201136740 (二)本代表圖之元件符號簡單說明： 塑質薄殼件複合體1 外表膜10 外飾層11 保護膜111 中間吸附隔熱層12 内黏著層13 塑質薄殼件20 周緣界線21 内表面23 結合件24 五、本案若有化學斜，請揭示最能顯*發明特徵的化 (無） 干八 六、發明說明： 【發明所屬之技術領域】201136740 (2) Brief description of the symbol of the representative figure: Plastic thin shell composite 1 Outer film 10 Exterior layer 11 Protective film 111 Intermediate adsorption heat insulation layer 12 Inner adhesive layer 13 Plastic thin shell member 20 Peripheral boundary 21 Inner surface 23 joint member 24 V. If there is chemical slant in this case, please reveal the most obvious features of the invention (none). Dry eight-six, invention description: [Technical field of invention]
本發明係有關一種塑質薄殼件複合體之外表膜及其應 =尤指-種可將該外表膜置於-成型模具内供在該^膜= ，型-塑質薄殼件’以形成—具有外表膜及㈣薄殼件著 性良好之複合體’供應用作為各種產品之外殼使用。 苦 【先前技術】 市面上各種電子產品，在此以電子產品為例說明但不限制， L含常見的電腦（computer)產品如筆記型電腦（ΝΒ)、通訊產σ t手機或消費性產品等3C產品但不限制，常應用一薄殼件;為Ζ πσ=外殼使用；該薄殼件隨產品的設計要求而具有不同的結構， 以外殼之薄殼件基體（base)所使用之材質而言，可概分為塑 質薄殼件及金屬薄殼件兩主要結構類別。 具有外在裝飾面之塑質薄殼件一般係利用嵌入模具式裝飾用 製程（in-mold decorating process，簡稱侃!)）製成，其係將一形 201136740 成三度空間成型形狀且印刷有圖案之载體（substrate)如塑質膜’ 以下簡稱IMD膜（IMD film)’嵌置於一成型模具内，再利用塑膠 射出成型技藝使熱熔樹脂射出成型在該IMD膜冬背面以成型該殼 體之基體’以下簡稱樹脂基體（resin base)，使該樹脂基體與imd 膜結合構成一一體式塑質薄殼件，其中，該IMD膜（IMDfilm) 可以固定結合方式設在樹脂基體（resjn base)的外表面上而形成 一永久性裝置物，供作為該塑質薄殼件之一外裝飾面或一保護面 或二者皆是；又該IMD膜亦可以暫時固定方式設在樹脂基體(resin base)的外表面上而形成一暫時性裝置物，完成後可將該IMD膜 撕離’並使該IMD膜上之印刷圖案轉印或留存在樹脂基體的外表 面上供作為該塑質薄殼件之一外裝飾面。 針對上述之塑質薄殼件結構設計及其製造方法，目前存在很 多先前技術，包含： US3,654,062係揭示一具有一壓合式表面片（a lamhated facing sheet)之模製飾板（a molded decorative plaque)的相關技術，其 係將熱熔塑膠射出成型在一已具有模具構造之壓合表面片的背面 上而形成。US6，117,384係揭示利用一具有多彩顏色之薄膜，再將 熱熔樹脂射出成型在該薄膜的背面而構成一永久結合之立體物件 之裝程相關技術。US4,391，954係揭示一包含芳香族碳酸鹽聚合物 (aromatic carbonate polymer )與一由一環己烧族 (cyclohexanedimethanol)取得之多元醋（p〇iyester)之熱塑型模 製複合體（thermoplastic molding composition )之相關技術。 US4，125,572係揭示一包含芳香族碳酸鹽聚合物 (aromatic carbonate polymer)與一由一脂肪踩（aliphatic )或環脂肪族 (cycloaliphatic diol)取得之多元醋（p〇iyester)之熱塑型模製複 合體（thermoplastic molding composition)之相關技術。US6,465，l〇2 係揭示一包含一裝飾用表面區域及一個一體式形成之聚合基體 (polymeric base)之物品及其模製方法，且該聚合基體包含透明 的王衣脂肪族多元S旨樹脂（cy cloaliphatic poly ester resin )，其中該環 脂肪族多元@旨樹脂係不受芳香族部分（aromatic moiety )干擾之相The invention relates to a film outside the plastic thin-shell composite and its should be, in particular, the outer film can be placed in a molding die for the film-type, plastic-shell Forming - a composite having a good outer film and (4) a good thin shell, is supplied as a housing for various products. Bitter [prior art] Various electronic products on the market, here is an example of electronic products, but not limited, L contains common computer products such as notebook computers (通讯), communication products, mobile phones or consumer products. The 3C product is not limited, and a thin shell member is often used; it is used for Ζ πσ = outer casing; the thin shell member has a different structure depending on the design requirements of the product, and the material used for the base of the thin shell member of the outer shell is In other words, it can be divided into two main structural categories: plastic thin shell and thin metal shell. A plastic thin-shell member having an outer decorative surface is generally formed by an in-mold decorating process (abbreviated as 侃!), which has a shape of 201136740 into a three-dimensional space and is printed with A substrate of a pattern such as a plastic film 'IMD film' is embedded in a molding die, and a plastic injection molding technique is used to project a hot melt resin on the back side of the IMD film to form the film. The base of the casing hereinafter is referred to as a resin base, and the resin matrix is combined with the imd film to form an integral plastic thin shell member, wherein the IMD film can be fixedly bonded to the resin matrix ( a permanent device on the outer surface of the resjn base) for providing an outer decorative surface or a protective surface or both of the plastic thin shell member; and the IMD film can also be temporarily fixed to the resin Forming a temporary device on the outer surface of the resin base, after which the IMD film can be torn away and the printed pattern on the IMD film is transferred or left on the outer surface of the resin substrate as the Plastic One of the outer shell of the decorative surface. In view of the above-mentioned plastic thin-shell structure design and its manufacturing method, there are many prior art, including: US 3,654,062 discloses a molded decorative sheet having a lamhated facing sheet (a molded decorative) A related art of plaque is formed by injection molding a hot melt plastic onto a back surface of a embossed surface sheet having a mold structure. US 6,117,384 discloses a process related technique for forming a permanently bonded three-dimensional article by using a film having a multi-colored color and then molding a hot-melt resin on the back side of the film. US 4,391,954 discloses a thermoplastic molding compound comprising an aromatic carbonate polymer and a polyacetal obtained from cyclohexanedimethanol (thermoplastic molding). Related technology. US 4,125,572 discloses a thermoplastic molding comprising an aromatic carbonate polymer and a poly- vinegar (p〇iyester) obtained from a fatty or cycloaliphatic diol. A related art of a thermoplastic molding composition. US 6,465,1 〇 2 discloses an article comprising a decorative surface region and an integrally formed polymeric base and a molding method thereof, and the polymeric matrix comprises a transparent king's clothing aliphatic multi-component a cy cloaliphatic polyester resin in which the cycloaliphatic polyvalent resin is not interfered by an aromatic moiety
