TW201241131A - Manufacturing method of pressure sensitive adhesive composition, pressure sensitive adhesive composition, and pressure sensitive adhesive tape used for the same - Google Patents

Abstract

One aspect of the present invention relates to a method of producing an adhesive composition, of a transparent conductive layer which is formed with ITO, for an adhesive tape which is adhered to a surface of the ITO, and the adhesive composition is obtained by the method comprising at least the following steps (1) and (2): (1) a step of fabricating a raw materials for an adhesive compound which is formed by mixing at least one type of an (meth) acrylate monomer containing a hydroxyl group and a photopolymerization initiator into a pressure-sensitive adhesive composition formed by an acrylate resin; and (2) a step of causing a polymerization reaction under light by using the raw materials for the adhesive compound and obtaining the adhesive composition.

Description

201241131 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an adhesive tape which is applied to the ITO surface of the layered body, and the transparent conductive accumulation body is suitable, and the growth product is formed by ITO (indium). / tin oxide two = the next case). More specifically, it is a composition for the adhesion of the drug, which is inhibited.

ίίΓ 并无 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境 环境The special wish 2G1〗 tears the j-month domain and puts its contents in this reward book. [Prior Art] 2 The electrical laminated system such as a transparent resin film or a glass plate Γ == ΐ: a transparent conductive film is used for various purposes. Examples of the use of the η transparent conductive laminated body include a touch panel, a liquid crystal display, an organic anal display, and a transparent electrode used for solar power 7. The present invention relates to a transparent conductive laminated body. Therefore, the touch panel used in the electrical laminated body is taken as an example, and the technical background of the completion of the present invention will be described below. Ge Yue is a touch-sensitive type that is assembled as a component in the j irt: J1 laminated body. In order to improve the operability and durability of the touch panel, various improvements have been made so far. For example, in the case of preventing the damage or deterioration of the surface of the touch panel, the following table is used to bond the surface of the touch panel to the surface of the touch panel; 4/47 201241131 Protective film (see, for example, Patent Documents 1 and 2). Transparent Conductivity Used in General Touch Panels == Known: Hard coated film of a substrate composed of a transparent resin film, which has two sides: d Co'), and a transparent film The transparent conductive laminated body of the SI conductive film of the second material is a transparent conductive laminated body which is bonded by an adhesive by a hard coating HH method (that is, a laminated transparent conductive layer laminated body, in recent years) In addition, the expansion of the use of the transparent conductive laminated body reduces the manufacturing cost. It is also required to reduce the number of components required for the transparent conductive laminated body to reduce the number of components of the transparent laminated body. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ A type of sticker: a protective thin film for protecting a transparent conductive film. Reference: A touch panel that is required to be used in a transparent conductive laminated body, and the appearance and size of the product are as follows: , in the assembly of a transparent conductive laminated body of light two-in-one Viscosity on the transparent conductive film = change in surface resistivity of the conductive film, and even after the environmental test under high temperature and high humidity 5/47 201241131, the adhesive layer is not turbid. Therefore, for bonding optical parts The adhesive sheet used in the belt - and the adhesive composition used in the same, and the adhesion of the environmental test towel j which is reduced or even under high temperature and high humidity (for example, refer to Patent Document 4 to 7)., turbidity production [Prior Art Document] Patent Document 1 Patent Document 2 Patent Document 3 Patent Document 4 Patent Document 5 Patent Document 6 Patent Document 7 [Summary of the Invention] 曰本特开平8-329767号Japanese Unexamined Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Problems to be Solved by the Invention] In the manufacturing step of the optical element in which the transparent conductive laminated body is assembled, as disclosed in Patent Document 3, the use of the light in the New York County In the step, even if the damage is caused by the seven factors in the heating step above the boots, it is not the damage caused by the turning, but it can be strengthened in the light (4). Therefore, the effect is healthy. The film for the transparent conductive film layer disclosed in the gland 2 patent document 3 is a film thermal resin film, so that the heating material of (10) or more can be utilized in the point of damage to the thief. The optical element processing step of the transparent conductive layer body does not help to solve the problem of the change in the surface resistivity of the through-material to produce 201241131. In addition, 'Patent Document 4 discloses a resin composition which is a factor of poor operation. The amount of gas generated is small, and the precise electrons are not corroded. The cow does not have a poor appearance, and the adhesive properties, especially the adhesion and adhesion of the pair are excellent. The composition of the fat is revealed. The resin composition and the viscous composition of the medicinal material and the slab of the smear of the smear of the invention are as follows: the adhesive sheet disclosed in Patent Document 4 uses an acrylic-based adhesive composition without using acrylic acid. Check board fit, at temperature 6 (TCx humidity 90 Under the environmental conditions of %RH, it is allowed to stand for 7 days, and there is no corrosive situation depending on the degree of thermal discoloration of the copper plate. = And 'turning the literature 4 towel, the environment under high temperature and high humidity π Μ is not caused by white turbidity in the adhesive layer - there is no record, and does not help solve the problem of white turbidity in the adhesive layer. Patent Document 5 Adhesive composition of the cap type and the adhesive tape of the use of the product, wherein the photopolymerizable county is formed as a surface of the surface of the rop (plasma display). When the material is used, it is also easy (4), in the environment of high temperature and high humidity, to produce white turbidity. In Patent Document 5, when it is attached to the surface of ιτο, it does not adversely affect the change of surface resistivity of the transparent conductive film. There is no record of the matter. Further, in the embodiment of Patent Document 5, although the acrylic adhesive composition which effectively prevents white turbidity is contained in the acrylic adhesive composition containing 4% by weight of acrylic acid, there is concern that the above-mentioned adhesive composition may be mixed due to the surface of the adhesive. The effect of increasing the resistivity of the 1τ film surface. Patent Document 6 discloses a resin composition for optical use, and an optical resin composition using the composition according to the composition, wherein the optical resin composition is transparent and has an appropriate adhesion and impact required for an image display device or the like. 7/47 201241131 Absorptive and inconspicuous image display device panel materials such as panels are used. Specifically, it is an optical resin composition comprising a propylene age derivative, a propylene riding contact polymer and a high molecular weight crosslinking agent. However, in Patent 2, after the environmental test under high temperature and high humidity, the white turbidity is not generated in the adhesive layer, and it does not help to solve the problem of white turbidity in the adhesive layer. Further, Patent Document 7 discloses an adhesive layer for an electronic display, which is an adhesive composition comprising a copolymer and/or a mixture of a (meth)acrylic acid alkyl ester monomer and a carboxyl group-containing monomer, even in There is no white turbidity in the environment under high temperature and high humidity. However, in Patent Document 7, there is no description of the problem that the surface resistivity of the transparent conductive film does not adversely affect the surface of the transparent conductive film, and whether the above-mentioned adhesive composition can be used for sticking It is not clear what is on the surface of ITO. As described above, in the prior art, an adhesive tape has not been found which is capable of preventing a change in the surface resistivity of the transparent conductive film, and at a high temperature, in the transparent conductive film layer (4) in the transparent conductive laminated body. There was no white turbidity after the % test in high humidity. That is, the object of the present invention is to provide a method for producing an adhesive composition, an adhesive composition, and an adhesive tape using the adhesive composition, wherein the adhesive composition is formed by laminating to form a transparent conductive In the adhesive tape on the ITO surface of the transparent conductive laminate of the film, the change in the surface resistivity of the transparent conductive film was suppressed, and no white turbidity occurred after the environmental test in the high temperature and high humidity. [Means for Solving the Problem] In order to suppress aggregation of water molecules caused by rapid external environmental changes and to prevent white turbidity of the adhesive layer, the technical idea of the present