201134681 模穴31 周緣界線32 溢料區33 塑質薄殼件40 射出料40汪 周緣界線41 凸緣42 五本案右有化學式時’請揭示最能顯示發明特徵的化學式： (無） 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種具有裝飾用外覆膜之塑質薄殼件及其製， 法，尤指一種先在一外覆膜如一布料層由天然或人造纖維構成或 一皮革層由Ρϋ、PVC或PU與PVC合成皮構成，之内表面上設 置一層TPR黏著層其由丁苯嵌段共聚物與碳氫石油樹脂合成之熱 塑性橡膠薄膜，再利用射出成型工藝於該TPR黏著層上射出成型 該塑質薄殼件，以形成一密著結合之一體化複合式塑賀薄殼件。 【先前技術】 市面上各種電子產品’包含常見的電腦（C〇mputer )產品如筆 3己型電細（Notebook computer，簡稱 NB)、通訊（communication) 產品如手機或消費性（consumer)產品等3C產品但不限制，常應 用一薄殼件作為產品之外殼使用；該薄殼件隨產品的設計要求而 具有不同的結構，而若以一薄殼件之基體（base)所使用之材質而 言’可概分為塑質薄殼件及金屬薄殼件兩主要結構類別》 具有外在裝飾面之塑質薄殼件一般係利用嵌入模具式裝飾用 製程（in-mold decorating proceh，簡稱 IMD)'製成，其係將一形 成二度空間成型形狀且印刷肴_案之载體（substrate)如塑質膜， 以下簡稱IMD膜（IMD film)，嵌置於一成型模具内，再利用塑膠 2/19 201134681 射出成型技藝使熱熔樹脂射出成型在該IMD臈之背面以成型該殼 體之基體，以下簡稱樹脂基體（reSinbase)，使該樹脂基體與ιμ〇 膜結合構成一一體式塑質薄殼件，其中，該IMD膜（iMDftlm) 可以固定結合方式設在樹脂基體（resin base)的外表面上而形成 一永久性裝置物，供作為該塑質薄殼件之一外裝飾面或一保護面 或二者皆;I：; X該IMD财可㈣咖定对設在翻旨基體(resin base)的外表面上而形成一暫時性裝置物，完成後可將該imd膜 撕離，並使該IMD膜上之印刷圖案轉印或留存在樹脂基體的外表 面上供作為該塑質薄殼件之一外裝飾面。 < 針對上述之塑質薄殼件結構設計及其製造方法，目前存在很 多先前技術，包含： US3,654,〇62係揭示一具有一壓合式表面片（a laminated facing sheet)之模製飾板（a molded decorative plaque)的相關技術，其 係將熱熔塑膠射出成型在一已具有模具構造之壓合表面片的背面 上而形成。US6，117,384係揭示利用一具有多彩顏色之薄膜，再將 熱熔樹脂射出成型在該薄膜的背面而構成一永久結合之立體物件 之製程相關技術。US4,391，954係揭示一包含芳香族碳酸鹽聚合物 (aromatic carbonate polymer )與一由一環己烧;族 (cyclohexanedimethanol)取得之多元酯（polyester)之熱塑型模 製複合體（thermoplastic molding composition)之相關技術。 US4，125,572係揭示一包含芳香族碳酸鹽聚合物 (aromatic carbonate polymer )與一由一脂肪族（aliphatic )或環脂肪族 (cycloaliphatic diol)取得之多元酯（p〇iyester)之熱塑型模製複 合體（thermoplastic molding composition )之相關技術。US6,465,102 係揭示一包含一裝飾用表面區域及一個一體式形成之聚合基體 (polymeric base)之物品及其模製方法，且該聚合基體包含魂明 的王衣脂肪族多元S旨樹脂（cycloaliphatic polyester resin )，其中該環 月曰肪族多元醋樹脂係不受芳香族部分（apomaticmoiety)干擾之相 關技術（An article comprising a decorative surface area and an integral formed polymeric base comprising transparent cycloaliphatic 3/19 201134681 polyester resin, wherein the cycloaliphatic polyester resin is free from an aromatic moiety and the method of molding thereof) ° US6,117,384 係揭示一改良的嵌入模具式裝飾用製程（in_m〇ld de’c〇rating process，IMD)的相關技術。US6，136,441係揭示多層式塑質物品 (multilayer plastic articles)的相關技術。參考上述各種有關塑質 威體的結構设計或製造方法等先前技術之專利說明書内容，可知 該等先前技術大都是將一塑質殼體所包含之塑質膜（即IMD嗥） 及樹脂基體（resinbase)分別作出進一步之限定（limitati〇n)，·如 將塑質膜（IMD膜）或樹脂基體（resinbase)限定為某一特殊化 學族塑質材料，藉以製成一穩固結合不易剝離之一體式複合塑質 板材’、且可與其他專利（先前技術）之間有區別性。 然，當一由複合材構成之塑質薄殼件物品之塑質膜（即IMD 膜）及/或榭脂基體（resh base).被分別特殊化限定時，不但使所 ，用之材料受到關’也使塑賊乂即細㈤及/或樹脂基體 (resm base)之應用相對受到限制，不利於所製成之塑質薄殼 的應用，例如為多樣化需要而欲選用包含但不限制布面、面、 樹脂纖維面等材料來作為塑質膜時，則往往無法利用相同的技術 或設備並達成生產效率高、可量祕且品佳之功效，相 ^Stf用效率及應用範圍，因此可視為上 述5亥#塑質溥殼件的缺點。.. 又’ f常見的金屬驗件包含：以金顧板她合金薄板藉 it物’或進一步在該金屬薄殼件形狀物 之外表面上另作表面加工處理以呈現光澤或_ 衫 另再設置，層如樹脂薄“ 金屬薄殼件形狀物之外表面上另設.置—層具有在f 以保護金屬外表面並增進產品之外觀美感或觸;隨』σ的:内 部組件之組裝需要而·塑膠射出成型技藝或注塑 4/19 | \ 201134681 件如凸緣形狀物或肋板形狀物等，用以簡化該等組裝用塑質结合 件之結構及整體厚度，並增進結磁強度。 /針對上述之金屬薄殼件的結構設計及其製造方法，目前已存 在很多先前技術，包含：美國發明專利US5,695,699，US5,472,782 及美國發明專利公開案.US2009/0117401、US2008/0^747’9、 US2007/021S721等，玆以下列專利分別說明： 〈 中國發明專利申晴號+ 2L02805359.1 (國際申請pcT / JP2〇〇2/0〇7267，國際公布係揭示、一種鋁合条與 樹脂的複合體及其製造方法的相關技術，其特徵在於，包括:丨經 過接觸工序的鋁合金形狀物，所述的接觸工序是使鋁合金形肤物 與溶解選自氨、胼（聯胺）、甲基胺及乙二胺中的一種以上的化合 物的水溶液接觸，使上述水窖液吸附、殘留在其表面的工序，和 通過注塑成型一體地附著在前述鋁合金形狀物的樹脂，所述樹脂 選自聚對苯二曱酸亞烷基酯、以前述翠對笨二甲酸亞烷基酯為主 體的共聚物、和含有前述聚對，苯二.甲酸亞烷基酯成分之熱塑性組 合物中的一種以上。 . ' 中國發明專利申請载ZL200380102886.0 (國際申:請 PCT/JP2003/014213，國際公布WQ2004/041532)係揭示一種铭丨合 金與樹，的複合體及其製造方法的相_關技術，其特徵在於，考^ • 過選自氨、胼（聯胺）和水溶性胺化合物一種以上的水溶液一浸 潰的浸潰工序的鋁合金形狀物和—體地附著在所述鋁合金形狀物 的表面上’合有聚苯硫醚成分的熱塑性組合物構成。 中國發明專利申請號，？L200380104500.X (國際申請 PCT/JP2003/014214，國際公布 W〇2〇〇4/〇41533)係揭示一種鋁合 金與樹脂的複合體及其製造方法的相關技術，其特徵在於，由表 面粗糖度為5μιη〜50μχη且其表面具有ΐμηι以下的微細凹部或凸 部的鋁合金形狀物，與浸入所述叫部或凸部而固定，縱橫平均線 膨脹係數為2〜AxlO^CT1的以聚，對苯二甲酸丁二醇酯樹脂或聚笨 硫鱗為主要成分的熱塑性組合物構成。 中國發明專利申請號江200680046075.7 (國際申/請 .5/19 , 1 201134681 PCT/JP2006/324493，國際公布 WO2007/066742)係揭示一種金屬 樹脂複合體及其製造方法的相關技術，其特徵在於，由鋁合金構 件和熱塑性合成樹脂組合物構件形成，所述鋁合金構件是如下構 件：經過浸潰於選自氨、胼（聯胺）和水溶性胺化合物的一種以 上的水溶液的工序，用電子顯微鏡觀察，其表面被數均内徑為1〇 〜80nm的凹部覆蓋，所述熱塑性合成樹塒組合物構件是如下構 件：經注塑成型而固著於所述鋁合金構件的所述表面上，並且樹 脂成分組成中的主要成分為聚酉先胺樹脂、次要成分為耐沖 改良材料。 ，.，. 然’上述中國發明專利ZL02805359.卜ZL200380102886.0、 ZL200380104500.X及ZL200680046075.7皆係揭示金屬與樹脂之 複合體及其製造方法的相關技術，而其各別特徵皆在於，該金屬 (如鋁合金）形狀物係經過特殊選擇的水溶液（如水溶性胺化合 物一種以上的水溶液）中浸潰的浸潰工序，而再以具特殊選擇成 分的熱塑性樹脂並以注塑成型方式一體地附著在該鋁合金形狀物 的表面上而構成，換言之，該複合體中金屬（鋁合金）形狀物之 表面處理工序及樹脂形狀物之成分均被特殊化限定，且相對地較 為複雜，使複合體之製程及應用受到限制，不利於該金屬薄殻件 之使用效率及應用範圍，尤其使用特殊選擇之水溶液更不符 合目前之環保要求，因此.上述.金屬薄殼件物品及其製法至少 ，了列缺點：如須在注塑成型模具中配合各樹脂結合件而分別設 ，單一灌注口以進行高壓定點注塑該樹脂結合件，導致該金層薄 f1件在注塑成型過程中因受高壓而容易變形損壞，而且增加製作 4庄塑成型模具<困難度；又由於金屬薄殼件之金屬表面須先以 f殊水溶液進行浸潰工序，導致製程較為繁複，不利於該金屬薄 设件之量產化’尤其該特殊水溶液更有環保問題。 另如國内發明專利申請號85100575 (公告號404888)「具有 優異加工密接性之高鮮映性樹脂被覆金屬板」係揭示一種樹^被 覆金屬板的相關技術，其係以金屬板為基板 > 至少在該基板冬片 面上，由基板側依序層合有塗料層、聚丙烯共聚物1〇〇〜2〇重量 .6/19 201134681 份和聚丙烯100〜〇重量份構成之5〜100μιη厚之變性丙烯樹脂 層:花樣或/及全面印刷層、接著劑層、5〜100μιη厚之聚酯系^ ，薄膜者（見其財項第丨項）；或*基板撇序層合有塗二層: 花樣或/曰及全面印刷層、聚丙烯共聚物100〜20重量份和聚丙烯_ 〜0重量份構成之5〜ΐΟΟμπι厚之變性丙烯樹脂層、接著劑層f、5 〜ΙΟΟμπι厚之聚酯系樹脂薄膜者（見其請求項第2項）；或由基板 側依序有塗料層、聚丙烯共聚物1〇〇〜2〇重量份和聚丙婦^㈨ 〜〇重量份構成之5〜ΐ〇〇μιη厚之變性丙烯樹脂層、接著劑層、5 〜ΙΟΟμηι厚之透明聚酯系樹脂薄膜者（.見其請求項第3項）；曰或由 基板側依序層合有塗料層、5〜loopm厚之變性烯烴層、接著劑 層、5〜100μιη厚之透明聚酯系樹脂薄膜者（請求項第4項）。然， 本^結構中由基板側依序層合之樹脂被覆層的成分均已被特士化 限定，且主要目的係該樹脂被覆金屬板具有高鮮映性，相對使該 金屬板之外形受到關，不槪所製狀金屬薄殼件的應用。 再如國内發明專利申請號_6332 (公告號434145)「具備 較ί ί晰反射性及優良工作黏著性驗覆樹脂金屬片」係揭示- ，塗覆樹脂金屬片的相關技術，.其包括：作為底層片之金屬片， 其粗糖度的算術平均值偏差幅·度（Ra)數值介於0微米及10微米 樹脂層’其包括未硬化的混合型態樹脂層，聚醋樹 或聚烯烴樹脂；包括顏料之接著層；具有兩面 ® 之透明樹脂薄膜，其中至少一金屬片表面被著色 脂層’接著層和翻械蓋’各層做金屬#侧到遗明 = 序覆蓋。然，本案結構中由金屬片側依序層合之樹脂 均已被特殊化限定，且主要目的係該樹脂被覆金屬 性’相對該金屬板之外形受到限制，不利於所製成 之金屬薄殼件的應用。 .7/19 驻番發明專利申請號_19015.(部書號j28〇i9〇)「電子 二成型方法及其結構」·，其係針對前述的發明專部申 I哚（公告號434145 )及發明專利申請號85100575 (公 ，破4_8)加时進，其麵—種設置越層種合金絲的i 201134681 相關技術’ι其方法至少包括：一「塗佈接著劑」步驟，係於一由 紹^金所製成之金屬基板的至少〒側表面塗佈一層接著劑，耳該 接著劑具有金屬粉末；-「烘烤加熱」步驟，加熱該塗佈接著劑 之金屬基板，使該接著劑適當軟化；一「滾壓」步驟，藉由加熱 之滚輪越層滚壓層合於該接著劑上，其中該皮膜層係由至 ^-聚氣乙烯層、-接著層、—料層依序層疊結合而成，且接 著層具屬粉末；一「冷卻成型」步驟，使該皮膜層與金屬基 板得以密著結合。然，本案转構中由鋁合金金屬基板一側表面所 層合之皮膜層的成分係由至少一聚氣乙烯層、一接著層、一聚酯 Φ 層依序層疊結合而成，因此該皮膜層已被特殊化限定，相對傳該 金屬基板所呈現之外形受到限制，不利於所製成之金屬薄殼件的 應用。 ，. 再如國内新型專利申請綠093210282 (証書號Μ261368)[電 子裝置殼體金屬板結構」係前述發明專利申請號〇93119〇15 (娃書 號1280190)中結構之新型專利案。然，本案結構即存在如同其發 明專利申請號093119015之皮膜層已被特殊化限定的缺點。 再如國内新型專利申請號097208521 (証書號M345706)「複 合金屬板結構」係揭示一包栝二金屬基板、一複合樹脂膠層'聋覆 於該金屬基板並加熱軟化、及一金屬面板以一輥輪滾壓層合於該 • 複合樹脂膠層上而使該金屬面板與金屬基板密著結合。然，本案 結構之二外側面一為金屬面板一為金屬基板，故存在二外側面已 被特殊化限定的缺點。 ·· 再如國内新型專利申請號096215339 (証書號M328384)「環 保型貼皮金屬結構」係揭示貼愈金屬結構之相關技術，其耳少 包括：一金屬基板；一接著劑層係塗佈於前述金屬基板的至少一 ，表面並加熱使之適當軟化；及一皮膜層係由一聚氨酯底層及聚 氨酯面層依序層疊結合而成，以一滚輪滚壓層合於前述接著劑層 上然後冷卻，使該皮膜層與金屬基板密著結合。然，本案結構中 之皮膜層的成分係由由一聚氨酯底層及聚氨酯面層依序層疊轉合 而成，因此該皮膜層已被特殊化界定，使該金屬基板所呈現之外 8/19 201134681 形或=感相對受到限制，不利於所製成之金屬薄殼件的應用。 