TW201224239A - Non-woven fabric and method for producing non-woven fabric - Google Patents

Non-woven fabric and method for producing non-woven fabric Download PDF

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Publication number
TW201224239A
TW201224239A TW100119311A TW100119311A TW201224239A TW 201224239 A TW201224239 A TW 201224239A TW 100119311 A TW100119311 A TW 100119311A TW 100119311 A TW100119311 A TW 100119311A TW 201224239 A TW201224239 A TW 201224239A
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Taiwan
Prior art keywords
woven fabric
fiber
fibers
fabric
woven
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TW100119311A
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Chinese (zh)
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TWI456096B (en
Inventor
Yoshihiko Kinugasa
Hideyuki Kobayashi
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Kao Corp
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Priority claimed from JP2011095915A external-priority patent/JP4982615B2/en
Priority claimed from JP2011095916A external-priority patent/JP4982616B2/en
Application filed by Kao Corp filed Critical Kao Corp
Publication of TW201224239A publication Critical patent/TW201224239A/en
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Publication of TWI456096B publication Critical patent/TWI456096B/en

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/04Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
    • D04H1/08Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres and hardened by felting; Felts or felted products
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00Non-woven pile fabrics
    • D04H11/08Non-woven pile fabrics formed by creation of a pile on at least one surface of a non-woven fabric without addition of pile-forming material, e.g. by needling, by differential shrinking
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C11/00Teasing, napping or otherwise roughening or raising pile of textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • D06C3/06Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics by rotary disc, roller, or like apparatus

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)

Abstract

The present invention provides a non-woven fabric (1) wherein a web comprising a long fiber (2) is fixed by a heat sealing part (3). The non-woven fabric (1) according to the invention is provided with a fiber (21) wherein the long fiber (2) is partially broken and one end (20a) thereof is exclusively fixed by the heat sealing part (3) while the free end (20b) in the other end side is thickened. In the non-woven fabric (1) according to the invention, the fiber (21) having the thickened free end (20b) shows an increase in the terminal diameter of the fiber of 15% or greater.

Description

201224239 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種包含長纖維之不織布。 【先前技術】 例如,拋棄式尿布等吸收性物品多使用紡#不織布,其 • 原、因在於斷裂強度較高H應性優異且較為經濟。但 是,纺黏不織布於製造方法上,缺乏整體之柔軟感等,難 以提昇肌膚觸感(質感)。 例如專利文獻1中記載有:以紡黏不織布作為基材,積 層短纖維,對此積層體進行針刺加工,使表面浮現弧狀纖 維環之不織布。然而,若將專利文獻】中所記載之浮㈣ 狀纖維環之不織布用於拋棄式尿布等吸收性物品,則此弧 狀纖維環會卡住皮膚,反而導致使用感降低。又,專利文 獻1中關於構成纖維之前端形狀無任何記載。 又’例如專利文獻2中記載有:將經延伸之連續長纖維 Z織布以其厚度方向之中間部為邊界進行剝離分離,而於 一面混合存在自纖維接合部剝離之纖維、或#長為環狀之 纖維等的立起狀不織布。然而,專利文獻2中所記載之立 起狀不織布亦於製造方法上,大量混合存在伸長為環狀之 •’纖維等’因而若用於拋棄式尿布等吸收性物品,則此環狀 之纖維亦會卡住皮膚,導致使用感降低。又,專利文獻2 中關於構成纖維之前端形狀亦無任何記載。 專利文獻3 t記載有將短纖維利用接著 由於植毛片材之前端未變粗大,纖維之切割 156621 .doc 201224239 面露出’故而有前端變得生硬而使肌膚觸感變差之情形。 又,由於使用接著劑將其他纖維附著於不織布上,故而有 所使用之接著劑等化學藥劑對皮膚造成不良影響,或對皮 膚產生刺激之危險。進而,亦存在使用時植毛纖維之剝 落'接著面之露出等問題。 為使不織布之構成纖維起毛之技術,例如可考慮使用 針刺或砂紙加工不織布,或藉由植毛技術對不織布植毛之 方法。 例如專利文獻4中記載有:對不織布施加由密接加工羞 ^機械力而於構成纖維上形成脆弱部後,使形成有脆据 P之不織布通過被覆有砂紙之輥,其後進而於起毛機中僅 構成纖維起毛的不織布之製造方法。又,專利文獻5中託 丨毛片材進行揉搓處理後,使用砂紙進行磨擦處 理的立毛片材之處理方法。201224239 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a nonwoven fabric comprising long fibers. [Prior Art] For example, a spun woven fabric such as a disposable diaper is often used as a non-woven fabric, and the original factor is that the breaking strength is high and the H is excellent and economical. However, the spunbonded non-woven fabric is not particularly versatile in terms of the manufacturing method, and it is difficult to enhance the touch (feel) of the skin. For example, Patent Document 1 discloses that a spunbonded nonwoven fabric is used as a base material, and short fibers are laminated, and the laminated body is subjected to needling processing to cause a non-woven fabric of an arc-shaped fiber loop to appear on the surface. However, when the non-woven fabric of the floating (four) fiber loop described in the patent document is used for an absorbent article such as a disposable diaper, the arc-shaped fiber loop catches the skin and causes a feeling of use to be lowered. Further, Patent Document 1 does not describe any shape of the front end of the constituent fibers. Further, for example, Patent Document 2 discloses that the stretched continuous long fiber Z woven fabric is peeled and separated at the intermediate portion in the thickness direction, and the fibers peeled from the fiber joint portion are mixed on one surface, or #长为为An upright non-woven fabric such as a looped fiber. However, the upright nonwoven fabric described in Patent Document 2 is also mixed with a large amount of 'fibers and the like which are elongated in a ring shape in the production method. Therefore, if it is used for an absorbent article such as a disposable diaper, the looped fiber is used. It also catches the skin, resulting in a reduced sense of use. Further, Patent Document 2 does not describe any shape of the front end of the constituent fibers. In the case of the short-fiber use, the short-fiber use is followed by the fact that the front end of the hair-planting sheet is not thickened, and the fiber is cut 156621.doc 201224239, and the front end becomes hard and the touch of the skin is deteriorated. Further, since the other fibers are adhered to the nonwoven fabric by using the adhesive, there is a risk that the chemical agent such as the adhesive to be used may adversely affect the skin or cause irritation to the skin. Further, there is also a problem that the peeling of the flocked fibers at the time of use, and the exposure of the subsequent faces. In order to swell the constituent fibers of the non-woven fabric, for example, a method of processing a non-woven fabric using a needle punch or a sandpaper, or a method of implanting a non-woven fabric by a hair-planting technique may be considered. For example, Patent Document 4 discloses that a non-woven fabric is subjected to a weak mechanical force to form a fragile portion on a constituent fiber, and a non-woven fabric in which a brittle material P is formed is passed through a roller coated with a sandpaper, and then in a pilling machine. A method of manufacturing only a non-woven fabric constituting a fiber fluffing. Further, in Patent Document 5, a method of treating a lanolin sheet which is subjected to rubbing treatment using a sandpaper after enthalpy treatment is used.

又’專利文獻6中印恭古.A _ 己載有.使網收縮,其後使用針刺處 理經收縮之網的不織布製Further, in Patent Document 6, Yin Gonggu. A _ has been carried out. The net is shrunk, and then the needle-punched non-woven fabric is used to treat the shrunken net.

Ik方法。又,專利文獻7中託 載^僅使不織布片材之構成纖維伸長至斷裂為止而製造 二:片材之f法」藉由上述專利文獻4〜7之製造方法而 2不織布等確實具有柔軟之肌膚觸感(質感)。 然而,專利文獻4中 载起毛之不織布之製造方 走及專利文獻5中所 击 載之立毛片材之處理方法由於均 使用砂紙加工不織布,故 ίλ ^ ^ 會對不織布產生較大損傷,難 以減輕所獲得之起毛 雜 又,直 ’之不織布斷裂強度之降低。 又專利文獻6中所記載之不镚太^ 不織布之製造方法由於使用針 156621.doc 201224239 刺進行處理’故而製造速度較慢難以抑制成本。又,專利 文獻7中所記載之不織布片材之製造方法由於僅利用延伸 處理進行起毛’故而延伸處理會對不織布產生較大損傷, 難以減輕所獲得之起毛不織布之不織布強度之降低。 先前技術文獻 專利文獻 專利文獻1 :日本專利特開平丨丨_丨9〇丨5號公報 專利文獻2 :日本專利特開2〇〇2·3〇2861號公報 專利文獻3 ·日本專利特開2〇〇1_198997號公報 專利文獻4:日本專利特開昭5〇_65645號公報 專利文獻5:曰本專利特開昭59_187665號公報 專利文獻6:日本專利特開昭54_1〇6676號公報 專利文獻7 : US4187343A 【發明内容】 :’本:明係提供一種儘管斷裂強度較高, 布。 π易卡住皮膚,肌膚觸感提昇之不鐵 不::則於—種利用熱炼接部固定包含長纖維之網, 部分斷裂,僅一端部利用 端。Ρ側之自由端部變粗大 不織布具備··上述長纖維之一 上述熱熔接部予以固定,且另— 之纖維。 又 本發明係提供— 種不織布之製造方法, 其係獲得構 I56621.doc 201224239 成纖維起毛之肌膚觸感良好之不織布,並且減輕所計之 起毛不織布之不織布斷裂強度之降低。又,本發明係: 一種不織布之製造方法,其獲得構成纖維起毛之不織布: 並且製造速度較快可抑制成本。 本發明係提供—種不織布之製造方法,其係於耽以下 之溫度下分別對不織布之複數處實施部分延伸加工,再對 該經部分延伸加丄之残布實施使該残布之構成纖維起 毛之起毛加工。 【實施方式】 以下,基於本發明之不織布之較佳實施形態一邊參照 圖1〜5 —邊對其進行說明。 本實施形態之不織布丨如圖丨所示,係利用熱熔接部3間 斷地时包含長纖維2之網的不織布,其具備:長纖維2之 一部分斷裂,僅一端部20a利用熱熔接部3予以固定,且另 一端部側之自由端部2〇b變粗大之纖維21。以下,如圖以斤 不,將不織布1之長度方向設為Y方向,將不織布1之寬度 方向設為X方向,對不織布〗進行説明。再者,關於不織布 1,根據構成纖維之配向方向,將沿著纖維之配向方向之 MD方向判斷為長度方向(γ方向),將與其正交之cd方向判 斷為寬度方向(X方向)。因此,於以下之説明中,長度方 向(Y方向)與MD方向係指同一方向,寬度方向(X方向)與 CD方向係指同一方向。 若對本實施形態之不織布1進行詳細說明,則不織布1原 本係形成為利用熱熔接部3間斷地將纖維彼此壓接或熔 156621.doc • 6 - 201224239 接’而固定包含長镳 一 、纖,准之網的紡黏不織布。以下,將复 稱為原本之纺黏不織布 乂下將其 裂,故而與通常之妨黏… 於長纖維之-部分斷 時亦具有柔軟感。 又敉潯之If形 此處’所謂「長纖維」,係指纖維長度為30 mm以上 者,若為纖維長度為l5〇m ‘”、 上 % ^ ^ - 上之所謂連續長纖維,則於 了獲付斷裂強度較高之不織布方面較佳。 就廉價且獲得良好之 士,不繃右^膚觸感及加工適應性之觀點而 s,不織布1之單位面積 5〜25 g/m2。 佳為5〜10〇 g/m2,更佳為 就使用時防止撕芻β Λ 止撕髮及加工適當性之觀 之斷裂強度之值較佳Α 5 ηΛ 不織布1 手乂佳為5.00 N/5〇 mm以 N/50 mm。再者,袜眘祖τ ,丄 文佳馮8〜30 而一盾士 見不織布1之斷裂強度之目的之觀點 , ^ 之斷裂強度之值較佳為7 Ν/50 mm以上,更佳為10〜5〇 Ν/sη N/50 mme根據本發明,可獲得藉 由下述起毛法製造之不織本丨,^ 了獲得藉 方法相比,自原本之_ I強度之值與其他起毛 ,^ ^ 黏不織布之斷裂強度之值之降低較 少者。不織布1及原本之 伞低較Ik method. In addition, in the patent document 7, the method of manufacturing the two sheets of the sheet of the non-woven fabric sheet to the extent that the constituent fibers of the nonwoven fabric sheet are stretched to break is "the method of the above-mentioned Patent Documents 4 to 7", and the non-woven fabric or the like is indeed soft. Skin touch (texture). However, in Patent Document 4, the manufacturing method of the non-woven fabric of the hair and the processing method of the vertical sheet which is carried out in the patent document 5 are processed by using a sandpaper, so that ίλ ^ ^ causes a large damage to the nonwoven fabric and is difficult to reduce. The obtained crepe is also reduced in the breaking strength of the non-woven fabric. Further, in the method of manufacturing the non-woven fabric described in Patent Document 6, since the processing is performed by using the needle 156621.doc 201224239, the manufacturing speed is slow and it is difficult to suppress the cost. Further, in the method for producing a non-woven fabric sheet described in Patent Document 7, since the stretching process is performed only by the stretching treatment, the stretching treatment causes a large damage to the nonwoven fabric, and it is difficult to reduce the decrease in the strength of the nonwoven fabric obtained by the raising nonwoven fabric. CITATION LIST Patent Literature Patent Literature 1: Japanese Patent Laid-Open Publication No. JP-A No. Hei. No. Hei. No. Hei. No. 2, No. 2, No. 2, No. 2, pp. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. 59-187665. Patent Document No. 5: Japanese Patent Laid-Open No. Hei. No. Hei. : US4187343A [Summary of the Invention]: 'This: The Ming system provides a cloth with a higher breaking strength. π is easy to get stuck in the skin, and the touch of the skin is not improved. No:: The mesh containing long fibers is fixed by a hot-melt joint, partially broken, and only one end is used. The free end portion of the crotch side is coarsened. The non-woven fabric is provided with one of the above-mentioned long fibers, and the other heat-sealed portion is fixed. Further, the present invention provides a method for producing a non-woven fabric which obtains a non-woven fabric having a good texture of the fiber which is raised by the fiber, and which reduces the reduction in the breaking strength of the non-woven fabric of the raised nonwoven fabric. Further, the present invention is a method for producing a non-woven fabric which obtains a non-woven fabric constituting a fiber fluffing: and the manufacturing speed is high, and the cost can be suppressed. The present invention provides a method for manufacturing a non-woven fabric, which performs partial extension processing on a plurality of non-woven fabrics at a temperature below the crucible, and then performs a partially stretched residual cloth to cause the constituent fibers of the residual fabric to fluff. Rising processing. [Embodiment] Hereinafter, preferred embodiments of the nonwoven fabric according to the present invention will be described with reference to Figs. 1 to 5 . The non-woven fabric of the present embodiment is a non-woven fabric including a net of long fibers 2 when the heat-fusible portion 3 is intermittently provided, and includes one portion of the long fibers 2 broken, and only one end portion 20a is thermally welded portion 3 The fiber 21 which is fixed and has a free end portion 2〇b on the other end side becomes coarse. Hereinafter, the non-woven fabric 1 will be described by taking the longitudinal direction of the nonwoven fabric 1 as the Y direction and the width direction of the nonwoven fabric 1 as the X direction. In the non-woven fabric 1, the MD direction along the direction of alignment of the fibers is determined as the longitudinal direction (γ direction), and the cd direction orthogonal thereto is determined as the width direction (X direction). Therefore, in the following description, the length direction (Y direction) and the MD direction refer to the same direction, and the width direction (X direction) and the CD direction refer to the same direction. When the nonwoven fabric 1 of the present embodiment is described in detail, the nonwoven fabric 1 is originally formed such that the fibers are pressure-bonded or melted by the heat-welding portion 3, and the fuses are fixed, including the long ones and the fibers. The spunbonded non-woven fabric of the quasi-net. In the following, the original spunbonded non-woven fabric will be smashed under the armpit, so that it is sticky with the usual ones... It also has a soft feeling when the long fibers are partially broken. In the case of the "form", the term "long fiber" refers to a fiber having a length of 30 mm or more, and if it is a so-called continuous long fiber having a fiber length of 15 〇 m '" and upper % ^ ^ - It is preferable to obtain a non-woven fabric having a high breaking strength. It is inexpensive and obtains good people, and does not stretch the right touch and the processing adaptability, and the unit area of the non-woven fabric 1 is 5 to 25 g/m2. It is preferably 5 to 10 〇g/m2, more preferably, it is preferably used to prevent tearing of the 刍β Λ 撕 撕 及 及 及 及 及 及 Λ Λ 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Mm is N/50 mm. In addition, the socks are ancestor τ, 丄文佳冯8~30 and the Shield sees the rupture strength of the woven fabric 1 , and the value of the breaking strength is preferably 7 Ν/50. More than mm, more preferably 10 to 5 〇Ν/s η N/50 mme According to the present invention, it is possible to obtain a non-woven fabric which is produced by the following raising method, and obtains the _I strength from the original method. The value is lower than the other fuzzing, ^ ^ The value of the breaking strength of the non-woven fabric is less. The non-woven fabric 1 and the original umbrella are lower.

黏不織布之斷裂強度較佳為於X ° 向)上滿足上述範圍。不織布1盥;5土 之斷裂強度之比(不織布!之斷裂強不声織布^原本之不織布 強度m佳為〇.5〜$更 又原本之不織布之斷裂 下方法測定。 $佳為。·7〜…斷裂強度係藉由以 [斷裂強度之測定法j 於22 C、65% RH之環培下, 竟下,自不織布1或原本之紡黏不 156621.doc 201224239 織布切取x方向(寬度方向)上為20〇 mmAY方向(長度方向) 上為50 mm之尺寸之長方形之測定片。將該切取之長方形 之測定片作為測定樣品。將該測定樣品以X方向成為拉伸 方向之方式安裝至拉伸試驗機(例如,〇rientec公司製造之 萬能拉力試驗機(Tensilon)「RTA-100」)之夾頭上。夾頭 間距設為150 mm。將測定樣品以30〇 mm/min進行拉伸, 將樣品斷裂時之最大荷重點設為X方向之斷裂強度β又, 切取Υ方向上為200 111111且又方向上為5〇 mm之尺寸之長方 形之測定片,將其作為測定樣品。將該測定樣品以其γ方 向成為拉伸方向之方式安裝至拉伸試驗機之夾頭上。藉由 與上述X方向之斷裂強度之測定方法相同之次序求出γ方 向之斷裂強度。 本實施形態之不織布1之特徵在於肌膚觸感良好。 先刖,已知有多種表示肌膚觸感之特性值,尤其熟知的 是Kato Tech股份有限公司製造之KES之特性值(參考文 獻:質感評價之標準化與分析(第2版)、作者川端季雄、發 行1980年7月10日)。尤其是表示柔軟感之特性值中亦已 知有稱為壓縮特性之三個特性值之LC(壓縮荷重·壓縮應變 曲線之直線性)、WC(壓縮工作量)、RC(壓縮回彈性)。該 等壓縮特性係由施加0.5〜50 gf/cm2之荷重(高感度測定時為 0.5〜10 gf/cm2)時之變形量而算出特性值。但是,單位面積 重量較小(5〜25 g/m2)不織布等非常薄之布未產生太大差 異’與肌膚觸感之相關性並不大。進而,人觸碰吸收性物 品時之荷重為1 g/cm2左右之極輕荷重時便會感覺到肌膚觸 156621.doc 201224239 感,為了表示本來之肌膚觸感,認為可使用小於先前之荷 重之範圍之特性值,從而由荷重係〇_3 gf/cm2至! gf/cm2之 間之荷重與此時之變形量發現了新的特性值。該特性值係 如實地表示紡黏不織布與熱風不織布之肌膚觸感之差異的 數值,可以表示紡黏不織布之肌膚觸感之新的特性值而表 不不織布。 [微小荷重時之壓縮特性值] 於22°C、65% RH之環境下,本發明中係將微小荷重時 之壓縮特性值定義為表示肌膚觸感之新的特性值。測定係 於22°C、65% RH之環境下進行。成為計算微小荷重時之 壓縮特性值之基礎的資料之測定係使用Kat〇 Tech股份有 限公司製造之KES FB3-AUTO-A(商品名)。將不織布!切割 為20 cmx20 cm之3片而準備測定樣品。其次,將其中 測定樣品以起毛面朝上之方式設置於試驗台上(未起毛之 情形時,或兩面起毛之情形時係測定兩面而採用較小 者)。其次’於具有面積為2 cm2之圓形平面的鋼板間進行 壓縮。壓縮速度為20 μηι/sec,最大壓縮荷重為i〇 gf/cm2, 恢復過程亦以同一速度進行測定。此時,將鋼板間之位移 量設為x(mm) ’荷重設為y(gf/cm2),檢測荷重之點之位置 設為x=0,於壓縮方向上進行測定。越被壓縮χ之值越大。 微小荷重時之壓縮特性值係自所測定之資料(x、y)中取 得微小荷重時之厚度變形量而算出。具體而言,取得並非 恢復過程之第一次之荷重為〇.3〇 gf/cm2至1.00 gf/cm2之間 之何重與該時之變形量之資料,針對X與y之關係,藉由最 156621.doc 201224239 小平方法求出近似直線,將此時之斜率設為上述特性值 (單位(gf/cm )/mm)。於1片測定樣品測定3處。3片樣品合 计測定9處。算出9處各自之特性值,將其等之平均值設為 此不織布之微小荷重時之壓縮特性值。 本發明者發現微小荷重時之壓縮特性值與肌膚觸感相 關,尤其發現原本之不織布相同之情形時有較強之相關 性。(微小荷重時之)壓縮特性值為越低數值,則表示越容 易於較小荷重下壓塌,可表示人之肌膚觸感之感覺(尤其 是柔軟感)之良好程度。例如,未實施下述加工處理且通 常之單位面積重量為5〜25 g/m2之原本之紡黏不織布之上述 壓縮特性值為20.0 (gf/cm2)/mm〜3〇 〇 (gf/cm2)/mm,相對於 此,對此紡黏不織布實施有下述加工處理的不織布丨之表 面易破壓塌,為18.0 (gf/cm2)/mm以下。即,就肌膚觸感 之觀點而言’對單位面積重量為5〜25 g/m2之原本之紡黏不 織布實施加工處理之不織布丨之上述壓縮特性值宜為18 〇 (gf/Cm2)/mm以下,較佳為15.〇 (gf/cm2)/mm以下,就形成 接近肌膚觸感良好之熱風不織布之肌膚觸感的觀點而言, 更佳為1〇.〇 (gf/cm2)/mm以下。對單位面積重量為5〜25 g/m2之原本之紡黏不織布實施加工處理的不織布丨之上述 壓縮特性值之下限並無特別限制,但就製造上之觀點而 s,宜為1.00 (gf/cm2)/mm左右。於先前之起毛方法等加 工處理中,難以在不使斷裂強度大幅度減少而具有如此之 特性值之情況下,對單位面積重量為5〜25g/m2之較低值之 原本之纺黏不織布實施加工處理。 156621.doc -10· 201224239The breaking strength of the non-woven fabric preferably satisfies the above range in the X° direction. Non-woven fabric 1 盥; 5 soil fracture strength ratio (non-woven! The break is strong and woven fabric ^ The original non-woven strength m is 〇.5~$ and the original non-woven fabric is broken under the method. $佳为.· The breaking strength of 7~... is taken by the [breaking strength measurement method in 22 C, 65% RH ring culture, and then, from the non-woven fabric 1 or the original spunbond 156621.doc 201224239 weaving cloth to cut the x direction ( In the width direction), a rectangular measuring piece having a size of 50 mm in the 20 〇 mmAY direction (longitudinal direction) is used. The cut rectangular measuring piece is used as a measurement sample, and the measurement sample is oriented in the X direction. Mounted on a chuck of a tensile tester (for example, Tensilon “RTA-100” manufactured by 〇rientec). The gap between the chucks is set to 150 mm. The sample is pulled at 30 〇mm/min. When the sample is broken, the maximum load is set to the breaking strength β in the X direction, and a rectangular measuring piece having a size of 200 111111 in the Υ direction and a size of 5 〇 mm in the direction is taken as a measurement sample. The sample is measured by its γ The direction is the direction of stretching, and is attached to the chuck of the tensile tester. The breaking strength in the γ direction is obtained in the same order as the method for measuring the breaking strength in the X direction. The non-woven fabric 1 of the present embodiment is characterized by the skin. The touch is good. First, there are a variety of characteristic values indicating the touch of the skin. Especially, the characteristic value of KES manufactured by Kato Tech Co., Ltd. is known (Reference: Standardization and Analysis of Texture Evaluation (2nd Edition), Author, Kawabata Hiroshi, issued July 10, 1980. In particular, it is known that LC of three characteristic values called compression characteristics (linearity of compression load and compressive strain curve), WC, is known in the characteristic value of soft feeling. (compression work amount), RC (compression resilience). These compression characteristics are calculated from the amount of deformation when a load of 0.5 to 50 gf/cm 2 is applied (0.5 to 10 gf/cm 2 in the case of high sensitivity measurement). However, the weight per unit area is small (5 to 25 g/m2). The very thin cloth such as non-woven fabric does not make much difference. The correlation with the touch of the skin is not large. Further, the load when the person touches the absorbent article is 1 When the g/cm2 is extremely light, the skin feels 156621.doc 201224239. In order to express the original skin feel, it is considered that the characteristic value smaller than the previous load range can be used, so that the load system 〇3 gf /cm2 to! The load between gf/cm2 and the amount of deformation at this time found a new characteristic value. This characteristic value faithfully indicates the difference in the skin feel between the spunbonded non-woven fabric and the hot air non-woven fabric, which can indicate the spunbond The new characteristic value of the non-woven fabric touch is not woven. [Compression characteristic value at the time of micro load] In the environment of 22 ° C and 65% RH, in the present invention, the compression characteristic value at the time of the minute load is defined as A new characteristic value indicating the touch of the skin. The measurement was carried out in an environment of 22 ° C and 65% RH. KES FB3-AUTO-A (trade name) manufactured by Kat〇 Tech Co., Ltd. was used for the measurement of the basis of the compression characteristic value at the time of calculation of the minute load. Will not weave! The sample was prepared by cutting into 3 pieces of 20 cm x 20 cm. Next, the sample to be measured is placed on the test stand with the raised side facing up (in the case of no fluffing, or when both sides are fluffed, the two sides are measured and the smaller one is used). Next, compression was performed between steel sheets having a circular plane having an area of 2 cm 2 . The compression speed is 20 μηι/sec, the maximum compression load is i〇 gf/cm2, and the recovery process is also measured at the same speed. At this time, the displacement between the steel sheets was set to x (mm), the load was set to y (gf/cm2), and the position at which the load was detected was set to x = 0, and the measurement was performed in the compression direction. The more compressed, the greater the value. The compression characteristic value at the time of the minute load is calculated from the amount of thickness deformation when the micro load is obtained from the measured data (x, y). Specifically, the data of the weight of the first time that is not the recovery process is between 〇3〇gf/cm2 and 1.00 gf/cm2 and the amount of deformation at that time is obtained, for the relationship between X and y, by Most 156621.doc 201224239 The Xiaoping method finds an approximate straight line, and sets the slope at this time to the above characteristic value (unit (gf/cm)/mm). Three samples were measured in one measurement sample. Three samples were collectively measured at 9 places. Each of the nine characteristic values was calculated, and the average value of the values was set as the compression characteristic value at the time of the micro load of the non-woven fabric. The inventors have found that the compression characteristic value at the time of minute load is related to the touch of the skin, and in particular, it is found that there is a strong correlation when the original non-woven fabric is the same. The lower the value of the compression characteristic value (at the time of the minute load), the more likely it is to collapse under a small load, and the degree of feeling of the human touch (especially the soft feeling) is good. For example, the above-mentioned compression characteristic value of the original spunbonded nonwoven fabric which is not subjected to the following processing and which has a basis weight of 5 to 25 g/m 2 is usually 20.0 (gf/cm 2 ) / mm 3 〇〇 (gf / cm 2 ) In the case of the spunbonded nonwoven fabric, the surface of the nonwoven fabric which is subjected to the following processing is easily broken and collapsed, and is 18.0 (gf/cm 2 )/mm or less. That is, in terms of the touch of the skin, the above-mentioned compression characteristic value of the non-woven fabric which is processed to the original spunbonded nonwoven fabric having a basis weight of 5 to 25 g/m 2 is preferably 18 〇 (gf/cm 2 ) / mm. In the following, it is preferably 15. (gf/cm2)/mm or less, and it is more preferably 1 〇.〇(gf/cm2)/mm from the viewpoint of the skin feel of the hot air non-woven fabric which is close to the skin. the following. The lower limit of the above-mentioned compression property value of the nonwoven fabric which has been subjected to the processing of the original spunbonded nonwoven fabric having a basis weight of 5 to 25 g/m 2 is not particularly limited, but it is preferably 1.00 (gf/ in terms of manufacturing). Cm2) / mm or so. In the processing such as the previous raising method, it is difficult to carry out the original spunbond nonwoven fabric having a lower basis value of 5 to 25 g/m 2 per unit area without having such a characteristic value without greatly reducing the breaking strength. Processing. 156621.doc -10· 201224239

