TW201201900A - Liquid clathrate with gas molecule dissolved therein in high density - Google Patents

Liquid clathrate with gas molecule dissolved therein in high density Download PDF

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Publication number
TW201201900A
TW201201900A TW100118432A TW100118432A TW201201900A TW 201201900 A TW201201900 A TW 201201900A TW 100118432 A TW100118432 A TW 100118432A TW 100118432 A TW100118432 A TW 100118432A TW 201201900 A TW201201900 A TW 201201900A
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TW
Taiwan
Prior art keywords
water
gas
molecules
liquid crystal
liquid
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TW100118432A
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Chinese (zh)
Inventor
Eiji Matsumura
Nobuko Hagiwara
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Eiji Matsumura
Nobuko Hagiwara
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Application filed by Eiji Matsumura, Nobuko Hagiwara filed Critical Eiji Matsumura
Publication of TW201201900A publication Critical patent/TW201201900A/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B5/00—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
    • B01F25/25—Mixing by jets impinging against collision plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B01F25/3124—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow
    • B01F25/31242—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow the main flow being injected in the central area of the venturi, creating an aspiration in the circumferential part of the conduit
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/005—Systems or processes based on supernatural or anthroposophic principles, cosmic or terrestrial radiation, geomancy or rhabdomancy
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/481—Treatment of water, waste water, or sewage with magnetic or electric fields using permanent magnets
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Physical Water Treatments (AREA)

Abstract

Provided are generating method, observation method, adoption method and so on for comprehending the reality of the water with gas molecule dissolved therein, wherein liquid clathrate is generated by dissolving gas molecule within raw water. Gas molecule is at least existed among the water molecules of the raw water, and hydrogen binding rate thereof is smaller than the hydrogen binding rate of the raw water. Liquid clathrate is generated by producing super-cavitation when gas is mixed into water.

Description

201201900 • 六、發明說明： . 【發明所屬之技術領域】 本發明係關於-種使氣體以分子單元高密度溶存於 水之液體及其利用技術。 【先前技術】 藉由於水或許多種類之溶液（以下，總稱為「液體」） 中添加氣體，可對液體賦予各式各樣的功能、性質之事實 已，人知。例如，藉由於液體中溶解氣體，同時並使氣體 以氣泡之狀態溶存於液體中，俾發揮特定功能的技術已為 人头又，為更提尚藉氣體之氣泡所發揮之特性效果同日夺 並保持該效果，使產生如微米泡或奈米泡之微細氣體的氣 泡，同時並於液體中溶存微細氣泡之技術已存在。 雖然因氣體之種類而異，但藉液體之溫度、壓力使氣 體溶解至一定的飽和濃度係已被證明，但當時於水構造引 起何種的變化則未被確認。又，氣泡係與飽和濃度無關係 而可於水中溶存，較5〇〇hm(奈米）更微細者已被揭示係不 易又浮力的影響。但，即使為超微細之數十奈米大小的氣 泡，離氣體分子之大小的程度還很遙遠，仍為極大的氣體 之塊體，溶存此等氣泡之水的構造究竟由原來的水產生何 種變化，與上述溶解飽和濃度氣體之液體同樣地未被確認。 上述技術係可於液體（液相）所使用者。另外，在固體 (固相）中之氣體的溶存技術，已知有被稱為氣體水合物 (Gas hydrate)、晶籠化合物（ciathrate)之技術。此等技 術係嘗試在高壓及接近冰溫之低溫下或負數十。c之低溫 3 323154 201201900 下，使氣體接觸液體，再進一步使氣體與液體接觸之環境 維持於高壓而使固化者。其結果，產生於以複數之液體分 子的結合所構成之籠狀構造（Cage)中封入的氣體分子（客 體（Guest)分子）部分，同時並生成成為固體之包接化合物 的氣體水合物、晶籠化合物者。亦即，此處所謂水合物、 晶籠化合物，係於分子間產生格子間鍵結之冰狀固體、或 於水之一部分產生格子間鍵結之漿液狀的流動液體，與未 進行格子間鍵結之水構造，經確認有明顯相異之相之現象 之物質狀態。 為了以省能源、低成本之方式貯存搬運LNG(Liguid Natural Gas ;液化天然氣）或 CNG(Compressed Natural Gas;壓縮天然氣）等目的，研究前述之冰狀的氣體水合物、 晶籠化合物的實用化。在氣體水合物、晶籠化合物之生成 過程，係必須有在約〇°C以下之低溫且數十氣壓以上之高 壓環境下進行氣體與液體之混合的條件。而且所生成之氣 體水合物、晶籠化合物的保管，則必須有負數十。C以下之 低溫環境條件。 另外’在專利文獻1中已提出一種對水照射波長2私m 至10/zm的非加熱性紅外線，改變水分子之oh伸縮振動 等’俾切斷水分子間之氮鍵，進行水構造之再編，生成水 晶籠化合物之方法。但不含有進行氣體滿合之提案。即使 不含氣體而單獨暫時切斷一定量氫鍵，由於在水之分子運 動中水分子係以奈秒以下之高速度變換自在地運動，故停 止紅外線照射後，氫鍵能量無法長時間保持相同的狀態， 4 323154 201201900 所謂可對水構造賦予安定之變化係很難想到β 又，在專利文獻2中已揭示一種氣體水合物之濃度檢 測方法，係使含有氣體水合物之漿液狀的溶液或冰、與不 含氣體水合物之漿液狀的溶液或冰等兩者，在相同的條件 下，使水之0Η吸收帶在特定的範圍進行紅外線分光測定， 再比較水分子之0Η吸收譜峰之方法。但，此係基本上以漿 液狀或冰之固體結晶、固體混合物為對象之測定方法，與 於液體之水構造上有變化之物質狀態有很大差異。 又，在專利文獻3中說明在水壓丨氣壓以上之水中， 產生顯示上昇速度較1職/秒更慢之性f的直徑為5()_以 下之氣體的超微錢泡的技術^在該文獻中餘述所謂藉 由該超後小氣㈣自己壓縮絲與壓壞現象強制形成水合 物的核之技術。在敘述中雖係在水中表現之案例，但從生 成時之水溫錄水合物平衡條件溫度低Q· 7ΐ之過冷條件 觀之其係限疋於經過黎液狀而變成冰之前，運動能量特 別降低狀態之氣液混合之方法，明顯地可理解係以水中之 至少-較_存在格子間繼之狀態為對象。於該幻 中並未歸水刀子之狀態及運耗量之變化等相關檢討 古進而在專利文獻4中揭示—種對水路内流動之水注 南屋喷水使產生空絲生成真空微泡，再以磁場對真空: 泡作用之水處理枝。_相微泡崩壞致水分子晶籠 合物進行微=化之說法，但實際上未進行有關水構造變 之水分子狀態。 [先前技術文獻] 323154 5 201201900 [專利文獻] [專利文獻1]日本特開2006、289335號公報 [專利文獻2]日本特開2009、115560號公報 [專利文獻3]日本特開2004、263152號公報 [專利文獻4]日本特開2006 - 181449號公報 【發明内容】 (發明欲解決之課題） 以水及其他液體為對象之任一技術，均限於使液體形 成漿液狀或至少冷卻至〇。〇附近而使運動能量降低之狀態 與氣體接觸或混合之方法。藉由在常溫、常壓條件下之氣 體/¾合法所生成者，提到特別之水構造的變化之文獻並不 存在’亦未嘗試測定分析。 本發明掌握溶存氣體分子之水的實態，對其生成方 法、觀測方法、利用方法等進行提案。 (用以解決課題之手段） 本案發明人專心研究有關使各種氣體溶存於水之技 術。繼而，在一定之條件下使氣體溶存於水所生成之液體 (氣體溶存液體）中，尋求可觀察該氣體之氣泡的方法，但 已確認在一定的條件下，即使實施各種方式的計測，亦無 法觀察氣體之氣泡。而且’亦已確認縱然使超過以往被認 為该氣體之過飽和濃度量之氣體溶存於水中時，亦無法觀 察氣體之氣泡的事例。 亦即，對於可觀察氣泡魏體，藉雷射射繞或動態光 散射光度計從氣泡之布朗運動演算存在之氣泡的分布，藉 323154 6 201201900 由類推氣泡之存在的方法進行觀察。在此過程中，發明人 等之目標在於調整可使用於水與氣體之混合的嘴射器的構 造，儘可能地適當調整壓力條件等，以得到更微細 發明人發現藉由條件之調整’使氣體混合於水中，在溶存 之瞬間使水中產生較高密度之空蝕作用，藉由更強力 使氣泡變形，可得到更微細之氣泡。 繼而，發現在以特疋條件下藉由喷射器產生氣體溶存 液體的製程中’在導入氣體同時使混合於水中之喷射器的 孔口部（小控部）之邊緣部產生空钱，但是不論孔口部之口 徑大小，若提高水之速度，雖於所生成之液體中未觀測到 氣泡，但可確認氣體之溶存，可長期間保持安定之溶存性。 累積詳細之觀察及研究有關本液體及其生成過程之 結果，發明人確定在奈秒間移動數十奈米之水中混入氣體 時，除了一般空蝕外，更藉由高密度之空蝕爆發氣泡，產 生分子粒（單一之分子）或分子群，分散於水中。亦即，並 非僅氣體之氣泡的溶存，被認為僅限發生於固相之晶籠化 合物·水合物現象’亦即，發明人確定客體氣體以分子狀 態存在於水構造内之晶籠化合物.水合物現象，基本上也 在與固相相異之液相條件下產生。 上述液體被認為係氣體分子溶存於水而生成之所謂 「液體晶籠化合物」之物質。在該液體中除了藉雷射繞射 或動態光散射光度計無法觀察到氣泡外，尚確認甚直玎藉 由密度差计測埃（A)大小之氣砲的所謂Spring 8 之X線小 角散亂計測裝置，未能觀察到氣泡。另外，藉紅外線分析’ 7 323154 201201900 令人驚訝地確認可實現水分子間之氫鍵相較於一般的水明 顯降低之狀態。 亦即，在液體晶籠化合物中，氣體分子或氣體分子群 進入水分子間，使水分子間之氫鍵距離產生變化的程度涵 蓋水全體而高密度溶存。氣體分子或氣體分原群當然不受 浮力的影響，在水分子間之鍵結交替（分子重組運動）持續 進行的水中繼續安定存在。而且，發明人成功達成前述狀 態生成時之水溫在20°C附近、可在大氣壓下生成保持，成 功獲得在常溫、常壓下於液體之分子（水分子）之間介入氣 體分子之新發現與物質。 從上述事項衍生出的本發明，係於原水中溶存氣體分 子所生成之液體晶籠化合物，係氣體分子至少存在於前述 原水的水分子間、氫鍵率小於前述原水的氫鍵率之液體晶 籠化合物。 *τ確疋在上述液體晶籠化合物中，藉由氣體分子進入 於水分子間而消滅水分子間的氫鍵。又可確定在上述液體 曰曰蘢化合物中，氫鍵能量小於前述原水之氩鍵能量。 前述原水亦可為含有有機物或微生物之至少任一者 的原液。 又，亦可確定在上述液體晶籠化合物中，藉由在前述 2 X中/合存氣體分子，水分子相較於周圍，高密度集合之 前述原水中的水分子團部分被破碎，相較於該原水則水分 子團部分被微細化，而且，前述氣體分子擴散至前述原水 存在 了保持前述被微細化之水分子團部分。 8 323154 201201900 再者’本發明係使氣體分子於水中溶存 晶籠化合物，亦包含肢外線分綠所測定之水 氫鍵能量之量小於水之液體晶籠化合物。 、 體曰Ltli發㈣絲體分子溶存於財巾所生成的液 曰曰籠化口物’亦包含氣體分子至少存在於前述原水的水 分子間，水分子以㈣圍更高之密度集合而成之水分子團 部分的水分子數較前述原水巾之水分子團部分的水分子數 少之液體晶籠化合物。 曰，外，本發明係使氣體分子溶存於原水中所生成的液 體晶籠化合物，亦包含於前述原水的水分子間不產生格子 間鍵結之液相中’氣齡子至少存在於前述原水的水分子 間之液體晶蘢化合物。 w又，上述液體晶籠化合物當然依氣體種而異，亦隨水 /皿條，而發生變化，但氣體分子完全溶人於水中之溶解現 ^、=泡存在之氣泡職等兩現象之程度並無關連，係以 風體刀子以對水獅能量與驗率造成影響之狀態存在的 ，體為對象。亦g卩，本發明之液體晶籠化合物不僅為只含 子之液體亦以含有氣體分子與氣泡等兩者的液 體作為其對象。 k 本發明亦包含液體晶蘢化合物生成裝置，係於 物生體刀子而生成液體晶籠化合物之液體晶籠化合 斜致，、置▲具備至少含有擠4傾斜路、擁路、開放傾 心述擠4傾斜路經過前削、徑路而於前述開放 斜路❹水之文丘里⑽聰）管；以及連接於前述小徑 9 323154 201201900 部’且供給氣體之氟體供給部’其特徵係前述擠出傾斜路 之截面積係朝向前述小徑路而變小，前述開玫傾斜路之截 面積係隨遠離前述小徑路而變大，而且前述文丘里 (VENTURI)管係於前述開放傾斜路内前端鄰接於前述小徑 路，同時具備為了在產生第一次空蝕作用之奈秒後使第二 次空蝕作用實施於氣體混合液之目的而搭载之至少含有從 該前端隨遠離前述小徑路而截面積擴大之擴大部的超空韻 作用部者。 在上述液體晶籠化合物生成裝 部之前端可藉平面部構成，前述擴大部可構成為圓錐形 狀。又，配置於前述文丘里（VENTURI)管之周圍，於至少^ 有前述前端之區域，亦可使構成超空蝕作用部之芯的構利 藉由連結強磁性體金屬與配置於該裝置之周圍的磁性電與 之強力磁場，形成橫跨液體流路加入磁性作用的構造。 此外，本發明係於水中溶存氣體分子，而生成液體£ 籠化合物之液體晶籠化合物生成方法，係包含：從文丘^ ⑽丽）管之擠錢斜路經過小徑路而於·傾斜路送 出水，藉從前述小徑路朝前述職傾斜路所送出之水的效 引壓力，從連接於前述小祕之氣體供給部使氣體供给至 前述小徑路内’藉由從前述小徑路朝前述開放傾斜路 =出之水的第丨㈣，壓縮前述氣體之氣泡而生細 氣體氣泡，再藉由传u 、各 氣_在特定部㈣度:高迷== = == 述微細氣體氣泡，《生成氣體分子，擴散至水中之液= 323154 10 201201900 籠化合物生成方法。 在上述液體晶籠化合物生成方法t，可將橫切之磁場 安置於前述特定部位。以本方法所生成之液體晶籠化合物 亦包含於本發明中。 此外，本發明係亦包含一種液體晶籠化合物之觀測方 法，係使氣體分子溶存於原水中所生成之液體晶籠化合物 之觀測方法，係將前述液體晶蘢化合物冷卻至特定溫度以 下，對所冷卻之前述液體晶籠化合物照射紅外線，藉由比 較前述液體晶籠化合物之紅外線吸光度與預先測得之原水 的紅外線吸光度，觀測得前述液體晶籠化合物之氫鍵率小 於前述原水之氩鍵率、在液體晶籠化合物中氣體分子至少 存在於前述原水之水分子間者。再者，本發明亦包含一種 液體晶籠化合物之觀測裝置，係使氣體分子溶存於原水中 所生成之液體晶籠化合物之觀察裝置，係具備將前述液體 晶籠化合物冷卻至特定溫度以下之冷卻裝置；以及對所冷 卻之前述液體晶籠化合物照射紅外線，藉由比較前述液體 晶籠化合物之紅外線吸光度與預先測得之原水的紅外線吸 光度，觀測前述液體晶籠化合物之氫鍵率小於前述原水之 氫鍵率、在液體晶籠化合物中氣體分子至少存在於前述原 水之水分子間之紅外線分光分析裝置。 上述之氣體分子，包含氧分子、氮分子、氫分子、臭 氧分子、二氧化碳氣體分子等，但是氣體種類並不限於這 些分子，其他氣體及含有其他氣體者亦可作為對象，氣體 濃度並無限制。 11 323154 201201900 (發明之欵果） 依本發明，可生成以往完全未有的溶存氣體分子之新 臟體’同時明瞭其特有性質，亦提示其利用方法ό 【實施方式j 於說明本發明之前，先說明於理解本發明時成為參考 八 9籠化合物（Clathrate)、水合物（hydrate)之觀 二之=籠化合物一般已知係於由特定化合物的結晶格所製 等之於^中’置入其他物質之原子或分子’不藉由共價鍵 (也表而以安定的狀態存在之物質。亦稱為包接化合物 以於特^為「包攝」、「抱攝」等）。例如矽晶籠化合物，係 客體原的=晶構造（有各種型式）之中封人驗金屬等 入物又/般已知之水合物（氣體水合物）亦稱為水包接化 ° ，係在藉由氫鍵以水分子構成的立體網狀構造的間隙 中以置入其他氣體分子之狀態存在的物質。牲釗當去& ^^K^(Methanehydrate),,^x^.4r,i, ，狀構造之間隙中置人甲烧分子所形成的外觀如冰、果子 路之物質，因係大量存在於日本近海之天然物質故其有 效利用廣受期待。 、 如甲烷水合物於海底或凍土之中以固體存在已為人 t般，-般已知所謂晶籠化合物、水合物之物質係在所謂 间壓環境、結冰溫度區域或其以下之低溫條件下，以具有 特疋結晶構造的固體物質之形態存在。 另外，說明本發明之概念時，亦可使用所謂「水合 323154 12 201201900 物」、「晶籠化合物」之用語’但意指本發明之生成物質時 的「水合物」、「晶籠化合物」，係不具有如上述一般認知之 固體、結晶格之構造、性質。 亦即’如已說明般’在本發明中為母體物質之水基本 上為液體’並非固體、結晶格子等格子間結合的構造’就 此點而言係與習知之晶籠化合物、水合物相異，本發明之 物質係亦可稱為液體晶籠化合物（液體水合物）者。與結晶 化冰狀固體之習知含氣體的固相物質比較，本發明之所謂 流動液相之母體物質狀態具有基本上差異，但是氣體以分 子單元分散於水中之點則係共通，故亦表現為晶籠化合物 者0 依2005年R. J. D· Miller等人之報告，對水照射雷射 脈沖而產生的構造變化係於50飛秒以内消失。（Utrafast memory loss and energy redistribution in the hydrogen bond network of liquid H2O、Nature 434，199-202，2005 年3月10日發表）。亦即，水之運動變化為極短時間之運 動’即使在時間上可計測之界限範圍的區域亦很難確實的 觀測。又，假如，包圍觀測對象之水的壓力條件即使為無 變化的狀態’有時水溫之變化造成運動能量巨大變動而無 法定量計測’因而阻礙在常溫條件之水物性研究之解明。 本發明之生成物質的液體晶籠化合物之概念圖表示 於第1圖。此係以模型表示水不斷運動之瞬間分子狀態的 圖。在第1圖中，水分子H2O中之Η原子係與電陰性度大 的0原子以共價鍵（圖中之虛線）結合，帶有正（+)電荷（氫 13 323154 201201900 離子）。此Η原子與其他ΗϋΟ分子中帶有負（-)電荷之〇原 子以氫鍵（圖中之虛線）結合。在無雜質之水中，圖中之各 分子以外的區域係成為非物質空間，於此非物質空間可置 入例如醇等可與水進行水和的物質因此水與醇混合後之總 和量係從兩者之單純體積的和減少一定量。又，在水之分 子運動中，在氫鍵處帶有負電荷之二個水分子的氧原子之 間，產生帶有正電荷之氫離子的交互往返（接球）已為人知。 使氣體溶解於水時，非Η2〇之氣體分子等其他物質與 醇同樣，於非物質空間容許而溶存之現象係表現為溶解。 依作用於水之環境壓力條件與水溫條件而溶存氣體濃度相 異，但已知在一定條件下，特定氣體溶存於水之量為一定 量。另外，在前述飽和濃度以下之溶解現象中，係未觀測 到水分子間之運動能量、亦即氫鍵率之變化。此係自以往 所知之氣體的溶解作用，並未對水之氫鍵率造成變化。 因此，此次發明人闡明在一定條件下藉由氣液混合所 進行的水處理，係使水之氫鍵率產生明暸的變化之製程， 且初次生成可被確認此等變化的物質並瞭解該物質的存 在。亦即，在該物質之液體水合物中，氣體係以分子單元 以高密度進入水分子間’因為押入擴展非物質區域，故水 分子間之氫鍵成立之比率（氫鍵率）相較於氣體分子未進入 之水的氫鍵率，降低至可計測的程度。 此配Ϊ關係（氣體分子對水分子間之氫鍵造成影嚮之 狀態的酕ί關係）係藉分子運動以數十飛秒至微微秒的極 豆時間艰位反覆朋壞與結合而變動，係很難觀測者。但在 14 323154 201201900 本發明之㈣晶籠化合物巾，該配置關係在經過數小 之試樣中，維射能制比她度之安紐。氣體分子擴 體而以高密度分散存在’故依據該配置關係的氫 鍵率降低，就總量而言為可顯著觀察之程度而可進行叶 被長時間維持。又，如後述般，被較為在氣液 ^之生成處理過程中，隨著氣體分子之擴散作用，被稱 為水分子®之水分子塊藉氣齡子之放射與介人而崩壞之 造成氩鍵率的降低。因此，在本發明之液體晶籠 ° 即使溶存氣體濃度在飽和濃度以下時，相較於 未溶存水’可確認氫鍵率明顯降低之現象。 、 本發明之液體晶籠化合物係於水中溶存氣體分子而 ^成，可硯為「水晶籠化合物」。此處，將溶存氣體分子之 前的原來之水規定為「原水」。所謂原水係—般的飲料水、 人2用水、純水等，被視為水概念者全部均被包含，亦包 =含有些許雜質者。亦包含含有如後述之有機物或微生物 ，但含有如此之刻意混合物的水，亦被視為為「原液」。 繼而’氣體分子溶存於原水之結果，生成雜晶籠化 Μ液體晶籠化合物之氫鍵率係小於溶存氣體分子 子Γ原氫鍵率。亦即，在液體晶籠化合物中的水分 率為鍵率的比率相較於在原水中氫鍵率成立的比 以溶存於仏在树明之㈣晶籠化合物巾，氣體分子係 明之液pi 態料祕的㈣，故亦可將本發 體曰曰4化合物稱為氣體分子溶存液體。 右由另外之看法，在本發明之液體晶籠化合物中，存 323154 15 201201900 在於水中之水分子間的非物質空間（電子或中性子等之素 粒子以外係本來即無释何的空間）之氟雜分子增加而押擠 展開非物質空間，消滅水分子間氫鍵么規象被掌握。氣體 分子進入水分子間，降礙在兩者之間的氮離子的捕捉球 者。在該現象中氣體分子使水分子間力雖離擴展f大於可 以氫鍵能量連繫水分子之距離’計測水方子間的氣鍵此量 時其總量降低。 又，在本發明之液赠晶籠化合物中’亦可謂藉由氣體 分子之作用，不僅水分手間，氫離子與其他混入物之間的 氫鍵所產生之氫鍵能量，較原水的氫嫁肖b：E更降低 此外，另外的現象该由，如後述雜在混0處理中使 用高速且高強度之例>鋒ί見象使氣雜封入液體中之過 程，氣體氣泡或氣體分孑群爆發，氣贌分子被放射。其後 重新說明，但認為在氣艨分子移動軌道上的水分子團一部 分斷裂，其總量係顯示降低氫鍵率之移度。此外，被放射 進入軌道之氣體分子因水之阻力而分別停止，以極高密度 散佈於水中之全域。藉由在此一連串的過程產生氫鍵被切 開的現象（主要在水分子團間的氫鍵之消失）、與前述因氣 體分子介入而氫鍵报難成立的現象（主要在氫分子間的氫 鍵之消失）等兩種現象之作用，被認為是產生此次揭示之水 的性質之變化現象之原阁。使水分子團崩壞的現象，即使 在飽和濃度以下之條件下，也被認為與氫鍵率顯著減少之 結果有關。 上述之此等作用如隨後之說明般，可藉紅外線分光法 16 323154 201201900 明確觀察氳鍵率相較於原來的水之原水更降低之程度中， 係以面密度、高濃度產生於液體中（亦即氣體分子以高密 度、面濃度於水中散佈）而對原水造成顯著的性質變化。 又，雖提示氫鍵率、氫鍵能量等概念作為比較原水與液體 晶籠化合物之要素，但比較時係必須在相同之條件下比 較。例如必須有氣體分子以外之成分等同等的原水與液體 晶籠化合物之間的比較。進而必須使水溫為一定。此外， 若水溫上昇則水運動能量激烈改變，計測困難性增加，因 此於低水溫進行計測至為重要，較佳係維持於所謂水分子 密度最安定的4°C進行計測。又，為了更無誤的觀察變化 之程度，宜對原水、氣體溶存水等對象液試樣一起進行複 數計測並將其數據平均化，由一起比較平均化之數據，可 掌握明顯的差異。在如此之條件τ ’在原水與㈣晶籠化 合物之間觀測如上述之氫鍵率、氫鍵能量等，具有意義， 兩者之間將產生可捉摸的差異。 各個水分子及氣體分子的作用以及分子間網絡之狀 態為微小世界的事件，且於微微秒程次不斷地進行運動變 化，故不可能直接觀察。但藉由掌握水全體之氫鍵能量， 可觀察液體晶籠化合物中氣體分子的行為。即使在一般的 水中，藉分子運動造成水分子間的氫鍵重複發生與消滅， 但在本發明之晶籠化合物中，藉由氣體分子進入水分子間， 使水分子間之氫鍵率錢水還大_率（每單位時^氮鍵 消滅之次數）消滅。 第2圖（a)係表示在一般水中水分子之行為的模示 323154 17 201201900 圖’第2圖（b)係表示本發明之液體晶籠化合物中水分子與 氣體分子之行為的模式圖，相當於以更寬的範圍看第j圖 圖第2圖（b)係表示氣體分子為臭氧分子之例，但是氣 體分T係不限於臭氧分子。如第2圖（a)所示般，在一般水 中水分子係採取以奈秒以下之_重複氫鍵之生成與斷裂 之狀〜另外，如第2圖（b)所示，在液體晶籠化合物中， 乱體分子係依後述之方式爆發成放射狀而擴散，如第19 圖所示其行進貫通粉碎水分子團，藉水之阻力停止時可 維持f分子之海的空間。此處，氣體分子使聽率相較於 周2的尺刀子團部微細化以消滅一部分鍵結，同時依前 述氫鍵的_妨礙氫鍵之成立條件，發揮減少—部 鍵作用。有關水分子團亦說明於後。 Μ二^批特定讀較_當於本發明之液體晶 〇 方法係無特別限定，而可採用所有的方法。簡 單之方法之—例，可舉例從液體藉減壓取出氣體之方法。 預先=¾鍵率等之液體使用公知的裝置使置於可充分脫 3製可使溶入之氣體(分子)強制性脫氣。對 的液體比率等，藉由與原本 對象液體是否為液體晶籠化合物。 、、w ，說明當本發明之液體晶籠化合物 次所採用之超霸生成時’本 亦被摇A* PeiXaVltatlQn)之概念。—般之空蝕 力低之部^現ί，謂以高速流動之流體（水等）之中的壓 ^ 刀仃氣化，於非常短的時間產生蒸氣袋，又以 非常短時間潰散而消滅的現象。可於引起此空錢象之處 323154 18 201201900 混^氣體而故意地進行強度高的混合。超空蝕係謂比一般 之空蝕更積極地大量產生，減少物體與周圍流體之摩擦的 方法亦即，超空钮係以高密度引起空钱，在流體流動方 向的下流域顯現減少與流體接觸之物質的摩擦阻力的效果 之見象藉空餘而使物體周圍的液體氣化，係因氣體之密 又运】於々IL體之液體，故依阻力減少的原因所致。此次之 實施例，係以如下之目的使用：更減少在混合裝置内之阻 力而加速含有氣體之液體的流速之目的；以及提高空蝕作 的強度，增加氣體氣泡的分裂效果，而得到氣體分子爆 發成為分子粒被放射之程度的作用。 第3圖係表示產生超空蝕之狀態的概念圖。以高速流 動之液體（以灰色所示之部分）中，放置的物體（黑）之後方 產生超空蝕。 其次參照第4圖，說明有關本實施形態之氣體混合液 生成裝置的構造。氣體混合液生成裝置201係包含：貯存 槽202、氣體供給裝置203、從貯存槽202取出之被處理液 返至貯存槽202之循環系裝置2〇4、設於循環系裝置2〇4 之中途的氣液品合裝_置（液體晶籠化合物生成裝置）2〇5、溶 解促進槽206、與附設於貯存槽202之溫度保持裝置2〇7。 如第4圖所示般，於貯存槽202係介由取水閥2〇2v 而注入作為被處理液之原水。貯存槽202係用以貯存介由 所取水之原水及後述之循環系裝置204而循環的氣體混合 液，亦即用以貯存液體晶籠化合物者。於貯存槽2〇2所貯 存之液體，係藉由溫度保持裝置207而保持於例如丨至2〇 323154 19 201201900 °c之範圍。藉由溫度設定於此範圍’例如氣體分子為臭氣 分子時，抑制伴隨亨利常數所說明之隨溫度上昇的臭氧自 己分解現象，效率佳地進行臭氧溶解及濃度上昇，且可不 降低所溶解之臭氧濃度。臭氧以外之氣體雖幾乎不具有所 謂因溫度上昇造成分解的特質，但保持不使水溫形成高溫 之程度的水分子運動之安定性’結果可維持高處理效率。 溫度保持裝置207係亦可依條件而省略。又，溫度設定範 圍亦可綜合性考量被處理液（原水及/或液體晶蘢化合物） 或氣體（氣體群）的種類或性質，以及添加物之有無等而設 定。溫度保持裝置207包含從貯存槽202取出被處理液之 泵浦21卜與用以冷卻所取出之被處理液的冷卻機212，貯 存槽202與泵浦211與冷卻機212之間，係藉由使被處理 液通過之配管213而連結。 藉由上述構成，貯存於貯存槽202之被處理液係藉由 泵浦211之作用而從貯存槽202取出，被送至冷卻機212。 冷卻機212係使被送來之被處理液冷卻至特定範圍的溫度 後返回貯存槽202。泵浦211係藉由在圖外之溫度計所計 測之貯存槽202内的被處理液之溫度，僅於超出特定範 圍、必須冷卻時才動作。藉由設置貯存槽202，藉由被處 理液暫時貯存而可進行上述冷卻，同時並使被處理液處於 安定狀態，藉此，例如氣體分子為臭氧分子時，對被處理 液保持臭氧之狀態，同時可藉由熟成類似的作用而促進溶 解。又在寒冷地等有被處理液凍結之顧慮等情形，取代上 述冷卻機或與上述冷卻機並用，亦可使用加熱器裝置加溫 20 323154 201201900 被處理液之構成。 本實施形態之氣體供給裝置203,係生成特定之氣體， 並用以供給之裝置。基本上氣液混合裝置205係伴隨空蝕 之發生而產生真空現象，供給氣體雖係從氣體供給裝置 203以負壓吸引，但亦可依需要進行加壓等之後進行供給。 若為可供給必要之氣體量者，氣體供給裝置203作用之氣 體的發生原理等無任何限制。藉氣體供給裝置203所生成 之氣體，係介由設於氣體供給管217之中間的電磁閥218 與逆止閥219而供給至氣液混合裝置205。混合於被處理 液之氣體例如若為大氣，空氣加壓裝置（compressor)等成 為此氣體供給裝置之主要構成要素。混合複數種類的氣體 時，係使用生成或採取各氣體等之裝置。 其次，參照第4圖及第5圖說明有關氣液混合裝置（液 體晶籠化合物生成裝置）205的内容。氣液混合裝置205 亦被稱為喷射器，如前述般，在發明人以得到水中更微細 的氣泡為目標之過程，具有藉由進行其調整所得到的構 成。氣液混合裝置205係含有文丘里（VENTURI)管231與作 為供給氣體之氣體供給部之氣體供給管239。本實施形態 之氣液混合裝置205係進一步含有超空蝕作用部237、與 磁性回路243。文丘里管231與氣體供給管239係藉由具 有透磁性之合成樹脂材一體構成。文丘里管231係具有使 從上流侧（第5圖之箭號A1側）所送出之被處理液朝下流側 (第5圖之箭號A2側）通過之管狀的外觀，被處理液係從箭 號A1沿A2之轴線方向（長方向）流動。朝長方向貫通文丘 21 323154 201201900 里管231、於文丘里管231内部所劃定之中空部，係從上 流侧朝向下流側，依照上流側大徑路232、擠出傾斜路 233、小徑路234、開放傾斜路235及下流側大徑路236之 順序連通的狀態形成^ 上流側大徑路232係對於氣體供給管239之軸線方向 (垂直於文丘里管231的軸線方向之方向）具有特定之第1 角度（例如50度等），而介由傾斜於擠出方向之擠出傾斜路 233而連接於小徑路234,其後，藉開放傾斜路235而對於 相同轴線方向具有特定之第2角度（例如30度等）而開放。 開放傾斜路235係連接於與上流側大徑路232相同外徑的 下流側大徑路236。換言之，擠出傾斜路233之截面積（流 路面積）係朝向小徑路234而變小，開放傾斜路235之截面 積（流路面積）係隨遠離小徑路234而變大。亦即，小徑路 234之截面積（流路面積）係在文丘里管231内最小。一般 設疋成第1角度>第2角度，擠出傾斜路233之傾斜度係 較開放傾斜路235之傾斜度更陡。 小徑路234係與其軸線方向垂直地連接氣體供給管 239’氣體供給裝置239之開口端在小徑路234之軸線方向 的中央部，開口於小徑路234。氣體供給管239之供給端（開 口於小徑路234之開口端的逆側）係連接與氣體供給裝置 203連通之氣體供給管217(第4圖）。 小徑路（孔口部）234之截面積（流路面積）係在文丘里 管231内最小，從擠出傾斜路233送出至小徑路2料之被 處理液，係因流路面積之急劇減少而曝露於極高之壓力。 323154 22 201201900 通過小徑路234後，被處理液隨遠離小徑路234而突入於 截面積變大的開放傾斜路235，由於從高壓開放，故小徑 路234之軸線方向的中央部或其下流側附近，係依被處理 液之壓力變化而成為真空或近似真空之狀態。到達氣體供 給管239之供給端的氣體係被吸引（被處理液之吸引壓力 作用）、被散佈於亂流化之被處理液内。此現象為後面說明 之第1空蝕。 較小徑路234更下流侧’開放傾斜路235及下流侧大 徑路236之内部，係即使在氣液混合裝置205之中設有專 司以超空飾之作用為主的超空钮作用部237。超空#作用 部237將於後述詳細說明。 於文丘里管231 ’藉螺絲（省略圖示）等固定磁性回路 243。磁性回路234係藉由使挾住文丘里管231而對向之一 側的磁石片245及另一侧之磁石片246，以及與一侧的磁 石片245及另一側之磁石片246連結、同時具有安農磁石 片於文丘里管231之功能的截面為u字狀之連結構件248 所構成。藉組入磁性回路，防止磁場朝向並非喷射器之混 合裝置周圍無益地放出。磁石片245與磁石片246係宜於 小徑路234及/或其附近（尤其小徑路234之下流侧）使其磁 力線（磁場）儘可能最多量通過以小徑路234為中心之喷射 器部管内的流水域全域般配置。藉由使磁力作用於被處理 液（水）與氣體兩者，被認為可對被處理液以最佳效率使氣 體溶解。 磁石片245與磁石片246係藉由钕磁石等構成，但磁 323154 23 201201900 石的種類無特別限定。連結構件248係為了抑制磁束洩漏 而使磁力作用儘可祕财於被處理㈣，由磁力透磁率 (以）大之構件（例如鐵等）構成。 藉氣液混合裝置2〇5所生成之液體晶籠化合物，係經 由配f 274送至溶解促進槽2〇6。溶解促進槽2〇6係構成 為圓筒形狀’促進氣體溶解於水者。經過溶解促進槽2〇6 之液體晶籠化合物，被送至氣液分離裝置265。氣液分離 裝置265係發揮用以分離排出被處理液與從此被處理液脫 氣之氣體的脫氣構造功能。藉由氣液分離裝置265所分離 之氣體’係藉域體分解|置267分解及無害化後放出至 裝置外部。 循％系裝置204係具有使通過氣液混合裝置2〇5之液 體晶籠化合物循環而再度使通過氣液混合裝置之功 月b再度使通過氣液混合裝置2〇5，係藉由於已溶解氣體 之被處理液（㈣晶籠化合物）再纽人氣體，而更提昇氣 體之溶解度與濃度。循環系裝置2〇4係料浦271作為驅 動源，以貯存槽202與溶解促進槽206作為主要的構成要 素亦即，泵浦271係將從貯存槽2〇2經由配管27〇取出 ^被處理液’經由逆止閥272及崎2?3壓送至氣液混合 、置205。藉由麗送而通過氣液混合裝置2的之被處理液， 係跳過配管274及溶解促進槽2〇6，經由配管奶返回貯 存槽搬。循環线置聊係構成為使上述步驟依需要而 #環之- 人數係為得到欲生成之液體晶籠化合 物的氣體溶解度或氣體濃度等，可自由地狀。又，於配 323154 24 201201900 之開關，被用來 的被處理液的水 管275之中途設有閥門276，藉閥門276 控制通過小徑路234之氣液混合裝置2〇5 壓。 繼而 M 超錢之主要部功㈣氣液混合 裝置205 ’尤其對於超空蝕作用部237，使用第5圖、第6 圖而㈣說明合裝置205係亦被稱為喷射器，發 日狀以得到水巾更微細的氣泡為目標之過程，具有可藉由 進行其調整而得到之構成。 如則述般車乂小徑路234更下流侧，開放傾斜路235 及下流側大徑路236之内部’設置在氣液混合裝置2〇5中 也專司以超錢仙為主的超线作用部237。超空姓作 用部237之截面中心係與開放傾斜路235及下流側大徑路 236之截面中心一致。亦即超空蝕作用部237之截面，係 相對於開放傾斜路235及下流側大徑路236之截面成為同 心圓。 超空蝕作用部237係位於上流侧（接近小徑路234之 侧），由呈現圓錐形狀之擴大部237a以及與該擴大部237a 一體連接而設於下流侧（遠離小徑路234之侧）之本體邹 237b所構成。擴大部237a係至開放傾斜路235之轴線方 向（文丘里管231之軸線方向）的中央部附近為止，朝向下 流側（隨遠離小徑部234)而徐緩地擴大截面積般形成，一 體連接於本體部237b。又’擴大部237a最接近小極路以4 的前端構成平面部237c，在開放傾斜路235内鄰接於巧 路234。該平面部237c係相對於擴大部237a之袖線方向 25 323154 201201900 (文丘里管231之軸線方向)’以垂 237b係基本上相對於軸線方向〜面構成不 在進-步實施的裝置中1 ⑽截面而形成°201201900 • VI. Description of the invention: .  TECHNICAL FIELD OF THE INVENTION The present invention relates to a liquid in which a gas is dissolved in water at a high density of molecular units and a utilization technique thereof. [Prior Art] It has been known that various functions and properties can be imparted to a liquid by adding a gas to water or a plurality of types of solutions (hereinafter, collectively referred to as "liquid"). For example, by dissolving a gas in a liquid and simultaneously dissolving the gas in a liquid state in a bubble state, the technique of exerting a specific function has become a leader, and the effect of the bubble which is further enhanced by the gas is maintained and maintained. This effect has been made to produce a bubble of a fine gas such as a microbubble or a nanobubble, and a technique of dissolving fine bubbles in a liquid. Although it varies depending on the type of gas, it has been proved that the gas is dissolved to a certain saturated concentration by the temperature and pressure of the liquid, but what kind of change is caused in the water structure at that time is not confirmed. Further, the bubble system has no relationship with the saturation concentration and can be dissolved in water, and it is revealed that it is less susceptible to buoyancy than the finer than 5 hm (nano). However, even the ultra-fine tens of nanometer-sized bubbles are far away from the size of the gas molecules, and are still extremely large blocks of gas. What is the structure of the water in which these bubbles are dissolved? The change was not confirmed in the same manner as the above-described liquid in which the saturated concentration gas was dissolved. The above techniques are available to liquid (liquid phase) users. Further, a technique called a gas hydrate or a ciathrate is known as a technique for dissolving a gas in a solid (solid phase). These techniques are attempted at low temperatures or near low temperatures at ice temperatures. The low temperature of c 3 323154 201201900, the gas is brought into contact with the liquid, and the environment in which the gas is in contact with the liquid is further maintained at a high pressure to cure the person. As a result, a gas molecule (guest molecule) enclosed in a cage structure composed of a combination of a plurality of liquid molecules is generated, and a gas hydrate or crystal which is a solid inclusion compound is simultaneously formed. Cage compound. That is, the hydrate or crystal cage compound herein is an ice-like solid which generates inter-grid bonds between molecules, or a slurry-like flowing liquid which generates inter-lattice bonding in one part of water, and does not perform inter-lattice bonding. The water structure of the knot, the state of matter confirmed by the phenomenon of distinct phases. In order to store and transport LNG (Liguid Natural Gas) or CNG (Compressed Natural Gas) for energy conservation and low cost, the application of the above-mentioned ice-like gas hydrates and cage compounds has been studied. In the process of forming a gas hydrate or a crystal cage compound, it is necessary to carry out a condition in which a gas and a liquid are mixed at a low temperature of about 〇 ° C or lower and a high pressure atmosphere of several tens of air or more. Moreover, the gas hydrate and crystal cage compound to be produced must have a negative number of ten. Low temperature environmental conditions below C. In addition, in Patent Document 1, a non-heating infrared ray having a wavelength of 2 to 10/zm is applied to the water, and the OH stretching vibration of the water molecule is changed, and the nitrogen bond between the water molecules is cut off to perform the water structure. Reprogramming, the method of generating crystal cage compounds. However, there is no proposal for gas filling. Even if a certain amount of hydrogen bonds are temporarily cut off without gas, since the water molecules move freely at a high speed of nanoseconds or less during the molecular motion of water, the hydrogen bond energy cannot remain the same for a long time after stopping the infrared irradiation. State, 4 323 154 201201900 It is difficult to think of a change in the stability of the water structure, and it is difficult to think of β. In Patent Document 2, a method for detecting the concentration of a gas hydrate is disclosed, which is a slurry-like solution containing gas hydrate or Method for performing infrared spectroscopy in a specific range under ice water, a slurry-like solution containing no gas hydrate or ice, etc. under the same conditions, and comparing the absorption peak of water molecules . However, this method is basically a method of measuring solid crystals in the form of a slurry or ice, and a mixture of solids, which is quite different from the state of the material having a change in the structure of the liquid water. Further, in Patent Document 3, a technique for generating ultrafine bubbles of a gas having a diameter f of 5 () _ or less which exhibits a slower rate f than a job/second in water in a water pressure or higher is described. In the literature, the technique of forcibly forming a nucleate of a hydrate by the self-compressing filament and the crushing phenomenon by the super-small gas (four) is described. In the narrative, although it is a case of performance in water, from the water temperature at the time of formation, the hydrate equilibrium condition temperature is low. Q·7ΐ The condition of supercooling is limited to the kinetic energy before it becomes ice by Li liquid. The method of gas-liquid mixing in a particularly reduced state is clearly understood to be based on at least a state in which water is present in the water. In the illusion, there is no review of the state of the water knife and the change in the amount of consumption, and the related review is disclosed in Patent Document 4 - a type of water flowing into the waterway is sprayed with water from the South House to generate vacuum microbubbles. Then treat the vacuum with a magnetic field: the water of the bubble. The _ phase microbubble collapses and the water molecule crystal cage is micronized, but the water molecule state of the water structure change is not actually carried out. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 4] JP-A-2006-181449 SUMMARY OF THE INVENTION (Problems to be Solved by the Invention) Any technique for water and other liquids is limited to forming a liquid slurry or at least cooling to a crucible. A method in which the state of kinetic energy is reduced and the gas is contacted or mixed. The literature describing the change of the special water structure does not exist by the gas/3⁄4 law generated under normal temperature and normal pressure conditions. The present invention grasps the actual state of water in which a gas molecule is dissolved, and proposes a method for producing the same, an observation method, a utilization method, and the like. (Means for Solving the Problem) The inventors of the present invention focused on the technique of dissolving various gases in water. Then, under a certain condition, the gas is dissolved in the liquid (gas-dissolved liquid) generated by the water, and a method of observing the bubbles of the gas is sought. However, it has been confirmed that under various conditions, even if various methods of measurement are performed, Unable to observe gas bubbles. Further, it has been confirmed that even if a gas which is considered to be a supersaturated concentration of the gas is dissolved in water, the gas bubbles are not observed. That is, for the observable bubble body, the distribution of bubbles existing from the Brownian motion of the bubble by a laser shot or a dynamic light scattering photometer is observed by the method of the analogy of the existence of the bubble by 323154 6 201201900. In the process, the inventors' object is to adjust the configuration of the mouthpiece that can be used for mixing water and gas, to appropriately adjust the pressure conditions and the like as much as possible, so as to obtain a finer inventor's discovery by adjusting the condition. The gas is mixed in the water to cause a higher density of cavitation in the water at the moment of dissolution, and the bubbles are deformed more strongly, and finer bubbles can be obtained. Then, it was found that in the process of producing a gas-dissolved liquid by the ejector under special conditions, 'the gas is introduced into the edge portion of the orifice portion (small control portion) of the ejector mixed in the water while introducing the gas, but regardless of When the diameter of the orifice is increased, no bubble is observed in the generated liquid, but it is confirmed that the gas is dissolved, and the stability of the stability can be maintained for a long period of time. Accumulating detailed observations and studies on the results of the liquid and its formation process, the inventors determined that when gas is mixed into the water of several tens of nanometers between nanoseconds, in addition to the general cavitation, the bubbles are erupted by high-density cavitation. Molecular granules (single molecules) or molecular groups are produced and dispersed in water. That is, the dissolution of bubbles other than gas only is considered to be limited to the crystal cage compound hydrate phenomenon occurring in the solid phase, that is, the inventors determined that the guest gas is present in the molecular state in the crystal structure of the cage compound. The hydrate phenomenon is basically produced under liquid phase conditions which are different from the solid phase. The liquid is considered to be a substance called a "liquid crystal cage compound" in which a gas molecule is dissolved in water. In the liquid, except for the fact that the bubble cannot be observed by the laser diffraction or the dynamic light scattering photometer, it is confirmed that the so-called Spring 8 X-ray small angular dispersion of the air gun of the size (A) by the density difference meter is confirmed. The device was not measured and no air bubbles were observed. In addition, by infrared ray analysis '7 323154 201201900, it was surprisingly confirmed that the hydrogen bond between water molecules can be reduced compared to the general water. That is, in the liquid crystal cage compound, a gas molecule or a gas molecule group enters between the water molecules, so that the hydrogen bond distance between the water molecules changes to a degree that covers the entire water and is highly densely dissolved. The gas molecules or gas sub-groups are of course not affected by buoyancy, and the water continues to settle in the water in which the bond between the water molecules alternates (the molecular recombination movement) continues. Moreover, the inventors succeeded in achieving the water temperature at the time of the formation of the aforementioned state at around 20 ° C, which can be generated and maintained at atmospheric pressure, and successfully obtain a new discovery of intervening gas molecules between liquid molecules (water molecules) at normal temperature and normal pressure. With matter. The present invention derived from the above matters is a liquid crystal cage compound formed by dissolving gas molecules in raw water, and is a liquid crystal in which gas molecules are present at least between water molecules of the raw water and having a hydrogen bonding ratio smaller than a hydrogen bonding ratio of the raw water. Cage compound. *τ 疋 In the above liquid crystal cage compound, hydrogen bonds between water molecules are eliminated by gas molecules entering between water molecules. Further, it is confirmed that the hydrogen bond energy in the liquid helium compound is smaller than the argon bond energy of the raw water. The raw water may also be a stock solution containing at least one of an organic substance or a microorganism. Further, in the liquid crystal cage compound, it is also determined that, in the above-mentioned 2 X/coexisting gas molecules, the water molecules are partially broken, and the water molecules in the raw water in the high-density pool are partially broken compared with the surroundings. In the raw water, the water molecule group is partially refined, and the gas molecules diffuse into the raw water to retain the water molecule group which is refined. 8 323154 201201900 Further, the present invention is a method in which a gas molecule is dissolved in water, and a crystal cage compound is also contained, and a liquid crystal cage compound having a water hydrogen bond energy smaller than that of water is also included. The body of the Ltli hair (four) filament molecules dissolved in the liquid sputum formed by the sputum cage mouth 'also contains gas molecules at least between the water molecules of the raw water, water molecules are gathered at a higher density of (four) The liquid crystal cage compound having a smaller number of water molecules in the water molecule portion than the water molecule portion of the raw water towel. In addition, the present invention is a liquid crystal cage compound formed by dissolving gas molecules in raw water, and is also contained in a liquid phase in which water molecules of the raw water do not generate inter-lattice bonds. The gas age is present at least in the raw water. A liquid crystalline compound between water molecules. w, the above liquid crystal cage compound is of course different depending on the gas species, and also changes with the water/dish strip, but the gas molecules are completely dissolved in the water, and the degree of bubble presence in the bubble is present. It is irrelevant. It is based on the state in which the wind knife affects the energy and test rate of the water lion. Further, the liquid crystal cage compound of the present invention is not only a liquid containing only a substance but also a liquid containing both gas molecules and bubbles. k The present invention also includes a liquid crystal ruthenium compound generating device, which is formed by a liquid crystal cage compound liquid crystal cage compound oblique knives, and has a ▲ at least a slanted road, a road, and an open heart (4) The slanting road passes through the front cutting and the path and is in the venturi of the open sloping water (10) Cong) pipe; and the fluorocarbon supply part connected to the aforementioned small diameter 9 323154 201201900 'the gas supply is characterized by the aforementioned extrusion The cross-sectional area of the inclined road is smaller toward the small diameter path, and the cross-sectional area of the inclined slope is larger as it goes away from the small path, and the VENTURI tube is attached to the front end of the open inclined road. Adjacent to the small-diameter path, at the same time, it is provided for the purpose of performing the second cavitation action on the gas mixture after the first cavitation is generated, and at least the distance from the front end is away from the small path. The super-space effect of the enlarged section with an enlarged cross-sectional area. The front end of the liquid crystal cage compound producing portion may be formed by a flat portion, and the enlarged portion may be formed in a conical shape. Further, it is disposed around the venturi (VENTURI) tube, and at least the region having the front end may be configured such that the core constituting the super cavitation portion is connected to the ferromagnetic metal and disposed on the device. The surrounding magnetic electricity and its strong magnetic field form a structure that adds magnetic action across the liquid flow path. In addition, the present invention is a method for producing a liquid crystal cage compound which dissolves a gas molecule in water and generates a liquid cage compound, which comprises: sending water from the slope of the road of the Wenqiu (10) Li) through the small path and on the inclined road And supplying the gas to the small-diameter road from the gas supply unit connected to the small secret by the effect pressure of the water sent from the small-diameter road toward the inclined position of the job, by using the small-diameter road toward the aforementioned Open inclined road = the fourth (4) of the water, compressing the bubbles of the gas to produce fine gas bubbles, and then by passing u, each gas _ at a specific part (four degrees): high == = == "Formation of gas molecules, liquids that diffuse into water = 323154 10 201201900 Method for the formation of cage compounds. In the above liquid crystal cage compound formation method t, a transverse magnetic field can be placed at the specific portion. Liquid crystal cage compounds produced by this method are also included in the present invention. In addition, the present invention also includes a method for observing a liquid crystal cage compound, which is a method for observing a liquid crystal cage compound formed by dissolving a gas molecule in raw water, and cooling the liquid crystal germanium compound to a specific temperature or lower. The cooled liquid crystal cage compound irradiates infrared rays, and by comparing the infrared absorbance of the liquid crystal cage compound with the infrared absorbance of the raw water measured in advance, it is observed that the hydrogen bonding ratio of the liquid crystal cage compound is smaller than the argon bond rate of the raw water, In the liquid cage compound, gas molecules are present at least between the water molecules of the aforementioned raw water. Furthermore, the present invention also includes an observation device for a liquid crystal cage compound, which is an observation device for a liquid crystal cage compound formed by dissolving a gas molecule in raw water, and is provided with cooling for cooling the liquid crystal cage compound to a specific temperature or lower. And irradiating infrared rays to the cooled liquid crystal cage compound, and comparing the infrared absorbance of the liquid crystal cage compound with the infrared absorbance of the raw water measured in advance, observing that the hydrogen bonding ratio of the liquid crystal cage compound is smaller than the raw water A hydrogen spectrometry, an infrared spectroscopic analyzer in which a gas molecule is present in at least a water molecule of the raw water in a liquid crystal cage compound. The above gas molecules include oxygen molecules, nitrogen molecules, hydrogen molecules, ozone molecules, carbon dioxide gas molecules, etc., but the types of gases are not limited to these molecules, and other gases and other gases may also be targeted, and the gas concentration is not limited. 11 323154 201201900 (Results of the Invention) According to the present invention, it is possible to generate a new dirty body of a dissolved gas molecule which has not existed before, and at the same time, to understand its unique properties, and to suggest its utilization method. [Embodiment j Before explaining the present invention, The cage compound which is referred to as the reference to the eight-cage compound and the hydrate in the understanding of the present invention is generally known to be inserted from the crystal lattice of the specific compound. The atom or molecule of another substance ' does not consist of a covalent bond (also a substance that exists in a stable state. It is also called an inclusion compound for special purposes, such as "photographing", "holding", etc.). For example, the crystal cage compound, the guest crystal = the crystal structure (there are various types), and the hydrate (gas hydrate) is also known as the water-inclusion. A substance existing in a state in which other gas molecules are placed in a gap of a three-dimensional network structure composed of water molecules by hydrogen bonding. When you go to & ^^K^(Methanehydrate),,^x^. In the gap between the 4r, i, and the structure of the human body, the appearance of the molecules such as ice and fruit roads is expected to be effective due to the large amount of natural substances present in the offshore Japan. For example, if methane hydrate is present as a solid in the seabed or frozen soil, it is generally known that the so-called cage compound and hydrate are in the so-called interstitial environment, the freezing temperature region or below. Next, it exists in the form of a solid substance having a characteristic crystal structure. In addition, when the concept of the present invention is described, the term "hydrated 323154 12 201201900" and "crystal cage compound" may be used, but means "hydrate" and "crystal cage compound" when the substance of the present invention is produced. It does not have the structure and properties of solids, crystal lattices as generally recognized above. That is, as described, the water of the parent substance in the present invention is substantially liquid. The structure in which the lattice is not solid, crystal lattice or the like is combined. In this point, it is different from the conventional crystal cage compound and hydrate. The substance of the present invention may also be referred to as a liquid crystal cage compound (liquid hydrate). Compared with the conventional gas-containing solid phase material which crystallizes the ice-like solid, the state of the parent material of the so-called flowing liquid phase of the present invention is substantially different, but the gas is dispersed in the water at the point where the molecular unit is common, so it also exhibits For the crystal cage compound 0 according to 2005 R.  J.  According to D. Miller et al., the structural changes caused by water-irradiated laser pulses disappear within 50 femtoseconds. (Utrafast memory loss and energy redistribution in the hydrogen bond network of liquid H2O, Nature 434, 199-202, published March 10, 2005). That is, the movement of water changes into a very short time of movement. Even in areas where the limits of time can be measured, it is difficult to observe them. In addition, if the pressure condition of the water surrounding the observation target is in a state of no change, the change in the water temperature causes a large change in the kinetic energy and cannot be quantitatively measured, thereby hindering the explanation of the water property study under normal temperature conditions. A conceptual diagram of a liquid cage compound of the produced material of the present invention is shown in Fig. 1. This is a model that represents the state of the molecule at the moment of continuous movement of water. In Fig. 1, the ruthenium atomic system in the water molecule H2O is bonded to a 0 atom having a large electrical negative degree by a covalent bond (dashed line in the figure) with a positive (+) charge (hydrogen 13 323154 201201900 ion). This helium atom is combined with a helium atom having a negative (-) charge in other helium molecules by a hydrogen bond (dashed line in the figure). In the water without impurities, the region other than each molecule in the figure is an immaterial space, and the non-physical space can be filled with a substance such as an alcohol which can be mixed with water, and thus the total amount of water and alcohol is mixed. The sum of the simple volumes of the two is reduced by a certain amount. Further, in the molecular motion of water, it is known that an alternating reciprocating (catching) of positively charged hydrogen ions is generated between oxygen atoms of two water molecules having a negative charge at a hydrogen bond. When the gas is dissolved in water, other substances such as gas molecules other than the oxime are allowed to dissolve in the non-substance space, and the phenomenon is dissolved. The concentration of the dissolved gas varies depending on the environmental pressure conditions acting on the water and the water temperature condition, but it is known that the amount of the specific gas dissolved in the water is a certain amount under certain conditions. Further, in the dissolution phenomenon below the saturation concentration, no change in the kinetic energy between the water molecules, that is, the hydrogen bond ratio was observed. This is a dissolution of the gas known from the prior art and does not change the hydrogen bonding rate of water. Therefore, the inventor of the present invention has clarified that the water treatment by gas-liquid mixing under certain conditions is a process for producing a clear change in the hydrogen bonding rate of water, and the first time a substance which can be confirmed to be such a change is known and understood. The existence of matter. That is, in the liquid hydrate of the substance, the gas system enters the water molecules at a high density in