invention is 8/47 201241131, an adhesive contact Gamma is a pressure-sensitive adhesive composition which is composed of an acrylic polymer having an acid value of "," to 33, even if it is bonded to an oxime table, which is an acrylic polymer which can suppress a change in surface resistivity of a transparent conductive film. The monomer of the silk is cross-linked, and a novel function of allowing the water molecules to exist in a state in which the water molecules are invisible to the extent that the eyes are invisible is obtained, and the adhesive composition of the function of the tiara function is obtained. η, that is, the present invention has At least one species of the (meth) propylene-containing precursor is deducted from the sensible material composition composed of the acrylic acid polymer having an acid value of 〇 to 33, and Prevents the condensation of water. In this way, it can provide a kind of environmental test which can suppress the change of the surface resistivity of the transparent conductive film even if it is bonded to the adhered m> and in high temperature and high humidity. No adhesive composition, and the viscosity of the domain Here, 'This Fortune' provides a manufacturing branch of a sticky material for the purpose of solving the above-mentioned problem*, which is an adhesive composition for bonding the adhesive tape of the above-mentioned surface of the film composed of (10). And the step of adjusting the raw material composition for the adhesive by the adhesive composition having the composition (the method of polymer enthalpy, 0) obtained by at least the following steps (1) to (7), the adhesive The = raw material composition is a pressure-sensitive adhesive composition (polymer enthalpy) composed of an acrylic resin having an acid value of 〇 to 33, and at least 1 with a transbasic (meth) oleic acid monomer. And (7) using the raw material composition for the above-mentioned adhesive, and obtaining an adhesive composition having physical properties (κ) by irradiation of light = polymerization reaction ( Step of Polymer C), 9/47 201241131 The above physical properties (κ) are defined as follows: After coating the adhesive composition (Polymer c) on the surface of the crucible to form a film having a thickness of 200 (4), the temperature is 8% from 85 ° C. 3 environment for the implementation of high-temperature, high-humidity environmental test for the hour : After the removal, the change rate of the resistance value of the pleura film, when it was taken out in the initial phase of the compound C) layer, was not removed in the white turbidity H phase. 'Adhesive composition (polymerized outside, this wealth provides - ageing In the method of producing a material, an adhesive composition for bonding an adhesive tape on the IT0 surface of a transparent conductive film made of IT0 is produced by the following steps (1) to (3) to obtain a physical property (κ) adhesion. a method for producing a composition (polymer C), (1) a step of adjusting a raw material composition for an adhesive, wherein the raw material composition for the adhesive is composed of an acid value of 〇 to 33 The pressure-sensitive adhesive composition (polymer enthalpy) is formed by combining a hydroxyl group-containing (methicone of at least a monomer of the olefinic acid vinegar (monomer hydrazine) and a photopolymerization initiator; (7) a step of applying a raw material composition for the above-mentioned adhesive to a base film formed of a long-length thermoplastic resin and drying it to obtain an elongated coating film; Using the above-mentioned long strip coating film to carry out a polymerization reaction by irradiation of light' while on the above substrate The step of obtaining the adhesive composition (polymer C) having the physical property (6) on the film, the physical property (K) being defined as follows: Applying the adhesive composition (polymer c) on the surface of the ITO to form a thickness after drying 10/47 201241131 After the film of 2_m, the high temperature of 500 hours is applied from the temperature environment, and the power of Gaocheng ==: the change ratio of the value is compared with: two substances C; when the layer is taken out in the box, *Juju一传:: 丄本本明 provides an adhesive composition (polymer C), = from ^: secret is 〇 to 33 __ grease composed of U-stick composition (polymer A A solid component (10) by weight, at least j kinds of monomers containing a (meth)acrylic acid vinegar, and a photopolymerization initiator. .01 to 〇 f Those who have physical properties (K), draw and 88. The above physical properties (K) are defined as follows:

Applying the adhesive composition on the surface of the ITO (the polymer is formed into a dry = 20 film), and the temperature of the TM film is removed from the high temperature environment of the high temperature of the temperature of 85tx humidity. The change rate of the value is compared with the initial value in the second and second, and when it is taken out from the above-mentioned flood box, there is no white turbidity in the layer of the adhesive composition (polymer C). The film is laminated on the film by the method of the above-mentioned method (polymer C). There is also a 'providing-type adhesive tape which is laminated on the substrate film to have the above-mentioned adhesive composition (polymerization). In addition, it is preferable that the present invention (10) is attached to the 所 所 。 。 。 。 。 。 。 。 。 。 。 。 。 。 发明 依 发明 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依/47 201241131 The pressure-sensitive adhesive composition of the existing acid value of 0 to 33 is modified, and the base of the adsorbed water molecules is dispersed. Thereby, the new function can be exerted: at high temperature, The moisture in the high humidity environment is paid to the hydroxyl group-containing polymer, even for The high cushioning and thickening agent layer prevents the occurrence of white turbidity due to the aggregation of the absorbed water molecules. Further, by appropriately adjusting the fluidity of the adhesive coating liquid, the coating thickness of the substrate is formed at a high level. [Embodiment] Hereinafter, the present invention will be described as a preferred embodiment. The following is a method for producing a polymer (the method for producing a polymer crucible. Adhesive agent formed by mixing a mixture of at least a monomer (monomer) and a photopolymerization initiator containing a transbasic (meth) propylene sulphuric acid vinegar The raw material composition to be used is adjusted, and then the raw material composition for the above-mentioned adhesive is transferred to a composition having a secret (κ)_agent (polymer C) by irradiation of t. The above physical properties (Κ) : Applying an adhesive composition (polymer to the surface of the crucible to form a film having a thickness of 200 mm after drying, and then performing a high temperature of 5 hours in an environment of a temperature of 85 〇 / humidity of 85% RH. Resistance of the 'IT film after removal in the oven for wet environment test The change magnification is 1.7 times or less compared to the initial value ,, and when it is taken out from the above-mentioned supply tank, no white turbidity is generated in the layer of the adhesive W composition (polymer c). _Manufacture of the adhesive composition of the present invention In the first, at least one hydroxyl-containing precursor (monomer B) and a photopolymer for polymerizing the monomer b are polymerized to form a sensory_adhesive composition composed of 12/47 201241131 == acid-based resin. (Polymerization, the composition of the hard-to-finish series. The raw material composition used in the threat I! can be contained in the photopolymerized sigma as a borrowing energy line. The sulfonic acid (single-cell monomer may have a polymerizable combination of a (4)) acrylic acid group which can be used for the radical polymerization of the starting agent 仃 radical polymerization, for example, has an ultraviolet ray in the range of 3 〇〇 nm to 4 〇〇 nm. A curable ultraviolet curable resin material. In addition, the term "n-tt" is a generic term for acryl vinegar and hydrazine acrylate. It is understood that the polymer A is the main component of the adhesive composition of the present invention, and ^ is G to 33, and if it is a solvent-containing acrylic monomer (monomer B), it is easy to disperse. The octameric & Α 以 以 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 为了 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸 丙烯酸This monomer is = = = olefinic acid, and the base of the money. Further, since the adhesive composition of the present invention is used for optical use, it is necessary to have transparency "and it is also easy to control the color of the lion. Therefore, the polymer oxime is preferably an acrylic polymer. The acid value is derived from the carboxyl group of the (fluorenyl)acrylic copolymer and the acidic group (hetero group, hetero group, etc.) of the oxime. The upper value refers to the number of mg of potassium hydroxide required for the free fatty acid and the resin acid contained in the neutralizing sample Ig. The acid value is determined by potentiometric titration. Specifically, according to JIS-K-2501: 2003 (Japanese Industrial Specification No.), the adhesive is dissolved in a titration solvent mixed with methyl sterol and decyl alcohol (1+1) (volume ratio) to 0.1 mol. /L potassium hydroxide / decyl alcohol solution was titrated, 13/47 201241131 The titration curve inflecti〇np〇int was used as the end point. The acid value was calculated from the titer until the end of the potassium hydroxide/decanol solution. After the adhesive composition of the present invention is applied onto a substrate (or a separator: preferably a release paper) and dried, it is polymerized by irradiation with light to obtain an adhesive tape. Meanwhile, in the present specification, the adhesive tape is not particularly distinguished by the width, and it also includes any of the adhesive tape and the adhesive