TW201236887A - Transcription method of 3D pattern solidified with UV light - Google Patents

Transcription method of 3D pattern solidified with UV light Download PDF

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Publication number
TW201236887A
TW201236887A TW100117773A TW100117773A TW201236887A TW 201236887 A TW201236887 A TW 201236887A TW 100117773 A TW100117773 A TW 100117773A TW 100117773 A TW100117773 A TW 100117773A TW 201236887 A TW201236887 A TW 201236887A
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TW
Taiwan
Prior art keywords
film
sub
substrate
graphic structure
ultraviolet light
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TW100117773A
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Chinese (zh)
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TWI385078B (en
Inventor
rui-fa Xie
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Imprinting Lithography Decoration Tech Co Ltd
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Priority to TW100117773A priority Critical patent/TW201236887A/en
Publication of TW201236887A publication Critical patent/TW201236887A/en
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Publication of TWI385078B publication Critical patent/TWI385078B/zh

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Abstract

A transcription method of a 3D pattern solidified with UV light includes providing a mother board having stick-proof processed and a first pattern, providing a child film coated with a first light solidifying glue, laminating the mother board and the child film so that the first light solidifying glue penetrates into the first pattern, solidifying the first light solidifying glue to form a second pattern on the child film, separating the child film from the mother board, providing a substrate coated with a second light solidifying glue, baking the substrate to transcript the second pattern onto the substrate so that a third pattern is formed on the substrate, solidifying the second light solidifying glue and exposing the substrate under the light. The present invention can form a 3D pattern on the shell of any electronic device.

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201236887 六、發明說明: 【發明所屬之技術領域】 一種轉寫方法’特別是指一種紫外線光固化立 體圖文轉寫方法。 【先前技術】 隨著科技的進度’大量的3C產品,如智慧型手 機、筆s己型電腦等各項產品,已成為現代人於曰常 生活上不可或缺的產品。 而筆記型電腦及各式3C產品,為追求視覺美 感,於其外殼上多半會作一些裝飾處理❶以傳統之 處理方式而言,若外殼材質為塑膠時,多半以噴塗 上色的方式來作處理。然而,此種製程方式均會於 製程中產生或多或少之有毒廢氣,造成汙染。此外, 喷塗後須額外作二次加工之程序,步驟繁瑣。 此外,亦有使用金屬表面裝飾處理的技術,對 外殼作表面處理,如使用化學著色、電解著色、裝 部電鍍或金屬表面蝕刻等技術,如於金屬殼體上: 生髮絲紋路。然而,此種處理方式成本較高,且具 有難以回收使用之缺點。 再者’傳統裝飾處理方法,多半僅能於外殼表 :作平面裝飾處理’而無法達到立體造型之裝飾效 果’無法完全滿足消費者對於美觀造型之要求。 201236887 【發明内容】 本發明之主要目的’旨在提供一種紫外線光固 化立體圖文轉寫方法,其可將立體圖文結構光固化 於基材上,以增進圖案及圖文之立體美觀感。 為達上述目的,本發明之紫外線光固化立體圖 文轉寫方法,其係包含下列步驟:首先,提供一母 板’該母板係經抗沾處理並具有一第一圖文結構; 接著,提供一子膜,該子膜係塗佈一第一光固化膠; 接著,滾壓貼合該子膜及該母板,以滲入該第一光 固化膠至該第一圖文結構;接著,光固化該第一光 固化膠’於該子膜上形成一第二圖文結構;接著, 離形該子膜及該母板;接著,提供一基材,該基材 係塗佈一第二光固化膠;接著,烘烤該基材;接著’ 轉寫該第二圖文結構於該基材,使該基材上形成一 第一圖文結構’並同步光固化該第二光固化膠,以 疋型該第二圖文結構;最後,正照處理該基材。 其中’於離形該子膜及該母板步驟後,該子膜 更經由下列步驟所處理:正照處理該基材,該第二 圖文結構係經二次光固化;電漿處理該子膜,該子 膜係、’’呈一-人至二次電漿處理;抗沾處理該子膜,該 子膜所使用之抗沾劑係為含氟化合物或矽膠;烘烤 處理該子膜’該子膜之棋,烤溫度為攝& 60度至12〇 度,烘烤時間為5至1〇分鐘。 其中,該第一光固化膠及該第二光固化膠係經 4 201236887 一紫外光照射而光固化’該紫外線光之照射能量係 為 500mj/cm2〜3〇〇〇mj/cm2。 其中,洪烤該基材之步驟中,當該基材為金屬 材料時’烘烤溫度係為攝氏5〇度至120度,棋烤時 間係為3〜1〇分種,當該基材為塑料材料時,烘烤溫 度係為攝氏40度至80度,烘烤時間係為3〜1〇分鐘。 其中’該第一圖文結構與該第二圖文結構之轉 寫率約為1:0.99。 其中,该母板係以不銹鋼及電鎢板或石英玻璃 所製成,該母板之該圖文結構係以化學蝕刻、鑽刻 或雷射蝕刻等方式所製成,該子膜係以選自聚碳酸 脂(polycarbonate,PC),聚甲基丙烯酸甲脂(pMMA) 或聚對苯二甲酸乙二醇脂(PET)等塑膠材料所製成。 其中,該母板上更鍵上一鑛膜,該鍍膜係為鈦 金屬、鈦合金、不銹鋼、銅金屬或鋼合金。 其中,該第一光固化膠及該第二光固化膠為含 氟化物、矽或矽膠。 上 鍍 之 ^其中,當於轉寫該第二圖文結構於該基材 後,更包括真空濺鍍該第二圖文結構以形成_ 膜,及轉寫一第三圖文結構於該第二圖文結 步驟。 其中,當真空濺鍍該第二圖文結構後,更包含 二次濺鍍該第二圖文結構之步,驟,以上色該第二圖 文結構。 5 201236887 其中,該紫外光固化立體圖文轉寫方法係以一 轉寫機轉寫該第二圖文結構,該轉寫機包括一承載 平台、一轉印件、一基材失具及一頂針元件,該轉 印件設置於該承載平台上方,該基材夾具具有一固 定式夾持單元及一可動式失持單元,該固定式夾持 單於設於該承載平台之間’該可動式夾持單元係設 置於該承載平台之另一側,該頂針元件設於該承載 平台及S亥可動式夾持單元之間。 其中’該轉印件具有-滾輪體及-紫外光照明 早疋’該固定式夾持單元及該可動式失持單元分別 夾持完成離形之該子膜的-端,當該滾輪體向下穿 壓該子膜至該基材時,該可 ^ 勒式夾持早兀則受該子 膜之帶動向下移動,當該頂 < & i 針卓70向上移動時,則 該可動式夾持單元受該子膜 ^ 動而向上及朝向該 承载十台之方向移動。 Λ 【實施方式】 為使貴審杳委員能、、主枯 -妥員^楚了解本發明之内容 以下列說明搭配圖式’敬請參閱。 謹 請參閱第1圖及第2Α至 土 圓所不,其分免丨 為本發明紫外線光固化立體圖文轉寫方法 驟流:圖及對應第一步驟流程圖之第—示意圖、第 二-意圖、第三示意圖、第四示意第 第六示意圖、第七示音厠 不意圖、 不意圖、第八示意圖及第九示意 6 201236887 圖。圖中’本發明紫外線光固化立體圖文轉寫方法 包含下列步驟: s 11 :提供一母板11 ’該母板11係經抗沾處理, 並具有一第一圖文結構111; S12:提供一子膜12’該子膜12係塗佈一第一 光固化膠121 ; S13:滾壓貼合該子膜12及該母板11,以滲入 該第一光固化膠121至該第一圖文結構111; S14:光固化該第一光固化膠121,於該子膜12 上形成一第二圖文結構122; S15:離形該子膜12及該母板11; S16:提供一基材13,該基材13係塗佈一第二光 固化膠1 3 1 ; S17:烘烤該基材13; S18··轉寫該第二圖文結構122於該基材13,並 同步固化該第二光固化膠131;及 S 1 9 :正照處理該基材1 3。 請參照第3圖及第4A至第4D圖’其係為本發 明紫外線光固化立體圖文轉寫方法之第二步騍流程 圖、第三步驟流程圖及對應第二步驟流程圖之第一 示意圖、第二示意圖、第三示意圖及第四示意圖。 其中,當完成離形該子膜12及該母板11之步驟後, 該子膜12更經下列步驟處理: S 2 1 :正照處理該子膜12 ’將該第二圖文結構 201236887 122經過二次光固化處理; 12係經二次至 S22:電漿處理該子膜丨2,該子膜 三次電漿處理; S23:抗沾處理該子膜12’該子膜12所 抗沾劑係為含氟化合物或矽膠;及 之 S24:烘烤處理該子膜12,該子膜12之烘烤溫 為攝氏60度至120度,烘烤時間為5至1〇分^ 請一併參照第5圖、第6A圖、第6B圖2第π 圖,其係為本發明紫外線光固化立體圖文轉寫方法 之第二步驟流程圖。此外,當於進行轉寫該第二圖 文結構122於該基材後,更包含下列步驟: S31 :真空濺鍍(sputtering)該第二圖文結構122 以形成一鍍膜1221 ; S32 :二次濺鍍該第二圖文結構122,以上色該 第二圖文結構;及 S33:轉寫一第三圖文結構123於該第二圖文結 構上。 