TW201313636A - Scribe method for glass substrate - Google Patents

Scribe method for glass substrate Download PDF

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TW201313636A
TW201313636A TW101130083A TW101130083A TW201313636A TW 201313636 A TW201313636 A TW 201313636A TW 101130083 A TW101130083 A TW 101130083A TW 101130083 A TW101130083 A TW 101130083A TW 201313636 A TW201313636 A TW 201313636A
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Taiwan
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crack
groove
glass
scribe
scribing
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TW101130083A
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Chinese (zh)
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Yu-Hang Su
Takeshi Ikeda
Koji Yamamoto
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Mitsuboshi Diamond Ind Co Ltd
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Priority claimed from JP2011182355A external-priority patent/JP5352642B2/en
Priority claimed from JP2011182354A external-priority patent/JP5352641B2/en
Application filed by Mitsuboshi Diamond Ind Co Ltd filed Critical Mitsuboshi Diamond Ind Co Ltd
Publication of TW201313636A publication Critical patent/TW201313636A/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Processing Of Stones Or Stones Resemblance Materials (AREA)

Abstract

This invention provides a scribe method for a glass substrate such that desired scribing trenches can be easily and stably formed on a tempered glass to prevent the glass from being naturally cracked. The method includes scribing a tempered glass surface formed with a compressed stress strengthened layer and forming a crack-restricting trench and a scribing trench. In the step of forming the crack-restricting trench, a predefined line having a predetermined width is drawn toward an end of a predefined crack-restricting area on the surface of glass in an intersection direction of the trench and the predefined line. In the step of forming the scribing trench, the glass surface is projected by laser beams to heat up and the heated glass area is cooled down so that the predetermined line can be drawn along to form the scribing trench by cutting.

Description

玻璃基板之劃線方法 Glass substrate scribe method

本發明係關於一種玻璃基板之劃線方法,特別是關於在表面具有具壓縮應力之強化層的玻璃進行劃線之玻璃基板之劃線方法。 The present invention relates to a method of scribing a glass substrate, and more particularly to a method of scribing a glass substrate in which a glass having a reinforcing layer having a compressive stress on the surface is scribed.

就為了斷開玻璃基板而形成劃線溝之方法而言,係有利用雷射光而形成劃線溝之方法。在此情形時,沿著劃線預定線照射雷射光,使基板之一部分溶解、蒸發而形成劃線溝。然而,在該方法中,被溶解、蒸發之基板的一部分係附著在基板表面,而有造成品質劣化之情形。此外,於溶解、蒸發之部分所形成之裂痕係成為基板端面強度降低之原因。 A method of forming a scribe groove in order to break a glass substrate is a method of forming a scribe groove by using laser light. In this case, the laser light is irradiated along a predetermined line of the scribe line, and one of the substrates is partially dissolved and evaporated to form a scribe groove. However, in this method, a part of the substrate which is dissolved and evaporated adheres to the surface of the substrate, which causes deterioration in quality. Further, the crack formed in the portion dissolved and evaporated is a cause of a decrease in the strength of the end face of the substrate.

因此,就形成劃線溝之其他方法而言,有專利文獻1或2所示之方法。其中,於成為玻璃基板之劃線溝之起點的場所形成有初期龜裂,在該初期龜裂照射有雷射光。藉此,在雷射照射部分產生熱應力,且龜裂會進展而形成劃線溝。 Therefore, there is a method shown in Patent Document 1 or 2 for other methods of forming a scribe groove. Among them, an initial crack is formed at a position which is a starting point of a scribe line of a glass substrate, and the initial crack is irradiated with laser light. Thereby, thermal stress is generated in the laser irradiation portion, and the crack progresses to form a scribe groove.

再者,在照射雷射光而形成劃線溝之方法中,會有在玻璃基板之周緣部中劃線溝之龜裂變深之傾向。在此狀態下,當沿著劃線溝將玻璃基板予以斷開時,會產生斷開面之品質降低之問題、或劃線溝不會筆直地形成之問題。 Further, in the method of forming the scribe groove by irradiating the laser light, the crack of the scribe groove tends to be deep in the peripheral portion of the glass substrate. In this state, when the glass substrate is broken along the scribe line, there is a problem that the quality of the broken surface is lowered or the scribe groove is not formed straight.

因此,在專利文獻3中揭示有一種在劃線預定線之終端部形成未形成有劃線溝之區域的雷射劃線方法。依據該 方法,可在不進行複雜之控制的情形下提升玻璃基板之終端部之斷開後的剖面品質。 Therefore, Patent Document 3 discloses a laser scribing method in which a region where a scribe groove is not formed is formed at a terminal portion of a predetermined line. According to this In this way, the cross-sectional quality of the terminal portion of the glass substrate can be improved without complicated control.

(先前技術文獻) (previous technical literature) (專利文獻) (Patent Literature)

專利文獻1:日本特開平3-489號公報 Patent Document 1: Japanese Patent Laid-Open No. 3-489

專利文獻2:日本特開平9-1370號公報 Patent Document 2: Japanese Patent Laid-Open Publication No. 9-1370

專利文獻3:日本再公表特許WO 2007/094348號公報 Patent Document 3: Japanese Re-issued Patent No. WO 2007/094348

然而,在最近之FPD(平板顯示器)業者中,由於重視基板端面之強度,因此主要使用在表面形成有強化層之化學強化玻璃,來作為玻璃基板。該化學強化玻璃係具有藉由離子交換處理在表面具壓縮應力之層(強化層),且在內部存在有拉伸應力。最近,該化學強化玻璃係使用在特別要求端面強度之觸控板等蓋玻璃。 However, in the recent FPD (flat panel display) industry, since the strength of the substrate end face is emphasized, a chemically strengthened glass having a reinforcing layer formed on its surface is mainly used as a glass substrate. The chemically strengthened glass has a layer (strengthening layer) which is subjected to compressive stress on the surface by ion exchange treatment, and has tensile stress inside. Recently, this chemically strengthened glass is used for a cover glass such as a touch panel which particularly requires end face strength.

本案發明人係藉由實驗發現:在該強化玻璃中,特別是在最近開發之表面高強度之強化玻璃中,藉由雷射劃線方法將劃線溝形成時,深的龜裂會主要從劃線溝之終端部沿著劃線溝進展而自然斷開。在此,所謂自然斷開係在形成劃線溝之後,在不實施斷開步驟之情形下玻璃基板沿著劃線溝斷開之現象。 The inventors of the present invention discovered through experiments that in the tempered glass, especially in the recently developed surface high-strength tempered glass, when the scribe line is formed by the laser scribing method, the deep crack will mainly come from The end portion of the scribe groove is naturally broken along the progress of the scribe groove. Here, the natural disconnection is a phenomenon in which the glass substrate is broken along the scribe line without forming the scribe line after the scribe line is formed.

自然斷開係可能起因於在玻璃基板之周緣部劃線溝之龜裂變深,而使該深的龜裂沿著劃線溝進展而產生者。而且,在玻璃基板之周緣部劃線溝之龜裂變深係可能為以下 之理由。 The natural disconnection system may be caused by the fact that the crack of the scribe groove in the peripheral portion of the glass substrate is deep, and the deep crack is generated along the scribe groove. Further, the crack depth of the scribe groove in the peripheral portion of the glass substrate may be as follows The reason.

