TW201210812A - Curable resin composition, laminate comprising same, and process for production of the laminate - Google Patents

Curable resin composition, laminate comprising same, and process for production of the laminate Download PDF

Info

Publication number
TW201210812A
TW201210812A TW100121058A TW100121058A TW201210812A TW 201210812 A TW201210812 A TW 201210812A TW 100121058 A TW100121058 A TW 100121058A TW 100121058 A TW100121058 A TW 100121058A TW 201210812 A TW201210812 A TW 201210812A
Authority
TW
Taiwan
Prior art keywords
resin composition
curable
resin layer
surface material
forming
Prior art date
Application number
TW100121058A
Other languages
Chinese (zh)
Other versions
TWI481503B (en
Inventor
Satoshi Niiyama
Naoko Aoki
Hitoshi Tsushima
Toyokazu Suzuki
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Publication of TW201210812A publication Critical patent/TW201210812A/en
Application granted granted Critical
Publication of TWI481503B publication Critical patent/TWI481503B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/1303—Apparatus specially adapted to the manufacture of LCDs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/067—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
    • B32B2457/202—LCD, i.e. liquid crystal displays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B32B37/1009—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using vacuum and fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1339—Gaskets; Spacers; Sealing of cells
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00—Materials and properties
    • G02F2202/28—Adhesive materials or arrangements

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonlinear Science (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Liquid Crystal (AREA)
  • Polymerisation Methods In General (AREA)
  • Sealing Material Composition (AREA)

Abstract

Disclosed is a curable resin composition which can fix surface materials to each other satisfactorily in the lamination/ integration of the surface materials through a resin layer comprising a cured product of the curable resin composition, and which can reduce a stress caused by the shrinkage of the resin layer upon curing. Specifically disclosed is a curable resin composition characterized by comprising a curable compound (II) and a non-curable oligomer (D), wherein the content of the non-curable oligomer (D) is 10 to 90 mass%. The curable compound (II) comprises one or more curable compounds that can cause a curing reaction in the curing of the curable resin composition, and at least one of the curable compounds has a hydroxy group that cannot react in the curing of the curable resin composition. The non-curable oligomer (D) cannot cause a curing reaction with the curable compound (II) in the curing of the curable resin composition, and is an oligomer having 0.8 to 3 hydroxy groups per molecule.