為能清楚理解上述步驟之製程參數及使用材 質,將於下述一並說明: 1:為穩定固化該第一光固化膠121及該第二光 固化膠131,該第一光固化膠121及該第二光固化 膠1 3 1係經一紫外線光照射而光固化,該紫外線光 之照射能量係為500毫焦耳/乎方厘米 (mj/cm2)〜3〇〇〇毫焦耳/平方厘米(mj/cm2) 8 201236887 :於烘烤該基材13之步驟中,當該基材13為金 屬材料時’烘烤溫度係為攝氏5〇度至120度,烘烤 時間則為3〜1 〇分鐘。而當該基材丨3為塑料材料時, 烘烤溫度係為攝氏40度至80度,烘烤時間係為3〜1 〇 分鐘β 3:上述該第一圖文結構U1與該第二圖文結構 122之轉寫率約為1:0.99,但不以此為限,可依實際 加工需求而提昇或降低比例精度。 4:就所使用之材料而言,該母板u係以不錄 鋼、電鑄板或石英玻璃所製成,該母板11之該第一 圖文結構111係以化學钮刻、鐵刻或雷射触刻等方 式所製成。而該子膜12則可以選自聚碳酸脂 (Polycarbonate,PC),聚對苯二甲酸乙二醇脂(PET) 等塑膠材質所製成。而該母板u若為非金屬材料, 則可於該母板11上再鍍上一層鍍膜(圖未示),該鍍 膜可為鈦金屬、鈦合金、不銹鋼、銅金屬或銅合金。 此外,該第一光固化膠121及該第二光固化膠131 可為含敗化物、石夕或>5夕膠。 5:當於真空濺鍍該第二圖文結構122時,可以鈦 金屬(Ti)、鉻金屬(Cr)、不鏽鋼(SUS系列)、鋁金屬 (A1)、錯金屬(Zr)、石夕或銅金屬(Cu)等材,使該第 二圖文結構122形成一鍍膜1221而具有金屬感、高 反射效果及更具立體質感(如具有鏡面不銹鋼板之 效果)。此外,於其他實施例中,亦可視產品或製程 201236887 條件,不需進行二次濺鍍來上色該第二圖文結構 122。 ° 6··於上色該第二圖文結構時122,係藉由導入一 氣體於真空腔室内,使其與濺鍍於第二 之金屬鑛…產生氧化反應形成氧化鑛膜構而變 色,所使用之氣體可為氮化物、碳化物、氰化物、 氧化物、氮氧化物,藉由不同的金屬薄臈與不同的 氣體產生氧化反應,使該第二圖文結構122形成對 應的顏色變化。此種上色方式稱為氧化鍍膜發色, 相較於傳統印刷方式,具有速度快、良率高及環保 之優點。 6.於轉寫該第三圖文結構123於該第二圖文結 構122上時,其目的在於防止該第二圖文結構122 上的鑛膜過度氧化而退色變色,或用以改變圖案, 增加或降低其反射率。 7:於上述轉寫該第二圖文結構122於該基材u 之步驟中,係搭配一轉寫機2來進行。而該轉寫機 2之構造可一併參照第7圖及第8圖所示,其分別 係為本發明紫外線光固化立體圖文轉寫機方法所使 用之轉寫機第一立體示意圖及第二立體示意圖。圖 中,該轉寫機2包括一承載平台21、一轉印件22、 一基材夾具23及一頂針元件24。該承載平台21係 承載該基材13。該轉印件22設置於該承載平台21 上方,並具有—滾輪體221、一紫外光照明單元222 10 201236887 及一昇降裝置223,該基材夾具23則具有一固定式 失持單元231及一可動式夾持單元232 ^該固定式 失持單元23 1及該可動式失持單元232分別爽持完 成離形之該子膜12之一端。 其中,該轉寫機2轉印該第二圖文結構122於 該基材1 3上之詳細製程,請一併參照下述文字及圖 式,以清楚了解。然而,值得注意的是,該轉寫機 2及其壓印步驟’僅為一種較佳之實施方式,而不 僅以此轉寫機2之結構及轉印製程為限: 請參照第9A圖至第9F圖,其係為本發明紫外 線光固化立體圖文轉寫方法所使用轉寫機之第一作 動示意圖、第二作動示意圖、第三作動示意圖、第 四作動不意圖、第五作動示意圖及第六作動示意 圖。於操作該轉寫機2時,該承載平台2 1則先復位 至一起始位置。接著,將塗佈該第二光固化膠i3i 之基材13置於該承載平台21上’接著,驅動該承 载平台21移動,而使位於該轉印件22之移動路徑 下方。接著,該昇降裝f 223驅動該紫外光照明單 元222發光,且該昇降裝置2”同步向下移動,使 該滾輪體22丨向下滾屢該子膜12至該基材13上, 以將該第二圖文結肖122轉印至該基材13上,將藉 由紫外光照射該第二光固化膠⑴,以結合該基材 13與該子膜12。 當於壓印過程中 該子膜12受該滾輪體221之 201236887 滾壓而向下方移動,使該可動式夾單元232受到該 子膜1 2之向下作用力而朝下方移動。藉此,可使該 基材13與壓印過程中受到穩定的張力作用,以緊密 貼附於該基材13,而不會因壓印力道不均或產生氣 泡之情況發生。 當該滾輪體221完成壓印動作並位移至該承載 平台21外側時,此時該頂針元件24受到驅動,而 往上移動,近而頂抵該子膜12向上移動,以與該基 材13分離。此時,該可動式夾持單元232亦受該子 膜12之帶動力量而向上及朝該承載平台21之方向 移動使該子膜12穩定分離於該基材丨3。當該子 膜12完全分離於該基材13後,則該承載平台21受 驅動而往終端位置移動,以便將該基材13取出。 綜上所述’本發明紫線外光固化立體圖文轉寫 方法,其功效在於可於任意金屬或非金屬之基材 上,形成一立體圖文之圖案,而可較習知技術僅能 作平面裝飾的方法’更具美觀美感。 唯,以上所述者,僅為本發明之較佳實施例而 已,並非用以限定本發明實施之範圍,在不脫離本 發:之精神與範圍下所作之均等變化與㈣,皆應 涵蓋於本發明之專利範圍内。 >T、上所述,本發明之紫外線光固化立體圖文轉 寫方法’係具有專利之發明性’及對產業的利用價 值’申晴人妥依專利法之規定,自鈞局提起發明 12 201236887 專利之申請。 13 201236887 【圖式簡單說明】 $ 1圓’為本發明紫外線光固化立體圖文轉寫方法 之第一步驟流程圖。 第2A圓’為本發明紫外線光固化立體圖文轉寫方法 對應第—击 步驟流程圖之第一示意圖。 2B圖’為本發明紫外線光固化立體圖文轉寫方法 對應第一步 & 步驟〜程圖之第二示意圖。 第 2 c fsi 、 如 圖’為本發明紫外線光固化立體圖文轉寫方法 對應第一步 歹鄉/爪程圖之第三示意圖〇 2D 11 ’為本發明紫外線光固化立體圖文轉寫方法 •"第步驟流程圖之第四示意圖。 第 2E _ 圓’為本發明紫外線光固化立體圖文轉寫方法 對應第_ at. 步驟流程圖之第五示意圖。 第 2 ρ 、 如 圖’為本發明紫外線光固化立體圖文轉寫方法 對應第一半ΒΙ& _ 步驟流程圖之第六示意圖。 第 2 Ρ 圓’為本發明紫外線光固化立體圖文轉寫方法 •應第一步驟流程圓之第七示意圖。 第2Η圖’為本發明紫外線光固化立體圖文轉寫方法 .應第一步驟流程圖之第八示意圖。 第 2Τ 圖’為本發明紫外線光固化立體圖文轉寫方法 對應第一舟萌》 ,驟流程圖之第九示意圖。 第3圖,為本發明紫外線光固化立體圖文轉寫方法 之第二步驟流程圖。 4Α圖’為本發明紫外線光固化立體圖文轉寫方法 201236887 對應第二步驟流程圖之第一示意圖。 第4B圖,為本發明紫外線光固化立體圖文轉寫方法 對應第二步驟流程圖之第二示意圖。 第4C圖,為本發明紫外線光固化立體圖文轉寫方法 對應第二步驟流程圖之第三示意圖。 第4D圖,為本發明紫外線光固化立體圖文轉寫方法 對應第二步驟流程圖之第四示意圖。 第5圖,為本發明紫外線光固化立體圖文轉寫方法 之第三步驟流程圖。 第6A圖,為本發明紫外線光固化立體圖文轉寫方法 對應第三步驟流程圖之第一示意圖。 第6B圖,為本發明紫外線光固化立體圖文轉寫方法 對應第三步驟流程圖之第二示意圖。 第6C圖,為本發明紫外線光固化立體圖文轉寫方法 對應第三步驟流程圖之第三示意圖。 第7圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第一立體示意圖。 第8圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第二立體示意圖。 第9A圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第一作動示意圖。 第9B圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第二作動示意圖。 第9C圖,為本發明紫外線光固化立體圖文轉寫方法 15 201236887 所使用轉寫機之第三作動示意圖。 第9D圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第四作動示意圖。 第9E圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第五作動示意圖。 第9F圖,為本發明紫外線光固化立體圖文轉寫方法 所使用轉寫機之第六作動示意圖。 【主要元件符號說明】 11 母板 111 第一圖文結構 12 子膜 121 第一光固化膠 122 第二圖文結構 1221鍍膜 123 第三圖文結構 13 基材 131 第二光固化膠 2 轉寫機 21 承載平台 22 轉印件 221 滾輪體 222 紫外光照明單元 223 昇降裝置 16 201236887 23 基材夾具 231 固定式夾持單元 232 可動式夾持單元 24 頂針元件 S11-S19 步驟流程 S21〜S24 步驟流程 S31〜S33 步驟流程 17201236887 VI. Description of the invention: [Technical field to which the invention pertains] A method of transliteration' particularly refers to a method of transliteration of an ultraviolet light-curing stereo image. [Prior Art] With the progress of technology, a large number of 3C products, such as smart phones, pens and computers, have become indispensable products for modern people. Notebook computers and various 3C products, in pursuit of visual aesthetics, will mostly be decorated on the outer casing. In the traditional way, if the outer casing is made of plastic, most of them are painted and colored. deal with. However, this type of process will produce more or less toxic waste gas in the process, causing pollution. In addition, there is an additional procedure for secondary processing after spraying, which is cumbersome. In addition, metal surface finishing techniques have been used to surface the outer casing, such as chemical coloring, electrolytic coloring, part plating or metal surface etching, such as on metal casings: hairline. However, this type of treatment is costly and has the disadvantage of being difficult to recycle. Moreover, the traditional decoration treatment method can only be used in the case of the outer casing: the decorative treatment of the flat surface, and the decorative effect of the three-dimensional shape cannot be achieved. 