TW201216848A - Mating disruption agent for sucking pests - Google Patents

Abstract

To provide a mating disruption agent for sucking pests which are major pests in rice cultivation. The inventors of the present invention discovered that the application of flonicamid to sucking pests in rice cultivation disrupted pest mating activity, demonstrating a stable and long-term controlling effect. This completely unexpected effect of disrupting pest mating represents a clear departure from the use of flonicamid as a simple pesticide. The present invention relates to a mating disruption agent for rice-feeding sucking pests which contains flonicamid as an active ingredient, and to a method of disrupting mating of such pests by treating with this mating disruption agent.

Description

201216848 VI. Description of the Invention: [Technical Field to Be Invented by the Invention] The present invention relates to an interfering action interfering agent for sucking juice pests. [Prior Art] ^ N-Cyanomethyl-4_trifluorodecylpyridiniumamine (commonly known as fluninic acid) is a compound described in Patent Document 1 as Compound No. Patent Document 2 describes a pest control agent composition containing a fluorinated nitrile-containing pyridine compound and various potency enhancing components. [Patent Document 1] Patent Document 1: European Patent No. 580374 Patent Document 2: International Publication No. WO-2009/128409 (Summary of the Invention) (The subject to be solved by the invention) The heart is regarded as a field towel, and is regarded as The main waste of the pests of the flying fines with high reproduction and breeding caused the harm of Mo A. In particular, the secret of brown fly is until the turn-over, = several generations and New Zealand, the hGpperbum is the main danger: the so-called Wei system caused by the harm of the brown-faced juice, and the fall of the field ΐ 对于 对于 飞 飞 之 之 之 之 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞 飞The prevention and control agent (the means to solve the problem) is studied in the prevention of the 'Norwegian 0-shaped storage containing the brown surface, and the correlation with the ecology of its characteristics. Under the moon: The area of if can't be winter. For example, in Japan, it is mainly at 6. Compared with the white paintings of the same overseas flying nature, the readings from & are relatively low, and the parasitic density at the time of flying does not cause the problem of 201216848. However, after flying, the female adult worms undergo 4 days of scabbard tissue spawning, and at 25 °C, they experience the pre-emergence period of the egg period 7 and the rice leaf mites are the lower-generation (first generation) adults. 4::, the insect's period of 14 days and two short-winged types. Because the short-winged females are not too big, the reproductive rate is geometrically 峨 = beneficial insects are not effective (four), and the law and the law, focusing on ϊίί to prevent brown fly from harming The way to carry out the production of the adult insects makes it difficult to produce and low. Will. The number or density of individuals in the next generation of the worm reduces this problem. Among the active ingredients of the two drugs, the flunitamide solution refers to the second end = the way of doing so. (4) Unfertilized (4) Not ^^ Female--(4) Reduced, and the step-by-step is controlled by the control of sucking juice: 'Offer by letting finnish act on the sucking pests and interfere with the weeding tree of the sucking pests Method for reducing the number of individuals in the next generation (the effect of the invention) / . During the extended period of time, the action interfering agent and the prevention and treatment method can reach a clear boundary line, and the use of gas nicotine as a simple killing agent can be used. For example, the situation in which the number of individuals in the second generation of the rod is reduced is completely unanticipated, and in the case of the control agent used,

S 201216848 尔妓__彳, but at least the next generation 2:= _ people ^ apply the so-called "production of pests of the box processing" (four) "all unanticipated effects", for example, apply to The seedling rider usually uses a fine coffee to play the juice. ^ Embodiments (Best form for carrying out the invention) The salt is Shuji·4·trifluoromethyl_3·. Flunidamine has an image class $本毛明, rice parasitic sucking pests can be exemplified: fly for the class, leaf zen class '椿fly 虱 class can be exemplified: brown planthopper, white back fly _ hole case: black tail turn; etc. _ _ : For example, the blind cockroach and the age class can be cited as: Fly butterflies and leafhoppers. Still further preferred is exemplified by brown planthopper. In the sucking pest of the object to be treated of the present invention, the insecticide is reduced in the susceptibility of the insecticide. In the present invention, the new nicotine-based ion-based surfactant, surfactant, and yin are blended with a conventional agricultural adjuvant, and can be formulated into an emulsion, a powder 1 = a love subject, and various Various forms such as foreign preparations. Here, the adjuvant agent, the granule, the suspending agent, the stabilizer, the dispersing agent, the wetting agent, the carrier, the suspending agent, and the like are preferably added as appropriate. The carrier can be divided into solid, ^dong^, antifoaming agent, etc., for example, starch, sugar, cellulose powder, cyclodextrin: liquid, body, solid carrier < π, activated carbon, soybean powder, 201216848 wheat flour , rice husk powder, wood flour, fish meal, powdered milk ^ Ji ^ ΐ t tTi'^: ίί J' 矽 lacquered earth, white slave, clay, alumina, oxidized 'fuss, powder, etc.; liquid fine example: water Ethers such as minerals such as ethanol; esters of kerosene, kerosene, flowing j, decane, tetrahydrofuran, toluene, benzene, cyclostene, diacetone, glycerides of fatty acids, etc. The vinegar can also be combined with the potentiation component of the potency to form a ^ shape, and then mixed. In this case, one or two thinners are converted into a predetermined one, and the square ii I is processed in a moon tank or a paddy field. In this case, it is treated as a nursery box. Water's production: "There is a remarkable effect of the chapter" The active ingredient of the agricultural compound, which is expected to have a solution of m, is absorbed by the drug from the root of rice, and thus can be effectively: ; (In the clear, the active ingredient flunis is very high in solubility, the water is very high in the mouth of your mouth · > « and "water bath solution. 52 〇〇 mg / L." Because the treatment box treatment agent must be Ϊ = long f continuation, seeking to control the melting and extruding of the active ingredients of agriculture, the other side is difficult to wait for the solubility of the compound of tf nicotine. The morphological change, Sx, and the system are used to solve the cause of the fluorine. The problem of the solubility of nitrile water is