等。可單獨使用該等各種樹脂之丨種, 可列舉聚偏二氣乙烯 i ’或混合使用2種以 上’亦可使用該等各種樹脂之改性物4,作為構成不織 布1之長纖維,亦可使用複合纖維。作為複合纖維,可使 用並列型(side by side)纖維、芯鞘纖維、具有偏芯之捲曲 的心鞘纖維、分割纖維等。於使用複合纖維之情形時,若 使用芯包含聚丙烯且鞘包含聚乙烯之芯鞘纖維,則於獲得 柔軟之起毛不織布方面較佳。又,長纖維2亦可使用賦予 有纖維著色劑、抗靜電特性劑、潤滑劑、親水劑等少量添 加物之纖維。長纖維2之纖維徑於下述加工前較佳為5〜3〇 ,更佳為10〜2〇 μπι。 就纺絲性之觀點而言,構成不織布1之原本之紡黏不織 布較佳為由作為聚烯烴系樹脂之聚丙烯樹脂所形成。作為 聚丙稀樹脂,就光滑進而提昇肌膚觸感之觀點與斷裂之容 易度方面而言,較佳為含有5〜1〇〇重量%、更佳為25重量 %〜80重量%之無規共聚物、均聚物、嵌段共聚物中之任一 種以上的樹脂。又,可混合該等共聚物或均聚物,亦可混 156621.doc 201224239 合其他樹脂,但就成形時不易斷頭之方面而言,較佳為聚 丙稀之均聚物與無規共聚物之混合。藉此,使纖維之結晶 t降低’起毛纖維本身變得柔軟,肌膚觸感變得良好,並 且可兼顧不織布強度,起毛纖維變得易於壓花等之溶接部 切斷,因此獲得壓花炫接點等接合部不再發生剝離,起毛 纖維變短’不易形成切,外觀亦良好者。又,由於溶點 之分佈變廣’故而密封性變得良好。進而,作為以丙稀成 刀作為基礎之無規絲物,較佳為與乙稀或稀烴共聚合 而成者’尤佳為乙烯-丙烯共聚物樹脂。作為聚丙烯樹 脂,就相同之觀點而言,較佳為含有5重量%以上、更佳 為3有25重量%以上之乙烯_丙烯共聚物樹脂的樹脂。乙 烯-丙烯共聚物樹脂中,乙烯濃度較佳為卜川重量。〆。,尤其 就無黏附且延伸時易伸長、脫毛性較小、維持斷裂強度之 方面而言,乙烯濃度更佳為3〜8%。又,作為聚丙烯樹 脂,就環境之觀點而言,較佳為含有25重量%以上、更佳 為含有50重量%以上之再生聚丙烯樹脂的樹脂。再者,不 織布1原本形成為紡黏層與熔喷層之積層不織布之情形時 亦相同。 關於由壓花產生之熱熔接部3,就肌膚觸感或加工適應 性之觀點而言’各熱熔接部3之面積較佳為〇 〇5〜1〇 , 更佳為0.1〜1 mm2。熱熔接部3之數量較佳為1〇〜25〇個/cm2, 更佳為35〜65個/cm2。於X方向上相鄰之熱熔接部3彼此之 中心間之距離較佳為〇·5〜10 mm,更佳為卜3 mm,於Y方 向上相鄰之熱熔接部3彼此之中心間之距離較佳為〇 〇 156621.doc 201224239 mm ’更佳為1〜3 mm。 等)之:H3T列舉藉由利用壓花(利用壓花凸輥與平輥 :間斷地形成者、藉由超音波炫接形成者、 地施加熱風而使之部分熔接者等。其中,由熱壓接形 :者於易使纖維斷裂方面而言較佳。熱熔接部3之形狀並 無特別限制,例如可為^ JT為圓形、菱形、三角形等任意形狀。 熱炼接部3之合計面積於不織布面之表面積中所佔的 比率較佳為5〜30%,就不易形成毛球方面而言,更佳為 10〜20% 〇 本實施形態之不織布i原本係形成為包含長纖維2之紡黏 不織布,形成有長纖維2之一部分斷裂,僅一端部2〇a利用 熱熔接部3予以固定之纖維2〇 ,纖維20含有自由端部2〇b變 粗大之纖維21 ^作為前端變粗大者,較佳為其前端部之剖 面為扁平狀(橢圓或壓塌之形狀)者。藉此,獲得前端柔軟 之起毛纖維,獲得對皮膚之刺激較小之不織布。如圖1所 示,僅一端部20a利用熱熔接部3予以固定之纖維2〇包含另 一端部側之自由端部20b變粗大之纖維21及自由端部2〇b未 變粗大之纖維22。此處,所謂「自由端部」,係指僅一端 部20a利用熱炼接部3予以固定之纖維20之「另一端部」, 換言之係指「前端部」。自由端部20b是否變粗大係藉由 以下測定法測定纖維徑,算出前端纖維徑之增加比率而判 斷。 [纖維徑之測定法] 首先,於22°C、65% RH之環境下,如圖5(a)所示,利用 156621.doc • 13· 201224239 鋒利之刹刀自所測定之不織布1上切取X方向上為2 cm且γ 方向上為2 cm之大小之測定片,將如圖5(b)所示藉由通過 複數個熱熔接部3之於X方向上延長之翻摺線Z進行正折之 測定樣品,如圖5(c)所示,放置並固定於載有碳膠帶之掃 描型電子顯微鏡(SEM)用之鋁製試樣台上。其次,自放大 至約750倍之SEM圖像隨機選出10根僅一端部20a利用熱炫 接部3予以固定之纖維20,對此等纖維之自由端部之前端 附近拍攝照片。自所獲得之照片(參照圖2),分別測定距離 自由端部20b之前端120 μιη之位置的纖維20之纖維徑(除自 由端部20b以外之部位之纖維20之纖維徑21a)。將測定除 自由端部20b以外之部位之纖維20之纖維徑2 la時之斜率直 接向自由端部20b側平行移動,測定自由端部2〇b之前端與 距離前端20 μηι之位置之間所夾之區域中最粗大之位置之 纖維21之纖維徑(自由端部20b之纖維21之纖維徑21b)。再 者,於前端部為扁平狀之情形時,根據觀察角度而定亦存 在前端未見變粗大之情形,此時亦利用所獲得之照片直接 測定》 所謂自由端部20b變粗大之纖維21,係指之前隨機選出 之10根纖維20中滿足如下條件之纖維:根據下述式(1),由 分別自10根纖維20之照片測得的自由端部2〇b之纖維2〇之 纖維徑21b、與除自由端部20b以外之部位之纖維2〇之纖維 徑2丨3求得之前端纖維徑之增加比率之值為15%以上;就抑 制於熱熔接部3彼此間(除熱熔接部3與纖維之邊界以外之 纖維形態部分)之纖維之切斷,抑制斷裂強度之減少’獲 156621 .doc 201224239 得肌膚觸感良好者方 而吕’該增加比率之值較佳為2〇〇/0 以上,更佳為25%以上。 前端纖維Μ增加㈣(%)=[(2㈣a)+2ia)x_…⑴ 一於不織布1中’就兼顧肌膚觸感與斷裂強度之觀點而 & ’僅一端部2〇3利用熱炫接部3予以固定之纖維20(自由 端°P2〇b變粗大之纖维21及自由端部20b未變粗大之纖维 22)中之自由端部細變粗大之纖維21之比率較佳為2〇%以 為30/。以上,尤佳為4〇%以上。自由端部2⑽變粗 大之纖維21之比率係自上述纖維徑之測定法令將隨機選出 之職纖維2〇放大至約750倍之隨圖像分別算出前端纖 、准位之增加比率’而算出自由端部鳥變粗大之纖維^之 比率。 不織布1 3有於熱熔接部3之周邊部被切斷之纖維。 針對不織布1之熱熔接部3,利用電子顯微鏡觀察隨機選出 之熱炼接部3之周邊部(自熱熔接部3與長纖”之邊界至外 側及内側⑽μιη以内之範圍’總計1〇随2)。於計數纖維 被切斷之痕跡(壓花部之纖維被屋塌之形狀、與未被壓塌 仍為纖維形狀之部分不連續之部分)之情形時,若該纖維 被切斷之痕跡之數量較多,則就獲得僅於最表面起毛,按 起毛量比柄較於斷裂強度高之不織布之方面而言,較佳為 3處以上被切斷之不織布,更佳為5處〜15處被切斷之不織 布。 不織布1如圖!所示’具有於熱溶接部3、3彼此間立起為 環狀之環狀之纖維23。所謂立起之「環狀之纖維…,係 156621.doc -15· 201224239 指上述纖維徑之測定法中如圖5(c)般進行觀察時另一端部 側不具有自由端部20b ’且距離翻指線Z 0.5 mm以上立起 之纖維。於本實施形態中,所謂環狀之纖維23 ,係指上述 立起之環狀之纖維。構成本實施形態之不織布i的纖維具 有包含自由端部20b變粗大之纖維21及自由端部2〇b未變粗 大之纖維22的僅一端部20a利用熱熔接部3予以固定之纖維 20、與纖維20以外之於熱熔接部3、3彼此間立起為環狀之 環狀之纖維23。就不織布1不會卡住皮膚,降低不適感, 從而提昇肌膚觸感之觀跸而言,構成不織布1之纖維中, 僅一端部20a利用熱熔接部3予以固定之纖維2〇及環狀之纖 維23之總數中之環狀之纖維23之比率較佳為小於5〇%,更 佳為45%以下,尤佳為40%以下。環狀之纖維23之比率係 藉由如下方式求得:自上述纖維徑之測定法中放大為約5〇 倍之SEM圖像中隨機選出1〇根纖維,並自隨機選出之1〇根 纖維中提取僅一端部20a利用熱熔接部3予以固定之纖維 2〇(自由端部20b變粗大之纖維21、自由端部2〇b未變粗大 之纖維22)、及環狀之纖維23,算出纖維幻、纖維22及纖 維23之總數中之纖維23(環狀之纖維)之比率。再者,同樣 地自其他部位之SEM圖像之9處求出比率,並算出此等1〇 處之平均值作為測定值。再者,於隨機選出之1〇根纖維中 含有1根環狀之纖維23之情形時,環狀之纖維23算作丨根。 於不織布1中,藉由含有自由度之相對提高之纖維,會 填埋纖維間之間隙,使表面之粗糙度較小而變得光滑。就 使肌膚觸感提昇之觀點而言,纖維徑之分佈(分散度)越廣 156621.doc •16· 201224239 越好,就肌膚觸感之觀點而言,若為〇.33以上則獲得充分 滿足之效果,若為〇·35以上則獲得進—步滿足之效果。纖 維徑之分佈(分散度)並無特別之上限,較佳為1〇〇以下。更 佳為纖維徑之分佈(分散度)為0.35〜〇.9。此處所謂纖維徑 之分佈(分散度),係指構成不織布1之全部纖維之纖維徑之 分佈(分散度),係僅一端部2〇a利用熱熔接部3予以固定之 纖維20、環狀之纖維23、及兩端部利用熱熔接部3予以固 疋且未立起為%狀之纖維(不受下述加工處理之影響的纖 維)整體之分佈。纖維徑之分佈(分散度)係藉由以下方法測 定。 纖維徑之測疋法[纖維徑之分佈(分散度)之測定法] 首先,於22 C、65¾ RH之環境下,利用鋒利之剃刀自 所測定之不織布1切取X方向上為2 cm、丫方向上為2 cm之 大小之測定片,不將其彎折而直接放置並固定於載有碳膠 帶之掃描型電子顯微鏡(SEM)用之鋁製試樣台上。其次, 自放大至約750倍之SEM圖像隨機抽取1 〇根纖維,測定除 自由端部20b以外之部位之各自之纖維徑(再者,所測定之 不織布1原本形成為紡黏層與熔噴層之積層不織布之情形 時,不選熔噴層之纖維,而僅選取紡黏層之纖維)。於㈠固 上述鋁製試樣台上,藉由上述方式測定丨〇根之纖維徑,由 所測得之10根之纖維徑(1广(11()求出平均值dave,根據下述式 (2) ’由所獲得之10根之纖維徑di〜di〇與平均值求出隨 機選出之10根纖維之纖維徑之分佈。測定.單位設為pm, 以0.1 μιη之分解能進行計測。對每片不織布丨製作6處上述 156621.doc •17· 201224239 紹製試樣台,將各處所獲得之1 〇根纖維之纖維徑之分佈的 平均值(參照下述式(3))設為不織布1中之纖維徑之分佈。 再者’ 10根纖維之纖維徑之分佈之計算係使用微軟公司之 製表軟體excel 2003中之VARPA函數。 1〇根纖維之纖維徑 2*m=[(d1-dave)2+(d2-dave)2+...(dHr dave) )]/1 0 …(2) 不織布1中之纖維徑之分佈(分散度)=(上述式(2)所獲得 之10根纖維之纖維徑之分佈之總和)/6…(3) 就肌膚觸感變得良好之觀點而言,不織布丨之起毛纖維 較佳為8根/cm以上,更佳為12根/(;〇1以上。又,就獲得充 刀之斷裂強度之觀點而言,上限較佳為i 〇〇根/cm以下更 佳為就外觀上未見起毛方面而言較佳為4〇根/cm以下。起 毛纖維係藉由以下測定法測定。 [起毛纖維之測定法] 圖6係表不於22t、65% RH之環境下測定構成不織布i 之纖維中起毛纖維之根數的方法的模式圖。首先,利用鋒 利之剃刀自所測定之不織布切取2〇 cmx2〇 cm之測定片, 如®㈣所7F ’於測定片之起毛面進行正折而形成測定樣 m 104。其次,將該測定樣品1〇4置於A4尺寸之黑色襯紙 上如圖6(b)所不,進而於其上放置開有長1 寬丄⑽之 7的A4尺寸之黑色襯紙。此時,如圖6(b)所示,以自 側之…、色襯紙之孔1〇7可見測《樣品之指線之方 式進行配置°兩襯紙係❹富士共和製紙股份有限公司之 令重265 g」。其後,自上側之襯紙之孔 156621.doc 201224239 107之兩側分別沿著摺線105向外側5 cm之位置,分別放置 50 g之結碼’形成測定樣品104完全摺疊之狀態。其次, 如圖6(c)所示’使用顯微鏡(KEYENCE公司製造之VHX- 900) ’以30倍之倍率觀察襯紙之孔1〇7内,計測起毛超過 假想線108之每1 cm之起毛纖維之根數,該假想線ι〇8係形 成於自樣品104之摺線105向上方平行移動〇·2 mm之位置。 計測9處’將平均值(將小數第二位四捨五入)設為起毛纖 維。 又’計數起毛纖維之數量時,例如圖6(c)所示之纖維 l〇6a般,有將位於摺線1〇5上方〇2 mm之假想線1〇8橫穿2 次之纖維之情形時,此纖維算作2根。具體而言,於圖6(c) 所示之例中,將假想線1〇8橫穿i次之纖維有4根,將假想 線1〇8橫穿2次之纖維⑺^有丨根,橫穿2次之纖維1〇6&算作 2根’起毛之纖維之根數為6根。 就提昇肌膚觸感之觀點而言,不織布丨之起毛纖維(橫穿 假想線108之纖維)之平均纖維徑較佳為小於同一面之未起 毛部位之表面纖維(未橫穿假想線1〇8而未到達假想線1〇8 之纖維)之平均纖維徑。平均纖維徑係指利用顯微鏡(光學 顯微鏡、或SEM等)計測起毛纖維及未起毛纖維各以處之 • 纖維徑而獲得的纖維徑。起毛纖維之纖維徑較佳為未起毛 纖維之97%〜40%,就肌膚觸感優異方面而言,更佳為 90%〜40% 〇 又’就不易形成毛球、$易脫毛、外觀顯得柔軟而較佳 之觀點而言,不織布丨之起毛纖維之高度較佳為15爪爪以 156621.doc -19- 201224239 下’更佳為G.8 mm以下。就上述觀點而言,起毛纖維之高 度越低越好,但為。·2 mm以上便可獲得肌膚觸感充分滿足 者:又,除此以外,為了兼顧斷裂強度,更佳為起毛纖維 之高度為1.5 _以下’且起毛纖維較佳為8根/加以上。進 而,就不易纏住皮膚而感觸較佳方面而言,起毛纖維之高 度宜為0.5 mm以下且起毛纖維宜為15根/(5111以上。此處了 所謂纖維之高度,不同於纖維之長度,係指測定纖維時不 進行拉伸之自然狀態之纖維之高度。若起毛纖維之長度之 值較大或纖維之剛性較高,則起毛纖維之高度有提高之傾 向。起毛纖維之高度係藉由以下之測定法進行測定。 起毛纖維之高度係於測定起毛纖維之根數之同時進行測 定。具體而言,如圖6(c)所示,觀察襯紙之孔1〇7内自摺 線105起,每隔0·05 mm平行地劃線,直至不再與起毛纖維 相交為止。其次,選擇與藉由上述方式測得之起毛纖維之 根數(根據位於上方〇·2 mm處之假想線1〇8進行判斷)相 比,與平行線相交之纖維達到一半之平行線,將該線至摺 線之距離設為起毛高度。對3片所測定之不織布進行以上 操作,每1片取3處、3片合計9處之平均值,設為起毛纖維 之高度。 於獲得柔軟者而肌膚觸感優異方面而言,起毛纖維之高 度、及起毛纖維進而不織布i之鬆厚柔軟度(bulk s〇ftness) 較佳為8.0 cN以下。就成為嬰兒或幼兒之繈褓之類的柔軟 者之方面而言,更佳為0.5〜3.〇 cN。鬆厚柔軟度係藉由以 下之測定法進行測定。 156621.doc •20- 201224239 [鬆厚柔軟度之測定方法] 不織布I之鬆厚柔軟度係於22〇c、65% RH之環境下,切 取MD方向上為150 mm、CD方向上為3〇 mm之不織布j, 使用釘書機將上下2處端部釘住,而製成直徑為45 mm之圓 環狀。此時,釘書機之芯係以沿MD方向變長之方式配 置。使用拉伸試驗機(例如,〇rientec公司製造萬能拉力試 驗機(Tensilon)「RTA_100」),將上述圓環於試樣台上立 為筒狀,利用與台大致平行之平板,以壓縮速度1〇 mm/min 之速度自上方進行壓縮,測定此時之最大荷重作為CD方 向之鬆厚柔軟度。其次,改變MD方向與CD方向並製作圓 環,同樣地測定MD方向之鬆厚柔軟度。對MD方向及cD 方向分別製作2條圓環並進行測定,將該等CD方向與 方向之平均值設為不織布丨之鬆厚柔軟度。 若對形成不織布1之原本之紡黏不織布混練或塗佈柔軟 劑,則本發明之效果更加有效。作為柔軟劑,例如可使 用:蠟乳液、反應型柔軟劑、聚矽氧系、界面活性劑等。 尤佳為使用含胺基之聚矽氧、含氧化烯基之聚矽氧、界面 活性劑。作為界面活性劑,可使用:羧酸鹽系之陰離子界 面活性劑、磺酸鹽系之陰離子界面活性劑、硫酸酯鹽系之 陰離子界面活性劑、磷酸酯鹽系之陰離子界面活性劑(尤 其是磷酸烷基酯鹽.)等陰離子界面活性劑;山梨糖醇酐脂 肪酸酯、二乙二醇單硬脂酸酯、二乙二醇單油酸酯、甘油 單硬脂酸酯、甘油單油酸酯、丙二醇單硬脂酸酯等多元醇 單月旨肪酸酯,N-(3-油醯氧基-2_羥基丙基)二乙醇胺、聚氧 156621.doc -21 - 201224239 乙稀硬化t麻油、聚氧乙稀山梨糖醇蜂纖、聚氧乙稀 糖醇針倍半硬脂酸酿、聚氧乙婦單油酸酷、聚氧乙稀山半 糖醇針倍半硬脂酸雖、聚氧乙婦甘油單油酸醋、聚氧乙稀 單硬脂酸醋、聚氧乙烯單月桂酸醋、聚氧乙烯單油酸醋、 聚氧乙稀錄躐基喊、聚氣r ,法曰4土 # a丨μ 不軋乙烯月桂基醚等非離子系界面活 性劑;4級銨鹽、胺鹽或胺等陽離子界面活性劑;含有羧 基、確酸根、硫酸根之2級或者3級胺之脂肪族衍生物、或 雜環式2級或者3級胺之脂肪族衍生物等兩性離子界面活性 劑等。又,亦可視需要使用公知之化學藥劑作為次要添加 劑(少量成分)而添加至本發明之柔軟劑中。 藉由含有柔軟劑,使肌膚觸感良好,脫毛性較小,表面 對皮膚之摩擦較小’斷裂強度亦高,於本發明中效果特別 南。 柔軟劑與上文所記載之上述無規共聚物併用於進一步增 大其效果方面較佳,於利用柔軟劑可減輕起毛纖維由無規 共聚物引起之黏滑感而獲得爽滑之肌膚觸感方面尤佳。 又,於使用不織布1原本形成為下述紡黏層與熔喷層之 積層不織布,且該積層不織布之紡黏層包含複數層、例如 紡黏·熔喷-紡黏積層不織布、紡黏_紡黏熔喷_紡黏積層不 織布等之情形時,較佳為僅於一層紡黏層中混練上述柔軟 劑,亦可混練於全部紡黏層中等。於一層紡黏層中混練柔 軟劑之情形時’若對此層側實施下述加工處理,而使其具 備自由端部變粗大之纖維’則於肌膚觸感良好、斷裂強度 亦向方面較佳◊如此,就易於調整肌膚觸感或斷裂強度方 156621.doc •22· 201224239 面而言,與不織布i原本形成為紡黏不織布單體相比,較 佳為原本形成為紡黏層與熔噴層之積層不織布。 其次,針對本發明之不織布丨之較佳製造方法,一邊參 照圖3、圖4-邊進行説n織布丨之製造方法所使用之 較佳製造裝置大致分為預加工部4、與配置於預加工部斗之 下游侧之起毛加工部5。 預加工部4如圖3所示,具備:包含於周面設置有相互嚙 合之凸部410與凹部420之一 _41、42的鋼模壓花親“。 如圖3所示,鋼模壓花輥43以相互喃合之方式形成有設置 於輥41之周面之複數個凸部41〇與設置於輥42之周面之複 數個凹部420,才复數個凸部41〇分別均一且規則地配置於親 41之旋轉轴方向及圓周方向。一對輥41、42藉由向任一方 之旋轉軸傳遞來自驅動機構(未圖示)之驅動力進行嚙合而 旋轉。又,預加工部4如例如圖3所示,於鋼模壓花輥“之 上游側及下游側具備搬送原料不織布1〇之搬送輥44、Μ。 關於輥41之各凸部410,輥41之周面至凸部41〇之頂點 止的高度較佳為1〜10 mm,更佳為2〜7 mm。於旋轉軸方向 上相鄰之凸部410彼此之距離(間距)較佳為〇〇1〜2〇 , 更佳為1〜10 mm,於圓周方向上相鄰之凸部41〇彼此之距 離(間距)較佳為0.01〜20 mm,更佳為卜1〇 mm。輥41之各 凸部410之頂部表面之形狀並無特別限制,例如可使用圓 形' 多邊形、橢圓形等,各凸部41〇之頂部表面之面積較 佳為〇.01〜500 mm2,更佳為0.1〜10 mm2。輥42之各凹部 420係配置於與輥41之各凸部41〇對應之位置。輥ο之各凸 156621.doc -23- 201224239 部410與輥42之各凹部420之嚙合深度(各凸部410與各凹部 420重疊之部分之長度)較佳為0.1〜10 mm,更佳為1〜5 起毛加工部5如圖4所示,具備周面設置有凸部51〇之凸 親5 1 ’且於凸輥5丨之上游側及下游側具備搬送原料不織布 1〇之搬送輥52、53。凸輥51係藉由對其旋轉軸傳遞來自驅 動機構(未圖示)之驅動力而旋轉。 關於凸輥51之各凸部510,凸輥51之周面至凸部51〇之頂 點為止的高度較佳為〇 〇〇1〜3 mm,更佳為〇 〇〇1〜〇 ^爪爪。 於旋轉軸方向上相鄰之凸部51〇彼此之距離(間距)較佳為 0.1〜50 mm,更佳為ojy mm,於圓周方向上相鄰之凸部 51〇彼此之距離(間距)較佳為〇丨〜5〇 mm,更佳為〇丄 mm。凸輥51之各凸部51〇之頂部表面之形狀並無特別^ 制,例如可使用圓形、多邊形、橢圓形等,各凸部5i〇j 頂部表面之面積較佳為〇·〇〇1〜2〇 mm2,更佳為〇 〇ι〜 mm2 ° 於具備此種構成之預加工部4及起毛加工部5之製造裝置 中,首先將作為不織布i之原料的例如帶狀之纺黏不織布 (原料不織布1〇)自輥(未圖示)中捲出,利用搬送輕料、 45,將原料不織布職送至鋼模㈣輥43之—對㈣、a 之間於預加工部4中,如圖3所示,將原料不織布於一 對棍41、42之間制,對原料不織布10施加損傷。於施加 損傷時,就不於紡黏不織布之構成纖維間引起㈣接之觀 點而言’鋼模壓花輥43之一對輥41、42較佳為不主動加 156621.doc •24· 201224239 熱,或於構成原料不織布10之纖維成分中溶點最低之成分 之溶點以下之溫度下、尤其是較該熔點低⑽以上之較低 溫度下進行鋼模壓花加工。 其次,利用搬送報52、53,將經損傷之原料不織布1〇· 搬送至周面設置有凸部510之凸輥51。於起毛加工…中, 利用凸報51對經損傷之原料不織布1(),之表面進行加工,使 構成纺黏不織布之長纖維2之—部分斷裂,形成具有僅一 端部心制紡黏不織布之_接部3予以固定之纖維⑼的 不織布U參照圖丨)。就使長纖維2之—部分斷裂,而效率良 好地形成圖1所示之纖維20的觀點而言,較佳為使凸輥“ 之旋轉方向相對於原料不織布1Gi之搬送方向為反方向而進 行旋轉,較佳為以相對於原料不織布1 之搬送速度為 〇·3〜H)倍之速度旋轉化5卜又,於圓周方向(相對於二送 方向為順時針方向)上旋轉之情形時,較佳為以15〜2〇倍之 速度旋轉㈣51。此處,凸親51之速度係指凸㈣之 之圓周速度。 就更有效率地使長纖維2之一部分斷裂,更有效率地形 成圖1所示之纖維20的觀點而言,較佳為如圖4所示將搬 送輥53之位置設定為高於凸輥51,使經損傷之原料不織布 10’以10〜180。之抱角α與凸輥51之接觸面相接觸以 30〜120。之抱角α進行接觸可抑制由不織布之縮幅引起之寬 度減少,故而更佳。 再者,於不織布1之兩面形成僅一端部2〇a利用熱熔接部 3予以固定之纖維20之情形時,藉由進而利用另—凸輥^ 156621.doc -25- 201224239 進行加工,可獲得與利用凸輥51進行加工之原料不織布1〇, 之表面不同的正面(背面)。 本發明者推測形成上述之纖維20之原因為:利用鋼模壓 花輥43,使紡黏不織布(原料不織布1〇)延伸,於紡黏不織 布(原料不織布10)之熱熔接部3形成弱化點,其後利用凸輥 51使長纖維2自不織布之熱熔接部3之最表面之弱化點發生 斷裂,而形成自熱熔接部3切斷之纖維。本發明者推測該 自熱熔接部3切斷之纖維係自由端部2〇b變粗大之纖維21。 又,本發明者推測:利用凸輥5 1,使長纖維2自熱熔接部3 之弱化點剝離,該自熱熔接部3剝離之纖維形成熱熔接部 3、3彼此間立起為環狀之環狀之纖維23。又,本發明者推 測:於利用凸輥51加工表面時,長纖維2於熱熔接部3、3 彼此間斷裂,而形成自由端部2〇b未變粗大之纖維22。藉 由上述本發明之不織布丨之較佳製造方法而製造之不織布 與藉由先前之起毛方法所製造之不織布相比,特徵在於環 狀之纖維23及未變粗大之纖維22之比率較少。若如藉由先 前之起毛方法所製造之不織布般大量存在未變粗大之纖維 22 ’則壓花部與壓花部之間等熱熔接部3間會發生斷裂, 而於熱熔接部3之間形成所謂縫隙(裂隙、孔)β藉此,可不 劃傷未起毛之基礎之纖維而進行起毛,獲得斷裂強度較高 者。相反’於未形成弱化點之狀態下起毛時,若不利用更 強之力摩擦纖維表面’則難以使纖維起毛,而於起毛至未 起毛之最表面以外之基礎之纖維時會導致劃傷,因此不織 布整體容易斷裂,難以保持強度。另—方面,藉由上述本 156621.doc •26- 201224239 發月之不織布1之較佳製造方法而製造之不織布由於未變 粗大之纖維22之比率較少’故而可保持斷裂強度。進而, 於將此種不織布用於内褲型抛棄式尿布等之外包材之情形 時’具有如下優點:若於穿戴尿布時將其上拉,則不^ =ΙΓ不易撕裂(穿破強度較高”又,用於内褲型 封之情形時,脫下尿布時,有時會撕開側 更=: :!不織布不易於尿布之橫向撕裂,獲得 幵。又,若於未形成弱化點之狀態下起毛,則 發生纖維自熱料部之剝離,起毛纖維之根數變少,同時 有起毛高度增高之傾向。^,變得易產生易形成絨毛等 利用上述鋼模壓花輥43,使熱熔接部3與熱溶接部3之間 之纖維延伸,同時於熱熔接部3之周邊部易形成弱化點。 弱化點之調整可藉由鋼模屢花觀43之上下-對輥41、42之 嗔合量而調整。弱化點於延伸方向上易形成接合部與接人 部之間之纖維長度較短者。藉 ° 稭由形成该弱化點,可形成脆 Ρ,於利用起毛加工部5之起毛時纖維容易自弱化點被 切斷’㈣獲得起域輪料,於獲得肌相感優異、 外觀上起毛不明顯、不易形成毛球、斷裂強度亦較高之起 毛不織布方面㈣。„,藉由延伸熱熔接部 部3之間之纖維,纖維會變細, …塔接 宵父、、,田,又,熱熔接部3亦變柔軟, 而獲得肌膚觸感良好之不織布。尤其是,利用鋼模廢花輥 43,使纖維較細地延伸而伸長為較長,藉此增加纖維間之 距離,透氣性提昇。此外,藉由利用起毛加工部5進行起 15662l.doc •27. 201224239 毛處理’起毛之表面纖維之鬆密度會降低,因而即使為相 同單位面積重量之不織布’起毛不織布之透氣度更加提 昇。如上所述’藉由組合纖維之延伸與起毛處理, 與原本之不織布相比,提昇至12〜2q倍更佳心〜二 倍。透氣度係利用Kat0 Tech製造之自動透氣性測試儀 (AUTOMATIC AIR- PERMEABILITY TESTER)KES-F8- AP1測定透氣阻力1其倒數而求出。所獲得之*織布之 透氣度較佳為成為24 m/(kPa. s)以上。作為肌膚觸感與透 氣度兩方良好之原料不織布1〇之紡黏不織布,較佳為由不 含熔喷層而僅積層紡黏層者(例如紡黏_紡黏_紡黏)所構成 之不織布。 以下,對使用上述本發明之實施形態之不織布〗時之作 用效果進行説明。 本實施形態之不織布丨中,如圖丨所示形成有長纖維2之 一部分斷裂,僅一端部20a利用熱熔接部3予以固定之纖維 20。由於形成有此種纖維20,故而可對不織布1整體賦予 柔軟感。又,由於僅長纖維2之一部分未斷裂,故而可將 斷裂強度保持為與原本之紡黏不織布相同之較高程度。 又’本實施形態之不織布1之纖維2〇如圖1所示,含有自由 端部20b變粗大之纖維21。由於含有自由端部2〇b變粗大之 纖維21,故而自由端部20b不會導致刺痛,不易卡住皮 膚,肌膚觸感良好。又,自由端部2〇b變粗大之纖維21, 其自由端部20b側易垂下,而變得光滑,故而肌膚觸感良 好》 156621.doc •28- 201224239 纺黏不織布或_積層*織布於以往柔軟感較小,與熱 風製法之不織布相比肌膚觸感差。根據上述本實施形態之 不織布1’可使纺黏層與溶喷層之積層不織布除具有如日 本、·氏之光/月性以外,還具有柔軟性,而大幅度提昇肌膚觸 感。 ,不織布1之利用範圍主要適合用於拋棄式尿布、生理用 衛生棉等吸收性物品中之構成構件。作為構成構件,例如 可列舉:正面片材、背面片材、構成外裝體之片材等。此 外不織布1之利用範圍亦適合用於清掃用片材。以下, 列舉利用不織布1之拋棄式尿布,具體地進行説明。 内褲型拋棄式尿布100,如圖7所示,具備含有吸收體4〇 之吸收性本體50、與位於吸收性本體5〇之非皮膚接觸面側 且固定該吸收性本體5〇之外包材6〇。 吸收性本體50,如圖8所示,具有液體透過性之正面片 材70、液體不透過性(亦包括撥水性)之背面片材8〇及介隔 於兩片材70、80之間的液體保持性之吸收體4〇,其實質上 縱向較長。 外包材60具有配置於穿戴者之背側之背側部a、配置於 腹側之腹側部B、位於其等之間而配置於胯襠部之下襠部 C ’背側部A與腹側部B之兩侧緣部6a、61>彼此接合,形成 有一對側封部(未圖示)、一對腿部開口部(未圖示)及腰部 開口部(未圖示又,外包材60具有形成尿布之外面的外 層片材62、位於其皮膚接觸面侧且部分地與該外層片材62 接合之内層片材61 ’於形成腰部開口部及腿部開口部之腰 156621.doc -29· 201224239 部及腿部6d之兩;ί#61、_,配置有㈣形成用之腰部 彈性構件63及腿部彈性構件64。 吸收性本體50,如圖7所示,配設於外包材6〇之背側部八 至腹側部Β,吸收性本體50之長度方向之兩端部位於較外 包材60之長度方向 < 兩端部向長度方向之内側後退之位 置。吸收性本體50,如圖8所示’吸收性本體5〇之背面月 材80之非皮膚接觸面係藉由利用接著劑、熱密封、超音波 密封等之接合法而與外包材60之内層片材61之皮膚接觸面 接合。 於吸收性本體50之長度方向之兩側部,如圖7所示,設 置有由液體不透過性或撥水性且透氣性之素材所構成之側 方翻邊55、55。各側方翻邊55之自由端部附近以伸長狀態 固定有側方翻邊形成用之彈性構件56。側方翻邊55可阻止 穿著尿布時自由端部側立起,導致排泄物向吸收性本體5〇 之寬度方向之流出。側方翻邊55形成用片材如圖8所 示,係使吸收性本體50之寬度方向外側之規定寬度之部分 55a捲入吸收體4〇之非皮膚接觸面側,而固定於吸收體 與背面片材80之間。再者,規定寬度之部分55a亦可固定 於背面片材30與外包材6〇之間。 本發明之不織布可較佳地用作外層片材62。又,本發明 起毛不織布亦可用作正面片材70、背面片材80、侧方翻 邊55形成用片材、内層片材61。於不使用本發明之不織布 之情形時之各部之構件’可無特別限制地使用通常用於拋 棄式尿布等吸收性物品者。例如,作為正面片材70,可使 156621.doc 201224239 用液體透過性之不織布、或開孔膜、該等積層體等,作為 背面片材80 ’可使用樹脂膜或樹脂膜與不織布之積層體 等°作為侧方翻邊55形成用片材,可使用伸縮性之膜、不 織布、織物或其等之積層片材等。作為内層片材61及外層 片材62,可使用撥水性之不織布等。 作為吸收體40 ’可無特別限制地使用先前用於拋棄式尿 布等吸收性物品者。例如,作為吸收體40,可使用利用紙 巾或透水性之不織布等被覆材,包裹紙漿等纖維材料之纖 維集合體或使其承載高吸收性聚合物者而成者等。 作為側方翻邊形成用之彈性構件56、腰部彈性構件Ο及 /彈I·生構件64,可無特別限制地使帛通常帛於拋棄式尿 =等吸收性物品者。例如可使用:包含天然橡膠、聚胺 *聚苯乙烯·聚異戊:缔共聚物、聚苯乙稀_聚丁二稀共 * 丙烯馱乙Sa_乙烯等聚乙烯-α烯烴共聚物等之伸缩 性材料等》 寸心呷、唯 本發明之不織布對上龙 这本貫施形態之不織布1並無任何 限制,可適宜變更。 例如’上述本實施形態之 本形成為纺點不織布Μθ亦可^巾雖然如圖2所不原 之積層不镟I认士 、了原本形成為紡黏層與熔喷層 層配置於熔啥届夕層不織布之情形時,較佳為將紡黏 ι%俗赁層之正面 與熔噴層之稽届π诚—次是面之不織布。關於紡黏層 觸咸 布,就其整體光滑且進一步提昇μ廢 觸感之觀點與起毛時纖八昇肌膚 重量%以上之U面^,尤佳為含有25 ,、規“物的乙烯-丙烯共聚物樹 156621.doc -31 · 201224239 層使用均聚物之聚丙烯樹脂。又’含有無規共聚物之樹脂 形成最外側層之紡黏層時,於柔軟層配置於外側因而彎曲 剛性降低而變柔軟方面較佳。就成本績效方面而言,製成 僅皮膚接觸面之紡黏層由含有上述無規共聚物之樹脂所形 成之積層不織布時,於可分擔為肌膚觸感良好之面(含有 無規共聚物之層)與斷裂強度較高之面,而可有效率地提 什肌膚觸感方面較佳。同樣地’由包含含有25重量%以上 之再生聚丙烯樹脂代替上述無規共聚物之聚丙烯樹脂之纖 維所構成時,於對環境負擔較小之觀點而言較佳。 作為形成不織布1之原本之不織布,除不織布(例如紡黏 不織布)、積層不織布(例如藉由熱壓花將紡黏層與熔喷層 積層而成之不織布)、將不織布與未結合之網積層並藉由 加熱等將該等接合而成者以夕卜,亦可列舉:利用加熱親等 將30 mm以上之短纖纖維熱壓接而成者、或者於熱風熱處 里後實施壓化加I者等。構成不織布之纖維可為單纖維、 複合纖維(並列型、芯稍、偏芯纖維)、捲縮纖維' 執收縮 纖維、熱伸張纖維、藉由延伸而分割之纖維。尤其就廉價 :面而言,較佳為單纖維。又’亦可為藉由接著劑或加 熱’於上述不織布上接合其他不織布或膜而成之複合不織 ^於Γ料,起毛加工可於貼合其他不織布或膜之前 進仃’亦可於之後進行。 ^於利用起毛加卫部5起毛時,凸輥以 不織布之饋進方向(MD方向),因 得万〇為 t U而織維之配向度(Md/c 較佳為1.1〜1.8、更佳為i.2〜15 ^ 於纖維易被凸報5 1之 156621.doc -32· 201224239 凸部51〇卡住而變得易獲得起毛量較高者方面較佳。纖維 之配向度係對切取MD方向上為95 mmaCD方向上為95 mm之正方形樣品,利用微波式分子配向計M〇A6〇〇4(〇ji Scientific lnstruments公司製造)測定M〇R值而獲得。纖維 之配向度設為樣品數5點之平均值。 使用上述製造裝置所製造之不織布不同於如先前技術的 專利文獻3中所揭示之植毛片材,由於並無使用接著劑等 於不織布上附著新的纖維的操作,故而可減低因所使用之 接著劑等化學藥劑對皮膚產生不良影響之危險性。又,不 同於植毛,亦不會發生使用時之植毛纖維之剝落、接著面 之露出等問題。又’例如’使用於吸收性物品之不織布之 -的紡黏不織布較薄’於一般之起毛加工中易發生撕裂而 存在困難,但根據使用上述製造裝置之不織布之製造方 法’可獲得起毛密度較高、肌膚觸感良好之起毛(纺黏 織布。 其次,針對本發明之不織布> a〜 施態樣,一邊參照圖式一邊進行説明 再者,關於不織布,觀看於構成纖維之配向方向,一般 將A著纖維之配向方向的方向設為方向或長度方向, =將與其正交之方向設為CD方向或寬度方肖,以下進行 Μ °又’於以下之説明中,搬送MD方向(長度方向)之不 織布的方向與藉由使輥沿著圓周方向旋轉而搬送片材之方 :係指同-方向’不織布之CD方向(寬度方向)與輥 方向係指同一方向。 神 156621.doc -33- 201224239 圖9~圖1 2係模式性地表示本發明之不織布之製造方法所 使用之加工裝置(以下簡稱為加工裝置)之一實施形態的 圖。 如圖9所示’本實施形態之加工裝置1大致分為部分延伸 加工部2、與配置於部分延伸加工部2之下游側的起毛加工 部3。 部分延伸加工部2係對不織布4之複數處分別實施部分延 伸加工的部分’於本實施形態之加工裝置1中,如圖9、圖 10所示,具備一對凹凸輥2 1、22。此處所謂「部分延伸」 加工,並非一般進行之藉由輥間之速度差而對不織布整體 實施延伸處理者,而是以具有未延伸部分與延伸部分之方 式進行加工的方法。所謂未延伸部分,係指不織布中之未 實施延伸處理的部分,所謂「未實施延伸處理」,係指加 工上未主動地實施延伸處理。 關於一對凹凸輥21、22,一個輥21於周面上具有複數個 凸。卩210,另一個報22於周面之與一個輥21之凸部對應 之位置具有凸部210可進入之凹部22〇。一對凹凸輥21、22 係鋁合金或鋼鐵等金屬性之圓筒形狀者。於本實施形態之 加工裝置1中,具備包含周面設置有相互喃合之凸部21〇與 凹部220之一對凹凸輥21、22的所謂鋼模壓花輥23。如圖 11所示,鋼模壓彳係以相互嗜合之方式形成有設置於 輥21之周面的複數個凸部210與設置於輥22之周面的複數 個凹部220,複數個凸部210分別均一且規則地配置於輥21 之旋轉轴方向及圆周方向。一對輥21、22係藉由使用齒輪 I56621.doc •34· 201224239 =,圖示)傳遞來自驅動機構(未圖示)之驅動力而旋轉。再 “了向任—方之旋轉軸傳遞來自驅動機構(未圖示)之驅 、’使-對輥21、22嚙合而旋轉,就藉由於相互之溝槽 之中心進行延伸而有效地進行部分延伸的觀點而言,較佳 示唾σ以外’使用齒輪傳遞驅動力。—對輥2卜之:之旋 轉速度(圓周速度V2)係由加工裝請具備之控制部(未圖 不)進行控制。此處,㈣、22之圓周速度v2係將(與輕η =尖外形1合之深_設為直徑,由輥之旋轉數求出 0周之速度。 輥2!之周面之凸部21〇之形狀自上部觀察可為圓形、四 形、橢圓形、菱形、長方形(於搬送方向或與搬送方向 ^之方向上較長)’就不織布4之斷裂強度降低較小方面 口較佳為圓形。又,作為自側面觀察凸部210之形 狀’可列舉梯形、四邊形、臀曲形狀等,就輥旋轉時之摩 ^較小方面而言’較佳為梯形’更佳為梯形之底邊角為70 度〜89度》 就使加工前之不織布4表現出較高之柔軟性等改良效 果’保持延伸後之不織布4,之斷裂強度的觀點而言,部分 延伸加工部2較佳為以機械延伸倍率1.05〜20倍分別延伸不 織布4之複數處’更佳為延伸至2〜⑺倍。此處所謂機械延 申倍率係心由對不織布4實施延伸處理之親21之凸部 與觀22之凹部22G之喷合形狀求出的值。複數處之各自之 機械延伸倍率如圖叫[係根據下述[數^、[數稿示 之數式,由輥2丨之圓周方向上相鄰之凸部21〇彼此之距離 15662l.doc -35- 201224239 (間距、輥21之旋轉軸方向上相鄰之凸部210彼此之距離 (間距P2)、及輥21之各凸部210與輥22之各凸部之嚙合之深 度D、及輥21之凸部210之頂點於圓周方向上之距離(點直 徑、輥2 1之凸部頂點於旋轉軸方向上之距離(點直徑a2) 求出。於輥21之凸部210之形狀與輥22之凸部之形狀不同 之情形時,係求出輥21與輥22各自之頂點於圓周方向上之 距離之平均值作為點直徑八丨。點直徑八2亦同樣地求出輥21 與輥22各自之頂點於旋轉軸方向上之距離之平均值。又, 點上面之形狀為長方形以外之圓形、橢圓、及多邊形之情 形時亦同樣地求出》此時之機械延伸倍率設為延伸倍率最 高之部分(輥2 1之凸部21 〇與輥22之凸部最接近之部位)之延 伸倍率。將其設為機械延伸倍率。其中,即使機械延伸倍 率不為輥形狀,而為例如日本專利特開2〇〇7_22〇66中所記 載之平板型、履帶型等形狀,亦同樣地求出. 圓周方向之機械延伸倍率 [數1] ^ΡχΧ) - 旋轉軸方向之機械延伸倍率 [數2] 再者,所求得之圓周方向及旋轉軸方向之任一方之機械 15662] .doc -36 - 201224239 延伸倍率滿足上述範圍之機械延伸倍率即可。 關於部分延伸加工部2之一對凹凸輥,為了將將機械延 伸倍率設為上述範圍,減低加工後所獲得之不織布之斷裂 強度降低,較佳為對相對於所供給之不織布4之總面積為 urn〜嶋之部分實施部分延伸加工’更佳為對4G%〜8〇%之 部分實施部分延伸加工。此處,所謂實施部分延伸加工之 不織布4之複數處,如圖u所示,係指藉由親以各凸部 2U)與輥22之各凹部22G之唾合而延伸之部分,若詳細,則 係指利用輥21之各凸部21〇之邊緣⑽、與親^之各凹部 .220之開始凹陷之邊緣22〇a進行延伸之部分。位於各凸部 之凸面(頂部表面)上的不織布部分不易主動地受到延伸作 用。因此,所謂相對於不織布4之總面積實施部分延伸加 工的部分’係指自所供給之不織布4之總面積減去將親Η 之各凸。P 210之頂部表面之面積總和的總面積,進而減去 將輥21之相鄰之各凸部21〇彼此之間之底面之面積總和的 總面積的部分。作為對不織布所施加之實際延伸效果 織布之總延伸倍率係由如下之值求出:將所延伸之部 Γ積率與所延伸之部分之上述不織布之延伸倍率相乘而獲 付 加上將未延伸部分(包括實質上未延伸之部分)之 延伸倍率設為1倍時之去μ从 々恬-之未延伸之面積率而獲得之值。又, =申之之:二之上述不織布之延伸倍率分為圓周方向_ 方向)之不織布延伸倍率與旋轉轴方向(CD 延伸倍率。即’根據下述式⑴求出。 不織布 不織布之總延伸倍率=4 申倍羊,周方向(MD方向)之不織布之 156621.doc •37- 。3 201224239 延伸倍率x不織布之]VfD大· a (CD方W Γ 之延伸面積率} +則軸方向 方白)之广布之延伸倍率X不織布之旋轉軸方向(CD =之延伸面積率} + {未延伸部分(包 之 :之延伸倍率卿不織布之未延伸之面積率卜二 織:= 周方向⑽方向)之不織布延伸倍率係根據不 =!而有所不同’因而係指將上述圓周方向 比㈤㈣^UT述供給速度與輕21(或輥22)之周速 敵會導Γ速/供給速度)而獲得的值。由於不織布上產生梢 縮幅’故而旋轉轴方向(CD方向)之不織布延伸倍 之通^"^_軸方向之機械延伸倍率乘以報21與親22 之通過前後之不織布之甯 邱之寬度變化比(輥通過後之不織布寬 通過前之不織布寬度)而獲得的值。助方向、CD方 向同時受到延伸之情形(不織布於傾斜方向受到延伸之情 ⑴時人’係將機械延伸倍率作為向量’求出md方向與CD方 成和°又’凸部之形狀自上部觀察為圓形等之情形 ’係求出各點之機械延伸倍率之積分值。若不織布之總 延伸倍率為下述範圍’則藉由部分延伸,原本之不織布所 、有之熱屋接部與熱屋接部之間之纖維變細的熱屡接部之 周邊部(熱壓接部與纖維之邊界附近)因延伸作用而形成縫 杳)起毛時纖維易於此部分被切斷,進而熱壓接部 會因延伸而發生變形,故而熱壓接部本身變得柔軟,因而 起毛時熱壓接部不易發生剝離,起毛纖維變短,獲得易起 毛肌膚觸感優異之不織布。就獲得與延伸前之原本之不 織布相比,由部分延伸加工引起之斷裂強度降低較小,且 156621 .doc -38· 201224239 肌膚觸感良好者方面而言,不織布之總延伸倍率較佳為 1:3倍〜4倍’更佳為i 5倍〜3倍。不織布之熱壓接部之面積 率…v«延伸倍率之比{不織布之熱壓接部之面積率(%),(绅 延伸倍率(倍)Xl 〇〇)}較佳為〇 〇2〜〇 12,京尤維㈣裂強度並 且適度破壞熱壓接部使起毛量增多之方面而言,更佳為 〇.〇4〜0.1G。再者,原本之不織布具備於平面方向規則地分 散之熱壓接部,所謂熱壓接部,不僅指由加熱產生之構成 纖維之壓接部’亦包括由超音波產生之構成纖維之壓接 部。 為了將機械延伸倍率設為上述範@,且將實施部分延伸 加工之部分設為上述範圍,如圖u所示,輥21之各凸部 210中,輥21之周面至凸部21〇之頂點為止之高度h較佳為 1〜10 mm,更佳為2〜7 mme於圓周方向上相鄰之凸部2ι〇 彼此之距離(間距P〇較佳為〇 〇1〜2〇 mm,更佳為丨〜1〇 mm ’於旋轉軸方向上相鄰之凸部21〇彼此之距離(間距 P2(未圖示))較佳為〇.〇1〜20 mm,更佳為1〜1〇 mm。輥21之 各凸部210之頂部表面形狀並無特別限制,例如可使用圓 形、多邊形、橢圓形等,各凸部210之頂部表面之面積較 佳為0.01〜500 mm2,更佳為0·1〜10 mm2»又,相鄰之各凸 部210彼此之間之各底面之面積較佳為〇〇ι〜5〇〇 mm2,更 佳為0.1〜10 mm2»又,於凸部210之邊緣部為R形狀時,於 加工時不織布不易開孔方面係較佳,作為R值,較佳為〇 2 mm〜0.5X點直徑A丨或0.5X點直徑A2。該情形時之凸部210 之表面之面積係設為R之中間點(自上面對凸部進行投 156621.doc -39- 201224239 影)。部分機械延伸倍率亦同樣地由t間點求出。 進而+織布之熱堡接部(由麗花等產生之熱溶接部等) 門距與對輥21、22之凸部210之間距之比的關係(不 織布之熱堡接部之間距/凸部之間距)為〇 〇5〜〇刀、更佳為 時於所延伸之部分存在不織布之熱壓接部的可能 \提间S1此’熱壓接部發生變形而變得柔軟,同時於不 織布之熱壓接部之周邊部易形成由延伸產生之弱化點因 而於如下方面較佳:易利用較輕之力使不織布之表面起 獲得起毛纖維較短者,獲得不易形成毛球且肌膚觸感 良好者。此處,不織布之熱壓接部之間距與一對輥21、22 之凸部2U)之間距之比的較佳範圍,滿足不織布於md方向 上之熱壓接部之間距與一對輥2丨、22之凸部2〗〇於圆周方 向上之間距P〗之比、及不織布於CD*向上之熱壓接部之間 距與對輥21、22之凸部210於旋轉軸方向上之間距p2之 比之任一方即可,較佳為滿足雙方。 輥22之各凹部220如圖1〇、圖丨丨所示,配置於與輥21之 各凸部210對應之位置^為了將機械延伸倍率設為上述範 圍,且將實施部分延伸加工之部分設為上述範圍,如圖i j 所示,輥21之各凸部210與輥22之各凸部之嚙合深度D(各 凸部210與各凹部220重疊之部分之長度)較佳為〇1〜1〇 mm,更佳為1〜8 mm。於輥21之凸部210之頂部與輥22之凹 部220之底部之間供給不織布4時,以不夾持不織布4之方 式空開間隔時,不織布4不會變硬,故而較佳。 又,部分延伸加工部2如圖1〇所示,於鋼模壓花輥23之 156621.doc -40· 201224239 上游側及下游側具備搬送不織布4之搬送輥24、25 ^不織 布4之搬送速度V1係由加工裝置1所具備之控制部(未圖示) 所控制。此處,所謂不織布4之搬送速度V1,係指自不織 布4之輥抽出之不織布4表面之速度。 起毛加工部3係使經部分延伸加工之不織布4,之構成纖 維41起毛的部分,本實施形態之加工裝置丨如圖12所示, 具備周面設置有凸部31〇之凸輥31。凸輥31係鋁合金或鋼 鐵等金屬性之圓筒形狀者。凸輥31藉由向其旋轉軸傳遞來 自驅動機構(未圖示)之驅動力而旋轉。凸輥31之旋轉速度 (圓周速度V4)係由加工裝置丨所具備之控制部(未圖示)所控 制。此處,所謂凸輥31之圓周速度V4,與輥21、22之圓周 速度V2同樣地表示凸輥31表面之速度。 起毛加工部3如圖12所示,於凸輥3 1之上游側及下游側 具備搬送不織布4,之搬送輥32、33。經延伸加工之不織布 4·之搬送速度V3係由加工裝置丨所具備之控制部(未圖示)所 控制。此處’所謂經延伸加工之不織布4,之搬送速度V3, 與延伸加工前之不織布4之搬送速度V1同樣地表示供於凸 輥31之不織布4’表面之速度。 關於凸輥31之各凸部310,凸輥31之周面至凸部310之頂 點為止之高度較佳為0.01〜3 mm,更佳為〇.〇1〜1 mm。於圓 周方向上相鄰之凸部310彼此之距離(間距)較佳為〇.〇卜% mm ’更佳為0.01〜3 mm ’於旋轉軸方向上相鄰之凸部31〇 彼此之距離(間距)較佳為0.01〜30 mm,更佳為0.01〜3 mm ^凸部之密度較佳為500〜5000個/cm2時,於起毛之作 I56621.doc •41 · 201224239 用點增多,獲得起毛量較多之不織布方面較佳。凸輥31之 各凸部310之頂部表面之形狀並無特別限制,例如可使用 圓形、多邊形、摘圓形等’纟凸部31〇之頂部表面之面積 較佳為0.001~20mm2’更佳為〇.01〜lmm2。 本實施形態之加工裝置!中,就使經部分延伸加工之不 織布4’之構成.纖維41更有效率地起毛之觀點而$,較佳為 如圖12所示,將凸㈣之下游側之搬送㈣之位置設定為 高於凸輥3丨之位置,經延伸加卫之不織料㈣〜蘭之抱 角α與凸輥31之接觸面相接觸,更佳為以3〇〜12〇。之抱“ 相接觸。再者,於本實施形態之加m中係以成為 抱角α之方式改變凸輥31與搬送較33之位置,亦可不改 變。 本實施形態之加工裝置1如上所述,具備控制部(未 示),該控制部依據規定之運作順序,對基於一對_ 22之驅動機構的圓周速度V2、基於凸輥之驅動機構的 周速度V4、基於由張力檢測器產生之張力之檢測的不織 4之搬送速度V1、及基於由張力檢測器產生之張力之檢: 的經延伸h之不織布4,之搬送速度v3進行速度控制。 其次’針對本發明之不織. ,A布之製每方法之一實施態樣 :用上述本貫施形態之加工農置!,一邊 _ 邊進行説明。 明之不織布之製造方法首先係於机以下之溫度Ί 匆別對不織布4之複數處實 樣中,如_所示,自輥伸加工。於本實施1 捲出作為原料之帶狀不織布4,矛 156621.doc •42· 201224239 用搬送輥24、25將不織布4供於部分延伸加工部2所具有之 鋼模壓花輥23之一對輥21、22之間,而對不織布4實施部 分延伸加工。具體而言,將由搬送輥24、25搬送之不織布 4於圖10、圖丨丨所示之一個輥21所具有之複數個凸部21〇、 與另一個輥22所具有之複數個凹部220之間進行挾壓,藉 由該σ卩刀延伸加工,對不織布4之複數處分別於搬送方向 及與搬送方向正交之方向上實施延伸加工。如此,藉由於 搬送方向及與搬送方向正交之方向上實施延伸加工,可按 照方向抑制不織布4之斷裂強度減少。此處,所謂5〇它以 下之溫度,係指不主動地對輥21、22施加溫度,對不織布 4實施延伸加工時為常溫.換言之,就對不織布4實施延伸 加工時,不會因於不織布之構成纖維間引起熱熔接而導致 不織布4變硬之觀點而言,係指低於任何種類之構成纖維 樹脂之熔點的溫度。再者,所謂與搬送方向正交之方向, 係指與上述輥之旋轉軸方向相同之方向。 於本實施態樣中’為了良好地實施部分延伸加工,將圖 1〇所示之不織布4供於一對凹凸輥21、22之間時之供給速 度VI與一對凹凸輥21、22之圓周速度¥2之關係較佳為設 為Vl> V2,更佳為V1/V22值設為1〇5以上,尤佳為 V1/V2之值設為hl以上。再者’關於上限值,就所搬送之 不織布4不會產生鬆弛之觀點而言,較佳為之值小於 10藉由減小V1/V2 ’ S毛量會進一步增加,肌膚觸感會 提昇。 並非如本實施態樣之部分延伸加I,而是通常進行之單 156621.doc -43- 201224239 轴l伸等整體延伸之情形時,由於平滑報之圓周速度大於 ,、速度&而上述Vl/V2變得小於i,例如對於通常之纺 黏不織布,若不織布之總延伸倍率(於單軸延伸中,係由 长出)為1.3倍以上,則會導致不織布發生撕裂等。 因此’無法提高不織布之總延伸倍率,但於本實施態樣 中卩使不織布之總延伸倍率為j 3倍以上,亦不易使不 織布發生撕裂等。 本發月之不織布之製造方法繼而對經部分延伸力口工之不 織布4·實施使不織布4,之構成纖維起毛之起毛加工。於本 實施態樣令,係如圖9所示,利用搬送輥32、33將經部分 延伸加工之不織布4,搬送至周面設置有凸部310之凸輥31, 並利用圖12所示之凸輥31,使經部分延伸加工之不織布4, 之構成纖維自不織布4·之表面起毛。 於本實施態樣中,就使不織布4,之構成纖維有效率地自 不織布4'之表面起毛的觀點而言,較佳為如圖12所示,使 凸輥31之旋轉方向相對於經延伸加工之不織布4,之搬送方 Θ為反方向而}疋轉◊如此向反方向旋轉之情形時,VW3 之值為0_3~10,較佳為V4〉V3,更佳為V4/V3之值為 1.1〜10,為1_5〜5時,可實現充分之起毛且輥上纏繞之纖維 較少,故而尤佳。藉由向反方向旋轉而於圓周速度方面產 生差異,可進一步增加起毛量,提昇肌膚觸感。再者,於 凸輥31並非反方向,而是相對於經延伸加工之不織布之 搬送方向為正方向之情形時,作為經部分延伸加工之不織 布4’之搬送速度V3與凸輥31之圓周速度v4之關係,v4/V3 156621.doc •44· 201224239 之值較佳為,,更佳為ι 作為實施上述% 尤佳為2〜8。 义办1工之不織布4 布、紡黏層與熔喑思+ 例如可使用紡黏不織 角積層不端 連續長纖維的不織布,一 、、,或者包含絲束狀態之 觀點而言,較佳為使^ ^斷裂強度較高、且較薄之 庄马使用紡黏不鏰古 不織布之情形時,較佳 '' 。再者,於為上述積層 /或背面的不織布於:紡黏層配置於熔喷層之正面及 較佳為其整體由含有〇番纺黏層與炫嘴層之積層不織布, 丙烯樹脂的纖維所槿& 上之再生聚丙烯樹脂之聚 之粗細較佳為5〜3二又,上述絲束狀態之連續刪 Θ 30帥’更佳為10〜2〇帥。 就廉^貝且獲得良好之浙盧越$ 古,不總右- 膚觸感、加工適應性之觀點而 ^ 25 ’/ 2 I位面積重量較佳為10〜100 g/m2,更佳為 =二。不織布4所具有之作為熱壓接部之複數個齡Wait. The above-mentioned various kinds of resins may be used alone, and examples thereof include a mixture of two or more kinds of polyvinylidene-ethylene oxides or a mixture of two or more kinds of resins, and may be used as the long fibers constituting the nonwoven fabric 1 or Use composite fibers. As the conjugate fiber, a side by side fiber, a core sheath fiber, a sheath fiber having a eccentric crimp, a split fiber, or the like can be used. In the case of using a conjugate fiber, it is preferred to obtain a soft raised nonwoven fabric if the core comprises polypropylene and the sheath comprises polyethylene core sheath fibers. Further, as the long fibers 2, fibers having a small amount of additives such as a fiber coloring agent, an antistatic property agent, a lubricant, and a hydrophilic agent may be used. The fiber diameter of the long fiber 2 is preferably 5 to 3 Å, more preferably 10 to 2 〇 μπι, before the processing described below. From the viewpoint of spinnability, the original spunbonded nonwoven fabric constituting the nonwoven fabric 1 is preferably formed of a polypropylene resin as a polyolefin resin. As the polypropylene resin, a random copolymer containing 5 to 1% by weight, more preferably 25% by weight to 80% by weight, is preferable in terms of smoothness and improvement in the feeling of the skin and ease of breakage. Any one or more of a homopolymer and a block copolymer. Further, the copolymer or homopolymer may be mixed or mixed. Doc 201224239 In combination with other resins, it is preferably a mixture of a homopolymer of polypropylene and a random copolymer in terms of being difficult to break when formed. In this way, the crystal t of the fiber is lowered, the hair raising fiber itself becomes soft, the skin feel is good, and the non-woven fabric strength can be achieved, and the fuzzing fiber is easily cut by the embossing portion such as embossing, so that embossing is obtained. The joints such as the dots are no longer peeled off, and the fuzzing fibers become shorter, which is less likely to be cut and has a good appearance. Further, since the distribution of the melting point is widened, the sealing property is improved. Further, as the random filament based on the acryl forming, it is preferred to copolymerize with ethylene or a dilute hydrocarbon, which is particularly preferably an ethylene-propylene copolymer resin. From the same viewpoint, the polypropylene resin is preferably a resin containing 5% by weight or more, more preferably 3 to 25% by weight or more of the ethylene-propylene copolymer resin. In the ethylene-propylene copolymer resin, the ethylene concentration is preferably the weight of the Buchuan. Hey. In particular, the ethylene concentration is more preferably from 3 to 8% in terms of no adhesion, elongation at the time of elongation, less hair removal, and maintenance of breaking strength. Further, the polypropylene resin is preferably a resin containing 25% by weight or more, more preferably 50% by weight or more of recycled polypropylene resin, from the viewpoint of the environment. Further, the same applies to the case where the nonwoven fabric 1 is originally formed as a laminated non-woven fabric of the spunbonded layer and the meltblown layer. With respect to the heat-fusible portion 3 produced by the embossing, the area of each of the heat-welding portions 3 is preferably 〇 〇 5 〜 1 〇 , and more preferably 0. 1 to 1 mm2. The number of the heat seal portions 3 is preferably from 1 〇 to 25 〇 / cm 2 , more preferably from 35 to 65 / cm 2 . The distance between the centers of the heat-welded portions 3 adjacent to each other in the X direction is preferably 〇·5 to 10 mm, more preferably 3 mm, between the centers of the heat-fusible portions 3 adjacent to each other in the Y direction. The distance is preferably 〇〇156621. Doc 201224239 mm ' is preferably 1 to 3 mm. Etc.: H3T is exemplified by the use of embossing (using embossing embossing rolls and flat rolls: forming intermittently, by means of ultrasonic splicing, by applying hot air to a part of the welder, etc.) The shape of the pressure-bonding portion is preferably such that the shape of the heat-fusible portion 3 is not particularly limited, and may be, for example, any shape such as a circle, a rhombus, or a triangle. The ratio of the area to the surface area of the non-woven surface is preferably 5 to 30%, and more preferably 10 to 20% in terms of the formation of the hair ball. The nonwoven fabric i of the present embodiment is originally formed to include the long fiber 2 The spunbonded non-woven fabric is formed with a part of the long fiber 2 broken, and only one end 2〇a is fixed by the heat-welding part 3, and the fiber 20 contains the fiber 21 of the free end 2〇b. The thicker one is preferably a flat shape (elliptical or collapsed shape) of the front end portion, thereby obtaining a fluffy fiber having a soft front end and obtaining a non-woven fabric which is less irritating to the skin. Only one end portion 20a is fixed by the heat fusion portion 3 The fiber 2 includes a fiber 21 whose outer end portion 20b is thickened at the other end side and a fiber 22 whose free end portion 2b is not thickened. Here, the "free end portion" means that only one end portion 20a uses heat. The "other end portion" of the fiber 20 to be fixed by the refining portion 3 means, in other words, the "front end portion". Whether or not the free end portion 20b is thickened is determined by measuring the fiber diameter by the following measurement method, and determining the increase ratio of the tip end fiber diameter. [Measurement of fiber diameter] First, in an environment of 22 ° C and 65% RH, as shown in Fig. 5 (a), use 156621. Doc • 13· 201224239 Sharp blade cuts the measuring piece of 2 cm in the X direction and 2 cm in the γ direction from the non-woven fabric 1 measured, and passes through a plurality of heats as shown in Fig. 5(b) The sample of the welded portion 3 which is extended in the X direction by the fold line Z is folded, and as shown in FIG. 5(c), it is placed and fixed on an aluminum test for a scanning electron microscope (SEM) carrying a carbon tape. On the stage. Next, from the SEM image magnified to about 750 times, ten fibers 20 which were fixed only by the heat-shrinking portion 3 at one end portion 20a were randomly selected, and photographs were taken near the front end of the free end portions of the fibers. From the obtained photograph (see Fig. 2), the fiber diameter of the fiber 20 at a position 120 μm from the front end of the free end portion 20b (the fiber diameter 21a of the fiber 20 other than the free end portion 20b) was measured. The slope of the fiber diameter 2 la of the fiber 20 other than the free end portion 20b was measured to be parallel to the free end portion 20b side, and the position between the front end of the free end portion 2〇b and the front end portion of 20 μηι was measured. The fiber diameter of the fiber 21 at the most coarse position in the region of the clip (the fiber diameter 21b of the fiber 21 of the free end portion 20b). Further, in the case where the front end portion is flat, depending on the observation angle, there is also a case where the front end is not coarsened. In this case, the fiber 21 obtained by the so-called free end portion 20b is directly measured by the obtained photograph. The fiber which satisfies the following conditions among the 10 fibers 20 which were randomly selected before: the fiber diameter of the fiber 2〇 of the free end portion 2〇b measured from the photograph of the 10 fibers 20, respectively, according to the following formula (1) 21b, the fiber diameter 2丨3 of the fiber 2〇 except the free end portion 20b is obtained by the fiber diameter 2丨3, and the value of the increase ratio of the fiber diameter at the front end is 15% or more; it is suppressed between the heat-welding portions 3 (except heat fusion) The cutting of the fibers of the fiber portion other than the boundary between the portion 3 and the fiber, and the reduction of the breaking strength are obtained. Doc 201224239 It is better to have a good touch on the skin. The value of the increase ratio is preferably 2〇〇/0 or more, more preferably 25% or more. Increase in front end fiber ( (4) (%) = [(2 (4) a) + 2ia) x _ (1) In the non-woven fabric 1 'from the point of view of the skin feel and breaking strength & 'only one end 2 〇 3 using the heat splicing joint 3 The ratio of the fibers 21 which are fixed to the fiber 20 (the fiber 21 whose free end is P2〇b coarsened and the fiber 22 which is not thickened at the free end portion 20b) is preferably coarsened and coarsened. % thought 30/. Above, it is particularly preferably 4% or more. The ratio of the fibers 21 which are thickened at the free end portion 2 (10) is calculated from the above-mentioned fiber diameter measurement method, and the randomly selected fiber 2 is enlarged to about 750 times, and the increase ratio of the front end fiber and the level is calculated as the image is calculated. The ratio of the fiber to the end of the bird. The nonwoven fabric 13 has fibers cut at the peripheral portion of the heat-welded portion 3. With respect to the heat-fusible portion 3 of the nonwoven fabric 1, the boundary between the peripheral portion (from the heat-welded portion 3 and the long fiber) of the randomly selected hot-melt joint portion 3 to the outside and inside (10) μm is observed by an electron microscope. In the case where the counted fiber is cut (the shape of the fiber of the embossed portion is collapsed by the shape of the house and the portion which is not collapsed and is still a part of the fiber shape), if the fiber is cut off If the number is large, the nonwoven fabric is cut only on the outermost surface, and the bristles are not more woven than the rupture strength. Preferably, the nonwoven fabric is cut at three or more places, and more preferably five to 15 Non-woven fabric that has been cut. The non-woven fabric 1 has a ring-shaped fiber 23 that rises in a ring shape between the heat-dissolving portions 3 and 3. As shown in the figure, the ring-shaped fiber is 156621. . Doc -15· 201224239 In the measurement method of the above fiber diameter, when viewed as shown in Fig. 5(c), the other end portion side does not have the free end portion 20b' and the distance is the finger line Z 0. Fibers raised above 5 mm. In the present embodiment, the term "annular fiber 23" means the above-mentioned ring-shaped fiber. The fiber constituting the nonwoven fabric i of the present embodiment has the fiber 20 in which only the one end portion 20a of the fiber 21 whose free end portion 20b is thickened and the fiber 22 whose free end portion 2b is not thickened is fixed by the heat fusion portion 3, and The fibers 23 other than the fibers 20 are formed in a ring-shaped annular shape between the heat-fusible portions 3 and 3. In the fiber constituting the non-woven fabric 1, only the fiber 1 of the non-woven fabric 1 is fixed by the heat-welding portion 3 and the ring shape is used for the non-woven fabric 1 to prevent the uncomfortable feeling. The ratio of the annular fibers 23 in the total number of the fibers 23 is preferably less than 5% by weight, more preferably 45% or less, still more preferably 40% or less. The ratio of the annular fibers 23 is determined by randomly selecting one fiber from the SEM image magnified about 5 times in the above fiber diameter measurement method, and randomly selecting one fiber from the root. The fiber 2 〇 (the fiber 21 in which the free end portion 20b is thickened, the fiber 22 in which the free end portion 2 〇 b is not thickened) and the ring-shaped fiber 23 are extracted from the one end portion 20a by the heat-welding portion 3, and the ring-shaped fiber 23 is calculated. The ratio of fibers 23 (annular fibers) in the total number of fibers, fibers 22, and fibers 23. Further, the ratio was obtained from 9 points of the SEM image of the other portion in the same manner, and the average value at the 1 〇 was calculated as the measured value. Further, in the case where one of the randomly selected fibers has one ring-shaped fiber 23, the ring-shaped fiber 23 is counted as a root. In the nonwoven fabric 1, by the fiber containing the relative increase in the degree of freedom, the gap between the fibers is filled, and the roughness of the surface is made small and smooth. The wider the distribution (dispersion) of the fiber diameter, from the viewpoint of improving the touch of the skin 156621. Doc •16· 201224239 The better, in terms of skin touch, if it is 〇. If it is 33 or more, it will be fully satisfied. If it is 〇·35 or more, the effect of the step is satisfied. There is no particular upper limit to the distribution (dispersion) of the fiber diameter, and it is preferably 1 or less. More preferably, the fiber diameter distribution (dispersion) is 0. 35~〇. 9. Here, the distribution (dispersion degree) of the fiber diameter means the distribution (dispersion degree) of the fiber diameter of all the fibers constituting the nonwoven fabric 1, and the fiber 20 and the ring which are fixed only by the heat-welding portion 3 at one end portion 2〇a. The fibers 23 and the fibers whose both ends are fixed by the heat-fusible portion 3 and which are not erected in a % shape (fibers which are not affected by the following processing) are distributed as a whole. The distribution (dispersion) of the fiber diameter was measured by the following method. Method for measuring fiber diameter [Measurement of distribution of fiber diameter (dispersion)] First, in a 22 C, 653⁄4 RH environment, a sharp razor is used to cut 2 mm in the X direction from the non-woven fabric 1 measured. The measurement piece having a size of 2 cm in the direction was directly placed and fixed on an aluminum sample stage for a scanning electron microscope (SEM) carrying a carbon tape without bending it. Next, one 〇 root fiber was randomly extracted from the SEM image enlarged to about 750 times, and the respective fiber diameters of the portions other than the free end portion 20b were measured (further, the non-woven fabric 1 measured was originally formed into a spunbond layer and melted. In the case where the laminate of the spray layer is not woven, the fibers of the meltblown layer are not selected, and only the fibers of the spunbond layer are selected. On the above-mentioned aluminum sample stage, the fiber diameter of the root was measured by the above method, and the fiber diameter of 10 pieces was measured (1 wide (11 ()), the average value dave was obtained, according to the following formula (2) 'The distribution of the fiber diameters of the 10 randomly selected fibers from the 10 fiber diameters di~di〇 and the average value obtained. The unit is set to pm, with 0. The decomposition of 1 μηη can be measured. Make 6 above for each piece of non-woven fabric. 156621. Doc •17· 201224239 The average sample (see the following formula (3)) of the distribution of the fiber diameters of the one-twist fibers obtained in each place is set as the distribution of the fiber diameters in the nonwoven fabric 1 . Furthermore, the calculation of the distribution of the fiber diameter of the '10 fibers was performed using the VARPA function in Microsoft Corporation's spreadsheet software excel 2003. 1 fiber diameter of the root fiber 2*m=[(d1-dave)2+(d2-dave)2+. . . (dHr dave) )] / 1 0 (2) The distribution of the fiber diameter (dispersion) in the nonwoven fabric 1 = (the sum of the distributions of the fiber diameters of the 10 fibers obtained by the above formula (2)) / 6 ( 3) From the viewpoint that the touch of the skin is good, the raised fiber of the non-woven fabric is preferably 8 pieces/cm or more, more preferably 12 pieces/(; 〇1 or more. Further, the breaking strength of the filling blade is obtained. In view of the above, the upper limit is preferably i 〇〇 / cm or less, more preferably 4 〇 / cm or less in terms of the appearance of pilling. The raised fibers are determined by the following measurement method. [Measurement method] Fig. 6 is a schematic view showing a method of measuring the number of raised fibers in the fibers constituting the nonwoven fabric i in an environment of 22t and 65% RH. First, a sharp razor is used to cut 2 自 from the measured non-woven fabric. The measuring piece of cmx2〇cm, such as the 4F of the test piece (4), is folded in the raised surface of the measuring piece to form the measuring sample m 104. Secondly, the measuring sample 1〇4 is placed on the A4 size black backing paper as shown in Fig. 6 ( b) No, and then placed on the A4 size black backing paper with a length of 1 丄 (10). At this time, as shown in Figure 6(b) In the case of the self-side..., the color lining paper hole 〇7 can be measured and measured in the way of the sample line. The two lining paper system ❹ Fuji Gonghe Paper Co., Ltd. has a weight of 265 g. The upper side of the paper liner hole 156621. On both sides of the doc 201224239 107, respectively, 5 cm to the outside along the fold line 105, respectively, a 50 g knot code is placed to form a state in which the measurement sample 104 is completely folded. Next, as shown in Fig. 6(c), 'Using a microscope (VHX-900, manufactured by KEYENCE Corporation)', the inside of the rim of the lining paper was observed at a magnification of 30 times, and the fluffing was measured every 1 cm of the imaginary line 108. The number of fibers, the imaginary line ι 8 is formed at a position shifted upward by 〇·2 mm from the fold line 105 of the sample 104. The measurement was performed at 9 places, and the average value (rounded by the second decimal place) was set as the fluffing fiber. Further, when the number of the raised fibers is counted, for example, as in the case of the fiber 16a shown in Fig. 6(c), there is a case where the imaginary line 1〇8 which is located 2 mm above the fold line 1〇5 is traversed twice. This fiber counts as two. Specifically, in the example shown in FIG. 6(c), there are four fibers in which the imaginary line 1〇8 is traversed i times, and the imaginary line 1〇8 is traversed twice in the fiber (7). The number of fibers that are crossed twice is 1〇6& and the number of fibers that count as two 'pillings' is six. From the viewpoint of improving the feel of the skin, the average fiber diameter of the non-woven fabric of the raised fibers (the fibers crossing the imaginary line 108) is preferably smaller than the surface fibers of the uncovered portion of the same surface (not crossing the imaginary line 1〇8). The average fiber diameter of the fiber that does not reach the imaginary line 1〇8). The average fiber diameter refers to a fiber diameter obtained by measuring the fiber diameter of each of the raised fibers and the unpilled fibers by a microscope (optical microscope, SEM, or the like). The fiber diameter of the raised fiber is preferably 97% to 40% of the unpilled fiber, and more preferably 90% to 40% in terms of excellent skin feel, and it is difficult to form a hair ball, easy to remove hair, and appearance. From a softer and better point of view, the height of the raised fibers of the non-woven fabric is preferably 15 claws to 156621. Doc -19- 201224239 下' is better for G. 8 mm or less. From the above point of view, the lower the height of the raised fibers, the better, but. ·After 2 mm or more, the skin feels fully satisfied: In addition, in addition to the breaking strength, the height of the raised fiber is 1. 5 Å or less and the raised fibers are preferably 8 / top. Further, in terms of being less entangled in the skin and having a better feeling, the height of the raised fibers is preferably 0. 5 mm or less and raised fibers should be 15 / (5111 or more. Here, the height of the fiber, different from the length of the fiber, refers to the height of the fiber in the natural state in which the fiber is not stretched when measuring the fiber. When the value of the length is large or the rigidity of the fiber is high, the height of the raised fibers tends to increase. The height of the raised fibers is measured by the following measurement method. The height of the raised fibers is determined by measuring the number of raised fibers. Specifically, as shown in Fig. 6(c), the inside of the hole 1〇7 of the liner was observed from the fold line 105, and was streaked in parallel every 0·05 mm until it no longer intersected with the raised fibers. Secondly, compared with the number of the raised fibers measured by the above method (determined according to the imaginary line 1〇8 located at 〇·2 mm above), the fibers intersecting the parallel lines reach half of the parallel lines, The distance from the line to the fold line is set as the raising height. The above-mentioned operation is performed on the three non-woven fabrics measured, and the average value of the total of nine places in three places and three pieces is set to the height of the raised fibers. Skin touch For different aspect, the height of raised fibers, and further fiber nonwoven fluff bulk softness of the i (Bulk s〇ftness) is preferably 8. 0 cN or less. It is preferably 0 in terms of being a soft person such as a baby or a toddler. 5~3. 〇 cN. The bulk softness is measured by the following measurement method. 156621. Doc •20- 201224239 [Method for measuring bulk softness] The softness of non-woven fabric I is in the environment of 22〇c and 65% RH, and it is cut in the MD direction by 150 mm and in the CD direction by 3〇mm. Non-woven j, using a stapler to pin the upper and lower ends, and make a ring shape with a diameter of 45 mm. At this time, the core of the stapler is configured to be elongated in the MD direction. Using a tensile tester (for example, Tensilon "RTA_100" manufactured by 〇rientec Co., Ltd.), the above-mentioned ring is formed into a cylindrical shape on the sample stage, and a flat plate substantially parallel to the table is used at a compression speed of 1 The speed of 〇mm/min was compressed from above, and the maximum load at this time was measured as the bulk softness in the CD direction. Next, the MD direction and the CD direction were changed to form a circular ring, and the bulk softness in the MD direction was measured in the same manner. Two rings were prepared and measured in the MD direction and the cD direction, and the average of the CD directions and directions was set to the softness of the nonwoven fabric. The effect of the present invention is more effective if the original spunbond nonwoven fabric forming the nonwoven fabric 1 is kneaded or coated with a softener. As the softening agent, for example, a wax emulsion, a reactive softener, a polyoxyxene system, a surfactant, or the like can be used. It is especially preferred to use an amine group-containing polyfluorene oxide, an oxyalkylene group-containing polyfluorene oxide, and a surfactant. As the surfactant, a carboxylate-based anionic surfactant, a sulfonate-based anionic surfactant, a sulfate-based anionic surfactant, and a phosphate-based anionic surfactant can be used (especially Alkyl phosphate salt. Anionic surfactant; sorbitan fatty acid ester, diethylene glycol monostearate, diethylene glycol monooleate, glyceryl monostearate, glycerol monooleate, propylene glycol single hard Polyol monoester fatty acid ester such as fatty acid ester, N-(3-oleomethoxy-2-hydroxypropyl) diethanolamine, polyoxy 156621. Doc -21 - 201224239 Ethylene hardened t sesame oil, polyoxyethylene sorbitol bee fiber, polyoxyethylene alcohol needle sesquisulfate, polyoxyethylene oleic acid cool, polyoxyethylene mountain half Sugar alcohol needle sesquisulphate, polyoxyethylene glycerol monooleate, polyoxyethylene monostearate, polyoxyethylene monolaurate, polyoxyethylene monooleate, polyoxyethylene Recording 躐 喊 shouting, gathering gas r, 曰 曰 4 soil # a丨μ not rolling non-ionic surfactants such as ethylene lauryl ether; 4-level ammonium salt, amine salt or amine and other cationic surfactant; containing carboxyl, indeed A zwitterionic surfactant such as an acid or an aliphatic derivative of a sulfate or a third-order amine or an aliphatic derivative of a heterocyclic 2- or tertiary amine. Further, it is also possible to add a known chemical agent as a secondary additive (a small amount of a component) to the softening agent of the present invention as needed. By containing a softening agent, the skin feels good, the hair removal property is small, and the surface is less rubbed against the skin. The breaking strength is also high, and the effect is particularly high in the present invention. The softening agent is preferably used in combination with the above-mentioned random copolymer described above for further enhancing the effect, and the softening agent can reduce the stickiness of the raised fibers caused by the random copolymer to obtain a smooth skin feel. Especially good. Moreover, the non-woven fabric 1 is originally formed into a laminated non-woven fabric of the following spunbond layer and the melt-blown layer, and the spunbonded layer of the laminated non-woven fabric comprises a plurality of layers, for example, spunbond, melt-blown-spun-bonded layer non-woven fabric, spunbond-spun In the case of a viscous melt-jet-spun non-woven fabric or the like, it is preferred to knead the softener in only one layer of the spunbond layer, or to knead the entire spunbond layer. In the case where the softening agent is kneaded in a layer of the spunbond layer, the following treatment is carried out on the side of the layer to provide a fiber having a free end portion, which is preferable in terms of good touch and fracture strength. ◊ So, it is easy to adjust the skin feel or breaking strength 156621. Doc •22· 201224239 In terms of surface, it is better to form a laminated non-woven fabric originally formed as a spunbond layer and a meltblown layer, as compared with the case where the nonwoven fabric i is originally formed as a spunbonded nonwoven fabric. Next, a preferred manufacturing method for manufacturing a non-woven fabric according to the present invention, which is a manufacturing method for manufacturing a n-woven fabric, with reference to Figs. 3 and 4, is roughly divided into a pre-processed portion 4 and disposed on The raised portion 5 on the downstream side of the pre-processing section. As shown in Fig. 3, the pre-machined portion 4 includes a steel mold embossing member provided with a convex portion 410 and a concave portion 420 which are mutually engaged with each other on the circumferential surface. As shown in Fig. 3, the steel mold embossing roller 43 a plurality of convex portions 41 设置 provided on the circumferential surface of the roller 41 and a plurality of concave portions 420 provided on the circumferential surface of the roller 42 are formed in a merging manner, so that the plurality of convex portions 41 〇 are uniformly and regularly arranged In the direction of the rotation axis and the circumferential direction of the parent 41, the pair of rollers 41 and 42 are meshed by transmitting a driving force from a drive mechanism (not shown) to one of the rotary shafts. Further, the pre-processed portion 4 is, for example, for example. As shown in Fig. 3, on the upstream side and the downstream side of the steel mold embossing roll, a conveying roller 44 and a crucible for conveying the raw material non-woven fabric 1 are provided. With respect to each convex portion 410 of the roller 41, the height from the circumferential surface of the roller 41 to the apex of the convex portion 41 is preferably 1 to 10 mm, more preferably 2 to 7 mm. The distance (pitch) between the adjacent convex portions 410 in the direction of the rotation axis is preferably 〇〇1 to 2 〇, more preferably 1 to 10 mm, and the distance between the adjacent convex portions 41 圆周 in the circumferential direction ( The pitch is preferably 0. 01~20 mm, more preferably 1〇mm. The shape of the top surface of each convex portion 410 of the roller 41 is not particularly limited. For example, a circular shape of a polygon, an ellipse or the like may be used, and the area of the top surface of each convex portion 41 is preferably 〇. 01~500 mm2, more preferably 0. 1 to 10 mm2. Each of the concave portions 420 of the roller 42 is disposed at a position corresponding to each convex portion 41 of the roller 41. Roll ο each convex 156621. Doc -23- 201224239 The depth of engagement of each of the recesses 420 of the portion 410 and the roller 42 (the length of the portion where each convex portion 410 overlaps each of the concave portions 420) is preferably 0. 1 to 10 mm, more preferably 1 to 5, as shown in Fig. 4, the raised portion 5 is provided with a convex portion 51 1 ' having a convex portion 51 on the circumferential surface thereof, and is provided on the upstream side and the downstream side of the convex roller 5 The raw materials are not woven by the transfer rollers 52 and 53. The convex roller 51 is rotated by transmitting a driving force from a driving mechanism (not shown) to its rotating shaft. Regarding each convex portion 510 of the convex roller 51, the height from the circumferential surface of the convex roller 51 to the apex of the convex portion 51 is preferably 〇1 to 3 mm, more preferably 〇1 to 〇^ claw. The distance (pitch) between the convex portions 51 adjacent to each other in the direction of the rotation axis is preferably 0. 1 to 50 mm, more preferably ojy mm, the distance (pitch) between the adjacent convex portions 51 于 in the circumferential direction is preferably 〇丨 5 5 mm, more preferably 〇丄 mm. The shape of the top surface of each convex portion 51 of the convex roller 51 is not particularly limited. For example, a circular shape, a polygonal shape, an elliptical shape, or the like can be used, and the area of the top surface of each convex portion 5i〇j is preferably 〇·〇〇1. 〜2〇mm2, more preferably 〇〇ι~mm2 ° In the manufacturing apparatus of the pre-processed part 4 and the raised processing part 5 which have such a structure, the strip-shaped spunbonded nonwoven fabric which is the raw material of the nonwoven fabric i ( The raw material non-woven fabric 1) is unwound from a roll (not shown), and the raw material non-woven fabric is transported to the steel mold (four) roll 43 by the transfer of the light material, and the (four) and a are in the pre-processed portion 4, such as As shown in Fig. 3, the raw material is not woven between the pair of sticks 41 and 42, and the raw material nonwoven fabric 10 is damaged. When the damage is applied, it is not caused by the (four) connection between the constituent fibers of the spunbonded nonwoven fabric. The pair of rolls 41, 42 of the steel mold embossing roll 43 is preferably not actively added. Doc •24· 201224239 The steel is embossed at a temperature lower than the melting point of the component having the lowest melting point among the fiber components constituting the raw material non-woven fabric 10, in particular, at a lower temperature (10) or more lower than the melting point. Next, the damaged raw material non-woven fabric is conveyed to the convex roller 51 provided with the convex portion 510 on the circumferential surface by the conveyance reports 52 and 53. In the raising process, the surface of the damaged raw material non-woven fabric 1 () is processed by the convexity 51, and the long fiber 2 constituting the spunbonded nonwoven fabric is partially broken to form a spunbond nonwoven fabric having only one end portion. The non-woven fabric U of the fiber (9) to which the joint portion 3 is fixed is referred to FIG. In order to partially break the long fibers 2 and efficiently form the fibers 20 shown in Fig. 1, it is preferable that the direction of rotation of the convex rolls is reversed with respect to the conveying direction of the raw material non-woven fabric 1Gi. When the rotation is preferably rotated at a speed of 〇·3 to H times the conveyance speed of the raw material non-woven fabric 1 and rotated in the circumferential direction (clockwise with respect to the two-feed direction), It is preferable to rotate (four) 51 at a speed of 15 to 2 times. Here, the speed of the convex pro 51 refers to the peripheral speed of the convex (four). It is more efficient to partially break the long fiber 2 and form a map more efficiently. From the viewpoint of the fiber 20 shown in Fig. 1, it is preferable to set the position of the conveying roller 53 to be higher than that of the convex roller 51 as shown in Fig. 4, and to make the damaged raw material non-woven fabric 10' 10 to 180. The contact with the contact surface of the convex roller 51 is 30 to 120. The contact angle α is controlled to prevent the width reduction caused by the shrinkage of the nonwoven fabric, so that it is more preferable. Further, only one end portion 2a is formed on both surfaces of the nonwoven fabric 1. In the case of the fiber 20 fixed by the heat fusion joint 3 By using another-convex roll ^ 156621. Doc -25- 201224239 After processing, it is possible to obtain a front surface (back surface) different from the surface of the raw material non-woven fabric processed by the convex roller 51. The inventors of the present invention presume that the fiber 20 is formed by stretching the spunbonded nonwoven fabric (raw material non-woven fabric 1) by the steel mold embossing roll 43, and forming a weakening point in the heat-welded portion 3 of the spunbonded nonwoven fabric (raw material non-woven fabric 10). Thereafter, the long fibers 2 are broken by the convex roller 51 from the weakened point of the outermost surface of the heat-welded portion 3 of the non-woven fabric, and the fibers cut by the heat-welding portion 3 are formed. The inventors of the present invention presume that the fibers 21 which are cut by the heat-sealed portion 3 and whose fiber end portions 2b are thickened. Further, the inventors of the present invention presume that the long fibers 2 are peeled off from the weakened portion of the heat-welded portion 3 by the convex rolls 51, and the fibers which are peeled off from the heat-sealed portion 3 form the heat-fusible portions 3 and 3 which are erected in a ring shape. The ring-shaped fiber 23. Further, the inventors have estimated that when the surface is processed by the convex roller 51, the long fibers 2 are broken between the heat-welded portions 3, 3 to form the fibers 22 whose free end portions 2b are not coarsened. The nonwoven fabric produced by the above preferred method for producing a nonwoven fabric of the present invention is characterized in that the ratio of the loop-shaped fibers 23 and the unconsolidated fibers 22 is small as compared with the nonwoven fabric produced by the prior raising method. If a large number of unconsolidated fibers 22' exist as in the non-woven fabric produced by the previous raising method, the heat-welded portion 3 between the embossed portion and the embossed portion may be broken, and between the heat-welded portions 3 By forming a so-called slit (fracture, pore) β, it is possible to fluff the fiber without scratching the base of the unpilling, and to obtain a higher breaking strength. On the contrary, when fluffing in a state where no weakening point is formed, it is difficult to cause the fiber to fluff if it is not rubbed with a stronger force, and scratching is caused when the fiber is raised to the base other than the outermost surface which is not raised. Therefore, the nonwoven fabric is easily broken as a whole, and it is difficult to maintain strength. Another aspect, by the above mentioned 156621. Doc • 26- 201224239 The non-woven fabric produced by the preferred manufacturing method of the non-woven fabric 1 of the month 2 has a small breaking ratio because of the fact that the ratio of the fibers 22 which are not coarsened is small. Further, when such a nonwoven fabric is used for a package other than a pant-type disposable diaper, the following advantages are obtained: if the diaper is pulled up when it is worn, it is not easy to tear (the piercing strength is relatively high) In the case of a panty-type seal, when the diaper is taken off, sometimes the side is torn off. =: :! Non-woven fabric is not easy to tear the diaper laterally, and the crepe is obtained. Also, if no weakening point is formed When the hair is raised, the fiber is peeled off from the hot material portion, the number of the raised fibers is reduced, and the raising height tends to increase. ^There is a tendency to easily form fluff and the like, and the steel mold embossing roll 43 is used. The fiber between the heat-welding portion 3 and the heat-melting portion 3 extends, and at the same time, a weakening point is easily formed at the peripheral portion of the heat-welding portion 3. The adjustment of the weakening point can be performed by the steel mold and the upper-down roller 41, 42 The weakening point is easy to form a shorter fiber length between the joint portion and the joint portion in the extending direction. The straw is formed by forming the weakened point, and the bristle processing portion is formed. When the hair is raised, the fiber is easily cut off from the weakened point '(4) The field wheel material is used for obtaining a raised non-woven fabric which is excellent in muscle sensation, has no obvious appearance, is not easy to form a hair ball, and has a high breaking strength. (4) By extending the fiber between the heat-welding portions 3, the fiber Thinning, ... the tower is connected to the father, the, the field, and the heat-sealed portion 3 is also softened, and the non-woven fabric having a good touch is obtained. In particular, the steel waste roller 43 is used to make the fibers extend finely. The elongation is longer, thereby increasing the distance between the fibers, and improving the gas permeability. Further, by using the raising portion 5, 15662l is used. Doc • 27.  201224239 Hair treatment The bulk density of the raised fibers is reduced, so that even the non-woven fabrics of the same basis weight are more breathable. As described above, by the extension and raising treatment of the combined fibers, it is improved to 12~2q times better than the original non-woven fabric. The air permeability was determined by measuring the reciprocal of the gas permeability resistance 1 using an automatic gas permeability tester (AUTOMATIC AIR-PERMEABILITY TESTER) KES-F8-AP1 manufactured by Kat0 Tech. The air permeability of the obtained woven fabric is preferably 24 m/(kPa.  s) above. As a raw material that is both good in touch and air permeability, it is preferably a non-woven fabric of non-woven fabric, preferably composed of a melt-free layer and only a layer of spunbond (for example, spunbonded_spunbond_spunbond). Not woven. Hereinafter, the effect of the use of the nonwoven fabric of the embodiment of the present invention described above will be described. In the nonwoven fabric of the present embodiment, as shown in Fig. 2, a part of the long fibers 2 is broken, and only one end portion 20a is fixed by the heat-welding portion 3. Since the fiber 20 is formed, it is possible to impart a soft feeling to the entire nonwoven fabric 1. Further, since only a part of the long fibers 2 is not broken, the breaking strength can be maintained to a high level similar to that of the original spunbonded nonwoven fabric. Further, as shown in Fig. 1, the fiber 2 of the non-woven fabric 1 of the present embodiment includes the fiber 21 whose free end portion 20b is thick. Since the fiber 21 having the free end portion 2〇b is thickened, the free end portion 20b does not cause tingling, and it is difficult to get stuck in the skin, and the skin feels good. Further, the fiber 21 having the free end portion 2〇b becomes thick, and the free end portion 20b side is liable to hang down, and becomes smooth, so that the skin feels good. 156621. Doc •28- 201224239 Spunbonded non-woven fabrics or _ laminate* woven fabrics have a low softness in the past, and have a poorer touch on the skin than the non-woven fabrics produced by the hot air method. According to the nonwoven fabric 1' of the present embodiment, the non-woven fabric of the spunbonded layer and the melt-sprayed layer can have flexibility in addition to the light/moon property of Japan, and the skin feel can be greatly improved. The use range of the non-woven fabric 1 is mainly suitable for use as a constituent member in absorbent articles such as disposable diapers and sanitary napkins. Examples of the constituent member include a front sheet, a back sheet, and a sheet constituting the outer body. Further, the use range of the nonwoven fabric 1 is also suitable for the sheet for cleaning. Hereinafter, a disposable diaper using the nonwoven fabric 1 will be specifically described. As shown in Fig. 7, the pull-on disposable diaper 100 includes an absorbent body 50 including an absorbent body 4, and a non-skin contact surface side of the absorbent body 5, and is fixed to the absorbent body 5 6〇. As shown in FIG. 8, the absorbent body 50 has a liquid-permeable front sheet 70, a liquid-impermeable (including water-repellent) back sheet 8〇, and a space between the two sheets 70 and 80. The liquid-retaining absorbent body 4 is substantially longitudinally long. The outer covering member 60 has a back side portion a disposed on the back side of the wearer, a belly side portion B disposed on the front side of the wearer, and is disposed between the crotch portion C and the back side portion A and the abdomen. The side edges 6a and 61 of the side portion B are joined to each other, and a pair of side seal portions (not shown), a pair of leg opening portions (not shown), and a waist opening portion are formed (not shown, 60 has an outer layer sheet 62 forming the outer surface of the diaper, the inner layer sheet 61' on the side of the skin contacting surface and partially joined to the outer layer sheet 62 to form the waist opening portion and the waist portion of the leg opening portion 156621. Doc -29· 201224239 Two parts of the leg and the leg part 6d; ί#61, _, the (4) waist elastic member 63 and the leg elastic member 64 are formed. As shown in Fig. 7, the absorbent body 50 is disposed on the back side portion 8 of the outer covering member 6 to the front side portion, and the both ends of the absorbent body 50 in the longitudinal direction are located in the longitudinal direction of the outer covering member 60. < The position where both end portions retreat toward the inner side in the longitudinal direction. The absorbent body 50, as shown in FIG. 8, the non-skin contact surface of the back surface moon 80 of the absorbent body 5 is bonded to the inner layer of the outer covering 60 by a bonding method using an adhesive, heat sealing, ultrasonic sealing or the like. The skin contacting surface of the sheet 61 is joined. As shown in Fig. 7, both side portions in the longitudinal direction of the absorbent main body 50 are provided with side flanges 55 and 55 which are made of liquid impermeable or water permeable and gas permeable material. An elastic member 56 for forming a side flange is fixed in an extended state in the vicinity of the free end portion of each of the side flanges 55. The side cuffs 55 prevent the free end side from rising when the diaper is worn, resulting in the discharge of excrement into the width direction of the absorbent body 5''. The sheet for forming the side flange 55 is as shown in Fig. 8. The portion 55a of the predetermined width in the width direction of the absorbent body 50 is wound around the non-skin contact surface side of the absorbent body 4, and is fixed to the absorbent body. Between the back sheets 80. Further, the portion 55a of the predetermined width may be fixed between the back sheet 30 and the outer covering 6?. The nonwoven fabric of the present invention can be preferably used as the outer layer sheet 62. Further, the raised nonwoven fabric of the present invention can also be used as the front sheet 70, the back sheet 80, the side flap 55 forming sheet, and the inner sheet 61. The member of each part when the non-woven fabric of the present invention is not used can be used without any particular limitation for an absorbent article such as a disposable diaper. For example, as the front sheet 70, a liquid-permeable non-woven fabric, an apertured film, or a laminate or the like can be used as the back sheet 80', and a resin film or a laminate of a resin film and a non-woven fabric can be used as the back sheet 80'. As the sheet for forming the side flange 55, a stretchable film, a nonwoven fabric, a woven fabric, or the like can be used. As the inner layer sheet 61 and the outer layer sheet 62, a water-repellent non-woven fabric or the like can be used. As the absorbent body 40', those previously used for absorbent articles such as disposable diapers can be used without particular limitation. For example, as the absorbent body 40, a coated material such as a paper towel or a water-permeable nonwoven fabric, a fiber aggregate of a fibrous material such as pulp, or a superabsorbent polymer can be used. As the elastic member 56 for forming the side burrs, the waist elastic member Ο, and the elastic member I and the living member 64, the sputum can be usually placed in a disposable urine type or the like without any particular limitation. For example, a polyethylene-α-olefin copolymer such as natural rubber, polyamine*polystyrene·polyisoprene: association copolymer, polystyrene-polybutylene diene* propylene/ethene Sa_ethylene, or the like can be used. The stretchable material, etc., is not limited to the non-woven fabric 1 of the present invention, and can be appropriately changed. For example, the above-mentioned embodiment of the present embodiment is formed as a spun point non-woven fabric Μθ. Although the laminate of the original layer as shown in Fig. 2 is not 镟I, the original layer is formed into a spunbond layer and a meltblown layer is disposed in the melting session. In the case where the woven layer is not woven, it is preferred that the front side of the spunbond layer and the meltblown layer are punctured. Regarding the spunbonded battered cloth, the U-face of the overall smoothness and further improvement of the μ-feeling touch and the weight of the skin at the time of hair-lifting are more than 25%, especially the ethylene-propylene containing 25 Copolymer tree 156621.doc -31 · 201224239 A polypropylene resin in which a homopolymer is used. When the resin containing a random copolymer forms a spunbond layer of the outermost layer, the flexible layer is disposed on the outer side, so that the bending rigidity is lowered. In terms of cost performance, in the case of cost performance, when the spunbond layer of the skin-only contact surface is formed of a non-woven fabric formed of a resin containing the above-mentioned random copolymer, the surface which can be shared with the skin can be shared ( The layer containing the random copolymer and the surface having a high breaking strength are preferable in terms of efficiently extracting the touch of the skin. Similarly, 'the above-mentioned random copolymer is replaced by a recycled polypropylene resin containing 25% by weight or more. When the fiber of the polypropylene resin is formed, it is preferable from the viewpoint of a small environmental burden. As the original non-woven fabric forming the nonwoven fabric 1, except for the non-woven fabric (for example, spunbonded nonwoven fabric), laminated a woven fabric (for example, a non-woven fabric obtained by laminating a spunbond layer and a meltblown layer by hot embossing), a non-woven fabric and an unbonded web laminate, and joined by heating or the like, or In the case of heat-bonding of staple fibers of 30 mm or more by heat, or by pressing and heating in a hot air, the fibers constituting the non-woven fabric may be single fibers or composite fibers (parallel type, Core slightly, eccentric fiber), crimped fiber 'Fixed fiber, heat stretched fiber, fiber divided by extension. Especially cheap: face, preferably single fiber. Also 'can be followed by Agent or heating 'combined with other non-woven fabrics or films on the above non-woven fabric to form a composite non-woven fabric, and the raising process can be carried out before the other non-woven fabric or film can be attached to the 'afterwards'. When the portion 5 is raised, the convex roller is in the feeding direction of the non-woven fabric (MD direction), and the alignment degree of the weaving dimension is Mw/c is preferably 1.1 to 1.8, more preferably i.2 to 15 ^ The fiber is easily proclaimed 5 1 of 156621.doc -32· 201224239 convex part 51〇 It is preferred to live with a higher amount of hair. The alignment of the fibers is a square sample of 95 mm in the direction of MD in the direction of 95 mmaCD, using a microwave molecular alignment meter M〇A6〇〇4 ( 〇 Scientific Scientific Scientific Scientific Scientific 测定 测定 测定 测定 测定 测定 测定 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维Since the use of the adhesive agent is equivalent to the operation of attaching new fibers to the non-woven fabric, the risk of adversely affecting the skin due to the chemical agent such as the adhesive used can be reduced. Problems such as peeling of the flocked fibers during use and exposure of the subsequent faces occur. Further, for example, the spunbonded nonwoven fabric used for the non-woven fabric of the absorbent article is thin, and it is difficult to tear in the general raising process, but the wool density can be obtained according to the manufacturing method of the nonwoven fabric using the above-described manufacturing apparatus. The pilling which is high in the skin and has a good touch (spun woven fabric. Next, the non-woven fabric of the present invention) is described with reference to the drawings, and the non-woven fabric is observed in the direction of alignment of the constituent fibers. Generally, the direction of the alignment direction of the fibers is set to the direction or the length direction, and the direction orthogonal to the direction is set to the CD direction or the width direction. The following is performed by Μ ° and 'in the following description, the MD direction is transferred ( The direction of the non-woven fabric in the longitudinal direction and the side where the sheet is conveyed by rotating the roller in the circumferential direction means that the CD direction (width direction) of the non-woven fabric in the same direction is the same direction as the roller direction. God 156621.doc -33- 201224239 Fig. 9 to Fig. 1 2 schematically show one of processing apparatuses (hereinafter simply referred to as processing apparatuses) used in the method of manufacturing the nonwoven fabric of the present invention As shown in Fig. 9, the processing apparatus 1 of the present embodiment is roughly divided into a partially extended processed portion 2 and a raised portion 3 disposed on the downstream side of the partially extended processed portion 2. The partially extended processed portion 2 is paired. In the processing apparatus 1 of the present embodiment, as shown in Figs. 9 and 10, a pair of uneven rolls 2 1 and 22 are provided in the processing apparatus 1 of the present embodiment. Here, the "partial extension" processing is performed. It is not generally a method of performing elongation processing on the entire nonwoven fabric by the speed difference between the rolls, but a method of processing the unstretched portion and the extended portion. The so-called unextended portion means that the non-woven fabric is not implemented. In the extension processing, the term "the extension processing is not performed" means that the stretching process is not actively performed on the processing. With respect to the pair of uneven rollers 21, 22, one roller 21 has a plurality of convexities on the circumferential surface. 卩210, another The report 22 has a concave portion 22 that the convex portion 210 can enter at a position corresponding to the convex portion of one roller 21. The pair of concave rollers 21 and 22 are metallic cylindrical shapes such as aluminum alloy or steel. In the processing apparatus 1 of the present embodiment, a so-called steel mold embossing roll 23 including a pair of convex portions 21 and a pair of concave portions 220 and 22 which are circumferentially provided with each other is provided, as shown in FIG. The steel die-casting system is formed with a plurality of convex portions 210 provided on the circumferential surface of the roller 21 and a plurality of concave portions 220 provided on the circumferential surface of the roller 22, and the plurality of convex portions 210 are uniformly and regularly arranged. In the rotation axis direction and the circumferential direction of the roller 21, the pair of rollers 21 and 22 are rotated by transmitting a driving force from a drive mechanism (not shown) by using a gear I56621.doc • 34·201224239 = (illustrated). Further, "the drive from the drive mechanism (not shown) is transmitted to the rotary shaft of the arbitrarily-rotating shaft, and the 'the pair of rollers 21 and 22 are meshed and rotated, and the portion is effectively extended by the center of the groove of each other. From the viewpoint of extension, it is preferable to use a gear to transmit the driving force other than the sigma σ. The counter roller 2: the rotation speed (circumferential speed V2) is controlled by the control unit (not shown) of the processing equipment. Here, the circumferential speed v2 of (4) and 22 is set to be the diameter _ with the light η = sharp shape 1 and the speed of 0 turns from the number of rotations of the roller. The convex portion of the circumferential surface of the roller 2! The shape of the 21〇 can be circular, quadrangular, elliptical, rhombic, or rectangular (longer in the direction of transport or in the direction of the transport direction) from the upper portion, and it is preferable that the fracture strength of the non-woven fabric 4 is small. Further, as the shape of the convex portion 210 as viewed from the side surface, a trapezoidal shape, a quadrangular shape, a hip shape, and the like are exemplified, and in the case of a small rotation of the roller, it is preferable that the trapezoid is more trapezoidal. The bottom corner angle is 70 degrees to 89 degrees, so that the non-woven fabric 4 before processing shows higher The effect of improving the flexibility, etc., from the viewpoint of the breaking strength of the non-woven fabric 4 after stretching, the partially stretched processed portion 2 preferably extends at a plurality of mechanical stretch ratios of 1.05 to 20 times, respectively, to extend the plurality of non-woven fabrics 4, more preferably to 2 to (7) times. Here, the mechanical extension ratio is a value obtained by the injection shape of the convex portion of the pro 21 and the concave portion 22G of the viewing 22 for the non-woven fabric 4. The mechanical extension ratio of each of the plurality of points is obtained. As shown in the figure, the distance between the convex portions 21 adjacent to each other in the circumferential direction of the roller 2丨 is 15662l.doc -35-201224239 (pitch, roll 21 according to the following formula) The distance between the adjacent convex portions 210 in the direction of the rotation axis (pitch P2), the depth D of the engagement of each convex portion 210 of the roller 21 with each convex portion of the roller 22, and the apex of the convex portion 210 of the roller 21 are The distance in the circumferential direction (the dot diameter and the distance between the apex of the convex portion of the roller 2 1 in the direction of the rotation axis (point diameter a2) is obtained. The shape of the convex portion 210 of the roller 21 is different from the shape of the convex portion of the roller 22. In the case, the distance between the respective apexes of the roller 21 and the roller 22 in the circumferential direction is determined. The value is the diameter of the dot octagonal. The average diameter of the apex of the roller 21 and the roller 22 in the direction of the rotation axis is also obtained in the same manner. The shape of the upper surface is a circle or an ellipse other than a rectangle. In the case of a polygon, the mechanical stretching ratio at this time is the extension ratio of the portion where the stretching ratio is the highest (the portion where the convex portion 21 辊 of the roller 2 1 is closest to the convex portion of the roller 22). In the case of a flat plate type or a crawler type described in, for example, Japanese Patent Laid-Open No. Hei. No. 2_22-66, the mechanical extension ratio is obtained in the same manner. Mechanical extension ratio [number 1] ^ΡχΧ) - Mechanical extension magnification in the direction of the rotation axis [Number 2] Further, the machine in which either the circumferential direction and the rotation axis direction are obtained 15662] .doc -36 - 201224239 The magnification can satisfy the mechanical stretching ratio of the above range. In order to reduce the breaking strength of the non-woven fabric obtained after the processing to reduce the breaking strength of the non-woven fabric obtained by the one of the partial extension processing portions 2, the total area of the non-woven fabric 4 is preferably reduced. Part of the urn~嶋 part of the implementation of the extension processing 'better for part of the 4G% ~ 8〇% implementation of the extension processing. Here, the plural portion of the non-woven fabric 4 that performs the partial extension processing, as shown in FIG. u, refers to a portion that extends by the salvation of each concave portion 22G of each of the convex portions 2U) and the roller 22, if detailed, It means a portion extending by the edge (10) of each convex portion 21 of the roller 21 and the edge 22〇a of the concave portion of the concave portion 220 of the parent. The non-woven portion on the convex surface (top surface) of each convex portion is not easily actively extended. Therefore, the portion "performing the partial extension with respect to the total area of the nonwoven fabric 4" means subtracting the convexity of the relatives from the total area of the nonwoven fabric 4 supplied. The total area of the total area of the top surface of P 210 is further subtracted from the total area of the total area of the areas of the bottom faces of the adjacent convex portions 21 of the rolls 21. The total stretch ratio of the woven fabric as the actual stretch effect applied to the nonwoven fabric is obtained by multiplying the extension ratio of the extension portion by the extension ratio of the non-woven fabric of the extended portion plus The value obtained by the extension ratio of the extended portion (including the substantially unextended portion) to the area ratio of the unextended portion of the μ-. Further, ============================================================================================================================ =4 Shenbi sheep, 156621.doc of the circumferential direction (MD direction) 156621.doc •37- .3 201224239 Extension ratio x non-woven]VfD large · a (CD area W Γ extended area ratio} + axis direction white ) The extension ratio of the wide X is the direction of the rotation axis of the non-woven fabric (CD = the area ratio of the extension) + {Unextended part (including: the extension ratio is not extended by the area ratio of the non-woven fabric) 2. The second direction: = the direction of the circumference (10) The non-woven stretch ratio varies depending on not =! Therefore, it means that the circumferential direction ratio (5) (four) is described as the supply speed and the speed of the light 21 (or the roller 22) is the enemy speed idling/supply speed) The obtained value. Because of the tip-shrinking width on the non-woven fabric, the non-woven stretch of the direction of the rotation axis (CD direction) is multiplied by the mechanical extension ratio of the ^_axis direction multiplied by the non-woven fabric before and after the passage of the 21 and the pro 22 Ning Qiu's width change ratio (after the roller passes The value obtained by the width of the woven fabric before passing through the width of the woven fabric. The direction of the assisting direction and the direction of the CD are simultaneously extended (when the woven fabric is extended in the oblique direction (1), the person's mechanical extension ratio is taken as a vector' to find the md direction and In the case where the shape of the CD square and the shape of the convex portion are circular or the like from the upper portion, the integral value of the mechanical stretching magnification of each point is obtained. If the total stretching magnification of the non-woven fabric is the following range, the partial extension is performed by partial extension. The original non-woven fabric, the peripheral portion of the heat-removing portion of the fiber between the hot house joint and the hot house joint (near the boundary between the thermocompression joint and the fiber) is formed by the extension action) When the fluffing, the fiber is easily cut in this portion, and the thermocompression bonding portion is deformed by the extension. Therefore, the thermocompression bonding portion itself becomes soft, so that the thermocompression bonding portion is less likely to be peeled off during the raising, and the fuzzing fiber becomes short and easy to obtain. A non-woven fabric with excellent skin feel and a reduction in the breaking strength caused by partial stretching processing compared with the original non-woven fabric before stretching, and 156621 .doc -38· 201224239 In terms of a good touch, the total stretch ratio of the non-woven fabric is preferably 1:3 to 4 times, more preferably 5 times to 3 times that of i. The area ratio of the thermocompression bonded portion of the non-woven fabric...v«the ratio of the stretching ratio {The area ratio (%) of the non-woven thermal crimping part, (绅 stretching ratio (times) Xl 〇〇)} is preferably 〇〇2~〇12, Jing Youwei (four) crack strength and moderate damage to the thermocompression joint In terms of the increase in the amount of fluffing, it is more preferably 〇. 〇 4 to 0.1 G. Further, the original non-woven fabric has a thermocompression bonding portion which is regularly dispersed in the plane direction, and the so-called thermocompression bonding portion refers not only to heating. The crimping portion constituting the fiber also includes a crimping portion of the constituent fibers generated by the ultrasonic waves. In order to set the mechanical stretching ratio to the above-described range @, and the portion where the partial extension processing is performed is set to the above range, as shown in FIG. u, in each convex portion 210 of the roller 21, the circumferential surface of the roller 21 to the convex portion 21 The height h of the apex is preferably 1 to 10 mm, more preferably 2 to 7 mme, and the distance between the adjacent convex portions 2 ι in the circumferential direction (pitch P 〇 is preferably 〇〇 1 to 2 〇 mm, more Preferably, the distance between the convex portions 21 相邻 adjacent to each other in the direction of the rotation axis (pitch P2 (not shown)) is preferably 〇 1 20 20 mm, more preferably 1 〇 1 〇. The shape of the top surface of each convex portion 210 of the roller 21 is not particularly limited. For example, a circular shape, a polygonal shape, an elliptical shape, or the like may be used. The area of the top surface of each convex portion 210 is preferably 0.01 to 500 mm 2 , and more preferably 0·1〜10 mm2» Further, the area of each of the bottom surfaces of the adjacent convex portions 210 is preferably 〇〇ι 5 〇〇 mm 2 , more preferably 0.1 〜 10 mm 2 » again, at the convex portion 210 When the edge portion is in the R shape, it is preferable that the non-woven fabric is not easily opened at the time of processing, and the R value is preferably 〇2 mm to 0.5X dot diameter A丨 or 0.5X dot diameter A2. The area of the surface of the convex portion 210 is assumed to be an intermediate point of R (the projection is made to the convex portion from the above, 156621.doc -39 - 201224239). The partial mechanical stretching magnification is also obtained from the point t. +The relationship between the door pitch and the ratio of the distance between the convex portions 210 of the pair of rollers 21 and 22 (the heat-bonding joint of the woven fabric, etc.) (the distance between the non-woven hot-spot joints/the convex portion) The pitch is 〇〇5~〇, and more preferably, there is a possibility of a non-woven thermal crimping portion in the extended portion. The hot-pressed portion is deformed and softened, and the heat is not woven. The peripheral portion of the crimping portion is likely to form a weakening point caused by the extension, and thus is preferable in that it is easy to use a light force to make the surface of the non-woven fabric obtain a shorter hair raising fiber, and it is difficult to form a hair ball and the skin feels good. Here, the preferred range of the ratio of the distance between the thermocompression bonding portions of the non-woven fabric and the convex portions 2U of the pair of rollers 21, 22 satisfies the distance between the thermocompression bonding portions and the pair of rollers which are not woven in the md direction. 2丨, 22 convex portion 2〗 〇 in the circumferential direction between the distance P, From non-woven fabric in CD * thermocompression bonding between a pair of upwardly and the rollers 21 and 22 can be in either the convex portion 210 than the pitch p2 of the rotation axis direction on one side, preferably both satisfied. As shown in FIG. 1A and FIG. 2A, each of the concave portions 220 of the roller 22 is disposed at a position corresponding to each convex portion 210 of the roller 21, in order to set the mechanical stretching ratio to the above range, and to carry out the partial extension processing. In the above range, as shown in Fig. ij, the depth D of the convex portions 210 of the roller 21 and the convex portions of the roller 22 (the length of the portion where each convex portion 210 overlaps each concave portion 220) is preferably 〇1 to 1 〇mm, more preferably 1 to 8 mm. When the nonwoven fabric 4 is supplied between the top of the convex portion 210 of the roller 21 and the bottom of the concave portion 220 of the roller 22, the nonwoven fabric 4 does not become hard when the nonwoven fabric 4 is not sandwiched, so that it is preferable. Further, as shown in FIG. 1A, the partial extension processing unit 2 is provided with conveyance rollers 24 and 25 for transporting the nonwoven fabric 4 on the upstream side and the downstream side of the 156621.doc -40·201224239 of the steel mold embossing roller 23, and the conveyance speed V1 of the nonwoven fabric 4 It is controlled by a control unit (not shown) provided in the processing apparatus 1. Here, the conveyance speed V1 of the nonwoven fabric 4 means the speed of the surface of the nonwoven fabric 4 which is taken out from the roll of the nonwoven fabric 4. The squeezing portion 3 is a portion in which the nonwoven fabric 4 which has been partially stretched is formed to have a bristles of the fibers 41. The processing apparatus according to the present embodiment has a convex roller 31 having a convex portion 31 on its circumferential surface as shown in Fig. 12 . The convex roller 31 is a metallic cylindrical shape such as an aluminum alloy or a steel. The convex roller 31 is rotated by a driving force from a driving mechanism (not shown) transmitted to the rotating shaft. The rotational speed (circumferential speed V4) of the convex roller 31 is controlled by a control unit (not shown) provided in the processing apparatus. Here, the peripheral speed V4 of the convex roller 31 indicates the speed of the surface of the convex roller 31 in the same manner as the circumferential speed V2 of the rollers 21 and 22. As shown in Fig. 12, the raising processing unit 3 is provided with conveying rollers 32 and 33 for conveying the nonwoven fabric 4 on the upstream side and the downstream side of the convex roller 31. The conveyance speed V3 of the stretched nonwoven fabric 4 is controlled by a control unit (not shown) provided in the processing apparatus. Here, the conveyance speed V3 of the stretched nonwoven fabric 4 is the speed of the surface of the non-woven fabric 4' of the convex roller 31, similarly to the conveyance speed V1 of the nonwoven fabric 4 before the extension processing. Regarding each convex portion 310 of the convex roller 31, the height from the peripheral surface of the convex roller 31 to the apex of the convex portion 310 is preferably 0.01 to 3 mm, more preferably 〇1 to 1 mm. The distance (pitch) between the adjacent convex portions 310 in the circumferential direction is preferably 〇.〇% mm 'more preferably 0.01 to 3 mm 'the distance between the adjacent convex portions 31 于 in the direction of the rotation axis ( The pitch is preferably 0.01 to 30 mm, more preferably 0.01 to 3 mm. ^ The density of the convex portion is preferably 500 to 5,000/cm 2 , and the fuzzing is used for I56621.doc •41 · 201224239 A larger amount of non-woven fabric is preferred. The shape of the top surface of each convex portion 310 of the convex roller 31 is not particularly limited. For example, a circular shape, a polygonal shape, a rounded shape, or the like may be used. The area of the top surface of the convex portion 31 is preferably 0.001 to 20 mm 2 'b. For 〇.01~lmm2. The processing device of this embodiment! In the case of the non-woven fabric 4' which is partially stretched, the fiber 41 is more efficiently raised. Preferably, as shown in Fig. 12, the position of the transport (4) on the downstream side of the convex (four) is set to be high. At the position of the embossing roller 3 ,, the woven fabric (4) to the supporting angle of the embossing roller 31 is contacted with the contact surface of the convex roller 31, and more preferably 3 〇 12 〇. In addition, in the case of adding m in the present embodiment, the position of the convex roller 31 and the transport 33 is changed so as to become the angle α. The processing apparatus 1 of the present embodiment is as described above. And a control unit (not shown) that generates a peripheral speed V2 based on the driving mechanism of the pair _ 22 and a peripheral speed V4 based on the driving mechanism of the convex roller according to a predetermined operational sequence, based on the tension detector The conveyance speed V1 of the non-woven fabric 4 for detecting the tension and the speed of the non-woven fabric 4 of the stretched h based on the tension generated by the tension detector are controlled by the conveyance speed v3. Next, 'for the present invention, One of the methods of each method of A cloth is to use the above-mentioned method of processing the above-mentioned embodiment, and the side is explained. The manufacturing method of the non-woven fabric is firstly set to the temperature below the machine 匆 rush to the plural of the non-woven fabric 4 In the actual sample, as shown in _, from the roll stretching process. In the present embodiment 1, the strip-shaped nonwoven fabric 4 as a raw material is taken up, and the spear 156621.doc • 42· 201224239 The non-woven fabric 4 is supplied to the partial extension by the conveyance rollers 24 and 25 Processing department 2 The non-woven fabric 4 is partially stretched between the pair of rolls 21 and 22 of the steel mold embossing roll 23, and specifically, the non-woven fabric 4 conveyed by the conveyance rolls 24 and 25 is shown in Fig. 10 and Fig. The plurality of convex portions 21 具有 of one roller 21 and the plurality of concave portions 220 of the other roller 22 are pressed, and the σ knives are extended, and the plurality of non-woven fabrics 4 are respectively in the transport direction. The stretching process is performed in a direction orthogonal to the conveyance direction. Thus, by performing the stretching process in the direction orthogonal to the conveyance direction and the conveyance direction, the breaking strength of the nonwoven fabric 4 can be suppressed in accordance with the direction. The following temperatures mean that the temperature is not actively applied to the rolls 21 and 22, and when the nonwoven fabric 4 is subjected to the stretching process, it is normal temperature. In other words, when the non-woven fabric 4 is subjected to the stretching process, the heat fusion is not caused by the constituent fibers of the nonwoven fabric. In view of the fact that the non-woven fabric 4 is hardened, it means a temperature lower than the melting point of any kind of constituent fiber resin. Further, the direction orthogonal to the conveying direction means the above-mentioned roller. The direction in which the directions of the rotation axes are the same. In the present embodiment, the supply speed VI and one when the non-woven fabric 4 shown in FIG. 1A is supplied between the pair of the uneven rollers 21 and 22 in order to perform the partial extension processing favorably The relationship between the peripheral speeds of the embossing rolls 21 and 22 is preferably V1 > V2, more preferably the V1/V22 value is set to 1 〇 5 or more, and particularly preferably the value of V1/V2 is hl or more. As for the upper limit, it is preferable that the non-woven fabric 4 to be conveyed does not cause slack, and it is preferable that the value is less than 10, and the amount of V1/V2'S hair is further increased, and the touch of the skin is improved. It is not the extension of I in this embodiment, but the general extension of the single 156621.doc -43-201224239 axis extension, etc., due to the smoothness of the circumferential velocity is greater than, speed & /V2 becomes smaller than i. For example, in the case of the usual spunbonded nonwoven fabric, if the total stretch ratio of the non-woven fabric (which is grown in the uniaxial stretching) is 1.3 times or more, the nonwoven fabric is torn or the like. Therefore, the total stretch ratio of the nonwoven fabric cannot be increased, but in the present embodiment, the total stretch ratio of the nonwoven fabric is 3 times or more, and the nonwoven fabric is less likely to be torn or the like. The manufacturing method of the non-woven fabric of this month is followed by the non-woven fabric 4 which is partially stretched and forced to perform the raising process of the non-woven fabric 4, which constitutes the raising of the fibers. In the present embodiment, as shown in FIG. 9, the partially stretched nonwoven fabric 4 is conveyed by the conveyance rollers 32 and 33 to the convex roller 31 provided with the convex portion 310 on the circumferential surface, and is shown in FIG. The convex roller 31 causes the constituent fibers of the partially stretched nonwoven fabric 4 to fluff from the surface of the non-woven fabric 4·. In the present embodiment, from the viewpoint that the constituent fibers of the nonwoven fabric 4 are efficiently raised from the surface of the nonwoven fabric 4', as shown in Fig. 12, the direction of rotation of the convex roller 31 is extended with respect to the stretched portion. When the processed non-woven fabric 4 is in the opposite direction and the rotation is rotated in the opposite direction, the value of VW3 is 0_3~10, preferably V4>V3, and more preferably V4/V3. 1.1 to 10, when it is 1_5 to 5, it is particularly preferable to achieve sufficient fluffing and less fibers to be wound on the roll. By making a difference in the peripheral speed by rotating in the opposite direction, the amount of hair raised can be further increased, and the touch of the skin can be improved. Further, when the convex roller 31 is not in the reverse direction but in the case where the conveying direction of the stretched nonwoven fabric is the positive direction, the conveying speed V3 of the partially stretched nonwoven fabric 4' and the peripheral speed of the convex roller 31 are used. The relationship of v4, v4/V3 156621.doc • 44· 201224239 is preferably, more preferably ι as the implementation of the above-mentioned %, especially preferably 2 to 8. The non-woven fabric 4 cloth, the spunbond layer and the fused layer + can be used, for example, a non-woven fabric of a spunbonded non-woven continuous layer of long fibers, preferably, or containing a tow state, preferably In order to make the ^ ^ fracture strength higher, and the thinner Zhuang Ma use spunbonded non-woven fabric, it is better. Further, the non-woven fabric of the laminated layer or the back surface is disposed on the front surface of the melt-blown layer, and preferably the laminated body of the nonwoven fabric containing the woven rubber layer and the dazzle layer, and the acryl resin. The thickness of the recycled polypropylene resin on the 槿& is preferably 5~3, and the above-mentioned tow state is continuously deleted. 30 handsome' is better for 10~2 〇 handsome. It is good to be good and good, and it is not good for the right-feel touch and processing adaptability. ^ 25 '/ 2 I-bit weight is preferably 10~100 g/m2, more preferably = two. Non-woven fabric 4 has a plurality of ages as a thermocompression joint

