201247553 六、發明說明： 【發明所屬之技術領域】 [隱1] 本發明係有關於一種被濃縮的礦泉水或者是礦泉水的粉 末。 【先前技術】 [0002] 伴隨著全國性的自來水的水質惡化，礦泉水的須求逐漸 增高。礦泉水不僅具有所謂美味的好處，並且依據產地 不同，亦含有許多為維持人體健康所不可欠缺的必要微 量元素。 〇 [0003] 另一方面，海水，特別是在海洋深層水中，由於富含有 各種離子，故原水或進行過各式各樣處理的海水，得以 廣泛地利用在食品、醫藥品、化妝品、農業、水產等各 方面。 [0004] 另外，下列表1係為表示海洋表層水及海洋深層水的分析 結果的一例之資料。海洋深層水具有低溫、生菌數少、 營養鹽類多等特徵。至於各種離子在表層水及深層水間 Ο ，則並未見有太大差異。 [0005] < 表 1 > 1003276649-0 100118057 表單編號A0101 第3頁/共21頁 201247553 [0006] 分析項目 表層水 深層水 —般項目 水溫（°C) 21.0 13.1 pH 8.19 7.87 8.33 營養鹽類 N〇3~N L49 25.9 P〇4-P 0.34 1.65 Si〇2-Si 13.6 64.2 微量元素 Pb 0.099 0.111 {βφ) Cd 0.099 0.029 Cu 0.320 0.173 Fe 0.371 0.281 Mn 1.214 0,153 Ni 0.33 0.376 Zn 0.66 0,71 As 0.33 0.41 Mo 7.81 7.73 [0007] [0008] [0009] [0010] [0011] 從上述海洋表層水獲得礦泉水（水）的方法中，係提出 有如下列各種各樣的方案。 〈專利文獻1 >特開平9-290260號公報 〈專利文獻2 >特開2001 —87762號公報 <專利文獻3 >特開2003 - 94055號公報 上述專利文獻1，係將鹽水藉由逆滲透膜分離成透過水及 濃縮海水，將濃縮海水藉由電透析法分離成濃縮海水及 脫鹽水，再使濃縮海水的水分蒸發而獲得蒸發水以及逆 滲透膜的透過水，將所獲得蒸發水以及逆滲透膜的透過 100118057 表單編號A0101 第4頁/共21頁 1003276649-0 201247553 [0012] [0013] Ο [0014] [0015] Ο [0016] 水當作飲料供料m㈣製造方法。 後，=2、’係將料深層水藉由逆渗透法且經脫鹽處理 的·'種將水’彻脫鹽水再藉由電透析法所完成 ❹料深層水進行脫祕理的水的製造方法。 水與濃m係由將海水進行脫鹽處理後，生成脫鹽處理 十農心 _脫鹽步驟；從於上述步驟中已生成的 海水:《分離而生成濃_泉水的—農縮礦泉 的、'*始驟以及將於該濃縮礦泉水生成步驟中已生成 ::::泉水，以於該脫鹽步驟已生成的該脫鹽處理水 点測量導電率邊進行稀釋而生成礦泉水的一礦泉水生 步驟所組成的-種礦物組成物、其製造方法及其使用 方法。 t發明内容】 <發明所欲解決的課題> 像這樣可以為了能夠將海水絲毫不剩地作為礦泉水（水 )加以利用’雖已提出了可製造出均衡良好地含有著海 水所含有的㉝、鎂等或氮、填等營養鹽；亦或是场、鋅 欽、蛾等微量元素的礦物質豐富的礦泉水的技術方案 但其所製造的礦泉水（水）係以原本的形態加 以流通 ，且係為運輸性等較無效率的方案。 此外’雖然說礦泉水（水）中含有許多為維持人體健康 所不可欠缺的必要微量元素，但一公升中的含有量，充 其量最多也僅介於50〜1〇〇微克程度，不喝大量的水的話 ，效果較不顯著。 100118057 表單編號A0101 第5頁/共21頁 1003276649-0 201247553 [0017] [0018] [0019] [0020] [0021] [0022] 口 如何將礦泉水濃縮，以提高礦物質的濃度加以使 用的技術一直以來備受檢視與研討。 例如，上述專利文獻3 ,係涉及關於以將礦泉水濃縮或乾 燥而獲得為特徵的礦物糊狀物或礦物粉末，亦或礦表水 ;以及含有以將礦物糊狀物及/或礦物粉末複合至飲料 、粉末飲料、加工食品、豆腐凝固劑、皮膚外用劑水溶 液、植物成長調整劑或動物成長調整劑的原料中為特徵 的礦物組成物的加工品的製造方法。 專利文獻3的說明書的段落號碼[0033]中，雖已記載「於 本發明中，因為經處理的原水及透析水係同時成為擁有 特定組成的離子水’所以雙方皆可作為製品加以使用。 此外，所獲得的離子水進一步藉由進行濃縮、固化、乾 燥等操作，亦可以礦物糊狀物或礦物粉末的形態加以利 用。」，然並未揭示所提及的濃縮、固化的具體方法。 使用透析裝置的一般的濃縮方法，雖然可達到將鹽濃度 的比率加以變化的濃縮，但卻具有所謂礦物質大量損失 的問題。 此外，當藉由使水分蒸發而濃縮時，例如，在包含海洋 深層水等的硫酸離子的礦泉水的情況下，含有於礦泉水 内的礦物成分’特別是鎂（Mg)或鈣（Ca)等鹼土類金 、屬會與硫酸離子相結合而生成不溶性的沉殿物。像這樣 當沉澱物產生時，因為沉澱物不會再溶解，就結果而論 ，將會發生礦泉水的液體中的礦物質減少的問題。 此外，當不溶性的沉澱物產生時，亦會發生如下的缺失 100118057 表單編號A0101 第6頁/共21頁 201247553 狀況。亦即’當將已濃縮的礦泉水以噴霧乾燥器使其乾 燥’而形成為粉末時，進一步變得容易管理，也增加運 輸的方便性’但是’ 一旦已濃縮的礦泉水中出現沉澱物 時’喷霧乾燥器將會發生網目阻塞情況。為了防止此類 情形，即便已於乾燥前將沉澱物除去，仍有因濃縮，而 於噴嘴或者是霧化器中發生固化情況，而使通管阻塞的 問題存在。 [0023] Ο [0024] [0025] 本發明之目的在於解決上述習知例的不便之處，提供一 種礦泉水及其粉末，其含有於礦泉水内的礦物成分不僅 不會生成為不溶性的沉澱物，還可於原本均勻的成分狀 態下進行濃縮及粉末化。 < 解決課題的手段 >201247553 VI. Description of the Invention: [Technical Field to Which the Invention Is Applicable] [Hidden 1] The present invention relates to a powder of concentrated mineral water or mineral water. [Prior Art] [0002] As the water quality of tap water in the country deteriorates, the demand for mineral water is gradually increasing. Mineral water not only has the so-called delicious benefits, but also contains many essential micro-elements that are essential for maintaining human health, depending on the place of origin. 〇[0003] On the other hand, seawater, especially in deep ocean water, is rich in various ions, so raw water or seawater that has been treated in various ways can be widely used in food, pharmaceuticals, cosmetics, agriculture. , aquatic products and other aspects. Further, the following Table 1 is an example of an analysis result of ocean surface water and ocean deep water. Deep ocean water has the characteristics of low temperature, few bacteria, and many nutrients. As for various ions in the surface water and deep water, there is no significant difference. [0005] <Table 1 > 1003276649-0 100118057 Form No. A0101 Page 3 of 21 201247553 [0006] Analysis item surface water depth water-like project water temperature (°C) 21.0 13.1 pH 8.19 7.87 8.33 Nutrient salt N〇3~N L49 25.9 P〇4-P 0.34 1.65 Si〇2-Si 13.6 64.2 Trace element Pb 0.099 0.111 {βφ) Cd 0.099 0.029 Cu 0.320 0.173 Fe 0.371 0.281 Mn 1.214 0,153 Ni 0.33 0.376 Zn 0.66 0,71 As 0.33 0.41 Mo 7.81 7.73 [0007] [0010] [0011] Among the methods for obtaining mineral water (water) from the above-mentioned