Description

201210812 六、發明說明： 【明戶斤屬々貝3 發明領域 本發明係關於頗適於面材接合的硬化性樹脂組成物、 使用該硬化性樹脂組成物進行面材層積的層積體、以及該 層積體之製造方法。 發明背景 在顯示元件上隔著接合樹脂層進行保護板層積的顯示 裝置，當使接合樹脂層硬化時，因該接合樹脂層的收縮所 產生應力會有對顯示元件造成影響之可能性。若對顯示元 件施加應力，便會發生下述問題。 •顯示元件中的顯示形成材料（以下稱「顯示材」）會因 應力而受影響，會有損及顯示均勻性之虞。例如#液晶顯 示元件的情況而言’顯示元件中所封入液晶的排列會因外 部應力而凌亂，導致被檢視到顯示斑。 •當在顯示元件靠顯示面側之基板表面上，形成諸如 視野角等為改善顯示品質用的光學膜時，因應力會導致該 光學膜的光學特性出現局部性變化，而有損及顯示之均句/ 性之虞。 再者’因為接合樹脂層係設置於顯示元件的檢視側，因 而若硬化的接合樹脂層中有存在氣泡，便會發生下述問題。 •來自顯示元件的出射光或反射光會因氣泡而凌亂， 會有大幅損及顯示影像之晝質之虞。 3 201210812 因為通過保護板殘存 •當顯示元件沒有顯示影像時 因而會有大幅損 於接合樹脂層中的氣泡較容易被檢視到 及製品品質的可能性。 •樹脂層與㈣元件間之界面料力、賴脂層與保 濩板間之界面接著力會降低。 —製造具有在顯示元件上層積有透明面材之層積構造顯 示裝置的方法，已知有如下述方法。 ⑴在樹脂製紐板上注人液態原料使硬化㈣成接合 樹脂後’或將捲片狀接合樹脂以脫氣狀態貼設於樹脂製保 護板上之後，-邊將液晶單元從—端按押—邊使以脫氣狀 態進行密接並層㈣方法i合飽旨的補較佳係使用聚 矽氧凝膠(專利文獻1)。 (2)在玻璃製保護板的狀位置處，利賴著構件將顯 示面板予以定位而暫時固定後，再對保護板與顯示面板之 間所形成的空間中，以減壓狀態注人液態樹脂材料並使硬 化，藉此而層積的方法。液態樹脂材料較佳係使用聚矽氧 樹脂（專利文獻2)。 先行技術文獻 專利文獻 專利文獻1:日本專利特開平7-209635號公報 專利文獻2 :曰本專利特開2006-58753號公報 【發明内容】 發明概要 發明欲解決之課題 201210812 ▲根據本發明者等的發現，藉由降低形成接合樹脂層的 树月日之極性與分子量，便可使接合樹脂層的彈性模數降 低。若在顯示元件與透日㈣材間所介存的接合樹脂層之彈 性模數降低，則硬化收縮時所產生的應力便會變小，俾可 抑制對顯示品質的影響。 然而，僅依賴降低#合樹脂層的彈性模數，會有將顯 示元件與透明面材予以固^的力嫌不^之情況例如當顯 示裝置係呈垂直設置使用時，顯示树會有經時性從透明 面材上偏移脫落、或脫離的可能性。 又，雖亦考慮在接合樹脂層的原料方面盡可能使用高 分子量的硬化前驅體化合物，俾使硬化反應之結合部位數 相對地減少，藉此使接合樹脂層的彈性模數降低之方法， 但未硬化時的組成物黏度變得過高而恐有難以注入或塗佈 之虞。此外，若因結合部位數減少而使得硬化後樹脂層的 交聯密度變得過小，帛以固定顯示元件與透明面材的力道 將變得不夠’例如當顯示裝置係呈#直設置❹時，顯示 元件會有經時性從透明面材上偏移脫落、或脫離的可能性。 本發明係有鑒於前述事情而完成，目的在於提供：當 隔著由硬化性樹脂組成物的硬化物所構成的樹脂層，將面 材層積一體化時，可將面材彼此間予以充分固定，且可降 低因樹脂層硬化時的收縮而產生之應力的硬化性樹脂組成 物及已使用該硬化性樹脂組成物進行面材之層積的層積 體。 再者，本發明目的在於提供：當隔著由硬化性樹脂組 201210812 成物的硬化物所構成樹脂層，將面材層積_體化時，可將 面材彼此間予以充分固定，且可降低因樹脂層硬化時的^ 縮所產生之應力，且可充分抑制樹脂料之氣泡產生的層 積體之製造方法。 曰 用以欲解決課題之手段 本發明的硬化性樹脂組成物，係使用於層積體，該層 積體係使未硬化之硬化性樹脂組成物挾持於一對面材間並 使其硬化而形成者，其特徵在於：前述—對面材係至少— 面材為透明，而前述硬化性樹脂組成物含有下述硬化性化 合物（II)及下述非硬化性寡聚物(D)，且該非硬化性寡聚物 (D)的含量係10〜90質量％ ; 硬化性化合物(II):由硬化性樹脂組成物硬化時會進行 硬化反應的硬化性化合物之1種以上構成，該硬化性化合物 的至少1種係具有在前述硬化性樹脂組成物硬化時不進行 反應的經基。 非硬化性募聚物(D):其係在硬化性樹脂組成物硬化時 不會與前述硬化性化合物(II)進行硬化反應，且每丨分子具 有0.8〜3個羥基的寡聚物。 較佳為前述硬化性化合物（II)係含有具硬化性基且具 羥基的單體。 較佳為前述硬化性化合物(II)係含有：寡聚物(A’），其 具硬化性基且分子量為1000〜100000 ;及單體(B〇，其具硬 化性基且分子量為125〜600，並且該單體(B，)含有具羥基的 單體(B3)。 201210812 二為〜前述非硬化性寡聚物(D)係聚氧伸境 知財暴聚物⑷係使用聚氧伸烧基多 醋為原料而合成的胺甲義旨寡聚物。 車X佳為前述寡聚物(A，)係具有丙 mi夕谷丨 文卷而月|j述單體 (B)之至少—部分係具有甲基丙烯酸基。 頫 -2且碳數3〜8 之 較佳為前述單體(B3)係含有具羥基數1 經炫*基的曱基丙稀酸經基醋。 較佳為前述單體(B，)係含有選自於由具碳數8〜u — 基的曱基丙烯酸烷基酯所構成群組中的單體⑴4)。之烷 較佳為不含有鏈轉移劑，或者含有鏈轉移劑，伸复八 量相對於硬化性化合物(11)100質量份計在〖質量份以^其含 本發明所提供的層積體，係由至少一去 — I钧边明面材的 一對面材隔著樹脂層進行層積而一體化者， 丘5亥Μ脂層倍 由本發明之硬化性樹脂組成物的硬化物所構成。 ’、 較佳為前述一對面材之其中一者係透明面材， 者係顯示元件。 另 本發明層積體之製造方法，該欲製造之層積體係 備：第1面材及第2面材，該第1及第2面材中的其中 '具 透明面材；樹脂層，係由該第i面材及第2面材所失持者係 及密封部，係包圍樹脂層周圍，該製造方法係包括有下= 步驟(a)〜(d): ' (a)在第1面材表面周緣部，塗佈含有硬化性化合物⑴ 及聚合起始劑的液狀密封部形成用硬化性樹嗚組成物，而 形成未硬化密封部的步驟； 201210812 (b) 對由未硬化密封部所包圍的區域，供應由本發明之 更化叫脂組成物所構成之樹脂層形成用硬化性樹脂組成 物的步驟； (c) 在1 〇〇pa以下的減壓環境下，於樹脂層形成用硬化性 樹月曰組成物上重曼第2面材’而獲得樹脂層形成用硬化性樹 脂組成物已由帛1面材、第2面材及未硬化密神所密封之 層積前驅體的步驟；及 (d) 在將層積前驅體放置M5〇kpa以上之壓力環境下的 狀態下，使未硬化密封部及樹脂層形成用硬化性樹脂組成 物進行硬化之步驟。 較佳為前述第1面材及第2面材之其中一者係透明面 材，另一者係顯示元件。 發明效果 根據本發明的硬化性樹脂組成物，藉由使其挾持於面 材之間並使硬化，便可將一對面材充分地固定，並可降低 因硬化時的收縮所產生之應力。 根據本發明的層積體，面材與面材可隔著樹脂層充分地 被固定’且可降低因該樹脂層硬化時的收縮所產生之應力。 根據本發明層積體之製造方法，可將一對面材隔著由 本發明硬化性樹脂組成物的硬化物所構成樹脂層充分地予 以固定，並可降低因該樹脂層硬化時的收縮所產生之應力， 且可在充分抑制樹脂層中氣泡發生的情況下製造層積體。 本發明的層積體係例如顯示裝置，根據本發明的製造 方法，可充分抑制顯示元件與保護板間之樹脂層中氣泡產 201210812 ”'、貝示元件與保護板隔著該樹脂層充分地被固定，且硬 化收縮時的應力可降低，便可獲得_止_應力所造成 顯示品質降低的顯示裝置。 圖式簡單說明 第1圖係利用透明面材保護顯示元件的顯示裝置一例 之剖視圖。 第2圖係第1圖之顯示裝置的平面圖。 第3圖係步驟(a)的態樣一例平面圖。 弟4圖係步驟(a)的態樣一例剖視圖。 第5圖係步驟(b)的態樣一例平面圖。 第6圖係步驟(b)的態樣一例剖視圖。 第7圖係步驟(c)的態樣一例剖視圖。 第8圖係步驟(d)的態樣一例剖視圖。 【實夠*方式】 用以實施發明之形態 本發明中，定義如下述。 「顯示裝置中，將成為顯示元件之保護板的透明面材稱 表面材」，將顯示元件稱「背面材」。 將表面材與背面材統稱為「面材」。 4面材巾，於本發明的製造方法巾，將麟部形成有 密封部且由密封部所包_區域被供應液狀硬化性樹脂組 成物的面材稱「第i面材」，將重疊於該硬化性樹脂組成物 上的面材稱「第2面材」。 將具有光穿透性的面材稱「透明面材」。 201210812 將由玻璃構成的透明面材稱「玻璃板」。 甚_ μ下’舉本發明較佳實卿態，就本發明的層積體係 』下裝置，—對面材係表面材(成為保護板的透明面材)與背 =材（顯示元件），且密封部形㈣硬化性樹肋祕及樹脂 曰形成用硬化性樹脂組成物係光硬化性樹脂組*物的實施 形態進行說明。 <顯示裝置> 第1圖係本貫施形態的顯示裝置一例之剖視圖，第2圖 係平面圖。 顯示裝置1係具有：透明面材10(第2面材（或第1面 材））、顯示元件50(第1面材（或第2面材)）、樹脂層40、密封 部42、可撓性印刷電路板54(FPC)、及遮光印刷部55(遮光 。叼，該透明面材10係屬於表面材，該顯示元件5〇係屬於背 面材，該樹脂層40係由透明面材1〇與顯示元件5〇所包夾， 5亥密封部42係包圍著樹脂層40的周圍，該可撓性印刷電路 板54係連接於顯示裝置50且搭載有使顯示裝置50啟動之驅 動1C，該遮光印刷部55係形成於透明面材10的周緣部。 顯示裝置1中，在透明面材10的周緣部設置遮光印刷部 55，且由遮光印刷部55所包圍的透光部56之面積小於由密 封部42所包圍的樹脂層40之面積，透明面材1 〇的面積係大 於顯示元件50的面積，樹脂層40與密封部42的合計面積小 於透明面材10與顯示元件50的各面積。 [表面材] 表面材係顯示元件之顯示影像能穿透過的透明面材 10 201210812 (保護板）。 透明面材係可舉例如玻璃板、或透明樹脂板，就對來 自顯示元件的出射光與反射光呈高透明性的觀點，當然亦 就具有对光性、低雙折射性、高平面精度、耐表面刮傷性、 高機械強度等觀點，最佳為玻璃板。就為使光硬化性樹脂 組成物進行硬化的光能充分穿透之觀點’亦是以玻璃板為 佳0 玻璃板的材料係可舉例如鈉鈣玻璃等玻璃材料，較佳 係鐵份更低、偏藍少的高穿透玻璃（冕玻璃P為提高安全 性，表面材亦可使用強化玻璃。 透明樹脂板的材料係可舉例如透明性高的樹脂材料 (諸如聚碳酸酯、聚甲基丙烯酸曱酯等）。 在透明面材中，為提升與樹脂層間之界面接著力，亦 可施行表面處理。表面處理的方法係有如：對透明面材之 表面利用碎院偶合劑施行處理的方法、或者利用由火焰燃 燒器所產生的氧化火燄形成氧化矽薄膜的處理等。 在透明面材上，為提高顯示影像的對比，亦可在與樹 脂層間的接合面之背面設置抗反射層。抗反射層係可利用 諸如在透明面材的表面上直接形成無機薄膜的方法、或將 设有抗反射層的透明樹脂薄膜貼合於透明面材上的方法而 進行設置。 再者，配合影像顯示之目的，透明面材之一部分或全 體亦可預先騎著色、或呈毛破璃狀而使光散射 、或利用 表面的細微凹凸等而使穿透時的光折射、或反射。又，亦 201210812 可將如上述樣態的光學膜、偏光膜等進行光學調變的光學 膜等經貼合於透明面材上形成一體物，使用為透明面材。 透明面材的厚度，就機械強度、透明性的觀點，當屬 玻璃板時通常為0.5〜25mm。在室内使用的電視接收器、PC 用顯示器等用途上，就顯示裝置的輕量化觀點，較佳為 0.7〜6mm，而設置於室外的大眾顯示用途時，較佳為 3〜20mm。透明面材係可使用強化玻璃，當透明面材較薄時 便可使用化學強化玻璃。透明樹脂板的情況較佳係 2〜10mm 〇 [背面材] 背面材係顯示元件。 圖示例的顯示元件50係將設有彩色濾光片的透明面材 52、與設有TFT的透明面材53進行貼合，再將其利用一對偏 光板51夾持而構成的液晶顯示元件一例，但本實施形態的 顯示元件並不侷限於圖示例。 顯示元件係在至少其中一者為透明電極的一對電極 中，挾持利用外部之電氣信號而變化光學樣態的顯示材。 依照顯示材的種類，有諸如：液晶顯示元件、EL顯示元件、 電漿顯示元件、電子墨水型顯示元件等。又，顯示元件係 具有貼合一對面材且該一對面材至少一者為透明面材的構 造，並配置成透明面材側鄰接於樹脂層。此時，部分的顯 示元件係在與樹脂層相鄰侧的透明面材最外層側，設置諸 如偏光板、相位差板等光學膜。此情況，樹脂層係呈顯示 元件上的光學膜與表面材相接合的樣態。 12 201210812 對顯不元件與樹脂層的接合面，為提升與密封部間之界 面接著力，亦可施行表面處理。表面處理係可僅對周緣部施 灯’亦可對面材的整體表面實施。表面處理的方法有如利用 可低溫加工的接著用底漆等施行處理之方法等。 顯不元件的厚度係當屬於利用TFT啟動的液晶顯示元 件時，通常為0.4〜4mm，當屬於EL顯示元件時通常為 0·2〜3mm。 [樹脂層] 樹脂層係由本發明的硬化性樹脂組成物（以下亦稱「樹 脂層形成用光硬化性樹脂組成物」）進行硬化而構成的層。 本發明的硬化性樹脂組成物（本實施形態的樹脂層形 成用光硬化性樹脂組成物），係可降低硬化後的彈性模數， 並可降低進行硬化時所產生的應力。所以，可抑制因該應 力對顯示元件的顯示性能造成不良影響。又，該硬化性樹 脂組成物在未硬化時的黏度較低，所以能在短時間施行對 面材表面的硬化性樹脂組成物供應，因而容易防止在表面 材與背面材的層積後出現氣泡殘留情形。 樹脂層的厚度較佳係0_03〜2mm、更佳係〇.1〜〇.8mm、 特佳係0.2〜0.6mm。若樹脂層的厚度達〇.〇3mm以上，樹脂 層便可有效的緩衝因來自透明面材側的外力所造成衝擊 專’俾可保護顯示元件。特別係當顯示元件對外力屬於敏 銳，較容易影響顯示品質的情況’較佳係設成達0.2mm以 上的厚度。又，本實施形態的製造方法中，即便在透明面 材與顯示元件之間混入超越樹脂層厚度的異物，樹脂層的 13 201210812 厚度仍不會有太大的變化’對光穿透性能的影響較少。若 樹脂層的厚度在2mm以下’在樹脂層中不易殘留氣泡，且 顯示裝置的整體厚衫會成W餘的厚。讀脂層的彈性 模數較小之情況，物制顯示元件經時性接合位置偏移等 情形，較佳係設為〇.6mm以下的厚度。 调整樹脂層厚度的方法，係有如調節後述密封部的厚 度’且同時調節對第丨面材所供應之液狀樹脂層形成用光硬 化性樹脂組成物的供應量之方法。 [密封部] 密封部係塗佈後述液狀密封部形成用光硬化性樹脂組 成物，經硬化而構成者。因為顯示元件的影像顯示區域之 外側區域比較狹窄，因而密封部的寬度以狹窄為宜。密封 部的寬度較佳係0.5〜2mm、更佳係ο』〜i.6mm。 [遮光印刷部] 視需要，可在透明面材的周緣部設置遮光印刷部。遮 光印刷部係依顯示元件的影像顯示區域之外均無法從透明 面材側看到的方式，隱藏連接於顯示元件的配線構件等。 遮光印刷部係可設置於透明面材與樹脂層的接合面、或其 背面’就降低遮光印刷部與影像顯示區域的視差之觀點， 以设置於透明面材與樹脂層的接合面為佳。當透明面材係 玻璃板的情況，若遮光印刷部係使用含黑色顏料的陶瓷印 刷’則遮光性較高，屬較佳。藉由將表面或背面已設有遮 光印刷部的透明薄膜貼合於透明面材上，亦可形成遮光印 刷部。亦可使用沒有遮光印刷部的透明面材。 201210812 [形狀] 顯示裝置的形狀通常係矩形。 顯示裝置的大小並無特別的限定，因為本實施形態的 製造方法特別適用於較大面積之顯示裝置的製造，因而告 屬於採用液晶顯示元件之情況，以pc螢幕的情況而言較佳 為(Umx〇.i8m，以電視接收器的情況而言較佳為〇 以上、更佳為〇.7mx〇.4m以上》顯示裝置的大小上限大多係 依照顯示元件的大小而決定。又，過大的顯示裝置在^置 等處理上容易趨於困難。顯示裝置的大小上限係從鸪等阼 制觀之’通常為2.5mxl_5m程度。小型顯示器的情況，較佳 為 0.14mx〇.〇8m 以上。 成為保護板的透明面材' 與顯示元件的尺寸係可為大 致相等，但就與收納顯示裝置的其他框體間之關係，多數 情況係透明面材較顯示元件大一圈。又，相反的依照其他 框體的構造，亦可使透明面材若干小於顯示元件。 <顯示裝置之製造方法> 本貫施形態的顯示裝置之製造方法，係包括有下述步 驟(a)〜(d)的方法。 ’ V 弟i面材（月曲材（或表面材))的表面周緣部，塗佈 含有硬化性化合物(I)及光聚合起始劑(α)的液狀密封 成用光硬化性樹脂組成物，而形成未硬化密封部的㈣ (但，當第1面材係顯示元件的情況，便在影像顯示側的表 面上形成密封部）。 (b)對未硬化柳卩所包_區域，供應含有硬化性化 15 201210812 合物(π)與光聚合起始劑(C2)的液狀樹脂層形成用光硬化性 樹脂組成物之步驟。 (c) 在lOOPa以下的減壓環境下，於樹脂層形成用光硬化 性樹脂組成物上重疊第2面材（表面材（或背面材）），而獲得 樹脂層形成用光硬化性樹脂組成物已由第丨面材、第2面材 及未硬化密封部加以密封之層積前驅體的步驟(但，當在第 2面材的表面設有抗反射膜時，便依其背面側的表面鄰接樹 脂層形成用光硬化性樹脂組成物的方式重疊。又，當第2面 材係顯示元件的情況’便依影像顯示側鄰接於樹脂層形成 用光硬化性樹脂組成物的方式重疊）。 (d) 將層積前驅體放置於5〇kPa以上之壓力環境下並於 此狀態下，對未硬化密封部及樹脂層形成用光硬化性樹脂 組成物施行光照射，而使硬化的步驟。 當透明面材上沒有形成遮光部的情況，便從層積前驅 體靠透明面材側，透過透光部對密封部及樹脂層形成用光 硬化性樹脂組成物照射光。 當在透明面材的周緣部有形成遮光部的情況，由該遮 光部所包圍的透光部面積，係小於由密封部所包圍的樹脂 層面積，且上述樹脂層形成用光硬化性樹脂組成物中所含 光聚合起始劑(C2)所具有的吸收波長區域（；12)，較上述密 封部形成用光硬化性樹脂組成物中所含光聚合起始劑（Ci) 的吸收波長區域（λ 1)更靠長波長側存在，而使在上述步驟 (d)中從層積前驅體的側邊所照射的光，涵蓋吸收波長區域 (λ 1)内的波長光及吸收波長區域（又2)内的波長光。 16 201210812 本貫施形態的製造方法係在減壓環境下，於第丨面材與 第2面材之間封入液狀樹脂層形成用光硬化性樹脂組成 物，在大氣壓環境下等高壓力環境下，使所封入的樹脂層 形成用光硬化性樹脂組成物硬化而形成樹脂層的方法（減 壓層積方法）。在減壓下進行樹脂層形成用光硬化性樹脂組 成物的封入，並非在第1面材與第2面材的間隙之窄而寬空 間中注入樹脂層形成用光硬化性樹脂的方法，而是對第丄面 材的幾乎整面供應樹脂層形成用光硬化性樹脂組成物，然 後重疊上第2面材，而在第1面材與第2面材之間封入樹脂層 形成用光硬化性樹脂組成物的方法。 在減壓下進行液狀樹脂層形成用光硬化性樹脂組成物 的封入、以及在大氣壓下利用樹脂層形成用光硬化性樹脂 組成物的硬化而進行透明層積體的製造方法一例，係屬公 知。例如國際公開第2008/81838號小冊子、國際公開第 2009/16943號小冊子所記載的透明層積體之製造方法、以 及該製造方法所使用的光硬化性樹脂組成物，均納入於本 說明書中。 [步驟⑷] 首先，沿第1面材一表面的周邊部形成未硬化密封部。 第1面材係可任意使用背面材、或使用表面材。 第1面材係當屬於成為顯示元件之保護板的透明面材 時’形成未硬化密封部之面係可任意為2個表面中之任一 面。當2個表面的性狀不同等情況時便選擇需要的一表面。 例如當其中一表面有施行為提升與樹脂層間之界面接著力 17 201210812 的表面處理時，便在該表面上形成未硬化密封部。又，卷 虽 在其中一表面上設有抗反射層的情況，便在其背面形成未 硬化密封部。 ¥第1面材係顯示元件的情況’形成未硬化密封部之 面便為影像顯示側的表面。 未硬化密封部重點在於：在後述步驟(C)中，具有、夜狀 樹脂層形成用光硬化性樹脂組成物不會從未硬化密封部與 第1面材間之界面、以及從未硬化密封部與第2面材間之界 面處茂漏出程度以上的界面接著力’以及具有能維持形狀 之程度的堅固度。所以，未硬化密封部最好係將黏度較高 的社封部形成用光硬化性樹脂組成物，利用諸如印刷、八 配等施行塗佈而形成。 再者’為保持第1面材與第2面材間之間隔，亦可在密 封部形成用光硬化性樹脂城物巾雜既定純的間隔粒 在达、封部形成用光硬化性樹脂組成物剛塗佈後，亦可 立即藉由照射用以使密封部硬化的光而使密封部呈局部性 半硬化，使密封部的形狀維持更長時間維持。 [密封部形成用光硬化性樹脂組成物] 密封部形成用光硬化性樹脂組成物（以下亦稱「密封 材」）’係含有光硬化性之硬化性化合物⑴與光聚合起始劑 (C1)的液狀組成物。 密封部形成用光硬化性樹脂組成物的黏度，較佳係 500〜3_Pa · S、更佳係_〜2500Pa · S、特佳係1〇〇〇〜 201210812 2000Pa· s。若黏度達500Pa· s以上，便可較長時間維持未 硬化密封部的形狀，可充分維持密封部的高度。若黏度在 3000Pa . s以下，便可利用塗佈法形成密封部。 密封部形成用光硬化性樹脂組成物的黏度，係在25它 下’使用E型黏度計進行測定。 (硬化性化合物(I)) 硬化性化合物⑴係就容易將密封部形成用光硬化性樹 脂組成物的黏度調整於前述範圍内的觀點，較佳係含有寡 聚物⑷之丨種以上、與單體⑼之丨種以上，該寡聚物⑷係 具有硬化性基且數量平均分子量為3〇〇〇〇〜1〇〇〇〇〇 ;該單體 (B)係具有硬化性基且分子量為丨25〜6〇〇。 募聚物(A)或單體(B)之硬化性基係可舉例如：加成聚合 性的不飽和基(諸如丙烯醯氧基、曱基丙烯醯氧基等”不飽 和基與硫醇基的組合等，就能獲得硬化速度快速與透明性 向之密封部的觀點，較佳係選自於由丙烯醯氧基及曱基丙 烯醯氧基所構成群組的基。 募聚物(A)中之硬化性基、與單體(B)中之硬化性基係可 互為相同、亦可為不同。因為分子量較高的寡聚物中之 硬化性基，反應性容易變得低於分子量較低的單體(B)中之 硬化性基，因而會有單體(B)的硬化先行進行導致組成物整 體的黏性急遽提高，造成硬化反應呈不均質的可能性。為 忐縮小二者硬化性基的反應性差，俾可獲得均質的密封 部，最好將寡聚物(A)中之硬化性基設為反應性較高的丙烯 醯氧基，並將單體(B)中之硬化性基設為反應性較低的甲基 201210812 丙烯醯氧基。 寡聚物(A)的數量平均分子量係30000〜100000、較佳係 40000〜80000、更佳係5〇000〜65000。若寡聚物(A)的數量平 均分子量在該範圍内，便容易將密封部形成用光硬化性樹 脂組成物的黏度調整於前述範圍内。 寡聚物（A)的數量平均分子量係利用Gpc測定而獲 得，屬於聚苯乙烯換算的數量平均分子量。另外，Gpc測 定中’當有ib現未反應之低分子量成分(單體等）的尖峰時， 便排除該尖峰求取數量平均分子量。 單體(B)的分子量係125〜_、較佳係14〇〜4〇〇、更佳係 150〜350。若單體(B)的分子量達125以上當利用後述減壓 層積方法進行顯示裝置製造時，便可抑制單體⑼的揮發。 若單體(_分子4在_町，便可提高單體(酬高分子 . 量寡聚物⑷的溶解性，俾可適當地進行㈣部形錢級 - 化性樹脂組成物的黏度調整。 (寡聚物(A)) 寡聚物⑷係就密封部形成用光硬化性樹脂組成物的 硬化性、密封部的機械特性等觀點，較佳為每i分子平均具 有1.8〜4個硬化性基者。 寡聚物(A)係可舉例如具有胺曱酸箱鍵結的胺甲酸酯 募聚物、聚氧伸貌基多元醇的聚（甲基）丙稀酸醋、聚酿多元 醇的聚（甲基）丙烯酸酯等β 依照胺甲酸酿鏈的分子設計等，就可廣範圍調整諸如 硬化後樹㈣機簡性、以及與吨間之密接性等觀點， 20 201210812 車乂佳係將夕辑與聚異氰義❹為原料而合成的胺甲酸 S曰寡聚物’更佳係後述胺甲酸酯寡聚物(A1)。多元醇較佳 係聚氧伸燒基多元醇。 (胺曱酸酯募聚物(A1)) 數量平均分子量在3〇〇〇〇〜1 〇〇〇〇〇範圍内的胺甲酸酯寡 聚物(Al) ’ g]為會成為高減，因喊難依照普通方法進 仃合成，即便可合成，但仍較難進行與單體的混合。 因而，較佳係依照使用單體(B)(下述單體(B1)與(B2)) 的合成方法合成胺甲_旨寡聚物(A1)後，直接將所獲得生成 物使用為密封部形成用光硬化性樹餘成物，或者將所獲得 生成物更進一步利用單體(B)(下述單體(B1)、單體(B3)等）進 行稀釋而使用為密封部形成用光硬化性樹脂組成物。 •單體(B1):單體(B)中，具有硬化性基且未具有會與 異氰酸酯基產生反應之基的單體。 •單體(B2):單體⑼中，具有硬化性基且具有會與異 氱酸酯基產生反應之基的單體。 •單體(B3):單體(B)中，具有硬化性基且具有羥基的 單體。 胺曱酸酯募聚物（A1)之合成方法： 在當作稀釋劑用的單體(B1)存在下，使多元醇與聚異 氰酸酯進行反應’而獲得具有異氰酸酯基的預聚物後，使 單體(B2)對該預聚物的異氰酸酯基進行反應之方法。 多元醇、聚異氰酸酯係屬於公知化合物，例如國際公開 第2009/016943號小冊子所記載當作胺曱酸酯系寡聚物(&)之 21 201210812 原料的多兀醇⑴、二異氰酸酯（…等，均納入於本說明書中。 多元醇⑴係可舉：聚氧乙二醇、聚氧伸丙基二醇等聚 氧伸烧基多元醇；聚酷多元醇、聚碳酸醋多元醇等。該等 之中’較佳係聚氧伸院基多元醇、更佳係聚氧伸丙基多元 醇。又，若將聚氧伸丙基乡元醇的氧伸丙基其卜部分取代 為氧伸乙基’便可提高樹脂層形成用光硬化性賴組成物與 其他成分的相溶性，因而屬更佳。 此處’所謂「亦可將氧伸丙基其中一部分利用氧伸乙 基進行取代」’係指將構成聚氧伸丙基多元醇分子的氧伸丙 基、、。構,、巾。卩刀’取代為氧伸乙基結構的分子結構。相 關後述同樣的記載亦係指相_涵義。氧伸乙基結構係π 依無規或嵌段存在於聚氧伸丙基多元醇分子卜又，氧伸 乙基結構係可在聚氧伸丙基多元醇分子的㈣，亦可剛好 位在末端經基之前。當氧伸乙基結構剛好位於末端經基之 ^情況，藉由在聚氧料❹元醇中域環氧乙院便可 係選自於脂_二異氰_ 1 旨及無變黃性芳香族二異氰_的二異# 醋。其令，脂肪族聚異氛酸醋之例係可舉例如： =氛酸酷、^三甲基_六亞甲基二異氰酸自旨、… :基-六亞“二異氣_等。脂環式聚異氰㈣之例係 =如汐佛爾酮二異氰_、亞甲基雙㈣己基異氛 醋）專。無變黃性芳麵二錢_係可舉例如伸茗基二 乳輯。該等係可單獨使用1種、亦可併用2種以上。 22 201210812 單體(B1)係可舉例如：具有碳數8〜22之烷基的（甲基） 丙烯酸烷基酯（諸如：（曱基）丙烯酸正十二烷基酯、（甲基） 丙烯酸正十八烷基酯、（甲基）丙烯酸正廿二烷基酯等）、具 有脂環式烴基的（曱基）丙烯酸酯（諸如：（甲基）丙烯酸異稻 酯、（曱基）丙烯酸金剛烷基酯等）。 單體(B2)係可舉例如具有活性氫（諸如羥基、胺基等） 及硬化性基的單體，具體係可舉例如：具有碳數2〜6之羥烷 基的（曱基）丙烯酸羥烷基酯（諸如：（甲基）丙烯酸-2-羥甲 酯、（曱基）丙烯酸-2-羥丙酯、（甲基）丙烯酸_2_羥丁酯、（甲 基）丙烯酸-4-羥丁酯等）等，較佳係具有碳數2〜4之羥烷基的 丙烯酸羥烷基酯。 (單體⑻） 單體(B)係就密封部形成用光硬化性樹脂組成物的硬 化性、密封部的機械特性等觀點，較佳為每1分子具有1〜3 個硬化性基者。 密封部形成用光硬化性樹脂組成物係就單體（B)而 言’亦可含有在上述胺曱酸酯寡聚物(A1)的合成方法中作 為稀釋劑用的單體(B1)。又，單體(B)亦可含有在上述胺甲 酸酯寡聚物(A1)的合成方法中所使用的未反應單體(B2)。 單體(B)係就面材與密封部間之密接性、後述各種添加 劑的溶解性之觀點，較佳為含有具羥基的單體(B3)。 具有羥基的單體(B3)較佳係例如：具有羥基數1〜2'碳 數3〜8之羥烷基的曱基丙烯酸羥基酯（諸如：曱基丙烯酸_2_ 經丙酯、甲基丙烯酸_2_羥丁酯、甲基丙烯酸-4-羥丁酯、甲 23 201210812 基丙烯酸-6-羥己酯、丙三醇單曱基丙烯酸酯等），更佳為甲 基丙稀酸-2-經丁 g旨。 密封部形成用光硬化性樹脂組成物中的單體(B)之含 有比例，在硬化性化合物⑴整體（100質量％)即寡聚物（A) 與單體(B)的合計（100質量％)中，以15~5〇質量％為佳、較佳 為20〜45質量％、更佳為25〜4〇質量％。若單體⑻的比例達 15質量％以上，密封部形成用光硬化性樹脂組成物的硬化 性、面材與密封部間之密接性便呈良好。若單體(B)的比例 在5〇質量％以下，便可輕易地將密封部形成用光硬化性樹 脂組成物的黏度調整於5〇OPa · s以上。 另外，在胺甲酸酯寡聚物(A1)的合成中，會與預聚物 的異氰酸S旨基產纽應之單帅2)，因為係轉聚物(A)一 部分的形式存在，EI而並不包括於密封部形成用光硬化性 樹脂組成物中的單體(B)含量中。另—方面，胺甲酸醋寡聚 物(A1)的合成中，作為稀釋劑使用的單體(Bi)、及在胺甲酸 醋寡聚物(A1)合成後才添加的單體(B)，係包括於密封部形 成用光硬化性樹脂組成物中的單體(B)含量中。 (光聚合起始劑（C1)) 密封部形成用光硬化性樹脂組成物中所含的光聚合起 始劑(C1)，係可舉例如：苯乙_、酮縮醇系、苯偶姻或 苯偶姻醚系、氧化膦系、二苯基酮系、噻噸酮系、醌系等 光聚合起始劑，較佳係例如：苯乙酮系、酮縮醇系、苯偶 姻醚系的光聚合起始劑。當利用短波長的可見光施行硬化 時’就吸收波長區域的觀點，李交佳係氧化膦系的光聚合起 24 201210812 始劑。藉由併用吸收波長區域不同的2種以上光聚合起始劑 (C1)，便可更加速硬化時間、或提高密封部的表面硬化性。 又’當在透明面材上設有遮光印刷部’並利用從面材的側 面之光照射，而使由遮光印刷部所挾持的未硬化密封部與 樹脂層形成用光硬化性樹脂組成物進行硬化時，亦可在不 會阻礙到未硬化密封部所鄰接部分的樹脂層形成用光硬化 性樹脂組成物的硬化之範圍内，併用後述光聚合起始劑 (C2)°當有併用的情況，聚合起始劑(C1)與聚合起始劑(C2) 的含有比例，就效率佳且有效的進行硬化之觀點，依(C1): (C2)的質量比計，較佳為5〇 :卜5 : i。為使由遮光印刷部 馳持的樹脂層形制級化性樹㈣成物，能隔著未硬 化密封材利用從面材側面所照射的光在短時間内硬化，密 封部形成用光硬化性樹脂組成物較佳係不含有光聚合起始 劑(C2)。 雄封部形成用光硬化性樹驗成物巾的光聚合起始劑 (C1)3量（备含有光聚合起始劑(C2)的情況，便為(C1)與(C2) 的合計量），係相對於硬化性化合物⑴整體（即寡聚物(A)與 軍體⑼的合計_質量份，較佳為0.01〜10質量份、更佳為 0·1〜5質量份。 (添加劑） 密封。卩形成用光硬化性樹脂組成物係視需要 ，亦可含 有例如·聚合終止劑、光硬化促㈣、鏈轉移劑、光安定 劑(諸如.紫外線吸收劑、自由基捕獲劑等）、抗氧化劑、難 燃化劑、接著性提升劑(魏偶合劑等）、顏料 ' 染料等各種 25 201210812 添加Μ ’較佳係含有聚合終止劑、光安定劑。特別係藉由 含有聚合終止劑之量少於聚合起始劑，便可改善密封部形 成用光硬化性樹脂組錢的安定性，亦可調整硬化後的樹 月曰層之分子置。當利用從面材的側面所照射之光使密封材 硬化時，具有使硬化反應延遲的效果之諸如聚合終止劑、 鏈轉移劑、光安定劑、顏料、㈣等，最好盡可能不要使 用、或減少含量。 〃聚合終止劑係可舉例如：氣蛾系（諸如2,5.二第三丁基 氫酿等）、兒茶㈣、（諸如對第三了基兒茶盼等）、蒽酿系、 盼嗟。井系、經甲苯系等聚合終止劑。 光女疋劑係可舉例如：紫外線吸收劑（諸如：苯并三唑 系、二苯基酮系、水楊酸醋系等）、自由基捕獲劑(諸如受阻 胺系）等。 抗氧化劑係可舉例如磷系、硫系的化合物。 該等添加劑的合計量係相對於硬化性化合物⑴整體即 募聚物(Α)與單體⑻的合計刚質量份，較佳為1〇質量份以 下、更佳為5質量份以下。 [步驟(b)] 經步驟(a)之後，便對由未硬化密封部所包圍的區域 中，供應液狀樹脂層形成用光硬化性樹脂組成物。 樹脂層形成用光硬化性樹脂組成物的供應量係預先設 疋為由密封部、第1面材及第2面材所形成空間會被樹脂層 形成用光硬化性樹脂組成物所填充，且將第丨面材與第2面 材之間隔開既定間隔（亦即樹脂層設為既定厚度）的份量。此 26 201210812 時’較佳_先考仙㈣層形成用光硬化性樹脂組成物 的硬化收縮而造成㈣賴少。所以，該份量較佳係樹脂 層升7成用光硬化性樹脂組成物的厚度，若干厚於樹脂層既 疋厚度的里。虽硬化收縮較小的情況，亦可將樹脂層的既 定厚度、與樹脂層形成用光硬化性樹脂組成物的厚度設為 大致相等。 供應方法係有如平放第1面材，並利用諸如分配器、模 具塗佈機等供應手段，呈點狀、線狀或面狀進行供應的方法。 [樹脂層形成用光硬化性樹脂組成物] 樹脂層形成用光硬化性樹脂組成物係液狀組成物且係 含有：光硬化性硬化性化合物(η)、光聚合起始劑(C2)、及 非硬化性寡聚物(D)。非硬化性寡聚物(D)係在樹脂層形成 用光硬化性樹脂組成物硬化時，不會與組成物中的硬化性化 合物(II)進行硬化反應，且每丨分子具有0.8〜3個羥基的寡聚 物。 樹脂層形成用光硬化性樹脂組成物的黏度，較佳係 0.05〜50Pa· s、更佳係1〜2〇pa· s。若黏度達0.05Pa· s以上， 便可抑制後述單體(B·)的比例，可抑制樹脂層的物性降低。 又，因為低沸點成分較少，因而頗適用於後述的減壓層積 方法。若黏度在50Pa· s以下，則樹脂層不易有氣泡殘留。 樹脂層形成用光硬化性樹脂組成物的黏度係在2 5 °C 下，使用E型黏度計進行測定。 (硬化性化合物(II)) 樹脂層形成用光硬化性樹脂組成物中的硬化性化合物 27 201210812 (π) ’係由該樹脂層形成用光硬化性樹脂組成物進行硬化 時’會進行硬化反應的硬化性化合物之1種以上構成，較佳 係該硬化性化合物之至少1種，具有在前述樹脂層形成用光 硬化性樹脂組成物進行硬化時，不會產生反應之羥基的化 合物(Ila)。 若硬化性化合物(π)係含有該化合物(na)，由硬化性化 合物(II)單獨進行硬化反應的硬化物中便存在羥基。該經基 的存在係對樹脂層形成用光硬化性樹脂組成物中的非硬化 性寡聚物安定化具有貢獻。 所以，具有前述硬化時不會產生反應之羥基的化合物 (Ila)’只要是硬化反應後有存在未反應羥基便可 ，例如即 使化合物(Ila)的羥基一部分進行硬化反應，另一部分未進 行硬化反應而以未反應狀態殘留的話便可。 該具有硬化時不會產生反應之羥基的化合物(IIa)，係 只要具有對硬化反應具貢獻的硬化性基且具有羥基者便 可’可為單體’亦可為具有重複單元的寡聚物。就較容易 調整未硬化時的光硬化性組成物黏度之觀點，較佳係使用 具有硬化性基且具有羥基的單體作為化合物(IIa)。屬於具 羥基之單體的化合物(Ila)具體例，較佳係：具有羥基數 1〜2、碳數3〜8之經烷基的（甲基）丙烯酸羥基酯[諸如：（甲基) 丙烯酸-2-羥丙酯、（甲基）丙烯酸_2_羥丁酯、（甲基）丙烯酸_4_ 經丁酯、（曱基）丙烯酸-6-羥己酯、丙三醇單（甲基）丙烯酸酯 等]’更佳係甲基丙烯酸-2-經丁醋。 硬化性化合物(II)較佳係含有寡聚物(八，)之〗種以上、與 28 201210812 單體(B’)之1種以上。該寡聚物(A，)係具硬化性基、且數量平 均分子量為1000〜100000，該單體(B’)係具有硬化性基、且 分子量為125〜600。若使用該硬化性化合物(11)，便可容易 將樹脂層形成用光硬化性樹脂組成物的黏度調整於前述較 佳範圍内。 此情況，較佳係單體(B，)至少一部分為使用具有硬化性 基並具有羥基且分子量為125〜600的單體(B3)。 寡聚物(A’)或單體(B，）中之硬化性基係可舉例如加成聚 合性不飽和基(諸如丙烯醯氧基、甲基丙烯醢氧基等）、或不 飽和基與硫醇基的組合等，就能獲得硬化速度快速及透明 性尚之樹脂層的觀點，較佳係選自於由丙烯醯氧基及甲基 丙烯醯氧基所構成群組的基。 养聚物(A')中之硬化性基、與單體(B')中之硬化性基係 可相互為相同、亦可不同。因為分子量較高的募聚物(A,) 之硬化性基，反應性較容易變得低於分子量較低的單體(B，） 之硬化性基，因而單體(B，)的硬化會先進行，導致組成物整 體的黏性急遽提高，會有造成硬化反應呈不均質的可能 性。為能縮小二者硬化性基的反應性差，俾可獲得均質樹 脂層，較佳係將寡聚物(A')中之硬化性基設為反應性較高的 丙烯醯氧基，且將單體(B·)中之硬化性基設為反應性較低的 曱基丙稀醯氧基。 (募聚物 募聚物(A’)的數量平均分子量較佳係ι〇〇〇〜100〇〇()、更 佳係10000〜70000。若寡聚物(A，)的數量平均分子量在該範 29 201210812 圍内’便容易將樹脂層形成用光硬化性樹脂㈣物的黏度 調整於前述範圍内。 寡聚物（A，）的數4平均分子量係利用Gpc測定所獲得 聚苯乙烯換算的數量平均分子量。另外，Gpc測定中，當 有出現未反魏好4齡(單料）的料時，㈣除該災 峰求取數量平均分子量。 寡聚物（A，)就樹脂層形成用光硬化性樹脂組成物的硬 化性、樹脂層的機械特性等觀點，較佳為每丨分子中平均具 有1.8〜4個硬化性基者。 寡聚物(A’)係可舉例如：具有胺甲酸酯鍵結的胺甲酸酯 寡聚物、聚氧伸院基多元醇的聚（曱基）丙烯酸酯、聚酯多元 醇的聚（甲基）丙烯酸酯等，就依照胺甲酸酯鏈的分子設計 等’可廣泛調整硬化後的樹脂機械特性、以及與面材間之 密接性等觀點，較佳為胺曱酸酯寡聚物(A2)。 胺曱酸酯寡聚物(A2)較佳係依照使多元醇與聚異氰酸 酯進行反應而獲得具異氰酸酯基之預聚物後，使該預聚物 的異氰酸酯基，與前述單體(B2)進行反應的方法而合成者。 多元醇、聚異氰酸S旨係屬於公知化合物，例如國際公開 第2009/016943號小冊子所記載當作胺甲酸酯系寡聚物(a)之 原料的多元醇(i)、二異氰酸酯（ii)等，均納入於本說明書中。 胺甲酸酯寡聚物（A2)亦可使用市售物’例如： EB230(DAICEL-CYTEC公司製，認為係官能基數2、聚丙二 醇/IPDI/丙烯酸-2-羥乙基己酯的反應生成物）、U-200AX(新 中村化學公司製，認為係官能基數2、脂肪族聚酯多元醇/ 30 201210812 脂肪族或脂環族聚異氰酸酯/丙烯酸_2_羥乙基己酯的反應 生成物）。 养聚物（A')的含有比例，在硬化性化合物(η)整體（1〇〇 質量。/〇)即寡聚物(A')與單體(B，)的合計（100質量％中，較佳 為20〜90質量％、更佳為30〜80質量％。若該寡聚物(A,)的比 例達20質量％以上，樹脂層的耐熱性會呈良好。若該寡聚物 (A)的比例在9〇質量％以下，則樹脂層形成用光硬化性樹脂 組成物的硬化性、以及面材與樹脂層間之密接性呈良好。 (單體(B')) 單體(B')的分子量較佳係125-600、更佳係14〇〜4〇〇。若 單體(B")的分子量達125以上，當依照後述減壓層積方法進 行顯示裝置的製造時，便可抑制單體揮發。若單體(B，)的分 子量在600以下，則面材與樹脂層間之密接性呈良好。 單體(B )係就樹脂層形成用光硬化性樹脂組成物的硬 化性、樹脂層的機械特性等觀點，較佳為每1分子具有1〜3 個硬化性基者。 單體(B1)的含有比例在硬化性化合物（η)整體（丨〇〇質量 %)即募聚物(A，)與單體(B，)的合計（1〇〇質量％)中，較佳為 10〜80質量％、更佳為20〜70質量％。 單體（B’）較佳係含有具硬化性基且具羥基的單體 (B3)。單體(B3)係對非硬化性寡聚物(D)的安定化具貢獻。 又，若使含有單體(B3)，便可輕易地獲得面材與樹脂層間 之良好密接性。單體⑺”的卜分子中之羥基數，係可任意選 擇能使非硬化性寡聚物(D)呈安定化的數目，但就取得容易 31 201210812 性的觀點，較佳為1分子中具有1〜2個。 具有羥基的單體(B3)，係可舉例如與密封部形成用光 硬化性樹脂組成物中的單體(B3)為同樣者，較佳為甲基丙 烯酸-2-羥丁酯。 單體(B3)的含有比例在硬化性化合物(I〗)整體（1〇〇質量 %)即募聚物(A·)與單體(B')的合計（1〇〇質量％)中，較佳為 10〜60質量％、更佳為20〜50質量％。若該單體(B3)的含有比 例達10質量％以上，便可輕易地充分獲得樹脂層形成用光 硬化性樹脂組成物之安定性提升、以及面材與樹脂層間之 Φ接性升的效果。右单體(B3)的含有比例在6〇質量％以 下’則由樹脂層形成用光硬化性樹脂組成物所構成硬化物 的硬度便不會變為過高，因而屬較佳。 單體(B')係就樹脂層的機械特性觀點，較佳係含有下述 單體(B4)。因為單體(B4)會使硬化後的樹脂層之玻璃轉移溫 度（Tg)降低，因而對硬化後的樹脂層之彈性模數降低具貢 獻，可提升該樹脂層的柔軟性。 但’當提高樹脂層形成用光硬化性樹脂組成物的硬化 性，並縮短硬化所需要時間等情況時，亦會有最好減少單 體(B4)的含量、或不要含有的情況。 單體(B4):選自於具有碳數8〜22之絲的甲基丙稀酸 烷基酯所構成群組之1種以上。若碳數達8以上，就可使硬 化物的玻璃轉移溫度降低之觀點，係屬較佳，若碳數在22 以下’就原料的醇可經由天‘然物輕易取得的觀點，係屬較 佳。 32 201210812 單體(B4)係可舉例如：曱基丙烯酸正十二烷基酯、甲基 丙烯酸正十八烷基酯、甲基丙烯酸正廿二烷基酯等，較佳為 甲基丙烯酸正十二烷基酯、或曱基丙烯酸正十八烷基酯。 單體(B4)的含有比例在硬化性化合物(II)整體（100質量 %)即寡聚物(A’)與單體(B，)的合計（1〇〇質量％)中，較佳為 5〜50質量％、更佳為15〜4〇質量。/。。若該單體⑺句的含有比 例達5質量％以上’便可輕易地獲得單體(B4)的充分添加效 (光聚合起始劑(C2)) 樹脂層形成用光硬化性樹脂組成物中所含的光聚合起 始劑(C2)，係可舉例如：苯乙酮系、酮縮醇系、苯偶姻或 苯偶姻醚系、氧化膦系、二苯基酮系、噻噸醐系、醌系等 光聚合起始劑，較佳為氧化膦系、或°塞嘲酮系的光聚合起 始劑，就經光聚合反應後抑制著色的觀點，更佳為氧化膦 系。 樹脂層形成用光硬化性樹脂組成物中的光聚合起始劑 (C2)之含量，相對於硬化性化合物(11)整體，即寡聚物(a,) 與單體(B’)的合計100質量份，較佳為0.01〜10質量份、更佳 為0· 1〜5質量份。 當利用從面材側邊所照射的光，而使密封材相鄰接的 樹脂層形成用光硬化性樹脂組成物其中一部分硬化時，光 聚合起始劑(C2)較佳係具有在較前述光聚合起始劑的 吸收波長區域⑴）’更靠長波長側所存在吸收波長區域（又 2)者。光聚合起始劑（C2)係可僅具有吸收波長區域（又2) 33 201210812 者、亦可具有與吸收波長區域U 1)重複的吸收波長區域(λι，) 及吸收波長區域(λ2)者。 (非硬化性寡聚物(D)) 非硬化性寡聚物(D)係在樹脂層形成用光硬化性樹脂 組成物中呈良好相溶且對硬化無具貢獻，因而可在不致損 及透明性與均質性的情況下，降低目劃旨層硬化時的收縮 所產生應力。 非硬化性寡聚物係在樹脂層形成用光硬化性樹脂 組成物進行硬化時，不會與組成物中的硬化性化合物(11)進 行硬化反應，每1分子中具有〇 8〜3個羥基的寡聚物。較佳 係每1分子的羥基為2〜3個。若每丨分子的羥基達〇.8個以 上，就非硬化性募聚物間，或者非硬化性寡聚物、與由硬 化性化合物(II)所獲得硬化物之間，可利用羥基間的相互作 用而安定地保持非硬化性寡聚物的觀點，係屬較佳，若每1 分子的羥基在3個以下，則就非硬化性寡聚物在樹脂層形成 用光硬化性樹脂組成物中可呈良好相溶的觀點，係屬較佳。 非硬化性寡聚物(D)平均1個羥基的數量平均分子量 (Μη)較佳係400〜8000。若平均1個羥基的數量平均分子量達 400以上，則非硬化性寡聚物(D)的極性不會變為過高，可 輕易獲得與樹脂層形成用光硬化性樹脂組成物中的硬化性 化合物(II)間之良好相溶性。若平均1個羥基的數量平均分 子量在8000以下，則利用源自硬化性化合物(π)的羥基、與 非硬化性寡聚物(D)的羥基間之相互作用，可輕易地獲得在 硬化後的樹脂層中使非硬化性寡聚物（D)呈安定化的效 34 201210812 果。該項相互作用推測係有氫鍵參與。 非硬化性寡聚_财單獨_種、亦可併用2種以 上。 旦t經基的非硬化性寡聚物（D)之例係可舉例如高分子 里的少⑽等，較佳為、聚氧伸院基多元醇、㈣多元醇、 或聚碳酸酯多元醇。 聚氧伸院基多元醇係可舉例如具有碳數2〜4個之氧伸 燒基重複單摘聚氧伸院基單醇、聚氧㈣基二醇或聚氧 伸烧基二醇。具體射舉例如：聚氧伸丙基單醇、聚氧乙 -醇、聚氧伸丙基二醇（以下亦稱「聚丙二醇」）、聚氧伸丙 基三醇、聚氧四亞曱基二醇等。 聚氧伸烷基多元醇平均1個羥基的數量平均分子量 (Μη) ’較佳係4〇〇〜8〇〇〇、更佳係6〇〇〜5〇㈨。 聚酷多元醇係可舉例如具有諸如：乙二醇、丙二醇、 μ 丁—醇等脂肪族二醇殘基、與諸如：戊二酸、己二酸、 癸二酸等脂肪族二㈣殘基的脂肪族系聚醋二醇。 匕聚碳酸S旨多元耗可舉例如：M•己二料具二醇殘基 的月曰肪族聚碳㈣二醇；或者脂肪族環狀碳酸㈣開環聚 合體專脂肪族聚碳酸醋二醇。 及酯多元醇或聚碳酸酯多元醇平均丨個羥基的數量平 均分子量(Μη)，較佳係400〜8000 '更佳係8〇〇〜6〇〇〇。 本說明書中，非硬化性寡聚物(D)的數量平均分子量係 由根據JISK1557-l(20〇7年版）所測定的經值Α(κ〇Η mg/g)、與非硬化性寡聚物(0)1分子内的羥基數Β，依照下 35 201210812 式u)進行計算出的值。 非硬化性暴聚物(D)的分子量=56 1xBx1〇〇〇/a (1) 就硬化後的樹脂層彈性模數容易變為更低的觀點，非 硬化性寡㈣(D)較㈣使料氧佩基多元醇、更佳係使 用聚氧伸丙基多it醇。X ’如後述，為調節非硬化性寡聚 物⑼的極性，亦可將聚氧伸丙基多元醇的氧伸丙基一部分 利用氧伸乙基進行取代。亦可將氧伸丙基—部分利用氧伸 乙基進行取代，此部分係與前述多元_中的說明相同。 例如就相溶性的觀點，較佳為寡聚物(A，)係將聚氧伸烷 基多元醇與聚異氰酸酯使用為原料而合成的胺曱酸酯寡聚 物，而非硬化性寡聚物(D)係聚氧伸烷基多元醇。 本發明中，為使未硬化時的樹脂層形成用光硬化性樹 脂組成物呈安定，俾抑制非硬化性寡聚物(D)從硬化後的樹 月曰層中刀離，較佳係寡聚物(A’)與非硬化性寡聚物(〇)具有 相同結構或類似結構的分子鍵。 具體而言，在合成樹脂層形成用光硬化性樹脂組成物 中之寡聚物(A·)時的原料，較佳係使用諸如多元醇等具羥基 的化合物（以下亦稱「含經基的化合物」），且將該相同的含 經基化合物使用為非硬化性寡聚物(D)。 例如當寡聚物(A')係將聚氧伸烷基多元醇與聚異氰酸 酯使用為原料而合成的胺甲酸酯寡聚物時，較佳係將該聚 氧伸烷基多元醇使用作為非硬化性寡聚物(D)。 或者’當使用為寡聚物(A')原料的含羥基化合物、與使 用為非硬化性寡聚物(D)的含羥基化合物，並非屬相同的情 36 201210812 況，較佳係二者分子鏈具有共通的重複單元等，部分性具 有共通結構’且將二者的極性設為相同程度。極性的調整 方法係有如：藉由導人姉基而提高姉的方法、藉由將 氧伸丙基。p刀利用氧伸乙基進行取代而提高極性的方 法、以及藉崎低平基的分子量而提高極性的方法 等。該等方法亦可組合使用。 例如券聚物(A)係使用了氧伸丙基一部分利用氧伸乙 基進行取代的聚氧伸丙基多㈣(a,)、及聚異氰酸醋，使用 為原料而合成的胺甲_旨絲物時，作為非硬化性募聚物 (D)較佳係使用不具有氧伸乙基的聚氧伸丙基多元醇，且平 均1個經基的分子量切前❹_(a,)的絲伸丙基多元 醇者。 最佳的樹脂層形成用光硬化性樹脂組成物—例係有 如下述寡聚物(A·)、非硬化性寡聚物(D)、及$體(Β·)的組成 物，該寡聚物(Α，)係使氧伸丙基一部分已利用氧伸乙基進行 取代的聚氧伸丙基二醇、與聚異氰酸酯化合物進行反應， 而獲得具有異氰酸酯基的預聚物之後，與前述單體(Β2)進 行反應而獲得胺甲酸酯寡聚物(Α2);該非硬化性寡聚物(D) 係與該胺甲酸酯寡聚物(Α2)的原料相同，將氧伸丙基一部 分已利用氧伸乙基進行取代的聚氧伸丙基二醇；且，該單 體(Β’)係具有羥基的單體(Β3)。 依此，若寡聚物(Α’)部分性具有與非硬化性寡聚物(D) 相同的分子結構，便可更加提高組成物中的非硬化性寡聚 物(D)之相溶性，更藉由單體(Βι)具有羥基，判斷利用硬化 37 201210812 性化合物(II)硬化後的分子結構中之羥基、與非硬化性寡聚 物(D)的分子結構中之羥基間的相互作用，便可使非硬化性 寡聚物(D)安定地存在於硬化物中。 再者，其他例方面，含有下述寡聚物、非硬化性寡 聚物(D)、及單體(B')的組成物，亦可獲得組成物中的非硬 化性寡聚物（D)呈良好相溶性’並可使非硬化性寡聚物(D) 安定地存在於硬化物中。該寡聚物(A，)係使將氧伸丙基一部 分已利用氧伸乙基進行取代的聚氧伸丙基二醇、與聚異氰 酸醋化合物進行反應，而獲得具有異氰酸酯基的預聚物之 後’與前述單體(B2)進行反應而獲得的胺曱酸酯寡聚物 (A2);該非硬化性寡聚物係未利用氧伸乙基進行取代的 聚氧伸丙基二醇’且分子量小於胺甲酸酯寡聚物(A2)原料 的聚氧伸丙基二醇；且，該單體(B，)係具有羥基的單體(B3)。 料脂層形成用光硬化性樹脂組成物中的非硬化性寡聚 物(D)的含量’較佳係1〇〜9〇質量％、更佳為3〇〜8〇質量％。 右非硬化性寡聚物的含量達10質量％以上，便可輕易地充 刀獲得降低因硬化時的樹脂收縮所產生應力之效果。若在 90質量％以下，便可輕易地使面材彼此間充分地固定，俾 可輕易且良好地防止表面材與背面材經接合後發生經時性 位置偏移情形。 樹脂層形成用光硬化性樹脂組成物係硬化後的樹脂層 動‘癌黏彈性測定中，儲存剪切彈性模數較佳為 5χ1〇2 〜lxl〇5pa、更佳為 8x1〇2 〜5xl〇4pa、特佳為 1x10〜5xl〇4pa。又，損失正切(tan (5)較佳係1.4以下、更佳 38 201210812 係1.0以下。損失正切的下限值並無特別的限^，可設為製 造上能達到的範圍，當屬於較柔軟的樹脂層時，通常係達 〇.〇1以上。韻存剪切彈性紐及損失正切㈣定方法， 你如後所詳述，使用動態㈣性測定裝置，對未硬化的樹 月旨層形成用光硬化性樹脂組成物—邊施加動態剪切應力、 /邊照射光，而使樹脂組成物硬化的方法來進行。 若硬化後的剪切彈性模數在lxl〇5pa以下，便可充分降 他因硬化時的樹脂收縮所產生之應力，俾可抑制對顯示面 板的顯示品質之影響。若該剪切彈性模數達Μ。％以上， 便可將-對面材(顯示元件與透明面材）良好地固定。又，若 損失正切在1.4以下，即便顯示裝置係垂直設置使用時，顯 亦元件仍可充分地固定於透明面材上，可良好地防止因顯 系元件的自重而造成樹脂層發生塑性變形等導致經時出 现顯示元件位置偏移情況。 藉由使樹脂層形成用光硬化性樹脂組成物含有非硬化 ，[生寡聚物(D) ’便可在上述抑制硬化後的樹脂層損失正切 (一)上升之情況下，使料剪切彈性模數降低，因而可同 恃達成動態黏彈性測定中储存剪切彈性模數與損失正切 (taM)的各自較佳範圍。 (添加劑） 樹脂層形成用光硬化性樹脂組成物係視需要，尚可含 有諸如：聚合終止劑、光硬化促進劑、鏈轉移劑、光安定 劍(諸如紫外線吸收劑、自*基捕獲劑等）、抗氧化劑、難燃 化劑、接著性提升劑(諸如魏偶合_)、顏料、染料等各 39 201210812 種添加劑，較佳係含有聚合終止劑、或光妓劑。特別係 藉由含有較聚合起始劑少量的聚合終止劑，便可改善樹脂 層形細光硬錄職組祕的安⑽，亦可雜硬化後 的樹脂層分子量。 藉由使少量含有鏈轉移劑，便可調整硬化後的樹脂層 分子量’降低_旨層_挪性_，但多數情況會造成 硬化速度變慢。 含有較多本發明非硬化性寡聚物(D)的樹脂層形成用 光硬化性樹脂組成物，因為可利用寡聚物⑼的含量調整彈 性模數，因而以減少鏈轉移劑的含量、或不含有為佳。具 體而言，相對於硬化性化合物(„)整體即寡聚物(A,)與單體 (B’)的合計100質量份，鏈轉移劑的添加量較佳係、在i質量份 以下、更佳係0.5質量份以下。 [步驟⑷] 經步驟(b)之後，便將已供應樹脂層形成用光硬化性樹 月曰組成物的第1面材，放入減壓裝置中，並在減壓裝置内的 固定支撐盤上，依硬化性樹脂組成物之面朝上的方式，平 放第1面材。 在減壓裝置内的上部，設有可於上下方向移動的移動 支撐機構，在移動支撐機構上安裝有第2面材。當第2面材 係顯示元件的情況，便將顯示影像該側的表面朝下。當在 第2面材的表面設有抗反射層之情況，便將沒有形成抗反射 層之一側的表面朝下。 第2面材係放置於第1面材的上方，且不與樹脂層形成 40 201210812 用光硬化性樹脂组成物接觸的位置處。即，使第1面材上的 樹脂層形成用光硬化性樹脂組成物、與第2面材不會相接觸 地呈相對向。 另外，亦可將於上下方向移動的移動支撐機構設置於 減壓裝置内的下部，並在移動支撐機構之上放置已被供應 硬化性樹脂組成物的第1面材。此情況’第2面材係安裝於 在減壓裝置内的上部所設置之固定支撐盤上，並使第1面材 與第2面材呈相對向。 再者，亦可將第1面材與第2面材二者均由設置於減壓 裝置内的上下之移動支撐機構所支撐。 將第1面材與第2面材配置於既定位置後，便對減壓褒 置的内部施行減壓而形成既定的減壓環境。若可能的話， 亦可在減壓操作中、或經形成既定減壓環境之後，便在減 壓裝置内使第1面材與第2面材位於既定位置處。 在減壓裝置的内部成為既定減壓環境之後，便將由移 支樓機構所支樓的第2面材朝下方移動，俾使第2面材重 疊於&面材上的樹脂層形成用光硬化性樹脂組成物之上。 藉由使進行重疊，便在由第丨面材的表面（以顯示元件 @ 影像顯示之_表面第2面材的表面（以顯示元 ^而讀為影像顯示之側的表面）、及未硬化密封部所包圍 工間:’密封著樹脂層形成用光硬化性娜組成物。 當進行重疊之際，利用第2面材的自重、來自移動支撐 機構的按押等’使樹脂層形成用光硬化性樹脂組成物被推 擠擴展’便使前述空間内充滿樹脂層㈣用光硬化性樹脂 41 201210812 組成物，然後當在步驟(d)中暴露於高壓力環境時，便形成 氣泡較少或沒有氣泡的樹脂層形成用光硬化性樹脂組成物 之層。 進行重疊時的減壓環境係100Pa以下、較佳係101^以 上。若減壓環境屬於太過的低壓，便會有對樹脂層形成用 光硬化性樹脂組成物中所含各成分（諸如硬化性化合物、光 聚合起始劑、聚合終止劑、光安定劑等）造成不良影響的可 能性。例如若減壓環境屬於太過的低壓，則各成分便會有 氣化的可能性，且為提供減壓環境會耗費時間。減壓環境 的壓力較佳係15〜40Pa。 從使第1面材與第2面材相重疊的時點起迄解除減壓環 境為止的時間並無特別的限定，可在樹脂層形成用光硬化 性樹脂組成物密封後，便馬上解除減壓環境，亦可在樹脂 層形成用光硬化性樹脂組成物密封後，將減壓狀態維持既 定時間。藉由減壓狀態轉既定時間，樹脂層形成用光硬 化性樹脂組成物便在密閉空間内流動，而使第丨面材與第2 面材間的間隔呈均勻，即便提高環境壓力仍可輕易地維持 也、封狀態。維持減壓狀態的時間係可為數小時以上的長時 間就生產效率的觀點，較佳係1小時以内、更佳係1〇分鐘 以内。 本實施形態的製造方法中，當塗佈點度高的密封部形 成用光硬化性樹脂組成物而形成未硬化密封部的情況，可 將由步驟(c)所獲得之層積前驅體的樹脂層形成用光硬化性 树月曰組成物厚度設為1 mm的較厚狀雜。 42 201210812 [步驟(d)] 在步驟(c)中’經解除減壓環境後，便將層積前驅體放 置於環境壓力達50kPa以上的壓力環境下。 若將層積前驅體放置於50kPa以上的壓力環境下，第1 面材與第2面材便利用上升的壓力朝相密接的方向被按押’ 因而若在層積前驅體内的密閉空間中有存在氣泡，樹脂層形 成用光硬化性樹脂組成物會流動於氣泡中，便使密閉空間整 體由樹脂層形成用光硬化性樹脂組成物均勻地填充。 壓力環境通常係80kPa〜120kPa。壓力環境係可為大氣 壓％境、亦可為較高於此的壓力。就樹脂層形成用光硬化 性樹脂組絲的硬化轉作可在不需要制設備情況下實 施的觀點，較佳為大氣壓環境。 從將層積前驅體放置於50kPa以上的壓力環境下之時 點起、迄樹脂層形細級化性樹脂組成物開始硬化為止 的寺門（乂下稱「南壓保持時間」）並無特別的限定。當將層 積月J驅體從減壓裝置中取出並移動至硬化裝置，直到開始 更化為止的t程均在大氣壓環境下進行的情況此項製程 ，需=時間便成為縫料時間。所以，當在放置於大 氣 兄下的時點，於層積前驅體的密閉空間内已無存在 氣泡的情況’或者在該製程期間錢泡;肖㈣情況，均可 馬脂層形成用光硬化性樹脂組成物硬化。當直到氣 均將声積時間的情況，便在截至氣泡消失為止前， 均將層^驅體保持於通㈣上的動環境下。又，因為 即便尚壓保持時間延長，通常仍不會構成阻礙，因而就製 43 201210812 程上的其他必要性，亦可延長高壓保持時l高壓保持時 間係可為1日以上的長時間，但就生產效率的觀點較佳係 6小時以内、更佳係1小時以内’就提高生產效率的觀點， 特佳在10分鐘以内。 接著，以將層積前驅體放置於5〇kPa以上的壓力環境下 之狀態，藉由使樹脂層形成用光硬化性樹脂組成物進行硬 化，便形成將顯示元件與保護板予以接合的樹脂層，可製 得顯示裝置》 樹脂層形成用光硬化性樹脂組成物及密封部形成用光 硬化性樹脂組成物’係照射光而使硬化。例如從光源(諸如 紫外線燈、高壓水銀燈、黑燈、化學燈、UV_LED等）照射 紫外線或短波長可見光，而使光硬化性樹脂組成物硬化。 再者’此時’由密封部形成用光硬化性樹脂組成物所 形成的未硬化密封部，係可與樹脂層形成用光硬化性樹脂 組成物的硬化同時進行硬化，亦可在樹脂層形成用光硬化 性樹脂組成物進行硬化前便使預先硬化。又，當透明面材 其中一部分有形成遮光印刷部，並由遮光印刷部挾持而形 成密封部的情況，因為在樹脂層形成用光硬化性樹脂組成 物的硬化時所採取之利用通過透明面材之透光部的光而使 密封部硬化係有困難，因而亦可在樹脂層形成用光硬化性 樹脂組成物硬化之後才使密封部硬化。 例如從層積前驅體的第1面材及第2面材中具有光穿透 性之側，對樹脂層形成用光硬化性樹脂組成物施行光照 射’且從層積前驅體側邊，對由遮光部及顯示元件所包夾 44 201210812 的未硬化密封部及樹脂層形成用級化性樹脂組成物，施 行光照射。 第1面材及第2面材當中，因為顯示元件在未使啟動的 狀態下並不具有光穿透性，因而從成為保護板的透明面材 之側通過透光部施行光照射。 再者，若在透明面材的周邊部設置遮光印刷部，並在 由遮光印刷部與顯示元件所挾持的區域巾有存在未硬化密 封。p或糾旨層形成用光硬化性樹脂組成物則僅依靠來自 透明面材之透光部的光並無法充分硬化。所以，從顯示元 件的側邊施行光照射。 光較佳係紫外線、或45〇nm以下的可見光。特別係當在 透明面材上設有抗反射層，且抗反射層或已形成抗反射層 的透月树月曰溥膜、或者在該抗反射薄膜與透明面材間設有 黏著層等紫外線無法穿透的情況，便必須利用可見光進行 硬化。 從側邊進行光照射的光源，係可使用當採取從透明面 材側進行光照射時所使用的光源，但就光源的配置空間、 與適用於特定地方的有效率光照射之觀點，較佳係使用紫 外線、或發出450nm以下之可見光的lED。 光照射的步驟係可在從透明面材一側施行光照射之後 再從側邊施行光照射，亦可相反，或同時施行光照射，為 能更加促進遮光印刷部的未硬化密封部與樹脂層形成用光 硬化性樹脂組成物的光硬化，較佳係先從側邊施行光照 射、或與側邊同時從透明面材側施行光照射。又，當經光 45 201210812 照射後經時會進行樹脂層形成用光硬化性樹脂組成物的硬 化等情況時、或者光硬化性樹脂組成物的硬化需要時間等 情況時，亦可在樹脂層形成用光硬化性樹脂組成物的硬化 大致完成後，再利用從側邊的光照射而使密封部硬化。 [具體例] 本實施形態的製造方法中，第i面材係可任意使用背面 材、或使用表面材。所以，顯示裝置係配合第丨面材的選擇， 可分別依照以下2種方法進行製造。 (α-l)第1面材係使用顯示元件（背面材），第2面材係使 用成為保護板的透明面材（表面材）之方法。 U-2)第1面材係使用成為保護板的透明面材(表面 材）’第2面材係使用顯示元件（背面材）的方法。 以下’以方法U-1)的情况為例，針對^圖的顯示裝 置之製造方法’使用圖式進行具體策明。 (步驟(a)) 如第3圖與第4圖所示，沿顯示元件5〇(第i面材）的周緣 部，利用分配器（未圖示）等塗佈密封部形成用光硬化性樹脂 組成物，而形成未硬化密封部12。 在顯示元件的外周部設置有傳遞用以使顯示元件啟動 之電氣信躺FPC等配輯件。本實闕㈣製造方法中， 當保持各面㈣，就使崎構件•魏絲易之觀點， 最好將顯示元件當作第1面材並配置於下側。 (步驟(b)) 接著，如第5圖及第6圖所示，對由顯示元物的未硬 46 201210812 化密封部12所包圍矩形狀區域13供應樹脂層形成用光硬化 性樹脂組成物14。樹脂層形成用光硬化性樹脂組成物14的 供應里係預先§史疋為由未硬化密封部12與顯示元件及透 明面材10(參照第7圖）所密閉的空間，剛好能利用樹脂層形 成用光硬化性樹脂組成物14填滿的量。 樹脂層形成用光硬化性樹脂組成物14的供應係如第5 圖及第6圖所示’將顯示元件50平放於下定盤18上，利用在 水平方向移動的分配器20，呈線狀、帶狀或點狀供應樹脂 層形成用光硬化性樹脂組成物14而實施。 分配器20係利用由一對導螺22、及與導螺22呈正交的 導螺24所構成之公知水平移動機構，可在區域13的全範圍 中進行水平移動。另外’亦可取代分配器2〇，改為使用模 具塗佈機。 (步驟(c)) 接著，如第7圖所示’將顯示元件5〇與透明面材1〇(第2 面材)搬入減壓裝置26内。在減壓裝置26内的上部，配置有 具備複數吸附墊32的上定盤3〇，並在下部設置有下定盤 31。上定盤30係利用氣缸34可於上下方向移動。 透明面材10係安震於吸附墊32上。顯示元件50係將被 供應樹脂層形成用光硬化性樹脂組成物14之面朝上，固定 於下定盤31之上。 接著，利用真空泵28抽吸減壓裝置26内的空氣。減壓 裝置26内的環境壓力係在到達例如i5〜4〇pa減壓環境之 後，便在將透明面材1 〇利用上定盤的吸附整32進行吸附 47 201210812 保持的狀態下，朝向下方呈待機的顯示元件50 ’使氣缸34 啟動而下降。然後，使顯示元件50與透明面材10隔著未硬 化密封部12相重疊，而構成層積前驅體’並在減壓環境下 保持層積前驅體既定時間。 另外，顯示元件50對下定盤31的安裝位置、吸附墊32 的個數、以及透明面材10對上定盤30的安裝位置等’係配 合顯示元件50及透明面材1〇的尺寸、形狀等而適當調整。 此時，吸附墊係使用靜電吸盤，藉由採用日本特願 2008-206124所附說明書（納入本說明書中）所記載的靜電吸 盤保持方法，可將玻璃基板安定地保持於減壓環境下。 (步驟(d)) 接著，將減壓裝置26的内部形成例如大氣壓之後，便 從減壓裝置26取出層積前驅體。若將層積前驅體放置於大 氣壓環境下，層積前驅體之顯示元件50側的表面與透明面 材1 〇側的表面便利用大氣壓而被按押，而密閉空間内的樹 脂層形成用光硬化性樹脂組成物14則被顯示元件50與透明 面材10加壓。利用該壓力，密閉空間内的樹脂層形成用光 硬化性樹脂組成物I4會流動，密閉空間整體便由樹脂層形 成用光硬化性樹脂組成物M均勻地填充。 胸接著在透明面材上&置遮光印刷部’當使由遮光印 Π所挾持的未硬化密封部與樹月旨層形成用光硬化性樹脂 邊:先行硬化時，便如第8圖所示，從層積前驅體的側 光印刷部55及顯示元件5g所包夾的未硬化密封 祕脂層形成用光硬化性樹脂纽成物14’涵蓋顯示元 48 201210812 件全周施行光（紫外線、或450nm以下的可見光）照射，且從 透明面材10之側’透過透光部56對樹脂層形成用光硬化性 樹脂組成物14施行光（紫外線、或450nm以下的可見光）照 射，而使層積前驅體内部的未硬化密封部12及樹脂層升》成 用光硬化性樹脂組成物14進行硬化，便製得顯示裝置i。 當透明面材上無設置遮光印刷部的情況，便從透明面 材10之側涵蓋層積前驅體全面施行光照射，藉由使層積前 驅體内部的未硬化密封部12及樹脂層形成用光硬化性樹脂 組成物14進行硬化，便製得顯示裝置1。 以上’，?尤方法（a _ 1)的情況為例，針對本實施形態的顯 示裝置之製造方法進行具體說明’而其他方法（α _2)的情況 亦同樣的可製造顯示裝置。 [作用效果：顯示裝置之製造方法] 根據以上所說明本實施形態的顯示裝置之製造方法， 可在樹脂層中不會產生氣泡的情況下，製造大面積的顯示 裝置。假設即便在減壓下施行密封的樹脂層形成用光硬化 性樹脂組成物中有氣泡殘存，對硬化前在高壓力環境下已 密封的樹脂層形成用光硬化性樹脂組成物施加該壓力，便 可減少該氣泡的體積，俾使氣泡容易消失。例如在lOOPa 下已密封的樹脂層形成用光硬化性樹脂組成物中，氣泡中 的氣體體積可認為係在lOOkPa下的1/1000。因為氣體亦會 溶解於樹脂層形成用光硬化性樹脂組成物中，因而微小體 積氣泡中的氣體會迅速溶解於樹脂層形成用光硬化性樹脂 組成物中並消失。 49 201210812 再者，因為即便對密封後的樹脂層形成用光硬化性樹 脂組成物施加大氣壓等壓力，液狀樹脂層形成用光硬化性 樹脂組成物仍屬於流動性的組成物，因而該壓力係均勻分 佈在顯示元件的表面上，不會對接觸到樹脂層形成用光硬 化性樹脂組成物的顯示元件表面其中一部分施加在此以上 的應力，對顯示元件造成損傷的威脅較低。 再者’由樹脂層形成用光硬化性樹脂組成物的硬化所 形成之樹脂層、與顯示元件、透明面材間之界面接著力， 局於利用熱溶接所產生的界面接著力。且，對流動性樹脂 層形成用光硬化性樹脂組成物加壓而密接於顯示元件、透 明面材的表面上’並使在此狀態下硬化，因而可獲得更高 的界面接著力’且可獲得對顯示元件、透明面材的表面呈 均勻的接著’界面接著力局部性降低的情況很少。 所以，在樹脂層的表面發生剝離的可能性低，且從界 面接著力不足的部分滲入水分、腐蝕性氣體的可能性亦較 低。 再者’相較於在2片面材間的狹窄且寬廣面積空間中注 入流動性樹脂層形成用光硬化性樹脂組成物的方法（注入 法）氣泡的產生少，且可在短時間内便填充樹脂層形成用光 硬化性樹脂組成物。且，樹脂層形成用光硬化性樹脂組成 物的黏度限制較少’可輕易地填充高黏度的樹脂層形成用 光硬化性樹脂組成物。所以，可使用含有可提高樹脂層強 度之高分子量硬化性化合物的高黏度樹脂層形成用光硬化 性樹脂組成物。 50 201210812 再者’樹脂層形成用光硬化性樹脂組成物的光聚合起 始劑（C2) ’係使用所具有的吸收波長區域(λ2)較未硬化密封 部的光聚合起始劑（C1)之吸收波長區域(λ1)更靠長波長側 存在的光聚合起始劑（C2)，且從層積前驅體的側邊方所照 射之光，係使用吸收波長區域(λ1)内的波長光與吸收波長區 域(λ2)内的波長光二者，藉此，便可使不會被未硬化密封部 的光聚合起始劑（C1)所吸收之吸收波長區域以2)内的波長 光’充分到達由遮光部中顯示元件所包夾的樹脂層形成用 光硬化性樹脂組成物，利用具有吸收波長區域(λ2)的光聚合 起始劑（C2)，便可充分地執行樹脂層形成用光硬化性樹脂 組成物的硬化。 [作用效果：硬化性樹脂組成物] 顯示元件與透明面材間之接合上，藉由降低硬化性樹 脂硬化時的收縮率、或降低硬化後的樹脂層彈性模數，便 可降低對顯示元件所施加的應力’而有效地防止顯示斑等 會損及顯示品質的情況發生。 但是，若為降低硬化時的收縮，而增加硬化性化合物 每個硬化部位的分子量，則硬化性化合物的黏性便會變 大，導致硬化性樹脂組成物對面材面的均勻供應趨於困 難，會有硬化時的硬化反應呈不均勻之可能性。 再者，若為降低硬化後的樹脂層的彈性模數，而使含有 對硬化無具貢獻的非硬化性成分，則在未硬化時，硬化性樹 脂組成物的相溶性會降低，導致損及硬化後的樹脂組成物之 透明性，或造成硬化後的樹脂層與面材面間之密接性降低， 51 201210812 亦會有造成表面材與背面材經時剝離的可能性。 相對於此，本發明的硬化性樹脂組成物係特別含有 10〜90質量％之每1分子中具有〇 8〜3個羥基的非硬化性寡聚 物，作為在硬化時不會與樹脂層形成用光硬化性樹脂組成 物中的硬化性化合物(II)進行硬化反應之非硬化性成分，同 時使硬化性化合物(II)中存在有硬化時不會產生反應的羥 基，藉此，便可使未硬化時的樹脂層形成用光硬化性樹脂 組成物之安定性呈良好，俾可降低黏性，且硬化時的硬化 反應均勻性良好，並可降低硬化時的收縮，且可降低硬化 後的樹脂之彈性模數。 若硬化時的收縮降低、硬化後的樹脂之彈性模數降 低，則樹脂層因硬化收縮所產生的應力便會降低。若未硬 化時的樹脂層形成用光硬化性樹脂組成物安定性良好，且 硬化時的硬化反應均勻性良好，便可輕易地獲得透明性良 好的樹脂層。若降低未硬化時的樹脂層形成用光硬化性樹 脂組成物之黏性，便可㈣地充分抑職泡產生，俾可輕 易地獲得面材與樹脂層間之良好界面接合力。 特別係當顯示元件係液晶顯示元件，甚至是 IPS(In-plane Switching，平面杻轉）式液晶顯示元件、或於 顯示面上經貼合視纽善的光學膜之ΤΝ(ΤΜ_价_〇 式液晶顯示元件的情況，因為對顯示元件所施加的應力容 易對顯示品質造成不良影響，gj而接合義層最好係屬於 低彈性模數。 所以，使用本發明硬化性樹脂組成物的顯示裝置中的 52 201210812 顯不元件’較佳係液晶顯示元件，更佳係IPS式液晶顯示元 件、或TN式液晶顯示元件。 另外’本發明的硬化性樹脂組成物並不僅偈限使用於 顯不褒置’亦可適用於一對面材隔著樹脂層進行層積的層 積體’可獲得同樣的效果。 再者’本發明的硬化性樹脂組成物係可為熱硬化性的 樹脂組成物，此情況，硬化性化合物的硬化性基係使用公 知的熱硬化性基。又，視需要使之含有公知的熱聚合起始 劑。上述實施形態中’當樹脂層形成用硬化性樹脂組成物 係屬於熱硬化性的情況，最好亦使密封部形成用硬化性樹 脂組成物為熱硬化性。 特別係因為光硬化性的樹脂組成物在硬化時並不需要 高溫，因而就因高溫而對面材等造成不良影響的威脅較少 之觀點’係屬較佳。 併用光聚合起始劑與熱聚合起始劑等情況，可同時施 行光硬化與熱硬化，或者亦可個別進行提高硬化性。 再者，使用本發明硬化性樹脂組成物製造層積體的方 法，並不僅侷限於上述實施形態的方法，亦玎適當使用公 知方法。 [實施例] 以下，例示為確認本發明有效性而實施的例子。例 1〜5、9及10係實施例，例6〜8係比較例。 (儲存剪切彈性模數、及其損失正切的測定方法） 硬化後的樹脂層之儲存剪切彈性模數及其損失正切 53 201210812 (tan (5 )，係使用流變儀（Anton Paar公司製，Physica MCR301)，將未硬化的樹脂層形成用光硬化性樹脂組成 物，夾持於鈉鈣玻璃製平台與測定用心軸(Anton Paar公司 製，D-PP20/AL/S07)間的〇.4mm間隙中，於氮環境下於35 °C下’ 一邊利用在平台下部所設置的黑燈（日本電氣公司 製’ FLISBL)照射30分鐘的2mW/cm2光一邊施加1%的動態 剪切應力，而使樹脂層形成用光硬化性樹脂組成物硬化並 進行測定。樹脂層形成用光硬化性樹脂組成物硬化時，係 依心軸的法線方向不會產生應力的方式，令心軸的位置自 動追蹤調整。 照射強度係使用照度計(USHIO電機公司製，紫外線強 度計UNIMETERUIT-101)，在有放置樹脂層形成用光硬化 性樹脂組成物的平台上進行測定。 (數量平均分子量） 募聚物的數量平均分子量係使用GPC裝置(T〇s〇H公 司製，HLC-8020)進行求取。 (黏度） 光硬化性樹脂組成物的黏度係利用E型黏度計（東機產 業公司製，RE-85U)進行測定。 (霧值） 霧值係使用東洋精機製作所公司製的Haze_Garcl π，根 據ASTM D1003進行測定而求得。 [例1] (顯示元件) 54 201210812 從市售17忖液晶監視器（Acer公司製，V137b)中取出液 曰曰顯示元件。液晶顯示元件係顯示模式為TN(Twisted Nematic，扭轉向列）式，顯示部的大小為長338mm、寬 270mm。液晶顯示元件的雙面上貼合著偏光板於長邊的 單側接合著6片驅動用FPC且在短邊的單側接合著3片驅動 用FPC，在長邊側的FPC端部接合著印刷電路板。將該液晶 顯示元件設為「顯示元件A」。 (玻璃板） 將長355mm、寬29〇mm、厚度2.8mm的鈉鈣玻璃作為 保護板的玻璃板B。 (密封部形成用光硬化性樹脂組成物） 將分子末端經加成環氧乙烷且1分子中具有2個羥基的 雙官能基聚m(㈣朗計算出的數量平均分子量： 4000,聚丙二醇分子中的環氧乙烧含量24質量％)、與六亞 甲基二異氰酸S旨’依成為6比7的莫耳比進行混合，接著利 用丙稀酸異彳“（域有機化學工業公3製，IBXA)進行稀 釋後，在錫化合物的觸媒存在下，依7代進行反應而獲得 預聚物’在該縣物中將_酸·玲乙祕大致成為如 的莫耳比添加，並添加2,5-二第三丁基氫酿（聚合終止 劑)0.03質量份，於耽下進行反應，藉此便獲得經3〇質量 %丙稀酸異❹旨稀釋過的胺甲酸§|丙稀酸募聚物（以下稱 「UC-1」）溶液。UC-1的硬化性基數係2，數量平均分子量 約550GG。UC-1溶液在6(rc下的黏度約细pa · s。 將UCM溶液90質量份、及曱基丙稀酸_2_經丁醋（共榮社 55 201210812 化學公司製，LIGHT ESTER® HOB) 10質量份均勻混合而獲 得混合物。將該混合物丨00質量份、丨_羥基_環己基_苯基_酮 (光聚合起始劑’汽巴超級化學公司製，IRGACURE 184)3 質量份均勻混合’便獲得密封部形成用光硬化性樹脂組成 物C。 在將密封部形成用光硬化性樹脂組成物c放入容器的 狀態下’依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持10分鐘，藉此施行脫泡處理。經測定密 封部形成用光硬化性樹脂組成物C在25°C下的黏度，結果約 1300Pa · s 〇 (樹脂層形成用光硬化性樹脂組成物） 將在分子末端經加成環氧乙烷且1分子中具有2個羥基 的雙官能基聚丙二醇（由羥值所計算出的數量平均分子量 4000 ’聚丙二醇分子中的環氧乙烷含量24質量％)、與異佛 爾酮二異氰酸酯，依成為4比5莫耳比進行混合，在錫化合 物的觸媒存在下’依70°C進行反應而獲得預聚物，在該預 聚物中將丙烯酸-2-羥乙酯依大致成為1比2的莫耳比添加， 並添加2,5-二第三丁基氫醌（聚合終止劑）〇.〇3質量份，於70 °C下進行反應，藉此便獲得胺曱酸酯丙烯酸酯寡聚物（以下 稱「UA-2」）。UA-2的硬化性基數係2，數量平均分子量約 24000，25°C 下的黏度約 830Pa · s。 將UA-2計40質量份、曱基丙烯酸-2-羥丁酯（共榮社化 學公司製，LIGHTESTER®HOB)30質量份、以及曱基丙烯 酸正十二烷基酯30質量份均勻混合，在該混合物1〇〇質量份 56 201210812 中，均勻溶解雙(2,4,6-三甲基笨甲醢基)-苯基氧化膦（光聚 合起始劑，汽巴超級化學公司製，IRGACURE 819)0.5質量 份，便獲得樹脂層形成用光硬化性樹脂組成物PD。 其次，使PD計40質量份、與UA-2合成時所使用者相同 之分子末端經加成環氧乙烷且1分子中具有2個羥基的雙官 能基聚丙二醇（由羥值所計算出的數量平均分子量4000,聚 丙二醇分子中的環氧乙烷含量24質量％)60質量份均勻溶 解，而獲得樹脂層形成用光硬化性樹脂組成物D。 在將樹脂層形成用光硬化性樹脂組成物D放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持10分鐘，藉此施行脫泡處理◎經測定樹 脂層形成用光硬化性樹脂組成物D在25°C下的黏度，結果為 1.3Pa · s。 另外’樹脂層形成用光硬化性樹脂組成物D所使用的光 聚合起始劑（前述IRGACURE 819)，係較密封部形成用光硬 化性樹脂組成物C所使用光聚合起始劑（前述IRGACURE 184)的吸收波長區域（約38〇nm以下），更靠長波長側亦具有 吸收波長區域（約440nm以下）。 接著’使用流變儀’測定樹脂層形成用光硬化性樹脂 組成物D光硬化後的黏彈性特性，結果儲存剪切彈性模數係 3.7xl03Pa、其損失正切(tan5)係0.61。 (步驟(a)) 涵蓋顯示元件A的影像顯示區域外側約3mm位置全 周，依成為寬約1mm、塗佈厚度約〇 6mm的方式，利用分 57 201210812 配器塗佈密封部形成用光硬化性樹脂組成物c，而形成未硬 化密封部。 (步驟(b)) 在顯示元件A的影像顯示區域外周所塗佈之未硬化密 封部的内側區域’使用分配器依總質量成為38g的方式，朝 複數地方供應樹脂層形成用光硬化性樹脂組成物D。 在供應樹脂層形成用光硬化性樹脂組成物D的期間，係 維持著未硬化密封部的形狀。 (步驟(c)) 在設有一對定盤的升降裝置之減壓裝置内，於下定盤 的上面，將顯示元件A依樹脂層形成用光硬化性樹脂組成物 D之面朝上的方式平放。 將玻璃板B依有形成遮光印刷部之側的表面與顯示元 件A相向的方式，在減壓裝置内的升降裝置之上定盤下面， 使用靜電吸盤，依從上面觀看時玻璃板B沒有遮光印刷部的 透光部、與顯示元件A的景Η象顯示區域具有約linm邊限而位 於相同位置、且在垂直方向上與顯示元件A間的距離為 3〇mm之方式予以保持。 將減壓裝置形成密封狀態並施行排氣直到減壓裝置内 的壓力成為約lGPa為止。利賴壓裝置⑽升降裝置使上 下定盤相靠近’再將顯示與玻璃板_著樹脂層形成 用光硬化性樹脂組成物D，依2kpa壓力施行壓接，並保則 分鐘。將靜電吸盤去電而使玻璃灿離開上㈣，並以約15 秒使減壓裝置内返回於大氣壓，便獲得樹脂層形成用光硬 58 201210812 化性樹脂組成物D已由顯示元件A、玻璃板B及未硬化密封 部予以密封的層積前驅體E。 層積前驅體E中’未硬化密封部的形狀係大致維持初期 狀悉。 (步驟(d)) 從層積則驅體E靠玻璃板b側之一面，均勻照射來自専 燈的紫外線及450nm以下的可見光3〇分鐘，而使樹脂層形成 用光硬化性樹脂組成物D硬化，藉此形成樹脂層而獲得顯示 裝置F。顯示裝置F係儘管不需要習知利用注入法進行製造 時所品要的氣泡去除之步驟，仍未發現到樹脂層中有殘留 氣泡等缺陷。又，亦未發現到有從密封部出現樹脂層形成 用光硬化性樹脂組成物洩漏等缺陷。又，樹脂層的厚度成 為目標厚度（約0.4mm)。 取代顯示元件A，改為使用大致相同尺寸的玻璃板，同 樣地製作透明層積體，經測定沒有印刷遮光部之部分處的 霧值’結果在1%以下，屬於透明度高的良好物。 將顯示裝置F送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式設置液晶監視器。經靜置5日後，切入 電源並連接於電腦使影像顯示，結果獲得涵蓋顯示畫面全 面均呈均質且良好的顯示影像，且顯示對比高於當初狀 態。即使手指頭強力按押影像顯示面，影像仍不會凌亂， 玻璃板B有效地保護著顯示元件A。 接著，同樣的設置顯示裝置F，經1個月後確認顯示元 59 201210812 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例2] (樹脂層形成用光硬化性樹脂組成物） 使例1所使用的樹脂層形成用光硬化性樹脂組成物 PD(30質量份）、與1分子中具有2個羥基的雙官能基聚丙二 醇（由羥值所計算出的數量平均分子量2〇〇〇，聚丙二醇中的 EO含量0質量％)70質量份均句溶解，便麟樹脂層形成用 光硬化性樹脂組成物D2。 在將樹脂層形成用光硬化性樹脂組成物D2放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持1〇分鐘，藉此施行脫泡處理 。經測定樹 月曰層形成用光硬化性樹脂組成物D2在25°C下的黏度，結果 為 0.6Pa · s。 其次，使用流變儀，測定樹脂層形成用光硬化性樹脂 組成物D2光硬化後的黏彈性特性，結果儲存剪切彈性模數 係9xl02Pa、其損失正切(加§)係〇 84。 與例1同樣，除密封部形成用光硬化性樹脂組成物係使 用組成物C ’且樹脂層#成用光硬化性樹脂細成物係使用組 成物D2之外，其餘均與例丨相同而獲得顯示裝置F2。將顯示 裝置F2送返被取出液晶顯示元件的液晶監視器之框體中， 經再度連接配線後，以接合於玻璃板B的顯示元件A成為垂 直之方式設置液晶監視器。經靜置5日後’切人電源並連接 於電腦使影像顯示，結果獲得涵蓋顯示畫面全面均呈均質 60 201210812 且良好的顯示影像，且顯示對比高於當初狀態。即使手指 頭強力按押影像顯示面，影像仍不會凌亂，玻璃板B有效地 保δ蔓著顯示元件a。 接著’同樣的設置顯示裝置F2，經1個月後確認顯示元 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例3] (樹脂層形成用光硬化性樹脂組成物） 將例1所使用UA-2計40質量份、曱基丙烯酸-2-羥丁酯 (共榮社化學公司製，LIGHT ESTER® HOB)30質量份、以 及甲基丙烯酸正十二烷基酯30質量份均勻混合，於該混合 物100質量份中均勻溶解雙(2,4,6-三甲基苯甲醯基)-苯基氧 化膦（光聚合起始劑，汽巴超級化學公司製，IRGacure 819)0.5質量份、與正十二烷基硫醇（鏈轉移劑，花王公司 製’ THIOKALCHOL® 20)0.5質量份，便獲得樹脂層形成用 光硬化性樹脂組成物PG。 其次’使PG60質量份、與UA-2合成時所使用者相同之 分子末端經加成環氧乙烷且丨分子中具有2個羥基的雙官能 基聚丙二醇（由羥值所計算出的數量平均分子量：4〇〇〇，聚 丙二醇分子中的環氧乙烷含量24質量％)4〇質量份均勻溶 解’便獲得樹脂層形成用光硬化性樹脂組成物G。 在將樹脂層形成用光硬化性樹脂組成物G放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持1〇分鐘，藉此施行脫泡處理。經測定樹 201210812 脂層形成用光硬化性樹脂組成物G在25°C下的黏度，結果為 1.7Pa · s。 其次，使用流變儀’測定樹脂層形成用光硬化性樹脂 組成物G光硬化後的黏彈性特性’結果儲存剪切彈性模數係 1.0xl04Pa、其損失正切(tan5)係0.83。 與例1同樣’除密封部形成用光硬化性樹脂組成物係使 用組成物C，且樹脂層形成用光硬化性樹脂組成物係使用組 成物G之外’其餘均與例1相同而獲得顯示裝置H。 將顯示裝置Η送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板8的顯示元 件Α成為垂直之方式設置液晶監視器。經靜置5日後切入 電源並連接於電腦使影像顯示，結果獲得涵蓋顯示晝面全 面均呈均質且良好的顯示影像，且顯示對比高於當初狀 態。即使手指麵力按押影像顯示面，影像仍不會凌亂， 玻璃板B有效地保護著顯示元件a。 接著’同樣的設置顯示裝置H，經！個月後確認顯示元 件的接合位置’並無發現位置偏料情形，良好地保持於 玻璃板。 ' [例4] (樹脂層形成用光硬化性樹脂組成物) —將分子末端經加成環氧乙烧幻分子中具有2健基的 雙S能基聚丙二醇（由難所計算出的數量平均分子旦. 侧，聚丙二醇分子中的環氧W含量叫量％)、^佛 爾酮二異氰_，依成為3比4的料比進行衫，在錫化 62 201210812 合物的觸媒存在下，依7(TC進行反應而獲得預聚物，在^玄 預聚物中將丙烯酸_2_羥乙酯依大致成為1比2的莫耳比添 加，並添加2,5-二第三丁基氫醌（聚合終止劑）〇〇3質量份， 藉由於7(TC使進行反應，便獲得胺曱峻料稀酸自旨^物 (以下稱「UA-3」）。UA-3的硬化性基數係2，數量平均分子 量約21000，25°C下的黏度約350Pa . s。 將UA-3(8〇質量份）、甲基丙稀酸·2，丁能（共榮社化學 公司製，LIGHT ESTER® HOB)20質量份進行混合再於該 混合物刚質量份中均勻溶解雙(2,4,6_三f基苯甲酿基)' 苯 基氧化膦（光聚合起始劑，汽巴超級化學公司製， 【RGACURE 819)0.5質量份，便獲得光硬化性且成物 PI ° 其次’使PI計30質量份、與1分子中具有2個經基的雙 官能基聚丙二醇（由羥值所計算出的數量平均分子量 2_，聚丙二醇中的E0含量〇質量％)7()質量份均‘解里 便獲得樹脂層形成用光硬化性樹脂組成物工。 在將樹脂層形成用光硬化性樹脂組成物】放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約2GPa並㈣1G分鐘，藉此施行脫泡處理。經測定樹 脂層形成用光硬化性樹脂組成物I在25°c下的黏产，钟果為 2.0Pa · s。 其次’使用流變儀’測定樹脂層形成用光硬化性樹脂 組成物I光硬化後的轉性雜，結果儲騎_性模數係 2.5xl04Pa ’ 其損失正切(tanS)係〇 〇6。 63 201210812 與例1同樣，除密封部形成用光硬化性樹脂組成物係使 用組成物c，且樹脂層形成用光硬化性樹脂组成物係使用組 成物I之外’其餘均與例丨相同而獲得顯示裝置J。 將顯示裝置J送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式設置液晶監視器。經靜置5日後切入電 源，結果可獲得涵蓋顯示畫面全面呈均質且良好的顯示影 像，且顯示對比高於當初狀態。即使手指頭強力按押影像 顯示面，影像仍不會凌亂，玻璃板B有效地保護著顯示元件 A 〇 接著’同樣的設置顯示裝置J，經1個月後確認顯示元 件的接合位置’並無發現位置偏移等情形，良好地保持於 玻璃板。 [例5] (樹脂層形成用光硬化性樹脂組成物） 使例4所使用之PI計2 0質量份、與1分子中具有2個經基 的雙官能基聚丙二醇（由羥值所計算出的數量平均分子f 2000，聚丙二醇中的EO含量0質量％)80質量份均勻溶解， 而獲得樹脂層形成用光硬化性樹脂組成物12。 在將樹脂層形成用光硬化性樹脂組成物12放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持1〇分鐘’藉此施行脫泡處理。經測定樹 脂層形成用光硬化性樹脂組成物12在25°C下的黏度，結果 為 1 .OPa · s 〇 64 201210812 其次，使用流變儀，測定樹脂層形成用光硬化性樹脂 組成物12光硬化後的轉性特性，結果儲存剪㈣性模數 係4.〇xl03Pa、其損失正切(tan§)係〇 〇7。 與例1同樣，除密封部形成用光硬化性樹脂组成物係使 用組成物C’且_旨層形❹級化，轉餘錢係使用組 成物12之外，其餘均與例丨相同而獲得顯示裝置J2。 將顯示裝置J2送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式设置液晶監視器。經靜置$曰後切入電 源，結果可獲得涵蓋顯示晝面全面呈均質且良好的顯示影 像，且顯示對比高於當初狀態。即使手指頭強力按押影像 顯示面，影像仍不會凌亂，玻璃板B有效地保護著顯示元件 A 〇 接著，同樣的設置顯示裝置J2，經1個月後確認顯示元 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例6] (樹脂層形成用光硬化性樹脂組成物） 在例1所使用的樹脂組成物PD中並沒有添加非硬化性寡 聚物之情況下，獲得樹脂層形成用光硬化性樹脂組成物K。 在將樹脂層形成用光硬化性樹脂組成物K放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持10分鐘，藉此施行脫泡處理。