Hi舉:藉由利用壓花凸觀與平親等之熱壓接 而間斷地形成者、藉由超音波炼接所形成者、或間斷地吹 :熱風進行部分溶接而形成者等。其中,藉由熱壓接所形 成者於易於起毛方面較佳。㈣接部之形狀並無特別限 制,例如可為圓形、菱形、三角形等任意形狀。熱溶接部 之合δ十面積於不織布4之一面之表面積中所佔的比率較佳 為5〜3〇°/°,就不易形成毛球方面而言,更佳為10〜20ο/ρ 於使用紡黏不織布之情形時,關於紡黏不織布所具有之 由壓花產生之複數個熱熔接部,各熱熔接部之面積較佳為 0·05 1〇 mm2,更佳為〇 mm2。上述熱熔接部之數量較 佳為10〜250個/cm2,更佳為35〜65個/cm2。上述熱熔接部 15662l.doc • 45· 201224239 之形狀並無特別限制,例如可為圓形、菱形、三角形等任 意形狀。熱熔接部之合計面積於紡黏不織布之一面之表面 積中所佔的比率較佳為5〜3〇%,更佳為j 〇〜2〇%。 又,紡黏不織布可為單層者,亦可為將複數層積層而成 者。 於使用紡黏不織布之情形時,構成紡黏不織布之構成纖 維包含熱塑性樹脂,作為熱塑性樹脂,可列舉:聚稀煙系 樹脂、聚醋系樹脂、聚醢胺系樹脂、丙稀腈系樹脂、乙稀 系樹月曰、亞乙烯系樹脂等。作為聚烯烴系樹脂,可列舉·· 聚乙稀f丙烯、聚丁浠等。作為聚醋系樹脂,可列舉: 聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯等。作為聚醯 胺系樹脂’可列舉尼龍等。作為乙稀系樹脂,可列舉聚氣 乙稀等。作為亞乙烯系樹脂,可列舉聚偏二氣乙稀等。亦 可使用該等各種樹脂之改性物或混合物等。上述構成纖維 之線徑於部分延伸加工前較佳為5〜30㈣,更佳為10〜20 μπι 〇 —如以上所説明,根據使用加工裝置1來製造不織布的本 實施態樣之不織布之製造方法,由於最初係進行於5(rc以 下之溫度下分別對不織布4之複數處實施部分延伸加工之 預加工’故而其後實施起毛加工時易起毛,又,不易熱熔 接’因而不織布4’之構成纖維起毛之肌膚觸感良好,獲得 柔軟之不織布4' X ’對於所獲得之不織布4",由於:別 對加工前之不織布4之複數處實施部分延伸加工,而該複 數處以外未實施該部分延伸加工,故而此部分可維持不織 156621.doc •46- 201224239 布強度,而可減輕不織布強度之降低。尤其是使用如紡黏 不織布之不織布本身之強度較高之不織布作為成為原料之 不織布4之情形時,可加快搬送速度,而可抑制不織布4,, 製迈成本。再者,於本實施態樣中,由於使用包含— 、 之輥進行部分延伸加工,進而使用包含凸輥31之 輥進仃起毛加工’故而可提高不織布4"之製造速度,進而 可抑制不織布4"之製造成本。 尤其是使用上述紡黏不織布作為不織布4之情形時,相 對=原本之紡黏不織布之斷裂強度之值於單位面積重量20 g/m下為1〇〜3〇 N/5〇 mm之不織布加工後所獲得之紡黏 不Λ布之斷裂強度之值為5〜2〇 N/5〇爪瓜,可將不織布強度 之降低減輕至5G%以下。如此,加工後所獲得之纺黏不織 布之斷裂強度之值與原本之紡黏不織布之斷裂強度之值大 致相同。關於斷裂.強度,較佳為原本之紡黏不織布或加工 後所獲彳于之紡黏不織布於Χ方向及γ方向之任一方向上滿 足上述範圍,更佳為於兩方向上滿足上述範圍。斷裂強度 係藉由以下方法而測定。 [斷裂強度之測定法] 針對原本之紡黏不織布或加工後所獲得之紡黏不織布, 刀取X方向(寬度方向' CD方向)上為200 mm且Υ方向(長度 方向、MD方向)為50 _之尺寸之長方形之測定片。將該 切取之長方形之測定片作為測定樣品。將該測定樣品以X 方向成為拉伸方向之方式安裝至拉伸試驗機(例如, 〇rienteC公司製造之萬能拉力試驗機(Tensilon)「RTA- 156621.doc •47· 201224239 100」)之夾頭上。夹頭間距設為150〇1〇1。w 300 mm/min拉 伸測定樣品’將樣品斷裂為止之最大荷重點設為x方向之 斷裂強度。又,切取γ方向(長度方向、MD方向)上為2〇〇 mm且X方向(寬度方向、CD方向)上為5〇 mm之尺寸之長方 形之測定片,將其作為測定樣品。將該測定樣品以其γ方 向成為拉伸方向之方式安裝至拉伸試驗機之夾頭上。藉由 與上述X方向之斷裂強度之測定方法相同之順序,求出y 方向之斷裂強度。 又尤其疋使用上述紡黏不織布作為不織布4之情形 時’自加工後所獲得之紡黏不織布之表面起毛之不織布之 構成纖維較短,不易損害美觀之外觀。此處,所謂自不織 布之表面起毛之構成纖維,係指起毛之構成纖維之前端位 於比不織布之表面更上方〇·2 mm以上的纖維。 於使用紡黏不織布之情料,本發明者推測自纺黏不織 布之表面起毛之不織布之構成纖維較短的原因為:於利用 部分延伸加工部2之鋼模壓花輥23延伸紡黏不織布時,於 纺黏不織布之熱溶接部形成弱化點,其後由於利用起毛加 工部3之凸較31加工表面,故而作為纺黏不織布之構成纖 維之連續長纖維自形成有弱化點之熱熔接部發生斷裂,而 形成自熱熔接部被切斷之纖維。 就肌膚觸感變得良好之觀點^言,㈣布之起毛纖維較 佳為8根/em以上’更佳為12根/啦以上。又,就獲得充分 之斷裂強度的觀點而言,上限較佳為⑽根/em以下,就外 觀上未見起毛方面而言,更佳為4〇根/cm以下。起毛之纖 15662I.doc -48· 201224239 維係藉由以下測定法而測定。 [起毛之構成纖維根數之測定方法] 圖13係表示測定起毛之構成纖維根數的方法的模式圖。 抽樣及測定環境係於22°C、65% RH之環境下進行。首 先’利用鋒利之剃刀,自所測定之不織布切取2〇 cmx2〇 cm之測定片,如圖n(a)所示,將測定片以起毛側朝向外 側之方式進行正折’而形成測定樣品1 〇4 ^其次,將該測 定樣品104放置於A4尺寸之黑色襯紙上,如圖13(b)所示, 進而於其上放置開有長1 cmx寬1 cm之孔107的A4尺寸之黑 色襯紙。此時,如圖丨3(b)所示,以自上側之黑色襯紙之孔 1〇7可見測定樣品1〇4之摺線1〇5之方式進行配置。兩襯紙 係使用富士共和製紙股份有限公司之「Kenran(黑色)令重 265 g」。其後,自上側之襯紙之孔1 〇7之兩側分別沿著摺 線105向外側5 cm之位置,分別放置5〇 g之砝碼,形成測 定樣品104完全摺疊之狀態。其次,如圖13(c)所示,使用 顯微鏡(KEYENCE公司製造VHX-900) ’以30倍之倍率觀察 襯紙之孔107内,計測超過假想線108之起毛之纖維之根 數’該假想線108係形成於自測定樣品1〇4之摺線ι〇5向上 方平行移動0.2 mm之位置。於此時所測定之不織布中經起 毛加工之部位之寬度為1 cm以上之情形時,以包括經起毛 加工之部位之方式切取3片20 Cmx20 cm之測定片並進行計 測。又,於經起毛加工之部位之寬度為i cm以下之情形 時,隨機切取3片20 cmx20 cm之測定片並進行計測。對3 片所測定之不織布進行以上操作,取合計9處之平均值設 156621.doc •49· 201224239 ’於計數起毛之構成纖維之數量時,例如圖n(c)所示 之纖維106a般,有將位於摺線1〇5上方〇 2 mm之假想線1〇8 橫穿2次之纖維之情形時,此纖維算作2根。具體而言,於 圖13(c)所示之例中,將假想線1〇8橫穿丨次之纖維有4根, 將假想線108橫穿2次之纖維1〇以有丨根,橫穿2次之纖維 106a算作2根,起毛之構成纖維之根數為6根。 藉由本發明之不織布之製造方法而獲得之構成纖維之起 毛不織布不同於植毛,並無使用接著劑等於不織布上附著 新的纖維的操作,故而可減輕所使用之接著劑等化學藥劑 對皮膚產生不良影響之危險性。又,亦無使用時之植毛纖 維之剝落、接著面$费+楚 ' …田題。又’例如作為吸收性物 二=不織布之一的纺黏不織布較薄,於一般起毛加 =發生撕裂而存在困難,但根據本發明之不 獲料毛密度較高、肌膚觸感良好之起毛⑼ 藉由本發明之不織布之製造方法 在於厚度較薄但較, 于之不織布之特徵 厚度幾乎無變前之不織布與高荷重下之 、 但低荷重下之厚度可見差& . 由本發明之;ϊ;姚士 , 又J見差異。例如,藉 ^ ''之製造方法而獲得之紡黏不織布、 …通常之纺點不織布於單位面積重量二及加 厚度均為〜Gl8 f1 1 改變。但是,於o.〇5gfW之攸1 18mm左右,無 紡黏不織布之厚唐 何重下,加工前之通常之 ’·、·41 mm〜0.46 mm,相對於此,藉由 I5662I.doc •50. 201224239 本發明之不織布之製造方法而獲得之纺黏不織布之厚度成 為〇·5咖〜〇.6麵之不同厚度。再者,〇 〇5抑‘之荷重 相當於人手指輕虔不織布時之荷重,識別該微小之厚度差 異,人會感覺到柔軟。 本發明之不織布之製造方法並不受上述實施態樣之製造 方法之任何限制,可適宜變更。 例如’於本f施態樣之残布之製造方法所使用之加工 裝置1中,如圖9、圖10所示,於部分延伸加工部2具備包 含-對相互鳴合之凹凸輥21、22之鋼模壓花親23,但亦可 八備周面。又置有相互嚙合之齒隙的一對齒隙輥代替鋼模壓 花輕23。X,於該情形時,—對齒隙輥可為於搬送方向上 哺合者,亦可為於與搬送方向交叉之方向上响合者。於採 :於與搬送方向交又之方向上嚙合之一對齒隙輥之情形 即使壓入量較多,由於一對齒隙親可進行旋轉,故而 可實施機械延伸倍率較高之加工,而獲得肌膚觸感良好之 不織布由於鋼模壓花輕藉由使未延伸部分間斷地分佈, 使不織布之斷裂強度降低較小,加工時不易產生褶級, 2 方向與⑶方向之雙方實施延伸而使肌膚觸感優 異’故而更佳。 索為了賦予設計性’較佳為起毛為條紋狀,或形成 化紋圖案而部分起毛。 署】由/本實施態樣之不織布之製造方法所使用之加工裝 置1中’如圖9、圖〗^张― 有凸部31〇之凸輥3 θ⑨起毛加工部3具備周面設置 ’但亦可具備周面設置有相互嚙合之 156621.doc •51· 201224239 隙的一對齒隙報代替凸輥31,亦可為經滾花加工之輥或 經喷塗加工之輥、梳針。又,亦可具備周面設置有具有摩 察阻力之素材的輥。作為上述輥之周面所設置之具有摩擦 阻力之素材’可列舉轉或砂紙等。進而,部分延伸與起 毛加工可連續進行’亦可逐次進行1據本實施態樣之不 織布之製造方法’亦具有如下優點:起毛加工後,即使捲 取為不織布捲筒而將起毛之纖維暫時壓塌,其後於捲開時 僅藉由手觸碰'或通過捲出機等之導輥預先使壓塌之起毛 之纖維立起’便可獲得肌膚觸感良好之不織布及吸收性物 品。 實施例 以下,藉由實施例更詳細地說明本發明。然而,本發明 之範圍並不限定於上述實施例。 [實施例1] 使用具有纖維徑為14.7 μπι之包含乙烯·丙烯共聚物樹脂 的紡黏層且單位面積重量為15 g/m2之不織布(紡黏_熔噴· 紡黏積層不織布,以下亦稱為SMS)(將該狀態之不織布設 為比較例5)。其次,將該SMS不織布通過圖3所示之鋼模 壓花輥43 ’並利用圖4所示之凸輥51進行表面加工,經兩 階段處理而獲得不織布。所使用之鋼模壓花輥43之輕41上 之各凸部410的高度為2.8 mm ’輥41之各凸部410與輥42之 各凹部420之喷合之深度為2.7 mm。又,於旋轉軸方向上 相鄰之凸部410彼此之距離(間距)為7 mm ’於圓周方向上 相鄰之凸部410彼此之距離(間距)為7 mm。又,所使用之 156621.doc •52· 201224239 凸輕51之各凸部51〇之高度為〇6 mm,於旋轉軸方向上相 鄰之凸部5 1 〇彼此之距離(間距)為1 4 mm,於圓周方向上 相鄰之凸部510彼此之距離(間距)為2丨mm。於相對於不 織布之搬送方向之反方向以4倍之速度旋轉凸輥。抱角為 130度。各自之搬送速度為10 m/min。 [實施例2] 使用具有纖維徑為17.7 μηι之包含丙烯樹脂之紡黏層且 單位面積重量為15 g/m2之不織布(紡黏-熔噴_紡黏積層不 織布,以下亦稱為SMS)»其次,將該SMS不織布於與實施 例1相同之條件下進行兩階段處理而獲得不織布。 [實施例3] 使用具有纖維徑為12.9 μηι之包含乙烯-丙稀共聚物樹脂 之纺黏層且單位面積重量為18 g/m2之不織布(紡黏_紡黏_ 熔喷-紡黏積層不織布,以下亦稱為SSMS ;該SSMS不織 布之兩面之纺黏層中混練有柔軟劑)。其次,將該SSMS不 織布於與實施例1相同之條件下進行兩階段處理而獲得不 織布。 [實施例4] 使用具有纖維徑為14.6 μηι之包含丙烯樹脂之纺黏層且 單位面積重量為12 g/m (紡黏-熔喷-溶噴-纺黏積層不織 布,以下亦稱為SMMS)之不織布。其次,將該SMMS不織 布於與實施例1相同之條件下進行兩階段處理而獲得不織 布》 [實施例5] 156621.doc •53· 201224239 使用具有纖維徑為14.9帥之包含乙烯.丙婦共聚物樹月旨 方黏層且單位面積重量為18 g/m2(紡黏-溶喷'纺點積層 不織布’以下亦稱為_)之不織布。又,該職之不織布 之單面之紡㈣中輯㈣軟劑1次,將該SMS不織布 之混練有柔軟劑之層之側於與實施例㈠目同之條件下進^ 兩階段處理而獲得不織布。 订 [實施例6] 使用具有纖維徑為15·0μιη之包含乙稀_丙稀共聚物樹脂 之纺黏層且單位面積重量為18 g/m2(纺黏'纺黏-纺黏積層 不織布’以下亦稱為sss)之不織布。又,該sss之不織布 中混練有柔軟#卜其次,將該sss不織布於與實施例i相同 之條件下進行兩階段處理而獲得不織布。 [實施例7] 使用具有纖維徑為叫之包含丙烯樹脂之纺點層且 單位面積重量為18〆(纺黏·纺黏,黏積層不織布,以 下亦稱為SSS)之不織布。其次,將該sss不織布於與實施 例1相同之條件下進行兩階段處理而獲得不織布。 [比較例1] 與實施m同樣地’使用具有纖維徑為14 7㈣之包含乙 烯-丙稀共聚物樹脂之紡黏層且單位面積重量為i5 —之 不織布(纺黏-熔喷-纺黏積層不織《,以下亦稱為圓)。 其次,為了於該不織布上再現針刺處理,使用尖頭鑷 子(TWEEZERS 製造,Pincette Κ-14、,ώ (Hi: It is formed by intermittently forming by the embossing convexity and the thermo-compression bonding of the flat parent, by the formation of the ultrasonic refining, or intermittently blowing: the hot air is partially melted. Among them, the person formed by thermocompression bonding is preferable in that it is easy to fluff. (4) The shape of the joint portion is not particularly limited, and may be any shape such as a circle, a rhombus or a triangle. The ratio of the area of the heat-dissolving portion to the surface area of one surface of the non-woven fabric 4 is preferably 5 to 3 〇 ° / °, and it is more preferably 10 to 20 ο / ρ in terms of the formation of the hair ball. In the case of spunbonding non-woven fabric, the area of each heat-welding portion is preferably 0·05 1 〇 mm 2 , more preferably 〇 mm 2 , for the plurality of heat-welding portions of the spunbonded nonwoven fabric which are produced by embossing. The number of the heat-welding portions is preferably from 10 to 250 / cm 2 , more preferably from 35 to 65 / cm 2 . The shape of the heat-fusible portion 15662l.doc • 45· 201224239 is not particularly limited, and may be any shape such as a circle, a rhombus or a triangle. The ratio of the total area of the heat-fusible portions to the surface area of one side of the spunbonded nonwoven fabric is preferably 5 to 3 % by weight, more preferably j 〇 2 to 2 %. Further, the spunbonded nonwoven fabric may be a single layer or a laminate of a plurality of layers. In the case of using a spunbonded nonwoven fabric, the constituent fibers constituting the spunbonded nonwoven fabric comprise a thermoplastic resin, and examples of the thermoplastic resin include a polystyrene resin, a polyester resin, a polyamide resin, and an acrylonitrile resin. Ethylene tree jelly, vinylidene resin, etc. Examples of the polyolefin-based resin include polyethylene f-propene and polybutylene. Examples of the vinegar-based resin include polyethylene terephthalate and polybutylene terephthalate. As the polyamine-based resin, nylon or the like can be given. Examples of the ethylene-based resin include polyethylene oxide and the like. Examples of the vinylidene resin include polyvinylidene oxide and the like. Modifications or mixtures of these various resins and the like can also be used. The wire diameter of the above-mentioned constituent fibers is preferably 5 to 30 (four), more preferably 10 to 20 μπι 前 before the partial stretching process. As described above, the nonwoven fabric of the present embodiment in which the nonwoven fabric is manufactured by using the processing device 1 is manufactured. Since the initial processing is carried out at 5 (the temperature below rc, the partial processing of the partial stretching process is performed on the plurality of nonwoven fabrics 4), and then the raising process is easy to be raised, and the heat is not easily welded, so the composition of the non-woven fabric 4' The fiber fluffed skin feels good, and the soft non-woven fabric 4' X ' is obtained for the obtained non-woven fabric 4" because: the partial extension processing is performed on the plural portions of the non-woven fabric 4 before processing, and the portion is not implemented except the plural Extending the processing, so this part can maintain the strength of the non-woven 156621.doc •46- 201224239, and can reduce the strength of the non-woven fabric. Especially, the non-woven fabric with high strength such as non-woven fabric of spunbonded non-woven fabric is used as the raw material non-woven fabric 4 In this case, the transport speed can be increased, and the non-woven fabric 4 can be suppressed, and the cost can be reduced. Further, in the present embodiment By using the roll including the roll, the partial stretch processing is performed, and the roll including the convex roll 31 is used for the creping process, the manufacturing speed of the nonwoven fabric 4" can be increased, and the manufacturing cost of the nonwoven fabric 4" can be suppressed. When the spunbonded non-woven fabric is used as the non-woven fabric 4, the value of the breaking strength of the original spunbonded non-woven fabric is not less than that of the non-woven fabric of 1〇~3〇N/5〇mm at a basis weight of 20 g/m. The value of the breaking strength of the sticky cloth is 5~2〇N/5〇 claw melon, which can reduce the strength of the non-woven fabric to less than 5G%. Thus, the value of the breaking strength of the spunbonded non-woven fabric obtained after processing is the same as the original The value of the breaking strength of the spunbonded non-woven fabric is substantially the same. Regarding the breaking strength, it is preferred that the spunbonded non-woven fabric or the spunbonded non-woven fabric obtained after processing satisfies the above range in either the rubbing direction and the γ direction. More preferably, the above range is satisfied in both directions. The breaking strength is measured by the following method. [Measurement of breaking strength] For the original spunbonded nonwoven fabric or obtained after processing The spunbonded non-woven fabric is obtained by taking a rectangular measuring piece of 200 mm in the X direction (the direction of the CD in the width direction) and having a size of 50 mm in the x direction (the length direction and the MD direction). The sample was measured and attached to a tensile tester in such a manner that the X direction was a tensile direction (for example, Tensilon "RTA-156621.doc •47·201224239 100" manufactured by 〇rienteC Co., Ltd.) On the chuck, the gap between the chucks is set to 150 〇 1 〇 1. w 300 mm / min tensile measurement sample 'The maximum load focus until the sample is broken is set to the breaking strength in the x direction. Further, a rectangular test piece having a size of 2 mm in the γ direction (longitudinal direction and MD direction) and a size of 5 mm in the X direction (width direction, CD direction) was cut out and used as a measurement sample. The measurement sample was attached to the chuck of the tensile tester in such a manner that the γ direction thereof was in the stretching direction. The breaking strength in the y direction is obtained in the same order as the method for measuring the breaking strength in the X direction described above. Further, in particular, when the above-mentioned spunbonded nonwoven fabric is used as the nonwoven fabric 4, the non-woven fabric of the surface of the spunbonded nonwoven fabric obtained after the processing is short, and the appearance of the fabric is not easily impaired. Here, the constituent fibers which are raised from the surface of the non-woven fabric refer to fibers having a front end of the constituent fibers of the raised fabric which are located more than 2 mm above the surface of the nonwoven fabric. In the case of using a spunbonded nonwoven fabric, the inventors speculated that the reason why the constituent fibers of the non-woven fabric which is raised from the surface of the spunbonded nonwoven fabric is shorter is that when the spunbonded nonwoven fabric is stretched by the steel mold embossing roll 23 of the partially stretched processed portion 2, A weakening point is formed in the hot-melt joint of the spunbonded nonwoven fabric, and thereafter, since the surface of the spun-processed portion 3 is used to machine the surface, the continuous long-fiber which is a constituent fiber of the spunbonded nonwoven fabric is broken from the heat-welded portion where the weakened portion is formed. And a fiber which is cut by the heat fusion portion is formed. In view of the fact that the touch of the skin is good, (4) The raised fibers of the cloth are preferably 8 pieces/em or more, and more preferably 12 pieces or more. Further, from the viewpoint of obtaining sufficient breaking strength, the upper limit is preferably (10)/em or less, and more preferably 4 〇/cm or less in terms of external appearance. Hairiness 15662I.doc -48· 201224239 Maintenance is determined by the following assay. [Method for Measuring the Number of Fibrous Fibers] Fig. 13 is a schematic view showing a method of measuring the number of constituent fibers of the fluffing. The sampling and measurement environment was carried out in an environment of 22 ° C and 65% RH. First, using a sharp razor, a measurement piece of 2 〇 cm x 2 〇 cm was cut out from the non-woven fabric to be measured, and as shown in Fig. n (a), the measurement piece was folded in such a manner that the hair raising side was outwardly formed to form a measurement sample 1 〇4 ^ Next, the measurement sample 104 was placed on an A4 size black backing paper, as shown in Fig. 13 (b), and then an A4 size black lining having a hole 107 of 1 cm x 1 cm in length was placed thereon. paper. At this time, as shown in Fig. 3(b), the arrangement is performed so that the fold line 1〇5 of the sample 1〇4 is visible from the hole 1〇7 of the upper black backing paper. The two-liner paper uses the "Kenran (black) weight 265 g" from Fuji Republic Paper Co., Ltd. Thereafter, a weight of 5 〇 g was placed on both sides of the hole 1 〇 7 of the backing paper along the fold line 105, respectively, to form a state in which the sample 104 was completely folded. Next, as shown in Fig. 13 (c), the inside of the hole 107 of the liner was observed at a magnification of 30 times using a microscope (VHX-900, manufactured by Keyence Corporation), and the number of fibers exceeding the raising of the imaginary line 108 was measured. The line 108 is formed at a position shifted upward by 0.2 mm from the fold line ι 5 of the measurement sample 1〇4. When the width of the portion subjected to the burr processing in the non-woven fabric measured at this time was 1 cm or more, three pieces of 20 Cmx 20 cm test pieces were cut out and subjected to measurement by the portion subjected to the raising process. Further, when the width of the portion subjected to the raising process was i cm or less, three pieces of 20 cm x 20 cm pieces were randomly cut and measured. The above operations are performed on the three non-woven fabrics measured, and the average value of the total of nine places is set to 156621.doc •49·201224239 'When the number of constituent fibers of the fluff is counted, for example, the fiber 106a shown in FIG. When there is a fiber in which the imaginary line 1〇8 which is located 2 mm above the fold line 1〇5 is traversed twice, the fiber is counted as two. Specifically, in the example shown in FIG. 13(c), there are four fibers that traverse the imaginary line 1〇8, and the imaginary line 108 traverses the fiber twice to have a root. The fiber 106a which was worn twice was counted as two, and the number of the constituent fibers of the hair was six. The fleece nonwoven fabric of the constituent fibers obtained by the method for producing a non-woven fabric of the present invention is different from the flocked hair, and the use of an adhesive is equivalent to the operation of attaching new fibers to the non-woven fabric, so that the chemical agent such as the adhesive to be used can be reduced to cause poor skin. The danger of impact. In addition, there is no peeling of the hair planting fibers when used, and then the face fee + Chu '... Further, for example, the spunbonded non-woven fabric which is one of the absorbent article 2 = non-woven fabric is thin, and it is difficult to cause tearing in general, and it is difficult to produce tearing. However, according to the present invention, the hair density is high and the skin feels good. (9) The manufacturing method of the non-woven fabric according to the present invention is characterized in that the thickness is relatively thin, but the thickness of the non-woven fabric is almost unchanged before the non-woven fabric and the high load, but the thickness under the low load is poorly visible & Yao Shi, and J see the difference. For example, a spunbond nonwoven fabric obtained by the manufacturing method of ''', ... usually a spun point non-woven fabric having a weight per unit area of two and a thickness of ~Gl8 f1 1 is changed. However, at about 18 mm of o.〇5gfW, the thickness of the non-woven non-woven fabric is heavy, and the usual '·,·41 mm~0.46 mm before processing, relative to this, by I5662I.doc •50 201224239 The thickness of the spunbonded nonwoven fabric obtained by the method for producing a non-woven fabric of the present invention is a thickness of 6·5 coffee to 〇.6 faces. Furthermore, the load of 〇 抑 5 ‘ is equivalent to the load of a person's finger when it is not woven, and the thickness of the tiny difference is recognized, and the person feels soft. The method for producing the nonwoven fabric of the present invention is not limited to the above-described production method, and can be appropriately changed. For example, as shown in FIG. 9 and FIG. 10, in the processing apparatus 1 used in the manufacturing method of the residual fabric of the present invention, the partial extension processing part 2 is provided with the unevenness rolls 21 and 22 including the pair of mutual sounds. The steel mold embossed pro 23, but it can also be used for eight weeks. A pair of backlash rolls, which are provided with intermeshing backlash, are used instead of the steel mold embossing light 23. X, in this case, the pair of backlash rollers may be in the direction of transport, or may be in the direction of crossing the direction of transport. In the case of engaging one of the pair of backlash rolls in the direction of the direction of the conveyance, even if the amount of press-fitting is large, since a pair of backlashes can be rotated, a machine having a high mechanical stretch ratio can be processed, and A non-woven fabric that obtains a good touch of the skin, because the steel mold embossing lightly distributes the unstretched portion intermittently, so that the breaking strength of the non-woven fabric is less reduced, and pleating is less likely to occur during processing, and both sides of the 2 direction and the (3) direction are extended to the skin. Excellent in touch. It is better. In order to impart design, it is preferable that the fuzzing is stripe-like, or the embossing pattern is formed to partially fluff. In the processing apparatus 1 used in the manufacturing method of the non-woven fabric according to the present embodiment, the embossing processing unit 3 having the convex portion 3 θ9 having the convex portion 31 具备 has the circumferential surface setting 'but as shown in FIG. 9 and FIG. It is also possible to have a pair of backlashes which are provided with a mutual engagement of 156621.doc • 51·201224239 gap instead of the convex roller 31, and may also be a knurled roller or a sprayed roller or a needle. Further, a roller having a material having a frictional resistance on the circumferential surface may be provided. The material having frictional resistance provided on the circumferential surface of the above-mentioned roll may be exemplified by transfer or sandpaper. Further, the partial extension and the raising process can be carried out continuously, and the manufacturing method of the non-woven fabric according to the present embodiment can also be carried out one by one. The following advantages are also obtained: after the raising process, the fibers of the raising are temporarily pressed even if the winding is a non-woven fabric roll. When it is collapsed, it is possible to obtain a non-woven fabric and an absorbent article having a good touch with the skin by merely touching the hand by a hand or by raising the fiber of the crushed hair by a guide roller such as a winder. EXAMPLES Hereinafter, the present invention will be described in more detail by way of examples. However, the scope of the invention is not limited to the above embodiments. [Example 1] A non-woven fabric having a spun adhesive layer containing an ethylene-propylene copolymer resin having a fiber diameter of 14.7 μm and having a basis weight of 15 g/m 2 (spunbond_meltblown/spunbonded non-woven fabric, hereinafter also referred to as It is SMS) (The non-woven fabric of this state is set as Comparative Example 5). Next, the SMS non-woven fabric was passed through the steel mold embossing roll 43' shown in Fig. 3 and subjected to surface processing by the convex roll 51 shown in Fig. 4, and a non-woven fabric was obtained by two-stage treatment. The height of each convex portion 410 on the light 41 of the steel mold embossing roll 43 used was 2.8 mm. The depth of the respective convex portions 410 of the roller 41 and the concave portions 420 of the roller 42 was 2.7 mm. Further, the distance (pitch) between the adjacent convex portions 410 in the direction of the rotation axis is 7 mm ', and the distance (pitch) between the convex portions 410 adjacent in the circumferential direction is 7 mm. Further, the height of each convex portion 51 of the convex light 51 is 〇6 mm, and the distance (pitch) between the convex portions 5 1 相邻 adjacent to each other in the direction of the rotation axis is 1 4 . In mm, the distance (pitch) between the convex portions 510 adjacent in the circumferential direction is 2 mm. The convex roller is rotated at a speed four times in the opposite direction to the conveying direction of the non-woven fabric. The angle of hug is 130 degrees. The respective conveying speed is 10 m/min. [Example 2] A non-woven fabric (spunbond-meltblown_spunbonded nonwoven fabric, hereinafter also referred to as SMS) having a spunbond layer containing a propylene resin having a fiber diameter of 17.7 μm and having a basis weight of 15 g/m2 was used. Next, the SMS was not woven under the same conditions as in Example 1 to carry out a two-stage treatment to obtain a nonwoven fabric. [Example 3] A non-woven fabric having a spun adhesive layer containing an ethylene-propylene copolymer resin having a fiber diameter of 12.9 μηι and having a basis weight of 18 g/m 2 (spunbond-spunbond_meltblown-spunbonded non-woven fabric) was used. The following is also known as SSMS; the softening agent is mixed in the spunbond layer on both sides of the SSMS non-woven fabric). Next, the SSMS was not woven under the same conditions as in Example 1 to carry out a two-stage treatment to obtain a nonwoven fabric. [Example 4] A spunbond layer containing a propylene resin having a fiber diameter of 14.6 μηι was used and the basis weight was 12 g/m (spunbond-meltblown-solvent-spunbonded nonwoven fabric, hereinafter also referred to as SMMS). It is not woven. Next, the SMMS was not woven under the same conditions as in Example 1 to carry out a two-stage treatment to obtain a non-woven fabric. [Example 5] 156621.doc •53·201224239 The use of an ethylene-containing copolymer having a fiber diameter of 14.9 was contained. The tree-shaped adhesive layer has a weight per unit area of 18 g/m2 (spun-bonded-sprayed-spun layered non-woven fabrics, also referred to as _). In addition, the one-side spinning of the non-woven fabric of the job (4) is the middle layer (4) soft agent, and the side of the layer of the softener is kneaded with the layer of the softener to obtain the two-stage treatment under the same conditions as the embodiment (I). Not woven. [Example 6] A spunbond layer comprising a vinyl-propylene copolymer resin having a fiber diameter of 15·0 μm was used and the basis weight was 18 g/m 2 (spunbonded spunbond-spunbonded non-woven fabric) Also known as sss). Further, in the non-woven fabric of the sss, the softness was mixed, and the sss was not woven under the same conditions as in the example i to carry out a two-stage treatment to obtain a nonwoven fabric. [Example 7] A non-woven fabric having a spun point layer having a fiber diameter of propylene resin and having a basis weight of 18 Å (spunbonding, spunbonding, non-woven fabric, or SSS, hereinafter) was used. Next, the sss was not woven under the same conditions as in Example 1 to carry out a two-stage treatment to obtain a nonwoven fabric. [Comparative Example 1] A non-woven fabric (spunbond-meltblown-spunbonded layer) having a spunbond layer containing an ethylene-propylene copolymer resin having a fiber diameter of 14 7 (four) and having a basis weight of i5 was used in the same manner as in the case of m. Do not weave, the following is also called the circle. Secondly, in order to reproduce the needling treatment on the non-woven fabric, a pointed tweezers (manufactured by TWEEZERS, Pincette Κ-14, ώ (