3/18 I S J 201136740 關技術（An article comprising a decorative surface area and an integral formed polymeric base comprising transparent cycloaliphatic polyester resin, wherein the cycloaliphatic polyester resin is free from an aromatic moiety and the method of molding thereof) ° US6,117,384 係揭示一改良的嵌入模具式裝飾用製程（in—moid dec〇rating process ’ IMD )的相關技術。US6,136,441係揭示多層式塑質物品 (multilayer plastic articles)的相關技術。參考上述各種有關塑質 殼體的結構設計或製造方法等先前技術之專利說明書内容，可知 該等先前技術大都是將一塑質殼體所包含之塑質膜（即IMD膜） 及樹脂基體（resinbase)分別作出進一步之限定（limitati〇n)，如 將塑質膜（IMD膜）或樹脂基體（resin base)限定為某一特殊化 學族塑質材料，藉以製成一穩固結合不易剝離之一體式複合塑質 板材，且又可與其他先前技術或相關專利之間有區別性。 然，當一複合體之塑質膜（即_膜），以下通稱為外表膜， 及/或其樹脂基體（resin base) ’以下通稱為塑質薄殼件，被分別特 殊^匕限定時，不但使所仙之材料受到關，也餅表膜及/或塑 ，薄殼件之應用相對受到限制，不利於所製成具外表膜及塑質薄 殼件之複合體的祕，例如為綠化需要而欲翻包含但不限制 布面、皮革面、樹脂纖維面等材料來作為外表膜時，則往往益法 利用相_技術錢備麟成生產效率高、可量產化且品^管 佳之功效，相對無法提昇該複合體，即塑質外殼，之使用效二 及應用範圍’因此可視為上述該等複合體的缺點。 由上可知’習知具外表膜之塑質薄殼件複合體之應用，確實 存在-些缺點及問題’本發明即針對US3,654，㈤、腦391 954、 ' US^13M41 【發明内容】 用方種塑質薄殼件複合體之外表膜及其應 用方法’該外飾膜係由-外飾層、—中間吸附隔熱層及一内黏著 4/18 201136740 層所依序疊置愚合構成之麵，其巾該嶋著層係— 共聚炭氫石油樹脂所合成之熱塑性橡膠薄膜，厚度約40Γ6〇 μ /、 °亥中間吸附隔熱層為由聚酿纖維（Tetoron/特多龍）、尼 ，（Nylon)或混紡材料構成，厚度約〇.2_〇.5mm ;其中該外飾層 ^由城纖維如植物纖維之棉、麻或動物纖維之毛、蠶絲構成 ^ ^造纖維如尼龍、職麟、壓克力纖維或混纺構成之布料 PU、PVC或PU與PVC合成皮構成之合成皮革層， 〆厌，.維層或一玻璃纖維層，厚度約0.2-0.6mm ;當應用時，可 =外，之不同選擇贱決定其中—種外表膜，再將該 膜平了3/18 ISJ 201136740 (an article comprising a decorative surface area and an infravable polymeric base comprising a transparent cycloaliphatic polyester resin, the cycloaliphatic polyester resin is free from an aromatic moiety and the method of molding thereof) ° US 6,117,384 A related art of an in-moid dec〇rating process (IMD) is disclosed. US 6,136,441 discloses related art of multilayer plastic articles. Referring to the above-mentioned various prior art patent specifications relating to the structural design or manufacturing method of the plastic shell, it is known that the prior art mostly uses a plastic film (i.e., IMD film) and a resin matrix contained in a plastic shell ( Resin base) further defines (limitati〇n), such as plastic film (IMD film) or resin base (resin base) is defined as a special chemical family of plastic materials, thereby making a stable bond is not easy to peel off a body Composite plastic sheet, and can be distinguished from other prior art or related patents. However, when a plastic film of a composite (ie, a film), hereinafter collectively referred to as an outer film, and/or a resin base thereof, is hereinafter referred to as a plastic thin shell member, respectively, when it is specifically defined. Not only does the material of the fairy material be closed, but also the surface of the cake film and/or plastic, and the application of the thin shell member is relatively limited, which is not conducive to the secret of the composite body having the outer film and the thin plastic shell member, for example, for greening. If you need to turn over but not limited to the fabric, leather surface, resin fiber surface and other materials as the outer film, it is often beneficial to use the phase _ technical money to prepare the production of high efficiency, mass production and quality control Efficacy, relatively unable to enhance the composite, that is, the plastic shell, the effectiveness of the application and the scope of application 'so can be regarded as the shortcomings of the above composites. It can be seen from the above that the application of the plastic thin-shell composite with the outer film does have some disadvantages and problems. The present invention is directed to US 3,654, (5), brain 391 954, 'US^13M41 [invention] The outer film of the plastic shell thin shell composite and the application method thereof are formed by the outer layer, the intermediate heat insulating layer and the inner layer 4/18 201136740 layer. The surface of the composition, the towel layer of the thermoplastic resin film synthesized by the copolymerized hydrocarbon hydrogen resin, the thickness of about 40 Γ 6 〇 μ /, ° Hai middle adsorption heat insulation layer is made of poly fiber (Tetoron / Tedron , Nylon, or a blended material, having a thickness of about 2.2_〇.5mm; wherein the outer layer is composed of a city fiber such as cotton of plant fibers, wool of animal or animal fibers, and silk. Such as nylon, yin, acrylic fiber or blended fabric PU, PVC or PU and PVC synthetic leather composed of synthetic leather layer, 〆 ,, 维 layer or a glass fiber layer, thickness of about 0.2-0.6mm; When applied, it can be different from the other choices, which determines the outer film, and then flatten the film.