經測定樹 脂層形成用光硬化性樹脂組成物K在25°C下的黏度，結果為 65 201210812 2.2Pa · s 〇 其次，使用流變儀，測定樹脂層形成用光硬化性樹脂 組成物K光硬化後的黏彈性特性，結果儲存剪切彈性模數係 3.1xl05Pa、其損失正切(tan5^〇 32。 與例1同樣，除密封部形成用光硬化性樹脂組成物係使 用組成物C，且樹脂層形成用光硬化性樹脂組成物係使用組 成物K之外’其餘均與例丨相同而獲得顯示裝置L。 將顯示裝置L送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式设置液晶監視器。經靜置$日後切入電 源，經連接於電腦並顯示影像，結果在顯示晝面的周緣部 有出現晝框狀顯示斑，特別係在半色調顯示時明顯被檢視 到。在沒有出現顯示斑的部分，可獲得較初期更高對比的 影像。 接著，同樣的設置顯示裝置L，經1個月後確認顯示元 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例7] (樹脂層形成用光硬化性樹脂組成物） 在例3所使用之樹脂組成物pg中未添加非硬化性寡聚 物之情況下’獲得樹脂層形成用光硬化性樹脂組成物Μ。 在將樹脂層形成用光硬化性樹脂組成物Μ放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持1〇分鐘，藉此施行脫泡處理。經測定樹 66 201210812 脂層形成用光硬化性樹脂組成物Μ在25。(：下的黏度，結果 為 2.1Pa · s。 其次’使用流變儀，測定樹脂層形成用光硬化性樹脂 組成物Μ光硬化後的黏彈性特性，結果儲存剪切彈性模數 係1.6xl05Pa、其損失正切(tan5)係〇 46。 與例1同樣’除密封部形成用光硬化性樹脂組成物係使 用組成物C，且樹脂層形成用光硬化性樹脂組成物係使用組 成物Μ之外，其餘均與例1相同而獲得顯示裝置 將顯示裝置Ν送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板Β的顯示元 件Α成為垂直之方式設置液晶監視器。經靜置5日後切入電 源，經連接於電腦並顯示影像，結果在顯示畫面的周緣部 有出現畫框狀顯示斑，特別係在半色調顯示時明顯被檢視 到。在沒有出現顯示斑的部分，可獲得較初期更高對比的 影像。 接著，同樣的設置顯示裝置N，經1個月後確認顯示元 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例8] (樹脂層形成用光硬化性樹脂組成物） 將例1所使用UA-2計40質量份、甲基丙烯酸·2_羥丁酯 (共榮社化學公司製，LIGHT ESTER® Η〇Β)20質量份、以 及曱基丙烯酸正十二烷基酯40質量份均勻混合，再於該混 合物100質量份中均勻溶解雙(2,4,6_三曱基苯甲醯基)苯基 67 201210812 氧化膦（光聚合起始劑’汽巴超級化學公司製，IRGACURE 819)0.3質量份、以及正十二烷基硫醇(鏈轉移劑，花王公司 製’ THIOKALCHOL® 20)1.5質量份，便獲得樹脂層形成用 光硬化性樹脂組成物Ο。 在將樹脂層形成用光硬化性樹脂組成物〇放入容器的 狀態下，依開放狀態設置於減壓裝置内，將減壓裝置内減 壓至約20Pa並保持10分鐘，藉此施行脫泡處理。經測定樹 脂層形成用光硬化性樹脂組成物〇在25°C下的黏度，結果為 1.9Pa · s 〇 其次，使用流變儀，測定樹脂層形成用光硬化性樹脂 組成物〇光硬化後的黏彈性特性，結果儲存剪切彈性模數係 7-5xl〇3pa、其損失正切(tans)係 1.8。 與例1同樣，除密封部形成用光硬化性樹脂組成物係使 用組成物C，且樹脂層形成用光硬化性樹脂組成物係使用組 成物Ο之外’其餘均與例丨相同而獲得顯示裝置p。 將顯不裝置p送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式設置液晶監視器。約丨小時後確認顯示 几件的接合位置’結果從玻璃板偏移脫落數mm程度，無法 將顯示元件良好地保持於玻璃板上。 此處，以接合於玻璃板B的顯示元件A呈水平之方式設 置顯不裴置P，經靜置5日後切入電源，結果顯示元件的偏 移並無變化，在顯示畫面的中央部可獲得均質且良好的顯 不影像，且顯示對比高於當初狀態。即使手指頭強力按押 68 201210812 &像顯不面，影像仍不會凌亂，玻璃板8有效地保護著顯示 元件A。 [例9] 除將分子末端並未加成環氧乙烷且丨分子中具有2個羥 基的雙官能基聚丙二醇（由羥值所計算出的數量平均分子 罝5500)、以及大致同量含有2,2,4三甲基·六亞曱基二異氰 酉文83與2,4,4-三曱基_六亞甲基二異氰酸酯的混合物，依1:2 莫耳比進行混合之外，其餘均與例丨相同而合成胺甲酸酯丙 烯酸酯寡聚物(UA_4)。UA_4的硬化性基數係2，數量平均分 子$約16000 ’ 25°C下的黏度約39Pa · s。 在例1中，除取代UA-2，改為使用UA-4之外，其餘均 與例1相同而獲得樹脂層形成用光硬化性樹脂組成物pQ。使 用PQ計40質量份、與UA_4合成時所使用者相同之分子末端 並未加成環氧乙烷且1分子中具有2個羥基的雙官能基聚丙 二醇（由羥值所計算出的數量平均分子量55〇〇)，獲得樹脂層 形成用光硬化性樹脂組成物Q。樹脂層形成用光硬化性樹脂 組成物Q在25。(：下的黏度係〇.8Pa · s。 利用流變儀測定樹脂層形成用光硬化性樹脂組成物Q 光硬化後的黏彈性特性，結果儲存剪切彈性模數係 2.4xl〇4pa、其損失正切(tanS)係0.13。 與例1同樣，除密封部形成用光硬化性樹脂組成物係使 用紐成物c’且樹脂層形成用光硬化性樹脂組成物係使用組 成物Q之外，其餘均與例丨相同而獲得顯示裝置R。 W顯示裝置r送返被取出液晶顯示元件的液晶監視器 69 201210812 之框體中，經再度連接配線後’以接合於玻璃板B的顯示元 件A成為垂直之方式設置液晶監視器。經靜置5日後切入電 源’結果可獲得涵蓋顯示晝面全面呈均質且良好的顯示影 像’且顯示對比高於當初狀態。即使手指頭強力按押影像 顯示面，影像仍不會凌亂’玻璃板B有效地保護著顯示元件 A 〇 接著，同樣的設置顯示裝置R ’經1個月後確認顯示元 件的接合位置，並無發現位置偏移等情形，良好地保持於 玻璃板。 [例 10] 除將分子末端並未加成環氧乙烷且1分子中具有2個經 基的雙官能基聚丙二醇（由羥值所計算出的數量平均分子 量2000)、與異佛爾嗣二異氛酸醋’依5 : 6莫耳比進行混合 之外，其餘均與例1相同而合成胺曱酸酯丙稀酸酯寡聚物 (UA-5)。UA-5的硬化性基數係2，數量平均分子量約丨8000， 25°C下的黏度約620Pa · s。 在例1中，除取代UA-2，改為使用UA-5之外，其餘均 與例1相同而獲得樹脂層形成用光硬化性樹脂組成物PS。使 用PS(40質量份）、UA-5合成時所使用者相同之分子末端並 未加成環氧乙烷且1分子中具有2個羥基的雙官能基聚丙二 醇（由羥值所計算出的數量平均分子量2000)30質量份、以及 分子量大於UA-5合成時所使用者之分子末端並未加成環氧 乙烷且1分子中具有2個羥基的雙官能基聚丙二醇（由羥值 所計算出的數量平均分子量5500)30質量份，獲得樹脂層形 70 201210812 成用光硬化性樹脂組成物s。樹脂層形成用光硬化性樹脂組 成物S在25°C下的黏度係〇.9Pa · s。 利用流變儀測定樹脂層形成用光硬化性樹脂組成物Q 光硬化後的黏彈性特性，結果儲存剪切彈性模數係 2.0xl04Pa、其損失正切(tan5)係0.15。 與例1同樣’除密封部形成用光硬化性樹脂組成物係使 用組成物C ’且樹脂層形成用光硬化性樹脂組成物係使用組 成物S之外，其餘均與例1相同而獲得顯示裝置τ。 將顯示装置T送返被取出液晶顯示元件的液晶監視器 之框體中，經再度連接配線後，以接合於玻璃板B的顯示元 件A成為垂直之方式設置液晶監視器。經靜置5日後切入電 源，結果可獲得涵蓋顯示畫面全面呈均質且良好的顯示影 像，且顯示對比高於當初狀態。即使手指頭強力按押影像顯 不面，影像仍不會凌亂，玻璃板B有效地保護著顯示元件A。 接著，同樣的設置顯示裝置T，經1個月後確認顯示元 件的接合位置，並無發現位置偏料情形，良好地保持於 玻璃板。 ' 含有本發明硬化性化合物（11)、及非硬化性募聚物 (D)，且該(D)的含量係佔硬化性樹脂組成物中的1〇〜9〇質量 %之例1〜5、9及1〇，得知可降低因樹脂層硬化時的收縮所 產生應力，可獲得涵蓋顯示液晶畫面全面呈均質且良奸的 顯示影像。 ^ 雖含有本發明硬化性化合物(II)，但未含有非硬化性寡 聚物(D)的例6、例7 ’在液晶顯示晝面的周緣部有出現顯示 71 201210812 斑，特別係半色調的顯示時會明顯被檢視到。又，特別係 相對於硬化性化合物(11)1〇〇質量份，鏈轉移劑含有超過 質量份的例8，並無法將顯示元件良好地保持於破璃板上。 產業上之可利用性 本發明的硬化性樹脂組成物係能有效利用於顯示裝置 所使用之層積體的製造。 、 另外，2010年6月16日所提出申請的日本專利申請案 2010-137532號之說明書、巾請專職圍圖式及摘要等全 部内容，均爰引於本案中，並納人為本發明說明書的揭示。 【圖式< 簡說^明】 第1圖係利用透明面材保護顯示元件的顯示裝置一例 之剖視圖。 第2圖係第1圖之顯示裝置的平面圖 第3圖係步驟(a)的態樣一例平面圖。 第4圖係步驟⑷的態樣一例剖視圖。 第5圖係步驟(b)的態樣一例平面圖。 第6圖係步驟(b)的態樣一例剖視圖。 第7圖係步驟(c)的態樣一例剖視圖。 第8圖係步驟(d)的態樣-例剖視圖。 【主要元件符號說明】 1，...顯示裝置 10, 52, 53…透明面材 12.··未硬化密封部 13...區域 H...樹脂層形成用光硬化性樹 脂組成物 18.31.. .下定盤 20.. .分配器 72 201210812 22, 24...導螺 42...密封部 26...減壓裝置 50...顯示元件 28...真空泵 51...偏光板 30...上定盤 54...可撓性印刷電路板 32...吸附墊 55...遮光印刷部(遮光部) 34.. .氣缸 40.. .樹脂層 56...透光部 73201210812 VIII. The invention relates to a curable resin composition which is suitable for surface material joining, a laminate in which a surface material is laminated using the curable resin composition, And a method of manufacturing the laminate. BACKGROUND OF THE INVENTION In a display device in which a protective layer is laminated on a display element via a bonding resin layer, when the bonding resin layer is cured, stress generated by shrinkage of the bonding resin layer may affect the display element. If stress is applied to the display element, the following problems occur. • The display forming material (hereinafter referred to as the "display material") in the display element is affected by stress, which may impair the uniformity of display. For example, in the case of the liquid crystal display element, the arrangement of the liquid crystal enclosed in the display element is disturbed by the external stress, and the display spot is observed. • When an optical film such as a viewing angle is used to improve the display quality on the surface of the substrate on the display surface side of the display element, the optical characteristics of the optical film may be locally changed due to stress, and the display may be damaged. Uniform sentence / Sexuality. Further, since the bonding resin layer is provided on the inspection side of the display element, if bubbles are present in the cured bonding resin layer, the following problem occurs. • The outgoing or reflected light from the display element will be messy due to air bubbles, which will greatly damage the quality of the displayed image. 3 201210812 Because it remains through the protective plate. • When the display element does not display an image, there is a possibility that the bubbles in the bonding resin layer are more easily detected and the quality of the product. • The interfacial force between the resin layer and the (4) component, and the interface between the lyophilized layer and the slab are reduced. - A method of manufacturing a laminated structure display device having a transparent face material laminated on a display element is known, and a method as described below is known. (1) After injecting a liquid raw material into a resin-made blank plate to harden (4) the bonded resin, or after attaching the rolled-shaped bonding resin to the resin protective plate in a degassed state, the liquid crystal cell is pressed from the end. - Polyoxygen gel (Patent Document 1) is used for the replenishment in the degassing state and in the layer (4) method. (2) At the position of the glass protective plate, the liquid crystal resin is injected under reduced pressure in the space formed between the protective plate and the display panel after the member is positioned and temporarily fixed by the member. The method of laminating the material and hardening it. The liquid resin material is preferably a polyoxyn resin (Patent Document 2). CITATION LIST Patent Literature PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT It has been found that the elastic modulus of the bonding resin layer can be lowered by lowering the polarity and molecular weight of the resin layer forming the bonding resin layer. When the elastic modulus of the bonding resin layer interposed between the display element and the Japanese (four) material is lowered, the stress generated during the hardening and contraction is reduced, and the influence on the display quality can be suppressed. However, depending on the reduction of the elastic modulus of the # resin layer, there is a case where the display element and the transparent surface material are not fixed. For example, when the display device is vertically disposed, the display tree may have a time. The possibility of being deflected off or detached from the transparent face material. In addition, it is considered that a high molecular weight hardening precursor compound is used as much as possible in the raw material of the bonding resin layer, and the number of bonding sites of the curing reaction is relatively decreased, whereby the elastic modulus of the bonding resin layer is lowered. The viscosity of the composition when it is not hardened becomes too high and there is a fear that it is difficult to inject or coat. Further, if the crosslink density of the resin layer after hardening becomes too small due to the decrease in the number of bonding sites, the force of fixing the display element and the transparent face material will become insufficient, for example, when the display device is set to #直设置❹, The display element may have the possibility of being deflected off or detached from the transparent face material over time. The present invention has been made in view of the above circumstances, and it is an object of the invention to provide a surface layer which can be sufficiently fixed to each other when a surface layer is integrated by a resin layer composed of a cured product of a curable resin composition. Further, a curable resin composition which can reduce stress caused by shrinkage during curing of the resin layer and a laminate in which the surface material is laminated using the curable resin composition can be used. In addition, it is an object of the present invention to provide a surface layer which is formed by laminating a surface layer of a cured resin formed of a curable resin group 201210812, and the surface materials can be sufficiently fixed to each other. A method for producing a laminate in which the stress generated by the shrinkage of the resin layer is reduced and the generation of bubbles in the resin material is sufficiently suppressed. The means for solving the problem of the present invention is a laminate for use in a laminate in which a uncured curable resin composition is held between a pair of face materials and cured. The surface material is at least a surface material which is transparent, and the curable resin composition contains the following curable compound (II) and the following non-curable oligomer (D), and the non-hardening property The content of the oligomer (D) is 10 to 90% by mass. The curable compound (II) is one or more types of a curable compound which undergoes a curing reaction when the curable resin composition is cured, and at least one of the curable compounds One type has a radical which does not react when the curable resin composition is cured. Non-curable polymer (D): an oligomer which does not undergo a curing reaction with the curable compound (II) when the curable resin composition is cured, and has 0.8 to 3 hydroxyl groups per molecule. It is preferred that the curable compound (II) contains a monomer having a curable group and having a hydroxyl group. Preferably, the curable compound (II) contains an oligomer (A') having a curable group and having a molecular weight of 1,000 to 100,000; and a monomer (B〇 having a curable group and having a molecular weight of 125 〜) 600, and the monomer (B,) contains a monomer having a hydroxyl group (B3). 201210812 The second is a non-hardening oligomer (D), and the polyoxygen extension polymer (4) is a polyoxygen extension. An amine-based oligo-polymer synthesized by using a polybasic vinegar as a raw material. The vehicle X is preferably the aforementioned oligomer (A,) having a propyl sulphate and a sulphide (a) Preferably, the monomer (B3) contains a mercaptopropionic acid via a base having a hydroxyl group of 1 and a carbon number of 3 to 8. Preferably, the above is preferred. The monomer (B,) contains a monomer (1) 4) selected from the group consisting of alkyl thioalkyl acrylates having a carbon number of 8 to u. Preferably, the alkane does not contain a chain transfer agent, or contains a chain transfer agent, and is extended in an amount of 100 parts by mass based on 100 parts by mass of the curable compound (11), and the layered body provided by the present invention is contained. A layer of a pair of face materials of at least one of the enamel-side materials is laminated by a resin layer, and the yam 5 ruthenium layer is composed of a cured product of the curable resin composition of the present invention. Preferably, one of the pair of face materials is a transparent face material, which is a display element. Further, in the method for producing a laminate according to the present invention, the laminated system to be produced includes: a first surface material and a second surface material, wherein the first and second surface materials have a transparent surface material; a resin layer; The person who is lost by the i-th face material and the second face material and the sealing portion surrounds the periphery of the resin layer, and the manufacturing method includes the following = steps (a) to (d): '(a) at the first a step of applying a curable tree smear composition for forming a liquid seal portion containing a curable compound (1) and a polymerization initiator to a peripheral portion of the surface of the surface material to form an uncured seal portion; 201210812 (b) uncured seal a step of supplying a curable resin composition for forming a resin layer composed of a modified fat composition of the present invention in a region surrounded by the portion; (c) forming a resin layer in a reduced pressure environment of 1 〇〇pa or less A laminated precursor of a curable resin composition for forming a resin layer having a curable resin composition for forming a resin layer, which has been sealed by a crucible 1 surface material, a second surface material, and an unhardened Mithene And (d) in a state in which the laminated precursor is placed under a pressure environment of M5 〇 kpa or more, The step of hardening the seal portion and the resin layer forming curable resin composition is performed. Preferably, one of the first surface material and the second surface material is a transparent surface material, and the other is a display element. According to the curable resin composition of the present invention, the pair of face materials can be sufficiently fixed by being held between the faces and cured, and the stress caused by shrinkage during hardening can be reduced. According to the laminate of the present invention, the face material and the face material can be sufficiently fixed by the resin layer, and the stress caused by the shrinkage when the resin layer is cured can be reduced. According to the method for producing a laminate of the present invention, the pair of face materials can be sufficiently fixed by the resin layer composed of the cured product of the curable resin composition of the present invention, and the shrinkage due to the curing of the resin layer can be reduced. The stress is formed, and the laminate can be produced while sufficiently suppressing the occurrence of bubbles in the resin layer. In the laminated system of the present invention, for example, a display device according to the present invention can sufficiently suppress the generation of bubbles in the resin layer between the display element and the protective sheet 201210812"", and the bezel element and the protective sheet are sufficiently interposed by the resin layer. The fixing device can reduce the stress at the time of hardening and contraction, and the display device with reduced display quality due to the stress can be obtained. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing an example of a display device for protecting a display element by a transparent surface material. 2 is a plan view of the display device of Fig. 1. Fig. 3 is a plan view showing an example of the step (a). Fig. 4 is a cross-sectional view showing an example of the step (a). Fig. 5 is a state of the step (b) Fig. 6 is a cross-sectional view showing an example of the aspect of the step (b). Fig. 7 is a cross-sectional view showing an example of the step (c). Fig. 8 is a cross-sectional view showing an example of the step (d). MODE FOR CARRYING OUT THE INVENTION In the present invention, the definition is as follows: "In the display device, a transparent surface material which is a protective sheet of a display element is referred to as a surface material", and a display element is referred to as a "back surface material". The surface material and the back material are collectively referred to as "face material". In the manufacturing method of the present invention, the surface material in which the sealing portion is formed in the rib portion and the liquid sclerosing resin composition is supplied from the sealing portion is referred to as the "i-th surface material", and the surface material is overlapped. The surface material on the curable resin composition is referred to as "second surface material". The light transmissive surface material is called "transparent surface material". 201210812 The transparent surface material made of glass is called "glass plate". In the case of the preferred embodiment of the present invention, the apparatus of the laminated system of the present invention, the surface material of the surface material (the transparent surface material of the protective sheet) and the back material (display element), and An embodiment in which the sealing portion (four) hardening ribs and the curable resin composition for forming a resin enamel are photocurable resin groups * will be described. <Display Device> Fig. 1 is a cross-sectional view showing an example of a display device of the present embodiment, and Fig. 2 is a plan view. The display device 1 includes a transparent surface material 10 (second surface material (or first surface material)), a display element 50 (first surface material (or second surface material)), a resin layer 40, a sealing portion 42, and the like. a flexible printed circuit board 54 (FPC) and a light-shielding printing unit 55 (light-shielding. The transparent surface material 10 belongs to a surface material, and the display element 5 is a back surface material, and the resin layer 40 is made of a transparent surface material 1 The 〇 and the display element 5 are sandwiched, and the 5H sealing portion 42 surrounds the periphery of the resin layer 40. The flexible printed circuit board 54 is connected to the display device 50 and is mounted with a driving 1C for starting the display device 50. The light-shielding printing portion 55 is formed on the peripheral edge portion of the transparent surface material 10. In the display device 1, the light-shielding printing portion 55 is provided on the peripheral portion of the transparent surface material 10, and the area of the light-transmitting portion 56 surrounded by the light-shielding printing portion 55 is provided. The area of the transparent surface material 1 系 is larger than the area of the resin layer 40 surrounded by the sealing portion 42 . The area of the transparent surface material 1 〇 is larger than the area of the display element 50 , and the total area of the resin layer 40 and the sealing portion 42 is smaller than each of the transparent surface material 10 and the display element 50 . [Surface material] The surface material is a display element that can be penetrated by the display image. Bright surface material 10 201210812 (protective plate). The transparent surface material is, for example, a glass plate or a transparent resin plate, and is highly transparent to the light emitted from the display element and reflected light. From the viewpoints of low birefringence, high planar precision, surface scratch resistance, and high mechanical strength, it is most preferably a glass plate. The viewpoint of sufficiently penetrating light energy for hardening a photocurable resin composition is also The glass plate is preferably a material of the glass plate, for example, a glass material such as soda lime glass, and preferably a high penetration glass having a lower iron content and less blue light (the glass P is used for safety improvement, and the surface material may be A tempered glass is used. The material of the transparent resin sheet is, for example, a resin material having high transparency (such as polycarbonate, polymethyl methacrylate, etc.). In the transparent surface material, in order to enhance the interfacial adhesion between the resin layer and the resin layer, Surface treatment can also be carried out. The method of surface treatment is, for example, a method of treating a surface of a transparent surface material with a broken yard coupling agent, or forming an yttrium oxide by using an oxidizing flame generated by a flame burner. Film treatment, etc. In the transparent surface material, in order to improve the contrast of the display image, an anti-reflection layer may be provided on the back surface of the joint surface with the resin layer. The anti-reflection layer may be formed directly on the surface of the transparent surface material, for example. A method of bonding an inorganic thin film or a method of bonding a transparent resin film provided with an antireflection layer to a transparent surface material is provided. Further, for the purpose of image display, a part or all of the transparent surface material may be colored in advance. Or it is light-scattered, and light is refracted or reflected by the fine unevenness of the surface, etc. Further, 201210812 can also optically optical film, polarizing film, etc. as described above. The modulated optical film or the like is bonded to the transparent surface material to form an integral body, and is used as a transparent surface material. The thickness of the transparent face material is usually 0.5 to 25 mm in terms of mechanical strength and transparency. The use of a television receiver for indoor use, a display for a PC, etc., is preferably 0.7 to 6 mm in terms of weight reduction of the display device, and is preferably 3 to 20 mm when used for outdoor display. Reinforced glass can be used for the transparent surface material, and chemically strengthened glass can be used when the transparent surface material is thin. In the case of a transparent resin sheet, it is preferably 2 to 10 mm. [Back material] The back material is a display element. The display element 50 of the illustrated example is a liquid crystal display in which a transparent surface material 52 provided with a color filter and a transparent surface material 53 provided with a TFT are bonded together and sandwiched by a pair of polarizing plates 51. Although an element is an example, the display element of this embodiment is not limited to the illustration. The display element is a display material in which an optical state is changed by an external electrical signal in a pair of electrodes in which at least one of them is a transparent electrode. Depending on the type of the display material, there are, for example, a liquid crystal display element, an EL display element, a plasma display element, an electronic ink type display element, and the like. Further, the display element has a configuration in which a pair of face materials are bonded and at least one of the pair of face materials is a transparent face material, and the transparent face material side is disposed adjacent to the resin layer. At this time, a part of the display elements are provided on the outermost layer side of the transparent face material on the side adjacent to the resin layer, and an optical film such as a polarizing plate or a phase difference plate is provided. In this case, the resin layer is in a state in which the optical film on the display element is bonded to the surface material. 12 201210812 The surface of the joint between the display element and the resin layer can be surface-treated to enhance the interface between the seal and the seal. The surface treatment can be applied to only the peripheral portion and can also be applied to the entire surface of the face material. The surface treatment method is, for example, a method in which a low-temperature process can be used followed by a primer or the like. The thickness of the display element is usually 0.4 to 4 mm when it is a liquid crystal display element activated by a TFT, and is usually 0. 2 to 3 mm when it belongs to an EL display element. [Resin layer] The resin layer is a layer formed by curing the curable resin composition of the present invention (hereinafter also referred to as "photocurable resin composition for forming a resin layer"). The curable resin composition of the present invention (the photocurable resin composition for forming a resin layer of the present embodiment) can reduce the modulus of elasticity after curing and can reduce the stress generated during curing. Therefore, it is possible to suppress the adverse effect on the display performance of the display element due to the stress. Further, since the curable resin composition has a low viscosity when it is not cured, the curable resin composition on the surface of the surface material can be supplied in a short time, so that it is easy to prevent bubble residue after the surface material and the back material are laminated. situation. The thickness of the resin layer is preferably 0_03 to 2 mm, more preferably 〇.1 to 〇.8 mm, and particularly preferably 0.2 to 0.6 mm. If the thickness of the resin layer is more than mm3 mm, the resin layer can effectively buffer the impact caused by the external force from the side of the transparent surface material. In particular, when the display element is sensitive to external force and is more likely to affect the display quality, it is preferably set to a thickness of 0.2 mm or more. Further, in the production method of the present embodiment, even if a foreign material exceeding the thickness of the resin layer is mixed between the transparent surface material and the display element, the thickness of the resin layer 13 201210812 does not change much, which affects the light penetration performance. less. If the thickness of the resin layer is 2 mm or less, the bubbles are less likely to remain in the resin layer, and the overall thick jersey of the display device will be thicker than W. When the elastic modulus of the fat-receiving layer is small, the time when the display element of the material display element is shifted with time or the like is preferably set to a thickness of 〇6 mm or less. The method of adjusting the thickness of the resin layer is a method of adjusting the thickness of the sealing portion described later and adjusting the supply amount of the liquid-hardening resin composition for forming the liquid resin layer supplied to the second surface material. [Sealing portion] The sealing portion is formed by applying a photocurable resin composition for forming a liquid sealing portion, which is described later, and is cured. Since the outer region of the image display area of the display element is relatively narrow, the width of the sealing portion is preferably narrow. The width of the sealing portion is preferably 0.5 to 2 mm, more preferably ο" to i.6 mm. [Light-shielding printing portion] A light-shielding printing portion can be provided on the peripheral portion of the transparent surface material as needed. The opaque printing unit hides the wiring member or the like connected to the display element so that it cannot be seen from the side of the transparent surface material except for the image display area of the display element. The light-shielding printing portion can be provided on the joint surface of the transparent surface material and the resin layer or the back surface thereof to reduce the parallax between the light-shielding printing portion and the image display region, and is preferably provided on the joint surface of the transparent surface material and the resin layer. In the case where the transparent surface material is a glass plate, it is preferable that the light-shielding printing portion is made of a ceramic printing plate containing a black pigment. The light-shielding printing portion can also be formed by bonding a transparent film having a light-shielding portion on the front surface or the back surface to the transparent surface material. A transparent face material without a light-shielding printing portion can also be used. 201210812 [Shape] The shape of the display device is usually rectangular. The size of the display device is not particularly limited, and the manufacturing method of the present embodiment is particularly suitable for the manufacture of a display device having a large area, and thus it is preferable to use a liquid crystal display element, and in the case of a pc screen, it is preferable ( Umx〇.i8m is preferably 〇 or more, more preferably 〇.7mx 〇.4m or more in the case of a television receiver. The upper limit of the size of the display device is often determined according to the size of the display element. The apparatus tends to be difficult to handle, etc. The upper limit of the size of the display device is usually about 2.5 mxl_5 m from the viewpoint of 鸪, etc. In the case of a small display, it is preferably 0.14 mx 〇. 〇 8 m or more. The transparent face material of the plate and the size of the display element can be substantially equal, but in relation to the other housings accommodating the display device, in most cases, the transparent face material is larger than the display element. The structure of the frame can also make the transparent surface material a little smaller than the display element. <Manufacturing Method of Display Device> The method of manufacturing the display device according to the present embodiment includes the following steps (a) to (d). The surface of the surface of the surface material of the V-shaped surface material (the moon-shaped material (or surface material)) is coated with a photo-curable resin containing a curable compound (I) and a photopolymerization initiator (α). (4) Forming an uncured seal portion (However, when the first face material is a display element, a seal portion is formed on the surface on the image display side). (b) A step of supplying a photocurable resin composition for forming a liquid resin layer containing a curable compound (2012) and a photopolymerization initiator (C2) to the uncured sputum. (c) The second surface material (surface material (or back material)) is superposed on the resin layer-forming photocurable resin composition under a reduced pressure of 100 Pa or less to obtain a photocurable resin for resin layer formation. a step of laminating a precursor having a second surface material, a second surface material, and an unhardened sealing portion (however, when an antireflection film is provided on the surface of the second surface material, the back side is The surface-adjacent resin layer is formed so as to overlap with the photocurable resin composition. In the case of the second surface-material display element, the image display side is superimposed on the photo-curable resin composition for resin layer formation. . (d) A step in which the uncured seal portion and the resin layer-forming photocurable resin composition are irradiated with light to be cured in a pressure environment of 5 kPa or more. When the light-shielding portion is not formed on the transparent surface material, the sealing portion and the resin layer-forming photocurable resin composition are irradiated with light from the laminated surface on the side of the transparent surface material through the light-transmitting portion. When the light shielding portion is formed on the peripheral portion of the transparent surface material, the area of the light transmission portion surrounded by the light shielding portion is smaller than the area of the resin layer surrounded by the sealing portion, and the resin layer is formed of a photocurable resin. The absorption wavelength region (12) of the photopolymerization initiator (C2) contained in the product is higher than the absorption wavelength region of the photopolymerization initiator (Ci) contained in the photocurable resin composition for sealing portion formation. (λ 1) exists on the longer wavelength side, and the light irradiated from the side of the laminated precursor in the above step (d) covers the wavelength light and the absorption wavelength region in the absorption wavelength region (λ 1 ) ( Also 2) wavelength light inside. 16 201210812 The manufacturing method of the present embodiment is a photocurable resin composition for forming a liquid resin layer between the second surface material and the second surface material in a reduced pressure environment, and a high pressure environment in an atmospheric pressure environment. Next, a method of forming a resin layer by curing the resin layer formed by curing the formed photocurable resin composition (decompression lamination method). The method of encapsulating the photocurable resin composition for forming a resin layer under reduced pressure is not a method of injecting a photocurable resin for forming a resin layer in a narrow space between the first surface material and the second surface material. The photocurable resin composition for forming a resin layer is supplied to almost the entire surface of the second surface material, and then the second surface material is superposed on the surface of the first surface material and the second surface material. A method of resin composition. An example of a method for producing a transparent laminate by encapsulating a photocurable resin composition for forming a liquid resin layer under reduced pressure and curing the photocurable resin composition for forming a resin layer under atmospheric pressure known. For example, the method for producing a transparent laminate described in the pamphlet of International Publication No. WO 2008/81838, the pamphlet of International Publication No. 2009/16943, and the photocurable resin composition used in the production method are incorporated in the present specification. [Step (4)] First, an uncured seal portion is formed along the peripheral portion of the surface of the first face material. The first surface material can be used arbitrarily as a back material or a surface material. When the first surface material belongs to a transparent surface material which is a protective sheet for a display element, the surface on which the uncured seal portion is formed can be arbitrarily one of two surfaces. When the characteristics of the two surfaces are different, the desired surface is selected. For example, when one of the surfaces has a surface treatment of the interface between the resin layer and the resin layer, the uncured seal is formed on the surface. Further, in the case where the roll is provided with an antireflection layer on one of the surfaces, an unhardened seal portion is formed on the back surface. In the case of the first surface material display element, the surface on which the uncured seal portion is formed is the surface on the image display side. The uncured seal portion is characterized in that, in the step (C) to be described later, the photocurable resin composition for forming a night-like resin layer does not have an interface between the unhardened seal portion and the first face material, and an unhardened seal. The interface between the portion and the second surface material has an interface adhesion force of more than the extent of the leakage and a degree of robustness capable of maintaining the shape. Therefore, it is preferable that the uncured seal portion is formed of a photocurable resin composition having a high viscosity and formed by coating such as printing or arranging. In addition, in order to maintain the space between the first surface material and the second surface material, it is also possible to form a photocurable resin for the sealing portion, and the spacer particles are formed of a photocurable resin for forming a sealing portion. Immediately after application, the sealing portion may be partially semi-cured by irradiating light for curing the sealing portion, and the shape of the sealing portion may be maintained for a longer period of time. [Photocurable resin composition for sealing portion formation] The photocurable resin composition for sealing portion formation (hereinafter also referred to as "sealing material") is a photocurable curable compound (1) and a photopolymerization initiator (C1). Liquid composition. The viscosity of the photocurable resin composition for forming the sealing portion is preferably 500 to 3 Pa·s, more preferably 2 to 2,500 Pa·s, and more preferably 1 to 12,108,028,200 Pa·s. When the viscosity is 500 Pa·s or more, the shape of the uncured seal portion can be maintained for a long period of time, and the height of the seal portion can be sufficiently maintained. If the viscosity is at 3000Pa.  