JP6254993B2 - Thickening composition with improved dispersibility and metal salt-containing starch degradation product used therefor - Google Patents
Thickening composition with improved dispersibility and metal salt-containing starch degradation product used therefor Download PDFInfo
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- JP6254993B2 JP6254993B2 JP2015223162A JP2015223162A JP6254993B2 JP 6254993 B2 JP6254993 B2 JP 6254993B2 JP 2015223162 A JP2015223162 A JP 2015223162A JP 2015223162 A JP2015223162 A JP 2015223162A JP 6254993 B2 JP6254993 B2 JP 6254993B2
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- Prior art keywords
- metal salt
- starch
- dispersibility
- thickening
- sodium
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- 229920002472 Starch Polymers 0.000 title claims description 64
- 235000019698 starch Nutrition 0.000 title claims description 63
- 239000008107 starch Substances 0.000 title claims description 63
- 230000008719 thickening Effects 0.000 title claims description 54
- 229910052751 metal Inorganic materials 0.000 title claims description 53
- 239000002184 metal Substances 0.000 title claims description 53
- 150000003839 salts Chemical class 0.000 title claims description 51
- 239000000203 mixture Substances 0.000 title claims description 42
- 239000007857 degradation product Substances 0.000 title claims description 23
- 239000000047 product Substances 0.000 claims description 45
- 238000000354 decomposition reaction Methods 0.000 claims description 31
- 150000004676 glycans Chemical class 0.000 claims description 16
- 229920001282 polysaccharide Polymers 0.000 claims description 16
- 239000005017 polysaccharide Substances 0.000 claims description 16
- 159000000007 calcium salts Chemical class 0.000 claims description 5
- 159000000003 magnesium salts Chemical class 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 1
- 238000010494 dissociation reaction Methods 0.000 claims 1
- 230000005593 dissociations Effects 0.000 claims 1
- 235000014655 lactic acid Nutrition 0.000 claims 1
- 239000004310 lactic acid Substances 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000002245 particle Substances 0.000 description 22
- 238000011156 evaluation Methods 0.000 description 19
- 238000002360 preparation method Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- 239000011230 binding agent Substances 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- 229920001285 xanthan gum Polymers 0.000 description 13
- 235000010493 xanthan gum Nutrition 0.000 description 13
- 239000000230 xanthan gum Substances 0.000 description 13
- 229940082509 xanthan gum Drugs 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229920002245 Dextrose equivalent Polymers 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 6
- 239000001527 calcium lactate Substances 0.000 description 6
- 235000011086 calcium lactate Nutrition 0.000 description 6
- 229960002401 calcium lactate Drugs 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 229920001353 Dextrin Polymers 0.000 description 5
- 239000004375 Dextrin Substances 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 229960002713 calcium chloride Drugs 0.000 description 5
- 235000011148 calcium chloride Nutrition 0.000 description 5
- 235000019425 dextrin Nutrition 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 229920001592 potato starch Polymers 0.000 description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000000176 sodium gluconate Substances 0.000 description 4
- 235000012207 sodium gluconate Nutrition 0.000 description 4
- 229940005574 sodium gluconate Drugs 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- 229920002261 Corn starch Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 229960003563 calcium carbonate Drugs 0.000 description 3
- 235000010216 calcium carbonate Nutrition 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229920000591 gum Polymers 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000283014 Dama Species 0.000 description 2
- 229920002148 Gellan gum Polymers 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 102000004139 alpha-Amylases Human genes 0.000 description 2
- 108090000637 alpha-Amylases Proteins 0.000 description 2
- 229940024171 alpha-amylase Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229940057801 calcium lactate pentahydrate Drugs 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- JCFHGKRSYPTRSS-UHFFFAOYSA-N calcium;2-hydroxypropanoic acid;hydrate Chemical compound O.[Ca].CC(O)C(O)=O JCFHGKRSYPTRSS-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- JNSGIVNNHKGGRU-JYRVWZFOSA-N diethoxyphosphinothioyl (2z)-2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoacetate Chemical compound CCOP(=S)(OCC)OC(=O)C(=N/OC)\C1=CSC(N)=N1 JNSGIVNNHKGGRU-JYRVWZFOSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000007515 enzymatic degradation Effects 0.000 description 2
- 235000010492 gellan gum Nutrition 0.000 description 2
- 239000000216 gellan gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 229960002337 magnesium chloride Drugs 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000001508 potassium citrate Substances 0.000 description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 2
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 229940100486 rice starch Drugs 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 2
- 229960005055 sodium ascorbate Drugs 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 229960002668 sodium chloride Drugs 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000001744 Sodium fumarate Substances 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 229960004256 calcium citrate Drugs 0.000 description 1
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940095643 calcium hydroxide Drugs 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229960002079 calcium pantothenate Drugs 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 229940095672 calcium sulfate Drugs 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- NIDRASOKXCQPKX-DFWYDOINSA-L calcium;(2s)-2-aminopentanedioate Chemical compound [Ca+2].[O-]C(=O)[C@@H](N)CCC([O-])=O NIDRASOKXCQPKX-DFWYDOINSA-L 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- VEJCUEBBRSCJRP-UHFFFAOYSA-L calcium;hydron;phosphonato phosphate Chemical compound [Ca+2].OP(O)(=O)OP([O-])([O-])=O VEJCUEBBRSCJRP-UHFFFAOYSA-L 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 230000020176 deacylation Effects 0.000 description 1
- 238000005947 deacylation reaction Methods 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- WDRWZVWLVBXVOI-QTNFYWBSSA-L dipotassium;(2s)-2-aminopentanedioate Chemical compound [K+].[K+].[O-]C(=O)[C@@H](N)CCC([O-])=O WDRWZVWLVBXVOI-QTNFYWBSSA-L 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 235000019820 disodium diphosphate Nutrition 0.000 description 1
- MSJMDZAOKORVFC-SEPHDYHBSA-L disodium fumarate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C\C([O-])=O MSJMDZAOKORVFC-SEPHDYHBSA-L 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 235000021056 liquid food Nutrition 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- MYUGVHJLXONYNC-QHTZZOMLSA-L magnesium;(2s)-2-amino-5-hydroxy-5-oxopentanoate Chemical compound [Mg+2].[O-]C(=O)[C@@H](N)CCC(O)=O.[O-]C(=O)[C@@H](N)CCC(O)=O MYUGVHJLXONYNC-QHTZZOMLSA-L 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 229940086065 potassium hydrogentartrate Drugs 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 1
- 229940074439 potassium sodium tartrate Drugs 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019294 sodium fumarate Nutrition 0.000 description 1
- 229940005573 sodium fumarate Drugs 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229940001516 sodium nitrate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 239000011755 sodium-L-ascorbate Substances 0.000 description 1
- 235000019187 sodium-L-ascorbate Nutrition 0.000 description 1
- NKAAEMMYHLFEFN-ZVGUSBNCSA-M sodium;(2r,3r)-2,3,4-trihydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O NKAAEMMYHLFEFN-ZVGUSBNCSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- JHYAVWJELFKHLM-UHFFFAOYSA-H tetrasodium;2-hydroxypropane-1,2,3-tricarboxylate;iron(2+) Chemical compound [Na+].[Na+].[Na+].[Na+].[Fe+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O JHYAVWJELFKHLM-UHFFFAOYSA-H 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- Grain Derivatives (AREA)
- Jellies, Jams, And Syrups (AREA)
Description
本発明は、金属塩を含有した澱粉分解物を用いることにより分散性の改善された、増粘組成物に関する。 The present invention relates to a thickening composition having improved dispersibility by using a starch decomposition product containing a metal salt.