ίίί—射出成麵具之模穴内，再_鋪射出工藝而於 該外f膜之内表面，即内黏著層上，射出成型一塑質薄殼件，該 ，質薄财即可藉㈣師著層及巾間吸眺熱層之作用，以與 該外表膜結合形成-密著結合之-體化複合體，藉明進該外表 膜與塑質薄殼件之間的結合強度及密著性，以提昇該複合體 型品質及應用範圍。 本發明再一目的係提供一種塑質薄殼件複合體之外表膜及其 應用方法，當應用時，該外表膜亦可平整設在一射出成型模具（或 押塑成ϋ模具）之模穴内，再利用塑料射出成型工藝而於該外表 膜之内表，’即内黏著層上，射出成型一塑質薄殼件，當該外表 膜之内黏著層上射出成型該塑質薄殼件時，該塑質薄殼件可藉由 射出成型時射出料的射㈣力及溫度以__著雜溶結合成 一體，並同時迫使該内黏著層之部分厚度約10_20%，即4_12μιη， 得渗透至該中間吸附隔熱層中既有之孔隙中以有效分散射出料的 射出壓力及溫度’也就是該中間吸附隔熱層可吸附該内黏著層之 部分厚度並隔離其熱量以分散射出料的射出壓力及溫度，避免射 出料的射出壓力及溫度因為過大而衝抵並破壞該外飾層之完整 I*生，並在射出成型過程中藉由該射出料的流動以迫使該外表膜形 成整平狀態，藉以形成一密著強度及品質皆良好之一體化複合體。 本發明另一目的係提供一種塑質薄殼件複合體之外表膜及其 應用方法，其中該外表膜亦可設在一押塑成型模具之模穴内再 5/18 m 201136740 利用塑料押塑成型工藝而於該外表膜之内黏著層上，押塑成型一 塑質薄殼件，以形成一連續式之一體化複合體。 為進一步瞭解本發明之詳細結構及其作用功效，玆配合圖示 說明於後。 【實施方式】 參考圖1，本發明塑質薄殼件複合體之外表膜包含：一外 飾層11設f外面供向外展示；一中間吸附隔熱層12設在外飾層 11與内黏著層13之間並可與外飾層η黏合成一體；及一内黏著 層13設在内面供一塑質薄殼件可成型在其表面上；且該外飾層 11、中間吸附隔熱層12及内黏著層13依序疊置壓合以構成一薄 膜。 該外飾層11可為下列各組群中之一種：一布料層，其由天然 纖維如植物纖維之棉、麻或動物纖維之毛、蠶絲構成或由人造纖 維如尼龍、聚脂纖維、壓克力纖維或混紡構成；一合成皮革層， 其由PU、（聚氨醋，Polyurethane)、pvc (氯乙烯樹脂）或ρυ與 pvc合成皮構成；一碳纖維層，其由碳纖維（carb〇nfiber)構成； 或一玻璃纖維層，其由玻璃纖維（glassfiber)構成；該外飾層U 之厚度約〇.2-0.6mm。 該中間及附隔熱層12為由聚g旨纖維（Tet〇ron/特多龍）、尼龍 (Nylon)或混紡材料構成，厚度約〇2_〇 5mm ;以該中間吸附隔 熱層12之構成材料而言’其耐熱性並不高，且遠低於先前技術中 選用PET作為塑質膜（gpIM□膜）之耐熱性；又該中間吸附隔熱 層12可形巧織布型態、不織布型態、發泡層型態或超纖層型態等 其中一種型態，且以具有高密度為佳，但其結構體上仍具有細微 孔隙。 該内黏著層13係-由丁苯嵌段共聚物與碳氫石油樹脂所合成 之熱塑性橡膠薄膜，厚度約40·60 μιη。 參考圖8,在此進一步說明本發明塑質薄殼件複合體之外表膜 10之應用方法’藉以同時說明應用本發明之外表膜1〇而製成之塑 6/18 m 201136740 件複合體1及其成型模具3的結構特徵。參考圖2-4，其八 別，應用本發明外表膜1〇所成型之塑質薄殼件複合體^ 二 之刖視、背視立體及斷面示意圖。參考5 實施例 膜10應用於一塑質薄殼件複合體!之射型d::外J 柱作為疋位點之侧面示意圖。 汗f澄刀 提供一本發明之外表臈10;該外表 梅， 有，； 產口 1腦卜⑽）、通訊產品如手機或職性產等 產口〇仁不限制，在此以一筆記型電 ===合體1如目2、3、4獅=== L==含一外飾層11、-中間吸附咖2及： III 12 ^ η疊置壓合'中間吸附隔熱層12與—内黏著層 以伴镬ΐ外飾層其他的加工處理而具有-層透明保護膜： 士 ·！站办Α 你雙化’貫細*時’该外表膜10亦可形忐一且 ί ΐί 3之長條料細ig並齡祕魏，供 =而輸也物^輸上蝴-私m裝 且3依出成型工#，提供—塑f薄殼件2G之射出成型模 =圖干表膜:整固定在該射出成型模具3之模穴/ 相關技術而構出依射出成型工藝之 共另〇構型態如灌注口位置、射出料 m 201136740 计安排並不須特別限制；當外表膜1〇固定在模穴31内後，其周 ?係超出模穴31之周緣界線32。又該模穴31之周緣界線 2係設計超出該塑質驗件2〇之成_周緣界線(或稱周緣端 成—環周緣且較薄之溢料區33，也就是該溢料區33 1、該f質，殼件2Q之周緣界線21之交界處形成-落差如圖6所 H _田Ϊ穴31之周緣外邊可設置數支彈性壓力柱34供作為 二一抑沒圖7所不，該等彈性壓力柱34之數目不限如圖7中 2定ΐΖΪί有三支彈性壓力柱34 ;而藉該數支彈性壓力柱34 膜10 /夾轉性拉撐該外細1G之外緣部分，以使該外表 =在A、母模3〇a、30b閉合時仍能保持平整狀態而不致產生 著層成型4 ’於該外細⑴之内表面，即内黏 熱溶結合成?Π二:，内黏著層13 之部分厚度約10·20%，即二f ’上度:_〇， 效之分散作用也出料20a的射出動及溫度產生有 孔隙以吸附該内其結構體既有之 當密度以隔離射出料20a的射出ϋ、σ/其、ϋ所具有之適 之射出壓力及溫度的功用， 酿度達成为散射出料20a 抵至該外飾層U致破壞該外飾層==射=及溫度衝 程中’亦同時藉由該射出料出成型過 平狀態，藉以形成—密菩返使该外表膜10形成整 1 ;由於該模穴3 ^之周緣界=二白良好之塑質薄殼件複合體 界線並形成-環周緣且較^ 出該塑質薄殼件20之周緣 料區33即可在該塑質薄殼件如之有洛差因此該溢 薄之凸緣22如圖6所示，也ϋ界線22外緣延伸形成-較 未去除毛邊之前)之外緣端上額j之塑質薄殼件20(尚 22，可當作該塑質薄殼件2〇成型紅-體成型之凸緣 8/丨8斤，、有之預設之毛邊，供在後 201136740 毛邊去，作業中再抑去除，·另，隨設計需要如欲於該 成里之塑㈣殼件2G之喊面23上直接絲電子構件如 等，可於射出成型該塑質薄殼件20時於該内表面23 : 成型所需之結合件24如圖3、4所示，使結合件24隨塑質 20時射出成型而形成一體式結構體； 買溥成件 塑質===峨麵成型完成之 再進行毛邊去除作業，由該塑質薄殼件2〇之周 除該模穴之溢料區33所形成之凸緣22如圖6所示，即:成一且 Ϊ 塑質薄殼件2〇並結合成一體之塑質薄殼二合體1 士述使縣發明之外械1(m製成―㈣薄殼件複合體 應用方法，由於本發明外表膜1〇之内黏著層13之部分 射=成型過程t渗透至該中間吸附隔熱層12中既有之孔“， ϊΐί ΐ f薄殼件2G穩固地熱炼密著結合成—體，故所製成之塑 ，相當良好之密著性，在經實體試驗後，㈣該外表1^〇二 足夠的抗獅性，故本發明之外細1G確實形、 化塑質薄殼件複合體i之結構強度。 4所域體 又在本發明外表膜10之應用方法上，特別在 之二！f計一環周緣且較薄(有落差)之溢料區33當 ί 出一般係由該模穴31之中央部位進入模穴 31，即灌注口設在該模穴31之中央部位，再住四周之 、 t射ίίίΐ以能較快速地流至該模穴31之周緣界線32，則射出料 向周緣界線％流動時，可相對壓迫設在該周緣 、更形在者且平整，因此當凸緣22被當作毛邊切除後，即 0/1 D ^ 201136740 增進塑質薄殼件複合體1完成品之周緣邊的外相品質。 藉由本發明之外表膜10的設計，使整片膜可直接置入 内以進行㈣驗件2G之射城型健，且該外械1G又可對、 射出料2Ga的射出壓力及溫度產生分散作用以避免因射出料 的射出壓力及溫度而破壞該外飾層U之完整性’使該外飾層u I選擇較多種不_材質，例如：布料層其可由天然纖維 ，人造纖_成，《-合做革科Pu(聚錢，PGlyu她 PVC (氣乙稀樹脂）或PU與PVC合成皮構成，且均可利用塑ίίί—Injecting into the cavity of the mask, and then spraying out the process and forming a thin plastic shell on the inner surface of the outer f film, that is, the inner adhesive layer. The layer and the surface of the towel absorb the hot layer, and combine with the outer film to form a dense-bonded composite body, and the bonding strength and adhesion between the outer film and the plastic thin shell member Sex to improve the quality and application range of the composite. A further object of the present invention is to provide a film outside the plastic thin shell composite and a method for applying the same, and when applied, the outer film can also be flatly disposed in a cavity of the injection molding die (or molded into a die) And then using a plastic injection molding process on the inner surface of the outer film, ie, on the inner adhesive layer, a plastic thin shell member is injection molded, and when the plastic thin shell member is injection molded on the adhesive layer inside the outer film The plastic thin shell member can be integrated into the body by the injection (four) force and temperature of the injection material during injection molding, and at the same time forcing the thickness of the inner adhesive layer to be about 10-20%, that is, 4_12 μm, to penetrate into The intermediate adsorption heat insulating layer has an injection pressure and a temperature for effectively scattering the discharge material in the pores, that is, the intermediate adsorption heat insulation layer can adsorb a part of the thickness of the inner adhesive layer and isolate the heat thereof to separate the emission of the discharge material. Pressure and temperature, avoiding the injection