之含金屬鹽之澱粉分解物,其中具有90%以上為500μm以下的粒徑。 The metal salt-containing starch decomposition product according to any one of the above sixth to ninth, wherein the starch has a particle diameter of 90% or more and 500 μm or less.

第十一是如上述第六至第十中任一項之含金屬鹽之澱粉分解物,其中藉由噴霧乾燥法及/或鼓式乾燥器法製 造。 The eleventh is a metal salt-containing starch decomposition product according to any one of the above sixth to tenth, wherein the method is a spray drying method and/or a drum dryer method. Made.

第十二是一種增黏組成物的製造方法,其係在澱粉分解物的製造步驟中(較佳是水解處理後且過濾處理前)添加金屬鹽。 Twelfth is a method for producing a thickening composition by adding a metal salt in a production step of a starch decomposition product (preferably after a hydrolysis treatment and before a filtration treatment).

以下,詳細地說明本發明。又,只要未特別預先告知的情況,在本發明之「%」係意味著「重量%」。 Hereinafter, the present invention will be described in detail. Further, the "%" in the present invention means "% by weight" unless otherwise specified.

在本發明,所謂增黏多糖類係以增黏作為目的而使用之水溶性多糖類的總稱,例如可舉出三仙膠、瓜爾膠(guar gum)、刺槐豆(locust bean)膠、塔拉膠(tara gum)、角又菜膠(carageenan)、葡甘露聚糖(glucomannan)、天然結冷膠(Gellan gum)、脫醞基型結冷膠、羅望子膠(tarmarind seed gum)、果膠、明膠(gelatin)、阿拉伯膠、瓊脂等,在本發明,能夠適合利用該等增黏多糖類之1種類或2種類以上的組合,以三仙膠及/或瓜爾膠(guar gum)為佳,較佳可利用三仙膠。 In the present invention, the term "viscosity-promoting polysaccharide" is a generic term for water-soluble polysaccharides used for the purpose of viscosity-increasing, and examples thereof include a sacral gum, a guar gum, a locust bean gum, and a tower. Tara gum, carageenan, glucomannan, Gellan gum, degummed gellan gum, tarmarind seed gum, fruit Gum, gelatin, gum arabic, agar, etc., in the present invention, it is possible to use one or a combination of two or more types of these thickening polysaccharides, and to use guar gum and/or guar gum. Preferably, it is preferable to use Sanxian gum.

就為了製造本發明的澱粉分解物之澱粉原料而言,可舉出馬鈴薯澱粉、木薯(tapioca)澱粉、甘藷澱粉、西米澱粉(sago starch)、玉米澱粉、糯玉米澱粉(waxy corn starch)、高直鏈玉米澱粉(high amylose corn starch)、小麥澱粉、在來米澱粉、糯米澱粉等通常的原料澱粉、或是將其等藉由瞇化、醋化、氣化處理等通常的手段進行處理而成之加工澱粉,以使用馬鈴著澱粉為佳。 The starch raw material for producing the starch decomposition product of the present invention may, for example, be potato starch, tapioca starch, sweet potato starch, sago starch, corn starch, waxy corn starch, High amylose corn starch, wheat starch, rice starch, glutinous rice starch, etc., or other raw materials such as mash, vinegar, gasification, etc. For the processing of starch, it is preferred to use starch and starch.

在本發明,所謂澱粉分解物,係指在上述的原料澱粉或加工澱粉添加酸及/或酵素,且在高壓釜、或是連續水解裝置等適當的裝置內進行加熱而以DE(右旋糖當量) 為6~25,較佳是10~20的方式進行水解,而且將源自澱粉、酵素、酸、中和劑等之不純物過濾後,按照必要進行脫色、脫鹽等的純化處理,並且濃縮至必要程度而成之液狀品以及藉由噴霧乾燥等方法將其乾燥而成之粉末品。 In the present invention, the term "starch decomposition product" refers to the addition of an acid and/or an enzyme to the above-mentioned raw starch or processed starch, and heating in a suitable apparatus such as an autoclave or a continuous hydrolysis apparatus to form DE (dextrose). equivalent) Hydrolysis is carried out in a manner of 6 to 25, preferably 10 to 20, and impurities derived from starch, an enzyme, an acid, a neutralizing agent, and the like are filtered, and then subjected to purification treatment such as decolorization and desalting as necessary, and concentrated to the necessity. A liquid product obtained by drying it to a degree and dried by a method such as spray drying.

