TW201245131A - Colored resin composition, color filter, liquid crystal display device, organic el display device - Google Patents

Abstract

The purpose of the invention is to provide a display having high image quality; to provide a colored resin composition with which it is possible to prevent a reduction in image quality of the display; and to provide a color filter having excellent pixel color purity and transmittance, as well as a high-quality liquid crystal display device and an organic EL display device, by using such a colored resin composition. The invention relates to a colored resin composition comprising (A) a dye, (B) a solvent, (C) a binder resin, and (D) a chain transfer agent that contains a specific compound.

Description

201245131 SUMMARY OF THE INVENTION [Technical Field] The present invention relates to a coloring resin composition, a color light-emitting sheet, a liquid crystal display device, and an organic EL display device. [Prior Art] In recent years, as a flat panel display, a color _ ‘ 芭 夜 夜 显 显 、 or an organic EL (EleCtr〇l UminescenCe, electroluminescence) display has attracted attention to the use of color filters in such displays. / For example, as an example of a color liquid crystal display device, there is a pure light including a black matrix, a color layer including a plurality of colors (usually red (R), green (G), and blue (8) 3 primary colors), a transparent electrode, and an alignment layer. The sheet substrate is provided with a thin film transistor (TFTX Thin-Fihn T-plane is), a pixel electrode, and an alignment sound electrode substrate, and the two substrates are sealed with a predetermined gap therebetween, and the sealing member is sealed. The liquid crystal layer formed by injecting a liquid crystal material into the gap is a transparent liquid crystal display dream A ^ 罝. Further, a reflective (four) reflective type display device is provided between the substrate and the coloring layer of the color H sheet. Regarding color filters, color purity, chroma, and light penetration are required. In order to increase the amount of the lens, the image formation is reduced. The content of the coloring pigment relative to the photosensitive resin, or formed by the image forming material. A method of thinning a pixel or the like. However, in these methods, the chroma of the color filter itself is lowered, and the result is 10110090 3 201245131. The overall display is whitish, and the problem of the vividness of the color necessary for display is lacking. On the other hand, if the coloring pigment content is increased in preference to the chroma, the entire display is darkened. In this case, in order to secure the brightness, it is necessary to increase the amount of light of the backlight, which causes a problem that the power consumption of the display increases. Further, in order to increase the amount of light penetration, a method of slightly dispersing the particle diameter of the pigment particles to 1/2 or less of the color wavelength of the pigment is known (Non-patent document), but the method needs to be further compared with the prior art. Micro-dispersion, cost increase and stability after dispersion become problems. On the other hand, the development of color filters using dyes as color materials is also being promoted. For example, as a colored resin composition for forming a blue pixel, Patent Document 1 discloses that CI red acid blue 83 (triallylamine anthraquinone) and CI solvent blue 67 (copper phthalocyanine dye) are provided. The blue color filter of the light layer. Further, as a colored resin composition for green pixel formation, Patent Document 2 discloses that a colored resin composition containing a zinc phthalocyanine pigment and a yellow dye is used when a green pixel is formed. [Prior Art Document] [Patent Document] Patent Document 1: Japanese Patent Laid-Open Publication No. 2002-14222 Patent Document 2: Japanese Patent Laid-Open Publication No. 2010-168531 [Non-Patent Document] 101110090 4 201245131 literation and publication of jJSJWU / [Summary of the Invention] 1 'Month (four) meeting" (1967 (invented by the invention) However, in the patent document, the fat composition of the ▲ color pixel is used for the coloring of the tree, and the (4) 4 white is lacking. The necessary color is not sufficient in the image quality reduction of the patent document. In the composition, the plain color is cut into the shape of the color. The present invention is complicated by the above-mentioned correction; ^ is sufficient. The high image quality of the two t supply;: the color, resin composition of the species, the formation and the quality of the image is reduced. The color of the benefit of the image is based on the use of such a coloring resin composition, providing a kind of pixel ^ pure ambiguity rate "Color, material = display device and organic pull display device. Night" (means for solving problems) The moon and other people conducted intensive research and found that in the case of the situation, dry crying + country you are using the button pixel " Reason for lowering - in The hardening is not sufficient, and the solvent resistance of the pixel is the solvent resistance of the pixel, which indicates the difficulty in eluting the eight materials (pigments or dyes) in the formed pixel. That is, it is presumed that if the image is not sufficient, such as the alignment film or the outer coating, the "coated shape" in the pixel is used to form the dissolved solution of the '% 101110090 201245131. The reason is that the image quality of the display is degraded. The result is that the color-resistant material (4) is easy to fall, and the reason is that the solvent-resistant ship is easy to fall. In the case of a dye, even if the photopolymerization initiator receives light energy 激发 in an excited state during exposure, due to contact with _, green compositing starts to move energy to the dye before generating radicals, photopolymerization initiator Some of them fail to function as a radical generating agent. It is presumed that the reason for causing the above phenomenon in the case of using a dye is that the blood color = the pigment phase tb accumulated in the colored resin composition, and the dye which exists almost in a single molecule state The probability of contact with the polymerization starter is greater. That is, the pigment phase is inclusive of the purely emotional relationship, and the growth is greater in the case of containing the dye than in the case of using the pigment. The free radical generating function of the initiator does not function sufficiently, resulting in a decrease in the solubility of the acid, and the pixel formation becomes insufficient according to the situation. The person pays the above-mentioned insights as a step-by-step study, and as a result, it is found that by making the package = The present invention can be solved by the compound containing a compound in the colored resin composition. The present invention relates to the following colored resin composition, color aerial film, liquid helium, liquid non-device, and organic EL display. (1) A colored resin composition comprising (A) a dye (8) solvent, (c) a binder resin, and (D) a chain transfer agent, and the above (9) chain transfer agent comprises the following formula 1〇1110090 201245131 (i) The compound represented (hereinafter referred to as "compound (i)"). IL Jp p(1) (In the above formula (I), p represents an integer of 2 to 4; • Ral represents a hydrogen atom, or an alkyl group which may have a substituent; • X represents a direct bond, a 2 to 4 carbon An atom, a 2 to 4 valent heterocyclic group or a 2 to 4 valent aromatic ring group. Further, a plurality of structures represented by the following formula (Γ) contained in one molecule [Chemical 2]

Can be the same or different). [2] The colored resin composition according to the above [1], wherein the content of the (D) chain transfer agent is 2% by weight or more and 10% by weight or less based on the total solid content. [3] The colored resin composition according to the above [1] or [2] wherein the dye is a triaryldecane dye. [4] The colored resin composition according to any one of the above [1] to [3] further comprising (E) a polymerizable monomer. [5] The colored resin composition according to the above [4], wherein the (E) polymerizable monomer is a compound having an ethylenically unsaturated double bond. The colored resin composition according to any one of the above-mentioned items, which further comprises at least one of (F) a photopolymerization starting component and a thermal polymerization starting component. [7] A color filter comprising a pixel formed using the colored resin composition according to any one of [6] to [6] above. [8] A liquid crystal display device comprising the color light-passing sheet of [7] above. [9] An organic EL display device having the color filter 0 of the above [7] (Effect of the Invention) By using the colored resin composition of the present invention, excellent pixel formation and developability can be formed, and solvent resistance can be obtained. High pixel. Therefore, the liquid crystal display device including the pixel formed using the colored resin composition of the present invention has high image quality. Moreover, by obtaining a color filter excellent in color purity and transparency of a pixel, the color filter can be used, whereby the backlight of the color light-passing sheet can be efficiently extracted, thereby providing a high color. Reproducible and high-brightness liquid crystal display, device or organic EL display device. [Embodiment] Hereinafter, embodiments of the present invention will be described in detail, and the following description is an example of an embodiment of the present invention. The present invention is not limited to the above. Here, in the present specification, "% by mass" and "weight by mass" and "weight of PPm", and "parts by mass" and "parts by weight, respectively = the same meaning. Again, in the case of PPm In the present invention, ''heavy® 101110090 8 201245131 ppm' 本' in the present invention ''(曱基)acrylic acid', '(曱基)acrylic acid 」 」 A" 曰 I I and/or 曱"Acrylic acid", "acrylic acid g and/or methyl acrylate vinegar", etc., such as "(mercapto)acrylic acid" means "propionic acid and/or mercaptopropionic acid". Further, it is referred to as "all solid parts", meaning "environmental light other than the following solvent components"; all components of the colored resin composition. Further, the term "aromatic ring" means both "aromatic hydrocarbon ring" and "aromatic heterocyclic ring". The colored resin composition of the present invention comprises (4) a dye, (8) a solvent, (a bismuth-bonding resin, and (9) a chain transfer agent, (9) a chain transfer agent containing a compound (1), preferably a ruthenium-containing (synaptic monomer, (7) integration_ The starting component of the nucleus and/or the hot condensate, and further contains other components to be blended as needed. First, the (D) chain transfer agent contained in the colored resin composition of the present invention will be described. [(D) Chain transfer agent] The (D) chain transfer agent of the present invention is a compound having a function of accepting the generated radical and transferring the radical to another compound. The present colored composition of the resin contains the following formula (I) The compound represented by (D) is a chain transfer agent. [Chemical 3] 101110090 201245131 X--C2—C2—OC-C2—CR*1 ° 5H p (i) (In the above formula (I), p represents 2 An integer of ~4;

Ral represents a hydrogen atom or an alkyl group which may have a substituent; X represents a direct bond, a 2 to 4 carbon atom, a 2 to 4 valent heterocyclic group or a 2 to 4 valent aromatic ring group. Further, a plurality of structures represented by the following formula (Γ) included in one molecule may be the same or different as the structure represented by the following formula (Chemical Formula 4) 0-C-II II 〇 1 SH ” (I,). (About Ral)

Ral represents a hydrogen atom or an alkyl group which may have a substituent. As the above alkyl group, the carbon number is usually from 1 to 8, more preferably from 1 or 2. Ral is preferably a hydrogen atom in terms of high reactivity of the compound and high surface hardenability of the obtained film. Further, the substituent which the alkyl group in Ral has may be, for example, those described in the following (Substituent Group W1). (Substituent group W1) An atom, a gas atom, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, a phenyl group, a 2,4,6-trimethylphenyl group, an anthracenylphenyl group, and a naphthyl group. , cyano group, acetoxy group, 101110090 10 201245131 alkyl carboxyl group having 2 to 9 carbon atoms, sulfonium sulfonate group, sulfoalkylguanidinyl group having 2 to 9 carbon atoms, alkyl group having 2 to 9 carbon atoms a carbonyl group, a phenethyl group, a hydroxyethyl group, an acetamethylene group, a dialkylamino group, a trimethyl group, a carbon number of 1 to 8 and a trialkyl group bonded by a carbon number of 1 to 4; An alkylthio group having an alkyl group, a nitro group and a carbon number of 1 to 8. (About X) In the formula (1), X represents a direct bond, a 2 to 4 carbon atom, a 2 to 4 valent heterocyclic group or a 2 to 4 valent aromatic ring group. Further, the case where X is a carbon atom of 2 to 4 grades means that X is a structure of any of the following. _______ η2 η Examples of the aromatic ring group in X include an aromatic hydrocarbon ring group and an aromatic heterocyclic group. The aromatic hydrocarbon ring group may be a monocyclic ring or a condensed ring, and is not particularly limited as long as the number of carbon atoms forming the ring is 5 to 18, and examples thereof include a benzene ring having 2 to 4 free valencies and a naphthalene ring. , anthracene ring, phenanthrene ring, anthracene ring, fused tetraphenyl ring, anthracene ring, benzofluorene ring, cave ring, extended triphenyl ring, anthracene ring, fluoranthene ring, anthracene ring and the like. Furthermore, the free price in the present invention is based on "Organic Chemistry - Biochemical Nomenclature" (Nanjiang Hall, issued on May 20, 1992, Hirayama Kenzo, 101110090 11 201245131 Hirayama Kazuo, pp. u~12 Recorded by). Further, the aromatic heterocyclic group may be a monocyclic ring or a polycondensed ring having a carbon number of 3 to 1 Å, and is not particularly limited, and may be a ring or a benzopyrene ring. The cockering ring and benzo-V 4 can be exemplified by: husband. South ν signed knives, 〇 咯 咯 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾. Mazole ^, D than ring, benzoiso (tetra) ring, benzopyrene ring 1 ☆ I and different % compared to the ring, three rings, 啥 环 ring, 嗤 嗤 ring, beer: well ring, Talbot, A pyridine ring, a stupid ring, a ring, a ring, and the like. Gendosporin 4, porphyrin ring, and on the other hand 'as a heterocyclic group (ie, non-aromatic may be a condensed ring. , a base), may be a monocyclic ring and a heterocyclic group containing a nitrogen atom, a rhyme and oxygen A non-aromatic ring of the original atom. The same as the heterocyclic group having a plurality of constituent rings may be different. In the case of clearing, these can be used together, and examples thereof include sulfhydryl groups, ketone groups, iso- and benzo-xazosyl groups, 4 dimethylimine groups, mother bites, and bismuth. The soil is a 2~4 grade rhyme for the soil with good preservation stability of the compound (1), and the core is a surface. Further, the carbon atom, the heterocyclic group and the aromatic ring group in 'X may have the following formula 101110090 201245131 (r) (hereinafter referred to as "the structure containing a p-aminophenylsulfonyl group") The substituent is, as the substituent, the one described in the above item (Substituent group w1). [化6] 广 · —_c—》一 g—Re1

II I L 〇 SH (I*) • (About p) p represents an integer from 2 to 4. In the compound (I), p is particularly preferably 4, because the reactivity of the compound is increased as the reaction site is increased, and the curability of the obtained pixel is sufficient. Specific examples of the compound (I) in the present invention are shown below, but the present invention is not limited thereto. _ [Specific Example of Compound (I)] A compound having two structures containing p-aminobenzenesulfonyl group: 1,2-ethanedithiol, 1,3-propanedithiol, 1,4- Butanedithiol, 2,3-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,8-octanedithiol, 1,9-nonanedithiol, 2,3-dimercapto-1-propanol, dithioerythritol, 1,2-benzenedithiol, 1,2-benzenedithiol, 1,3-benzenedithiol, 3, 4-Dimercaptopurine, 4-chloro-1,3-benzenedithiol, 2-hexylamino-4,6-dimercapto-1,3,5-tri. Well, 2-diethylamino-4,6-dimercapto-1,3,5-trisyl, 2-cyclohexylamino-4,6-dimercapto-1,3,5-three , B2101110090 13 201245131 Alcohol bis(3-mercaptopropionate), 2,5-dimercapto-indenyl thiadiazole, 2,2-bis(2-pyridyl-3-sulfopropoxy) a compound having three structures containing p-aminophenylsulfonyl group, such as trishydroxypropyl propane ginseng (3-diylpropionic acid brewing), trimethyl ketone tris-glycolic acid g |, u, 6_ hexanetriol tris-glycolic acid §, etc., a compound of the structure of octa3, 3, and oxasulfonyl amide: quaternary glycolic acid vinegar, pentaerythritol hydrazine (3 benzyl vinegar). Among the above, it is particularly preferred to be pentaerythritol oxime (3-sulfopropyl (tetra)). (Regarding the content) The content of the (D) chain transfer agent in the month of the month is usually 2% by weight or more, preferably 4% by weight or more, and more preferably 6% by weight or more in the solid portion of the colored resin composition. , a difficult 7 is 10% by weight or less, preferably 9% by weight from: more preferably 8.5% by weight or less. Easy ===: It is preferable that the obtained pixel has sufficient hardenability and is not required to be removed. In the above range, the content of the (〇) chain transfer agent is in the above, fr· is only the compound (1) as the (9) chain transfer agent, and preferably A is contained in the upper side. The reason why the effect of the liquid crystal display obtained by the suppression of the liquid crystal display of the device is reduced by the configuration of the present invention is as follows. The reason why the image quality of the liquid crystal display is lowered is as described above, and the solvent-resistant ship of the obtained pixel is not sufficient. In the case of improving the hardenability of the pixel, it is necessary to sufficiently function the adhesive layer polymerizable Wei component contained in the colored resin composition. The fact that the polymerizable curable component sufficiently functions means that polymerization is caused in a wide range of pixels. In the case of the photopolymerization system, for example, polymerization is generated only in a region very close to the photopolymerization initiator, and the resulting freedom is not so good that it is difficult to set up a wide range of polymerization. Hardening is obtained to the extent that the pixel is solvent resistant. Here, in the present invention, by the inclusion of the radicals produced by the above formula (1), the radicals generated by the above formula (I) are catalyzed in a wide range, and as a result, the polymerization reaction is made easier. The degree of solvent resistance of the oblique pixel can suppress the liquid crystal display to a low level of 0 廑. The image density can be extended to a sufficient image quality [(A) Dye] The dye of the present invention is not particularly limited as long as the effect of the present invention is not impaired, and for example, an even gas dye or hydrazine is preferably exemplified. g Kunming dye-limited phthalocyanine 101110090 201245131 Dyes, quinone imine dyes, porphyrin dyes, nitro dyes, Yiji dyes, methine dyes, cyanine dyes, triaryl decane dyes, etc. . Examples of the azo dye include c丄 acid yellow u, C I. acid orange 7, CI acid red 37, CI acid red 180, cj acid blue 29, c丄 direct red 28, CI direct red 83, CI. Direct Yellow 12, CI Direct Orange 26, CI Direct Green 28, CI Direct Green 59, c丄 Reactive Yellow 2, c丄 Reactive Red 17, CI Reactive Red 120, CI•Reactive Black 5, CI•Disperse Orange $, CI Disperse Red 58, CI Disperse Blue 165, c』Experimental Blue 4 Buc> Authentic Red 18, CI Medium Red 7, CI. Medium Yellow 5, c丨 Medium Black 7, etc. Examples of the lanthanoid dyes include c丄Reducing Blue 4, ci•Acid Blue 40, CI Acid Green 25, CI Reactive Blue 19, cj Reactive Blue 49, c丄Disperse Red 60, and CI Disperse Blue 56. Cj disperses blue 6〇 and so on. Further, as the phthalocyanine dye, for example, it can be mentioned. Examples of the quinone imine dyes include, for example, c blue blue, c i. blue, and the like. Examples of the phthalocyanine dye include C I. Solvent Yellow 33. Ci, acid κ 3, CI disperse yellow 64, etc., as a wall-based dye, for example, CI·Acid Yellow Bu CI Acid Orange 3, c】Disperse Yellow 42 and the like. The 'best dye' varies depending on the desired pixel color. In the case of f-blue pixels, the tongue is preferably a triaryl-based dye and a cyanine dye, and particularly preferably a triarylmethane dye. Further, in the case where the effect of the present invention is more easily obtained, the case of the triaryl 101110090 201245131 decane-based dye is preferred. Further, in the case of forming a red pixel or a green pixel, if a yellow dye is used as the complementary color, it is easy to obtain the effect of the present invention favorably, and an azo yellow dye is particularly preferable. First, a dye which can be preferably used in the coloring resin composition for forming a blue pixel, that is, a triaryl decane-based dye and a cyanine dye, will be described in detail. [Triaryl decane dye] (triaryl decane dye: compound represented by formula (II)) As a triaryl decane dye, it is excellent in heat resistance, and the obtained pixel is especially blue purity. In addition, it is a compound represented by the following formula (II) (hereinafter referred to as "compound (II)"). [Chemistry 7]

(In the above formula (II), Zml· represents a valence anion. ml represents an integer of 1 to 4. R1 to R6 each independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms which may have a substituent, or may have The aromatic ring group of the substituent. R1 to 101110090 17 201245131 R6 may be bonded to each other to form a ring. Further, the ring may have a substituent. R7 and R8 represent a hydrogen atom or an arbitrary substituent. R7 and R8 may be used. Further, the benzene ring of the above formula (II) may have any substituent. Further, a plurality of compounds are contained in one molecule.