高齢化の進行に伴い、嚥下困難者向けの飲食物の粘度を調整する目的で使用される増粘組成物、所謂とろみ調整剤の需要が増大している。しかし、とろみ調整剤の主剤であるキサンタンガムは分散性が極めて低く、水に添加された粉体の集合体は、水と接触する部分から膨潤を開始し、集合体の表面を覆い、集合体の内部への水の浸透を遮蔽し、所謂「ダマ」を形成する。このようなダマを完全に溶解させることは非常に困難であり、とろみ調整剤の使用の上で問題となっていた。 With the progress of aging, there is an increasing demand for thickening compositions used for the purpose of adjusting the viscosity of foods and drinks for those with difficulty in swallowing, so-called thickening regulators. However, xanthan gum, which is the main component of the thickener, has extremely low dispersibility, and the aggregate of powder added to water starts to swell from the portion in contact with water, covers the surface of the aggregate, It shields the penetration of water into the interior and forms a so-called “dama”. It is very difficult to completely dissolve such lumps, which has been a problem in the use of thickeners.
これまで、キサンタンガム粉末を造粒する際に用いるバインダー液を改良することにより、分散性を改善させた特許が多数出願されている。 So far, many patents have been filed in which dispersibility is improved by improving the binder liquid used when granulating xanthan gum powder.
例えば、特開2004−49225号公報(特許文献1)には、キサンタンガムなどのゾル化剤およびデキストリンなどの水溶性分散剤を造粒することにより、液状食品に対して分散性、溶解性がよく、ゲル化またはゾル化後の食品の低付着性、高凝集性を実現させた技術が開示されている。 For example, JP 2004-49225 A (Patent Document 1) discloses good dispersibility and solubility in liquid foods by granulating a solubilizing agent such as xanthan gum and a water-soluble dispersing agent such as dextrin. In addition, a technique for realizing low adhesion and high cohesion of food after gelation or sol formation is disclosed.
特開2010−81943号公報(特許文献2)、特開2008−61608号公報(特許文献3)、特許第3930897号明細書(特許文献4)では、キサンタンガムの粉末表面にカリウム塩やアルギン酸塩、カルボキシルメチルセルロース(CMC)または金属塩溶液をバインダーとして噴霧し造粒することにより、ダマにならずに分散・溶解し添加後2分でピーク粘度の90%以上に達することを実現させた技術が開発されている。 In JP 2010-81943 A (patent document 2), JP 2008-61608 A (patent document 3), and Japanese Patent No. 3930897 specification (patent document 4), a potassium salt or an alginate on the powder surface of xanthan gum, Developed a technology that achieves 90% or more of the peak viscosity in 2 minutes after addition by dispersing and dissolving without damaging by spraying and granulating carboxyl methyl cellulose (CMC) or metal salt solution as a binder Has been.
特開2008−68194号公報(特許文献5)には、塩化カルシウム、乳酸カルシウム、及びパントテン酸カルシウムからなる群から選ばれる1種以上を含有する水溶液をバインダーとして水溶性高分子の粉末を造粒することにより、スパーテルなどによる手攪拌といった弱い攪拌条件においても、水溶性高分子などの粉末がダマを起こさずに容易に分散・溶解させることを実現させた技術が開示されている。 In JP 2008-68194 A (Patent Document 5), a water-soluble polymer powder is granulated using an aqueous solution containing at least one selected from the group consisting of calcium chloride, calcium lactate, and calcium pantothenate as a binder. Thus, a technique has been disclosed in which a powder such as a water-soluble polymer can be easily dispersed and dissolved without causing lumps even under weak stirring conditions such as manual stirring with a spatula or the like.
特開2011−120538号公報(特許文献6)では、増粘多糖類及びデキストリンを含有する粉末原料にデキストリンを18〜35重量%含有する水溶液をバインダー液として噴霧・造粒するとともに、粉末原料にCMCナトリウム塩を含有することで、飲食品の風味を損なうことなく、粘度の立ち上がりと持続性が良好で、かつ分散性が良好で、ダマの発生が抑制できる増粘剤造粒物を得られる技術が開発されている。 JP 2011-120538 A (Patent Document 6) sprays and granulates an aqueous solution containing 18 to 35% by weight of dextrin as a powder raw material containing a thickening polysaccharide and dextrin as a binder liquid. By containing CMC sodium salt, it is possible to obtain a thickener granule that has good viscosity rise and sustainability, good dispersibility, and can suppress the occurrence of lumps without impairing the flavor of food and drink. Technology has been developed.
また、キサンタンガムの改良の他、分散剤として添加するデキストリンの種類を限定することにより、分散性を改善させた特許も出願されている。特開2006−6252号公報(特許文献7)では、ゲル化及び/又は増粘する性質を有する水溶性高分子とDE値5以下のデキストリンを含む混合物を顆粒化することにより、水溶性高分子のランピングを防止する技術が開発されている。 In addition to the improvement of xanthan gum, patents that improve dispersibility by limiting the type of dextrin added as a dispersant have been filed. In JP 2006-6252 A (Patent Document 7), a water-soluble polymer is granulated by granulating a mixture containing a water-soluble polymer having a gelling and / or thickening property and a dextrin having a DE value of 5 or less. Technology to prevent ramping is being developed.
しかしながら、上記の従来技術では、とろみ調整剤として許容できる程度にダマの発生を防ぐことは困難であり、特に噴霧造粒に使用するバインダー液を改良する方法では、製造される組成物の組成を一定にするためバインダー液の噴霧量を調整しなくてはならず、またバインダー溶液の溶質が噴霧ノズルの目詰まりを起こすため作業性が悪く、さらなる造粒方法の改良が求められている。 However, in the above prior art, it is difficult to prevent the occurrence of lumps to an extent acceptable as a thickening adjuster. In particular, in the method of improving the binder liquid used for spray granulation, the composition of the composition to be produced is changed. In order to make it constant, the spray amount of the binder liquid must be adjusted, and since the solute of the binder solution causes clogging of the spray nozzle, workability is poor, and further improvement of the granulation method is required.