molecular units. Because the diffusion of the non-substance regions is extended, the ratio of hydrogen bonds between the water molecules (hydrogen bond ratio) is compared with The hydrogen bonding rate of the water into which the gas molecules have not entered is reduced to a measureable extent. The relationship between the enthalpy (the relationship between the gas molecules and the hydrogen bond between the water molecules) is caused by the movement of the molecules in the tens of femtoseconds to the picoseconds. It is difficult to observe. However, in 14 323 154 201201900, the (four) crystal cage compound towel of the present invention has a configuration relationship in which a small amount of sample is used, and the dimensional energy can be made to be more important than her. Since the gas molecules are dispersed and dispersed at a high density, the hydrogen bond rate in accordance with the arrangement relationship is lowered, and the total amount of the particles can be observed for a long period of time. Further, as will be described later, in the process of generating gas and liquid, the water molecules called water molecules are broken by the radiation and intermediation of the gas molecules as the gas molecules diffuse. A decrease in the argon bond rate. Therefore, in the liquid crystal cage of the present invention, even when the concentration of the dissolved gas is below the saturated concentration, the hydrogen bond rate is remarkably lowered as compared with the undissolved water. The liquid crystal cage compound of the present invention is a "crystal cage compound" which is obtained by dissolving gas molecules in water. Here, the original water before the dissolved gas molecules is defined as "raw water". The so-called raw water system-like beverage water, human 2 water, pure water, etc., are all considered to be water concepts, and include = some impurities. Water containing organic substances or microorganisms as described later, but containing such a deliberate mixture, is also considered to be a "stock solution". Then, as a result of the dissolution of the gas molecules in the raw water, the hydrogen bond ratio of the heterogeneous caged liquid crystal cage compound is smaller than the hydrogen bond rate of the dissolved gas molecules. That is, the ratio of the water content in the liquid cage compound is higher than the ratio of the hydrogen bond in the raw water to be dissolved in the (4) crystal cage compound towel, and the gas molecule is the liquid pi state. (4), the compound of the present invention can also be referred to as a gas molecule-dissolving liquid. From the other point of view, in the liquid crystal cage compound of the present invention, 323154 15 201201900 is a fluorine in the non-physical space between water molecules in the water (the space other than the electron particles such as electrons or neutrals, which is originally unreleased) As the hybrid molecules increase and squeeze into the non-material space, the hydrogen bond between the water molecules is eliminated. Gas molecules enter the water molecules, which hinder the capture of the nitrogen ions between the two. In this phenomenon, the gas molecules cause the total amount of water molecules to decrease when the distance between the water and the molecular force is greater than the distance between the water molecules and the hydrogen bond energy. Moreover, in the liquid crystal cage compound of the present invention, it can be said that the hydrogen bond energy generated by the hydrogen bond between the hydrogen ions and the other mixed substances by the action of the gas molecules is more hydrogen-rich than the original water. b: E is more lowered. In addition, another phenomenon is caused by the use of high-speed and high-intensity in the mixing process described below. > The process of sealing the gas into the liquid, the gas bubble or the gas branching group The eruption, the gas molecules are emitted. Thereafter, it is re-explained, but it is considered that a part of the water molecule group on the moving orbit of the gas molecule is broken, and the total amount thereof shows a shift in the hydrogen bond rate. In addition, the gas molecules that are emitted into the orbit are stopped by the resistance of the water, and are dispersed in the water at a very high density. In this series of processes, the hydrogen bond is cleaved (mainly in the disappearance of hydrogen bonds between water molecules), and the hydrogen bond is difficult to form due to the intervention of gas molecules (mainly hydrogen between hydrogen molecules). The role of the two phenomena, such as the disappearance of the key, is considered to be the original cabinet that produces the phenomenon of the change in the nature of the water revealed. The phenomenon of collapse of a water molecule group is considered to be related to a result of a significant decrease in the hydrogen bond rate even under a saturated concentration. As described above, the above-mentioned effects can be clearly observed by the infrared spectroscopy method 16 323154 201201900. The 氲 bond rate is lower than the original water raw water, and is produced in the liquid at an areal density and a high concentration ( That is, gas molecules are dispersed in water at a high density and a surface concentration, and significant changes in properties are caused to the raw water. Further, although the concepts of the hydrogen bond ratio and the hydrogen bond energy are suggested as elements for comparing the raw water and the liquid crystal cage compound, they must be compared under the same conditions. For example, it is necessary to compare a raw water with a liquid cage compound having a composition other than a gas molecule. In addition, the water temperature must be made constant. Further, if the water temperature rises, the water kinetic energy changes drastically, and the measurement difficulty increases. Therefore, it is important to measure at a low water temperature, and it is preferable to perform measurement at 4 ° C which is the most stable water molecule density. Further, in order to make a more accurate observation of the degree of change, it is preferable to perform a complex measurement on the target liquid sample such as raw water or gas-dissolved water, and to average the data, and to compare the averaged data together to grasp the significant difference. It is meaningful to observe the above-described hydrogen bond ratio, hydrogen bond energy, and the like between the raw water and the (tetra) crystal cage compound under such a condition τ ', and there is a discreet difference between the two. The action of each water molecule and gas molecule and the state of the intermolecular network are events in the tiny world, and the motion changes continuously in the picoseconds, so it is impossible to directly observe. However, by grasping the hydrogen bond energy of the entire water, the behavior of the gas molecules in the liquid cage compound can be observed. Even in ordinary water, the hydrogen bond between the water molecules is repeatedly generated and destroyed by the molecular motion, but in the crystal cage compound of the present invention, the hydrogen bond between the water molecules is obtained by the gas molecules entering the water molecules. Also large _ rate (the number of times the nitrogen bond is destroyed per unit) is eliminated. Fig. 2(a) is a model showing the behavior of water molecules in general water 323154 17 201201900. Fig. 2(b) is a schematic view showing the behavior of water molecules and gas molecules in the liquid crystal cage compound of the present invention, Corresponding to a wider range, the second diagram (b) shows an example in which the gas molecules are ozone molecules, but the gas fraction T is not limited to ozone molecules. As shown in Fig. 2(a), the water molecule in the general water adopts the formation and fracture of the hydrogen bond in the form of nanoseconds or less. In addition, as shown in Fig. 2(b), in the liquid crystal cage In the compound, the chaotic molecular system is radially expanded and diffused as described later, and as shown in Fig. 19, it travels through the pulverized water molecule group, and the space of the sea of the f molecule can be maintained when the resistance of the water is stopped. Here, the gas molecules make the hearing rate finer than that of the knives of the circumference of the circumference 2 to eliminate a part of the bonds, and at the same time, the sufficiency of the hydrogen bonding is performed under the condition that the hydrogen bonding _ hinders the hydrogen bonding. The water molecule group is also explained later. The liquid crystal crystallization method of the present invention is not particularly limited, and all methods can be employed. A simple method - for example, a method of taking out a gas from a liquid by decompression can be exemplified. A liquid having a predetermined ratio of a bond rate or the like is subjected to a known device to be forcibly degassed by a gas (molecular) which can be sufficiently desorbed. The ratio of the liquid to the liquid, etc., by whether or not the liquid is the liquid crystal cage compound. , , w, the concept of the A* PeiXaVltatlQn which is also shaken when the liquid crystal cage compound of the present invention is used. In general, the part with low air erosion power is called vaporization in a high-speed flowing fluid (water, etc.), which generates a vapor pocket in a very short time and is destroyed in a very short time. The phenomenon. At the point where the empty money is caused, 323154 18 201201900 is mixed with gas to deliberately carry out high-intensity mixing. The supercavitation system is produced more actively than the general cavitation, and the method of reducing the friction between the object and the surrounding fluid, that is, the super-empty button system causes the empty money to be high density, and the fluidity in the lower flow direction of the fluid flow direction is reduced and fluid. The effect of the frictional resistance of the material in contact is that the liquid around the object is vaporized by the vacancy, which is caused by the tightness of the gas and the liquid of the 々IL body, so it is caused by the decrease of the resistance. The present embodiment is used for the purpose of reducing the resistance in the mixing device and accelerating the flow rate of the liquid containing the gas; and increasing the strength of the cavitation, increasing the splitting effect of the gas bubbles, and obtaining the gas. The molecular explosion becomes a function of the extent to which the molecular particles are emitted. Fig. 3 is a conceptual diagram showing a state in which supercavitation is generated. Super-cavitation occurs after the object (black) is placed in a liquid that flows at a high speed (in gray). Next, the structure of the gas mixed liquid producing apparatus of the present embodiment will be described with reference to Fig. 4 . The gas mixture generation device 201 includes a storage tank 202, a gas supply device 203, a circulation system device 2〇4 that returns the liquid to be treated taken out from the storage tank 202 to the storage tank 202, and is disposed in the middle of the circulation system device 2〇4. The gas-liquid product is assembled (liquid crystal cage compound generating device) 2〇5, the dissolution promoting tank 206, and the temperature holding device 2〇7 attached to the storage tank 202. As shown in Fig. 4, the raw water as the liquid to be treated is injected into the storage tank 202 through the water intake valve 2〇2v. The storage tank 202 is for storing a gas mixture circulating through the raw water of the taken water and the circulation system 204 described later, that is, the liquid crystal cage compound. The liquid stored in the storage tank 2〇2 is maintained by, for example, 丨 to 2〇 323154 19 201201900 °c by the temperature holding device 207. When the temperature is set to the range, for example, when the gas molecules are odor molecules, the ozone self-decomposition phenomenon with the increase in temperature as described by the Henry's constant is suppressed, and ozone dissolution and concentration increase are efficiently performed, and the dissolved ozone is not lowered. concentration. The gas other than ozone hardly has the property of decomposing due to an increase in temperature, but the stability of water molecules is maintained at a level that does not cause the water temperature to form a high temperature. As a result, high treatment efficiency can be maintained. The temperature holding device 207 can also be omitted depending on the conditions. Further, the temperature setting range can be comprehensively considered in consideration of the type or nature of the liquid to be treated (raw water and/or liquid crystalline compound) or the gas (gas group), and the presence or absence of the additive. The temperature holding device 207 includes a pump 21 for taking out the liquid to be treated from the storage tank 202, a cooler 212 for cooling the liquid to be treated, and a storage tank 202 and a pump 211 and a cooler 212. The pipe 213 through which the liquid to be treated passes is connected. According to the above configuration, the liquid to be treated stored in the storage tank 202 is taken out from the storage tank 202 by the action of the pump 211, and sent to the cooler 212. The cooler 212 returns the supplied liquid to a specific temperature and returns to the storage tank 202. The pump 211 is operated only by the temperature of the liquid to be treated in the storage tank 202 measured by the thermometer outside the figure, only when it exceeds a certain range and must be cooled. By providing the storage tank 202, the liquid to be treated can be temporarily stored by temporarily storing the liquid to be treated, and the liquid to be treated is kept in a stable state, whereby, for example, when the gas molecules are ozone molecules, the liquid to be treated is kept in a state of ozone. At the same time, dissolution can be promoted by ripening into a similar action. Further, in the case where there is a concern that the liquid to be treated is frozen, such as in the cold, in place of the above-described cooling machine or in combination with the above-described cooling machine, it is also possible to use a heater device to heat the composition of the liquid to be treated 20 323 154 201201900. The gas supply device 203 of the present embodiment is a device for generating a specific gas and supplying it. Basically, the gas-liquid mixing device 205 generates a vacuum phenomenon due to the occurrence of cavitation, and the supply gas is sucked by the gas supply device 203 under a negative pressure, but may be supplied after being pressurized or the like as needed. If the amount of gas required is supplied, the principle of generation of the gas acting on the gas supply device 203 is not limited. The gas generated by the gas supply device 203 is supplied to the gas-liquid mixing device 205 via the electromagnetic valve 218 provided in the middle of the gas supply pipe 217 and the check valve 219. The gas mixed in the liquid to be treated is, for example, an atmosphere, and an air compressor or the like is a main component of the gas supply device. When a plurality of types of gases are mixed, a device that generates or takes each gas or the like is used. Next, the contents of the gas-liquid mixing device (liquid crystal cage compound generating device) 205 will be described with reference to Figs. 4 and 5 . The gas-liquid mixing device 205 is also referred to as an ejector. As described above, the inventors have a configuration for obtaining finer bubbles in water, and having a configuration obtained by performing the adjustment. The gas-liquid mixing device 205 includes a VENTURI tube 231 and a gas supply pipe 239 as a gas supply portion for supplying a gas. The gas-liquid mixing device 205 of the present embodiment further includes a super cavitation action portion 237 and a magnetic circuit 243. The venturi tube 231 and the gas supply tube 239 are integrally formed by a synthetic resin material having a magnetic permeability. The venturi tube 231 has a tubular appearance that passes the liquid to be treated sent from the upstream side (the arrow A1 side of Fig. 5) toward the downstream side (the arrow A2 side of Fig. 5), and the liquid to be treated is The arrow A1 flows in the direction of the axis of A2 (long direction). The hollow portion defined in the interior of the venturi tube 231 in the direction of the long section of the venturi 21 323154 201201900 is from the upstream side to the downstream side, according to the upstream side large diameter path 232, the extrusion inclined path 233, and the small path 234. The state in which the open inclined path 235 and the downstream large diameter path 236 are sequentially connected to each other is formed. The upper flow side large diameter path 232 is specific to the axial direction of the gas supply pipe 239 (the direction perpendicular to the axial direction of the venturi 231). The first angle (for example, 50 degrees or the like) is connected to the small-diameter path 234 via the extrusion inclined path 233 inclined to the extrusion direction, and thereafter, by the open inclined path 235, it is specific to the same axial direction. Open at the second angle (for example, 30 degrees, etc.). The open inclined path 235 is connected to the downstream large diameter path 236 having the same outer diameter as the upstream large diameter path 232. In other words, the cross-sectional area (flow path area) of the extrusion inclined path 233 becomes smaller toward the small diameter path 234, and the cross-sectional area (flow path area) of the open inclined path 235 becomes larger as it goes away from the small diameter path 234. That is, the cross-sectional area (flow path area) of the small path 234 is the smallest in the venturi tube 231. Generally, the first angle > the second angle is set, and the inclination of the extrusion inclined path 233 is steeper than the inclination of the open inclined path 235. The small-diameter passage 234 is connected to the gas supply pipe 239' perpendicularly to the axial direction. The open end of the gas supply device 239 is opened at the center portion of the small-diameter passage 234 in the axial direction, and is opened to the small-diameter passage 234. The supply end of the gas supply pipe 239 (opened to the opposite side of the open end of the small diameter path 234) is connected to a gas supply pipe 217 (Fig. 4) that communicates with the gas supply device 203. The cross-sectional area (flow path area) of the small-diameter path (orifice portion) 234 is the smallest in the venturi tube 231, and the liquid to be treated which is sent from the extrusion inclined path 233 to the small-diameter road 2 is due to the flow path area. Drastically reduced and exposed to extremely high pressures. 