WO2011083709A1 - Granular agrochemical composition - Google Patents
Granular agrochemical composition Download PDFInfo
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- WO2011083709A1 WO2011083709A1 PCT/JP2010/073484 JP2010073484W WO2011083709A1 WO 2011083709 A1 WO2011083709 A1 WO 2011083709A1 JP 2010073484 W JP2010073484 W JP 2010073484W WO 2011083709 A1 WO2011083709 A1 WO 2011083709A1
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- granule composition
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- agrochemical granule
- agrochemical
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Definitions
- the present invention relates to an agrochemical granule composition.
- R 1 represents a halogen atom or a C1-C4 haloalkyl group
- R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group
- R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group
- R 4 represents a hydrogen atom or a C1-C4 alkyl group
- R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, ⁇ (C1-C4 alkoxy) carbonyl ⁇ (C1-C4 alkyl) amino group
- R 6 represents a halogen atom
- This invention makes it a subject to provide the agrochemical formulation containing the compound shown by the said formula (I).
- the present inventors have studied to find an agrochemical preparation containing the compound represented by the formula (I), and have reached the present invention.
- the present invention includes the following [1] to [11].
- R 1 represents a halogen atom or a C1-C4 haloalkyl group
- R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group
- R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group
- R 4 represents a hydrogen atom or a C1-C4 alkyl group
- R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, ⁇ (C1-C4 alkoxy) carbonyl ⁇ (C1-C4 alkyl) amino group
- R 6 represents a halogen atom.
- the content ratio of the compound represented by the formula (I) and the plant disease controlling active compound in the agrochemical granule composition is the sum of the compound represented by the formula (I) and the plant disease controlling active compound.
- Granule composition is any one of [1] to [3], wherein the content of the extender containing smectite mineral in the agricultural chemical granule composition is 40 to 98 weight percent with respect to the total amount of the agricultural chemical granule composition.
- the agrochemical granule composition of the present invention has the formula (I) [Where, R 1 represents a halogen atom or a C1-C4 haloalkyl group, R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group, R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group, R 4 represents a hydrogen atom or a C1-C4 alkyl group, R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, ⁇ (C1-C4 alkoxy) carbonyl ⁇ (C1-C4 alkyl) amino group
- One or more plant disease control active compounds selected from the group consisting of thiazinyl, isothianyl, probenazole and acibenzoral-S-methyl (hereinafter sometimes referred to as the present plant disease control active compound); A bulking agent containing a smectite mineral; It contains a water-soluble binder.
- This amide compound is, for example, a compound described in JP-A-2008-280341. This amide compound can be manufactured by the method of this literature description.
- the content of the present amide compound in the agrochemical granule composition of the present invention is usually 0.1 to 5 percent by weight, preferably 0.5 to 2 percent by weight, based on the total amount of the agrochemical granule composition of the present invention.
- Specific examples of the amide compound include the following compounds.
- This plant disease control active compound is the following compounds.
- Thiazinyl has the formula (II) It is a compound shown by these.
- Isotianil has the formula (III) It is a compound shown by these.
- Probenazole has the formula (IV) It is a compound shown by these.
- Acibenzoral-S-methyl has the formula (V) It is a compound shown by these. All the plant disease controlling active compounds are commercially available. In the agrochemical granule composition of the present invention, one or more of the plant disease control active compounds are contained. The content of the plant disease controlling active compound in the agrochemical granule composition of the present invention is usually 1 to 25 weight percent, preferably 1 as the total amount of the plant disease controlling active compound relative to the total amount of the agrochemical granule composition of the present invention. ⁇ 5 weight percent.
- the content ratio of the present amide compound and the present plant disease control active compound contained in the agrochemical granule composition of the present invention is usually 100 in terms of the total amount of the present plant disease control active compound relative to 100 parts by weight of the present amide compound. It is ⁇ 5000 parts by weight, preferably 100 to 600 parts by weight.
- the total content of the present amide compound and the present plant disease control active compound in the agricultural chemical granule composition of the present invention is usually 1.1 to 30 weight percent, preferably 1 based on the total amount of the agricultural chemical granule composition of the present invention. 1 to 5 weight percent.
- the agrochemical granule composition of the present invention may contain other agrochemical active compounds.
- Examples of such other agrochemical active compounds include insecticidal active compounds, fungicidal active compounds, insect growth controlling active compounds, herbicidal active compounds and plant growth controlling active ingredients.
- Specific examples of such other agrochemical active compounds include the following compounds.
- Examples of insecticidal active compounds include pyrethroid compounds such as deltamethrin, tralomethrin, acrinathrin, tetramethrin, and tefluthrin; Organic phosphorous compounds such as acephate, trichlorfone, tetrachlorvinphos, dimethylbinphos, pyridafenthion, azinephosethyl and azinephosmethyl; Fenthiuron, hexythiazox, novallon, teflubenzuron, tri Lumron, 4-chloro-2- (2-chloro-2-methylpropyl) -5- (6-iodo-3-pyridylmeth
- bactericidal active compound examples include benzimidazole compounds such as benomyl, carbendazim, thiabendazole and thiophanate methyl; phenyl carbamate compounds such as dietofencarb; dicarboximide compounds such as procimidone, iprodione and vinculozoline; diniconazole, epoxyconazole, tebuconazole, Difenoconazole, cyproconazole, flusilazole and triazimephone azole compounds; acylalanine compounds such as metalaxyl; carboxamide compounds such as furametopil, tifluzamide, mepronil, flutolanil and trifluzamide; organophosphorus compounds such as tolcrophos methyl, fosetyl aluminum and pyrazophos Anilinopyri such as pyrimethanil, mepanipyrim and cyprodinil Gin compounds; Cyanopyrrole compounds such as fludiox
- Examples of the plant growth regulating active compound include maleic hydrazide, chlormecat, etephone, gibberellin, mepicut chloride, thiazuron, inavenfide, paclobutrazol and uniconazole.
- the agrochemical granule composition of the present invention contains other agrochemical active compounds
- the content of other agrochemical active compounds in the agrochemical granule composition of the present invention is based on the total amount of the agrochemical granule composition of the present invention. Usually 2 to 40 weight percent.
- the agrochemical granule composition of the present invention contains a smectite mineral and, if necessary, an extender other than the smectite mineral.
- smectite mineral examples include saponite, hectorite, saconite, stevensite, nontronite, montmorillonite, and beidellite.
- montmorillonite examples include bentonite Fuji (made by Hojun Co.), bentonite Hotaka (made by Hojun Co.), bentonite Akagi (made by Hojun Co.), bentonite Myogi (made by Hojun Co.), super clay (made by Hojun Co.), Kunigel V1 (Kunimine) Kunigel V2 (manufactured by Kunimine Industries), Kunigel VA (manufactured by Kunimine Industries), Kunibond (manufactured by Kunimine Industries), and Kansai bentonite (manufactured by Kanesan Industries).
- Examples of bulking agents other than smectite minerals include kaolin minerals such as kaolinite, dicanite, nacrite, and halosite, serpentine such as chrysotile, lizarite, anticolite, and amesite, pyrophyllite, talc, rholite, and baiyun.
- kaolin minerals such as kaolinite, dicanite, nacrite, and halosite
- serpentine such as chrysotile, lizarite, anticolite, and amesite, pyrophyllite, talc, rholite, and baiyun.
- mica such as fengite, sericite, illite, silica such as cristobalite, quartz, hydrous magnesium silicate such as attapulgite, sepiolite, sulfate mineral such as gypsum, dolomite, gypsum, zeolite, zeolite, tuff, vermiculite, Mineral carriers such as laponite, pumice, diatomaceous earth, calcium carbonate; plant carriers such as corn cob flour, walnut shell flour, rice husk, wheat flour, wood flour, straw, bran, soybean flour; and urea, lactose, sucrose, Examples thereof include water-soluble solid carriers such as sodium chloride and mirabilite.
- a bulking agent containing a smectite mineral is usually contained in an amount of 40 to 98 percent by weight, preferably 60 to 95 percent by weight, based on the total amount of the pesticidal granule composition of the present invention.
- the proportion of smectite mineral in the extender containing smectite mineral is usually 1 to 100 percent by weight, preferably 1 to 75 percent by weight, more preferably 5 to 50 percent by weight based on the total amount of extender containing smectite mineral. .
- the agrochemical granule composition of the present invention contains a water-soluble binder.
- water-soluble binders examples include sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose, methyl cellulose, methyl ethyl cellulose, hydroxypropyl cellulose, sodium polyacrylate, tragacanth gum, polyvinyl pyrrolidone, polyvinyl alcohol, pregelatinized starch, dextrin, Examples include alginic acid and sodium alginate.
- the water-soluble binder is usually contained in an amount of 1 to 10 weight percent, preferably 1 to 5 weight percent based on the total amount of the pesticidal granule composition of the present invention.
- the present agrochemical granule composition of the present invention may optionally contain other agrochemical active compounds.
- Surfactants, solvents, stabilizers, preservatives, colorants, fragrances, and other formulation adjuvants can also be contained.
- such a preparation adjuvant is usually contained in an amount of 0 to 5 percent by weight based on the total amount of the pesticidal granule composition of the present invention.
- the agrochemical granule composition of the present invention is used for the present amide compound, the present plant disease control active compound, a bulking agent containing a smectite mineral and a water-soluble binder, and optionally other agrochemical active compounds and formulations.
- Manufactured by adding water to a mixture containing an auxiliary agent, kneading, granulating the obtained kneaded product, drying the obtained granulated product, and performing the operation of aligning the size of the particles if necessary be able to.
- the amount of water used for kneading is usually 3 to 50 parts by weight with respect to 100 parts by weight of the mixture.
- the kneaded material is granulated by, for example, extrusion granulation.
- the extrusion granulation of the kneaded product is usually performed using a screen of 0.5 to 2.0 mm ⁇ , preferably 0.7 to 1.5 mm ⁇ .
- the granulated product after extrusion granulation is usually dried at 30 to 90 ° C, preferably 30 to 80 ° C.
- the grain length of the agrochemical granule composition of the present invention after being dried is usually 0.5 to 6.0 mm, preferably 0.7 to 4.0 mm.
- the grain length means the maximum length that the grain can take.
- examples of the kneader used in the kneading step include a kneader, a Nauter mixer, and a Redige mixer.
- examples of the extrusion granulator used in the granulation step include a screw type extrusion granulator, a roll type extrusion granulator, a disk pelleter type extrusion granulator, a pellet mill type extrusion granulator, and a basket type extrusion granulation machine.
- Machine blade type extrusion granulator, oscillating type extrusion granulator, gear type extrusion granulator, and ring die type extrusion granulator.
- the extrusion granulator include twin dome gran (Fuji Paudal Co., Ltd.) and single dome gran (Fuji Paudal Co., Ltd.).
- the agrochemical granule composition of the present invention can be applied to, for example, a rice seedling box.
- the application time of the agrochemical granule composition of the present invention to the seedling box includes, for example, any time from sowing and from germination to transplanting to paddy fields.
- the application amount of the agrochemical granule composition of the present invention is, for example, 0.05 to 4.0 g as a total amount of the present amide compound and the present plant disease controlling active compound per seedling box having a size of 30 cm ⁇ 60 cm. .
- Reference Production Example 1 Preparation of Powdered Pesticide Composition 1 70.0 parts by weight of 2′-cyano-3,4-dichloroisothiazole-5-carboxyanilide (generic name: isothianyl) and 30.0 parts by weight of wax (Katsuyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) was uniformly mixed and pulverized with a centrifugal pulverizer, and 2′-cyano-3,4-dichloroisothiazole-5-5 having a volume median diameter of 4.12 ⁇ m.
- powdered agricultural chemical composition 1 A powdery agricultural chemical composition containing carboxyanilide (hereinafter referred to as powdered agricultural chemical composition 1) was obtained.
- Reference Production Example 2 Preparation of Powdered Pesticide Composition 2 70.0 parts by weight of the present amide compound 16 (compound described in Compound No. 16 in the above [Table 1]) and 30.0 parts by weight of branstone (Katsu A powdery pesticide composition (hereinafter referred to as a powdery state) containing the present amide compound 16 having a volume median diameter of 4.55 ⁇ m, which is uniformly mixed with Katsuyama clay S (manufactured by Katsuyama Mining Co., Ltd.) and pulverized with a centrifugal pulverizer. This is referred to as agrochemical composition 2.).
- Reference Production Example 3 Preparation of Powdered Pesticide Composition 3 70.0 parts by weight of the present amide compound 9 (compound described in Compound No. 9 in [Table 1] above) and 30.0 parts by weight of branstone (Katsu A powdery agricultural chemical composition containing the present amide compound 9 having a volume median diameter of 3.86 ⁇ m (hereinafter referred to as powder) This is referred to as agrochemical composition 3.).
- Reference Production Example 4 Preparation of Powdered Pesticide Composition 4 70.0 parts by weight of the present amide compound 20 (compound described in Compound No.
- powdered agricultural chemical composition 5 By grinding, a powdery agricultural chemical composition containing clothianidin having a volume median diameter of 4.44 ⁇ m (hereinafter referred to as powdered agricultural chemical composition 5) is obtained.
- Reference Production Example 6 Preparation of Powdered Pesticide Composition 6 70.0 parts by weight of Frametopill and 30.0 parts by weight of a wax (Katsumiyama Clay S, manufactured by Katsumiyama Mining Co., Ltd.) are uniformly mixed and centrifuged with a crusher. By pulverizing, a powdery agricultural chemical composition (hereinafter referred to as powdered agricultural chemical composition 6) containing furametopil having a volume median diameter of 4.02 ⁇ m is obtained.
- Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide activity) 1.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Pesticide Granule Composition 5 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (1.5 parts by weight as an agrochemical active compound), 5.0 weights of pregelatinized starch (Amilox No.
- Pesticide Granule Composition 6 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.8 parts by weight of powdered pesticide composition 6 (4.0 parts by weight as an agrochemical active compound), 5.0 parts by weight of pregelatinized starch (Amilox No.
- Pesticide Granule Composition 7 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (4.0 parts by weight as a pesticide active compound), and 5.8 parts by weight of powdered pesticide composition 6 (as a pesticide active compound) 4.0 parts by weight), pregelatinized starch (Amylox No.
- Control Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Control Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Control Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide) 1.0 part by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Control Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No.
- Test Example 1 Growth test on rice by pre-soiling treatment at the time of sowing of paddy rice Before the sowing of paddy rice seedling box (30 cm x 60 cm), the test grain composition was treated at a rate of 100 g / nurturing box, : Hinohikari) was sown. After germination for 3 days in a seedling device (30 ° C.
- the growth rate (%) was calculated by comparing the plant height of the treated group with the plant height of the untreated group according to the following formula (A), and the growth status was evaluated according to the following criteria.
- the agrochemical granule composition of the present invention is excellent as a preparation for application to a nursery box.
Abstract
Disclosed is a granular agrochemical composition, which contains: a compound represented by formula (I); one or more compounds that have plant disease control activity and are selected from the group consisting of tiadinil, isotianil, probenazole and acibenzolar-S-methyl; an extender containing a smectite mineral; and a water-soluble binder. The granular agrochemical composition is excellent as a preparation that is applied to a seedling raising box.
Description
本発明は、農薬粒剤組成物に関する。
The present invention relates to an agrochemical granule composition.
農薬製剤を育苗箱に施用する植物病害の防除方法及び農薬製剤を育苗箱に施用する害虫の防除方法が知られている。
これらの防除方法では、生育初期の植物体に大量の農薬活性成分が施用されるため、条件に応じて植物体の生育初期に生育不良等を引き起こす場合もある。このため、施用される農薬活性成分に応じて製剤が工夫されている。
特開２００８−２８０３４１号公報において、式（Ｉ）
〔式中、
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物が有害生物防除活性化合物として知られている。
国際公開第２００８／００７７７８号及び植物防疫第６１巻 第１０号（２００７）第５３１頁−第５３６頁（社団法人 日本植物防疫協会 発行）において、チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルがイネいもち病などの植物病害に対する活性化合物として知られている。 There are known a method for controlling plant diseases in which an agrochemical formulation is applied to a nursery box and a method for controlling pests in which an agricultural chemical formulation is applied to a seedling box.
In these control methods, a large amount of an agrochemical active ingredient is applied to a plant body in the early stage of growth, so that it may cause poor growth in the early stage of growth of the plant body depending on conditions. For this reason, the formulation is devised according to the agrochemical active ingredient to be applied.
In Japanese Patent Application Laid-Open No. 2008-280341, the formula (I)
[Where,
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
Is known as a pest control active compound.
In International Publication No. 2008/007778 and Plant Protection No. 61, No. 10 (2007), pages 531 to 536 (issued by the Japan Plant Protection Association), thiazinyl, isothianyl, probenazole and acibenzoral-S-methyl are rice. It is known as an active compound against plant diseases such as blast.
これらの防除方法では、生育初期の植物体に大量の農薬活性成分が施用されるため、条件に応じて植物体の生育初期に生育不良等を引き起こす場合もある。このため、施用される農薬活性成分に応じて製剤が工夫されている。
特開２００８−２８０３４１号公報において、式（Ｉ）
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物が有害生物防除活性化合物として知られている。
国際公開第２００８／００７７７８号及び植物防疫第６１巻 第１０号（２００７）第５３１頁−第５３６頁（社団法人 日本植物防疫協会 発行）において、チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルがイネいもち病などの植物病害に対する活性化合物として知られている。 There are known a method for controlling plant diseases in which an agrochemical formulation is applied to a nursery box and a method for controlling pests in which an agricultural chemical formulation is applied to a seedling box.
In these control methods, a large amount of an agrochemical active ingredient is applied to a plant body in the early stage of growth, so that it may cause poor growth in the early stage of growth of the plant body depending on conditions. For this reason, the formulation is devised according to the agrochemical active ingredient to be applied.
In Japanese Patent Application Laid-Open No. 2008-280341, the formula (I)
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
Is known as a pest control active compound.
In International Publication No. 2008/007778 and Plant Protection No. 61, No. 10 (2007), pages 531 to 536 (issued by the Japan Plant Protection Association), thiazinyl, isothianyl, probenazole and acibenzoral-S-methyl are rice. It is known as an active compound against plant diseases such as blast.
本発明は、前記式（Ｉ）で示される化合物を含有する農薬製剤を提供することを課題とする。
本発明者等は、前記式（Ｉ）で示される化合物を含有する農薬製剤を見出すべく検討し、本発明に至った。
本発明は、以下の〔１〕~〔１１〕のものである。
〔１〕 式（Ｉ）
〔式中、
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物と、
チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルからなる群より選ばれる１以上の植物病害防除活性化合物と、
スメクタイト鉱物を含む増量剤と、
水溶性結合剤と
を含有する農薬粒剤組成物。
〔２〕 式（Ｉ）で示される化合物１００重量部に対して、植物病害防除活性化合物が１００~５０００重量部の含有割合である〔１〕記載の農薬粒剤組成物。
〔３〕 農薬粒剤組成物における、式（Ｉ）で示される化合物及び植物病害防除活性化合物の含有割合が、式（Ｉ）で示される化合物と植物病害防除活性化合物との合計で、農薬粒剤組成物全量に対して１~３０重量パーセントである〔１〕又は〔２〕記載の農薬粒剤組成物。
〔４〕 農薬粒剤組成物における、スメクタイト鉱物を含む増量剤の含有割合が農薬粒剤組成物全量に対して４０~９８重量パーセントである〔１〕~〔３〕いずれか一項記載の農薬粒剤組成物。
〔５〕 農薬粒剤組成物における、水溶性結合剤の含有割合が農薬粒剤組成物全量に対して１~１０重量パーセントである〔１〕~〔４〕いずれか一項記載の農薬粒剤組成物。
〔６〕 植物病害防除活性化合物が、イソチアニルである〔１〕~〔５〕いずれか一項記載の農薬粒剤組成物。
〔７〕 ネオニコチノイド化合物を含有する〔１〕~〔６〕いずれか一項記載の農薬粒剤組成物。
〔８〕 ネオニコチノイド化合物が、クロチアニジンである〔７〕記載の農薬粒剤組成物。
〔９〕 スメクタイト鉱物を含む増量剤が、スメクタイト鉱物及び炭酸カルシウムを含む増量剤である〔１〕~〔８〕いずれか一項記載の農薬粒剤組成物。
〔１０〕 スメクタイト鉱物が、ベントナイトである〔１〕~〔９〕いずれか一項記載の農薬粒剤組成物。
〔１１〕 水溶性結合剤が、アルファー化デンプンである〔１〕~〔１０〕いずれか一項記載の農薬粒剤組成物。
本発明の農薬粒剤組成物は、式（Ｉ）
〔式中、
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物（以下、本アミド化合物と記す場合もある。）と、
チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルからなる群より選ばれる１以上の植物病害防除活性化合物（以下、本植物病害防除活性化合物と記す場合もある。）と、
スメクタイト鉱物を含む増量剤と、
水溶性結合剤と
を含有するものである。
本アミド化合物は、例えば、特開２００８−２８０３４１号公報に記載された化合物である。本アミド化合物は、該文献記載の方法で製造することができる。本発明の農薬粒剤組成物における本アミド化合物の含有量は、本発明の農薬粒剤組成物全量に対して通常０．１~５重量パーセント、好ましくは０．５~２重量パーセントである。
本アミド化合物としては、具体的には例えば以下の化合物が挙げられる。
下記式（Ｉ）で示される化合物。
式中、Ｒ１、Ｒ２、Ｒ３、Ｒ４、Ｒ５及びＲ６は〔表１〕に記載の組合せを表す。
本植物病害防除活性化合物は、以下の化合物である。
チアジニルは、式（ＩＩ）
で示される化合物である。
イソチアニルは、式（ＩＩＩ）
で示される化合物である。
プロベナゾールは、式（ＩＶ）
で示される化合物である。
アシベンゾラル−Ｓ−メチルは、式（Ｖ）
で示される化合物である。
本植物病害防除活性化合物は、いずれも市販されている。本発明の農薬粒剤組成物には、本植物病害防除活性化合物が１種又は２種以上が含有される。本発明の農薬粒剤組成物における本植物病害防除活性化合物含有量は、本発明の農薬粒剤組成物全量に対して本植物病害防除活性化合物の全量として通常１~２５重量パーセント、好ましくは１~５重量パーセントである。また、本発明の農薬粒剤組成物に含有される本アミド化合物と本植物病害防除活性化合物との含有割合は、本アミド化合物１００重量部に対して、本植物病害防除活性化合物全量で通常１００~５０００重量部、好ましくは１００~６００重量部である。本発明の農薬粒剤組成物に対する本アミド化合物と本植物病害防除活性化合物との合計含有量は、本発明の農薬粒剤組成物全量に対して通常１．１~３０重量パーセント、好ましくは１．１~５重量パーセントである。
本発明の農薬粒剤組成物には、他の農薬活性化合物が含有されていてもよい。かかる他の農薬活性化合物としては、例えば、殺虫活性化合物、殺菌活性化合物、昆虫成長制御活性化合物、除草活性化合物及び植物成長制御活性成分を挙げることができる。かかる他の農薬活性化合物としては例えば次に示す化合物を具体的に挙げることができる。
殺虫活性化合物としては、例えば、デルタメトリン、トラロメトリン、アクリナトリン、テトラメトリン及びテフルスリン等のピレスロイド化合物；プロポキサー、イソプロカルブ、キシリルカルブ、メトルカルブ、チオジカルブ、ＸＭＣ、カルバリル、ピリミカルブ、カルボフラン、メソミル、フェノキシカルブ及びフェノブカルブ等のカーバメート化合物；アセフェート、トリクロルホン、テトラクロルビンホス、ジメチルビンホス、ピリダフェンチオン、アジンホスエチル及びアジンホスメチル等の有機リン化合物；ジフルベンズロン、クロルフルアズロン、ルフェヌロン、ヘキサフルムロン、フルフェノクスロン、フルシクロクスロン、シロマジン、ジアフェンチウロン、ヘキシチアゾクス、ノヴァルロン、テフルベンズロン、トリフルムロン、４−クロロ−２−（２−クロロ−２−メチルプロピル）−５−（６−ヨード−３−ピリジルメトキシ）ピリダジン−３（２Ｈ）−オン、１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（トリフルオロメチル）フェニル］ウレア、１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（１，１，２，３，３，３−ヘキサフルオロプロポキシ）フェニル］ウレア、２−ｔｅｒｔ−ブチルイミノ−３−イソプロピル−５−フェニル−３，４，５，６−テトラヒドロ−２Ｈ−１，３，５−チアジアゾン−４−オン及び１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（１，１，２，２−テトラフルオロエトキシ）フェニル］ウレア等のウレア化合物；イミダクロプリド、アセタミプリド、クロチアニジン、ニテンピラム、チアメトキサム、ジノテフラン及びチアクロプリド等のネオニコチノイド化合物；フィプロニル及びエチプロール等のフェニルピラゾール化合物、スピロテトラマット、スピロメシフェン及びスピロジクロフェン等のテトラミックアシッド化合物；カルタップ、ブプロフェジン、チオシクラム、ベンスルタップ、フェナザキン、フェンピロキシメート、ピリダベン、ヒドラメチルノン、クロルフェナピル、フェンプロキシメート、ピメトロジン、ピリミジフェン、テブフェノジド、テブフェンピラド、トリアザメート、インドキサカーブ、スルフルラミド、ミルベメクチン、アベルメクチン、ホウ酸並びにパラジクロロベンゼンを挙げることができる。
殺菌活性化合物としては、例えば、ベノミル、カルベンダジム、チアベンダゾール及びチオファネートメチル等のベンズイミダゾール化合物；ジエトフェンカルブ等のフェニルカーバメート系化合物；プロシミドン、イプロジオン及びビンクロゾリン等のジカルボキシイミド化合物；ジニコナゾール、エポキシコナゾール、テブコナゾール、ジフェノコナゾール、シプロコナゾール、フルシラゾール及びトリアジメフォンのアゾール化合物；メタラキシル等のアシルアラニン化合物；フラメトピル、チフルザミド、メプロニル、フルトラニル及びトリフルザミド等のカルボキシアミド化合物；トルクロホスメチル、フォセチルアルミニウム及びピラゾホス等の有機リン化合物；ピリメサニル、メパニピリム及びシプロジニル等のアニリノピリミジン化合物；フルジオキソニル及びフェンピクロニル等のシアノピロール化合物；ブラストサイジンＳ、カスガマイシン、ポリオキシン及びバリダマイシンの抗生物質；アゾキシストロビン、オリサストロビン、メトミノストロビン、クレソキシムメチル及びＳＳＦ−１２６等のメトキシアクリレート化合物；クロロタロニル、マンゼブ、キャプタン、フォルペット、トリシクラゾール、ピロキロン、フサライド、シモキサニル、ジメトモルフ、ＣＧＡ２４５７０４、ファモキサドン、オキソリニック酸、フルアジナム、フェリムゾン、ジクロシメット、カルプロパミド、クロベンチアゾン、イソバレジオン、テトラクロオロイソフタロニトリル、チオフタルイミドオキシビスフェノキシアルシン、３−アイオド−２−プロピルブチルカーバメイト、パラヒドロキシ安息香酸エステル、デヒドロ酢酸ナトリウム、ソルビン酸カリウム並びにチウラムを挙げることができる。
植物成長調節活性化合物としては、例えば、マレイックヒドラジド、クロルメカット、エテフォン、ジベレリン、メピカットクロライド、チジアズロン、イナベンファイド、パクロブトラゾール及びウニコナゾールを挙げることができる。
本発明の農薬粒剤組成物が他の農薬活性化合物を含有する場合、本発明の農薬粒剤組成物中の他の農薬活性化合物の含有量は、本発明の農薬粒剤組成物全量に対して通常２~４０重量パーセントである。
本発明の農薬粒剤組成物には、スメクタイト鉱物と、必要によりスメクタイト鉱物以外の増量剤とが含有される。
スメクタイト鉱物としては、例えばサポナイト、ヘクトライト、ソーコナイト、スチーブンサイト、ノントロナイト、モンモリロナイト及びバイデライトが挙げらる。モンモリロナイトとしては、例えば、ベントナイト富士（ホージュン社製）、ベントナイト穂高（ホージュン社製）、ベントナイト赤城（ホージュン社製）、ベントナイト妙義（ホージュン社製）、スーパークレー（ホージュン社製）、クニゲルＶ１（クニミネ工業社製）、クニゲルＶ２（クニミネ工業社製）、クニゲルＶＡ（クニミネ工業社製）、クニボンド（クニミネ工業社製）、及び関西ベントナイト（カネサン工業社製）が挙げられる。
スメクタイト鉱物以外の増量剤としては、例えば、カオリナイト、ディッカナイト、ナクライト、ハロサイト等のカオリン鉱物、クリソタイル、リザータイト、アンチコライト、アメサイト等の蛇紋石、パイロフィライト、タルク、ロウ石、白雲母、フェンジャイト、セリサイト、イライト等の雲母、クリストバライト、クォーツ等のシリカ、アタパルジャイト、セピオライト等の含水珪酸マグネシウム、石膏等の硫酸塩鉱物、ドロマイト、ギプサム、ゼオライト、沸石、凝灰石、バーミキュライト、ラポナイト、軽石、珪藻土、炭酸カルシウム等の鉱物質担体；トウモロコシ穂軸粉、クルミ殻粉、籾殻、小麦粉、木粉、糠、ふすま、大豆粉等の植物系担体；並びに尿素、乳糖、ショ糖、食塩、芒硝等の水溶性固体担体が挙げられる。
本発明の農薬粒剤組成物には、スメクタイト鉱物を含む増量剤が、本発明の農薬粒剤組成物全量に対して、通常４０~９８重量パーセント、好ましくは６０~９５重量パーセント含有される。スメクタイト鉱物を含む増量剤中のスメクタイト鉱物の割合は、スメクタイト鉱物を含む増量剤全量に対して、通常１~１００重量パーセント、好ましくは１~７５重量パーセント、さらに好ましくは５~５０重量パーセントである。