201236887 SUMMARY OF THE INVENTION The main object of the present invention is to provide an ultraviolet light-curing stereoscopic image transfer method which can photo-cure a stereoscopic image structure onto a substrate to enhance the three-dimensional appearance of the pattern and the graphic. In order to achieve the above object, the ultraviolet light curing stereoscopic graphic transfer method of the present invention comprises the following steps: First, providing a mother board which is subjected to anti-stick treatment and has a first graphic structure; a sub-film, the sub-film is coated with a first photo-curing adhesive; then, the sub-film and the mother board are rolled to penetrate the first photo-curable adhesive to the first graphic structure; then, the light Curing the first photocurable adhesive to form a second graphic structure on the sub-film; then, dissecting the sub-film and the mother substrate; and then providing a substrate coated with a second light Curing the substrate; then, baking the substrate; then 'transferring the second graphic structure to the substrate, forming a first graphic structure on the substrate' and simultaneously photocuring the second photocurable adhesive The second graphic structure is in the form of a crucible; finally, the substrate is processed in the same manner. After the step of dislodging the sub-film and the mother board, the sub-film is further processed by the following steps: treating the substrate in a normal manner, the second graphic structure is subjected to secondary photo-curing; and the sub-film is treated by plasma treatment. , the sub-membrane system, ''in a one-to-human secondary plasma treatment; anti-stain treatment of the sub-film, the anti-staining agent used in the sub-film is a fluorine-containing compound or tannin; baking the sub-film' The chess film is baked at a temperature of 60 degrees to 12 degrees and a baking time of 5 to 1 minute. Wherein, the first photocurable adhesive and the second photocurable adhesive are photocured by ultraviolet light irradiation according to 4 201236887, and the irradiation energy of the ultraviolet light is 500 mj/cm 2 to 3 μm/cm 2 . Wherein, in the step of bake the substrate, when the substrate is a metal material, the baking temperature is 5 to 120 degrees Celsius, and the baking time is 3 to 1 minute, when the substrate is In the case of plastic materials, the baking temperature is 40 to 80 degrees Celsius, and the baking time is 3 to 1 minute. The transfer rate of the first picture structure and the second picture structure is about 1:0.99. Wherein, the mother board is made of stainless steel and electric tungsten plate or quartz glass, and the graphic structure of the mother board is formed by chemical etching, drilling or laser etching, and the sub-film is selected. It is made of plastic materials such as polycarbonate (PC), polymethyl methacrylate (pMMA) or polyethylene terephthalate (PET). Wherein, the mother plate is further bonded with a mineral film, which is made of titanium metal, titanium alloy, stainless steel, copper metal or steel alloy. Wherein, the first photocurable adhesive and the second photocurable adhesive are fluoride, bismuth or silicone. After plating the second graphic structure on the substrate, the method further comprises vacuum sputtering the second graphic structure to form a film, and transferring a third graphic structure to the first The second graphic step. Wherein, after vacuum sputtering the second graphic structure, the step of second sputtering the second graphic structure is further included, and the second graphic structure is colored. 5 201236887 wherein the ultraviolet curing stereoscopic text transfer method is to transfer the second graphic structure by a transfer machine, the transfer machine includes a carrying platform, a transfer member, a substrate missing tool and a thimble An element is disposed above the carrying platform, the substrate holder has a fixed clamping unit and a movable holding unit, and the fixed clamping unit is disposed between the carrying platform. The clamping unit is disposed on the other side of the carrying platform, and the ejector component is disposed between the carrying platform and the S-type movable clamping unit. Wherein the 'transfer member has a roller body and an ultraviolet light early warning', the fixed clamping unit and the movable disengagement unit respectively clamp the end of the sub-film that is out of shape, when the roller body is oriented When the sub-film is