323154 22 201201900 After passing through the small-diameter path 234, the liquid to be treated protrudes into the open inclined path 235 having a large cross-sectional area as it moves away from the small-diameter path 234, and is opened at a high pressure, so that the central portion of the small-diameter path 234 in the axial direction or The vicinity of the downstream side is in a state of being vacuum or approximately vacuum depending on the pressure of the liquid to be treated. The gas system that has reached the supply end of the gas supply pipe 239 is sucked (the suction pressure of the liquid to be treated) and is dispersed in the fluid to be treated which is turbulent. This phenomenon is the first cavitation described later. The smaller path 234 is further located inside the lower inclined side 235 and the lower side large diameter path 236, and even if the gas-liquid mixing device 205 is provided with a super-empty button function mainly for super-empty decoration, Department 237. The super-empty action unit 237 will be described in detail later. The magnetic circuit 243 is fixed to the venturi tube 231' by a screw (not shown). The magnetic circuit 234 is connected to the magnet piece 245 on one side and the magnet piece 246 on the other side by the venturi tube 231, and is connected to the magnet piece 245 on one side and the magnet piece 246 on the other side. At the same time, the Annon magnet piece is formed in the u-shaped connecting member 248 having a function of the venturi tube 231. By incorporating a magnetic circuit, the magnetic field is prevented from being released undesirably around the mixing device that is not the injector. The magnet piece 245 and the magnet piece 246 are preferably disposed on the small path 234 and/or its vicinity (especially on the flow side below the small path 234) such that the magnetic lines (magnetic fields) pass through the ejector centered on the small path 234 as much as possible. The flow water in the pipe is configured as a whole. By applying a magnetic force to both the liquid to be treated (water) and the gas, it is considered that the gas to be treated can be dissolved at an optimum efficiency. The magnet piece 245 and the magnet piece 246 are made of neodymium magnet or the like, but the type of the magnet 323154 23 201201900 is not particularly limited. The connecting member 248 is configured to prevent the magnetic flux from leaking, and to make the magnetic force function to be processed (4), and is composed of a member having a large magnetic permeability (for example, iron). The liquid crystal cage compound produced by the gas-liquid mixing device 2〇5 is sent to the dissolution promoting tank 2〇6 via the distribution f 274. The dissolution promoting tank 2〇6 is configured in a cylindrical shape to promote the dissolution of gas into the water. The liquid crystal cage compound which has passed through the dissolution promoting tank 2〇6 is sent to the gas-liquid separation device 265. The gas-liquid separation device 265 functions as a degassing structure for separating and discharging the gas to be treated and the gas degassed from the liquid to be treated. The gas separated by the gas-liquid separation device 265 is decomposed by the domain body, and is decomposed and detoxified, and then released to the outside of the apparatus. The %-based device 204 has a liquid crystal cage compound that has passed through the gas-liquid mixing device 2〇5, and the gas-liquid mixing device 2〇5 is again passed through the gas-liquid mixing device 2〇5, because the dissolved The treated liquid of the gas ((4) crystal cage compound) is added to the new gas, and the solubility and concentration of the gas are further enhanced. The circulation system 2〇4 is a driving source, and the storage tank 202 and the dissolution promoting tank 206 are main components, that is, the pump 271 is taken out from the storage tank 2〇2 via the piping 27 The liquid 'pressure is sent to the gas-liquid mixture via the check valve 272 and the squid 2 to 3, and is set to 205. The liquid to be treated which has passed through the gas-liquid mixing device 2 by the delivery is skipped by the piping 274 and the dissolution promoting tank 2〇6, and is returned to the storage tank via the piping milk. The circulation line is configured such that the above-mentioned steps are required to be used. The number of persons is free to be obtained by obtaining the gas solubility or gas concentration of the liquid crystal cage compound to be produced. Further, in the switch of 323154 24 201201900, a valve 276 is provided in the middle of the water pipe 275 of the liquid to be treated, and the gas-liquid mixing device 2〇5 passing through the small path 234 is controlled by the valve 276. Then, the main part of the M super money (4) gas-liquid mixing device 205', in particular, for the super cavitation action portion 237, using the fifth and sixth figures, and (d), the 205 device is also referred to as an ejector. The process of obtaining a finer bubble of the water towel is achieved, and it can be obtained by adjusting it. As described above, the rudder path 234 is further on the downstream side, and the inside of the open sloping path 235 and the downstream side large-diameter 236 is set in the gas-liquid mixing device 2〇5, and the super line mainly based on the super money fairy is also provided. Acting section 237. The cross-sectional center of the super-emptive surname portion 237 coincides with the cross-sectional center of the open inclined path 235 and the downstream large-diameter path 236. That is, the cross section of the super cavitation action portion 237 is concentric with respect to the cross section of the open inclined path 235 and the downstream large path 236. The super cavitation action portion 237 is located on the upstream side (on the side close to the small diameter path 234), and is provided on the downstream side (the side away from the small diameter path 234) by the enlarged portion 237a having a conical shape and integrally connected to the enlarged portion 237a. The body is composed of Zou 237b. The enlarged portion 237a is formed in the vicinity of the center portion of the open inclined path 235 in the axial direction (the axial direction of the venturi 231), and is formed so as to gradually expand the cross-sectional area toward the downstream side (with the small-diameter portion 234), and is integrally connected. The body portion 237b. Further, the enlarged portion 237a is formed closest to the small pole path by the front end of the flat portion 237c, and is adjacent to the smart path 234 in the open inclined path 235. The flat portion 237c is formed in a device that is not advanced with respect to the sleeve direction 25 323154 201201900 (the axial direction of the venturi 231) of the enlarged portion 237a, and is substantially perpendicular to the axial direction to the surface 1 (10). Sectional formation

超空钮作用部237係以PTFE (P〇lytetrafl_ethyl咖，聚四氣乙缔）被覆，怒部之構 成母材係以伽性體之鐵構成1前述龜回路集合於流 液部之磁性，係在與流路中心之鐵材的超心作用部挪 =無_的形成強力磁場，成材發揮使氣體與液體一 起有效地作用而生成水分子團之構造。又，此實施形態係 基本上為-例，超⑽作用部237之形態係料別限定， 若為可產生後述之超空姓作用（尤其第2心之作⑴者， 即可適宜自由變形。 其次，瞭解到藉此次之氣液混合襄置2〇5而得到之作 用’亦即使用第5圖、第6圖說明產生超空蚀之機制。如 第5圖之箭號A1所示般’通過上流側大徑路2犯之被處理 液（以下以「水」說明），係通過擠出傾斜路232時被壓縮， 水壓急劇提高，壓力衝擊波被施加於液體與液體所含有的 氣體氣泡、氣體分子。同時水之通過速度亦急劇上昇。水 之壓力、速度係於通過小徑路（孔口部）234時達到高峰。 通過小徑路（孔口部）234之水，係以高速、高壓通過 小徑路234。通過小徑路234之後，水係被送出至開放傾 斜路235，但被送出至開放傾斜路235之後亦藉慣性之法 則，水係依然以高速移動。但因水移動經路的容積（開放傾 斜路235之流路面積）急速地增大（小徑路234 -->開放傾 斜路235)，故於水中可實現減壓現象以及高的真空環境。 26 323154 201201900 藉此現象，於水產生將連接於小徑路234之氣體供給管239 内，氣體吸引至小徑路234内（引入）之吸引壓力，藉該吸 引壓力之作用，從氣體供給管239經由小徑路234使氣體 之氣泡被供給至水中，產生氣液混合液（第6圖（3))。 繼而，如第6圖（b)所示般，因小徑路（開口部）234之 高壓的壓力衝擊波，氣泡被壓縮，產生空蝕而如第6圖（1)) 所示般’氣泡被分割並微細化（第1空独）。 此外，含有被微細化之氣泡的氣體混合液若沿著水之 流動而從小徑路234進行至下流之開放傾斜路235，如第6 圖（c)所示般，碰撞超空蝕作用部237之擴大部237a的平 面部237c。繼而，氣液混合液中被微細化之氣泡係藉碰撞 之衝擊進行爆發粉碎，向外周放射，引起分子單元的擴散 運動。所放射之氣體氣泡及分子群係於周圍的水分子中以 氣體分子單元廣泛地擴散（第2空蝕）。藉爆發粉碎呈輻射 狀飛出之氣體分子係於水分子中零散飛行，一邊通過一邊 藉水中之摩擦阻力分別停止於水中之特定位置，如第6圖 ⑷所示般㈣於水分子運動巾之空間。結果生成液體晶籠 化合物。 第6圖（e)係表示流速之影像的模式圖。從此爆發粉 碎進行放射、擴散而至停止之現象，係在強力的磁場中進 行，故生成效率高。又，通過小徑路234之水的速度愈快， 高密度之空蝕，亦即超空蝕的密度愈高，但在引起第^空 钮之部位，裝置表面與液流接觸之面的摩擦阻力明顯降 低，故可高速地維持液流速。又’從第1空蝕經過瞬間後 27 323154 C： 201201900 重複第2空蝕作用的現象，係反覆進行至氣體分子之塊變 成更微細的大小為止。 除了上述記載之生成過程，一度經過超空姓製程的氣 泡，是細小至於桶槽内不會浮起之程度的數以n 氣泡，再度突入於超空蝕的製程，受到重複超空蝕的作用。 上述之製程可大致區分成如下之3階段。亦即， 水中之氣泡受壓力衝擊波壓壞，（2)以高速通過小徑路 之水受到空蝕作用，（3)水受到超空蝕作用之3階段。亦 即藉由「壓力衝擊波」、「真空空蝕」、「以超空蝕引起之再 度真空造成的分裂」之三個作用，氣體分子進行爆發粉碎 而呈輻射狀飛出，在各別之軌道剌入水中而貫通後，萨水 阻力保持於水中各處。 3 又’在本實施形態中係如上述般，超空蝕作用部 係藉由於強磁性體材料（鐵）被覆PTFE (polytetrafluoroethylene，聚四氟乙烯）系樹脂所構成。 採用藉由從氣體供給管239之附近作用於成為真空環境的 區域之磁性回路243 ’以使水及氣泡直行之狀態於液流路 全體無間隙地形成磁場，對水及氣泡、進而對氣體分子群、 氣體分子之全體賦予磁場作用之構造。繼而，尤其在引起 超空#之區域（平面部237c之周邊），在磁性回路243與超 空蝕作用部237之構造材（樹脂被覆強磁性體材料）之間， 形成於氣液混合液中橫切之強力磁場區域。如此之構成可 對於常磁性體之水的分子使氣體以2階段引起空蝕之程度 強力混合，同時以磁性對其作用。繼而，藉由使水分子本 28 323154 201201900 - 身物理性微細化，被認為易接受藉爆發粉碎放射之侧的氣 . 體氣泡及分子，亦即有助於減輕氣體分子放射時水中的阻 力性。 本實施形態之氣液混合裝置205的規格如下。 送液水壓：0.4MPa(流入侧） 通水速度：23m/秒 通水量：15升/分 氣體供給量：3升/分 磁性回路（鈦磁石）：表面磁束密度2720高斯/吸附力35Kg， 在流水位置之磁束密度4248高斯（磁石間距離i〇mm部分之 計算值）The super-empty button action portion 237 is covered with PTFE (P〇lytetrafl_ethyl coffee, polytetrafluoroethylene), and the base material of the anger portion is composed of iron of the galaxoid body 1 and the magnetic circuit of the turtle circuit is collected in the fluid portion. A strong magnetic field is formed in the supercardiographic action portion of the iron material at the center of the flow path, and the material exhibits a structure in which the gas and the liquid act together effectively to form a water molecule cluster. Further, this embodiment is basically an example, and the form of the super (10) action portion 237 is not limited, and may be freely deformed if it is capable of generating a super-space name (hereinafter, the second heart (1). Secondly, the effect obtained by the second gas-liquid mixing device 2〇5 is understood, that is, the mechanism for generating supercavitation is illustrated using FIG. 5 and FIG. 6. As shown by the arrow A1 in FIG. The liquid to be treated (described by "water" in the upstream side large-path 2) is compressed by the extrusion of the inclined path 232, and the water pressure is rapidly increased, and the pressure shock wave is applied to the gas contained in the liquid and the liquid. Bubbles and gas molecules. At the same time, the water passing speed also rises sharply. The pressure and speed of the water reach a peak when passing through the small diameter path (orifice portion) 234. The water passing through the small diameter path (orifice portion) 234 is The high speed and high pressure pass through the small diameter path 234. After passing through the small diameter path 234, the water system is sent to the open inclined road 235, but after being sent to the open inclined road 235, the water system is still moving at a high speed by the law of inertia. The volume of water moving through the road (open tilt) The flow path area of the road 235 is rapidly increased (the small path 234 --> the open inclined road 235), so that the decompression phenomenon and the high vacuum environment can be realized in the water. 26 323154 201201900 This phenomenon is generated in water. The gas is supplied to the gas supply pipe 239 of the small-diameter path 234, and the gas is sucked into the suction pressure in the small-diameter path 234 (introduced), and the bubble of the gas is made from the gas supply pipe 239 via the small-diameter path 234 by the suction pressure. It is supplied to the water to generate a gas-liquid mixture (Fig. 6 (3)). Then, as shown in Fig. 6(b), the bubble is compressed by the high pressure shock wave of the small path (opening) 234. The cavitation is generated and the bubble is divided and refined (first empty) as shown in Fig. 6 (1). Further, when the gas mixture containing the finely divided gas bubbles flows from the small diameter path 234 to the downstream open inclined path 235 along the flow of water, as shown in Fig. 6(c), the collision cavitation action portion 237 is collided. The flat portion 237c of the enlarged portion 237a. Then, the bubbles which are miniaturized in the gas-liquid mixture are blasted by the impact of the collision, and are radiated to the outer periphery to cause diffusion of the molecular unit. The emitted gas bubbles and molecular groups are widely diffused by gas molecular units in the surrounding water molecules (second cavitation). The gas molecules flying out of the smashing and smashing are flying in the water molecules, and stop at a specific position in the water by the frictional resistance of the water, as shown in Fig. 6 (4) (4) in the water molecule sports towel space. The result is a liquid cage compound. Fig. 6(e) is a schematic view showing an image of a flow velocity. Since the bursting of the powder, the phenomenon of radiation, diffusion, and cessation is performed in a strong magnetic field, so the generation efficiency is high. Moreover, the faster the speed of the water passing through the small path 234, the higher the density of the cavitation, that is, the higher the density of the supercavitation, but the friction between the surface of the device and the surface of the device at the portion where the hollow button is caused. The resistance is significantly reduced, so the liquid flow rate can be maintained at high speed. Further, the phenomenon of repeating the second cavitation action is repeated after the first cavitation is passed. 27 323154 C: 201201900 The process proceeds to a smaller size until the block of gas molecules becomes smaller. In addition to the above-mentioned process of formation, the bubbles that once passed through the super-emptive surname process are small bubbles of n to the extent that they do not float in the tank, and once again protrude into the process of supercavitation, subject to repeated supercavitation. . The above processes can be roughly divided into the following three stages. That is, the bubbles in the water are crushed by the pressure shock wave, (2) the water passing through the small path at high speed is cavitation, and (3) the water is subjected to three stages of supercavitation. That is, by the three functions of "pressure shock wave", "vacuum cavitation erosion" and "separation caused by re-vacuum caused by supercavitation", the gas molecules are pulverized and fluttered out in a radial shape, in separate tracks. After passing through the water, the resistance of the Sa water remains throughout the water. In the present embodiment, as described above, the super cavitation action portion is formed of a PTFE (polytetrafluoroethylene) resin coated with a ferromagnetic material (iron). By using a magnetic circuit 243' that acts on a region that is in a vacuum environment from the vicinity of the gas supply pipe 239, a magnetic field is formed in the liquid flow path without gaps in a state where water and bubbles go straight, and water, bubbles, and gas molecules are applied. The structure in which the entire group and gas molecules impart a magnetic field. Then, particularly in the region (the periphery of the flat portion 237c) causing the super-empty #, between the magnetic circuit 243 and the structural material (resin-coated ferromagnetic material) of the super cavitation acting portion 237, it is formed in the gas-liquid mixed liquid. A strong magnetic field that crosses. Such a composition can strongly mix the molecules of the water of the normal magnetic body to cause the gas to cavitation in a two-stage manner while magnetically acting on it. Then, by making the water molecules physically finer, it is considered to be easy to accept the gas bubbles and molecules on the side of the pulverizing radiation, which helps to reduce the resistance in the water when the gas molecules are emitted. . The specifications of the gas-liquid mixing device 205 of the present embodiment are as follows. Water supply pressure: 0.4 MPa (inflow side) Water flow rate: 23 m / sec Water volume: 15 liters / min Gas supply: 3 liters / minute magnetic circuit (titanium magnet): surface magnetic flux density 2720 Gauss / adsorption force 35Kg, The magnetic flux density at the flow position is 4248 Gauss (calculated value of the distance between magnets i〇mm)

水溫：20°C 在通過小徑路（開口部）234之時點及其隨後在超空餘 作用部237碰撞之水流速度係每秒約23m，但若換算成每i 奈秒’則為20nm之高速度。因此設想碰撞平面部237c而 爆發粉碎並呈輻射狀飛出之氣體分子的運動速度係極大。 若對於上述之製程進一步檢討，於小徑路234以高速 流動之水從小徑路234送出至開放傾斜路235時，因為通 過#路之容量急劇增大，所被急劇減壓而實現真空環境。 藉此真空，從氣體供給管239吸引氣體，混入於水，同時 並藉小徑路234内之高壓壓縮至成為小氣泡，產生第1空 钱。氣體氣泡再藉由碰撞超空蝕作用部237之擴大部237a 的平面部237c，而產生氣體分子爆發粉碎之第2空蝕。 上述製程係假設流速為20m/秒，僅在1/10000秒以下 29 323154 201201900 之極短時間之間，成為第丨空蝕與第2空蝕連續實行 程。受到第1空織第2空狀二個作用而爆發放， 體分子係以2Gnm/奈秒之高速度向水分子之海飛出 : 被稱為超空蝕之現象^ & 在不引起於第1空餘被壓縮之微細氣體氣泡再入 現象的短時間内，實施第2錢，微細之氣體氣泡口 進行所謂爆發粉碎之激烈高密度仙。魏流㈣2 = :起產生微細的氣體氣泡、氣泡分子群各別的爆發粉ς ^ ’微細氣域錢體分子於水分子中呈輕射 ，各別之氣體好係受水分子之阻力而停止，於 ，之水中的空m水分子運動的空間）零散存在。亦即在^ 空^減㈣氣職泡，所生叙微細氣體氣泡成為第 ^之m紙細氣體錢碰撞如單面部237e之特定部 之第2空蝕’粉碎微細氣體氣泡。藉由以二個 :所產生之超空蝕，以極高密度產生氣體分子。如此之 :可理解為與一般呈固體狀結晶物質之晶籠化合物之物理 =性㈣樣之㈣麵财被實現者，亦可謂液體晶龍 化口物之物質，藉此次所說明之製程初次生成。 八以往所知作為水合物、晶籠化合物的物質，係在以水 分子所構成的立體網狀構造之間隙中，以其他之氣體分子 ^入的狀態存在之物f。繼而’為於水分子間產生格子間 結合之冰或雪路狀的固體，其生成製程係在極高壓、低溫 :進行者’在液層中係不顯現。另外，本發明之液體晶籠 合物係可能在例如2(rc、大氣壓下之所謂#溫、常壓下 323154 30 201201900 生成者，後述之被微細化的水分子團部存在，在水分子間 未產生格子間鍵結的液相下，氣體分子進入於水分子間。 如此則本發明之液體晶籠化合物，從生成物之形態及性質 以及生成製程的觀點，被認為係與以往之水合物、晶籠化 合物完全相異之物。 又，在此次之液體晶籠化合物的生成時，係採用超空 蝕之概念，使用第4及5圖之裝置，但此等之概念、裝置 基本上僅為生成方法之一例。本發明之液體晶籠化合物， 藉由此等裝置所生成的液體係未受限定，藉超空蝕之概念 所生成的液體亦未受限定。若為可使氣體分子溶存於原水 之水分子間的程度使水斷裂成分子層次，及可使氣體以分 子單元被放射溶存者，生成之技術係無特別限定。 其次，說明有關為探究本發明之液體晶籠化合物實態 的紅外線照射分析實驗。對於物質之解析、鑑定，一般係 進行顯微鏡、X線照射或拉曼分光照射、雷射光照射，在 此可使用之散射光譜峰偏移的觀測等。此次藉第4圖、第 5圖之裝置所得到的液體，藉各種觀測方法，嘗試觀察其 實態，尤其水中之氣體氣泡。 但，有關在特定條件下藉第4圖、第5圖之裝置所得 到之估計含有氣泡的試樣液體，係確實藉溶存濃度計測裝 置以及試藥滴定法確認氣體之溶存。但是對於此等之試樣 液體觀測氣泡分布時，發生在可計測的氣泡分布區域亦未 觀測到氣泡的存在之特異事態。受到此事態，發明人進一 步檢討其他觀察方法，結果採用並非以觀測氣泡為目的、 31 323154 201201900 而是表述及預測水本身之一些變化之藉由紅外線照射之分 析實驗。繼而，發明人檢討前述本發明的液體晶籠化合物 之捕捉計測方式而確立觀測方法，檢討生成方法’解明有 關水晶籠化合物水的生成方法與新的物質狀態。 如本發明為了觀測於水中溶存氣體分子之狀態，必需 觀測相較於原來的水（原水）於水中之氫鍵率發生之變化 (氫鍵率的降低）^ X線照射方式適用於結晶體之計測’但 不適於具有流動性之液體的計測而無法觀測氫鍵之狀態。 在拉曼分光照射之光線特性難謂最適於水計測，從精度（分 解能）之點觀之實有不足，無法得到有關明確差異之計測結 果。此次藉由紅外線照射之分析實驗，發明人等不只在本 發明之液體晶籠化合物的生成上為史上首次成功’其觀測 亦為史上首次成功。以下，說明有關藉由紅外線照射之分 析實驗的内容。本實驗係所謂紅外線分光法（rared spectroscopy )，係對測定對象之物質照射紅外線，對透過 光（或反射光）進行分光而得到光譜（光譜峰），以暸解對象 物之特性的方法。 於實施紅外線分析實驗時，係使用Perkinelmer公司 製之傅立㈣換紅外線分光分析裝置speetrum_〇ne system B。作為汎用品之本裝置係如第7圖（3)所示，從光 ，發射之紅外線，通過鏡與稜鏡，照射於檢體之液體（液體 了蘢化合物）’被液肢射d外㈣過稜鏡與鏡而導入於 受光部以計測其變化。 亦即’傅立葉變換紅外線分光分析裝置3〇〇係具備被 323154 32 201201900 彎曲成L字型之鏡301、稜鏡302、以及檢體配置用座台 303。於檢體配置用座台303之上面中心設有檢體填充孔 303a，於檢體配置用座台303的上面藉滴管等滴下檢體之 液體L，使液體L充滿檢體填充孔303a。 當觀測時從光源所發射之紅外線IR1被L字型鏡301 的第1面反射而導入於稜鏡302。突入於稜鏡302内之紅 外線IR1被導入於檢體配置用座台303的檢體填充孔 303a’藉由檢體填充孔303a内之液體L遷移至特性相異的 紅外線IR2，同時被液體L反射，在稜鏡302内行進，從 稜鏡302射出。從稜鏡302所射出之紅外線IR2到達L字 型鏡301的第2面同時被第2面而反射，導入於未圖示之 受光面。藉由解析紅外線IR1與紅外線IR2之特性差異， 可觀測液體L之實態。 但在如此之況用品的構成中，作為檢體之液體L係以 被滴入於凹陷成直徑10腿左右的圓形鉢狀而形成之檢體 填充孔3 0 3a的狀態被觀測，與在檢體配置用座台3 〇 3之上 面貫穿於外界之部分相通。此部分之體積不大（數滴程度之 滴下容量）’故包含檢體填充孔303内之部分所滴下之液體 L的全體溫度與裝置周邊之溫度（室溫）瞬間同步，上昇至 室溫（28 C左右）。在此環境下之計測中，水之分子運動非 常激烈，在紅外線分析之解析性能中彳艮難評估試驗結果。 因此，發明人觀測本發明之液體時，認為降低水溫使 液體維持於水之密度最高之3_98t附近的溫度，以及=加 液量以避免對象液與檢出裝置之接觸部位接觸而發生變曰化° 323154 33 201201900 最為重要。如第7圖（b)所示，準備保持器3〇4，配置於檢 體配置用座台303之上面。亦即，使所生成之液體（液體晶 籠化合物）在觀測前先予冷卻，使用冰囊使傅立葉變換紅外 線分光分析裝置300的檢體配置用座台3〇3與保持器3〇4 於觀測前冷卻至附近。而且為了儘可能防止室溫（配備 裝置之至内為28。〇造成水溫上昇，故於檢體配置用座台 303之上面使用保持器304保持液體，同時並使在2〇。〇之 常溫所生成的試樣液以一端密閉容器冷卻至附近。在 觀測時間中為免引起瞬間之水溫上昇，使注入保持器3〇4 之試樣液量增加至l〇ml。 在第7圖⑻之構成’可抑制觀測中之晶籠化合物的 溫度上昇’可進行維持於i至2ΐ左右、未達1(rc之溫度 帶，亦即水分子運動被抑制、可解析氫鍵率之變化程度的 狀態之觀測（無水分子運動之抑制與水溫變化造成條件變 動的觀測）。 繼而，說明分析之内容及結果。當實際分析時 ，在各 试樣中，從觀測開始時o°c附近使溫度地上昇，並 且進行紅外線之吸光度的測定，進行測定至10〇c。繼而， 平均全部之試樣，對於0。〇至丨❶它之水分子運動比較安定 之溫度區域之计測數據加以平均，以比較原水與氣體溶存 液之數據的方法進行檢討。從成為分析對象之氣體溶存液， 減去未使氣體溶存之對照組的原水之方式確認差異。又， 試樣係以原水之自來水、原水經離子交換膜過濾後之水、 以及4種類的氣體溶存水等合計6種類進行檢討。 34 323154 201201900 將藉紅外線分析所得狀㈣晶籠化合 示於第8圖至第13圖。全部之數據係最上部_定值為水 溫10C時者，以下記載每降低rc的狀態者。在測定開始 時點的水溫之數㈣的數據，相順序係從下方每 上昇rc記錄較值而表示全部被測㈣數據。橫轴的單 位為KayseK心，相當於紅外線之振動數。縱軸係對應 於紅外線之吸光度各數據間的相對強度者，無單位。 -般而論，以紅外線分析水之代表性吸光度之嫌峰 (以下，記載為「譜峰」）係於3400 Kayser附近（詳而曰言之， 3200 Kayser與3600 Kayser)所得到，同時並於⑽〇 Kayser附近亦得到特有的譜峰。3細附近之譜峰 係對應於氫鍵之狀態者。3600 KaySer附近之譜峰係對曰應 於水分子内之氧原子與氫原子之結合（共價鍵）的伸縮， 3200 Kayser附近之譜峰係對應於水分子間的氫鍵與其他 之分子（氣體分子）間之結合的量。 ~ ' 第8圖係表示作為混入氣體前的原水之新渴縣燕市的 自來水之測定數據。為存在於大氣環境之水，溶存氧噥产 為8. 4 mg/升。