所謂在本發明之改善增黏組成物的分散性之含金屬鹽之澱粉分解物,係指在澱粉分解物添加必要量之本發明的金屬鹽且乾燥而得到之粉末品。就其製造方法而言,能夠在上述之澱粉分解物的製造步驟,在水解處理且噴霧乾燥為止之步驟、較佳是水解後過濾處理之前,添加本發明的金屬鹽且溶解而得到含金屬鹽之澱粉分解物濃縮液,並且將該澱粉分解物濃縮液噴霧乾燥而得到。 The starch-decomposing product containing a metal salt in the present invention for improving the dispersibility of the tackifying composition means a powder obtained by adding a necessary amount of the metal salt of the present invention to the starch decomposition product and drying it. In the production method, the metal salt of the present invention can be added and dissolved to obtain a metal salt in the step of producing the starch-decomposed product described above, in the step of hydrolysis treatment and spray drying, preferably after the post-hydrolysis filtration treatment. The starch decomposition product concentrate is obtained by spray-drying the starch decomposition product concentrate.

又,就其他方法而官,能夠將經濃縮至必要程度之澱粉分解物的液狀品或經噴霧乾燥之澱粉分解物溶解於必要量的水而成之液體,添加必要量之本發明的金屬鹽且溶解而成之適當濃度(55~65%,較佳是60%)的液體,進行鼓式乾燥器乾燥處理而得到。 Further, in another method, a liquid product obtained by dissolving a liquid product of a starch decomposed product to a certain extent or a spray-dried starch decomposition product in a necessary amount of water can be added, and a necessary amount of the metal of the present invention can be added. A liquid having an appropriate concentration (55 to 65%, preferably 60%) dissolved in salt is obtained by drying in a drum dryer.

在本發明之含金屬鹽之澱粉分解物,係能夠適合採用90%以上的粒子為具有500μm以下的粒徑者,較佳是具有150μm以下的粒徑者。 In the starch-decomposing product containing a metal salt of the present invention, it is possible to suitably use 90% or more of the particles to have a particle diameter of 500 μm or less, and preferably have a particle diameter of 150 μm or less.

在本發明,含有能夠添加在食品之金屬鹽之澱粉分解物,係為了改善增黏多糖類的分散性之目的而使用。在本發明所使用之金屬鹽,只要是通常被使用在食品等之金屬鹽類即適合而可以利用,例如可舉出鈉鹽、鉀鹽、鈣鹽、鎂鹽,以由包含該等之群組中選擇至少1種以上 為佳。 In the present invention, the starch-decomposable product which can be added to the metal salt of the food is used for the purpose of improving the dispersibility of the polysaccharide-promoting polysaccharide. The metal salt to be used in the present invention can be used as long as it is usually used as a metal salt of a food or the like, and examples thereof include a sodium salt, a potassium salt, a calcium salt, and a magnesium salt. Select at least 1 or more in the group It is better.

就鈉鹽而言,例如、L-抗壞血酸鈉、氯化鈉、葡糖酸鈉、苯甲酸鈉、檸檬酸亞鐵鈉、檸檬酸三鈉、L-麩釀胺酸鈉、乙酸鈉、溴化鈉、重碳酸鈉、酒石酸鉀鈉、酒石酸氫鈉、DL-酒石酸鈉、L-酒石酸鈉、硝酸鈉、碳酸鈉、乳醜鈉、焦磷酸四鈉、焦磷酸二氫二鈉、酞酸鈉、多磷酸鈉、偏磷酸鈉、亞硫酸氫鈉、硫酸鈉、磷酸氫二鈉、磷酸二氫鈉、磷酸三鈉,在本發明,以由包含該等之群組中選擇1種以上為佳。 In terms of sodium salt, for example, sodium L-ascorbate, sodium chloride, sodium gluconate, sodium benzoate, sodium ferrous citrate, trisodium citrate, sodium L-glutamate, sodium acetate, sodium bromide , sodium bicarbonate, sodium potassium tartrate, sodium hydrogen tartrate, DL-sodium tartrate, sodium L-tartrate, sodium nitrate, sodium carbonate, sodium sulphate, tetrasodium pyrophosphate, disodium dihydrogen pyrophosphate, sodium citrate, Sodium phosphate, sodium metaphosphate, sodium hydrogen sulfite, sodium sulfate, disodium hydrogen phosphate, sodium dihydrogen phosphate, and trisodium phosphate are preferred. In the present invention, it is preferred to select one or more selected from the group containing the above.

就鉀鹽而言,可舉出氯化鉀、檸檬酸亞鉀、檸檬酸三鉀、DL-酒石酸氫鉀、L-酒石酸氫鉀、碳酸鉀、焦磷酸四鉀、多磷酸鉀、偏磷酸鉀、磷酸三鉀、磷酸氫二鉀、硫酸鉀、亞硫酸氫鉀、葡糖酸鉀、L-麩釀膠酸鉀、乙酸鉀、溴化鉀、硝酸鉀、山梨酸鉀,在本發明,以由包含該等之群組中選擇1種以上為佳。 Examples of the potassium salt include potassium chloride, potassium citrate, tripotassium citrate, DL-potassium hydrogen tartrate, potassium hydrogen t-tartrate, potassium carbonate, tetrapotassium pyrophosphate, potassium polyphosphate, potassium metaphosphate. , tripotassium phosphate, dipotassium hydrogen phosphate, potassium sulfate, potassium hydrogen sulfite, potassium gluconate, potassium L-gluten, potassium acetate, potassium bromide, potassium nitrate, potassium sorbate, in the present invention, It is preferred to select one or more of the groups including the above.