曰綜上述，各種複合板材之先前技術確實都·存在一些缺點及:問 題’而本發明係針對先前技術中有攔塑質薄殼件之US3,654,062、 US4,391,954 > US6,465}102 ^ US6,117,384 > US65136,441 ，術的缺點如其中裝飾用外覆膜（即塑質膜AMD膜）及/或塑質薄 喊件（即樹脂基體/resinbase)都另進一步限定以致相對限縮所使 用材料之選擇性及/或增加製程之不方便性，而加以解決。丨 【發明内容】 .' - ，本發明之目的係提供一種具有裝飾用外覆膜之塑質薄殼件及 其製法，其係提供一裝飾用外覆膜，其可為一布料層由天然纖維 如植物纖維之棉、麻或動物纖維之毛、蠶絲構成或由人造纖維如 尼龍、聚脂纖維、壓克力纖蜂或滬餘構成；或為一合成皮革層如 由PU、PVC或PU與PVC备成皮構成;再於該外覆膜之内表面 士設置一層TPR黏著層，該TI屯麩薯層係由丁苯嵌段共聚物與碳 氫石油樹脂合成之熱塑性橡膠薄膜，、厚度约4〇〇_5〇〇μιη，其設置 方式不限制如藉滾輪熱壓方式貼合，且該設有TPR黏著層之外覆 膜具有適當延展性；再將該已設有TPR黏著層之外覆膜平整罔定 在一塑質薄殼件之射出成型稹具之模穴内，且可在模六之周錶外 邊藉由數個彈性壓力柱作為定位點用來拉撐該外覆膜以使其在. 公、母模閉合時能在模穴中保持拉平狀態不致内縮，又固定後之 外覆膜之周緣界線超出模穴之周緣界線；再利用塑料射出成型工 藝’於該TPR黏著層上射出成型該塑質薄殼件，其中該模穴之周 緣界線超出該塑質薄殼件之周緣界線並形成一環周緣且較薄之溢 料區’該溢料區即當作該塑質薄殼件之預設毛邊區；再由模具中 ，出完成品，再裁切毛邊區而完成一具有裝飾用外覆膜之塑質薄 殼件；其中該射出成型之塑質薄殼件可藉由射出成型時射出料之 壓力及溫度以與該丁PR黏著層熔接結合成一體，並同時迫使該 TPR黏著層之部分厚度如10%約4〇·5〇哗得滲透至該外覆膜之表 面上既有之數個細凹部中，故可增進所形成一體化複合式結構體 9/19 201134681 之結構強度，又該預設之溢料區可形成毛邊區供整齊切除，故可 增進完成品之周緣邊的品質.，並5避免.先前技術如IMD (in-mold decorating process)製程之缺點如其所用之外覆膜如布料層易因其 射出成型之高溫或高壓而發生.溶化或滲出或破損之不良品質，蜂 本發明可達成製程簡化及提昇完成品品質之目的。 為使審查委員能進一步瞭解本發明之詳細結構及作用功效， 玆配合圖示說明於後。 【實施方式】 ,201134681 Die 31 periphery boundary 32 Overfill area 33 Plastic thin shell 40 Injection material 40 Wang margin boundary 41 Flange 42 Five cases with chemical formula right 'Please reveal the chemical formula that best shows the characteristics of the invention: (None) VI. Invention Description: TECHNICAL FIELD The present invention relates to a plastic thin shell member having a decorative outer covering and a method thereof, and more particularly to an outer covering film such as a cloth layer composed of natural or man-made fibers Or a leather layer consisting of ruthenium, PVC or PU and PVC synthetic skin, with a TPR adhesive layer on the inner surface thereof, a thermoplastic rubber film synthesized from styrene-butadiene block copolymer and hydrocarbon petroleum resin, and then using an injection molding process. The plastic thin shell member is injection molded on the TPR adhesive layer to form a tightly bonded integrated composite plastic shell member. [Prior Art] Various electronic products on the market 'contains common computer (C〇mputer) products such as notebook computer (Notebook computer, NB), communication products such as mobile phones or consumer products. The 3C product is not limited, and a thin shell member is often used as the outer casing of the product; the thin shell member has a different structure depending on the design requirements of the product, and if the material used for the base of a thin shell member is Words can be divided into two main types of plastic thin shells and thin metal shells. Plastic shells with external decorative surfaces are generally in-mold decorating proceh (IMD). 