1力自 5 cmx5 cn^sMS 不織布之上面側利用尖頭部分勾住不織布表面之纖維並將 J56621.doc -54- 201224239 該不織布表面之纖維 行30次而庐γ差而 ,而撕扯該纖維,將上述操作進 人而獲件表面之纖維浮起之不織布。 [比較例2] 與實施例1同樣地,使用 烯-丙煻丘咿札站 纖維徑為14.7 μηι之包含乙 ’、〇脂之紡黏層且單位面積重量為15 g/m2之 不織布(纺黏____ 積重里為15咖之 其次,對物^繼_。 用之切割方法係利用刹刀將③入:而獲付不織布。所使 黏不織布切斷。 /又錢中5分鐘而凍結之紡 [比較例3] 烯與貫施丘例i同樣地’使用具有纖維經為Μ 7叫之包含乙 八聚物樹脂之纺黏層且單位面積重量W⑽之 =布(纺黏-溶喷'紡黏積層不織布,以下亦稱為sms)。 =,㈣雙面膠帶,將We()Nakayama(股份)製造之砂 讀度賴接著至φ110之親之全周,於此輥之全周36〇度 之内以接觸角為8.5度之狀態抱合,且以i〇m/min_ SMS不織布。此時,接著有砂紙之輥係、以5Q 於與行 進方向相反之方向旋轉,而獲得使纖維斷裂之不織布。 [比較例4] 使用實施例i所使用之具有纖維徑為147哗之包含乙稀_ 丙烯共聚物樹脂之紡黏層且單位面積重量為15〆之不織 布(紡黏-熔喷·紡黏積層不織布,以下亦稱為sms)。尤其 是未進行起毛加 工。 [比較例5] 156621.doc •55· 201224239 使用實施例2所使用之具有纖維徑為177帅之包含丙稀 ^脂之纺黏層且單位面積重量為15〆之不織布(纺黏-溶 不織布’以下亦稱為SMS)。其次,為了於該1 force from 5 cmx5 cn^sMS The upper side of the non-woven fabric uses the pointed portion to hook the fiber on the surface of the non-woven fabric and J56621.doc -54- 201224239 The fiber on the non-woven surface is made 30 times and the 庐γ is poor, and the fiber is torn, The above operation is carried out to obtain a non-woven fabric in which the fibers on the surface of the member are floated. [Comparative Example 2] In the same manner as in Example 1, a non-woven fabric comprising a spunbond layer of B', blush and having a basis weight of 15 g/m2 having a fiber diameter of 14.7 μm was used. Viscosity ____ The weight is 15 for the second, and for the object ^ _. The cutting method is to use the brake knife to enter 3: and get the non-woven fabric. The sticky non-woven fabric is cut off. / The money is frozen for 5 minutes. Spinning [Comparative Example 3] The ene is the same as the schistosomiasis i. The use of a spunbond layer containing a fiber conjugate comprising an ethylene octapolymer resin and having a basis weight W (10) = spunbond-solvent Spunbonded non-woven fabric, hereinafter referred to as sms). =, (4) Double-sided tape, the sand reading degree of We() Nakayama (share) is followed by the pro-week of φ110, the whole week of this roll is 36〇 Within the degree of contact angle of 8.5 degrees, and weaving with i〇m/min_ SMS. At this time, the roller system of the sandpaper is rotated in the direction opposite to the traveling direction by 5Q, and the fiber is broken. Non-woven fabric [Comparative Example 4] The ethylene-containing propylene copolymer having a fiber diameter of 147 Å used in Example i was used. A non-woven fabric (spunbond-meltblown/spunbonded non-woven fabric, hereinafter also referred to as sms) with a weight per unit area of 15 Å. In particular, no pilling is performed. [Comparative Example 5] 156621.doc •55 · 201224239 The non-woven fabric (spunbond-dissolved fabric 'hereinafter referred to as SMS) having a spunbond layer of propylene and having a fiber diameter of 177 and having a basis weight of 15 使用 is used. For this