ocean surface water, various proposals are as follows. [Patent Document 1 > Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The reverse osmosis membrane is separated into permeated water and concentrated seawater, and the concentrated seawater is separated into concentrated seawater and desalted water by electrodialysis, and then the water of the concentrated seawater is evaporated to obtain evaporated water and permeated water of the reverse osmosis membrane, and the obtained evaporation is obtained. Permeation of water and reverse osmosis membrane 100118057 Form No. A0101 Page 4 of 21 Page 1003276649-0 201247553 [0013] [0015] [0016] Water [0016] Water is used as a beverage supply m (four) manufacturing method. After that, =2, 'the deep water is treated by the reverse osmosis method and the desalted water, the 'water is' is dehydrated, and the deep water of the deep water is removed by electrodialysis. method. The water and the concentrated m system are desalted by the seawater, and the desalination treatment is carried out. The demineralization step is carried out; the seawater that has been generated in the above steps: "the separation and the formation of the concentrated spring water - the agricultural shrinkage mineral spring, '* And a spring water step which is formed in the concentrated mineral water generating step to generate mineral water by measuring the conductivity of the desalting water point which has been generated in the desalination step - a mineral composition, a method for producing the same, and a method of using the same. (Explanation of the Invention) <Problems to be Solved by the Invention> In order to be able to use seawater as a mineral water (water), it has been proposed to produce a well-balanced seawater content. 33. Magnesium or other nitrogen or filling nutrients; or a mineral-rich mineral water solution of trace elements such as field, zinc, moth, etc., but the mineral water (water) produced by it is in the original form. Circulation, and is a less efficient solution such as transportation. In addition, although mineral water (water) contains many essential trace elements that are essential for maintaining human health, the content of one liter is at most 50 to 1 microgram, and does not drink a lot. If water is used, the effect is less significant. 100118057 Form No. A0101 Page 5 of 21 1003276649-0 201247553 [0020] [0022] [0022] [0022] How to condense mineral water to increase the concentration of minerals to use It has always been subject to review and discussion. For example, the above-mentioned Patent Document 3 relates to a mineral paste or a mineral powder or a mineral water which is obtained by concentrating or drying mineral water; and a compound for mixing a mineral paste and/or a mineral powder. A method for producing a processed product of a mineral composition characterized by a raw material of a beverage, a powdered beverage, a processed food, a tofu coagulant, an aqueous solution for external use of a skin, a plant growth regulator, or an animal growth regulator. In the paragraph number [0033] of the specification of the patent document 3, it is described that "in the present invention, since the treated raw water and the dialysis water system simultaneously become ionized water having a specific composition", both of them can be used as products. The obtained ionic water is further subjected to concentration, solidification, drying, etc., and may be utilized in the form of a mineral paste or a mineral powder." However, the specific method of concentration and solidification mentioned is not disclosed. The general concentration method using a dialysis apparatus, although concentrating which changes the ratio of the salt concentration, can be achieved, but has a problem of a large amount of so-called mineral loss. Further, when it is concentrated by evaporating water, for example, in the case of mineral water containing sulfate ions such as deep ocean water, the mineral component contained in the mineral water is particularly magnesium (Mg) or calcium (Ca). Alkaline earth gold and genus combine with sulfate ions to form insoluble sediments. In this way, when the precipitate is produced, since the precipitate does not dissolve again, as a result, there is a problem that the mineral in the liquid of the mineral water is reduced. In addition, when insoluble precipitates are produced, the following defects will also occur. 