‧ 在形成有劃線溝之玻璃基板的終端部中,由於端面不被拘束,因此劃線溝之兩側容易張開。 ‧ In the end portion of the glass substrate in which the scribe groove is formed, since the end faces are not restrained, both sides of the scribe groove are easily opened.

‧ 在形成有劃線溝之玻璃基板的終端部中,因沒有使熱從終端部往前散熱之場所,而造成熱停滯在終端部。 ‧ In the end portion of the glass substrate in which the scribe groove is formed, heat is not stopped at the end portion due to the fact that heat is not radiated from the terminal portion.

由於以上之原因而產生自然斷開時,後序步驟之處理將變得困難。 When a natural disconnection occurs due to the above reasons, the processing of the subsequent steps becomes difficult.

因此,為了使劃線溝不會形成在玻璃基板之周緣部,係可考慮在劃線預定線之終端部貼上鋁帶而遮蔽雷射光。然而,從生產性之觀點來看,該方法並不實用。 Therefore, in order to prevent the scribe groove from being formed on the peripheral edge portion of the glass substrate, it is conceivable to affix the aluminum strip to the end portion of the predetermined line to shield the laser light. However, this method is not practical from the viewpoint of productivity.

再者,可考慮藉由控制雷射光之照射,使加熱處理及冷卻處理不會在玻璃基板之周緣部實施,而可使劃線溝不會到達至劃線預定線之終端。然而,該方法難以在所希望之位置擋止劃線溝,且不具穩定性。 Further, it is conceivable that the heat treatment and the cooling treatment are not performed on the peripheral portion of the glass substrate by controlling the irradiation of the laser light, and the scribe line does not reach the end of the predetermined line. However, this method is difficult to stop the scribe groove at the desired position and is not stable.

再者,本案發明人發現不僅在玻璃基板之終端部亦在開始端產生同樣之問題。亦即,當在屬於劃線預定線之開始端的玻璃基板之端緣部形成初期龜裂時,在劃線溝之形成步驟中,初期龜裂會深深地形成。並且,起因於該深的龜裂,在形成劃線溝之後,在不實施斷開步驟之情形下,玻璃基板會自然地斷開。 Furthermore, the inventors of the present invention found that the same problem occurs not only at the end portion of the glass substrate but also at the beginning. That is, when an initial crack is formed at the edge portion of the glass substrate belonging to the beginning end of the line to be scribed, the initial crack is formed deeply in the step of forming the scribe groove. Further, due to the deep crack, after the scribe line is formed, the glass substrate is naturally broken without performing the breaking step.

因此,就避免自然斷開之對策而言,可考慮從開始端(基板之端緣)往內部側偏置地形成初期龜裂。然而,即使採取上述對策,亦會有同樣地造成自然斷開之情形。針對此情形時之現象更詳細地說明。首先,在劃線溝之形成步 驟中,亦有與雷射光之掃描方向相反地龜裂從初期龜裂朝玻璃基板之端緣進展之情形。然後,當龜裂從初期龜裂進展至玻璃基板之端緣時,玻璃基板之端緣部分之龜裂的深度會深達遍及至基板厚度之整體。因形成在該端緣部之深的龜裂,玻璃基板會沿著劃線溝而自然地斷開。當產生該種自然斷開時,後序步驟之處理將變得困難。 Therefore, in order to avoid the countermeasure of natural disconnection, it is conceivable to form an initial crack from the start end (the edge of the substrate) to the inner side. However, even if the above countermeasures are taken, the situation of natural disconnection will be similarly caused. The phenomenon in this case is explained in more detail. First, the formation step in the dash In the second step, the crack is opposite to the scanning direction of the laser light, and the crack progresses from the initial crack to the edge of the glass substrate. Then, when the crack progresses from the initial crack to the edge of the glass substrate, the depth of the crack at the edge portion of the glass substrate is as deep as the entire thickness of the substrate. The glass substrate is naturally broken along the scribe groove due to the crack formed deep in the edge portion. When such a natural disconnection occurs, the processing of the subsequent steps becomes difficult.

因此,亦可考慮增加偏置之量。然而,當增加偏置之量時,在玻璃基板周緣部會增加浪費之部分(無法確保作為製品之部分),且良品率差。 Therefore, it is also considered to increase the amount of bias. However, when the amount of the offset is increased, a waste portion is added to the peripheral portion of the glass substrate (the portion which is a product cannot be secured), and the yield is poor.

本發明之課題係在於對在表面具備強化層之玻璃容易且穩定地形成所希望之劃線溝,以防止自然斷開。 An object of the present invention is to easily and stably form a desired scribe groove for a glass having a reinforcing layer on its surface to prevent natural breakage.

第1發明之玻璃基板之劃線方法,係對在表面具有具壓縮應力之強化層的玻璃進行劃線之方法,且包含龜裂限制溝形成步驟及劃線溝形成步驟。在龜裂限制溝形成步驟中,於玻璃之表面,將具有預定寬度之龜裂限制用溝朝與劃線預定線交叉之方向形成在劃線預定線之終端部。在劃線溝形成步驟中,將雷射光照射在玻璃之表面並予以加熱,並且將加熱過之區域予以冷卻,並使龜裂沿著劃線預定線進展而形成劃線溝。 The method for scribing a glass substrate according to the first aspect of the invention is a method of scribing a glass having a reinforcing layer having a compressive stress on a surface thereof, and includes a crack restricting groove forming step and a scribing groove forming step. In the step of forming the crack restricting groove, a crack restricting groove having a predetermined width is formed on the surface of the glass at a terminal end portion of a predetermined line of the scribe line in a direction intersecting the predetermined line of the scribe line. In the scribe groove forming step, the laser light is irradiated onto the surface of the glass and heated, and the heated region is cooled, and the crack progresses along the predetermined line of the scribe line to form a scribe groove.

在此,將用以限制龜裂進展之溝朝與劃線預定線交叉之方向形成在劃線預定線之終端部。然後,將雷射光照射在玻璃之表面而予以加熱,並且將加熱過之區域予以冷卻。藉由該加熱及冷卻處理,龜裂沿著劃線預定線進展而 形成劃線溝。龜裂之進展係藉由先形成之龜裂限制溝而受到限制。因此,在劃線預定線之終端部不形成劃線溝。 Here, the groove for restricting the progress of the crack is formed at the end portion of the predetermined line of the scribe line in a direction intersecting the predetermined line of the scribe line. Then, the laser light is irradiated on the surface of the glass to be heated, and the heated region is cooled. With this heating and cooling process, the crack progresses along the predetermined line of the scribe line. A scribe groove is formed. The progress of the crack is limited by the first formed crack limiting groove. Therefore, no scribe groove is formed at the end portion of the scribe line.

藉由該方法而可防止深的龜裂在劃線預定線之終端部形成,且可避免自然斷開。此外,不需要貼上鋁帶等之煩雜作業,且可穩定地在所希望之位置阻止劃線溝之形成。 By this method, deep cracks can be prevented from being formed at the end portion of the predetermined line of the scribe line, and natural breakage can be avoided. Further, it is not necessary to apply an affliction to the aluminum tape or the like, and the formation of the scribe groove can be stably prevented at a desired position.