pressed down to the substrate, the pre-clamping early movement is moved downward by the sub-film, and when the top <& i needle 70 moves upward, the movable The clamping unit is moved by the sub-film to move upward and toward the ten-carrying direction. Λ [Embodiment] In order to enable the members of the committee to understand, the main squad, the singer, and the singer, understand the contents of the present invention. Please refer to Figure 1 and Figure 2 to the soil circle. The sub-flow is the flashing method for the UV-cured stereo image transfer method of the present invention: the figure and the flow chart corresponding to the first step - the schematic diagram, the second-intention The third schematic diagram, the fourth schematic sixth schematic diagram, the seventh soundproof toilet not intended, the non-intentional, the eighth schematic diagram and the ninth schematic diagram 6 201236887. In the figure, the ultraviolet light curing stereoscopic text transfer method of the present invention comprises the following steps: s 11 : providing a mother board 11 'the mother board 11 is subjected to anti-stick treatment, and has a first graphic structure 111; S12: providing a The sub-film 12' is coated with a first photo-curable adhesive 121; S13: rolling the sub-film 12 and the mother board 11 to infiltrate the first photo-curable adhesive 121 to the first graphic Structure 111; S14: photocuring the first photocurable adhesive 121, forming a second graphic structure 122 on the sub-film 12; S15: separating the sub-film 12 and the mother board 11; S16: providing a substrate 13. The substrate 13 is coated with a second photocurable adhesive 1 3 1 ; S17: baking the substrate 13; S18·· transferring the second graphic structure 122 to the substrate 13 and simultaneously curing the substrate 13 The second photocurable adhesive 131; and S19: the substrate 13 is treated in the same manner. Please refer to FIG. 3 and FIG. 4A to FIG. 4D for the second step of the ultraviolet light curing stereoscopic image transfer method, the third step flow chart and the first schematic diagram of the corresponding second step flow chart. Second schematic diagram, third schematic diagram and fourth schematic diagram. Wherein, after the step of disengaging the sub-film 12 and the mother board 11 is completed, the sub-film 12 is further processed by the following steps: S 2 1 : processing the sub-film 12' in the normal condition to pass the second graphic structure 201236887 122 Secondary photocuring treatment; 12 series is passed to S22: plasma treatment of the sub-film 丨2, the sub-film is treated by three plasma treatments; S23: anti-stick treatment of the sub-film 12' of the anti-adhesive system of the sub-film 12 a fluorine-containing compound or silicone; and S24: baking the sub-film 12, the baking temperature of the sub-film 12 is 60 degrees Celsius to 120 degrees Celsius, baking time is 5 to 1 minute points ^ Please refer to the same 5, 6A, 6B, 2, and π, which are flowcharts of the second step of the ultraviolet light curing stereo graphic transfer method of the present invention. In addition, after performing the transfer of the second graphic structure 122 on the substrate, the method further includes the following steps: S31: vacuum sputtering the second graphic structure 122 to form a plating film 1221; S32: secondary The second graphic structure 122 is sputtered, and the second graphic structure is colored; and S33: a third graphic structure 123 is transferred to the second graphic structure. In order to clearly understand the process parameters and materials used in the above steps, the following will be described together: 1: to stably cure the first photocurable adhesive 121 and the second photocurable adhesive 131, the first photocurable adhesive 121 and The second photocurable adhesive 133 is photocured by irradiation with ultraviolet light, and the irradiation energy of the ultraviolet light is 500 mJ/cm2 (mj/cm2) to 3 〇〇〇mJ/cm2 ( Mj/cm2) 8 201236887: In the step of baking the substrate 13, when the substrate 13 is a metal material, the baking temperature is 5 to 120 degrees Celsius, and the baking time is 3 to 1 〇 minute. When the substrate 丨3 is a plastic material, the baking temperature is 40 degrees Celsius to 80 degrees Celsius, and the baking time is 3 〜1 〇 minutes β 3 : the first graphic structure U1 and the second figure described above The transfer rate of the text structure 122 is about 1:0.99, but it is not limited thereto, and the proportional precision can be increased or decreased according to actual processing requirements. 