本発明の農薬粒剤組成物には、水溶性結合剤が含有される。かかる水溶性結合剤としては、例えば、カルボキシメチルセルロースナトリウム、ヒドロキシプロピルメチルセルロース、メチルセルロース、メチルエチルセルロース、ヒドロキシプロピルセルロース、ポリアクリル酸ナトリウム、トラガントガム、ポリビニルピロリドン、ポリビニルアルコール、アルファー化デンプン（ｐｒｅｇｅｌａｔｉｎｉｚｅｄ ｓｔａｒｃｈ）、デキストリン、アルギン酸、及びアルギン酸ナトリウムが挙げられる。
本発明の農薬粒剤組成物には、水溶性結合剤が本発明の農薬粒剤組成物全量に対して通常１~１０重量パーセント、好ましくは１~５重量パーセント含有される。
本発明の農薬粒剤組成物には、本アミド化合物、本植物病害防除活性化合物、スメクタイト鉱物を含む増量剤及び水溶性結合剤、任意に含有されていてもよい他の農薬活性化合物に加えて、界面活性剤、溶剤、安定剤、防腐剤、着色料、香料等の製剤用補助剤を含有することもできる。
本発明の農薬粒剤組成物には、かかる製剤用補助剤が本発明の農薬粒剤組成物全量に対して通常０~５重量パーセント含有される。
本発明の農薬粒剤組成物は、本アミド化合物、本植物病害防除活性化合物、スメクタイト鉱物を含む増量剤及び水溶性結合剤、並びに任意に含有されていてもよい他の農薬活性化合物及び製剤用補助剤を含有する混合物に、水を加えて混練し、得られた混練物を造粒し、得られた造粒物を乾燥し、必要により粒子の大きさを揃える操作を行うことで製造することができる。混練の際に用いられる水の量は、前記混合物１００重量部に対して、通常３~５０重量部の割合である。
前記の混練物は例えば押出造粒により造粒される。
前記混練物の押出造粒は、通常０．５~２．０ｍｍφ、好ましくは０．７~１．５ｍｍφのスクリーンを用いて行われる。押出造粒後の造粒物は、通常３０~９０℃、好ましくは３０~８０℃で乾燥される。乾燥された後の本発明の農薬粒剤組成物の粒長は、通常０．５~６．０ｍｍ、好ましくは０．７~４．０ｍｍである。ここで粒長とは、粒が取り得る最大長さを意味する。
本発明の農薬粒剤組成物を製造において、混練工程で用いられる練合機としては、例えばニーダー、ナウターミキサー、及びレディゲミキサーが挙げられる。造粒工程で用いられる押出造粒機としては、例えばスクリュー型押出造粒機、ロール型押出造粒機、ディスクペレッター型押出造粒機、ペレットミル型押出造粒機、バスケット型押出造粒機、プレード型押出造粒機、オシレーティング型押出造粒機、ギア式押出造粒機、及びリングダイス式押出造粒機が挙げられる。押出造粒機として具体的には例えばツインドームグラン（不二パウダル（株））、及びシングルドームグラン（不二パウダル（株））が挙げられる。
本発明の農薬粒剤組成物は、例えばイネの育苗箱に施用して用いることができる。育苗箱への本発明の農薬粒剤組成物の施用時期は例えば、播種時、及び発芽から水田への移植までのいずれかの時期が挙げられる。本発明の農薬粒剤組成物の施用量は、例えば３０ｃｍ×６０ｃｍの大きさの育苗箱１枚あたり、本アミド化合物及び本植物病害防除活性化合物の合計量として０．０５~４．０ｇである。 This invention makes it a subject to provide the agrochemical formulation containing the compound shown by the said formula (I).
The present inventors have studied to find an agrochemical preparation containing the compound represented by the formula (I), and have reached the present invention.
The present invention includes the following [1] to [11].
[1] Formula (I)
[Where,
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
A compound represented by
One or more plant disease control active compounds selected from the group consisting of thiazinyl, isotianil, probenazole and acibenzoral-S-methyl;
A bulking agent containing a smectite mineral;
An agrochemical granule composition containing a water-soluble binder.
[2] The agrochemical granule composition according to [1], wherein the plant disease control active compound is contained in an amount of 100 to 5000 parts by weight per 100 parts by weight of the compound represented by the formula (I).
[3] The content ratio of the compound represented by the formula (I) and the plant disease controlling active compound in the agrochemical granule composition is the sum of the compound represented by the formula (I) and the plant disease controlling active compound. The agrochemical granule composition according to [1] or [2], which is 1 to 30% by weight relative to the total amount of the agent composition.
[4] The agricultural chemical according to any one of [1] to [3], wherein the content of the extender containing smectite mineral in the agricultural chemical granule composition is 40 to 98 weight percent with respect to the total amount of the agricultural chemical granule composition. Granule composition.
[5] The agrochemical granule according to any one of [1] to [4], wherein the content ratio of the water-soluble binder in the agrochemical granule composition is 1 to 10 weight percent with respect to the total amount of the agrochemical granule composition. Composition.
[6] The agrochemical granule composition according to any one of [1] to [5], wherein the plant disease controlling active compound is isotianil.
[7] The agrochemical granule composition according to any one of [1] to [6], which contains a neonicotinoid compound.
[8] The agrochemical granule composition according to [7], wherein the neonicotinoid compound is clothianidin.
[9] The agrochemical granule composition according to any one of [1] to [8], wherein the extender containing a smectite mineral is an extender containing a smectite mineral and calcium carbonate.
[10] The agrochemical granule composition according to any one of [1] to [9], wherein the smectite mineral is bentonite.
[11] The agrochemical granule composition according to any one of [1] to [10], wherein the water-soluble binder is pregelatinized starch.
The agrochemical granule composition of the present invention has the formula (I)
[Where,
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
(Hereinafter also referred to as the present amide compound),
One or more plant disease control active compounds selected from the group consisting of thiazinyl, isothianyl, probenazole and acibenzoral-S-methyl (hereinafter sometimes referred to as the present plant disease control active compound);
A bulking agent containing a smectite mineral;
It contains a water-soluble binder.
This amide compound is, for example, a compound described in JP-A-2008-280341. This amide compound can be manufactured by the method of this literature description. The content of the present amide compound in the agrochemical granule composition of the present invention is usually 0.1 to 5 percent by weight, preferably 0.5 to 2 percent by weight, based on the total amount of the agrochemical granule composition of the present invention.
Specific examples of the amide compound include the following compounds.
A compound represented by the following formula (I).
In the formula, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 represent the combinations described in [Table 1].
This plant disease control active compound is the following compounds.
Thiazinyl has the formula (II)
It is a compound shown by these.
Isotianil has the formula (III)
It is a compound shown by these.
Probenazole has the formula (IV)
It is a compound shown by these.
Acibenzoral-S-methyl has the formula (V)
It is a compound shown by these.
All the plant disease controlling active compounds are commercially available. In the agrochemical granule composition of the present invention, one or more of the plant disease control active compounds are contained. The content of the plant disease controlling active compound in the agrochemical granule composition of the present invention is usually 1 to 25 weight percent, preferably 1 as the total amount of the plant disease controlling active compound relative to the total amount of the agrochemical granule composition of the present invention. ~ 5 weight percent. The content ratio of the present amide compound and the present plant disease control active compound contained in the agrochemical granule composition of the present invention is usually 100 in terms of the total amount of the present plant disease control active compound relative to 100 parts by weight of the present amide compound. It is ˜5000 parts by weight, preferably 100 to 600 parts by weight. The total content of the present amide compound and the present plant disease control active compound in the agricultural chemical granule composition of the present invention is usually 1.1 to 30 weight percent, preferably 1 based on the total amount of the agricultural chemical granule composition of the present invention. 1 to 5 weight percent.
The agrochemical granule composition of the present invention may contain other agrochemical active compounds. Examples of such other agrochemical active compounds include insecticidal active compounds, fungicidal active compounds, insect growth controlling active compounds, herbicidal active compounds and plant growth controlling active ingredients. Specific examples of such other agrochemical active compounds include the following compounds.
Examples of insecticidal active compounds include pyrethroid compounds such as deltamethrin, tralomethrin, acrinathrin, tetramethrin, and tefluthrin; Organic phosphorous compounds such as acephate, trichlorfone, tetrachlorvinphos, dimethylbinphos, pyridafenthion, azinephosethyl and azinephosmethyl; Fenthiuron, hexythiazox, novallon, teflubenzuron, tri Lumron, 4-chloro-2- (2-chloro-2-methylpropyl) -5- (6-iodo-3-pyridylmethoxy) pyridazin-3 (2H) -one, 1- (2,6-difluorobenzoyl) -3- [2-Fluoro-4- (trifluoromethyl) phenyl] urea, 1- (2,6-difluorobenzoyl) -3- [2-fluoro-4- (1,1,2,3,3, 3-hexafluoropropoxy) phenyl] urea, 2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazon-4-one and 1- Urea compounds such as (2,6-difluorobenzoyl) -3- [2-fluoro-4- (1,1,2,2-tetrafluoroethoxy) phenyl] urea; imidacloprid, acetami Neonicotinoid compounds such as Lido, clothianidin, nitenpyram, thiamethoxam, dinotefuran and thiacloprid; phenylpyrazole compounds such as fipronil and ethiprole; tetramic acid compounds such as spirotetramat, spiromethifene and spirodiclofen; cartap, buprofezin, thiocyclam , Bensultap, phenazaquin, fenpyroximate, pyridaben, hydramethylnon, chlorfenapyr, fenproximate, pymetrozine, pyrimidifen, tebufenozide, tebufenpyrad, triazamate, indoxacarb, sulphuramide, milbemectin, avermectin, boric acid and paradichlorobenzene.
Examples of the bactericidal active compound include benzimidazole compounds such as benomyl, carbendazim, thiabendazole and thiophanate methyl; phenyl carbamate compounds such as dietofencarb; dicarboximide compounds such as procimidone, iprodione and vinculozoline; diniconazole, epoxyconazole, tebuconazole, Difenoconazole, cyproconazole, flusilazole and triazimephone azole compounds; acylalanine compounds such as metalaxyl; carboxamide compounds such as furametopil, tifluzamide, mepronil, flutolanil and trifluzamide; organophosphorus compounds such as tolcrophos methyl, fosetyl aluminum and pyrazophos Anilinopyri such as pyrimethanil, mepanipyrim and cyprodinil Gin compounds; Cyanopyrrole compounds such as fludioxonil and fenpiclonyl; Antibiotics of blastcidin S, kasugamycin, polyoxin and validamycin; methoxy acrylate compounds such as azoxystrobin, orissastrobin, metminostrobin, cresoxime methyl and SSF-126; chlorothalonil; Manzeb, captan, phorpet, tricyclazole, pyroxylone, fusaride, simoxanyl, dimethomorph, CGA245704, famoxadone, oxolinic acid, fluazinam, ferrimzone, diclocimet, carpropamide, clobenazone, isovaredione, tetrachloroisophthalonitrile, thiophthalimidooxybisphenoxy Arsine, 3-iodo-2-propylbutylcar Mate, parahydroxybenzoic acid ester, sodium dehydroacetate, sorbic acid and the potassium and thiuram.