Below s, the sealing portion can be formed by a coating method. The viscosity of the photocurable resin composition for forming the seal portion was measured at 25 Å using an E-type viscometer. (The curable compound (I)) The curable compound (1) is preferably one in which the viscosity of the photocurable resin composition for forming a sealing portion is adjusted within the above range, and it is preferable to contain the oligo (4) or more. More than or equal to the monomer (9), the oligomer (4) has a curable group and has a number average molecular weight of 3 Å to 1 Å; the monomer (B) has a curable group and a molecular weight of丨25~6〇〇. The curable group of the polymer (A) or the monomer (B) may, for example, be an unsaturated group having an addition polymerizable group (such as a propylene fluorenyl group, a decyl propylene oxy group or the like) and a thiol group. From the viewpoint of the combination of the groups and the like, the viewpoint of the fast curing rate and the transparency to the sealing portion can be obtained, and is preferably selected from the group consisting of a acryloxy group and a mercapto acryloxy group. The curable group in the monomer and the curable group in the monomer (B) may be the same or different from each other. Because of the hardening group in the oligomer having a relatively high molecular weight, the reactivity tends to become lower than The hardening group in the monomer (B) having a relatively low molecular weight, and thus the hardening of the monomer (B) proceeds first, resulting in an increase in the viscosity of the entire composition, resulting in an inhomogeneity of the hardening reaction. The reactivity of the hardening group is poor, and a homogeneous sealing portion can be obtained, and the hardening group in the oligomer (A) is preferably a highly reactive propylene oxy group, and the monomer (B) is used. The hardening group in the middle is set to a less reactive methyl group 201210812 propylene oxime. The number average molecular weight of the oligomer (A) 30000 to 100000, preferably 40,000 to 80,000, more preferably 50,000 to 65,000. If the number average molecular weight of the oligomer (A) is within this range, the sealing portion is easily formed into a photocurable resin composition. The viscosity is adjusted within the above range. The number average molecular weight of the oligomer (A) is obtained by Gpc measurement, and is a polystyrene-converted number average molecular weight. In addition, in the Gpc measurement, 'when there is a low molecular weight component which is unreacted by ib When the peak of (monomer or the like) is sharp, the peak is excluded from the number average molecular weight. The molecular weight of the monomer (B) is 125 to _, preferably 14 〇 to 4 Å, more preferably 150 to 350. When the molecular weight of the body (B) is 125 or more, when the display device is produced by the pressure reduction lamination method described later, volatilization of the monomer (9) can be suppressed. If the monomer (_ molecule 4 is in the _ town, the monomer can be increased) Polymer .  The solubility of the oligomer (4) can be appropriately adjusted, and the viscosity of the (four)-shaped resin-based resin composition can be appropriately adjusted. (Oligomer (A)) The oligomer (4) is preferably an average of 1. per molecule for the viewpoint of the curability of the photocurable resin composition for forming a sealing portion and the mechanical properties of the sealing portion. 8 to 4 hardening bases. The oligomer (A) may, for example, be a urethane condensate having an amine phthalate linkage, a poly(methyl) acrylate vinegar of a polyoxyl extension polyol, or a polyphenol polyol. β (meth) acrylate, etc. According to the molecular design of the carboxylic acid smelting chain, it is possible to broadly adjust the viewpoints such as the simplicity of the tree after hardening (4) and the adhesion to the ton, 20 201210812 The urethane sulfonate oligomer (A1) which is synthesized by using polyisocyanide as a raw material is more preferably a urethane oligomer (A1) which will be described later. The polyhydric alcohol is preferably a polyoxyalkylene-based polyol. (Amine phthalate polymer (A1)) The urethane oligomer (Al) 'g' having a number average molecular weight of 3 〇〇〇〇 to 1 〇〇〇〇〇 is highly degraded. It is difficult to carry out the mixing with the monomer because it is difficult to perform the synthesis according to the ordinary method, even if it can be synthesized. Therefore, it is preferred to use the obtained product as a seal after synthesizing the amine-method (A1) according to the synthesis method using the monomer (B) (the following monomers (B1) and (B2)). The photo-curable tree residue is formed in the portion, or the obtained product is further diluted with the monomer (B) (the following monomer (B1), monomer (B3), etc.) to be used as a sealing portion. Photocurable resin composition. • Monomer (B1): A monomer having a curable group and a group which does not react with an isocyanate group in the monomer (B). • Monomer (B2): a monomer having a curable group and having a group reactive with an isodecanoate group in the monomer (9). • Monomer (B3): A monomer having a curable group and having a hydroxyl group in the monomer (B). Method for synthesizing amine phthalate polymer (A1): reacting a polyol with a polyisocyanate in the presence of a monomer (B1) as a diluent to obtain a prepolymer having an isocyanate group, and then The monomer (B2) is a method of reacting the isocyanate group of the prepolymer. The polyhydric alcohol and the polyisocyanate are known compounds, and are, for example, a polyterpene alcohol (1), a diisocyanate (..., etc.) which is a raw material of an amine phthalate oligomer (& 21,108,108) described in the pamphlet of International Publication No. 2009/016943. The polyhydric alcohol (1) may be a polyoxyalkylene-based polyol such as polyoxyethylene glycol or polyoxypropylene propylene glycol; a poly-polyol or a polycarbonate polyol. Among them, 'preferably polyoxyl extension-based polyol, more preferably polyoxy-extension propyl polyol. Also, if the oxygen extension of the polyoxypropyl propylene glycol is partially substituted with oxygen extension Ethyl' is preferable because it can improve the compatibility of the photocurable composition for forming a resin layer with other components. Here, "the so-called "some of the oxygen-extended propyl group can be substituted with an oxygen-extended ethyl group". 'Represents the molecular structure of the oxygen-extended ethyl structure of the oxygen-extended propyl group, which constitutes the polyoxy-extension propylene polyol molecule. The same description as described later refers to the phase _ Meaning. Oxygen-extended ethyl structure π is random or block exists in polyoxygen The propyl polyol molecule, in addition, the oxygen-extended ethyl structure can be in the polyoxy-extension propyl polyol molecule (4), or just before the terminal via the base. When the oxygen-extended ethyl structure is located at the end of the base group ^ In the case, in the polyoxyl oxime alcohol, the epoxy epoxide can be selected from the lipid _ diisocyanate _ 1 and the non-yellowing aromatic diisocyanate _ 2 vinegar. Examples of the aliphatic polyiso-acid vinegar are as follows: = acid cool, trimethyl _ hexamethylene diisocyanate, ...: ki-sixa "diiso-gas", etc. Examples of the cyclic polyisocyanate (4) are as follows: 汐 尔 酮 二 二 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 These may be used alone or in combination of two or more. 22 201210812 The monomer (B1) may, for example, be an alkyl (meth)acrylate having an alkyl group having 8 to 22 carbon atoms (such as: Mercapto) n-dodecyl acrylate, n-octadecyl (meth) acrylate, n-decyl (meth) acrylate, etc., (fluorenyl) acrylate having an alicyclic hydrocarbon group ( For example, (meth)acrylic acid isodecyl ester, (fluorenyl)adamantyl acrylate, etc.) The monomer (B2) may, for example, be a monomer having an active hydrogen (such as a hydroxyl group, an amine group, etc.) and a curable group. Specifically, for example, a hydroxyalkyl (meth) acrylate having a hydroxyalkyl group having 2 to 6 carbon atoms (such as 2-hydroxymethyl (meth) acrylate or (fluorenyl) acrylate-2- Hydroxypropyl ester, 2-hydroxybutyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, etc., etc., preferably a hydroxyalkyl acrylate having a hydroxyalkyl group having 2 to 4 carbon atoms (Monomer (8)) The monomer (B) is preferably one to three hardening groups per molecule from the viewpoints of the curability of the photocurable resin composition for forming a sealing portion, the mechanical properties of the sealing portion, and the like. The photocurable resin composition for forming a seal portion may contain a monomer (B1) as a diluent in the method for synthesizing the above-described amine phthalate oligomer (A1) in terms of the monomer (B). . Further, the monomer (B) may contain the unreacted monomer (B2) used in the method for synthesizing the above-described urethane oligomer (A1). The monomer (B) preferably contains a monomer having a hydroxyl group (B3) from the viewpoint of the adhesion between the face material and the sealing portion and the solubility of various additives described later. The monomer (B3) having a hydroxyl group is preferably, for example, a hydroxyalkyl methacrylate having a hydroxyalkyl group having a hydroxyl group number of 1 to 2' carbon number of 3 to 8 (such as methacrylic acid _2_propyl acrylate, methacrylic acid) _2_hydroxybutyl ester, 4-hydroxybutyl methacrylate, methyl 23 201210812 hexamethylene hexaacrylate, glycerol monodecyl acrylate, etc.), more preferably methacrylic acid-2 - The purpose of the Ding. The content ratio of the monomer (B) in the photocurable resin composition for forming a sealing portion, and the total amount (100% by mass) of the curable compound (1), that is, the total of the oligomer (A) and the monomer (B) (100 mass) In the %), it is preferably 15 to 5 % by mass, more preferably 20 to 45% by mass, still more preferably 25 to 4 % by mass. When the ratio of the monomer (8) is 15% by mass or more, the curability of the photocurable resin composition for forming a seal portion and the adhesion between the face material and the sealing portion are good. When the ratio of the monomer (B) is 5% by mass or less, the viscosity of the photocurable resin composition for sealing portion formation can be easily adjusted to 5 〇 OPa · s or more. In addition, in the synthesis of the urethane acrylate oligomer (A1), the isocyanate of the prepolymer is intended to be a single-handed product, 2), because the form of a part of the transpolymer (A) exists. EI is not included in the monomer (B) content in the photocurable resin composition for sealing portion formation. On the other hand, in the synthesis of the urethane methacrylate oligomer (A1), the monomer (Bi) used as a diluent and the monomer (B) added after the synthesis of the urethane carboxylic acid oligomer (A1), It is included in the content of the monomer (B) in the photocurable resin composition for forming a seal portion. (Photopolymerization initiator (C1)) The photopolymerization initiator (C1) contained in the photocurable resin composition for sealing portion formation may, for example, be phenethyl ketone, ketal ketone or benzoin Or a photopolymerization initiator such as a benzoin ether system, a phosphine oxide system, a diphenyl ketone system, a thioxanthone system or an anthraquinone system, and is preferably, for example, an acetophenone system, a ketal system, or a benzoin ether. A photopolymerization initiator. When the short-wavelength visible light is used for hardening, the photopolymerization of the Lithium-based phosphine oxide system starts from the viewpoint of absorbing the wavelength region. By using two or more kinds of photopolymerization initiators (C1) having different absorption wavelength regions in combination, the hardening time can be further accelerated or the surface hardenability of the sealing portion can be improved. In addition, when the transparent surface material is provided with a light-shielding printing portion, and the light is irradiated from the side surface of the surface material, the uncured seal portion held by the light-shielding portion and the photo-curable resin composition for resin layer formation are used. In the case of hardening, it is possible to use a photopolymerization initiator (C2) which will be described later in the range of curing of the resin layer-forming photocurable resin composition which does not inhibit the adjacent portion of the uncured seal portion. The ratio of the polymerization initiator (C1) to the polymerization initiator (C2) is preferably 5 Å in terms of the mass ratio of (C1):(C2) in terms of efficiency and effective hardening. Bu 5: i. In order to allow the resin layer-shaped graded tree (4) to be held by the light-shielding printing portion, the light irradiated from the side surface of the surface material can be hardened in a short time via the uncured sealing material, and the photocurable resin for forming the sealing portion can be formed. The composition preferably does not contain a photopolymerization initiator (C2). The amount of the photopolymerization initiator (C1) 3 of the photocurable tree test fabric formed by the male seal portion (when the photopolymerization initiator (C2) is contained, the total amount of (C1) and (C2) is obtained. The total amount of the curable compound (1) (i.e., the total amount of the oligomer (A) and the military (9) is _ part by mass, preferably 0. 01 to 10 parts by mass, more preferably 0·1 to 5 parts by mass. (Additive) Sealed. The photocurable resin composition for forming a ruthenium may optionally contain, for example, a polymerization terminator, a photohardening agent, a chain transfer agent, a light stabilizer (such as. Various additives such as ultraviolet absorbers, radical scavengers, antioxidants, flame retardants, adhesion promoters (wei couplers, etc.), pigments, dyes, etc. 2012 20121212 Add Μ 'Better contains polymerization terminator, light stabilizer Agent. In particular, since the amount of the polymerization terminator is less than that of the polymerization initiator, the stability of the photocurable resin composition for the seal portion can be improved, and the molecular layer of the hardened tree layer can be adjusted. When the sealing material is hardened by light irradiated from the side surface of the face material, such as a polymerization terminator, a chain transfer agent, a light stabilizer, a pigment, (4), etc., which have an effect of delaying the hardening reaction, it is preferable not to use as much as possible. Or reduce the content. The hydrazine polymerization terminator may be, for example, a moth moth (such as 2, 5. Two third butyl hydrogen, etc.), catechu (four), (such as the third base of tea, etc.), brewing, hope. A polymerization terminator such as a well system or a toluene system. The photopigmenting agent may, for example, be a UV absorber (such as a benzotriazole system, a diphenylketone system or a salicylic acid vinegar system), a radical scavenger (such as a hindered amine system), or the like. The antioxidant is, for example, a phosphorus-based or sulfur-based compound. The total amount of the additives is preferably 1 part by mass or less, more preferably 5 parts by mass or less, based on the total mass of the curable compound (1), that is, the total amount of the polymer (Α) and the monomer (8). [Step (b)] After the step (a), a liquid curable resin composition for forming a liquid resin layer is supplied to a region surrounded by the unhardened sealing portion. The supply amount of the resin layer-forming photocurable resin composition is set in advance so that the space formed by the sealing portion, the first surface material, and the second surface material is filled with the photocurable resin composition for forming a resin layer, and The portion between the second surface material and the second surface material is spaced apart by a predetermined interval (that is, the resin layer is set to a predetermined thickness). In the case of the light-curable resin composition of the photo-curable resin, the formation of the light-curable resin composition is less than (4). Therefore, the amount is preferably such that the resin layer is increased by 7 to the thickness of the photocurable resin composition, and a certain amount is thicker than the thickness of the resin layer. In the case where the hardening shrinkage is small, the predetermined thickness of the resin layer and the thickness of the photocurable resin composition for forming a resin layer may be made substantially equal. The supply method is a method in which the first surface material is laid flat and supplied in a dot shape, a line shape or a surface shape by means of a supply means such as a dispenser or a mold coater. [Photocurable resin composition for forming a resin layer] The liquid curable resin composition for forming a resin layer is a liquid composition and contains a photocurable curable compound (η), a photopolymerization initiator (C2), And non-hardening oligomer (D). When the non-curable oligomer (D) is cured by the photocurable resin composition for forming a resin layer, it does not undergo a hardening reaction with the curable compound (II) in the composition, and has a ruthenium molecule of 0. 8 to 3 hydroxyl oligomers. The viscosity of the photocurable resin composition for forming the resin layer is preferably 0. 05~50Pa·s, better system 1~2〇pa·s. If the viscosity is 0. When the amount is more than 05 Pa·s, the ratio of the monomer (B·) to be described later can be suppressed, and the deterioration of the physical properties of the resin layer can be suppressed. Further, since the low boiling point component is small, it is suitable for the pressure reduction lamination method to be described later. When the viscosity is 50 Pa·s or less, the resin layer is less likely to have bubbles remaining. The viscosity of the photocurable resin composition for resin layer formation was measured at 25 ° C using an E-type viscometer. (Curable compound (II)) Curable compound 27 in the photocurable resin composition for forming a resin layer 201210812 (π) 'When the resin composition for forming a resin layer is cured, it hardens. At least one of the curable compounds is preferably one of the curable compounds, and the compound (Ila) which does not generate a reactive hydroxyl group when the photocurable resin composition for forming a resin layer is cured. . When the curable compound (π) contains the compound (na), a hydroxyl group is present in the cured product in which the curable compound (II) is hardened alone. The presence of the warp group contributes to the stabilization of the non-curable oligomer in the photocurable resin composition for forming a resin layer. Therefore, the compound (Ila) having the hydroxyl group which does not react at the time of hardening may be any unreacted hydroxyl group after the hardening reaction, for example, even if a part of the hydroxyl group of the compound (Ila) is hardened, the other part is not hardened. It can be left in an unreacted state. The compound (IIa) having a hydroxyl group which does not react upon curing may be an oligomer having a repeating unit as long as it has a curable group which contributes to the hardening reaction and has a hydroxyl group. . From the viewpoint of easily adjusting the viscosity of the photocurable composition at the time of uncured, it is preferred to use a monomer having a curable group and having a hydroxyl group as the compound (IIa). Specific examples of the compound (Ila) which is a monomer having a hydroxyl group are preferably an alkyl group-containing (meth)acrylic acid hydroxy ester having a hydroxyl group number of 1 to 2 and a carbon number of 3 to 8 [such as (meth)acrylic acid] -2-hydroxypropyl ester, 2-hydroxybutyl (meth)acrylate, _4_butyl butyl, (hexyl) hydroxyhexyl acrylate, glycerol mono(methyl) Acrylate, etc.] is more preferably methacrylic acid-2-butyl vinegar. The curable compound (II) preferably contains one or more of the oligomers (VIII) and one or more of the 2012 20121212 monomers (B'). The oligomer (A,) has a curable group and an average number of molecular weights of from 1,000 to 100,000. The monomer (B') has a curable group and a molecular weight of from 125 to 600. When the curable compound (11) is used, the viscosity of the resin layer-forming photocurable resin composition can be easily adjusted to the above-mentioned preferable range. In this case, it is preferred that at least a part of the monomer (B,) is a monomer (B3) having a curable group and having a hydroxyl group and having a molecular weight of from 125 to 600. The curable group in the oligomer (A') or the monomer (B,) may, for example, be an addition polymerizable unsaturated group (such as a acryloxy group, a methacryloxy group, etc.), or an unsaturated group. From the viewpoint of a combination of a thiol group and the like, a resin layer having a fast curing rate and a transparent property can be obtained, and is preferably selected from the group consisting of an acryloxy group and a methacryloxy group. The curable group in the nutrient (A') and the curable group in the monomer (B') may be the same or different from each other. Because of the hardening group of the higher molecular weight polymer (A,), the reactivity is more likely to become lower than the hardening group of the lower molecular weight monomer (B,), and thus the hardening of the monomer (B,) When it is carried out first, the viscosity of the entire composition is rapidly increased, and there is a possibility that the hardening reaction is inhomogeneous. In order to reduce the reactivity of the curable groups, the homogeneous resin layer may be obtained, and the sulfomethoxy group in the oligomer (A') is preferably a highly reactive propylene oxime group, and The curable group in the body (B.) is a non-reactive thiol acryloxy group. (The number average molecular weight of the polymer concentrating polymer (A') is preferably 〇〇〇 〇〇〇 100 〇〇 (), more preferably 10,000 〜 70,000. If the number average molecular weight of the oligomer (A,) is In the case of the film, it is easy to adjust the viscosity of the photocurable resin (four) for resin layer formation within the above range. The number average molecular weight of the oligomer (A) is measured by GPC. The number average molecular weight. In addition, in the Gpc measurement, when there is a material that is not anti-Wei 4 (single material), (4) the number average molecular weight is obtained in addition to the peak. The oligomer (A,) is used for the formation of the resin layer. The viewpoint of the curability of the photocurable resin composition, the mechanical properties of the resin layer, and the like is preferably 1. 8 to 4 hardening bases. The oligomer (A') may, for example, be a urethane-bonded urethane oligomer, a polyoxyalkylene-based poly(indenyl) acrylate, or a polyester polyol. The (meth) acrylate or the like is preferably an amine phthalate oligomer according to the molecular design of the urethane chain, etc., from the viewpoint of broadly adjusting the mechanical properties of the resin after curing and the adhesion to the surface material. (A2). The amine phthalate oligomer (A2) is preferably obtained by reacting a polyol with a polyisocyanate to obtain a prepolymer having an isocyanate group, and then reacting the isocyanate group of the prepolymer with the monomer (B2). The method of reaction is synthesized. The polyol and the polyisocyanate are intended to belong to a known compound, for example, a polyol (i) or a diisocyanate which is a raw material of the urethane-based oligomer (a) described in the pamphlet of International Publication No. 2009/016943 (for example). Ii), etc., are included in this specification. The urethane oligomer (A2) may also be a commercially available product, for example, EB230 (manufactured by DAICEL-CYTEC Co., Ltd., which is believed to be a reaction group 2, a polypropylene glycol/IPDI/-2-hydroxyethylhexyl acrylate reaction). , U-200AX (manufactured by Shin-Nakamura Chemical Co., Ltd., believed to be a functional group of 2, aliphatic polyester polyol / 30 201210812 aliphatic or alicyclic polyisocyanate / 2 - hydroxyethyl hexyl acrylate) ). The content ratio of the oligomer (A') is in the total of the curable compound (η) (1 〇〇 mass / 〇), that is, the total of the oligomer (A') and the monomer (B,) (100% by mass) It is preferably 20 to 90% by mass, more preferably 30 to 80% by mass. If the proportion of the oligomer (A) is 20% by mass or more, the heat resistance of the resin layer is good. When the ratio of (A) is 9% by mass or less, the curability of the photocurable resin composition for forming a resin layer and the adhesion between the surface material and the resin layer are good. (Monomer (B')) Monomer ( The molecular weight of B') is preferably from 125 to 600, more preferably from 14 to 4%. When the molecular weight of the monomer (B") is 125 or more, when the display device is manufactured according to the reduced pressure lamination method described later, When the molecular weight of the monomer (B,) is 600 or less, the adhesion between the surface material and the resin layer is good. The monomer (B) is a photocurable resin composition for forming a resin layer. From the viewpoints of the curability and the mechanical properties of the resin layer, it is preferably one to three hardening groups per molecule. The content ratio of the monomer (B1) is in the curable compound (η) (% by mass), that is, the total of the polymer (A,) and the monomer (B,) (1% by mass), preferably 10 to 80% by mass, more preferably 20 to 70% by mass. The monomer (B') preferably contains a monomer having a curable group and having a hydroxyl group (B3). The monomer (B3) contributes to the stabilization of the non-curable oligomer (D). By containing the monomer (B3), good adhesion between the face material and the resin layer can be easily obtained. The number of hydroxyl groups in the monomer of the monomer (7)" can be arbitrarily selected to enable the non-hardening oligomer (D) In view of the fact that the number of the monomers is stabilized, it is preferably 1 to 2 in one molecule. The monomer (B3) having a hydroxyl group is, for example, a photocurable resin for forming a sealing portion. The monomer (B3) in the composition is the same, preferably 2-hydroxybutyl methacrylate. The content ratio of the monomer (B3) is in the entire curable compound (I) (1% by mass) That is, in the total (1% by mass) of the polymer (A·) and the monomer (B′), it is preferably 10 to 60% by mass, more preferably 20 to 50% by mass. If the monomer (B3) The content of the product is 10% by mass or more, The effect of improving the stability of the photocurable resin composition for forming a resin layer and the Φ contact property between the surface material and the resin layer can be easily obtained. The content ratio of the right monomer (B3) is 6 〇 mass% or less. The hardness of the cured product composed of the photocurable resin composition for forming a resin layer is not excessively high, and is preferable. The monomer (B') is preferably a mechanical property of the resin layer. The monomer (B4) is contained. Since the monomer (B4) lowers the glass transition temperature (Tg) of the resin layer after hardening, it contributes to a decrease in the elastic modulus of the resin layer after hardening, and the resin can be improved. The softness of the layer. However, when the curing property of the photocurable resin composition for forming a resin layer is increased and the time required for curing is shortened, it is preferable to reduce the content of the monomer (B4) or not. Monomer (B4): one or more selected from the group consisting of alkyl methacrylates having a carbon number of 8 to 22. If the carbon number is 8 or more, the glass transition temperature of the cured product can be lowered, which is preferable. If the carbon number is below 22, the viewpoint that the alcohol of the raw material can be easily obtained through the sky is comparable. good. 32 201210812 The monomer (B4) may, for example, be n-dodecyl methacrylate, n-octadecyl methacrylate or n-decyl methacrylate, and is preferably methacrylic acid. Dodecyl ester, or n-octadecyl methacrylate. The content ratio of the monomer (B4) is preferably (100% by mass) of the entire curable compound (II), that is, the total amount (% by mass) of the oligomer (A') and the monomer (B), preferably 5 to 50% by mass, more preferably 15 to 4% by mass. /. . When the content of the monomer (7) is 5% by mass or more, the sufficient addition effect of the monomer (B4) can be easily obtained (photopolymerization initiator (C2)). The resin composition for forming a resin layer is used in the photocurable resin composition. The photopolymerization initiator (C2) to be contained may, for example, be an acetophenone system, a ketal system, a benzoin or a benzoin ether system, a phosphine oxide system, a diphenyl ketone system or a thioxanthene group. A photopolymerization initiator such as a phthalocyanine-based or fluorene-based photopolymerization initiator is preferably a phosphine oxide-based photopolymerization initiator, and is preferably a phosphine oxide-based photopolymerization initiator. The content of the photopolymerization initiator (C2) in the photocurable resin composition for forming a resin layer is the total amount of the oligomer (a,) and the monomer (B') with respect to the entire curable compound (11). 100 parts by mass, preferably 0. 01 to 10 parts by mass, more preferably 0. 1 to 5 parts by mass. When a part of the photocurable resin composition for forming a resin layer adjacent to the sealing material is hardened by light irradiated from the side of the face material, the photopolymerization initiator (C2) preferably has a The absorption wavelength region (1)) of the photopolymerization initiator has an absorption wavelength region (again 2) on the longer wavelength side. The photopolymerization initiator (C2) may have only an absorption wavelength region (also 2) 33 201210812, and may also have an absorption wavelength region (λι,) and an absorption wavelength region (λ2) which are repeated with the absorption wavelength region U 1). . (Non-curing oligomer (D)) The non-curable oligomer (D) is excellent in compatibility with the photocurable resin composition for forming a resin layer and does not contribute to hardening, so that it can be prevented from being damaged. In the case of transparency and homogeneity, the stress generated by shrinkage at the time of hardening of the layer is reduced. When the non-curable oligomer is cured by the photocurable resin composition for forming a resin layer, it does not undergo a curing reaction with the curable compound (11) in the composition, and has 8 to 3 hydroxyl groups per molecule. Oligomer. Preferably, the number of hydroxyl groups per molecule is 2 to 3. If the hydroxyl group per molecule is up to 〇. 8 or more, between the non-curable polymer, or between the non-curable oligomer and the cured product obtained from the curable compound (II), the non-hardening property can be stably maintained by the interaction between the hydroxyl groups. The viewpoint of the oligomer is preferable, and when the number of hydroxyl groups per molecule is three or less, the non-curable oligomer can be suitably dissolved in the photocurable resin composition for forming a resin layer. The system is preferred. The number average molecular weight (?n) of the average of one hydroxyl group of the non-curable oligomer (D) is preferably from 400 to 8,000. When the number average molecular weight of the average number of hydroxyl groups is 400 or more, the polarity of the non-curable oligomer (D) does not become too high, and the curability in the photocurable resin composition for forming a resin layer can be easily obtained. Good compatibility between the compounds (II). When the number average molecular weight of one hydroxyl group is 8000 or less, the interaction between the hydroxyl group derived from the curable compound (π) and the hydroxyl group of the non-curable oligomer (D) can be easily obtained after hardening. The effect of making the non-hardening oligomer (D) stable in the resin layer 34 201210812. The interaction is speculated to involve hydrogen bonding. Non-hardening oligomerization can be used alone or in combination of two or more. Examples of the non-curable oligomer (D) having a t-based group include, for example, a small amount (10) in a polymer, preferably a polyoxyl extension-based polyol, (IV) a polyol, or a polycarbonate polyol. . The polyoxyl extender-based polyol may, for example, be an oxygen-extended repeating single-extracted polyoxyalkylene monool, a polyoxy(tetra) diol or a polyoxyalkylene diol having a carbon number of 2 to 4. Specific shots are, for example, polyoxyl-propanol monool, polyoxyethylene-alcohol, polyoxypropylene propylene glycol (hereinafter also referred to as "polypropylene glycol"), polyoxypropylene glycerol, polyoxytetradecyl sulfhydryl Glycol and the like. The number average molecular weight (?n) of the average hydroxyl group of the polyoxyalkylene polyol is preferably 4 Å to 8 Å, more preferably 6 Å to 5 Å (9). The polyhydric polyol may, for example, have an aliphatic diol residue such as ethylene glycol, propylene glycol or butyl alcohol, and an aliphatic di(tetra) residue such as glutaric acid, adipic acid or sebacic acid. The aliphatic polyglycol diol.