pressure and temperature of the injection material, which is too large to smash and destroy the complete I* of the outer layer, and force the formation of the outer film by the flow of the injection material during the injection molding process. The leveling state is to form an integrated composite with good adhesion strength and quality. Another object of the present invention is to provide a film outside the plastic thin shell composite and a method for applying the same, wherein the outer film can also be placed in a cavity of a plastic molding die and then 5/18 m 201136740 by plastic molding. The process is formed on the adhesive layer of the outer film to form a plastic thin shell member to form a continuous integrated composite body. In order to further understand the detailed structure of the present invention and its function and effect, it will be described later in conjunction with the drawings. [Embodiment] Referring to Figure 1, the outer film of the plastic thin-shell composite of the present invention comprises: an outer layer 11 provided with an outer surface for outward display; and an intermediate adsorption layer 12 disposed on the outer layer 11 and adhered thereto. Between the layers 13 and may be integrally bonded to the outer layer η; and an inner adhesive layer 13 is disposed on the inner surface for a plastic thin shell member to be formed on the surface thereof; and the outer decorative layer 11 and the intermediate adsorption heat insulating layer 12 and the inner adhesive layer 13 are sequentially laminated and pressed to form a film. The exterior layer 11 may be one of the following groups: a cloth layer composed of natural fibers such as cotton of plant fibers, wool of animal or animal fibers, silk or by rayon such as nylon, polyester fiber, pressure Made of gram fiber or blend; a synthetic leather layer composed of PU, (Polyurethane), pvc (vinyl chloride resin) or ρυ and pvc synthetic skin; a carbon fiber layer made of carbon fiber (carb〇nfiber) Or a glass fiber layer composed of glass fibers; the outer layer U has a thickness of about 0.2-0.6 mm. The intermediate and heat-insulating layer 12 is made of a fiber (Tet〇ron/Tedron), a nylon (Nylon) or a blended material, and has a thickness of about 〇2_〇5 mm; In terms of constituting materials, the heat resistance is not high, and is far lower than the heat resistance of PET used as a plastic film (gpIM □ film) in the prior art; and the intermediate absorbing heat insulating layer 12 can be shaped into a woven fabric, One of the non-woven type, the foamed layer type, or the ultra-fibrous layer type, and preferably has a high density, but the structure still has fine pores. The inner adhesive layer 13 is a thermoplastic rubber film synthesized from a styrene-butadiene block copolymer and a hydrocarbon petroleum resin, and has a thickness of about 40·60 μm. Referring to Fig. 8, the application method of the outer surface film 10 of the plastic thin-shell composite of the present invention will be further described, which is a plastic 6/18 m 201136740 composite 1 which is prepared by simultaneously applying the outer film of the present invention. And the structural features of the molding die 3. Referring to Figures 2-4, it is a schematic view of a squint, a rear view, and a cross-section of a plastic thin-shell composite formed by applying the outer film of the present invention. Reference 5 Example Membrane 10 is applied to a plastic thin shell composite body! The injection type d:: the outer J column is a side view of the crucible point. Khan f Cheng knife provides an external appearance of the invention 臈 10; the appearance of plum, there,; production mouth 1 brain (10)), communication products such as mobile phones or professional products, such as the mouth of the mouth is not limited, here a notebook Electricity === fit 1 such as 2, 3, 4 lion === L== with an exterior layer 11, - intermediate adsorption coffee 2 and: III 12 ^ η stacked pressure 'intermediate adsorption insulation layer 12 and - The inner adhesive layer has a transparent protective film with the other processing of the outer layer: 士·! Station Office Α When you double the 'fine*', the outer film 10 can also be shaped and ί ΐί 3 long strips fine ig and age secret Wei, for = and lose also ^ lose the butterfly - private m And 3 according to the molding worker #, providing - plastic f thin shell member 2G injection molding die = dry surface film: fixed in the injection molding die 3 cavity / related technology and constructed according to the injection molding process The configuration of the crucible such as the position of the infusion port and the ejection material m 201136740 are not particularly limited; when the outer membrane 1〇 is fixed in the cavity 31, the circumference thereof exceeds the peripheral boundary 32 of the cavity 31. Further, the peripheral boundary 2 of the cavity 31 is designed to extend beyond the circumference of the plastic inspection piece 2 (or the peripheral edge into a circumferential