Examples of the plant growth regulating active compound include maleic hydrazide, chlormecat, etephone, gibberellin, mepicut chloride, thiazuron, inavenfide, paclobutrazol and uniconazole.
When the agrochemical granule composition of the present invention contains other agrochemical active compounds, the content of other agrochemical active compounds in the agrochemical granule composition of the present invention is based on the total amount of the agrochemical granule composition of the present invention. Usually 2 to 40 weight percent.
The agrochemical granule composition of the present invention contains a smectite mineral and, if necessary, an extender other than the smectite mineral.
Examples of the smectite mineral include saponite, hectorite, saconite, stevensite, nontronite, montmorillonite, and beidellite. Examples of the montmorillonite include bentonite Fuji (made by Hojun Co.), bentonite Hotaka (made by Hojun Co.), bentonite Akagi (made by Hojun Co.), bentonite Myogi (made by Hojun Co.), super clay (made by Hojun Co.), Kunigel V1 (Kunimine) Kunigel V2 (manufactured by Kunimine Industries), Kunigel VA (manufactured by Kunimine Industries), Kunibond (manufactured by Kunimine Industries), and Kansai bentonite (manufactured by Kanesan Industries).
Examples of bulking agents other than smectite minerals include kaolin minerals such as kaolinite, dicanite, nacrite, and halosite, serpentine such as chrysotile, lizarite, anticolite, and amesite, pyrophyllite, talc, rholite, and baiyun. Mother, mica such as fengite, sericite, illite, silica such as cristobalite, quartz, hydrous magnesium silicate such as attapulgite, sepiolite, sulfate mineral such as gypsum, dolomite, gypsum, zeolite, zeolite, tuff, vermiculite, Mineral carriers such as laponite, pumice, diatomaceous earth, calcium carbonate; plant carriers such as corn cob flour, walnut shell flour, rice husk, wheat flour, wood flour, straw, bran, soybean flour; and urea, lactose, sucrose, Examples thereof include water-soluble solid carriers such as sodium chloride and mirabilite.
In the pesticidal granule composition of the present invention, a bulking agent containing a smectite mineral is usually contained in an amount of 40 to 98 percent by weight, preferably 60 to 95 percent by weight, based on the total amount of the pesticidal granule composition of the present invention. The proportion of smectite mineral in the extender containing smectite mineral is usually 1 to 100 percent by weight, preferably 1 to 75 percent by weight, more preferably 5 to 50 percent by weight based on the total amount of extender containing smectite mineral. .
The agrochemical granule composition of the present invention contains a water-soluble binder. Examples of such water-soluble binders include sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose, methyl cellulose, methyl ethyl cellulose, hydroxypropyl cellulose, sodium polyacrylate, tragacanth gum, polyvinyl pyrrolidone, polyvinyl alcohol, pregelatinized starch, dextrin, Examples include alginic acid and sodium alginate.
In the pesticidal granule composition of the present invention, the water-soluble binder is usually contained in an amount of 1 to 10 weight percent, preferably 1 to 5 weight percent based on the total amount of the pesticidal granule composition of the present invention.
In addition to the present amide compound, the present plant disease control active compound, a bulking agent containing a smectite mineral and a water-soluble binder, the present agrochemical granule composition of the present invention may optionally contain other agrochemical active compounds. , Surfactants, solvents, stabilizers, preservatives, colorants, fragrances, and other formulation adjuvants can also be contained.
In the pesticidal granule composition of the present invention, such a preparation adjuvant is usually contained in an amount of 0 to 5 percent by weight based on the total amount of the pesticidal granule composition of the present invention.
The agrochemical granule composition of the present invention is used for the present amide compound, the present plant disease control active compound, a bulking agent containing a smectite mineral and a water-soluble binder, and optionally other agrochemical active compounds and formulations. Manufactured by adding water to a mixture containing an auxiliary agent, kneading, granulating the obtained kneaded product, drying the obtained granulated product, and performing the operation of aligning the size of the particles if necessary be able to. The amount of water used for kneading is usually 3 to 50 parts by weight with respect to 100 parts by weight of the mixture.
The kneaded material is granulated by, for example, extrusion granulation.
The extrusion granulation of the kneaded product is usually performed using a screen of 0.5 to 2.0 mmφ, preferably 0.7 to 1.5 mmφ. The granulated product after extrusion granulation is usually dried at 30 to 90 ° C, preferably 30 to 80 ° C. The grain length of the agrochemical granule composition of the present invention after being dried is usually 0.5 to 6.0 mm, preferably 0.7 to 4.0 mm. Here, the grain length means the maximum length that the grain can take.
In the production of the agrochemical granule composition of the present invention, examples of the kneader used in the kneading step include a kneader, a Nauter mixer, and a Redige mixer. Examples of the extrusion granulator used in the granulation step include a screw type extrusion granulator, a roll type extrusion granulator, a disk pelleter type extrusion granulator, a pellet mill type extrusion granulator, and a basket type extrusion granulation machine. Machine, blade type extrusion granulator, oscillating type extrusion granulator, gear type extrusion granulator, and ring die type extrusion granulator. Specific examples of the extrusion granulator include twin dome gran (Fuji Paudal Co., Ltd.) and single dome gran (Fuji Paudal Co., Ltd.).
The agrochemical granule composition of the present invention can be applied to, for example, a rice seedling box. The application time of the agrochemical granule composition of the present invention to the seedling box includes, for example, any time from sowing and from germination to transplanting to paddy fields. The application amount of the agrochemical granule composition of the present invention is, for example, 0.05 to 4.0 g as a total amount of the present amide compound and the present plant disease controlling active compound per seedling box having a size of 30 cm × 60 cm. .
本発明者等は、前記式（Ｉ）で示される化合物を含有する農薬製剤を見出すべく検討し、本発明に至った。
本発明は、以下の〔１〕~〔１１〕のものである。
〔１〕 式（Ｉ）
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物と、
チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルからなる群より選ばれる１以上の植物病害防除活性化合物と、
スメクタイト鉱物を含む増量剤と、
水溶性結合剤と
を含有する農薬粒剤組成物。
〔２〕 式（Ｉ）で示される化合物１００重量部に対して、植物病害防除活性化合物が１００~５０００重量部の含有割合である〔１〕記載の農薬粒剤組成物。
〔３〕 農薬粒剤組成物における、式（Ｉ）で示される化合物及び植物病害防除活性化合物の含有割合が、式（Ｉ）で示される化合物と植物病害防除活性化合物との合計で、農薬粒剤組成物全量に対して１~３０重量パーセントである〔１〕又は〔２〕記載の農薬粒剤組成物。
〔４〕 農薬粒剤組成物における、スメクタイト鉱物を含む増量剤の含有割合が農薬粒剤組成物全量に対して４０~９８重量パーセントである〔１〕~〔３〕いずれか一項記載の農薬粒剤組成物。
〔５〕 農薬粒剤組成物における、水溶性結合剤の含有割合が農薬粒剤組成物全量に対して１~１０重量パーセントである〔１〕~〔４〕いずれか一項記載の農薬粒剤組成物。
〔６〕 植物病害防除活性化合物が、イソチアニルである〔１〕~〔５〕いずれか一項記載の農薬粒剤組成物。
〔７〕 ネオニコチノイド化合物を含有する〔１〕~〔６〕いずれか一項記載の農薬粒剤組成物。
〔８〕 ネオニコチノイド化合物が、クロチアニジンである〔７〕記載の農薬粒剤組成物。
〔９〕 スメクタイト鉱物を含む増量剤が、スメクタイト鉱物及び炭酸カルシウムを含む増量剤である〔１〕~〔８〕いずれか一項記載の農薬粒剤組成物。
〔１０〕 スメクタイト鉱物が、ベントナイトである〔１〕~〔９〕いずれか一項記載の農薬粒剤組成物。
〔１１〕 水溶性結合剤が、アルファー化デンプンである〔１〕~〔１０〕いずれか一項記載の農薬粒剤組成物。
本発明の農薬粒剤組成物は、式（Ｉ）
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物（以下、本アミド化合物と記す場合もある。）と、
チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルからなる群より選ばれる１以上の植物病害防除活性化合物（以下、本植物病害防除活性化合物と記す場合もある。）と、
スメクタイト鉱物を含む増量剤と、
水溶性結合剤と
を含有するものである。
本アミド化合物は、例えば、特開２００８−２８０３４１号公報に記載された化合物である。本アミド化合物は、該文献記載の方法で製造することができる。本発明の農薬粒剤組成物における本アミド化合物の含有量は、本発明の農薬粒剤組成物全量に対して通常０．１~５重量パーセント、好ましくは０．５~２重量パーセントである。
本アミド化合物としては、具体的には例えば以下の化合物が挙げられる。
下記式（Ｉ）で示される化合物。
チアジニルは、式（ＩＩ）
イソチアニルは、式（ＩＩＩ）
プロベナゾールは、式（ＩＶ）
アシベンゾラル−Ｓ−メチルは、式（Ｖ）
本植物病害防除活性化合物は、いずれも市販されている。本発明の農薬粒剤組成物には、本植物病害防除活性化合物が１種又は２種以上が含有される。本発明の農薬粒剤組成物における本植物病害防除活性化合物含有量は、本発明の農薬粒剤組成物全量に対して本植物病害防除活性化合物の全量として通常１~２５重量パーセント、好ましくは１~５重量パーセントである。また、本発明の農薬粒剤組成物に含有される本アミド化合物と本植物病害防除活性化合物との含有割合は、本アミド化合物１００重量部に対して、本植物病害防除活性化合物全量で通常１００~５０００重量部、好ましくは１００~６００重量部である。本発明の農薬粒剤組成物に対する本アミド化合物と本植物病害防除活性化合物との合計含有量は、本発明の農薬粒剤組成物全量に対して通常１．１~３０重量パーセント、好ましくは１．１~５重量パーセントである。
本発明の農薬粒剤組成物には、他の農薬活性化合物が含有されていてもよい。かかる他の農薬活性化合物としては、例えば、殺虫活性化合物、殺菌活性化合物、昆虫成長制御活性化合物、除草活性化合物及び植物成長制御活性成分を挙げることができる。かかる他の農薬活性化合物としては例えば次に示す化合物を具体的に挙げることができる。
殺虫活性化合物としては、例えば、デルタメトリン、トラロメトリン、アクリナトリン、テトラメトリン及びテフルスリン等のピレスロイド化合物；プロポキサー、イソプロカルブ、キシリルカルブ、メトルカルブ、チオジカルブ、ＸＭＣ、カルバリル、ピリミカルブ、カルボフラン、メソミル、フェノキシカルブ及びフェノブカルブ等のカーバメート化合物；アセフェート、トリクロルホン、テトラクロルビンホス、ジメチルビンホス、ピリダフェンチオン、アジンホスエチル及びアジンホスメチル等の有機リン化合物；ジフルベンズロン、クロルフルアズロン、ルフェヌロン、ヘキサフルムロン、フルフェノクスロン、フルシクロクスロン、シロマジン、ジアフェンチウロン、ヘキシチアゾクス、ノヴァルロン、テフルベンズロン、トリフルムロン、４−クロロ−２−（２−クロロ−２−メチルプロピル）−５−（６−ヨード−３−ピリジルメトキシ）ピリダジン−３（２Ｈ）−オン、１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（トリフルオロメチル）フェニル］ウレア、１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（１，１，２，３，３，３−ヘキサフルオロプロポキシ）フェニル］ウレア、２−ｔｅｒｔ−ブチルイミノ−３−イソプロピル−５−フェニル−３，４，５，６−テトラヒドロ−２Ｈ−１，３，５−チアジアゾン−４−オン及び１−（２，６−ジフルオロベンゾイル）−３−［２−フルオロ−４−（１，１，２，２−テトラフルオロエトキシ）フェニル］ウレア等のウレア化合物；イミダクロプリド、アセタミプリド、クロチアニジン、ニテンピラム、チアメトキサム、ジノテフラン及びチアクロプリド等のネオニコチノイド化合物；フィプロニル及びエチプロール等のフェニルピラゾール化合物、スピロテトラマット、スピロメシフェン及びスピロジクロフェン等のテトラミックアシッド化合物；カルタップ、ブプロフェジン、チオシクラム、ベンスルタップ、フェナザキン、フェンピロキシメート、ピリダベン、ヒドラメチルノン、クロルフェナピル、フェンプロキシメート、ピメトロジン、ピリミジフェン、テブフェノジド、テブフェンピラド、トリアザメート、インドキサカーブ、スルフルラミド、ミルベメクチン、アベルメクチン、ホウ酸並びにパラジクロロベンゼンを挙げることができる。
