TW201208566A - Granular pesticidal composition - Google Patents
Granular pesticidal composition Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- Pest Control & Pesticides (AREA)
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- Agronomy & Crop Science (AREA)
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Abstract
Description
201208566 六、發明說明： 【發明所屬之技術領域】 本發明是關於一種顆粒狀農藥組成物。 【先前技術】 人以往，在農作物的栽培上，有許多有害生物防治活性 化二物、植物病害防治活性化合物、除草活性化合物等的 農藥活性成分，以種種的形態被適用。 例如，在水稻的栽培上，在育苗箱預先施用農藥製 1則在°亥月苗箱生育的幼苗在水田移植同時，前述農藥 製劑所含的農藥活性成分也會被施用到水田中。移植後前 述農藥活性成分有可能產生效力時’這個方法就可成為在 ^稻栽培上的對有害生物、植物病害、雜轉有效率的防 治方法。因此，為了能適用於該防治方法而有 製劑的開發。 ,㈣晨樂 在前述防治方法中，有要求農藥活性成分能長期發揮 防治效力，並有要求大量的農藥活性成分的施用。但是， 在水稻幼苗等的生育初期的植物體施用過量的農藥活性成 分時，也有引起植物體的生育不良等情況，有其改善的要 求。 農藥活性成分而言，做為有害生物防治活性化合物而 為人所知有起安勃（〇11〇犷&111^&11丨11?1*〇16)(—般名，式（1) 表示的化合物）（例如，參照專利文獻1): 323181 4 201208566201208566 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a particulate pesticide composition. [Prior Art] Conventionally, in the cultivation of crops, there are many pesticidal active ingredients such as a pest control active compound, a plant disease control active compound, and a herbicidal active compound, which are applied in various forms. For example, in the cultivation of rice, the pesticide is pre-applied in the nursery box. The seedlings which are grown in the box at the time of the year are transplanted in the paddy field, and the pesticide active ingredient contained in the above-mentioned pesticide preparation is also applied to the paddy field. When the above-mentioned pesticide active ingredient is likely to produce efficacy after transplantation, this method can be used as an effective method for controlling pests, plant diseases, and miscellaneous transformation in rice cultivation. Therefore, in order to be applicable to the control method, there is a development of a preparation. (4) Chenle In the above-mentioned control methods, it is required that the active ingredient of the pesticide can exert the control effect for a long period of time, and a large amount of the active ingredient of the pesticide is required to be applied. However, when an excessive amount of agrochemical active ingredient is applied to a plant body at the early stage of growth such as rice seedlings, there is a case where the plant body is poorly fertilized, and there is a demand for improvement. In the case of a pesticidal active ingredient, it is known as an active compound for pest control, and it is known as Anbo (〇11〇犷&111^&11丨11?1*〇16) (general name, formula (1) )) (for example, refer to Patent Document 1): 323181 4 201208566
又’ 〇塞酿卤胺（tiadinil)、異0塞菌胺（isotianil)、 撲殺熱（probenazole)及甲噻活素（Acibenzolar-S-methyl) 都是為人所知的作用於水稻的植物體，而表現對稻熱病等 的對植物病害的抵抗性誘導的活性物質（例如，參照專利 文獻2及非專利文獻1)。 [先前參考文獻] [專利文獻] [專利文獻1]特表2004-538328號公報 [專利文獻2]國際公開2008/007778號小冊 [非專利文獻] [非專利文獻1]植物防疫，第61卷第10號（2007)， 第531頁-第536頁（社團法人日本植物防疫協會發行） 【發明内容】 [發明要解決的課題] 本發明是提供含有前述式（I)表示的化合物，並有優 異性能的農藥製劑為課題。 [解決課題的手段] 本發明者等’為了要找出含有前述式（I)表示的化合 物’並有優異的性能的農藥製劑起見精心檢討的結果，發 現含有前述式（I)表示的化合物，與由售醯菌胺（tiadinil)、 5 323181 201208566 異0塞菌胺（isotianil)、撲殺熱（probenazole)及曱嗟活素 (Acibenzolar-S-methyl)所成的群中所選的1種以上的植 物病害防治活性化合物，含有膨潤石（smect i te)礦物的增 量劑’與水溶性結合劑的農藥顆粒狀組成物，有優異的性 能而達成本發明。 即，本發明如下之[1]至[11]。 [1] 一種顆粒狀農藥組成物，係含有以式（I)表示的化合 物， nuAlso, 'tiadinil, isosanil, probenazole, and Acibenzolar-S-methyl are well-known plant bodies that act on rice. In addition, an active substance that exhibits resistance to plant diseases such as rice fever (see, for example, Patent Document 2 and Non-Patent Document 1). [PATENT DOCUMENT] [Patent Document 1] Japanese Patent Publication No. 2004-538328 [Patent Document 2] International Publication No. 2008/007778 (Non-Patent Document) [Non-Patent Document 1] Plant Epidemic Prevention, No. 61 [Volume No. 10 (2007), p. 531 - p. 536 (issued by the Japanese Society for Plant Epidemic Prevention) [Problems to be Solved by the Invention] The present invention provides a compound represented by the above formula (I), and A pesticide preparation having excellent properties is a subject. [Means for Solving the Problem] The inventors of the present invention found that the compound represented by the above formula (I) was found as a result of careful examination of a pesticide preparation having an excellent performance in order to find a compound represented by the above formula (I). , one selected from the group consisting of tiadinil, 5 323181 201208566 isotianil, probenazole, and Acibenzolar-S-methyl The above plant disease controlling active compound, a pesticide granular composition containing a bulking agent of smectite mineral and a water-soluble binder, has excellent properties to achieve the present invention. That is, the present invention is as follows [1] to [11]. [1] A particulate pesticide composition containing a compound represented by the formula (I), nu
由噻醯菌胺（tiadinil)、異噻菌胺（isotianil)、撲 殺熱（probenazole)、甲0塞活素（Acibenzolar-S_methyl) 所成之群中所選的1種以上的植物病害防治活性化合物， 含有膨潤石礦物的增量劑，與 水溶性結合劑。 [2] 如[1]所述的顆粒狀農藥組成物，對式〇)表示之化合 物100部，植物病害防治活性化合物是1〇〇至5〇〇〇 重量份的含有比率。 [3] 如[1]或[2]所述的顆粒狀農藥組成物，該顆粒狀農藥 組成物的式[1 ]表示之化合物與植物病害防治活性化 合物的合計含有比率在1至3〇重量％。 [4] 如[1]至[3]所述的任1種顆粒狀農藥組成物，該顆粒 323181 6 201208566 狀農藥組成物中的含有膨潤石礦物的增量劑含有比 率在40至98重量％。 [5] 如[1]至[4]所述的任1種顆粒狀農藥組成物’該顆粒 狀農藥組成物中的水溶性結合劑的含有比率在1至10 重量％。 [6] 如[1]至[5]所述的任1種顆粒狀農藥組成物’該顆粒 狀農藥組成物中的植物病害防治活性化合物為異嘆 菌胺（isotiani 1)。 [7] 如[1]至[6]所述的任1種顆粒狀農藥組成物，再含有 新類尼古丁（Neonicotinoid)化合物。 [8] 如[7]所述的顆粒狀農藥組成物，該新類尼古丁是可尼 丁（Clothianidin)。 [9] 如[1]至[8]所述的任1種顆粒狀農藥組成物，其所含 的含有膨潤石礦物的增量劑是含有膨潤石礦物及碳 酸鈣。 [10] 如[1]至[9]所述的任1種顆粒狀農藥組成物，該膨潤 石礦物疋息土（bentonite)， [11] 如[1]至[10]所述的任1種顆粒狀農藥組成物，該水溶 f生化合物疋預糊化殿粉（alphatized starch)。 [發明的效果] 由本發明可提供有優異性能的農 藥製劑。 