就鈣鹽而言,可舉出氯化鈣、乳酸鈣、檸檬酸鈣、葡糖酸鈣、L-麩醯膠酸鈣、乙酸鈣、氫氧化鈣、碳酸鈣、乳酸鈣、焦磷酸二氫鈣、硫酸鈣、磷酸三鈣、磷酸一氫鈣、磷酸二氫鈣,在本發明,以由包含該等之群組中選擇1種以上為佳。 Examples of the calcium salt include calcium chloride, calcium lactate, calcium citrate, calcium gluconate, calcium L-glutenic acid, calcium acetate, calcium hydroxide, calcium carbonate, calcium lactate, and dihydrogen pyrophosphate. Calcium, calcium sulfate, tricalcium phosphate, monohydrogen phosphate, and calcium dihydrogen phosphate are preferable. In the present invention, it is preferred to select one or more selected from the group containing the above.

就鎂鹽而言,可舉出氯化鎂、L-麩醯胺酸鎂、碳酸鎂、硫酸鎂,在本發明,以由包含該等之群組中選擇1種以上為佳。 The magnesium salt may, for example, be magnesium chloride, magnesium L-glutamate, magnesium carbonate or magnesium sulfate. In the present invention, it is preferred to select one or more selected from the group containing the above.

以上之中,就分散性改善效果較高者而言,以使用乳酸鈣、氯化鈉、氯化鈣、蔔糖酸鈉為較佳。 Among them, in the case where the effect of improving the dispersibility is high, it is preferred to use calcium lactate, sodium chloride, calcium chloride or sodium silicate.

在本發明,該等金屬鹽相對於澱粉分解物之添加量,係相對於100質量份澱粉分解物為0.5~40質量份,以1~30質量份為佳,較佳是2~10質量份。金屬鹽的含量小於0.5質量份時,增黏組成物的分散性無法改善。另一方面,大於40質量份時,因為對含金屬鹽之澱粉分解物的製造及硬度、吸濕性造成不良影響,乃是不佳。又,因為大於10質量份時,係顯示與10質量份以下的添加量時同等的分散性且對味道亦有影響,以併用不含金屬鹽的澱粉分解物,來調整增黏組成物中的金屬鹽含量為佳。 In the present invention, the amount of the metal salt added to the starch decomposition product is 0.5 to 40 parts by mass, preferably 1 to 30 parts by mass, more preferably 2 to 10 parts by mass, per 100 parts by mass of the starch decomposition product. . When the content of the metal salt is less than 0.5 part by mass, the dispersibility of the tackifying composition cannot be improved. On the other hand, when it is more than 40 parts by mass, it is not preferable because it adversely affects the production of the metal salt-containing starch decomposition product and the hardness and hygroscopicity. In addition, when it is more than 10 parts by mass, it exhibits dispersibility equivalent to that of 10 parts by mass or less and affects taste, and the starch-decomposing product containing no metal salt is used in combination to adjust the viscosity-increasing composition. The metal salt content is preferred.

在本發明,所謂增黏組成物,係指含有含金屬鹽之澱粉分解物及增黏多糖類者,在增黏組成物所含有之含金屬鹽之澱粉分解物與增黏多糖類的質量比,係含金屬鹽之澱粉分解物:增黏多糖類=55:45~99:1,以60:40~99:1為佳,較佳是65:35~99:1,最佳是70:30~99:1。相較於含金屬鹽之澱粉分解物:增黏多糖類=55:45,含金屬鹽之澱粉分解物含有比為較小時,係無法觀察到分散性的改善。 In the present invention, the term "viscosity-increasing composition" refers to a mass ratio of a starch-decomposing substance containing a metal salt contained in a viscosity-increasing composition and a polysaccharide-promoting polysaccharide, and a starch-decomposing product containing a metal salt and a polysaccharide-promoting polysaccharide. , a starch-decomposing product containing a metal salt: a polysaccharide-promoting polysaccharide = 55:45 to 99:1, preferably 60:40 to 99:1, preferably 65:35 to 99:1, and most preferably 70: 30~99:1. The improvement in dispersibility was not observed when the starch-decomposing product containing the metal salt was 55:45 and the content ratio of the starch-decomposing product containing the metal salt was small.