制生不 現針刺處理’使用尖㈣子(了抑咖RS 化,Pmcette K_14),自5咖5咖之⑽不織布之上面 側,利用尖頭部分勾住不織布表面之纖維並將該不織布表 ^纖維上拉’㈣扯該纖維’將上述操作進行3〇次而獲 得表面之纖維浮起之不織布。 [比較例6] /吏用實施例2所使用之具有纖維徑為之包含丙烯 樹脂之紡黏層且單位面積重量 喑㈣m 曲積重量為15 ^之不織布(紡黏-熔 纺黏積層不織布’以下亦稱為SMS)。尤其是未進行起 毛加工〇 [比較例7] 使用實施例3所使用之具有纖 另隹仫為12.9 μιη之包含乙烯- :稀共聚物樹脂之纺黏層且單位面積重量為Η—之不織 布(紡黏-紡黏-熔喷-紡勒镥思T W ‘ 貢'万黏積層不織布’以下亦稱為SSMS; 不織布之兩面之纺黏層中混練有柔軟劑)。尤盆是 未進行起毛加工。 〃 [比較例8] ^用實施例4所使用之具有纖維徑為心师之包含丙稀 =月曰之紡黏層且單位面積重量㈣g/m2(纺黏叫炫喷_ ^黏積層不織布,以下亦稱為s_s)之不織布。尤其是未 進行起毛加工。 >5662l.d〇c •56- 201224239 [比較例9] 使用實施例5所使用之具有纖維徑為149㈣之包含丙雄 樹脂之紡黏層且單位面積重量為18 g/m2(紡黏熔喷·紡黏 積層不織布,以下亦稱為SMS)之不織布。又,該sms之不 織布之單面之纺黏層中混練有柔軟劑。尤其是未進行起毛 加工。 [比較例1 〇] 使用實施例6所使用之具有纖維徑為15.0㈣之包含乙烯_ 丙稀共聚合樹脂之纺黏層且單位面積重量為i8 g/m2(纺t 纺黏·纺黏積層不織布’以下亦稱為SSS)之不織布… 該SSS之不織布中捏合有柔軟劑。尤其是未進行起毛加 工 〇 [比較例11 ] 使用實施例7所使用之具有纖維徑為14 m之 g/m2w^; '紡黏積層不織布,以下亦稱為sss)之不織布。尤其 疋未進行起毛加工。 、 [性能評價] 一實施例1〜7、比較例卜3、比較例5中所獲得之不織 徑之之測定法測定纖維徑,求出前端纖維 率’將所求出之前端纖維徑之增加比率為15% 之情形設為0,將未達15%之情形設為χ並示 表2、表3、表4。 針對實施例1〜7、比較例1〜3、比較例5中所獲得之 156621.doc .57· 201224239 不織布,藉由上述纖維徑之測定法,求出僅一端部2〇a利 用熱熔接部3予以固定之纖維20(自由端部2〇b變粗大之纖 維21及自由端部2〇b未變粗大之纖維22)中之自由端部2〇b 變粗大之纖維21的比率,將所求出之變粗大之纖維2ι之比 率為20%以上之情形設為〇,將未達織之情形設為χ並示 於表1、表2、表3、表4。 又,針對實施例1〜7、比較例1〜3、比較例5中所獲得之 不織布,藉由上述纖維徑之測定法,求出構成不織布之纖 維(僅一端部20a利用熱熔接部3予以固定之纖維2〇(自由端 部20b變粗大之纖維21及自由端部2〇b未變粗大之纖維 及環狀之纖維23)中之環狀之纖維23的比率,將所求出之 環狀之纖維23之比率小於50%之情形設為〇,將為5〇%以 上之情形設為X並示於表1、表2、表3、表4。 又,針對實施例1〜7、比較例1〜11中所獲得之不織布, 藉由上述纖維徑之分佈之測定法,求出不織布中之纖維徑 之分佈,將所4出之纖維徑之分佈為〇 33以上之情形設為 〇,將未達0,33之情形設為X並示於表1、表2、表3、表4。 [肌膚觸感之官能評價] 針對實施例1〜7、比較例1〜3、比較例5〜11中所獲得之不 織布,以比較例4之不織布作為基準(3分)時之1〇個等級之 (約接近10分肌膚觸感越好)官能評價,針對各不織布,求 出3片之平均值並四捨五入至整數位,若實施例丨〜?、比較 例1 3、比較例5中所獲得之不織布各自相對於各未處理之 不織布(實施例1與比較例5、實施例2與比較例6、比較例5 與比較例6、實施例3與比較例7、實施例4與比較例8、實 156621.doc •58· 201224239 施例5與比較例9、實施例6與比較例1 〇、實施例7與比較例 11、比較例1〜4與比較例5)而求出之官能評價之平均值有 所提昇,則設為〇’平均值無變化者設為X,並示於表1、 表2、表3、表4。 [斷裂強度之比之評價] 針對實施例1〜7、比較例1〜11中所獲得之不織布,藉由 上述斷裂強度之測定法,取得X方向(寬度方向)為2〇〇 mm 且γ方向(長度方向)為50 mm之測定樣品,利用夾頭間距設 為15〇 mm之拉伸試驗機(島津製作所製造)以3〇〇 mm/min之 拉伸速度進行拉伸,測定X方向(寬度方向)之強度,將4片 之平均值設為X方向(寬度方向)之強度。其次,測定實施 例1〜7、比較例1〜3、比較例5中所獲得之不織布之起毛加 工前之原本之不織布(例如對於實施例丨而言,為比較例5) 於X方向(寬度方向)上之強度,求出實施例卜7、比較例 1〜3、比較例5中所獲得之不織布與起毛加工前之原本之不 織布之斷裂強度之比,將所求出之比為5〇%以上之情形嗖 為〇’將未達50%之情形設為X並示於表1、表2、表3、表 4 〇 [脫毛性評價] 針對實施例1〜7、比較例1〜11中所獲得之不織布,取得 X方向(寬度方向)為200 mm且Y方向(縱向)為2〇〇功爪之螭 驗片,將該試驗片之一面作為評價面而進行評價。具體而 言,將該評價面朝上’’利用膠帶將試驗片之四邊固定至平 板上。套有海綿(Moltopren MF-30)之摩擦板設置於試驗片 上。海綿之荷重為240 g。將順時針旋轉3次、逆時針旋轉 156621.doc •59- 201224239 3次设為1組,使摩擦板旋轉。將旋轉進行。組。速度設為 3移旋轉1次°其後,使藉由上述旋轉而附著至海綿上之全 部纖維附著於透明黏著膠帶上。將該黏著膠帶貼在黑色襯 紙上。根據試驗片之表面狀態與附著於黏著膠帶上之纖 ,·隹依據以下基準目測評價脫毛之程度。將所獲得之結果 示於表1、表2、表3、表4。 〇.*式驗片上幾乎無絨毛及毛球。黏著膠帶上幾乎未附 著纖維。 △.试驗片上可見絨毛或毛球,但黏著膠帶上無塊狀纖 維。 X.4驗片上可見絨毛或毛球,黏著膠帶上大量可見塊 狀纖維。 又,針對實施例1〜7、比較例1〜丨丨中所獲得之不織布, 藉由上述微小荷重時之壓縮特性值之測定法,求出不織布 於微小荷重時之壓縮特性之值’將所求出之壓縮特性之值 為18·0 (gf/cm2)/mm以下之情形設為〇,將大於η 〇 (gf/cm2)/mm之情形設為x並示於表1、表2、表3、表4。 *又,針對實施例1〜7、比較例1Μ1中所獲得之不織布, 藉由上述起毛纖維之測定法,求出起毛纖維之根數,將所 求出之纖維之根數為8根/cm以上之情形設為〇,將小於8 根/cm之情形設為x並示於表1、表2、表3、表4。 又,針對實施例卜7、比較例i〜u中所獲得之不織布, 藉由上述起毛纖料高度之測定法,求以毛纖維之高 ,’將所求出之纖維高度為1.5 _以下之情形設為〇,將 高於1.5 mm之情形設為X並示於表1、表2、表3、表4。 156621.doc •60- 201224239 [表1] 單位 實施例1 1比較例1 比較例2丨比較例3 比較例4 自由端部之纖維徑之比率 (前端纖維徑之增加比率) % 37 I 2 -1 6 無 Ο 1 X X X 無 自由端部變粗大之纖維之 比率 60 10 0 30 無 — ο χ— X 〇 無 環狀之纖維之比率 % 38 68 0 33 無 〇 X 〇 〇 無 纖維徑之分佈 - 0.408 0.308 0.248 0.953 0.248 〇 X X 〇 - 肌膚觸感 分 6 3 3 6 3 〇 X X 〇 - X方向之斷裂強度 cN 910 1510 1510 671 1510 0(60%) 0(100%) 0(100%) Χ(44%) - 脫毛性 • 〇 〇 〇 X 〇 微小荷重時之壓縮特性值 (gf/cm2)/ mm 10.4 22 22.3 11.3 23.7 〇 X X 〇 X 起毛纖維之根數 根/cm 20 3 5 41 0 〇 X X 〇 X 起毛纖維之高度 mm 0.66 1.1 0.3 0.5 0 〇 〇 〇 〇 〇 [表2] 單位|實施例2 比較例5 比較例6 實施例3 比較例7 自由端部之纖維徑之比率 (前端纖維徑之增加比率) 15 -5 無 32 無 〇 X 無 〇 無 自由端部變粗大之纖維之 比率 % 50 0 無 60 無 〇 X 無 〇 無 環狀之纖維之比率 % 45 75 無 20 無 〇 X 無 〇 無 纖維徑之分佈 - 2.48 1.89 0.310 0.447 0.318 〇 〇 X 〇 X 肌膚觸感 分 3 2 2 8 4 〇 X 〇 X方向之斷裂強度 cN 832 1550 1628 1415 1777 0(51%) 0(95°/〇P - 0(80%) • 脫毛性 〇 〇 〇 〇 〇 微小荷重時之壓縮特性值 (gf/cm2)/ mm 11.9 22.1 23.8 10.8 25.8 〇 X X 〇 X 起毛纖維之根數 根/cm 15 10 0 18 0 〇 〇 X 〇 X 起毛纖維之高度 mm 0.5 1.64 0 0.57 0 〇 X 〇 〇 〇 . •61 · 156621.doc 201224239 [表3] 單位 實施例4 比較例8 實施例5 比較例9 自由端部之織維徑之比率 (前端纖維徑之增加比率) % 50 無 26 無 〇 無 〇 無 自由端部變粗大之纖維之比率 % 90 無 90 無 -ο 無 〇 無 環狀之纖維之比率 % 23 無 43 無 〇 無 〇 無 纖維徑之分佈 - 0.951 0.299 1.204 0.303 〇 X 〇 X 肌膚觸感 分 3 2 9 4 〇 _ 〇 - X方向之斷裂強度 cN 788 1394 1416 1888 0(57%) 0(75%) - 脫毛性 _ 〇 〇 〇 〇 微小荷重時之壓縮特性值 (gfi^cm2)/mm 12.3 16.6 10.9 25.8 〇 X 〇 X 起毛纖維之根數 ^/cm 10 0 11 0 〇 X 〇 X 起毛纖維之高度 mm 0.38 0 0.44 0 〇 〇 〇 〇 [表4] 單位 實施例6 比較例10 實施例7 比較例11 自由端部之纖維徑之比率 43 無 40 無 (前端纖維徑之增加比率) % 〇 無 〇 無 自由端部變粗大之纖維之 % 60 無 50 無 比率 〇 無 〇 無 環狀之纖維之比率 39 無 37 無 % 〇 無 〇 無 纖維徑之分佈 1.18 0.104 0.606 0.179 〇 X 〇 X 肌膚觸感 9 5 6 4 分 〇 〇 - X方向之斷裂強度 cN 1330 ]540 1260 1450 0(86%) OC87%) - 脫毛性 _ 〇 〇 〇 〇 微小荷重時之壓縮特性值 (gf/cm2)/mm 7.58 19.1 9.78 19.2 〇 X 〇 X 起毛纖維之根數 24 0 14 0 才艮/cm 〇 X 〇 X 起毛纖維之高度 0.69 0 0.32 0 mm 〇 〇 〇 156621.doc -62- 201224239 由表1所示之結果明讀得知:實施例!之不織布與比較例 1〜3之不織布相比,自由 _ 端部2〇b變粗大之纖維21之比率提 向。又’得知實施例1之不織布與比較例卜3之不織布相 比前端纖維徑之增加比率較高。進而,得知實施例1之 ^織布與比較例1〜3之不織布相比,環狀之纖維23之比率 較小,纖耗D佈亦較廣。實施⑷^織布與未處理 之比較例4之不織布相tb,肌膚觸感優異,斷裂強度之減 =較^不易脫毛或起毛球,獲得不會卡住皮膚之不織 另方面’得知比較例1、2之不織布與未處理之比較 例4之不織布相比’肌膚觸感之評價無變化,比較例3之不 織布與未處理之比較例4之不織布相比,雖然肌膚觸感有 所提昇’但斷裂強度明顯減少。上述實施例i之不織布與 未處理之比較例4之不織布相比肌膚觸感優異亦可根據如 下情況判斷:實施例i之不織布與未處理之比較例4之不織 布相比’微小荷重時之壓縮特性之值較低,起毛纖維之根 數較多。 又,由表2、表3、表4所示之結果明確得知:於使用構 成實施例1之不織布的成分不同之樹脂之情形、及與實施 例1之不織布相比變更單位面積重量、有無柔軟劑之實施 例2〜7之不織布,與實施例丨同樣地,與未處理之比較例 6〜9之不織布相比肌膚觸感有所提昇,獲得抑制了斷裂強 二減y的不織布。與實施例丨同樣地,肌膚觸感優異亦可 藉由如下情況判斷:實施例2〜7之不織布與未處理之比較 例6〜11之不織布相比,微小荷重時之壓縮特性之值較低, 】5662 l.doc •63- 201224239 起毛纖維之根數較多。其中,如比較例5之不織布般,即 使起毛纖維之根數多於未處理之比較例6之不織布,但若 起毛纖維之高度變得過高’則肌膚觸感之評價變差。又, 得知若於樹脂中混練乙烯-丙烯共聚物或柔軟劑,則肌膚 觸感會變得更加良好。又,實施例6、7之不織布由於微小 锜重時之壓縮特性值良好,故而獲得肌膚觸感良好之結 果。 [實施例8] 使用具有包含乙烯-丙烯共聚物樹脂之紡黏不織布之層 且單位面積重量為15 g/m2、1.3 dtex、熱壓接部(由壓花產 生之熱溶接部)之面積率為15%之SMS不織布。獲得藉由圖 9〜圖12所示之上述加工方法實施起毛加工的實施例8之不 織布。所使用之鋼模壓花輥23之輥上之各凸部21〇的高度 為2.8 mm,輥21之各凸部210與輥22之各凸部之嚙合之深 度D為2.7 mm。又,機械延伸倍率為2 9倍,於旋轉軸方向 上相鄰之凸部210彼此之距離(間距p2)為7 mm,於圓周方 向上相鄰之凸部210彼此之距離(間距Ρι)為7 mm。鋼模壓 花輥之圓周速度V2為20 m/min,不織布之搬送速度¥1為26 m/rnin。又,起毛所使用之凸輥31之各凸部31〇之高度為 0.6 mm,於旋轉軸方向上相鄰之凸部彼此之距離(間距)為 1.4 mm,於圓周方向上相鄰之凸部彼此之距離(間距)為21 mm。不織布之搬送速度V3為2〇 m/min,於相對於不織布 之搬送方向之反方向上以4倍之圓周速度乂4旋轉凸輥31。 抱角為13 0度。於貫施例8中,僅於單面起毛。不織布之總 156621.doc -64 - 201224239 延伸倍率為1.7倍。不織布之熱壓接部之間距與凹凸輥之 凸部之間距之比(不織布之熱壓接部之間距/凸部之間距)於 MD方向(親圓周方向)上為〇43 ’於CD方向(輕旋轉轴方向) 上為〇·37。不織布之熱壓接部之面積率與不織布之總延伸 倍率之比為0.088。 " [實施例9] 使用具有包含丙烯樹脂之紡黏不織布之層且單位面積重 量為13 g/m2、纖維徑為15·9 μΓη、熱壓接部(由壓花產生之 熱熔接部)之面積率為13%之SMS不織布。實施與實施例8 相同之條件之加I ’獲得實施例9之不織布。不織布之總 延伸倍率為1.7倍。不織布之熱壓接部之間距與凹凸輥之 凸部之間距之比(不織布之熱壓接部之間距/凸部之間距)於 MD方向(輥圓周方向)上為〇41 ’於⑶方向(觀旋轉轴方向) 上為0.24。不織布之熱麼接部之面積率與不織布之總延伸 倍率之比為0.076。 [實施例10] s使用具有包含丙烯樹脂之紡黏不織布之層且單位面積重 1為18 g/m、1.8 dtex、熱塵接部(由塵花產生之執炫接 部)之面積率為的麟喷層而僅有紡黏層之不織;。實 施與實施例8相同之條件之加工,獲得實施例ι〇之不織 布。不織布之總延伸倍率為口倍。不織布之㈣接部之 間距與凹凸輥之凸部之間距之比(不織布之熱壓接部之間 距/凸部之間距)於MD方向(輥圓周方向)上為〇3,於⑶方 向(輥旋轉軸方向)上為〇·3。不織布之熱屋接部之面積率與 156621 .doc -65· 201224239 不織布之總延伸倍率之比為0.071。 [實施例11 ] 與實施例8同樣地’使用具有包含乙烯_丙稀共聚物樹脂 之紡黏不織布之層且單位面積重量為15 g/m2、Μ ^之 SMS不織布。與實施例8同樣地進行利用鋼模壓花報之加 工。不織布之總延伸倍率為1>7倍。不織布之熱壓接部之 間距與凹凸輥之凸部之間距之比(不織布之熱壓接部之間 距/凸部之間距)於MD方向(輥圓周方向)上為〇 43,kCD方 向(輥旋轉軸方向)上為〇.37。不織布之熱壓接部之面積率 與不織布之總延伸倍率之比為〇 〇88。其後,起毛係使用 突起高度最大約為0.07 mm且突起之密度約為2000個/cm2 之凸輥。不織布之搬送速度V3為20 m/min,於相對於不織 布之搬送方向之反方向上以4倍之圓周速度V4旋轉凸報 3 1。抱角為60度。於實施例11中,亦僅於單面起毛。 [比較例12] 與實施例8同樣地’使用具有包含乙烯-丙烯共聚物樹脂 之紡黏不織布之層且單位面積重量為15 g/m2、ι·3 ^以之 SMS不織布作為比較例12之不織布。 [比較例13 ] 與實施例8同樣地,使用具有包含乙烯-丙烯共聚物樹脂 之紡黏不織布之層且單位面積重量為15 g/m2、1.3 dtex之 SMS不織布。其次,利用雙面膠帶,將Trusco Nakayama (股份)製砂紙粒度#240接著至φ110之輥之全周上,於此報 之全周360度之内以接觸角為8·5度之狀態進行抱合,以10 156621.doc • 66· 201224239 m/min饋進該SMS不織布 m/min於與行進方向相反 較例13之不織布。 此時,將接著有砂紙 之方向旋轉進行起毛, 之輥以4〇 而獲得比 [比較例14] 丙烯樹脂之紡黏不織 纖維徑為15.9 μη之 與實施例9同樣地,使用具有包含 布之層且單位面積重量為13 g/m2、 SMS不織布作為比較例14之不織布。 [比較例15] 與實施例9同樣地’使用具有包含丙稀樹脂之纺黏不織 布之層且單位面積重量為13 g/m2、纖維徑為15 9从爪之 SMS不織布。其次,實施與比較例13相同條件之加工,獲 得比較例15之不織布。 [比較例16] 與實施例10同樣地,使用具有包含丙稀樹脂之紡黏不織 布之層且單位面積重量為18 g/m2、I.8 dtex的無炼嘴層而 僅有紡黏層之不織布作為比較例16之不織布。 [比較例17] 與實施例1 〇同樣地,使用具有包含丙稀樹脂之紡黏不織 布之層且單位面積重量為18 g/m2、1.8 dtex的無熔噴層而 僅有紡黏層之不織布。其次’實施與比較例13相同條件之 加工,獲得比較例17之不織布。 性能評價 [肌膚觸感之官能評價] 針對實施例8〜11、比較例12〜16中所獲得之不織布,進 156621.doc •67· 201224239 之10個等級之(越The acupuncture treatment is not used. The use of the tip (four) sub- (Rickey RS, Pmcette K_14), from the upper side of the 5 coffee 5 (10) non-woven fabric, using the pointed portion to hook the fiber of the non-woven surface and the non-woven table ^Fiber Pulling '(4) Pulling the Fiber' The above operation was carried out 3 times to obtain a non-woven fabric in which the fibers of the surface were floated. [Comparative Example 6] / Non-woven fabric (spunbond-melt-spun-bonded non-woven fabric) having a spunbond layer containing a propylene resin and having a basis weight of 喑(4)m and a basis weight of 15^ used in Example 2 Also referred to below as SMS). In particular, no raising process was carried out [Comparative Example 7] A non-woven fabric having a spunbond layer containing an ethylene-: dilute copolymer resin having a fiber enthalpy of 12.9 μm and having a basis weight of Η-using was used. Spunbond-spun-melt-melt-spinning TW' Gong' Wan's non-woven fabric 'hereinafter referred to as SSMS; non-woven fabric on both sides of the spunbond layer has a softening agent). Yupen is not raised. 〃 [Comparative Example 8] ^The spunbond layer containing the fiber diameter of the exemplified propylene = sapphire used in Example 4 and the weight per unit area (four) g/m2 (spun squeegee _ ^ adhesion layer non-woven fabric, The following is also referred to as s_s) non-woven fabric. In particular, no raising is carried out. >5662l.d〇c •56- 201224239 [Comparative Example 9] The spunbond layer containing the propylene male resin having a fiber diameter of 149 (four) and having a basis weight of 18 g/m 2 (spun fused) was used as used in Example 5. The non-woven fabric of the spray-spun adhesive layer non-woven fabric, hereinafter also referred to as SMS). Further, a softener is mixed in the single-side spun layer of the sms. In particular, no raising is carried out. [Comparative Example 1 使用] A spunbond layer comprising an ethylene-propylene copolymer resin having a fiber diameter of 15.0 (4) and having a basis weight of i8 g/m 2 (spun t-spun viscose-spun layer) was used. Non-woven fabric of non-woven fabric 'hereinafter referred to as SSS'... The softening agent is kneaded in the non-woven fabric of SSS. In particular, no raising work was carried out. [Comparative Example 11] A non-woven fabric having a fiber diameter of 14 m g/m2w^; a spunbonded non-woven fabric (hereinafter also referred to as sss) used in Example 7 was used. In particular, pilling is not carried out. [Performance Evaluation] The fiber diameters were measured by the measurement methods of the nonwoven diameters obtained in Examples 1 to 7, Comparative Example 3, and Comparative Example 5, and the fiber diameter at the tip end was determined. The case where the increase ratio is 15% is set to 0, and the case where the increase ratio is 15% is set to χ and Table 2, Table 3, and Table 4 are shown. With respect to Examples 1 to 7 and Comparative Examples 1 to 3 and Comparative Example 5, 156621.doc.57·201224239 non-woven fabric, the fiber diameter measurement method was used to determine that only one end portion 2〇a was thermally welded. (3) The ratio of the fibers 21 which are fixed to the fiber 20 (the fiber 21 whose free end portion 2〇b becomes coarse and the fiber 22 whose free end portion 2〇b is not coarsened) becomes larger and larger than the fiber 21 of the free end portion 2〇b The case where the ratio of the fiber 2i which is coarsened to 20% or more is determined is 〇, and the case where the woven fabric is not woven is set to χ and shown in Table 1, Table 2, Table 3, and Table 4. Further, with respect to the nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3 and Comparative Example 5, fibers constituting the nonwoven fabric were obtained by the measurement method of the fiber diameter (only one end portion 20a was used by the heat fusion portion 3) The ratio of the ring-shaped fibers 23 in the fixed fiber 2〇 (the fiber 21 of the free end 20b and the fiber 24 and the ring 23 of the free end 2〇b) The case where the ratio of the fibers 23 is less than 50% is 〇, and the case where the ratio is 5 〇% or more is X and is shown in Table 1, Table 2, Table 3, and Table 4. Further, for Examples 1 to 7, In the non-woven fabrics obtained in Comparative Examples 1 to 11, the distribution of the fiber diameters in the nonwoven fabric was determined by the measurement of the distribution of the fiber diameters, and the distribution of the fiber diameters of the four fibers was set to 〇33 or more. In the case where the ratio is less than 0, 33, it is shown in Table 1, Table 2, Table 3, and Table 4. [Functional Evaluation of Skin Touch] For Examples 1 to 7, Comparative Examples 1 to 3, and Comparative Examples The non-woven fabric obtained in 5 to 11 is one level at the time of the non-woven fabric of Comparative Example 4 (3 points) (about 10 minutes, the touch of the skin is more Good) Functional evaluation, for each non-woven fabric, the average of the three pieces was determined and rounded to the whole number, and the non-woven fabrics obtained in the examples 丨~?, the comparative example 13 and the comparative example 5 were each untreated with respect to each untreated fabric. (Example 1 and Comparative Example 5, Example 2 and Comparative Example 6, Comparative Example 5 and Comparative Example 6, Example 3 and Comparative Example 7, Example 4 and Comparative Example 8, and 156621.doc • 58·201224239 When the average value of the sensory evaluations obtained in Example 5, Comparative Example 9, Example 6 and Comparative Example 1 实施, Example 7 and Comparative Example 11 and Comparative Examples 1 to 4 and Comparative Example 5) was improved, it was set as 〇 'The average value is unchanged, and is set to X, and is shown in Table 1, Table 2, Table 3, and Table 4. [Evaluation of Ratio of Breaking Strength] For Examples 1 to 7 and Comparative Examples 1 to 11, In the non-woven fabric, a measurement sample having an X direction (width direction) of 2 mm and a γ direction (longitudinal direction) of 50 mm was obtained by the above-described measurement method of breaking strength, and a tensile test with a chuck pitch of 15 mm was used. The machine (manufactured by Shimadzu Corporation) was stretched at a tensile speed of 3 〇〇mm/min, and the X direction was measured ( In the intensity of the degree, the average of the four sheets was set to the intensity in the X direction (width direction). Next, before the raising process of the nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3 and Comparative Example 5 was measured. The original non-woven fabric (for example, Comparative Example 5 in the Example )) was obtained in the X direction (width direction), and the non-woven fabric obtained in Example 7, Comparative Examples 1 to 3, and Comparative Example 5 was obtained. The ratio of the breaking strength of the original non-woven fabric before the raising process is 5%, and the case where the ratio is less than 50% is set as X and is shown in Table 1, Table 2. Table 3 and Table 4 〇 [Evaluation of Hair Removal] The non-woven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 11 were obtained in the X direction (width direction) of 200 mm and the Y direction (longitudinal direction). The test piece of the test piece was evaluated by using one of the test pieces as the evaluation surface. Specifically, the evaluation surface was turned upside by the tape to fix the four sides of the test piece to the flat plate. A friction plate provided with a sponge (Moltopren MF-30) was placed on the test piece. The load of the sponge is 240 g. Rotate clockwise 3 times and counterclockwise 156621.doc •59- 201224239 3 times set to 1 set to rotate the friction plate. The rotation will proceed. group. The speed was set to 3 shifts and rotated once. Thereafter, all the fibers attached to the sponge by the above rotation were attached to the transparent adhesive tape. Apply the adhesive tape to the black liner. According to the surface state of the test piece and the fiber attached to the adhesive tape, the degree of hair removal was evaluated visually according to the following criteria. The results obtained are shown in Table 1, Table 2, Table 3, and Table 4. 〇.* The test piece has almost no fluff and hair balls. There is almost no fiber attached to the adhesive tape. △. The fluff or hair ball is visible on the test piece, but there is no lump fiber on the adhesive tape. The fluff or hair ball can be seen on the X.4 test piece, and a large amount of blocky fiber is visible on the adhesive tape. Further, with respect to the non-woven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to ,, the value of the compression characteristics when the non-woven fabric was applied to the micro load was determined by the measurement method of the compression characteristic value at the time of the micro load. The case where the value of the compression characteristic obtained is 18·0 (gf/cm 2 )/mm or less is set to 〇, and the case where η 〇 (gf/cm 2 )/mm is larger is set as x and is shown in Table 1, Table 2, Table 3 and Table 4. * For the nonwoven fabrics obtained in Examples 1 to 7 and Comparative Example 1Μ1, the number of the raised fibers was determined by the measurement method of the raised fibers, and the number of fibers obtained was 8 pieces/cm. The above case is set to 〇, and the case of less than 8 pieces/cm is set to x and is shown in Table 1, Table 2, Table 3, and Table 4. Further, with respect to the non-woven fabric obtained in Example 7 and Comparative Examples i to u, the height of the fiber was determined by the height measurement method of the raising fiber, and the fiber height determined was 1.5 _ or less. The case is set to 〇, and the case where the value is higher than 1.5 mm is set to X and is shown in Table 1, Table 2, Table 3, and Table 4. 156621.doc •60-201224239 [Table 1] Unit Example 1 1 Comparative Example 1 Comparative Example 2 丨 Comparative Example 3 Comparative Example 4 Ratio of fiber diameter at the free end portion (increased ratio of the tip end fiber diameter) % 37 I 2 - 1 6 无Ο 1 XXX Ratio of fibers without free ends. 60 10 0 30 None — ο χ — X 〇 ratio of non-annular fibers% 38 68 0 33 No 〇 X 〇〇 no fiber diameter distribution - 0.408 0.308 0.248 0.953 0.248 〇XX 〇- Skin touch is 6 3 3 6 3 〇XX 〇- Breaking strength in the X direction cN 910 1510 1510 671 1510 0(60%) 0(100%) 0(100%) Χ( 44%) - Depilation • 压缩X 压缩 Compressive characteristic value at minute load (gf/cm2) / mm 10.4 22 22.3 11.3 23.7 〇XX 〇X Number of roots of hair fiber/cm 20 3 5 41 0 〇XX 〇X Height of raised fiber mm 0.66 1.1 0.3 0.5 0 〇〇〇〇〇 [Table 2] Unit | Example 2 Comparative Example 5 Comparative Example 6 Example 3 Comparative Example 7 Ratio of fiber diameter at the free end (front end fiber diameter) Increase ratio) 15 -5 No 32 No 〇X No 〇 no ratio of fibers with free ends % 50 0 无 60 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无 无8 4 〇X 〇X direction breaking strength cN 832 1550 1628 1415 1777 0(51%) 0(95°/〇P - 0(80%) • Depilation 〇〇〇〇〇Symmetric load value at minute load ( Gf/cm2)/ mm 11.9 22.1 23.8 10.8 25.8 〇XX 〇X Roots of raised fibers/cm 15 10 0 18 0 〇〇X 〇X Height of raised fibers mm 0.5 1.64 0 0.57 0 〇X 〇〇〇. 61 · 156621.doc 201224239 [Table 3] Unit Example 4 Comparative Example 8 Example 5 Comparative Example 9 Ratio of the weave diameter at the free end (increased ratio of the fiber diameter at the tip end) % 50 No 26 No flaws, no freedom The ratio of the fiber which becomes thicker at the end% 90 No 90 No - ο The ratio of the fiber without ring and no ring % 23 No 43 The distribution of the fiber without fiber flaws - 0.951 0.299 1.204 0.303 〇X 〇X Skin touch points 3 2 9 4 〇 _ 〇 - breaking strength in the X direction cN 788 1394 14 16 1888 0(57%) 0(75%) - Depilation _ 压缩 Compressive characteristic value at minute load (gfi^cm2)/mm 12.3 16.6 10.9 25.8 〇X 〇X Number of hair fibers ^/cm 10 0 11 0 〇X 〇X Height of raised fibers mm 0.38 0 0.44 0 〇〇〇〇 [Table 4] Unit Example 6 Comparative Example 10 Example 7 Comparative Example 11 Ratio of fiber diameter at the free end 43 None 40 (increased ratio of fiber diameter at the front end) % 〇 No fiber without fiber at the free end. 60 No 50 No ratio 〇 No 〇 No ring fiber ratio 39 No 37 No % 〇 No 〇 no fiber diameter distribution 1.18 0.104 0.606 0.179 〇X 〇X Skin feel 9 5 6 4 分〇〇 - X-direction breaking strength cN 1330 ]540 1260 1450 0(86%) OC87%) - Hair removal _ 〇〇〇〇 Minor load Compressive property value (gf/cm2)/mm 7.58 19.1 9.78 19.2 〇X 〇X Number of raised fibers 24 0 14 0 艮/cm 〇X 〇X Height of raised fibers 0.69 0 0.32 0 mm 〇〇〇156621.doc -62- 201224239 The results shown in Table 1 are clearly read: ExamplesThe non-woven fabric was compared with the non-woven fabrics of Comparative Examples 1 to 3, and the ratio of the fibers 21 which were free from the end portion 2〇b was raised. Further, it was found that the non-woven fabric of Example 1 had a higher ratio of increase in the front end fiber diameter than the non-woven fabric of Comparative Example 3. Further, it was found that the nonwoven fabric of Example 1 had a smaller ratio of the looped fibers 23 and a wider fiber D fabric than the nonwoven fabrics of Comparative Examples 1 to 3. The (4)^ weaving cloth and the untreated comparative example 4 non-woven fabric phase tb, the skin feels excellent, the breaking strength is reduced = it is not easy to depilate or fluff the ball, and the non-woven is not stuck. The non-woven fabrics of Examples 1 and 2 had no change in the evaluation of the skin feel compared to the untreated nonwoven fabric of Comparative Example 4, and the non-woven fabric of Comparative Example 3 was improved in the touch of the skin as compared with the non-woven fabric of Comparative Example 4 which was not treated. 'But the breaking strength is significantly reduced. The non-woven fabric of the above Example i was superior to the untreated nonwoven fabric of Comparative Example 4 in that the skin feel was excellent. The non-woven fabric of Example i was compared with the non-woven fabric of Comparative Example 4 which was untreated. The value of the characteristic is lower, and the number of the raised fibers is larger. Further, from the results shown in Tables 2, 3, and 4, it is clear that the resin having a different composition of the non-woven fabric of the first embodiment is used, and the unit weight is changed or not compared with the non-woven fabric of the first embodiment. In the non-woven fabrics of Examples 2 to 7 of the softening agent, as compared with the non-woven fabrics of Comparative Examples 6 to 9 which were not treated, the touch of the skin was improved, and a non-woven fabric in which the breaking strength was reduced by y was obtained. In the same manner as in Example ,, the skin feel was excellent, and it was judged that the non-woven fabrics of Examples 2 to 7 had lower compression characteristics at a minute load than the non-woven fabrics of Comparative Examples 6 to 11 which were not treated. , 5662 l.doc •63- 201224239 The number of raised fibers is large. In the case of the non-woven fabric of Comparative Example 5, even if the number of the raised fibers was larger than that of the untreated nonwoven fabric of Comparative Example 6, the height of the raised fibers became too high, and the evaluation of the skin feel was deteriorated. Further, it has been found that when the ethylene-propylene copolymer or the softener is kneaded in the resin, the skin feel is further improved. Further, in the non-woven fabrics of Examples 6 and 7, since the compression property value was small when the weight was small, the skin feel was good. [Example 8] An area ratio of a layer having a spunbonded nonwoven fabric containing an ethylene-propylene copolymer resin and having a basis weight of 15 g/m2, 1.3 dtex, and a thermocompression bonded portion (heat-bonded portion by embossing) was used. 15% of SMS is not woven. A nonwoven fabric of Example 8 in which the raising process was carried out by the above-described processing method shown in Figs. 9 to 12 was obtained. The height of each convex portion 21A on the roller of the steel mold embossing roll 23 used was 2.8 mm, and the depth D of the engagement between each convex portion 210 of the roller 21 and each convex portion of the roller 22 was 2.7 mm. Further, the mechanical stretching ratio is 29 times, the distance (pitch p2) between the adjacent convex portions 210 in the direction of the rotation axis is 7 mm, and the distance (pitch Ρ) between the convex portions 210 adjacent in the circumferential direction is 7 mm. The circumferential speed V2 of the steel molding roll is 20 m/min, and the conveying speed of the non-woven fabric is ¥1 to 26 m/rnin. Further, the height of each convex portion 31 of the convex roller 31 used for raising is 0.6 mm, and the distance (pitch) between the adjacent convex portions in the direction of the rotation axis is 1.4 mm, and the convex portions adjacent in the circumferential direction The distance (pitch) from each other is 21 mm. The conveyance speed V3 of the nonwoven fabric was 2 〇 m/min, and the convex roller 31 was rotated at a peripheral speed 乂4 of 4 times with respect to the conveyance direction of the nonwoven fabric. The angle of the hug is 13 degrees. In Example 8, only one side was raised. Total non-woven fabric 156621.doc -64 - 201224239 The extension ratio is 1.7 times. The ratio of the distance between the thermocompression portions of the non-woven fabric and the convex portion of the uneven roller (the distance between the thermocompression portions of the non-woven fabric/the distance between the convex portions) is 〇43' in the CD direction in the MD direction (the pro-circular direction) ( The direction of the light axis is 〇·37. The ratio of the area ratio of the non-woven thermal crimping portion to the total stretch ratio of the non-woven fabric is 0.088. <Example 9] A layer having a spunbonded nonwoven fabric containing an acrylic resin and having a basis weight of 13 g/m 2 , a fiber diameter of 15.9 μΓ, and a thermocompression bonded portion (heat-welded portion by embossing) The SMS area is 13% non-woven. The nonwoven fabric of Example 9 was obtained by the same conditions as in Example 8. The total stretch ratio of non-woven fabric is 1.7 times. The ratio of the distance between the thermocompression bonding portions of the non-woven fabric and the convex portion of the uneven roller (the distance between the thermocompression portions of the non-woven fabric/the distance between the convex portions) is 〇41' in the (3) direction in the MD direction (the circumferential direction of the roller) The direction of the rotation axis is 0.24. The ratio of the area ratio of the non-woven fabric to the total extension ratio of the non-woven fabric is 0.076. [Example 10] s using a layer having a spunbonded nonwoven fabric containing a propylene resin and having an area ratio of a weight of 1 g of 18 g/m, 1.8 dtex, and a hot dust joint (a brilliant portion produced by dust) The lining of the lining and only the woven layer is not woven; The processing under the same conditions as in Example 8 was carried out to obtain a non-woven fabric of Example ι. The total stretch ratio of non-woven fabric is doubled. The ratio between the distance between the (4) joints of the non-woven fabric and the convex portion of the uneven roller (the distance between the thermocompression joints of the non-woven fabric/the distance between the convex portions) is 〇3 in the MD direction (roller circumferential direction), and the (3) direction (roller) The direction of the rotation axis is 〇·3. The ratio of the area ratio of the non-woven hot-shell joint to the total stretch ratio of the 156621 .doc -65· 201224239 non-woven fabric is 0.071. [Example 11] An SMS non-woven fabric having a layer of a spunbonded nonwoven fabric comprising an ethylene-propylene copolymer resin and having a basis weight of 15 g/m2, Μ^ was used in the same manner as in Example 8. The processing by the steel stamp embossing was carried out in the same manner as in the eighth embodiment. The total stretch ratio of non-woven fabric is 1 > 7 times. The ratio of the distance between the thermocompression portions of the non-woven fabric and the convex portion of the uneven roller (the distance between the thermocompression portions of the non-woven fabric/the distance between the convex portions) is 〇43 in the MD direction (the circumferential direction of the roller), and the kCD direction (roller) The direction of the rotation axis is 〇.37. The ratio of the area ratio of the non-woven thermal crimping portion to the total stretch ratio of the non-woven fabric is 〇 〇 88. Thereafter, the fuzzing system uses a convex roller having a projection height of at most about 0.07 mm and a projection density of about 2000/cm2. The conveyance speed V3 of the non-woven fabric was 20 m/min, and the projection 3 1 was rotated at a peripheral speed V4 of 4 times with respect to the conveyance direction of the non-woven fabric. The angle of hug is 60 degrees. In Example 11, only one side was raised. [Comparative Example 12] In the same manner as in Example 8, an SMS non-woven fabric having a layer of a spunbonded nonwoven fabric containing an ethylene-propylene copolymer resin and having a basis weight of 15 g/m 2 and 10 μm was used as Comparative Example 12. Not woven. [Comparative Example 13] In the same manner as in Example 8, an SMS nonwoven fabric having a layer of a spunbonded nonwoven fabric comprising an ethylene-propylene copolymer resin and having a basis weight of 15 g/m2 and 1.3 dtex was used. Next, using a double-sided tape, Trusco Nakayama (share) sandpaper size #240 is applied to the entire circumference of the roll of φ110, and the contact angle is 8.5 degrees within 360 degrees of the full circumference of the report. The SMS non-woven fabric m/min was fed at 10 156621.doc • 66·201224239 m/min in a non-woven fabric of Example 13 opposite to the traveling direction. At this time, the fleece was rotated in the direction of the sandpaper, and the roll was obtained in a ratio of 4 μ to [Comparative Example 14], and the spunbonded nonwoven fiber diameter of the acryl resin was 15.9 μη. The layer had a basis weight of 13 g/m2, and SMS non-woven fabric was used as the non-woven fabric of Comparative Example 14. [Comparative Example 15] An SMS non-woven fabric having a layer having a spunbonded nonwoven fabric comprising an acryl resin and having a basis weight of 13 g/m 2 and a fiber diameter of 15 9 was used in the same manner as in Example 9. Next, the same conditions as in Comparative Example 13 were carried out, and a non-woven fabric of Comparative Example 15 was obtained. [Comparative Example 16] In the same manner as in Example 10, a non-refining layer having a layer of a spunbonded nonwoven fabric containing an acryl resin and having a basis weight of 18 g/m2 and 1.8 dtex was used, and only a spunbond layer was used. Nonwoven fabric was used as the non-woven fabric of Comparative Example 16. [Comparative Example 17] A non-woven fabric having a sputter-free layer having a layer of a spunbonded nonwoven fabric comprising an acryl resin and having a basis weight of 18 g/m2 and 1.8 dtex and having only a spunbond layer was used in the same manner as in Example 1 . Next, the same conditions as in Comparative Example 13 were carried out to obtain a nonwoven fabric of Comparative Example 17. Performance evaluation [Functional evaluation of skin touch] For the nonwoven fabrics obtained in Examples 8 to 11 and Comparative Examples 12 to 16, 10 grades of 156621.doc •67·201224239 were entered.