edge and a thin flash area 33, that is, the overflow area 33 1 The f-quality, the boundary of the peripheral boundary 21 of the shell member 2Q is formed - the drop is as shown in Fig. 6. The outer edge of the H-field hole 31 can be provided with a plurality of elastic pressure columns 34 as the second one. The number of the elastic pressure columns 34 is not limited to three elastic pressure columns 34 as shown in FIG. 7 , and the outer elastic 1B outer edge portion is sandwiched by the plurality of elastic pressure columns 34. So that the appearance = when A, the mother molds 3〇a, 30b are closed, can still maintain a flat state without causing the formation of the layer 4' on the inner surface of the outer thin (1), that is, the internal heat and heat are combined into two: The thickness of the inner adhesive layer 13 is about 10·20%, that is, the two f'up degrees: _〇, the effect of the dispersion is also the ejection of the discharge 20a and the temperature is generated to have pores to adsorb the inner structure of the structure. The density is used to isolate the injection enthalpy of the injection material 20a, the appropriate injection pressure and temperature of the σ/, ϋ, and the degree of brewing reaches the scattering discharge 20a. The outer layer U causes destruction of the outer layer == shot = and the temperature stroke is also formed by the injection of the material out of the flat state, thereby forming the outer film 10 to form an integral 1; The periphery of the hole 3 ^ = the boundary of the white thin plastic shell composite and form a ring circumference and the peripheral material area 33 of the thin plastic shell 20 can be obtained in the thin plastic shell Therefore, the thin flange 22 is as shown in FIG. 6, and the outer edge of the boundary line 22 is extended to form a plastic thin shell member 20 on the outer edge of the outer edge. It can be used as the plastic thin shell member 2〇formed red-body-formed flange 8/丨8 kg, with preset burrs for the back of the 201136740 burr, and then removed during the operation, · another, According to the design, if necessary, the direct electronic component such as the surface of the plastic part (4) of the shell member 2G can be formed on the inner surface 23 when the plastic thin shell member 20 is injection molded: the combination required for molding As shown in Figs. 3 and 4, the member 24 is formed by molding the bonding member 24 to form an integral structure with the plastic material 20; the plastic part of the product is replaced by a plastic part === In the removing operation, the flange 22 formed by the overflow portion 33 of the cavity is removed from the periphery of the plastic thin shell member 2, as shown in Fig. 6, that is, a thin plastic shell member is formed and joined. One-piece plastic thin-shell dimer 1 The method of applying the invention of the outer-machine 1 (m--four) thin-shell composite, due to the partial injection of the adhesive layer 13 in the outer film of the present invention = molding process t penetrates into the existing pores in the intermediate adsorption heat insulation layer 12, and the thin shell member 2G is firmly heat-sealed and combined into a body, so that the plastic is made, and the adhesion is quite good. After the physical test, (4) the external surface 1 ^ 2 is sufficient to resist the lion, so the structural strength of the thin 1G shape and the thin plastic shell composite i is fine. The four domain bodies are in the application method of the outer film 10 of the present invention, especially in the second! The flash area 33 which is a thin circumference of the ring and which is thin (with a drop) is generally inserted into the cavity 31 from the central portion of the cavity 31, that is, the filling port is provided at the central portion of the cavity 31, and then stays for four weeks. The t-element can flow to the peripheral boundary 32 of the cavity 31 more quickly, and when the injection material flows toward the peripheral boundary line, the relative compression can be provided on the circumference, which is more flat and flat, so when the flange 22 is treated as a raw edge, ie 0/1 D ^ 201136740 to improve the quality of the outer phase of the periphery of the finished product of the thin plastic shell composite 1. By the design of the outer membrane 10 of the present invention, the entire film can be directly placed therein to perform (4) the shot type 2G of the inspection piece 2G, and the outer mechanical 1G can disperse the injection pressure and temperature of the injection material 2Ga. The function is to prevent the integrity of the outer layer U from being damaged due to the injection pressure and temperature of the injection material. The outer layer u I is selected to be more than a plurality of materials, for example, the cloth layer can be made of natural fibers and rayon. "-Complete leather division Pu (poly money, PGlyu her PVC (gas ethylene resin) or PU and PVC synthetic leather, and can use plastic