第2發明之玻璃基板之劃線方法係在第1發明之劃線方法中,復包含初期龜裂形成步驟,該步驟係作為劃線溝形成步驟之前步驟,將強化層之一部分予以去除,以在玻璃之表面形成初期龜裂。 In the scribing method of the glass substrate according to the first aspect of the invention, the initial scribing step is further included as a step before the step of forming the scribing groove, and a part of the reinforcing layer is removed. An initial crack is formed on the surface of the glass.

在此,藉由切割輪等,將形成在玻璃之表面的強化層之一部分予以去除,以形成初期龜裂。然後,將雷射光照射在初期龜裂並予以加熱,並且將加熱過之區域予以冷卻。藉此,初期龜裂會沿著劃線預定線使龜裂進展。因此,可穩定地形成所希望之劃線溝。 Here, a portion of the reinforcing layer formed on the surface of the glass is removed by a cutting wheel or the like to form an initial crack. Then, the laser light is irradiated to the initial crack and heated, and the heated region is cooled. Thereby, the initial crack will cause the crack to progress along the line of the scribe line. Therefore, the desired scribe groove can be stably formed.

第3發明之玻璃基板之劃線方法,係對在表面具有具壓縮應力之強化層的玻璃進行劃線之方法,且包含初期龜裂形成步驟、劃線溝形成步驟、及龜裂限制溝形成步驟。初期龜裂形成步驟係將強化層之至少一部分予以去除,以在玻璃之表面形成初期龜裂。劃線溝形成步驟係將雷射光照射在玻璃之表面而予以加熱,並且將加熱過之區域予以冷卻,並使初期龜裂沿著劃線預定線進展而形成劃線溝。龜裂限制溝形成步驟係為了限制初期龜裂朝與在劃線溝形成步驟中之龜裂進展方向相反之方向進展,而在玻璃之表面中於初期龜裂與玻璃基板之端緣之間,朝與劃線預定線 延伸之方向交叉的方向形成具有預定寬度之龜裂限制溝,作為初期龜裂形成步驟之前處理或後處理。 The method for scribing a glass substrate according to a third aspect of the present invention is a method of scribing a glass having a reinforcing layer having a compressive stress on a surface thereof, and includes an initial crack forming step, a scribing groove forming step, and a crack restricting groove forming method. step. The initial crack formation step removes at least a portion of the strengthening layer to form an initial crack on the surface of the glass. The scribe groove forming step heats the laser light on the surface of the glass, cools the heated region, and advances the initial crack along the predetermined line of the scribe line to form a scribe groove. The crack restricting groove forming step is for restricting the initial crack from progressing in a direction opposite to the progress of the crack in the step of forming the groove, and between the initial crack and the edge of the glass substrate in the surface of the glass. Toward and line the line The direction in which the directions of the intersection intersect is formed into a crack restricting groove having a predetermined width as a pre-treatment or post-treatment of the initial crack forming step.

在此,在劃線預定線之開始端部的附近形成有初期龜裂。並且,在初期龜裂與玻璃基板之端緣之間形成有限制龜裂朝與劃線預定線延伸之方向交叉的方向形成進展之溝。然後,將雷射光照射在玻璃表面而予以加熱,並且將加熱過之區域予以冷卻。藉由該加熱及冷卻處理,龜裂會沿著劃線預定線進展而形成劃線溝。此時,龜裂雖係朝劃線預定線之終端部進展,但亦有朝相反方向進展之情形。然而,朝該反方向進展之龜裂係藉由形成在初期龜裂與玻璃基板之端緣之間的溝而停止。 Here, an initial crack is formed in the vicinity of the beginning end of the planned line of the scribe line. Further, between the initial crack and the edge of the glass substrate, a groove which restricts the formation of the crack in a direction intersecting the direction in which the predetermined line is extended is formed. Then, the laser light is irradiated onto the surface of the glass to be heated, and the heated region is cooled. By this heating and cooling treatment, the crack progresses along the predetermined line of the scribe line to form a scribe groove. At this time, although the crack progresses toward the end portion of the predetermined line, there is a case where the crack progresses in the opposite direction. However, the crack that progresses in the opposite direction is stopped by forming a groove between the initial crack and the edge of the glass substrate.

因此,可避免初期龜裂朝反方向進展且在玻璃基板端緣部分形成深的龜裂。因此,可抑制劃線預定線形成後之自然斷開。 Therefore, it is possible to prevent the initial crack from progressing in the opposite direction and to form a deep crack at the edge portion of the glass substrate. Therefore, the natural disconnection after the formation of the predetermined line of the scribe line can be suppressed.

再者,由於可限制從初期龜裂朝基板端緣形成龜裂,因此可使初期龜裂與基板端緣之間無法確保作為製品的部分減少,且可提升製品之成品率。 Further, since the crack can be restricted from the initial crack to the edge of the substrate, the initial crack can be prevented from being reduced as a part of the product, and the yield of the product can be improved.

第4發明之玻璃基板之劃線方法係在第1至第3發明中任一之劃線方法中,於龜裂限制溝形成步驟中,龜裂限制溝係以朝與劃線預定線垂直之方向延伸的方式形成。 In the scribing method according to any one of the first to third aspects of the present invention, in the step of forming the crack limiting groove, the crack restricting groove is perpendicular to a predetermined line of the scribe line. The direction is extended to form.

在此,由於龜裂限制溝係以朝與劃線預定線垂直之方向形成,因此可更確實地阻止龜裂之進展。 Here, since the crack restricting groove is formed in a direction perpendicular to a predetermined line of the scribe line, the progress of the crack can be more reliably prevented.

第5發明之玻璃基板之劃線方法係在第1至第4發明中任一之劃線方法中,於龜裂限制溝形成步驟中,龜裂限 制溝係形成為比在劃線溝形成步驟中形成之劃線溝之深度更淺。 In the scribing method of the glass substrate according to any one of the first to fourth aspects of the present invention, in the step of forming a crack limiting groove, the cracking limit is The groove system is formed to be shallower than the depth of the scribe groove formed in the scribe groove forming step.

在此,當將龜裂限制溝加深時,由於玻璃基板之內部的拉伸應力,會有龜裂以龜裂限制溝為起點自然地進展,且基板會因該龜裂而分離之情形。 When the crack limiting groove is deepened, the crack tends to progress naturally from the crack limiting groove due to the tensile stress inside the glass substrate, and the substrate may be separated by the crack.

因此,在第5發明中,使龜裂限制溝的深度比劃線溝之深度更淺,以避免基板之自然斷開。 Therefore, in the fifth invention, the depth of the crack restricting groove is made shallower than the depth of the scribe groove to avoid natural breakage of the substrate.

第6發明之玻璃基板之劃線方法係在第2或第3發明之劃線方法中,於初期龜裂形成步驟中形成之初期龜裂、與在龜裂限制溝形成步驟中形成之溝,係在兩者之間隔著間隔而形成。 The scribing method of the glass substrate according to the sixth aspect of the invention is the initial crack formed in the initial crack forming step and the groove formed in the crack restricting groove forming step in the scribing method according to the second or third aspect of the invention. It is formed at intervals between the two.