本発明は、上記問題に鑑み、ダマの形成を抑制できる、分散性の改善された増粘組成物を提供することを目的とする。
さらに、本発明は、増粘組成物製造の際に造粒が必要な場合に、バインダーの添加量による組成への影響を考慮する必要がなく、作業が容易となる、分散性を向上させた増粘組成物を提供することを目的とする。
In view of the above problems, an object of the present invention is to provide a thickening composition with improved dispersibility that can suppress the formation of lumps.
Furthermore, the present invention has improved dispersibility, making it easy to work without the need to consider the effect of the added amount of the binder on the composition when granulation is required in the production of the thickening composition. An object is to provide a thickening composition.
本発明者らは、上記目的を達成すべく鋭意研究した結果、各種金属塩を製造時に配合し粉末化した澱粉分解物と、増粘多糖類とを用いることにより、キサンタンガムをはじめとする増粘多糖類の分散性を改善させる効果があることを見出し、本発明を完成するに至った。 As a result of diligent research to achieve the above-mentioned object, the present inventors have found that xanthane gum and other thickening agents can be obtained by using a starch decomposition product obtained by blending various metal salts at the time of production and a thickening polysaccharide. It has been found that there is an effect of improving the dispersibility of the polysaccharide, and the present invention has been completed.
すなわち、本発明は第一に、金属塩を含有する澱粉分解物と増粘多糖類とを含む分散性の改善された増粘組成物である。
第二に、金属塩の含有量が、澱粉分解物100質量部に対し、0.5〜40質量部であることを特徴とする、上記第一に記載の増粘組成物である。
第三に、金属塩がカルシウム塩、ナトリウム塩、カリウム塩、マグネシウム塩から選択される1種以上であることを特徴とする、上記第一または第二に記載の増粘組成物である。
第四に、増粘組成物に含まれる金属塩含有澱粉分解物と増粘多糖類との質量比が、金属塩含有澱粉分解物:増粘多糖類=55:45〜99:1であることを特徴とする、上記第一から第三のいずれか一つに記載の増粘組成物である。
第五に、上記第一から第四のいずれか一つに記載の増粘組成物を含む、とろみ調整剤である。
第六に、上記第一から第四のいずれか一つに記載の増粘組成物の成分である、金属塩含有澱粉分解物である。
第七に、金属塩の含有量が、澱粉分解物100質量部に対し、0.5〜40質量部であることを特徴とする、上記第六に記載の金属塩含有澱粉分解物である。
第八に、金属塩がカルシウム塩、ナトリウム塩、カリウム塩、マグネシウム塩から選択される1種以上であることを特徴とする、上記第六または第七に記載の金属塩含有澱粉分解物である。
第九に、デキストロース当量が6〜25であることを特徴とする、上記第六から第八のいずれか一つに記載の金属塩含有澱粉分解物である。
第十に、90%以上が500μm以下の粒径を有することを特徴とする、上記第六から第九のいずれか一つに記載の金属塩含有澱粉分解物である。
第十一に、噴霧乾燥法および/またはドラムドライヤー法によって製造されることを特徴とする、上記第六から第十のいずれか一つに記載の金属塩含有澱粉分解物である。
第十二に、澱粉分解物の製造工程中(好ましくは、加水分解処理後であって、ろ過処理前)に、金属塩を添加することを特徴とする、上記第一から第四のいずれか一つに記載の増粘組成物の製造方法である。
That is, the present invention is first a thickening composition with improved dispersibility, comprising a starch degradation product containing a metal salt and a thickening polysaccharide.
2ndly, it is 0.5-40 mass parts with respect to 100 mass parts of starch decomposition products, It is a thickening composition as described in said 1st characterized by the above-mentioned.
Third, the thickening composition according to the first or second aspect, wherein the metal salt is at least one selected from a calcium salt, a sodium salt, a potassium salt, and a magnesium salt.
Fourth, the mass ratio of the metal salt-containing starch decomposition product and the thickening polysaccharide contained in the thickening composition is metal salt-containing starch decomposition product: thickening polysaccharide = 55: 45 to 99: 1. The thickening composition according to any one of the first to third, characterized in that:
Fifth, it is a thickener containing the thickening composition as described in any one of the first to fourth.
Sixth, it is a metal salt-containing starch decomposition product which is a component of the thickening composition according to any one of the first to fourth.
Seventh, the metal salt-containing starch decomposition product according to the sixth aspect, wherein the content of the metal salt is 0.5 to 40 parts by mass with respect to 100 parts by mass of the starch decomposition product.
Eighth, the metal salt-containing starch degradation product according to the sixth or seventh aspect, wherein the metal salt is at least one selected from calcium salt, sodium salt, potassium salt, and magnesium salt .
Ninth, the metal salt-containing starch degradation product according to any one of the sixth to eighth aspects, wherein the dextrose equivalent is 6 to 25.
Tenth, the metal salt-containing starch degradation product according to any one of the sixth to ninth, wherein 90% or more has a particle size of 500 μm or less.
Eleventhly, the metal salt-containing starch degradation product according to any one of the sixth to tenth aspects, which is produced by a spray drying method and / or a drum dryer method.
Twelfth, any one of the first to fourth aspects, wherein a metal salt is added during the production process of the starch decomposition product (preferably after the hydrolysis treatment and before the filtration treatment). It is a manufacturing method of the thickening composition as described in one.
以下に本発明を詳細に説明する。なお、特に断りのない場合、本発明において「%」は、「重量%」を意味する。 The present invention is described in detail below. In the present invention, “%” means “% by weight” unless otherwise specified.
本発明において、増粘多糖類とは、増粘を目的として用いられる水溶性多糖類の総称であり、例えば、キサンタンガム、グアーガム、ローカストビーンガム、タラガム、カラギーナン、グルコマンナン、ネイティブ型ジェランガム、脱アシル型ジェランガム、タマリンドシードガム、ペクチン、ゼラチン、アラビアガム、寒天などが挙げられ、本発明においては、これらの増粘多糖類の1種類または2種類以上の組み合わせのものが好適に利用できるが、好ましくはキサンタンガム及び/又はグアーガムが、より好ましくはキサンタンガムが利用できる。 In the present invention, the thickening polysaccharide is a general term for water-soluble polysaccharides used for the purpose of thickening. For example, xanthan gum, guar gum, locust bean gum, tara gum, carrageenan, glucomannan, native gellan gum, deacylation Type gellan gum, tamarind seed gum, pectin, gelatin, gum arabic, agar and the like. In the present invention, one or a combination of two or more of these thickening polysaccharides can be suitably used, but preferably Xanthan gum and / or guar gum can be used, more preferably xanthan gum.