S 201216848 g effect form. The blending amount is from 〗 〖3G wt%, preferably from q 5 to 25 wt. = The present invention = the average particle size of fluniin used is from 丨 to lake, desirably from 1 to ΙΟΟμπι, further preferably from 5 to 5〇μιη. Age riding makes it possible to paste: ethylene·ethyl acetate copolymer, ethylene-tertiary carbonic acid copolymer, styrene-acrylic acid vinegar, acrylic acid, oxidized polyethylene, guanidinium carbamate, Lu ^ 脂 fat and so on. Water insoluble _ is expected to be used as an emulsion. Special period of example. Copolymer emulsion. The ethylene-propionic acid copolymer emulsion, for example, can be used in a resin emulsion such as a paste, and can be mixed. Incorporation of 1, the solid matter is from 1 to 30% by weight, preferably from 1 to 15%, and the body of the invention is not particularly limited. For example, a powder, a material π, a carbonic acid, a sericite, or the like can be used. ~ (trade name), acid gypsum is not a carrier such as i Zhanshi, Bora, and green gangue. For the blending amount and 2C, it is 4g to ".8% by weight, preferably (10) to the heart weight% of the amber. Examples of measuring: county polyoxyethylene, sodium benzoate, higher alcohol sulfate, hospital naphthalene acid sodium, ethylene burning, polyoxyethylene styryl phenyl vinegar, polyoxygenation only == = poly t-styrene-based phenyl acid vinegar. In the case of the case, it is used for the change of the other. The humectant is preferably used in an amount of from 0 to 5 and is not particularly limited to 'from _ to 10% by weight'. The granulation method generally used in the manufacture of pesticides, for example, energy method, compression violet method, rotation system Granular method, rotary flow granulation method, fluidized bed granulation system. , '^,,, stirring mixing granulation method, coating granulation method, tableting method, etc., etc. 201216848 For example, evenly mixed human, fat emulsion, using kneading machine ^,, ^ agent and carrier after 'adding water difficult Soluble tree granules dry, whole grain ^ _ example and other extrusion systems, can be added - step control. Melt extrusion speed in the δ hai composition, dangerous in the preparation of the preparation to ensure that pesticides are corrected, such as In the case of the purpose of improving the granulation property of the pesticide of the present invention, the purpose of '= and the amount of the optional component in the case of granulation, the surfactant may be contained in the present invention, and (4) in the present invention, if necessary, It is possible to mix and adjust the agent to grow freshly. In this case, T also shows that further excellent ίΪίίΠί can improve the scope of application, the period of drug treatment, and the prevention and control activity. Further, it is possible to use I nitrile in combination with other agricultural products, and it is possible to use them in a mixture of the preparations at the time of dispersion, or to use them in combination. For example, in the case of modulating the composition, it is also possible to prepare the nicotinamide together with other pesticide components other than the other. In the present invention, in such a manner, the case where the active ingredient is mixed and applied is also included. An active ingredient compound of an insecticide, a miticidal agent, a nematicide or a soil-killing insecticide in the above other pesticides, that is, for example, an insecticidal compound (generally: one containing the application, or the test code) is Bufeisong Qjr0fen0f0s), dichlorvos, fenamiphos, fenitrothion, epirubicin (EPN), dizinon, chlorpyrifos, chlorpyrifos-methyl ), acephate, prothiofos, fosthiazate, cadusafos, dislufoton, isoxathion, isofenphos, Ethion, etrimfos, quinalphos, dimethylvinphos, dimethoate, sulprofos, sulphur Thiometon, vamidothion, pyraclofos, pyridaphthion, pirimiphos-methyl, propaphos, pine fen powder 201216848 (phosalone), blessing Formothion, marathion, insecticide (te Trachlovinphos), chlorfenvinphos, cyanophos, trichlorfon, methidathion, phenthoate, ESP, azinphos-methyl, fen Fenthion, heptenophos, methoxychlor, parathion, phosphocarb, demeton-S-methyl, monocrotophos, Methamidophos, an imicyanafos, parathion-methyl, terbufos, phospamidon, phosmet, tofusone (phorate), phoxim, triazophos organic compound compounds; such as carbaryl, propoxur, aldicarb, carbofUran ), thiodicarb, methomyl, oxamyl, ethiofencarb, pirimicarb, fenobucarb, butyl plus Carbosulfan, benfiiracarb, bendiocarb, fUrathiocab, isoprocar b), metolcarb, xylylcarb, XMC, fenotiiiocarb, methotrexate; cartap, thiocyclam, bensultap , thiosultap-sodium, monosultap, bisultap, thiocyclam hydrogen oxalate of the toxin derivative; such as dicofol, Organochlorine compounds of tetradifon, endosulfan, dienochlor, and dieldrin; organometallic systems such as fenbutatin oxide and