In the case of the same, the configurations may be the same or different configurations. (About R1 to R6) Each of R1 to R6 independently represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms which may have a substituent, or an aromatic ring group which may have a substituent. Examples of the alkyl group in R1 to R6 include a linear, branched or cyclic alkyl group, and the carbon number thereof is usually 1 or more, and usually 8 or less, preferably 5 or less. Specific examples thereof include a methyl group, an ethyl group, a n-propyl group, a 2-propyl group, a n-butyl group, an isobutyl group, a tert-butyl group, and a cyclohexyl group. Examples of the aromatic ring in R1 to R6 include an aromatic hydrocarbon ring and an aromatic hetero ring. 101110090 18 201245131 The aromatic hydrocarbon ring group may be a monocyclic ring or a condensed ring, and is not particularly limited as long as the number of carbon atoms forming the ring is 5 to 18, and examples thereof include a benzene ring having one free valence and naphthalene. Ring, anthracene ring, phenanthrene ring, garland, slightly tetraphenyl ring, ring, benzofluorene ring, ring ring, extended triphenyl ring, anthracene ring, fluoranthene ring, i ring and the like. Further, the aromatic heterocyclic group may be a monocyclic ring or a condensed ring, and is not particularly limited as long as the number of carbon atoms forming the ring is from 3 to 10, and examples thereof include a sigma ring having one free valence. Benzo-α-amyl ring. The thiophene ring, the benzoxe ring, the ° ratio ring, the α ratio α ring, the ° meter σ ring, the σ number two 11 ring, the bud ring, the taste π ring, the η ratio σ 0 m D ring, '^ ratio ρ and ° ratio σ ring, α ratio 并 and α than 咯 ring, α 塞 并 ° ° 17 each ring, D phenophene. The thiophene ring and furan. Pyrrole ring, furan oxime ring, ° phenanthrofuran ring, benzopyrene ring, benzoisoindole α ring, benzopyrene ring, ° bite ring, α ratio D well ring , tower talk ring, D dense bite ring, three talk ring, 喧. Lin Huan, Yi Qi Lin Ring, Jin Lin Ring, 啥σ and other Lin Huan, brown bite ring, benzo flavor. Ring, bite ring, 啥 琳 环 ring, • σ quetalone ring, ring ring and other base. - Adjacent R1 to R6 may be bonded to each other to form a ring, and thus the ring may have a substituent. In the case where adjacent R1 to R6 are bonded to each other to form a ring, these may be rings which are crosslinked by using a hetero atom. Specific examples of the ring include the following. The rings may have a substituent. 101110090 19 201245131 In terms of chemical stability, as ri~r6, it is preferred that each of them is a hydrogen atom, a carbon number of 可~8 which may have a substituent, or a benzene which may have a substituent The base or the adjacent R1 to R6 are bonded to each other (4), and the carbon number of the substituent is more preferable in terms of improving the heat resistance of the dye and the light resistance of the obtained color filter. The base of the group 8 or a stupid group which may have a substituent. When R to R6 are a group of a carbon number which can have a substituent, it is presumed that the charge in the cation is dispersed by the superconjugation, and the cation is stabilized. Further, in the case where R1 to R64 may have a phenyl group as a substituent, it is presumed that the cation is extended by the extension of the conjugated system, whereby the cation is stabilized. Thus, as a result of the stabilization of the cation, it is considered that the light resistance of the obtained color filter is further improved. The ring formed by bonding the alkyl group, the aromatic hydrocarbon ring group, and the adjacent r1 to r6 to each other in R1 to R6 may have a substituent, and examples thereof include the following (substituting group W2). (Substituent group W2) an alkyl group having an inverse number of 1 to 8, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having a carbon number of 丨8, an aryl group having a number of 6 to 15, and a carbon number of 2 to 9. An alkylcarbonyloxy group, an arylcarbonyloxy group having 7 to 16 carbon atoms, an alkoxycarbonyl group having 2 to 9 carbon atoms, an aryloxycarbonyl group having 7 to 16 carbon atoms, an amine methyl group, and a carbon number of 2 to 9 Alkylamine methyl sulfonyl group, arylamine carbaryl group having a carbon number of 7 to 16, an amine sulfonyl group, an alkylamine fluorenyl group having a carbon number of 88, and an arylamine having a number of 6 to 15 Base, carbon number 2 to 9 alkyl group 101110090 20 201245131 base, carbon number 7~16 aryl carbonyl group, carbon number 〜8 alkyl sulfonyl group, carbon number 1~8 alkyl group a group of an alkyl group having an alkyl group having 6 to 15 carbon atoms, an alkyl group bonded to an amine group, an alkyl group having 1 to 8 carbon atoms, and an alkyl group having 1 to 4 carbon atoms. a dialkylamino group, an arylamino group having 6 to 15 carbon atoms, an aryl group having 6 to 15 carbon atoms, an arylalkylamino group bonded with a carbon number of 1 to 4, and a carbon number of 6~ a diarylamine group, a phenethyl group, a hydroxyethyl group, an alkylcarbonylamino group having 1 to 8 carbon atoms, an arylcarbonylamino group having 7 to 16 carbon atoms, carbon bonded to an aryl group of 15 a dialkylaminoethyl group, a trifluoromethyl group, a trialkylsulfonyl group having 1 to 8 carbon atoms, an alkylthio group having a carbon number of -8, and a carbon number of 6 to 4 A dentate atom such as an arylthio group, a hydroxyl group, a nitro group, a cyano group, a carboxyl group, a sulfo group, a fluorine atom or a chlorine atom. Specific examples of the aryl group in the substituent group W2 include those in the case of Ri to R6 which are referred to as an aromatic ring group. The aryl group may further have a lower alkyl group such as a mercapto group or an ethyl group, a lower alkoxy group such as a decyloxy group or an ethoxy group, a nitro group, a trifluoromethyl group, a cyano group, an amine fluorenyl group or an amine sulfonyl group. A halogen atom such as a fluorine atom or a chlorine atom is used as a substituent. In the above, the alkyl group, the aromatic ring group and the ring formed by the interconnection in R1 to R6 may have a substituent, and are preferably an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms. Phenyl, fluorenylphenyl, alkylcarbonyloxy having 2 to 9 carbon atoms, amidino group, amine fluorenyl group, alkylamine aragonidin group having 1 to 8 carbon atoms, trifluoromethyl group, cyano group, sulfonate Base and fluorine atom. (About R7 and R8) !〇1110090 21 201245131 R7 and R8 represent a hydrogen atom or an arbitrary substituent. Examples of the optional substituent include a dentate atom, an alkyl group having 1 to 8 carbon atoms which may have a substituent, an aromatic ring group which may have a substituent, and the like. Further, R7 and R8 may be bonded to each other to form a ring. In the case where R7 and R8 are bonded to each other to form a ring, these may be rings which are crosslinked by a hetero atom. Specific examples of the ring include the following. The rings may have a substituent. [化10]

(In the above, 1112 and 1122 each independently represent a hydrogen atom or a burnt group.) In view of the fact that the obtained color filter sheet is blue and has a south brightness, it is preferable that R7 and R8 are not connected to each other. ring. Further, the benzene ring in the above formula (II) may further have any substituent. The substituent which the benzene ring may have is, for example, the one described in the above (Substituent Group W2). (About Zml·)

ZmN represents a ml valence anion. The anion 'is not particularly limited as long as the effect of the present invention is not impaired, and examples thereof include halide ions such as F·, Cl·, Br·, and cesium; (a boron anion such as (6160) 4 ugly _; and CH 3 CO 〇 - a carboxylate anion such as C2H5COO·, C6H5CO〇, etc.; s〇42-101110090 22 201245131 a sulfate anion such as HSCV; an acid anion such as ήρο42-, P〇43·; a sulfonic acid anion, etc. As a sulfonic acid anion, for example Listed: trifluorosulfonium sulfonic acid, hydrazine sulfonic acid, pentanesulfonic acid, hexanesulfonic acid, heptanesulfonic acid, dodecanesulfonic acid, camphorsulfonic acid and the like aliphatic aliphatic acid anion; benzenesulfonic acid, An aromatic sulfonic acid anion which may have a substituent such as toluenesulfonic acid, 1-naphthalenesulfonic acid or 2-naphthalenesulfonic acid; Acid Blue 80 (C.1.61585), Acid Green 25 (C.1.61570), Acid Blue 45 ( CI63010), Acid Blue 43 (CI63000), Acid Blue 25 (C.1.62055), Acid Blue 40 (C.1.65125), etc. Anion of lanthanide pigment with sulfonic acid group; Direct Blue 86 (C.1.74810) An anion of a phthalocyanine-based pigment having a sulfonic acid group such as Direct Blue 199 (CI14190); a sulfonic acid having an acid blue 74 (CI73015) or the like An anion of the indigo dye; a diterpenoid, an anthracene anion, etc. wherein 'preferably a disulfonyl quinone imine anion, the compound represented by the above formula (11) is preferably represented by the following formula (Π_1) Compound. [11] 101110090 23 201245131

(wherein R1 to R8 have the same meanings as R1 to R8 in the above formula (II). R21 and R22 each independently represent a carbon group having 1 to 8 carbon atoms which may have a substituent, and a carbon number which may have a substituent 2 Alkenyl group of hexamethylene or hexamethylene having a substituent of 3'^^8. Further, R21 and R22 may be bonded to each other to form a ring) (About R21 and R22) R21 and R22 are independently A group having a carbon number of 1 to 8 which may have a substituent, a dilute group having 2 to 6 carbon atoms which may have a substituent, or a bad group having 3 to 8 carbon atoms which may have a substituent. Further, R21 and R22 may be bonded to each other to form a ring. Examples of the substituent include the above-mentioned (substituent group W2). Among these, in particular, as a substituent which the alkyl group, the alkenyl group or the cycloalkyl group in R21 and R22 has, the charge of the anion is further delocalized, and the heat resistance of the color material is improved. It is preferred to have a fluorine atom as a substituent. That is, R21 and R22 are preferably a perfluoroalkyl group having 1 to 8 carbon atoms in terms of dispersion of an anion charge and stabilization of anion. 101110090 24 201245131 More specifically, the anion represented by the compound represented by the above formula (II) is a compound represented by the formula (II12) 21 〇 R21-S-N-S-R22 6 6 (hereinafter referred to as "the above formula (II) The case of the anion "in the compound represented by the compound" is more preferably a compound represented by the following formula (ΙΓ-l).化 0 F2n+1Cn - I - N - S - Cn, F2n_ + i Ο Ο (I r -1) (In the above formula (ΙΓ-l), η and η' each independently represent 1~ An integer of 8) η and η' are usually an integer of 1 to 8, preferably an integer of 1 to 4. η and η' may be the same or different. Specific examples of the sulfonyl quinone imine anion in the case where η and η' are the same include bis(trifluoroanthracenesulfonic acid) quinone imine, bis(pentafluorobutanesulfonic acid) ruthenium, and the like. Specific examples of the sulfonyl quinone imine anion in the case where η and i are different include ruthenium trifluorosulfonate sulfonimide, heptafluoropropane sulfonate, Gas butyl acid III II bismuth acid imine and so on. Among the above, for the reason that the anion is most stabilized, bis(pentafluoroethanesulfonic acid) quinone imine having η = η' = 2 is particularly preferable. On the other hand, R11 and R12 may be bonded to each other to form a ring. In the case of forming a ring, R11 and R12 are particularly preferably those having a carbon number of 2 to 12, 101110090 25 201245131. In other words, the anion in the compound represented by the above formula (?-1) is more preferably an anion represented by the following formula (?-2). [Chem. 14]

(I I* -2) (In the above formula (ΙΓ-2), η" represents an integer of 2 to 12). From the viewpoint of heat resistance, η " is preferably 2 to 8, more preferably 3. The smaller the number of ηπ molecules, the smaller the effect of steric repulsion becomes, and the interaction becomes stronger. That is, it is presumed that the smaller the η", the larger the interaction between the anion and the cation becomes, the more stable the ion pair is, and the heat resistance of the color material is improved. Hereinafter, preferred embodiments of the compound represented by the formula (II) in the present invention are shown, but the present invention is not limited thereto. [Specific Example of Compound (II)] [Chem. 15] 101110090 26 201245131

101110090 27 201245131 [Chem. 16]

101110090 28 201245131 [化π]

The triaryl carbene dye is more preferably a compound represented by the following formula (IV) (hereinafter referred to as "compound (III)"), in terms of light resistance, heat resistance, and high transmittance. [Chem. 18]

M2 table Joe 1 to 4 integer. R11 to R each independently represent a carbon atom having a substituent of 1 101110090 29 201245131 to 8 or an aromatic ring group which may have a substituent and ri2, r3 and R14, and R15 and R16, respectively. Bonded to each other to form a ring structure. R17 and R18 each independently represent a hydrogen atom or an arbitrary substituent. And R18 may also be bonded to each other to form a ring. Further, the benzene ring and the anthracene ring in the above formula (III) may further have any substituent. Furthermore, 'containing a plurality of molecules in one molecule.

In the case of the same structure, the same structure may be a different structure (about R11 to R16). R"~R16 each independently represents a hydrogen atom, may have an amine of 8 to 8 or may have a substituent. Family ring base. The carbon number of 8 and the carbon group of 1 and the number of carbon atoms which may have a substituent as the carbon number 1 are the same as those described in the above (for R1 R6).

, R and R14 and R Xing κ, do not; F mesh mutual bond and the same as those described in the items R1 to R6). ,,,. Further, in the case of forming a ring structure, the above-mentioned R1 and Ri2, r13 101110090 201245131 (about R17 and R18), R17 and R18, each represent a hydrogen atom or an arbitrary substituent. Examples of the optional substituent include the above R1. Further, R17 and R18^ are bonded to each other to form a ring. When R17 and R18 are bonded to each other to form a ring, these may be a ring in which a hetero atom is crosslinked, and specific examples thereof The above is the same as that described in the item (for R7 and R8). The ring may have a substituent. In terms of the color filter obtained in a purple color and high brightness, R7 and R8 preferably do not mutually interact with each other. Linking to form a loop. Also, 'in terms of the color of the shirt obtained>, the light-receiving sheet is red, and in terms of high brightness, it is preferable to form a loop by mutual connection. Further, 'in the compound (III), 'stupid ring and The anthracene ring may further have a substituent. That is, it may have a substituent other than those specifically described in the formula (IH) within the range in which the effects of the present invention are not impaired. Examples of such a substituent include the above (substituent group) Substituents described in item w2). In the benzene ring of the formula (III), the bond to the carbon atom at the center of the triaryl sulfhydryl structure is bonded to the base of the larger volume of the ortho-position, and the planarity of the molecule is impaired. The color purity of the compound is lowered. Therefore, it is preferred that the compound has no substituent or is substituted with a halogen atom or a carbon number of 1 to 4. Further, the compound (III) can be extended, for example, by Rn to Ru. To form a dimer 101110090 31 201245131 or a trimer, etc. (About the compound represented by the formula (m-ι)) In the sulfonate (111), it is particularly preferred that the anion is a diterpenoid. In the above formula (III), a compound represented by the following formula (cut) is preferably used (hereinafter referred to as "compound (ΙΠ-1)").

(wherein R11 to Ris are the same as R11 to r18 in the above formula (111). R and R each independently represent an alkyl group having a carbon number of 丨~8 which may have a substituent, and a carbon number which may have a substituent of 2~ An alkenyl group of 6 or a cycloalkyl group having 3 to 8 carbon atoms which may have a substituent. Further, R and R32 may be bonded to each other to form a ring) (About R31 and R32) R and R 2 each independently represent The alkyl group having 1 to 8 carbon atoms having a substituent may have a substituent having a carbon number of 2 to 6 or a cycloalkyl group having 3 to 8 carbon atoms which may have a substituent. Further, R31 and R32 may be bonded to each other to form a ring. R31 and R32 are the same as RU and R22 in the above formula (Π-1), and the preferred aspect is also the same as 10Π10090 32 201245131. That is, the anion represented by the above formula (III-1) is more preferably an anion represented by the above formula (ΙΓ-1) or (ΙΓ-2). Hereinafter, preferred examples of the compound represented by the formula (III) in the present invention are shown, but the present invention is not limited thereto. [Specific Example of Compound (III)] [Chem. 21]

101110090 33 201245131 [Chem. 22]

The diaryl stilbene dye is more preferably a compound represented by the following formula (IV) (hereinafter referred to as "compound (IV)) in terms of high luminance and high voltage holding ratio. "The situation". [Chem. 23]

(In the above formula, R to R46 each independently represent a hydrogen atom, an alkyl group which may have a substituent, or an aromatic ring group which may have a substituent. The adjacent R41 to R46 may be bonded to each other to form a ring, and the ring may have a substitution. 101110090 34 201245131 R47 and R48f independently represent a hydrogen atom or an arbitrary substituent. They may be bonded to each other to form a ring, and the ring may have a substituent. The group c. (c) (IV) benzene ring and 嗓The ring may in turn have any substituted A ion, metal cation, soil test metal cation, ammonium cation or quaternary ammonium cation. — η represents an integer from 0 to 4 (for R4I to R46) R41 to R46 are each independently妯矣-> The individual is independently a gas atom, an alkyl group which may have a substituent, or an aromatic ring group which may have a substituent. The alkyl group which may have a substituent and the aromatic ring group which may have a substituent include those described in the above (for R1 to R6). In terms of improving the heat resistance of the compound (IV) and the heat resistance of the obtained color filter, it is more preferably a carbon number which may have a substituent or a carbon number which may have a substituent. The aromatic hydrocarbon ring group of ～1〇, more preferably an alkyl group having 1 to 8 carbon atoms or a phenyl group which may have a substituent. In the case where at least one of R to R is an alkyl group having 1 to 8 carbon atoms which may have a substituent, it is presumed that the charge in the cation is dispersed by the superconjugation, and the cation is stabilized. Further, when at least one of R41 to R46 is an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a substituent, since the conjugated system is elongated, the charge in the cation is dispersed and the cation is stabilized. Thus, it is considered that the result of the cation stabilization makes the heat resistance of the obtained color filter more excellent. 101110090 35 201245131 卩R R & preferably is a substituent having a carbon number of 1 to 8 of a substituent or an aromatic hydrocarbon group having a carbon number of 6 to 10 which may have a substituent. Examples of the substituent which may be contained in the ring formed by the alkyl group, the aromatic ring group and the interconnection in R R include, for example, the above (substituent group w2). (About R47 and R48) R and R48 represent a hydrogen atom or an arbitrary substituent. Examples of the optional substituent include a dentate atom, an alkyl group having a carbon number of 8 which may have a substituent, an aromatic ring group which may have a substituent, and the like. The rulers 47 and R48' are the same as those described in the above (for R17 and R18). The preferred aspect is also the same. (About M+ and η) Μ represents a hydrogen ion, an alkali metal cation, an alkaline earth metal cation, a tertiary ammonium cation or a quaternary cation. As the metal for the metal cation, there are mentioned, for example, a clock, a nano, a discharge, and the like. Further, examples of the alkaline earth metal as the alkaline earth metal cation include magnesium, calcium, barium, and the like. The secondary ammonium cation is n+hr3 (r represents a hydrogen atom, a substituent group which may have a substituent, or an aromatic ring group which may have a substituent. Further, a plurality of Rs may be the same or different) . The preferred carbon number of the alkyl group in the above R, and examples of the substituent which may be present, are the same as those exemplified in the case of the alkyl group of the above R41 to r46. The aromatic 101110090 36 201245131 preferred carbon number of the cyclic group, and examples of the substituent which may be present, are the same as those exemplified in the case of the above-mentioned aromatic ring group of "丨~#46. Specific examples thereof include a lower alkylammonium cation having 1 to 6 carbon atoms (for example, a mercapto ammonium cation 'ethyl ammonium cation, a diethyl ammonium cation, a triethyl ammonium cation, etc.), and a stone substituted by a hydroxyl group. a number of 1-6 cations (such as ethanol cations, diethanolammonium cations, triethanolammonium cations, etc.), substituted by a carboxyl group, carbon number 丨 ~ 6 alkyl ammonium cations (such as carboxyl sulfonium ammonium cation, carboxyl An ethylammonium cation, a carboxypropylammonium cation, a dicarboxydecylammonium cation, or the like, an ammonium cation (for example, N,N-diethylphenyl cation, etc.) substituted with an aromatic ring group and an alkyl group. The quaternary ammonium cation is represented by N+R4, and R represents a group which may have a substituent or an aromatic ring group which may have a substituent. Furthermore, the plurality of Rs included may be the same or different. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those exemplified in the case of the alkyl group of the above R1 to R6. The preferred carbon number of the aromatic ring group and the substituent which may be present are the same as those exemplified in the case of the above aromatic ring group of Ri to R6. Specific examples thereof include a quaternary ammonium alkyl cation having 1 to 6 carbon atoms (e.g., a tetradecyl ammonium cation, a tetraethylammonium cation, a tetrabutyl cation, etc.). Further, the type of the cation of M+ is not limited to the species, and a plurality of species may be mixed. Further, a plurality of kinds may be mixed in one molecule of the compound, or a plurality of kinds may be mixed in the colored resin composition. Preferred as M+, from the viewpoint of solubility in the solvent of the organic 101110090 37 201245131 used in the colored resin composition, hydrogen ions, alkali gold (10) ions, trilysine cations, and quaternary cations are preferred. More preferably, it is a zirconium ion and a nanometer scorpion 'four τ base (tetra) ion. η represents an integer of 0 to 4. The larger the η, the more the compound (IV) is replaced by the county with more hydrophilic groups, the resistance and the financial strength are improved, and the solubility of the compounder V) in the noisy liquid crystal towel is also lowered, so the voltage lung rate is also improved. It is preferably 〇2 in terms of high solubility of the organic solvent used in the colored resin composition. [About the compound represented by the formula (IV-1)] The compound (Ιν) of the present invention is excellent in color purity and transmittance of the obtained pixel by use in a color calendering sheet. The compound represented by the preferred formula σν·υ (hereinafter referred to as "combination conversion shape". [Chem. 24]

(In the above formula, (IV-1) RR each independently represents an alkyl group which may have a substituent, or an aromatic ring group which may have a substituent. 101110090 38 201245131 Adjacent R51 to R56 may be bonded to each other to form a ring, The ring may have a substituent. R57 and R58 each independently represent a hydrogen atom or an arbitrary substituent. R57 and R58 may be bonded to each other to form a ring, and the ring may have a substituent. Further, in the above formula (IV-1) The benzene ring and the anthracene ring may further have any substituent. Further, the SO group represented by the above formula (IV-1) represents a carbon of any one of the substituted anthracene rings. Further, in the case where the benzene ring in the above formula (IV-1) and R11 to R18 described below are substituted with a sulfo group, the sulfo group may form a salt with M+ represented by the above formula (IV). (About R51 to R56) R51 to R56 have the same meanings as R41 to R46 in the compound (IV), respectively. The specific examples and preferred aspects are also the same. (About R57 and R58) R57 and R58 have the same meanings as R47 and R48 in the compound (IV), respectively. The same is true for the specific and preferred aspects. [About the compound represented by the formula (IV-2)] The compound (IV) of the present invention is superior in terms of color purity and transmittance of the obtained pixel by use in a color filter. It is preferably a compound represented by the following formula (IV-2) (hereinafter referred to as "compound (IV-2)"). [Chem. 25] 101110090 39 201245131