【實施方式】 本發明的農藥顆粒狀組成物，含有式（I)表示的化合 物： 7 323181 201208566One or more plant disease control active compounds selected from the group consisting of tiadinil, isotianil, probenazole, and Acibenzolar-S_methyl , an extender containing bentonite minerals, and a water-soluble binder. [2] The particulate pesticide composition according to [1], which is a compound represented by the formula (〇), and a plant disease control active compound is a content ratio of from 1 to 5 parts by weight. [3] The particulate pesticide composition according to [1] or [2], wherein the total content of the compound represented by the formula [1] and the plant disease controlling active compound of the particulate pesticide composition is 1 to 3 Torr. %. [4] The granule-containing pesticide composition according to any one of [1] to [3], wherein the tillinkite mineral-containing extender content ratio of the granule 323181 6 201208566 is 40 to 98% by weight . [5] The particulate pesticide composition according to any one of [1] to [4] wherein the content ratio of the water-soluble binder in the particulate pesticide composition is from 1 to 10% by weight. [6] The particulate disease-controlling active compound according to any one of [1] to [5], wherein the plant disease controlling active compound in the particulate pesticide composition is isotretin (isotiani 1). [7] The particulate pesticide composition according to any one of [1] to [6], further comprising a novel nionicotinoid compound. [8] The granular pesticide composition according to [7], wherein the new nicotine is Clothianidin. [9] The particulate pesticide composition according to any one of [1] to [8], wherein the extender containing the bentonite mineral contains a bentonite mineral and calcium carbonate. [10] Any one of the particulate pesticide compositions according to any one of [1] to [9], the bentonite mineral bendonite, [11] as described in [1] to [10] A granular pesticide composition, the water-soluble compound 疋 pre-gelatinized starch. [Effects of the Invention] The present invention can provide a pharmaceutical preparation having excellent properties. [Embodiment] The pesticide granular composition of the present invention contains the compound represented by the formula (I): 7 323181 201208566
由嗟酿菌胺（tiadinil)、異噻菌胺（is〇tianil)、撲 殺熱（probenazole)、曱噻活素（Acibenzolar S methyl) 所成之群所選1種以上的植物病害防治活性化合物（以下 有簡稱為本植物病害防治活性化合物）， 含有膨潤石礦物的增量劑，與 水溶性結合劑。 前述式（I)的化合物是一般名為人所知的剋安勃 (Chlorantraniliprole)的醢胺化合物。式（I)的化合物， 例如日本專利特表2004-538328公報的實施例6所述，可 使用該文獻所述之方法製造。 本發明的農藥顆粒狀組成物中的式（〗）的化合物的含 有量通常是約0. 1至5重量％。理想是約〇. 5至2重量％。 本植物病害防治活性化合物異噻菌胺（is〇tianil)是 下式（II)表不的化合物：One or more plant disease control active compounds selected from the group consisting of tiadinil, is〇tianil, probenazole, and Acibenzolar S methyl The following is abbreviated as a plant disease control active compound), an extender containing a bentonite mineral, and a water-soluble binder. The compound of the above formula (I) is a guanamine compound generally known as Chlorantraniliprole. The compound of the formula (I), for example, as described in Example 6 of JP-A-2004-538328, can be produced by the method described in the literature. 1至重量重量。 The amount of the compound of the formula (A) of the present invention is usually from about 0.1 to 5% by weight. The ideal is about 5 to 2% by weight. The plant disease control active compound isthomycin (is〇tianil) is a compound represented by the following formula (II):
異噻菌胺（isotianil)是下式（III)表示的化合物： 8 323181 201208566Isotianil is a compound represented by the following formula (III): 8 323181 201208566
撲殺熱（probenazole)是下述式（IV)表示的化合物：The probenazole is a compound represented by the following formula (IV):
曱α塞活素（人以56112〇131--5-11161±71)是下述式（¥)表示的化 合物：曱α-capsaicin (man: 56112〇131--5-11161±71) is a compound represented by the following formula (¥):
ς\ on 都可使用市售的化合物。 本發明的農藥顆粒組成物中，含有本植物病害防治活 性化合物之1種或2種以上，但其含有量通常是約1至25 重量％，理想是1至5重量％。 又，本發明的農藥顆粒狀組成物中所含的式（I)的化 合物與本植物病害防治活性化合物的含量比率是，對式（I) 的化合物100重量份為約100至5000重量份，理想是約 100至600重量份。 在本發明的農藥顆粒狀組成物中的式（I)的化合物與 本植物病害防治活性化合物的合計含有量通常是約1至30 重量％，理想是約1.5至7重量％，更理想是約1.5至5重 量％。 9 323181 201208566 本發明的農藥顆粒狀組成物，除了式（丨）的化合物及 本植物病害防治活性化合物之外’再可含有其他的農藥 性化合物。這種其他的農藥活性化合物而言，例如可 殺蟲活性化合物、殺菌活性化合物、昆蟲成長調控活性化 合物、除草活性化合物及植物成長調控活性成分。 本發明的農藥顆粒狀組成物中含有其他的農藥、、舌& 化合物時’這種其他的農藥活性化合物在本發明的* 粒狀組成物中的含有量通常是約0.5至40重詈。/ 、顆 王至’理相曰 1至10重量％。 …疋 在本發明的農藥顆粒狀組成物中含有的含有膨、門石 礦物的增量劑可以是膨潤石礦物本身，或膨潤石礦物與臉 潤石礦物以外的物質的混合物也可以。 、夕 膨潤石礦物而言，詳細而言可舉：皂石（saponi t ) 水輝石（hectorite)、辞蒙脫石（Sauconite)、斯蒂文石 (Stevensite)、鐵膨潤石（nontronite)、蒙脫石 (montmoril Ionite)及鐵鋁膨潤石（beidellite)，合適的 β 可舉蒙脫石。做為蒙脫石具體而言，可舉蒙脫石含 疋 、 田士、蒙 脫石穗高、蒙脫石赤城、蒙脫石妙義、超黏土（均為商品名， 豐順（Hojun)公司製）、KunigelVl、KunigelV2、 KunigelVA、Kunibond(均為註冊商標，Kunimine工業公司 製）、關西.蒙脫石（商品名，Kanesan.工業公司製）等的蒙脫 石 增量劑是膨閑石礦物與膨潤石礦物以外的物質的混合 物時’做為膨潤石以外的礦物而言，例如可舉：高嶺石、的 323181 10 201208566 狄克石（dickite)、珍珠石（nacrite)、禾樂石（halloysite) 等尚嶺石類礦物’溫石綿（chryS〇tile)、渐蛇紋石 (lizardite)、葉蛇紋石（antig〇rite)、鎮紹蛇紋石 (amesite)等蛇紋石，葉蠟石（pyr〇phyiiite)、滑石（taic)、 犧石、白雲母、多石夕白雲母（phengite)、絹雲母（sericite)、 伊來石（illite)等雲母，方;g夕石（crist〇balite)、石英 (quartz)等氧化石夕，厄帖浦石（attapulgite)、海泡石 (sepiolite)等含水發酸錢，石賞等硫酸鹽礦物，白雲石 (dolomite)、石膏（gypsum)、沸石（zeolite)、沸石、凝灰 石、蛭石（vermiculite)、合成鋰皂石（laponite)、浮石、 石夕藻土、碳酸鈣等礦物質承載物；玉米穗軸粉、胡桃殼粉、 稻殼粉、小麥粉、木粉、糠、麩糠、大豆粉等的植物系承 載物；尿素、乳糖、蔗糖、食鹽、芒硝等的水溶性固體承 載物。 在本發明的農藥顆粒狀組成物中，含有膨潤石礦物的 增里劑’對本發明的農藥顆粒狀組成物全體通常含有約4〇 至98%重量％，理想是約60至95重量％。 在本發明的農藥顆粒狀組成物中的增量劑是膨潤石 礦物與膨潤石礦物以外的物質的混合物時，對本發明的農 藥顆粒狀組成物的膨潤石礦物的含有量而言，例如可舉：5 至40重量％，理想是5至20重量％。 在本發明的農藥顆粒狀組成物中，含有水溶性結合劑。 34種結合劑而言，例如可舉：羧曱基纖維素鈉、羥丙基曱 基纖維素、甲基纖維素、曱基乙基纖維素、羥丙基纖維素、 323181 201208566 聚丙烯酸鈉、黃蓍膠、聚乙烯°比咯酮、聚乙烯醇、預糊化 殿粉、糊精、海藻酸及海藻酸納。 在本發明的農藥顆粒狀組成物中’水溶性結合劑通常 含有約1炱10重量0/β，理想是約1至5重量％。 本發明的農藥顆粒狀組成物，除了式（I)的化合物、 本植物病害防治活性化合物、含有膨潤石礦物的增量劑及 水溶性結合劑、再加任意含有的其他農藥活性化合物之 外，也可含有界面活性劑、溶劑、安定劑、防腐劑、著色 劑、香料等。 本發明的農藥顆粒狀組成物，例如以擠出造粒法、含 浸法、或覆篥法而製成顆粒狀製劑。 本發明的農藥顆粒狀組成物’在含有式（I)的化合 物、本植物病害防治活性化合物、含有膨潤石礦物的增量 劑及水溶性結合劑、再視需要如何而加任意含有的其他農 藥活性化合物、界面活性劑、溶劑、安定劑、防腐劑、著 色劑、香料等的混合物中，加水而混練’將所得混練物造 粒，將所得造粒物乾燥’視需要而進行破碎、筛選、整粒 等而製造。 前述混練中’可使用摻合機。摻合機而言，可舉捏合 機（kneader)、諾塔混合機（nauta mixer)、羅迪格混合機 (Loedige mixer)等。 混練時所用的水量’對前述混合物100重量份通常是 3至50重量份的比率。 將前述混練物擠出造粒時，通常是使用〇. 5至2. 〇_妒， 12 323181 201208566 理想是0. 7至1 · 5mm φ的篩網而實施。 使用的擠出造粒機而言，可列舉螺桿型（screw type) 擠出造粒機、滾筒型（roller type)擠出造粒機、圓盤製粒 型（disk pel letor type)擠出造粒機、製粒型擠出造粒機 (pellet mill type)、籃塑（basket type)擠出造粒機、格 子（plaid type)型擠出造粒機、振盪擠出造粒機 (oscillating type)、齒輪型（gear type)擠出造粒機、圓 環模子型（ring type)擠出造粒機等。具體而言，可使用不 二（Fuji) Paudal公司製的雙半球形型造粒機（twin dome granulator)、單半球形型造粒機（single dome granulator) 等。 所得造粒物通常是在30至90°C，理想是在30至8(TC 乾燥。 乾燥後’所得本發明的農藥顆粒狀組成物的粒長通常 是0. 5至6. Omm ’理想是〇. 7至4. Omm。又，在本發明的粒 長就是’指顆粒可以有的最大長度而言。 本發明的農藥顆粒狀組成物，可在對水稻的育苗箱的 播種時或發芽後到移植於水田前的水稻育苗時施用於育苗 箱。其施用1，依式（I)的化合物及本植物病害防治活性化 合物的含有量及水稻育苗箱的大小而可變動，但例如： 30cmx60cm大小的水稻育苗箱每i箱，式（1)的化合物及本 植物病害防治活性化合物的合計量約為〇. 〇5至4. 〇g。 [實施例] 其次’將本發明以參考製造例、比較例及試驗例更詳 13 323181 201208566 細說明’但本發明不受其任何限定。 參考製造例1粉狀農藥組成物1的調製 70.0重量份的2，-氰基-3, 4-二氯異噻唑-5-羧基苯 胺化物（一般名：異噻菌胺（isotianil))及30. 〇重量份的 蠟石（商品名：勝光山黏土5，勝光山鑛業公司製）混合均 勻，以離心粉碎機全量粉碎，得容積中值粒徑為4. 12#讯 (以MALVERN製MASTERSIZER2000測定）的含有2’ _氰基 -3, 4-二氯異噻唑-5-羧基苯胺化物的粉狀農藥組成物（以 下簡稱為粉狀農藥組成物1)。 參考製造例2粉狀農藥組成物2的調製 70.0重量份的式（I)的化合物及30.〇重量份的蠟石 (商品名：勝光山黏土 S，勝光山鑛業公司製）混合均勻， 以離心粉碎機全量粉碎’得容積中值粒徑為3.92/zm(以 MALVERN製MASTERSIZER2000測定）的含有式（I)的化合物 的粉狀農藥組成物（以下簡稱為粉狀農藥組成物2)。 參考製造例3粉狀農藥組成物3的調製 70. 〇重量份的（E)-l-(2-氯-1，3-噻唑-5-基甲基）-3-甲基-2-硝基胍（一般名：可尼丁（CLOTHIANIDIN))及30.0 重量份的蠟石（商品名：勝光山黏土 S，勝光山鑛業公司製） 混合均勻’以離心粉碎機全量粉碎，得容積中值粒徑為 8.20//m(以 MALVERN 製 MASTERSIZER2000 測定）的含有 (E)-l-(2-氯-1，3-噻唑-5-基甲基）-3-曱基-2-硝基胍的粉 狀農藥組成物（以下簡稱為粉狀農藥組成物3)。 