cyhexatin Compounds; such as fenvalerate, permethrin, cypermethrin, deltamethrin, cyhalothrin, tefluthrin, vinegar (ethofenprox), flufenprox, cyfluthrin, fenpropathrin, flucythrinate, fluyanthine vinegar, and acetaminophen CyCi〇pr〇thrin), lambda-cyhalothrin, pyrethrins, cyanamide Pyrethroid 201216848 (esfenvalerate), tetramethrin, resmethrin, protrifenbute, bifenthrin, zeta-cypermethrin, ananin (acrinathrin), alpha-cypermethrin, allethrin, gamma-cyhalothrin, theta-cypermethrin, fua -fluvalinate), trolomethrin, profluthrin, beta-cypermethrin, beta-cyfluthrin, metofluthrin, phenbutin (phenothrin), flumethrin, decamethrin, in addition to succulent compounds; such as diflubenzuron, chlorfluazuron, flubufenzuron, fluoride Flufenoxuron, triflumuron, hexaflumuron, lufenuron, novaluron, noifurumuron, bistrifluron a phenylhydrazinourea compound of fluazuron; Such as metoprene, pyriproxyfen, fenoxycarb, diofenolan, juvenile hormone compounds; such as pyridaben's 哒α well ketone system匕 ;; such as fenpyroximate, fipronil, tebufenpyrad, ethiprole, tolfenpyrad, acetoprole, ° ratio of pyrafluprole, pyripramine (pyriprole) than salivary compounds; such as imidacloprid, nitenpyram, acetamiprid , ° thiacloprid, thiamet: hoxam, clothianidin, nidinotefbran, dinotefbran, and nitid. New nicotine such as nithiazine; such as tuffenozoide, nethoxyfenozide, chromafenozide, halofenozide, etc.; a special window acid compound such as spirodiclofen; a spheroid compound such as fluacrypyrin; an amine ratio biting compound such as flufenerim; 201216848 Dinitrogen compounds, organic sulfur compounds, urea compounds, tri-p compounds, lanthanides or other compounds, such as: buprofezin, hep, hexy (hexythiazox), double methyl moon (amitraz) insecticidal moon rice (chl〇rdimef〇rm), flurazepam (silafluofen), π sitawei (txiazamate), pymetrozine, pyrimidifen, kefanpai ( Chlorfenapyr), indoxacarb, acequinocyl, etoxazole, cyromazine, 1,3-dichloropropene, dibutyl ether urea (diafenthiuron), isothiazolid (benclothiaz) combined with this month (bifenazate), snail @|(spiromesifen), spirotetramat, propargite, clofentezine, metaflumizone, 3-bromo-N-(2-bromo-4-gas) -6-(1-cyclopropylethylaminemethane)phenyl)-1-(3-chloropyridin-2-yl)-1Η·pyrazole-5-decylamine, 3-bromo-N -(4j_2-(l-cyclopropylethylamine fluorenyl)-6-nonylphenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-decylamine, 3-bromo-N-(2-bromo-4-chloro-6-(cyclopropyldecylamine decyl)phenyl)-1-(3-chloro0-biti-2-yl)-1Η-η啥-5-decylamine, flubendiamide, cyflumetofen, chlorantraniliprole, cyantraniliprole, cyenopyrafen, pear fluoride Pyrifluquinazone, fenazaquin, amidoflumet, chlorobenzoate, sulfluramid, hydramethylnon, metaldehyde, HGW -86, AKD-1022, ryanodine, pyridalyl, verbutin, compound of thiazolylcinnanonitrile, etc.Further, it can be used in combination with, for example, Bacillus thuringienses subspecies aizawai, Bacillus thuringienses subspecies kurstaki, Bacillus thuringienses subspecies israelensis, Bacillus thuringienses. Subspecies japonensis, Bacillus thuringienses subspecies tenebrionis, Bacillus thuringienses, crystallization protein toxins, entomopathogenic virus agents, entomopathogenic linear agents, nematode pathogenic bacteria, etc. Aver 壹 ect (avermectin), emamectin benzoate, milbemectin, milbemycin, spinosad, ivermectin, kill Lepimectin, DE-175, abatatin 201216848 (abamectin), emamectin, spinetorram anti-biomass and semi-synthetic antibiotics; eg azadirachtin, rotenone (r〇tenone) natural product; decoction of decoction (deet). The active ingredient compound of the above-mentioned other pesticides, that is, the bactericidal compound (general name; including a part of the application; or the Japanese Plant Epidemic Prevention Association test code), for example, may be exemplified by: mepanipyrim, pyrimethanil Amine (pyrimethanil), cyprodinil, and imiline-based mouth of fermzone. a compound such as 5-gas-7-(4-mercaptopiperidin-1-yl)-6-(2,4,6-trifluorophenyl)[1,2,4]triazinyl[l , 5-a]pyrimidine triazalpyrimidine compound; such as acetazinam amine 0 oxime compound; such as triadimefon, bitertanol, triflumizole , etaconazole, propiconazole, penconazole, flusilazole, myclobutanil, cyproconazole, tebuconazole, phenanthrene Hexaconazole, fbrconazole-cis, prochloraz, metconazole, epoxiconazole, tetraconazole, mouthwash mouth rice Acid salt (0\卩000xian 20匕1111 dish plus 6), Shixi fluoride (5丨卩 (: 011 & 2〇16), prothioconazole, triadimenol, pink sterol (flutriafol), difenoconazole, Ι1#'1 fluquinconazole, fenbuconazole, bromuconazole, diniconazole, tricyclazole, flutter Probenazole, simeconazole, peflirazoate, ipconazole, imibenconazole 2°^ compound; such as quinomethionate 啥D#1# Compounds; such as maneb, zineb, mancozeb, polycarbamate, metiram, propineb, Thiram thiol compound; such as fthalide, chlorothalonil, quinozene organochlorine compounds; 3611011154), 曱基多保净 (this 0卩1^1 plus 6-161161; 11) 4), Beffen