'made", which will form a two-dimensional space forming shape and print a recipe, such as a plastic film, hereinafter referred to as IMD film (IMD film), embedded in a molding die, and then reuse Plastic 2/19 201134681 Injection molding technology enables hot melt resin to be injection molded on the back side of the IMD crucible to form the base of the casing, hereinafter referred to as a resin matrix (reSinbase), to bond the resin matrix with the ιμ〇 film. Forming an integrated plastic thin shell member, wherein the IMD film (iMDftlm) can be fixedly combined on the outer surface of the resin base to form a permanent device for use as the plastic thin shell member. An exterior decorative surface or a protective surface or both; I: X The IMD can be used to form a temporary device on the outer surface of the resin base. The imd film is peeled off and the printed pattern on the IMD film is transferred or left on the outer surface of the resin substrate to provide an outer decorative surface for the plastic thin shell member. < In view of the above-described plastic thin shell structure design and manufacturing method thereof, there are many prior art, including: US 3,654, 〇62 series reveals a molding with a laminated facing sheet A related art of a molded decorative plaque is formed by injection molding a hot melt plastic onto a back surface of a laminated surface sheet having a mold structure. US 6,117,384 discloses a process related technique for forming a permanently bonded three-dimensional article by using a film having a colorful color and then injection molding a hot melt resin on the back side of the film. US 4,391,954 discloses a thermoplastic molding composition comprising an aromatic carbonate polymer and a polyester obtained from cyclohexanedimethanol. Related technology. US 4,125,572 discloses a thermoplastic molding comprising an aromatic carbonate polymer and a polyester (p〇iyester) obtained from an aliphatic or cycloaliphatic diol. A related art of a thermoplastic molding composition. US 6,465,102 discloses an article comprising a decorative surface region and an integrally formed polymeric base and a molding method thereof, and the polymeric matrix comprises a soft-shelled Wang Yi aliphatic multi-component resin (cycloaliphatic) An example of a decorative surface area and an infra-red polymer (apomaticmoiety). , the cycloaliphatic polyester resin is free from an aromatic moiety and the method of molding thereof) ° US 6,117,384 discloses a related technique for in-m〇ld de'c〇rating process (IMD) . US 6,136,441 discloses related art of multilayer plastic articles. Referring to the above-mentioned various patent specifications relating to the structural design or manufacturing method of the plastic body, it is known that the prior art mostly uses a plastic film (ie, IMD) and a resin matrix contained in a plastic shell. (resinbase) respectively to further limit (limitati〇n), such as the plastic film (IMD film) or resin matrix (resinbase) is defined as a special chemical family of plastic materials, thereby making a stable bond is not easy to peel off One-piece composite plastic sheet', and can be distinguished from other patents (prior art). However, when a plastic film (i.e., IMD film) and/or a resin base (resh base) of a plastic thin-shell article composed of a composite material is separately defined, not only the materials used but also the materials used are subjected to Off' also makes the use of plastic thieves, ie fine (five) and/or resin bases, relatively limited, which is not conducive to the application of the finished