4: In terms of materials used, the mother board u is made of unrecorded steel, electroformed plate or quartz glass, and the first graphic structure 111 of the mother board 11 is chemically engraved and iron-engraved. Or made by laser or other means. The sub-film 12 can be made of a plastic material such as polycarbonate (PC) or polyethylene terephthalate (PET). If the mother board u is a non-metal material, the mother board 11 may be further coated with a plating film (not shown), which may be titanium metal, titanium alloy, stainless steel, copper metal or copper alloy. In addition, the first photocurable adhesive 121 and the second photocurable adhesive 131 may be a ruthenium-containing compound, a stone or a granule. 5: When vacuum sputtering the second graphic structure 122, titanium (Ti), chromium metal (Cr), stainless steel (SUS series), aluminum metal (A1), wrong metal (Zr), Shi Xi or Copper metal (Cu) and the like, the second graphic structure 122 forms a coating 1221 and has a metallic feeling, a high reflection effect and a more three-dimensional texture (such as the effect of having a mirror stainless steel plate). In addition, in other embodiments, the second graphic structure 122 may be colored without secondary sputtering, depending on the product or process 201236887. °6·· When coloring the second graphic structure 122, discoloration is achieved by introducing a gas into the vacuum chamber to cause oxidation reaction with the second metal ore to form an oxidized ore film structure. The gas used may be a nitride, a carbide, a cyanide, an oxide or an oxynitride. The oxidation reaction of different metal thin enamels with different gases causes the second graphic structure 122 to form a corresponding color change. . This type of coloring is called oxidative coating color development. Compared with the traditional printing method, it has the advantages of high speed, high yield and environmental protection. 6. When the third graphic structure 123 is transferred to the second graphic structure 122, the purpose is to prevent the mineral film on the second graphic structure 122 from being excessively oxidized and discolored, or to change the pattern. Increase or decrease its reflectivity. 7: The step of transferring the second graphic structure 122 to the substrate u is performed in conjunction with a transfer machine 2. The structure of the transfer machine 2 can be referred to as shown in FIG. 7 and FIG. 8 respectively, which are respectively a first stereoscopic diagram and a second diagram of the transfer machine used in the ultraviolet light curing stereoscopic image transfer machine method of the present invention. Stereoscopic view. In the figure, the transfer machine 2 includes a carrying platform 21, a transfer member 22, a substrate holder 23 and a ejector member 24. The carrier platform 21 carries the substrate 13. The transfer member 22 is disposed above the carrying platform 21 and has a roller body 221, an ultraviolet light illumination unit 222 10 201236887 and a lifting device 223. The substrate holder 23 has a fixed drop unit 231 and a The movable clamping unit 232 ^ the fixed holding unit 23 1 and the movable holding unit 232 respectively hold one end of the sub-film 12 which is out of shape. The detailed process of transferring the second graphic structure 122 on the substrate 13 by the transfer machine 2 is referred to the following text and drawings for clarity. However, it is worth noting that the transfer machine 2 and its embossing step 'is only a preferred embodiment, and not only the structure of the transfer machine 2 but also the transfer process: Please refer to FIG. 9A to 9F diagram, which is a first actuation diagram, a second actuation diagram, a third actuation diagram, a fourth actuation intention, a fifth actuation diagram, and a sixth operation of the transfer machine used in the ultraviolet light curing stereoscopic graphic transfer method of the present invention. Actuation diagram. When the transfer machine 2 is operated, the carrying platform 2 1 is first reset to a starting position. Next, the substrate 13 coated with the second photocurable adhesive i3i is placed on the carrying platform 21. Next, the loading platform 21 is driven to move, so as to be positioned below the moving path of the transfer member 22. Then, the lifting device f 223 drives the ultraviolet light illumination unit 222 to emit light, and the lifting device 2" synchronously moves downward, so that the roller body 22丨 rolls down the sub-film 12 onto the substrate 13 to The second graphic image 122 is transferred onto the substrate 13, and the second light-curing adhesive (1) is irradiated by ultraviolet light to bond the substrate 13 and the sub-film 12. When the imprinting process The sub-film 12 is rolled downward by the 201236887 of the roller body 221, and the movable clamp unit 232 is moved downward by the downward force of the sub-film 12, whereby the substrate 13 can be made During the embossing process, it is subjected to a stable tension to be closely attached to the substrate 13 without occurrence of uneven printing force or bubble generation. When the roller body 221 completes the embossing action and is displaced to the carrier When the outer side of the platform 21 is at this time, the