S 12 201216848 (carbendazim), thiabendazole, fuberiazole imidazole compound; cyanoxamine compound such as cymoxanil; such as metalaxyl, dextromethorphan Metalaxyl-M, mefenoxam, 0Xadixyl, furosemide (0ftjrace), benalaxyl, bentaxol-M, alias kiralaxyl, chiralaxyl ), furiralaxyl, cyprofiiram, carb〇xin, oxycarboxin, thifluzamide, boscalid, biphenyl An amine benzene compound of bixafen, isotianil, tiadinil, sedaxane; an amine compound such as dichlofluanid; Such as cupric hydroxide, copper compound of organic copper (oxine copper); such as the different σ of hymexazol. Sitrate compounds; such as fosetyl-Al, tolclofos-Methyl, S-phenylene diisopropyl thioate, 0-ethyl-S, S-diphenyl Organic phosphorus compounds such as dithio acid vinegar, ethyl ethyl aluminum phosphate, edifenphos, and ipr〇benfos; such as captan, captafol, A bismuth imine compound which sterilizes folpet; a dicarboxy quinone imine compound such as procymidone, iprodione, or vinclozolin; such as flutolanil, Benzoquinone-based compound of mepronil; such as penthiopryad, 3-(difluoroindolyl) fluorenyl-N-[(1RS, 4SR, 9RS)-1,2,3 , 4-tetrazolium-9-isopropyl-1,4-decyloxyna-5-yl sitting _4_曱-amine and 3-(difluoroindolyl)-1-methyl_N-[( 1RS, 4SR, 9SR)-1,2,3,4·tetrahydro-9-isopropyl-1,4-nonyloxynaphthalen-5-yl]pyrazole-4-decylamine mixture (naphthylpyridinium) Isoprozam, silthiopham, fenoxanil, fbrametpyr amine compound; 13 201216848 such as fluopyrazine Yram), a benzoguanamine compound of zoxamide; such as triforine. Specific ratios of σ wells; such as flonicamid, phenanol (pyrifenc^i1^11); methanolic compounds such as fenarimol; such as fenpropidin. a compound such as a fenpropimorph or a tridemorph; an organotin compound such as fentin hydroxide or fentin acetate; a urea compound of pencycuron; a cinnamic acid compound such as dimethomorph or flumorph; a phenylamine phthalate compound such as diehofencarb; (fludioxonil), fenpiclonil cyanide ratio ° various compounds; such as atropine (azoxystrobin), kresoxim-methyl, metominostrobin, trifloxystrobin , oxytocin, oryzastrobin, dimoxystrobin, pyraclostrobin, fluoxastrobin, fluoxastrobin; Such as the slogan β sputum g (famoxadone) D No. a compound; such as Han Leing (ethaboxam) beta-supplemented amide amine compound; such as iprovalicarb, benthiavalicarb-isopropyl's 'salt amidoxime-based compound; -N_(isopropyloxycarbonyl)-L-amidoxime-(3RS)-3-(4-chlorophenyl)-β-alanine (valiphenalate) a proline-based compound; The taste of fenamidone is a compound of quinone ketone; a guanamine compound such as fenhexamid; a benzoamide compound such as flusulfamide; Cyflufenamid) effluent ether compound; 14 201216848 lanthanide compound; crotonic acid compound; such as validamycin, kasugamycin, polyoxins antibiotics; Bismuth octylamine acetate (iminoctadine), tannin (dodine) lanthanide compound; such as 6-tertiary butyl-8-fluoro-2,3-dimethylquinolin-4-yl acetate a quinone compound of tebufloquin; such as (Z)-; 2-(2-fluoro-5-(trifluoromethyl)phenylthio)_2_(3_(2_曱-oxyphenyl)tetra Hydroquinone 0 sitting-2-subunit) acetonitrile (嗟 嗟 ( (fl Utinian)) tetrahydroquinone salivary compounds; other compounds can be exemplified by: pyribencarb, isoprothiolane, pyroquilon, dici〇mezine, vebufen ( Quinoxyfen), pr〇pamocarb hydrochloride, chloro (chloropicrin), dazomet, metam-sodium, nichofien, annihil Metrafenone, UBF-307, diclocymet, propoxyquinoline (pr〇qUinazid), carbazolam (amisurobrom; alias amberromdole), 3-(2,3,4- Trimethoxy-6-mercaptophenyl))-5-chloro-2-methoxy-4-indenyl acridine, 4-(2,3,4-trimethoxy-6-nonylbenzene曱醯-)-2,5-dichloro-3-trifluoromethyl 11-bite, pyri- fen sputum (pyri〇fen〇ne), diacetyl glucosamine (mandipropamid), fluoro-n-bispermidine (f|UOpic〇iide), carpropamid, meptyidinocap, n_[(3,,4,-diox-1,1·didecyl)benzene醯Methyl]-3-trifluoromethyl-2-pyridinecarboxamide, N-[(3,4,-dichloro-1,1-dimethyl)phenylhydrazinyl]-3-methyl -2- Thiopheneamine, N-[(3',4,-dioxa-1,1-dimercapto)phenylindolyl]-1-mercapto-3-trifluoromethyl-4-° ratio Indoleamine, N-[[2,-fluorenyl-4'-(2-propoxy)-U-diindenyl]phenylhydrazinyl]-3-trifluoromethyl-2-pyridiniumamine, Ν·[[2'-mercapto_4'-(2-propoxy)-1,1-dimethyl]phenylhydrazino]_3_mercapto-2- thiophene, N-[[r- Indenyl 4'_(2·propoxymethyl]phenylhydrazinylmethyl_3_trifluoromethyl-4-pyrazolecarbamamine, N_[[4,-(2-propoxy)- 1,1-dimercapto]benzoyl]_3_trifluoromethyl_2_pyridinecarboxamide, Ν·[[4'_(2_propoxy)_Ucmethyl]phenyl fluorenyl] -3-methyl-2-thiophene decylamine, N_[[4,_(2-propoxyindolyl)benzoyl]-1 -indolyl-3-trifluoromethyl-4-pyrazole Indoleamine, Ν·[[2,_曱基-4,-(2-pentyloxy-15 201216848)-l,1-dimethyl]phenylhydrazinemethyl]-3-trifluoromethyl_2_ Pyridylcarbamide, N-[[4, -(2-pentyloxy)-1,1-dimethyl]benzoinyl]_3_trifluoromethyl-2-pyridinecarboxamide, high-m (ferimzone), spiroxamine, S2188 (fenpyrazamine), S-2200, ZF-9646, BCF-05 Bu BCM-06 Bu BCM-062 . In this issue, because the treatment amount of flunidom is different depending on the target crop, the treatment method, and the condition of the preparation, it is difficult to specify it, usually 〇! to 24,000g/ha. In the case of dispersion treatment, the treatment amount of fluniin is usually 〇j to 10,000 g/ha 'expected to 1 to i, _g/ha, further expected to be 1 〇 to township, and f" ' ί further expected to be 25 to 500 g /ha. In the case of surface treatment, fluniin 5 μl, 〇〇0g/ha, 1〇 ^ ? is expected to be 50 to 600 g/ha. In the case of the nursery box treatment, the nitrile ^ to l 〇 0g / box is expected. .丨 to 1〇g/carton, further expectation is two] 700ΡΡ^ί ί 〇〇〇 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着 接着. , & Long L, but hunting such as the example, (1) - the transpiration of the rice parasitic sucking pests of the active ingredient of finnish. The complex y is contained as a worm (4) pest as a mites and two of the pests as a fly ash. The parasitic action of the squirting insect pests to control the snails of the snails of the snails of the snails (5), the method of which contains the method of ___, which is '(7) in the stalk of (7) Under the suction of pests, the entanglement of the insects interferes with the rice parasitic generation of the flunitamide, and the number of the population is protected from the pest. (8) The method according to (5), wherein the fluorine is treated at 24,000 g/ha. The effective amount of the scoop is 0.1 to (9) in the method described in (5), wherein the treatment (10) is carried out in the method described in (5). Agent. The treatment of the mating action in the ruler field (11) is contained in (5) the method of §, which is in the # && + π» turbulence agent. The processing described in (5) in the method of (5), wherein the amount of water treated, the dispersion treatment of the ruthenium amine = 1 to (13), the method described in (5), Among them, the amount of treatment in the paddy field is treated with water surface treatment of flunidom to control the pest. , __μμ (method described in i4il (5), in which the treatment of fluanilide is