出成型工藝來製成一具良好品質之塑質薄殼件複合體1，故 成製程簡化之目的。 在本發明外表膜10之上述應用中，該塑質薄殼件20之射出 料20a相對可選擇較多種不同的塑料，例如：(苯乙烯樹脂）、 Pf ^聚碳酸酯，p〇iycarbonate resin)、Acrylic resin (壓克力 樹脂/丙烯酸樹脂）、Nylon (尼龍/聚醯胺樹脂）等；又該等射出料 ^在射出成型時之壓力及溫度分別為:之射出壓力8〇kg/_ 射出溫度200 C ; PC之射出壓力120kg/mm2，射出溫度26〇。(：；The molding process is used to produce a plastic thin-shell composite 1 of good quality, so that the process is simplified. In the above application of the outer film 10 of the present invention, the shot 20a of the plastic thin shell member 20 can be selected from a plurality of different plastics, for example: (styrene resin), Pf ^ polycarbonate, p〇iycarbonate resin) , Acrylic resin (acrylic resin / acrylic resin), Nylon (nylon / polyamide resin), etc.; and the pressure and temperature of the injection material ^ in the injection molding: the injection pressure 8 〇 kg / _ injection The temperature is 200 C; the injection pressure of PC is 120 kg/mm2, and the injection temperature is 26 〇. (:;
Acrylic resiI^射出壓力1〇〇kg/mm2，射出溫度施。^及啦^ 尼龍酿胺樹脂）之射出壓力80kg/mm2 ’射出溫度260°C ;其 中該塑質薄殼件20藉由射出成型時射出料2〇a的射出壓力及溫 度，，可與該外表膜10之内黏著層13熱熔結合成一體，並同時 迫使该内黏著層13，厚度約40-60 μιη ’之部分厚度約10—20%， 即4-12μιη，得滲透至該該中間吸附隔熱層12中既有之孔隙中。 另，本發明之外表膜10亦可應用於塑料押塑成型領域，其中 該外表膜10可設在一押塑成型模具之模穴内，再利用塑料押^成 型工藝而於該外表膜10之内黏著層13上押塑成型一塑質薄殼 件’以形成一連續式之一體化複合體；由於塑料押塑成型工藝與 塑料射出成型工藝類似，故於此不再贅述。 再藉以下各應用實施例，進一步說明本發明之應用方法及其 所月色達成之作用功效： 、 10/18 U] 201136740 實施例1 本實施例之外表膜10中，該外飾層U係選用一皮革層其由 PU (聚氨酯，Polyurethane)、PVC或PU與PVC合成皮構成，厚 度約為0.2-0.3mm，且外飾層u為不透明且其外表面加工形成壓 紋；該中間吸附隔熱層12為由聚酯纖維（Tet〇r〇n)、尼龍（Nyi〇n) 或混紡材料構成，厚度約為0.35_0.45mm，且本實施例之中間吸附 隔熱層12係織製成布面型態；該内黏著層13為由芏 物與碳氫石油樹脂所合成之熱塑性橡膠薄層膜， (0.04-0.05mm)，·該塑質薄殼件 20 係選用 pc (p〇lycarb〇nate resin，聚碳_旨）或ABS (苯乙烯樹脂）之其中一種為射出料 20a，而利用塑料射出成型工藝射出成型在外表膜1〇之内表面即 内黏著層13上，厚度約為2 mm，長、寬為加職⑽腿；又 該塑質薄殼件2G之喊面23上紗同時—體射出成型數個妹合 件（24)其高度為9.5晒；結果發現，本實施例之 質薄殼件20之間的剝離強度密著性為每平方公分8公 試密著性為由俄至蚊以及航至俄每分鐘升溫或降溫]、 C且經4次循環，該外表膜10與塑質薄殼件2〇不剝離，藉此古正 明本發日月之外表膜1確實可增進該外表膜j與塑殼曰° 成一體化塑質薄殼件複合體丨之結構強度及密著性。 實施例2 本實施例之外表臈1〇中，該外飾層U係選用一 施例1其由(聚氨酯，P〇lyUrethane)、PVC或PU與PVC人成 但本實施例之外飾層U之外表、 如表其喊關加轉成敎並經電鍍上 色’該中間吸附隔熱層12為由聚醋纖維㈤嶋）·； 或混紡材料構成，厚度約為〇.3湖咖，且本實施彳； 人1、1物與奴虱石油樹脂所合成之熱塑性橡膠薄膜， 3〇-40μιη (〇.〇3-〇.〇4mm);該塑質薄殼件2〇係選用pc又、” L iil 11/18 201136740 (Polycarbonate resin，聚碳酸酯）或ABS (苯乙烯樹脂）之其 中一種為射出料2〇a，而利用塑料射出成型工藝射出成型在外表膜 1〇之内表面即内黏著層13上，厚度約為2mm，長、寬為262mm *178mm，又該塑質薄殼件2〇之内表面23上設有同時一體射出成 型數個結合件（24)其高度為9.5 mm ;結果發現，本實施例之外 表膜10與塑質薄殼件2〇之間的剝離強度密著性為每平方公分8 公=’環境測試密著性為由_4〇。〇至85°C以及85°C至-40°C每分鐘 升溫f降溫rc且經4次循環，該外表膜10與塑質薄殼件20不剝 ’藉此証明本發明之外表膜確實可增進該外表膜10與塑質 薄忒件20所形成一體化塑質薄殼件複合體丨之結構強度及密著 性0 實施例3Acrylic resiI^ injection pressure 1〇〇kg/mm2, injection temperature application. ^和啦^ Nylon-based amine resin) injection pressure 80kg/mm2 'injection temperature 260 ° C; wherein the plastic thin shell member 20 can be injected with the injection pressure and temperature of the injection material 2〇a, The adhesive layer 13 in the outer film 10 is thermally fused and integrated, and at the same time, the inner adhesive layer 13 is forced to have a thickness of about 40-60 μm, and the thickness of the portion is about 10-20%, that is, 4-12 μm, which penetrates into the middle. The heat insulating layer 12 is adsorbed in both pores. In addition, the outer film 10 of the present invention can also be applied to the field of plastic compression molding, wherein the outer film 10 can be disposed in a cavity of a plastic molding die, and then used in the outer film 10 by a plastic molding process. A plastic thin shell member is formed on the adhesive layer 13 to form a continuous integrated composite body; since the plastic extrusion molding process is similar to the plastic injection molding process, it will not be described herein. The application method of the present invention and the effect of the moonlight color achieved by the following application examples are further illustrated: 10/18 U] 201136740 Embodiment 1 In the outer film 10 of this embodiment, the outer layer U is A leather layer is selected which is composed of PU (Polyurethane), PVC or PU and PVC synthetic skin, and has a thickness of about 0.2-0.3 mm, and the outer layer u is opaque and the outer surface is processed to form embossing; The thermal layer 12 is made of polyester fiber (Tet〇r〇n), nylon (Nyi〇n) or a blended material, and has a thickness of about 0.35 mm to 0.45 mm, and the intermediate heat insulating layer 12 of the embodiment is woven. The inner adhesive layer 13 is a thin layer of a thermoplastic rubber synthesized from a sputum and a hydrocarbon petroleum resin, (0.04-0.05 mm), and the plastic thin shell member 20 is selected from pc (p〇lycarb). One of the 〇nate resin, polycarbonate or ABS (styrene resin) is the injection material 20a, and is injection molded on the inner surface of the outer film, that is, the inner adhesive layer 13, by a plastic injection molding process, and the thickness is about 2 mm, length and width are added (10) legs; and the plastic thin shell 2G shouting face 23 is on the yarn The time-body injection molding of several sister fittings (24) has a height of 9.5; as a result, it was found that the peeling strength adhesion between the thin shell