在此,由於初期龜裂與龜裂限制溝係相互隔開而形成,因此可更確實地抑制初期龜裂進展至玻璃基板之端緣。 Here, since the initial crack and the crack restricting groove are formed apart from each other, it is possible to more reliably suppress the progress of the initial crack to the edge of the glass substrate.

如上所述,本發明係對於在表面具有具壓縮應力之強化層的玻璃,容易且穩定地在劃線預定線之終端部正前阻止龜裂之進展。因此,可防止在將劃線溝形成在玻璃之時間點玻璃自然斷開。 As described above, the present invention is directed to the glass having a reinforcing layer having a compressive stress on the surface, and it is easy and stable to prevent the progress of the crack immediately before the end portion of the predetermined line. Therefore, it is possible to prevent the glass from being naturally broken at the time when the scribe groove is formed in the glass.

此外,本發明係可抑制初期龜裂朝玻璃基板之端緣往相反方向進展。因此,可防止在將劃線溝形成在玻璃之時間點玻璃自然斷開。 Further, in the present invention, it is possible to suppress the initial crack from progressing in the opposite direction toward the edge of the glass substrate. Therefore, it is possible to prevent the glass from being naturally broken at the time when the scribe groove is formed in the glass.

第1圖係顯示用以實施本發明之一實施形態之劃線方法之裝置的概略構成圖。劃線裝置1係將例如母玻璃基板 斷開成使用在FPD(平板顯示器)之複數個單位基板的裝置。在此之玻璃基板係主要使用表面形成有強化層之化學強化玻璃。如前所述,該化學強化玻璃係具有藉由離子交換處理而在表面具壓縮應力的強化層。 Fig. 1 is a schematic block diagram showing an apparatus for carrying out a scribing method according to an embodiment of the present invention. The scribing device 1 is, for example, a mother glass substrate The device is disconnected into a plurality of unit substrates used in an FPD (Flat Panel Display). Here, the glass substrate mainly uses a chemically strengthened glass in which a reinforcing layer is formed on the surface. As described above, the chemically strengthened glass has a strengthening layer which has a compressive stress on the surface by ion exchange treatment.

<劃線裝置> <Line device>

劃線裝置1係具備使雷射束朝玻璃基板G照射之照射部2、冷卻部3、及未圖示之移動部。冷卻部3係透過噴嘴4噴射從未圖示之冷媒源供給之冷媒而形成冷卻點CP。移動部係使照射部2及冷卻部3之噴嘴4,沿著設定在玻璃基板G之劃線預定線SL在與玻璃基板G之間相對移動。 The scribing device 1 includes an illuminating unit 2 that radiates a laser beam toward the glass substrate G, a cooling unit 3, and a moving unit (not shown). The cooling unit 3 discharges the refrigerant supplied from a refrigerant source (not shown) through the nozzle 4 to form a cooling point CP. In the moving unit, the nozzles 4 of the irradiation unit 2 and the cooling unit 3 are relatively moved between the glass substrate G and the predetermined line SL set on the glass substrate G.

照射部2係具有照射雷射束LB之雷射振盪器(例如CO2雷射),透過光學系統將該雷射束LB作為射束點LS照射在玻璃基板G上。 The illuminating unit 2 has a laser oscillator (for example, a CO 2 laser) that irradiates the laser beam LB, and the laser beam LB is irradiated onto the glass substrate G as a beam spot LS through an optical system.

在此,雖未圖示,但在玻璃基板G之端部設置有用以形成作為劃線之起點之初期龜裂的初期龜裂形成手段。就初期龜裂形成手段而言,係使用切割輪等機械用工具,但亦可藉由雷射束之照射形成初期龜裂。 Here, although not shown, an initial crack forming means for forming an initial crack as a starting point of the scribe line is provided at the end of the glass substrate G. In the initial crack forming means, a mechanical tool such as a cutting wheel is used, but an initial crack may be formed by irradiation of a laser beam.

〔劃線方法〕 [scoping method] (第1實施形態) (First embodiment)

首先,如第1圖所示,利用切割輪等初期龜裂形成手段,在玻璃基板G之端部形成作為劃線之起點之初期龜裂TR。此時,初期龜裂TR之深度係設為形成在玻璃基板(強化玻璃)之表面的強化層被剝離之程度的深度。具體而言,將初期龜裂TR之深度設為強化層之厚度的1.0倍以上2.0 倍以下。 First, as shown in Fig. 1, an initial crack TR as a starting point of a scribe line is formed at an end portion of the glass substrate G by an initial crack forming means such as a cutter wheel. At this time, the depth of the initial crack TR is a depth to which the reinforcing layer formed on the surface of the glass substrate (tempered glass) is peeled off. Specifically, the depth of the initial crack TR is set to 1.0 times or more of the thickness of the reinforcing layer. Less than the following.

就以上之初期龜裂的前步驟或後步驟而言,在劃線預定線SL之終端部形成用以阻止龜裂沿著劃線預定線SL進展之複數個龜裂限制溝S。複數個龜裂限制溝S之各者係以預定之寬度形成在與劃線預定線SL正交之方向。並且,龜裂限制溝S之深度較佳為形成比在後序步驟中形成之劃線溝的深度更淺。其理由為當龜裂限制溝S過深時,由於玻璃基板之內部的拉伸應力,龜裂會以龜裂限制溝S為起點自然地進展,且基板因該龜裂而分離之故。再者,龜裂限制溝S之深度較佳為設成比強化層之厚度更深。 In the preceding step or the subsequent step of the initial cracking, a plurality of crack restricting grooves S for preventing the crack from progressing along the scribe line SL are formed at the end portion of the scribe line SL. Each of the plurality of crack restricting grooves S is formed in a direction orthogonal to the predetermined line SL by a predetermined width. Further, the depth of the crack restricting groove S is preferably formed to be shallower than the depth of the scribe groove formed in the subsequent step. The reason is that when the crack limiting groove S is too deep, the crack naturally progresses from the crack limiting groove S as a starting point due to the tensile stress inside the glass substrate, and the substrate is separated by the crack. Further, the depth of the crack restricting groove S is preferably set to be deeper than the thickness of the reinforcing layer.

此外,龜裂限制溝S亦可為與所有之劃線預定線SL正交之1條溝。然而,為了使在該溝形成時產生之粉塵等異物減少,較佳為局部地形成複數條溝。 Further, the crack restricting groove S may be one groove orthogonal to all the planned line SL. However, in order to reduce foreign matter such as dust generated when the groove is formed, it is preferable to form a plurality of grooves locally.