匕Polycarbonate S is a multi-component energy consumption, for example: M•二二料 diol residue of ruthenium aliphatic poly (tetra) diol; or aliphatic cyclic carbonic acid (IV) ring-opening polymer special aliphatic polycarbonate 2 alcohol. And the average molecular weight (?n) of the average number of hydroxyl groups of the ester polyol or the polycarbonate polyol is preferably from 400 to 8000', more preferably from 8 to 6 Å. In the present specification, the number average molecular weight of the non-curable oligomer (D) is a value Α (κ〇Η mg/g) measured according to JIS K1557-1 (20〇7 edition), and non-hardening oligomerization. The number of hydroxyl groups in the molecule (0) 1 is calculated according to the formula of the following 35 201210812 formula u). Molecular weight of the non-curable emulsion (D) = 56 1xBx1 〇〇〇 / a (1) From the viewpoint that the elastic modulus of the resin layer after hardening is likely to be lower, the non-hardening oligo (4) (D) is higher than (4) The oxyperkiol polyol is more preferably a polyoxypropylidene polyol. As described later, in order to adjust the polarity of the non-curable oligomer (9), a part of the oxygen-extended propyl group of the polyoxy-extension propylene polyol may be substituted with an oxygen-extended ethyl group. The oxygen-extended propyl group may also be partially substituted with an oxygen-extended ethyl group, which is the same as described above for the plural. For example, from the viewpoint of compatibility, an oligomer (A) is preferably an amine phthalate oligomer synthesized by using a polyoxyalkylene polyol and a polyisocyanate as a raw material, instead of a curable oligomer. (D) is a polyoxyalkylene polyol. In the present invention, in order to stabilize the photocurable resin composition for forming a resin layer when it is not cured, it is preferable to suppress the non-curable oligomer (D) from being cut away from the hardened layer of the tree layer. The polymer (A') has a molecular bond of the same structure or a similar structure as the non-curable oligomer (〇). Specifically, in the case of forming the oligomer (A·) in the photocurable resin composition of the synthetic resin layer, it is preferred to use a compound having a hydroxyl group such as a polyhydric alcohol (hereinafter also referred to as "containing a radical". Compound "), and the same trans-containing compound is used as the non-curable oligomer (D). For example, when the oligomer (A') is a urethane oligomer synthesized using a polyoxyalkylene polyol and a polyisocyanate as a raw material, it is preferred to use the polyoxyalkylene polyol as Non-hardening oligomer (D). Or, when the hydroxyl group-containing compound used as the raw material of the oligomer (A') and the hydroxyl group-containing compound used as the non-curable oligomer (D) are not the same, it is preferable that the two molecules are The chain has a common repeating unit or the like, and the partiality has a common structure' and the polarities of the two are set to the same extent. The method of adjusting the polarity is, for example, a method of increasing the enthalpy by introducing a sulfhydryl group, by stretching the propyl group by oxygen. The p-knife is a method of increasing the polarity by substitution with an oxygen-extended ethyl group, and a method of increasing the polarity by the molecular weight of the lower-lying group. These methods can also be used in combination. For example, the valence polymer (A) is a polyoxyl propyl poly(tetra) (a), which is substituted with an oxygen-extended ethyl group, and a poly-isocyanate, which is synthesized by using a raw material. In the case of the filaria, it is preferred to use a polyoxy-extension propylene polyol having no oxygen-extended ethyl group as the non-curable polymer (D), and the average molecular weight of one base is 切_(a,) The wire stretches propyl polyol. The photocurable resin composition for forming an optimum resin layer is exemplified by a composition of the following oligomer (A·), non-curable oligomer (D), and body (Β·). The polymer (Α,) is a polyoxypropyl propylene glycol in which a part of the oxygen-extended propyl group has been substituted with an oxygen-extended ethyl group, and reacted with a polyisocyanate compound to obtain a prepolymer having an isocyanate group, and The monomer (Β2) is reacted to obtain an amine formate oligomer (Α2); the non-hardening oligomer (D) is the same as the raw material of the urethane oligomer (Α2), and the oxygen is extended to C A polyoxyalkylene propylene glycol in which a part of the base has been substituted with an oxygen-extended ethyl group; and the monomer (Β') is a monomer having a hydroxyl group (Β3). According to this, if the oligomer (Α') partially has the same molecular structure as the non-curable oligomer (D), the compatibility of the non-hardening oligomer (D) in the composition can be further improved. Further, by the hydroxyl group of the monomer (Βι), the interaction between the hydroxyl group in the molecular structure of the hardened 37 201210812 compound (II) and the hydroxyl group in the molecular structure of the non-hardening oligomer (D) is judged. The non-hardening oligomer (D) can be stably present in the hardened material. Further, in other examples, a composition containing the oligomer, the non-curable oligomer (D), and the monomer (B') may be used to obtain a non-hardening oligomer in the composition (D). ) is in good compatibility' and allows the non-hardening oligomer (D) to be stably present in the hardened material. The oligomer (A,) is obtained by reacting a polyoxypropyl propylene glycol having a part of an oxygen-extended propyl group with an oxygen-extended ethyl group, and reacting with a polyisocyanate compound to obtain a pre-isocyanate group. An amine phthalate oligomer (A2) obtained by reacting with the aforementioned monomer (B2); the non-hardening oligomer is a polyoxypropylene propylene glycol which is not substituted with an oxygen-extended ethyl group. 'The polyoxypropyl propylene glycol having a molecular weight smaller than the raw material of the urethane acrylate oligomer (A2); and the monomer (B,) is a monomer (B3) having a hydroxyl group. The content of the non-curable oligomer (D) in the photocurable resin composition for forming a fat layer is preferably from 1 to 9 % by mass, more preferably from 3 to 8 % by mass. When the content of the right non-hardening oligomer is 10% by mass or more, the effect of reducing the stress generated by the shrinkage of the resin during hardening can be easily obtained by filling. If it is 90% by mass or less, the face materials can be easily fixed to each other sufficiently, and the temporal positional displacement of the surface material and the back material can be easily and satisfactorily prevented. In the resin layer viscoelasticity measurement after the resin layer forming photocurable resin composition is cured, the storage shear modulus is preferably 5χ1〇2 to lxl〇5pa, more preferably 8x1〇2 to 5xl〇. 4pa, especially good for 1x10~5xl〇4pa. Also, the loss tangent (tan (5) is preferably 1. 4 or less, better 38 201210812 Series 1. 0 or less. The lower limit of the loss tangent is not particularly limited, and can be set to a range that can be achieved in a manufacturing process. When it is a soft resin layer, it is usually 达. 〇 1 or more. Rhyme shear elastic bond and loss tangent (four) method, as detailed later, using a dynamic (four) measuring device to form a photohardenable resin composition for the unhardened tree layer, applying dynamic shear stress And / or a method of hardening the resin composition to harden the resin composition. If the shear modulus after hardening is 1 x l 〇 5 Pa or less, the stress caused by shrinkage of the resin during hardening can be sufficiently reduced, and the influence on the display quality of the display panel can be suppressed. If the shear modulus is up to Μ. More than %, the face material (display element and transparent face material) can be well fixed. Also, if the loss is tangent at 1. 4 or less, even when the display device is used vertically, the display element can be sufficiently fixed to the transparent surface material, and the display element can be prevented from occurring due to plastic deformation of the resin layer due to the own weight of the display element. Position offset. When the photocurable resin composition for forming a resin layer contains non-hardening, the [raw oligomer (D)' can cut the material under the condition that the resin layer loss tangent (1) after the hardening is suppressed The elastic modulus is reduced, so that the respective preferred ranges of storage shear modulus and loss tangent (taM) in the dynamic viscoelasticity measurement can be achieved. (Additive) The photocurable resin composition for forming a resin layer may contain, for example, a polymerization terminator, a photohardening accelerator, a chain transfer agent, a light stabilizer (such as an ultraviolet absorber, a self-based capture agent, etc.). ), an antioxidant, a flame retardant, an adhesion promoter (such as Wei coupling), a pigment, a dye, and the like, each of which has a polymerization terminator or a photoinhibitor. In particular, by using a small amount of a polymerization terminator which is more than a polymerization initiator, it is possible to improve the hardness of the resin layer-shaped fine-light hard-recording group, and also the molecular weight of the resin layer after the hardening. By making a small amount of the chain transfer agent contained, the molecular weight of the resin layer after hardening can be adjusted to decrease the thickness of the resin layer, but in many cases, the hardening rate is slowed down. The photocurable resin composition for forming a resin layer containing a large amount of the non-curable oligomer (D) of the present invention, since the elastic modulus can be adjusted by the content of the oligomer (9), the content of the chain transfer agent can be reduced, or Not included is preferred. Specifically, the amount of the chain transfer agent added is preferably in the range of i parts by mass or less based on 100 parts by mass of the total of the oligomer (A) and the monomer (B'). Better system 0. 5 parts by mass or less. [Step (4)] After the step (b), the first surface material to which the photocurable tree-forming composition for resin layer formation is supplied is placed in a decompression device, and the support plate is fixed in the decompression device. The first face material is placed flat on the side of the curable resin composition. A moving support mechanism that is movable in the vertical direction is provided in an upper portion of the decompression device, and a second surface material is attached to the movable support mechanism. When the second face material is the display element, the surface on the side where the image is displayed faces downward. When the antireflection layer is provided on the surface of the second face material, the surface on which one side of the antireflection layer is not formed faces downward. The second face material is placed above the first face material and is not formed with the resin layer. 40 201210812 The position where the photocurable resin composition is in contact with each other. In other words, the photocurable resin composition for forming a resin layer on the first surface material is opposed to the second surface material without coming into contact with each other. Further, a moving support mechanism that moves in the vertical direction may be provided in a lower portion of the decompression device, and a first face material to which a curable resin composition is supplied may be placed on the moving support mechanism. In this case, the second surface material is attached to the fixed support disk provided on the upper portion of the pressure reducing device, and the first surface material and the second surface material face each other. Further, both the first face material and the second face material may be supported by the upper and lower movement supporting mechanisms provided in the decompression device. After the first face material and the second face material are placed at a predetermined position, the inside of the reduced pressure device is decompressed to form a predetermined reduced pressure environment. If possible, the first face material and the second face material may be placed at a predetermined position in the pressure reducing device after the pressure reduction operation or after the predetermined pressure reduction environment is formed. After the inside of the decompression device is in a predetermined decompression environment, the second face material of the building supported by the shifting and lowering mechanism is moved downward, and the second face material is superposed on the resin layer forming light on the & face material. Above the curable resin composition. By overlapping, the surface of the second surface material (the surface of the second surface material displayed on the display element @ image) (the surface on the side where the image is displayed as the display element) and the uncured surface are not hardened. In the work chamber surrounded by the sealing portion: 'The photocurable composition of the resin layer is sealed. When the overlap is performed, the resin layer is formed by the self weight of the second face material, the press from the moving support mechanism, or the like. The curable resin composition is pushed and expanded to fill the space with the resin layer (4) with the photocurable resin 41 201210812 composition, and then when exposed to a high pressure environment in step (d), bubbles are formed less or The resin layer having no bubbles forms a layer of the photocurable resin composition. The pressure reduction environment at the time of superposition is 100 Pa or less, preferably 101 V or more. If the decompression environment is too low pressure, there will be a resin layer. It is possible to form an adverse effect on each component (such as a curable compound, a photopolymerization initiator, a polymerization terminator, a light stabilizer, etc.) contained in the photocurable resin composition. For example, if the decompression environment belongs to If the pressure is too low, the components may be vaporized, and it takes time to provide a reduced pressure environment. The pressure in the reduced pressure environment is preferably 15 to 40 Pa. From the first surface material to the second surface material. The time until the time when the pressure-reducing environment is released is not particularly limited, and after the resin layer-forming photocurable resin composition is sealed, the pressure-reducing environment can be immediately released, and the resin layer can be cured by light. After the resin composition is sealed, the reduced pressure state is maintained for a predetermined period of time, and the photocurable resin composition for resin layer formation flows in the sealed space by the reduced pressure for a predetermined period of time, and the second surface material and the second surface material are The interval between the face materials is uniform, and the temperature can be easily maintained and sealed even if the environmental pressure is increased. The time for maintaining the reduced pressure state can be a production time with a long time of several hours or more, preferably within one hour or less. In the manufacturing method of the present embodiment, when the photocurable resin composition for forming a sealing portion having a high degree of application is applied to form an uncured sealing portion, the step (c) can be used. The resin layer of the laminated precursor is formed into a thicker impurity having a thickness of 1 mm as a photocurable sapphire composition. 42 201210812 [Step (d)] In step (c), the decompression environment is released. After that, the laminated precursor is placed in a pressure environment with an ambient pressure of 50 kPa or more. If the laminated precursor is placed in a pressure environment of 50 kPa or more, the first surface material and the second surface material are conveniently raised toward each other. When the airtight resin composition for resin layer formation flows in the air bubbles, the entire sealed space is formed by the resin layer, so that there is a bubble in the sealed space in the laminated precursor. The photocurable resin composition is uniformly filled. The pressure environment is usually 80 kPa to 120 kPa, and the pressure environment may be atmospheric pressure or higher. The hardening of the photocurable resin composition yarn for resin layer formation can be carried out in the case where the apparatus is not required, and it is preferably an atmospheric pressure environment. There is no particular limitation on the temple door (hereinafter referred to as "Southern pressure holding time") when the resin layer-shaped fine-graded resin composition starts to harden from the time when the laminated precursor is placed in a pressure of 50 kPa or more. . When the layered month J body is taken out from the decompression device and moved to the hardening device until the t-step is started in the atmospheric pressure environment, the process is required to become the sewing time. Therefore, when placed under the atmosphere of the atmosphere, there is no bubble in the confined space of the laminated precursor' or during the process; in the case of Xiao (4), the photohardenability of the formation of the marshallic layer The resin composition is hardened. When the gas is accumulated for a period of time, the layer is maintained in the dynamic environment above (four) until the bubble disappears. Moreover, even if the pressure holding time is prolonged, it usually does not constitute an obstacle. Therefore, the other necessity in the process of 201210812 can be extended, and the high-pressure holding time can be extended for a long period of time or more, but From the viewpoint of production efficiency, it is preferably within 6 hours, and more preferably within 1 hour, in terms of improving production efficiency, particularly preferably within 10 minutes. Then, the layered precursor is placed in a pressure environment of 5 kPa or more, and the resin layer forming photocurable resin composition is cured to form a resin layer for bonding the display element and the protective sheet. In the display device, the photocurable resin composition for forming a resin layer and the photocurable resin composition for forming a sealing portion are irradiated with light to be cured. For example, a light source (such as an ultraviolet lamp, a high pressure mercury lamp, a black lamp, a chemical lamp, a UV lamp, or the like) is irradiated with ultraviolet rays or short-wavelength visible light to harden the photocurable resin composition. In addition, the uncured seal portion formed of the photocurable resin composition by the sealing portion is formed at the same time, and can be cured simultaneously with curing of the photocurable resin composition for forming a resin layer, or can be formed in the resin layer. The hardening resin composition is pre-hardened before being hardened. In addition, when a part of the transparent surface material is formed with a light-shielding printing portion and is held by the light-shielding printing portion to form a sealing portion, the use of the transparent surface material is performed when the resin layer forming photocurable resin composition is cured. It is difficult to harden the sealing portion by the light in the light transmitting portion, and the sealing portion can be cured only after the resin layer forming photocurable resin composition is cured. For example, from the side of the first surface material and the second surface material of the laminated precursor having light permeability, the light-curable resin composition for forming a resin layer is irradiated with light, and from the side of the laminated precursor, The uncured seal portion of the 201210812 and the graded resin composition for forming a resin layer are sandwiched between the light-shielding portion and the display element, and light irradiation is performed. In the first surface material and the second surface material, since the display element does not have light transmittance without being activated, light is irradiated from the side of the transparent surface material serving as the protective plate through the light transmitting portion. Further, when the light-shielding printing portion is provided in the peripheral portion of the transparent surface material, the portion which is held by the light-shielding printing portion and the display element has an unhardened seal. The photocurable resin composition for p or the formation of the correcting layer is not sufficiently cured by the light from the light transmitting portion of the transparent surface material. Therefore, light irradiation is performed from the side of the display element. The light is preferably ultraviolet light or visible light of 45 Å or less. In particular, when the transparent surface material is provided with an anti-reflection layer, and the anti-reflection layer or the moon-reflecting layer which has formed the anti-reflection layer, or an ultraviolet layer such as an adhesive layer between the anti-reflection film and the transparent surface material In the case of impenetrable, it is necessary to use visible light for hardening. A light source used for light irradiation from the side may be a light source used when light is irradiated from the side of the transparent surface material, but it is preferable from the viewpoint of the arrangement space of the light source and the efficient light irradiation applied to a specific place. It is an ultraviolet ray or a lED which emits visible light of 450 nm or less. The step of irradiating light may be performed by irradiating light from the side of the transparent surface material, and then irradiating light from the side, or vice versa, or simultaneously performing light irradiation, so as to further promote the uncured seal portion and the resin layer of the light-shielding printing portion. In the photocuring of the photocurable resin composition, it is preferred to perform light irradiation from the side or light irradiation from the side of the transparent surface material simultaneously with the side. In addition, when the photocurable resin composition for forming a resin layer is cured, or the curing time of the photocurable resin composition is required, the resin layer may be formed in the resin layer. After the hardening of the photocurable resin composition is substantially completed, the sealing portion is cured by irradiation with light from the side. [Specific Example] In the production method of the present embodiment, the ith surface material can be arbitrarily used as a back material or a surface material. Therefore, the display device can be manufactured in accordance with the following two methods in accordance with the selection of the second surface material. (α-l) The first surface material is a display element (back surface material), and the second surface material is a method of using a transparent surface material (surface material) as a protective sheet. U-2) The first surface material is a transparent surface material (surface material) used as a protective sheet. The second surface material is a method using a display element (back surface material). In the following, the case of the method U-1 is taken as an example, and the manufacturing method of the display device of the figure is specifically described using the drawings. (Step (a)) As shown in Figs. 3 and 4, the photocuring property of the sealing portion is formed by a dispenser (not shown) or the like along the peripheral edge portion of the display element 5 (the i-surface material). The resin composition forms an uncured seal portion 12. An arrangement such as an electric letter FPC for transmitting the display element is provided on the outer peripheral portion of the display element. In the manufacturing method of the fourth embodiment, when the respective faces (4) are held, it is preferable to use the display element as the first face material and to arrange it on the lower side. (Step (b)) Next, as shown in Fig. 5 and Fig. 6, the resin layer forming photocurable resin composition is supplied to the rectangular region 13 surrounded by the unsealed 46 201210812 sealing portion 12 of the display element. 14. The supply of the resin layer-forming photocurable resin composition 14 is a space in which the unhardened sealing portion 12 and the display element and the transparent surface material 10 (see Fig. 7) are sealed, and the resin layer can be used. The amount filled with the photocurable resin composition 14 is formed. The supply layer of the resin layer-forming photocurable resin composition 14 is as shown in Fig. 5 and Fig. 6 'The display element 50 is placed flat on the lower fixed plate 18, and is linearly formed by the dispenser 20 moving in the horizontal direction. The strip-shaped or dot-shaped supply resin layer forming photocurable resin composition 14 is used. The dispenser 20 is horizontally movable over the entire range of the region 13 by a known horizontal movement mechanism including a pair of guide screws 22 and a guide screw 24 orthogonal to the guide screw 22. Alternatively, instead of the dispenser 2, a mold coater can be used instead. (Step (c)) Next, as shown in Fig. 7, the display element 5A and the transparent surface material 1 (the second surface material) are carried into the decompression device 26. In the upper portion of the decompression device 26, a top plate 3A having a plurality of adsorption pads 32 is disposed, and a lower plate 31 is disposed at a lower portion. The upper plate 30 is movable in the vertical direction by the air cylinder 34. The transparent face material 10 is mounted on the adsorption pad 32. The display element 50 is fixed to the lower fixed plate 31 with the surface of the resin layer-forming photocurable resin composition 14 facing upward. Next, the air in the decompression device 26 is sucked by the vacuum pump 28. After the ambient pressure in the decompression device 26 reaches the decompression environment of, for example, i5 to 4 〇pa, the transparent surface material 1 进行 is held by the adsorption 32 of the upper plate and held in the state of the adsorption of 2012 20121212, and is directed downward. The standby display element 50' causes the cylinder 34 to start and descend. Then, the display element 50 and the transparent surface material 10 are overlapped with each other via the unhardened sealing portion 12 to form a laminated precursor ', and the laminated precursor is held for a predetermined period of time under a reduced pressure environment. In addition, the mounting position of the display element 50 to the lower fixed plate 31, the number of the adsorption pads 32, and the mounting position of the transparent surface material 10 to the upper fixed plate 30, etc., match the size and shape of the display element 50 and the transparent surface material 1〇. Wait and adjust accordingly. In this case, the electrostatic chuck is used in the adsorption pad, and the glass substrate can be stably maintained in a reduced pressure environment by the electrostatic chuck holding method described in the specification attached to Japanese Patent Application No. 2008-206124 (incorporating this specification). (Step (d)) Next, after the inside of the decompression device 26 is formed, for example, at atmospheric pressure, the laminated precursor is taken out from the decompression device 26. When the laminated precursor is placed in an atmospheric pressure environment, the surface on the display element 50 side of the laminated precursor and the surface on the side of the transparent surface material 1 are conveniently pressed by atmospheric pressure, and the resin layer in the sealed space is formed with light. The curable resin composition 14 is pressurized by the display element 50 and the transparent face material 10. By this pressure, the resin layer forming photocurable resin composition I4 flows in the sealed space, and the entire sealed space is uniformly filled with the resin layer forming photocurable resin composition M. The chest is then placed on the transparent surface material & the light-shielding printing portion 'when the uncured seal portion held by the light-shielding stamp and the tree-shaped layer are formed with the photocurable resin side: when it is hardened first, as shown in Fig. 8 The photocurable resin conjugate 14' of the uncured seal layer formed by the side light-printing portion 55 of the laminated precursor and the display element 5g covers the display element 48 201210812 Irradiation with visible light of 450 nm or less and irradiation of light (ultraviolet rays or visible light of 450 nm or less) to the resin layer forming photocurable resin composition 14 from the side of the transparent surface material 10 through the light transmitting portion 56 The unhardened sealing portion 12 and the resin layer in the laminated precursor are cured by the photocurable resin composition 14, and the display device i is obtained. When the light-shielding printing portion is not provided on the transparent surface material, the laminated precursor is entirely irradiated with light from the side of the transparent surface material 10, and the uncured sealing portion 12 and the resin layer are formed in the laminated precursor. The photocurable resin composition 14 is cured to obtain a display device 1. In the case of the above-described method (a _ 1), the method of manufacturing the display device of the present embodiment will be specifically described. In the case of the other method (α _2), the display device can be manufactured in the same manner. [Operation and Effect: Manufacturing Method of Display Device] According to the method of manufacturing the display device of the present embodiment described above, it is possible to manufacture a large-area display device without generating bubbles in the resin layer. It is assumed that air bubbles remain in the photocurable resin composition for forming a resin layer which is sealed under reduced pressure, and the pressure is applied to the photocurable resin composition for forming a resin layer which is sealed under a high pressure environment before curing. The volume of the bubble can be reduced, and the bubble can be easily eliminated. For example, in the photocurable resin composition for forming a resin layer which has been sealed at 100 Pa, the volume of gas in the bubble can be considered to be 1/1000 at 100 kPa. Since the gas is dissolved in the photocurable resin composition for forming a resin layer, the gas in the fine volume bubbles is quickly dissolved in the resin layer forming photocurable resin composition and disappears. In addition, even if a pressure such as an atmospheric pressure is applied to the resin layer forming photocurable resin composition after sealing, the liquid resin composition for forming a liquid resin layer is a fluid composition, and thus the pressure system is used. Evenly distributed on the surface of the display element does not exert a stress on a part of the surface of the display element which is in contact with the resin layer forming photocurable resin composition, and the damage to the display element is low. Further, the interfacial adhesion between the resin layer formed by curing the resin layer-forming photocurable resin composition and the display element and the transparent surface material is in contact with the interface adhesion force by thermal fusion. In addition, the photocurable resin layer-forming photocurable resin composition is pressed and adhered to the surface of the display element or the transparent surface material, and is cured in this state, so that a higher interfacial adhesion force can be obtained and It is rare to obtain a uniform surface of the display element and the transparent face material, followed by a decrease in the locality of the interface. Therefore, there is a low possibility that peeling occurs on the surface of the resin layer, and there is a low possibility that water or corrosive gas is infiltrated from a portion where the boundary adhesion is insufficient. In addition, a method of injecting a photocurable resin composition into a fluid resin layer in a narrow and wide area between two sheets of materials (injection method) produces less bubbles and can be filled in a short time. A photocurable resin composition for forming a resin layer. Further, the photocurable resin composition for forming a resin layer has a small viscosity limitation, and the photocurable resin composition for forming a resin layer having a high viscosity can be easily filled. Therefore, a photocurable resin composition for forming a high-viscosity resin layer containing a high molecular weight curable compound capable of increasing the strength of the resin layer can be used. 50 201210812 Further, the photopolymerization initiator (C2) of the photocurable resin composition for resin layer formation uses a photopolymerization initiator (C1) having an absorption wavelength region (λ2) which is smaller than the uncured seal portion. The absorption wavelength region (λ1) is further on the long wavelength side of the photopolymerization initiator (C2), and the light irradiated from the side of the layered precursor is wavelength light in the absorption wavelength region (λ1). Both the wavelength light in the absorption wavelength region (λ2) can be used to make the absorption wavelength region which is not absorbed by the photopolymerization initiator (C1) of the uncured seal portion When the photocurable resin composition for forming a resin layer which is sandwiched by the display element in the light-shielding portion is reached, the photopolymerization initiator (C2) having the absorption wavelength region (λ2) is used to sufficiently perform the light for forming the resin layer. Hardening of the curable resin composition. [Operation: Hardening Resin Composition] The bonding between the display element and the transparent surface material can reduce the shrinkage factor at the time of curing the curable resin or reduce the elastic modulus of the resin layer after curing. The applied stress ' effectively prevents the occurrence of display spots and the like from damaging the display quality. However, if the molecular weight per hardened portion of the curable compound is increased to reduce the shrinkage at the time of curing, the viscosity of the curable compound becomes large, and the uniform supply of the surface of the surface of the curable resin composition tends to be difficult. There is a possibility that the hardening reaction at the time of hardening is uneven. In addition, when the non-hardening component which does not contribute to hardening is contained in order to reduce the elastic modulus of the resin layer after hardening, the compatibility of the curable resin composition may fall, and it may damage. The transparency of the cured resin composition or the adhesion between the resin layer and the surface of the surface after hardening is lowered, and there is a possibility that the surface material and the back material may be peeled off over time. On the other hand, the curable resin composition of the present invention contains, in particular, 10 to 90% by mass of a non-curable oligomer having 8 to 3 hydroxyl groups per molecule, which does not form a resin layer during curing. When the curable compound (II) in the photocurable resin composition is subjected to a non-hardening component which is subjected to a curing reaction, and the curable compound (II) is present, a hydroxyl group which does not react during curing is present, whereby The photocurable resin composition for forming a resin layer when not cured is excellent in stability, and the viscosity can be lowered, and the curing reaction uniformity at the time of curing is good, and shrinkage at the time of hardening can be reduced, and the hardening can be reduced. The modulus of elasticity of the resin. When the shrinkage at the time of hardening is lowered and the elastic modulus of the resin after hardening is lowered, the stress caused by the hardening shrinkage of the resin layer is lowered. When the photocurable resin composition for forming a resin layer is not cured, the stability of the curing reaction is good, and the resin layer having good transparency can be easily obtained. When the viscosity of the photocurable resin composition for forming a resin layer in the unhardened state is lowered, the foam can be sufficiently suppressed by (4), and a good interfacial bonding force between the face material and the resin layer can be easily obtained. In particular, when the display element is a liquid crystal display element, or even an IPS (In-plane Switching) liquid crystal display element, or an optical film attached to the display surface on the display surface (ΤΜ_价_〇) In the case of a liquid crystal display device, since the stress applied to the display element is likely to adversely affect the display quality, the bonding layer preferably has a low elastic modulus. Therefore, the display device using the curable resin composition of the present invention is used. 52 201210812 The display element is preferably a liquid crystal display element, more preferably an IPS type liquid crystal display element or a TN type liquid crystal display element. Further, the curable resin composition of the present invention is not limited to use. The same effect can be obtained by applying the same to the laminated body in which a pair of surface materials are laminated via a resin layer. Further, the curable resin composition of the present invention may be a thermosetting resin composition. In the case of the curable group of the curable compound, a known thermosetting group is used. Further, a known thermal polymerization initiator is contained as needed. In the above embodiment, 'when the resin When the curable resin composition for forming is thermosetting, it is preferable that the curable resin composition for forming a sealing portion is thermosetting. In particular, since the photocurable resin composition does not require high temperature during hardening. Therefore, the viewpoint of less adverse effects on the surface material due to high temperature is preferable. In the case of using a photopolymerization initiator and a thermal polymerization initiator, photohardening and thermal hardening can be simultaneously performed, or Further, the method of producing a laminate using the curable resin composition of the present invention is not limited to the method of the above embodiment, and a known method is suitably used. [Examples] Hereinafter, it is exemplified as Examples in which the present invention was confirmed to be effective. Examples 1 to 5, 9 and 10 are examples, and examples 6 to 8 are comparative examples. (Storage shear modulus and measurement method of loss tangent) Hardened resin Storage Shear Elastic Modulus of Layer and Loss Tangent 53 201210812 (tan (5), using a rheometer (Physica MCR301, manufactured by Anton Paar), for forming an uncured resin layer Curable resin composition sandwiched between the soda lime glass was measured with internet mandrel (Anton Paar Corporation, D-PP20 / AL / S07) between the square. In a 4 mm gap, a dynamic shear stress of 1% was applied while irradiating a light of 2 mW/cm 2 for 30 minutes with a black lamp (FLISBL manufactured by Nippon Electric Co., Ltd.) installed in a lower portion of the platform at a temperature of 35 ° C in a nitrogen atmosphere. On the other hand, the resin layer-forming photocurable resin composition was cured and measured. When the resin layer-forming photocurable resin composition is cured, the position of the mandrel is automatically tracked and adjusted so that no stress is generated in the normal direction of the mandrel. The irradiation intensity was measured on a platform having a photocurable resin composition for forming a resin layer, using an illuminometer (manufactured by USHIO Electric Co., Ltd., UV intensity meter UNIMETERUIT-101). (Quantum average molecular weight) The number average molecular weight of the polymer was determined by using a GPC apparatus (HLC-8020, manufactured by T〇s〇H Co., Ltd.). (Viscosity) The viscosity of the photocurable resin composition was measured by an E-type viscometer (manufactured by Toki Sangyo Co., Ltd., RE-85U). (Fog value) The haze value was determined by using Haze_Garcl π manufactured by Toyo Seiki Seisakusho Co., Ltd., and measuring according to ASTM D1003. [Example 1] (Display element) 54 201210812 The liquid 曰曰 display element was taken out from a commercially available 17-inch LCD monitor (V137b, manufactured by Acer Co., Ltd.). The display mode of the liquid crystal display device is TN (Twisted Nematic), and the size of the display portion is 338 mm long and 270 mm wide. On the both sides of the liquid crystal display device, a polarizing plate is bonded to one side of the long side to join six driving FPCs, and three driving FPCs are joined on one side of the short side, and the FPC end portions are joined to the long side. A printed circuit board. This liquid crystal display element is referred to as "display element A". (glass plate) will be 355mm long, 29mm wide, and 2. 