members 20 of the present embodiment was 8 metric per square centimeter. From Russia to mosquitoes and air to Russia to heat up or cool down every minute], C and after 4 cycles, the outer film 10 and the plastic thin shell 2〇 are not peeled off, whereby the film is indeed outside the sun and the moon. The structural strength and adhesion of the outer film j and the molded case 一体化° into the integrated plastic thin shell composite body can be improved. Embodiment 2 In the outer surface of the present embodiment, the exterior layer U is selected from a first embodiment, which is made of (polyurethane, P〇lyUrethane), PVC or PU and PVC, but the outer layer U of the embodiment. The outer surface, such as the table, is turned into a crucible and is electroplated and colored. The intermediate adsorption thermal insulation layer 12 is composed of a polyester fiber (five), or a blended material, and has a thickness of about 湖.3 lake coffee, and The present invention is a thermoplastic rubber film synthesized by human 1, 1 and slave petroleum resin, 3〇-40μιη (〇.〇3-〇.〇4mm); the plastic thin shell member 2 is selected from pc and "Lilil 11/18 201136740 (Polycarbonate resin, polycarbonate) or ABS (styrene resin) is one of the injection material 2〇a, and is injection molded on the inner surface of the outer film 1〇 by a plastic injection molding process. The adhesive layer 13 has a thickness of about 2 mm and a length and a width of 262 mm * 178 mm. Further, the inner surface 23 of the plastic thin shell member is provided with a plurality of simultaneous injection moldings (24) having a height of 9.5 mm. As a result, it was found that the peeling strength adhesion between the film 10 and the plastic thin-shell member 2〇 outside the present embodiment was 8 gong per square centimeter = The environmental test adhesion is _4 〇. 〇 to 85 ° C and 85 ° C to -40 ° C per minute heating f cooling rc and after 4 cycles, the outer film 10 and the plastic thin shell 20 are not stripped 'This proves that the outer film of the present invention can enhance the structural strength and adhesion of the integrated plastic thin-shell composite body formed by the outer film 10 and the plastic thin element 20.
本實施例之外表膜1〇中，該外飾層U係選用一皮革層其由 pu (聚氨酯，Polyu讀咖）、pvc或pu與pvc合成皮構成、 度約為〇.2_0.3随’且外飾層u為不透明且其外表面加工形成壓 紋；該中間吸附隔熱層12為由聚醋纖維（Tet〇r〇n)、尼龍（Nyl〇n) 或混紡材料構成，厚度約為〇.35-0.45mm，且本實施例之中間吸附 隔熱，12係形成不織布·、發泡層㈣或超纖層縣之其中一 種；該内黏著層13為由了絲段共聚物與碳氫石油樹^所合成之 40·50μιη (a〇4-a〇5mm) ^ ^ ϊ ί ί、用本乙烯樹脂）或 PC (Polycarbonate resin，聚 石J，)之其中一種為射出料2〇a，而利用塑料射出成型工藝射出 ΐϊΐί表5⑽之内表面即内黏著層13上，厚度約為2職，長、 寬為262 mm*178mm ;又該塑質薄殼件20之内表面23 時二體射出成型數個結合件（24)其高度為95馳；結果發現。， 卜tf膜1與塑㈣殼件2之間的剝離強度密著性為 環境測試密著性為由销至85°C以及阶至 :40 C母刀鐘升溫或降溫rc且經4次循環’該外表膜1〇與塑質 设件20不剝離，藉此註明本發明之外表膜10確實可增^該外^ 12/18 201136740 Ϊ i〇與〜塑/薄殼件20所形成一體化塑質薄殼件複合體1之結構 強度及密著性。 實施例4 本實施例之外表膜10中，該外飾層u係選用一布料層其以 士造纖維，如尼龍、聚脂纖維、壓克力纖維或祕材料構成，、 =〇.2-0.3mm ;該中間吸附隔熱層12為由聚醋纖維（Tet〇 尼龍（Nylon)或混紡材料構成，厚度約為〇35_〇45mm，而 施例之中間吸附隔熱層12可形成織布型態 ^ ^或超細_中-種；朗賴13 嵌= 物與碳虱石崎脂所合成之鮮性橡膠_，厚度約4Q m“ (〇.〇4-0.05麵）；該塑質薄殼件2〇係選用pc (ρ〇ι幫 resni，聚碳酸酯）或abs (苯乙烯樹脂）之其中一種 ㈣之内表面即内 為長、寬為262細*178咖；又該 ίϋϋΐι内表面23上設有同時一體射出成型數個結合 件（24)其南度為9.5 mm ;結果發現，本實施例之外 質薄殼件20之間的剥離強度密著性為每平方 、二 試密著性勝贼至85。⑶及8心_4 ; f或^， 本發明之外表膜10確實可增進該外表膜 月 形成-體化塑質薄殼件複合體！之結構強度及密^生秘牛20所 實施例5 本貫施例之外表膜ω中，該外飾層u包含—布 合層及-樹脂透明外覆層，該布料層細 ， 層厚度為购編㈣嫩層膠合 體，该樹脂透明外覆層係貼合在布料層之外表面上 0.1-0.2mm，故所形成之外飾層1〇之厚 =又乃為 間吸附隔熱層12融聚賴維㈤嶋)，、絲（聊 201136740 材料構成，厚度為〇.35_0.45麵，而本實施例之中間吸附隔熱層 可形成織布型態、不織布型態、發泡層型態或超纖層型態等其 ^-^;該内黏著層13為由丁苯嵌段共聚物與碳氮石油樹脂所合 f t熱船生橡膠_，厚度約40_50μιη (__〇.〇5mm);該塑質薄 選用、PC⑽卿—眺咖111 ’聚碳酸酯）或_ 卜表膜10之内表面即内黏著層13上，厚度約為2 r上^有irnfi78mm;又該該塑質薄殼件2〇之内表面 9 ^ 射出成型數個結合件其高度為9.5 mm ;結果發 :义=外表臈1〇與塑質薄殼件2〇之間的著 斤’環境測試密著性為由俄至坑以= ί f 溫或降溫lt：錄4次麵，料麵10與塑 2G不剝離’減註明本發明之外表膜1Q確實可該 結構強i及與密塑著I薄殼件20所形成-體化刚殼件複合體' : ίίίϊ限f的精神和範圍内可對其進行許多改變，修i ί至 專效變更，飾將紅本發明的賴範_。 甚至 【圖式簡單說明】 塑質薄殼件複合體之外表膜之結構示意圖。 之前之外表膜所成型之塑質薄殼件複合體-實施例 圖3係圖2實施例之背視立體示意圖。 圖4係圖2、3所示實施例之斷面示意ι 外表膜應—塑㈣殼件複合體之射出成型模 姻，其中塑質薄 201136740 圖7係圖5射出成型模具機台上以三個彈性壓力柱作為定位點之 側面示意圖。 圖8係本發明外表膜應用於一塑質薄殼件複合體之成型流程示意 圖。 【主要元件符號說明】 塑質薄殼件複合體1 外表膜10 外飾層11 保護膜111 Φ 中間吸附隔熱層12 内黏著層13 周緣界線15 塑質薄殼件20 射出料20a 周緣界線21 凸緣22 内表面23 結合件24 成型模具3 • 模穴31 周緣界線32 溢料區33 彈性壓力柱34 15/18In the outer film of the embodiment, the outer layer U is made of a leather layer which is composed of pu (polyurethane, polyu read coffee), pvc or pu and pvc synthetic skin, and the degree is about 2.2_0.3 with ' The outer layer u is opaque and the outer surface thereof is processed to form an embossing; the intermediate adsorption heat insulation layer 12 is made of polyester fiber (Tet〇r〇n), nylon (Nyl〇n) or a blended material, and has a thickness of about 35.35-0.45mm, and in the middle of this embodiment, the heat-insulating heat insulation, 12 series forms one of non-woven fabric, foam layer (four) or super-fiber layer county; the inner adhesive layer 13 is composed of wire segment copolymer and carbon One of the 40.50μιη (a〇4-a〇5mm) ^ ^ ϊ ί ί, using the vinyl resin) or PC (Polycarbonate resin, poly stone J,) synthesized by the hydrogen petroleum tree is the injection material 2〇a And using the plastic injection molding process to produce