本発明の澱粉分解物を作成するための澱粉原料としては、馬鈴薯澱粉、タピオカ澱粉、甘藷澱粉、サゴ澱粉、コーンスターチ、ワキシコーンスターチ、ハイアミロースコーンスターチ、小麦澱粉、粳米澱粉、もち米澱粉などの通常の原料澱粉、あるいはそれらをエーテル化、エステル化、酸化処理など通常の手段により処理した加工澱粉が挙げられるが、馬鈴薯澱粉を用いることが好ましい。 As starch raw materials for preparing the starch degradation product of the present invention, potato starch, tapioca starch, sweet potato starch, sago starch, corn starch, waxy corn starch, high amylose corn starch, wheat starch, sticky rice starch, glutinous rice starch, etc. Raw material starch, or processed starch obtained by treating the starch by ordinary means such as etherification, esterification or oxidation treatment, potato starch is preferably used.
本発明において、澱粉分解物とは、上記の原料澱粉や加工澱粉に酸および/または酵素を添加し、オートクレーブ、あるいは連続加水分解装置などの適当な装置内で加熱してDE(デキストロース当量)6〜25好ましくは、10〜20になるように加水分解し、澱粉、酵素、酸、中和剤などに由来する不純物をろ過後、必要に応じ脱色、脱塩などの精製処理を行い、必要な程度まで濃縮した液状品およびそれを噴霧乾燥などの方法で乾燥した粉末品をいう。 In the present invention, the starch degradation product refers to DE (dextrose equivalent) 6 by adding an acid and / or enzyme to the above-mentioned raw material starch and processed starch, and heating in an appropriate apparatus such as an autoclave or a continuous hydrolysis apparatus. ~ 25, preferably hydrolyzed to 10-20, after filtering impurities derived from starch, enzyme, acid, neutralizing agent, etc. It refers to a liquid product concentrated to a degree and a powder product obtained by drying it by a method such as spray drying.
本発明における増粘組成物の分散性を改善する金属塩含有澱粉分解物とは、澱粉分解物に本発明における金属塩を必要量添加して、乾燥して得られる粉末品をいう。その製造方法として、上記の澱粉分解物の製造工程において、加水分解処理し噴霧乾燥するまでの工程、好ましくは加水分解後ろ過処理をする前に、本発明の金属塩を添加溶解して得られる、金属塩含有澱粉分解物濃縮液を噴霧乾燥して得ることができる。 The metal salt-containing starch decomposition product for improving the dispersibility of the thickening composition in the present invention refers to a powder product obtained by adding a necessary amount of the metal salt in the present invention to the starch decomposition product and drying. As the production method, in the production process of the above-mentioned starch decomposition product, it is obtained by adding and dissolving the metal salt of the present invention before the hydrolysis treatment and the spray drying step, preferably before the filtration treatment after hydrolysis. It can be obtained by spray-drying the concentrated metal salt-containing starch degradation product concentrate.
また、他の方法として、必要な程度まで濃縮した澱粉分解物の液状品、または噴霧乾燥した澱粉分解物を必要量の水に溶解した液に、本発明の金属塩を必要量添加溶解した適当な濃度(55〜65%、好ましくは60%)の液をドラムドライヤー乾燥処理して得ることができる。 As another method, the required amount of the metal salt of the present invention is added and dissolved in a liquid product of the starch decomposition product concentrated to the required level or a solution obtained by dissolving the spray-dried starch decomposition product in the required amount of water. A liquid having a high concentration (55 to 65%, preferably 60%) can be obtained by a drum dryer drying treatment.
本発明における金属塩含有澱粉分解物においては、90%以上の粒子が、500μm以下の粒径を有するもの、好ましくは150μm以下の粒径を有するものが好適に採用できる。 In the metal salt-containing starch decomposition product of the present invention, those having 90% or more of particles having a particle size of 500 μm or less, preferably 150 μm or less can be suitably employed.
本発明においては、食品に添加可能な金属塩を含有する澱粉分解物が、増粘多糖類の分散性を改善する目的で用いられる。本発明に用いられる金属塩とは、一般的に食品などに用いられている金属塩類であれば好適に利用でき、例えば、ナトリウム塩、カリウム塩、カルシウム塩、マグネシウム塩が挙げられ、これらからなる群より選ばれる少なくとも1種以上であることが好ましい。 In the present invention, a starch degradation product containing a metal salt that can be added to food is used for the purpose of improving the dispersibility of the thickening polysaccharide. The metal salt used in the present invention can be suitably used as long as it is a metal salt generally used in foods, and examples thereof include sodium salts, potassium salts, calcium salts, and magnesium salts. It is preferably at least one selected from the group.
ナトリウム塩としては、例えば、L−アスコルビン酸ナトリウム、塩化ナトリウム、グルコン酸ナトリウム、安息香酸ナトリウム、クエン酸第一鉄ナトリウム、クエン酸三ナトリウム、L−グルタミン酸ナトリウム、酢酸ナトリウム、臭化ナトリウム、重炭酸ナトリウム、酒石酸カリウムナトリウム、酒石酸水素ナトリウム、DL−酒石酸ナトリウム、L−酒石酸ナトリウム、硝酸ナトリウム、炭酸ナトリウム、乳酸ナトリウム、ピロリン酸四ナトリウム、ピロリン酸二水素二ナトリウム、フマル酸ナトリウム、ポリリン酸ナトリウム、メタリン酸ナトリウム、亜硫酸水素ナトリウム、硫酸ナトリウム、リン酸水素二ナトリウム、リン酸二水素ナトリウム、リン酸三ナトリウムが挙げられ、本発明においては、これらからなる群より選ばれる少なくとも1種以上であることが好ましい。 Examples of the sodium salt include sodium L-ascorbate, sodium chloride, sodium gluconate, sodium benzoate, sodium ferrous citrate, trisodium citrate, sodium L-glutamate, sodium acetate, sodium bromide, and bicarbonate. Sodium, potassium sodium tartrate, sodium hydrogen tartrate, DL-sodium tartrate, sodium L-tartrate, sodium nitrate, sodium carbonate, sodium lactate, tetrasodium pyrophosphate, disodium dihydrogen pyrophosphate, sodium fumarate, sodium polyphosphate, metalin Sodium sulfate, sodium hydrogen sulfite, sodium sulfate, disodium hydrogen phosphate, sodium dihydrogen phosphate, and trisodium phosphate are exemplified, and in the present invention, they are selected from the group consisting of these. It is preferred even without at least one.