sheet specified in JIS Z _9 (Japanese Industrial Standard Number). Specific examples thereof include a single-sided adhesive tape (or a single-sided adhesive sheet) having adhesion on one side of a substrate, and a double-sided adhesive tape (or double-sided adhesive tape having a enamel layer on both sides of the substrate). Adhesive sheet) or a transfer belt (Transfer 丨叩 2) in which 4 coating layers are formed without a substrate. The adhesive sheet can be made into a large area, and can be directly used in the horizontal width, or can be cut into a thin strip shape as an adhesive tape. The adhesive or adhesive tape can be utilized to conform the component to the display. Fig. 1A is a view schematically showing an example of a single-sided transfer belt 5 having an adhesive layer 2 formed using the adhesive composition of the present invention. The single-sided adhesive layer 5 is attached to the single-sided adhesive layer 2 which is the support of the adhesive layer 2, and the adhesive surface of the adhesive layer 2 is protected by the separator 3. When used, the separator 3 is peeled off to expose the adhesive surface, and the adhesive layer 2 having the back surface layer is bonded to the adherend. Soil The structure of the double-sided adhesive tape having a substrate is not particularly shown, but the shape is formed on both sides of the substrate, and each of the adhesive layers is protected by a separator. Fig. 1B is a view schematically showing an example of a transfer belt 6 having an adhesive layer 2 using the adhesive composition of the present invention. Separators 3, 3 are provided on both sides of the transfer belt 6 of the adhesive layer 2. When it is used, the peeling side exposes the one-side adhesive surface on the 14/47 201241131 separator 3 and adheres to the adherend. Further, in the case where the other separator 3 is peeled off, only the film-like adhesive layer 2 can be transferred to the adherend. After peeling off the other separator 3, other adherends can also be applied to the new adhesive surface. The improvement effect of the towel of the present invention on preventing the occurrence of white turbidity under the environmental conditions in high temperature and high humidity, when the adherend adhered to the type of the transfer belt is glass (heat machine broken glass) or propylene When a material having poor water permeability such as an acid resin (acrylic glass) is used, a remarkable effect can be obtained. This is based on the following reasons. In the fit of water molecules? In the case of a poorly difficult film, water molecules dispersed in the adhesive layer in the case of a resin film can be lightly penetrated. Therefore, the possibility of agglomeration of water molecules is reduced, and even if water molecules are aggregated, they can be immediately discharged through the resin film. Therefore, the time of white turbidity is shorter: =, and when the material with poor penetrability of water molecules is attached, once the water molecules are condensed and white 纠 is generated, in order to diffuse the water molecules to the peripheral end of the adhesive tape, It takes a long time and there is continuous white turbidity. (Inductive pressure-sensitive adhesive composition (Polymer A)) In the present invention, the pressure-sensitive adhesive composition (Polymer A) composed of an acrylic resin is used by having an ester group (_c〇〇_). It is preferable to manufacture the acrylic monomer. The acrylic acid monoester having an ester group (-COO-) may, for example, be a formula CH2 = cri_c〇〇r2 (wherein R1 represents a ^ or a methyl group, and R2 represents a group of carbon numbers i to M) The (mercapto) acrylate which is represented by (fluorenyl) propylene oxime or hydroxy group-containing (meth) acrylate. A (meth)acrylic acid represented by the formula CH2 = CR]-COOR2 (wherein Ri represents hydrogen or a fluorenyl group; r2 represents a number 1 to μ), and specifically, for example, ) decyl acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, (mercapto) acrylate 15/47 201241131 butyl ester, (meth) acrylate Butyl ester, tert-butyl (meth)acrylate, n-amyl (meth)acrylate, isoamyl (decyl)acrylate, n-hexyl (decyl)acrylate, 2-ethylhexyl (decyl)acrylate , (mercapto) n-octyl acrylate, isooctyl (meth) acrylate, isodecyl (meth) acrylate, bismuth (meth) acrylate or (decyl) (10) acid Among them, two or more kinds may be used alone or in combination. Among these, (2-mercapto)acrylic acid 2-ethylhexyl ester or (decyl)n-butyl acrylate is preferably used. From the viewpoint of adhesion, the carbon number of the alkyl group R2 of the alkyl (meth) acrylate is set to 1 to 14. When the carbon number of the filament is 15 or more, the adhesion is lowered, which is not preferable. The carbon number of the filament R2 is preferably from 12 to 12, more preferably from 4 to 12 carbon atoms, still more preferably from 4 to 8 carbon atoms. Further, in the alkyl group of 'alkyl R2' to 14 (meth) acrylate, the carbon number of the base group R2 may be 1 to 3 or 13 to 14 (mercapto) propyl vinegar as a monomer. - used in part. (4) The (f-based) acrylic acid having a carbon number of 4 to 2 is used as an essential component (for example, 5 Å to ear °/〇). In addition, the filaments R2 may be linear or branched. (Monomer B) Further, 'as a mercapto group containing a mercapto group, for example, (meth)acrylic acid 2-ethylidene vinegar, (meth)acrylic acid 2 methacrylic acid , (meth)acrylic acid 4_ via butyl § |, polyethylene glycol mono (meth) propylene, polypropylene glycol early (methyl) propylene vinegar or cyclohexane dimethanol mono (methyl ) acrylate special. Further, examples of the propylene monomer having an entrained group include, for example, acrylic acid, methyl methic acid, maleic acid, itaconic acid or aroyl benzoate 6/47 201241131 having an ester. The mixing ratio of the acrylic monomer and the thiol-containing body can be imparted to the heat by cross-linking with the _ body-shaped agent, and has an ester group for preventing floating from the adherend. At least the seed of the acrylic monomer is 85 to 95 parts by weight, and at least the acrylic monomer having a mercapto group! It is preferred that the mixing ratio is 5 to 15 by weight. In the raw material monomer for producing the pressure-sensitive adhesive composition (polymer A) composed of an acrylic resin, other monomers may be added. A monomer having, for example, a secret, a pyrithione group, an amine group, or a hydrophilic group may be selected and used. In the monomer of the polymer A of the temple, the proportion of the thief of the (meth) propionic acid-based vinegar and the monomer having the water-based base is also dependent on the characteristics required of the adhesive or the type of the early body, and the hydrophilicity. Based on the weight ratio of (4) in the i molecule, etc. The above compounding ratio (iv) is preferably 5 to 5 G% by weight of a monomer having a hydrophilic group and 95 to 50% by weight of an alkyl (meth)acrylate. Further, examples of the propylene-based acid-based monomer containing an aerobic oxy-stone group include, for example, (meth)acrylic acid r-tri-f-oxygen sulfonate, (meth)acrylic acid plant, and methyl dimethyl oxysulfide. Xiji vinegar or (methyl) propylene fosphate triethoxy stone kiwi vinegar temple. The non-acrylic monomer containing an alkoxyfluorenyl group may, for example, be vinylmethoxysilane or vinyltrioxane. ...as an amino group-containing acrylic monomer, in addition to (meth)acrylic acid:amino group, (meth) enoyl dimethylaminopropyl vinegar, (methyl) propyl acetophenate - butylamine B In addition to an amine group-containing (meth)acrylic acid vinegar such as an ester or a monomethylaminoethyl (meth)acrylate, for example, (meth) acrylamide, Ikang Brew, and A Aminopropyl (meth) acrylamide, dimethylaminoethyl 17/47 201241131 (meth) acrylamide, N-methoxymethyl acrylamide ethoxy propyl amide, hydrazine - methoxymethyl (fluorenyl) acrylamide or hydrazine-butoxymethyl (meth) acrylamide. The main part of the polymer ruthenium (for example, 50% by weight or more, more preferably 8% by weight or more) is preferably an acrylic monomer (alkyl (meth) acrylate and acrylic monomer having a hydrophilic group). In the configuration, a monomer other than the acrylic monomer (non-acrylic monomer) may be used in combination with the degree of the effect of the present invention. In order to polymerize the acrylic monomer constituting the polymer A and the optionally blended non-acrylic monomer, it may be carried out by a known method such as melt-knit, block-knit, suspension polymerization or emulsion polymerization. Among these, it is suitable to use a solution which is easy to remove heat. Specific examples of the organic solvent to be used in the solution polymerization include aromatic cigarettes such as hydrazine and diphenylbenzene; aliphatic vinegars such as ethyl ester and butyl acetate; and alicyclic groups such as cyclohexane. Touching; or aliphatic hydrocarbons such as hexane or pentane, etc., if it is not inhibited from the above polymerization reaction, it is particularly advantageous. These solvents may be used alone or in combination of two or more. The amount of the solvent used can be appropriately determined. In general, t: 'solution polymerization reflection, the county polymerization temperature of the ancient, the molecular weight of the material is reduced. When the polymerization reaction is carried out in a solvent, the enthalpy is dissolved; the side = the polymer A having the temperature of the point which is suitable for the polymerization reaction. The second conductivity of the pressure-sensitive transmission film composed of the dilute acid resin of the composition of the month can also suppress the surface of the transparent conductive film. The above-mentioned adhesive composition is a so-called acid-free adhesive composition. /47 201241131 Good 0 (4) At this time, as the change in the surface resistance value of the permeate resistance, the acid value of the