8 mm soda lime glass is used as the glass plate B of the protective plate. (Photocurable resin composition for sealing portion formation) A bifunctional polym group having a molecular terminal added to ethylene oxide and having two hydroxyl groups in one molecule (the number average molecular weight calculated by (four) lan: 4000, polypropylene glycol Ethylene oxide content in the molecule is 24% by mass), mixed with hexamethylene diisocyanate S, which is 6 to 7 molar ratio, followed by isopropyl acetonide (domain organic chemical industry) After the dilution, the IBXA) is diluted in the presence of a catalyst of a tin compound, and the prepolymer is obtained in a 7th generation. And adding 2,5-di-tert-butyl hydrogen (polymerization terminator). The mixture was subjected to a reaction under a volume of 03 parts by mass, whereby a solution of §|acrylic acid condensate (hereinafter referred to as "UC-1") which was diluted with 3 Å by mass of acrylonitrile was obtained. The hardening base of UC-1 is 2, and the number average molecular weight is about 550 GG. The viscosity of the UC-1 solution at 6 (rc is about fine pa · s. 90 parts by mass of UCM solution, and thioglycolic acid _2_ via butyl vinegar (Kyoeisha 55 201210812 Chemical Co., Ltd., LIGHT ESTER® HOB) 10 parts by mass were uniformly mixed to obtain a mixture. The mixture was 丨 00 parts by mass, and 丨_hydroxy-cyclohexyl phenylene ketone (photopolymerization initiator "Ciba Specialty Chemical Co., Ltd., IRGACURE 184") was uniformly distributed in an amount of 3 parts by mass. In the state in which the photocurable resin composition C for forming a sealing portion is obtained, the photocurable resin composition C for forming a sealing portion is placed in a state in which the sealing portion is formed in a container, and the decompression device is installed in an open state. The internal pressure was reduced to about 20 Pa and held for 10 minutes to carry out a defoaming treatment. The viscosity of the photocurable resin composition C for sealing portion formation at 25 ° C was measured, and it was about 1300 Pa · s 〇 (for resin layer formation) Photocurable resin composition) A difunctional polypropylene glycol having an ethylene oxide added to a molecular end and having two hydroxyl groups in one molecule (a number average molecular weight of 4000' in a polypropylene glycol molecule calculated from a hydroxyl value Ethylene oxide content of 24% by mass), and The ketone diisocyanate is mixed at a ratio of 4 to 5 molar ratio, and reacted at 70 ° C in the presence of a catalyst of a tin compound to obtain a prepolymer in which 2-hydroxy acrylate is obtained. The ethyl ester is roughly added to a molar ratio of 1 to 2, and 2,5-di-t-butylhydroquinone (polymerization terminator) is added. The reaction was carried out at 70 ° C in 3 parts by mass of ruthenium, whereby an amine phthalate acrylate oligomer (hereinafter referred to as "UA-2") was obtained. The hardening base of UA-2 is 2, the number average molecular weight is about 24,000, and the viscosity at 25 ° C is about 830 Pa · s. 40 parts by mass of UA-2, 30 parts by mass of 2-hydroxybutyl methacrylate (LIGHTESTER® HOB, manufactured by Kyoeisha Chemical Co., Ltd.), and 30 parts by mass of n-dodecyl methacrylate were uniformly mixed. Uniformly dissolve bis(2,4,6-trimethylabendyryl)-phenylphosphine oxide in a mixture of 1 part by mass of 2012 201212. (Photopolymerization initiator, Ciba Super Chemical Co., Ltd., IRGACURE 819) 0. At 5 parts by mass, a photocurable resin composition PD for forming a resin layer was obtained. Next, 40 parts by mass of the PD meter, the same molecular end as the user of the UA-2 synthesis, was subjected to addition of ethylene oxide and a bifunctional polypropylene glycol having 2 hydroxyl groups in one molecule (calculated from the hydroxyl value). The number average molecular weight of 4000 and the ethylene oxide content of the polypropylene glycol molecule (24% by mass) were uniformly dissolved in 60 parts by mass, and the photocurable resin composition D for resin layer formation was obtained. In the state where the resin layer-forming photocurable resin composition D is placed in a container, it is placed in a decompression device in an open state, and the inside of the decompression device is decompressed to about 20 Pa for 10 minutes, thereby performing defoaming. Treatment ◎ The viscosity of the photocurable resin composition D for forming a resin layer at 25 ° C was measured, and it was 1. 3Pa · s. In addition, the photopolymerization initiator (the IRGACURE 819) used for the resin layer-forming photocurable resin composition D is a photopolymerization initiator (the aforementioned IRGACURE) used for the photocurable resin composition C for sealing portion formation. The absorption wavelength region (about 38 Å or less) of 184) has an absorption wavelength region (about 440 nm or less) on the longer wavelength side. Then, the viscoelastic property after photohardening of the photocurable resin composition D for resin layer formation was measured by using a rheometer, and as a result, the shear elastic modulus system was stored. 7xl03Pa, its loss tangent (tan5) is 0. 61. (Step (a)) Covering the entire circumference of the image display area of the display element A at a position of about 3 mm, and forming a seal portion for photocuring by means of a distribution of 57 201210812 by a width of about 1 mm and a coating thickness of about 6 mm. The resin composition c forms an uncured seal. (Step (b)) The inner region of the uncured seal portion applied to the outer periphery of the image display region of the display element A is supplied with a photocurable resin for forming a resin layer in a plurality of places so that the total mass is 38 g. Composition D. While the resin layer forming photocurable resin composition D is supplied, the shape of the unhardened sealing portion is maintained. (Step (c)) In the pressure reducing device provided with a pair of fixed lifting devices, the display element A is flat on the upper surface of the lower fixing plate in such a manner that the surface of the resin layer forming photocurable resin composition D faces upward. put. The glass plate B is placed on the lower surface of the lifting device in the decompression device so that the surface on the side on which the light-shielding printing portion is formed faces the display element A. The electrostatic chuck is used, and the glass plate B is not shielded from light when viewed from above. The light transmitting portion of the portion is held in such a manner that the light-emitting portion of the display element A has a linm margin and is located at the same position, and the distance between the display element A and the vertical direction is 3 mm. The pressure reducing device was sealed and evacuated until the pressure in the pressure reducing device became about 1 GPa. The lifting device (10) lifting device brings the upper and lower fixing plates closer to each other, and the display and the glass plate are formed with a photocurable resin composition D, which is pressure-bonded at a pressure of 2 kPa and kept for a minute. The electrostatic chuck is de-energized to leave the glass (4), and the inside of the decompression device is returned to atmospheric pressure in about 15 seconds to obtain a light hardening for resin layer formation. 201210812 The composition of the resin D has been made up of the display element A and the glass. The plate B and the unhardened sealing portion are sealed to form a laminated precursor E. The shape of the 'uncured seal portion' in the laminated precursor E is substantially maintained at the initial stage. (Step (d)) The photocurable resin composition D for forming a resin layer is uniformly irradiated with ultraviolet light from a xenon lamp and visible light of 450 nm or less from the side of the glass plate b side. The display device F is obtained by hardening, thereby forming a resin layer. The display device F has no defects such as residual bubbles in the resin layer, although it is not necessary to carry out the step of removing the bubbles required for the production by the injection method. Further, there have been no defects such as leakage of the photocurable resin composition for forming a resin layer from the sealing portion. Further, the thickness of the resin layer is the target thickness (about 0. 4mm). In place of the display element A, a glass plate having substantially the same size was used instead, and a transparent laminate was produced in the same manner, and it was determined that the haze value at the portion where the light-shielding portion was not printed was 1% or less, which was a good transparency. The display device F is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After standing for 5 days, cut in the power and connect it to the computer to display the image. The result is a uniform and good display image covering the entire display screen, and the display contrast is higher than the original state. Even if the finger is strongly pressed against the image display surface, the image is not messy, and the glass plate B effectively protects the display element A. Next, the display device F was set in the same manner, and after one month, the bonding position of the display element 05 201210812 was confirmed, and the positional shift or the like was not observed, and the glass plate was favorably held. [Example 2] (Photocurable resin composition for resin layer formation) The photocurable resin composition PD (30 parts by mass) for forming a resin layer used in Example 1 and a bifunctional group having two hydroxyl groups in one molecule The base polypropylene glycol (the number average molecular weight calculated from the hydroxyl value is 2〇〇〇, and the EO content in the polypropylene glycol is 0% by mass) is 70 parts by mass, and the photocurable resin composition D2 is formed into a resin layer. In the state in which the resin layer-forming photocurable resin composition D2 is placed in a container, it is placed in a decompression device in an open state, and the inside of the decompression device is decompressed to about 20 Pa for 1 minute, thereby performing the removal. Bubble treatment. The viscosity of the photocurable resin composition D2 formed by the moon enamel layer at 25 ° C was measured, and the result was 0. 6Pa · s. Then, the viscoelastic property after photocuring of the photocurable resin composition D2 for resin layer formation was measured by a rheometer, and as a result, the shear elastic modulus system 9x102 Pa and the loss tangent (plus §) system 84 were stored. In the same manner as in Example 1, except that the composition C' was used for the photocurable resin composition for forming a sealing portion, and the composition D2 was used for the photocurable resin fine structure, the resin layer # was the same as the example. A display device F2 is obtained. The display device F2 is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After standing for 5 days, the power was cut and connected to the computer to display the image. The result was a uniform display of 60 201210812 and a good display image, and the display contrast was higher than the original state. Even if the finger is strongly pressed against the image display surface, the image is not disturbed, and the glass plate B effectively holds the display element a. Then, the display device F2 was set in the same manner, and after one month, the bonding position of the display element was confirmed, and no positional deviation was observed, and the glass plate was favorably held. [Example 3] (Photocurable resin composition for resin layer formation) 40 parts by mass of UA-2 used in Example 1 and 2-hydroxybutyl methacrylate (LIGHT ESTER® HOB, manufactured by Kyoeisha Chemical Co., Ltd.) 30 parts by mass and 30 parts by mass of n-dodecyl methacrylate are uniformly mixed, and bis(2,4,6-trimethylbenzylidene)-phenyl oxide is uniformly dissolved in 100 parts by mass of the mixture. Phosphine (photopolymerization initiator, manufactured by Ciba Super Chemical Co., Ltd., IRGacure 819). 5 parts by mass with n-dodecyl mercaptan (chain transfer agent, Kao Corporation's THIOKALCHOL® 20) 0. The photocurable resin composition PG for forming a resin layer was obtained in an amount of 5 parts by mass. Next, '60 parts by mass of PG, which is the same as the user at the time of synthesis of UA-2, is a difunctional polypropylene glycol having an ethylene oxide added thereto and having two hydroxyl groups in the oxime molecule (the amount calculated from the hydroxyl value) The average molecular weight: 4 Å, the ethylene oxide content in the polypropylene glycol molecule is 24% by mass), and 4 parts by mass is uniformly dissolved, and the photocurable resin composition G for forming a resin layer is obtained. In the state in which the resin layer-forming photocurable resin composition G is placed in a container, it is placed in a decompression device in an open state, and the pressure in the decompression device is reduced to about 20 Pa for 1 minute, thereby performing the removal. Bubble treatment. Measured tree 201210812 The viscosity of the photocurable resin composition G for the formation of a lipid layer at 25 ° C, the result is 1. 7Pa · s. Next, the viscoelastic property after photohardening of the photocurable resin composition for forming a resin layer G was measured using a rheometer, and the shear elastic modulus system was stored. 0xl04Pa, its loss tangent (tan5) is 0. 83. In the same manner as in Example 1, except that the composition C was used for the photocurable resin composition for forming a sealing portion, and the composition G was used for the photocurable resin composition for forming a resin layer, the rest was obtained in the same manner as in Example 1. Device H. The display device is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed so that the display element 接合 bonded to the glass plate 8 is vertical. After standing for 5 days, the power is cut into the computer and connected to the computer to display the image. The result is a uniform and good display image covering the entire surface, and the display contrast is higher than the original state. Even if the finger force presses the image display surface, the image is not messy, and the glass plate B effectively protects the display element a. Then 'the same setting display device H, by! After the month, it was confirmed that the joint position of the display member was not found in the positional deviation, and was favorably held on the glass plate. [Example 4] (Photocurable resin composition for resin layer formation) - Addition of a molecular end to a double S-energetive polypropylene glycol having 2 groups in an epoxy epoxigen molecule (the average number calculated by difficulty) Molecular denier.  On the side, the content of epoxy W in the polypropylene glycol molecule is called %), and the sulphonic diisocyanate _, according to the ratio of 3 to 4, in the presence of a catalyst of tin oxide 62 201210812, 7 (TC is reacted to obtain a prepolymer, and 2-hydroxyethyl acrylate is added to a molar ratio of approximately 1 to 2 in the dimethyl prepolymer, and 2,5-di-tert-butyl hydrogen is added.醌 (polymerization terminator) 〇〇 3 parts by mass, and 7 (TC is used to carry out the reaction to obtain an amine sulphur acid (hereinafter referred to as "UA-3"). The hardening base of UA-3 Line 2, the number average molecular weight is about 21000, and the viscosity at 25 ° C is about 350 Pa.  s. 20 parts by mass of UA-3 (8 parts by mass), methyl acrylate acid 2, Ding Neng (manufactured by Kyoeisha Chemical Co., Ltd., LIGHT ESTER® HOB), and then uniformly dissolved in the mixture of the mass parts (2,4,6_trif-phenylbenzyl)' Phenylphosphine oxide (photopolymerization initiator, manufactured by Ciba Super Chemical Co., Ltd., [RGACURE 819) 0. 5 parts by mass, photohardenability and yield PI ° were obtained, followed by '30 parts by mass of PI, and 2 groups of difunctional polypropylene glycols having 1 basis group (the number average molecular weight calculated from the hydroxyl value 2_) In the case where the E0 content (% by mass) in the polypropylene glycol is 7% by mass, the photocurable resin composition for forming a resin layer is obtained. In a state in which the photocurable resin composition for forming a resin layer is placed in a container, it is placed in a decompression device in an open state, and the pressure in the decompression device is reduced to about 2 GPa and (4) 1 G minutes, thereby performing defoaming treatment. . The adhesion of the photocurable resin composition I at 25 ° C for the formation of the resin layer was determined. 0Pa · s. Next, the photo-curing resin composition I for the resin layer formation was subjected to photo-curing after the photo-hardening resin composition was used, and the storage-type modulus was obtained. 5xl04Pa ’ loss tangent (tanS) system 〇 。6. 63 201210812 In the same manner as in Example 1, except that the composition c is used for the photocurable resin composition for sealing portion formation, and the composition I is used for the photocurable resin composition for resin layer formation, the rest are the same as the example. The display device J is obtained. The display device J is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After 5 days of standing, the power was cut in, and the result was a comprehensive and uniform display image covering the display screen, and the display contrast was higher than the original state. Even if the finger is strongly pressed against the image display surface, the image will not be messy, and the glass plate B effectively protects the display element A. Then, the same setting display device J, after one month, confirms the bonding position of the display element. It was found that the positional shift or the like was well maintained on the glass plate. [Example 5] (Photocurable resin composition for resin layer formation) 20 parts by mass of PI used in Example 4 and bifunctional polypropylene glycol having 2 groups in one molecule (calculated from hydroxyl value) The number average molecular weight f 2000, the EO content in the polypropylene glycol (0% by mass), 80 parts by mass, was uniformly dissolved, and the photocurable resin composition 12 for forming a resin layer was obtained. In the state in which the resin layer-forming photocurable resin composition 12 is placed in a container, it is placed in a decompression device in an open state, and the pressure in the decompression device is reduced to about 20 Pa for 1 minute. Bubble treatment. The viscosity of the photocurable resin composition 12 for forming a resin layer at 25 ° C was measured and found to be 1 . OPa s 〇 64 201210812 Next, the rheological property of the photocurable resin composition for resin layer formation 12 after photohardening was measured using a rheometer, and as a result, the shear (four) modulus was stored. 〇xl03Pa, its loss tangent (tan§) system 〇 。7. In the same manner as in Example 1, except that the composition C' was used for the photocurable resin composition for forming a sealing portion, and the layer was formed into a layer, and the composition was used for the remainder of the money, the same was obtained as in the example. Display device J2. The display device J2 is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After standing for $曰, the power is cut into the power, and the result is a comprehensive and good display image covering the display surface, and the display contrast is higher than the original state. Even if the finger is strongly pressed against the image display surface, the image is not messy, and the glass plate B effectively protects the display element A. Next, the display device J2 is similarly set, and after one month, the position of the display element is confirmed. It was found that the positional shift or the like was well maintained on the glass plate. [Example 6] (Photocurable resin composition for resin layer formation) When the non-curable oligomer is not added to the resin composition PD used in Example 1, a photocurable resin composition for forming a resin layer is obtained. K. In the state where the resin layer-forming photocurable resin composition K is placed in a container, it is placed in a decompression device in an open state, and the inside of the decompression device is decompressed to about 20 Pa for 10 minutes, thereby performing defoaming. deal with. The viscosity of the photocurable resin composition K for forming a resin layer at 25 ° C was measured, and the result was 65 201210812. 2Pa · s 〇 Next, the viscoelastic property of the photocurable resin composition for forming a resin layer after photo-curing was measured using a rheometer, and as a result, the shear elastic modulus system was stored. In the same manner as in the first embodiment, the composition C is used for the photocurable resin composition for forming a sealing portion, and the composition K is used for the photocurable resin composition for forming a resin layer. In the same manner as in the example, the display device L is obtained. The display device L is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the display element A bonded to the glass plate B is bonded. The liquid crystal monitor is set to be vertical. After standing for $$, the power is cut into the computer, and the image is displayed on the computer. The result is a frame-shaped display spot on the peripheral portion of the display surface, especially in the halftone display. In the portion where the display spot is not present, an image with a higher contrast than that of the initial stage can be obtained. Next, the display device L is set in the same manner, and after 1 month, the joint position of the display element is confirmed, and no positional deviation is found. [Example 7] (Photocurable resin composition for resin layer formation) No non-curable oligomer was added to the resin composition pg used in Example 3. In the case where the resin layer-forming photocurable resin composition Μ is placed in a container, the pressure-reducing device is placed in a decompression device in an open state. The internal pressure was reduced to about 20 Pa and held for 1 Torr, whereby defoaming treatment was carried out. The photocurable resin composition for forming a lipid layer of 20126812 was measured at 25 ((: viscosity), and the result was 2. 1Pa · s. Next, the viscoelastic property of the photocurable resin composition for forming a resin layer after calendering was measured using a rheometer, and as a result, the shear elastic modulus was stored. 6xl05Pa, its loss tangent (tan5) system 46. In the same manner as in Example 1, except that the composition C was used for the photocurable resin composition for forming a sealing portion, and the composition Μ was used for the photocurable resin composition for forming a resin layer, the same results as in Example 1 were obtained. The apparatus returns the display device to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after reconnecting the wiring, the liquid crystal monitor is disposed such that the display element 接合 bonded to the glass plate Α is vertical. After standing for 5 days, the power was cut into the computer and displayed on the computer. As a result, a frame-like display spot appeared on the periphery of the display screen, especially when it was displayed in halftone. In the portion where the display spot is not present, an image with a higher contrast than the initial one can be obtained. Then, the display device N was set in the same manner, and after one month, the bonding position of the display element was confirmed, and no positional deviation was observed, and the glass plate was favorably held. [Example 8] (Photocurable resin composition for resin layer formation) 40 parts by mass of UA-2 used in Example 1 and 2-hydroxybutyl methacrylate (LIGHT ESTER® 制, manufactured by Kyoeisha Chemical Co., Ltd.) 〇Β) 20 parts by mass, and 40 parts by mass of n-dodecyl methacrylate are uniformly mixed, and then uniformly dissolving bis(2,4,6-trimethyl benzhydryl)benzene in 100 parts by mass of the mixture Base 67 201210812 Phosphine oxide (photopolymerization initiator - Ciba Super Chemical Co., Ltd., IRGACURE 819) 0. 3 parts by mass, and n-dodecyl mercaptan (chain transfer agent, Kao Corporation's THIOKALCHOL® 20) 1. The photocurable resin composition Ο for forming a resin layer was obtained in an amount of 5 parts by mass. In a state where the resin layer-forming photocurable resin composition is placed in a container, it is placed in a decompression device in an open state, and the inside of the decompression device is depressurized to about 20 Pa for 10 minutes, thereby performing defoaming. deal with. The viscosity of the photocurable resin composition for forming a resin layer at 25 ° C was measured, and the result was 1. 9Pa · s 〇 Next, the viscoelastic property of the photocurable resin composition for forming a resin layer after calendering is measured by a rheometer, and as a result, the shear elastic modulus system is 7-5xl 〇 3pa, and the loss tangent (tans) )1. 8. In the same manner as in Example 1, except that the composition C was used for the photocurable resin composition for forming a sealing portion, and the photocurable resin composition for forming a resin layer was used, the composition was the same as the example. Device p. The display device p is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After about an hour, it was confirmed that the joint position of several pieces was displayed. As a result, the glass plate was offset by a few mm, and the display element could not be satisfactorily held on the glass plate. Here, the display element A bonded to the glass plate B is horizontally disposed, and the power is turned on after 5 days of standing. As a result, the offset of the display element does not change, and the center portion of the display screen is available. Homogeneous and good display image, and the display contrast is higher than the original state. Even if the finger is pressed strongly, the image will not be messy, and the glass plate 8 effectively protects the display element A. [Example 9] A difunctional polypropylene glycol (a number average molecular weight 罝 5500 calculated from a hydroxyl value) having substantially no ethylene oxide added to the molecular terminal and having two hydroxyl groups in the oxime molecule, and substantially the same amount a mixture of 2,2,4 trimethyl·hexamethylenediisocyanidin 83 and 2,4,4-tridecyl-hexamethylene diisocyanate, mixed in a 1:2 molar ratio The rest were synthesized in the same manner as in the case of the urethane acrylate oligomer (UA_4). The hardening base of UA_4 is 2, and the number average molecular weight is about 16,000 Å. The viscosity at 25 ° C is about 39 Pa · s. In the example 1, except that UA-2 was used instead of UA-4, the photocurable resin composition pQ for resin layer formation was obtained in the same manner as in Example 1. Using 40 parts by mass of PQ, the same molecular end as the user of UA_4 was synthesized without adding ethylene oxide and having two hydroxyl groups in one molecule (the average number calculated from the hydroxyl value) A molecular weight of 55 〇〇) was obtained, and a photocurable resin composition Q for forming a resin layer was obtained. The resin layer forming photocurable resin composition Q is 25. (: The viscosity system underneath. 8Pa · s. The viscoelastic property of the photocurable resin composition for forming a resin layer after Q-light curing was measured by a rheometer, and as a result, the shear elastic modulus system was stored. 4xl〇4pa, its loss tangent (tanS) is 0. 13. In the same manner as in Example 1, except that the photocurable resin composition for forming a sealing portion was used as the photo-forming resin c', and the photocurable resin composition for forming a resin layer was used as the composition Q, the same procedure was obtained. Display device R. The display device r returns the liquid crystal monitor of the liquid crystal display device to which the liquid crystal display element is taken out. In the frame of 201210812, after the wiring is reconnected, the liquid crystal monitor is disposed such that the display element A bonded to the glass plate B is vertical. After 5 days of standing, the power was cut into. The result was obtained to show that the kneading surface was completely homogeneous and good in display image' and the display contrast was higher than the original state. Even if the finger is strongly pressed against the image display surface, the image will not be messy. 'The glass plate B effectively protects the display element A. Then, the same setting display device R' confirms the position of the display element after one month, and there is no It was found that the positional shift or the like was well maintained on the glass plate. [Example 10] Except that the terminal of the molecule was not added with ethylene oxide and the bifunctional polypropylene glycol having two radicals in one molecule (the number average molecular weight calculated from the hydroxyl value of 2000), and the isophora The amine phthalate acrylate oligomer (UA-5) was synthesized in the same manner as in Example 1 except that the second oleic acid vinegar was mixed at a molar ratio of 5:6. The hardening base of UA-5 is 2, the number average molecular weight is about 8000, and the viscosity at 25 ° C is about 620 Pa · s. In the same manner as in Example 1, except that UA-2 was used instead of UA-2, a photocurable resin composition PS for resin layer formation was obtained. Using PS (40 parts by mass), UA-5 synthesized, the same molecular end does not add ethylene oxide and has 2 hydroxyl groups in one molecule of difunctional polypropylene glycol (calculated from hydroxyl value) a number average molecular weight of 2000) 30 parts by mass, and a difunctional polypropylene glycol having a molecular weight greater than that of the user at the time of synthesis of UA-5 without adding ethylene oxide in one molecule and having two hydroxyl groups in one molecule (by hydroxyl value) The calculated number average molecular weight of 5,500) was 30 parts by mass, and a resin layered form 70 201210812 was used to form a photocurable resin composition s. The viscosity of the photocurable resin composition S for resin layer formation at 25 ° C. 9Pa · s. The viscoelastic property of the photocurable resin composition for forming a resin layer after Q-light curing was measured by a rheometer, and as a result, the shear elastic modulus system was stored. 0xl04Pa, its loss tangent (tan5) is 0. 15. In the same manner as in Example 1, except that the composition C' was used for the photocurable resin composition for forming a seal portion, and the composition S was used for the photocurable resin composition for forming a resin layer, the same results as in Example 1 were obtained. Device τ. The display device T is returned to the casing of the liquid crystal monitor from which the liquid crystal display element is taken out, and after the wiring is reconnected, the liquid crystal monitor is placed such that the display element A bonded to the glass plate B is vertical. After 5 days of standing, the power was cut in, and the result was a comprehensive and uniform display image covering the display screen, and the display contrast was higher than the original state. Even if the image of the finger is strongly pressed, the image is not messy, and the glass plate B effectively protects the display element A. Next, the display device T was set in the same manner, and after one month, the bonding position of the display element was confirmed, and no positional deviation was observed, and it was favorably held in the glass plate. 'The curable compound (11) of the present invention and the non-curable polymer (D) are contained, and the content of the (D) is 1 to 9 % by mass of the curable resin composition. In addition, it was found that the stress generated by the shrinkage at the time of hardening of the resin layer can be reduced, and a display image covering the display of the liquid crystal screen in a uniform manner and good rape can be obtained. ^ Although the curable compound (II) of the present invention is contained, the examples 6 and 7 which do not contain the non-curable oligomer (D) appear on the peripheral portion of the liquid crystal display surface, and the surface of the liquid crystal display shows 71 201210812, especially halftone. The display will be noticeable. In addition, in particular, the chain transfer agent contained Example 8 exceeding 1 part by mass based on 1 part by mass of the curable compound (11), and the display element could not be satisfactorily held on the glass plate. Industrial Applicability The curable resin composition of the present invention can be effectively utilized in the production of a laminate used in a display device. In addition, the contents of the Japanese Patent Application No. 2010-137532, which is filed on June 16, 2010, and the full-text layout and abstracts of the application are all cited in this case, and the person is the specification of the present invention. reveal. 【figure < BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing an example of a display device for protecting a display element by a transparent surface material. Fig. 2 is a plan view of a display device of Fig. 1 Fig. 3 is a plan view showing an example of a step (a). Fig. 4 is a cross-sectional view showing an example of the aspect of the step (4). Fig. 5 is a plan view showing an example of the aspect of the step (b). Fig. 6 is a cross-sectional view showing an example of the aspect of the step (b). Fig. 7 is a cross-sectional view showing an example of the aspect of the step (c). Figure 8 is a cross-sectional view of the aspect of the step (d). [Description of main component symbols] 1. Display device 10, 52, 53... Transparent surface material 12. Unhardened sealing portion 13... Region H... Photocurable resin composition for resin layer formation 18.31 .. . Lower fixed plate 20.. Dispenser 72 201210812 22, 24... Guide screw 42... Sealing portion 26... Pressure reducing device 50... Display element 28... Vacuum pump 51... Polarized light Plate 30...Upper plate 54...Flexible printed circuit board 32...Adsorption pad 55...Light-shielding printing portion (light-shielding portion) 34.. Cylinder 40.. Resin layer 56... Light transmitting portion 73