接著,對於玻璃基板G從照射部2照射雷射束LB。該雷射束LB係作為射束點LS照射在玻璃基板G上。然後,使從照射部2射出之雷射束LB,沿著劃線預定線SL與玻璃基板G相對地移動。玻璃基板G係藉由射束點LS而被加熱至比玻璃基板G之軟化點為低的溫度。此外,使冷卻點CP追隨在射束點LS之移動方向後方。此外,在射束點及冷卻點之掃描中,雖亦可考慮在龜裂進展停止用溝停止,但為了使雷射照射之控制容易,較佳為執行至玻璃基板G之端部為止。 Next, the laser beam LB is irradiated from the irradiation unit 2 to the glass substrate G. This laser beam LB is irradiated onto the glass substrate G as a beam spot LS. Then, the laser beam LB emitted from the illuminating unit 2 is moved relative to the glass substrate G along the scribe line SL. The glass substrate G is heated to a temperature lower than the softening point of the glass substrate G by the beam spot LS. Further, the cooling point CP is caused to follow the moving direction of the beam spot LS. Further, in the scanning of the beam spot and the cooling point, it is also conceivable to stop the groove for stopping the crack growth. However, in order to facilitate the control of the laser irradiation, it is preferable to perform the end portion of the glass substrate G.

如上所述,在藉由雷射束LB之照射而加熱之射束點LS的附近會產生壓縮應力,但之後立即藉由冷媒之噴射而 形成冷卻點,因此會產生對於垂直裂痕的形成有效之拉伸應力。藉由該拉伸應力,以形成在玻璃基板G之端部的初期龜裂TR為起點而形成沿著劃線預定線SL之垂直裂痕,以形成所希望之劃線溝。 As described above, compressive stress is generated in the vicinity of the beam spot LS heated by the irradiation of the laser beam LB, but immediately after the ejection by the refrigerant A cooling point is formed, thus producing an effective tensile stress for the formation of vertical cracks. By the tensile stress, a vertical crack along the predetermined line SL of the scribe line is formed with the initial crack TR formed at the end portion of the glass substrate G as a starting point to form a desired scribe groove.

在此,於劃線預定線SL之終端部、亦即玻璃基板G之周緣部形成有龜裂限制溝S,因此沿著劃線預定線SL進展之龜裂係因為該溝而停止。因此,龜裂不會進展至玻璃基板G之全深度,而可防止基板自然地被斷開。 Here, since the crack restricting groove S is formed at the end portion of the scribe line SL, that is, the peripheral portion of the glass substrate G, the crack which progresses along the scribe line SL is stopped by the groove. Therefore, the crack does not progress to the full depth of the glass substrate G, and the substrate can be prevented from being naturally disconnected.

(第2實施形態) (Second embodiment)

第2圖顯示其他方法之實施形態。在該實施形態中,與第1實施形態不同點僅在於形成龜裂限制溝S之位置,其他方法係與第1圖之實施形態相同。 Figure 2 shows an embodiment of another method. In this embodiment, the difference from the first embodiment is only the position at which the crack restricting groove S is formed, and the other methods are the same as those in the first embodiment.

具體而言,就形成初期龜裂TR之步驟的前步驟或後步驟而言,在屬於下一步驟之劃線溝形成步驟中,為了防止龜裂從初期龜裂TR朝與龜裂進展之方向(雷射束LB之掃描方向)相反之方向進展,而形成龜裂限制溝S。該溝S係在玻璃基板G之表面,形成在初期龜裂TR與玻璃基板G之端緣Ge之間。而且,龜裂限制溝S係以預定之寬度形成在與劃線預定線SL延伸之方向正交的方向。 Specifically, in the step of forming the initial crack TR, in the step of forming the groove in the next step, in order to prevent the crack from progressing from the initial crack TR to the crack (the scanning direction of the laser beam LB) progresses in the opposite direction to form the crack limiting groove S. The groove S is formed on the surface of the glass substrate G between the initial crack TR and the edge Ge of the glass substrate G. Further, the crack restricting groove S is formed in a direction orthogonal to the direction in which the predetermined line SL is extended with a predetermined width.

此外,關於龜裂限制溝S之深度或條數等,係與第1實施形態相同。亦即,龜裂限制溝S之深度較佳為形成為比在後序步驟中形成之劃線溝之深度更淺。再者,龜裂限制溝S亦可對應複數個劃線預定線SL之各者而形成,亦可為與所有之劃線預定線SL正交之1條溝。 In addition, the depth or the number of the crack limiting grooves S is the same as that of the first embodiment. That is, the depth of the crack restricting groove S is preferably formed to be shallower than the depth of the scribe groove formed in the subsequent step. Further, the crack restricting groove S may be formed corresponding to each of the plurality of scribe lines SL, or may be one groove orthogonal to all the scribe lines SL.

在該實施形態中,於劃線溝形成步驟中,即使龜裂從初期龜裂TR朝雷射束LB之掃描方向相反之方向進展,亦因為在初期龜裂TR與玻璃基板G之端緣Ge之間形成有龜裂限制溝S,所以龜裂係在龜裂限制溝S停止。因此,可避免龜裂從初期龜裂TR進展至玻璃基板G之端緣Ge,且在玻璃基板G之端緣部形成深的龜裂。藉此,可防止玻璃基板G自然地斷開。 In this embodiment, in the step of forming the scribe groove, even if the crack progresses from the initial crack TR to the direction opposite to the scanning direction of the laser beam LB, the edge of the initial crack TR and the glass substrate G is Ge. Since the crack restricting groove S is formed between them, the crack is stopped in the crack restricting groove S. Therefore, it is possible to prevent the crack from progressing from the initial crack TR to the edge Ge of the glass substrate G, and to form a deep crack at the edge portion of the glass substrate G. Thereby, the glass substrate G can be prevented from being naturally disconnected.

(實驗例) (Experimental example) (關於玻璃基板的斷開之驗證) (Verification of disconnection of glass substrate) 〔習知例之實驗例〕 [Experimental Example of Conventional Example]

第3圖係顯示習知方法之例,亦即在不形成龜裂限制溝S之情形下從劃線預定線之開始端至終端為止進行雷射加熱及冷卻之情形之例。基板係整體厚度0.7mm、強化層之厚度為18μm之強化玻璃。此外,雷射束之條件係為雷射輸出200W、掃描速度200mm/sec。此外,在第3圖中,玻璃基板之端部區域並未顯示。 Fig. 3 is a view showing an example of a conventional method, that is, a case where laser heating and cooling are performed from the beginning end to the end of the predetermined line of the scribe line without forming the crack restricting groove S. The tempered glass having a substrate thickness of 0.7 mm and a thickness of the reinforcing layer of 18 μm. In addition, the condition of the laser beam is a laser output of 200 W and a scanning speed of 200 mm/sec. Further, in Fig. 3, the end region of the glass substrate is not shown.

第3圖(a)係劃線剛結束後之狀態。在此,劃線溝係未遍及基板之全深度進展之狀態(以下將該狀態稱為「半切」),圖中係以薄的線來表示。 Fig. 3(a) shows the state immediately after the end of the scribe line. Here, the scribe line is not in a state in which the full depth of the substrate progresses (hereinafter, this state is referred to as "half-cut"), and is indicated by a thin line in the drawing.

第3圖(b)係從劃線處理5秒後之狀態。在此,從劃線之開始點側(圖之右側)至圖之中央附近劃線線為全切(圖中以粗線表示)。 Fig. 3(b) shows the state after 5 seconds from the scribing process. Here, the scribe line from the start point side (the right side of the figure) to the center of the figure is full cut (indicated by a thick line in the figure).