100118057 Form No. A0101 Page 6 of 21 201247553 Status. That is, when the concentrated mineral water is dried by a spray dryer to form a powder, it becomes easier to manage and also increases the convenience of transportation 'but 'once the precipitate appears in the concentrated mineral water' Mesh blocking will occur in the spray dryer. In order to prevent such a situation, even if the precipitate has been removed before drying, there is a problem that condensation occurs in the nozzle or the atomizer, and the problem of clogging of the pipe exists. [0025] [0025] The object of the present invention is to solve the inconvenience of the above conventional examples, and to provide a mineral water and a powder thereof, which not only does not form an insoluble precipitate in the mineral component contained in the mineral water. The material can also be concentrated and pulverized under the condition of a homogeneous component. < means to solve the problem >
為達成上述目的，本發明的礦泉水是，第_，係於至少 包含錢或財任-成分之礦泉水内，加人胺基酸經濃縮 而得；第二，相對於礦泉水中所含有之礦物扪莫耳，係加入〇.1莫耳以上之絲酸；第三，絲酸料甘胺酸等 為要旨之發明》 寻 [0026] [0027] 此外，第四，至少包含鎂或鈣中任一 海洋冰層水為要旨之發明。 成分之礦泉水係為 再者’就礦泉水的粉末而言，則是以於至少 中任一成分之礦泉水内，添加胺基酸及㈣糖漿或_ 澱粉《’《職’藉㈣霧賴Μ已知的方法使 其乾燥而經粉末化所得為要旨之發明。 [0028] 100118057 根據申請專利範圍第！項所界定的本發明， 表單編號Α0101 第7頁/共21頁 藉由礦泉水中 1003276649-0 201247553 礦物質的金屬離子與胺基酸而得以形成螯合化合物，由 於金屬離子是藉由胺基酸分子而被捕捉至螯合環之間， 於濃縮後即使加以乾燥，仍不會因礦泉水中的硫酸離子 而生成不溶性的沉澱物，還可於原本均勻的成分狀態下 進行濃縮。 [0029] 根據申請專利範圍第2項所界定的本發明，除上述作用外 ，更加上藉由相對於礦泉水中所含有之礦物質1莫耳，加 入0. 1莫耳以上之胺基酸，可充分迴避因之後的濃縮而產 生沉殿物的危險性。 [0030] 此外，就胺基酸而言，雖可以使用纈草胺酸、白胺酸、 異白胺酸、丙胺酸、精胺酸、麩醯胺、賴胺酸、天冬醯 胺酸、麩醯胺酸、脯胺酸、半胱胺酸、息寧胺酸、曱硫 胺酸、組胺酸、苯丙胺酸、酪胺酸、色胺酸、天冬醯胺 、甘胺酸、絲胺酸中任一種，但根據申請專利範圍第3項 所界定的本發明，於其中擁有最為簡單的構造，且分子 量亦為最小的甘胺酸，就分子量及分子形狀等方面來說 ，最為適宜。 [0031] 根據申請專利範圍第4項所界定的本發明，一旦經乾燥濃 縮，即可獲得一方面可克服所謂的因礦物質與硫酸離子 而容易產生不溶性的沉澱物的海洋深層水的弱點；並且 另一方面可發揮作為所謂的生菌數少、營養鹽類多等優 點的礦泉水。 [0032] 根據申請專利範圍第5項所界定的本發明，藉由礦泉水中 礦物質的金屬離子與胺基酸而得以形成螯合化合物，由 100118057 表單編號A0101 第8頁/共21頁 1003276649-0 201247553 於金屬離子疋藉由胺基酸分子而被捕捉至螯合環之間， 於濃縮後卩便加以乾燥，仍不會因礦泉水中的硫酸離子 而生成不溶性的沉澱物。因此，即便將已濃縮的礦泉水 以喷霧乾燥器使其乾燥仍不會有乾燥器内的喷嘴 ^或嘴霧乾燥器内部中礦物質固化而阻塞等情況， 還可獲得維持於原本均勻的成分狀態下的粉末。此外， 可因所添加的殺粉糖漿或還原殿粉糖衆而形成為完美的 粉末狀。 [0033] <發明的效果> 〇 [0034] 如上所述，根據本發明的礦泉水及其粉末，含有於礦泉 水内的礦物成分不僅不會生成為不溶性的沉殿物，還可 ㈣本^的成分狀態下進行濃縮及粉末化。 【實施方式】 [_] W下’將對本發明的實施型態進行詳細說明。第1圖係表 示本發明的礦泉水及其粉末的第 一實施型態的製造步驟 圖第2圖則表示同上第二實施型態的製造步驟圖，其中 C) 第lBI為使用海洋深層礦泉水的情況、第2圖則為使用 海洋深層礦物鹽水的情況。 [0036] 如第1圖所千，+ 口 β 所不本發明是於用以作為至少包含鎂或鈣中任 成刀（包含雙方的情況較多）之礦泉水的海洋深層礦 泉水或海洋深層礦物鹽水内，加入胺基酸於55°C下混合 再以濃縮器經濃縮而得（固形率25% )。 _ w自絲取得上㈣泉水的情訂，獲㈣水、海洋深 層礦泉水、海洋深層礦物鹽水、鹽水的方法則表示於第3 100118057 表單編號A0101 第9頁/共21頁 1003276649-0 201247553 [0038] [0039] [0040] [0041] [0042] 圖中。 如第3圖所示，將海洋深層水26透過取水管36，藉由取水 幫浦室37的取水幫浦37a向上抽吸，輸送至—次貯液槽38 後，將此水當作被處理水，進一步藉由送水幫浦38a而朝 各處理作業線輸送。依據處理的方式，可以獲得原水21 、礦泉水208、鹽水209、淡水18、礦物鹽水19等複數種 類的水。 首先，針對獲得淡水18及礦物鹽水19的方法進行說明時 ，係具備著已設有逆滲透膜（以下，稱肋膜）的㈧膜分 〇離裝置13。 於RO膜分離裝置13中，例如可使用醋酸纖維膜亦或合成 尚分子臈（聚乙烯系、架橋酿胺系、架橋聚醯胺系等） 等用以作為RQ膜。此外，膜是可使用中空線型、螺旋 型等各種各樣的型式，其中，使賴塊形狀的薄膜，較 為適合。 貯存於給水槽39内，目朗要何設計為藉由給水M Q 39a而朝各別的給水站28送出，當於無法自給水站28取出 之時，使其加以循環，進而可設計為藉由uv殺菌裝置29 進行定期的殺菌。 供給至上述R0膜分離裝置13的R〇膜，再將水17中的鹽等 冷質藉由膜分離而除去，其中，透過⑽膜後的該些溶質 已被減少的水可被當作淡水（透過水）18獲得；該些溶 質為無法透過R〇膜且已被濃縮的水則被當作礦物鹽水（ 非透過水）19獲得。 100118057 表單編號A0101 第頁/共21頁 1003276649-0 201247553 [0043] [0044] ❸ [0045] Ο [0046] 其次’針對獲得礦泉水208及鹽水209的方法進行說明。 將原水置入電透析裝置203而生成，其中，含有多量已被 稀釋化的礦物質的製品係為礦泉水2〇8 ;而濃縮侧的製品 則為鹽水209。 上述電透析裝置203是由以離子交換膜分段的空間所構成 ’離子交換膜則是將選擇性僅使陽離子透過的陽離子膜 ’以及選擇性僅使陰離子透過的陰離子膜交互地組裝著 。於本發明中，從通過電透析裝置2〇3的海水等，將鈉離 子亦或氣離子等盡量脫鹽，並盡可能地不脫鹽而大量殘 存著鉀、鈣、鎂等有用的礦物成分較佳。但是，不令鉀 、鈣、鎂等所須金屬離子透過而使其殘留下來的陽離子 臈’係不存在。於此，係使用一價離子選擇性膜作為陽 離子膜。藉此，從海水等’將鈉、鉀、氣離子等一價離 子選擇性地去除；而二價以上的離子則不會被除去，原 本存在於原水中的二價以上的離子幾乎皆可殘留下來。 就於電透析裝置203中所使用的相關一價離子選擇性膜而 言，例如’可舉（株式會社）ASTOM社製的產品型號k-192為例。此外，就陰離子交換膜（負離子膜）而言，雖 可使用任意薄膜，但具體來說，例如，可舉（株式會社 )ASTOM社製的產品型號A —501為例。 