本觀測結果係與從一般水所得到者门樣 第9圖係表示使上述原水經離子交換樹脂⑺『 八Water temperature: 20 ° C The water flow velocity at the time of passing the small diameter path (opening) 234 and then colliding with the super-air residual portion 237 is about 23 m per second, but if converted to every nanosecond, it is 20 nm. High speed. Therefore, it is assumed that the velocity of the gas molecules which are blasted by the collision plane portion 237c and which flutters out in a radial manner is extremely large. When the above-described process is further reviewed, when the water flowing at a high speed on the small-diameter road 234 is sent from the small-diameter road 234 to the open-inclined road 235, the capacity of the passage # abruptly increases, and the vacuum is rapidly decompressed to realize a vacuum environment. By this, the gas is sucked from the gas supply pipe 239, mixed with water, and compressed by the high pressure in the small path 234 to become small bubbles, and the first money is generated. The gas bubbles then collide with the planar portion 237c of the enlarged portion 237a of the supercavitation portion 237 to generate a second cavitation in which the gas molecules are blasted. The above process assumes a flow rate of 20 m/sec, which is only a short period of time between 1/10000 sec and 29 323 154 201201900, and becomes the third cavitation and the second cavitation continuous process. It is released by the first air-weaving second hollow shape, and the body molecule flies out to the sea of water molecules at a high speed of 2Gnm/nanosecond: a phenomenon called supercavitation ^ & In the short period of time when the first vacant small gas bubbles are reintroduced, the second money is applied, and the fine gas bubble mouth is subjected to a so-called burst pulverization. Wei Liu (4) 2 = : Produces fine gas bubbles, individual bursts of bubble molecules. ^ 'Micro gas volume molecules are lightly emitted in water molecules, and each gas is stopped by the resistance of water molecules. The space in which the m-water molecules move in the water is scattered. That is, in the air bubble, the fine gas bubble becomes the second gas bubble collision of the second part of the single face 237e, and the fine gas bubble is pulverized. Gas molecules are produced at very high density by supercavitation produced by two:. Such: it can be understood as the physical property of the crystal cage compound which is generally solid crystalline material (4). (4) The face is realized by the liquid crystal dragon, and the process described by the second time is described. generate. In the past, a substance which is a hydrate or a crystal cage compound is a substance f which exists in a state in which another gas molecule is introduced in a gap of a three-dimensional network structure composed of water molecules. Then, in order to create an ice or snow-like solid which is bonded between the water molecules, the formation process is extremely high pressure and low temperature: the progresser does not appear in the liquid layer. Further, the liquid crystal cage of the present invention may be produced by, for example, 2 (rc, atmospheric pressure, under the so-called #temperature, normal pressure, 323154 30 201201900, and the water molecules which are described later are refined, between water molecules. In the liquid phase in which no inter-lattice bonding occurs, gas molecules enter between water molecules. Thus, the liquid crystal cage compound of the present invention is considered to be a former hydrate from the viewpoint of the form and properties of the product and the production process. The crystal cage compound is completely different. Moreover, in the formation of the liquid crystal cage compound, the concept of super-cavitation is used, and the devices of Figures 4 and 5 are used, but the concepts and devices are basically For example, the liquid crystal cage compound of the present invention is not limited by the liquid system formed by such a device, and the liquid generated by the concept of super cavitation is not limited. The degree of the difference between the water molecules dissolved in the raw water causes the water to break down at the sub-layer level, and the technology system that can generate the gas in the molecular unit is not particularly limited. The infrared ray irradiation analysis experiment of the liquid crystal cage compound of the invention. For the analysis and identification of the substance, generally, the microscope, the X-ray irradiation or the Raman spectroscopic irradiation and the laser irradiation are used, and the scattering spectrum peak shift can be used here. Observations, etc. The liquid obtained by the apparatus of Fig. 4 and Fig. 5, by various observation methods, tries to observe the actual state, especially the gas bubbles in the water. However, under the specific conditions, borrow 4, 5 The sample liquid containing the bubble estimated by the apparatus of the figure is confirmed by the dissolved concentration measuring device and the reagent titration method to confirm the dissolution of the gas. However, when the bubble distribution of the sample liquid is observed, the bubble can be measured. The specific situation of the existence of bubbles was not observed in the distribution area. In response to this state of affairs, the inventors further reviewed other observation methods, and the results were based on the observation and prediction of bubbles, 31 323 154 201201900, but to express and predict some changes in the water itself. Infrared irradiation analysis experiment. Then, the inventors reviewed the aforementioned liquid crystal cage compound capture of the present invention. The observation method is established by the method of measuring and measuring, and the production method is reviewed to explain the method for generating water of the crystal cage compound and the new material state. As the present invention is to observe the state of the dissolved gas molecules in water, it is necessary to observe the water compared with the original water (raw water). Change in hydrogen bond rate in water (reduction in hydrogen bond rate) ^ X-ray irradiation method is suitable for measurement of crystals 'but not suitable for measurement of liquid with fluidity and cannot observe hydrogen bond state. It is difficult to determine the light characteristics of the illumination, and it is not suitable for the measurement of the accuracy. The generation of liquid crystal cage compounds was the first success in history. 'The observations were also the first success in history. Below, the contents of the analysis experiments by infrared irradiation are explained. This experiment is a method of irradiating infrared rays to a substance to be measured, and splitting transmitted light (or reflected light) to obtain a spectrum (spectral peak) to understand the characteristics of the object. For the implementation of the infrared analysis experiment, the Fourier (four) infrared spectroscopic analysis device speetrum_〇ne system B manufactured by Perkinelmer Co., Ltd. was used. The device as a pan-product is as shown in Fig. 7 (3), from the light, the emitted infrared rays, through the mirror and the sputum, the liquid irradiated to the sample (the liquid sputum compound) is shot by the liquid limb (4) The ridge and the mirror are introduced into the light receiving portion to measure the change. In other words, the 'Fourier transform infrared spectroscopic analyzer 3' includes a mirror 301 that is bent into an L shape by 323154 32 201201900, a crucible 302, and a specimen placement base 303. A sample filling hole 303a is provided in the center of the upper surface of the sample placing base 303, and the liquid L of the sample is dropped on the upper surface of the sample placing base 303 by a dropper or the like, and the liquid L is filled in the sample filling hole 303a. The infrared ray IR1 emitted from the light source during reflection is reflected by the first surface of the L-shaped mirror 301 and introduced into the 稜鏡 302. The infrared ray IR1 that has been introduced into the sputum 302 is introduced into the sample filling hole 303a' of the sample arranging table 303. The liquid L in the sample filling hole 303a migrates to the infrared ray IR2 having a different characteristic, and is simultaneously liquid L. The reflection travels within the crucible 302 and exits from the crucible 302. The infrared ray IR2 emitted from the 稜鏡 302 reaches the second surface of the L-shaped mirror 301 while being reflected by the second surface, and is introduced into a light-receiving surface (not shown). By analyzing the difference in characteristics between the infrared IR1 and the infrared IR2, the actual state of the liquid L can be observed. However, in the configuration of the article, the liquid L as the sample is observed in a state in which the sample filling hole 3 0 3a formed by being dropped into a circular shape having a diameter of about 10 legs is observed, and The top of the sample configuration table 3 〇3 is connected to the outside. The volume of this portion is not large (the drop capacity is a few drops). Therefore, the entire temperature of the liquid L dropped in the portion including the sample filling hole 303 is instantaneously synchronized with the temperature (room temperature) around the device, and rises to room temperature ( 28 C or so). In the measurement under this environment, the molecular motion of water is very intense, and it is difficult to evaluate the test results in the analytical performance of infrared analysis. Therefore, when the inventors observe the liquid of the present invention, it is considered that the temperature of the water is lowered to maintain the liquid at a temperature near the highest density of 3_98t of water, and the amount of liquid added is changed to avoid contact between the target liquid and the contact portion of the detecting device. ° ° 323154 33 201201900 The most important. As shown in Fig. 7(b), the holder 3〇4 is prepared and placed on the upper surface of the sample placement base 303. In other words, the generated liquid (liquid crystal cage compound) is cooled before observation, and the sample arrangement table 3〇3 and the holder 3〇4 of the Fourier transform infrared spectroscopic analyzer 300 are observed using an ice capsule. Cool before going to the vicinity. Further, in order to prevent the room temperature as much as possible (the inside of the apparatus is 28), the water temperature rises, so that the holder 304 is used to hold the liquid on the upper surface of the specimen arranging table 303 while keeping the temperature at 2 〇. The generated sample solution is cooled to the vicinity by a closed container at one end. In order to avoid an instantaneous rise in water temperature during the observation time, the amount of the sample liquid injected into the holder 3〇4 is increased to 10 μm. In Fig. 7 (8) The configuration 'can suppress the temperature rise of the cage compound during observation' can be maintained at about i to about 2 、 and not up to 1 (the temperature band of rc, that is, the movement of water molecules is suppressed, and the degree of change in the hydrogen bond rate can be analyzed) Observation of the state (observation of the movement of the anhydrous molecular motion and observation of the change of the condition caused by the change of the water temperature). Next, the contents and results of the analysis are explained. When the actual analysis is performed, in each sample, the temperature is made near the °C from the start of the observation. The ground is raised, and the measurement of the absorbance of the infrared ray is performed, and the measurement is performed until 10 〇c. Then, the average sample is measured, and the measurement data of the temperature region in which the water movement of the water is relatively stable is performed. The average is compared with the data of the raw water and the gas-dissolved liquid. The difference is confirmed by subtracting the raw water of the control group in which the gas is not dissolved, and the sample is made of raw water. A total of six types of tap water, water filtered through an ion exchange membrane, and four kinds of gas-dissolved water were reviewed. 34 323154 201201900 The results obtained by infrared analysis (4) are shown in Fig. 8 to Fig. 13. The data is the uppermost level. When the water temperature is 10C, the following is the case where the state of rc is lowered. The data of the number of water temperatures (four) at the start of the measurement, the phase sequence is displayed from the lower rc record. All measured (four) data. The unit of the horizontal axis is KayseK, which is equivalent to the number of vibrations of infrared rays. The vertical axis corresponds to the relative intensity between the data of the absorbance of infrared rays, and there is no unit. - Generally speaking, the water is analyzed by infrared rays. The representative absorbance peak (hereinafter referred to as "peak") is obtained near 3400 Kayser (more specifically, 3200 Kayser and 3600 Kayser), and There is also a unique peak near 〇Kayser. The peak near the 3 is the state of the hydrogen bond. The peak near the 3600 KaySer is the combination of the oxygen atom and the hydrogen atom in the water molecule. The expansion and contraction of the key) The peak near the 3200 Kayser corresponds to the amount of hydrogen bonding between water molecules and other molecules (gas molecules). ~ ' Figure 8 shows the new thirst as raw water before mixing with gas. The measured data of the tap water in the city of Yan, the dissolved oxygen produced in the water of the atmosphere is 8.4 mg / liter. The results of this observation are the same as those obtained from the general water. By ion exchange resin (7)

司製 G5G-B Filter : CJ0102S201//m miliDnr。、:gan〇 A p〇re)進行過濾 所得到的過濾原水之測定數據。與第8圖之搭^ 〜屌水同樣，溶 存氧濃度為8. 4 mg/升。 第10圖係表示使用本發明之技術使純氡氣體* 原水之氧水（氧分子溶存液體）的測定數據。、合存方 7豕第11圖係表 323154 35 201201900 使用本發明之技術使純氮氣體溶存於原水之氮水（氮分+ - 赫液體〕的測定數據。第U圖係表示使用本發明之技術， 使=氣體溶存於原水之氫水（氫分子溶存液體）的測定數-據/今存氫濃度為1. 3 mg/升。第13圖係表示使95%濃度 的氧藉3無聲放電進行臭氧化（封人臭氧氣體濃度：氣相： 45g/Nm)，所得到之臭氧氣體使用本發明之技術使溶存於 原水之臭氧水（臭氧分子溶存液體）的測定數據。觀測係在 臭氧濃度18 mg/升的時點進行。 以下，從第9圖至第13圖之測定數據減去第8圖之 原水的剛定數據，比較檢討是否在氣體溶存前後於氫鍵產 生變化。於第14圖至第1圖8表示其結果。 如第14圖所示般，從過濾原水之測定數據減去原水 之測定數據的值幾乎一定《亦即，過濾原水之測定數據與 原水之測定數據之間，於表示氫鍵能量之32〇〇 Kayse]f至 3600 Kayser附近之譜峰形狀未見有變化。 另外如第1圖5所示般，表示從氧水之測定數據減去 原水之測疋數據的值之圖，於3200 Kayser至3600 Kayser 附近看到很大的變化。3200 Kayser*及3600 Kayser附近 係表示氫鍵之鍵結能量’ 3200 Kayser附近減少同時3600 Kayser附近增加。有關氧水，藉紅外線分光法所測定之水 分子間氫鍵之譜峰，相較於水（原水）很明顯地變小。亦即 有關氧水，觀測到相對於原水極明顯地產生氫鍵之鍵結能 的量減少。同樣地，如第1圖6所示般，有關氮水也觀測 到明顯地產生氫鍵之鍵結能的量減少。如第丨圖7所示般， 36 323154 201201900 ，有關氯水也觀測到產生氫鍵之鍵結能的量減少。如第i圖 • 8所τ般有關臭氧水也觀測到產生氫鍵之鍵結能的量減 少。 上述奴無關氣體之種類，若依本發明對晶籠化合 物的、，工外線刀析’可觀測到一般之氣體氣泡對液體之溶解 無，付到的明顯氫鍵能量的量之減少效果。本結果顯示， 依試樣間之差異，作為比較點之唯一關鍵點的氣體分子之 存在’在水中被無盡且連續地展開之氫鍵，進行紅外線分 析等顯示以可計測程度顯著地減少，亦有暗示大量的氣體 於=中（水中）以分子之狀態存在的觀測結果。又，氣體非 以分子早70而係以氣泡存在於液中時，水與氣體氣泡的界 面已月暸水之氫鍵並未發生可計測程度之變化。 ^依上述觀察，於水帽存氣體分子所生成之液體晶 1 4 ’藉紅外線分光法測定之水分子_氫鍵之譜 峰，可確認得到譜峰小於水之液體晶籠化合物。換言之， 在本發明之液體晶籠化合物中，水分子間的氫鍵之譜峰小 2水之程度可藉紅外線分光法觀測’氣體分子係以高密度 分散於水全體。亦即，本發明之液體晶籠化合物，從紅外 線分光法之觀察法的面而言，亦可確認為新穎的物質。 在上述之實驗中，已確認氣體分子為氧分子、氮分子、 氫刀子與臭氧刀子時可生成液體晶籠化合物，但是氣體分 子之種類並不特別限定於此等。即使為二氧化碳氣體或其 他分子時’同樣可生成液體晶籠化合物。 又，在上述觀測方法中，對於液體晶蘢化合物之冷卻 323154 37 201201900 使用檢體配置用座台303與保持器304，但若具有可冷卻 並維持液體晶籠化合物在適於觀測之特定溫度以下之冷卻 裝置’則其形態無特別限定。若為適於觀測之條件，冷卻 溫度、觀測之试樣液的里專各種條件亦未特別限定於實施 形態者。 此外’發明人係如前述般，發現氣體分子分散於原水、 原液之結果’可改變該原水、原液中之水分子的分子圈（水 分子團部）之狀態。於獨立行政法人理化學研究所之出版物 「於被§忍為均一之液體的水中發現不均一的微細構造」 (http : //ww.riken. go. jp/r-word/research/results/2009 /090811/index, html)亦有記載，若為均一之液體，在長期 思考之水中已知存在微細的構造（不均一性）。以大型放射 光設施Spring-8的X線光束「IBL45XU小角散射與高精度 拉曼光分析裝置等之解析結果，可知水之密度的不均一性 源自於水中之2種類的微細構造所產生。亦即，密度之不 均一性，係「充分類似冰之微細構造」形成如於「氫鍵變 形之水分子群」之海中使用的水珠樣子之微細構造而生成。 此處，「充分類似冰之微細構造」係水分子相較於周 圍以高密度聚集的狀態，形成一種分子團構造。此事被理 解為係以飛秒的單位計測水分子觀測所得者，分子團構造 係理解為以極短時間重複生成、消耗。以此高密度聚集的 水分子群之狀態，亦即水珠的珠部分相較於其他的分子以 低密度存在的水區域而可謂氫鍵率高。 第19圖（a)係表示於一般之水（原水）中的水分子團之 323154 38 201201900 -狀態之模式圖，數十個左右的水分子之塊以奈秒以下之速 度持續改變構成。在第19圖⑷中係模式地表示水分子團 部為圓環狀的分子團區域。環狀之分子團以⑽、表示時， 水分子H2〇之數目以系對於例如3至6〇者進行檢討，但未 特別限疋η的範圍。繼而，各水分子之單獨運動亦存在， 如此則水分子聚集成如葡萄串之狀態的分子團（以下，稱為 水刀子團部」）亦在水中生成，同時表示獨自的運動。 另外’第19圖（b)係表示在本發明之液體晶籠化合物 中水分子團之狀態的模式圖。如上述般，在本發明中氣體 分子爆發、擴散時，大量的氣體分子貫通、橫切原水之水 分子海’但藉由該氣體分子之作用，第19圖⑷所示之水 分子團部被分割而細分化。在第19圖⑹中係模式地表示 被細分化之水分子團部（被微細化之水分子團部）之擴圓環 狀之分子團域。其後，氣體分子存在於水分子間亦即， 在第19圖⑸之液體晶籠化合物中，藉由在原水中溶存氣 體分子，使水分子以較周圍更高密度集合之原水中的水分 子團部被破碎，相較於第19圖⑷之原水，水分 微細化。結果，在本發明之液體晶籠化合物中，水 部之水分子的平均數，係少於原㈣4分+團 子之平均數。此外，氣料子㉞齡人叫 刀 之水分子團中’形紅的水分子團職__之狀Γ 保持被微細化之水分子團部。結果，在本發明 化合物中’若比較未處理之財，可長時 體阳蘢 平均較小的狀態。 ’、付水分子團 323154 39 201201900 在本發明之液體晶籠化合物中，保持被微細化之水分 子團# ’係意指以高密度水分子存在之區域較原水減少。 此事係思、指水分子間之平均距離變遠結果祕晶籠化合 物之氫鰱率低於原水之氫鍵率。亦日卩在本發明中，造成氮 鍵率降低之氣體分子的仙，不僅存在於水分子間而減弱 該^分子間之氫鍵（降低氫鍵能量）之仙。藉由氣體分子 破壞原水之分子團部使微細化，並發揮保持被微細化之水 分子團部的作用，亦可產生所謂氫鍵率降低之效果。因此 生成本發明之液體晶籠化合物之條件，所溶存之氣體量並 不須達職和濃度，如已說明之生成製程般，在—定之生 成條件下即使氣體之量為飽和濃度以下時，亦可生成液體 晶籠化合物。 本發明所得到之液體水合物及其生餘術，係減少氮 鍵而以高密度保有氣體，且所保有的對象物係以氣體分子 ^身所構成。所保有之對象物若以並非氣體分子之微泡或 ^米泡甚至於水中顯現混合氣體特有之效果的效力為前 提’則更顯著地具有發揮氣體功能之顯著效果者乃很明 白。氣體分子在水分子中長期間極安定地存在，即使在高 壓下散水等亦很難脫氣。此外，因氣體分子作用之故，^ 於動植物、微生物等具有被細胞直接吸收功能之利用領域 不計其數《再者，在生成液體晶籠化合物之過程中，水本 身的構造係微細化域鍵降低之程度，故於水之渗透性與 賦予細胞等的功能可重新調整，此等之個領域可謂極廣。 本發明之液體晶籠化合物在產業上的利用領域並無 323154 40 201201900 特別限定，被認為適用於各種應用領域。首先，說明有 本發明之液體晶籠化合物，尤其使用氧分子溶存於原液之 氧分子溶存液體所實施的微生物活性化之方法。 微生物利用在廢水等之淨化處理時被廣泛使用。盆代 2方性污泥法’係使微生物，尤其好氣性細菌， 質之有機一發揮淨化作㈣方t㈣細菌捕食〜蜀物 減少處理後產生之剩餘污泥㈣=廢水處理效率、 環境污染、廢棄物處理成本之刪減=污泥之削減以抑制 效率化。另外^ μ. 咸專為目的而強烈地尋求 效羊化科，活性污泥法技術 技術面_展。就活性污染處理^^年^本上無 細菌活潑地活動，在曝氣槽内二哉而吕，為使好氣性 溶存氧濃卢π 、 值（dissolved oxygen : 度為〇、/升以上之濃 若依至今之實證眚&amp; 0 辰度已為人知》但是 氣液，嗜氣為U以上之高濃度 發明人係預=:的微生物活性亦完全未提高。 合物，係使氡以叙生下A而開始實證：若為液體晶籠化 比較的程度之高二^知之散氣管等（僅氧氣泡的溶存） 分子於廢水中廢液中、以及並非氣泡而是氧 氧變細至分子，1度' 合存之％境才可提高微生物活性。 其細胞内物之氧叫中，氧分子直接被攝入 究所用之超空飾物活性明顯地提昇。此外，在採用本研 覆蛋白包覆之嗜t用的氣液混合系統中，由於並無使被包 籠化合物作用俾极I田菌滅亡的機械剪切之部位’液體晶 辕用與廢从料嗜錄細狀活性污泥 323154 41 201201900 同時與氧進行氣液混合之方法β 在飲料製造工廠之廢水處理設施中進行效果的實證。 曝氣槽係3槽串聯配置，自流入第1曝氣槽至由第3曝氣 槽排出為止之處理時間為33小時。為研究微生物之淨化作 用的活性度，故比較在習知之廢水處理設施中之廢水淨化 結果與在利用本發明之液體晶籠化合物（氧分子溶存液體） 的廢水處理設施中之廢水淨化結果。淨化製程係使用所謂 之活性污泥法。該方法係使用細菌、黴菌類、藻類、原生 動物、輪蟲類、線蟲類等各種微生物（稱為嗜氣性細菌）之 集合體的活性污泥’廢水中之有機物/污染物質被活性污染 吸附後，成為微生物之營養源被捕食分解而被除去。此時， 微生物集團之污泥係以浮游狀態與廢水接觸，同時姐處理 污染物質。 第20圖係表示習知之廢水處理設施4〇〇β廢水處理設 施400具備調整槽410、第1曝氣槽42卜第2曝氣槽422、 第3曝氣槽423、沈澱槽430、鼓風機440。在淨化製轾中 係使貯存於調整槽410之未處理廢水依序送至第丨曝氣槽 42卜第2曝氣槽422、第3曝氣槽423。在第1曝氣槽421、 第2曝氣槽422、第3曝氣槽423分別貯存含有處理廢水 之微生物的污泥，淨化通過之廢水。通過第丨曝氣槽421、 1 2曝氣槽422、第3曝氣槽423之污泥被送至沈溅槽43〇, 投予如聚氧脑之凝制^未被除去之污泥中的冷染物質 與凝集劑反應而成為團塊（凝集），沈澱於沈殿槽43〇之 底。含有團塊之廢水再被返送至第丨曝氣槽421後，重複 42 323154 201201900 i 淨化製程。繼而，在第1曝氣槽421、第2曝氣槽422、第 • 3曝氣槽423藉鼓風機44〇輸送空氣，從散氣管放出至廢 水液中。空氣中之氧被曝氣而一部分溶解於廢水中，藉此 溶存氧試行使嗜氣性之微生物活性化同時使增殖。System G5G-B Filter : CJ0102S201//m miliDnr. ,: gan〇 A p〇re) The measured data of the filtered raw water obtained by filtration. 4体积每升。 The same as the Figure 8 ~ ~ 屌 water, the dissolved oxygen concentration was 8.4 mg / liter. Fig. 10 is a view showing measurement data of oxygen water (oxygen molecule-dissolved liquid) of pure helium gas* raw water using the technique of the present invention.合 方 豕 豕 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 323 The number of measurements of the hydrogen water (hydrogen molecule-dissolved liquid) in which the gas is dissolved in the raw water - the current hydrogen concentration is 1. 3 mg / liter. Figure 13 shows that the 95% concentration of oxygen is silently discharged by 3 Ozonation (concentration of ozone gas: gas phase: 45 g/Nm), and the obtained ozone gas uses the technique of the present invention to measure the ozone water (ozone molecularly dissolved liquid) dissolved in the raw water. At the time of 18 mg/liter, the following is the subtraction of the raw water data of Fig. 8 from the measurement data of Fig. 9 to Fig. 13 to compare whether the hydrogen bond changes before and after the gas is dissolved. The result is shown in Fig. 8. As shown in Fig. 14, the value of the measurement data obtained by subtracting the raw water from the measurement data of the filtered raw water is almost constant, that is, between the measurement data of the filtered raw water and the measurement data of the raw water. Indicates the hydrogen bond energy of 32谱Kayse]f to 3600 The peak shape near Kayser has not changed. Also, as shown in Fig. 1 and Fig. 5, the value of the measured data of the original water minus the measured data of the raw water is shown in 3200 Kayser. 3600 Kayser sees a big change nearby. 3200 Kayser* and 3600 Kayser near the system represent hydrogen bond bond energy '3200 Kayser near the reduction and 3600 Kayser increase. About oxygen water, by infrared spectrometry The peak of the hydrogen bond is significantly smaller than that of water (raw water), that is, with respect to oxygen water, a decrease in the amount of bonding energy that apparently generates hydrogen bonds with respect to the raw water electrode is observed. Similarly, as in the first As shown in Fig. 6, the amount of bonding energy which apparently produces hydrogen bonds is also observed with respect to nitrogen water. As shown in Fig. 7, 36 323154 201201900, a bond of hydrogen bond is also observed in the chlorine water. The amount of energy is reduced. As shown in Figure ith, the amount of bonding energy for hydrogen bonding is also observed in the ozone water. The above-mentioned slave-independent gas type, according to the invention, is for the crystal cage compound. External line analysis 'can be observed in general The effect of the bubble on the liquid is not dissolved, and the amount of apparent hydrogen bond energy is reduced. This result shows that the existence of the gas molecule as the only key point of the comparison point is endless in the water depending on the difference between the samples. Continuously expanding hydrogen bonds, performing infrared analysis or the like shows that the degree of measurement is remarkably reduced, and there are also observations suggesting that a large amount of gas exists in a state of molecules in water (in water). When a bubble exists in the liquid, the interface between the water and the gas bubble has not changed the degree of measurement of the hydrogen bond of the water. ^ According to the above observation, the liquid crystal formed by the gas molecules in the water cap 1 4 ' By measuring the peak of the water molecule_hydrogen bond by infrared spectroscopy, it was confirmed that a liquid crystal cage compound having a peak smaller than water was obtained. In other words, in the liquid crystal cage compound of the present invention, the peak of the hydrogen bond between the water molecules is small. 