第3圖(c)係從劃線處理20秒後之狀態。在此,在圖中顯示之所有部分,劃線線為全切(圖中以粗線表示)。 Fig. 3(c) shows the state after 20 seconds from the scribing process. Here, in all the parts shown in the figure, the scribe line is full cut (indicated by a thick line in the figure).

如此,遍及從劃線預定線之開始端至終端為止之所有部位進行雷射加熱及冷卻而形成劃線溝時,基板會自然地斷開(被全切)。 As described above, when the scribe line is formed by performing laser heating and cooling over all the portions from the start end to the end of the predetermined line of the scribe line, the substrate is naturally disconnected (completely cut).

〈實施例〉 <Example>

針對以上之習知例,將龜裂限制溝S形成在劃線預定線SL之終端部、亦即形成在距離玻璃基板G之端面10至20mm之間,而可避免基板之全切。 In the above conventional example, the crack limiting groove S is formed at the end portion of the scribe line SL, that is, between 10 and 20 mm from the end surface of the glass substrate G, and the full cutting of the substrate can be avoided.

再者,藉由將龜裂限制溝S形成在初期龜裂TR與玻璃基板G之端緣Ge之間,可防止龜裂從初期龜裂TR朝基板端緣Ge形成,而可避免基板之全切、亦即自然斷開。 Further, by forming the crack limiting groove S between the initial crack TR and the edge Ge of the glass substrate G, it is possible to prevent the crack from being formed from the initial crack TR to the edge of the substrate Ge, and the entire substrate can be avoided. Cut, that is, naturally disconnected.

此外,在任一情形下,溝S皆係形成為比所形成之劃線溝之深度更淺。 Further, in either case, the grooves S are formed to be shallower than the depth of the formed scribe grooves.

〔關於初期龜裂之考察〕 [Investigation on initial cracks]

在本實施形態之方法中,初期龜裂之深度等對於製造品質之影響大。因此,以下顯示關於初期龜裂之深度的實驗例。 In the method of the present embodiment, the depth of the initial crack or the like has a large influence on the manufacturing quality. Therefore, an experimental example regarding the depth of the initial crack is shown below.

〈實驗例1〉 <Experimental Example 1>

第4圖係顯示對於整體厚度0.55mm、強化層之厚度18μm之強化玻璃形成劃線溝的實驗例1。具體而言,第4圖係顯示初期龜裂形成時之工具對於玻璃的推壓荷重與此時之溝深度之關係,並且顯示之後的雷射加熱及冷卻處理之劃線結果。 Fig. 4 shows Experimental Example 1 in which a tempered glass was formed into a scribe groove with an overall thickness of 0.55 mm and a thickness of the reinforcing layer of 18 μm. Specifically, Fig. 4 shows the relationship between the pressing load of the tool for the initial crack formation and the groove depth at the time of the formation of the crack, and shows the results of the scribing of the subsequent laser heating and cooling treatment.

此時之加熱處理用之雷射輸出為200W、加工速度為230mm/sec。此外,冷卻條件係在射束後端配置冷卻噴嘴, 將冷卻水及空氣送出至在射束點加熱之部分。 At this time, the laser output for the heat treatment was 200 W, and the processing speed was 230 mm/sec. In addition, the cooling condition is to arrange a cooling nozzle at the rear end of the beam. The cooling water and air are sent to the portion heated at the beam spot.

由該實驗例1得知,只要是初期龜裂之溝深度為19至30μm(強化層之厚度之1.05至1.67倍),則沿著劃線預定線可形成所希望之劃線溝。並且得知,在溝深度未達19μm時,龜裂並未確實地進展(不穩定),當溝深度超過30μm時會產生斷裂,且在劃線預定線以外形成龜裂。 According to the experimental example 1, as long as the initial crack groove depth is 19 to 30 μm (1.05 to 1.67 times the thickness of the reinforcing layer), a desired scribe groove can be formed along the predetermined line of the scribe line. Further, it was found that when the groove depth was less than 19 μm, the crack did not progress reliably (unstable), and when the groove depth exceeded 30 μm, cracking occurred and cracks were formed outside the line to be scribed.

此外,第5圖係顯示初期龜裂之溝深度之例。如第5圖所示,將確保預定之面積的最深部分的深度稱為「溝深度」,對於局部尖銳地到達深部之龜裂則予以忽略。 In addition, Fig. 5 shows an example of the depth of the initial crack groove. As shown in Fig. 5, the depth of the deepest portion of the predetermined area is referred to as the "ditch depth", and the crack which is partially sharply reached to the deep portion is ignored.

〔實驗例2〕 [Experimental Example 2]

第6圖係顯示對於整體厚度0.7mm、強化層之厚度21μm之強化玻璃形成劃線溝的實驗例2。圖之橫軸與縱軸之關係係與第4圖相同。此時之加熱處理用之雷射輸出為200W、加工速度170mm/sec。此外,冷卻條件係與實驗例1相同。 Fig. 6 shows Experimental Example 2 in which a tempered glass having a total thickness of 0.7 mm and a thickness of the reinforcing layer of 21 μm was formed into a scribe groove. The relationship between the horizontal axis and the vertical axis of the figure is the same as in Fig. 4. At this time, the laser output for the heat treatment was 200 W, and the processing speed was 170 mm/sec. Further, the cooling conditions were the same as in Experimental Example 1.

由該實驗例2得知,只要是初期龜裂之溝深度為約24至50μm(強化層之厚度之1.14至2.38倍),則沿著劃線預定線可形成所希望之劃線溝。並且得知,在溝深度未達24μm時,龜裂並未確實地進展(不穩定),當溝深度超過50μm時會產生斷裂,且在劃線預定線以外形成龜裂。此外,若推壓荷重為約6至24N,則即使溝深度超過50μm也可形成所希望之劃線溝,但若僅著眼於溝深度時,初期龜裂之溝深度較佳為約24至50μm。 According to the experimental example 2, as long as the initial crack groove depth is about 24 to 50 μm (1.14 to 2.38 times the thickness of the reinforcing layer), a desired scribe groove can be formed along the predetermined line of the scribe line. Further, it was found that when the groove depth was less than 24 μm, the crack did not progress reliably (unstable), and when the groove depth exceeded 50 μm, cracking occurred and cracks were formed outside the line to be scribed. Further, if the pressing load is about 6 to 24 N, the desired scribe groove can be formed even if the groove depth exceeds 50 μm, but the initial crack groove depth is preferably about 24 to 50 μm if only the groove depth is focused. .

〔實驗例3〕 [Experimental Example 3]

第7圖係顯示對於整體厚度1.1mm、強化層之厚度34μm之強化玻璃形成劃線溝的實驗例3。圖之橫軸與縱軸之關係係與第4圖相同。此時之加熱處理用之雷射輸出為200W、加工速度為170mm/sec。此外,冷卻條件係與實驗例1相同。 Fig. 7 shows Experimental Example 3 in which a tempered glass having a total thickness of 1.1 mm and a thickness of the reinforcing layer of 34 μm was formed into a scribe groove. The relationship between the horizontal axis and the vertical axis of the figure is the same as in Fig. 4. At this time, the laser output for the heat treatment was 200 W, and the processing speed was 170 mm/sec. Further, the cooling conditions were the same as in Experimental Example 1.