plastic shell, for example, for the needs of diversification, but not limited When a material such as a cloth surface, a surface, or a resin fiber surface is used as a plastic film, it is often impossible to use the same technology or equipment and achieve high production efficiency, high volume and good quality, and the efficiency and application range of the phase. It can be regarded as the shortcoming of the above-mentioned 5 hai #plastic oyster shell. .. and 'f common metal specimens include: use the alloy sheet of the metal sheet to borrow the object' or further surface treatment on the outer surface of the shape of the metal shell to give a gloss or _ shirt Set, the layer is thin like a resin. The metal thin-shell shape is additionally provided on the surface. The layer has a layer to protect the metal outer surface and enhance the aesthetic appearance or touch of the product; with σ: assembly of internal components · Plastic injection molding technology or injection molding 4/19 | \ 201134681 pieces such as flange shape or rib shape, etc., to simplify the structure and overall thickness of the assembly of plastic components for assembly, and improve the magnetic strength. / </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; 747'9, US2007/021S721, etc., are respectively described in the following patents: < Chinese invention patent Shen Qing + 2L02805359.1 (International application pcT / JP2〇〇2/0〇7267, international publication reveals, an aluminum strip With resin A related art of a composite body and a method for producing the same, comprising: an aluminum alloy shape subjected to a contact step, wherein the contacting step is to dissolve the aluminum alloy skin type and the selected one selected from the group consisting of ammonia and hydrazine (hydrazine) a step of contacting an aqueous solution of one or more of methylamine and ethylenediamine, adsorbing and remaining the surface of the aqueous mash, and a resin integrally attached to the aluminum alloy shaped article by injection molding, The resin is selected from the group consisting of polyalkylene terephthalate, a copolymer mainly composed of the aforementioned alkylene sulfonate, and a thermoplastic composition containing the above-mentioned poly(p-phenylene terephthalate) component. More than one of the . . . Chinese invention patent application ZL200380102886.0 (International application: please PCT/JP2003/014213, international publication WQ2004/041532) reveals a phase of the alloy and the tree, and its manufacturing method An off-axis technique characterized in that an aluminum alloy shape of an impregnation process in which one or more aqueous solutions selected from the group consisting of ammonia, hydrazine (hydrazine) and a water-soluble amine compound are impregnated and adhered thereto The surface of the alloy shape is composed of a thermoplastic composition containing a polyphenylene sulfide component. Chinese Invention Patent Application No. L200380104500.X (International Application PCT/JP2003/014214, International Publication W〇2〇〇4/〇41533 A related art of a composite of an aluminum alloy and a resin, and a