TW201222875A - Photocatalyst light emitting diode lamp - Google Patents

Photocatalyst light emitting diode lamp Download PDF

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Publication number
TW201222875A
TW201222875A TW99139714A TW99139714A TW201222875A TW 201222875 A TW201222875 A TW 201222875A TW 99139714 A TW99139714 A TW 99139714A TW 99139714 A TW99139714 A TW 99139714A TW 201222875 A TW201222875 A TW 201222875A
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Taiwan
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light
emitting diode
substrate
photocatalyst
layer
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TW99139714A
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Chinese (zh)
Inventor
jing-jun Wang
shu-mei Zhang
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Cwhled Optical Corp
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Priority to TW99139714A priority Critical patent/TW201222875A/en
Publication of TW201222875A publication Critical patent/TW201222875A/en

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Abstract

A photocatalyst light emitting diode lamp comprises a substrate, at least one light emitting diode chip on the substrate, and a transparent photocatalyst layer formed upwardly from the substrate to isolate the light emitting diode chip from the outside. When providing electricity for the light emitting diode chip through the substrate to make the light emitting diode chip emit light, the photocatalyst layer is stimulated by the rays generated from the light emitting diode chip to produce electron-hole pairs with high energy for sterilization, deodorization, and self-cleansing effects. Moreover, the invention uses the photocatalyst layer to directly package the light emitting diode chip, so as to isolate it from external pollutants and moisture, which simplifies the manufacturing process and reduces the production costs.

Description

201222875 六、發明說明: 【發明所屬之技術領域】 本發明是有關於發光二極體燈具,特別是指一種可殺. 菌的光觸媒發光二極體燈具。 【先前技術】 發光二極體(Light Emitting Diode,簡稱LED)的應用 商品在生活中隨處可見,主要作為背光顯示及照明等用途 。而隨著發光二極體產業愈加成熟地發展,已發展出許多 除作為照明功用外,還可經由光激發產生化學反應而達到 具有其他副屬效能的的產品。具有殺菌、除臭及自我潔淨 功能的光觸媒發光二極體燈具即是其中一例。 參閱圖1,現行具有殺菌、除臭及自我潔淨功能的光觸 媒發光二極體燈具包含一基板Η、複數發光二極體燈i2i, 及一罩殼13。201222875 VI. Description of the Invention: [Technical Field] The present invention relates to a light-emitting diode lamp, and more particularly to a photocatalytic light-emitting diode lamp capable of killing bacteria. [Prior Art] Applications of Light Emitting Diodes (LEDs) Products can be found everywhere in life, mainly for backlight display and lighting applications. With the development of the light-emitting diode industry, many products have been developed, in addition to being used as lighting functions, to generate chemical reactions through photoexcitation to achieve other subordinate performance. Photocatalytic LED lamps with sterilization, deodorization and self-cleaning functions are examples. Referring to Fig. 1, a photocatalytic LED lamp having a sterilization, deodorizing and self-cleaning function comprises a substrate Η, a plurality of illuminating diode lamps i2i, and a casing 13.