殺菌活性化合物としては、例えば、ベノミル、カルベンダジム、チアベンダゾール及びチオファネートメチル等のベンズイミダゾール化合物；ジエトフェンカルブ等のフェニルカーバメート系化合物；プロシミドン、イプロジオン及びビンクロゾリン等のジカルボキシイミド化合物；ジニコナゾール、エポキシコナゾール、テブコナゾール、ジフェノコナゾール、シプロコナゾール、フルシラゾール及びトリアジメフォンのアゾール化合物；メタラキシル等のアシルアラニン化合物；フラメトピル、チフルザミド、メプロニル、フルトラニル及びトリフルザミド等のカルボキシアミド化合物；トルクロホスメチル、フォセチルアルミニウム及びピラゾホス等の有機リン化合物；ピリメサニル、メパニピリム及びシプロジニル等のアニリノピリミジン化合物；フルジオキソニル及びフェンピクロニル等のシアノピロール化合物；ブラストサイジンＳ、カスガマイシン、ポリオキシン及びバリダマイシンの抗生物質；アゾキシストロビン、オリサストロビン、メトミノストロビン、クレソキシムメチル及びＳＳＦ−１２６等のメトキシアクリレート化合物；クロロタロニル、マンゼブ、キャプタン、フォルペット、トリシクラゾール、ピロキロン、フサライド、シモキサニル、ジメトモルフ、ＣＧＡ２４５７０４、ファモキサドン、オキソリニック酸、フルアジナム、フェリムゾン、ジクロシメット、カルプロパミド、クロベンチアゾン、イソバレジオン、テトラクロオロイソフタロニトリル、チオフタルイミドオキシビスフェノキシアルシン、３−アイオド−２−プロピルブチルカーバメイト、パラヒドロキシ安息香酸エステル、デヒドロ酢酸ナトリウム、ソルビン酸カリウム並びにチウラムを挙げることができる。
植物成長調節活性化合物としては、例えば、マレイックヒドラジド、クロルメカット、エテフォン、ジベレリン、メピカットクロライド、チジアズロン、イナベンファイド、パクロブトラゾール及びウニコナゾールを挙げることができる。
本発明の農薬粒剤組成物が他の農薬活性化合物を含有する場合、本発明の農薬粒剤組成物中の他の農薬活性化合物の含有量は、本発明の農薬粒剤組成物全量に対して通常２~４０重量パーセントである。
本発明の農薬粒剤組成物には、スメクタイト鉱物と、必要によりスメクタイト鉱物以外の増量剤とが含有される。
スメクタイト鉱物としては、例えばサポナイト、ヘクトライト、ソーコナイト、スチーブンサイト、ノントロナイト、モンモリロナイト及びバイデライトが挙げらる。モンモリロナイトとしては、例えば、ベントナイト富士（ホージュン社製）、ベントナイト穂高（ホージュン社製）、ベントナイト赤城（ホージュン社製）、ベントナイト妙義（ホージュン社製）、スーパークレー（ホージュン社製）、クニゲルＶ１（クニミネ工業社製）、クニゲルＶ２（クニミネ工業社製）、クニゲルＶＡ（クニミネ工業社製）、クニボンド（クニミネ工業社製）、及び関西ベントナイト（カネサン工業社製）が挙げられる。
スメクタイト鉱物以外の増量剤としては、例えば、カオリナイト、ディッカナイト、ナクライト、ハロサイト等のカオリン鉱物、クリソタイル、リザータイト、アンチコライト、アメサイト等の蛇紋石、パイロフィライト、タルク、ロウ石、白雲母、フェンジャイト、セリサイト、イライト等の雲母、クリストバライト、クォーツ等のシリカ、アタパルジャイト、セピオライト等の含水珪酸マグネシウム、石膏等の硫酸塩鉱物、ドロマイト、ギプサム、ゼオライト、沸石、凝灰石、バーミキュライト、ラポナイト、軽石、珪藻土、炭酸カルシウム等の鉱物質担体；トウモロコシ穂軸粉、クルミ殻粉、籾殻、小麦粉、木粉、糠、ふすま、大豆粉等の植物系担体；並びに尿素、乳糖、ショ糖、食塩、芒硝等の水溶性固体担体が挙げられる。
本発明の農薬粒剤組成物には、スメクタイト鉱物を含む増量剤が、本発明の農薬粒剤組成物全量に対して、通常４０~９８重量パーセント、好ましくは６０~９５重量パーセント含有される。スメクタイト鉱物を含む増量剤中のスメクタイト鉱物の割合は、スメクタイト鉱物を含む増量剤全量に対して、通常１~１００重量パーセント、好ましくは１~７５重量パーセント、さらに好ましくは５~５０重量パーセントである。
本発明の農薬粒剤組成物には、水溶性結合剤が含有される。かかる水溶性結合剤としては、例えば、カルボキシメチルセルロースナトリウム、ヒドロキシプロピルメチルセルロース、メチルセルロース、メチルエチルセルロース、ヒドロキシプロピルセルロース、ポリアクリル酸ナトリウム、トラガントガム、ポリビニルピロリドン、ポリビニルアルコール、アルファー化デンプン（ｐｒｅｇｅｌａｔｉｎｉｚｅｄ ｓｔａｒｃｈ）、デキストリン、アルギン酸、及びアルギン酸ナトリウムが挙げられる。
本発明の農薬粒剤組成物には、水溶性結合剤が本発明の農薬粒剤組成物全量に対して通常１~１０重量パーセント、好ましくは１~５重量パーセント含有される。
本発明の農薬粒剤組成物には、本アミド化合物、本植物病害防除活性化合物、スメクタイト鉱物を含む増量剤及び水溶性結合剤、任意に含有されていてもよい他の農薬活性化合物に加えて、界面活性剤、溶剤、安定剤、防腐剤、着色料、香料等の製剤用補助剤を含有することもできる。
本発明の農薬粒剤組成物には、かかる製剤用補助剤が本発明の農薬粒剤組成物全量に対して通常０~５重量パーセント含有される。
本発明の農薬粒剤組成物は、本アミド化合物、本植物病害防除活性化合物、スメクタイト鉱物を含む増量剤及び水溶性結合剤、並びに任意に含有されていてもよい他の農薬活性化合物及び製剤用補助剤を含有する混合物に、水を加えて混練し、得られた混練物を造粒し、得られた造粒物を乾燥し、必要により粒子の大きさを揃える操作を行うことで製造することができる。混練の際に用いられる水の量は、前記混合物１００重量部に対して、通常３~５０重量部の割合である。
前記の混練物は例えば押出造粒により造粒される。
前記混練物の押出造粒は、通常０．５~２．０ｍｍφ、好ましくは０．７~１．５ｍｍφのスクリーンを用いて行われる。押出造粒後の造粒物は、通常３０~９０℃、好ましくは３０~８０℃で乾燥される。乾燥された後の本発明の農薬粒剤組成物の粒長は、通常０．５~６．０ｍｍ、好ましくは０．７~４．０ｍｍである。ここで粒長とは、粒が取り得る最大長さを意味する。
本発明の農薬粒剤組成物を製造において、混練工程で用いられる練合機としては、例えばニーダー、ナウターミキサー、及びレディゲミキサーが挙げられる。造粒工程で用いられる押出造粒機としては、例えばスクリュー型押出造粒機、ロール型押出造粒機、ディスクペレッター型押出造粒機、ペレットミル型押出造粒機、バスケット型押出造粒機、プレード型押出造粒機、オシレーティング型押出造粒機、ギア式押出造粒機、及びリングダイス式押出造粒機が挙げられる。押出造粒機として具体的には例えばツインドームグラン（不二パウダル（株））、及びシングルドームグラン（不二パウダル（株））が挙げられる。
本発明の農薬粒剤組成物は、例えばイネの育苗箱に施用して用いることができる。育苗箱への本発明の農薬粒剤組成物の施用時期は例えば、播種時、及び発芽から水田への移植までのいずれかの時期が挙げられる。本発明の農薬粒剤組成物の施用量は、例えば３０ｃｍ×６０ｃｍの大きさの育苗箱１枚あたり、本アミド化合物及び本植物病害防除活性化合物の合計量として０．０５~４．０ｇである。 This invention makes it a subject to provide the agrochemical formulation containing the compound shown by the said formula (I).
The present inventors have studied to find an agrochemical preparation containing the compound represented by the formula (I), and have reached the present invention.
The present invention includes the following [1] to [11].
[1] Formula (I)
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
A compound represented by
One or more plant disease control active compounds selected from the group consisting of thiazinyl, isotianil, probenazole and acibenzoral-S-methyl;
A bulking agent containing a smectite mineral;
An agrochemical granule composition containing a water-soluble binder.
[2] The agrochemical granule composition according to [1], wherein the plant disease control active compound is contained in an amount of 100 to 5000 parts by weight per 100 parts by weight of the compound represented by the formula (I).
[3] The content ratio of the compound represented by the formula (I) and the plant disease controlling active compound in the agrochemical granule composition is the sum of the compound represented by the formula (I) and the plant disease controlling active compound. The agrochemical granule composition according to [1] or [2], which is 1 to 30% by weight relative to the total amount of the agent composition.
[4] The agricultural chemical according to any one of [1] to [3], wherein the content of the extender containing smectite mineral in the agricultural chemical granule composition is 40 to 98 weight percent with respect to the total amount of the agricultural chemical granule composition. Granule composition.
[5] The agrochemical granule according to any one of [1] to [4], wherein the content ratio of the water-soluble binder in the agrochemical granule composition is 1 to 10 weight percent with respect to the total amount of the agrochemical granule composition. Composition.
[6] The agrochemical granule composition according to any one of [1] to [5], wherein the plant disease controlling active compound is isotianil.
[7] The agrochemical granule composition according to any one of [1] to [6], which contains a neonicotinoid compound.
[8] The agrochemical granule composition according to [7], wherein the neonicotinoid compound is clothianidin.
[9] The agrochemical granule composition according to any one of [1] to [8], wherein the extender containing a smectite mineral is an extender containing a smectite mineral and calcium carbonate.
[10] The agrochemical granule composition according to any one of [1] to [9], wherein the smectite mineral is bentonite.
[11] The agrochemical granule composition according to any one of [1] to [10], wherein the water-soluble binder is pregelatinized starch.
The agrochemical granule composition of the present invention has the formula (I)
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
(Hereinafter also referred to as the present amide compound),
One or more plant disease control active compounds selected from the group consisting of thiazinyl, isothianyl, probenazole and acibenzoral-S-methyl (hereinafter sometimes referred to as the present plant disease control active compound);
A bulking agent containing a smectite mineral;
It contains a water-soluble binder.
This amide compound is, for example, a compound described in JP-A-2008-280341. This amide compound can be manufactured by the method of this literature description. The content of the present amide compound in the agrochemical granule composition of the present invention is usually 0.1 to 5 percent by weight, preferably 0.5 to 2 percent by weight, based on the total amount of the agrochemical granule composition of the present invention.
Specific examples of the amide compound include the following compounds.
A compound represented by the following formula (I).
Thiazinyl has the formula (II)
Isotianil has the formula (III)
Probenazole has the formula (IV)
Acibenzoral-S-methyl has the formula (V)
All the plant disease controlling active compounds are commercially available. In the agrochemical granule composition of the present invention, one or more of the plant disease control active compounds are contained. The content of the plant disease controlling active compound in the agrochemical granule composition of the present invention is usually 1 to 25 weight percent, preferably 1 as the total amount of the plant disease controlling active compound relative to the total amount of the agrochemical granule composition of the present invention. ~ 5 weight percent. The content ratio of the present amide compound and the present plant disease control active compound contained in the agrochemical granule composition of the present invention is usually 100 in terms of the total amount of the present plant disease control active compound relative to 100 parts by weight of the present amide compound. It is ˜5000 parts by weight, preferably 100 to 600 parts by weight. The total content of the present amide compound and the present plant disease control active compound in the agricultural chemical granule composition of the present invention is usually 1.1 to 30 weight percent, preferably 1 based on the total amount of the agricultural chemical granule composition of the present invention. 1 to 5 weight percent.
The agrochemical granule composition of the present invention may contain other agrochemical active compounds. Examples of such other agrochemical active compounds include insecticidal active compounds, fungicidal active compounds, insect growth controlling active compounds, herbicidal active compounds and plant growth controlling active ingredients. Specific examples of such other agrochemical active compounds include the following compounds.
Examples of insecticidal active compounds include pyrethroid compounds such as deltamethrin, tralomethrin, acrinathrin, tetramethrin, and tefluthrin; Organic phosphorous compounds such as acephate, trichlorfone, tetrachlorvinphos, dimethylbinphos, pyridafenthion, azinephosethyl and azinephosmethyl; Fenthiuron, hexythiazox, novallon, teflubenzuron, tri Lumron, 4-chloro-2- (2-chloro-2-methylpropyl) -5- (6-iodo-3-pyridylmethoxy) pyridazin-3 (2H) -one, 1- (2,6-difluorobenzoyl) -3- [2-Fluoro-4- (trifluoromethyl) phenyl] urea, 1- (2,6-difluorobenzoyl) -3- [2-fluoro-4- (1,1,2,3,3, 3-hexafluoropropoxy) phenyl] urea, 2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazon-4-one and 1- Urea compounds such as (2,6-difluorobenzoyl) -3- [2-fluoro-4- (1,1,2,2-tetrafluoroethoxy) phenyl] urea; imidacloprid, acetami Neonicotinoid compounds such as Lido, clothianidin, nitenpyram, thiamethoxam, dinotefuran and thiacloprid; phenylpyrazole compounds such as fipronil and ethiprole; tetramic acid compounds such as spirotetramat, spiromethifene and spirodiclofen; cartap, buprofezin, thiocyclam , Bensultap, phenazaquin, fenpyroximate, pyridaben, hydramethylnon, chlorfenapyr, fenproximate, pymetrozine, pyrimidifen, tebufenozide, tebufenpyrad, triazamate, indoxacarb, sulphuramide, milbemectin, avermectin, boric acid and paradichlorobenzene.