由該實驗例3得知,只要是初期龜裂之溝深度為24至60μm(強化層之厚度之0.71至1.76倍),則沿著劃線預定線可形成所希望之劃線溝。並且得知,在溝深度過淺時,龜裂並未進展,而當溝深度超過60μm時,龜裂進展會不穩定。此外,與實驗例2同樣地,若推壓荷重為約6至24N,則即使溝深度超過60μm也可形成所希望之劃線溝,但若僅著眼於溝深度時,初期龜裂之溝深度較佳為約24至60μm。 According to the experimental example 3, as long as the initial crack groove depth is 24 to 60 μm (0.71 to 1.76 times the thickness of the reinforcing layer), a desired scribe groove can be formed along the predetermined line of the scribe line. It is also known that when the depth of the groove is too shallow, the crack does not progress, and when the groove depth exceeds 60 μm, the crack progress is unstable. Further, in the same manner as in Experimental Example 2, if the pressing load is about 6 to 24 N, a desired scribe groove can be formed even if the groove depth exceeds 60 μm, but the depth of the initial crack groove is only focused on the groove depth. It is preferably about 24 to 60 μm.

〔總結〕 〔to sum up〕

由以上得知,為了沿著劃線預定線而形成所希望之劃線溝,初期龜裂之深度較佳為強化玻璃之強化層之厚度的1.0倍以上2.0倍以下。並且得知,初期龜裂之深度較佳為,玻璃板厚為0.55mm時係為30μm(5.5%)以下,玻璃板厚為0.7mm時係為50μm(7.1%以下,玻璃板厚為1.1mm時係為60μm(5.4%)以下。這是表示初期龜裂之深度在最大時亦以玻璃板厚之7%以下為佳。 From the above, it is understood that the depth of the initial crack is preferably 1.0 times or more and 2.0 times or less the thickness of the reinforcing layer of the tempered glass in order to form a desired scribe line along the predetermined line of the scribe line. Further, it is understood that the depth of the initial crack is preferably 30 μm (5.5%) or less when the thickness of the glass sheet is 0.55 mm, and is 50 μm (7.1% or less, and the thickness of the glass sheet is 1.1 mm when the thickness of the glass sheet is 0.7 mm). The time is 60 μm (5.4%) or less. This means that the depth of the initial crack is preferably 7% or less of the thickness of the glass sheet at the maximum.

〔特徵〕 〔feature〕 -第一實施形態- - First embodiment -

(1)由於在劃線預定線SL之終端部、亦即掃描終了側 之端部區域形成有與劃線預定線SL正交之龜裂進展停止用之溝S,因此可實現基板之半切,且可避免基板之自然斷開。因此,交叉劃線等之後序的加工步驟變得容易。 (1) Since the end portion of the predetermined line SL is scanned, that is, the end of the scanning side The end portion is formed with a groove S for stopping the crack development orthogonal to the predetermined line SL, so that the half cut of the substrate can be realized, and the natural disconnection of the substrate can be avoided. Therefore, the subsequent processing steps of the cross-dash or the like become easy.

(2)由於形成溝作為用以使劃線預定線SL之終端部之龜裂進展停止之手段,因此能以簡單之方法避免基板之自然斷開。 (2) Since the groove is formed as a means for stopping the cracking of the end portion of the scribe line SL, the natural detachment of the substrate can be avoided in a simple manner.

-第二實施形態- - Second embodiment -

(1)由於在劃線預定線SL之開始端部,即初期龜裂與基板端緣之間形成用以限制與劃線預定線SL正交之龜裂的溝S,因此可防止龜裂從初期龜裂朝基板端緣進展。因此,可避免在基板之端緣部形成深的龜裂,且可避免因該深的龜裂所造成之基板的自然斷開。因此,交叉劃線等之後的加工步驟變得容易。 (1) Since the groove S at the beginning end of the scribe line SL, that is, the initial crack and the edge of the substrate, is formed to restrict the crack orthogonal to the scribe line SL, the crack can be prevented from being The initial crack progresses toward the edge of the substrate. Therefore, it is possible to avoid formation of deep cracks at the edge portions of the substrate, and it is possible to avoid natural breakage of the substrate due to the deep cracks. Therefore, the processing steps after the cross-dash or the like become easy.

(2)由於限制從初期龜裂朝基板端緣之龜裂的形成,因此可減少初期龜裂從基板端緣之偏置量,因此,在基板中,無法確保作為製品之部分會變少,且可使製品之成品率提升。 (2) Since the formation of cracks from the initial crack to the edge of the substrate is restricted, the amount of offset of the initial crack from the edge of the substrate can be reduced, and therefore, it is impossible to ensure that the portion as a product is reduced in the substrate. And the product yield can be improved.

(3)由於形成溝作為用以使從初期龜裂朝基板端緣之龜裂停止之手段,因此能以簡單之方法避免基板之自然斷開。 (3) Since the groove is formed as a means for stopping the crack from the initial crack toward the edge of the substrate, the natural disconnection of the substrate can be avoided in a simple manner.

(4)由於初期龜裂與龜裂限制溝係分離地形成,因此可更確實地使從初期龜裂朝基板端緣之龜裂停止。 (4) Since the initial crack and the crack restricting groove are formed separately, it is possible to more reliably stop the crack from the initial crack toward the edge of the substrate.

-共通之特徵- - Common features -

由於龜裂限制溝係局部地形成,因此可儘可能地抑制 粉塵之產生,且可避免玻璃基板之品質的降低。 Since the crack restricts the formation of the ditch locally, it can be suppressed as much as possible The generation of dust and the deterioration of the quality of the glass substrate can be avoided.

〔其他實施形態〕 [Other Embodiments]

本發明並非限定在以上之實施形態者,在不脫離本發明之範圍之下可進行各種變形或修正。 The present invention is not limited to the embodiments described above, and various modifications and changes can be made without departing from the scope of the invention.

龜裂進展停止用之溝雖較佳為以與劃線預定線正交之方式形成,但只要形成為與劃線預定線交叉,則亦可不正交。 Although the groove for stopping the progress of cracking is preferably formed so as to be orthogonal to the predetermined line of the scribe line, it may not be orthogonal as long as it is formed so as to intersect the line to be scribed.

1‧‧‧劃線裝置 1‧‧‧ scribe device

2‧‧‧照射部 2‧‧‧ Department of Irradiation

3‧‧‧冷卻部 3‧‧‧ Cooling Department

4‧‧‧噴嘴 4‧‧‧ nozzle

CP‧‧‧冷卻點 CP‧‧‧cooling point

G‧‧‧玻璃基板 G‧‧‧glass substrate

Ge‧‧‧玻璃基板之端緣 The edge of the Ge‧‧‧ glass substrate

LB‧‧‧雷射束 LB‧‧‧Laser beam

LS‧‧‧射束點 LS‧‧·beam point

S‧‧‧龜裂限制溝 S‧‧‧ crack limit groove

SL‧‧‧劃線預定線 SL‧‧‧lined line

TR‧‧‧初期龜裂 TR‧‧‧ initial crack

第1圖係用以實施本發明之第1實施形態之劃線方法之裝置的概略構成圖。 Fig. 1 is a schematic configuration diagram of an apparatus for carrying out the scribing method according to the first embodiment of the present invention.