Claims (1)

201210812 七、申請專利範圍： 1· 一種硬化性樹脂組成物，係使用於層積體，該層積體係 使未硬化之硬化性樹脂組成物挾持於一對面材間並使 其硬化而形成者，其特徵在於： 前述一對面材係至少一面材為透明，而前述硬化性 樹脂組成物含有下述硬化性化合物（11)及下述非硬化性 养聚物（D)，且該非硬化性寡聚物(D)的含量係丨質 量％ ; 硬化性化合物(II):由硬化性樹脂組成物硬化時會 進行硬化反應的硬化性化合物之1種以上構成，該硬化 性化合物的至少1種係具有在前述硬化性樹脂組成物硬 化時不進行反應的羥基； 非硬化性寡聚物(D):其係在硬化性樹脂組成物硬 化時不會與前述硬化性化合物(H)進行硬化反應，且每i 分子具有0.8〜3個羥基的寡聚物。 2.如申請專利範圍第1項之硬化性樹脂組成物，其中前述 硬化性化合物(II)係含有具硬化性基且具羥基的單體。 3·如申請專利範圍第2項之硬化性樹脂組成物，其中前述 硬化性化合物(II)係含有：寡聚物(A，），其具硬化性基且 分子量為1000〜100000 ;及單體(B，），其具硬化性基且分 子量為125〜600，並且該單體（B，)含有具羥基的單體 (B3)〇 4.如申請專利範圍第3項之硬化性樹脂組成物，其中前述 非硬化性寡聚物(D)係聚氧伸烧基多元醇，且前述寡聚 74 201210812 物(A1)係使用聚氧伸烷基多元醇及聚異氰酸酯為原料而 合成的胺曱酸酯募聚物。 5. 如申請專利範圍第3或4項之硬化性樹脂組成物，其中前 述寡聚物(A’)係具有丙烯酸基，而前述單體(B，)之至少一 部分係具有曱基丙烯酸基。 6. 如申請專利範圍第3至5項中任一項之硬化性樹脂組成 物’其中前述單體(B3)係含有甲基丙烯酸羥基酯，而該 曱基丙烯酸羥基酯具有羥基數1〜2且碳數3〜8之羥烷基。 7. 如申請專利範圍第3至6項中任一項之硬化性樹脂組成 物’其中前述單體(B')係含有選自於由具有碳數8〜22之 烷基的甲基丙烯酸烷基酯所構成群組中的單體(B4)。 8. 如申請專利範圍第1至7項中任一項之硬化性樹脂組成 物’其係不含鏈轉移劑，或者含有鏈轉移劑，但其含量 係相對於硬化性化合物（11)100質量份計在1質量份以 下。 9. 一種層積體，係由至少一者為透明面材的一對面材隔著 樹脂層進行層積而一體化者，且該樹脂層係由如申請專 利範圍第1至8項中任一項之硬化性樹脂組成物的硬化 物所構成。 丫坷寻刊範圍第9項之層槓體 .....j义一 甸材之 其中一者係透明面材，而另一者係顯示元件。 11· 一種層積體之製造方法，該欲製造之層積體係具備：第 1面材及第2面材，該第1及第2面材中的其中一者係透明 面材；樹脂層，係由該第1面材及第2面枒所失持.以及 75 201210812 ⑽酬餐賴糊包括有下述 ⑴及(:在第1面材表面周緣部，塗佈含有硬化性化合物 物合起始劑的液狀密封部形成用硬化性樹脂組成 形成未硬化密•的步驟； (b)對由未硬化密封部所包圍的區域，供應由如申請 範圍第1至8射任―項之硬化性樹脂組成物所構 成之科脂層形成用硬化性樹脂組成物的步驟； (c)在l〇〇pa以下的減壓環境下，於樹脂層形成用硬 化性樹脂組成物上重疊第2面材，而獲得樹脂層形成用 硬化性樹脂組成物已由第1面材、第2面材及未硬化密封 部所密封之層積前驅體的步驟；及 (d)在將層積前驅體放置於50kPa以上之壓力環境下 的狀態下，使未硬化密封部及樹脂層形成用硬化性樹脂 組成物進行硬化之步驟。 12.如申請專利範圍第11項之層積體之製造方法’其中前述 第1面材及第2面材之其中一者係透明面材’另一者係顯 不元件0 76201210812 VII. Patent application scope: 1. A curable resin composition for use in a laminate in which an uncured curable resin composition is held between a pair of face materials and hardened. The above-mentioned pair of face materials are at least one material which is transparent, and the curable resin composition contains the following curable compound (11) and the following non-curable polymer (D), and the non-hardening oligomer The content of the material (D) is 丨% by mass. The curable compound (II) is one or more types of curable compounds which undergo a curing reaction when the curable resin composition is cured, and at least one of the curable compounds has a hydroxyl group which does not react when the curable resin composition is cured; a non-curable oligomer (D) which does not undergo a hardening reaction with the curable compound (H) when the curable resin composition is cured, and An oligomer having 0.8 to 3 hydroxyl groups per i molecule. 2. The curable resin composition according to claim 1, wherein the curable compound (II) contains a monomer having a curable group and having a hydroxyl group. 3. The curable resin composition of claim 2, wherein the curable compound (II) comprises: an oligomer (A,) having a curable group and having a molecular weight of 1000 to 100,000; and a monomer (B,) having a sclerosing group and having a molecular weight of from 125 to 600, and the monomer (B,) contains a monomer having a hydroxyl group (B3) 〇 4. The curable resin composition of claim 3 Wherein the non-hardening oligomer (D) is a polyoxyalkylene-based polyol, and the oligo 74 201210812 (A1) is an amine oxime synthesized using a polyoxyalkylene polyol and a polyisocyanate as a raw material. Acid ester condensate. 5. The curable resin composition according to claim 3, wherein the oligomer (A') has an acrylic group, and at least a part of the monomer (B,) has a mercaptoacryl group. 6. The curable resin composition of any one of claims 3 to 5 wherein the aforementioned monomer (B3) contains a hydroxy methacrylate, and the hydroxy methacrylate has a hydroxyl number of 1 to 2 And a hydroxyalkyl group having a carbon number of 3 to 8. 7. The curable resin composition of any one of claims 3 to 6, wherein the aforementioned monomer (B') contains an alkyl methacrylate selected from an alkyl group having a carbon number of 8 to 22 The monomer (B4) in the group formed by the base ester. 8. The curable resin composition of any one of claims 1 to 7 which does not contain a chain transfer agent or a chain transfer agent, but the content thereof is 100 mass relative to the curable compound (11) The fraction is 1 part by mass or less. A laminate in which at least one of a pair of face materials of a transparent face material is laminated via a resin layer, and the resin layer is obtained by any one of claims 1 to 8 It is composed of a cured product of the curable resin composition.层 范围 范围 第 第 第 ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... A method for producing a laminate, the laminated system to be produced comprising: a first face material and a second face material, wherein one of the first and second face materials is a transparent face material; and a resin layer; The first surface material and the second surface material are lost. 75 201210812 (10) The following foods (1) and (: on the surface of the first surface material, the coating contains a curable compound The liquid seal portion of the starter is formed by a curable resin composition to form an uncured seal; (b) for the region surrounded by the uncured seal portion, the hardening is performed by the first to eighth shots of the application range Step of forming a curable resin composition for forming a chemical layer composed of a resin composition; (c) superposing the second surface on the curable resin composition for forming a resin layer in a reduced pressure environment of 10 Å or less a step of obtaining a laminated precursor in which the curable resin composition for forming a resin layer has been sealed by the first surface material, the second surface material, and the unhardened sealing portion; and (d) placing the laminated precursor The uncured seal portion and the resin layer are formed in a state of a pressure of 50 kPa or more The step of curing the hardened resin composition. The method for producing a laminate according to the eleventh aspect of the invention, wherein the one of the first surface material and the second surface material is a transparent surface material Display component 0 76
TW100121058A 2010-06-16 2011-06-16 A hardened resin composition, a laminate using the same, and a method for producing the layered product (2) TWI481503B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2010137532 2010-06-16