每一發光二極體燈121具有一設置於該基板u上的燈 座124、-設置於該燈座124中並於供電後可發光的發光二 極體晶粒122’及-包覆該發光二極體晶粒122並可供光穿 透的透明封裝層123。 …該罩殼13包括—與該基板u連結並共同界^出可容 該等發光二極體燈121之容室的殼體i3i,及—塗佈於罩 13外表面的光_ 132,該光觸媒膜132以二氧化敍 為主要材料構成’可在照光時激發出高能量的電子1 二氧化; 的無害物質,達到殺菌、脫臭H ^ 201222875 汙垢及自我潔淨等功效。 該光觸媒發光二極體燈具在經過基& u對該發光二極 體燈121提供電能時該等發光二極體晶粒122產生光,產 生的光經該罩殼.13至外界而可作為光源;且該等發光二極 體燈121產生的光在穿經該罩殼13的光觸媒膜132時,光 觸媒膜132激發出高能量的電子電洞對而可將汙染物或化 學物分解為無害的二氧化碳與水,進而達到殺菌、脫臭、 除霉、分解汙垢’及自我潔淨的功效。 這樣的光觸媒發光二極體燈具雖然確實可以達成作為 光源,與消毒、殺菌、除臭等功* ;但是由於發光二極體 燈121之發光二極體晶粒122發出的光需穿過該透明封裝 層123、該發光二極體燈12與罩殼13間的空氣及該罩殼 13的殼體131才能進入光觸媒膜132中行光觸媒反應,而 經過這許多介質後進人龍光觸媒膜132㈣的能量已減 弱大半’致使殺菌、脫臭等功效並不明顯。 此外,這樣的光觸媒發光二極體燈具的組裝製作過程 極為複雜一必須先將發光二極體晶粒122封裝成發光二極體 燈m,同時另外製作基板u、罩殼13,最後再將基板u 、罩殼13、發光二極體燈121組裝成完整的光觸媒發光二 極體燈具一生產、製作成本也因而相對較高。 【發明内容】 因此,本發明之目的,即在提供一種光能利用率高、 構造簡易、成本低的光觸媒發光二極體燈具。 於是,本發明一種光觸媒發光二極體燈具包含一基板 201222875 、至少一發光二極體晶粒及一光觸媒層,該發光二極體晶 粒。X·置於該基板上並在經該基板供電時發光,該光觸媒層 自該基板向上形成於該發光二極體晶粒上而使該發光二極 體晶粒與外界隔絕,並在該發光二極體晶粒發出的光通過 時激發出高能量的電子電洞對。 本發明之功效:用該光觸媒層直接自基板向上形成並 包覆該發光二極體晶粒達到封裝、使其與外界的汙染物及 水氣隔絕,而可簡化製作過程、降低生產成本,且因此可 讓該發光二極體晶粒產生的光無損耗地直接進入光觸媒層 中激發出高能量的電子電洞對,進而達到殺菌、除臭、及 自我潔淨的功效。 【實施方式】 配合參考圖式之二個較佳實施例的詳細說明中,將可 清楚的呈現。 在本發明被詳細描述之前,要注意的是,在以下的說 明内容中,類似的元件是以相同的編號來表示。 參閱圖2,本發明光觸媒發光二極體燈具之一第一較佳 實施例包含-基板2、至少__設置於該基板2上的發光二極 體晶粒3 ’及-自該基板2向上形成用於封裝該發光二極體 晶粒3的光觸媒層4。 忒發光二極體晶粒3包括一連結於該基板2上的基材 31、-由該基材31往上延伸的蟲晶層體32、—形成於該蟲 晶層體32上的透明導電層33,及二用於與該基板2電連接 而分別與該遙晶|體32及該透明導電層33電連接的電極 201222875 34,須說明的是圖示中以示意方式繪示多數發光二極體晶 粒3,具備本技術領域中通常知識的技術人士均知其間差異 ,而在此不再多加贅釋。 當經該基板2將外界的電能分別再經過該二電極34、 透明導電層33提供至該磊晶層體32時,該透明導電層33 令電流水平且均勻地橫向擴散通過該磊晶層體32,進而使 〇亥磊Μ層體32將電能轉換成光的形式透過該透明導電層Μ 向上發出;在該第-較佳實施例中’該發光二極體晶粒3 發出的光的波長範圍是1〇〇奈米〜76〇奈米約在紫外光至 可見光的範圍。 本發明的光觸媒層4透明可透光且選自例如Ti〇2、 V2Os、Mo〇3、Al2〇3,及此等之一組合為材料—在本例中是 以T1〇2為材料,並配合藉由電毁化學氣相沈積系統(Each of the LED lamps 121 has a lamp holder 124 disposed on the substrate u, a light-emitting diode die 122' disposed in the lamp holder 124 and capable of emitting light after being powered, and coating the light The diode die 122 is transparent to the transparent encapsulation layer 123. The cover 13 includes a housing i3i coupled to the substrate u and accommodating a cavity of the light-emitting diode lamp 121, and a light _132 coated on the outer surface of the cover 13, The photocatalyst film 132 is composed of dioxin as a main material, and is a non-hazardous substance that can excite high-energy electrons 1 during oxidation, and achieves the effects of sterilization, deodorization, H ^ 201222875 dirt and self-cleaning. The photodiode light-emitting diode lamp generates light when the light-emitting diode lamp 121 is supplied with power through the base & u, and the generated light passes through the casing .13 to the outside. When the light generated by the light-emitting diode lamps 121 passes through the photocatalyst film 132 of the casing 13, the photocatalyst film 132 excites a high-energy electron hole pair to decompose pollutants or chemicals into harmless The carbon dioxide and water, in order to achieve sterilization, deodorization, mold removal, decomposition of dirt 'and self-cleansing effect. Such a photocatalytic light-emitting diode lamp can be achieved as a light source, and disinfection, sterilization, deodorization, etc.; however, light emitted from the light-emitting diode die 122 of the light-emitting diode lamp 121 needs to pass through the transparency. The encapsulating layer 123, the air between the LED lamp 12 and the casing 13 and the casing 131 of the casing 13 can enter the photocatalyst film 132 to react with the photocatalyst, and the energy of the photocatalyst film 132 (4) after passing through the plurality of media has been Attenuation of the majority of 'caused sterilization, deodorization and other effects are not obvious. In addition, the assembly process of such a photocatalytic LED lamp is extremely complicated. First, the LED die 122 must be packaged into a light-emitting diode lamp m, and the substrate u, the cover 13 and the substrate are finally fabricated. u, the casing 13, and the light-emitting diode lamp 121 are assembled into a complete photocatalytic light-emitting diode lamp, and the production cost is relatively high. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a photocatalytic light-emitting diode lamp having high utilization of light energy, simple structure, and low cost. Therefore, a photocatalytic LED lamp of the present invention comprises a substrate 201222875, at least one light emitting diode die and a photocatalyst layer, and the light emitting diode crystal grain. X· is disposed on the substrate and emits light when power is supplied through the substrate, and the photocatalyst layer is formed on the light-emitting diode die from the substrate upward to isolate the light-emitting diode die from the outside, and the light is emitted The light emitted by the diode grains excites a pair of high-energy electron holes. The effect of the invention is that the photocatalyst layer is directly formed from the substrate and coated with the light-emitting diode crystal grains to form a package, which is insulated from external pollutants and moisture, thereby simplifying the manufacturing process and reducing the production cost, and Therefore, the light generated by the light-emitting diode crystal grains can directly enter the photocatalyst layer to generate a high-energy electron hole pair without loss, thereby achieving sterilization, deodorization, and self-cleaning effects. [Embodiment] A detailed description of two preferred embodiments of the reference drawings will be apparent. Before the present invention is described in detail, it is noted that in the following description, similar elements are denoted by the same reference numerals. Referring to FIG. 2, a first preferred embodiment of the photocatalytic LED lamp of the present invention comprises a substrate 2, at least a light-emitting diode die 3' disposed on the substrate 2, and - from the substrate 2 A photocatalyst layer 4 for encapsulating the light emitting diode crystal grains 3 is formed. The 忒 light-emitting diode die 3 includes a substrate 31 coupled to the substrate 2, a worm layer 32 extending upward from the substrate 31, and a transparent conductive layer formed on the worm layer 32. The layer 33 and the electrodes 201222875 34 for electrically connecting to the substrate 2 and electrically connected to the crystal plate body 32 and the transparent conductive layer 33 respectively are illustrated in a schematic manner to show most of the light-emitting two The polar body 3, which is known to those skilled in the art, is not known to the extent. When the external electric energy is supplied to the epitaxial layer 32 through the two electrodes 34 and the transparent conductive layer 33 through the substrate 2, the transparent conductive layer 33 allows the current to horizontally and uniformly diffuse laterally through the epitaxial layer. 32, which in turn causes the 〇 Μ Μ layer 32 to convert electrical energy into light and emit it upward through the transparent conductive layer; in the first preferred embodiment, 'the wavelength of light emitted by the luminescent diode 3 The range is 1 〇〇 nanometer ~ 76 〇 nanometer in the range of ultraviolet to visible light. The photocatalyst layer 4 of the present invention is transparent and permeable to light and is selected from, for example, Ti〇2, V2Os, Mo〇3, Al2〇3, and one of the combinations is a material—in this case, T1〇2 is used as the material, and Cooperating with an electro-destructive chemical vapor deposition system (