參考製造例4含有農藥之熱硬化性樹脂粉末1的調製 14 323181 201208566 將46. 3重量份的SumiphenTM(註冊商標，Sumitomo Bayer Urethane公司製，支鏈型聚醚聚醇），52· 2重量份 的 Sumiphen 1600U(註冊商標，Sumitomo Bayer Urethane 公司製，直鏈型聚醚聚醇），及1.5重量份的2, 4, 6-三（二 甲基胺基甲基）酚（KAYAKUAKZ0製造）混合均勻，而得聚醇 與觸媒的液狀混合物（以下簡稱為聚醇前混合物1)。聚醇 前混合物1的黏度是322m · Pa(以B型黏度計，25°C，12 回轉，1號轉子（rotor)測定）。 在高速混合機裝置（深江Powteck公司製FS-GS-25 型；有貫穿圓盤形的容器部的底面中心的垂直線為回轉軸 的攪拌片及貫穿圓盤型的容器部的側面的水平線為回轉軸 的切碎片的裝置）的容器内，裝入100重量份的粉狀農藥組 成物3，轉動該裝置的攪拌片（回轉數：382rpm)及切碎片 (回轉數：3500rpm)。其次，將混合容器加溫，在保持粉狀 農藥組成物3的品溫於85±5°C，費2分鐘添加1· 93重量 份的聚醇前混合物1。可觀察到該聚醇前混合物1受到粉 狀農藥組成物3所濕潤的狀況。在3分鐘後，將品溫保持 在85±5°C ’費2分鐘添加1. 〇7重量份的Sumi jul 44V10(註 冊商標，Sumitomo Bayer Urethane公司製，聚亞曱基聚 苯基聚異氰酸酯，黏度130m · Pa(25°C))。添加後立即可 確認增黏現象’之後，黏度降低，觀察到聚胺酯樹脂的硬 化（對100重量份的粉狀農藥組成物3，相當於3. 〇重量份 的聚胺酯樹脂）。在6分鐘後，將品溫保持在g5±5〇c，將 下述的胺曱酸乙酯（urethane)的添加操作重複34次。 323181 15 201208566 [胺甲酸乙酯的添加操作] 將1. 93重量份的聚醇前混合物1費2分鐘添加s等 待3分鐘—將1. 07重量份的Sumi jul 44V10費2分鐘添加 —等待6分鐘。 在上述的胺甲酸乙酯的添加操作中，高速混合機裝置 繼續同條件下有煎斷力的授株混合。 對於100重量份的粉狀農藥組成物3，添加合計1〇5 重量份的聚胺酯樹脂原料。上述操作完成後，添加4. % 重量份的碳酸妈NS#2300(日東粉化公司製），混合3分鐘。 混合後，冷卻該混合物’而得粉狀農藥組成物3被聚胺醋 樹脂固定，覆蓋而成的硬化性樹脂微粉末（以下稱為含有農 藥之熱硬化性樹脂微粉末1 ;容積中值粒徑：44//m，容積 重（bulk density, apparent density) : 〇. 42g/ml) 〇 製造例1 農藥顆粒狀組成物1的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物丨的2 9 重量份（農藥活性化合物2.0重量份），粉狀農藥組成物2 的1.1重量份（農藥活性化合物0.75重量份），預糊化殺粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5 〇 重量份’重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇 〇 重置份’蒙脫石（商品名：.蒙脫石穗高’豐順公司製）的1〇 〇 重量份，及蠟石（商品名：勝光山黏土 s，勝光山鑛業公司 製）的65. 6重量份的混合物中’加入含有界面活性劑（聚氧 伸乙基二本乙蝉基苯基醚，Sorpol T~20(註冊商標），東邦 323181 16 201208566 化學工業製）1. 〇重量份的水約20重耋份’而混練。所付 混練物的約1.5kg投入於附有G.gnnnW _網的籃裂擠出造 粒機（HU-G型畑式造粒機，畑製作戶以），先將該造粒機運 轉10秒鐘。除掉在10秒鐘内得到的造粒物後，再開動該 造粒機’收取在30秒鐘内所得的造敉物’將該造粒物在 7(TC乾燥30分鐘，而得農藥顆粒狀祖成物1 ° 製造例2 農藥顆粒狀組成物2的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重里份 (農藥活性化合物1. 5重量份），粉狀農藥組成物1的2. 9 重量份（農藥活性化合物2. 0重量份）’粉狀農藥組成物2 的1. 1重量份（農藥活性化合物0. 75重量份），預糊化殿粉 (商品名：amy 1 ox No. 1A，日本玉米丨殿粕么司製）的5. 〇 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的10. 0 重量份，蒙脫石（商品名：蒙脫石穗高’豐順公司製）的7. 5 重量份，及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司 製）的68· 1重量份的混合物中，加入含有界面活性劑（聚氧 伸乙基三苯乙烯基苯基醚’ Sorpol T-2〇(註冊商標）’東邦 化學工業製）1· 0重量份的水約20重量份’而混練。所得 混練物的約1.5kg投入於附有〇·9_0筛網的籃变擠出造 粒機（HU-G型畑式造粒機，畑製作所製）’先將該造粒機運 轉10秒鐘。除掉在10秒鐘内得到的造粒物後’再開動該 造粒機，收取在30秒鐘内所得的造粒物，將該造粒物在 7(TC乾燥30分鐘，而得農藥顆粒狀組成物2 ° 製造例3 農藥顆粒狀組成物3的調製 323181 17 201208566 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物1的2. 9 重量份（農藥活性化合物2. 0重量份），粉狀農藥組成物2 的1. 1重量份（農藥活性化合物0. 75重量份），預糊化澱粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5. 〇 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇.〇 重量份，蒙脫石（商品名：蒙脫石妙義，豐順公司製）的1〇· 0 重量份，及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司 製）的6 5. 6重量份的混合物中，加入含有界面活性劑（聚氧 伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標），東邦 化學工業製）1. 〇重量份的水約20重量份，而混練。所得 混練物的約1. 5kg投入於附有0. 9mm少篩網的籃型擠出造 粒機（HU-G型畑式造粒機，畑製作所製），先將該造粒機運 轉10秒鐘。除掉在10秒鐘内得到的造粒物後，再開動該 造粒機，收取在30秒鐘内所得的造粒物，將該造粒物在 70°C乾燥30分鐘，而得農藥顆粒狀組成物3。 製造例4 農藥顆粒狀組成物4的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物1的2. 9 重量份（農藥活性化合物2.0重量份），粉狀農藥組成物2 的1. .1重量份（農藥活性化合物0. 7 5重量份），預糊化殿粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5.〇 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的10.0 重量份，蒙脫石（商品名：Kunigel VA(註冊商標），Kunimine 18 323181 201208566 工業公司製）的10. 〇重量份，及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司製）的65.6重量份的混合物中，加入含 有界面活性劑（聚氧伸乙基三苯乙烯基苯基醚，s〇rp〇i T-20(註冊商標），東邦化學工業製）1.〇重量份的水約2〇 重量份，而混練。所得混練物的約1. 5kg投入於附有 〇.9mmp篩網的籃型擠出造粒機（HU-G型畑式造粒機，畑製 作所製）’先將該造粒機運轉10秒鐘。除掉在1〇秒鐘内得 到的造粒物後，再開動該造粒機，收取在3〇秒鐘内所得的 造粒物，將該造粒物在7(TC乾燥30分鐘，而得農藥顆粒 狀組成物4。 製造例5 農藥顆粒狀組成物5的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物丨的2. 9 重量份（農藥活性化合物2.0重量份），粉狀農藥組成物2 的1. 1重里伤（農藥活性化合物〇. 7 5重量份），預糊化搬粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5 〇 畫量份’重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇 〇 貧量份，蒙脫石（商品名：Kunigel V2(註冊商標），Kunimine 火業公司製）的10.0重量份’及蠟石（商品名：勝光山黏土 S ’勝光山鑛業公司製）的65· 6重量份的混合物中，加入含 有界面活性劑（聚氧伸乙基三苯乙烯基苯基醚，s〇rp〇1 T-20(註冊商標）’東邦化學工業製）ι.〇重量份的水約2〇 重量份’而混練。所得混練物的約1· 5kg投入於附有 〇. 9ππηφ篩網的籃型擠出造粒機（HU-G型畑式造粒機，畑製 323181 19 201208566 作所製），先將該造粒機運轉ι〇秒鐘。除掉在ίο秒鐘内得 到的造粒物後，再開動該造粒機，收取在30秒鐘内所得的 造粒物，將該造粒物在7〇°C乾燥30分鐘，而得農藥顆粒 狀組成物5。 製造例6 農藥顆粒狀組成物6的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物1的2. 9 重量份（農藥活性化合物2. 0重量份），粉狀農藥組成物2 的1. 1重量份（農藥活性化合物0. 75重量份），預糊化澱粉 (商品名：amyloxNo. 1A’日本玉米澱粉公司製）的.5. 0 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇.〇 重量份’蒙脫石（商品名Kim i bond，Kun imi工業公司製） 的10.0重量份，及蠟石（商品名：勝光山黏土 S，勝光山 鑛業公司製）的65. 6重量份的混合物中，加入含有界面活 性劑（聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商 標），東邦化學工業製）1. 0重量份的水約2 0重量份，而混 練。所得混練物的約1.5kg投入於附有〇.9顏φ篩網的籃 型擠出造粒機（HU-G型畑式造粒機，畑製作所製），先將該 造粒機運轉1〇秒鐘。除掉在1〇秒鐘内得到的造粒物後， 再開動該造粒機’收取在30秒鐘内所得的造粒物，將該造 粒物在70°C乾燥30分鐘，而得農藥顆粒狀組成物6-。 製造例7 農藥顆粒狀組成物7的調製 對粉狀農藥組成物1的2. 9重量份（農藥活性化合物 2. 〇重量份），粉狀農藥組成物2的1. 1重量份（農藥活性 20 323181 201208566 化合物0.75重量份），預糊化殿粉（商品名：amylox No. ΙΑ，日本玉米澱粉公司製）的5. 0重量份，重質碳酸鈣 (SS#80,曰東粉化工業公司製）的1〇.〇重量份，蒙脫石（商 品名：蒙脫石穗高，豐順公司製）的1〇.〇重量份，及蠟石（商 品名.勝光山黏土 S，勝光山鑛業公司製）的70.0重量份 的混合物中，加入含有界面活性劑（聚氧伸乙基三苯乙烯基 苯基醚，Sorpol T-20(註冊商標），東邦化學工業製）1.〇 重量份的水約20重量份，而混練。所得混練物的約1. 5kg 投入於附有0.9丽p篩網的籃型擠出造粒機（HU-G型畑式 造粒機’畑製作所製），先將該造粒機運轉10秒鐘。除掉 在10秒鐘内得到的造粒物後，再開動該造粒機，收取在 30秒鐘内所得的造粒物，將該造粒物在7〇°C乾燥30分鐘， 而得農藥顆粒狀組成物7。 製造例8 農藥顆粒狀組成物8的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物1的2. g 重量份（農藥活性化合物2. 0重量份），粉狀農藥組成物2 的Μ重量份（農藥活性化合物〇. 75重量份），預糊化澱粉 (商品名：amylox No. 1Α，日本玉米澱粉公司製）的5. 〇 重量份’重質碳酸i弓（SS#80，日東粉化工業公司製）的1〇. 〇 重置伤’象脫石（商品名.蒙脫石穩尚，豐順公司製）的2〇 〇 重量份’及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司 製）的55. 6重量份的混合物中，加入含有界面活性劑（聚氧 伸乙基二本乙稀基苯基謎，Sorpol Τ-20(·|主冊商標），東邦 323181 21 201208566 化學工業製）1. 〇重量份的水約20重量份，而混練。所得 混練物的約1.5kg投入於附有篩網的籃变擠出造 粒機（HU-G型畑式造粒機，畑製作所製），先將該造粒機運 轉10秒鐘。除掉在1〇秒鐘内得到的造粒物後，再開動該 造粒機，收取在3〇秒鐘内所得的造粒物，將該造粒物在 7〇 C乾燥30分鐘，而得農藥顆粒狀組成物8。 製造例9農藥顆粒狀組成物9的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物i的2. 9 重罝份（農藥活性化合物2.0重量份），粉狀農藥組成物2 的〇. 7重量份（農藥活性化合物〇. 5〇重量份），預糊化澱粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5. 〇 ί量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇0 重墨知，蒙脫石（商品名：蒙脫石穗高，豐順公司製）的20. 〇 重里份，及蠟石（商品名：勝光山黏土3，勝光山鑛業公句 製)的56.0重量份的混合物中，加入含有界面活性劑(聚氧 伸乙基三苯乙烯基苯基醚，Sorp〇1 τ_2〇(註冊商標），東邦 化學工業製儿〇重量份的水約2〇重量份，而混練。所得 處練物的約Ukg投入於附有〇.9_ _的藍型擠出造 粒機（HU-G型畑式造粒機’畑製作所製），切該造粒機遂 轉1M少鐘。.除掉在1G秒鐘内得到的造粒物後，再開動該 造粒機’收取在30秒鐘内所得的造粒物，將該造粒物在 70 c乾燥30分鐘，而得農藥顆粒狀組成物9。 製造例10農藥顆粒狀組成物10的調製 323181 22 201208566 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1. 5重量份），粉狀農藥組成物丨的2. 9 重量份（農藥活性化合物2.0重量份），粉狀農藥組成物2 的0· 7重里伤（辰藥活性化合物〇. 50重量份），預糊化殿粉 (商品名：amylox No. 1A ’日本玉米澱粉公司製）的5. 〇 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇.〇 重量份，蒙脫石（商品名：蒙脫石穗高，豐順公司製）的1〇. 