method for producing the same, characterized in that it has an aluminum alloy shape having a surface roughness of 5 μm to 50 μm and a fine concave portion or a convex portion having a surface of ΐμηι or less. It is composed of a thermoplastic composition containing a polybutylene terephthalate resin or a polystyrene scale as a main component, which is fixed by being immersed in the called portion or the convex portion and having a longitudinal and transverse average linear expansion coefficient of 2 to AxlO^CT1. Chinese Patent Application No. 200680046075.7 (International Application No. 5/19, 1 201134681 PCT/JP2006/324493, International Publication No. WO2007/066742) discloses a related art of a metal resin composite and a method of manufacturing the same, characterized in that It is formed of an aluminum alloy member and a thermoplastic synthetic resin composition member which is a step of immersing in one or more aqueous solutions selected from the group consisting of ammonia, hydrazine (hydrazine) and a water-soluble amine compound, and using electrons Observed by a microscope, the surface thereof is covered by a concave portion having a number average inner diameter of 1 〇 80 80 nm, and the thermoplastic synthetic sapphire composition member is a member which is fixed by injection molding to the surface of the aluminum alloy member, Further, the main component of the resin component composition is a polydecalamine resin, and the secondary component is a impact-resistant material. ,. The above-mentioned Chinese invention patents ZL02805359. ZL200380102886.0, ZL200380104500.X and ZL200680046075.7 are related technologies for revealing a composite of metal and resin and a manufacturing method thereof, and each of its characteristics is that The metal (e.g., aluminum alloy) shape is a dipping process in which a specially selected aqueous solution (e.g., one or more aqueous solutions of a water-soluble amine compound) is impregnated, and then a thermoplastic resin having a specially selected composition is integrally attached by injection molding. It is configured on the surface of the aluminum alloy shaped article, in other words, the surface treatment process of the metal (aluminum alloy) shape object and the components of the resin shape object in the composite body are specifically limited, and relatively complex, so that the composite body The process and application are limited, which is not conducive to the use efficiency and application range of the metal thin-shell member. In particular, the use of the specially selected aqueous solution does not meet the current environmental protection requirements. Therefore, the above-mentioned metal thin-shell articles and their preparation methods are at least Disadvantages of the column: if it is necessary to match the resin bonding parts in the injection molding die, the single infusion port is The high-pressure fixed-point injection molding of the resin joint member causes the thin layer of the gold layer to be easily deformed and damaged due to high pressure during the injection molding process, and increases the difficulty of making the 4 mold plastic