Plasma Chemical Vap〇r Deposition » ffi^PLCVD) 2向上延伸’麵成足夠厚度以完整包覆該發光二極體晶粒 3的透明層體所構成’而達到將該等發光丄極體晶粒3封裝 而與外界隔絕的目#,且利用該電聚化學氣相沈積的方式 可使沈積於該基板2及包覆該發光二極體晶粒3的該光觸 媒層4為非晶相結構’使來自該發光二極體晶粒3的光不 會產生偏折而可往同—古A ,在.+ # a J方向仃進,在該第一較佳實施例中 ’該光觸媒層4的犀声盔。Λ . 旱度為20nm〜5um即可達到封裝的效果 2對該發 3產生光 本發明的光觸媒發光二極體燈具經過該 光二極體晶粒3提供電能時該等發光二極體 201222875 ,產生的光因為光觸媒層4直接形成於該等發光二極體晶 粒3上而可無損耗地直接穿過該光觸媒層*進而至外界, 此時’該光觸媒層4因直接吸收來自該發光二極體晶粒3 的所有光能而激發高能量的電子電洞對,受激發的該電子 電洞與空氣中的汙染物反應並釋放能量產生光觸媒反應, 使該汙染物分解為以二氧化碳(c〇2)及水為主的無害物質 ’達到殺菌、脫臭、除霉及自我潔淨的功能;並且,該發 光二極體晶养立3 |出的光射入該以二氧化#太為主要成份的 • 透明光觸媒層4時,可將光經由多次的内部折射及反射而 使光由原本自該光觸媒層4發出時的點光源調整為柔和且 均勻的面光源再向外射出,而達到作為光源使用的要求。 由上述說明可知,本發明以直接形成於該等發光二極 體晶粒3的光觸媒層4達到封裝的目的,而可簡化製作的 程序及降低生產的成本,同時,燈具本身在作動時,發光 二極體晶粒3產生的光可無損耗地直接、完全進入該光觸 媒層4後至外界,而使得光能被該光觸媒層4充分利用以 鲁 激發出尚能量的電子電洞對進而將環境中的汙染物分解為 以二氧化碳及水為主的無害物質,達到殺菌、脫臭、除霉 • 、分解汙垢,及自我潔淨的功效。 .如圖3所示,為本發明的發光二極體燈具的一第二較 佳貫施例,與上述該第一較佳實施例相似,其不同處僅在 於该基板2包括複數形成於頂面並間隔排列的設置槽2丄, 每一設置槽21具有二呈一角度傾斜並供該等發光二極體晶 粒3固設的設置面211。 7 201222875 曰藉此,使得當固設於該設置槽21上的該等發光二極體 晶粒3發出光時,可因該等傾斜的設置面2u使該等發光二 極體晶粒3發出的光可交錯地呈__角度發散開,而有效增 力^作為光源時的出光均勻度,並同時提高該等發光二極^ 曰曰粒3發出的光與該光觸媒層4間的光觸媒作用,進而強 化本發明的殺菌、脫臭及自我潔淨等功能。 綜上所述,本發明主要是藉由電漿化學氣相沈積的方 式沈積該光觸媒層4且完整包覆該基板2上的發光二極體 晶粒3,達到封裝的目的以相對簡化目前光觸媒發光二極體 燈具的生產、組裝製程,同時,可讓發光二極體晶粒3發 出的光無損耗地直接、完全進入該光觸媒層4中進行光觸 媒作用,而達到殺菌、除臭及自我潔淨等功效,有效改善 目前的光觸媒發光二極體燈具因實質進入罩殼的光觸媒膜 的光此較低’而致使殺菌、脫臭等功效並不明顯的缺點, 再者’本發明直接以該光觸媒層4作為封裝層體,可以使 該發光二極體晶粒3發出的光由點光源成為面光源向外射 出,而不用再另外設置罩殼,而有效節省生產成本,故確 實能達成本發明之目的。 惟以上所述者’僅為本發明之較佳實施例而已,當不 能以此限定本發明實施之範圍,即大凡依本發明申請專利 範圍及發明說明内容所作之簡單的等效變化與修飾,皆仍 屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 圖1是習知一發龙二極體燈具的示意圖; 201222875Plasma Chemical Vap〇r Deposition » ffi^PLCVD) 2 extending upward to form a sufficient thickness to completely cover the transparent layer of the light-emitting diode die 3 to achieve the light-emitting diode die 3 The photocatalyst layer 4 deposited on the substrate 2 and covering the light-emitting diode crystal 3 is made of an amorphous phase structure by means of the electro-chemical chemical vapor deposition. The light from the light-emitting diode die 3 does not deflect and may go to the same - ancient A, in the direction of .+ # a J, in the first preferred embodiment 'the rhythm of the photocatalyst layer 4 Sound helmet. Λ . The effect of encapsulation is achieved by a drought of 20 nm to 5 um. 2 The light is generated by the photocatalytic LED lamp of the present invention. When the photodiode luminaire 3 is supplied with electric energy through the photodiode die 3, the illuminating diode 201222875 is generated. Since the photocatalyst layer 4 is directly formed on the light-emitting diode crystal grains 3, it can directly pass through the photocatalyst layer* and then to the outside without loss. At this time, the photocatalyst layer 4 is directly absorbed from the light-emitting diode. All of the light energy of the bulk crystal 3 excites a pair of high-energy electron holes, and the excited electron hole reacts with the pollutants in the air and releases energy to generate a photocatalytic reaction, which decomposes the pollutant into carbon dioxide (c〇 2) The water-based harmless substance 'has the function of sterilization, deodorization, mold removal and self-cleaning; and the light-emitting diode crystal raises the light that is emitted into the oxidation target. • When the transparent photocatalyst layer 4 is used, the light can be emitted from the point light source originally emitted from the photocatalyst layer 4 to a soft and uniform