〇 重量份，及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司 製）的6 6. 0重量份的混合物中，力σ入含有界面活性劑（聚氧 伸乙基三苯乙浠基苯基鍵，Sorpol Τ-20(註冊商標），東邦 化學工業製）1 · 0重量份的水約20重量份，而混練。所得 混練物的約1. 5kg投入於附有〇. 9mm ρ篩網的籃型擠出造 粒機（HU-G型畑式造粒機，畑製作所製），先將該造粒機運 轉10秒鐘。除掉在10秒鐘得到的造粒物後，再開動該造 粒機，收取在30秒鐘内所得的造粒物，將該造粒物在 乾燥30分鐘，而得農藥顆粒狀組成物1〇。 比較例1 對照農藥顆粒狀組成物1的調製 對含有農藥之熱硬化性樹脂微粉末1的4. 4重量份 (農藥活性化合物1· 5重量份）’粉狀農藥組成物1的2. 9 重量份（農藥活性化合物2. 0重量份），粉狀農藥組成物2 的1. 1重量份（農藥活性化合物0.75重量份），預糊化澱粉 (商品名：amylox No. 1A，日本玉米澱粉公司製）的5. 〇 重量份，重質碳酸鈣（SS#80,日東粉化工業公司製）的1〇 〇 重量份’及蠟石（商品名：勝光山黏土 S，勝光山鑛業公司 323181 23 201208566 製）的75.6重量份的混合物中，加入含有界面活性劑（聚氧 伸乙基三苯乙烯基苯基醚，Sorpol T^20(註冊商標），東邦 化學工業製）1· 〇重量份的水約20重量份’而混練。所得 混練物的約I 5kg投入於附有0. 9ππηΡ筛網的籃塑擠出造 粒機（HU-G型畑式造粒機，畑製作所製），先將該造粒機運 轉10秒鐘。除掉在10秒鐘内得到的造粒物後，再開動該 造粒機，收取在30秒鐘内所得的造粒物，將該造粒物在 7(TC乾燥30分鐘，而得對照農藥賴粒狀組成物1。 比較例2對照農藥顆粒狀組成物2的調製 對粉狀農藥組成物1的2. 9重量份（農藥活性化合物 2 0重量份）’粉狀農樂組成物2的1.1重里彳77 (農樂活性 化合物0.75重量份），預糊化澱粉（商品名：amyi〇x No. ΙΑ，日本玉米澱粉公司製）的5.〇重量份’重質碳酸轉 (ss#g〇，日東粉化工業公司製）的10. 0重量份’及蠟石（商 品名：勝光山黏土 s’勝光山鑛業公司製）的8〇.〇重量份 的混合物中，加入含有界面活性劑（聚氧伸乙基三苯乙烯基 苯基醚，Sorpol T-20(註冊商標），東邦化學工業製）1.0 重量份的水約20重量份，而混練。所得混練物的約1. 5kg 投入於附有0.9丽少篩網的籃型擠出造粒機（HU_G型畑式 造粒機，畑製作所製先將該造粒機運轉1〇秒鐘。除掉 在10秒鐘内得到的造粒物後，再開動該造粒機’收取在 3〇秒鐘肉所得的造粒物，將該造粒物在70°C乾燥30分鐘， 而得對照農藥顆粒狀組成物2。 試驗例1水稻的播種時覆土前處理對水稻之生育試驗 24 323181 201208566 在水稻育苗箱（30cmx6Ocm)的播種前覆土前將供試顆 - 粒狀組成物以1〇〇g/育苗箱的比率處理，將濕稻榖（品種： 1光）播種l60g。在育苗器（全日30。〇發芽3日後，移動 於屋外而官叫 上丨^ 另一 田，在播種1週後測量水稱（處理區）的草高。 樣方々、/測定除了不以顆粒狀組成物處理外’與前述同 複）:將1订播種及育曲的水稻（無處理區）的草高（二重 將處理區盥盔走 出生育率⑻:、;、&理11的草高以下述式（A)做對比而算 於第！表，，心j定基準評估生育狀況。將其結果示 [數1] (A) 生育率（％)= 區的草高[^2 《生育狀况的判定£:》理區的草高[叫χΐ〇〇 評估Commercially available compounds can be used for ς\ on. The pesticide particle composition of the present invention contains one or more of the active compounds for controlling plant diseases, but the content thereof is usually from about 1 to 25% by weight, preferably from 1 to 5% by weight. Further, the content ratio of the compound of the formula (I) and the plant disease controlling active compound contained in the pesticidal particulate composition of the present invention is about 100 to 5000 parts by weight based on 100 parts by weight of the compound of the formula (I). It is desirably about 100 to 600 parts by weight. The total content of the compound of the formula (I) and the plant disease controlling active compound in the pesticidal granular composition of the present invention is usually from about 1 to 30% by weight, preferably from about 1.5 to 7% by weight, more preferably about 1.5 to 5% by weight. 9 323181 201208566 The pesticide granular composition of the present invention may further contain other pesticidal compounds in addition to the compound of the formula (及) and the plant disease controlling active compound. Such other pesticidal active compounds are, for example, insecticidally active compounds, bactericidal active compounds, insect growth regulating active compounds, herbicidal active compounds, and plant growth regulating active ingredients. When the pesticide granular composition of the present invention contains other pesticides, and the tongue & compound, the content of the other pesticidal active compound in the *granular composition of the present invention is usually about 0.5 to 40 weights. /, Wang Zhizhi's theory is 1 to 10% by weight. The swell containing the swell and the rock stone mineral contained in the granule composition of the pesticide of the present invention may be a bentonite mineral itself or a mixture of a bentonite mineral and a substance other than the terrazzo mineral. For the ceramsite minerals, in detail, saponi t hectorite, sauconite, Stevensite, nontronite, and Mongolian Montmoril Ionite and beidellite, suitable beta can be montmorillonite. Specifically, as montmorillonite, montmorillonite, scorpion, montmorillonite, montmorillonite, montmorillonite, smectite, super clay (all are trade names, Hojun) The montmorillonite extender of Kunigel Vl, Kunigel V2, Kunigel VA, Kunibond (both registered trademarks, manufactured by Kunimine Industries Co., Ltd.) and Kansai montmorillonite (trade name, manufactured by Kanesan Industrial Co., Ltd.) is a swelled stone mineral and swelled. In the case of a mixture of substances other than the minerals, for example, as a mineral other than bentonite, for example, kaolinite, 323181 10 201208566 dickite, nacrite, halloysite, etc. Shangling stone minerals: chryS〇tile, lizardite, antig〇rite, amesite, serpentine, pyr〇phyiiite, Talc, sacred stone, muscovite, phengite, sericite, illite, etc. m; stone (crist〇balite), quartz (quartz) Etc. oxidized stone, attapulgite, sea Sediolite, such as sepiolite, sulphate minerals such as stone, dolomite, gypsum, zeolite, zeolite, tuff, vermiculite, laponite ), ore bearing materials such as pumice, Shixia, and calcium carbonate; plant line carriers such as corn cob powder, walnut shell powder, rice husk powder, wheat flour, wood flour, alfalfa, bran, and soybean powder; A water-soluble solid carrier of urea, lactose, sucrose, salt, thenardite or the like. In the pesticidal particulate composition of the present invention, the granules containing the bentonite minerals usually contain from about 4 to 98% by weight, preferably from about 60 to 95% by weight, based on the total of the pesticide granular composition of the present invention. When the extender in the pesticidal particulate composition of the present invention is a mixture of a bentonite mineral and a substance other than the bentonite mineral, the content of the bentonite mineral of the agricultural chemical particulate composition of the present invention may be, for example, : 5 to 40% by weight, desirably 5 to 20% by weight. The pesticide granular composition of the present invention contains a water-soluble binder. For the 34 kinds of binders, for example, sodium carboxymethyl cellulose, hydroxypropyl decyl cellulose, methyl cellulose, mercaptoethyl cellulose, hydroxypropyl cellulose, 323181 201208566 sodium polyacrylate, Astragalus gum, polyethylene pyrrolidone, polyvinyl alcohol, pre-gelatinized powder, dextrin, alginic acid and sodium alginate. The water-soluble binder in the granular composition of the pesticide of the present invention usually contains about 1 炱 10 by weight / β, preferably about 1 to 5% by weight. The pesticide granular composition of the present invention, in addition to the compound of the formula (I), the plant disease controlling active compound, the extender containing a bentonite mineral, and a water-soluble binder, together with any other pesticidally active compound