ejector pin 24 is driven to move upward, and the top sub-film 12 is moved upward to be separated from the base material 13. At this time, the movable clamping unit 232 is also subjected to The sub-film 12 is moved upwards and in the direction of the carrying platform 21 to bring the sub-film 12 The film 12 is stably separated from the substrate 丨 3. When the sub-film 12 is completely separated from the substrate 13, the carrier platform 21 is driven to move to the end position to take the substrate 13 out. The invention discloses a purple-line external light-curing stereoscopic graphic transfer method, and the effect thereof is that a pattern of a three-dimensional graphic can be formed on a substrate of any metal or non-metal, and the method can only be used for planar decoration compared with the prior art. The above is only the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and the equivalent changes and (4) are made without departing from the spirit and scope of the present invention. All of them should be covered by the patent of the present invention. >T, the above-mentioned ultraviolet light-curing stereoscopic image transfer method of the present invention has the patented invention 'and the use value of the industry' According to the provisions of the Patent Law, the application for invention 12 201236887 is filed from the Bureau of Health. 13 201236887 [Simple description of the diagram] $1 circle' is the first step flow chart of the method for translating the ultraviolet light stereoscopic image. 2A circle 'is the first schematic diagram of the first step of the ultraviolet light curing stereoscopic graphic transfer method corresponding to the first step. 2B picture 'is the first step of the ultraviolet light solidified stereo graphic transfer method of the present invention & The second schematic diagram of the figure. The second c fsi, as shown in the figure, is the third schematic diagram of the first step of the ultraviolet light curing stereoscopic image transfer method 〇 2D 11 'is the ultraviolet light curing stereoscopic view of the present invention The text transfer method • " The fourth schematic diagram of the first step flow chart. The 2E _ circle 'is the fifth schematic diagram of the flow chart of the ultraviolet light solidified stereo graphic transfer method corresponding to the first step. The second ρ, as shown in FIG. 2 is a sixth schematic diagram of the flow chart of the first half ΒΙ & _ step of the ultraviolet light curing stereoscopic image transfer method of the present invention. The second Ρ circle ' is the ultraviolet light curing stereoscopic graphic transfer method of the present invention. Fig. 2 is a schematic diagram of the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 2 is a ninth schematic diagram of the flow chart of the ultraviolet light curing stereoscopic image transfer method corresponding to the first boat. Fig. 3 is a flow chart showing the second step of the ultraviolet light curing stereoscopic image transfer method of the present invention. 4Α图' is the ultraviolet light curing stereoscopic graphic transfer method of the present invention 201236887 corresponds to the first schematic diagram of the second step flow chart. FIG. 4B is a second schematic diagram of a flow chart corresponding to the second step of the ultraviolet light curing stereoscopic image transfer method of the present invention. FIG. 4C is a third schematic diagram of a flow chart corresponding to the second step of the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 4D is a fourth schematic diagram of the flow chart of the ultraviolet light curing stereoscopic image transfer method corresponding to the second step. Fig. 5 is a flow chart showing the third step of the ultraviolet light curing stereoscopic image transfer method of the present invention. FIG. 6A is a first schematic diagram of a flow chart corresponding to the third step of the ultraviolet light curing stereoscopic image transfer method of the present invention. FIG. 6B is a second schematic diagram of a flow chart corresponding to the third step of the ultraviolet light curing stereoscopic image transfer method of the present invention. Figure 6C is a third schematic diagram of the flow chart of the ultraviolet light-cured stereoscopic image transfer method corresponding to the third step. Fig. 7 is a first perspective view showing the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 8 is a second perspective view showing the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 9A is a schematic view showing the first operation of the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 9B is a schematic view showing the second operation of the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Figure 9C is a schematic diagram of the third operation of the translucent machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 9D is a schematic view showing the fourth