カリウム塩としては、塩化カリウム、クエン酸第一カリウム、クエン酸三カリウム、DL−酒石酸水素カリウム、L−酒石酸水素カリウム、炭酸カリウム、ピロリン酸四カリウム、ポリリン酸カリウム、メタリン酸カリウム、リン酸三カリウム、リン酸水素二カリウム、硫酸カリウム、亜硫酸水素カリウム、グルコン酸カリウム、L−グルタミン酸カリウム、酢酸カリウム、臭化カリウム、硝酸カリウム、ソルビン酸カリウムが挙げられ、本発明においては、これらからなる群より選ばれる少なくとも1種以上であることが好ましい。 Potassium salts include potassium chloride, primary potassium citrate, tripotassium citrate, DL-potassium hydrogen tartrate, potassium L-tartrate, potassium carbonate, tetrapotassium pyrophosphate, potassium polyphosphate, potassium metaphosphate, triphosphate Examples include potassium, dipotassium hydrogen phosphate, potassium sulfate, potassium hydrogen sulfite, potassium gluconate, potassium L-glutamate, potassium acetate, potassium bromide, potassium nitrate, and potassium sorbate. In the present invention, from the group consisting of these It is preferable that it is at least one selected.
カルシウム塩としては、塩化カルシウム、乳酸カルシウム、クエン酸カルシウム、グルコン酸カルシウム、L−グルタミン酸カルシウム、酢酸カルシウム、水酸化カルシウム、炭酸カルシウム、乳酸カルシウム、ピロリン酸二水素カルシウム、硫酸カルシウム、リン酸三カルシウム、リン酸一水素カルシウム、リン酸二水素カルシウムが挙げられ、本発明においては、これらからなる群より選ばれる少なくとも1種以上であることが好ましい。 As calcium salts, calcium chloride, calcium lactate, calcium citrate, calcium gluconate, calcium L-glutamate, calcium acetate, calcium hydroxide, calcium carbonate, calcium lactate, calcium dihydrogen pyrophosphate, calcium sulfate, tricalcium phosphate , Calcium monohydrogen phosphate, and calcium dihydrogen phosphate. In the present invention, at least one selected from the group consisting of these is preferable.
マグネシウム塩としては、塩化マグネシウム、L−グルタミン酸マグネシウム、炭酸マグネシウム、硫酸マグネシウムが挙げられ、本発明においては、これらからなる群より選ばれる少なくとも1種以上であることが好ましい。 Examples of the magnesium salt include magnesium chloride, magnesium L-glutamate, magnesium carbonate, and magnesium sulfate. In the present invention, at least one selected from the group consisting of these is preferable.
以上の中でも、より分散性改善効果が高いものとして、乳酸カルシウム、塩化ナトリウム、塩化カルシウム、グルコン酸ナトリウムを用いることがより好ましい。 Among these, it is more preferable to use calcium lactate, sodium chloride, calcium chloride, or sodium gluconate as a higher dispersibility improving effect.
本発明において、これら金属塩の澱粉分解物に対する添加量は、澱粉分解物100質量部に対し、0.5〜40質量部、好ましくは1〜30質量部、より好ましくは2〜10質量部である。金属塩の含有量が0.5質量部未満の場合は、増粘組成物の分散性が改善されない。一方、40質量部を超える場合、金属塩含有澱粉分解物の製造および硬度、吸湿性に悪影響を及ぼすため好ましくない。また、10質量部を超える場合は、10質量部以下の添加量の場合と同等の分散性を示すこと、味への影響もあることから、金属塩を含有しない澱粉分解物と併用し、増粘組成物中の金属塩含有量を調整することが好ましい。 In this invention, the addition amount with respect to the starch degradation product of these metal salts is 0.5-40 mass parts with respect to 100 mass parts of starch degradation products, Preferably it is 1-30 mass parts, More preferably, it is 2-10 mass parts. is there. When content of a metal salt is less than 0.5 mass part, the dispersibility of a thickening composition is not improved. On the other hand, when it exceeds 40 mass parts, since manufacture, hardness, and hygroscopic property of a metal salt containing starch decomposition product are adversely affected, it is not preferable. In addition, when it exceeds 10 parts by mass, it exhibits dispersibility equivalent to that of an addition amount of 10 parts by mass or less and has an influence on the taste. It is preferable to adjust the metal salt content in the viscous composition.
本発明において、増粘組成物とは金属塩含有澱粉分解物と増粘多糖類とを含むものであり、増粘組成物に含まれる金属塩含有澱粉分解物と増粘多糖類との質量比は、金属塩含有澱粉分解物:増粘多糖類=55:45〜99:1、好ましくは60:40〜99:1、より好ましくは65:35〜99:1、最も好ましくは70:30〜99:1である。金属塩含有澱粉分解物:増粘多糖類=55:45より金属塩含有澱粉分解物の含有比が小さい場合は分散性の改善が認められない。 In the present invention, the thickening composition includes a metal salt-containing starch decomposition product and a thickening polysaccharide, and a mass ratio of the metal salt-containing starch decomposition product and the thickening polysaccharide contained in the thickening composition. Is a metal salt-containing starch degradation product: thickening polysaccharide = 55: 45-99: 1, preferably 60: 40-99: 1, more preferably 65: 35-99: 1, most preferably 70: 30- 99: 1. When the content ratio of the metal salt-containing starch decomposition product: thickening polysaccharide = 55: 45 is smaller than the metal salt-containing starch decomposition product, no improvement in dispersibility is observed.
本発明における「分散性が良い状態」とは、増粘組成物を水に投入、攪拌した際に、粒子同士が十分に離れてから膨潤することにより、粒子同士が結着することなく、別の粒子の膨潤を阻害しない状態であり、「分散性が悪い状態」とは、粒子同士が十分に離れる前に膨潤し、隣接する粒子と接触して水の移動を阻害する膜を形成することによって、他の粒子の水と接触が阻害され、膨潤していない粒子、膨潤が不十分な粒子が膨潤した粒子の膜で取り囲まれた「ダマ」を多数生成する状態である。 In the present invention, “the state of good dispersibility” refers to the case where the particles are sufficiently separated from each other when the thickening composition is charged into water and stirred, so that the particles do not bind to each other. Is a state that does not inhibit the swelling of the particles, "the state of poor dispersibility" is to swell before the particles are sufficiently separated from each other, contact with the adjacent particles to form a film that inhibits the movement of water In this state, contact with water of other particles is inhibited, and a large number of “dama” in which particles that are not swollen and particles that are not swollen are surrounded by a film of swollen particles is generated.