電透析裝置203，經適度地調整脫鹽利用率，進而可依照 所須，加以調整脫一價離子化水207中的礦物質》 而且，可以不經像上述般的步驟，而可獲得一模一樣的 原水21。像這樣所得到的各種類的水，可暫時地貯存於 100118057 表單編號A0101 第11頁/共21頁 1003276649-0 [0047] 201247553 給水槽39内，因應須要而可設計為藉由給水幫浦39a而朝 各別的給水站28送出’當於無法自給水站28取出之時， 可使其加以循環’進而可設計為藉由UV殺菌裴置29進行 定期的殺菌。 [0048] 這些各種水之中’特別是包含多量礦物成分的礦泉水208 與礦物鹽水19 (以下’稱海洋深層礦泉水20)係，可如 第1圖、第2圖所示執行濃縮。 [0049] 如第1圖所示，於混合機32中，相對於海洋深層礦泉水2〇 ，10,000. 00 (kg)，將當作胺基酸的甘胺酸3〇,以 70. 0〇 ( kg)的比例進行添加’並如上所述，於55。〇下 混合，藉由循環式減壓濃縮機33以80〇L/H的蒸發量使其 乾燥加以濃縮。於濃縮中，液溫則會上升至60〜7(TC為 止。 [0050] 當最終的液量變少，無法以循環式減壓濃縮機33進行濃 縮時，再藉由1 000L減壓濃縮機34進行最後階段的濃縮。 之後，將藉由以這些乾燥機使其乾燥，進而使之濃縮的 生成物，於85°C、進行10分鐘殺菌•過熱•攪:拌，並使 用60網目的篩子過篩，除去異物，而獲得濃縮礦泉水22 〇 [0051] 像這樣所獲得的濃縮礦泉水22，除了是照原本的狀態包 含著海洋深層礦泉水20的成分，不僅如此，亦是不會將 礦物質中，特別是將屬於對人體有用的成分的鎂（Mg) 亦或鈣（Ca)等變成沉澱物而有所損失而包含著的水。 [0052] 甘胺酸擁有最為簡單的構造，且為分子量原本就小的胺 100118057 表單編號A0101 第12頁/共21頁 201247553 [0053] Ο [0054] Ο 基酸，為最適宜的胺蓁酸，但就替代上述甘胺酸的胺基 酸而言，亦可使用綠草胺酸、白胺酸、異白胺酸、丙胺 酸、精胺酸、麩醯胺、賴胺酸、天冬醯胺酸 '麩醯胺酸 、脯胺酸、半胱胺據、息寧胺酸、曱硫胺酸 '組胺酸、 苯丙胺酸、祕酸、色胺酸、天冬酿胺、甘胺酸、絲胺 酸等。 礦物鹽水19的情Ί ’貞】如第2®所示’於展合機32中’相 對於礦物鹽水19 , 〇〇〇· 〇〇 (kg)，將當作胺基酸的甘 胺酸30，以100. 〇0 (kg)的比例進行添加，並如上所述 ，於55。(：下混合，藉由循環式減壓濃縮機33以800L/H 的蒸發量使其㈣〆n於濃縮中，液溫則會上升 至60〜70°C為止。 當最終的液量變少，無法以循環式減壓漢縮機33進行濃 縮時，再藉由1〇〇〇1>滅壓浪縮機34進行最後階段的濃縮。 之後，將藉由以這毖乾燥機使其乾燥，進而使之濃縮的 生成物，於85T：、進行1〇分鐘殺菌•過熱•攪拌，並使 用60網目的篩子過篩，除去異物’而獲得濃縮礦物鹽水 22 /。 [0055] 此外，進一步進行粉末化的情況，相對於上述海洋深層 礦泉水20，10,〇〇0.0〇(1^)，將當作胺基酸的甘胺酸 30，以70. 00 (kg)的比例進行添加的混合物中，將澱 粉糖漿或還原澱粉楗漿31 (就還原澱粉糖漿而言 ，可使 用商品名PO-10最為適宜）’以1 60.00 (kg)的比例進 行添加，並如上所述，於55 C下混合，藉由以循環式減 壓濃縮機33及1 000L減壓濃縮機34使其乾燥 100118057In order to achieve the above object, the mineral water of the present invention is, for example, contained in mineral water containing at least money or a financial component, and the amino acid is concentrated; second, relative to the mineral water. Mineral 扪 Mo ear, is added to 〇.1 mol or more of silk acid; third, silk acid material glycine acid, etc. is the invention of the gist. 寻 [0026] [0027] In addition, the fourth, at least contains magnesium or calcium Any ocean ice water is the invention of the gist. The mineral water system of the ingredient is the same as the powder of mineral water, which is based on at least one of the mineral waters of the component, adding amino acid and (4) syrup or _ starch "'"发明 A known method is to dry it and pulverize it to obtain the invention. [0028] 100118057 According to the scope of the patent application! The invention as defined in the item, Form No. Α0101, Page 7 of 21, is formed by the metal ions of the mineral water and the amino acid in the mineral water, and the metal ion is formed by the amino acid. The molecules are trapped between the chelate rings, and even if they are dried after concentration, they do not form insoluble precipitates due to sulfate ions in the mineral water, and can be concentrated under the original uniform component state. The above-mentioned effect, in addition to the above-mentioned effects, in addition to the minerals contained in the mineral water 1 mole, adding more than 0.1 mole of amino acid, The danger of creating a sinking property due to subsequent enrichment can be fully avoided. [0030] Further, in the case of an amino acid, it is possible to use humative, leucine, isoleucine, alanine, arginine, glutamine, lysine, aspartic acid, Gluten, valine, cysteine, cyanoic acid, guanidine, histidine, phenylalanine, tyrosine, tryptophan, aspartame, glycine, silk Any of the acids, but according to the invention as defined in the third aspect of the patent application, the glycine acid having the simplest structure and having the smallest molecular weight is most suitable in terms of molecular weight and molecular shape. [0031] According to the invention as defined in claim 4 of the patent application, once concentrated by drying, a weak point of the ocean deep water which overcomes the so-called precipitate which is liable to generate insoluble precipitates due to minerals and sulfate ions can be obtained; On the other hand, it is possible to exhibit mineral water which has the advantages of a small number of bacteria and a large number of nutrients. [0032] According to the invention