在本發明所謂「分散性良的狀態」,係指將增黏組成物投入水中、攪拌時,由於粒子之間係在充分地分離之後產生膨潤,粒子之間不會結著而不會阻礙其他粒子的膨潤之狀態,而所謂「分散性差之狀態」,係指由於粒子之間在充分地分離之前,產生膨潤且與鄰接的粒子接觸而形成阻礙水的移動之膜,其他粒子與水接觸受到阻礙,而產生許多未膨潤的粒子、膨潤不充分的粒子被已 膨潤之粒子的膜包圍之「疙瘩」狀態。 In the present invention, the "dispersible state" means that when the viscosity-increasing composition is put into water and stirred, the particles are swollen after being sufficiently separated, and the particles are not adhered to each other without hindering the other. The state in which the particles are swollen, and the "state in which the dispersibility is poor" means that the particles are swollen before being sufficiently separated from each other and come into contact with the adjacent particles to form a film that hinders the movement of water, and the other particles are in contact with water. Obstruction, and many unexpanded particles, insufficiently swollen particles have been The "疙瘩" state surrounded by the film of the swollen particles.

在本發明之分散性的評價,係藉由分散性評價試驗而進行。本發明之分散性評價試驗係依照以下程序而進行。相對於100g之20℃的水或80℃的熱水添加3.0g增黏組成物後,水係靜置5秒後,熱水係靜置3秒後,使用攪拌棒且水係攪拌1分鐘,熱水係攪拌30秒且以目視確認所產生之疙瘩的大小及數目,從分散性良好者起,採用以下4階段進行評價,-(分散性良好且未產生疙瘩)、+(分散性良好但是產生數個小疙瘩)、++(分散性稍差且產生許多小疙瘩)、+++(分散性差且產生許多大疙瘩)。 The evaluation of the dispersibility in the present invention was carried out by a dispersion evaluation test. The dispersibility evaluation test of the present invention was carried out in accordance with the following procedure. After adding 3.0 g of the viscosity-increasing composition to 100 g of water of 20 ° C or hot water of 80 ° C, the water system was allowed to stand for 5 seconds, and then the hot water was allowed to stand for 3 seconds, and then the mixture was stirred for 1 minute using a stirring bar. The hot water was stirred for 30 seconds, and the size and number of the ruthenium produced were visually confirmed, and the evaluation was carried out in the following four stages from the viewpoint of good dispersibility, - (dispersibility was good, no enthalpy was generated), and + (dispersibility was good, but Produce several small flaws), ++ (slightly dispersive and produce many small flaws), +++ (poor dispersion and many large flaws).

在本發明所謂分散性的改善,係意味著在增黏組成物,不變更其組成比而與將澱粉分解物取代成為不含金屬鹽者比較,在分散性評價試驗之分散性評價階段係柱分散性良好側提升。 The improvement of the dispersibility in the present invention means that in the viscosity-increasing composition, the composition is not changed, and the starch decomposition product is substituted into a metal salt-free one, and the column is evaluated in the dispersion evaluation stage of the dispersion evaluation test. Good dispersion and side lift.

藉由使用依照本發明而得到的增黏組成物,能夠得到經抑制在使用時產生疙瘩之稠度調整劑。而且,在本發明,不必將先前技術所記載之金屬鹽溶液使用作為黏合劑,而能夠使增黏組成物的分散性提升。亦即,在製造增黏組成物製造時有必要造粒之情況,能夠只有將水作為黏合劑而造粒,因為不必考慮黏合劑的添加量對組成所造成的影響,而能夠比較自由地進行噴霧量、噴霧時問等的設定,使得作業變為容易 By using the thickening composition obtained according to the present invention, it is possible to obtain a consistency adjusting agent which suppresses generation of ruthenium during use. Further, in the present invention, it is not necessary to use the metal salt solution described in the prior art as a binder, and the dispersibility of the adhesion-promoting composition can be improved. That is, it is necessary to granulate in the manufacture of the tackifying composition, and it is possible to granulate only by using water as a binder, since it is not necessary to consider the influence of the amount of the binder added on the composition, and it can be carried out relatively freely. The amount of spray, spray time, etc. make the job easy

[用以實施發明之形態] [Formation for implementing the invention]

以下,針對本發明之增黏組成物,配合實施例而詳細地說明,但是本發明的技術範圍係不被以下的例子限定。 Hereinafter, the tackifier composition of the present invention will be described in detail with reference to examples, but the technical scope of the present invention is not limited by the following examples.

在本發明係使用以下的試劑。 In the present invention, the following reagents are used.

三仙膠:ECHO-GUM T(CP Kelco公司製) Sanxianjiao: ECHO-GUM T (manufactured by CP Kelco)

乳酸鈣:五水合乳酸鈣(扶桑化學工業股份公司製) Calcium lactate: calcium lactate pentahydrate (made by Fuso Chemical Industry Co., Ltd.)

氯化鈣:氯化鈣(林純藥工業股份公司製) Calcium Chloride: Calcium Chloride (made by Lin Chun Pharmaceutical Industry Co., Ltd.)