the inner surface of the inner surface of the surface of the surface of the surface of the inner surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of the surface of The body was injection molded into several joints (24) with a height of 95 rpm; the results were found. , the peel strength between the tf film 1 and the plastic (four) case 2 is the environmental test adhesion from the pin to 85 ° C and the order to: 40 C master knife temperature rise or cool rc and 4 cycles 'The outer film 1〇 and the plastic material set 20 are not peeled off, thereby indicating that the outer film 10 of the present invention can indeed increase the integration of the outer surface 12/18 201136740 Ϊi〇 with the plastic/thin shell member 20. The structural strength and adhesion of the plastic thin shell composite 1 . Embodiment 4 In the outer film 10 of the embodiment, the outer layer u is selected from a cloth layer, such as nylon, polyester fiber, acrylic fiber or secret material, =〇.2- 0.3mm; the intermediate adsorption heat insulation layer 12 is made of polyester fiber (Ty〇 nylon (Nylon) or a blended material, and has a thickness of about 〇35_〇45mm, and the intermediate adsorption heat insulation layer 12 of the embodiment can form a woven fabric. Type ^ ^ or superfine _ medium - species; Langlai 13 embedded = fresh rubber synthesized with carbon gangue sashimi _, thickness about 4Q m " (〇. 〇 4-0.05 surface); The inner part of the shell member 2 is selected from pc (ρ〇ι帮resni, polycarbonate) or abs (styrene resin) (4), the inner surface is long and the width is 262 fine *178 coffee; and the inner surface of the ίϋϋΐι 23 is provided with a plurality of simultaneous injection molding joints (24) with a south degree of 9.5 mm; as a result, it is found that the peel strength between the outer thin shell members 20 of the present embodiment is per square and second. Sexually win the thief to 85. (3) and 8 hearts _4; f or ^, the outer film 10 of the present invention can indeed enhance the outer film forming a body-shaped plastic thin-shell composite! Example 5 of the structure strength and density of the baby. In the film ω outside the present embodiment, the exterior layer u comprises a cloth layer and a resin transparent outer layer. The cloth layer is fine and the layer thickness is purchased. (4) The tender layer glue, the resin transparent outer cover is attached to the outer surface of the cloth layer by 0.1-0.2mm, so the thickness of the outer layer formed by the outer layer is also the same as the heat-absorbing layer 12 Poly Laiwei (5) 嶋), silk (Lian 201136740 material composition, the thickness is 〇.35_0.45 surface, and the middle adsorption heat insulation layer of this embodiment can form a woven fabric type, a non-woven fabric type, a foamed layer type Or the ultra-fibrous layer type, etc.; the inner adhesive layer 13 is made of styrene-butadiene block copolymer and carbon-nitrogen resin ft heat ship rubber _, thickness about 40_50μιη (__〇.〇5mm) The plastic thin is selected, PC (10) qing - 眺 111 111 'polycarbonate) or _ _ _ film 10 on the inner surface of the inner adhesive layer 13, the thickness is about 2 r on the ^ innfi78mm; and the plastic thin The inner surface of the shell member 2 is 9 ^ injection molded several joints with a height of 9.5 mm; the result is: the meaning = the outer surface 臈 1 〇 and the plastic thin shell 2 〇 between the environmental test For the Russian to the pit to = ί f temperature or cooling lt: recorded 4 times, the material surface 10 and plastic 2G are not stripped 'minus note that the outer membrane of the invention 1Q can indeed be strong i and with a thin shell I Piece 20 is formed into a body-formed rigid shell composite ': ίίίϊ 的 的 的 的 的 的 的 的 f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f Brief Description of the Structure: Schematic diagram of the structure of the outer membrane of the plastic thin shell composite. The plastic thin shell composite formed by the outer membrane before - embodiment FIG. 3 is a rear perspective view of the embodiment of FIG. Figure 4 is a cross-sectional view showing the embodiment of the embodiment shown in Figures 2 and 3, the injection molding die of the outer film of the outer film, the plastic film is thin, and the plastic film is thin, 201136740, Fig. 7 is the injection molding die on the machine table. A flexible pressure column is used as a schematic view of the side of the positioning point. Fig. 8 is a schematic view showing the molding process of the outer film of the present invention applied to a plastic thin shell composite. [Main component symbol description] Plastic thin shell composite 1 Outer film 10 Exterior layer 11 Protective film 111 Φ Intermediate adsorption heat insulation layer 12 Inner adhesive layer 13 Peripheral boundary line 15 Plastic thin shell member 20 Injection material 20a Peripheral boundary line 21 Flange 22 Inner surface 23 Joint member 24 Molding mold 3 • Cavity 31 Peripheral boundary line 32 Flash area 33 Elastic pressure column 34 15/18