R63 and R84 (I V-2) R to R65 each independently represent a hydrogen atom or an aromatic ring group which may have a substituent. The leuco group having a substituent and the adjacent R61 to R65 may be bonded to each other. The core may have a substituent. R and H68 each independently represent a hydrogen atom, a substituent of R67^R68-tj: or any of them. The Q oxime is bonded to form a ring, and the ring may have a substituent. The Q table is not selected from the group consisting of a divalent aromatic ring group which may have a substituent, a divalent aliphatic hydrocarbon group which may have a substituent, a divalent aliphatic heterocyclic ring which may have a substituent, 0·, | The base of i, or the base of 2 or more. Further, the benzene ring and the ten ring in the above formula (IV-2) may further comprise a phenyl ring, an a ring, a q2 in the above formula (IV-2), and r6i to R65 and R67 and R68 described below. In the case of a base substitution, the contig may form a salt with M+ represented by the above formula (Iv). (About R61 to R65) 101110090 201245131 R61 to R65 have the same meanings as R41 to R45 in the compound (IV), respectively. The specific examples and preferred aspects are also the same. (About R67 and R68) R67 and R68 have the same meanings as R47 and R48 in the compound (IV), respectively. The same is true for the specific and preferred aspects. (About Q2) Q2 represents a divalent aliphatic hydrocarbon group selected from a divalent aromatic ring group which may have a substituent, a divalent aliphatic hydrocarbon group which may have a substituent, a divalent aliphatic heterocyclic group which may have a substituent, -C(=0) One of the groups consisting of -, -0-, -S-, -NH-, or a group of two or more of these groups bonded. The divalent aromatic ring group may have two free valences and a carbon number of 2 to 14 in the aromatic ring having one free valence described in the above (in the case of R51 to R56). base. The substituent which the base group may have, for example, the above (substituent group W2). The divalent aliphatic hydrocarbon group may, for example, be a linear, branched or cyclic aliphatic hydrocarbon group, and the carbon number thereof is usually 1 or more, and usually 8 or less, preferably 6 or less. Specific examples thereof include an alkylene group having 1 to 8 carbon atoms, a cyclopentadienyl group, and a cyclohexanediyl group. As the substituent which the group may have, for example, the above (substituent group W2) may be mentioned. Examples of the divalent aliphatic heterocyclic group include a piperidinyl group, a pyrrolidinyl group, a imipenem group, and an η ratio. Dingji, brigade base, Weilinji, 吲D shower base, isoporphyrinyl and so on. The substituent which the base group may have is, for example, one of the above (substituent group w2): 101110090 41 201245131. [About the compound represented by the formula (IV-3)] The compound (IV) of the present invention is superior in terms of color purity and transmittance of the obtained pixel by use in a color filter. It is preferably a compound represented by the following formula (IV-3) (hereinafter referred to as "the compound (IV-3) of the present invention"). [Chem. 26]

(In the above formula, R71 to R73 and R75 to R76 each independently represent a hydrogen atom, an alkyl group which may have a substituent, or an aromatic ring group which may have a substituent. Q3 represents a divalent aromatic group selected from the group which may have a substituent. a group consisting of a cyclic group, a divalent aliphatic hydrocarbon group which may have a substituent, a divalent aliphatic heterocyclic group which may have a substituent, -C(=0)-, -0-, -S_, -NH- One of the groups, or a group of two or more of these groups bonded. The adjacent R71 and R72, R73 and Q3, and R75 and R76 may be bonded to each other to form a ring, and the ring may have a substituent. R77 and R78 are each independently The ground represents a hydrogen atom or an arbitrary substituent. 101110090 42 201245131 R and R may be bonded to each other to form a ring, and the ring may have a substituent. Further, the ring of the formula (IV-3) and the ring of 0 bow Further, in the case of the above-mentioned formula (IV-3), the stupid ring, the called ring, the following description q3, the Han 71 to R 5 and the R77 to R78 (four) base, the county may A salt is formed with M+ represented by the above formula (IV). (About R71 to R73, R75, and R76) R71 to R73, R75, and R76 have the same meanings as r4丨 to r43, r45, and R in the compound (Iv), respectively. The specific examples and preferred aspects are also the same. (About R77 and R78) R77 and R78 have the same meanings as R47 to R48 in the compound (Iv), respectively. The specific examples and preferred aspects are also the same. (Regarding Q3) Q Table 7F is selected from a divalent aliphatic hydrocarbon group which may have a substituent, a divalent aliphatic hydrocarbon group which may have a substituent, a divalent aliphatic heterocyclic group which may have a substituent, -C(=〇 )...the group of s-, -NH-! a group, or a group of 2 or more such groups. Examples of the divalent aromatic ring group include an aromatic ring having one free valence recorded in the above (in respect to r5 to r56), and having two free valencies and a carbon number of 2 〜 The base of Η. Examples of the substituent which the group may have include, for example, the above-mentioned (substituent group W2) β as the divalent aliphatic hydrocarbon group, and examples thereof include a linear chain, a branched chain or a ring 43 101110090 201245131. The aliphatic nicotyl group has a carbon number of usually 1 or more, and usually 8 or less, preferably 6 or less. Specific examples thereof include a stretched wire having a carbon number of 1 to 8, a cyclopentadienyl group, a cyclohexanediyl group, and the like. As the substituent which the group may have, for example, the above (substituent group W2) may be mentioned. Examples of the divalent aliphatic heteropolyglycan group include a piperidinyl group, a pyrrolidinyl group, an imidazolidinyl group, an IJ-pyrazole main group, a piperidinyl group, a porphyrin group, a porphyrin group, and the like. Isoxalinyl and the like. Examples of the substituent which the base group and the temple group can have are the above-mentioned (substituent group W2). [Molecular weight] The molecular weight of the yttrium compound (4) in the present month is usually more than 6 〇 0 or more and more preferably 5,000 or less, and preferably 2,000 or less. When it is in the above range, it is preferable in terms of good solubility in a solvent and ease of production. Further, preferred examples of the compound (Ιν) of the present invention are shown in the following Table, but the present invention is not limited thereto. [Specific Example of Compound (IV)] [Chem. 27] 101110090 201245131

101110090 45 201245131 [Chem. 28]

101110090 46 201245131 [化29]

101110090 47 201245131 [Chem. 30]

101110090 48 * 201245131 [化31]

ΑχΛ Ax A

SwS '3ft 's^

i?a, aHOk ^y^xxX'tx jyxxa^k 〇~^x〇^. 101110090 49 201245131 [化32]

^ιχ.σ^χ

Xxjaxc djxy" .a^tx χ^χχα^ l,^xx.cr,cccu

101110090 50 201245131 [Chem. 33]

101110090 51 201245131 [Chem. 34]

101110090 52 201245131 [化35]

V3CH

Όί〇Ψ〇Ό ^C^O^oO ^'OyoO 03⁄4^ 03⁄4.. o-by^u O-tO G<O ^χχ,^χχτ

101110090 53 201245131 [Chemistry 36]

101110090 54 201245131 [化37]

The above compounds (II) to (IV) can be, for example, according to J. Chem. Soc., Perkin Trans. 1998, 2, 297., International Publication No. 2006/120205, "Total Synthetic Dyes" (Sakaguchi, Sankyo Publishing, 1968) The method described in the method is synthesized. (triaryl decane dye: compound represented by formula (V)) [Chem. 38] 101110090 55 201245131

6 to 10 aromatic hydrocarbon groups. T3 b 5 jb — No, S〇3, -S03H, -S03M, -C02H, -C02Rb6, -S03Rb6, -S02NHRb8 ^-S〇2NRb8Rb9 〇 m is not an integer of ~5. In the case where m is an integer of 2 or more, the plurality of Rs may be the same or different.

Rb6 represents a saturated hydrocarbon group having 1 to 10 carbon atoms. And R each independently represents a linear or branched alkyl group having a carbon number of 丨10 or a cycloalkyl group having a carbon number of 3 to 30. Q represents an aromatic hydrocarbon group having 6 to 10 carbon atoms or an aromatic heterocyclic group having 5 to 10 carbon atoms. Μ denotes a nano atom or an atom. D is not a halogen atom. a represents an integer of ruthenium or osmium) (About Rb6) As Rb6, a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a pentyl group, an isopentyl group, a neopentyl group, and a ring are exemplified. Pentyl, hexyl, cyclohexyl, heptyl, cycloheptyl, octyl, 2-ethylhexyl, cyclooctyl, decyl, decyl, tricyclodecyl, methoxypropyl, ethoxypropyl , hexyloxypropyl, 2-ethyl 101110090 56 201245131 hexyloxypropyl, nonyloxyhexyl, ethoxypropyl and the like. Examples of the -SCbR156 include a sulfonyl group, an ethylsulfonyl group, a hexylsulfonyl group, and a sulfonyl group. Examples of -C〇2Rb6 include a mercaptooxycarbonyl group, an ethyloxycarbonyl group, a propyloxycarbonyl group, an isopropyloxycarbonyl group, a butyloxycarbonyl group, an isobutyloxycarbonyl group, and a pentyl group. Oxycarbonyl, isopentyloxycarbonyl, neopentyloxycarbonyl, • cyclopentyloxycarbonyl, hexyloxycarbonyl, cyclohexyloxycarbonyl, heptyloxycarbonyl, cycloheptyloxycarbonyl, Octyloxycarbonyl, 2-ethylhexyloxycarbonyl, cyclooctyloxycarbonyl, decyloxycarbonyl, decyloxycarbonyl, tricyclodecyloxycarbonyl, decyloxypropyloxycarbonyl An ethoxypropyloxycarbonyl group, a hexyloxypropyloxy group, a 2-ethylhexyloxypropyloxy group, a methoxyhexyloxycarbonyl group or the like. Examples of -S〇2NHRb8' include: sulfonamide, decylamine sulfonyl, ethionamide, propylamine, isopropyl sulfoxide, butyl sulfoxide, butyl sulfonyl Butyramine sulphate, sulphonate, sulphonate, sulphonate, sulphate, sulphonate, sulphate, sulphate, sulphate, hexamethylene amide Base, heptaniline, sulfhydryl, cycloheptylamine, sulfhydryl, octylamine, 2-ethylhexylamine, ruthenium, 1,5-didecyl hexylamine, cycline Anthraquinone, hydrazine, hydrazine, hydrazine, hydrazine, tricyclic hydrazine, hydrazine, methoxy propyl sulfonamide, ethoxypropyl amide, thiol Oxypropenyl amide, isopropoxy propyl sulphate, hexyl propyl sulphate, 2-ethylhexyl propyl propyl hydrazine, decyl hexyl hydride Base, 3-phenyl-1-101110090 57 201245131 Methylpropaneamine sulfonyl group and the like. Further, examples of -S02NHRb8 and -S02NRb8Rb9 include a group represented by the following formula. [化39]

NHs02 HHS〇2 I I [ I I AANis〇2 ^λ^Ν»!ΐ5〇2 -j-ΝΗδΟ, JytiiiS02 >1^^ y^°2 ^Jf^2

[化40] * NHSQf H〇~(4):丄丄{丄 HO^^NHSOa ,ΝΗ^〇2

NwOH~丄~丄 CF3CHaNHi〇i CF3(CF2)jCH2Nh1〇2 Jl in the formula 'X-table TFi atom. As the halogen atom in oxime 1, a fluorine atom, a gas atom, and a bromine atom are listed.可化 [41] 101110090 58 201245131

MeO-NHSOz^NH^Oa[4b 42][Chem. 43] Nine, NHS〇2 ^°'NHS〇a ^Or^NHSOa , NHS〇2 /N>s>-^NH®02 o2shn

NHS〇2ύΥ'

K人NH^Oj -^NhIoj C,'^vNHS〇i ^'^''ΝΗ^Οί ?丄2 0Anh"<^Uvnh‘ 〇Λ " [化 44] 101110090 59 201245131

In the above formula, X3 represents an alkyl group having 1 to 3 carbon atoms or an alkoxy group having 1 to 3 carbon atoms, and the nitrogen atom of the alkyl group and the alkoxy group may be substituted by a halogen atom. The alkyl group having 1 to 3 carbon atoms which may be substituted with a ii atom may, for example, be a methyl group, an ethyl group, a propyl group, an isopropyl group or a perfluoromethyl group. Examples of the alkoxy group having 1 to 3 carbon atoms which may be substituted with a ii atom include a decyloxy group, an ethoxy group, a propoxy group and the like. [化45]

101110090 60 201245131 [Chem. 46]

[化47]

[化48] .ΝΗΘ〇2 ^ΝΗ^Ρ2 ^NHSOsU ί

NW

Ιδ〇2

MaO, 丫, OMe FjC OMe

NHSO^ OMe

Me ΝΗ^ mlo, nhIo, hA V 0 IS〇2 "NHSQa

Cl

Nhso2 r^NHSOa 3^' In the above formula, X2 represents an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms, a halogen atom or a nitro group, and the hydrogen atom of the alkyl group and the alkoxy group may be Substituted by a ii atom. 101110090 61 201245131 As the halogen atom in x2, a atom, a gas atom and an amphoteric atom are exemplified. Examples of the alkyl group having a carbon number i to 3 which may be substituted by a functional atom include a methyl group, an ethyl group, a propyl group, an isopropyl group, a perfluoromethyl group and the like. Examples of the alkoxy group having a carbon number which may be substituted by a ii atom are methoxy, ethoxy, propoxy and the like. [化49]

101110090 62 201245131 [化 51]

I 802

S〇2 HO-^Ν'^ν'ΟΗ 1 S〇2 S^V'O^V'' [Chem. 52]

In the above formula, X2 represents the same meaning as described above. 101110090 63 201245131 [Chem. 54]

[化55] V>T^X> NHSOi

NHSOj

X^XJ IHS〇2 h〇^v^nh^〇2

[化56]

[化57] 101110090 64 201245131

In the above formula, x3 represents the same meaning as described above. As W and Rb9 contained in -S〇2NRb8Rb9, a branched alkyl group having a carbon number of 8, an alicyclic alkyl group having a carbon number of 5 to 7, an allyl group, a stupid group, and a carbon number of 8 are preferably used. An aralkyl group of 10, a hydroxyl group-containing alkyl group having 2 to 8 carbon atoms, and an alkoxy group-containing alkyl group or aryl group having 2 to 8 carbon atoms, particularly preferably 2-ethylhexyl group. Examples of the aromatic hydrocarbon group of 6 to 10 include a phenyl group and a naphthyl group. The substituent of the aromatic hydrocarbon group having 6 to 10 carbon atoms is preferably an ethyl group, a propyl group, a phenyl group or a dinonylphenyl group. _S〇3Rb6 or -S〇2NHRb8. The γ atom which may be a substituent of the aromatic hydrocarbon group having 6 to 10 carbon atoms may, for example, be a fluorine atom, a chlorine atom or a bromine atom. The substituent of the aromatic hydrocarbon group is preferably ethyl, propyl, strepyl, dimethylphenyl, _S〇3Rb6 or ·8〇2ΝΗΙ^8. As a carbon having 6 to 10 carbon atoms having a substituent Examples of the nicotyl group include methylphenyl, dimethylphenyl, trimethylphenyl, ethylphenyl, hexylphenyl, nonylphenyl, Iphenyl, chlorophenyl, phenyl, and Phenyl, decyloxy, dimethyl Phenylphenyl, ethoxyphenyl, hexyloxyphenyl, decyloxyphenyl, 101110090 65 201245131 trifluoromethylphenyl, etc. (Synthesis of Compound (v)) Compound (v) can be as follows Method for producing: for example, by gasifying a dye or a dye intermediate having -S03H, the obtained dye or dye intermediate having -S02C1 is reacted with an amine represented by R8-NH2. In the same manner as described above, the dye produced by the method described in the right upper column to the lower left barrier of page 3 of Japanese Patent Laid-Open No. Hei 3-78702 is chlorinated, and then reacted with an amine. (Specific Example) The following shows a specific example of the compound (V).

[化59] 101110090 66 201245131

101110090 67 201245131 (Crystalline dye: a compound represented by the formula (νι)) As a cyanine dye, it is preferably represented by the following formula (VI) in terms of heat resistance, light resistance, and high transmittance. The compound (hereinafter referred to as "compound (VI)"). M3 (ν ϊ ) (wherein, Zm3_ represents an m3 valence anion. 2^3-

Ar1 m3 represents an integer of 1 to 4.

Ar1 and Ar2 each independently represent a nitrogen-containing heterocyclic group which may have a substituent. q represents an integer of 1 to 5) (About q) q represents an integer of 1 to 5. q is preferably 1 to 5, and particularly preferably 1 to 1 (for Ar1 and Ar2) in terms of the heat of the color material.

Ar1 and Ar2 each independently represent a nitrogen-containing heterocyclic group which may have a substituent. Examples of the nitrogen-containing heterocyclic group include a fluorene ring having one free valence, a benzofluorene ring, a pseudofluorene ring, a benzofluorene ring, a carbazole ring, a benzo ring, and an anthracene. Α-ring, benzo-B-salt ring, benzo-β-ring or 喧-ring ring. Among them, in terms of high brightness, an anthracene ring, a benzofluorene ring, a pseudofluorene ring, a benzofluorene ring, and more preferably an anthracene ring or a benzofluorene ring. 101110090 68 201245131 iM. The nitrogen-containing heterocyclic ring in the present invention may have a substituent as long as it is not particularly limited, and examples thereof include methyl group, ethyl group, ==, butyl group, isobutyl group, and second group. Base, tert-butyl, pentyl, pentyl pentyl, third pentose aliphatic hydrocarbon group; benzene, o-tolyl, m-tolyl, p-tolyl, xylyl, 2,4,6-dimethyl unyl An aromatic hydrocarbon group such as isopropylphenyl, m-isopropylphenyl or p-cumyl; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, Alkoxy group such as monobutoxy group, second butoxy group or pentyloxy group; aryloxy group such as phenoxy group; aralkyloxy group such as benzyloxy group; methoxy group, ethoxycarbonyl group, propoxy group a group having an ester bond such as a carbonyl group, an ethoxylated group or a benzamidine group; a mercaptoamine sulfonyl group, a dimethylamine sulfonyl group, an ethylamine sulfonyl group, a diethylamine sulfonyl group, N-propylamine sulfonyl, bis-n-propylamine sulfonyl, isopropylamine sulfonyl, diisopropylamine sulfonyl, n-butylamine sulfonyl, di-n-butylamine sulfonate Alkylamine sulfonyl group such as fluorenyl; sulfhydryl sulfonyl group, ethyl sulfonate Alkyl sulfonium such as mercapto, propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutylsulfonyl, t-butylsulfonyl, tert-butylsulfonyl a halogen atom such as a fluorine atom, a gas atom, a bromine atom or an iodine atom; a nitro group and a cyano group; 101110090 69 201245131 In the case where the above substituent has a hydrogen atom, the hydrogen atom may pass through a halogen atom such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom; methoxy is ethoxy, propoxy or different. Propyloxy, butoxy, isobutoxy, second butoxy, second butoxy, pentyloxy, alkoxy; phenoxy, oxy, etc., aryloxy, base, ortho An aromatic hydrocarbon group such as a methyl group, an anthracene group, a phenyl group, a toluene 2,4,6-diphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group; a carboxyl group; a cyano group; a nitro group or the like. The compound represented by the above formula (VI) may be a cis-trans isomer at the cation site, and may be any isomer. The compound represented by the above formula (VI) is more preferably a compound represented by the following formula (¥1-1), in terms of improving the brightness and heat resistance of the coating film. [化 62]

(In the above formula (VI_1), n has the same meaning as η in the above formula (VI). R and R each independently represent an aliphatic hydrocarbon group having 1 to 2 carbon atoms which may have a substituent. R91 and R92 are each independently _〇~s·, _Ν·, _Se_ or -cr9〇3r904_. R and r9 (M each independently represent a hydrogen atom or an aliphatic hydrocarbon group having 1 to 6 carbon atoms. Among them, R91 and R92 are _CR9. In the case of 〇3R9〇4_, r9〇3 may be bonded to each other to form a ring with each other. 101110090 201245131. The ring may have a substituent. Rings Y and Y2 each independently represent a benzene ring which may have a substituent, or may have a substitution The naphthalene ring: R and R each independently represent a decyl group having 1 to 8 carbon atoms which may have a substituent, an alkenyl group having 2 to 6 carbon atoms which may have a substituent, or a carbon number which may have a substituent of 3 to 6 Further, R81 and R82 may be bonded to each other to form a ring) (About R9G1 and r902) R9〇l 9〇2 K each independently represents an aliphatic group having 1 to 20 carbon atoms which may have a substituent As the niobium aliphatic hydrocarbon group, for example, methyl, ethyl, vinyl, ethynyl, propyl, s #isopropyl, isopropene , 1-propenyl, 2-propenyl, 2-propynylbutyl, isobutyl, second butyl, tert-butyl, 2-butenyl, 1,3- "7* -— Rfe gan t-decyl, isopentyl, neopentyl, third amyl, 1 -decylpentyl, 2-methylpentyl, 9々α μ _-penten-4-ynyl, hexyl , isohexyl, 5-methylhexyl, heptyl, octyl. The aliphatic hydrocarbon group may have a substituent, and examples thereof include a phenyl group, a methyl group, a benzyl group, a m-methyl group, a p-tolyl group, and a xylyl group. , 2,4,6·trimethylbenzene ▲ #isopropylphenyl, m-isopropylphenyl, p-cumyl and other groups of nicotine; methoxy, b-glycolyl, propoxy, isopropoxy, Butyloxy, isobutoxy, second butoxy, 筮-^ „ alkoxy storms such as monobutoxy, pentyloxy, phenoxy, benzyloxy, 101110090 71 201245131 Fluorine, gas, desert Further, a carboxyl group, a nitro group, and a cyano group. R9G1 and R902 are each preferably an alkyl group having 1 to 8 carbon atoms, more preferably a carbon group having 1 to 5 carbon atoms. R92) R91 and R92 each independently represent -0-, -S-, -N-, -Se-4-CR9()3R904-. R9G3 and R9 134 each independently represents a hydrogen atom or an aliphatic hydrocarbon group having 1 to 6 carbon atoms. In the case where R91 and R92 are -CR9()3R9()4-, R903 may be bonded to each other to form a ring. A preferred example of the ring in which R91 and R92 are bonded to each other can be exemplified, for example, the following, but the present invention is not limited thereto. [化63]