as defined in claim 5, the chelate compound is formed by the metal ion of the mineral in the mineral water and the amino acid, by 100118057 Form No. A0101 Page 8 of 21 page 1003276649- 0 201247553 The metal ion enthalpy is trapped between the chelate rings by the amino acid molecule, and is dried after being concentrated, so that no insoluble precipitate is formed due to the sulfate ion in the mineral water. Therefore, even if the concentrated mineral water is dried by a spray dryer, there is no case where the nozzle in the dryer or the mineral inside the nozzle mist dryer is solidified and clogged, and the like can be maintained evenly. Powder in the state of ingredients. In addition, it can be formed into a perfect powder form due to the added powdered syrup or the reduction of the powdered sugar. <Effects of the Invention> [0034] As described above, the mineral water contained in the mineral water and the powder thereof according to the present invention, not only do not form an insoluble matter in the mineral water, but also (4) Concentration and pulverization were carried out in the component state of the present. [Embodiment] The embodiment of the present invention will be described in detail below. Fig. 1 is a view showing a manufacturing step of the first embodiment of the mineral water and the powder of the present invention. Fig. 2 is a view showing a manufacturing step of the second embodiment, wherein C) the first BI is a deep ocean mineral water. In the case of the case, the second picture shows the use of deep marine mineral brine. [0036] As shown in FIG. 1, the + port β is not used in the present invention as a deep ocean mineral water or a deep ocean layer which is used as a mineral water containing at least a magnesium or calcium (including both cases). In the mineral brine, an amino acid was added and mixed at 55 ° C and concentrated by a concentrator (solid form ratio of 25%). _ w obtained from the silk (4) spring water, the (four) water, ocean deep mineral water, ocean deep mineral brine, salt water method is shown in the 3 100118057 Form No. A0101 Page 9 / 21 pages 1003276649-0 201247553 [ [0040] [0042] [0042] In the figure. As shown in Fig. 3, the deep ocean water 26 is passed through the water discharge pipe 36, and is sucked up by the water receiving pump 37a of the water pumping chamber 37, and is sent to the secondary liquid storage tank 38, and the water is treated as treated. The water is further transported to the respective processing lines by the water supply pump 38a. Depending on the treatment, a plurality of types of water such as raw water 21, mineral water 208, brine 209, fresh water 18, and mineral brine 19 can be obtained. First, when the method of obtaining the fresh water 18 and the mineral salt water 19 is described, the (eight) membrane separation device 13 having a reverse osmosis membrane (hereinafter referred to as a rib membrane) is provided. In the RO membrane separation device 13, for example, a cellulose acetate membrane or a synthetic molecular ruthenium (polyethylene, bridged amine, or occluded polyamine) can be used as the RQ membrane. Further, the film may be of various types such as a hollow wire type or a spiral type, and a film having a shape of a block is suitable. It is stored in the water supply tank 39, and is designed to be sent to the respective water supply stations 28 by the water supply MQ 39a. When it is not taken out of the water supply station 28, it is circulated, and can be designed to be The uv sterilizer 29 performs regular sterilization. The R 〇 film supplied to the R0 membrane separation device 13 is removed by separating the cold material such as salt in the water 17 by the membrane, and the water having the solute reduced by the (10) membrane can be regarded as fresh water. Obtained (through water) 18; the solute is water that is impermeable to the R 〇 membrane and has been concentrated as mineral brine (non-permeable to water) 19. 