設為〇’彳均值無變化者設為χ ’並示於表5、表6、表 行以比較例12之不織布作為基準(3分)時 接近10分肌膚觸感越好)官能評價,針對 片之平均值並四捨五入至整數位,若實匆 [起毛之構成纖維之評價] 比較例12〜16中所獲得之不織布,藉 針對實施例8〜11、 由上述起毛之構成纖維之根數之測定方法,測定起毛之構 成纖維之根數。將起毛之構成纖維之根數為1〇根以上之情 形設為〇,將20根以上之情形設為◎,將未達1〇根之情形 5又為χ並示於表5、表6、表7。 [斷裂強度之評價] 針對實施例8〜11、比較例12〜16中所獲得之不織布藉 由上述斷裂強度之測定法,取得X方向(寬度方向、CD方 向)上為200 mm且γ方向(長度方向、MD方向)上為5〇 之測定樣品’利用夾頭間距為丨5〇 mm之拉伸試驗機(島津 製作所製造)’以300 mm/min之拉伸速度進行拉伸,測定χ 方向(寬度方向、CD方向)之強度,將4片之平均值設為乂方 向(寬度方向、CD方向)之強度。其次,將相對於各未處理 之不織布(實施例8與比較例12、實施例9與比較例14、實 156621.doc •68· 201224239 施例10與比較例16、比較例13與比較例12、比較例15與比 較例14、比較例17與比較例16)、X方向(寬度方向、CD方 向)之強度之比為50%以上之情形設為〇,將未達50%之情 形設為X並示於表5、表6、表7。 [表5] 單位 實施例8 比較例12 比較例13 實施例11 肌膚觸感 分 7 3 6 8 〇 X 〇 〇 起毛量 根/cm 20.2 - 48.7 14.7 ◎ X ◎ 〇 X方向之斷裂強度 cN 1120 1520 750 1180 0(73%) 0(100%) χ(49°/〇) 0(77%) [表6] 單位 實施例9 比較例14 比較例15 肌膚觸感 分 3 1 1 〇 X X 起毛量 根/cm 23.7 - 14.8 ◎ X 〇 X方向之斷裂強度 cN 750 1150 1040 0(65%) 0(100%) 0(90%) [表7] 單位 實施例10 比較例16 比較例17 肌膚觸感 分 3 1 1 〇 X X 起毛量 根/cm 16.3 - 19.2 〇 X 〇 X方向之斷裂強度 cN 1120 1730 1760 0(65%) 0(100%) 0(102%) 由表5所示之結果明確得知:實施例8之不織布係肌膚觸 感優異,斷裂強度減少亦較少之不織布。具體而言,得知 實施例8之不織布與比較例12之不織布相比,肌膚觸感大 156621.doc -69- 201224239 為提昇。另-方面,得知比較例13之不織布與比較例以 不織布相比,雖然肌膚觸感變得良好,但斷裂強度之減少 明顯。關於實施例8之不織布,多數起毛之纖維並非環 狀,而是端部被切斷,亦未被指尖勾住。又,輥部上未見 纖維碎頭而良好。另_ 士工 , ^另方面,於製造比較例13之不織布 時,砂紙上可見纖維碎頭之附著,於砂紙之耐久性方面亦 產生問題。 由表6所示之結果明確:實施例9之不織布亦與實施例8 之不織布同樣地,係肌膚觸感有所提昇,斷裂強度減少亦 較少之不織布。具體而言,比較例丨5之不織布與原本之比 較例14之不織布相比,斷裂強度雖然並未太過降低,但未 見肌膚觸感之提昇,僅實施例9之不織布與原本之比較例 14之不織布相比肌膚觸感提昇,斷裂強度減少亦獲得抑 制。 由表7所示之結果明確:實施例10之不織布亦與實施例8 之不織布同樣地,係肌膚觸感有所提昇,斷裂強度減少亦 較少之不織布。具體而言,比較例17之不織布與原本之比 較例16之不織布相比’斷裂強度雖然並未太過降低,但未 見肌膚觸感之提昇,僅實施例10之不織布與原本之比較例 16之不織布相比肌膚觸感提昇,斷裂強度減少亦獲得抑 制。 產業上之可利用性 根據本發明之不織布,儘管斷裂強度較高,全體亦有柔 軟感’肌膚觸感提昇。又,根據本發明之不織布,環狀之 15662l.doc -70· 201224239 纖維較少,不易卡住皮膚,肌膚觸感提昇。 又’根據本發日m織布之製造方法,可獲得構成纖維 起毛之肌膚觸感良好之不織布,並且可獲 ^ 亚且』摱得減輕所獲得之 起毛不織布之不織布斷裂強度之降低的不織布。又,根據 本發明之不織布之製造μ,可獲得構成纖㈣毛之不織 布並且製造速度較快可抑制成本。 、 【圖式簡單說明】 圖1係表示本發明之不織布之一實施形態的立體圖。 圖2係表示圖!所示之不織布所具有之自由 纖維的立體圖。 雙祖大之 圆3係表示用於製造圖i所示之不織布之較佳裝置的 圖0 圖4係表示用於製造圖丨所示 1 〈+織布之較佳裝置的模式 圖0 圖5⑷〜圖5⑷係表示測定本發明之不織布前端纖維徑之 方法的模式圖。 不織布之起毛纖維根數 圖6(a)〜圖6(c)係表示測定本發明 之方法的模式圖。 圖7係用於說明本發明之不織布之使用形態之例的圖, 係表示展開内褲型拋棄式尿布而使之伸長之狀態的展開平 面圖。 圖8係圖7之χι·χι線剖面圖。 圖9係表示本發明之不織布製 衣坆方法所使用之較佳加 工裝置的模式圖。 156621.doc •71- 201224239 所具有之部分延 要部分之放大刮 圖10係自斜向觀察圖9所示之加工裝置 伸加工部的模式圖。 圖11係圖10所示之部分延伸加工部之主 面圖。 圖12係自斜向觀察圖9所示之加 工部的模式圖。 工裝置所具有之起毛 加 圖13(a)〜圖13(c)係表示測定本發It is set to 〇', and the average value is not changed. It is shown in Table 5, Table 6, and Table. The non-woven fabric of Comparative Example 12 is used as a reference (3 points). The average value of the pieces was rounded to the whole number, and if it was rushed [evaluation of the constituent fibers of the raising] the non-woven fabrics obtained in Comparative Examples 12 to 16, by the number of the constituent fibers of the above-mentioned raising of the hairs of Examples 8 to 11, The measurement method measures the number of constituent fibers of the fuzz. The case where the number of the constituent fibers of the raised hair is 1 or more is set to 〇, and the case where 20 or more is used is ◎, and the case where 5 is less than 1 is χ and is shown in Table 5 and Table 6. Table 7. [Evaluation of the breaking strength] The nonwoven fabrics obtained in Examples 8 to 11 and Comparative Examples 12 to 16 were obtained by the measurement of the breaking strength in the X direction (width direction, CD direction) of 200 mm and the γ direction ( The measurement sample of 5 〇 in the longitudinal direction and the MD direction was stretched at a tensile speed of 300 mm/min using a tensile tester (manufactured by Shimadzu Corporation) having a chuck pitch of 丨5 〇 mm, and the χ direction was measured. The intensity of the (width direction, CD direction) is set to the average of the four directions (the width direction, the CD direction). Next, the untreated nonwoven fabrics were used (Example 8 and Comparative Example 12, Example 9 and Comparative Example 14, and 156621.doc • 68·201224239 Example 10 and Comparative Example 16, Comparative Example 13, and Comparative Example 12). In the case of Comparative Example 15 and Comparative Example 14, Comparative Example 17 and Comparative Example 16), the ratio of the intensity in the X direction (width direction, CD direction) was 50% or more, and the case where the ratio was less than 50% was set as X is also shown in Table 5, Table 6, and Table 7. [Table 5] Unit Example 8 Comparative Example 12 Comparative Example 13 Example 11 Skin touch feeling 7 3 6 8 〇X 〇〇 Hair amount root/cm 20.2 - 48.7 14.7 ◎ X ◎ 断裂X direction breaking strength cN 1120 1520 750 1180 0 (73%) 0 (100%) χ (49 ° / 〇) 0 (77%) [Table 6] Unit Example 9 Comparative Example 14 Comparative Example 15 Skin touch feeling 3 1 1 〇 XX hair amount root /cm 23.7 - 14.8 ◎ X 〇 X direction breaking strength cN 750 1150 1040 0 (65%) 0 (100%) 0 (90%) [Table 7] Unit Example 10 Comparative Example 16 Comparative Example 17 Skin touch points 3 1 1 〇 XX raising amount/cm 16.3 - 19.2 断裂X 〇X direction breaking strength cN 1120 1730 1760 0(65%) 0(100%) 0(102%) It is clear from the results shown in Table 5. The non-woven fabric of Example 8 is a non-woven fabric which is excellent in touch and has a small reduction in breaking strength. Specifically, it was found that the non-woven fabric of Example 8 was more sensitive to the skin than the non-woven fabric of Comparative Example 12, 156621.doc -69 - 201224239. On the other hand, it was found that the non-woven fabric of Comparative Example 13 and the comparative example had a better touch on the skin as compared with the non-woven fabric, but the reduction in the breaking strength was remarkable. Regarding the non-woven fabric of Example 8, most of the raised fibers were not ring-shaped, but the ends were cut and not caught by the fingertips. Further, the fiber portion was not seen on the roll portion and was good. Another _ Shigong, ^ On the other hand, when the non-woven fabric of Comparative Example 13 was produced, the adhesion of the fiber breakage was observed on the sandpaper, which also caused problems in the durability of the sandpaper. As is clear from the results shown in Table 6, the non-woven fabric of Example 9 was similar to the non-woven fabric of Example 8, and was a non-woven fabric in which the touch of the skin was improved and the breaking strength was reduced. Specifically, in the non-woven fabric of Comparative Example 5, the breaking strength was not too lowered as compared with the original non-woven fabric of Comparative Example 14, but no improvement in the touch of the skin was observed, and only the non-woven fabric of Example 9 was compared with the original one. 14 non-woven fabrics have improved touch as compared with the skin, and the reduction in breaking strength is also suppressed. As is clear from the results shown in Table 7, the non-woven fabric of Example 10 was similar to the non-woven fabric of Example 8, and was a non-woven fabric in which the touch of the skin was improved and the breaking strength was reduced. Specifically, the non-woven fabric of Comparative Example 17 was not excessively lowered in the breaking strength as compared with the original non-woven fabric of Comparative Example 16, but no improvement in the touch of the skin was observed, and only the non-woven fabric of Example 10 and the original Comparative Example 16 were used. The non-woven fabric is improved in touch compared to the skin, and the reduction in breaking strength is also suppressed. Industrial Applicability According to the non-woven fabric of the present invention, although the breaking strength is high, the overall feeling of softness is improved. Further, according to the non-woven fabric of the present invention, the ring 15662l.doc -70· 201224239 has less fibers, is not easy to get stuck on the skin, and the touch of the skin is improved. Further, according to the manufacturing method of the m-woven fabric of the present day, a non-woven fabric which is excellent in the texture of the fibers constituting the fibers can be obtained, and a non-woven fabric which can reduce the reduction in the breaking strength of the non-woven fabric of the raised non-woven fabric can be obtained. Further, according to the manufacture of the nonwoven fabric of the present invention, a nonwoven fabric constituting the fiber (four) hair can be obtained, and the manufacturing speed can be increased to suppress the cost. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view showing an embodiment of a nonwoven fabric of the present invention. Fig. 2 is a perspective view showing a free fiber of the non-woven fabric shown in Fig.! The double ancestor circle 3 shows the preferred device for manufacturing the non-woven fabric shown in Fig. i. Fig. 4 shows the pattern used to manufacture the preferred device of the <+ woven fabric shown in Fig. 0. Fig. 5(4) 5(4) is a schematic view showing a method of measuring the fiber diameter of the nonwoven fabric tip of the present invention. The number of raised fibers of the nonwoven fabric Fig. 6(a) to Fig. 6(c) are schematic views showing the method of measuring the present invention. Fig. 7 is a view for explaining an example of the use form of the nonwoven fabric of the present invention, and is a developed plan view showing a state in which the pull-on disposable diaper is stretched and stretched. Figure 8 is a cross-sectional view of the line ι·χι of Figure 7. Fig. 9 is a schematic view showing a preferred processing apparatus used in the method of fabricating the woven fabric of the present invention. 156621.doc •71-201224239 A part of the enlarged portion of the enlarged portion is shown in Fig. 9 as a schematic view of the processing unit shown in Fig. 9. Fig. 11 is a front elevational view showing a portion of the stretched portion shown in Fig. 10. Fig. 12 is a schematic view showing the processing portion shown in Fig. 9 from an oblique direction. The lifting of the equipment is shown in Figure 13 (a) ~ Figure 13 (c) shows the measurement of the hair