(The ring Y1 and the Y ring Y1 and Y2 each independently represent a benzene ring which may have a substituent or a naphthalene ring which may have a substituent. The aliphatic hydrocarbon group in R9G3 and R9Q4, and R91 and R92 may be bonded to each other. The benzene ring and the naphthalene ring in the ring and the rings Y1 and Y2 may have a substituent, and examples thereof may include a substituent which the aliphatic hydrocarbon group in the above R9G1 and R9Q2 may have. (About R81 and R82) 101110090 72 201245131 R81 and R82 Each of them independently represents an alkyl group having 1 to 8 carbon atoms which may have a substituent, an alkenyl group having 2 to 6 carbon atoms which may have a substituent, or a cycloalkyl group having 3 to 8 carbon atoms which may have a substituent. R81 and R82 may be bonded to each other to form a ring. R81 and R82 have the same meanings as R21 and R22 in the above formula (II-1), and preferably have the same state. That is, the compound represented by the above formula (VI_1) Further, the anion in the above formula is preferably a compound represented by the above formula (ΊΓ-1) or (ΙΓ-2). Further, the compound represented by the above formula (VI) can be formed by, for example, R9G1 to R9Q2 and R91 and R92 extended linkers. Dimer or trimer, etc. Hereinafter, preferred compounds of the formula (VI) in the present invention are shown. Style, but the present invention is not limited to such. [Specific Example] '[of 64] 101 110 090 73 201 245 131

In the case where the colored resin composition of the present invention is a colored resin composition for forming a red pixel or a colored resin composition for forming a green pixel, a yellow dye can be used as a complementary color. In the case where a yellow dye is contained, the image forming property or the developability tends to be insufficient before the solvent resistance is lowered. 101110090 74 201245131 It is presumed that the absorption wavelength of the yellow dye coincides with the absorption wavelength of the photopolymerization initiator, so that the photopolymerization initiator cannot sufficiently obtain the light energy, resulting in a decrease in the amount of radical generation, and the coloring resin composition The photopolymerization initiator contained therein does not function sufficiently. That is, it is preferable that the colored resin composition contains the yellow dye described later, and the effect of the present invention is more easily obtained. The yellow dye is described in detail below. [Yellow dye] Examples of the yellow dye in the present invention include an azo dye, a quinophthalone dye, a cyanine dye, an anthraquinone dye, a fluorene based dye, and a dimercaptosyl dye. And among them, an azo dye is preferred. Examples of the azo-based dye include a pyridone azo dye, a pyrazolone azo dye, and a barbituric azo dye, and particularly have an absorption end in an absorption spectrum of from 400 nm to 500 nm. In terms of obtaining a pixel having a high luminance, a σ ratio ketone azo dye is preferred. The pyridone azo dye is not particularly limited, and a known one can be used. However, in view of high solubility in the colored resin composition, a compound represented by the following formula (VII) is preferred (hereinafter There is a case called "compound (VII)"). [化65] 101110090 75 201245131

(In the above formula (VII), 'A' represents an aromatic hydrocarbon ring group which may have a substituent or a heterocyclic group which may have a substituent. R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms which may have a substituent, Carboxyl or trifluoromethyl. R2a represents a hydrogen atom, a cyano group, an amine carbenyl group, an alkylamine group which may have a substituent, an arylamine group which may have a substituent, a carboxyl group, an amine sulfonyl group Or a sulfo group. R3a represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 30 carbon atoms which may have a substituent, and an aralkyl group having 7 to 20 carbon atoms which may have a substituent a heterocyclic group having 3 to 2 carbon atoms which may have a substituent, an amine carbenyl group, an alkylamine carbenyl group having 2 to 2 carbon atoms which may have a substituent, and a carbon number 7 which may have a substituent An arylamine oxime group of ～30, an amine sulfonyl group, an alkylamine sulfonyl group having 1 to 20 carbon atoms which may have a substituent, an arylamine sulfonyl group having a carbon number of 6 to 30 which may have a substituent An alkoxycarbonyl group having 2 to 2 carbon atoms of a substituent, an aryloxycarbonyl group having 7 to 3 carbon atoms which may have a substituent, a fluorenyl group having 2 to 30 carbon atoms which may have a substituent, Alkyl sulfonyl group having a carbon number of a substituent or a sulfonyl group having 6 to 3 carbon atoms which may have a substituent) (About A) A represents an aromatic hydrocarbon ring group which may have a substituent Or a 101110090 76 201245131 heterocyclic group which may have a substituent. Examples of the slit ring group include a benzene having a free valence = nevi, a trans, a (tetra) benzene ring, an anthracene, a benzoxene ring, a coexisting divalent 1 naphthalene ring, a ring, a ring, and the like. Examples of the heterocyclic group ' include a fluorenyl group and a W group. More than 唾 嗟 嗟 、 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 啊 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Base, furyl, thienyl and the like. As the aromatic hydrocarbon ring group or a substituent which the heterocyclic group may have, in terms of improving the solubility of the compound (1) in a solvent, it is preferred that the hydrophilic group is the same as that of the color tone. Preferably, it has a basis of electron supply or electron seeking. More specifically, an alkyl group which may have a substituent, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, an alkoxy group which may have a substituent, an amine group, may have a substitution An alkylamino group, an arylamine group which may have a substituent, a mercaptoamine group which may have a substituent, an amine mercapto group, an alkylamine-methyl group which may have a substituent, and an aromatic group which may have a substituent a carbylamino group, an amine sulfonyl group, an alkylamine sulfonyl group which may have a substituent, an arylamine sulfonyl group which may have a substituent, an alkoxycarbonyl group which may have a substituent, may have a substituent An aryloxycarbonyl group, a nitro group, a carboxyl group, a sulfo group, a hydroxyl group, a cyano group, a dentate atom or the like. The number of carbon atoms of the alkyl group which may have a substituent is usually 1 or more, and is usually 12 or less, preferably 10 or less. The group which can substitute the alkyl group is exemplified by: 101110090 77 201245131 Alkoxy group having 1 to 10 carbon atoms, a strepyl group, a hydroxyl group, an amine group, a dimethylamino group, a diethylamino group, a halogen atom, a Renewal base and silk. Specific examples of the working group are exemplified by methyl, ethyl, n-propyl, hydroxyethyl, hydrazine, 2 dihydroxypropyl, 2-decyloxyethyl, 2·ethoxyethyl, 2_ Butoxyethyl, 2-(2-methoxyethoxy)ethyl, 2-(2-ethoxyethoxy)ethyl, 2-(2-butoxyethoxy)ethyl, benzyl , phenethyl and the like. The number of carbon atoms of the aryl group which may have a substituent is usually 6 or more, and is usually 14 or less, preferably 12 or less. Examples of the aryl group include a phenyl group, a naphthyl group, and an anthracenyl group. Examples of the group which may be substituted for the aryl group include an alkyl group having a carbon number of 丨8, a oxy group having a carbon number of 1 to 8, a hydroxyl group, an amine group, a dimercaptoamine group, a diethylamino group, and a dentate. Atom, sulfo group and carboxyl group. Specific examples of the aryl group include a phenyl group, a p-nonylphenyl group, a m-tolyl group, a p-nonyloxyphenyl group, a naphthyl group, an anthracenyl group and the like. The number of carbon atoms of the monovalent heterocyclic group which may have a substituent is usually 2 or more, and is usually 14 or less, preferably 12 or less. Examples of the monovalent heterocyclic group include a pyrrolyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, a carbazolyl group, a triazolyl group, a thiadiazolyl group, an acridinyl group, a pyrimidinyl group, a tridecyl group, and a quinoline. , isoquinolyl, benzo-β-sodium, ortho-diimine, benzo-mymiline-based, α-furanyl, porphinyl, °-pyranyl, pyridyl, ° is slightly biting the base, miso bite, ^. It is a sulfhydryl group, a succinyl group, a morpholinyl group, a porphyrin group, an isoindolyl group or the like. Examples of the group which can substitute the monovalent heterocyclic group include an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, a hydroxyl group, an amine group, a dimercaptoamine group, and a diethylamino group. , odontogen original, 101110090 78 201245131 sulfo and carboxyl groups. Specific examples of the monovalent heterocyclic group include 2-pyridyl. Each group, 2-imidazolyl, 1-pyrazolyl, 2-thiazolyl, 2-oxazolyl, 1,2,4-tris-s--1-yl, 4-° ratio, 2-° dense 1&gt ; base, 4,6-diamino-2-tri-well, 8-cylinyl, 8-isoquinolinyl, 2-phenylthiazolyl, 6-methyl-7-sulfo-2- Stupid and thiophene. Sitting group, 1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl, 1H-benzimidazol-2-yl, 2-flufanyl, 2-. The thiophene group, the 1-vi bottom α-based group, and the 1-° ratio are slightly fixed. Fixed base, 1- « than "sitting bite, sputum, 1-midinky, 1- called budolin, 2-iso called budolin. The number of carbon atoms of the alkoxy group which may have a substituent is usually 1 or more, and is usually 12 or less, preferably 10 or less. Examples of the group which may be substituted with the alkoxy group include alkoxy groups having 1 to 10 carbon atoms, phenyl groups, hydroxyl groups, amine groups, dinonylamino groups, diethylamino groups, dentate atoms, and cyano groups. Sulfo group and carboxyl group. Specific examples of the alkoxy group include a decyloxy group, an ethoxy group, a n-propoxy group, a n-butoxy group, a hydroxyethoxy group, a 1,2-dihydroxypropoxy group, and a 2-methoxy group. Oxy, 2,ethoxyethoxy, 2-butoxyethoxy, 2-(2-decyloxyethoxy)ethoxy, 2-(2.-ethoxyethoxy) Ethoxy, 2-(2-butoxyethoxy)ethoxy, benzyloxy, phenethyloxy, and the like. The alkylamine group which may have a substituent is represented by -NRnaR12a, Rlla represents an alkyl group which may have a substituent, and R12a represents a hydrogen atom or an alkyl group which may have a substituent. The number of carbon atoms of the alkyl group is usually 1 or more, and is usually Π or less, preferably 10 or less. Examples of the group which may be substituted for the alkyl group include an alkoxy group having 1 to 10 carbon atoms, a phenyl group, a hydroxyl group, an amine group, a dimethylamino group, a diethylamino group, and 101110090 79 201245131 halogen atom, cyano group. And a hydrazine, a carboxyl group, etc., as a specific example of a base, a methyl group, ethyl, n-propyl, n-butyl, cyclohexyl, hydroxyethyl, 1,2- dihydroxypropyl, 2- Oxyethyl, 2-ethoxyethyl, 2-butoxyethyl, 2(2-methoxyethoxy)ethyl, 2 ethoxyethoxyethyl), 2_(2 - butoxyethoxy)ethyl, benzyl, phenethyl and the like. Specific examples of the silk amine group include an ethylamino group, a dinonylamino group, a diethylamino group, a dibutylamino group, a di(2-ethoxyethyl)amino group, and a second embodiment. Ethylethylamino, cyclohexylethyl and the like. The arylamine group which may have a substituent is represented by NRnaRHa, and represents an aryl group which may have a substituent, and RMA represents a hydrogen atom, an alkyl group which may have a substituent, and an aryl group which may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the alkyl group of the above-mentioned Hans 13 and R! 2a. The number of carbon atoms of the aryl group is usually 6 or more, and usually 14 or less, preferably 12 or less, and examples thereof include a phenyl group, a naphthyl group, and an anthracenyl group. Examples of the group in which the aryl group is substituted with an aryl group include an alkyl group having a carbon number of 丨8, an alkoxy group having a carbon number of 丨8, a hydroxyl group, an amine group, a dimethylamino group, a diethylamino group, and an element. Atom, cyano group, sulfo group and carboxyl group. Specific examples of the aryl group include a phenyl group, a p-tolyl group, a m-tolyl group, a p-methoxyphenyl group, a naphthyl group, and an anthracenyl group. Specific examples of the arylamine group include a phenylamino group, a diphenylamino group, a bis(p-tolyl)amino group, a di(p-methoxyphenyl)amino group, and an ethyl strepamine. Base, n-butyl stupylamino group and the like. The mercaptoamine group &_NH_C〇Rl5a which may have a substituent means that the Rl5a table 101110090 80 201245131 is a material which may have a substituent and may have a substituent. The preferred carbon number of the reduced base and the substituent which may be present are the same as those exemplified in the case of the above-mentioned Han 113 and Rl 2a. The preferred carbon number of the fluorene aryl group may have the same substituent as the aryl group of the above R13a. Specific examples of the mercaptoamine group include an ethenylamino group, a claudylamino group, and a 2-ethylhexylcarbonylamino group. The alkylamine fluorenyl group which may have a substituent means that Rl6a and 11173 each independently represent a hydrogen atom or an alkyl group which may have a substituent. The preferred carbon number of the alkyl group, which may have a substituent, is the same as the substituent which the alkyl group in the above Rna and R may have. Specific examples of the alkylamine thiol group include methylamino fluorenyl group, ethyl amide thiol group, phenethyl amide fluorenyl group, 2-ethylhexylamine carbhydryl group, and 2-ethyl group. Oxyethylamine carbenyl, 2-(2-ethoxyethoxy)ethylaminecarbamyl, and the like. The arylamine fluorenyl group which may have a substituent is represented by _C〇-:NR18aR19a, and R represents an aryl group which may have a substituent. R19a represents a hydrogen atom, an alkyl group which may have a substituent, and an aryl group which may have a substituent. The preferred carbon number of the alkyl group, and the substituent which may be present, may be the same as the substituent which the alkyl group in the above Riia & Rua may have. The preferred carbon number of the aryl group and the substituent which may be present are the same as those exemplified in the case of the aryl group of the above R13a. Specific examples of the arylamine fluorenyl group include a phenylamine methyl sulfonyl group, a naphthylamino fluorenyl group, a p-nonylphenylamine fluorenyl group, and a p-nonyloxyphenylamine fluorenyl group. The alkylamine sulfonyl group which may have a substituent is represented by _S〇2_NR2〇aR2la, and 101110090 81 201245131 R2Qa& R21a each independently represents a hydrogen atom or an alkyl group which may have a substituent. The preferred carbon number of the alkyl group, which may have a substituent, is the same as the substituent which the alkyl group in the above Rna and RI2a may have. Specific examples of the alkylamine sulfonyl group include a mercaptoamine sulfonyl group, an ethylamine sulfonyl group, a phenethyl virgin stone, a 2-ethylhexylamine continuation group, and 2 - ethoxyethylamine phosphatyl, 2-(2-ethoxyethoxy)ethylamine sulfonyl and the like. The arylamine sulfonyl group which may have a substituent is represented by -S02-NR22aR23a, and R22a represents an aryl group which may have a substituent. R23a represents a hydrogen atom, an alkyl group which may have a substituent, and an aryl group which may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the alkyl group of the above-mentioned rule 113 and R12a. The preferred carbon number of the aryl group and the substituent which may be present are the same as those exemplified in the case of the aryl group of the above R13a. Specific examples of the arylamine sulfonyl group include a phenylamine fluorenyl group, a naphthylamine fluorenyl group, a p-tolylamine sulfonyl group, and a p-methoxyphenylamine sulfonyl group. The alkoxycarbonyl group which may have a substituent is represented by _CO-OR24a, and the ruler 243 represents an alkyl group which may have a substituent. The preferred carbon number of the alkyl group, which may have a substituent, is the same as the substituent which the alkyl group in the above-mentioned rulers (1) and R12a may have. Specific examples of the sulfoalkyl group include a methoxy group, an ethoxycarbonyl group, a phenethyloxycarbonyl group, a 2-ethylhexyloxycarbonyl group, and a 2-ethoxyethoxycarbonyl group. , 2-(2-ethoxyethoxy)ethoxycarbonyl, and the like. The aryloxycarbonyl group which may have a substituent is represented by _C〇-〇R25a, and the ruler 253 represents an aryl group which may have a substituent. The preferred carbon number of the aryl group, which may be taken as 101110090 82 201245131, is the same as the substituent which the above-mentioned aromatic aryl group may have. Specific examples of the aryloxycarbonyl group include a phenoxycarbonyl group, a naphthyloxycarbonyl group, a p-tolyloxycarbonyl group, and a p-methoxyphenoxycarbonyl group. Examples of the halogen atom include a fluorine atom, a gas atom, a bromine atom, and an iodine atom. Among them, a fluorine atom or a gas atom having a high anion property is preferable. (About Rla) R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms which may have a substituent, a carboxyl group or a trisyl group. The number of carbon atoms of the alkyl group which may have a substituent is usually 1 or more, and usually the following is preferably 5 or less. The group which may be substituted with the alkyl group may, for example, be an alkoxy group having 1 to 8 carbon atoms or a hydroxyl group. Specific examples of the alkyl group include a mercapto group, an ethyl group, a n-propyl group, an isopropyl group, a hydroxyethyl group, and a decyloxy group. (About R2a) R2a represents a hydrogen atom, a cyano group, an amine fluorenyl group, an alkylamine fluorenyl group which may have a substituent, an arylamine carbhydryl group which may have a substituent, a carboxyl group, an amine sulfonyl group or a base group . The alkylaminecarbamyl group which may have a substituent is represented by -CO-NR56aR57a, and each of 11563 and R57a independently represents a hydrogen atom or an alkyl group which may have a substituent. The preferred carbon number of the alkyl group, which may have a substituent, is the same as the substituent which the alkyl group in the above R11a and R12a may have. Specific examples of the alkylamine thiol group include methylamine methyl sulfonyl group, ethyl amine fluorenyl group, phenethylamine methyl fluorenyl group, 2-ethylhexylamino fluorenyl group, and 2-ethyl group. Ethoxyethylamine formazan 101110090 83 201245131, 2-(2-ethoxyethoxy)ethylamine fluorenyl and the like. The arylamine fluorenyl group which may have a substituent is represented by _C〇_NR58aR59a, and R58a represents an aryl group which may have a substituent. R59a represents a hydrogen atom, an alkyl group which may have a substituent, and an aryl group which may have a substituent. The preferred carbon number of the alkyl group, and the substituent which may be present, may be the same as the substituent which the alkyl group in the above R11a and R]2a may have. The preferred carbon number of the aryl group and the substituent which may be present are the same as those exemplified in the case of the aryl group of the above R13a. Specific examples of the arylamine-methyl group include a phenylamine fluorenyl group, a naphthylamino group, a p-mentylaminocarbamyl group, a p-nonyloxyphenylamine carbaryl group, and the like. (About R3a) R a represents a hydrogen atom, an alkyl group having 1 to 2 carbon atoms which may have a substituent, an aryl group having 6 to 30 carbon atoms which may have a substituent, and a carbon number of 7 to 2 which may have a substituent. An aralkyl group, a heterocyclic group having 3 to 20 carbon atoms which may have a substituent, an amine aryl group, an alkylamine fluorenyl group having 2 to 20 carbon atoms which may have a substituent, and a carbon number which may have a substituent 7 to 30 arylamine methyl sulfonyl group, amine sulfonyl sulfonyl group, alkylamine sulfonyl group having 1 to 20 carbon atoms which may have a substituent, and arylamine sulfonium having 6 to 30 carbon atoms which may have a substituent An alkoxycarbonyl group having 2 to 20 carbon atoms which may have a substituent, an aryloxycarbonyl group having 7 to 30 carbon atoms which may have a substituent, a fluorenyl group having 2 to 30 carbon atoms which may have a substituent, and may have The alkylsulfonyl group having 1 to 30 carbon atoms of the substituent or the arylsulfonyl group having 6 to 30 carbon atoms which may have a substituent. The number of carbon atoms of the alkyl group having 1 to 20 carbon atoms which may have a substituent is usually 1 or more, and is usually 20 or less, preferably 15 or less. As a group which can substitute the alkyl group, 101110090 84 201245131 may, for example, be an alkoxy group having 1 to 15 carbon atoms, a hydroxyl group, an amine group, a dimethylamino group, a diethylamino group, a halogen atom, a cyano group or a sulfo group. And carboxyl groups and the like. Specific examples of the alkyl group include methyl group, ethyl group, n-propyl group, hydroxyethyl group, L2-dihydroxypropyl group, 2-methoxyethyl group, 2-ethoxyethyl group, and 2-butyl group. Oxyethyl, 2-(2-decyloxyethoxy)ethyl, 2-(2-ethoxyethoxy)ethyl, 2-(2-butoxyethoxy)ethyl, and the like. The number of carbon atoms of the aryl group having 6 to 30 carbon atoms which may have a substituent is usually 6 or more, and is usually 30 or less, preferably 25 or less. Examples of the aryl group include a phenyl group, a naphthyl group, an anthracenyl group and the like. Examples of the group which may be substituted for the aryl group include an alkyl group having 1 to 15 carbon atoms, an alkoxy group having 1 to 15 carbon atoms, a hydroxyl group, an amine group, a dimethylamino group, a diethylamino group, and a halogen atom. , sequel and sputum. Specific examples of the aryl group include a phenyl group, a p-nonylphenyl group, a m-nonylphenyl group, a p-nonyloxyphenyl group, a naphthyl group, and an anthracenyl group. The number of carbon atoms of the aralkyl group having 7 to 20 carbon atoms which may have a substituent is usually 7 or more, and is usually 20 or less, preferably 15 or less. Examples of the group which may be substituted for the aralkyl group include an alkyl group having 1 to 15 carbon atoms, an alkoxy group having 1 to 15 carbon atoms, a hydroxyl group, an amine group, a dinonylamino group, a diethylamino group, and a halogen. Atom, sulfo group and carboxyl group. Specific examples of the aryl group include a benzyl group, a phenethyl group, a mercaptobenzyl group, a nonylphenylethyl group, a/5-mercaptophenylethyl group, and an anthracenyl group. The number of carbon atoms of the heterocyclic group having 3 to 20 carbon atoms which may have a substituent is usually 3 or more, and usually 20 or less, preferably 15 or less. The monovalent heterocyclic group 'is a pyrrolyl group, an imidazolyl group, a pyrazolyl group, or a thiazolyl group. Azolyl, triazole 101110090 85 201245131 base, thiadiazolyl, pyridyl, pyrimidinyl, tri-cultivation, quinolinyl, isoquinolinyl, benzothiazolyl, phthalimido, benzene And imidazolinyl,. Furamyl, thienyl and the like. Examples of the group which may be substituted for the monovalent heterocyclic group include an alkyl group having 1 to 15 carbon atoms, an alkoxy group having 1 to 15 carbon atoms, a hydroxyl group, an amine group, a dinonylamino group, and a diethylamino group. , i atom, sulfo group and carboxyl group. Specific examples of the i-valent heterocyclic group include 2-pyrrolyl, 2-imidazolyl, oxime-saltyl, 2-thiazolyl, 2-oxazolyl, 1,2,4-triazole-1. - base, 4-pyridyl. Stationary, 2_pyrimidinyl, 4,6-diamino-2·trimage, 8-quinolinyl, 8-isoquinolinyl, 2_benzothiazolyl, 6-methyl-7-sulfo-2 - benzothiazolyl, 1,3-dihydro-indole, 3_dioxy-2-indole-iso.引出-2-基,1Η-Benzene 0米° sit-2-yl, 2-°夫°南基, 2_. Sequito. The alkylamine-methyl indenyl group having 2 to 20 carbon atoms which may have a substituent is represented by -CO-NR6QaR61a, and R is a group which independently represents a hydrogen atom or may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the alkyl group of the above-mentioned ruthenium (1) and R12a. Specific examples of the alkylaminecarbamyl group include methylamine methyl sulfonyl group, ethyl amine fluorenyl group, phenethylamine methyl fluorenyl group, 2-ethylhexylamine carbaryl group, and 2-ethyl group. Oxyethylamine carbenyl, 2-(2-ethoxyethoxy)ethylaminecarbamyl, and the like. The arylaminecarbamyl group having 7 to 30 carbon atoms which may have a substituent is represented by _C0_NR62aR63a, and R62a represents an alkyl group which may have a substituent H R63a and which may have a hydrogen atom, may have a substituent, and may have a substituent. base. The preferred carbon number of the alkyl group, which may have a substituent, may be the same as the substituent which the above-mentioned Rlla 101110090 86 201245131 R12a may have. The preferred carbon number of the aryl group and the substituent which may be present are the same as those exemplified in the case of the above aryl group of R13a. Specific examples of the arylamine fluorenyl group include a phenylamine methyl fluorenyl group, a naphthylamino fluorenyl group, a p-tolylamine carbhydryl group, and a p-methoxyphenylamine fluorenyl group. The alkylamine sulfonyl group having 1 to 20 carbon atoms which may have a substituent is represented by ?S?2-NR64aR65a, and R? each independently represents a hydrogen atom or a group which may have a substituent. The preferred carbon number of the alkyl group, which may have a substituent, may be the same as the substituent which the alkyl group in the above Rlla & R12a may have. Specific examples of the alkylamine sulfonyl group include a mercaptoamine sulfonyl group, an ethylamine hydrazino group, a phenethylamine continuation group, a 2-ethylhexylamine hydrazino group, and a 2-ethyl group. The oxyethylamine stone is only a base, 2-(2-ethyllacylethoxy)ethylamine, and the like. The arylamine sulfonyl group having 6 to 30 carbon atoms which may have a substituent is represented by -S〇2_NR66aR67a, and R66a represents an aryl group which may have a substituent. Fa represents a hydrogen atom, an alkyl group which may have a substituent, and an aryl group which may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the alkyl group in the above R11a and R12a. The preferred carbon number of the aryl group and the substituent which may be present are the same as those exemplified in the case of the above aryl group of R13a. Specific examples of the arylamine sulfonyl group include a phenylamine fluorenyl group, a naphthylamine sulfonyl group, a p-nonylphenyl sulfonyl group, a p-nonyloxyalkyl sulfonyl group, and the like. The alkoxycarbonyl group having 2 to 20 carbon atoms which may have a substituent is represented by _c〇7 R68a 101110090 87 201245131, and R68a represents an alkyl group which may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the above-mentioned alkyl group and the alkyl group. Specific examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxy group, a phenethyloxy group, a 2-ethylhexyloxycarbonyl group, and a 2-ethoxyethoxy group. , 2-(2-ethoxyethoxy)ethoxymethyl and the like. The aryloxycarbonyl group having 7 to 30 carbon atoms which may have a substituent is represented by _c〇_〇R69a, and R09a represents an aryl group which may have a substituent. The preferred carbon number of the aryl group, which may have a substituent, may be the same as the substituent of the above aryl group in R23a. Specific examples of the aryloxycarbonyl group include a phenoxycarbonyl group, a naphthyloxycarbonyl group, a p-tolyloxycarbonyl group, and a p-methoxyphenoxycarbonyl group. The fluorenyl group having 2 to 30 carbon atoms which may have a substituent is represented by -COR7Ga, and R7〇a represents an alkyl group which may have a substituent, an aryl group which may have a substituent, and a preferred carbon number of the alkyl group may have Examples of the substituent may be the same as the substituent which the alkyl group in the above R11a and Rl2a may have. The preferred carbon number of the aryl group, which may have a substituent, is the same as exemplified in the case of the above aryl group of Rlh. Specific examples of the brewing base include an ethyl hydrazino group, a benzoinyl group, and a 2-ethylhexylcarbonyl group. The alkylsulfonyl group having 1 to 3 carbon atoms which may have a substituent is represented by ·S〇2_R7la'. R713 represents an alkyl group which may have a substituent. The preferred carbon number of the alkyl group and the substituent which may be present are the same as those of the alkyl group of the above Rlla and Rlh. Specific examples of the alkylsulfonyl group include a methyl sulfonyl group, an ethylsulfonyl group, a phenethylsulfonyl group, a 2-ethylhexylsulfonyl group, and 101110090 88 201245131 2-ethoxy group. Ethylsulfonyl, 2-(2-ethoxyethoxy)ethylsulfonyl and the like. The arylsulfonyl group having 6 to 30 carbon atoms which may have a substituent is represented by -S02-R72a, and R72a represents an aryl group which may have a substituent. The preferred carbon number of the aryl group, which may have a substituent, may be the same as the substituent of the above aryl group in R23a. Specific examples of the arylsulfonyl group include a phenylsulfonyl group, a naphthylsulfonyl group, a p-tolylsulfonyl group, a p-nonoxyphenylsulfonyl group, and the like. [Specific Example of Compound (VII)] Hereinafter, preferred specific examples of the compound (VII) are shown, but the present invention is not limited thereto. [化66]