100118057 Form No. A0101 Page 21 of 21 1003276649-0 201247553 [0044] [0046] Next, a method for obtaining mineral water 208 and brine 209 will be described. The raw water is placed in the electrodialysis unit 203, wherein the product containing a large amount of minerals which have been diluted is mineral water 2〇8; and the product on the concentrated side is brine 209. The electrodialysis device 203 is composed of a space segmented by an ion exchange membrane. The ion exchange membrane is a cationic membrane that selectively transmits only cations and an anion membrane that selectively transmits only anions. In the present invention, sodium ions or gas ions are desalted as much as possible from seawater or the like which passes through the electrodialysis apparatus 2〇3, and as much as possible, no salt is removed, and a large amount of useful mineral components such as potassium, calcium, magnesium, etc. remain. . However, the cation 臈' which does not allow the metal ions such as potassium, calcium, magnesium, etc. to pass through, does not exist. Here, a monovalent ion selective membrane is used as the cation membrane. Thereby, monovalent ions such as sodium, potassium, and gas ions are selectively removed from seawater or the like; and ions of two or more valences are not removed, and almost all of the divalent or higher ions originally present in the raw water remain. Come down. For example, the product type k-192 manufactured by ASTOM Co., Ltd. is exemplified as the related monovalent ion selective membrane used in the electrodialysis apparatus 203. In addition, as for the anion exchange membrane (negative ion membrane), any film may be used. Specifically, for example, product model A-501 manufactured by ASTOM Co., Ltd. is used as an example. The electrodialysis device 203 adjusts the desalination utilization rate moderately, and further adjusts the minerals in the deionized ionized water 207 as needed. Further, the same raw water can be obtained without the above steps. twenty one. The various types of water obtained in this way can be temporarily stored in 100118057 Form No. A0101 Page 11 / Total 21 Page 1003276649-0 [0047] 201247553 In the sink 39, it can be designed to be supplied by the water supply pump 39a according to the need. The respective water supply stations 28 are sent 'when they cannot be taken out of the water station 28, they can be circulated' and can be designed to be periodically sterilized by the UV sterilizing device 29. [0048] Among these various waters, in particular, mineral water 208 containing a large amount of mineral components and mineral brine 19 (hereinafter referred to as "sea deep mineral water 20") can be concentrated as shown in Figs. 1 and 2 . [0049] As shown in Fig. 1, in the mixer 32, relative to the deep ocean mineral water 2 〇, 10,000. 00 (kg), will be treated as amino acid glycine 3 〇, to 70. 0 〇 The ratio of (kg) is added 'and as described above, at 55. The mixture was submerged and dried by a circulating vacuum concentrator 33 by evaporation at 80 Torr/H. During concentration, the liquid temperature rises to 60 to 7 (TC until [0050] When the final liquid amount is small and cannot be concentrated by the circulating vacuum concentrator 33, the pressure is further reduced by a 1 000 L vacuum concentrator 34. The final stage of concentration is carried out. After that, the product which is dried by these dryers and concentrated, is sterilized at 85 ° C for 10 minutes, overheated, stirred, mixed, and sieved using a 60 mesh sieve. Screening, removing foreign matter, and obtaining concentrated mineral water 22 〇 [0051] The concentrated mineral water 22 obtained in this way, in addition to the original state containing the components of the deep ocean mineral water 20, not only that, but also will not mine Among the substances, in particular, magnesium (Mg) or calcium (Ca) which is a component which is useful for the human body is a precipitate which is lost and contains water. [0052] Glycine has the simplest structure, and The amine is originally a small molecular weight 100118057 Form No. A0101 Page 12 of 21 201247553 [0053] Hydrazine acid, which is the most suitable amino acid, but replaces the amino acid of the above glycine It is also possible to use chlorinic acid, leucine, Amino acid, alanine, arginine, glutamine, lysine, aspartic acid, glutamic acid, valine, cysteamine, serotonin, sulphonic acid Amino acid, phenylalanine, secret acid, tryptophan, aspartame, glycine, serine, etc. The condition of mineral brine 19 '贞】 as shown in the second ® 'in the exhibition machine 32' Glycine 30, which is an amino acid, is added in a ratio of 100. 