operation of the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 9E is a schematic view showing the fifth operation of the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. Fig. 9F is a schematic view showing the sixth operation of the transfer machine used in the ultraviolet light curing stereoscopic image transfer method of the present invention. [Main component symbol description] 11 Motherboard 111 First graphic structure 12 Sub-film 121 First photo-curing adhesive 122 Second graphic structure 1221 coating 123 Third graphic structure 13 Substrate 131 Second light-curing adhesive 2 Transfer Machine 21 Loading platform 22 Transfer member 221 Roller body 222 Ultraviolet light illumination unit 223 Lifting device 16 201236887 23 Substrate clamp 231 Fixed clamping unit 232 Movable clamping unit 24 Thimble component S11-S19 Step flow S21~S24 Step flow S31~S33 Step Flow 17

Claims (1)

201236887 七、申請專利範圍: 1. 一種紫外線光固化立體圖文轉寫方法,包含下列步 驟: 提供一母板,該母板係經抗沾處理並具有一第一 圖文結構; 提供一子膜,該子膜係塗佈一第一光固化膠; 滾壓貼合該子膜及該母板,以滲入該第一光固化 膠至該第一圖文結構; 光固化該第一光固化膠,於該子膜上形成一第二 圖文結構; 離形該子膜及該母板; 提供一基材,該基材係塗佈一第二光固化膠; 烘烤該基材; 轉寫該第二圖文結構於該基材,並同步光固化該 第一光固化膠;及 正照處理該基材。 2. 如申請專利範圍第1項所述之紫外線光固化立體圖 文轉寫方法,其中於離形該子膜及該母板之步驟後, 該子膜更經下列步驟處理: 正照處理該子膜’該第二圖文結構係經二次光固 化; 理; 電漿處理該子膜,該子膜係經二次至三次電漿處 抗沾處理該子膜,該子膜所使用之抗沾劑係為含 18 201236887 氟化合物或梦膠,·及 度至=處理該子膜’該子膜之供烤溫度為攝氏60 度至120度’烘烤時間為5至1〇分鐘。 3.: I吻專利範圍帛1項所述之紫外光固化立體圖文 二方法,其中’該第一光固化膠及該第二光固化膠 係經-紫外線光照射而光固化,該紫外線光之照射能 量係為500毫焦耳/平方厘米〜3000毫焦耳/平方厘 米,且該第一光固化膠及該第二光固化膠為含氟化 物、矽或矽膠。。 4·如申請專利範圍帛1項所述之紫外光固化立體圖文 轉寫方法,其中烘烤該基材步驟十,當該基材為金屬 材料時,烘烤溫度係為攝氏50度至120度,烘烤時 間係為3〜1〇分鐘,當該基材為塑料材料時,烘烤溫 度係為攝氏40度至80度,烘烤時間係為3〜1〇分鐘。 5. 如申請專利範圍第1項所述之紫外光固化立體圖文 轉寫方法,其中,該第一圖文結構與該第二圖文結構 之轉寫率約為1:0.99。 6. 如申請專利範圍第丨項所述之紫外光固化立體圖文 轉寫方法,其中,該母板係以不銹鋼、電鑄板或石英 玻璃所製成,該母板之該第一圖文結構係以化學蝕 刻、鑽刻或雷射蝕刻等方式所製成,該子膜係以選自 聚碳酸脂(Polycarbonate,PC),聚甲基丙烯酸甲脂 (PMMA)或聚對苯二甲酸乙二醇脂(pet)等塑膠材質 所製成。 19 201236887 魏宜:專利範圍第1項所述之紫外光固化立體圖文 ·’’去其中,該母板上更鍍上一鍍膜,該鍍膜係 I由杜,欽合金、不銹鋼、鋼金屬或銅合金。 燄宜月專利缸圍帛1項所述之紫外光固化立體圖文 轉寫方法,豈Φ,a认姑& # 八 *於轉寫該第二圖文結構於該基材 後,更包括下列步驟: 9. 真空濺鍍該第二圖文結構以形成一鍍膜;及 轉寫一第二圖文結構於該第二圖文結構上。 如申請專利範Μ 8項所述之紫外光固化立體圖文 轉寫方法,其中,冑於真空賤鍍該第三圖文結構後, 更包含二次濺鍍該第二圖文結構之步驟,以上色該第 二圖文結構之鍍膜,上色該第二圖文結構之方式係藉 由導入敗化物、碳化物、氛化物、氣氧化物等氣體噢 該第二圖文結構之鍍膜反應形成,該真空濺鍍所使用 之纪材係為鈦、鉻、不銹鋼、在呂、錯、石夕或銅。 1〇.如巾請專利範Μ 1項所述之紫外光ϋ化立體圓文 轉寫方法’其中’係以一轉寫機轉寫 構,該轉寫機包括-承載平台、一轉印件、一基材爽 具及一頂針元件,該轉印件設置於該承載平台上方, 該基材夾具具有—固定式夾持單元及-可動式夾持 單元,該固定式夾持單元設於該承載平台之一側該 可動式夾持單元係設置於該承載平台之另一側,該頂 針元件設於該承載平台及該可動式夾持單元之間7該 轉印件具有一滾輪體及一紫外光照明單元,該固定式 20 子膜之帶動而向上及Ί別該可動式处付早; 朝向該承載平台之方向移 201236887 夾持單元及該可動式夾持單元分別夾持完成離形 該子犋之一端,當該滚輪體向下滚壓該子膜至該基 二式爽持單元則受該子膜之帶動向下移® 田該頂針早元向上 7 — 動時’則該可動式夾持單元受 動 之 材 , 該 21201236887 VII. Patent application scope: 1. An ultraviolet light curing stereoscopic graphic transfer method, comprising the following steps: providing a mother board which is subjected to anti-stick treatment and has a first graphic structure; providing a sub-film, The sub-film is coated with a first photo-curing adhesive; the sub-film and the mother board are rolled and adhered to infiltrate the first photo-curable adhesive to the first graphic structure; and the first photo-curing adhesive is cured by light. Forming a second graphic structure on the sub-film; separating the sub-film and the mother substrate; providing a substrate, the substrate is coated with a second photo-curable adhesive; baking the substrate; The second graphic is structured on the substrate, and the photocurable adhesive is simultaneously photocured; and the substrate is processed in the same manner. 2. The method according to claim 1, wherein the sub-film is further processed by the following steps: after the step of separating the sub-film and the mother board: The second graphic structure is subjected to secondary photocuring; the plasma film is treated by plasma, and the sub-film is treated with anti-stick treatment twice to three times, and the sub-film is used for anti-sticking. The dosage system contains 18 201236887 fluorine compound or dream gel, and the degree to the treatment of the sub-film 'the baking temperature of the sub-film is 60 degrees Celsius to 120 degrees Celsius' baking time is 5 to 1 minute. 3. The invention relates to the ultraviolet curing stereoscopic image method of claim 1, wherein the first light curing adhesive and the second light curing adhesive are photocured by ultraviolet light irradiation, and the ultraviolet light is cured. The irradiation energy is 500 mJ/cm to 3,000 mJ/cm, and the first photocurable adhesive and the second photocurable adhesive are fluoride, bismuth or silicone. . 4. The method of translating the ultraviolet-cured stereo image according to claim 1, wherein the substrate is baked in a step 10, and when the substrate is a metal material, the baking temperature is 50 degrees Celsius to 120 degrees Celsius. The baking time is 3 to 1 minute. When the substrate is a plastic material, the baking temperature is 40 to 80 degrees Celsius, and the baking time is 3 to 1 minute. 5. The method as claimed in claim 1, wherein the first graphic structure and the second graphic structure have a transfer rate of about 1:0.99. 