material A is preferably U33. A sensitizing adhesive composition composed of an acrylic acid tree. As the "complex A", it is possible to use a pressure-sensitive adhesive which is commercially available. The commercially available pressure-sensitive adhesive can be a so-called acid-free adhesive composition such as a non-ketone-based or acrylic acid-based adhesive. Commercially available acid-free agent: The adult system (for example, SK DWE 2147) is a small adhesive tape with a small change in the surface resistance value of the IT 市 commercially available from the company. (manufacturing)), MMH-F25, MHM-F50, =HM'Fl25 (made by Riyong Chemical Co., Ltd.) or ZB7〇32W (manufactured by DIC) 荨. The molecular weight distribution of polymer A is determined by the number average molecular weight. (Mn) is 7 / dying and the weight average molecular weight (Mw) is 1. More than 10,000. More preferably, the weight average molecular weight (Mw) is 12 million or more. When the molecular weight of the U material A is large, the heat is rich. And the weather resistance is more excellent. - When the amount of 77 is too large, the viscosity of the adhesive composition becomes too high, so that the adhesive composition layer is reduced in the riding speed when the ride is accumulated. (6) In the case of a method such as temperature and the like, it is generally considered that the upper limit of the knives can be further enlarged. However, when coating at room temperature, it is generally considered that a material having a Mw of less than 5 million is preferable. At least one kind of a monomer (monomer B) containing a transbasic (meth)acrylic acid vinegar. The raw material for the adhesive of the present invention In a preferred embodiment of the composition, a hydroxyl group-free (meth) acrylate and an acrylic monomer are polymerized, and 19/47 201241131, a propylene-based polymer and a hydroxyl group-containing (meth) acrylate are obtained. The monomers are present in a mixed state in which they are not, t, and in a dispersed state. In another preferred embodiment, the polymer A obtained by polymerizing a monomer containing a hydrophilic monomer, and a hydroxyl group-containing (A) The single system of the acrylate is contained in the raw material composition for adhesion. The content of the monomer B (the total amount of the monomer B when it is two or more), the phase of the main back H s (polymer A) ) The weight is 5 to π by weight, and the test is to be 5 to 15 parts by weight when the temperature is 85tx and the humidity is 85% rh. The material 1 containing the radical acrylic polymer may contain a plurality of (meth)acrylic acid-containing succinic acid, the unreacted monomer L, and the content of the adhesive and the adhesive material of the present invention. The ratio of the group-containing (meth) acetoacetate in the composition is significantly lower. The adhesive of the present invention The composition (the method for producing the polymer crucible is as shown in Figure 1. The pressure-sensitive composition of the base resin is at least 1 of the monomer of the (meth) acrylate containing the radical. The adhesive composition uses a raw material composition to be irradiated with light, and i gathers 1 to make a raw material composition on the reverse-use library and passes through the material C). The mouth reaction can obtain the adhesive composition (polymerized into (n 1 f'acrylic resin-based pressure-sensitive adhesive group = do not ("object a", a monomer containing a trans-group (meth) acetoacetate (single oxime: first polymerization initiator) Acrylic: state, or uniform distribution of the coating and the monomer containing the warp group (monomer b);) ^ The acrylic acid solvent is sprayed into a resin solution. 20/47 201241131 Acrylic acid obtained by dissolving a monomer (monomer B) containing a fluorenyl phthalate in a pressure-sensitive adhesive composition (polymer VIII) composed of the above acrylic resin In the step of slurrying, the monomer B is dissolved in the polymer A, and is preferably washed with an organic solvent or the like as required. Thereby, the unreacted acrylic monomer can be removed by the polymer A. Further, by more accurately quantizing the weight of the polymer a, the content of the monomer B and the photopolymerization initiator used in the next step can be more precisely adjusted to prepare an acrylic liquid. When the acrylic slurry is produced, the monomer B may be dissolved in the polymer A, and the organic solvent or the like may be washed. When a photopolymerization initiator is added to the acrylic slurry, the ultraviolet light contained in the chamber or the sun-deficient liquid reacts with the acrylic acid green liquid, and there are three rows of polymerization reactions. Therefore, it is difficult to control the acrylic-based slurry. Therefore, it is preferred that the photopolymerization initiator should dissolve the resin solution of the acrylic-based poly-solution in the coating step of the subsequent step. The point to be noted is to prevent the photopolymerization agent from starting to react before coating/film formation due to external factors. In the adhesive composition of the United States (polymer 〇 to give an agent suitable for coating the viscosity of the organic solvent, specifically published as ϋ ϋ read (4) liquid organic 溶 ethyl ester, acetic acid butadiene fat: di: xylene, etc. Aromatic cigarettes; hexose acetate, arsenic fat alicyclic hydrocarbons; or the purpose of the dispersion, that is, no _ limited '. However, if the above coating and distribution of the adhesive coating liquid ^ B can be achieved And the three kinds of photopolymerization initiators are obtained by: obtaining the organic solvent solution in the polymer A and the polymer agent, and the dissolving ratio is not particularly limited. Example 21/47 201241131 For example, the monomer B' photopolymerization initiator can be directly added to the acrylic slurry containing the polymer A, and the monomer B and the photopolymerization initiator can be added to the liquid of the organic solvent in the polymer A. t In the present invention, the hydroxyl group-containing (meth)acrylic acid acrylate monomer used as the monomer B may be, for example, (meth)acrylic acid 2-acetic acid acetate, (meth)acrylic acid 2 - propyl acetoacetate, (meth) propyl acetoate 3- propyl acetonate '(methyl) acrylate 4 - hydroxybutyl ester, (meth) acrylic acid 5- Hydroxyamyl ester, 6-hydroxyhexyl (meth)acrylate, 7-hydroxyheptyl (meth)acrylate, 8_=yloctyl (meth)acrylate, 7-fluorenyl-8-hydroxy (meth)acrylate Octyl ester, (meth)propionic acid 2-methylhydroxyoctyl ester, 9-hydroxydecyl (meth)acrylate, (methyl) = enoic acid 10-hydroxydecyl ester or (meth)acrylic acid 12-hydroxyl Lauryl ester, etc. These I may be used alone or in combination of two or more. In particular, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate or 4-hydroxy(meth)acrylate Butyl ester is suitable. The hydroxyl group-containing (meth) enoate is suitable for hydroxyalkyl (meth) acrylate. This is the thief of the diol (diol compound). One of the hydroxyl groups is acetated with acrylic acid or methacrylic acid to obtain one of a hydroxyl group and a vinyl group. The monomer B__ used in the present invention varies depending on the adhesion of the adhesive tape and the storage elastic modulus. In the case of = adhesive, since it can be _the number of modulo 7 and = the object, it is an indicator of bismuth monomer B, and it is preferable to use Tg at room temperature or higher. It is necessary to have strong adhesion. Or when it is desired to lower the storage elastic modulus, the temperature of the anti-temperature is preferably such that g becomes zero lower temperature (photopolymerization initiator) 22/47 201241131 ^In the invention, the photopolymerization initiation_combination 疋, examples thereof Such as: acetophenone photopolymerization initiator, Anzixiang Li: polymerization initiator, diphenyl ketone Liguang 肀 human tank d female heart 糸忐 糸忐 starter or other photopolymerization initiator, etc. The photopolymerization initiator may, for example, be: ethyl ketone, ρ·(third butyl), 1,1 -dioxaacetophenone, benzene benzene, etc., 2,2, _diethoxybenzene _ , acetophenone, 2,2·dimethoxy 2, phenyl acetophenone, 2-amino acetophenone or dialkyl amide copper, etc. Listed as: diphenylethylene dioxime, arsenic, benzoin oxime & |, benzoin (10), benzoin _, benzoin ^ : Jun, hexyl hexyl phenyl _, 2 • hetero _2 _ methyl benzene Base - A ^ 丙 院 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副 副. The diphenyl-photopolymerization initiator may, for example, be diphenyl ketone, stupid abbreviated acid, benzoic acid hydrazine hydrazine, methyl·0_benzhydryl benzoic acid vinegar, 4 Stupid base (four), transbasic phenyl group, phenyl diphenyl ketone, diphenyl acrylate or 4,4 ' bis (di) amide group, two stupid and the like. (4) The ketone-based photopolymerization initiator may, for example, be an anthrone, a 2-chloropyridone or a 2-indenyl group.塞"顿_ or diethyl gar, dimethyl ketone, etc. Other examples of the photoinitiator can be exemplified by: α·Silk, benzoquinone-oxime-ethoxymethyl)_〇:·single, II-based phosphine oxide, ethyl vinegar, fragrant 3 - ketone, 2-ethyl fluorenone, camphor, tetrakisyl thiuram disulfide, azobisisobutyronitrile, peroxidation, second-pass peroxide or tert-butyl peroxyisobutyrate . These photopolymerization initiators may be used alone or in combination of two on 23/47 201241131. The content of the photopolymerization initiator is preferably from 0.005 to 5% by mass in the total amount of the polymerizable compound (in the present invention, a mercapto group-containing acrylate) as a 100% by weight weight ratio. When the content of the photopolymerization initiator is from 5% to 5% by mass, the polymerizable compound can be polymerized in a short time, and when it is 5% by mass or less, the photopolymerization initiator is used. The residue does not easily remain in the hardened material. Further, as described above, the monomer B containing a thiol-based acrylate (the total amount when two or more kinds are used) is preferably from 3 to 20 parts by weight, based on 100 parts by weight of the polymer A, for example: A temperature of 85 is required. 