Examples of the bactericidal active compound include benzimidazole compounds such as benomyl, carbendazim, thiabendazole and thiophanate methyl; phenyl carbamate compounds such as dietofencarb; dicarboximide compounds such as procimidone, iprodione and vinculozoline; diniconazole, epoxyconazole, tebuconazole, Difenoconazole, cyproconazole, flusilazole and triazimephone azole compounds; acylalanine compounds such as metalaxyl; carboxamide compounds such as furametopil, tifluzamide, mepronil, flutolanil and trifluzamide; organophosphorus compounds such as tolcrophos methyl, fosetyl aluminum and pyrazophos Anilinopyri such as pyrimethanil, mepanipyrim and cyprodinil Gin compounds; Cyanopyrrole compounds such as fludioxonil and fenpiclonyl; Antibiotics of blastcidin S, kasugamycin, polyoxin and validamycin; methoxy acrylate compounds such as azoxystrobin, orissastrobin, metminostrobin, cresoxime methyl and SSF-126; chlorothalonil; Manzeb, captan, phorpet, tricyclazole, pyroxylone, fusaride, simoxanyl, dimethomorph, CGA245704, famoxadone, oxolinic acid, fluazinam, ferrimzone, diclocimet, carpropamide, clobenazone, isovaredione, tetrachloroisophthalonitrile, thiophthalimidooxybisphenoxy Arsine, 3-iodo-2-propylbutylcar Mate, parahydroxybenzoic acid ester, sodium dehydroacetate, sorbic acid and the potassium and thiuram.
Examples of the plant growth regulating active compound include maleic hydrazide, chlormecat, etephone, gibberellin, mepicut chloride, thiazuron, inavenfide, paclobutrazol and uniconazole.
When the agrochemical granule composition of the present invention contains other agrochemical active compounds, the content of other agrochemical active compounds in the agrochemical granule composition of the present invention is based on the total amount of the agrochemical granule composition of the present invention. Usually 2 to 40 weight percent.
The agrochemical granule composition of the present invention contains a smectite mineral and, if necessary, an extender other than the smectite mineral.
Examples of the smectite mineral include saponite, hectorite, saconite, stevensite, nontronite, montmorillonite, and beidellite. Examples of the montmorillonite include bentonite Fuji (made by Hojun Co.), bentonite Hotaka (made by Hojun Co.), bentonite Akagi (made by Hojun Co.), bentonite Myogi (made by Hojun Co.), super clay (made by Hojun Co.), Kunigel V1 (Kunimine) Kunigel V2 (manufactured by Kunimine Industries), Kunigel VA (manufactured by Kunimine Industries), Kunibond (manufactured by Kunimine Industries), and Kansai bentonite (manufactured by Kanesan Industries).
Examples of bulking agents other than smectite minerals include kaolin minerals such as kaolinite, dicanite, nacrite, and halosite, serpentine such as chrysotile, lizarite, anticolite, and amesite, pyrophyllite, talc, rholite, and baiyun. Mother, mica such as fengite, sericite, illite, silica such as cristobalite, quartz, hydrous magnesium silicate such as attapulgite, sepiolite, sulfate mineral such as gypsum, dolomite, gypsum, zeolite, zeolite, tuff, vermiculite, Mineral carriers such as laponite, pumice, diatomaceous earth, calcium carbonate; plant carriers such as corn cob flour, walnut shell flour, rice husk, wheat flour, wood flour, straw, bran, soybean flour; and urea, lactose, sucrose, Examples thereof include water-soluble solid carriers such as sodium chloride and mirabilite.
In the pesticidal granule composition of the present invention, a bulking agent containing a smectite mineral is usually contained in an amount of 40 to 98 percent by weight, preferably 60 to 95 percent by weight, based on the total amount of the pesticidal granule composition of the present invention. The proportion of smectite mineral in the extender containing smectite mineral is usually 1 to 100 percent by weight, preferably 1 to 75 percent by weight, more preferably 5 to 50 percent by weight based on the total amount of extender containing smectite mineral. .
The agrochemical granule composition of the present invention contains a water-soluble binder. Examples of such water-soluble binders include sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose, methyl cellulose, methyl ethyl cellulose, hydroxypropyl cellulose, sodium polyacrylate, tragacanth gum, polyvinyl pyrrolidone, polyvinyl alcohol, pregelatinized starch, dextrin, Examples include alginic acid and sodium alginate.
In the pesticidal granule composition of the present invention, the water-soluble binder is usually contained in an amount of 1 to 10 weight percent, preferably 1 to 5 weight percent based on the total amount of the pesticidal granule composition of the present invention.
In addition to the present amide compound, the present plant disease control active compound, a bulking agent containing a smectite mineral and a water-soluble binder, the present agrochemical granule composition of the present invention may optionally contain other agrochemical active compounds. , Surfactants, solvents, stabilizers, preservatives, colorants, fragrances, and other formulation adjuvants can also be contained.
In the pesticidal granule composition of the present invention, such a preparation adjuvant is usually contained in an amount of 0 to 5 percent by weight based on the total amount of the pesticidal granule composition of the present invention.
The agrochemical granule composition of the present invention is used for the present amide compound, the present plant disease control active compound, a bulking agent containing a smectite mineral and a water-soluble binder, and optionally other agrochemical active compounds and formulations. Manufactured by adding water to a mixture containing an auxiliary agent, kneading, granulating the obtained kneaded product, drying the obtained granulated product, and performing the operation of aligning the size of the particles if necessary be able to. The amount of water used for kneading is usually 3 to 50 parts by weight with respect to 100 parts by weight of the mixture.
The kneaded material is granulated by, for example, extrusion granulation.
The extrusion granulation of the kneaded product is usually performed using a screen of 0.5 to 2.0 mmφ, preferably 0.7 to 1.5 mmφ. The granulated product after extrusion granulation is usually dried at 30 to 90 ° C, preferably 30 to 80 ° C. The grain length of the agrochemical granule composition of the present invention after being dried is usually 0.5 to 6.0 mm, preferably 0.7 to 4.0 mm. Here, the grain length means the maximum length that the grain can take.
In the production of the agrochemical granule composition of the present invention, examples of the kneader used in the kneading step include a kneader, a Nauter mixer, and a Redige mixer. Examples of the extrusion granulator used in the granulation step include a screw type extrusion granulator, a roll type extrusion granulator, a disk pelleter type extrusion granulator, a pellet mill type extrusion granulator, and a basket type extrusion granulation machine. Machine, blade type extrusion granulator, oscillating type extrusion granulator, gear type extrusion granulator, and ring die type extrusion granulator. Specific examples of the extrusion granulator include twin dome gran (Fuji Paudal Co., Ltd.) and single dome gran (Fuji Paudal Co., Ltd.).
The agrochemical granule composition of the present invention can be applied to, for example, a rice seedling box. The application time of the agrochemical granule composition of the present invention to the seedling box includes, for example, any time from sowing and from germination to transplanting to paddy fields. The application amount of the agrochemical granule composition of the present invention is, for example, 0.05 to 4.0 g as a total amount of the present amide compound and the present plant disease controlling active compound per seedling box having a size of 30 cm × 60 cm. .
次に本発明を製造例、試験例等によりさらに詳しく説明するが、本発明はこれらの例のみに限定されるものではない。
参考製造例１ 粉状農薬組成物１の調製
７０．０重量部の２’−シアノ−３，４−ジクロロイソチアゾール−５−カルボキシアニリド（一般名：イソチアニル）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．１２μｍの２’−シアノ−３，４−ジクロロイソチアゾール−５−カルボキシアニリドを含有する粉状農薬組成物（以下、粉状農薬組成物１と記す。）を得た。
参考製造例２ 粉状農薬組成物２の調製
７０．０重量部の本アミド化合物１６（前記〔表１〕において、化合物Ｎｏ．１６に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．５５μｍの本アミド化合物１６を含有する粉状農薬組成物（以下、粉状農薬組成物２と記す。）を得た。
参考製造例３ 粉状農薬組成物３の調製
７０．０重量部の本アミド化合物９（前記〔表１〕において、化合物Ｎｏ．９に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が３．８６μｍの本アミド化合物９を含有する粉状農薬組成物（以下、粉状農薬組成物３と記す。）を得た。
参考製造例４ 粉状農薬組成物４の調製
７０．０重量部の本アミド化合物２０（前記〔表１〕において、化合物Ｎｏ．２０に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．９０μｍの本アミド化合物２０を含有する粉状農薬組成物（以下、粉状農薬組成物４と記す。）を得た。
参考製造例５ 粉状農薬組成物５の調製
７０．０重量部のクロチアニジン及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．４４μｍのクロチアニジンを含有する粉状農薬組成物（以下、粉状農薬組成物５と記す。）を得る。
参考製造例６ 粉状農薬組成物６の調製
７０．０重量部のフラメトピル及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．０２μｍのフラメトピルを含有する粉状農薬組成物（以下、粉状農薬組成物６と記す。）を得る。
製造例１ 農薬粒剤組成物１の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物２を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物１を得た。
製造例２ 農薬粒剤組成物２の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物３を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物２を得た。
製造例３ 農薬粒剤組成物３の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を１．５重量部（農薬活性化合物として１．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６９．６重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物３を得た。
製造例４ 農薬粒剤組成物４の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物４を得た。
製造例５ 農薬粒剤組成物５の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物５を２．２重量部（農薬活性化合物として１．５重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６６．０重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物５を得る。
製造例６ 農薬粒剤組成物６の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物６を５．８重量部（農薬活性化合物として４．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６２．４重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物６を得る。
製造例７ 農薬粒剤組成物７の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物５を２．２重量部（農薬活性化合物として４．０重量部）、粉状農薬組成物６を５．８重量部（農薬活性化合物として４．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６０．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物７を得る。
参考例１ 対照農薬粒剤組成物１の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物２を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物１を得た。
参考例２ 対照農薬粒剤組成物２の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物３を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物２を得た。
参考例３ 対照農薬粒剤組成物３の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を１．５重量部（農薬活性化合物として１．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７９．６重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物３を得た。
参考例４ 対照農薬粒剤組成物４の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物４を得た。
試験例１ 水稲の播種時覆土前処理によるイネに対する生育試験
水稲育苗箱（３０ｃｍ×６０ｃｍ）の播種前覆土前に供試粒剤組成物を１００ｇ／育苗箱の割合で処理し、湿籾（品種：ヒノヒカリ）を１６０ｇ播種した。育苗器（終日３０℃）で３日間発芽させた後、屋外に移動させて育苗を行い、播種１週間後にイネ（処理区）の草丈を測定した。一方、粒剤組成物を処理しない以外は前記と同様に播種及び育苗を行ったイネ（無処理区）の草丈を測定した（２反復）。処理区の草丈と無処理区の草丈とを下記式（Ａ）により対比して生育率（％）を算出し、下記の判定基準に従い生育状況を評価した。
《生育状況の判定基準》
［評価］ 生育率
−− ： ９８％以上
− ： ９５％以上９８％未満
＋ ： ９２％以上９５％未満
＋＋ ： ８９％以上９２％未満
＋＋＋ ： ８５％以上８８％未満
＋＋＋＋ ： ８５％未満
その結果を、〔表２〕に示す。
Next, the present invention will be described in more detail with reference to production examples, test examples, and the like, but the present invention is not limited to only these examples.
Reference Production Example 1 Preparation of Powdered Pesticide Composition 1 70.0 parts by weight of 2′-cyano-3,4-dichloroisothiazole-5-carboxyanilide (generic name: isothianyl) and 30.0 parts by weight of wax (Katsuyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) was uniformly mixed and pulverized with a centrifugal pulverizer, and 2′-cyano-3,4-dichloroisothiazole-5-5 having a volume median diameter of 4.12 μm. A powdery agricultural chemical composition containing carboxyanilide (hereinafter referred to as powdered agricultural chemical composition 1) was obtained.
Reference Production Example 2 Preparation of Powdered Pesticide Composition 2 70.0 parts by weight of the present amide compound 16 (compound described in Compound No. 16 in the above [Table 1]) and 30.0 parts by weight of branstone (Katsu A powdery pesticide composition (hereinafter referred to as a powdery state) containing the present amide compound 16 having a volume median diameter of 4.55 μm, which is uniformly mixed with Katsuyama clay S (manufactured by Katsuyama Mining Co., Ltd.) and pulverized with a centrifugal pulverizer. This is referred to as agrochemical composition 2.).
Reference Production Example 3 Preparation of Powdered Pesticide Composition 3 70.0 parts by weight of the present amide compound 9 (compound described in Compound No. 9 in [Table 1] above) and 30.0 parts by weight of branstone (Katsu A powdery agricultural chemical composition containing the present amide compound 9 having a volume median diameter of 3.86 μm (hereinafter referred to as powder) This is referred to as agrochemical composition 3.).
Reference Production Example 4 Preparation of Powdered Pesticide Composition 4 70.0 parts by weight of the present amide compound 20 (compound described in Compound No. 20 in the above [Table 1]) and 30.0 parts by weight of branstone (Katsu A powdery pesticide composition (hereinafter referred to as a powdery form) containing the present amide compound 20 having a volume median diameter of 4.90 μm, which is uniformly mixed with Katsuyama clay S, manufactured by Katsumiyama Mining Co., Ltd., and pulverized with a centrifugal pulverizer. This is referred to as agrochemical composition 4.).
Reference Production Example 5 Preparation of Powdered Pesticide Composition 5 70.0 parts by weight of clothianidin and 30.0 parts by weight of a wax (Katsumiyama Clay S, manufactured by Katsumiyama Mining Co., Ltd.) are mixed uniformly, and are centrifuged. By grinding, a powdery agricultural chemical composition containing clothianidin having a volume median diameter of 4.44 μm (hereinafter referred to as powdered agricultural chemical composition 5) is obtained.