6. The method according to claim 2, wherein the mother board is made of stainless steel, electroformed plate or quartz glass, and the first graphic structure of the mother board It is made by chemical etching, drilling or laser etching. The sub-membrane is selected from the group consisting of polycarbonate (PC), polymethyl methacrylate (PMMA) or polyethylene terephthalate. Made of plastic materials such as alcohol. 19 201236887 Wei Yi: The UV-cured stereo image described in the first paragraph of the patent range · ''Where, the mother board is coated with a coating, which is made of Du, Chin alloy, stainless steel, steel metal or copper. alloy. The method of transliteration of the ultraviolet-cured stereoscopic image described in the patent of the Yiyiyue patent cylinder cofferdam, 岂Φ, a 姑姑&#八*, after transcoding the second graphic structure on the substrate, further includes the following Step: 9. Vacuum sputtering the second graphic structure to form a plating film; and transferring a second graphic structure to the second graphic structure. The method for translating the ultraviolet-cured stereo image according to the application of the patent specification, wherein the step of vacuum plating the third graphic structure further comprises the step of second sputtering the second graphic structure, Coloring the coating of the second graphic structure, and forming the second graphic structure by forming a coating reaction of the second graphic structure by introducing a gas such as a ruin, a carbide, a salt, a gas oxide, or the like, The material used for the vacuum sputtering is titanium, chromium, stainless steel, in Lu, Wrong, Shi Xi or copper. 1〇.如巾请专利范Μ 1 The ultraviolet light-stained three-dimensional circular transfer method 'where' is a transfer machine, the transfer machine includes - carrying platform, a transfer a substrate cooling device and a thimble member, the transfer member is disposed above the carrying platform, the substrate holder has a fixed clamping unit and a movable clamping unit, wherein the fixed clamping unit is disposed on the One side of the carrying platform is disposed on the other side of the carrying platform, and the ejector component is disposed between the carrying platform and the movable clamping unit. The transfer member has a roller body and a The ultraviolet light illuminating unit is driven by the fixed type 20 sub-film to lift up and discriminate the movable type; the direction of the carrying platform is moved to 201236887, and the clamping unit and the movable clamping unit are respectively clamped to complete the release. One end of the sub-cylinder, when the roller body rolls down the sub-film to the base-type cooling unit, the sub-film is moved downwards by the sub-film. Clamping unit is driven by the material, the 21
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US20150020959A1 (en) * 2013-07-17 2015-01-22 Suntek Precision Corp. Multi-layer 3d pattern manufacturing method and manufacturing apparatus thereof
CN112778918A (en) * 2019-11-07 2021-05-11 Oppo广东移动通信有限公司 Mother board membrane, decorative membrane, shell, preparation method and electronic equipment
TWI776600B (en) * 2021-07-21 2022-09-01 柏騰科技股份有限公司 Colorful structure with dispersion phenomenon and method of manufacturing the same

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CN104249594A (en) * 2013-06-25 2014-12-31 非翌股份有限公司 Preparation method and manufacture equipment for multilayer stereo pattern

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US3551232A (en) * 1967-12-22 1970-12-29 Gen Motors Corp Method of vacuum forming laminated articles
EP0721834B1 (en) * 1994-07-29 2001-09-05 Sekisui Kagaku Kogyo Kabushiki Kaisha Skin material having plurality of minute recesses and projections in and on its surface, method of manufacturing the same, and method of manufacturing molded products using the same skin material
TWI268843B (en) * 2006-01-18 2006-12-21 E San Prec Coating Corp Method of producing hard coating applied to in-mold decoration injection molding
US20090110947A1 (en) * 2007-10-31 2009-04-30 Compal Electronics, Inc. Apparatus and method of decorating a surface of a workpiece and decorated part

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US20150020959A1 (en) * 2013-07-17 2015-01-22 Suntek Precision Corp. Multi-layer 3d pattern manufacturing method and manufacturing apparatus thereof
CN112778918A (en) * 2019-11-07 2021-05-11 Oppo广东移动通信有限公司 Mother board membrane, decorative membrane, shell, preparation method and electronic equipment
CN112778918B (en) * 2019-11-07 2022-12-27 Oppo广东移动通信有限公司 Mother board diaphragm, decorative diaphragm, shell, preparation method and electronic equipment
TWI776600B (en) * 2021-07-21 2022-09-01 柏騰科技股份有限公司 Colorful structure with dispersion phenomenon and method of manufacturing the same

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