〇 <After the humidity of 85% RH is high in the high temperature and high humidity, such as a test, it is preferably 5 to 15 parts by weight. Therefore, the light is based on 1 part by weight of the polymer A. The content of the polymerization initiator is preferably from 〇〇1 to 〇5 parts by weight. In the present invention, it is desirable that the adhesive composition after photopolymerization is polymerized in the range of 40 to 80% by weight (preferably 5 to 7 % by weight) of the monomer. That is, the residual range of the unreacted monomer is expected to be in the range of 6 Torr to 2 Torr by weight (preferably 50 to 25 wt. / 〇). When the polymerization rate is less than 4% by weight, the obtained polymer does not have sufficient adhesiveness, and in the polymerization rate exceeding 8 8% by weight, the cohesive force is lowered, and when the adhesive layer is peeled off, residue is generated. Glue phenomenon. A material which is obtained by applying a raw material composition for an adhesive to a substrate to form an adhesive tape, has transparency, heat resistance, and 35 〇 nm to 4 硬化 which hinders curing of the ultraviolet curable resin composition. It is preferable that the scattering/absorption is small in the ultraviolet region near 〇nm. For example, polyethylene terephthalate (PET) or polyethylene naphthalate (pen), such as polyester, polyglycol, poly-wind, polystyrene, polyglycolate, and poly Polyethers such as ether ketone, polycarbonate, polyethylene or polypropylene, polyamide, nylon, 24/47 201241131 Polyimine, triethylene fluorene cellulose (cellulose triacetate), cellulose diacetate, hydrazine棊)Acrylic acid: ester, poly(fluorenyl) acrylate copolymer, poly(methacrylic acid) styrene, polytetrafluoroethylene or polytrifluoroethylene fluororesin, poly & Ethylene copolymer, ethylene ethoxide-acetic acid acetonitrile copolymer, polyvinyl alcohol, cell 〇 e 或 or cellulose film. These materials may be used alone or in combination of two or more. In particular, in the above substrate, polyethylene terephthalate is preferably used in terms of heat resistance, ultraviolet transmittance, and price. Further, the thickness of the substrate is preferably from 16 to 200 / / m, and more preferably from 188 mm. When the thickness of the substrate is too thin, the thickness of the substrate is deteriorated. The thickness of the substrate is excessive, which is disadvantageous due to an increase in manufacturing cost, and is also disadvantageous due to a decrease in workability. (Transparent Resin Film) The substrate used in the adhesive tape described in the present invention 俜 The optical element of the layer or the second; the heat is fixed at a high temperature of about 5%, and the shoulder has a heat resistance of at least 1503⁄4. ^This is such a heat resistance _ _ (4) is a (four) selected from the group consisting of polyethylene terephthalate _, polyethylene naphthalate; ^ ^ formed into a resin film: b) r conductive laminated body -General heat treatment temperature *丄t:: Guide: Product 2 == 25/47 201241131 Words, preferably in the form of rollable. Therefore, the transparent resin film must have burntability. In order to have a thickness of the flexible 'transparent resin film, _ is less, and the thickness is preferably from 10 to 150 (four). When the thickness is _ down, _ (four) is soft and __, and the thickness is 5 〇〇 (4), because the rigidity is too strong to be rolled into a report. Further, the transparent resin film used in the base material of the adhesive tape of the present invention has a heat shrinkage rate at 150 ° C for 3 minutes, a MD direction (flow direction at the time of film formation), and a TD direction (width at the time of film formation). In any direction of direction), it is preferably 0.5% or less. The substrate towel of the adhesive tape of the present invention enables the translucent film to have a heat-shrinkage rate of 0.5% or less in any of the MD direction and the TD direction as described above, so that the heat treatment step or the like can be performed. The curl caused by the generated thermal stress is reduced. Therefore, the transparent resin film used in the substrate of the adhesive tape of the present invention is preferably subjected to a S-fire treatment which reduces the heat shrinkage rate. By the application of the annealing treatment, a polyester resin having a heat shrinkage ratio of 1% or less (preferably 0.5 or less) can be obtained. The conventional annealing method can be carried out by the annealing treatment performed on the transparent resin film used for the base material of the adhesive tape of the present invention. The transparent resin film used in the base material of the adhesive tape of the present invention is, for example, a mechanical The strength is excellent, so the polyethylene terephthalate (ρΕτ) film is biaxially oriented. The cooked oriented PET is fine, and the unstretched H PET film is pulled in the longitudinal direction and the width direction. After stretching for about 2 to 6 彳p, the crystals are oriented by heat treatment. Moreover, when the biaxially oriented PET is used, the PET film is subjected to 15 (the heat shrinkage measured by the PET film after TC heating for 30 minutes is at The length direction of pET and the vertical direction of 26/47 201241131 are less than 5%. It is better to be etched by annealing treatment, etc. The PET film is heat treated at high temperature. In the private state, since the deformation of the PET film substrate is small, it is easy to manufacture a high-precision panel. Further, the transparent resin film used in the substrate of the adhesive tape of the present invention can be formed by extrusion molding. Membrane method or solution casting ^ (Solut Ion Casting) Thin film-formed unstretched transparent pET film, such as film forming method, further subjected to annealing treatment to have a heat shrinkage ratio of 5% or less. Further, if it is produced by a solution casting method, the MD direction of the film can be made and It is preferable that the residual stress in the TD direction is lowered. The transparent resin film used in the substrate of the adhesive tape of the present invention also uses a cyclic poly; #te. The cyclic polydisperse main chain has an alicyclic structure of a polyolefin. Examples of the alicyclic structure of the main chain include a naphthenic structure and a cyclic hydrocarbon structure. Specific examples of the cyclic polyolefin include, for example, a norbornene-based polymer and a monocyclic cyclic alkene (IV). Polymer, a total of diene-based polymers, and hydrogenated products, ethylene alicyclic hydrocarbon polymers and their chlorinated compounds, cyclic dilute hydrocarbon monomers and ethylene-addition polymers. Examples of the cyclic polyolefin-based resin to be sold include, for example, the product name z_r 1060R 〇 (release film) manufactured by ZeGn (8), Japan. The adhesive tape of the present invention is peeled off on one surface (for example, the top surface) of the transparent resin film. The treated release film 3 is laminated via the adhesive layer 2. The substrate of the release film used in the film may be, for example, paper such as Daolin paper, transparent paper or coated paper; polyethylene terephthalate (ρΕτ), polyethylene naphthalate (SI) (PEN), poly Synthetic tree such as quinone imine (ΡΙ), polystyrene (pps) diethylene and polypropylene, polyolefin resin, polyethylene powder resin, polyuric acid 27/47 201241131 vinegar resin, acrylic resin, fluorine resin, etc. In terms of easiness, 'the synthetic resin is suitable. The thickness of the base material of the wood release film is not particularly limited, and the substrate which can be used' can also be formed by laminating a plurality of sheet-like base materials. , ^ New can be color-coded or in order to give the secret to the secret layer of the _ thin _ substrate on the side of the money. The method of the peeling treatment can be carried out by coating a single side of a sheet-like substrate with a compound such as a sulphur compound or a chain-burning compound = (transparent conductive laminated body) The adhesive tape of the present invention is singulated on a transparent substrate The surface of the transparent layer 3 - ® is preferably a transparent conductive film formed of a hard-coated transparent conductive laminated body: a transparent conductive laminated body is formed on the translucent surface thereof, === in the conductive laminated body, the material is a group of resistant resin made of polyethylene terephthalate _ resin, polynaphthalene resin, and cop resin. Choose one type or transparent glass substrate. US: The thickness of the transparent substrate used in the daily laminate. When the transparent substrate is a transparent fine enamel substrate, it is preferably 0 to 250 _ = two transparent:: material; drought, such as (4) - When thin, the thickness is reduced by M] G to 25G " m is better, and 28/47 201241131 30 to 200 #m is better. Further, the target substrate of the adhesion of the electric film and the transparent guide: a shaft for easy adhesion or a flame treatment; surface treatment such as slurry treatment. In addition, it is also treated by the electric army and the bottom coating between the electric films. Turning the substrate and the transparent conductive layer in the transparent conductive laminated body: the surface material of the plate can be used as the second = two protective - general and a 'error pen hardness test value 2 /, the title: deleted The resin is not particularly limited, and is a thermosetting type protective layer resin such as a chylomicron or a melamine-based amine, or an ultraviolet curing type lyophilized tree such as a sulphuric acid or an acrylic acid. ', two::: the thickness of 1 to 1 〇 _ is better 'from 2 to 8 two = the ratio is thinner than the thin one', the protection is not easy to occur ^ does not make the ultraviolet curing type protective layer resin, and When the thickness of the protective layer is thicker than 1 〇 / / m, the protective layer film itself is easy to curl, and the θ valley is = and the lining can be added as necessary. (4) The antistatic agent and the protective layer are given ==:= = = = Conventional methods such as brushing. The g-gravure printing plate of the transparent conductive substrate of the transparent conductive laminated body of the present invention is formed by a method selected from the group consisting of a transparent conductive film forming method, and a transparent conductive film layer is formed. In the forming step, or after the step of forming the transparent conductive film 29/47 201241131, and including forming a pair of the transparent conductive film. The method of forming the wiring pattern of the transparent electrode can be carried out by the method of the conventional method. The method represented can be graphically shaped as a button. Further, a conductive film layer may be formed on the glass substrate as a transparent conductive substrate. = coating device for coating the raw material composition on the substrate, such as two; (4) uniformly supplying and coating the raw material composition for the adhesive on the substrate: coating 2:::::: even: the adhesive is grounded The raw material composition for the raw material composition supply: the storage of the material is suitable for the storage of the adhesive system, and the like. In the cloth cloth device, the enamel film layer (coating film) of the raw material composition is formed on one side of the substrate. Further, after the coating = cloth, the raw material composition for paste is not hardened and is liquid, and has fluidity suitable for coating. Thickness: ,), the thickness of the coating film coating film (4) is more than 2 mm. equal. In the present invention, the thickness of the adhesive layer is almost equal to the thickness of the adhesive layer of 4 mm, and preferably 3] to 2 plus. The raw material composition for the adhesive is a solution = thick, and becomes the above-mentioned coating film thickness == sub. The thickness of the coating film after 2 is the same as that of the scented liquid. After the degree of suction, the thickness of the adhesive layer is also thinned, so that the impact is poor. In addition, 'coating_thickness: 30/47 201241131 is disadvantageous. n is a schematic display of the method for producing a transfer belt of the present invention. The coating film 12 is formed on the substrate 11. Reference numeral 22 is a support roller 22 which is disposed on the base material U of the floor. Shape L2 cloth = (four) in addition to ^ tree drying room 23 _. After drying, the separator 13 is supplied onto the coating film 12 by the reverse supply shock 24, and is bonded by the nip roller 25. The temperature in the tempering chamber 23 is such that the solvent in the coating film 12 is sufficiently = the temperature at which the polymerizable compound rides is not riding the temperature of the thermal polymerization. The separator supply device 24 is formed by winding a separator 13 into a cylindrical body, a shaft of a cylindrical body, or the like. The nip roller 25 is composed of a pair of rollers in which the substrate u and the separator 13 on which the coating film 12 is formed are sandwiched, and the two are attached to each other to provide a pressing device for bonding. Preferably, it is preferable to apply a uniform pressure to the film, and it is preferable that at least one of the rolls is made of rubber. ▲ Examples of the separator include, for example, a polycarbonate film, a polyacrylate film, a polyether ruthenium film, a polyhard film, a film of a poly amide film, a polyimide film, a polystyrene film, and a poly An olefin film, a decylene-based film, an oxime-based polymer film, or a single-layer or a plurality of layers of a plastic film formed of an organic gas-permeable film, which is subjected to a release treatment by a polyfluorene-based release agent or the like to at least single A release sheet having a peeling property on the surface; a release paper having a peeling property on at least one side, a fluorine-based resin film or a film such as a polyolefin film, which is subjected to a release treatment such as a polychlorinated release agent or the like. It has its own phase of stripping 31/47 201241131; it is internally added with a stripping ride. The degree of the separator is not particularly limited, and it is generally made 5 to 5 mm, preferably 10 to 1 〇〇 _. The separator is the choice of the agent and the strength of use. The ...t external line irradiation device 26 is provided with a cooling device that generates a ultraviolet light source unit and removes heat generated by the light source. The light source unit is a light-emitting diode that can sufficiently cure the polymerizable compound of the coating film, and can be used in a high-pressure mercury lamp, a metal-near light source, or a light-emitting diode having a light-emitting material in an ultraviolet region. The towel is free to choose. The coating film 12 is polymerized by irradiation of a polymerizable compound in the coating film 12 with a suitable sheet to improve cohesive force and to be county-inducing. Further, in the case of manufacturing a double-sided adhesive tape such as a transfer tape which is a transfer tape of the present invention, it is supplied not only as the separator 13 but also as a substrate for conveyance u. A separator, a primer layer is formed on the separator. Further, in the case of manufacturing a double-mask which is a support for the adhesive tape of the present invention, the application of the coating liquid, the drying, and the photopolymerization of the coating film can be carried out at each off time or sequentially. After the light irradiation for photopolymerization, the crosslinking reaction is carried out for maintenance. The method of curing is not limited, for example, it can be placed in a _ shape and placed under a predetermined temperature and coffee conditions. The curing temperature also varies depending on the type of the crosslinking agent, and should be heated as needed (for example, 4 () to 8 〇. (7). The adhesive layer to be applied is to adhere the adhesive surface to the adherend After leaving 1 + at 23 ° C and 5 G % RH € , the peeling speed is 300 mm / min. The adhesion of the glass and the acrylic resin is preferably l / N / 25 mm or more. Obtaining such high-saturation, the adhesive that forms the adhesive layer of 32/47 201241131 is above 23t, 104Pa and less than 1χ1()6ρ to be better at lx a, at 85 ° C, 85% RH When ordering 4 temples for high durability, mu) Va or more 5xl 〇 5pa =: more: when the modulus of elasticity is low, the adhesive layer is soft and easy to fit. When the storage modulus is within the above-mentioned range, it is a combination of two components (for example, a hard material such as a glass plate or an acrylic plate), and the bonding property after bonding. Sex, as well as adhesion. The adhesive tape of the present invention can be applied to the use of a member to be bonded to the face of a transparent conductive laminate used in a touch panel or the like. EXAMPLES Hereinafter, the present invention will be specifically described based on examples. Using the raw material compositions for the adhesives shown in Table 1 below, the adhesive tapes of Examples 1 to 3 and Comparative Examples 1 to 6 were produced as follows. 33/47 201241131 [Table i] Polymer A (acid value) Hardener / Additive monomer B Photopolymerization initiator Kinds Parts by weight Types and parts by weight Example 1 2094 (33) E-AX 0.27 4HBA 10 Irgl 84 Example 2 2147(0) TD-75 A-50 0.06 0.04 4HBA 5 Irgl84 Example 3 2147(0) TD-75 A-50 0.06 0.04 4HBA 10 Irgl84 Comparative Example 1 Control group - Comparative Example 2 2094(33) E-AX 0.27 - - Comparative Example 3 2147(0) TD-75 A-50 0.06 0.04 - - Comparative Example 4 2147(0) TD-75 A-50 0.06 0.04 4HBA 15 Irgl84 Comparative Example 5 AA/2EHA=13/ 87(101) EX-830 0.8 4HBA 6 Irg651 Comparative Example 6 AA/2EHA=5/9 5(38) EX-830 0.6 4HBA 4 Irg651 Furthermore, in Table 1, 2094 and 2147 respectively represent SKDYNE (registered trademark) 2094, SKDYNE (registered trademark) 2〇47; "AA/2EHA" means a copolymer of acrylic acid and 2-ethylhexyl acrylate; "4HBA" means 4-hydroxybutyl acrylate; Irgl84 and lrg651 respectively represent irgacure (registered trademark) 184, Irgacure (registered) Trademark) 651. Further, the photopolymerization initiator of Irgacure (registered trademark) 184 has a μ-based cyclohexyl-phenyl-ketone as an active ingredient. Product Name: The photopolymerization initiator of Irgacure (registered trademark) 651 contains a clumpy dimethyl ketal as a component. — 34/47 201241131 (Example 1) As a material for a pressure-sensitive adhesive composition (Polymer A), SKDYNE 2〇94c Comprehensive Chemicals Co., Ltd. was used in an amount of 1000 g: 2.7 g, respectively; Value: 33) A solution prepared by preparing an acrylic resin polymer (polymer enthalpy) from a solution prepared by using 硬化_ΑΧ (manufactured by K.K. Chemical Co., Ltd.) as a curing agent. In the obtained pressure-sensitive adhesive composition (polymer enthalpy), an acrylic acid 4-mercapto butyl group which is a monomer (monomer oxime) containing a hydroxyl group (mercapto) acrylate is additionally added (Osaka Organic Materials Industry ( Manufactured; 4HBA) l〇〇.〇g, photopolymerization initiator with alkyl benzoquinone (manufactured by Ciba-japan); product name: ι84) 〇.ι〇§, used as an adhesive The raw material composition. The substrate is composed of polyethylene terephthalate (Mitsubishi Shuyue Co., Ltd.; product name: Tl〇〇' thickness 38/zm) coated with a coating machine On the upper surface of the film, the thickness of the adhesive layer after drying was 2 G"m. New, make it dry, and make a laminate with a layer of adhesive. Then, the separator (made by Mitsubishi Resin Co., Ltd., product name: MRF, thickness 38_) was laminated on the adhesive layer of the obtained laminate, and a laminated film having an adhesive layer was formed. Using a continuous uv irradiation device of a high-pressure mercury lamp, the irradiation amount is about 2 〇〇mj (wavelength to 400 nm), and the conveyance speed of the adhesive film as a substrate and the light of the UV county are adjusted. Lay, shot uv j is photopolymerized, and the initiator is polymerized to obtain the adhesive tape of the first embodiment having the adhesive composition (polymer C). 35/47 201241131 (Example 2)