surface light source through a plurality of internal refractions and reflections, thereby achieving light source Requirements for use. It can be seen from the above description that the present invention achieves the purpose of packaging by directly forming the photocatalyst layer 4 of the light-emitting diode crystal grains 3, thereby simplifying the manufacturing process and reducing the production cost, and at the same time, the lamp itself emits light when it is activated. The light generated by the diode crystal 3 can be directly and completely entered into the photocatalyst layer 4 without loss, and the light energy can be fully utilized by the photocatalyst layer 4 to excite the energy electron hole pair and then the environment. The pollutants in the decomposition are decomposed into harmless substances mainly composed of carbon dioxide and water, which achieve the effects of sterilization, deodorization, mold removal, decomposition of dirt, and self-cleaning. As shown in FIG. 3, a second preferred embodiment of the LED lamp of the present invention is similar to the first preferred embodiment described above, except that the substrate 2 includes a plurality of layers formed on the top. Each of the installation slots 21 has two mounting faces 211 which are inclined at an angle and are fixed for the LED die 3 to be fixed. 7 201222875 曰, so that when the light-emitting diode crystal grains 3 fixed on the installation groove 21 emit light, the light-emitting diode crystal grains 3 can be emitted by the inclined installation surfaces 2u. The light can be dispersed at an angle of __, and the effective power is increased as a light source uniformity, and at the same time, the photocatalytic effect between the light emitted by the light-emitting diodes 3 and the photocatalyst layer 4 is enhanced. Further, the functions of sterilization, deodorization, and self-cleaning of the present invention are enhanced. In summary, the present invention mainly deposits the photocatalyst layer 4 by plasma chemical vapor deposition and completely encapsulates the light-emitting diode die 3 on the substrate 2 to achieve the purpose of packaging to relatively simplify the current photocatalyst. The production and assembly process of the light-emitting diode lamp can simultaneously and directly enter the photocatalyst layer 4 for photocatalytic action without loss, thereby achieving sterilization, deodorization and self-cleaning. The effect is effective to improve the shortcomings of the current photocatalytic LED lamp due to the fact that the light of the photocatalyst film entering the casing is substantially lower, and the effect of sterilization and deodorization is not obvious, and the invention directly uses the photocatalyst. The layer 4 is used as an encapsulation layer body, and the light emitted from the light-emitting diode die 3 can be emitted from the point light source to the surface light source without any additional cover, thereby effectively saving production cost, so the invention can be achieved. The purpose. However, the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, that is, the simple equivalent changes and modifications made by the scope of the invention and the description of the invention, All remain within the scope of the invention patent. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of a conventional hair dragon diode lamp; 201222875