氯化鈉:氯化鈉(林純藥工業股份公司製) Sodium chloride: sodium chloride (made by Lin Chun Pharmaceutical Industry Co., Ltd.)

葡糖酸鈉:葡糖酸鈉(和光純藥工業股份公司製) Sodium gluconate: sodium gluconate (made by Wako Pure Chemical Industries, Ltd.)

L-抗壞血酸鈉:L-抗壞血酸鈉(林純藥工業股份公司製) L-ascorbate: L-ascorbate (made by Lin Chun Pharmaceutical Co., Ltd.)

氯化鉀:氯化鉀(林純藥工業股份公司製) Potassium Chloride: Potassium Chloride (made by Lin Pure Pharmaceutical Industry Co., Ltd.)

氯化鎂:六水合氯化鎂(林純藥工業股份公司製) Magnesium chloride: Magnesium chloride hexahydrate (made by Lin Chun Pharmaceutical Industry Co., Ltd.)

硬脂酸鈣:硬脂酸鈣(林純藥工業股份公司製) Calcium stearate: Calcium stearate (made by Lin Chun Pharmaceutical Co., Ltd.)

[調製例1](藉由噴霧乾燥製造本發明之含金屬鹽之澱粉分解物) [Preparation Example 1] (Production of a metal salt-containing starch decomposition product of the present invention by spray drying)

在水1250質量份(以下稱為「份」)於攪拌下添加1000份馬鈴著澱粉而調製之漿料,添加1份α-澱粉醃(α-amylase)(酵素力價13000U/g),且於88~90℃進行酵素分解處理150分鐘。隨後,使用稀鹽酸調整為pH4.0來使酵素去活之後,添加70份五水合乳酸鈣且溶解,並且使用碳酸鈣調整為pH5.5,在該液體添加平均液體的固體含量為0.5%的過濾助劑(Radiolite#800、昭和化學工業股份公司製)及0.5%的活性碳,於液溫65~75℃進行吸引過濾、濃縮且使用NIRO公司製MOBILE MINOR型噴霧式 乾燥器,以入口溫度170~180℃、出口溫度100~105℃進行噴霧乾燥而得到含有5%乳酸鈣之澱粉分解物(調製品1)。DE16.2而比容積係2.3mL/g。90%以上的粒子係粒徑為150μm以下。 1250 parts by mass of water (hereinafter referred to as "parts") was added with 1000 parts of starch mixed with starch under stirring, and 1 part of α-amylase (α-amylase) (enzyme price 13000 U/g) was added. The enzyme was decomposed and treated at 88 to 90 ° C for 150 minutes. Subsequently, after the enzyme was deactivated using dilute hydrochloric acid adjusted to pH 4.0, 70 parts of calcium lactate pentahydrate was added and dissolved, and calcium carbonate was adjusted to pH 5.5, and the solid content of the liquid added to the liquid was 0.5%. Filtration aid (Radiolite #800, manufactured by Showa Chemical Industry Co., Ltd.) and 0.5% activated carbon, suction filtration, concentration at 65 to 75 ° C, and use of MOBILE MINOR spray type manufactured by NIRO The dryer was spray-dried at an inlet temperature of 170 to 180 ° C and an outlet temperature of 100 to 105 ° C to obtain a starch decomposition product (modulation 1) containing 5% calcium lactate. DE16.2 and the specific volume is 2.3 mL/g. 90% or more of the particle system has a particle diameter of 150 μm or less.

[比較調製例1](藉由噴霧乾燥製造澱粉分解物) [Comparative Modification Example 1] (Production of starch decomposition product by spray drying)

在水1250質量份(以下稱為「份」)於攪拌下添加1000份馬鈴著澱粉而調製之漿料,添加1份α-澱粉(α-amylase)(酵素力價13000U/g),且於88~90℃進行酵素分解處理140分鐘。隨後,使用稀鹽酸調整為pH4.0來使酵素去活之後,使用碳酸鈣調整為pH5.5,在該液體添加平均液體的固體含量為0.5%的過濾助劑(Radiolite#800、昭和化學工業股份公司製)及0.5%的活性碳,於液溫65~75℃進行吸引過濾、濃縮且使用NIRO公司製MOBILE MINOR型噴霧式乾燥器,以入口溫度170~180℃、出口溫度100~105℃進行噴霧乾燥而得到澱粉分解物(比較調製品1)。DE15.3而比容積係2.2mL/g。90%以上的粒子係粒徑為150μm以下。 1250 parts by mass of water (hereinafter referred to as "parts") was added with 1000 parts of a slurry prepared by stirring starch, and 1 part of α-amylase (enzyme cost 13000 U/g) was added, and Enzyme decomposition treatment was carried out at 88 to 90 ° C for 140 minutes. Subsequently, after diluting the enzyme to pH 4.0 using dilute hydrochloric acid, the calcium carbonate was adjusted to pH 5.5, and a filter aid having an average liquid solid content of 0.5% was added to the liquid (Radiolite #800, Showa Chemical Industry) Co., Ltd.) and 0.5% activated carbon are suction filtered and concentrated at a liquid temperature of 65 to 75 ° C and used a MOBILE MINOR spray dryer manufactured by NIRO, with an inlet temperature of 170-180 ° C and an outlet temperature of 100-105 ° C. Spray drying was carried out to obtain a starch decomposition product (Comparative Preparation 1). DE15.3 and the specific volume is 2.2mL/g. 90% or more of the particle system has a particle diameter of 150 μm or less.