〇0 (kg) relative to mineral brine 19, 〇〇〇·〇〇 (kg), and as described above, at 55. : Under mixing, the circulating vacuum decompressor 33 is used to make (4) 〆n concentrated in the evaporation amount of 800 L/H, and the liquid temperature rises to 60 to 70 ° C. When the final liquid amount is small, it is impossible to When concentration is carried out by the circulation type reduced pressure reduction machine 33, the final stage of concentration is carried out by a 1〇〇〇1> pressure reduction machine 34. Thereafter, it is dried by the dryer, thereby The concentrated product was sterilized at 85T: for 1 minute, • overheated, stirred, and sieved using a 60 mesh sieve to remove foreign matter' to obtain concentrated mineral brine 22 / [0055] In addition, in the case of further pulverization, compared with the above-mentioned marine deep mineral water 20,10, 〇〇0.0〇(1^), the glycine acid 30 which is regarded as an amino acid is 70. 00 (kg). In the mixture to be added, starch syrup or reduced starch mash 31 (in the case of reduced starch syrup, commercially available under the trade name PO-10 is most suitable) is added in a ratio of 160.00 (kg), and as described above, The mixture was mixed at 55 C, and dried by a circulating vacuum concentrator 33 and a 1000 L vacuum concentrator 34.
表單編號A010I ，並將直到 第13頁/共21頁 1003276649-0 201247553 糖分濃度Bx = 25為止使之濃縮的生成物，於85°C、進行 10分鐘殺菌•過熱•攪拌，並使用6〇網目的篩子過篩， 除去異物後，進而藉由喷霧乾燥器35使其乾燥，再經使 用20網目的篩子過篩’使用磁路進行磁選。藉此，獲得 粉末礦泉水27。 [0056] 或者，相對於礦物鹽水丨9，5, 〇〇〇. 〇〇 (kg)，將當作胺 基酸的甘胺酸30，以loo. 〇〇 (kg)的比例進行添加的混 合物中’將殿粉糖漿或還原澱粉糖漿31 (就還原澱粉糖 漿而言，可使用商品名PO—1〇最為適宜），以115.〇〇( kg)的比例進行添加’並如上所述’於55°c下混合，藉 由以循環式減壓濃縮機33及l〇〇〇L減壓濃縮機34使其乾 燥，並使之濃縮的生成物，於85°c、進行1〇分鐘殺菌· 過熱•攪拌，並使用60網目的篩子過篩，除去異物後， 進而藉由喷霧乾燥器35使其乾燥，再經使用20網目的篩 子過篩，使用磁路進行磁選《藉此，獲得粉末礦物鹽水 27 ' [0057] 故於此際，依照上述，當濃縮礦泉水22或濃縮礦物鹽水 〇 22係照原本的狀態包含著鎂（Mg)亦或妈（Ca)等礦 物質的時候，礦物質不會成為沉澱物，因而可獲得照原 本的狀態含有礦物質的粉末礦泉水27、粉末礦物鹽水27 〇 [0058] 而且’因為此粉末礦泉水27或粉末礦物鹽水27 '係為已 將水分除去的製品，所以較輕，再者因為為固體所以容 易運輸。此外，此粉末礦表水27或粉末礦物鹽水27 ^對 於水來說，亦可良好地溶解於其中。 100118057 表單編號A0101 第14頁/共21頁 1003276649-0 201247553 [0059]此外，雖然省略圖示，但原水21亦同樣地可於至少包含 鎮或約巾任-成分之礦泉水内’ “胺級及澱粉糖槳 或還原殺粉糖漿，經濃縮後，藉由Μ乾㈣使其乾燥 而經粉末化所得。 [0_如此所獲得到的濃縮水或粉末，係可藉*複合至飲料、 叙末飲料、加工食品、豆腐凝固劑、皮膚外用劑水溶液 、植物成長調整劑或動物成長調整劑的原料中而加以利 用。 〇 [0061]海水，特別是在海洋深層水中，由於豐富地含有各種離 子，故原水或進行過各式各樣處理的海水，得以廣泛地 利用在食品、醫藥品、化妝品、農業、水產等各方面。 此外，近年來，藉由補給礦物成分而以增進健康、預防 生活習慣病為目的之健康飲料備受注目，就作為原料而 言，也很適宜。 【圖式簡單說明】 [0062]第1圖係表示本發明的第一實施型態的礦泉水及其粉末的 Ο 製造步驟的說明圖； 第2圖係表示本發明的第二實施型態的礦物鹽水及其粉末 的製造步驟的說明圖；以及 第3圖係從海洋深層水所獲得各種水的製造步驟的說明圖 【主要元件符號說明】 [0063] 11:被處理水； 12 :前處理裝置； 13 : RO膜分離裝置； 100118057 表單編號 Α0101 第 15 頁/共 21 頁 1003276649-0 201247553 14 :填充塔； 15 :螯合形成性纖維床； 16 :過濾水； 17 :水； 18 :淡水； 19 :礦物鹽水； 20 :海洋深層礦泉水； 21 .原水， 22 :濃縮礦泉水； 22 > :濃縮礦物鹽水； 26 :海洋深層水； 2 7 ·粉末礦泉水， 27 / :粉末礦物鹽水； 28 :給水站； 29 : UV殺菌裝置； 30 :甘胺酸； 31 :澱粉糖漿或還原澱粉糖漿； 32 :混合機； 33 :循環式減壓濃縮機； 34 : 1000L減壓濃縮機； 35 :喷霧乾燥器； 36 :取水管； 37 :取水幫浦室； 37a :取水幫浦； 38 : —次貯液槽； 38a :送水幫浦； 100118057 表單編號A0101 第16頁/共21頁 1003276649-0 201247553 39 :給水槽； 3 9 a :給水幫浦； 203 :電透析裝置； 207 :水； 208 :礦泉水；以及 209 :鹽水。Form No. A010I, and until 13th / 21st page 1003276649-0 201247553 Concentration of sugar concentration Bx = 25, the product is concentrated at 85 ° C for 10 minutes sterilization • Overheating • Stirring, and using 6〇网The sieve is sieved, and the foreign matter is removed, and then dried by a spray dryer 35, and then sieved using a 20 mesh sieve to perform magnetic separation using a magnetic circuit. Thereby, powdered mineral water 27 is obtained. [0056] Alternatively, a mixture of glycine acid 30, which is an amino acid, is added in a ratio of loo. 