Reference Production Example 6 Preparation of Powdered Pesticide Composition 6 70.0 parts by weight of Frametopill and 30.0 parts by weight of a wax (Katsumiyama Clay S, manufactured by Katsumiyama Mining Co., Ltd.) are uniformly mixed and centrifuged with a crusher. By pulverizing, a powdery agricultural chemical composition (hereinafter referred to as powdered agricultural chemical composition 6) containing furametopil having a volume median diameter of 4.02 μm is obtained.
Production Example 1 Preparation of Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 1 was obtained.
Production Example 2 Preparation of Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 2 was obtained.
Production Example 3 Preparation of Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide activity) 1.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight of Hodaka (Hojun Co.) and 69.6 parts by weight of wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) was added to polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 3 was obtained.
Production Example 4 Preparation of Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. The agrochemical granule composition 4 was obtained.
Production Example 5 Preparation of Pesticide Granule Composition 5 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (1.5 parts by weight as an agrochemical active compound), 5.0 weights of pregelatinized starch (Amilox No. 1A, manufactured by Nippon Corn Starch) Parts, 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Co., Ltd.), 10.0 parts by weight of montmorillonite (Bentonite Hotaka, manufactured by Hojun Co., Ltd.) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mine) About 6 parts by weight of water containing 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industry) is added to 66.0 parts by weight of the mixture and kneaded. . About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 5 is obtained.
Production Example 6 Preparation of Pesticide Granule Composition 6 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.8 parts by weight of powdered pesticide composition 6 (4.0 parts by weight as an agrochemical active compound), 5.0 parts by weight of pregelatinized starch (Amilox No. 1A, manufactured by Nippon Corn Starch) Parts, 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Co., Ltd.), 10.0 parts by weight of montmorillonite (Bentonite Hotaka, manufactured by Hojun Co., Ltd.) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mine) Add about 20 parts by weight of water containing 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) to 62.4 parts by weight of the mixture, and knead. . About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 6 is obtained.
Production Example 7 Preparation of Pesticide Granule Composition 7 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (4.0 parts by weight as a pesticide active compound), and 5.8 parts by weight of powdered pesticide composition 6 (as a pesticide active compound) 4.0 parts by weight), pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch) 5.0 parts by weight, calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Industries) 10.0 parts by weight, montmorillonite (bentonite hotaka, A mixture of 10.0 parts by weight of Hojun Co., Ltd. and 60.2 parts by weight of wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) is mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, Toho Chemical Business Ltd.) by addition of water to about 20 parts by weight containing 1.0 part by weight, and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 7 is obtained.
Reference Example 1 Preparation of Control Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 1 was obtained.
Reference Example 2 Preparation of Control Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 2 was obtained.
Reference Example 3 Preparation of Control Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide) 1.0 part by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) 79.6 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 3 was obtained.
Reference Example 4 Preparation of Control Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded product is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, the operation of the granulator is resumed, the granulated material obtained in 30 seconds is obtained, and the granulated material is dried at 70 ° C. for 30 minutes. A control agrochemical granule composition 4 was obtained.
Test Example 1 Growth test on rice by pre-soiling treatment at the time of sowing of paddy rice Before the sowing of paddy rice seedling box (30 cm x 60 cm), the test grain composition was treated at a rate of 100 g / nurturing box, : Hinohikari) was sown. After germination for 3 days in a seedling device (30 ° C. throughout the day), the seedlings were transferred to the outdoors to raise seedlings, and the plant height of rice (treated area) was measured one week after sowing. On the other hand, the plant height of rice (non-treated area) seeded and raised was measured in the same manner as described above except that the granule composition was not treated (2 repetitions). The growth rate (%) was calculated by comparing the plant height of the treated group with the plant height of the untreated group according to the following formula (A), and the growth status was evaluated according to the following criteria.
<< Growth criteria >>
[Evaluation] Growth rate −−: 98% or more −: 95% or more and less than 98% +: 92% or more and less than 95% ++: 89% or more and less than 92% ++++: 85% or more and less than 88% +++ +: Less than 85% Is shown in [Table 2].
参考製造例１ 粉状農薬組成物１の調製
７０．０重量部の２’−シアノ−３，４−ジクロロイソチアゾール−５−カルボキシアニリド（一般名：イソチアニル）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．１２μｍの２’−シアノ−３，４−ジクロロイソチアゾール−５−カルボキシアニリドを含有する粉状農薬組成物（以下、粉状農薬組成物１と記す。）を得た。
参考製造例２ 粉状農薬組成物２の調製
７０．０重量部の本アミド化合物１６（前記〔表１〕において、化合物Ｎｏ．１６に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．５５μｍの本アミド化合物１６を含有する粉状農薬組成物（以下、粉状農薬組成物２と記す。）を得た。
参考製造例３ 粉状農薬組成物３の調製
７０．０重量部の本アミド化合物９（前記〔表１〕において、化合物Ｎｏ．９に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が３．８６μｍの本アミド化合物９を含有する粉状農薬組成物（以下、粉状農薬組成物３と記す。）を得た。
参考製造例４ 粉状農薬組成物４の調製
７０．０重量部の本アミド化合物２０（前記〔表１〕において、化合物Ｎｏ．２０に記載の化合物）及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．９０μｍの本アミド化合物２０を含有する粉状農薬組成物（以下、粉状農薬組成物４と記す。）を得た。
参考製造例５ 粉状農薬組成物５の調製
７０．０重量部のクロチアニジン及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．４４μｍのクロチアニジンを含有する粉状農薬組成物（以下、粉状農薬組成物５と記す。）を得る。
参考製造例６ 粉状農薬組成物６の調製
７０．０重量部のフラメトピル及び３０．０重量部のロウ石（勝光山クレーＳ、勝光山鉱業所製）を均一に混合し、遠心粉砕機で粉砕して、体積中位径が４．０２μｍのフラメトピルを含有する粉状農薬組成物（以下、粉状農薬組成物６と記す。）を得る。
製造例１ 農薬粒剤組成物１の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物２を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物１を得た。
製造例２ 農薬粒剤組成物２の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物３を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物２を得た。
製造例３ 農薬粒剤組成物３の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を１．５重量部（農薬活性化合物として１．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６９．６重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物３を得た。
製造例４ 農薬粒剤組成物４の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物４を得た。
製造例５ 農薬粒剤組成物５の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物５を２．２重量部（農薬活性化合物として１．５重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６６．０重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物５を得る。
製造例６ 農薬粒剤組成物６の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物６を５．８重量部（農薬活性化合物として４．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６２．４重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物６を得る。
製造例７ 農薬粒剤組成物７の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物５を２．２重量部（農薬活性化合物として４．０重量部）、粉状農薬組成物６を５．８重量部（農薬活性化合物として４．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部、モンモリロナイト（ベントナイト穂高、ホージュン社製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）６０．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練する。得られる混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転する。１０秒間で得られる造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られる造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、農薬粒剤組成物７を得る。
参考例１ 対照農薬粒剤組成物１の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物２を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物１を得た。
参考例２ 対照農薬粒剤組成物２の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物３を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物２を得た。
参考例３ 対照農薬粒剤組成物３の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を１．５重量部（農薬活性化合物として１．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７９．６重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物３を得た。
参考例４ 対照農薬粒剤組成物４の調製
粉状農薬組成物１を２．９重量部（農薬活性化合物として２．０重量部）、粉状農薬組成物４を２．９重量部（農薬活性化合物として２．０重量部）、アルファ化澱粉（アミロックスＮｏ．１Ａ、日本コーンスターチ製）５．０重量部、炭酸カルシウム（ＳＳ♯８０、日東粉化工業製）１０．０重量部及びロウ石（勝光山クレーＳ、勝光山鉱業所製）７８．２重量部の混合物に、ポリオキシエチレントリスチリルフェニルエーテル（界面活性剤：Ｓｏｒｐｏｌ Ｔ−２０、東邦化学工業製）１．０重量部を含有する水 約２０重量部を加えて、混練した。得られた混練物の約１．５ｋｇを、０．９ｍｍφのスクリーン付きバスケット型押出造粒機（ＨＵ−Ｇ型畑式造粒機、畑製作所機）に投入し、まず１０秒間だけ当該造粒機を運転した。１０秒間で得られた造粒物を取り除いた後、当該造粒機の運転を再開し、３０秒間で得られた造粒物を取得し、当該造粒物を７０℃で３０分間乾燥して、対照農薬粒剤組成物４を得た。
試験例１ 水稲の播種時覆土前処理によるイネに対する生育試験
水稲育苗箱（３０ｃｍ×６０ｃｍ）の播種前覆土前に供試粒剤組成物を１００ｇ／育苗箱の割合で処理し、湿籾（品種：ヒノヒカリ）を１６０ｇ播種した。育苗器（終日３０℃）で３日間発芽させた後、屋外に移動させて育苗を行い、播種１週間後にイネ（処理区）の草丈を測定した。一方、粒剤組成物を処理しない以外は前記と同様に播種及び育苗を行ったイネ（無処理区）の草丈を測定した（２反復）。処理区の草丈と無処理区の草丈とを下記式（Ａ）により対比して生育率（％）を算出し、下記の判定基準に従い生育状況を評価した。
［評価］ 生育率
−− ： ９８％以上
− ： ９５％以上９８％未満
＋ ： ９２％以上９５％未満
＋＋ ： ８９％以上９２％未満
＋＋＋ ： ８５％以上８８％未満
＋＋＋＋ ： ８５％未満
その結果を、〔表２〕に示す。
Reference Production Example 1 Preparation of Powdered Pesticide Composition 1 70.0 parts by weight of 2′-cyano-3,4-dichloroisothiazole-5-carboxyanilide (generic name: isothianyl) and 30.0 parts by weight of wax (Katsuyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) was uniformly mixed and pulverized with a centrifugal pulverizer, and 2′-cyano-3,4-dichloroisothiazole-5-5 having a volume median diameter of 4.12 μm. A powdery agricultural chemical composition containing carboxyanilide (hereinafter referred to as powdered agricultural chemical composition 1) was obtained.
Reference Production Example 2 Preparation of Powdered Pesticide Composition 2 70.0 parts by weight of the present amide compound 16 (compound described in Compound No. 16 in the above [Table 1]) and 30.0 parts by weight of branstone (Katsu A powdery pesticide composition (hereinafter referred to as a powdery state) containing the present amide compound 16 having a volume median diameter of 4.55 μm, which is uniformly mixed with Katsuyama clay S (manufactured by Katsuyama Mining Co., Ltd.) and pulverized with a centrifugal pulverizer. This is referred to as agrochemical composition 2.).
Reference Production Example 3 Preparation of Powdered Pesticide Composition 3 70.0 parts by weight of the present amide compound 9 (compound described in Compound No. 9 in [Table 1] above) and 30.0 parts by weight of branstone (Katsu A powdery agricultural chemical composition containing the present amide compound 9 having a volume median diameter of 3.86 μm (hereinafter referred to as powder) This is referred to as agrochemical composition 3.).
Reference Production Example 4 Preparation of Powdered Pesticide Composition 4 70.0 parts by weight of the present amide compound 20 (compound described in Compound No. 20 in the above [Table 1]) and 30.0 parts by weight of branstone (Katsu A powdery pesticide composition (hereinafter referred to as a powdery form) containing the present amide compound 20 having a volume median diameter of 4.90 μm, which is uniformly mixed with Katsuyama clay S, manufactured by Katsumiyama Mining Co., Ltd., and pulverized with a centrifugal pulverizer. This is referred to as agrochemical composition 4.).
Reference Production Example 5 Preparation of Powdered Pesticide Composition 5 70.0 parts by weight of clothianidin and 30.0 parts by weight of a wax (Katsumiyama Clay S, manufactured by Katsumiyama Mining Co., Ltd.) are mixed uniformly, and are centrifuged. By grinding, a powdery agricultural chemical composition containing clothianidin having a volume median diameter of 4.44 μm (hereinafter referred to as powdered agricultural chemical composition 5) is obtained.
Reference Production Example 6 Preparation of Powdered Pesticide Composition 6 70.0 parts by weight of Frametopill and 30.0 parts by weight of a wax (Katsumiyama Clay S, manufactured by Katsumiyama Mining Co., Ltd.) are uniformly mixed and centrifuged with a crusher. By pulverizing, a powdery agricultural chemical composition (hereinafter referred to as powdered agricultural chemical composition 6) containing furametopil having a volume median diameter of 4.02 μm is obtained.
Production Example 1 Preparation of Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 1 was obtained.
Production Example 2 Preparation of Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 2 was obtained.
Production Example 3 Preparation of Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide activity) 1.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight of Hodaka (Hojun Co.) and 69.6 parts by weight of wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) was added to polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. Agrochemical granule composition 3 was obtained.
Production Example 4 Preparation of Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical), montmorillonite (bentonite) A mixture of 10.0 parts by weight Hotaka (Hojun Co., Ltd.) and 68.2 parts by weight wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) was mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-). 20, manufactured by Toho Chemical Co., Ltd.) About 20 parts by weight of water containing 1.0 part by weight was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. The agrochemical granule composition 4 was obtained.
Production Example 5 Preparation of Pesticide Granule Composition 5 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (1.5 parts by weight as an agrochemical active compound), 5.0 weights of pregelatinized starch (Amilox No. 1A, manufactured by Nippon Corn Starch) Parts, 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Co., Ltd.), 10.0 parts by weight of montmorillonite (Bentonite Hotaka, manufactured by Hojun Co., Ltd.) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mine) About 6 parts by weight of water containing 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industry) is added to 66.0 parts by weight of the mixture and kneaded. . About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 5 is obtained.
Production Example 6 Preparation of Pesticide Granule Composition 6 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 5.8 parts by weight of powdered pesticide composition 6 (4.0 parts by weight as an agrochemical active compound), 5.0 parts by weight of pregelatinized starch (Amilox No. 1A, manufactured by Nippon Corn Starch) Parts, 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Co., Ltd.), 10.0 parts by weight of montmorillonite (Bentonite Hotaka, manufactured by Hojun Co., Ltd.) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mine) Add about 20 parts by weight of water containing 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) to 62.4 parts by weight of the mixture, and knead. . About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 6 is obtained.