2 The degree of water can be observed by infrared spectroscopy. The gas molecule is dispersed at a high density in the entire water. That is, the liquid crystal cage compound of the present invention can also be confirmed as a novel substance from the surface of the observation method of infrared spectroscopy. In the above experiment, it has been confirmed that the liquid crystal cage compound can be formed when the gas molecules are oxygen molecules, nitrogen molecules, hydrogen knives, and ozone knives, but the type of the gas molecules is not particularly limited thereto. Liquid crystal cage compounds can be formed even in the case of carbon dioxide gas or other molecules. Further, in the above observation method, the sample placement table 303 and the holder 304 are used for the cooling of the liquid crystal compound 323154 37 201201900, but the liquid crystal cage compound can be cooled and maintained at a specific temperature suitable for observation. The form of the cooling device is not particularly limited. The conditions for the cooling temperature and the sample liquid to be observed are not particularly limited to the embodiment. Further, the inventors have found that the result of dispersing gas molecules in raw water and stock solution as described above can change the state of the molecular circle (water molecule group) of the water molecules in the raw water or the raw liquid. In the publication of the Institute of Physical and Chemical Research of the Independent Administrative Corporation, "uneven micro-structures were found in the water that was tolerated by §" (http://www.riken.go.jp/r-word/research/results/ 2009 /090811/index, html) It is also stated that in the case of a uniform liquid, a fine structure (heterogeneity) is known in water for long-term thinking. The analysis results of the X-ray beam of the large-scale radiation facility Spring-8 "IBL45XU small-angle scattering and high-precision Raman light analysis device" show that the density of water is not uniform due to the two types of fine structures in the water. In other words, the density unevenness is formed by forming a fine structure of a water droplet-like structure used in the sea of the "hydrogen-bonded water molecule group". Here, "substantially similar to the fine structure of ice" is a molecular group structure in which water molecules are aggregated at a high density compared with the surrounding. This matter is understood to mean that the water molecules are observed in units of femtoseconds, and the molecular structure is understood to be repeated and consumed in a very short time. The state of the water molecules clustered at such a high density, that is, the bead portion of the water droplets is higher in hydrogen bonding rate than the water regions in which other molecules are present at a low density. Fig. 19(a) shows a pattern of water molecules in a general water (raw water) 323154 38 201201900 - State diagram, and blocks of dozens of water molecules are continuously changed at a rate of not more than nanoseconds. In Fig. 19 (4), the molecular cluster region in which the water molecule group is annular is schematically shown. When the cyclic molecular group is represented by (10), the number of water molecules H2〇 is reviewed for, for example, 3 to 6 ,, but the range of 疋η is not particularly limited. Then, the individual movements of the water molecules are also present, and thus the molecular clusters in which the water molecules are aggregated into a state like a grape bunch (hereinafter referred to as a water knife group) are also generated in the water and represent the individual movement. Further, Fig. 19(b) is a schematic view showing the state of water molecule groups in the liquid crystal cage compound of the present invention. As described above, in the present invention, when gas molecules are erupted and diffused, a large amount of gas molecules penetrate and cross the water molecules of the raw water, but by the action of the gas molecules, the water molecule group shown in Fig. 19 (4) is Segmentation and segmentation. In Fig. 19 (6), the molecular cluster region of the water-molecule group (the water molecule group to be miniaturized) which is subdivided is schematically represented. Thereafter, the gas molecules are present between the water molecules, that is, in the liquid crystal cage compound of Fig. 19 (5), by dissolving the gas molecules in the raw water, the water molecules are gathered in the raw water of the raw water at a higher density than the surroundings. The part is broken, and the water is finer than the raw water of Fig. 19 (4). As a result, in the liquid crystal cage compound of the present invention, the average number of water molecules in the water portion is less than the average of the original (four) 4 points + the group. In addition, the 34-year-old man of the gas is called the water molecule cluster of the knife, and the shape of the red water molecule is maintained as a micronized water molecule. As a result, in the compound of the present invention, if the untreated wealth is compared, the average body state of the body is long. </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> <RTIgt; This matter is thought to mean that the average distance between water molecules is farther. As a result, the hydroquinone rate of the crystal cage compound is lower than that of the original water. Also in the present invention, the gas molecules which cause a decrease in the nitrogen bond rate are not only present between the water molecules but also weaken the hydrogen bonds (reducing the hydrogen bond energy) between the molecules. The molecular group of the raw water is destroyed by the gas molecules to refine the pores, and the effect of reducing the hydrogen bond rate can be exhibited. Therefore, the conditions of the liquid crystal cage compound of the present invention are generated, and the amount of the dissolved gas does not need to be attained by the working level and the concentration, as in the production process described above, even if the amount of the gas is below the saturation concentration under the conditions of the formation, A liquid cage compound can be produced. The liquid hydrate obtained by the present invention and the remainder thereof retain a nitrogen bond and retain a gas at a high density, and the object to be retained is composed of gas molecules. It is clear that the object to be preserved has the effect of exhibiting the remarkable effect of the gas function if it is effective in the effect of the microbubble or the m-bubble of the gas molecule or even the effect of the mixed gas in the water. Gas molecules are extremely stable during the long period of time in water molecules, and it is difficult to degas even when water is dispersed under high pressure. In addition, due to the action of gas molecules, there are countless fields in which animals, plants, and microorganisms have functions of direct absorption by cells. "In addition, in the process of producing liquid cage compounds, the structure of water itself is a micro-domain bond. The degree of reduction is such that the permeability of water and the functions of imparting cells and the like can be readjusted, and such fields are extremely wide. The liquid crystal cage compound of the present invention is not particularly limited in the field of industrial use, and is considered to be suitable for various application fields. First, a method of activating a microorganism having a liquid crystal cage compound of the present invention, in particular, an oxygen molecule-dissolved liquid in which an oxygen molecule is dissolved in a stock solution will be described. Microbial use is widely used in the purification treatment of wastewater and the like. The basin-type 2-particulate sludge method makes microorganisms, especially aerobic bacteria, and the organic ones play a role in purification. (4) Square t (4) Bacterial predation ~ The excess sludge produced after the treatment is reduced (4) = wastewater treatment efficiency, environmental pollution, Reduction of waste disposal costs = reduction of sludge to reduce efficiency. In addition, ^ μ. Salt is specifically for the purpose of seeking effective sheep chemical, activated sludge technology technical surface _ exhibition. In the case of active pollution treatment, there is no active activity in the bacteria, and it is in the aeration tank. In order to make the aerobic dissolved oxygen concentration π, the value (dissolved oxygen: the degree is 〇, / liter or more If the empirical evidence of 至今 &amp; 0 is known, but the gas-liquid, high-concentration inventors are more than U, the inoculant pre-: the microbial activity is not improved at all. Let's start with the following: If the degree of liquid crystal cage is higher, the degree of the liquid is higher than that of the air tube (the only oxygen bubbles are dissolved). The molecules are in the waste liquid of the waste water, and the bubbles are not bubbles but the oxygen is reduced to the molecules. The degree of 'coexistence' can increase the microbial activity. In the oxygen of the cell, the activity of the ultra-empty ornaments used by the oxygen molecules is directly increased. In addition, the coating is coated with the protein. In the gas-liquid mixing system for t-type use, there is no mechanical shearing site where the entrapped compound acts on the extinction of the bacteria. The liquid crystal crucible and the waste material are recorded as activated sludge 323154 41 201201900 At the same time, the method of gas-liquid mixing with oxygen is in drinking The effect of the effect in the wastewater treatment facility of the manufacturing plant. The aeration tank is arranged in series in 3 tanks, and the treatment time from the first aeration tank to the discharge from the third aeration tank is 33 hours. The degree of activity is compared with the result of wastewater purification in a conventional wastewater treatment facility and the wastewater purification process in a wastewater treatment facility utilizing the liquid crystal cage compound (oxygen molecule-dissolving liquid) of the present invention. The purification process uses so-called activity. Sludge method. This method uses activated sludge from wastewater, bacteria, molds, algae, protozoa, rotifers, nematodes, and other microorganisms (called aerobic bacteria). After being adsorbed by active pollution, the nutrient source of the microorganism is preyed and decomposed and removed. At this time, the sludge of the microbial group is in contact with the wastewater in a floating state, and the sewage is treated by the sister. Fig. 20 shows a conventional wastewater treatment facility. The 4〇〇β wastewater treatment facility 400 includes an adjustment tank 410, a first aeration tank 42, a second aeration tank 422, a third aeration tank 423, and sedimentation. The tank 430 and the blower 440. The untreated wastewater stored in the adjustment tank 410 is sequentially sent to the second aeration tank 42 and the second aeration tank 422 and the third aeration tank 423 in the purification system. The aeration tank 421, the second aeration tank 422, and the third aeration tank 423 respectively store sludge containing microorganisms for treating wastewater, and purify the wastewater that has passed through the third aeration tank 421, 1 2 aeration tank 422, and (3) The sludge of the aeration tank 423 is sent to the sinking tank 43〇, and the cold dyed substance in the sludge which is not removed by the condensation of the polyoxygen is reacted with the aggregating agent to become agglomerate (aggregation). The precipitate is deposited at the bottom of the chamber of the shoal. The waste water containing the agglomerate is returned to the third aeration tank 421, and the purification process is repeated 42 323154 201201900 i. Then, air is supplied to the first aeration tank 421, the second aeration tank 422, and the third aeration tank 423 by the blower 44, and is discharged from the diffuser to the waste liquid. The oxygen in the air is aerated and a part of the oxygen is dissolved in the waste water, whereby the dissolved oxygen is used to activate the microbial activation of the microorganism while proliferating.

然而，以上述習知之方法依然很難使充分的氧供給至 微生物。係因以散氣管進行曝氣時，僅能放出數英对至數 毫米直徑之氣泡，大多數空氣係於液中直接上昇通過而未 溶解，浪費地放出於大氣中。又，生存於廢水中之許多嗜 氣性微生物，為了呼吸必須有大量之氧，結果在第i與第 2曝氣槽中，都發生廢水中之液面下lm附近的D〇值均為 O.Omg/升之所謂缺氧狀態。若引起缺氧，則嗜氣性細菌於 每-P皆段滅亡胁活動’不需要氧之厭錄微生物則增 生。為避免如此之事態，使用散氣管時，例如以pSA (Pressure Swing Adsoirption :氧濃縮裝置）使氧以氣泡過 剩地供給，使成為例如8 0mg/升以上之情形亦正被研究。 但疋廢水之狀態係成為所謂過曝氣之狀態，為進行污泥之 氧化（好氣性硝化），使上述團塊微細化（pinfl〇ck)後沈澱 於沈澱槽430之底變困難，有時處理效果降低。若團塊狀 態惡化，在後段之沈澱槽之凝集沈殿變困難，已送至第^ 曝氣槽421之污泥返送變困難，同時後處理後之澄清液的 污濁度未降低’結果未能成為淨化充分者。 另外’將利用本發明之液體晶籠化合物（氧分子溶存 液體）的廢水處理設施4〇1表示於第21圖中。廢水處理設 施401具備調整槽41〇、第丨曝氣槽42卜第2曝氣槽422、 323154 43 201201900 第3曝氣槽423、沈澱槽430、鼓風機440、晶籠化合物氧 (氧分子溶存液體）供給部450、原水供給用泵浦460。淨化 製程係與第20圖之情形相同，但在本例中係於第1曝氣槽 421從晶籠化合物氧供給部450供給氧分子溶存液體。藉 本作用’在第1曝氣槽421中好氣性微生物曝發性增殖， 可得到高的淨化作用。又，不須從鼓風機440供給多量空 氣’亦可防止團塊的形成。第22圖（a)、第22圖（b)係分 別表示藉第20圖、第21圖之設施所淨化之廢水狀態。如 液面L3所示’可知在同量之廢水中，利用第22圖（b)之本 發明的氧分子溶存液體之廢水處理設施401所造成的廢水 污泥之量（L1)，相較於第22圖（a)之習知的廢水處理設施 400所造成的廢水污泥之量（L2)約成為1/5,可得到大的淨 化效果。 如下之表1係表示利用本發明的液體晶籠化合物（氧 分子溶存液體）之廢水處理設施4〇1所造成的廢水污泥之 調查結果。MLSS (Mixed Liquor Suspended Sol ids)係表 不微生物與污染物質的總量之指標，但一般以活性污泥法 所產生的廢水經曝氣處理後，相較於曝氣處理開始以前成 為1/2最理想。然而’利用本發明之氧分子溶存液體的結 果’可得到MLSS值從5〇〇〇rog/升減少至970mg/升（1/5)之 所謂劇烈效果。若假設污染物質之量成為1/5，以其作為 營養之微生物的量亦成為1/5 ’或藉以不測餌之變相的損 傷假定成為1/5以下’但實際每1(χ只從28〇〇萬個減少至 710萬個（「一般細菌（個)」）。亦即，微生物之量係只 44 323154 201201900 減少至1/4，即使營養成分之污染物質減少，微生物仍存 活乃可理解。此事係表示本發明之氧分子溶存液體有助於 (好氣性）微生物之生存、增殖。 在本研究中係從第1曝氣槽使含有活性污泥（微生物） 之廢水以水中泵浦汲起，在液體晶籠化合物處理裝置中藉 pSA以95%濃度的氧氣作為分子使高密度溶存，連續地返送 至相同的第1曝氣槽。其時曝氣槽内之D0值為了使氣體混 合效率極高，故維持20. 〇mg/升前後之所謂一般不可能程 度的南溶存氧濃度。一般，藉散氣管進行曝氣時必然成為 過曝氣，但以液體晶籠化合物處理看不出異常。在曝氣槽 即使維持2. Omg/升以上之D〇值，微生物活性亦不提高， 然而以液體晶籠化合物氧分子溶存的結果，改變淨化能力 未提间之習知常識，廢水處理裝置全體的處理能力高達2 倍以上。此外，如第22圖的照片，靜置習知法之第3曝氣 槽排出液而使MLSS成分沈澱。成為(a)之量，藉液體晶籠 ，合物氧分子溶存處理同樣於第3曝氣槽排出後靜置的 咖成分係成為⑻之量’可大幅地減容化至Μ』。· 理内:-般係使5G%作為返送污泥而於第丨曝氣槽再度處 活用其中含有之好氣性細菌，但其餘之⑽係成為剩 、尼作為產業廢棄物而成為被焚化處分者。從仙％ 叫：、、、1/2. 5之事實，暗示可返送沉澱分離之全部㈣，可 =不需處理在成本面與環境面兩者都成為問題之剩餘污 ^推斷此污泥減容係為活性污泥之好氣性細菌，在潤濕 適宜的氧分子豐富之廢水_為極活潑，另外，隨著成為 323154 45 201201900 斜之污濁物急速的淨化，細菌雖減少但仍生存，微生物間 進行共食之結果被減量。 [表1] 檢查結果 經過時間（h) 0 14 BOD(mg/l) 260 120 MLSS(mg/l) 5000 2400 般細菌（個/ml) 28, 〇〇〇, 〇〇〇 11,000, 000 23 33 110 51 21〇〇 970 18,0〇〇,〇〇〇 7,1〇〇.〇〇〇 第23圖（a)、第23圖（b)分別表示藉第20圖、第21 圖之設施所淨化的排水中之微生物狀態。相對於第2〇圖之 習知廢水處理設施400之廢水污泥存在許多厭氣性之微生 物（絲狀菌），藉第21圖之本發明的液體晶籠化合物處理， 利用氧分子溶存液體僅7小時後，從廢水處理設施401所 採取的污泥變成好氣性微生物的大量存在菌相，同時成為 幾乎看不到厭氣性微生物之絲狀菌的狀態《若依本發明， 可知可得到好氣性微生物的增殖作用’同時對活性污泥處 理造成不良影響之廢水中的厭氣性微生物明顯地減少。 此外 赞叨人付到微生物在氧分子不絕而豐富地存 之廢水中顯著增大淨化能力之結果，確認該微生物本身 生物活性提高。所使用之裝置係TSanalyzer(註冊商 為小川環境研究所股份公司製（已取得日本特許第 木; 3585905號）。在習知之廢水處理與使用本發明之液體曰 化合物的廢水處理之各過程中，經各2週實施以同條曰 採取試樣的計測。其結果，確認微生物活性/分解迷 46 323154 201201900 知之處理下為平均〇·23，但在㈣本發 物的處訂，成為平均。.58,以2.52倍之二趙二合 以習進行空氣或氧㈣氣不可能得到之 力氧若依本發制可實現。麵體晶籠化 係呈八Η 4，）的生錢㈣廢水Μ供給之氧， Μ刀 l且為向密度，故微生物易吸收為其主要因 素:此外’隨著廢水中之氫鍵率降低的程度，水分子團進 订微細化，此為微生物活性齡之重要原因亦可。 活性污泥法進行廢水處理“氣 性微生物（細菌）的活性提高。依據相同之 明可適用於浮游生物等小型生物、魚類、貝類機= ::之Si棘皮動物進行呼吸之生物的幼魚、幼貝的孵 率抑制、成長之促進。尤其與好氣性細菌同樣， 裒境取水（原液），於液體晶籠化合物生成 後使德％而返回至育成場所的方法為適宜。 值，與廢水中之微生物同樣地，可期待所謂特別 ^昇效果的氧分子仙，同咖水分子團之微細化而賦予 良好影響亦可預想。此外，在許多之水生生物的環境中因 病原體造成的污染而發生傳染病等而出現被害，但在不與 =物接觸的液體晶籠化合物生成過程中，以適宜的濃度供 給臭氧’在不殘㈣條件下亦可使賴氧錯化。此時所 使用之臭氧係於結束殺g後，形成氧分子而分散於水中， 有助於生物活性提昇。此外，在液體晶籠化合物之生成處 中與般之氣液混合法相異，可利用容易達成飽和濃 47 323154 201201900 ==之氣體濃度條件的性質。亦即，吸引氧 邊乎不例外的放出二氧化碳，但 =果亦=待所謂從水中使二氧化碳強制脫氣代 效果’亦可利用於長期間保持水質。 、甬禍翻心在本發明之液體晶籠化合物生成製程中，在 機構的瞬間’例如3〇rog/升至48mg/升之範圍 *门/辰又之氧被溶存。藉由如此之高濃度的氧，如上述般， 有使二氧化碳從水中強制職之作用。在例如缔魚之幼 魚、幼鳗魚等之水產養殖巾，驗时吸氧氣所產生的二 氧化碳之氣體取代作用。 接著介紹於相同地廢水處理設備使用液體晶籠化合 物（氧分子溶存液體）的事例。廢水對象係來自火腿、香腸 等畜產加工工廠，源自正己烷等油脂使廢水易形成厭氣性 的成分多。在同工廠中一天產生2〇〇〇噸的廢水，但產生廢 水量之數成在傍晚的洗淨作業被排出。於原水流入量有很 大的變動，但要求在活性污泥法的曝氣槽中經常維持一定 量流動而於廢水負荷變動不產生變化。是故，於該工廠的 曝氣槽之前，有1000噸容量的調整槽，發揮緩衝的角色。 但，在滯留數小時至數十小時之調整槽中氧完全不足，成 為大里之厭氣性細菌的溫床，經常產生大量之硫化氛氣體 而有危險。在同調整槽之上方解放部中產生流出550 ppm 至600 ppm之高濃度硫化氫氣體，因有人吸八時之致死量 低於1500 ppm之危險性而成為很重要的問題。 於該設施暫設液體晶籠化合物生成裝置，對於1000 48 323154 201201900 噸之厭氣狀態的廢水使每分鐘100升之氧形成分子而分散 供給。其結果’供給開始後僅經過1小時後，硫化氫氣體 濃度係以驚人速度激減至0. 2ppm以下而改善至幾乎無宝 的濃度’其後亦可維持。此現象係與所謂提昇好氣性細菌 的活性度之前述飲料工廠廢水之例相異。在廢水中大量地 生存而成為排出硫化氫之原因的厭氣性細菌，主要為住在 槽内之大量甲烷菌類，氧分子以高密度充滿於調整槽内的 液體全域，同時液體之環境成為完全之好氣狀態而瞬時造 成曱烷菌類無法活動之結果。如此不僅提高微生物之活 性’若依對象與目的而選定使分子溶存之氣體種類，亦可 用來停止目的微生物之活動。 同樣地，對於酵母、酵素亦可造成同樣的效果。若依 酵母或酵素的特性，可以氧等氣體提高增殖速度，若使用 氮亦可完全停止不成為污染之嗜氣性生物的產生。同樣地 若對處理方法之氣體進行選擇與濃度之最適化，即使進行 生物乙醇精製、或發酵技術亦可適用於處理效率的提昇或 效率控制。 藉使二氧化碳取代封人晶籠化合物之對象氣體，於眼 蟲藻或海藻等之成長促進亦顯現效果。對任一氣體，在常 溫常壓下可使氣體分子高密度分散存至液中之水分子相互 間氫鍵減少之程度。因此’被認為在生物之細胞内吸收氣 體係與氣泡無關，該對象氣體特有之功能於細胞組織内作 用而顯現效果之現象。 本發明利用於生物的可能性敘述如上述，但不限於上 323154 49 201201900 述領域，而本發明當然可廣泛適用於生物測定之相關技 術。不論土耕栽培或水耕栽培，植物之根的氧吸收若使用 液體晶籠化合物（氧分子溶存水），可以使細胞單元適宜化。 此外’本發明之氣體分子溶存液體，被認為適用於其 他各種應用領域。可期待在廣泛的領域應用的特性，被認 為在溶存氣體之高濃度的溶存維持功能。尤其期待以臭氧 氣體的溶存維持高氧化效果（殺菌效果等）。 如本發明般，氣體分子分散於原水、原液時，氣體溶 存速度係以高的效率增加。同樣地，氣體分子分散於水分 子間’脫軋之氣體量明顯減少，結果賦予濃度安定性高的 功能水之特性。例如，即使為難溶解性之臭氣氣體時，亦 很難從水中脫氣（安定化）。 於未添加濃度安定劑等之水或純水中，若依使臭氧氣 體以氣液混合使溶存之習知見識（參照日本特許第 ^34207號公報等），溶存臭氧濃度從生成之時點放置到成 為50%的半衰期係為}分鐘以内。在同日本特許中提議藉 由除去一定量存在於對象之純水中的過氧化氫，可延長半 長期，但即使如此，如在4分鐘之事例，並未改變極短時 間之事實。若依液體晶籠化合物，可以所謂氣體分子之形 態將臭氧散佈在水分子之海中。因此，所謂難溶解性之臭 氧的性質，亦不妨礙本發明氣體溶存安定化之效果。在藉 超空飯所生成之液體晶薇化合物(臭氧分子溶存水）中，在 15C之低溫條件時’即使為所謂55 mg/升至60 mg/升之高 遭度，在大氣壓中半衰期亦為1小時以上。 50 323154 201201900 此外氣體種類係特別不安定的臭氧時，一般若水溫從 低溫昇高至40°C、60°C、80°C，水之分子運動徐緩地活潑 化，水中之臭氧氣體易脫除（不依氣體種而異，氣體之飽和 濃度隨水溫上昇而大幅減少）。但是舉出作為習知之臭氧水 的生成方法的氣液混合法與電解法之任一者的生成方法所 產生的臭氧水相比較，在本發明之液體晶籠化合物（臭氧分 子溶存液體）中係可保持極安定化之狀態。 因此，以直接保持高溶存臭氧濃度（溶存臭氧分子濃 度）的狀態，可經長距離配管送水而給水至利用場所。若記 述實例，使臭氧分子溶存水10 mg/升使用1英吋徑的氯化 乙烯製配管以每分60升送水至300m遠方時，於2. 5分後 到達使用點（作用點），但其排出場所維持9.2 mg/升的高 濃度。即使對於氣體溶存之濃度安定性，亦可發揮優異的 效果。 於臭氧之情形係如亨利常數所示，藉溫度上昇臭氧分 子運動活潑化而引起自我分解，有返回氧之特性。考量如 此之特性，生成氣體分子溶存液體而使氣體分子之溶存狀 態安定化，同時並使水溫以低溫（20°C以下，宜為10°C以 下之低水溫）生成貯存的狀態進行送水，以鄰接於使用點之 前的加熱器等進行加熱，加熱之後於作用點使氣體分子溶 存液體散水、接觸即為有效。其時，臭氧分子本身之分子 運動成為極活潑，迅速地返回氧之變化加速，但已知原來 氧化性能高之臭氧，隨溫度上昇而更發揮數倍之氧化效 果。發明人經研究之結果，瞭解到於10秒以内之瞬間使之 51 323154 201201900 突沸而使臭氧水水溫上昇至6(rc的例子 1分鐘内濃度徐緩地降彳 達60C後之 濃度激減。 降低錢，祕敏齡解反應而 ^外’亦已明瞭臭氧分子係與水 化反應強，_，洗淨意除 =時，氣 使臭氧之溶存安定化，因安=㈣（聽分子溶存液趙 濃度臭氧水。臭氧#如前=线’可對使用點供給高 藉溫度上昇，熱則反應性提高，但 束處理。溶存於水之必須於短時間内結 時同氧化效果日_，同時在㈣w讀仙’使水溫上昇 為重要。若換4 使用㈣行難使發生作用乃 水分子與上ΠΓ昇氧化效果所需之要素，係使 程進行極活潑的分子運動之中間於===氧之過 降低之時間長常安定而至臭氧濃度 用的臭氧分子溶存水，相較♦ H與水分子—起經常作 之效果。 _於—般臭氧水可特別顯現優異 實驗此於本發明可適用的領域進行研究，進行 ==tr係㈣化魏糾所生成的液 :市售之碳酸水藉自然開封降低濃度而在成為· mg/升的時點，添加糊精（dextrin)製劑（商品名：τ_咖r f日清〇lUl0公司製）每1升I3g並檀拌使增黏，生成 323154 52 201201900 第1試樣（黏性體）。將同試樣移至容器内之後，拴緊而以 5 C冷藏，經過3日之時點所觀測的結果表示於第24圖（a) 中。本黏性流體係生成後立即持續產生二氧化碳之大氣 泡’二氧化碳約全量形成氣泡而集合於容器上部進行脫 氣，看不出成為透明之二氧化碳氣體的維持效果。 然後’於作為原水之自來水中混合二氧化碳成為本發 明之液體晶籠化合物，調整含量使成為近似大氣壓飽和溶 存濃度之1700 mg/升後，添加糊精製劑（與上述相同）每丄 升13g並攪拌使增黏，生成第2試樣（黏性體）。將同試樣 不加壓而移至容器内之後，拴緊而以5°C冷藏，經過3日 之時點所觀測的結果表示於第24圖（13)中。與第24圖。） 之情形對照，在本試樣中不產生二氧化碳的大氣泡。反而 產生許多二氡化碳的細氣泡，成為乳白色的黏性體，但持 續如此之乳白色的狀態❶亦即，可確認二氧化碳的分散狀 態之維持。 然而，溶存二氧化碳濃度係藉滴定法計算。