In addition to the material of the pressure-sensitive adhesive composition (Polymer A), SKDYNE 2147 (manufactured by Synthetic Chemical Co., Ltd.; acid value: 〇) was prepared using a knife at a ratio of l〇〇〇g : 0 4g : 〇 6g. ), TD-75 (manufactured by Kaneko Chemical Co., Ltd.) as a curing agent, and red solution prepared by A_5〇 (manufactured by Xiagen Chemical Co., Ltd.) as an additive, which is composed of C. Pressure sensitive adhesive composition (Polymer A). In addition to the obtained pressure-sensitive adhesive V] composition (Polymer A), it is additionally added as a monomer containing a mercapto (fluorenyl) acrylate (monomer printed 4_hydroxybutyl acrylate (Osaka organic material) Industrial (stock) manufacturing; 4HBA) 5〇〇g, with alkyl ketone-based photopolymerization initiator (Ciba-japan (manufactured by the company); product name: __ 184) 0.10g, prepared into an adhesive The adhesive tape of Example 2 was obtained in the same manner as in Example 1 except that the raw material composition was obtained. (Example 3) As a material of the pressure-sensitive adhesive composition (Polymer A), respectively, 1000 g : 〇 was used. .4g : 〇.6g ratio of SKDYNE2147 (manufactured by Xiagen Chemical Co., Ltd.; acid value: 〇), TD_75 as a hardener (manufactured by Xiagen Chemical Co., Ltd.) and A-50 as an additive a method of preparing a solution of the pressure-sensitive adhesive composition (polymer A) composed of an acrylic resin polymer, in addition to the obtained pressure-sensitive adhesive composition (polymer A), Further added 4-butyl butyl acrylate as a monomer (monomer B) containing a trans (meth)propionic acid vinegar (Osaka Organic Materials Industry Co., Ltd. manufactures '4HBA) 100.0g, and is a photopolymerization initiator (manufactured by Ciba-Japan Co., Ltd., product name: ilgacure i84), which is used in the preparation of an adhesive. In the same manner as in Example ,, the same procedure as in Example , was carried out to obtain an adhesive tape of Example 3. 36/47 201241131 (Comparative Example 1) ιτ as a point for comparing the present invention to ιτ〇s The surface of the surface of the _ _ _ scale (group), the county posted the enamel film of the adhesive tape of the invention (made by Zhong Jing Wei # (share); product name: =etaforce 125R2XA, surface resistivity In the oven (Comparative Example 2) 材料 材料 Μ SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK SK Month and '酉 ..33.', as the hardener e_axc comprehensive research chemistry (share W made) prepared by the adhesive _ composition (polymer 〇, the light is the same as the same example 1) The adhesive tape of Comparative Example 2. (Comparative Example 3) Eight materials except for L as a composition for an adhesive (Polymer C) were used. 00g · 〇.4g · 〇.6g ratio of SKDYNE 2147 (Comprehensive chemistry (shared 舻 舻 舻 Λ 庳 庳 文 文 文 文 文 文 文 文 文 文 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 TD TD TD TD TD TD In the same manner as in the Example (4), the adhesive tape of Comparative Example 3 was obtained, except for the composition for the adhesive of the j-week S (polymer C). (Comparative Example 4) _ t Pressure-sensitive adhesive composition (Polymer A) was obtained by using a component of ... g · 〇.4g. 〇.6g in proportion to SKDYNE2147 (a comprehensive research); acid value: 〇) TD-75 (manufactured by Seiko Chemical Co., Ltd.) and a_5q (manufactured by Synthetic Chemical Co., Ltd.) as a curing agent to obtain a pressure-sensitive type of acrylic resin polymer. Secret (Polymer oxime). In addition to the obtained money hybrid composition 37/47 201241131 (Polymer A), acrylic acid 4 as a monomer (monomer B) containing a hydroxyl group (meth) acrylate is additionally added. -Hydroxybutyl ester (manufactured by Osaka Organic Materials Co., Ltd.; 4HBA) 150.0 g, with an alkyl ketone-based photopolymerization initiator (manufactured by Ciba-Japan Co., Ltd.; product name: Irgacure 184) 〇1〇g The adhesive tape of Comparative Example 4 was obtained in the same manner as in Example 1 except that the raw material composition for the adhesive (polymer C) was used for 5 weeks. (Comparative Example 5) As a pressure-sensitive adhesive composition (polymer) A) The material is used in an amount of 1000g: 8.0g to prepare acrylic acid/acrylic acid 2-ethylhexanyl = 87: 13 (acid value 101.25) in ethyl acetate A pressure-sensitive adhesive composition composed of an acrylic resin polymer is obtained by polymerizing 40% of a polymer and EX-830 (manufactured by Nagase Chemtex) as a curing agent. In the obtained pressure-sensitive adhesive composition (Polymer A), 4-butyl butyl acrylate (single B) which is a monomer containing a hydroxyl group (meth) acrylate (monomer B) is additionally added ( Manufactured by Osaka Organic Materials Industry Co., Ltd.; 4HBA) 60.0g, with a photopolymerization initiator of alkyl benzophenone (manufactured by Ciba-Japan Co., Ltd.; product name: ilgacure 651) 040g, prepared into a raw material for adhesives The same procedure as in Example 1 was carried out except for the polymer (polymer C) to obtain an adhesive tape of Comparative Example 5. (Comparative Example 6) As a material of the pressure-sensitive adhesive composition (Polymer A), 1000g: 6.0g ratio of acrylic acid / 2-ethylhexyl acrylate = 95 : 5 (acid value: 38.2) in acetic acid B - a concentration of 34% of the polymer, as a hardener EX-830 (Nagase Chemtex ) a solution prepared by the method of producing a pressure-sensitive adhesive composed of an acrylic resin polymer Composition (Polymer A). In addition to the resulting pressure-sensitive adhesive composition (Poly 38/47 201241131 A), a monomer which is added as a hydroxyl group-containing (mercapto) acrylate (monomer B) 4% hydroxybutyl acrylate (manufactured by Osaka Organic Materials Co., Ltd.) 40.0 g, and an alkyl ketone-based photopolymerization initiator (manufactured by Ciba-Japan Co., Ltd., product name: ilgacure 65i) The adhesive tape of Comparative Example 6 was obtained in the same manner as in Example 1 except that the raw material composition (polymer c) for the adhesive was prepared. <Testing Method of Adhesive Tape> * Using the adhesive sheets of the above Examples 1 to 3 and Comparative Examples 2, 3, 5, and 6, the adhesive tape was attached to the film to prepare a test piece, and the resistance of the film was applied. The measurement of the change magnification of the value, and the test for confirming the occurrence of white turbidity. Further, as a blank control group, in the comparative example, the ιτο film to which the adhesive tape was attached was directly placed in an oven, and the change ratio of the resistance value of the ιτ〇 film was measured. (Method for measuring the change rate of the resistance value of the conductive film of the moon) Preparing the film (made by Zhongjing Industry Co., Ltd.; Product Name:

2M5etaf°rrr5R2XA, the surface resistivity is then cut into a width =: Γ〇 _ long slice. In the cutting of the thin sheet of the ι 〇 长 长 长 长 长 长 长 长 长 长 长 长 长 财 财 财 财 财 财 财 财 财 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 In order to improve the bonding strength of the two = two, the test sample was put into the high pressure dad, = 40 degree. . A 15 minute heating operation was carried out. Apply silver paste to the film of the sample (10) of the sample of money (Fuji Canghuacheng (the sputum knives are not attached to the sticky tribute to the hot artillery, after the test sample for two minutes, it is called the 疋 terminal, against the tester, measured 39 /47 201241131 Determine the resistance between the two ends of the IT film as the initial resistance value of the transparent conductive film. Then, put the test piece into the oven at a temperature of 85 〇 < humidity 85% RH, after 500 hours, take it out, Again, the measurement terminals at both ends of the Ting (4) film are placed against the resistance between the two ends of the tester, as the resistance value after the environmental test in the high temperature and high humidity. The resistance value of the film after the test piece The change magnification is calculated according to the following calculation formula. (The change ratio of the resistance value of the transparent conductive film) The gas resistance at high temperature and high humidity 'degree of environmental resistance) / (initial resistance value) (Confirmation test for white turbidity generation) The test piece prepared by measuring the change ratio of the resistance value of the transparent conductive film was taken at a temperature of 85 ° C x a humidity of 85% RH, a high humidity piano, and taken out after 12 hours. Then, it was placed at a temperature of 50. Under the environment of %RH' with the naked eye Appearance change of test piece ^ recognize, there are considered two generators rated clouding (X) 'can not be confirmed were evaluated as cloudiness is generated (§ formula experimental results) The above test results are shown in Table 2. 40/47 201 241 131