第2圖係用以實施本發明之第2實施形態之劃線方法之裝置的概略構成圖。 Fig. 2 is a schematic configuration diagram of an apparatus for carrying out the scribing method according to the second embodiment of the present invention.

第3圖係顯示藉由習知方法實施劃線時,基板自然地分離之狀況的圖。 Fig. 3 is a view showing a state in which the substrate is naturally separated when the scribing is performed by a conventional method.

第4圖係顯示相對於厚度0.55mm之強化玻璃之初期龜裂形成用之推壓荷重與初期龜裂之關係及劃線結果的圖。 Fig. 4 is a graph showing the relationship between the pressing load for initial crack formation and the initial crack and the result of scribing with respect to the tempered glass having a thickness of 0.55 mm.

第5圖係形成有初期龜裂之強化玻璃之一部分的放大剖面圖。 Fig. 5 is an enlarged cross-sectional view showing a portion of the tempered glass in which initial cracks are formed.

第6圖係顯示相對於厚度0.7mm之強化玻璃之初期龜裂形成用之推壓荷重與初期龜裂之關係及劃線結果的圖。 Fig. 6 is a graph showing the relationship between the pressing load for initial crack formation and the initial crack and the result of scribing with respect to the tempered glass having a thickness of 0.7 mm.

第7圖係顯示相對於厚度1.1mm之強化玻璃之初期龜裂形成用之推壓荷重與初期龜裂之關係及劃線結果的圖。 Fig. 7 is a graph showing the relationship between the pressing load for initial crack formation and the initial crack and the scribing result with respect to the tempered glass having a thickness of 1.1 mm.

1‧‧‧劃線裝置 1‧‧‧ scribe device

2‧‧‧照射部 2‧‧‧ Department of Irradiation

3‧‧‧冷卻部 3‧‧‧ Cooling Department

4‧‧‧噴嘴 4‧‧‧ nozzle

CP‧‧‧冷卻點 CP‧‧‧cooling point

G‧‧‧玻璃基板 G‧‧‧glass substrate

LB‧‧‧雷射束 LB‧‧‧Laser beam

LS‧‧‧射束點 LS‧‧·beam point

S‧‧‧龜裂限制溝 S‧‧‧ crack limit groove

SL‧‧‧劃線預定線 SL‧‧‧lined line

TR‧‧‧初期龜裂 TR‧‧‧ initial crack

Claims (6)

一種玻璃基板之劃線方法,係對在表面具有具壓縮應力之強化層的玻璃進行劃線者,該方法係包含:龜裂限制溝形成步驟,於玻璃之表面,將具有預定寬度之龜裂限制用溝朝與劃線預定線交叉之方向形成在劃線預定線之終端部;及劃線溝形成步驟,將雷射光照射在玻璃之表面而予以加熱,並且將加熱過之區域予以冷卻,並使龜裂沿著劃線預定線進展而形成劃線溝。 A method for scribing a glass substrate by scribing a glass having a reinforcing layer having a compressive stress on the surface, the method comprising: a crack restricting groove forming step, and a crack having a predetermined width on a surface of the glass The restricting groove is formed at a terminal end of the predetermined line of the scribe line in a direction intersecting the predetermined line of the scribe line; and the step of forming the scribe groove, the laser light is irradiated on the surface of the glass to be heated, and the heated region is cooled. The crack is formed along the predetermined line of the scribe line to form a scribe groove. 如申請專利範圍第1項所述之玻璃基板之劃線方法,復包含初期龜裂形成步驟,該步驟係作為前述劃線溝形成步驟之前步驟,將強化層之一部分予以去除,以在玻璃之表面形成初期龜裂。 The method for scribing a glass substrate according to claim 1, further comprising an initial crack forming step of removing a portion of the reinforcing layer as a step before the step of forming the dash groove to be in the glass The surface forms an initial crack. 一種玻璃基板之劃線方法,係對在表面具有具壓縮應力之強化層的玻璃進行劃線者,該方法係包含:初期龜裂形成步驟,將強化層之至少一部分予以去除,以在玻璃之表面形成初期龜裂;劃線溝形成步驟,將雷射光照射在玻璃之表面而予以加熱,並且將加熱過之區域予以冷卻,並使前述初期龜裂沿著劃線預定線進展而形成劃線溝;及龜裂限制溝形成步驟,為了限制前述初期龜裂朝與在前述劃線溝形成步驟中之龜裂進展方向相反之方向進展,而在玻璃之表面中於前述初期龜裂與玻璃基板之端緣之間,朝與劃線預定線延伸之方向交叉的方向形成 具有預定寬度之龜裂限制溝,作為前述初期龜裂形成步驟之前處理或後處理。 A method for scribing a glass substrate by scribing a glass having a reinforcing layer having a compressive stress on a surface thereof, the method comprising: an initial crack forming step of removing at least a portion of the reinforcing layer to be in the glass The surface is initially cracked; the scribe groove forming step is performed by irradiating the laser light on the surface of the glass, heating the heated region, and cooling the heated region to form a scribe line along the predetermined line of the scribe line. a groove and a crack restricting groove forming step for restricting the initial crack from progressing in a direction opposite to a direction in which the crack progresses in the step of forming the groove, and forming the initial crack and the glass substrate on the surface of the glass Between the end edges, forming a direction crossing the direction in which the predetermined line of the scribe line extends A crack limiting groove having a predetermined width is treated as a pre-treatment or post-treatment of the initial crack forming step. 如申請專利範圍第1項至第3項中任一項所述之玻璃基板之劃線方法,其中,於前述龜裂限制溝形成步驟中,前述龜裂限制溝係以朝與劃線預定線垂直之方向延伸的方式形成。 The method for scribing a glass substrate according to any one of claims 1 to 3, wherein, in the step of forming the crack limiting groove, the crack limiting groove is oriented toward a line Formed in a vertical direction. 如申請專利範圍第1項至第3項中任一項所述之玻璃基板之劃線方法,其中,於前述龜裂限制溝形成步驟中,前述龜裂限制溝係形成為比在前述劃線溝形成步驟中形成之劃線溝之深度更淺。 The method for scribing a glass substrate according to any one of the preceding claims, wherein, in the step of forming a crack limiting groove, the crack limiting groove is formed to be larger than the scribing line The depth of the scribe groove formed in the groove forming step is shallower. 如申請專利範圍第2項或第3項所述之玻璃基板之劃線方法,其中,於前述初期龜裂形成步驟中形成之初期龜裂、與在前述龜裂限制溝形成步驟中形成之溝,係在兩者之間隔著間隔而形成。 The method for scribing a glass substrate according to the second or third aspect of the invention, wherein the initial crack formed in the initial crack forming step and the groove formed in the crack restricting groove forming step , formed by the interval between the two.
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