101110090 89 201245131 [Chemistry 67]

No. 2005-126529, special opening 2005-226022, special opening 2006-58701, special opening 2006-124634, special opening 2009-2180691, special opening 2009-299030, special opening 2010-1469 The ketones described in the publications of the Japanese Patent Laid-Open Publication No. 2010-152160, JP-A-2010-168531, JP-A-2010-275533, JP-A-2011-148989, JP-A-2011-148990, and JP-A-2011-148991 The azo dyes, the mis-formed pyridone azo dyes described in each of JP-A-2011-148993, and JP-A-2011-148993, the Japanese Patent Publication No. 2006-265495 The polymerized pyridone azo dye, the dimerized pyridine-azo dye described in each of JP-A-2010-170073 and JP-A-2002-275531. 101110090 90 201245131 [Other color materials] The colored resin composition of the present invention contains (A) a dye as a color material, and other color materials may be used in combination with the dye. Examples of the other color material include pigments and the like, and can be appropriately combined and used depending on the desired pixel color. For example, when a blue pixel is formed, when the dye contains the compound (II) or (VI), a violet pigment is preferably used as the pigment which can be used in combination. As the purple pigment, CI Pigment Violet 1, 1:1, 2, 2: 2, 3, 3: Bu 3: 3, 5, 5: Bu 14, 15, 16, 19, 23, 25, 27, 29, 31, 32, 37, 39, 42, 44, 47, 49, 50, etc. Among these, C.I. Pigment Violet 19, 23, etc. are preferable, and C.I. Pigment Violet 23 etc. are more preferable. Further, when the blue pixel is formed, when the dye contains the compound (III) to (V), a blue pigment is preferably used as the pigment which can be used in combination. Examples of the blue pigment include CI Pigment Blue 1, 1: 2, 9, 14, 15, 15 : 1 , 15 : 2 , 15 : 3 , 15 : 4 , 15 : 6 , 16 , 17 , 19 , 25, 27, 28, 29, 33, 35, 36, 56, 56: 1, 60, 61, 61: 1, 62, 63, 66, 67, 68, 71, 72, 73, 74, 75 '76, 78, 79, etc. Among these, a blue copper phthalocyanine pigment is preferable, and as the copper phthalocyanine pigment, CI Pigment Blue 15, 15: 1, 15: 2, 15: 3, 15: 4, 15 is preferably exemplified. : 6 etc., more preferably CI Pigment Blue 15: 6. Further, in the case of forming a green pixel, in the case where the dye contains the compound (VII) 101110090 91 201245131, it is preferable to use green halogen as the pigment which can be used in combination. As the green pigment, CL pigment green 1, 2, 4, 7, 8, 10, 13, Η, 15, 17, 18, 19, 26, 36, 45, 48, 50, 5, 54, 55, 58 and so on. Among these, 'preferably CI. Pigment Green 7, 7, 58, and the like. Particularly in the case of using C.I. Pigment Green 58, it is preferable in terms of easily obtaining the effects of the present invention. Further, a yellow pigment or a red pigment or the like may be appropriately contained. As such pigments, for example, the pigments described in JP-A-2009-25813 can be used. Further, when the pigment is contained in the color material, the average particle diameter of the pigment is usually 100 nm or less, preferably 80 nm or less, more preferably 2 Å nm or more and 70 nm or less. The present invention is particularly effective in the case of a composition containing a highly micronized pigment, and therefore it is particularly preferable to include a pigment having an average-secondary particle diameter of 2 〇 nm or more and 60 nm or less. By setting the average primary particle diameter of the pigment to be used in the above range, it is possible to obtain a pigment which exhibits excellent depolarization characteristics, high contrast, transmittance, and the like, and which has excellent dispersion stability and excellent heat resistance and light resistance. Dispersion and coloring resin composition. Further, the primary particle diameter of the pigment can be obtained by the following method. First, the pigment was ultrasonically dispersed in a gas imitation, dropped on a web to which a rubber film was attached, dried, and observed by a transmission electron microscope (TEM, Transmission Electron Microscopy) to obtain a primary particle of the pigment 101110090 92 201245131 Like. In the case of an organic pigment, the particle diameter of each pigment particle is defined as an area circle equivalent diameter of a circle of the same area, and a plurality of (usually about 200 to 300) pigment particles are obtained. path. Using the value of the obtained primary particle diameter, the average value is calculated as shown in the following calculation formula, and the average particle diameter is determined. [Number 1] Particle diameter of each pigment particle: ..., xl5...xm Average particle diameter / mi = l The pigment thus obtained may be used singly or in combination within the range of the effect of the present invention. Two or more kinds of pigments. (Content of Color Material) The content of the color material contained in the colored resin composition of the present invention varies depending on the desired pixel color, for example, the total content of the above (A) dye and other color materials, relative to all solid parts. It is usually 1% by weight or more, preferably 3% by weight or more, more preferably 5% by weight or more, still more preferably 50% by weight or less, still more preferably 40% by weight or less, still more preferably 30% by weight or less. When it is within the above range, the film thickness is moderate with respect to the color density, and it is easy to control the gap at the time of liquid crystal cell formation. Further, it is preferable because it has high dispersion stability and is less likely to cause re-aggregation or thickening. [(8) Solvent] The solvent (B) in the present invention has a function of dissolving or dispersing each component contained in the colored resin composition and adjusting the viscosity. 101110090 93 201245131 As the (B) solvent, as long as >&> is required, combined or dispersed to form a colored resin composition or a knife, it is preferable to select a range of 100 to 200 ° C. By. More preferably, the boiling point is 120~ι7〇ΐ. As such a solvent, for example, the following may be mentioned. Ethyl alcohol, single ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monopropyl bond, ethylene glycol monobutyl ether, propylene glycol monoterpene ether, propylene glycol - single third butyl ether, diethylene glycol single 曱 mystery, two ^ two Alcohol monoethyl hydrazine, methoxymethylpentanol, propylene glycol monoethyl hydrazine, dipropanol early B (tetra), dipropylene glycol monomethyl n-decyl _3_ decyloxybutanol, tripropylene glycol monoterpene ether Glycol monoalkyl ethers; ethylene glycol monohydrazine, ethylene glycol diacetamidine, diethylene glycol dimethyl diacetate, diethylene glycol di "'diethylene glycol di(tetra), diethylene glycol Classes of diol dialkyl ethers; ethylene glycol monoacetic acid vinegar, ethylene glycol monoacetic acid vinegar, propylene glycol monomethyl ether acetate S, propylene glycol monoethyl ether acetate g, propylene glycol mono (tetra) acetic acid vinegar, acetic acid Oxybutanol, acetic acid 3-methoxybutyrate, methoxyacetic acid acetate, diethylene glycol monoacetic acid acetic acid, diethylene glycol monobutyl acetate, dipropylene glycol monomethyl acetic acid Glycol-burning acetates such as acetic acid 3·methyl·3_methoxybutyl ester; diethyl ether, dipropyl ether, diisopropyl ether, dipentyl ether, ethyl isobutyl ether, dihexyl Ether such as ether ; acetone, methyl ethyl ketone, decyl ketone, methyl isopropanone, methyl isoamyl ketone, diisopropanone, diisobutyl ketone, methyl isobutyl ketone, cyclohexanone, ethyl pentanone, methyl 101110090 94 201245131 Ketones such as basal, methylhexyl, decyl fluorenone; ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, Monohydric or polyhydric alcohols such as glycerin; aliphatic hydrocarbons such as 戍 戍, Zheng Xin Yuan, diisobutylene, n-hexan, hexan, isoprene, pentane, undecane; , alicyclic hydrocarbons such as methylcyclohexane, methylcyclohexene, and cyclohexyl; & aromatic hydrocarbons such as benzophenone, mono-toluene, and cumene; Ethyl formate, ethyl acetate, butyl acetate, propyl acetate, pentyl acetate, isotonic acid 曱, glycol acetic acid s, propionic acid s, propionate propyl vinegar, butyrate butyrate I, Butyric acid butyric acid, isoflavone@, octanoic acid, butyl succinate, benzo ghg, 3 ethoxy propionate, 3, ethoxy propionate, 3 -methoxypropane a chain or cyclic ester such as methyl ester, ethyl 3-methoxypropionate, propyl 3-methoxypropionate, butyl 3-methoxypropionate or tau-butyrolactone; Alkoxylates of carboxylic acid such as 3-methoxypropionate or 3-ethoxypropionate; dentate hydrocarbons such as gas butane and chloropentane; Ether ketones; nitriles such as acetonitrile or benzoquinone;

As a solvent equivalent to the above-mentioned commercially available ones, there may be mentioned mineral spirits, BARSOL #2, Apco #18 solvent, Apco diluent, Socal solvent No.l and Νο.2, SolveSSO#150, ShellTS28 solvent, carbitol. , Ethyl carbitol, Ding 101110090 95 201245131 Kikabi Alcohol, Acrylic Cyrus, Ethyl Cyrus, Ethyl Acetate Acetate, Mercapto Luce Acetate, Diethylene Glycol Dimethyl ether (all trade names) and the like. The 5 HAI·# solvent may be used alone or in combination of two or more. Among the above solvents, in view of the solubility of the dye of the above (8) of the present invention, a diol monoalkyl ether is preferred. Among them, propylene glycol monoterpene ether is particularly preferable in terms of solubility of various constituents in the composition. Further, for example, when a pigment described later is contained as an optional component, the balance between coating application, surface tension, and the like is good, and the solubility of the constituent components in the composition is relatively good. The alcohol burns ether acetate as a solvent. Further, in the composition containing a pigment, the diol monoalkyl ether has a high polarity, and tends to aggregate the pigment, and the viscosity of the colored resin composition is increased to lower the storage stability. Therefore, the amount of the diol monoalkyl ether to be used is not excessive, and the ratio of the diol monoalkyl ether in the solvent (B) is preferably 5 to 50% by weight, more preferably 5 to 3% by weight. Further, from the viewpoint of the adaptability to the slit coating method of a large substrate or the like recently, it is also preferable to use a solvent having a boiling point of 15 〇〇 c or more. In this case, the content of such a high boiling point solvent is preferably from 3 to 50% by weight based on the total amount of the solvent (B). /. More preferably, it is 5~4〇% by weight, especially preferably 5~3〇 Reset °/. . When the amount of the high-boiling solvent is too small, for example, the dye component is equal to the possibility of precipitation or solidification of the tip end of the slit nozzle to cause foreign matter defects, and if too large, the drying speed of the composition is slow, and color filtering is described later. In the sheet manufacturing step, the process of the vacuum drying step is poor, or the pre-baked pore marks 101110090 96 201245131 and the like. Further, the solvent having a boiling point of 150 ° C or higher may be a glycol alkyl ether acetate or a glycol, and in this case, it may not contain a solvent having a boiling point of 15 or more. In the colored resin composition of the present invention, the content of the solvent (B) is not particularly limited, and the upper limit is usually set to 99% by weight. When the content of the solvent (B) in the composition exceeds 99% by weight, the concentration of each component other than the solvent (B) becomes too small, and it is not suitable for forming a coating film. On the other hand, the lower limit of the content of the solvent (B) is usually 75 wt%, preferably 80 wt%, more preferably 82 wt%, in view of the viscosity suitable for coating or the like. [(C) Adhesive Resin] (C) The adhesive resin is preferably a resin depending on the curing means. In the case where the colored resin composition of the present invention is a photopolymerizable resin composition, 'as a binder resin (C), for example, Japanese Patent Laid-Open No. Hei 7-207211, No. Hei 8-259876, and No. Hei 10-300922 The polymer compound described in each of the publications of the Japanese Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The resins (C-1) to (C-5) are described. (C-1): an unsaturated monobasic acid is added to the epoxy group of the copolymer with respect to a copolymer of an epoxy group-containing (fluorenyl) acrylate and another radical polymerizable monomer. a resin obtained by at least a part of the resin or a polybasic acid anhydride obtained by adding at least a part of the hydroxyl group formed by the addition reaction, 101110090 97 201245131 (hereinafter referred to as "resin (c))" (C-2). A linear alkali-soluble resin containing a carboxyl group (c_ "Resin (C-2)") (C3) Adding a 3 % oxy-unsaturated compound to the above tree Resin based on the base part (hereinafter referred to as "resin (c_3)" (C-4) · (mercapto) acrylic resin (hereinafter referred to as "tree wax (shape))") Resin (C-5). A propylene oxide resin having a slow-base (hereinafter referred to as (C-5).) Among them, a resin (C_1) is exemplified, and the resin will be described below. The resin (C-2) to (C-5) may be any one which is soluble in an alkaline developer and has a solubility to the extent that the target development treatment is completed. It is the same as that of the same item in the Japanese Patent Laid-Open Publication No. 2009-025813. The preferred embodiment is the same. (C-1): relative to the epoxy group-containing (meth) acrylate, and other freedoms a copolymer of a base polymerizable monomer, a resin obtained by adding an unsaturated monobasic acid to at least a part of an epoxy group of the copolymer, or a polybasic acid anhydride added to be formed by the addition reaction The alkali-soluble tree obtained on at least a part of the hydroxyl group is one of the resins which are particularly preferable as the resin (C-1), and it is exemplified by 5 to 90 mol with respect to the epoxy group-containing (meth) acrylate. %, a copolymer of 1% to 95% by mole with other radical polymerizable monomers, and an unsaturated monobasic acid is added to 10 to 100 mol% of the epoxy group of the total 98 101110090 201245131 polymer a resin obtained by adding a polybasic acid anhydride to an alkali-soluble resin obtained by 10 to 100 mol% of a hydroxyl group formed by the addition reaction. As the epoxy group-containing (fluorenyl) acrylate For example, (曱-based) glycidyl acrylate, ( (3)-butyl butyl acrylate, (3,4-epoxycyclohexyl) decyl (meth) acrylate, 4-hydroxybutyl epoxide (meth) acrylate, etc. The epoxy group-containing (fluorenyl) acrylate may be used singly or in combination of two or more kinds thereof as the epoxy group-containing (meth) group. The other radical polymerizable monomer to which the acrylate is copolymerized is not particularly limited as long as the effects of the present invention are not impaired, and examples thereof include a vinyl aromatic type, a diene type, and a (meth) acrylate type. a decyl acrylate, a vinyl compound, an unsaturated dicarboxylic acid diester, a mono-n-butylene diimine, etc., and a mono-methyl group having a structure represented by the following formula (7) is particularly preferable. )Acrylate. The repeating unit derived from a mono(indenyl) acrylate having a structure represented by the following formula (7) is preferably contained in a repeating unit derived from "other radical polymerizable monomer", preferably 5 to 90%. The ear %, more preferably contains 10 to 70 mol%, and particularly preferably contains 15 to 50 mol%. H2C=C—C—R90