[調製例2](藉由鼓式乾燥器乾燥製造本發明之含金屬鹽之澱粉分解物) [Preparation Example 2] (Production of a metal salt-containing starch decomposition product of the present invention by drying in a drum dryer)

在300份比較調製品1,添加水而調製濃度60%的澱粉分解物水溶液,在該等的液體溶解在表1所表示的金屬鹽,且依照常用方法而藉由KATSURAGI工業股份公司製常壓開放式雙鼓式乾燥器(Φ 1250mm×L3000mm、蒸氣內壓0.8MPa、轉數1.6rpm)進行乾燥粉末化,來得到乾燥粉末(調製品2-1~2-12)。90%以上的粒 子係粒徑為500μm以下。 In 300 parts of the comparative preparation 1, water was added to prepare a 60% aqueous solution of a starch decomposition product, and the liquid was dissolved in the metal salt shown in Table 1, and the atmospheric pressure was made by KATSURAGI Industries Co., Ltd. according to a usual method. An open double drum dryer (Φ 1250 mm × L 3000 mm, a vapor internal pressure of 0.8 MPa, and a number of revolutions of 1.6 rpm) was subjected to dry powdering to obtain a dry powder (adjusted products 2-1 to 2-12). More than 90% of the particle size is 500 μm or less.

[比較調製例2](藉由鼓式乾燥器乾燥製造澱粉分解物) [Comparative Modification Example 2] (Production of starch decomposition product by drum dryer drying)

在300份比較調製品1,添加水而調製濃度60%的澱粉分解物水溶液,在該液體依照常用方法而藉由KATSURAGI工業股份公司製常壓開放式雙鼓式乾燥器(Φ 1250mm×L30O0mm、蒸氣內壓0.8SMPa、轉數1.6rpm)進行乾燥粉末化,來得到乾燥粉末(比較調製品2-1)。90%以上的粒子係粒徑為500μm以下。 In 300 parts of the comparative preparation 1, water was added to prepare a 60% aqueous solution of a starch decomposition product, and the liquid was subjected to a normal-pressure open double drum dryer (Φ 1250 mm × L30 O0 mm, manufactured by KATSURAGI Industrial Co., Ltd. according to a usual method). Drying powder was carried out by a vapor internal pressure of 0.8 SMPa and a number of revolutions of 1.6 rpm to obtain a dry powder (Comparative Preparation 2-1). 90% or more of the particle system has a particle diameter of 500 μm or less.

又,在300份比較調製品1,添加水而調製濃度60%的澱粉分解物水溶液,在該液體溶解硬脂酸鈣(添加量:0.3質量份,調製品中的金屬鹽含量:0.1質量份/澱粉分解物100質量份),依照常用方法而藉由KATSURAGI工業股份公司製常壓開放式雙鼓式乾燥器(Φ 1250mm× L3000mm、蒸氣內壓0.8MPa、轉數1.6rpm)進行乾燥粉末化,來得到乾燥粉末(比較調製品2-2)。90%以上的粒子係粒徑為500μm以下。 Further, 300 parts of the comparative preparation product 1 was added with water to prepare a 60% aqueous solution of a starch decomposition product, and calcium stearate was dissolved in the liquid (addition amount: 0.3 parts by mass, metal salt content in the preparation: 0.1 part by mass) /100% by mass of starch decomposition product, by atmospheric pressure open double drum dryer manufactured by KATSURAGI Industrial Co., Ltd. according to the usual method (Φ 1250 mm × Dry powdering was carried out by L3000 mm, a vapor internal pressure of 0.8 MPa, and a number of revolutions of 1.6 rpm to obtain a dry powder (Comparative Preparation 2-2). 90% or more of the particle system has a particle diameter of 500 μm or less.

[實施今1] [Implementation 1] (增黏組成物的製造) (Manufacture of adhesion-increasing composition)

將三仙膠及調製品以表2表示的比例稱取在直徑60mm的塑膠容器,將該等容器之間以相向的狀態進行混合,而得到本發明之實施品1-17。 The Sanxian gum and the preparation were weighed in a plastic container having a diameter of 60 mm in the ratio shown in Table 2, and the containers were mixed in a state of being opposed to each other to obtain an embodiment 1-17 of the present invention.