carried out in the nursery box with _1 to l〇〇g/phase to control the pest. (15) - Species (Fluorine and water-insoluble resin). The composition for pest control according to (15), which is formed by a nitrile and a poorly water-soluble resin. The composition described in any one of (15) to (17), wherein the water-insoluble resin is a composition described in any one of (15) to (17). (19) The composition according to any one of (15) to (17), wherein the gas nicotine has a particle diameter of from 1 to ΙΟΟμηη. (20) The composition according to (18), The average particle diameter of the fluniin is 丨 to i(8) μηι. (21) A composition for controlling pests, wherein the composition according to any one of (15) to (17) is a granule. (22) A composition for controlling a pest, wherein the composition according to (18) or (2) is a granule. (23) The method for producing a composition according to (21), wherein Have progress (24) A method for producing a composition according to (22), wherein the towel has a vinylidene fluoride-acrylic acid copolymer, and a step of mixing/mixing/granulating and drying the composition of the composition of the composition of the invention. Step of mixing/mixing/granulation and drying. Resin (4) A pest control composition containing fluniline and water-insoluble (26) The pest control composition described in (25), nitrile Forming a matrix with a poorly water-soluble resin. The composition of the sputum brake formazan acid ^2.5) or (26), the water injection is difficult _ fat is ethylene - propyl, its more towels - slaves, detailed composition, Granules - she is a product, her anger is called. (10) The composition according to (10), wherein the average particle diameter of the fluniin is from 1 to the surface tester, and any one of the (9) nets is the composition (33) of (10) (31) The method for producing the composition described is a mixture of ethylene-acrylic acid copolymer/clearing and drying, and the step of drying and granulating is carried out. (34) In (32) shouting secret manufacturing method, shooting a woman = dilute acid copolymer The steps in the mixing/mixing sanding/granulation and drying process are as described in the Examples of the present invention. However, the present invention is not subject to the formulation examples of the above examples. 1 part by weight of the mixed flunitamide 'Expanded soil (Fengshun system) 76 parts by weight ==: GR-3 boots Wei salt water final Sanyo Chemical cylinder #公卿重量份, s following 201216848 water amount 2 ^ aqueous solution, Nippon Paper - 1 company) 3 parts by weight And must-have pesticide granules. After seeing the granulation mechanism of the extrusion granules, 'drying, granulating, and then obtaining the styrene content of the preparation example 2, 92.3 parts by weight of the carbonic acid, and polyoxyethylene f, after iMSGrpGl 5G96, manufactured by Toho Chemical Co., Ltd.) 3 weight = back mouth # read with 27w / w% women. Acrylic copolymer water-based milk, · f, YTEC W111 (Dongbang Chemical Industry # 公_), add the necessary water 篁 AI with a dispenser After the granules, the granules of the pesticide are obtained by drying and granulating. In the preparation example 3, after 2 parts by weight of nicotine, 92.3% by weight of clay, and 3 parts by weight of polyoxyethylene styrene basic ether sulfur and sulphur (S〇rp〇1 5096, manufactured by Toho Chemical Co., Ltd.), Add 10 parts by weight of a 27w/w% ethylene-acrylic acid copolymer name: HYTEcwm (manufactured by Toho Chemical Co., Ltd.), and add necessary; stir, granulate by an extruder, and then dry, A pesticide granule is obtained after the whole granule. Example 5: The control effect on the brown planthopper obtained by the treatment of fluniline seedling box was at the root bead of 1.2cmxl.2cm unit seedlings (3 plants/plant), and the ratio of 15mg ai/plant was in the nursery box. The granules prepared in accordance with Formulation Example 1 were treated. One day after the treatment with flunidom, the soil was pulled from the unit together with the soil, and the alfalfa was transplanted to each other to maintain the water depth at 3 cm. Two small greenhouses were prepared, and 24 pots were set in each of the small greenhouses with flunisamide treatment and no treatment. After 10, 17 and 30 days of transplantation, 100 adults of Nilaparvata lugens were fed at room temperature. After the larvae, the number of adults per 24 rice cultivars in rice cultivation and the number of larvae in the next generation of the new generation were measured at regular intervals. The results are shown in Table 1 and Figure 1. Further, in Fig. 1, 〇-〇 (circle symbol) indicates the number of larvae (only) in the fluniin treatment zone, and Δ - △ (triangle symbol) indicates larvae in the untreated zone. Number (only). ... [Table 1] 19 201216848 The number of larval parasitic larvae of the brown planthopper of the first table / 24 strains (only) The number of days after rice transplant 17 18 21 25 29 35 39 45 51 57 63 Fluonamide treatment zone 2 9 12 27 61 146 94 149 301 687 566 untreated area 5 21 114 458 722 609 300 479 1050 1775 1100 In Table 1 and Figure 1, the number of larvae from no treatment, the 29th day after rice transplant is the peak of the first generation, rice The 57th day after transplantation is the peak of the 2nd generation. On the 39th day after rice transplantation, the number of larvae was reduced, and it can be presumed that the first generation of adults was printed as a state before the prevalence. In addition, the '3rd adult insect feeding system is in the actual paddy field, and it is assumed that the brown flying insects fly from other areas. In this case, in the fluniin-treated area, the number of larvae of the second generation was also greatly suppressed by the peak of the first generation. Test Example 2: Interference with the action of the tailings of the brown planthopper The rice of the omega grain was sown in cotton wool of 40 mm x 4 mm, and the preparation length was about - the paddy field was treated with an aqueous solution containing the active ingredient Dunlin 2 (8) ppm, air-dried, and placed. The glass tube bottle (inner diameter 4〇_height 75 surface; capacity 2; from the time of the infancy), the adult of the larvae (10) aparvata lugens, which is bred with no _ treated rice seedlings. On the 7th day after emergence, the pi system was treated with impregnation of rice for each insect. In the feathers, the day is caught and the place is only at the beginning of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The next generation of ^^^ treatment area) and the non-agent treated rice seedlings (no treatment area) are the second to the next generation - generation of larvae. There is no treatment area, there is no under the state of Xiang tail - generation generation, and the number of generations of the next generation larvae is measured on the surface of the result. [Table 2]