II 0 101110090 99 (7) 201245131 In the above formula (7), R89 represents a hydrogen atom or a methyl group, and R90 represents a structure represented by the following formula (8). [化69]

In the above formula (8), R91 to R98 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. Furthermore, R96 and R98 can be linked to each other to form a ring. The ring formed by the linking of R96 and R98 is preferably an aliphatic ring, either saturated or unsaturated, more preferably having a carbon number of 5 to 6. Among them, in the structure represented by the formula (8), those represented by the following structural formulae (8a), (8b), or (8c) are particularly preferable. [化70]

101110090 100 201245131 Further, the mono(methyl)thene sulphate having the structure of the above formula (8) may be used singly or in combination of two or more. As the "other radical polymerizable monomer" other than the mono(methyl)acrylic acid st having the structure represented by the above formula (8), the colored resin group can be improved in terms of properties and strength. Examples thereof include: phenethyl hydrazine, (meth) enoic acid-n-butyl vinegar, (meth)acrylic acid _ third butyl vinegar, (meth) propylene hydrazine; hexyl vinegar, (meth) acrylic acid isoborneol g, (methyl) propyl acetoacetate vinegar, (methacrylic acid vinegar, (mercapto) propionate 2 • trans-ethyl vinegar, N-phenyl cis-butyl diimide, imine, N-ring The content of at least one repeating mono which is selected from the above monomer group is preferably from 1 to 70 mol%, more preferably from 3 to 50 mol%/〇. The copolymerization process of the above-mentioned epoxy group-containing (meth) acrylate and the above other radical polymerizable monomer can be carried out by a known polymerization method. In the present invention, as the above epoxy group-containing a copolymer of (mercapto) acrylic acid vinegar and the above other free-fild monomer, preferably containing 5 to 9 mole % of the repeating unit derived from the epoxy group-containing (meth) acrylate. The repeating unit derived from the other radical polymerizable monomer is from 1% to 95% by mole, more preferably from 20 to 80% by mole of the former, and from 8% to 2% by mole of the latter, particularly preferably The former is 30 to 70% by mole, and the latter is 70 to 30%. If it is within the above range, the amount of addition of the polymerizable component and the soluble component to be described later is sufficiently ', and heat resistance or strength is sufficient. Preferably, the epoxy group 101110090 101 201245131 of the epoxy group-containing copolymer synthesized in the above manner is reacted with an unsaturated-acid acid (polymerizable component soluble component). The reaction is further combined with a polybasic acid anhydride (alkali here). As an example of the addition of the ring to the ring, for example, the unsaturated acid of the bauxite can be used as a specific example, and the unsaturated unsaturated acid of the ship-unsaturated double bond can be used. Methyl M dilute acid, crotonic acid, o-, m-, phenyl, or cyano, etc. = 2: base, alkoxy, dentate atom, good (曱基(四)料单魏, etc. .)) C can be used alone in β, or can be used in combination with 2 to increase the age. The resin-polymerizable monobasic acid is usually added to the epoxy group of the above-mentioned copolymer to 〜100 mol%, preferably 3 〇~ 〜100 mol%. If it is in Wudou/. It is preferable that the colored resin composition is in the range of 50 Å, and further, as a method of adding an unsaturated-acid acid to the epoxy group of the copolymer, a known method can be employed. Further, 'the polybasic acid anhydride in the prefecture which is formed when the unsaturated-acid acid is added to the ring gas group of the copolymer is known. For example, maleic anhydride and the like are mentioned. _ wild, itaconic acid liver, o-benzene di-acid acid, tetrahydrophthalic acid liver, hexahydrophthalic anhydride, chloralic acid anhydride and other dibasic anhydrides, trimellitic anhydride, pyromellitic anhydride, two An acid anhydride of a three-phase acid such as phenylindole tetraacic anhydride or biphenyl tetraacetic anhydride. Preferably, it is 101U0090 102 201245131 and a tetra-phthalic acid needle. One type of these polybasic acids may be used in combination of two or more. The addition of an alkali soluble hydrazine to such a component can be imparted to the present invention using a silky resin, which is usually added by adding an unsaturated-it acid to the above-mentioned "polymer" having an epoxy group. The generated reduction of 10~1〇〇莫耳/〇车 is preferably 20~9〇莫耳%, more preferably 3〇~8〇莫耳%. Right in the above-mentioned crimes Since the film ratio and the solubility are sufficient, a method of adding a polybasic acid anhydride to the hydroxyl group may be employed. Further, in order to increase the photosensitivity, the polybasic acid anhydride may be added after the addition of the polybasic acid anhydride. The formed slow-radical-partially added (meth)acrylic acid propylene glycol or a propylene-propylene compound having a polymerizable unsaturated group. Regarding the structure of such a resin, for example, Japanese Patent Laid-Open No. Hei 8_297366 No. 2001-89533 discloses the above-mentioned adhesive resin (ci) using GPC (Gel Permeati〇n)

The weight average molecular weight (Mw) measured by Chromatography (Polycol Penetration Chromatography) in terms of polystyrene is preferably from 3 Å to 1 Torr, particularly preferably from 5,000 to 50,000. If the molecular weight is less than 3,000, the heat or film strength may be deteriorated. If it exceeds 1 〇 (), the solubility in the developer tends to be insufficient. Further, as a standard of the molecular weight distribution, the weight average molecular weight of 101110090 103 201245131 _ 〇 / number average good amount (Mn) is preferably 2.0 to 5.0. Further, the acid value of the binder resin (ci) is usually from 1 〇 to 2 〇〇 mg_K 〇 H / g, preferably from 15 to 15 〇 mg-KOH / g, more preferably from 25 to 1 〇〇 mg_K 〇 H / Ge If the value of 'the father is too low', the solubility in the developer is lowered. On the contrary, if the ground is too high, there is a case where the film becomes rough. The content of the (C) binder resin is usually 〇丨 8 8% by weight, preferably 1 〇 6 〇 〇 / 0 in all solid parts. When it is in the above range, it is preferable in that the adhesion to the substrate is good, the penetration of the developer in the exposed portion is moderate, and the surface smoothness or sensitivity of the pixel is good. [(E) Polymerizable monomer] The colored resin composition of the present invention contains (E) a polymerizable monomer, which is preferable in terms of easy control of the crosslinking density in the film. A well-known material can be used as the (E) polymerizable monomer, and a compound having an ethylenically unsaturated double bond is preferable in terms of a low dark reactivity in the colored resin composition. In the case where the colored resin composition of the present invention is irradiated with active light, the compound having an ethylenic double bond, such as addition polymerization and hardening, is carried out by the action of a photopolymerization starting component described later. Further, the (E) polymerizable monomer in the present invention means a dimer, a trimer or an oligomer in addition to the narrowly defined monomer with respect to the concept of a so-called high molecular substance. Examples of the ethylenic compound include unsaturated 101110090, such as (mercapto)acrylic acid, 102, 2012, 00, 00, 00, 00, 00, 00, 00, 00, 00, 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00; An ester of a hydroxy compound and an unsaturated carboxylic acid; an ester obtained by a reaction of an unsaturated carboxylic acid, a polyvalent carboxylic acid, a polyvalent hydroxy compound, or an aromatic poly-based compound such as an aromatic poly-based compound; The polyisocyanate compound is reacted with (meth) propyl group and has a carbamate (4). σ is an aliphatic poly-based compound and an unsaturated hydrazine. (meth) propionate, triethylene glycol di(meth)acrylic acid vinegar, +triethyl:yl=tris(methyl) Acrylate, trimethyl ketone) C: 曰, 戊 叫 二 (methyl) propyl _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _酉 、, dipentaerythritol hexahydrate (methyl ketone, propyl sulphur, glycerol (meth) acrylate vinegar and other (meth) acrylate soil) can be cited as: the state of the base acid called methyl) handsome = partial replacement of the clothing The purpose of the coffee, the diced _ Department: itaconic acid vinegar, or _ dilute acid part of the succinic acid.. maleic acid ester and so on. - As a matter of the (4) base compound, it is possible to use a monophenolic (meth) acrylate or a resorcinol dibenzoic acid (tetra) (tetra) acid material. - (Methyl) propyl axis, o. 101110090, which can be obtained as a mono-substance by unsaturated carboxylic acid, polycarboxylic acid and poly- carboxylic acid, or may be: = 2 105 201245131, for example, a condensate of acrylic acid, phthalic acid, and ethylene glycol; a condensate of (meth)acrylic acid, maleic acid, and diethylene glycol; (mercapto)acrylic acid, terephthalic acid And a condensate of pentaerythritol; a condensate of (meth)acrylic acid, adipic acid, butanediol, and glycerin. Examples of the ethylenic compound having a urethane skeleton obtained by reacting a polyisocyanate compound with a hydroxy compound containing a (fluorenyl) acrylonitrile group include hexamethylene diisocyanate and tridecyl hexamethylene. An aliphatic diisocyanate such as a diisocyanate; an alicyclic diisocyanate such as cyclohexane diisocyanate or isophorone diisocyanate; an aromatic diisocyanate such as anthraquinone diisocyanate or diphenyldecane diisocyanate; and (meth) A reaction product of a (meth) propyl sulfhydryl group-containing compound such as 2-hydroxyethyl acrylate or 3-hydroxy[1,1,1-tris(indenyl)acrylenyloxyindenyl]propane. In addition, examples of the ethylenic compound used in the present invention include exoethyl bis(meth)acrylamide or the like (mercapto) acrylamide; and olefin such as diallyl phthalate; a propyl ester or a vinyl group-containing compound such as divinyl phthalate. Among these, an ester of an aliphatic polyhydroxy compound and an unsaturated carboxylic acid is preferred, and a (mercapto) acrylate of pentaerythritol or dipentaerythritol is more preferred, and dipentaerythritol hexakis(meth) acrylate is preferred. Further, the ethylenic compound may also be a monomer having an acid value. As the monomer having an acid value, for example, an ester of an aliphatic polyhydroxy compound and an unsaturated carboxylic acid, it is preferred to react an unreacted hydroxyl group of the aliphatic poly-based compound with a non-aromatic hydrazine 101110090 106 201245131 acid anhydride. The polyfunctional monomer having an acid group is particularly preferably one in which the 'aliphatic poly-based compound is pentaerythritol and/or dipentaerythritol. These monomers may be used singly, but in the case where it is difficult to obtain a single compound in the production, a mixture of two or more kinds may be used. Again, according to. It is necessary to use, as the (8) polymerizable monomer, a polyfunctional monomer having no acid group and a polyfunctional monomer having an acid group. The preferred acid value of the polyfunctional monomer having an acid group is (U 4 4 mg-KOH/g, and particularly preferably 5 to 3 G mg__g. If the multi-column value is too low, the tendency to reduce the solubility characteristics of the product is lowered. In the case of the second system, the photopolymerization performance is also shown in the following table = the case where the hardening property is deteriorated. Therefore, when two or more types of surface slip are used together, or if they are used together, they do not have the same material. The acid group of the multi-material material body is in the above-mentioned Fans == 'more preferable polyfunctional single system East Asian synthetic male vinegar, di-penta (10):: commercially available dipentaerythritol hexa-acrylic acid - five Propylene g-ester, dipentaerythritol penta-propyl

Sx sB is a mixture of main materials. It can also be combined to make it a multi-functional monomer. In the case of the flat resin and the colored resin composition, the 篁' is usually (10) or more in all the solid parts, preferably = 101110090 107 201245131, preferably 7% by weight or less by weight. More preferably 50 weight. The following 'more preferably 40 ° sex early body is usually more than 1% by weight, preferably 5% by weight, 1 jin, more than 2% by weight, more preferably 2% by weight, and usually more ^' Preferably, it is 1 (9)% by weight or less, more preferably 8 〇^%= If it is within the above range, the light effect is sufficient, and the adhesion is not easy to be caused, and the cross section is not easily formed into an inverted cone shape. Further, it is preferable that the peeling phenomenon, the peeling failure, and the like caused by the decrease in solubility are less likely to occur, etc. [(F) Photopolymerization starting component and/or silky starting component] In order to make the present invention The coating film hardening of the colored resin composition preferably includes at least one of (F) a photopolymerization starting component and a thermal polymerization starting component, but a further modification may also be performed by the initiators Other than the method of the present invention, especially when the resin of the present invention contains a resin having an ethylene double bond as the component (c) or a compound containing an ethylene compound as the component (E) The cross-linking contains a direct absorption light, or a photo-sensitization-induced decomposition reaction or hydrogen abstraction. A photopolymerization starting component which generates a function of polymerizing a living radical and/or a thermal polymerization starting component which generates a living radical by heat generation. Further, in the present invention, as a photopolymerization starting component ( The component F) means a polymerization accelerator (hereinafter referred to as a component (F1) arbitrarily referred to as a component (F1)), and a sensitizing dye (hereinafter referred to as 101110090 108 201245131 (hereinafter referred to as arbitrarily). F3) a mixture of additives such as a component. (Photopolymerization starting component) The colored resin composition of the present invention preferably contains (F) a photopolymerization starting component. As a photopolymerization starting component, (F1) photopolymerization is usually used. A mixture of an initiator, an additive such as (F2) a polymerization accelerator, and a (F3) sensitizing dye added as needed, which directly absorbs light or undergoes photo-sensitization to cause a decomposition reaction or a hydrogen abstraction reaction to cause polymerization. The component of the function of the active radicals. The (F1) photopolymerization initiator which is a photopolymerization starting component, for example, is disclosed in JP-A-59-152396, JP-A-61-151197, and the like. Documented The hexaarylbiimidazole derivatives described in Japanese Patent Laid-Open No. Hei 10-300922, JP-A-H11-174224, JP-A-2000-56118, and the like; A halogenated oxadiazole derivative, a halogenated thiol-second third cultivating derivative, or an N-aryl-α-amino group such as N-phenylglycine, as described in Japanese Laid-Open Patent Publication No. 10-39503 Free radical activators such as acid, sulfonium-aryl-α-amino acid salts, fluorene-aryl-α-amino acid esters, α-amino benzophenone derivatives; Japanese Patent Special Open 2000 An oxime ester derivative or the like described in the publication No. 80068 or the like. Specifically, for example, a photopolymerization initiator described in International Publication No. 2009/107734 or the like can be mentioned. Among the photopolymerization initiators, more preferred are aminoalkylphenone derivatives, oxime ester derivatives, biimidazole derivatives, acetophenone derivatives, and 9-oxopurine derivatives. Things. 101110090 109 201245131 Further, 'as an oxime ester derivative, 1,2-octanedione, iota-[4-(phenylthio)phenyl]-, 2-(o-benzoquinone), ethyl ketone , 1-[9-ethyl-6-(2-methylphenylhydrazone)-9Η-σ card π-spin-3-yl], 1-(o-ethylidene:), and the like. In addition, examples thereof include benzoin ethers and anthracene derivatives; and acetophenone derivatives such as 2-mercapto-(4'-nonylthiophenyl)_2-carbolinyl-1-propanone; 2-Ethyl 9-oxosulfonate p-star, 2,4-diethyl 9-oxothiop-p-p-star, etc. 9-oxo-sulfur p-p-star derivatives, benzoate derivatives. Hey. Derivatives, morphine derivatives, anthrone derivatives, and the like. Among these photopolymerization initiators, α-aminoalkylbenzoyl derivatives, 9-oxosulfonate hawthorn derivatives, and oxime ester derivatives are more preferred. It is especially preferred to be an oxime ester derivative. Examples of the (F2) polymerization accelerator to be used as needed include hydrazine, hydrazine-dimethylamino benzoate, and the like, hydrazine dialkylamino benzoic acid alkyl esters; 2-mercaptobenzoene a sulfhydryl compound having a heterocyclic ring such as thiazole, 2-mercaptobenzoxazole or 2-mercaptobenzimidazole; or a mercapto compound such as an aliphatic polyfunctional fluorenyl compound. These (F1) photopolymerization initiators and (F2) polymerization accelerators may be used alone or in combination of two or more. Further, (F3) a sensitizing dye is used to increase the sensitivity of the induction as needed. The sensitizing dye can be used in accordance with the wavelength of the image-exposure light source. For example, the ρ ρ 星 色素 色素 色素 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Japanese Patent Application Laid-Open No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei. The 3-keto coumarin dye described in the publication of the Japanese Patent Laid-Open Publication No. Hei 6-19240, and the like. No. 54-155292, Special Public Show No. 45-37377, Special Open No. 48-84183, Special Open No. 52-112681, Special Open No. 58-15503, Special Open No. 60-88005, Special Open 59- Dialkylamines as described in each of the publications of Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A pigment such as a benzene skeleton. (F3) The sensitizing dye may be used singly or in combination of two or more. In the colored resin composition of the present invention, the content of the (F) photopolymerization starting component is usually 0.1% by weight or more, preferably 0.2% by weight or more, more preferably 0.5% by weight based on the total of the solid content. The above is usually 40% by weight or less, preferably 30% by weight or less, and more preferably 20% by weight or less. When it is in the above range, it is preferable that the sensitivity to the exposure light is good, and the solubility of the unexposed portion in the developer is sufficient, and development failure is unlikely to occur. (Thermal polymerization starting component) Specific examples of the thermal polymerization starting component (thermal polymerization initiator) which can be contained in the colored resin composition of the present invention include an azo compound and an organic 101110090 111 201245131 peroxide. And hydrogen peroxide and the like. Among these, an azo compound can be preferably used. More specifically, for example, a thermal polymerization initiator described in, for example, International Publication No. 2009/107734 can be used. These thermal polymerization initiators may be used alone or in combination of two or more. [Optional Component] The colored resin composition of the present invention may contain, in addition to the above components, a surfactant, an organic carboxylic acid, and/or an organic carboxylic anhydride, a thermosetting compound, a plasticizer, or the like as described above in the present invention. (A) a dye other than a dye, a thermal polymerization inhibitor, a storage stabilizer, a surface protective agent, a adhesion enhancer, a development improver, etc., and may contain a dispersant or a knife auxiliary when a pigment is used as a pigment. . As the above-mentioned arbitrary components, various compounds described in, for example, Japanese Patent Laid-Open Publication No. Hei No. 7-11-1-1 can be used. [Dispersing agent] When the coloring resin composition of the hairs contains a pigment, it preferably contains a dispersing agent. The dispersant in the class is particularly limited as long as it can disperse and stabilize the pigment. For example, a cationic type or an anionic type dispersing agent can be used, and a polymorphic octagonal or amphoteric polymer can be used, and examples thereof include a block acid vine salt, a cation (four), a silk ammonium salt of a polymer copolymer, or a good block (IV). #ρ余船聚合料. In the dispersant, the material, the polyamino group, and the cationic dentate grafted poly 101110090 112 201245131. More preferably, it is a block copolymer, and among them, a block copolymer comprising a solvophilic A block and a B block having a functional group containing a nitrogen atom is preferred. Specifically, examples of the B block having a functional group containing a nitrogen atom include a unit structure having a quaternary ammonium salt group and/or an amine group in a side chain, and on the other hand, a solvophilic A-inlay. Examples of the segment include a unit structure having no quaternary ammonium salt group and an amine group. The B block constituting the acrylic block copolymer has a unit structure containing a quaternary ammonium salt group and/or an amine group, and a site having a pigment adsorption function. Further, in the case where the B block contains a quaternary ammonium salt group, the quaternary ammonium salt group may be directly bonded to the main chain or may be bonded to the main chain via a divalent linking group. As such a block copolymer, for example, those described in JP-A-2009-025813 can be cited. Further, the colored resin composition of the present invention may contain a dispersing agent other than the above. As the other dispersing agent, for example, those described in JP-A-2006-343648 can be cited. In the case where the colored resin composition of the present invention contains a pigment, it is preferred that the content of the dispersing agent in all solid parts is 2 to 1000% by weight, particularly 5 to 500% by weight, especially 10%, based on the total content of the pigment. A dispersant is used in a range of 250% by weight. When it is in the above range, the heat resistance of the dye is not affected, the pigment dispersibility is ensured, and the dispersion stability of the pigment is further improved. 101110090 113 201245131 [Dispersing Aid] The dispersing aid may be contained in the colored resin composition of the present invention. The dispersing aid herein may be a pigment derivative, and as the pigment derivative, for example, JP-A-2001-220520, JP-A-2001-271004, JP-A-2002-179976, JP-A 2007 Various compounds and the like described in Japanese Laid-Open Patent Publication No. H07-186681, and the like. Further, the content of the dispersing aid in the colored resin composition of the present invention is usually 0.1% by weight or more, and usually 3 % by weight or less, preferably 20% by weight or less based on the total solid content of the pigment. More preferably, it is 10% by weight or less and further preferably 5% by weight or less. By controlling the amount of addition to the above range, it is preferable to exhibit the effect as a dispersing aid and to further improve the dispersibility and dispersion stability. [Dispersion Resin] The colored resin composition of the present invention may contain a part or all of a resin selected from the above (c) bonded tree sorghum or other adhesive resin as the following dispersion tree-- In the L-Taste Resin 驵 物 & 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵 驵As a result, the amount of the dispersant added can be reduced, which is preferable. Further 4:: It is better to improve the non-pixel portion of the substrate, such as Γ:: 114 201245131 The adhesion of the board is improved. Thus, the (c) binder resin used in the dispersion treatment step is sometimes referred to as a dispersion resin. The amount of the dispersion resin relative to the total amount of the pigment in the colored resin composition is preferably from about 0 to about 2% by weight, more preferably from about 1 to about 10% by weight. [Method for Producing Colored Resin Composition] In the present invention, the colored resin composition can be produced by a suitable method, for example, by the above (A) dye, (c) a binder resin, and P containing the compound (1). The chain transfer agent is prepared by mixing together with (B) a solvent and other additives. In addition, as a method of producing a pigment in addition to the dye (A), a method of using a pigment in a solvent, a dispersing agent, and a dispersing aid added as needed may be used as a part of the case. (C) The binder resin' is a mixture of, for example, a paint shaker, a sand mill, a ball mill, a roll mill, a stone mill, a jet mill, a homogenizer, and the like, and is mixed while being pulverized. (A) dye, (C) binder resin, 1) chain transfer agent are added to the coloring dispersion, and (E) a polymerizable monomer, (F) a photopolymerization initiator, and a thermal polymerization initiator are added as needed. The additive is prepared by mixing at least one of the additives. [Application of Colored Resin Composition] The colored resin composition of the present invention is usually in a state in which all constituent components are dissolved or dispersed in a solvent. The colored resin composition is supplied onto a substrate, and is formed into a black color filter or a liquid crystal display device member by a device such as a 101110090 115 201245131 EL display device. The composition of the resin composition of the present invention is preferably an application example of the colored resin composition of the coloring tree coloring film of the color secret film, and the liquid crystal display (panel) of the coloring material and the (four) material. The organic display is not explained. <Color Filter> The light sheeting method is described in the coloring resin composition of the present invention. The pixels can be formed in various ways (four). Here, the case where the photochromic resin composition is formed by the photolithography method is exemplified as a lamp, but the method is the case. First, a black matrix is formed on the surface of the substrate in such a manner as to form a portion of the pixel, and after coating the colored resin composition of the present invention on the substrate, the film is pre-baked to dissolve and form a coating film. . After being exposed to the 5 liter coating film through the reticle, the developing solution is used for development, and the unexposed portion of the coating film is dissolved and removed, and then baked, thereby forming red, green, and blue colors. For each pixel pattern, a color filter is produced as a substrate used for forming a pixel. As long as it is transparent and has a moderate strength, 101110090 116 201245131 = no limitation, and examples thereof include a polycyclic gas tree tire and a hot money resin: ::: The equivalence tree, the moon material, and the armor may be subjected to suitable pretreatment such as a film formation treatment by a sand-burning coupler, an amine-based day, or a surface treatment such as corona discharge. The odor treatment is applied to a method of coating a colored resin composition on a substrate, and a method of coating a half-soil, a coating, a coating method, a coating method, a coating method, a coating method, etc. Preferably, the slit spin coating method and the die coating: the thickness of the coating film, as the film thickness after drying, is usually 〇.2~2〇:, preferably G.5~i〇#m, especially It is preferable that it is easy to perform the gap adjustment in the pattern development or the liquid crystal cell formation step, and it is easy to express a desired color, in the above range. For the radiation to be used, for example, visible light, ultraviolet light, far ultraviolet light, electron beam, x-ray, etc. may be used, and radiation having a wavelength in the range of 190 to 450 nm is preferably used. The image is exposed to emit a wavelength of 190 to 450 nm. The light source of the radiation is not particularly limited, and examples thereof include a xenon lamp, a tooth lamp, a tungsten lamp, a high pressure mercury lamp, an ultrahigh pressure mercury lamp, a metallization lamp, a medium pressure mercury lamp, a low pressure mercury lamp, a carbon arc lamp, and a fluorescent lamp. Equal light source; argon ion laser, Y AG (Yttrium-Aluminum-Gamet '钇-aluminum-garnet) laser, standard score 101110090 117 201245131 laser, nitrogen laser, helium-cadmium laser, semiconductor laser, etc. In the case of light of a specific wavelength, an optical filter can be used. The amount of exposure of the radiation is preferably from 10 to 10,000 J/m 2 . Further, as the above-mentioned developer, it is preferably, for example, sodium hydroxide or hydroxide. Hydrogen hydroxide, sodium carbonate, carbonic acid unloading, sodium hydrogencarbonate, potassium hydrogencarbonate, sodium sulphate, stagnation, partiality, sodium citrate, potassium citrate, sodium hydrogen hydride, scaly Inorganic basic compound such as hydrogen unloading, sodium dihydrogenate, potassium dihydrogenate, and hydrogen hydroxide; mono-, di- or tri-ethanolamine, mono-, di- or tri-decylamine, mono-, and _ or tri-ethylamine, mono- or di-isopropylamine, n-butylamine, mono-, di- or tri-isopropanolamine, ethyleneimine, ethylenediamine, hydroxide tetra An aqueous solution of an organic basic compound such as decyl ammonium (Tetramethylammonium Hydroxide) or choline. In the above alkali developing solution, an appropriate amount of, for example, isopropyl group may be added. , alcohol, ethyl celecoxib, butyl 赛路苏, stupid sulphate, di diol, diketone alcohol, etc. _ interface _ solution. _ _ usually after washing ❶ 鲰 〜 ~ as The development treatment method may be a development method, an ultrasonic development method, or the like (23. 〇, 5 to 300 seconds. : a stain development method, a spray development method, a brush brushing condition, preferably a room temperature development treatment condition. In particular, it is preferably 15 Ux, more enthalpy, and the developing temperature is usually in the range of (hereinafter, preferably 45 〇 c ^ 2 GC or more) and usually 5 〇 101110090, more preferably 40 c or less. . 118 201245131 The development method can be any method such as a dipping development method, a spray development method, a brush development method, or an ultrasonic development method. When the color filter thus produced is used in a liquid crystal display device, a transparent electrode such as ITO can be formed directly on the image, and it can be used as a part of a color display or a liquid crystal display device, but in order to improve For surface smoothness or durability, an outer coating such as polyimide or polyimide may be provided on the image as needed. Further, in some applications such as an IPS (In Plane Switching mode), a transparent electrode may not be formed. Further, in the vertical alignment type drive mode (MVA (Multi-domain Vertical Alignment) mode), a barrier wall may be formed. Further, a column structure (photosensitive spacer) by photolithography may be formed instead of the bead-dispersion type spacer. <Liquid Crystal Display Device> The liquid crystal display device of the present invention uses the above-described color calender of the present invention. The type or configuration of the liquid crystal display device of the present invention is not particularly limited, and the color filter of the present invention can be used and assembled in accordance with a conventional method. For example, the liquid crystal display device of the present invention can be formed by the method described in the "Liquid Crystal Device Handbook" (Japanese Industrial Press, September 29, 1989, issued by the Japan Society for the Promotion of Science). <Organic EL display device> In the case of producing an organic EL display device including the color filter of the present invention, for example, as shown in Fig. 1, on the transparent support substrate 10, the color of the invention was invented by the present invention 101110090 119 201245131 On the blue color filter in which the pixel 20 is formed of the resin composition, the organic light-emitting body 500 is laminated via the organic protective layer 30 and the inorganic oxide film 40, thereby producing a multi-color organic EL element. As a method of laminating the organic light-emitting body 500, a method of sequentially forming the transparent anode 50, the hole injection layer 5, the hole transport layer 52, the light-emitting layer 53, the electron injection layer 54, and the cathode 55 on the color filter may be mentioned. Or a method of bonding the organic light-emitting body 500 formed on another substrate to the inorganic oxide film 40 or the like. The organic EL device 1 thus fabricated can be applied to an organic EL display device of a passive driving type, and can also be applied to an organic EL display device of an active driving method. [Embodiment] The present invention will be specifically described by way of examples, but the present invention is not limited thereto, and is not limited to the description of the following examples. <Colored resin composition for blue pixel formation> [Synthesis of dye] (Synthesis of Compound A)