[比較例1](增黏組成物的製造) [Comparative Example 1] (manufacture of a thickening composition)

將三仙膠及調製品、比較調製品以表3表示的比例 稱取在直徑60mm的塑膠容器,將該等容器之間以相向的狀態進行混合,而得到比較品1~19。 The proportions of Sanxianjiao and modified products and comparative preparations are shown in Table 3. A plastic container having a diameter of 60 mm was weighed, and the containers were mixed in a facing state to obtain Comparative Products 1 to 19.

[實施例2] [Embodiment 2]

將30g三仙膠、70g調製品1混合之後,投入流動層造粒機(FLO-MINI/FREUND產業製),且設定為吸氣溫度80℃之後,將40g水作為黏合劑而以2.5g/min的流速連續噴霧,黏合劑全量噴霧復,於吸氣溫度80℃乾燥5分鐘。使用孔眼開度1.40mm及0.15mm的篩將所得到的造粒物進行分級,將通過孔眼開度1.40mm且不通過孔 眼閉度0.15mm的篩者回收而得到本發明之實施品18。 After mixing 30 g of Sanxian gum and 70 g of the preparation 1 , the mixture was poured into a fluidized bed granulator (manufactured by FLO-MINI/FREUND), and set to an inhalation temperature of 80 ° C, and then 40 g of water was used as a binder to 2.5 g / The flow rate of min was continuously sprayed, and the total amount of the binder was sprayed and dried at an inhalation temperature of 80 ° C for 5 minutes. The obtained granules were classified using a sieve having a hole opening of 1.40 mm and 0.15 mm, and the opening was 1.40 mm and passed through the hole. The sieve of the eye opening degree of 0.15 mm was recovered to obtain the product 18 of the present invention.

[比較例2] [Comparative Example 2]

將30g三仙膠、70g比較調製品混合之後,投入流動層造粒機(FLO-MINI/FREUND產業製),且進行在實施例2所記載的操作而得到比較品20。 After mixing 30 g of Sanxian gum and 70 g of a comparative preparation, the mixture was poured into a fluidized bed granulator (manufactured by FLO-MINI/FREUND), and the operation described in Example 2 was carried out to obtain a comparative product 20.

[評價例] [Evaluation example] (分散性評價試驗) (Dispersion evaluation test)

分散性評價試驗係依照以下的程序進行。 The dispersion evaluation test was carried out in accordance with the following procedure.

(在20℃的水之試驗) (test of water at 20 ° C)

1.將3.0g增黏組成物添加至300mL容量的燒杯中之100g 20℃的水後,靜置5秒zxab 1. Add 3.0 g of the adhesion-increasing composition to 100 g of water at 20 ° C in a 300 mL capacity beaker and let stand for 5 seconds zxab

2.使用攪拌棒攪拌1分鐘zxab 2. Stir for 1 minute with a stir bar zxab

3.依據下述的評價基準以目視評價zxad 3. Visually evaluate zxad based on the following evaluation criteria

(在80℃的熱水之試驗) (Test of hot water at 80 ° C)

1.將3.0g增黏組成物添加至300mL容量的燒杯中之100g 80℃的水後,靜置3秒zxab 1. Add 3.0 g of the adhesion-increasing composition to 100 g of water at 80 ° C in a 300 mL capacity beaker and let stand for 3 seconds zxab

2.使用攪拌棒攪拌30秒鐘zxab 2. Stir for 30 seconds with a stir bar zxab

3.依據下述的評價基準以目視評價 3. Visual evaluation based on the following evaluation criteria

(評價基率) (evaluation basis rate)

-(分散性良好且不產生疙瘩), - (dispersive and does not produce defects),

+(分散性良好但是產生數個小疙瘩), +(Good dispersion but several small defects),

+++(分散性稍差且產生許多小疙瘩), +++ (slightly dispersive and produces many small flaws),

+++(分散性差且產生許多大疙瘩)。 +++ (poor dispersion and many big problems).

[測定例1](金屬鹽含量的比較) [Measurement Example 1] (Comparison of metal salt content)

對金屬鹽含量不同的實施品、比較品,實施分散性 評價試驗來進行評價而得到表4的結果。 Dispersion of implements and comparative products with different metal salt contents The test results were evaluated to obtain the results of Table 4.

從該結果,得知相較於不含有者,含有含0.5質量份金屬鹽/100質量份澱粉分解物以上的澱粉分解物之增黏組成物,其分散性係提升。 From the results, it was found that the viscosity-increasing composition containing a starch decomposition product containing 0.5 parts by mass or more of the metal salt/100 parts by mass or more of the starch-decomposed product is improved in dispersibility.