optionally contained, It may also contain a surfactant, a solvent, a stabilizer, a preservative, a colorant, a fragrance, and the like. The granular granular composition of the present invention is prepared into a granular preparation by, for example, extrusion granulation, impregnation, or rubbing. The pesticide granular composition of the present invention contains the compound of the formula (I), the plant disease control active compound, the extender containing a bentonite mineral, and a water-soluble binder, and optionally contains other pesticides as needed. In a mixture of an active compound, a surfactant, a solvent, a stabilizer, a preservative, a coloring agent, a perfume, etc., water is added and kneaded. The obtained kneaded product is granulated, and the obtained granulated product is dried, and crushed and sieved as needed. Manufactured by whole grain, etc. In the aforementioned kneading, a blending machine can be used. The blender may be a kneader, a nauta mixer, a Loedige mixer or the like. The amount of water used in the kneading is usually a ratio of 3 to 50 parts by weight to 100 parts by weight of the aforementioned mixture. When the foregoing kneaded product is extruded and granulated, it is usually carried out using a sieve of 至. 5 to 2. 〇 妒, 12 323181 201208566 ideally 0.7 to 1 · 5 mm φ. The extrusion granulator to be used includes a screw type extrusion granulator, a roller type extrusion granulator, and a disk pel letor type extrusion. Granulator, pellet mill type, basket type extrusion granulator, plaid type extrusion granulator, oscillating extrusion granulator (oscillating type) ), gear type extrusion granulator, ring type extrusion granulator, and the like. Specifically, a twin dome granulator manufactured by Fuji Paudal Co., Ltd., a single dome granulator, or the like can be used. The granules of the granules of the granules of the present invention are usually from 0.5 to 6. Omm 'ideal is the granules of the granules of the granules of the present invention.至. 7 to 4. Omm. Further, in the present invention, the granule length is 'the maximum length which the granules can have. The granule composition of the pesticide of the present invention can be used at the time of sowing or after germination of the rice seedling box. It is applied to the nursery box at the time of rice seedling transplanted before the paddy field. The application 1 may vary depending on the compound of the formula (I) and the content of the plant disease control active compound and the size of the rice seedling box, but for example: 30 cm x 60 cm The rice seedling box per unit, the total amount of the compound of the formula (1) and the plant disease control active compound is about 〇. 5 to 4. 〇g. [Examples] Next, the present invention is referred to the production example. Comparative Example and Test Example are more detailed 13 323181 201208566 Detailed description 'But the present invention is not limited thereto. Reference Production Example 1 Preparation of Powdered Pesticides Composition 1 70.0 parts by weight of 2,-cyano-3,4-dichloro Isothiazol-5-carboxyaniline (general name: isothiophene)至############################################################################################################## A powdered pesticide composition containing 2'-cyano-3,4-dichloroisothiazol-5-carboxyaniline (hereinafter referred to as powdered pesticide composition 1) by reference (measured by MASTERSIZER 2000 manufactured by MALVERN). Example 2 Preparation of Powdered Pesticide Composition 2 70.0 parts by weight of the compound of the formula (I) and 30 parts by weight of the wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) were uniformly mixed and centrifuged. A powdery pesticide composition containing a compound of the formula (I) (hereinafter referred to as a powdery pesticide composition 2) having a volume median diameter of 3.92/zm (measured by MASTERSIZER 2000 manufactured by MALVERN) was obtained. 3 Preparation of powdered pesticide composition 3 70. 〇 by weight of (E)-l-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroindole ( General name: CLOTHIANIDIN) and 30.0 parts by weight of wax stone (trade name: Shengguangshan clay S, Shengguangshan Mining Co., Ltd.) Mixed and uniformly pulverized by a centrifugal pulverizer to obtain (E)-l-(2-chloro-1,3-thiazole--containing a volume median diameter of 8.20/m (measured by MALVERN MASTERSIZER2000) Powdered pesticide composition of 5-methylmethyl)-3-mercapto-2-nitroindole (hereinafter referred to as powdered pesticide composition 3). Preparation of thermosetting resin powder 1 containing agricultural chemicals according to Production Example 4 14 323181 201208566 46.3 parts by weight of SumiphenTM (registered trademark, manufactured by Sumitomo Bayer Urethane Co., Ltd., branched polyether polyol), 52.2 parts by weight of Sumiphen 1600U (registered trademark, manufactured by Sumitomo Bayer Urethane Co., Ltd., linear a polyether polyol), and 1.5 parts by weight of 2,4,6-tris(dimethylaminomethyl)phenol (manufactured by KAYAKUAKZ0) are uniformly mixed to obtain a liquid mixture of a polyalcohol and a catalyst (hereinafter referred to as It is a pre-polyol mixture 1). The viscosity of the pre-mix 1 of the polyalcohol was 322 m · Pa (measured by a B-type viscometer, 25 ° C, 12 turns, rotor No. 1). In the high-speed mixer device (Model FS-GS-25 manufactured by Deepwater Powteck Co., Ltd.; the vertical line in which the vertical line of the bottom surface of the container portion penetrating the disk-shaped portion is the rotary shaft and the horizontal line of the side surface of the container portion penetrating the disk-shaped portion are In a container of the device for cutting chips of the rotary shaft, 100 parts by weight of the powdery agrochemical composition 3 was placed, and the stirring piece (rotation number: 382 rpm) of the apparatus and the chips (revolution number: 3500 rpm) were rotated. Next, the mixing container was heated, and the pre-polyol premix 1 of 1.93 parts by weight was added for 2 minutes while maintaining the temperature of the powdery pesticide composition 3 at 85 ± 5 °C. It was observed that the pre-polyol mixture 1 was wetted by the powdery pesticide composition 3. After 3 minutes, the product temperature was maintained at 85 ± 5 ° C. A fee of 2 minutes was added. 〇 7 parts by weight of Sumi jul 44V10 (registered trademark, polymethylene polyphenyl polyisocyanate, manufactured by Sumitomo Bayer Urethane Co., Ltd., Viscosity 130m · Pa (25 ° C)). Immediately after the addition, the viscosity-increasing phenomenon was confirmed, and the viscosity was lowered, and the polyurethane resin was hardened (for 100 parts by weight of the powdery agrochemical composition 3, which corresponds to 3. 〇 by weight of the polyurethane resin). After 6 minutes, the product temperature was maintained at g5 ± 5 〇 c, and the following addition operation of urethane was repeated 34 times. 323181 15 201208566 [Addition operation of ethyl urethane] 1.93 parts by weight of the pre-polyalcohol mixture 1 is added for 2 minutes, and s is waited for 3 minutes - 1.07 parts by weight of Sumi jul 44V10 is added for 2 minutes - wait 6 minute. In the above-described addition operation of the urethane ethyl ester, the high-speed mixer apparatus is continuously mixed with the inducing plant having a frying force under the same conditions. To 100 parts by weight of the powdery agrochemical composition 3, a total of 1 〇 5 parts by weight of a polyurethane resin raw material was added. After the above operation was completed, 4.% by weight of carbonated mother NS#2300 (manufactured by Nitto Powder Chemical Co., Ltd.) was added and mixed for 3 minutes. After mixing, the mixture is cooled to obtain a curable resin fine powder in which the powdery agrochemical composition 3 is fixed by a polyurethane resin (hereinafter referred to as a thermosetting resin fine powder 1 containing a pesticide; volume median particles) The diameter of 44: / m, bulk density (apparent density): 〇. 42g / ml) 〇 Production Example 1 Preparation of the pesticide granular composition 1 to the pesticide containing thermosetting resin fine powder 1 of 4.4 Parts by weight (1.5 parts by weight of the agrochemical active compound), 29 parts by weight of the powdered pesticide composition 2.0 (2.0 parts by weight of the pesticide active compound), 1.1 parts by weight of the powdered pesticide composition 2 (0.75 parts by weight of the pesticide active compound) ), a pre-gelatinized powder (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), 5 parts by weight of 'heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Co., Ltd.) 1 part by weight of montmorillonite (trade name: montmorillonite spike high), and wax stone (trade name: Shengguangshan clay s, manufactured by Shengguangshan Mining Co., Ltd.) 65. 6 Adding a surfactant (polyoxygen) in a mixture of parts by weight Ethyl cicada two ethyl phenyl ether, Sorpol T ~ 20 (registered trademark) 323 181 16 201 208 566 Toho Chemical Industries, Ltd.) 1 parts by. Weight of water from about 20 billion weight Die 'and kneading. About 1.5 kg of the kneaded material was put into a basket splitting granulator (HU-G type granulator), which was attached to the G.gnnnW _ net, and the granulator was first operated 10 Seconds. After removing the granules obtained in 10 seconds, the granulator was started to 'receive the cres obtained in 30 seconds'. The granules were dried at 7 (TC for 30 minutes, and the pesticide granules were obtained). The granules of the granules of the granules of the granules of the granules of the granules of the granules 1 重量份 (pesticide active compound 2.0 parts by weight) '1. 1 part by weight of the powdered pesticide composition 2 (pesticide active compound 0. 75 parts by weight), pre-gelatinized powder (product name: Amy 1 ox No. 1A, 5. 重量重量份, 蒙石石((##80, manufactured by Nitto Powder Chemical Industry Co., Ltd.) Product name: 7.5 parts by weight of montmorillonite sorghum 'made by Fengshun Co., Ltd., and 68. 1 part by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) Containing a surfactant (polyoxy-extended ethyltriphenylstyrene-phenyl ether 'Sorpol T-2〇 (registered trademark)' Toho Chemical Industry Co., Ltd.) 0 parts by weight of water is about 20 parts by weight 'mixed. About 1.5 kg of the obtained kneaded material is put into a basket-type extrusion granulator with a 〇·9_0 sieve (HU-G type granulator, 畑 畑 畑The system was first operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was restarted and the granules obtained within 30 seconds were collected. 4重量份。 The granules were dried at 30 ° for 30 minutes, and the pesticide granule composition was 2 °. Production Example 3 Preparation of the pesticide granule composition 3 323181 17 201208566 4. 4 parts by weight of the thermosetting resin fine powder 1 containing the pesticide 1重量份(Pesticide-active compound) 2. 9 parts by weight of the powdered pesticide composition 1 (pesticide active compound 2.0 parts by weight), powdered pesticide composition 2 0. 75 parts by weight), 5. by weight of pre-gelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.) 1〇·〇 by weight, montmorillonite (trade name: montmorillonite Miaoyi, manufactured by Fengshun Co., Ltd.) 1〇· 0 parts by weight, and wax stone Trade name: Shengguangshan Clay S, 6 5.6 parts by weight of the mixture, added with surfactant (polyoxy-extended ethyltristyrylphenyl ether, Sorpol T-20 (registered) The basket-type extrusion granulator with a mesh of 0. 9mm is placed in a sieve with a sieve of 0. 9mm (with a mesh of about 9 parts by weight). The HU-G type granulator was manufactured by Nippon Seisakusho Co., Ltd., and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain pesticide granules. Composition 3. The weight of the powdered pesticide composition 1 is 2. 4 parts by weight of the pesticide-containing thermosetting resin fine powder 1 (4 parts by weight of the pesticide active compound). Part (1.2 parts by weight of the agrochemical compound), 1.1 parts by weight of the powdered pesticide composition 2 (pesticide active compound 0.75 parts by weight), pre-gelatinized powder (trade name: amylox No. 1A, Japan) 5% by weight of heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.), montmorillonite (trade name: Kunigel VA (registered trademark), Kunimine 18 323181 10.085 parts by weight of the 201208566 industrial company, and 65.6 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.), containing a surfactant (polyoxy-extension ethyl three) Styryl phenyl ether, s〇rp〇i T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) 1. About 2 parts by weight of water, and mixed. About 1.5 kg of the obtained kneaded material was put into a basket type extrusion granulator (HU-G type granulator, manufactured by Nippon Seisakusho Co., Ltd.) with a 〇.9 mmp sieve. The granulator was operated for 10 seconds. bell. After removing the granules obtained in 1 second, the granulator was started, and the granules obtained in 3 sec. were collected, and the granules were dried at 7 (TC for 30 minutes). 