- Table 2 20 201216848 : Ending the mating within 90 minutes. : Not crossed. The new nicotine-based insecticide, which represents the new nicotine-based insecticide, is said to be the same as the brown-faced thief. A comparison 'measured the number of larvae produced in the next generation. [Table 3] The number of generations of insects (only) 87

Λ1Α_ There is no treatment area in the fluniin treatment area ※^: The tailing action is not observed. ※匕: Ending the tailing test within 1 minute. Example 4: Interference with the action of the tailing movement of the white-backed planthopper White back Lai (s〇gatdla, same = test) for the I nitrile treated area and no treatment area - comparison, the number of generations of larvae was measured. The results are shown in Table 4. [Table 4] ' 珩Η The number of the next generation of the worms is sold (the sale) The fluamine treatment area 4a 〇 no treatment area 〇 ※ 130 ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ 交 交 交 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 For the interference effect of the tailings of the spotted cockroach, replace the brown fly touch of the test example 2 with the zebras (Lai (jeiphax striatella), the same; the ground mixed, the needle nitrile treated area and the untreated area - Contrast, the number of larvae produced in the next generation was measured. The results are shown in Table 5. [Table 5] ' 21 201216848

Fly - ί== to the 5th wire, strong wealth and wealth, ride all kinds of; that interference, suppress the number of individuals in the next generation. In addition, it was found that the test case 6: the interference effect on the tailing action of the brown planthopper was performed by using the active ingredient fluniamine 5 〇, test example 2 === display; ir for comparison, the next-generation larvae were measured Generate a number. Will result