[測定例2](澱粉分解物含有比的比較) [Measurement Example 2] (Comparison of the content ratio of starch decomposition products)

對澱粉分解物的含有比不同之實施品、比較品,實施分散性評價試驗來進行評價而得到表5及6的結果。 The results of Tables 5 and 6 were obtained by performing a dispersion evaluation test on the products and comparative products having different content ratios of the starch-decomposed products.

從該結果,得知相較於較少者,以質量比計含金屬鹽之澱粉分解物比增黏多糖類更多者,其分散性係提升。又,得知相較於使用不含金屬鹽之澱粉分解物者,使用含金屬鹽之澱粉分解物之增黏組成物,其分散性係 提升。 From the results, it was found that the dispersibility of the starch-decomposing product containing the metal salt was higher than that of the polysaccharide in the mass ratio. Further, it has been found that a viscosity-increasing composition of a starch-decomposing product containing a metal salt is used as compared with a starch-decomposing product containing no metal salt, and the dispersibility is Upgrade.

[測定例3](依照金屬鹽種類之比較) [Measurement Example 3] (comparison of metal salt types)

對金屬鹽不同的實施品,實施分散性評價試驗來進行評價而得到表7的結果。 The results of Table 7 were obtained by performing a dispersion evaluation test on different products having different metal salts.

從該結果,得知本發明之增黏組成物係不管金屬鹽的種類如何,均顯示良好的分散性。 From the results, it was found that the tackifying composition of the present invention showed good dispersibility regardless of the kind of the metal salt.

[測定例4](依照製造法之比較) [Measurement Example 4] (comparison according to the manufacturing method)

對製造法不同的實施品,實施分散性評價試驗來進行評價而得到表8的結果。 The results of Table 8 were obtained by performing a dispersion evaluation test on the products having different manufacturing methods.

從該結果,得知關於流動造粒品,本發明亦能夠觀察到效果。 From the results, it was found that the effect of the present invention can also be observed with respect to the flow granulated product.

[實施例3] [Example 3] (利用作為稠度調整劑) (utilized as a consistency adjuster)

將4.5g實施品3添加至300mL容量的燒杯中之100g 20℃的水,使用攪拌棒攪拌1分鐘,藉此能夠得到具有適當稠度的水溶液。 4.5 g of the product 3 was added to 100 g of water at 20 ° C in a 300 mL-capacity beaker, and stirred with a stir bar for 1 minute, whereby an aqueous solution having an appropriate consistency could be obtained.

[產業上之利用可能性] [Industry use possibility]

藉由實施本發明,能夠得到分散性良好的增黏組成物、及利用其之稠度調整劑。 By carrying out the present invention, it is possible to obtain a thickening composition having good dispersibility and a consistency adjusting agent using the same.

Claims (7)

一種經改善分散性之增黏組成物,其係含有含金屬鹽之澱粉分解物及增黏多糖類。 A viscosity-increasing composition having improved dispersibility, which comprises a starch-decomposing product containing a metal salt and a polysaccharide-promoting polysaccharide. 如申請專利範圍第1項之增黏組成物,其中相對於100質量份澱粉分解物,金屬鹽的含量為0.5~40質量份。 The viscosity-increasing composition of claim 1, wherein the content of the metal salt is from 0.5 to 40 parts by mass based on 100 parts by mass of the starch decomposition product. 如申請專利範圍第1或2項之增黏組成物,其中金屬鹽係從鈣鹽、鈉鹽、鉀鹽、鎂鹽選擇之1種以上。 The viscosity-increasing composition of the first or second aspect of the invention, wherein the metal salt is one or more selected from the group consisting of a calcium salt, a sodium salt, a potassium salt, and a magnesium salt. 如申請專利範圍第1至3項中任一項之增黏組成物,其中在增黏組成物所含有之含金屬鹽之澱粉分解物及增黏多糖類之質量比,係含金屬鹽之澱粉分解物:增黏多糖類=55:45~99:1。 The viscosity-increasing composition according to any one of claims 1 to 3, wherein the mass ratio of the metal-containing salt-decomposed starch and the polysaccharide-promoting polysaccharide contained in the viscosity-increasing composition is a metal salt-containing starch Decomposition: Tackified polysaccharide = 55:45~99:1. 一種稠度調整劑,其係含有如申請專利範圍第1至4項中任一項之增黏組成物。 A consistency adjusting agent comprising the tackifying composition according to any one of claims 1 to 4. 一種含金屬鹽之澱粉分解物,其係如申請專利範圍第1至4項中任一項之增黏組成物的成分。 A metal salt-containing starch decomposition product which is a component of the adhesion-promoting composition according to any one of claims 1 to 4. 一種增黏組成物的製造方法,其係在澱粉分解物的製造步驟中添加金屬鹽。 A method for producing a viscosity-increasing composition, which comprises adding a metal salt in a step of producing a starch decomposition product.
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