卜,布之起毛之構成 纖維根數之方法的模式圖。 X 【主要元件符號說明】 1 不織布/加工裝置 2 長纖維/部分延伸办 3 熱炫接部/起毛加了 4 不織布/預加工部 4,、4,, 不織布 5 起毛加工部 6a ' 6b 側緣部 6d 腿部 10、10, 原料不織布 20 纖維 20a 端部 20b 自由端部 21 自由端部變粗大之 21a 、 21b 纖維徑 21 凸輥 工部 156621.doc -72· 201224239 22 自由端部未變粗 22 凹輥 23 環狀之纖維 23 鋼模壓花輥 24、25 搬送輥 31 凸輥 32、33 搬送輥 40 吸收體 41、42 輥 43 鋼模壓花輥 44 &gt; 45 搬送輥 50 吸收性本體 51 凸輥 52、53 搬送輥 55 側方翻邊 55a 規定寬度之部分 56 彈性構件 60 外包材 61 内層片材 62 外層片材 63 腰部彈性構件 64 腿部彈性構件 70 正面片材 80 背面片材 156621.doc -73, 201224239 100 内褲型拋棄式尿布 104 測定樣品 105 摺線 106a 纖維 107 108 假想線 210 凸部 210a 凸部之邊緣 220 凹部 220a 凹部之邊緣 310 凸部 410 凸部 420 凹部 510 凸部 A 背側部 Aj 點直徑 B 腹側部 C 下襠部 D 深度 H 高度 Pi 間距 VI、V2、V3、V4 圓周速度 X、Y 方向 z 翻摺線 a 角度 156621.doc .74·Bu, a pattern diagram of the method of fabricating the number of fibers. X [Description of main component symbols] 1 Non-woven fabric/processing device 2 Long fiber/partial extension 3 Thermal joints/hairing 4 Non-woven/pre-finished parts 4, 4, Non-woven 5 Raised parts 6a ' 6b Side edge Part 6d Legs 10, 10, raw material non-woven fabric 20 fiber 20a end portion 20b free end portion 21 free end portion becomes thick 21a, 21b fiber diameter 21 convex roller working portion 156621.doc -72· 201224239 22 free end portion is not thickened 22 concave roller 23 annular fiber 23 steel mold embossing roller 24, 25 conveying roller 31 convex roller 32, 33 conveying roller 40 absorbent body 41, 42 roller 43 steel mold embossing roller 44 &gt; 45 conveying roller 50 absorbent body 51 convex Roller 52, 53 Transfer roller 55 Side flange 55a Part 56 of the specified width Elastic member 60 Outer material 61 Inner sheet 62 Outer sheet 63 Waist elastic member 64 Leg elastic member 70 Front sheet 80 Back sheet 156621.doc -73, 201224239 100 Pants-type disposable diaper 104 Determination sample 105 Fold line 106a Fiber 107 108 Illusion line 210 Convex portion 210a Edge of the convex portion 220 Concave portion 220a Side of the concave portion 310 convex portion 410 convex portion 420 concave portion 510 convex portion A back side portion Aj point diameter B belly portion C lower jaw portion portion depth H height Pi spacing VI, V2, V3, V4 circumferential speed X, Y direction z folding line a angle 156621.doc .74·