本発明において分散性の評価は、分散性評価試験によっておこなう。本発明における分散性評価試験は、以下の手順で行う。増粘組成物3.0gを20℃の水または80℃の熱水100gに対して添加後、水では5秒静置後、熱水では3秒静置後、水では1分、熱水では30秒攪拌棒で攪拌し、目視で発生したダマの大きさと数を確認し分散性の良いほうから、−(分散性が良好でダマの発生なし)、+(分散性は良好だが小さなダマが数個発生)、++(分散性がやや悪く、小さなダマが多数発生)、+++(分散性が悪く、大きなダマが多数発生)の4段階で評価を行った。 In the present invention, the evaluation of dispersibility is performed by a dispersibility evaluation test. The dispersibility evaluation test in the present invention is performed according to the following procedure. After adding 3.0 g of thickening composition to 100 g of 20 ° C. water or 80 ° C. hot water, after standing for 5 seconds in water, after standing for 3 seconds in hot water, for 1 minute in water, in hot water Stir with a stir bar for 30 seconds, check the size and number of lumps generated visually, and from the one with good dispersibility,-(good dispersibility and no lumps), + (good dispersibility but small lumps The evaluation was made in four stages: ++ (a few occurrences), ++ (a little dispersibility, many small lumps were generated), and ++ (a poor dispersibility, many large lumps were generated).
本発明における分散性の改善とは、増粘組成物において、その組成比を変更せず、澱粉分解物を、金属塩を含まないものと置き換えたものと比較して、分散性評価試験における分散性の評価段階が分散性の良い側に向上したことを意味する。 The improvement in dispersibility in the present invention means that in a thickening composition, the composition ratio is not changed, and the starch decomposition product is replaced with one not containing a metal salt. This means that the property evaluation stage has been improved to the side of good dispersibility.
本発明によって得られた増粘組成物を使用することによって、使用時にダマの発生の抑えられたとろみ調整剤を得ることができる。さらに、本発明においては、従来技術に記載の、金属塩溶液をバインダーとして用いることなく、増粘組成物の分散性を向上させることが可能である。すなわち、増粘組成物製造の際に造粒が必要な場合、水のみをバインダーとして造粒することが可能となり、バインダーの添加量による組成への影響を考慮する必要がないため噴霧量、噴霧時間などの設定を比較的自由に行うことが出来、作業が容易となる。 By using the thickening composition obtained by the present invention, it is possible to obtain a thickener with reduced occurrence of lumps during use. Furthermore, in this invention, it is possible to improve the dispersibility of a thickening composition, without using the metal salt solution as described in a prior art as a binder. In other words, when granulation is required in the production of the thickening composition, it is possible to granulate only water as a binder, and it is not necessary to consider the influence on the composition due to the added amount of the binder. Time etc. can be set relatively freely, and the work becomes easy.
以下に、本発明に係る増粘組成物について、実施例を交えて詳細に説明するが、本発明の技術的範囲は以下の例に限定されるものではない。 Hereinafter, the thickening composition according to the present invention will be described in detail with reference to examples, but the technical scope of the present invention is not limited to the following examples.
本発明においては以下の試薬を用いた。
キサンタンガム:エコーガムT(CPケルコ社製)
乳酸カルシウム:乳酸カルシウム五水和物(扶桑化学工業株式会社製)
塩化カルシウム:塩化カルシウム(林純薬工業株式会社製)
塩化ナトリウム:塩化ナトリウム(林純薬工業株式会社製)
グルコン酸ナトリウム:グルコン酸ナトリウム(和光純薬工業株式会社製)
L−アスコルビン酸ナトリウム:L−アスコルビン酸ナトリウム(林純薬工業株式会社製)
塩化カリウム:塩化カリウム(林純薬工業株式会社製)
塩化マグネシウム:塩化マグネシウム六水和物(林純薬工業株式会社製)
ステアリン酸カルシウム:ステアリン酸カルシウム(林純薬工業株式会社製)
In the present invention, the following reagents were used.
Xanthan gum: Echo gum T (CP Kelco)
Calcium lactate: Calcium lactate pentahydrate (manufactured by Fuso Chemical Industry Co., Ltd.)
Calcium chloride: Calcium chloride (manufactured by Hayashi Junyaku Kogyo Co., Ltd.)
Sodium chloride: Sodium chloride (manufactured by Hayashi Junyaku Kogyo Co., Ltd.)
Sodium gluconate: Sodium gluconate (Wako Pure Chemical Industries, Ltd.)
L-sodium ascorbate: sodium ascorbate (manufactured by Hayashi Junyaku Kogyo Co., Ltd.)
Potassium chloride: Potassium chloride (Hayashi Junyaku Kogyo Co., Ltd.)
Magnesium chloride: Magnesium chloride hexahydrate (manufactured by Hayashi Junyaku Kogyo Co., Ltd.)
Calcium stearate: Calcium stearate (manufactured by Hayashi Junyaku Kogyo Co., Ltd.)
[調製例1] (本発明に係る金属塩含有澱粉分解物の噴霧乾燥による製造) [Preparation Example 1] (Production of spray-dried metal salt-containing starch degradation product according to the present invention)
水1250質量部(以下「部」という)に攪拌下、馬鈴薯澱粉1000部を添加して調製したスラリーに、アルファアミラーゼ(酵素力価13000U/g)を1部加え、88〜90℃にて150分間酵素分解処理を行った。ついで、希塩酸でpH4.0に調整し酵素を失活させた後、乳酸カルシウム・五水和物を70部、添加溶解し、炭酸カルシウムでpH5.5に調整し、この液に液固形分当り0.5%のろ過助剤(ラヂオライト#800、昭和化学工業株式会社製)および0.5%の活性炭を加え、液温65〜75℃で吸引ろ過し、濃縮し、ニロ社製モービルマイナ型スプレードライヤーにて、入口温度170〜180℃、出口温度100〜105℃で噴霧乾燥して、乳酸カルシウムを5%含有する澱粉分解物を得た(調製品1)。DE16.2で、比容積は2.3mL/gであった。90%以上の粒子は粒径が150μm以下であった。 1 part of alpha amylase (enzyme titer 13000 U / g) is added to a slurry prepared by adding 1000 parts of potato starch under stirring to 1250 parts by weight of water (hereinafter referred to as “parts”), and 150 ° C. at 150 to 88 ° C. Enzymatic degradation treatment was performed for a minute. Next, after adjusting the pH to 4.0 with dilute hydrochloric acid to inactivate the enzyme, 70 parts of calcium lactate pentahydrate was added and dissolved, and adjusted to pH 5.5 with calcium carbonate. Add 0.5% filter aid (Radiolite # 800, Showa Chemical Co., Ltd.) and 0.5% activated carbon, suction filter at a liquid temperature of 65-75 ° C, concentrate, and mobile minor manufactured by Niro Co., Ltd. Using a type spray dryer, spray drying was performed at an inlet temperature of 170 to 180 ° C. and an outlet temperature of 100 to 105 ° C. to obtain a starch decomposition product containing 5% calcium lactate (preparation 1). In DE 16.2, the specific volume was 2.3 mL / g. 90% or more of the particles had a particle size of 150 μm or less.