Publications (2)

Publication Number Publication Date
TW201210812A true TW201210812A (en) 2012-03-16
TWI481503B TWI481503B (en) 2015-04-21

Family

ID=45348239

Family Applications (1)

Application Number Title Priority Date Filing Date
TW100121058A TWI481503B (en) 2010-06-16 2011-06-16 A hardened resin composition, a laminate using the same, and a method for producing the layered product (2)

Country Status (5)

Country Link
JP (2) JP5729385B2 (en)
KR (1) KR101839635B1 (en)
CN (1) CN102939312B (en)
TW (1) TWI481503B (en)
WO (1) WO2011158840A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104936778A (en) * 2012-12-28 2015-09-23 旭硝子株式会社 Transparent face plate with an adhesive layer, laminate, display device, and production methods thereof
TWI739962B (en) * 2016-11-29 2021-09-21 日商住友化學股份有限公司 Gas barrier film and flexible electronic device

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5738641B2 (en) * 2011-03-25 2015-06-24 株式会社日本触媒 Optical UV-curable resin composition, cured product, and display device
TW201317315A (en) * 2011-08-26 2013-05-01 Denki Kagaku Kogyo Kk Curable resin composition
JP5969375B2 (en) * 2012-12-18 2016-08-17 オリジン電気株式会社 UV-curable adhesive composition and laminate using the same
JP6226652B2 (en) * 2013-09-09 2017-11-08 昭和電工株式会社 Manufacturing method of image display device
JPWO2015159957A1 (en) * 2014-04-17 2017-04-13 旭硝子株式会社 Transparent surface material with adhesive layer, display device, manufacturing method thereof, and adhesive sheet
TW201609933A (en) * 2014-07-28 2016-03-16 Asahi Glass Co Ltd Curable resin composition, method for preparing curable resin composition, method for manufacturing laminate, and display device
JP6425119B2 (en) * 2014-08-05 2018-11-21 Ｔｉａｎｍａ Ｊａｐａｎ株式会社 Device and method of manufacturing device
JP2016169335A (en) * 2015-03-13 2016-09-23 旭硝子株式会社 Curable composition, cured article, laminate and picture display device
JP6730006B2 (en) * 2015-05-21 2020-07-29 株式会社きもと Optical shading member and manufacturing method thereof
WO2019004160A1 (en) * 2017-06-26 2019-01-03 大日本印刷株式会社 Light modulating member, sun visor, and movable body
JP6904161B2 (en) * 2017-08-24 2021-07-14 デクセリアルズ株式会社 Manufacturing method of image display device
JP2019174739A (en) * 2018-03-29 2019-10-10 三菱電機株式会社 Manufacturing method of image display device

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58138766A (en) * 1982-02-10 1983-08-17 Nippon Synthetic Chem Ind Co Ltd:The Photo-setting type adhesive composition for glass
JP2909661B2 (en) * 1990-11-16 1999-06-23 大阪有機化学工業株式会社 Radiation-curable pressure-sensitive adhesive composition
JPH083266A (en) * 1994-06-27 1996-01-09 Japan Energy Corp Photocurable resin composition
EP0973815B1 (en) * 1997-04-08 2003-10-22 DSM IP Assets B.V. Radiation-curable binder compositions having high elongation at break and toughness after cure
JP4741257B2 (en) * 2004-03-04 2011-08-03 ノーテープ工業株式会社 UV curable liquid adhesive composition
JP5343391B2 (en) * 2007-07-17 2013-11-13 デクセリアルズ株式会社 Resin composition and image display device
KR101463640B1 (en) * 2007-07-30 2014-11-19 아사히 가라스 가부시키가이샤 Curable resin composition, transparent laminate using the same, and method for producing the transparent laminate
JP5596262B2 (en) * 2007-08-22 2014-09-24 三菱樹脂株式会社 Adhesive sheet
JP2009091434A (en) * 2007-10-05 2009-04-30 Sekisui Chem Co Ltd Polymerizable composition for interlayer, interlayer and transparent laminate
JP5098722B2 (en) * 2008-03-17 2012-12-12 Ｊｓｒ株式会社 Curable resin composition, film laminate for sticking, and laminate for impact absorption
TWI481634B (en) * 2009-05-20 2015-04-21 Asahi Glass Co Ltd A hardened resin composition, a transparent laminate, and a method for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104936778A (en) * 2012-12-28 2015-09-23 旭硝子株式会社 Transparent face plate with an adhesive layer, laminate, display device, and production methods thereof
TWI739962B (en) * 2016-11-29 2021-09-21 日商住友化學股份有限公司 Gas barrier film and flexible electronic device

Also Published As

Publication number Publication date
JP5729385B2 (en) 2015-06-03
CN102939312A (en) 2013-02-20
CN102939312B (en) 2014-12-03
JP2013224036A (en) 2013-10-31
KR20130089579A (en) 2013-08-12
JPWO2011158840A1 (en) 2013-08-19
KR101839635B1 (en) 2018-03-16
WO2011158840A1 (en) 2011-12-22
TWI481503B (en) 2015-04-21
JP5494865B2 (en) 2014-05-21

Similar Documents

Publication Publication Date Title
TW201210812A (en) Curable resin composition, laminate comprising same, and process for production of the laminate
TWI519624B (en) A method for manufacturing a transparent surface material, a display device, and the like, which are provided with an adhesive layer (1)
TWI513791B (en) (2) A method for producing a transparent surface material, a display device and the like,
TWI549821B (en) A hardened resin composition, a laminate using the same, and a method for producing the layered product (1)
TWI493012B (en) A transparent surface material attached to an adhesive layer, a display device, and the like
TWI433822B (en) A method of manufacturing a display device
US20160342254A1 (en) Ultraviolet-Curable Adhesive Composition For Touch Panel, Optical Member Producing Method Using Same, Cured Product, And Touch Panel
KR20170020344A (en) Ultraviolet curable resin composition for touch panel, bonding method using same, and product
TW201640193A (en) Method for producing image display device, curable resin composition to be used therein, touch panel, and image display device
KR20170039183A (en) Method for producing optical member and curable resin composition used therein
KR20170023878A (en) Image display device manufacturing method, hardening resin composition used therein, and image display device
TW201133058A (en) Method for manufacturing liquid crystal display device
TWI429608B (en) The manufacturing method of the layered body

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees