JP3821973B2 - Pesticide granular wettable powder and method of using the same - Google Patents

Description

評価基準
Ａ：投入直後から２分以内に原形を失うまで崩壊した。
Ｂ： 〃 ４分以内 〃
Ｃ： 〃 原形を失うまで崩壊するのに１０分以上かかった。
【００３４】
試験例３（育苗箱中の培土への薬剤の残存率試験）
（１）育苗箱：予め慣行の種子予措を行った稲籾（品種：コシヒカリ）を、標準育苗箱（３０ｃｍ×６０ｃｍ×３ｃｍ）に箱あたり１８０ｇ（乾籾相当量）播種し、移植時期（２．８葉期）まで栽培管理しこの稚苗を供試した。
なお、培土は市販の人工粒状培土（くみあい合成培土３号：三井東圧製）を用い、床土１８０ｍＬ、覆土１２０ｍＬ／箱とした。
（２）薬剤処理：実施例1−５および比較例１−５の供試薬剤を、箱内に均一になるように、稲苗の上から所定量（３０〜５０ｇ／箱）散粒し、その後葉や茎に付着した粒状水和剤を覆土上に落とすため、苗を手で十分払った後、箱当たり５００ｍＬの水を灌水した。
（３）評価方法：灌水後１０分間静置した後、バットの上で育苗箱を垂直に立てた状態にし、５回軽く左右に揺すった。バットに落ちた粒状水和剤を回収し液体クロマトグラフィーで分析し、回収して、農薬活性成分量を求めた。そして、回収した農薬活性成分量と予め処理した農薬活性成分量とから、培土に残存している農薬活性成分残存率を算出した。
【００３５】
【数１】

その結果は表２のとおりである。
【００３６】
【表２】

これらの結果から了解されるように、本発明にかかる実施例1−５は、崩壊性が良好であり、いずれも比較例１−５に対し、優れた残存率を示し、育苗箱から脱落する量がほとんどなかった。
【００３７】
【発明の効果】
上記したところから明らかなように、本発明を実施すると、次のような効果がもたらされる。すなわち、第１に、育苗箱に散布すると、稲の株元に到着し、育苗培土に固着する。その結果、育苗箱を手で振動させても薬剤が脱落しない。その結果、高い防除効果が発揮されるようになる。
また、第２に、育苗箱から脱落する量がほとんどなくなるから、従来の粒剤の使用量に比べて少薬量の使用でよく、しかも、従来以上の防除効果が発揮される。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an agrochemical granular wettable powder suitable for application to a seedling box and a method for using the seedling box.
[0002]
[Prior art]
As a method of treating pesticides in a rice seedling box, conventionally, (1) a method of spraying from the seedling of rice, (2) a method of treating after seeding and before covering, (3) after seeding and covering There are four methods: a method of treating on the soil covering, (4) a method of mixing with the floor soil of the seedling box, seeding on the soil, and covering the soil. Compared to spraying to paddy fields, the chemical treatment method for these seedling boxes has the advantage that it can be sprayed in a short time and requires only a small amount of spraying. Is excellent.
In particular, the method of spraying from the seedlings of rice has been widely used in recent years, because many agricultural chemicals have been developed according to the treatment method. Pesticide dosage forms used in these seedling box treatments are mainly granules.
Since the granule has a large particle size, the drug can reach the plant origin if it is sprayed as it is from the seedling. However, in the case of conventional granules, after the drug is processed in the seedling box, it reaches the root of the stock by the vibration when transporting the seedling box and the vibration when trying to remove the seedling from the box to transplant it to Honda. The drug particles fall from the soil surface in the box. As a result, the desired pest control effect may not be fully exhibited.
[0003]
[Problems to be solved by the invention]
Therefore, as a method of spraying the drug to the rice seedling box, it is desired to develop a preparation that can provide the desired high control effect without causing the drug to fall out of the seedling box even if the seedling box is slightly vibrated. Is the actual situation.
Under such circumstances, the object of the present invention is to pay attention to the granular wettable powder in which the wettable powder is formulated into granules, suitable for post-treatment of the seedling box covering soil, or suitable for spraying from the seedling. And providing an excellent agrochemical granular wettable powder and a method of using the same.
[0004]
[Means for Solving the Problems]
The present inventors diligently studied to solve these problems. As a result, the above-mentioned problems can be solved by applying the granular wettable powder originally developed for the purpose of drug treatment by diluting with water without applying treatment such as diluting with water, and applying it directly to the seedling box. I found out.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
In the method of using the pesticide granular wettable powder for the seedling box according to the present invention, "apply as it is to the seedling box" refers to the pesticide granular wettable powder for the seedling box in the period immediately before transplanting from the seedling box after covering Is not diluted with water from the seedling box after covering the soil or on the seedlings in the seedling box, and is sprayed as it is while maintaining the granular dosage form. In general, the wettable powder is poured into a large amount of water and stirred to form a uniform suspension, which is sprayed with a spreader. The present invention breaks such common sense.
By such an application method, the grains fall to the seedlings of the seedlings, and the fallen grains are easily disintegrated and diffused into fine particles by water in the culture medium in the box or by irrigation after spraying the medicine. At the same time, penetrating agent and surfactant contained in the preparation improve permeability to the soil and adherence. Furthermore, since the fall of the agrochemical active ingredient from the seedling box is suppressed, the action on the plant body is stabilized and a desired effect is obtained.
The agrochemical granular wettable powder according to the present invention can be applied as a soil covering pretreatment method and a floor soil mixing treatment method in addition to the application method described above. Even if it does in this way, there is no problem. In the soil covering pretreatment method, after sowing the seedling box, the agrochemical granular wettable powder is dispersed and applied so as to cover the soil. Can be applied as a soil for seedling boxes, seeded on the seedling box, and further covered with a granular soil.
[0006]
Furthermore, the present inventors have found that the agrochemical granular wettable powder has an average dispersed particle size (hereinafter simply referred to as “average particle size”) of 15 μm or less and 25 μm or less when diluted and dispersed with water. The inventors have found that particles having a particle size of 80% by weight or more and 10 μm or less are 40% by weight or more are useful as a box application agent, and have found that the above-described problems can be solved.
Further, the average particle size is larger than 15 μm, or the particle size of 25 μm or less is less than 80% by weight. Alternatively, if the number of particles of 10 μm or less is less than 40% by weight, the particle disintegration and diffusibility are deteriorated, and a desired effect cannot be obtained.
The average particle size and particle size distribution were measured by the methods of test examples described later.
[0007]
Next, the agrochemical granular wettable powder according to the present invention will be specifically described. The agrochemical granular wettable powder according to the present invention is composed of a composition comprising an agrochemical active ingredient, a surfactant, a binder and a carrier.
[0008]
The agrochemical active ingredient of the agrochemical granular wettable powder according to the present invention may be any insecticide, fungicide, or the like that is generally used as an agrochemical, and one or more of these may be used in combination. . Examples of such pesticidal active ingredients include the following.
[0009]
Examples of insecticides include diazinon, PHC, cartap, carbosulfan, benfuracarb, bensultap, fipronil, propaphos and the like.
Examples of fungicides Kasugamycin, flutolanil, pencyclon, validamycin, probenazole, isoprothiolane, pyroxylone, flametopyr, tricyclazole, azoxystrobin and the like can be mentioned.
The amount of these agrochemical active ingredients added to the preparation is not particularly limited, but is generally 0.01 to 90% by weight, preferably 0.1 to 60% by weight, based on the total amount of the preparation.
In addition, these agrochemical active ingredient names are general names described in “Agricultural Chemicals Handbook 1994” (published by the Japan Plant Protection Association).
[0010]
Surfactants that can be used in the present invention include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Specifically, the following can be used. .
[0011]
Nonionic surfactants Polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkylate, polyoxyethylene phenyl ether polymer, Examples include polyoxyethylene alkylene aryl phenyl ether, polyoxyethylene alkylene glycol, and polyoxyethylene / polyoxypropylene block polymer.
[0012]
Anionic surfactants Lignin sulfonates such as sodium lignin sulfonate and calcium lignin sulfonate, alkylaryl sulfonates such as sodium alkylaryl sulfonate, calcium alkylaryl sulfonate, and ammonium alkyl aryl sulfonate Examples thereof include salts, dialkyl sulfosuccinates, polyoxyethylene alkyl aryl ether sulfates, alkyl naphthalene sulfonates such as sodium alkyl naphthalene sulfonate, polyoxyethylene styryl phenyl ether sulfate, and the like.
[0013]
Cationic surfactants Alkylamine salts and the like can be mentioned.
Amphoteric surfactants Quaternary ammonium salts, alkylbetaines, amine oxides and the like can be mentioned.
[0014]
The surfactant that can be used in the present invention is not limited to these, and there is no problem even if one or more of these are used in combination. Moreover, the addition amount of these surfactant is not specifically limited, However, 0.1-30 weight part is desirable in a formulation from an effect and economical efficiency.
[0015]
Although the binder which can be used by this invention is not specifically limited, For example, the following can be mentioned.
Starch, dextrin, cellulose, methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethyl starch, pullulan, sodium alginate, ammonium alginate, propylene glycol ester alginate, guar gum, locust bean gum, gum arabic, xanthan gum, gelatin Casein, polyvinyl alcohol, polyethylene oxide, polyethylene glycol, ethylene / propylene block polymer, sodium polyacrylate, polyvinyl pyrrolidone, and the like.
[0016]
These 1 type (s) or 2 or more types can be used together. Moreover, although the addition amount of these binders is not specifically limited, 0.1-40 weight part is desirable in a formulation from an effect and economical efficiency.
[0017]
The carrier that can be used in the present invention may be an inorganic carrier or an organic carrier. Although not particularly limited, for example, the following can be mentioned.
Inorganic support <br/> Clay, bentonite, talc, calcium carbonate, sodium carbonate, dikelite, sericite, acid clay, quartzite, diatomaceous earth, pumice, zeolite, vermiculite, potassium chloride, urea, white carbon, ammonium sulfate, sodium sulfate , Perlite, magnesium sulfate and the like.
Organic carriers Glucose, maltose, sucrose, lactose and the like can be mentioned.
These inorganic carriers or organic carriers can be used alone or in combination of two or more. Of course, an inorganic carrier and an organic carrier can be used in combination.
[0018]
Moreover, the agrochemical granular wettable powder concerning this invention can contain an adjuvant further in addition to the above-mentioned component. For example, an antiseptic and fungicidal agent and a solvent can be contained, and an antioxidant, an ultraviolet ray inhibitor, a crystal precipitation inhibitor and the like can be added as needed as stabilizers for the agrochemical active ingredient. However, it is not limited to the adjuvant illustrated in this way.
[0019]
For example, as the solvent that can be used in the present invention, polybasic acid alcohol esters such as isobutyl adipate, dioleyl adipate, diisodecyl adipate, diethylhexyl phthalate, didecyl phthalate, 2-ethylhexyl trimellitic acid, triisodecyl trimellitic acid , Fatty acid alcohol esters such as cetyl 2-ethylhexanoate, coconut fatty acid cetyl, methyl laurate, methyl myristate, methyl oleate, octyl oleate, polyhydric alcohol fatty acid esters such as sorbitan monolaurate, sorbitan monooleate, Higher alcohols such as octyl alcohol and lauryl alcohol, 1,2-dimethyl-4-ethylbenzene, methylnaphthalene, 1-phenyl-1-xylylethane, 1-xylyl-1,3-diphenyl And aromatic hydrocarbons such as butane can be used.
[0020]
Although the preparation method of the agrochemical granular wettable powder concerning this invention is not specifically limited, It can prepare with the following method.
For example, an agrochemical active ingredient is mixed with a surfactant, a binder, and a carrier, and if necessary, an auxiliary agent such as a preservative and fungicide or a stabilizer for an agrochemical active ingredient. After granulation, drying and sizing.
Further, it may be granulated with a tumbling granulator while adding water, dried and sized. Further, the powder mixture before addition of water may be dispersed in water and granulated by a spray granulator, or a binder solution or an agrochemical active ingredient may be sprayed while the powder mixture is flowing. You may granulate with the fluidized-bed granulator which granulates.
The particle size of the pesticidal granular wettable powder according to the present invention is desirably in the range of 0.1 to 10 mm to the same extent as that of the conventional granular preparation.
[0021]
【Example】
Next, the present invention will be described more specifically with reference to the following examples, but the present invention is not limited thereto. In the following description, “parts” means all parts by weight.
Example 1
2 parts of kasugamycin hydrochloride, 5 parts of sodium lignin sulfonate, 3 parts of sodium dodecylbenzenesulfonate, 5 parts of solubilized starch and 85 parts of clay were mixed with a hammer mill (manufactured by Fuji Powder Co., Ltd.). Thereafter, 13 parts of water was added to 100 parts of the mixture, and kneaded and mixed with a double-arm kneader (manufactured by Fuji Powder Co., Ltd.). Next, the mixture is granulated with an extrusion granulator (manufactured by Nippon Pharmaceutical Co., Ltd.) equipped with a 0.8 mm diameter screen, further dried with a fluidized bed dryer (manufactured by Fuji Powder Co., Ltd.), and sieved. An agrochemical granular wettable powder of 0.6 to 1.0 mm was obtained. The average particle size of the obtained agrochemical granular wettable powder was 92% by weight for particles of 10 μm and 25 μm or less, and 60% by weight for particles of 10 μm or less.
[0022]
Example 2
2 parts of kasugamycin hydrochloride, 2 parts of sodium lauryl sulfate, 5 parts of polyoxyethylene styryl phenyl ether, 5 parts of pullulan and 86 parts of magnesium sulfate were mixed with a hammer mill. Thereafter, 14 parts of water was added to 100 parts of this mixture and kneaded and mixed with a double-arm kneader. Next, the mixture was granulated with an extrusion granulator equipped with a 0.8 mm diameter screen, further dried with a fluid bed dryer and sieved to obtain an agrochemical granular wettable powder with a particle size of 0.6 to 1.0 mm. . The average particle size of the obtained agrochemical granular wettable powder was 8 μm, particles of 25 μm or less were 95% by weight, and particles of 10 μm or less were 70% by weight.
[0023]
Example 3
2 parts of kasugamycin hydrochloride, 5 parts of β-naphthalenesulfonic acid formalin condensate sodium salt, 2 parts of dialkylsulfosuccinate, 3 parts of dextrin, 20 parts of granulated sugar and 68 parts of siegrite were mixed with a hammer mill. Thereafter, 14 parts of water was added to 100 parts of this mixture and kneaded and mixed with a double-arm kneader. Next, the mixture was granulated with an extrusion granulator equipped with a 0.8 mm diameter screen, further dried with a fluid bed dryer and sieved to obtain an agrochemical granular wettable powder with a particle size of 0.6 to 1.0 mm. . The average particle diameter of the obtained agrochemical granular wettable powder was 15 μm, particles of 25 μm or less were 80% by weight, and particles of 10 μm or less were 40% by weight.
[0024]
Example 4
4 parts of carpropamide, 2 parts of calcium dodecylbenzenesulfonate, 4 parts of polyoxyethylene styryl phenyl ether, 5 parts of dextrin, 6 parts of white carbon and 79 parts of clay were mixed with a hammer mill. Thereafter, 14 parts of water was added to 100 parts of this mixture and kneaded and mixed with a double-arm kneader. Next, the mixture was granulated with an extrusion granulator equipped with a 0.8 μm diameter screen, further dried with a fluidized bed dryer and sieved to obtain an agrochemical granular wettable powder having a particle size of 0.6 to 1.0 mm. The average particle diameter of the resulting agrochemical granular wettable powder was 13 μm, particles of 25 μm or less were 88% by weight, and particles of 10 μm or less were 49% by weight.
[0025]
Example 5
9 parts of diazinon, 3 parts of calcium dodecylbenzenesulfonate, 5 parts of polyoxyethylene styryl phenyl ether, 4 parts of pullulan, 39 parts of diatomaceous earth and 40 parts of clay were mixed in a hammer mill. Thereafter, 15 parts of water was added to 100 parts of this mixture and kneaded and mixed with a double arm kneader. Next, the mixture was granulated with an extrusion granulator equipped with a 0.8 mm diameter screen, further dried with a fluid bed dryer and sieved to obtain an agrochemical granular wettable powder with a particle size of 0.6 to 1.0 mm. . The average particle diameter of the obtained agrochemical granular wettable powder was 10 μm, particles of 25 μm or less were 89% by weight, and particles of 10 μm or less were 57% by weight.
[0026]
Comparative Example 1
5 parts of the solubilized starch of Example 1 was replaced with 3 parts of polyvinyl alcohol and 85 parts of clay was replaced with 87 parts of diatomaceous earth, and the rest was prepared according to Example 1 to obtain an agrochemical granular wettable powder. The average particle diameter of the obtained agrochemical granular wettable powder was 19% by weight, particles of 25 μm or less were 60% by weight, and particles of 10 μm or less were 30% by weight.
[0027]
Comparative Example 2
5 parts of solubilized starch of Example 1 was replaced with 5 parts of carboxymethyl cellulose, and the rest was prepared according to Example 1 to obtain an agrochemical granular wettable powder. The average particle diameter of the obtained agrochemical granular wettable powder was 17 μm, particles of 25 μm or less were 72% by weight, and particles of 10 μm or less were 42% by weight.
[0028]
Comparative Example 3
2 parts of kasugamycin hydrochloride, 5 parts of sodium lauryl sulfate, 2 parts of polyoxyethylene nonylphenyl ether, 3 parts of dextrin and 88 parts of clay were mixed with a hammer mill. Thereafter, 13 parts of water was added to 100 parts of this mixture and kneaded and mixed with a double-arm kneader. Next, the mixture was granulated with an extrusion granulator equipped with a 0.8 mm diameter screen, further dried with a fluid bed dryer and sieved to obtain an agrochemical granular wettable powder with a particle size of 0.6 to 1.0 mm. . The average particle size of the obtained agrochemical granular wettable powder was 15 μm, particles of 25 μm or less were 95% by weight, and particles of 10 μm or less were 20% by weight.
[0029]
Comparative Example 4
5 parts of the dextrin of Example 4 was replaced with 3 parts of polyvinyl alcohol and 79 parts of clay was replaced with 81 parts, and the rest was prepared according to Example 4 to obtain an agrochemical granular wettable powder. The average particle diameter of the obtained agrochemical granular wettable powder was 20 μm, particles of 25 μm or less were 64% by weight, and particles of 10 μm or less were 28% by weight.
[0030]
Comparative Example 5
Replace 4 parts of pullulan of Example 5 with 4 parts of solubilized starch, 39 parts of diatomaceous earth with 9 parts of white carbon, and 40 parts of clay with 70 parts, and the rest is prepared according to Example 5 and is agrochemical granular hydrated An agent was obtained. The average particle diameter of the obtained agrochemical granular wettable powder was 15 μm, particles of 25 μm or less were 85% by weight, and particles of 10 μm or less were 33% by weight.
[0031]
Next, in order to test the effect of the present invention using the drugs according to Example 1-5 and Comparative Example 1-5, the following Test Example 1-3 was performed.
Test Example 1 (Measurement of average particle size and particle size distribution)
Put 0.1 g of the granular wettable powder of Example 1-5 and Comparative Example 1-5 into a 100 mL capacity closed graduated cylinder containing 99.9 mL of ion-exchanged water, let stand for 1 minute, and then turn over (180 ° The operation of rotating and then returning to the original state in about 2 seconds) is performed 30 times to disperse the particles. The dispersion was measured with a Coulter counter (manufactured by Coalter Electronics INC), a particle size distribution measuring machine, and the volume median particle diameter “Agricultural Chemicals Dictionary”, page 254 (Japan Plant Protection Association, issued June 15, 1994) ) "And the particle size distribution.
The volume median diameter was indicated as the average dispersed particle diameter. In addition, regarding the particle size distribution, a rate of 25 μm or less and a rate of 10 μm or less were displayed in weight%. The results are shown in Table 1.
[0032]
Test example 2 (disintegration test)
The granular wettable powders of Example 1-5 and Comparative Example 1-5 were cut with a razor blade so that the grain length was 1 mm. A glass petri dish with a diameter of 9 cm is filled with DH 3 degree hard water with a water temperature of 25 ° C., and three particles are put apart from each other.
The time until the collapse progressed and the original shape was lost was measured according to the following evaluation criteria to determine the collapse property. The results are shown in Table 1.
[0033]
[Table 1]

Evaluation criteria A: Collapsed until the original shape was lost within 2 minutes immediately after the addition.
B: 〃 Within 4 minutes 〃
C: 〃 It took more than 10 minutes to collapse until the original form was lost.
[0034]
Test example 3 (residual rate test of drug on soil in seedling box)
(1) Seedling box: Rice seedlings (variety: Koshihikari) that had been subjected to conventional seed preparation in advance were sown in a standard seedling box (30 cm x 60 cm x 3 cm) per box (180 g dry weight equivalent) and transplanted ( The young seedlings were subjected to cultivation management until 2.8 leaves).
In addition, as the soil, a commercially available artificial granular soil (Kumiai Synthetic Culture No. 3 manufactured by Mitsui Toatsu) was used, and the floor soil was 180 mL and the covering soil was 120 mL / box.
(2) Drug treatment: Reagents of Example 1-5 and Comparative Example 1-5 were sprinkled in a predetermined amount (30-50 g / box) from above the rice seedling so as to be uniform in the box, Thereafter, in order to drop the granular wettable powder adhering to the leaves and stems onto the covering soil, the seedlings were sufficiently paid by hand, and then 500 mL of water per box was irrigated.
(3) Evaluation method: After being allowed to stand for 10 minutes after irrigation, the seedling box was set up vertically on the bat and lightly shaken to the left and right five times. The granular wettable powder that fell on the vat was collected, analyzed by liquid chromatography, and collected to determine the amount of the agrochemical active ingredient. Then, the residual ratio of the agrochemical active ingredient remaining in the culture soil was calculated from the amount of the collected agrochemical active ingredient and the amount of the pretreated pesticide active ingredient.
[0035]
[Expression 1]

The results are shown in Table 2.
[0036]
[Table 2]

As can be understood from these results, Example 1-5 according to the present invention has good disintegration properties, and both show an excellent remaining rate with respect to Comparative Example 1-5, and fall off from the nursery box. There was almost no amount.
[0037]
【The invention's effect】
As is apparent from the above description, the following effects are brought about by implementing the present invention. That is, first, when sprayed in a seedling box, it arrives at the rice plant stock and sticks to the seedling culture soil. As a result, the drug does not fall off even if the nursery box is vibrated by hand. As a result, a high control effect is exhibited.
Second, since there is almost no amount to drop off from the seedling box, it is possible to use a small amount of medicine compared to the amount of conventional granule used, and the control effect more than conventional is exhibited.

Claims (4)

An agrochemical granular wettable powder comprising an agrochemical active ingredient, a surfactant, a binder, and a carrier, and having an average particle diameter of 15 μm or less when dispersed in water and 80% by weight of particles of 25 μm or less The seedling box is seeded with the agrochemical granular wettable powder in which particles of 10 μm or less are 40% by weight or more, and the seedling box is placed on the seedling box in the period immediately before transplanting from the seedling box after covering the soil. Or by spraying as it is without diluting with water from the seedlings of the nursery box, while maintaining the granular dosage form, the particles of the agrochemical granular wettable powder are dropped on the seedling stock, The fallen grains are disintegrated and diffused into fine particles by water in the soil in the seedling box or by irrigation after spraying the chemical, and at the same time, the soil is cultivated by the action of the binder and surfactant contained in the agricultural chemical granular wettable powder. pesticides, characterized in that penetration, to fix the How to use the Jo wettable powder. The above-mentioned pesticide granular wettable powder mixes a pesticide active ingredient with a surfactant, a binder, and a carrier, and an auxiliary agent such as a preservative fungicide, a pesticide active ingredient stabilizer, if necessary, 2. The method of using the agrochemical granular wettable powder according to claim 1 , wherein the granulated powder is dried and granulated after granulation. An agrochemical granular wettable powder comprising an agrochemical active ingredient, a surfactant, a binder, and a carrier, and having an average particle diameter of 15 μm or less when dispersed in water and 80% by weight of particles of 25 μm or less Above, 10 μm or less particles are 40% by weight or more, seeded in a seedling box, and from the seedling box after covering, to the seedling box in the period immediately before transplanting from above the seedling box or the seedling box Agrochemical granular wettable powder that is sprayed as it is without diluting with water from the seedlings of the seedlings while maintaining the granular dosage form .  Agrochemical active ingredients are mixed with surfactants, binders, and carriers, and, if necessary, auxiliary agents such as antiseptic fungicides and agrochemical active ingredient stabilizers, granulated, dried, and adjusted. 4. The pesticidal granular wettable powder according to claim 3, which is prepared by granulating.