[比較調製例1] (澱粉分解物の噴霧乾燥による製造) [Comparative Preparation Example 1] (Production of starch degradation product by spray drying)
水1250質量部(以下「部」という)に攪拌下、馬鈴薯澱粉1000部を添加して調製したスラリーに、アルファアミラーゼ(酵素力価13000U/g)を1部加え、88〜90℃にて140分間酵素分解処理を行った。ついで、希塩酸でpH4.0に調整し酵素を失活させた後、炭酸カルシウムでpH5.5に調整し、この液に液固形分当り0.5%のろ過助剤(ラヂオライト#800、昭和化学工業株式会社製)および0.5%の活性炭を加え、液温65〜75℃で吸引ろ過し、濃縮し、ニロ社製モービルマイナ型スプレードライヤーにて、入口温度170〜180℃、出口温度100〜105℃で噴霧乾燥して、澱粉分解物を得た(比較調製品1)。DE15.3で比容積は2.2mL/gであった。90%以上の粒子は粒径が150μm以下であった。 1 part of alpha amylase (enzyme titer: 13000 U / g) was added to a slurry prepared by adding 1000 parts of potato starch under stirring to 1250 parts by weight of water (hereinafter referred to as “parts”), and 140 to 88 ° C. at 140 ° C. Enzymatic degradation treatment was performed for a minute. Next, after adjusting the pH to 4.0 with dilute hydrochloric acid to deactivate the enzyme, the pH was adjusted to 5.5 with calcium carbonate, and 0.5% of filter aid (Radiolite # 800, Showa, Showa) was added to this liquid. Chemical Industry Co., Ltd.) and 0.5% activated carbon were added, suction filtered at a liquid temperature of 65 to 75 ° C., concentrated, and the inlet temperature was 170 to 180 ° C. and the outlet temperature was measured with a mobile minor spray dryer manufactured by Niro. Spray-dried at 100 to 105 ° C. to obtain a starch degradation product (Comparative Preparation 1). DE 15.3 had a specific volume of 2.2 mL / g. 90% or more of the particles had a particle size of 150 μm or less.
[調製例2] (本発明に係る金属塩含有澱粉分解物のドラムドライヤー乾燥による製造) [Preparation Example 2] (Production of the metal salt-containing starch degradation product according to the present invention by drying with a drum dryer)
比較調製品1の300部に水を加えて濃度60%の澱粉分解物水溶液を調製し、これらの液に表1に示す金属塩を溶解し、常法に従って、カツラギ工業株式会社製常圧開放式ダブルドラムドライヤー(φ1250mm×L3000mm、蒸気内圧0.8MPa、回転数1.6rpm)で乾燥粉末化し、乾燥粉末を得た(調製品2−1〜2−12)。90%以上の粒子は粒径が500μm以下であった。 Water is added to 300 parts of Comparative Preparation 1 to prepare an aqueous starch decomposition product solution having a concentration of 60%, and the metal salts shown in Table 1 are dissolved in these solutions. Dry powder was obtained by using a double drum dryer (φ1250 mm × L3000 mm, steam internal pressure 0.8 MPa, rotation speed 1.6 rpm) to obtain dry powder (prepared products 2-1 to 2-12). 90% or more of the particles had a particle size of 500 μm or less.
[比較調製例2] (澱粉分解物のドラムドライヤー乾燥による製造) [Comparative Preparation Example 2] (Production of starch degradation product by drum dryer drying)
比較調製品1の300部に水を加えて濃度60%の澱粉分解物水溶液を調製し、この液を常法に従って、カツラギ工業株式会社製常圧開放式ダブルドラムドライヤー(φ1250mm×L3000mm、蒸気内圧0.8MPa、回転数1.6rpm)で乾燥粉末化し、乾燥粉末を得た(比較調製品2−1)。90%以上の粒子は粒径が500μm以下であった。 Water was added to 300 parts of Comparative Preparation 1 to prepare an aqueous starch decomposition product solution having a concentration of 60%, and this solution was subjected to a normal pressure open double drum dryer (φ1250 mm × L3000 mm, steam internal pressure) according to a conventional method. A dry powder was obtained at 0.8 MPa and a rotation number of 1.6 rpm) to obtain a dry powder (Comparative Preparation 2-1). 90% or more of the particles had a particle size of 500 μm or less.
また、比較調製品1の300部に水を加えて濃度60%の澱粉分解物水溶液を調製し、この液にステアリン酸カルシウム(添加量:0.3質量部、調製品中の金属塩含有量:0.1質量部/澱粉分解物100質量部)を溶解し、常法に従って、カツラギ工業株式会社製常圧開放式ダブルドラムドライヤー(φ1250mm×L3000mm、蒸気内圧0.8MPa、回転数1.6rpm)で乾燥粉末化し、乾燥粉末を得た(比較調製品2−2)。90%以上の粒子は粒径が500μm以下であった。 Moreover, water is added to 300 parts of Comparative Preparation 1 to prepare an aqueous starch decomposition product solution having a concentration of 60%, and calcium stearate (addition amount: 0.3 parts by weight, metal salt content in the preparation: 0.1 parts by mass / 100 parts by mass of starch degradation product), and in accordance with a conventional method, Katsuragi Industry Co., Ltd., normal pressure open double drum dryer (φ1250 mm × L3000 mm, steam internal pressure 0.8 MPa, rotation number 1.6 rpm) To obtain a dry powder (Comparative Preparation 2-2). 90% or more of the particles had a particle size of 500 μm or less.
(増粘組成物の製造) (Production of thickening composition)
キサンタンガムおよび調製品を表2に示す割合で直径60mmのプラスチック容器に量り取り、これら容器同士を向き合わせた状態で混合し、本発明に係る実施品1〜17を得た。 Xanthan gum and preparations were weighed out in a plastic container having a diameter of 60 mm in the ratio shown in Table 2, and mixed in a state where these containers faced each other to obtain Examples 1 to 17 according to the present invention.
[比較例1] (増粘組成物の製造) [Comparative Example 1] (Production of thickening composition)
キサンタンガムおよび調製品、比較調製品を表3に示す割合で直径60mmのプラスチック容器に量り取り、これら容器同士を向き合わせた状態で混合し、比較品1〜19を得た。 Xanthan gum, preparations, and comparative preparations were weighed out in plastic containers having a diameter of 60 mm at the ratios shown in Table 3, and mixed in a state where these containers faced each other to obtain comparative products 1-19.