圖2是一示意圖,說明本發明光觸媒發光二極體 燈具之一第一較佳實施例;及 圖3是一示意圖,說明本發明光觸媒發光二極體 燈具之一第二較佳實施例。 9 201222875 【主要元件符號說明】 2 ..........基板 21.........設置槽 211 .......設置面 3 ..........發光二極體晶粒 31.........基材 32 .........蟲晶層體 33 .........透明導電層 34 .........電極 4 ..........光觸媒層Figure 2 is a schematic view showing a first preferred embodiment of the photocatalytic LED of the present invention; and Figure 3 is a schematic view showing a second preferred embodiment of the photocatalytic LED of the present invention. 9 201222875 [Description of main component symbols] 2 ..........Substrate 21...Setting slot 211 .......Setting face 3 ....... ...light-emitting diode crystal 31.........substrate 32 .... insect crystal layer 33 .... transparent conductive layer 34. ........electrode 4 ..........photocatalyst layer

1010

Claims (1)

201222875 七、申請專利範圍: 1.. 一種光觸媒發光二極體燈具,包含: 一基板.; 至少一發光二極體晶粒,設置於該基板上並在經該 基板供電時發光;及 一光觸媒層,自該基板向上形成於該發光二極體晶 粒上而使該發光二極體晶粒與外界隔絕,並在該發光二 極體晶粒發出的光通過時激發出高能量的電子電洞對。 • 2.根據申請專利範圍第1項所述之光觸媒發光二極體燈具 ,其中,S亥發光二極體晶粒具有一與該基板連接的基材 、一自該基材向上形成並在供電時產生光子的磊晶層體 ,及二與該磊晶層體電連接並用於與該基板電連接的電 極0 3. 根據申請專利範圍第2項所述之光觸媒發光二極體燈具 ,其中,該發光二極體晶粒還具有—形成在該遙晶層體 上使電流橫向均勻擴散的透明導電層。 4. 根據巾晴專利範圍第3項所述之光_發光二極體燈具 ’其中’該光觸媒層以電漿化學氣相沈積的方式自該基 板向上且包覆該發光二極體晶粒的形成。 5·根據W專㈣圍第4項所述之光顧發光二極體燈具 太:中’該發光二極體晶粒發出的光的波長範圍為⑽ 76G奈米’且該光觸媒層選自Ti〇2、V2〇s、M〇〇3 、Al2〇3,及此等之—組合為材料構成。 6‘根據申請專㈣圍第5項料之光«發光二極體燈具 201222875 ,包含複數發光二極體晶粒,且該基板包括至少一具有 二彼此成預定角度供該等發光二極體晶粒固設之傾斜設 置面的設置槽。201222875 VII. Patent application scope: 1. A photocatalyst light-emitting diode lamp comprising: a substrate; at least one light-emitting diode die disposed on the substrate and emitting light when power is supplied through the substrate; and a photocatalyst a layer is formed on the light-emitting diode die upward from the substrate to isolate the light-emitting diode die from the outside, and excites high-energy electrons when the light emitted by the light-emitting diode die passes The hole is right. 2. The photocatalytic light-emitting diode lamp according to claim 1, wherein the S-light-emitting diode die has a substrate connected to the substrate, and is formed upward from the substrate and is powered An epitaxial layer body that generates a photon, and an electrode that is electrically connected to the epitaxial layer and is electrically connected to the substrate. 3. The photocatalytic LED lamp according to claim 2, wherein The light-emitting diode crystal grains further have a transparent conductive layer formed on the crystal layer to uniformly diffuse current in a lateral direction. 4. The light-emitting diode lamp according to item 3 of the patent application scope of the invention, wherein the photocatalyst layer is coated upward from the substrate by plasma chemical vapor deposition and covers the light-emitting diode die form. 5. According to the fourth paragraph of the W (4), the illuminating diode lamp is too: the light emitted by the illuminating diode dies has a wavelength range of (10) 76G nanometers and the photocatalyst layer is selected from the group consisting of Ti 〇 2. V2〇s, M〇〇3, Al2〇3, and the like—combination of materials. 6' According to the application of (4) the fifth item of light [light-emitting diode lamp 201222875, comprising a plurality of light-emitting diode crystal grains, and the substrate comprises at least one having two predetermined angles to each other for the light-emitting diode crystals A groove for setting the inclined setting surface of the granule. 1212
TW99139714A 2010-11-18 2010-11-18 Photocatalyst light emitting diode lamp TW201222875A (en)

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