^ ·. The parent tail movement has not been observed - ◊ · End of the 30-minute period of the end of the tail of the white tail of the interference action treatment of rice seedlings 2, 12.5 and 3.lppm of the aqueous treatment area for - contrast, ^ ^ 仃 surface 'for l Nitrile treatment zone and no table 7. The number of larvae produced in the next generation is measured. Display the results in [Table η

S 22 201216848 1 Table 7

Treatment area ※a : The tailing action is not ^^b: Ending the tailing test within 30 minutes. Example 8: Interfering with the action of the mating of the spotted surface. Treatment of fluniline 5G, 12.5 and 3. The aqueous solution of Yiluoli: pure fun example 5 and 1 ' 'for the fluniin treatment zone and the comparison - the number of generations of the next generation larvae is measured [Table 8]

The eighth table ii The amine treatment area The remedy treatment area The area ※a • The tailing movement is not observed ※^ : The ending is completed within 30 minutes. The tail-tailed 彳 ^ Ni Gu has been reduced by the brown _ system, and the rice seedlings were treated with a fine aqueous solution to measure the number of generations of the next-generation larvae. Display the results and the table

• 'The end of the action is not observed'. ※匕: The result of the end of the payment of the money is less than 30 minutes. The result of the test is 6 to 9'. It is known that it is effective for the daily storage of the 23 201216848 ΐΐ 3'1PPm # In the case of the ingredients, it is also used in the case of the brown _, which has a reduced susceptibility to the estamide, and the present invention, and the effective ingredient of the .lPPm weight, also shows excellent efficacy test example 10: for pseudo black-tailed spider mites The tailing action was selected to replace the brown fly of Test Example 2 with the pseudo-amp; - the comparison of the bribes and the untreated areas treated by the tir solution. The results are shown in Table 10.