30gのキサンタンガムと、70gの調製品1を混合したのち流動層造粒機(FLO−MINI/フロイント産業製)に投入し、吸気温度80℃に設定した上で、バインダーとして水40gを2.5g/minの流速で連続噴霧し、バインダー全量噴霧後、吸気温度80℃で5分間乾燥した。得られた造粒物を目開き1.40mmと0.15mmのふるいを用いて分級し、目開き1.40mmを通過し、目開き0.15mmの篩を通過しないものを回収し、本発明に係る実施品18を得た。 After mixing 30 g of xanthan gum and 70 g of preparation 1 and putting it into a fluidized bed granulator (FLO-MINI / Freund Industrial Co., Ltd.), setting the intake air temperature at 80 ° C., 2.5 g of 40 g of water as a binder Sprayed continuously at a flow rate of / min, and after spraying all of the binder, it was dried at an intake air temperature of 80 ° C. for 5 minutes. The obtained granulated material is classified using sieves having an aperture of 1.40 mm and 0.15 mm, and those passing through an aperture of 1.40 mm and not passing through a sieve having an aperture of 0.15 mm are collected. The execution product 18 which concerns on was obtained.
[比較例2] [Comparative Example 2]
30gのキサンタンガムと、70gの比較調製品1を混合したのち流動層造粒機(FLO−MINI/フロイント産業製)に投入し、実施例2に記載の操作を行い、比較品20を得た。 30 g of xanthan gum and 70 g of comparative preparation 1 were mixed and then charged into a fluidized bed granulator (FLO-MINI / Freund Sangyo Co., Ltd.). The operation described in Example 2 was performed to obtain a comparative product 20.
[評価例] [Evaluation example]
(分散性評価試験)
分散性評価試験は、以下の手順で行った。
(Dispersibility evaluation test)
The dispersibility evaluation test was performed according to the following procedure.
(20℃の水における試験)
1.増粘組成物3.0gを300mL容ビーカー中の20℃の水100gに添加後5秒静置
2.1分間攪拌棒で攪拌
3.下記の評価基準に基づき目視で評価
(Test in 20 ° C water)
1. 2. Add 3.0 g of thickening composition to 100 g of water at 20 ° C. in a 300 mL beaker and leave it for 5 seconds. Visual evaluation based on the following evaluation criteria
(80℃の熱水における試験)
1.増粘組成物3.0gを300mL容ビーカー中の80℃の熱水100gに添加後3秒静置
2.30秒間攪拌棒で攪拌
3.下記の評価基準に基づき目視で評価
(Test in hot water at 80 ° C)
1. 2. Add 3.0 g of thickening composition to 100 g of hot water at 80 ° C. in a 300 mL beaker, and leave it for 3 seconds 2. Stir with a stir bar for 30 seconds Visual evaluation based on the following evaluation criteria
(評価基準)
−(分散性が良好でダマの発生なし)、
+(分散性は良好だが小さなダマが数個発生)、
++(分散性がやや悪く、小さなダマが多数発生)、
+++(分散性が悪く、大きなダマが多数発生)
(Evaluation criteria)
-(Good dispersibility and no lumps),
+ (Dispersibility is good but several small lumps occur),
++ (Dispersibility is slightly worse, many small lumps occur),
+++ (Poor dispersibility, many large lumps occur)
[測定例1] (金属塩の含有量の比較) [Measurement Example 1] (Comparison of metal salt content)
金属塩含有量の異なる実施品、比較品に対し分散性評価試験を実施し評価を行い表4の結果を得た。 The dispersibility evaluation test was performed on the products with different metal salt contents and comparative products, and the evaluation was performed. The results shown in Table 4 were obtained.
この結果から、金属塩を0.5質量部/澱粉分解物100質量部以上含有する澱粉分解物を含有した増粘組成物は含有しないものに比べ分散性が向上していることが分かる。 From this result, it can be seen that the dispersibility is improved as compared with the case where the thickening composition containing the starch decomposition product containing 0.5 parts by mass of the metal salt / 100 parts by mass of the starch decomposition product is not included.
[測定例2] (澱粉分解物含有比の比較) [Measurement Example 2] (Comparison of starch degradation product content ratio)
澱粉分解物の含有比の異なる実施品、比較品に対し分散性評価試験を実施し評価を行い表5及び6の結果を得た。 Dispersibility evaluation tests were performed on the products with different content ratios of the starch degradation products and comparative products, and evaluations were performed. The results shown in Tables 5 and 6 were obtained.
この結果から、増粘多糖類よりも質量比で金属塩含有澱粉分解物を多く含む増粘組成物は、少ないものに比べ、分散性が向上していることが分かる。また、金属塩を含有する澱粉分解物を使用した増粘組成物は、金属塩を含有しない澱粉分解物を使用したものに比べ分散性が向上していることが分かる。 From this result, it is understood that the dispersibility of the thickening composition containing a larger amount of the metal salt-containing starch degradation product by mass ratio than that of the thickening polysaccharide is improved as compared with a small amount. Moreover, it turns out that the dispersibility is improving the thickening composition using the starch decomposition product containing a metal salt compared with the thing using the starch decomposition product which does not contain a metal salt.
[測定例3] (金属塩の種類による比較) [Measurement Example 3] (Comparison by type of metal salt)
金属塩の異なる実施品に対し分散性評価試験を実施し評価を行い表7の結果を得た。 The dispersibility evaluation test was performed on the products with different metal salts, and the results shown in Table 7 were obtained.
この結果から、本発明に係る増粘組成物は、金属塩の種類に係わらず良好な分散性を示すことが分かる。 From this result, it can be seen that the thickening composition according to the present invention exhibits good dispersibility regardless of the type of metal salt.
[測定例4] (製造法による比較) [Measurement Example 4] (Comparison by production method)
製造法の異なる実施品に対し分散性評価試験を実施し評価を行い表8の結果を得た。 The dispersibility evaluation test was conducted on the products with different production methods, and the results shown in Table 8 were obtained.
この結果から、本発明は、流動造粒品についても効果が認められることが分かる。 From this result, it can be seen that the present invention is also effective for fluidized granulated products.
(とろみ調整剤としての利用) (Use as a thickener)
実施品3の4.5gを300mL容ビーカー中の20℃の水100gに添加し、1分間攪拌棒で攪拌することで、適度なとろみの付いた水溶液を得ることができた。 4.5 g of the product 3 was added to 100 g of 20 ° C. water in a 300 mL beaker, and stirred with a stir bar for 1 minute, whereby an aqueous solution with a moderate thickness could be obtained.
本発明の実施により、分散性のよい増粘組成物、およびそれを利用したとろみ調整剤を得ることができる。 By carrying out the present invention, it is possible to obtain a thickening composition with good dispersibility and a thickening regulator using the same.
Claims (1)
The content of the metal salt obtained by pulverizing a solution containing at least one metal salt selected from calcium salt, sodium salt, potassium salt, and magnesium salt and a starch decomposition product is 100 parts by mass of the starch decomposition product. 0.5 to 40 parts by mass of thickening polysaccharide-containing thickening composition containing a metal salt-containing starch degradation product (excluding those containing acids having a degree of dissociation greater than lactic acid) Dispersibility improver .
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