藉添加增However, it is still difficult to supply sufficient oxygen to microorganisms by the above-described conventional methods. When aeration is performed with a diffusing pipe, only bubbles of several tens of millimeters to several millimeters in diameter can be released, and most of the air is directly ascended through the liquid and is not dissolved, and is wasted in the atmosphere. Moreover, many of the gasphilic microorganisms that survive in the wastewater must have a large amount of oxygen in order to breathe. As a result, in the i-th and second aeration tanks, the D 〇 values near the liquid surface in the wastewater are all O. .Omg / liter of the so-called hypoxia state. If hypoxia is caused, the gassing bacteria will be inactivated in every -P phase. In order to avoid such a situation, when a gas pipe is used, for example, a gas is excessively supplied as a bubble by a pSA (Pressure Swing Adsoirption), and it is considered to be, for example, 80 mg/liter or more. However, the state of the waste water is in a state of so-called over-aeration. In order to carry out oxidation of the sludge (aerobic nitrification), it is difficult to precipitate the precipitate at the bottom of the sedimentation tank 430 after the pellet is finely pulverized. The treatment effect is reduced. If the state of the agglomerates deteriorates, the agglomeration of the sedimentation tank in the latter stage becomes difficult, and the return of the sludge which has been sent to the second aeration tank 421 becomes difficult, and the fouling degree of the clear liquid after the post-treatment is not lowered. Purify the full. Further, a wastewater treatment facility 4〇1 using the liquid crystal cage compound (oxygen molecule-dissolved liquid) of the present invention is shown in Fig. 21. The wastewater treatment facility 401 includes an adjustment tank 41, a second aeration tank 42, a second aeration tank 422, a 323154 43 201201900 a third aeration tank 423, a sedimentation tank 430, a blower 440, and a crystal cage compound oxygen (oxygen molecule dissolved liquid) The supply unit 450 and the raw water supply pump 460. The purification process is the same as in the case of Fig. 20, but in this example, the first aeration tank 421 supplies the oxygen molecule-dissolved liquid from the cage compound oxygen supply unit 450. By this action, aerobic microorganisms are proliferated in the first aeration tank 421, and a high purification action can be obtained. Further, it is not necessary to supply a large amount of air from the blower 440, and formation of agglomerates can be prevented. Fig. 22 (a) and Fig. 22 (b) show the state of the wastewater purified by the facilities of Figs. 20 and 21, respectively. As shown by the liquid surface L3, it is known that the amount of wastewater sludge (L1) caused by the wastewater treatment facility 401 of the oxygen-molecule-dissolving liquid of the present invention in the same amount of wastewater is the same as that of the wastewater treatment facility 401 of the present invention. The amount (L2) of the wastewater sludge caused by the conventional wastewater treatment facility 400 of Fig. 22(a) is about 1/5, and a large purification effect can be obtained. Table 1 below shows the results of investigation of wastewater sludge caused by the wastewater treatment facility 4〇1 of the liquid crystal cage compound (oxygen molecule-dissolved liquid) of the present invention. MLSS (Mixed Liquor Suspended Sol ids) is an indicator of the total amount of microorganisms and pollutants. However, the wastewater produced by the activated sludge process is generally treated as a 1/2 before the aeration treatment. The most ideal. However, the use of the result of the oxygen-containing liquid of the present invention can provide a so-called violent effect that the MLSS value is reduced from 5 〇〇〇 rog / liter to 970 mg / liter (1 / 5). If the amount of pollutants is assumed to be 1/5, the amount of microorganisms that are used as nutrients is also 1/5' or the damage of the disguised bait is assumed to be 1/5 or less 'but the actual number is only 1〇 The number of microbes has been reduced to 7.1 million ("general bacteria"). That is, the amount of microorganisms is reduced to only 1/4 of 44 323154 201201900. Even if the pollutants of nutrients are reduced, it is understandable that the microorganisms are still alive. This indicates that the oxygen molecularly-soluble liquid of the present invention contributes to the survival and proliferation of (aerobic) microorganisms. In the present study, wastewater containing activated sludge (microorganisms) was pumped in water from the first aeration tank. In the liquid crystal cage compound processing apparatus, the high density is dissolved by using pSA with 95% oxygen as a molecule, and is continuously returned to the same first aeration tank. At this time, the D0 value in the aeration tank is used to mix the gas. The efficiency is extremely high, so the concentration of the south dissolved oxygen in the so-called generally impossible degree before and after 〇mg/liter is maintained. Generally, the aeration is inevitably caused by the aeration of the gas pipe, but it cannot be treated by the liquid cage compound. Abnormal Even if the tank maintains a D 〇 value of 2. Omg / liter or more, the microbial activity does not increase. However, as a result of the dissolution of the liquid crystal cage compound oxygen molecules, the conventional knowledge of the purification capacity is not changed, and the processing capacity of the entire wastewater treatment apparatus is improved. Up to 2 times or more. In addition, as shown in the photograph of Fig. 22, the third aeration tank discharge liquid of the conventional method is allowed to stand to precipitate the MLSS component, which is the amount of (a), and the dissolved oxygen molecules are dissolved by the liquid crystal cage. The coffee component that has been left to stand still after being discharged from the third aeration tank has the amount of (8), which can be greatly reduced to Μ. · Li Nei: Generally, 5G% is used as the return sludge and is exposed. The gas tank is again used to use the aerobic bacteria contained in it, but the rest (10) is the remaining waste, and the waste is incinerated as an industrial waste. The fact that it is called:,,, 1/2. 5 Returning all of the sedimentation separation (4), can be = no need to deal with the remaining pollution that is both a problem in both the cost and environmental aspects. It is inferred that this sludge reduction is a kind of aerobic bacteria of activated sludge, which is suitable for wetting oxygen molecules. Rich wastewater _ is extremely lively, in addition, along with 323154 45 201201900 The turbid turbidity is rapidly purifying, although the bacteria are reduced but still survive, and the result of co-feeding between microorganisms is reduced. [Table 1] Elapsed time (h) 0 14 BOD(mg/l) 260 120 MLSS (mg/l) 5000 2400 bacteria (units/ml) 28, 〇〇〇, 〇〇〇11,000, 000 23 33 110 51 21〇〇970 18,0〇〇,〇〇〇7,1〇〇.〇 23(a) and 23(b) respectively show the state of microorganisms in the drainage purified by the facilities of Figs. 20 and 21, respectively. There are many anaerobic microorganisms (filamentous bacteria) in the wastewater sludge, which are treated by the liquid crystal cage compound of the present invention in Fig. 21, and the sludge taken from the wastewater treatment facility 401 after only 7 hours of storage of the liquid by the oxygen molecules. In the state in which a large number of aerobic microorganisms are present, and a filamentous fungus in which an anaerobic microorganism is hardly observed, "the growth of aerobic microorganisms can be obtained by the present invention", and the treatment of activated sludge is poor. The anaerobic microorganisms in the affected wastewater are significantly reducedIn addition, the tribute to the microorganisms significantly increases the purification ability in the wastewater in which the oxygen molecules are abundantly abundant, and it is confirmed that the microorganism itself has an increased biological activity. The device to be used is TSanalyzer (the registrar is manufactured by Ogawa Environmental Research Co., Ltd. (Japanese Patent No. 3585905). In the processes of conventional wastewater treatment and wastewater treatment using the liquid hydrazine compound of the present invention, The measurement of the sample was carried out in the same section for each of the two weeks. As a result, it was confirmed that the microbial activity/decomposition fan 46 323154 201201900 was treated as the average 〇·23, but in the (4) order of the hair product, it became an average. 58, with 2.52 times the second Zhao Dihe to learn the air or oxygen (4) gas is impossible to obtain the power of oxygen can be achieved according to the system. The face crystal cage system is the gossip 4,) the money (four) wastewater supply Oxygen, boring knife l is the density of the body, so the microbes are easily absorbed as the main factor: In addition, as the hydrogen bond rate in the wastewater decreases, the water molecules are ordered and refined, which is an important reason for the age of the microorganisms. can. Activated sludge method for wastewater treatment "Environmental microbial (bacteria) activity is improved. According to the same, it can be applied to small organisms such as plankton, fish, shellfish machine =::Si echinoderms for juveniles, young fish, young The hatching rate of shellfish is inhibited and promoted. Especially in the case of aerobic bacteria, it is suitable to take water (raw liquid) in the divine environment and return it to the breeding site after the liquid crystal cage compound is formed. In the same way, it is expected that the oxygen molecules in the so-called special effect can be expected to be affected by the miniaturization of the water molecules. In addition, infection occurs in the environment of many aquatic organisms due to contamination by pathogens. Occurrence of illness, etc., but in the formation of a liquid crystal cage compound that is not in contact with the object, the ozone is supplied at an appropriate concentration, and the ozone can be mis-discharged under the condition of no residue (4). After the end of killing g, oxygen molecules are formed and dispersed in water, which contributes to the improvement of biological activity. In addition, in the formation of liquid crystal cage compound, it is similar to the general gas. The mixing method is different, and the nature of the gas concentration condition of the saturated concentration of 47 323154 201201900 == can be easily utilized. That is, the oxygen is released without exception, but the fruit is also = the so-called forced degassing of carbon dioxide from the water. The effect ' can also be used to maintain the water quality for a long period of time. 甬 翻 在 in the liquid crystal cage compound formation process of the present invention, in the moment of the mechanism 'for example, 3 〇 rog / rose to the range of 48 mg / liter * door / chen again The oxygen is dissolved. With such a high concentration of oxygen, as described above, there is a role in forcing carbon dioxide from the water. In aquaculture towels such as juvenile fish, juveniles, etc., oxygen is produced during the test. Carbon dioxide gas substitution effect. Next, an example of using a liquid crystal cage compound (oxygen molecule-dissolved liquid) in the same wastewater treatment facility will be described. The waste water object is derived from a livestock processing factory such as ham and sausage, and is derived from oil such as n-hexane to make wastewater easy to form. There are many anaerobic ingredients. In the same factory, 2 tons of wastewater is produced in one day, but the amount of wastewater generated is reduced in the evening. There is a large change in the amount of raw water inflow, but it is required to maintain a certain amount of flow in the aeration tank of the activated sludge process, and there is no change in the change of the wastewater load. Therefore, before the aeration tank of the plant, There is a 1000-ton capacity adjustment tank to play the role of buffer. However, the oxygen in the adjustment tank that stays for several hours to several tens of hours is completely insufficient, and it becomes a hotbed of anaerobic bacteria in Dali, often producing a large amount of sulfurized atmosphere. Danger. Producing a high concentration of hydrogen sulfide gas from 550 ppm to 600 ppm in the Liberation Department above the adjustment tank is an important issue due to the risk of lethal doses below 1500 ppm. The liquid crystal cage compound generating device is temporarily provided, and the waste water of 1000 48 323154 201201900 tons of anaerobic state is formed by dispersing and supplying 100 liters of oxygen per minute. As a result, after only one hour after the start of the supply, the hydrogen sulfide gas concentration was abruptly reduced to 0.2 ppm or less and improved to a concentration of almost no treasure, which was maintained thereafter. This phenomenon is different from the case of the aforementioned beverage factory wastewater which promotes the activity of aerobic bacteria. The anaerobic bacteria that survive in the wastewater and become the cause of the discharge of hydrogen sulfide are mainly a large number of methanogens living in the tank. The oxygen molecules are filled at a high density in the entire liquid of the adjustment tank, and the liquid environment becomes complete. The aerobic state and the transient cause of the inability of the decane bacteria to move. In this way, not only the activity of the microorganisms is increased, but the type of gas in which the molecules are dissolved depending on the object and the purpose can also be used to stop the activity of the microorganisms of interest. Similarly, the same effect can be achieved for yeast and enzymes. According to the characteristics of yeast or enzyme, a gas such as oxygen can be used to increase the rate of proliferation, and if nitrogen is used, the production of a gas-free organism that does not become contaminated can be completely stopped. Similarly, if the gas of the treatment method is selected and the concentration is optimized, the bioethanol purification or fermentation technique can be applied to the improvement of the treatment efficiency or the efficiency control. The carbon dioxide is substituted for the target gas of the human crystal cage compound, and the growth promotion of the ocular algae or seaweed is also effective. For any gas, at a normal temperature and a normal pressure, the gas molecules can be dispersed at a high density to a degree where hydrogen bonds between the water molecules in the liquid are reduced. Therefore, it is considered that the absorption gas system in the cells of the living organism is independent of the bubble, and the specific function of the target gas functions in the cell tissue to exhibit an effect. The possibility of utilizing the present invention for use in living organisms is as described above, but is not limited to the above-mentioned field of 323154 49 201201900, and the present invention is of course widely applicable to the related art of bioassay. Regardless of soil cultivation or hydroponic cultivation, if the liquid crystal cage compound (oxygen molecule-dissolved water) is used for the oxygen absorption of the root of the plant, the cell unit can be optimized. Further, the gas molecule-dissolving liquid of the present invention is considered to be applicable to various other fields of application. The characteristics that can be expected to be applied in a wide range of fields are considered to be a function of maintaining a high concentration of a dissolved gas. In particular, it is expected to maintain a high oxidation effect (sterilization effect, etc.) by the dissolution of ozone gas. As in the present invention, when gas molecules are dispersed in raw water or stock solution, the gas storage rate is increased with high efficiency. Similarly, the amount of gas in which the gas molecules are dispersed in the water phase is significantly reduced, and as a result, the characteristics of the functional water having high concentration stability are imparted. For example, even in the case of an odor gas which is difficult to dissolve, it is difficult to degas (stable) from water. In the case of water or pure water in which no concentration stabilizer is added, if the ozone gas is mixed by gas-liquid mixing and is known (refer to Japanese Patent No. 34207, etc.), the dissolved ozone concentration is placed from the point of generation to The 50% half-life is within ± minutes. In the Japanese license, it is proposed to extend the half-long period by removing a certain amount of hydrogen peroxide present in the pure water of the object, but even so, as in the case of 4 minutes, the fact that the extremely short time is not changed. According to the liquid crystal cage compound, ozone can be dispersed in the sea of water molecules in the form of a so-called gas molecule. Therefore, the nature of the ozone which is insoluble in solubility does not impede the effect of the gas storage stability of the present invention. In the liquid crystal jelly compound (ozone molecular dissolved water) produced by the super-empty rice, at the low temperature condition of 15C, even if it is the so-called 55 mg/liter to 60 mg/liter, the half-life at atmospheric pressure is also More than 1 hour. 50 323154 201201900 In addition, when the gas type is particularly unstable, generally, if the water temperature rises from low temperature to 40 ° C, 60 ° C, 80 ° C, the molecular motion of water is slowly and active, and the ozone gas in the water is easily removed. (It does not vary depending on the gas species, and the saturation concentration of the gas decreases drastically as the water temperature rises). However, in the liquid crystal cage compound (ozone molecularly dissolved liquid) of the present invention, the gas-liquid mixing method which is a method for producing the conventional ozone water is compared with the ozone water produced by any of the methods for producing the electrolytic method. It can maintain a state of extreme stability. Therefore, in a state where the concentration of ozone (concentration of dissolved ozone molecules) is directly maintained, water can be supplied to the use site by water supply through a long distance pipe. For example, when the ozone molecular dissolved water is 10 mg/liter, a 1-inch diameter vinyl chloride pipe is used to deliver water to a distance of 300 m per minute, and the point of use (action point) is reached after 2.5 minutes. The discharge site maintained a high concentration of 9.2 mg / liter. Excellent effects can be achieved even with respect to the concentration stability of gas storage. In the case of ozone, as indicated by the Henry's constant, the ozone is activated by the temperature rise, causing self-decomposition and returning oxygen. Considering such characteristics, the gas molecules are dissolved in the gas to stabilize the dissolved state of the gas molecules, and the water temperature is supplied to the storage state at a low temperature (lower than 20 ° C, preferably lower than 10 ° C). Heating is performed by a heater or the like adjacent to the point of use, and it is effective to disperse and contact the liquid molecules at the point of action after the heating. At this time, the molecular motion of the ozone molecule itself becomes extremely active, and the change in the oxygen return rapidly is accelerated. However, it is known that ozone having a high oxidation performance exerts several times the oxidation effect as the temperature rises. As a result of the research, the inventors learned that the temperature of the ozone water was raised to 6 by the sudden rise of 51 323154 201201900 within 10 seconds (the example of rc was drastically reduced to 60C in 1 minute. Money, the secret sensitive age reaction and ^ outside 'have already been clear that the ozone molecule and hydration reaction is strong, _, when the washing intention is divided, the gas makes the dissolution of ozone stable, because of the = (four) (listen molecular solution solution Zhao Concentration of ozone water. Ozone #如前=线' can supply high temperature rise to the point of use, heat is more reactive, but beam treatment. Dissolved in water must be combined in a short time with the same oxidation effect _, at the same time (4) w reading xian 'to make the water temperature rise is important. If you use 4 (4), it is difficult to make the effect of water molecules and the elements required for the upper oxidative effect, so that the process is carried out in the middle of the extremely active molecular motion === The oxygen is reduced for a long period of time, and the ozone molecular dissolved water for ozone concentration is often used for the effect of ♦ H and water molecules. _ O-Ozone water can particularly show excellent experiments. Suitable areas for research The liquid produced by the ==tr system is used to reduce the concentration by natural opening, and the dextrin preparation is added at the time of becoming mg/liter (trade name: τ_咖rf day) Qingyi lUl0 company) 1 liter I3g and sandalwood to make the viscosity, to produce 323154 52 201201900 first sample (viscosity). After moving the same sample into the container, tighten and refrigerate at 5 C, after The results observed at the time of the 3rd day are shown in Fig. 24(a). The large bubble of carbon dioxide continues to be generated immediately after the generation of the viscous flow system, and the carbon dioxide is formed into a bubble and collected in the upper part of the vessel for degassing. The effect of maintaining the transparent carbon dioxide gas. Then, the carbon crystal cage compound of the present invention is mixed with carbon dioxide as the raw water, and the content is adjusted to be approximately 700 mg/liter of the saturated atmospheric concentration of the atmospheric pressure, and then the dextrin preparation is added (with The same as above) 13 g per liter and stirring to make the second sample (viscous body). After the same sample was transferred to the container without pressurization, it was kneaded and refrigerated at 5 ° C for 3 days. Point of time The results of the measurement are shown in Fig. 24 (13). In contrast to the case of Fig. 24, the large bubbles of carbon dioxide are not generated in the sample, but a lot of fine bubbles of carbon dioxide are generated, which becomes a milky white sticky. Sexuality, but it continues to be so milky white, that is, it can confirm the maintenance of the dispersed state of carbon dioxide. However, the dissolved carbon dioxide concentration is calculated by titration.