Claims (1)

201224239 七、申請專利範園: 1. 一種不織布,装後&amp; 、係利用熱熔接部固定包含 者,且具備:E 長義維之網 述長纖維之一部分斷裂,僅— 上述熱熔接部予以旧— 僅端部利用 . 大之纖維。 疋’且另-端部側之自由端部變粗 .2.如請求項1之不織布,其中自由端部變粗大之上? 之前端纖維徑之掷Λ 上述纖維 &lt;增加比率為15%以上。 3·如請求項⑷之不織布,其中 部予以固定之έ ± ^ …用上述熱熔接 率為聰以上 之自由端部變粗大之上述纖維之比 I =項1或2之不織布’其於上述熱熔接部之間具有立 起為環狀之環妝夕錄认 兩立 上述熱溶接部予以固—2環狀之纖維及僅-端部利用 比率小於5()% ^之纖維之總數中該環狀之纖維之 ^求項1或2之不織布,其中構成上料織布之纖維之 纖維!之分散度為0.33〜1〇〇。 6.如請求項1或2之 、 不織布,其中上述不織布原本係基於紡 ^織布L層與熔噴層之積層不織布所形成。 求項6之不織布,其中上述紡黏不織布、或紡黏層 ”熔喷層之上述積層不織布包含含有5%以上之乙烯-丙 稀共聚物樹腊、或25重量%以上之再生聚丙烯樹脂之聚 丙烯樹脂。 請求項6之不織布,其中上述纺黏不織布係含有 劑者。 156621.doc 201224239 9.如請求項6之不織布, 層與溶噴層之上述積層;織=布原本係基於紡點 _層包含複數層並:布所形成,該積層不織布之 二述長纖維之一部分斷裂,僅-端部利用上述-熔接部予以固定,曰 、 鳊°卩側之自由端部變粗大之纖 、准的紡黏層係含有柔軟劑者。 1〇1請求項1或2之不織布,其中微小荷重時之磨縮特性值 (g cm )/mm以下,CD方向之斷裂強度之值為$ 〇〇 祕⑽以上,單位面積重量為5〜25g/m2。 U.如請求項1或2之不織布’其中起毛纖維之平均纖維徑小 於同©之未起毛部位之表面纖維之平均纖維徑。 12·如請求項1或2之不織布’其中起毛纖維為8根/_上, 且起毛纖維之高度為1.5 mm以下。 13. 如請求項!或2之不織布’其中上述長纖維之—部分之斷 裂係於上述熱熔接部之周邊部。 14. 種不織布,其係原本係基於紡黏不織布、或紡黏層與 熔喷層之積層不織布所形成者,並且 微小荷重時之壓縮特性值為18.〇 (gf/cm2)/_以下, CD方向之斷裂強度之值為5⑼N/5em以上,單位面積重 量為5〜25 g/m2。 15. —種吸收性物品,其係將請求項丨或14之不織布用作構 成構件。 16_ —種不織布之製造方法,其係於5〇七以下之溫度下分別 對不織布之複數處貫施部分延伸加工,再對該經部分延 156621.doc 201224239 17. 18. 19. 20. 21. 22. 伸加工之不織布實施使該不織布之構成纖維起毛之起毛 加工。 如請求項16之不織布之製造方法’其中上述部分延伸加 工係將上述不織布之上述複數處分別以1 〇5〜2〇倍之機械 延伸倍率進行延伸。 如請求項16或17之不織布之製造方&amp;,其係藉由上述部 分延伸加工,向搬送方向及與搬送方向正交之方向分別 對上述不織布之上述複數處實施延伸加工。 如請求項16或17之不織布之製造方法,其中上述部分延 伸加工係使用一對凹凸輥而進行; 一個輥於周面上具有複數個凸部,另一個輥於周面上 之與上述-個輥之上述凸部對應之位置具有該凸部可進 入之凹部; 將上述不織布供給於一對上述凹凸輥間,而對該不織 布實施上述部分延伸加工。 如請求項19之不織布之製造方法,其中—對上述凹凸親 係對相對於所供給之上述不織布之總面積為㈣〜娜之 部分實施上述部分延伸加工。 如請求項19之不織布之製造方法,其中將上述不織布供 給於-對上述凹ώ輥之間時之供給速度νι與—對上述凹 凸輥之圓周速度V2之關係設為Vl&gt; V2。 如請求項16或17之傾布之製造方法,其中上述起毛加 工係使用肖面具有複數個凸部&lt;凸輥而進行; 使上述凸輥之旋轉方向相對於上述不織布之搬送方向 156621.doc 201224239 為反方向而進行旋轉; 將上述經實施部分延伸加工之不織布之搬送速度V3與 上述凸親之圓周速度V4之關係設為V4/V3 = 0.3〜10。 23. 24. 如請求項16或17之不織布之製造方法,其中上述不織布 之總延伸倍率為1.3〜4.〇倍。 如請求項16或17之不織布之製造方法,其中原本之上述 不織布具備於平面方向上規則地分散之熱壓接部,上述 熱壓接部之間距與-對上述凹凸輥之上述凸部之間距之 比(熱壓接部之間距/凸部之間距)為〇 〇5〜〇 7。 156621.doc *4-201224239 VII. Application for Patent Park: 1. A non-woven fabric, after loading &amp;, using a heat-welding joint to fix the inclusion, and having: E Changyiwei's net length of one of the long fibers is broken, only - the above-mentioned heat-welding part is old — Use only at the end. Big fiber. The free end of the 疋' and the other end side becomes thicker. 2. The non-woven fabric of claim 1, wherein the free end portion becomes thicker? Rolling of the front end fiber diameter The above fiber &lt; increase ratio is 15% or more. 3. If the request item (4) is not woven, the middle part is fixed ^ ± ^ ... using the above-mentioned heat fusion ratio, the free end of the Supreme is thicker than the above-mentioned fiber ratio I = the non-woven fabric of item 1 or 2 The ring-shaped ring-shaped ring between the welded portions is recorded in the ring of the heat-bonding portion of the heat-bonding portion, and the fiber-only ring-to-end utilization ratio is less than 5 ()% ^ The non-woven fabric of the fiber 1 or 2, which constitutes the fiber of the fiber of the weaving fabric! The dispersion is 0.33~1〇〇. 6. The non-woven fabric of claim 1 or 2, wherein the non-woven fabric is originally formed based on a laminated nonwoven fabric of the L-woven fabric layer and the melt-blown layer. The non-woven fabric of claim 6, wherein the above-mentioned laminated non-woven fabric of the spunbonded nonwoven fabric or the spunbonded layer comprises a propylene-acrylic copolymer wax containing 5% or more, or a recycled polypropylene resin of 25% by weight or more. Polypropylene resin. The non-woven fabric of claim 6, wherein the spunbonded nonwoven fabric contains the agent. 156621.doc 201224239 9. The non-woven fabric of claim 6, the layer of the layer and the spray spray layer; the weave = cloth is based on the spinning point The _ layer comprises a plurality of layers and is formed by a cloth, and one of the long fibers of the laminated non-woven fabric is partially broken, and only the end portion is fixed by the above-mentioned welded portion, and the free end portion of the 曰, 鳊°卩 side is coarsened, The quasi-spun layer is a softener. 1〇1 Non-woven fabric of claim 1 or 2, wherein the value of the shrinkage characteristic (g cm )/mm or less in the case of a small load, and the value of the breaking strength in the CD direction is $ 〇〇 The secret weight per unit area is 5 to 25 g/m2. U. The non-woven fabric of claim 1 or 2 wherein the average fiber diameter of the raised fibers is smaller than the average fiber diameter of the surface fibers of the unpilled portion of the same. Request item 1 or 2 Non-woven fabrics in which the raising fibers are 8 pieces/_ and the height of the raising fibers is 1.5 mm or less. 13. The non-woven fabric of claim 2 or 2, wherein the break of the long fibers is around the heat-sealing portion 14. A kind of non-woven fabric, which was originally formed based on spunbonded non-woven fabric, or laminated non-woven fabric of spunbonded layer and meltblown layer, and the compression characteristic value at the time of micro load is 18.〇(gf/cm2)/_ Hereinafter, the value of the breaking strength in the CD direction is 5 (9) N/5 em or more, and the basis weight is 5 to 25 g/m 2 . 15. An absorbent article which uses the nonwoven fabric of the request item or 14 as a constituent member. a method for manufacturing a non-woven fabric, which is subjected to partial extension processing of a plurality of non-woven fabrics at a temperature of not less than 5.7, and then the partial extension is 156621.doc 201224239 17. 18. 19. 20. 21. 22 The non-woven fabric of the stretched fabric is subjected to a raising process for raising the constituent fibers of the nonwoven fabric. The method for manufacturing the non-woven fabric of claim 16 wherein the partial extension processing system respectively sets the plurality of the nonwoven fabrics to 1 〇 5 〜 2 The mechanical stretching ratio of the doubling is extended. The manufacturer and the non-woven fabric of claim 16 or 17 are subjected to the above-described partial extension processing, and the above-mentioned plural of the non-woven fabric is respectively applied to the conveying direction and the direction orthogonal to the conveying direction. The method of manufacturing the non-woven fabric of claim 16 or 17, wherein the partial extension processing is performed using a pair of embossing rolls; one roller has a plurality of convex portions on the circumferential surface, and the other roller is on the circumferential surface. The recess corresponding to the convex portion of the one roller has a concave portion into which the convex portion can enter; and the non-woven fabric is supplied between the pair of the uneven rollers, and the partial stretch processing is performed on the nonwoven fabric. The non-woven fabric manufacturing method according to claim 19, wherein the partial extension processing is performed on the portion of the unevenness relative to the total area of the nonwoven fabric supplied (four) to Na. The non-woven fabric manufacturing method according to claim 19, wherein the non-woven fabric is supplied with a relationship between the supply speed νι of the concave roller and the peripheral speed V2 of the concave roller is V1 &gt; V2. A manufacturing method according to claim 16 or 17, wherein the raising process is performed using a plurality of convex portions &lt; convex rollers; and the direction of rotation of the convex roller is opposite to the conveying direction of the non-woven fabric 156621.doc 201224239 is rotated in the reverse direction; the relationship between the transport speed V3 of the non-woven fabric subjected to the extension processing described above and the peripheral speed V4 of the convex pro is V4/V3 = 0.3 to 10. 23. The method of manufacturing a non-woven fabric of claim 16 or 17, wherein the total stretch ratio of the non-woven fabric is 1.3 to 4. times. The manufacturing method of the non-woven fabric of claim 16 or 17, wherein the non-woven fabric is provided with a thermocompression bonding portion which is regularly dispersed in a plane direction, and the distance between the thermocompression bonding portions and the convex portion of the uneven roller is The ratio (the distance between the thermocompression bonding portions / the distance between the convex portions) is 〇〇5 to 〇7. 156621.doc *4-
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WO2009063889A1 (en) * 2007-11-12 2009-05-22 Mitsui Chemicals, Inc. Eccentric hollow composite long fiber, long-fiber nonwoven fabric made therefrom, and use thereof

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CN104220662A (en) * 2012-12-19 2014-12-17 花王株式会社 Nonwoven fabric and manufacturing method therefor
CN104884697A (en) * 2012-12-19 2015-09-02 花王株式会社 Nonwoven fabric
CN104884697B (en) * 2012-12-19 2016-08-24 花王株式会社 Non-woven fabrics
CN104220662B (en) * 2012-12-19 2017-06-13 花王株式会社 Non-woven fabrics and its manufacture method

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TWI456096B (en) 2014-10-11

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