The next result was found in the seedling box of the pseudo-black-tailed spider mites in the present day, and the control effect of the pseudo-black-tailed spider mites was obtained in the nursery box of 30 cm x 60 cm obtained by the treatment of the fluramide seedling box. 12, 24%% trait = treatment in the nursery box was transplanted to the market of 32 m2 in the sputum area according to the ga f rtn tWm^24 ^ : aL · day f domain modulated by the preparation example 2. In the move 20 = Tianchang - 2, feed the brown fly butterfly each 5 〇〇 (four) il it transplant %, 89 and % of the parasitic in the rice crop every 24 rice plants have 'in the reference to Figure 2, for gas Nitrile treatment area ==

S 24 4 201216848 • The situation of the fluniin treatment zone is shown in the figure. · _φ (black circle symbol) indicates the number of larvae (only) in the 24 § & | / 1 〇 & nitrite treatment zone, mouth - mouth (white horn symbol) is not treated with amine granules The number of larvae in the area (only), △ - △ (white triangle symbol) indicates the number of larvae in the Datnam granule treatment area (only) ' X — x (x symbol) indicates the number of larvae in the untreated area (only). Days after treatment of concentrated rice transplants (days) 70 78 89 96 Flunidamine treatment zone 36 g ai/10 a 11 3 17 78 Fluanisil treatment IS 24gai/10 a 14 5 14 47 Fluanidil treatment 菡12 g ai /10 a 88 16 8 106 Flunidamine treatment zone 6 g ai/10 a 53 5 6 70 .. edamine hydrating agent treatment (3⁄4 24 g ai/10 a 9 44 170 50 Dartnan water solvent treatment zone 24 g ai/10 a 11 28 72 116 No treatment area 77 166 610 355 [Table 11] Table 11 The fifth locust is carried out in the paddy field of the southwestern warm land, and it is carried out in the same period as the brown planthopper flies from the area. The number of larvae changes, and the day after rice transplant is the peak of the first generation (next generation) of the younger brother. In the control agent starkie box granule treatment area, although the parasitization has been inhibited 7 days after the start of the investigation. The larvae density, but the money turned into an increase. Shouting in the opposite of the Admife silk, the marriage sample ^ investigation began to transplant 70 days after the inhibition of parasitic larval density, but after the conversion, observed on the 89th day after transplantation The peak of the i-th generation (next generation). This is the case, and the third generation is not observed in the messy amine treatment zone. The number of petals of the mystery. This result, the hair _ in the case of the medicine pot ship sucking fruit test case 12: the control effect of the brown face obtained by the treatment of the flavanis stems and leaves is transplanted to the 1st district 32m2 After the transplant, %, guilt, Η, and 65 days later, for the 圃 scene m2, feed the brown fly _ worm each · only and (4) _ 25 201216848 heading period, use 150L / 1 〇 a of the amount of water to carry out the fluorine leaf Set no treatment area, send clean water hydrating agent (trade name: Chess ring ==== solution = will = table 12

- The second H is in the southwestern warm land of the waterfield towel, the age of the brown fly in the New Zealand area. The number of larvae that have not been treated in the world is changed, and the 19th day is the first enough wave bee. On the 26th day of treatment, the number of larvae gradually decreased, and the state before the disintegration of the second sword was able to exhibit a high density inhibition effect in the solvent treatment zone of the control. In this case, the peak of the first generation (lower-generation) was not observed in the treatment zone until [==:] inhibited the number of parasitic larvae as much as the control agent. The __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ extract.

S 26 201216848 [Simplified illustration of the figure j Figure 1 shows the number of lower-generation individuals at the time of the feeding trial of fluniamide granules. The adult plant of the brown planthopper showed the granules of the flonitamine seedling box treatment. A graph showing the results of the suppression effect of the next generation of individuals on the occasion of the feeding trial of the brown planthopper, the adult, according to the treatment. [Main component symbol description] None 0 27

Claims (1)

201216848 VII. Scope of application for patents: ^ The raw material of the raw material is used as a dry _, and its age is as effective as i, such as the application of sashimi 1 slave _ oblique _, the insecticide as the active ingredient of flunisamide rice 4. A pest that crosses the tail / stands ί Γ the pest. : 4 parasitic action of rice parasitic sucking pests; containing (four) = cis, (four) - step 4 of the # ray for interference green, its cap step 7 such as ^ two generations of individuals 'protected rice from the pests of the disease. Item 4 is a pest interfering action method in which the fluni gas is treated with α 1 to 24,000 *. The method for interfering with the pests of the fourth item of the soil circumference, wherein the treatment of the insects of the four items of the insects is carried out in the nursery box. Γ.5— ί 有 有 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物 生物A composition for pest control according to claim 10, wherein the water-resistant bath resin is an ethylene-acrylic acid copolymer. 12. For the pest control composition of the first paragraph of the patent scope of May, it further contains a humectant. 13. The composition for pest control according to claim 12, wherein the humectant is polyoxyethylene styryl phenyl ether sulfate. 14. The composition for pest control according to the first aspect of the invention, wherein the flunisamide has an average particle diameter of from 1 to 100 μm. 28 S 201216848 § 15. A composition for pest control, which is exemplified in the scope of the patent application. The composition for pest control is a granule. 16. The method for controlling a pest control according to claim 15 which comprises the step of performing a copolymerization and drying of fluniin and ethylene-acrylic acid. This σ / this withdrawal of pellets 17.- lipid pests (four) inspection joints, listening to Wei-nil and water-insoluble trees == please patent fine 丨 7 items have * biology (four) reliance, which also contains L9 into one Matter = 5 matter _ composition, which is like ___ π, the pattern: 29