黏劑的糊精製劑而增加的黏度，旋轉黏度計之旋轉子的旋 轉數在 60 RPM 之時點為 590 cP(centip〇se)，在 3〇 RpM 時點為980 cP，在12 RPM之時點為2170 cP。從賦予黏性 之觀點以糊精作為主成分之此次的黏性體為非牛頓性（剪 斷應力不正比於剪斷變形速度的性質），亦確認黏度依旋轉 數流動變化。在本研究中雖不使用，但預測藉由使用凝膠 =製劑（例如寒天等），可長期間保存氣體成分之所謂氣體 办存黏性體’可藉本發明之液體晶籠化合物生成技術來製 53 323154 201201900 每又本第24叫⑹令雖產生二氧化碳氣 但此狀態係與習知之含氣泡的液體不相同=用包 發明之液體晶籠化合物才初次達 ;使用本 了名治丨V从和备 咬肷町孔體之保持狀態，除 外，存在於起始物質之液體晶蘢化合物中的-氣 化碳分子亦存在於水分子間。 ^的-氧 胜古I使為任一者’液體晶籠化合物（氣體分子溶存液體） 寺有的效果’亦即安定之氣體分子的保持功能，即使藉由 與增黏劑之併用亦可顯社事實已被確認。因此 =力能與濃度的研究，以本發明之㈣日日日籠化合物作2 有樂物輸送功能之醫藥品，可利用來作為飲料、食/植 康食品等已被蜂認。若依本發明，以習知不可能^ 程度使氣體（分子）封人㈣性體，㈣至希 時，可提供任意調整效果的程度之技術。‘，、見政果之 此外’發明人對於本發明可適用的領域進行研究，進 二Γ敘述之例，係使氫氣溶存於水所生成的液體 曰曰IL化合物之例。 氣水係含豐富氫，還原力強，具有抗氧化性能。發明 人遇為面對壓力大的社會環境時，氫水之活用可能有助於 人的生活慢性病的改善。繼而’本發明人認為為充分發揮 如此之氫水的性能，形成液體晶籠化合物使氫以分子單元 溶存至水之氫鍵減少的程度之本發明的技術係適宜者。因 此，計劃飲用市售之氫水（使用製造填充時之溶存氫濃度為 1.2 mg/升之鋁箔包裝的氫水商品/容量18〇…裝^瓶^ 了 與液體晶籠化合物之氫分子溶存水（溶存氫濃度l 4mg/升 323154 54 201201900 /玻璃瓶裝/360 ml)而確認其效果。 使人攝取以液體晶籠化合物所產生之氫分子溶存水 以及市售氫水，檢討有無差異，同樣由攝取氫水所得到之 效果聚焦於氧化壓力標記的變化而實施試驗。對象者係男 女各試驗區共5名’男性之體重係在58 kg至70 kg進行 選定，女性之體重係在58 kg以下進行選定。男女均以未 達40歲作為對象。 液體晶籠化合物（氫分子溶存水）飲用區與市售氫水 飲用區，均於1日内使攝取360ml而連續攝取20日。攝取 方法係容器開封後於60分鐘内，以自由飲用方式飲完全 量。又，對於抽煙、喝酒之生活習慣係不改變。檢查係藉 尿檢查實施，依血中80 HdG=氧化壓力指標物質的分析（若 細胞受氧化壓力引起障礙變化則增加之尿中核酸代謝物） 來進行。又’ 80 HdG之計測係使用New 80 HdG Check ELISA(日研Zail股份有限公司）的套組。尿檢查係於觀測 開始日之早上實施，於2〇日後之相同早上採取尿液進行觀 測。計測結果表示於第25圖中。又，相對於市售氫水填充 時的溶存氫濃度為1.2mg/升，液體晶籠化合物（氫分子溶 存水）的濃度為1.4mg/升，雖有些許差異，但被認為仍在 約相同之濃度區域。 從第25圖明顯可知，在舰晶籠化合物（氫分子溶存 水）飲用區中’尿中之氧化壓力標記係開始攝取後經過20 日之時點’具有所謂平均28%之極明顯的降低值。另外， 在市售氫水巾壓力標記未降低而看* ώ效果。市售氫水之 55 323154 201201900 溶存氫濃度於填充時標禾 ” ^ ^ 為升，實際上攝取時亦 可月b降低，但製造年月Β 了刀 為使用前之1個月以内，故經判 斷為並非造成大幅影響者。 、、生月 若依本研究，攝取幾乎含有㈣氫濃度的水時， 現刀Γ成減少水之氣鰱率的程度之液體晶籠化合物顯 現效果。故可確認本發明 ^ 士康食。時，相較於習知者係為更有效者。 關本發明可適用的領域，列舉如下。當然， 可適用之領域係不限定於下述者。 ’、、 •使用氫氣體之壓力的恢復。 利氧氣H所產㈣_擊及加減理 少、高濃度保持之性皙，π 肌孔 貝不僅限於雞卵洗淨、果樹洗淨·之 殺菌技術’亦用於除去農藥（防霉劑）之技術。 表氧乳體進行之半導體及液晶面板等的表面洗淨與 、·歷(聚錢乙稀）等具有對臭氧性的材質之MF、UF膜過 ;慮益的洗淨㈣液體分子團純水，完全除去附著於膜表 面成為污垢的蛋白_，使膜再生而以長期間無交換繼續 水處理之用途。 …:而本發明係不超出本發明之要旨及範 圍，依據說 Μ 及周知之技術’熟悉此技術者進行各種變 更、應用均為本發明之預定處，包含於尋求保護的範圍。 又在不超出本發明之要旨的範圍，亦可任意地組合上述 實施形態之各構成要素。 56 323154 201201900 • 【圖式簡單說明】 - 第1圖係表示其他氣體分子進入水分子間的狀態之模 式圖。 第2圖（a)係表示在一般水中之水分子狀態的模式圖， (b)係表示氣體分子進入水分子間的狀態之模式圖。 第3圖係超空姓之概略圖。 第4圖係氣體混合液生成裝置之概略構成圖。 第5圖係氣體混合液生成裝置中之氣液混合裝置的斜 視圖。 第6圖係表示藉由超空蝕使從氣體氣泡產生氣體分子 之擴散的製程之概念圖。 第7圖（a)係汎用之富立葉變換紅外線分光分析裝置 之斜視圖，（b)係用以觀測本發明之液體晶籠化合物的富立 葉變換紅外線分光分析裝置之剖面圖。 第8圖係表示原水的紅外線分析之觀測結果的測定數 據》 第9圖係表示過濾原水的紅外線分析觀測結果的測定 數據。 第10圖係表示氧水的紅外線分析觀測結果的測定數 據。 第11圖係表示氮水的紅外線分析觀測結果的測定數 據。 第12圖係表示氫水的紅外線分析觀測結果的測定數 據。 57 323154 201201900 第13圖係表示臭氧水的紅外線分析觀測結果的測定 數據。 第14圖係表示從過濾原水的測定數據減去原水之測 定數據之值的圖。 第15圖係表示由氧水之測定數據滅去原水之測定數 據的差值之圖。 第16圖係表示由氮水之測定數據滅去原水之測定數 據的差值之圖。 第17圖係表示由氫水之測定數據減去原水之測定數 據的差值之圖。 第18圖係表示由臭氮水之測定數據減去原水之測定 數據的差值之圖。 第19圖（a)表示一般之水中水分子團狀態的模式圖’ (b)表示本發明之液體晶籠化合物中水分手團狀態之模式 圖。 第20圖係習知活性污泥法之廢水處理設施之概念圖。 第21圖係利用本發明之氧分子溶存液體之活性污泥 法之廢水處理設施之概念圖。 第22圖（a)及（b)分別表示依第20圖、第21圖之設 施所淨化之排水污泥的未作用及已作用後減量效果的照 片。 第23圖（a)及（b)分別表示依第20圖、第21圖之設 施所淨化之排水中作用前及作用後微生物狀態的照片。 第24圖（a)表示於市售之碳酸水加入增黏劑後經過特 58 323154 201201900 . 定時間後黏性體的照片，（b)表示於原水混合二氧化碳氣體 , 而生成液體晶籠化合物，加入增黏劑後經過特定時間之黏 性體的照片。 第25圖係表示觀察尿中之壓力標記變化之實驗結果 的圖。 【主要元件符號說明】 201 氣體混合液生成裝置 202 貯存槽 203 氣體供給裝置 204 循環系裝置 205 氣液混合裝置（氣體分子溶存液體生成裝置） 206 溶解促進槽 207 溫度保持裝置 231 文丘里（VENTURI)管 232 上流侧大徑路 233 擠出傾斜路 234 小徑路 235 開放傾斜路 236 下流侧大徑路 237 超空蝕作用部 239 氣體供給管 243 磁性回路 245 一者之磁石片 246 另一者之磁石片 265 氣液分離裝置 267 氣體分解裝置 300 傅立葉變換紅外線分光分析裝置 301 L字型鏡 302 稜鏡 303 檢體配置用座台 304 保持器 400、 401 廢水處理設施 410 調整槽 421 第1曝氣槽 422 第2曝氣槽 423 第3曝氣槽 430 沉澱槽 59 323154 201201900 440 鼓風機 450 晶籠化合物氧（氧分子溶存液體）供給部 460 原水供給用泵浦 60 323154The viscosity of the adhesive dextrin preparation, the rotation of the rotary viscometer is 590 cP (centip〇se) at 60 RPM, 980 cP at 3 RpM, and 2170 at 12 RPM cP. From the viewpoint of imparting viscosity, the adhesive body containing dextrin as a main component is non-Newtonian (the shear stress is not proportional to the shear deformation speed), and it is also confirmed that the viscosity changes according to the number of revolutions. Although not used in this study, it is predicted that a so-called gas-carrying viscous body which can store a gas component for a long period of time by using a gel=preparation (for example, cold weather, etc.) can be obtained by the liquid cage compound formation technique of the present invention. System 53 323154 201201900 Each of the 24th (6) orders produces carbon dioxide gas, but this state is different from the conventional bubble-containing liquid = the liquid crystal cage compound invented with the package is the first time; In addition to the state of holding the pores of the simmering sputum, the gasified carbon molecules present in the liquid crystalline compound of the starting material are also present between the water molecules. ^ - Oxygen wins the ancient I for any one of the 'liquid crystal cage compound (gas molecular dissolved liquid) Temple has the effect 'that is, the stability of the gas molecule retention function, even with the use of tackifier can also be The facts of the community have been confirmed. Therefore, according to the study of the force energy and the concentration, the (4) day-day cage compound of the present invention is used as a medicine having a music-transporting function, and can be used as a beverage, a food/vegetable food, and the like. According to the present invention, it is possible to provide a technique in which the gas (molecular) is sealed to a (four) physique, and (iv) to sir, to the extent that any adjustment effect can be provided. Further, the inventors have studied the field to which the present invention is applicable, and the example described is an example in which hydrogen is dissolved in a liquid 曰曰IL compound formed by water. The gas water system is rich in hydrogen, has strong reducing power and has antioxidant properties. When the inventor encounters a social environment with great pressure, the use of hydrogen water may contribute to the improvement of chronic diseases in people's lives. Then, the inventors believe that the technique of the present invention which is sufficient to exhibit the performance of such hydrogen water and to form a liquid crystal cage compound to reduce the hydrogen bond of hydrogen in a molecular unit to water is suitable. Therefore, it is planned to drink commercially available hydrogen water (hydrogen water packaged with aluminum foil packaged with a dissolved hydrogen concentration of 1.2 mg/liter at the time of manufacture), 18 liters of water, dissolved in hydrogen, and dissolved in liquid crystal cage compound. (Dissolved hydrogen concentration l 4mg / liter 323154 54 201201900 / glass bottle / 360 ml) to confirm the effect. Ingestion of hydrogen molecular dissolved water produced by liquid crystal cage compound and commercially available hydrogen water, review whether there is any difference, also by The effect of ingesting hydrogen water was focused on the change of the oxidative stress mark and the test was carried out. The target group was selected from 5 male and female test areas, the male body weight was selected from 58 kg to 70 kg, and the female body weight was below 58 kg. The men and women are all under the age of 40. The liquid crystal cage compound (hydrogen molecular dissolved water) drinking area and the commercially available hydrogen water drinking area are ingested for 360 days in a single day for 20 days. Ingestion method is a container. Within 60 minutes after opening, the amount of drinking is free to drink. In addition, the habits of smoking and drinking do not change. The examination is carried out by urine test, according to the blood 80 HdG = oxidation pressure The analysis of the indicator substance (if the cell is increased by the oxidative stress causes the change in the urinary nucleic acid metabolite), and the '80 HdG measurement system uses the New 80 HdG Check ELISA (Nikken Zail Co., Ltd.) kit. The urine test was carried out on the morning of the observation start day, and urine was taken in the same morning after 2 days. The measurement results are shown in Fig. 25. In addition, the dissolved hydrogen concentration at the time of filling with commercially available hydrogen water was 1.2 mg. / liter, the concentration of the liquid crystal cage compound (hydrogen molecular dissolved water) is 1.4 mg / liter, although there is a slight difference, it is considered to be still in the same concentration region. It is apparent from Fig. 25 that the ship cage compound ( In the drinking area, the 'oxidative pressure label in the urine is 20 points after the start of ingestion' and has a so-called average reduction of 28%. In addition, the pressure mark on the commercially available hydrogen water towel is not lowered. See * ώ effect. Commercially available hydrogen water 55 323154 201201900 The dissolved hydrogen concentration in the filling time is marked with "^ ^ as the rise, in fact, the monthly b can be reduced when ingested, but the manufacturing year is the first time before use. Within a month, it is judged that it does not cause a significant impact. If, according to the study, when the water is almost ingested with water containing (4) hydrogen concentration, the liquid crystal cage compound is reduced to a degree that reduces the gas enthalpy rate. Therefore, it is confirmed that the present invention is more effective than those of the prior art. The fields applicable to the present invention are as follows. Of course, the applicable fields are not limited to the following. ',, • The recovery of the pressure of hydrogen gas. The production of oxygen gas H (4) _ hit and increase and decrease, the high concentration of retention 皙, π muscle hole shell is not limited to chicken eggs washed, fruit trees washed · Sterilization technology is also used to remove pesticides (mold inhibitors). Surface cleaning of semiconductors and liquid crystal panels, etc., and MF and UF films of ozone-resistant materials such as Oxygen-based emulsions; cleaning of the benefits (4) Liquid molecular group pure water The protein _ which adheres to the surface of the film to become dirt is completely removed, and the film is regenerated to continue the water treatment without exchange for a long period of time. The present invention is not intended to be limited to the scope and spirit of the invention. It is intended to be a part of the invention. Further, the constituent elements of the above-described embodiments may be arbitrarily combined without departing from the scope of the invention. 56 323154 201201900 • [Simplified illustration] - Figure 1 is a schematic diagram showing the state of other gas molecules entering between water molecules. Fig. 2(a) is a schematic view showing the state of water molecules in general water, and Fig. 2(b) is a schematic view showing a state in which gas molecules enter between water molecules. Figure 3 is a rough picture of the super-short name. Fig. 4 is a schematic configuration diagram of a gas mixture generating device. Fig. 5 is a perspective view of the gas-liquid mixing device in the gas mixture generating device. Fig. 6 is a conceptual diagram showing a process for diffusing gas molecules from gas bubbles by supercavitation. Fig. 7(a) is a perspective view showing a general-purpose Fourier transform infrared spectroscopic analyzer, and Fig. 7(b) is a cross-sectional view showing a Fourier transform infrared spectroscopic analyzer for observing the liquid crystal cage compound of the present invention. Fig. 8 is a view showing measurement data of an observation result of infrared analysis of raw water. Fig. 9 is a measurement data showing an observation result of infrared analysis of filtered raw water. Fig. 10 is a view showing measurement data of an infrared analysis observation result of oxygen water. Fig. 11 is a view showing measurement data of an infrared analysis observation result of nitrogen water. Fig. 12 is a view showing measurement data of an infrared analysis observation result of hydrogen water. 57 323154 201201900 Figure 13 shows the measurement data of the infrared analysis observation results of ozone water. Fig. 14 is a view showing the value of the measured data minus the raw water from the measured data of the filtered raw water. Fig. 15 is a view showing the difference of the measured data of the raw water by the measurement data of the oxygen water. Fig. 16 is a view showing the difference of the measured data of the raw water by the measurement data of the nitrogen water. Fig. 17 is a graph showing the difference between the measured data of the raw water and the measured data of the raw water. Fig. 18 is a graph showing the difference between the measured data of the raw water and the measured data of the raw water. Fig. 19(a) is a schematic view showing the state of water molecule clusters in the general water. Fig. 19(b) is a schematic view showing the state of the moisture mass in the liquid crystal cage compound of the present invention. Figure 20 is a conceptual diagram of a wastewater treatment facility of the conventional activated sludge process. Fig. 21 is a conceptual diagram of a wastewater treatment facility utilizing the activated sludge method of the oxygen molecule-dissolving liquid of the present invention. Fig. 22 (a) and (b) show photographs showing the effects of the untreated and post-action reduction effects of the drainage sludge purified by the facilities of Figs. 20 and 21, respectively. Fig. 23 (a) and (b) are photographs showing the state of microorganisms before and after the action in the drainage water purified by the facilities of Figs. 20 and 21, respectively. Figure 24(a) shows a photograph of a cohesive body after a fixed time of adding a viscosity-increasing agent to a commercially available carbonated water, and (b) showing a mixed liquid carbon dioxide gas in the raw water to form a liquid crystal cage compound. A photograph of the viscous body after a certain period of time after the addition of the tackifier. Fig. 25 is a view showing the results of an experiment for observing changes in pressure marks in urine. [Description of main component symbols] 201 Gas mixture generation device 202 Storage tank 203 Gas supply device 204 Circulation system device 205 Gas-liquid mixing device (gas molecule-dissolving liquid generating device) 206 Dissolution promoting tank 207 Temperature holding device 231 Venturi (VENTURI) Tube 232 Upflow side large diameter path 233 Extrusion inclined path 234 Small diameter path 235 Open inclined path 236 Downflow side large diameter path 237 Super cavitation action part 239 Gas supply pipe 243 Magnetic circuit 245 One magnet piece 246 The other Magnet piece 265 Gas-liquid separation device 267 Gas decomposition device 300 Fourier transform infrared spectroscopic analysis device 301 L-shaped mirror 302 稜鏡 303 Sample configuration table 304 Retainer 400, 401 Wastewater treatment facility 410 Adjustment groove 421 1st aeration Slot 422 second aeration tank 423 third aeration tank 430 sedimentation tank 59 323154 201201900 440 blower 450 crystal cage compound oxygen (oxygen molecule dissolved liquid) supply unit 460 raw water supply pump 60 323154

Claims (1)

201201900 七、申請專利範圍： 1. 一種液體晶籠化合物，係使氣體分子溶存於原水中而生 成，氣體分子至少存在於前述原水之水分子間，其氫鍵 率小於前述原水之氳鍵率。 2. 如申請專利範圍第1項之液體晶籠化合物，其中，藉由 氣體分子進入水分子間，使水分子間之氬鍵消滅者。 3. 如申請專利範圍第1或2項之液體晶籠化合物，其中， 其氫鍵能量小於前述原水之氫鍵能量者。 4. 如申請專利範圍第1至3項中任一項之液體晶籠化合 物，其中，前述原水為含有有機物或微生物之至少任一 者的原液者。 5. 如申請專利範圍第1至4項中任一項之液體晶籠化合 物，其中，藉由使氣體分子溶存在前述原水中，前述原 水中水分子以較周圍更高之密度集合而成之水分子團 部被破壞，與該原水比較之下水分子團部分更微細化， 復藉由前述氣體分子在前述原水中擴散存在，而保持前 述被微細化之水分子團部分者。 6. —種液體晶籠化合物，係使氣體分子溶存於原水中而生 成，藉由紅外線分光法測定之水分子間的氫鍵能量之 量，小於前述原水之氫鍵能量的量。 7. —種液體晶籠化合物，係使氣體分子溶存於原水中而生 成，氣體分子至少存在於前述原水之水分子間，水分子 以較周圍更高之密度集合而成之水分子團部分的水分 子數，少於前述原水中之水分子團部分的水分子數。 1 323154 201201900 8. —種液體晶籠化合物，係使氣體分子溶存於原水中而生 成，在前述原水之水分子間未產生格子間鍵之液相下， 氣體分子至少存在於前述原水的水分子間。 9. 一種液體晶籠化合物之觀測方法，該液體晶籠化合物係 使氣體分子溶存於原水中而生成該觀測方法係 將前述液體晶籠化合物冷卻至特定溫度以下， 對冷卻後之前述液體晶籠化合物照射紅外線， 藉由比較前述液體晶籠化合物之紅外線吸光度與 預先得到之原水的紅外線吸光度，觀測前述液體晶籠化 合物之氫鍵率小於前述原水之氫鍵率，在液體晶籠化合 物中氣體分子至少存在於前述原水之水分子間者。 10. —種液體晶籠化合物之觀測裝置，該液體晶籠化合物係 使氣體分子溶存於原水中而生成該觀測裝置具備 將前述液體晶籠化合物冷卻至特定溫度以下之冷 卻裝置；以及 對冷卻後之前述液體晶籠化合物照射紅外線，藉由 比較前述液體晶籠化合物之紅外線吸光度與預先得到 之原水的紅外線吸光度，觀測前述液體晶籠化合物之氫 鍵率小於前述原水之氫鍵率，在液體晶籠化合物中氣體 分子至少存在於前述原水之水分子間之紅外線分光分 析裝置。 2 323154201201900 VII. Patent application scope: 1. A liquid crystal cage compound is produced by dissolving gas molecules in raw water. The gas molecules are present at least between the water molecules of the raw water, and the hydrogen bond ratio is less than the bond rate of the raw water. 2. The liquid crystal cage compound of claim 1, wherein the argon bond between the water molecules is eliminated by the gas molecules entering between the water molecules. 3. The liquid crystal cage compound according to claim 1 or 2, wherein the hydrogen bond energy is less than the hydrogen bond energy of the raw water. 4. The liquid crystal cage compound according to any one of claims 1 to 3, wherein the raw water is a stock solution containing at least one of an organic substance or a microorganism. 5. The liquid crystal cage compound according to any one of claims 1 to 4, wherein the water molecules in the raw water are collected at a higher density than the surroundings by dissolving the gas molecules in the raw water. The water molecule group is destroyed, and the water molecule group is more refined in comparison with the raw water, and the gas molecules are diffused in the raw water to maintain the aforementioned water molecules. 6. A liquid crystal cage compound produced by dissolving gas molecules in raw water, and the amount of hydrogen bond energy between water molecules measured by infrared spectroscopy is smaller than the amount of hydrogen bond energy of the raw water. 7. A liquid crystal cage compound formed by dissolving gas molecules in raw water, wherein the gas molecules are present at least between the water molecules of the raw water, and the water molecules are assembled at a higher density than the surrounding water molecules. The number of water molecules is less than the number of water molecules in the water molecule portion of the aforementioned raw water. 1 323154 201201900 8. A liquid crystal cage compound which is formed by dissolving a gas molecule in raw water, and a gas molecule having at least a water molecule in the raw water in a liquid phase in which no inter-column bond occurs between water molecules of the raw water between. 9. A method for observing a liquid crystal cage compound, wherein the liquid crystal cage compound is formed by dissolving a gas molecule in raw water to form the observation method, wherein the liquid crystal cage compound is cooled to a specific temperature or lower, and the liquid crystal cage is cooled. The compound is irradiated with infrared rays, and by comparing the infrared absorbance of the liquid crystal cage compound with the infrared absorbance of the raw water obtained in advance, it is observed that the hydrogen bond ratio of the liquid crystal cage compound is smaller than the hydrogen bond ratio of the raw water, and the gas molecule in the liquid crystal cage compound At least in the water molecules of the aforementioned raw water. 10. An apparatus for observing a liquid crystal cage compound, wherein the liquid crystal cage compound is formed by dissolving a gas molecule in raw water to form a cooling device for cooling the liquid crystal cage compound to a specific temperature or lower; and after cooling The liquid crystal cage compound irradiates infrared rays, and by comparing the infrared absorbance of the liquid crystal cage compound with the infrared absorbance of the raw water obtained in advance, it is observed that the hydrogen bond ratio of the liquid crystal cage compound is smaller than the hydrogen bond ratio of the raw water, in the liquid crystal An infrared spectroscopic analysis device in which a gas molecule in a cage compound exists at least between water molecules of the aforementioned raw water. 2 323154
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