Hb 71]

Compound A (Reaction 1) 101110090 120 201245131 Compound 2 (5.02 g, 20 mmol), Compound ι (ΐ4 ml 80 mm〇i), Sodium butoxide sodium pwg, go mm〇i) in a nitrogen ring a mixture of toluene (1 〇〇 ml), acetic acid! Bar (ii) (〇.55 g, 2.45 mmol), tri-tert-butylphosphine (1% hexane solution, 10 g, 4.94 mmo) After heating to the cold portion to room temperature for 1 hour, water was added, and the mixture was filtered with brucite, and the filtrate was extracted with toluene to be washed with water. The toluene layer was concentrated under reduced pressure, and purified by Shixi gum column chromatography (Shi Xi谬 5〇〇g, hexane/acetic acid ethyl acetate 1〇/ι~8/ι~6/1), using cold 曱The obtained powder was washed with an alcohol to obtain Compound A (4.59, yield: 53%). (Synthesis Example 1: Synthesis of Dye (1)) [Chem. 72]

Adding phosphorus oxychloride (12 2 eg, 134 mmol) to a mixture of compound A (39 g, 89.3 nmi〇I), compound 3 (18 5 g, 89 3 leg 〇1), toluene (120 ml) Heating under reflux for 3.5 hours. After returning to room temperature, σ water was added, and extraction was performed with chloroform, and the chloroform layer was washed three times with saturated brine. 101110090 121 201245131 Gas imitation / sterol 15 / 1) Pure compound B (54.8 g, produced by silica gel column chromatography (300 g of phthalocyanine, solid obtained by washing with hexane, rate 93%). (Reaction 3) Compound B (29 g, 43 j hydrazino) quinone imine (12.6 g, 43 8 颜(4)^咖1), chain = bis(trifluoroanthracene 1.5 hours) was stirred at 5 ° C. Concentration by pressure, using a mixture solid of sterol alcohol 075 ml) to obtain dye (1) (33.59 g, yield 84 > 1/2 W/0 obtained by washing) (Synthesis Example 2: Dye (2) Synthesis) [Chem. 73]

Reaction 4 3 4 (Reaction 4) α dye (2)

Addition of oxygenated phosphorus (15 m 164 mmol) to a mixture of compound 4 (35.4 g '109 mmol), compound 3 (22 6 g, 1 〇 9 mmol), and methyl (200 ml) for 4 hours It is heated to reflux. After returning to room temperature, water was added and extraction was carried out by gas-mesh. The gas-like layer was washed three times with saturated brine. Pure 101110090 122 201245131 was purified by silica gel column chromatography (300 g, oxime / sterol 10/1 to 8/1), and the obtained solid was washed with hexane to obtain Compound C (20 g, yield 33%) ° (Reaction 5) Stabilize compound C (18 g, 32, 7 mmol), lithium = bis(trifluorite xanthine) quinone imine (9.4 g, 32.7 mmol) and decyl alcohol at 50 °C (reaction 5) Mixture of 60 ml) for 1 hour. The mixture was concentrated under reduced pressure, and the obtained solid was washed with methanol/water = 1/2 to obtain a dye (2) (17.7 g, yield 68%). (Synthesis Example 3: Synthesis of Dye (3)) [Chem. 74]

The compound 5 (6.0 g, 25 mmol: synthesized by the method described in International Publication No. 2008/003604) and the compound 6 (6.4 ml, 50 mmol··Tokyo Chemical Co., Ltd.) were stirred and stirred at 110 to 125 °C. , carbonic acid oblique (6.9 g, 50 mmol), N-methyl-2-0 to 17 each. A mixture of ketone (25 ml) was used for 4 hours. After cooling to room temperature, water was added, and extraction was carried out with toluene, and the toluene layer was washed with dilute hydrochloric acid and saturated brine, and dried over anhydrous sodium sulfate. Concentration under reduced pressure gave 9,2 g of pale brown oil. This oil was dissolved in ethanol (40 ml), and a solution of sodium hydroxide (2 g, 52.3 mmol) in water (25 ml) was added, and the mixture was stirred at 85 ° C for 1 hour. After allowing to cool, the mixture was extracted with benzene, and the toluene layer was washed with saturated 101110090 123 201245131 brine, and dried with anhydrous sodium sulfate. The residue was concentrated under reduced pressure and purified using silica gel column chromatography (hexane / ethyl acetate = 3/1) to afford compound 7 (5.95 g, yield 94%). [化75]

7

For compound 8 (1.47 g, 4.34 mmol: synthesized by the method described in International Publication No. 2009/107734), compound 7 (1.1 g, 4.34 mmol), toluene (30 ml), oxychloride glass (0.6 ml) The mixture was heated and refluxed for 4 hours, cooled to room temperature, and water was added thereto, followed by extraction with chloroform. The chloroform layer was concentrated under reduced pressure, and purified by silica gel column chromatography (developing solvent: chloroform / decyl alcohol = 15/1 to 10/1), and the obtained solid was washed with hexane to obtain compound 9 (1.32 g). Rate 50%). [化76]

101110090 124 201245131 A mixture of compound 9 (8.9 g, 14.6 mmol), compound 10 (4.2 g, 14.6 mmol: manufactured by Tokyo Chemical Industry Co., Ltd.) and methanol (50 ml) was mixed at 50 C for 1.5 hours, and then concentrated under reduced pressure. The solid obtained was washed with decyl alcohol/water = 1/2 to obtain a dye (3) (1) 5 g, yield 92.3%). (Synthesis Example 4: Synthesis of Dye (4)) [Chem. 77]

N-ethyl-p-anisidine (manufactured by Tokyo Chemical Industry Co., Ltd., 138 g) was dissolved in N,N-dimercaptocaramine (52 〇ml), and cooled in an ice bath, and a small amount was added each time. Potassium butoxide (115 g). Then, DMF (Dimethylformamide, dimethylformamide) of 4,4'-difluorodiphenyl ketone (manufactured by Tokyo Chemical Industry Co., Ltd., 37 g) was added dropwise for 30 minutes while cooling with an ice bath. After (180 ml) the solution, at 5 Torr. The mixture was stirred for 3 hours. Water and toluene were added, and the organic layer was separated, and the organic layer was washed with water. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. Purification was carried out to give Compound D (63.6 g) as a pale yellow solid.

Hb 78] 101110090 125 201245131

Compound D was added to a mixture of the compound D (24 g), the compound 3 (11.1 g) (manufactured by Tokyo Chemical Industry Co., Ltd.), and the benzene (130 ml), and phosphorus oxychloride (7.3 ml) (manufactured by Wako Pure Chemical Industries, Ltd.). Heating and refluxing was carried out for 5 hours. After cooling to room temperature, water was added, and extraction was carried out by gas-mesh, and the organic layer was washed three times with saturated brine. The mixture was concentrated under reduced pressure and purified by <[Lambda]>> [化79]

Dye (4) A mixture of compound E (6.66 g) and lithium = bis(trifluorosulfonyl) quinone imine (manufactured by Tokyo Chemical Industry Co., Ltd., 2.87 g) 'methanol (100 ml) was stirred at 40 °C. After a minute, concentration under reduced pressure was carried out, and the obtained solid was washed with a mixture of methanol/water (1/2) to obtain a dye (4) (6.51 g). (Synthesis Example 5: Synthesis of Dye (5)) (Synthesis of Intermediate C1) [Chem. 80] 101110090 126 201245131

Intermediate Cl

Compound D is added to the mixture of intermediate D (24 g), 1-mercapto-2-phenyl abendole (11.1 g manufactured by Tokyo Chemical Industry Co., Ltd.), and toluene (130 mi). Manufactured by Wako Pure Chemical Industries, Ltd., 7.3 ml) 'heated back for 5 hours. After cooling to room temperature, water was added, and extraction was performed with chloroform, and the organic layer was washed three times with saturated brine. After drying with anhydrous sodium sulfate, the mixture was subjected to purification under reduced pressure and purified by silica gel column chromatography (methanol / decyl alcohol = 12 / 1) to obtain Intermediate Cl (34.8 g). [化81]

A mixture of Intermediate Cl (6.0 g) and 95% sulfuric acid (9 〇 g) was stirred at 7 Torr for 6 hours, and after mixing at 8 Torr for 4 hours, it was poured into ice water to separate the precipitate by filtration. After dissolving in acetone and diluting with water, the pH was adjusted to 8 with a 1 N aqueous sodium hydroxide solution, and the mixture was dried and dried to obtain a dye 1 (5.4 g). The dye (5) is a mixture of dye (7)a and dye (5)B of 64:36 by analysis of ιΗ. [化82] 101110090 127 201245131

Mxx Dyes (5) A Dye (5) B The results of 1H NMR and MS are shown below. NMR (500 MHz, CD3OD) δ 1.25 (t, H-4), 2.39 (s, Hl), 3.88 (m, H-5, H-ll), 6.4 - 6.8 (br, H-6), 7.00 ( d, H-15), 7.12 (d, H-3), 7.23 - 7.38 (m, H-2, H-7, H-8, H-9, H-10), 7.60(d, H-12 ), 7.63 (dd, H-16), 7.71 (dH-14), 7.87 (dd, H-13), 8.11 (d, H-17) MS(LDI, posi) m/z 718 (M+H, C46H44N303S), 740 (M+Na, C46H43N3Na03S). [化83]

Dye (5) A Dye (5) B (Synthesis Example 6: Synthesis of Dye (6)) Gas (222.9 g) and N, N- were added to CI Acid Red 289 (manufactured by Tokyo Chemical Industry Co., Ltd., 22.29 g). Dimethyl decylamine (13.225 g) was added with thidium chloride (16.19 g) while maintaining the internal temperature below 20 °C. After the dropwise addition, the temperature was raised, and the reaction was carried out at 50 ° C for 5 hours, and then cooled to 20 ° C or lower, and triethylamine (32·8 g, 0.324 mol), 101110090 128 201245131 and 2 were added dropwise over 35 minutes. A mixture of ethylhexylamine (18.57 g, 0.1436 mol) was maintained at a temperature of 20 ° C or less. Thereafter, the mixture was stirred at room temperature for 5 hours. The solvent was concentrated, and decyl alcohol (15 ml) was added thereto, and the mixture was stirred well, and the mixture was poured into water (557 g) while stirring to precipitate red crystals. After the residue was redissolved in decyl alcohol, it was concentrated, and water was again added thereto to cause crystallization. The filtered crystals were washed once with water (300 ml) and dried under reduced pressure to obtain a dye (6) (21.823 g) 〇 [Chem. 84]

(Reference Synthesis Example 1: Synthesis of Resin A) One surface of propylene glycol monoterpene ether acetate (145 parts by weight) was stirred with nitrogen and heated to 120 °C. 82 parts by weight of styrene (20 parts by weight), glycidyl methacrylate (57 parts by weight), and monoacrylic acid vinegar (FA-513M manufactured by Hitachi Chemical Co., Ltd.) having a tricyclodecane skeleton were added dropwise thereto. Stirring was continued for 2 hours at 120 °C. Then, the air in the reaction vessel was replaced with trisylamino decylphenol (0.7 parts by weight) and hydroquinone (0.12 parts by weight) in 27 parts by weight of acrylic acid, and the reaction was continued at 120 ° C for 6 hours. Thereafter, 101110090 129 201245131 52 parts by weight of Tetrahydrophthalic anhydride and triethylamine (0.7 parts by weight) were added, and the mixture was reacted at 120 ° C for 3.5 hours. The weight average molecular weight Mw of the resin A thus obtained measured by GPG was about 15,000. The structure of the resin A is as follows (a polymer compound containing the following four kinds of repeating units). [化85]