4 重量份 (1. 5 parts by weight of agrochemically active compound), a powdered pesticide composition. The preparation of the pesticide granules is as follows. 2. 9 parts by weight of the substance (2.0 parts by weight of the pesticide active compound), 1.1 parts of the powdered pesticide composition 2 (pesticide active compound 〇. 75 parts by weight), pre-gelatinized powder (product name: Amylox No. 1A, 5 parts of the amount of heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.), montmorillonite (trade name: Kunigel) V6 (registered trademark), Kunimine Fire Co., Ltd.) 10.0 parts by weight of 'and wax stone (trade name: Shengguangshan clay S 'Shengguangshan Mining Co., Ltd.) 65.6 parts by weight of the mixture, including the surfactant (Polyoxyethylene ethyltristyrylphenyl ether, s〇rp〇1 T-20 (registered trademark)' East邦. 〇 〇 〇 〇 〇 约 约 约 约 约 约 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Type granulator, manufactured by 323181 19 201208566, first run the granulator for 1 second. After removing the granules obtained in ί seconds, the granulator is activated. The granulated product obtained in 30 seconds was collected, and the granulated product was dried at 7 ° C for 30 minutes to obtain a pesticide granular composition 5. Production Example 6 Preparation of Pesticide Granular Composition 6 For pesticides 4 parts by weight (pesticide active compound 1.5 parts by weight), 2.9 parts by weight of the powdered pesticide composition 1 (pesticide active compound 2.0 parts by weight), powdered pesticide 1重量份的质量质量质量。 1. 1 part by weight of the composition 2 (pesticide active compound 0. 75 parts by weight), pre-gelatinized starch (trade name: amyloxNo. 1A' Japan Corn Starch Co., Ltd.). 5 parts by weight, heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.) 1 〇. 〇 by weight 'montmorillonite (trade name Kim i bond, Kun imi industrial 10.0 parts by weight, and 65.6 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.), containing a surfactant (polyoxyethylene striphenylyl) Phenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.) 1. 0 parts by weight of water, about 20 parts by weight, and kneaded. About 1.5 kg of the obtained kneaded material was put in with 〇.9 颜A basket type extrusion granulator (HU-G type granulator, manufactured by Nippon Seisakusho Co., Ltd.) was used to run the granulator for 1 second. After removing the granules obtained in 1 second, the granulator was started to collect the granules obtained in 30 seconds, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide. Granular composition 6-. Manufactured Example 7 Preparation of Pesticide Granular Composition 7 To 1.9 parts by weight of the powdered pesticide composition 1 (pesticide active compound 2. 〇 by weight), 1.1 parts by weight of the powdered pesticide composition 2 (pesticide activity) 20 323181 201208566 Compound 0.75 parts by weight), 5.0 parts by weight of pre-gelatinized powder (trade name: amylox No. ΙΑ, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Jidong Powder Chemical Industry) 1 part. 〇 by weight of the company, montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), 〇. 〇 by weight, and wax stone (trade name. Shengguangshan clay S, win 70.0 parts by weight of a mixture prepared by K.K., Ltd.), containing a surfactant (polyoxyethylene striphenylstyrene ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) The water is about 20 parts by weight and is mixed. About 1.5 kg of the obtained kneaded material was put into a basket type extrusion granulator (manufactured by HU-G type granulator) manufactured by a 丽 p 筛 screen, and the granulator was operated for 10 seconds. bell. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 7 ° C for 30 minutes to obtain a pesticide. Granular composition 7. Manufactured Example 8 Preparation of Pesticide Granular Composition 8 4. 4 parts by weight of the thermosetting resin fine powder 1 containing the pesticide (1.5 parts by weight of the pesticide active compound), 2. g by weight of the powdered pesticide composition 1. Parts (2.0 parts by weight of the pesticide active compound), Μ by weight of the powdered pesticide composition 2 (pesticide active compound 〇. 75 parts by weight), pregelatinized starch (trade name: amylox No. 1 Α, Japanese corn starch company) 5. 〇 重量 重量 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 2 parts by weight of the company) and 55.6 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.), containing a surfactant (polyoxyethylene) This vinyl phenyl mystery, Sorpol Τ-20 (·|main volume trademark), Toho 323181 21 201208566 Chemical Industry) 1. About 20 parts by weight of water, and mixed. About 1.5 kg of the obtained kneaded product was placed in a basket-extruded granulator (HU-G type granulator, manufactured by Nippon Seisakusho Co., Ltd.) with a sieve, and the granulator was first run for 10 seconds. After removing the granules obtained in 1 second, the granulator was started, and the granules obtained in 3 seconds were collected, and the granules were dried at 7 ° C for 30 minutes. Pesticide granular composition 8.重量重。 The phytochemical composition of the physicochemical composition of the physicochemical composition罝 (2.0 parts by weight of the pesticide active compound), 〇. 7 parts by weight of the powdered pesticide composition 2 (pesticide active compound 〇. 5 〇 parts by weight), pregelatinized starch (trade name: amylox No. 1A, Japanese corn) 5. 量 量 量 , , , , , , , 重 重 重 重 重 重 重 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( 20% by weight of the 顺 里 里 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Styryl phenyl ether, Sorp〇1 τ_2〇 (registered trademark), Toho Chemical Industry Co., Ltd. 〇 〇 〇 〇 〇 〇 〇 约 约 约 约 约 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Blue type extrusion granulator (manufactured by HU-G type granulator), cut and granulated 1M less clock. After removing the granules obtained in 1G seconds, the granulator was activated to collect the granules obtained in 30 seconds, and the granules were dried at 70 c for 30 minutes. 4重量份(Pesticide active compound 1.5 parts by weight). Manufacture of the granules of the granules of the granules of the granules of the granules of the granules. 2. 9 parts by weight of the powdered pesticide composition (2.0 parts by weight of the pesticide active compound), 0. 