〇〇 (kg) relative to mineral brine 丨9,5, 〇〇〇.〇〇 (kg). 'In the case of the temple powder syrup or reduced starch syrup 31 (in the case of reduced starch syrup, the trade name PO-1 is most suitable), and added in the ratio of 115. 〇〇 (kg) and as described above The mixture was mixed at 55 ° C, and dried by a circulating vacuum concentrator 33 and a 减压L vacuum concentrator 34, and the resulting product was concentrated and sterilized at 85 ° C for 1 minute. Overheating, stirring, and sieving using a 60 mesh sieve to remove foreign matter, and then drying it by a spray dryer 35, and then sieving through a sieve of 20 mesh, using a magnetic circuit for magnetic separation. Mineral salt water 27 ' [0057] Therefore, according to the above, when the concentrated mineral water 22 or the concentrated mineral salt water 22 is originally contained in the state containing magnesium (Mg) or mother (Ca) and other minerals, the mine The substance does not become a precipitate, so that the mineral water containing the mineral in the original state can be obtained 27 Mineral salt powder 27 billion [0058] and '27 because the mineral powder or mineral powder saline 27' was based article has the moisture removed, so that light, it is furthermore easy because of the solid transport. Further, this powdered mineral surface water 27 or powdered mineral salt water 27 is also well dissolved in water for water. 100118057 Form No. A0101 Page 14 of 21 1003276649-0 201247553 [0059] Further, although not shown in the drawings, the raw water 21 can also be similarly contained in mineral water containing at least a town or a towel. And the starch syrup or the reduced sucrose syrup, which is concentrated and dried by mashing (4) to be pulverized. [0_ The concentrated water or powder thus obtained can be compounded to the beverage, It is used as a raw material for the final beverage, processed food, tofu coagulant, aqueous solution for skin external application, plant growth regulator or animal growth regulator. 〇 [0061] Seawater, especially in deep ocean water, contains abundant ions. Therefore, raw water or seawater that has been treated in various ways can be widely used in food, pharmaceuticals, cosmetics, agriculture, aquatic products, etc. In addition, in recent years, it has been used to improve health and prevent life by replenishing mineral components. A health drink for the purpose of habitual disease is attracting attention, and it is also suitable as a raw material. [Simplified illustration] [0062] Fig. 1 shows a first embodiment of the present invention FIG. 2 is an explanatory view showing a manufacturing step of the mineral water and the powder of the second embodiment of the present invention; and FIG. 3 is an explanatory view showing the manufacturing steps of the mineral salt water and the powder thereof according to the second embodiment of the present invention; Explanation of manufacturing steps of various waters obtained [Explanation of main component symbols] [0063] 11: treated water; 12: pretreatment device; 13: RO membrane separation device; 100118057 Form No. 1010101 Page 15 of 21 1003276649 -0 201247553 14 : packed tower; 15 : chelated forming fiber bed; 16 : filtered water; 17 : water; 18 : fresh water; 19 : mineral brine; 20 : deep ocean mineral water; 21 ; raw water, 22 : concentrated mineral water Water; 22 >: concentrated mineral brine; 26: deep ocean water; 2 7 · powdered mineral water, 27 /: powdered mineral brine; 28: water supply station; 29: UV sterilization device; 30: glycine; 31: starch Syrup or reduced starch syrup; 32: mixer; 33: circulating vacuum concentrator; 34: 1000L vacuum concentrator; 35: spray dryer; 36: water pipe; 37: water pump room; 37a: water Pump; 38: - secondary reservoir; 38 a : water supply pump; 100118057 form number A0101 page 16 / 21 page 1003276649-0 201247553 39 : water supply tank; 3 9 a: water supply pump; 203: electric dialysis device; 207: water; 208: mineral water; 209: brine.
DD
100118057 表單編號A0101 第17頁/共21頁 1003276649-0100118057 Form No. A0101 Page 17 of 21 1003276649-0