(The measurement result of the change rate of the resistance value of the transparent conductive film) It is known from the test results of Table 2 that compared with the commercially available acid-based resin having an acid value of 0 to 33 Comparative Examples 2 and 3 of the pressure-sensitive adhesive composition (Polymer A) were added in the age-sensitive product (polymer t) composed of (4) I (four) lai in the same acid value of 〇 to 33. Examples 1 to 3 in which at least one of the hydroxyl group-containing (meth) acrylate monomers (monomer B) and a photopolymerization initiator are polymerized to form an adhesive composition (Polymer C), It can reduce the change ratio of the resistance value of ITO. The inventors believe that the one (monomer B) of the monomer having at least a hydroxyl group-containing (meth) acrylate does not increase the change ratio of the resistance value of the ITO film, and is added to the commercially available acid value 〇 to 33 of acrylic resin rouge. When the composition of the adhesive composition (polymer A) is formed, the polymer A is diluted with the monomer B to increase the warp group in the resin, whereby the effect of lowering the change ratio of the electric resistance value of the ITO film can be obtained. The acid value was larger than that of Examples 1 to 3. More than the introduction of the monomer B and the photopolymerization initiator, the change ratio of the resistance value of the film of Ting 41 / 47 201241131 was significantly increased. From this, it was confirmed that the effect of further reducing the change ratio of the electric resistance value of the ITO film is not only the presence of the polymer of the monomer B, but also the acid value of the marine product (polymer A). (Successful test results of white turbidity of the adhesive tape) It was not possible to confirm the occurrence of white turbidity in Examples 1 to 3 and Comparative Examples 5 and 6. In Comparative Examples 2 and 3, the occurrence of white turbidity was confirmed. Comparative Examples 2 and 3 Since the monomer and the photopolymerization initiator were not introduced, the monomer B could not be polymerized even by UV irradiation. In Comparative Example 2, since it was not possible to improve the effect of preventing the whitecurrant, it was confirmed that the monomer B polymerizer had an effect of improving self-healing. In the case 4, since the monomer B and the photopolymerization initiation_ are present, the photopolymerization agent reacts under irradiation. However, in Comparative Example 4, as compared with Example 3, since the content of the monomer B was large, white turbidity was caused in Comparative Example 4. From this, it was confirmed that white turbidity does not occur under the general conditions, and the effect of preventing white turbidity when taken out from high temperature and high humidity is not only the presence of the polymer of the monomer B, but also the composition ratio is important. In addition, the graph shown by the change in the haze value after taking out the environmental test (4) under high temperature and high humidity in Fig. 3 is available for reference as a white turbidity after environmental test under high temperature and high humidity. The effect of the invention. In the embodiment 1 of the adhesive tape of the present invention, even after being taken out from the oven for environmental test under high temperature and high degree, and after being taken out from the oven, the haze value is unchanged after 6 minutes, and it is known that Prevent white turbidity and produce excellent performance. On the other hand, in the case of Comparative Example 2, just after 11% of the large value in the environmental test box of the 42/47 201241131 environmental test in high temperature and high humidity, the tendency to rise to the lowest value with the value of the M group . However, it can be seen that the value of the slow haze is lower. The state of white turbidity can last for 120 minutes to be between the fine soil hU, between the plates or between the poly-p-butyl phthalate (PET) and the like. Force plate ==='In the case of poor gas permeability, any white turbidity generated in the environmental test of the hood is caused by the white turbidity disappearing (4) to be transparent when placed in the tray for several hours. From the above results, it is possible to provide a method for producing a composition of a prefecture agent, a composition for an adhesive, and a method for producing a composition of Laiqi #j, as the main ingredient of the present invention: The acid value is 〇 to 33 by the acrylic acid pressure sensitive adhesive (tetra) polymer (polymer A), the monomer containing the acid vinegar is less - the species (monomer B) and the silky adhesive roller Silk, the county riding agent composition (polymer 〇, by this, even if it is attached to the surface of the transparent conductive film, the change of the surface, and the environmental test under high temperature will not A white turbidity is formed in the adhesive layer. [Schematic description of the drawings] Fig. 2 is a cross-sectional view schematically showing an example of a single-sided adhesive tape having an adhesive layer formed using the adhesive composition of the present invention. A cross-sectional view showing an example of a transfer belt of an adhesive layer formed of the adhesive (four) composition of the present invention is shown in Fig. 2, which is an explanatory view showing an example of a method for producing an adhesive film of the present invention, 43/47 201241131. 3A shows an environmental test just under high temperature and high humidity for Example 1 and Comparative Example 2. A graph showing the change in haze value after taking out in an oven is used as a reference for the effect of the present invention which does not cause white turbidity after an environmental test under high temperature and high humidity. Fig. 3B is an enlargement of the time of Fig. 3A to 0. Chart of the range of 40 minutes. [Main component symbol description] 1 Substrate 2 Adhesive layer 3 Separator 5 Single-sided adhesive tape 6 Transfer belt 11 Substrate or separator 12 to be transported Coating film 13 Separator 21 Mold coating Machine 22 Support roller 23 Drying chamber 24 Separator supply device 25 Clamping roller 26 Ultraviolet irradiation device 44/47

Claims (1)

201241131 VII. 1. Patent application scope: A method for adhering the adhesive composition of the above-mentioned IT 〇 surface to the above-mentioned IT 〇 surface adhesive composition, and is via at least the following (1) to (7) Step = to the method of having the physical (κ) adhesive composition (polymer c), in step =) adjusting the raw material composition for the adhesive, the adhesive raw material composition will be from the acid value to 33丙 烤 成 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 'To obtain a physical (κ) adhesive composition (poly I) step, the above physical properties (Κ) are defined as follows: After applying the adhesive composition (polymer c) on the surface of the crucible, the degree is 20 After the film was taken out from the baked phase of the environmental test at a high temperature and high humidity for 500 hours at a temperature of 85 tx and a humidity of 85 Å, the change ratio of the resistance value of the ITO film was compared with the initial value. .7 times or less, just taken from the above oven into the 2. (polymer C) layer and No white turbidity is produced. A method for producing an adhesive composition, which is a method for adhering an adhesive tape (4) of a composition of the rib surface of a transparent conductive film composed of ιτ〇, and A method of obtaining an adhesive composition (polymer enthalpy) having physical properties (K) by at least the following steps (1) to (3), (1) a step of adjusting a raw material composition for an adhesive, and a raw material for the adhesive The composition is composed of an acrylic resin having an acid value of 〇33 to 45/47 201241131. (7) A method in which the thickness of the base film composed of the elongated thermoplastic resin is 2 〇 to _ a step of applying a raw material composition for the above-mentioned adhesive and drying it to form a long strip coating; (3) using the above-mentioned elongated coating film, performing polymerization reaction by riding light to obtain physical properties on the substrate thin layer The step of the material (Polymer C), n and the above physical property (K) are defined as follows: Applying an adhesive composition (Polymer c) on the surface of the ITO and forming a film after f, 20 μm 'from the temperature at 85 tx Humidity 85 〇 fine = implementation under extreme conditions After the hourly high temperature, high humidity environment test was taken out in the oven, the change ratio of the resistance value of the ITO film was 1.7 times or less compared with the period value, and the agent (polymer c) was just taken out from the above oven. There is no white wealth. ^ 3. An adhesive composition consisting of an acrylic resin containing an acid value of 〇 to 33. Adhesive composition (Polymer A) Solid content _ part by weight, inclusive At least one of the monomers of the hydroxyl group (meth)acrylic acid (monoterpenoid B), 5 to 15 parts by weight, and the photopolymerization initiator, to the polymer c, which is 0.5 parts by weight, And the physical property (K), the above physical properties (Κ) are defined as follows: /, no surface coating adhesive composition (polymer c) to form a film after drying thickness of 20 〇 _, from the temperature of 85 ° 5 (: χ humidity%. Under the circumstances of the implementation of the small _ high temperature, high humidity Wei test for the removal of the resistance value of the ITO film after the removal of the phase, compared to the initial 46/47 201241131 4 · 5. 6. The value is at 1 · 7 When it is just taken out from the above oven, no white turbidity is generated in the layer of the adhesive composition (polymer C). An adhesive tape obtained by laminating an adhesive composition (polymer c) produced by a method for producing an adhesive composition according to the first or second aspect of the patent application. The adhesive layer is laminated on the base film and has an adhesive composition (polymer c) as disclosed in claim 3, which is a tape which is attached to the surface of the patent application. The shaft used on the display is strapped. * $ ''s make the component fit on the display 47/47