7 weight loss of the powdered pesticide composition 2 (50 parts by weight of the active compound of the drug), pre-gelatinized temple 5% by weight of powder (product name: amylox No. 1A 'made by Japan Corn Starch Co., Ltd.), 1 part by weight of heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Co., Ltd.), montmorillonite (product name: montmorillonite sorghum, manufactured by Fengshun Co., Ltd.) 1 〇. 〇 by weight, and a mixture of 0.66 parts by weight of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) Medium, force σ into the inclusion of surfactant (polyoxy-extension ethyltriphenylethyl phenyl bond, Sorpol Τ-20 (registered The trademark of the company is made up of about 0 parts by weight of water and about 20 parts by weight, and the mixture is kneaded. About 1.5 kg of the obtained kneaded product is put into a basket type extrusion granulator with a 9 mm ρ screen. The HU-G type granulator was made by 畑 畑, and the granulator was run for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started and charged for 30 seconds. The granules obtained in the granules were dried for 30 minutes to obtain a granule-like composition of the pesticide. Comparative Example 1 Preparation of Comparative Pesticide Granular Composition 1 Thermosetting resin fine powder containing a pesticide 4重量份的份的生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生生1 part by weight (0.75 parts by weight of the agrochemical active compound), 5. Pre-gelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.) 5. 〇 by weight, heavy calcium carbonate (SS#80, Nitto Powder 1 part by weight of industrial company) and wax stone (trade name: Shengguangshan clay S, Shengguangshan Mining Company) In a mixture of 75.6 parts by weight of 323181 23 201208566, a surfactant (polyoxyethylene striphenylstyrene ether, Sorpol T^20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. A portion of water is about 20 parts by weight 'mixed. About 1.5 kg of the obtained kneaded material was put into a basket-type extrusion granulator (HU-G type granulator, manufactured by Nippon Seisakusho Co., Ltd.) with a 0.9 ππηΡ sieve, and the granulator was operated for 10 seconds. . After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 7 (TC for 30 minutes to obtain a control pesticide). </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> 1.1 zhongli 彳 77 (0.75 parts by weight of active chemical compound), pre-gelatinized starch (trade name: amyi〇x No. ΙΑ, manufactured by Japan Corn Starch Co., Ltd.) 5. 〇 by weight 'heavy carbonic acid conversion (ss#g 10, Nitto Powder Chemical Co., Ltd.), 1.0 parts by weight of 'and wax stone (trade name: Shengguangshan clay s' Shengguangshan Mining Co., Ltd.) (5. 5kg input of the obtained kneaded material. The amount of the kneaded product is about 1. 5kg. Basket-type extrusion granulator with 0.9 ray screen (HU_G type granulator) The granulator was operated for 1 sec. After the granules obtained in 10 seconds were removed, the granulator was started to collect granules obtained in 3 sec. of the granules, and the granules were granulated. Dry at 70 ° C for 30 minutes, and obtain the control pesticide granular composition 2. Test Example 1 Rice seeding pre-treatment of rice before the fertility test on rice 24 323181 201208566 Before the planting of the rice seedling box (30cmx6Ocm) Test granules - The granular composition was treated at a ratio of 1 〇〇 g / seedling box, and the wet rice blast (variety: 1 light) was sown for l60 g. In the seedling device (all day 30. 〇 germination for 3 days, moved outside the house and called Shangyu ^ Another field, after 1 week of sowing, measure the grass height of the water scale (treatment area). The sample square 々, / determination is not treated with the granular composition 'the same as the above): 1 seeding and breeding The grass height of the rice (without treatment area) (the double weight will be taken out of the fertility rate in the treatment area (8):;;, &, the grass height of the law 11 is compared with the following formula (A) and counted in the table! The heart is determined by benchmarking the birth status. The results are shown in [1] (A) Fertility rate (%) = grass height in the area [^2 "Birth Conditions determine £: "management area of tall grass [called χΐ〇〇 assessment
生育率 98%以上 以上未達g 89%以上未達g 85%以上未達g 未達85% 323181 25 201208566 [第1表] 供試顆粒劑組成物 生育狀況 農藥顆粒狀組成物1 _ 農藥顆粒狀組成物2 _ 農藥顆粒狀組成物3 — 農藥顆粒狀組成物4 _ 農藥顆粒狀組成物5 — 農藥顆粒狀組成物6 — 農藥顆粒狀組成物7 _ 農藥顆粒狀組成物8 — 農藥顆粒狀組成物9 — 農藥顆粒狀組成物10 _ 對照農藥顆粒狀組成物1 + + + 對照農藥顆粒狀組成物2 + + 【圖式簡單說明】 無 【主要元件符號說明】 無 26 323181Fertility rate of 98% or more does not reach g 89% or more does not reach g 85% or more does not reach g, does not reach 85% 323181 25 201208566 [Table 1] Test granule composition growth status Pesticide granular composition 1 _ Pesticide granule Composition 2 _ pesticide granular composition 3 - pesticide granular composition 4 _ pesticide granular composition 5 - pesticide granular composition 6 - pesticide granular composition 7 _ pesticide granular composition 8 - pesticide granular Composition 9 - Pesticide Granular Composition 10 _ Control Pesticide Granular Composition 1 + + + Control Pesticide Granular Composition 2 + + [Simple Description] No [Main Component Symbol Description] None 26 323181
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| JP6862718B2 (en) * | 2015-09-07 | 2021-04-21 | 住友化学株式会社 | Coated rice seeds and their manufacturing methods |
| JP6862719B2 (en) * | 2015-09-07 | 2021-04-21 | 住友化学株式会社 | Coated rice seeds and their manufacturing methods |
| TW202139840A (en) | 2020-01-14 | 2021-11-01 | 日商拜耳作物科學股份有限公司 | Granular agricultural chemical composition for rice seedling raising box with which harmful effects are reduced |
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| JP4722581B2 (en) * | 2005-06-27 | 2011-07-13 | 住友化学株式会社 | Insecticide composition |
| JP2009073820A (en) * | 2007-08-31 | 2009-04-09 | Sumitomo Chemical Co Ltd | Granular agrichemical composition |
| EP2070413A1 (en) * | 2007-12-11 | 2009-06-17 | Bayer CropScience AG | Active compound combinations |
| KR101570536B1 (en) * | 2008-05-16 | 2015-11-19 | 수미토모 케미칼 컴퍼니 리미티드 | Agrichemical granules |
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| JP2010090089A (en) * | 2008-10-10 | 2010-04-22 | Sumitomo Chemical Co Ltd | Composition for controlling harmful organism and method of controlling harmful organism |
| WO2011083709A1 (en) * | 2010-01-08 | 2011-07-14 | 住友化学株式会社 | Granular agrochemical composition |
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