Production Example 7 Preparation of Pesticide Granule Composition 7 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as a pesticide active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide activity) 2.0 parts by weight as a compound), 2.2 parts by weight of powdered pesticide composition 5 (4.0 parts by weight as a pesticide active compound), and 5.8 parts by weight of powdered pesticide composition 6 (as a pesticide active compound) 4.0 parts by weight), pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch) 5.0 parts by weight, calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical Industries) 10.0 parts by weight, montmorillonite (bentonite hotaka, A mixture of 10.0 parts by weight of Hojun Co., Ltd. and 60.2 parts by weight of wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) is mixed with polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, Toho Chemical Business Ltd.) by addition of water to about 20 parts by weight containing 1.0 part by weight, and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ screen-equipped basket-type extrusion granulator (HU-G type field granulator, Hata Seisakusho), and first the granulator for 10 seconds. To drive. After removing the granulated material obtained in 10 seconds, the operation of the granulator is restarted, the granulated material obtained in 30 seconds is obtained, the granulated material is dried at 70 ° C. for 30 minutes, Granule composition 7 is obtained.
Reference Example 1 Preparation of Control Pesticide Granule Composition 1 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 2 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 1 was obtained.
Reference Example 2 Preparation of Control Pesticide Granule Composition 2 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 3 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 2 was obtained.
Reference Example 3 Preparation of Control Pesticide Granule Composition 3 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 1.5 parts by weight of powdered pesticide composition 4 (pesticide) 1.0 part by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) 79.6 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded material is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, restart the operation of the granulator, obtain the granulated material obtained in 30 seconds, and dry the granulated material at 70 ° C. for 30 minutes. A control agrochemical granule composition 3 was obtained.
Reference Example 4 Preparation of Control Pesticide Granule Composition 4 2.9 parts by weight of powdered pesticide composition 1 (2.0 parts by weight as an agrochemical active compound) and 2.9 parts by weight of powdered pesticide composition 4 (pesticide) 2.0 parts by weight as an active compound), 5.0 parts by weight of pregelatinized starch (Amylox No. 1A, manufactured by Nippon Corn Starch), 10.0 parts by weight of calcium carbonate (SS # 80, manufactured by Nitto Flour Chemical) and wax (Katsumiyama Clay S, manufactured by Katsuyama Mining Co., Ltd.) 78.2 parts by weight of a mixture contains 1.0 part by weight of polyoxyethylene tristyryl phenyl ether (surfactant: Sorpol T-20, manufactured by Toho Chemical Industries) About 20 parts by weight of water to be added was added and kneaded. About 1.5 kg of the obtained kneaded product is put into a 0.9 mmφ basket-type extrusion granulator with a screen (HU-G type field granulator, Hata Seisakusho), and first granulated for 10 seconds. I drove the machine. After removing the granulated material obtained in 10 seconds, the operation of the granulator is resumed, the granulated material obtained in 30 seconds is obtained, and the granulated material is dried at 70 ° C. for 30 minutes. A control agrochemical granule composition 4 was obtained.
Test Example 1 Growth test on rice by pre-soiling treatment at the time of sowing of paddy rice Before the sowing of paddy rice seedling box (30 cm x 60 cm), the test grain composition was treated at a rate of 100 g / nurturing box, : Hinohikari) was sown. After germination for 3 days in a seedling device (30 ° C. throughout the day), the seedlings were transferred to the outdoors to raise seedlings, and the plant height of rice (treated area) was measured one week after sowing. On the other hand, the plant height of rice (non-treated area) seeded and raised was measured in the same manner as described above except that the granule composition was not treated (2 repetitions). The growth rate (%) was calculated by comparing the plant height of the treated group with the plant height of the untreated group according to the following formula (A), and the growth status was evaluated according to the following criteria.
[Evaluation] Growth rate −−: 98% or more −: 95% or more and less than 98% +: 92% or more and less than 95% ++: 89% or more and less than 92% ++++: 85% or more and less than 88% +++ +: Less than 85% Is shown in [Table 2].
本発明の農薬粒剤組成物は、育苗箱に施用するための製剤として優れるものである。
The agrochemical granule composition of the present invention is excellent as a preparation for application to a nursery box.
Claims (11)
- 式（Ｉ）
〔式中、
Ｒ１は、ハロゲン原子又はＣ１−Ｃ４ハロアルキル基を表し、
Ｒ２は、水素原子、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ３は、水素原子、シアノ基、ハロゲン原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ４は、水素原子又はＣ１−Ｃ４アルキル基を表し、
Ｒ５は、Ｃ１−Ｃ４アルキル基、Ｃ３−Ｃ７シクロアルキル基、（Ｃ３−Ｃ７シクロアルキル）Ｃ１−Ｃ４アルキル基、（Ｃ１−Ｃ４アルコキシ）カルボニル基、（Ｃ１−Ｃ４アルコキシ）カルボニルアミノ基、｛（Ｃ１−Ｃ４アルコキシ）カルボニル｝（Ｃ１−Ｃ４アルキル）アミノ基を表し、
Ｒ６は、ハロゲン原子を表す。〕
で示される化合物と、
チアジニル、イソチアニル、プロベナゾール及びアシベンゾラル−Ｓ−メチルからなる群より選ばれる１以上の植物病害防除活性化合物と、
スメクタイト鉱物を含む増量剤と、
水溶性結合剤と
を含有する農薬粒剤組成物。 Formula (I)
[Where,
R 1 represents a halogen atom or a C1-C4 haloalkyl group,
R 2 represents a hydrogen atom, a halogen atom or a C1-C4 alkyl group,
R 3 represents a hydrogen atom, a cyano group, a halogen atom or a C1-C4 alkyl group,
R 4 represents a hydrogen atom or a C1-C4 alkyl group,
R 5 is a C1-C4 alkyl group, a C3-C7 cycloalkyl group, a (C3-C7 cycloalkyl) C1-C4 alkyl group, a (C1-C4 alkoxy) carbonyl group, a (C1-C4 alkoxy) carbonylamino group, { (C1-C4 alkoxy) carbonyl} (C1-C4 alkyl) amino group,
R 6 represents a halogen atom. ]
A compound represented by
One or more plant disease control active compounds selected from the group consisting of thiazinyl, isotianil, probenazole and acibenzoral-S-methyl;
A bulking agent containing a smectite mineral;
An agrochemical granule composition containing a water-soluble binder. - 式（Ｉ）で示される化合物１００重量部に対して、植物病害防除活性化合物が１００~５０００重量部の含有割合である請求項１記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 1, wherein the plant disease control active compound is contained in an amount of 100 to 5000 parts by weight per 100 parts by weight of the compound represented by the formula (I).
- 農薬粒剤組成物における、式（Ｉ）で示される化合物及び植物病害防除活性化合物の含有割合が、式（Ｉ）で示される化合物と植物病害防除活性化合物との合計で、農薬粒剤組成物全量に対して１~３０重量パーセントである請求項１又は２記載の農薬粒剤組成物。 In the agrochemical granule composition, the content ratio of the compound represented by formula (I) and the plant disease controlling active compound is the sum of the compound represented by formula (I) and the plant disease controlling active compound, and the agrochemical granule composition The agrochemical granule composition according to claim 1 or 2, which is 1 to 30 percent by weight based on the total amount.
- 農薬粒剤組成物における、スメクタイト鉱物を含む増量剤の含有割合が農薬粒剤組成物全量に対して４０~９８重量パーセントである請求項１~３いずれか一項記載の農薬粒剤組成物。 The agrochemical granule composition according to any one of claims 1 to 3, wherein a content ratio of the extender containing the smectite mineral in the agrochemical granule composition is 40 to 98 weight percent with respect to the total amount of the agrochemical granule composition.
- 農薬粒剤組成物における、水溶性結合剤の含有割合が農薬粒剤組成物全量に対して１~１０重量パーセントである請求項１記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 1, wherein the content ratio of the water-soluble binder in the agrochemical granule composition is 1 to 10 weight percent with respect to the total amount of the agrochemical granule composition.
- 植物病害防除活性化合物が、イソチアニルである請求項１記載の農薬粒剤組成物。 2. The agrochemical granule composition according to claim 1, wherein the plant disease controlling active compound is isotianil.
- ネオニコチノイド化合物を含有する請求項１~６いずれか一項記載の農薬粒剤組成物。 The agrochemical granule composition according to any one of claims 1 to 6, comprising a neonicotinoid compound.
- ネオニコチノイド化合物が、クロチアニジンである請求項７記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 7, wherein the neonicotinoid compound is clothianidin.
- スメクタイト鉱物を含む増量剤が、スメクタイト鉱物及び炭酸カルシウムを含む増量剤である請求項１記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 1, wherein the bulking agent containing smectite mineral is a bulking agent containing smectite mineral and calcium carbonate.
- スメクタイト鉱物が、ベントナイトである請求項１記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 1, wherein the smectite mineral is bentonite.
- 水溶性結合剤が、アルファー化デンプンである請求項１記載の農薬粒剤組成物。 The agrochemical granule composition according to claim 1, wherein the water-soluble binder is pregelatinized starch.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010800606863A CN102686103A (en) | 2010-01-08 | 2010-12-17 | Granular agrochemical composition |
| KR1020127017186A KR20120125458A (en) | 2010-01-08 | 2010-12-17 | Granular agrochemical composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010002681 | 2010-01-08 | ||
| JP2010-002681 | 2010-01-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011083709A1 true WO2011083709A1 (en) | 2011-07-14 |
Family
ID=44305445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2010/073484 WO2011083709A1 (en) | 2010-01-08 | 2010-12-17 | Granular agrochemical composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2011157351A (en) |
| KR (1) | KR20120125458A (en) |
| CN (1) | CN102686103A (en) |
| WO (1) | WO2011083709A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011134876A1 (en) * | 2010-04-30 | 2011-11-03 | Syngenta Participations Ag | A method of reducing insect-vectored viral infections |
| KR20190096995A (en) | 2016-12-27 | 2019-08-20 | 이시하라 산교 가부시끼가이샤 | Solid compositions for controlling harmful organisms containing cyclolanifrol or salts thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012017271A (en) * | 2010-07-06 | 2012-01-26 | Du Pont Kk | Agrochemical granule composition |
| JP6645016B2 (en) * | 2015-03-10 | 2020-02-12 | 住友化学株式会社 | Pesticide granules |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008280341A (en) * | 2007-04-12 | 2008-11-20 | Sumitomo Chemical Co Ltd | Hydrazide compound and its use in controlling harmful organism |
| WO2009020191A1 (en) * | 2007-08-08 | 2009-02-12 | Nippon Soda Co., Ltd. | Tetrazoyloxime derivative and plant disease control agent |
| JP2009073820A (en) * | 2007-08-31 | 2009-04-09 | Sumitomo Chemical Co Ltd | Granular agrichemical composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000063205A (en) * | 1998-08-19 | 2000-02-29 | Chisso Corp | Agrochemical grain for coated agrochemical granule, coated agrochemical granule, its production and cultivation of field crop using coated agrochemical granule |
| CN101287721B (en) * | 2005-10-14 | 2013-03-27 | 住友化学株式会社 | Hydrazide compound and pesticidal use of the same |
| JP5186751B2 (en) * | 2005-10-14 | 2013-04-24 | 住友化学株式会社 | Hydrazide compounds and their pest control applications |
| EP2070413A1 (en) * | 2007-12-11 | 2009-06-17 | Bayer CropScience AG | Active compound combinations |
| KR101570536B1 (en) * | 2008-05-16 | 2015-11-19 | 수미토모 케미칼 컴퍼니 리미티드 | Agrichemical granules |
| JP5256870B2 (en) * | 2008-06-11 | 2013-08-07 | 住友化学株式会社 | Agrochemical granules |
| JP2012017271A (en) * | 2010-07-06 | 2012-01-26 | Du Pont Kk | Agrochemical granule composition |
-
2010
- 2010-12-17 KR KR1020127017186A patent/KR20120125458A/en not_active Application Discontinuation
- 2010-12-17 WO PCT/JP2010/073484 patent/WO2011083709A1/en active Application Filing
- 2010-12-17 CN CN2010800606863A patent/CN102686103A/en active Pending
-
2011
- 2011-01-07 JP JP2011001823A patent/JP2011157351A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008280341A (en) * | 2007-04-12 | 2008-11-20 | Sumitomo Chemical Co Ltd | Hydrazide compound and its use in controlling harmful organism |
| WO2009020191A1 (en) * | 2007-08-08 | 2009-02-12 | Nippon Soda Co., Ltd. | Tetrazoyloxime derivative and plant disease control agent |
| JP2009073820A (en) * | 2007-08-31 | 2009-04-09 | Sumitomo Chemical Co Ltd | Granular agrichemical composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011134876A1 (en) * | 2010-04-30 | 2011-11-03 | Syngenta Participations Ag | A method of reducing insect-vectored viral infections |
| KR20190096995A (en) | 2016-12-27 | 2019-08-20 | 이시하라 산교 가부시끼가이샤 | Solid compositions for controlling harmful organisms containing cyclolanifrol or salts thereof |
| US10897902B2 (en) | 2016-12-27 | 2021-01-26 | Ishihara Sangyo Kaisha, Ltd. | Pesticidal solid composition containing cyclaniliprole or its salt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102686103A (en) | 2012-09-19 |
| KR20120125458A (en) | 2012-11-15 |
| JP2011157351A (en) | 2011-08-18 |
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