Resin A

[Preparation of Blue Pigment Dispersion] CI Pigment Blue 15: 6 11.36 parts by weight as a blue pigment, 57.5 parts by weight of propylene glycol monomethyl ether acetate as a solvent, and dispersant "Disperbig 2000" (manufactured by BYK-Chemie Co., Ltd.) In a solid content conversion, 3.02 parts by weight and 215.7 parts by weight of cerium oxide beads having a particle diameter of 0.5 mm were filled in a stainless steel container, and dispersed by a paint shaker for 6 hours to prepare a blue pigment dispersion. [Preparation of a coloring resin composition] The respective dyes obtained in the [synthesis of dyes], the resin A obtained in [synthesis of a resin], and other components are prepared in such a manner as to have the compositions described in Tables 1 to 3, and are prepared. A colored resin composition. Further, the numerical values in Tables 1 to 3 are 101110090 130 201245131 showing the parts by weight in the solid portion of the photoresist. The solid content in the photoresist was 22%, and the solvent composition was set to PGMEA (propylene glycol monoterpene ether acetate): PGME (propylene glycol monoterpene ether) = 7:3. While mixing, the mixture was stirred for 1 hour or more until the components were sufficiently mixed, and finally filtered by a 5 μm wedge filter to remove foreign matter. Further, the numerical values in Tables 1 to 3 represent the parts by weight of the components added. 101110090 131 201245131 [1^:1 Comparative Example 1 (N Os 11.7 1 00 1 I 29.8 I 31.5 (N 〇 Example 12 12.3 I 10.1 11.2 inch rn inch VO I 25.6 II 27.9 I CN 〇 Example 11 12.3 1 10.1 ( N inch wS I 26.0 II 28.3 I CN 〇iT) Example 10 12.3 幽10.1 CN inchcn 00 26-4 I 28.7 I CN 〇in Example 9 — 12.3” 1 〇CN 1 < inch rn ο — I 26.8 I 29.1 CN 〇Embodiment 8 Li2^ 1 ”0_1 11.2 inch rn CN rn 27.2 29.5 _ CN 〇to Example 7 1 12·3 1 1 〇<N inch cn 〇\ CN ^27.4 L29.6 (N 〇in implementation Example 6 1 12-3 1 1 lo^J 〇00 1 v〇in I 29.3 315| <N 〇Example 5 1 12·3 1 1 o 00 1 00 — 1 29.7 I L31,9 (N 〇Example 4 丨 12.3 I 1 LjojJ s 1 p inch L3〇-iJ 1 32.31 CN Ο yn in Example 3 1 12·3 1 1 1··^ c5 S 1 <N ro 1 30-5 1 | 32.7 I CM Ο Example 2 <Ν α\ 1 S 1 q Inch 1 31.0 | | 32.7 I CN 实施 Example 1 (Ν 丨ν 丨 Old 1 1 1 | 29.0 I | 30.7 I <N Ο Photoresist component Blue pigment dispersion Liquid Dyes (1) Dyes (2) OXE02 (Manufactured by BASF 2,4-diethyl 9-oxosulfide. Mountain Star PET-P (manufactured by Dian Chemical Co., Ltd.) Resin A dipentaerythritol hexaacrylate "F475" (manufactured by DIC Corporation) "LfganoxlOlO j (manufactured by BASF Corporation) "JPP- 100" (manufactured by Seongbuk Chemical Industry Co., Ltd.) Dye photopolymerization starting component chain transfer agent Resin polymerizable monomer surfactant active antioxidant (Wenxi "硇镲-e"»--is0v# : d-HHd 0 ioluol 201245131 (N<] |Comparative Example 21 1 0.72 1 I 0.00 I 1 129 J 0.00 0.00 in 0.00 1 6.41 1 丨6.54 1 0.02 | 0.26 I 0.26 Example 18 | 4.62 | 0.00 0.00 0.00 0.22 ο 1- 0.08 3.84 4.68 0.02 0.23 0.23 1 Example Π 1 0.84 0.00 1.02 0.00 0.04 1.53 0.09 6.40 | 6.56 | 0.02 1 0.26 0.26 Example 16 1 0.72 0.00 0.00 11-29 | 0.00 1.51 0.09 1 6.37 1 6.50 | 0.02 0.26 0.26 Example 15 | 4.65 1L15 1 0.00 0.00 0.00 1.20 0.09 1 4_27 1 丨5.12 1 0.02 0.26 0.26 Example 14 4.07 1.00 0.00 0.00 丨(4) 1 1.25 0.09 4.56 5.30 0.02 0.26 0.26 Example 13 0.72 0.00 11-29 1 0.00 0.00 1.51 0.09 | 6.37 I 6.50 | 0.02 0.26 0.26 photoresist composition blue color Dispersion dyes (3) Dyes (4) Dyes (5) Dyes (6) CGI242 PET-P manufactured by BASF (manufactured by Dian Chemical Co., Ltd.) Resin A dipentaerythritol hexaacrylate "F475" (manufactured by DIC Corporation) "IrganoxlOlOj ( (Manufactured by BASF) (Keibei Chemical Industry) "JPP-100" (A) Dye photopolymerization starting component bond transfer agent Resin polymerizable monomer surfactant active agent επ 06001112 201245131 [ε<] 1 Comparative Example 7| 1 1 1 0.22 I 8.45 I 8.45 1.59 0.00 0.02 0.26 0.26 Comparative Example 6丨1 1 1 1.20 I 1 | 8.00 | I 8.00 I 0.00 0.02 0.26 0.26 Comparative Example 5 0.98 1 1 0.19 | 8.01 | 8.01 ι-*Μ 0.00 0.02 0.26 0.26 Comparative Example 4 〇1 1 1 | 8.04 | 18.04 I 1.52 0.00 0.02 0.26 0.26 Comparative Example 3| 1 1 1 | 8.00 | 8.00 1.51 0.00 0.02 0.26 0.26 Example 231 1 1 _0.22 I | 8.40 | |_8·4— 0 I 1.59 0.10 0.02 0.26 0.26 Example 221 1 1 | 1.20 | 1 7.96 | 1 7.96 | 1.50 0.09 0.02 0.26 0.26 | Example 21 | 0.98 1 1 1^19 1 | 7.97 I | 7.97 I 1.50 0.09 0.02 0.26 0.26 Implementation Example 20 〇1 1 1 | 8.00 | | 8.00 | 1.51 0.09 0.02 0.26 0.26 | Example 19| 1 | 1.20 I 1 1 1 7.96 1 丨7.96 | 0.09 0.02 0.26 0.26 Dyes (3) Dyes (4) Dyes (5) Dyes (6) Resin A Dipentaerythritol Hexaacrylate "CGI242" PET manufactured by BASF -P (manufactured by Dian Chemical Co., Ltd.) DIC Company manufactures "F475" "IrganoxlOlOj BASF company manufactures "JPP-100" City North Chemical Industry Dye Resin Polymeric Monomer Starter Chain Transfer Agent Surfactant Antioxidant Inch-060011101 201245131 < The production of the colored resin film and the evaluation of the solvent resistance were carried out on the glass substrate cut into 5 cm square, and the above-mentioned respective ancient coatings were applied by a coating method of a dry coating and a dry film thickness of 1.8 /zm. After drying under reduced pressure, the ribs were placed on a hot plate. 0 The wax is graded and the pre-baked for 3 or 8 hours. Thereafter, the entire surface was warmed/knife in a clean oven at a exposure amount of 60 mJ/cm 2 and calcined at 23 (TC for 30 minutes. *Light 'after' was measured by a spectrophotometer U-3310 (manufactured by Hitachi, Ltd.) The chromaticity (C light source) in the XYZ color system was calculated, and then the substrate was immersed in PGMEA for 30 minutes, and the spectral transmittance was measured in the same manner as above to calculate the XYZ color system. The chromaticity of the medium (C light source). The results obtained by measuring the color resistance of the chromaticity after the immersion, that is, the measurement of the solvent resistance, are collectively shown in Tables 4 to 6. Further, for the above substrate, the spectrophotometer U- The measurement was carried out in 3310 (manufactured by Seiko Seisakusho Co., Ltd.), and the results are shown in Tables 7 and 8. [Table 4] Table 4 Solvent Resistance Solvent Resistance AE*ab Example 1 2.4 Example 2 8.2 Example 3 12.8 Example 4 11.5 Example 5 7.4 Example 6 6.5 Example 7 9.5 Example 8 9.9 Example 9 7.5 Example 10 5.0 Example 11 5.5 Example 12 3.8 Comparative Example 1 96.7 101110090 135 201245131 [Table 5] Table 5 Comparison of the solvent properties If solvent Δ E*ab Example 13 18 Example 14 16 Example 15 25 Example 16 3 Example 17 9 Example 18 0 Comparative Example 2 72 [Table 6] Table 6 Solvent Resistance Comparison Δ E*ab Example 19 17 Example 20 15 Example 21 16 Example 22 14 Example 23 18 Comparative Example 3 70 Comparative Example 4 85 Comparative Example 5 75 Comparative Example 6 72 Comparative Example 7 81 [Table 7] Table 7 contains the luminance of the blue pigment and the dyed resin composition of the dye. Y Example 13 10.46 Comparative Example 2 10.40 136 101110090 201245131 [Table 8] Table 8 Brightness Brightness Y of the colored resin composition containing the dye Example 19 10.23 Example 20 10.55 Example 21 10.43 Example 22 10.02 Example 23 37.7 Comparative Example 3 10.03 Comparative Example 4 10.24 Comparative Example 5 10.13 Comparative Example 6 9.83 Comparative Example 7 36.6 As shown in Tables 4 to 6, it was found that the pixel formed by using the colored resin composition of the present invention is remarkably excellent in solvent resistance. Further, Tables 7 and 8 As shown, the brightness of the pixel formed using the colored resin composition of the present invention is high. Therefore, the liquid crystal display device having the pixel formed using the colored resin composition of the present invention has high image quality. Colored resin composition for green pixel formation > [1] Synthesis of yellow dye <Synthesis Example 1: Synthesis of compound (Ι-i)> 4-Ethylaminobenzenesulfonate gas was added to a four-necked flask 117 Parts by weight, 1600 parts by weight of dichlorosilane, 56 parts by weight of triethylamine, and 3 parts by weight of 4-didecylaminopyridine were cooled to 5 °C. Then, 71 parts by weight of 1,5-dimethylhexylamine was added dropwise over 15 minutes, followed by stirring at room temperature for 6 hours. The organic layer was washed twice with 1000 parts by weight of 1 mol/L hydrochloric acid, and then washed with 1000 parts by weight of a saturated aqueous solution of sodium hydrogencarbonate, and the organic layer obtained by drying 101110090 137 201245131 was dried over anhydrous sodium sulfate. After filtering the desiccant, the solvent was distilled off to obtain 154 parts by weight of a white solid intermediate (i-a). [化86]

98 parts by weight of an intermediate (i-a) and 250 parts by weight of 5% by weight of hydrochloric acid were added to a four-necked flask, and the mixture was stirred at 90 ° C for 5 hours to obtain (i-b) as a white solid. The white solid did not need to be purified and used directly in the next reaction. [化87]

To the suspension containing the above (i-b), 1000 parts by weight of water and 24 parts by weight of concentrated hydrochloric acid were added, and the mixture was cooled to 5 ° C, and 8 parts by weight of sodium nitrite was added thereto, followed by stirring for 30 minutes. 26 parts by weight of 1-(2-ethylhexyl)-1,2-dihydro-6-hydroxy-4-mercapto-2-oxo-3-pyridonitrile is added to 80 parts by weight of methanol and water 50 The mixture containing the diazonium salt was added dropwise to the mixed solution of the parts by weight while cooling to 5 ° C while maintaining the pH at 8 with sodium hydroxide. The reaction liquid was evacuated to obtain an orange solid. The solid was purified by silica gel chromatography to obtain 66 parts by weight of the compound (1 - i) as a yellow solid. [化88] 101110090 138 i) 201245131

u The compound is 431 nm in a 10 ppm gas-like night, and the spectral absorption coefficient is 87 <maximum absorption wavelength (λ max) & The following shows the results of NMR. !H NMR (CDC13, 400 MHz) δ 7 (d, 2H, J = 8.8 Hz), 7.57 (d, 2H, 8.8 Hz), 4.26 (d, 2H, R . Ττ λ ^•4 Hz), 4.00- 3.83 (m, 2H), 3.45-3.30 (m, 1H), 2.64 (s, 3H), 1 87 】... h (m, 1H), 1.48-1.00

(m, 18H), 0.97-0.86 (m, 6H), 0.81 rdH _ T 1 Wd, 6H, J = 6.4, 2.4 Hz). [2] Synthesis of Resin <Reference Synthesis Example 2: Synthesis of Resin B> A separation flask equipped with a cooling tube was prepared as a reaction vessel, and after adding propylene glycol monofluorene-acetic acid S to 4 GG parts by weight, after nitrogen substitution, The mixture was heated by an oil bath while stirring, and the temperature of the reaction vessel was raised to 9 Torr. Hey. On the other hand, 30 parts by weight of dimercapto-2,2·-[oxybis(methylene)]bis-2-acrylate, 6 parts by weight of methacrylic acid, and methacrylic acid are added to the monomer tank. 110 parts by weight of cyclohexyl ester, 52 parts by weight of (2-ethylhexanoic acid) tert-butyl ester, 40 parts by weight of propylene glycol monoterpene ether acetate, and n-dodecylsulfide added to the chain transfer agent tank 5.2 parts by weight of the alcohol and 27 parts by weight of propylene glycol monomethyl ether acetate were stabilized at 902⁄4 after the temperature of the reaction vessel, and the temperature was maintained at 9 Torr from the start of the dropwise addition of H from the monomer tank and the chain transfer agent tank. 〇, one side is added dropwise for 135 minutes of palladium, and the addition is completed. After 60 minutes of 101110090 139 201245131, the temperature is raised, and the reaction tank is made ii〇〇c ^ After maintaining for 110C for 3 hours, gas is introduced into the separation flask. Tube, start foaming of oxygen/nitrogen = 5/95 (v/v) mixed gas. Then, 39.6 parts by weight of glycidyl propyl acrylate and 2,2'-fluorenylene bis(4-fluorenyl-6-second butyl phenol) 〇. 4 parts by weight, three were added to the reaction vessel. 8 parts by weight of ethylamine oxime, directly in this state at 11 (reaction for 9 hours at TC), the weight average molecular weight in terms of polystyrene measured by GPC of the resin b thus obtained

The Mw is 8000 and the acid value is 1〇1 mg-KOH/g. <Reference Synthesis Example 3: Synthesis of Resin c> One 145 parts by weight of propylene glycol monomethyl ether acetate was stirred while being nitrogen-substituted, and the temperature was raised to 120 °C. 1 part by weight of stupid ethylene, 85.2 parts by weight of glycidyl propyl acrylate, and 66 parts by weight of monoacrylic acid FA-513M (manufactured by Hitachi Chemical Co., Ltd.) having a tricyclodecane skeleton, and costing 3 An amount of 8.47 parts by weight of 2,2,-azobis-2-methylbutyronitrile was added dropwise over an hour, and stirring was continued for 2 hours at 9 Torr. Then, the air in the reaction vessel was replaced with 7 parts by weight of trimethylaminomethylphenol phenol and 0.12 parts by weight of p-benzoic acid in 43.2 parts by weight of acrylic acid, and the reaction was continued at 100 Torr for π hours. Thereafter, 56.2 parts by weight of tetrahydrophthalic anhydride (ΤΗΡΑ) and 0.7 parts by weight of triethylamine were added and reacted at 10 Torr for 3.5 hours. The resin C thus obtained had a weight average molecular weight Mw of about 8400 and an acid value of 8 〇 mg_KOH/g as measured by GPC in terms of polystyrene. Further, propylene glycol monoterpene ether acetate was added to adjust the solid content concentration to 101110090 140 201245131 40%. [3] Synthesis of Photopolymerization Initiator A photopolymerization initiator (Compound 1-1) is shown. [化89]

Synthesized by the method described. [4] Preparation of Green Pigment Dispersion: 12.7 parts by weight of CI Pigment Green 58 (manufactured by DIC Corporation) as a halogenated metal phthalocyanine pigment, and BYK-LPN6919 manufactured by 3丫1^01^111丨6 company as a dispersing agent. (methacrylic AB block copolymer, amine value: 121 mg-KOH/g, acid value: 1 mg-KOH/g or less) 3.2 parts by weight in terms of solid content, and reference to the resin B synthesized in Synthesis Example 2 The mixture was mixed in an amount of 4.2 parts by weight in terms of solid content, and propylene glycol monoterpene ether acetate was used as a solvent to adjust the solid content concentration to 20%. 100.5 parts by weight of this mixed solution and 300 parts by weight of zirconia beads having a particle diameter of 5 mm were filled in a stainless steel container, and dispersed for 6 hours by a coating shaker to prepare a green pigment dispersion. [5] Preparation of Colored Resin Composition The dye synthesized in [1], the resin C synthesized in [2], and the photopolymerization initiator synthesized in [3] were mixed in the ratio shown in Table 9. 4] 101101090 141 201245131, a dispersion liquid, a dipentaerythritol hexapropylene as a polymerizable monomer, pentaerythritol-indole (3-mercaptopropionate) as a bond transfer agent (manufactured by Ding Chemical Co., Ltd.) And a 1% propylene glycol monomethyl ethoxide-based dilution gas-based surfactant F_475 (manufactured by DIC Corporation) as a surfactant, and propylene glycol monomethyl ether acetate was used as a solvent to adjust the solid concentration to 2〇. %, the colored resin compositions of the examples and the comparative examples were prepared in this manner. Further, the numerical values in Table 9 are contents (parts by weight) excluding the solvent. A component of the following composition was mixed and dissolved to prepare a colored photopolymerizable composition. Further, the numerical values in Table 9 are the contents (parts by weight) excluding the solvent. [Table 9]

Further, the numerical values in Table 9 indicate the parts by weight of the components to be added. Further, each of the compounds in Table 9 is as follows. PET P. Pentaerythritol-indole (3_mercaptopropionate) (manufactured by Dian Chemical Co., Ltd.) DPHA. Dipentaerythritol hexaacrylate F475. Fluorine-based surfactant pIC company) [5] Determination of dissolution time and residual film rate The glass substrate AN100 (manufactured by Asahi Glass 101110090 142 201245131, manufactured by the company) which was cut into 5 cm squares after the β-washing was applied by the spin coating method to apply the above-mentioned respective coloring trees with a dry film thickness of 2.0 μt. The composition was dried under reduced pressure. Using a 0.04 cc/t aqueous solution of hydrazine hydroxide, the nozzle was exposed at a pressure of 0.25 MPa under the temperature of the developer, and the colored resin composition of the unexposed portion was completely dissolved in the developing solution, and the substrate was exposed. The coloring time of the resin composition was set to be the dissolution time. • The method of measuring the dissolution time is the same. The colored resin composition is applied to the cleaned glass substrate 00 (manufactured by Asahi Co., Ltd.) and dried: thereafter, the entire surface is exposed with an exposure amount of 5 GIUW, using _ Heavy f% potassium hydroxide aqueous solution at a developer temperature of 23 < 3 (: under pressure)

Mpa is spray developed. Further, the development time was set to a dissolution time of +2 sec. After the development, the film was cleaned with sufficient pure water, and dried/cleaned by clean air to measure the film thickness of the colored husks remaining on the substrate. The ratio of the film thickness after development when the film thickness of the development film was set to 1 GG% was defined as residue 7 * The results are summarized in Table 10. Μ ° [6] Width measurement of the light-cured portion (Examples 24 to 27, Comparative Example 8) m In the same manner as the above-mentioned [5] dissolution time, the substrate A N10 0 was cleaned (Xu Shixiao) The company manufactures a coating of each coloring tree with a composition of 2 and dried it. Thereafter, a mask having a linear pattern of a width of 40 and a length of 3 mm was used, and exposure was performed at an exposure amount of 50 mJ/cm 2 , using a 〇〇 4 wt% potassium hydroxide aqueous solution at a developer temperature of 23 Ω. Pressure 〇101110090 143 201245131

Mpa is spray developed. Further, the development time was carried out under the conditions of a dissolution time of + 10 seconds and a dissolution time of +20 seconds. After development, it was washed with sufficient pure water, dried by clean air, and calcined in an oven at 230 ° C for 20 minutes. Thereafter, the line width of the photohardened portion was measured using a 50-fold optical microscope. The results are summarized in Table 10. 101110090 144 201245131 014] [6] Width measurement of light hardening section Development time = dissolution time + 20 seconds Η 婼 〇3 〇 \ 〇V〇 Bub ¥ inch cn" * o Development time (seconds) (Ν CO CN mmmmmm CN CO dissolution time (seconds) (Ν ro cn rH »···η CN development time = dissolution time +10 seconds scale 3 CN ^5 etc. On inch inch T 卜 co development time (seconds) CN (Ν CN CN cn CN m (N (N (N (N) dissolution time (seconds) (Ν CN m T-^ (N [5] dissolution time and residual film rate determination residual film rate (%) 〇\ 〇OS On oo 〇\ / \ /<-S development time (seconds) CN m cs mmmm cs m dissolution time (seconds) CN (N mm in < N \ Example 24 | Example 25 I Example 26 Example 27 Comparative Example 8 Comparative Example 9. Gong Yi Pao i#<s3 杷 杷 ^ ^ ^^w rims long. /. 0 朱琏傲(u

SH 0600IH0I 201245131 As shown in Table 10, in the colored resin composition containing a yellow dye, it was difficult to form an image without including a chain transfer agent (Comparative Example 9). On the other hand, the pixel formed by using the colored resin composition of the present invention has a surface hardenability, so that the film surface of the exposed portion is not dissolved by the development, exhibits a high residual film ratio, and a patterned mask is used. The alkali development t after the exposure can form a good pixel (Examples 24 to 27). Therefore, the formation of the color filter including the color filter using the pixel formed by the colored resin composition of the present invention is excellent, and the liquid crystal display device and the organic EL display device including the color filter are high in quality. It is to be understood by those skilled in the art that the present invention may be described in detail with reference to the specific embodiments of the invention, and various changes and modifications may be added without departing from the spirit and scope of the invention. This application is based on a Japanese patent application filed on March 23, 2011, which is filed on March 23, 2011. (Japanese Patent Application No. 2011_064454), filed on July 28, 2011, (Japanese Patent Application 2011) -259238), the contents of which are incorporated herein by reference. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view showing an example of an organic EL element including a color filter of the present invention. [Main component symbol description] 20 pixels 30 Organic protective layer 101110090 146 201245131 40 50 51 52 53 54 55 100 500 Inorganic acidified film transparent anode hole injection layer Hole transport layer Light-emitting layer Electron injection layer Cathode organic EL element Organic light-emitting body 101110090 147

Claims (1)

201245131 VII. Patent application scope: 1. A colored resin composition comprising (A) dye, (B) solvent, (C) binder resin and (D) chain transfer agent, wherein the above (D) chain transfer agent Is a compound represented by the following formula (I), [Chemical Formula 1] (In the above formula (I), p represents an integer of 2 to 4; Ral represents a hydrogen atom or an alkyl group which may have a substituent; X represents a direct bond, a carbon atom of 2 to 4 stages, and a heterocyclic group of 2 to 4 Or a 2 to 4 valent aromatic ring group; Further, a structure represented by the following formula (Γ) contained in one molecule may be the same or different. 2. The colored resin composition according to claim 1, wherein the content of the (D) chain transfer agent is 2% by weight or more and 10% by weight or less based on the total solid content. 3. The colored resin composition according to claim 1 or 2, wherein the dye is a triarylmethane dye. The coloring resin composition according to any one of claims 1 to 3, which further contains (E) a polymerizable monomer. 5. The colored resin composition of claim 4, wherein the (E) polymerizable monomer is a compound having an ethylenically unsaturated double bond. 6. The colored resin composition β according to any one of claims 1 to 5, which further comprises at least one of (F) a photopolymerization starting component and a thermal polymerization starting component. A color filter comprising a pixel formed using the colored resin composition of any one of claims 1 to 6. 8. A liquid crystal display device having the color filter of claim 7 of the patent application. An organic EL display device having the color filter of claim 7 of the patent application. 101110090 149 S