molds; and the metal of the thin metal shell member. The surface must first be dipped with a special aqueous solution, resulting in a complicated process, which is not conducive to the mass production of the thin metal parts. In particular, the special aqueous solution is more environmentally friendly. In addition, the domestic invention patent application No. 85100575 (Announcement No. 404888) "high-precision resin-coated metal sheet having excellent processing adhesion" discloses a related art of a tree-coated metal sheet, which is based on a metal plate. At least on the substrate side of the substrate, a coating layer, a polypropylene copolymer 1 〇〇 2 〇 . . 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 Thick denatured acryl resin layer: pattern or / and full printed layer, adhesive layer, 5 ~ 100μιη thick polyester system, film (see its financial item )); or * substrate order laminated with coating Two layers: pattern or /曰 and full-print layer, polypropylene copolymer 100~20 parts by weight and polypropylene _~0 parts by weight composed of 5~ΐΟΟμπι thick denatured acryl resin layer, adhesive layer f, 5 ~ ΙΟΟμπι thick The polyester resin film (see item 2 of the request); or the coating layer on the substrate side, the polypropylene copolymer 1〇〇~2〇 part by weight, and the polyacrylonitrile (9)~〇 part by weight 5~ΐ〇〇μιη thick denatured acrylic resin layer, followed by Layer, 5 ~ ΙΟΟμηι thick transparent polyester resin film (see item 3 of the request); 曰 or layered with a coating layer, 5~loopm thick denatured olefin layer, adhesive layer , 5~100μιη thick transparent polyester resin film (item 4 of the request). However, in the present structure, the components of the resin coating layer which are sequentially laminated from the substrate side have been defined by the taxi, and the main purpose is that the resin-coated metal sheet has high vividness, and the outer shape of the metal sheet is relatively opposed. Close, not the application of thin metal parts. Another example is the domestic invention patent application number _6332 (Announcement No. 434145) "Resistance of the resin sheet with better transparency and good work adhesion", revealing the related technology of coating resin metal sheets, including : As the metal piece of the back sheet, the arithmetic mean deviation of the gross sugar content is in the range of 0 μm and 10 μm resin layer. It includes an uncured mixed type resin layer, a polyester tree or a polyolefin. Resin; an adhesive layer comprising a pigment; a transparent resin film having a double-sided®, wherein at least one of the surface of the metal sheet is covered with a layer of the colored grease layer 'adhesive layer and the flap'. However, the resin laminated in this structure from the side of the metal sheet has been specifically defined, and the main purpose is that the resin coating metality is limited relative to the shape of the metal sheet, which is disadvantageous to the metal thin shell member produced. Applications. .7/19 Invented Invention Patent Application No. _19015. (Part No. j28〇i9〇) "Electronic Two-Forming Method and Structure"·, which is directed to the aforementioned invention-specific application (Issue No. 434145) and invention Patent application No. 85100575 (public, broken 4_8) plus time, its surface - a kind of layered alloy wire i 201134681 Related technology 'ι method includes at least: a "coating agent" step, tied to a ^ at least the side surface of the metal substrate made of gold is coated with a layer of an adhesive, the adhesive has a metal powder; - a "bake heating" step, heating the metal substrate coated with the adhesive to make the adhesive suitable Softening; a "rolling" step of laminating and laminating the adhesive by means of a heated roller, wherein the film layer is sequentially laminated to the poly-ethylene layer, the --layer layer, and the layer The combination is formed, and the adhesive layer is a powder; a "cooling molding" step allows the coating layer to be intimately bonded to the metal substrate. However, in the case of the present invention, the composition of the film layer laminated on the surface of one side of the aluminum alloy metal substrate is formed by laminating at least one gas-gas layer, one adhesive layer and one polyester Φ layer in sequence, so that the film is formed. The layer has been specifically defined, and the shape of the metal substrate is relatively limited, which is disadvantageous for the application of the fabricated metal shell member. Another example is the domestic new patent application Green 093210282 (Certificate No. 261368) [Electrical device housing metal plate structure" is a new type of patent structure in the aforementioned invention patent application No. 93119〇15 (Wa No. 1280190). However, the structure of the present invention has the disadvantage that the film layer of the invention patent application No. 093119015 has been specifically defined. For example, the domestic composite patent application No. 097208521 (Certificate No. M345706) "Composite metal plate structure" discloses a package of a two-metal substrate, a composite resin layer "overlying the metal substrate and heating and softening, and a metal panel to A roller is rolled and laminated on the composite resin layer to bond the metal panel to the metal substrate. However, the outer side of the second structure of the present invention is a metal panel and a metal substrate, so that there are disadvantages that the two outer sides have been specifically defined. · · The new domestic patent application number 096215339 (Certificate No. M328384) "Environmental-type skinned metal structure" reveals the related technology of the metal structure, the ear includes: a metal substrate; an adhesive layer coating And at least one surface of the metal substrate is heated and softened appropriately; and a film layer is formed by laminating a polyurethane underlayer and a polyurethane surface layer in a sequential manner, and is rolled and laminated on the adhesive layer by a roller. The film layer is cooled and adhered to the metal substrate. However, the composition of the film layer in the structure of the present invention is formed by sequentially laminating a polyurethane underlayer and a polyurethane surface layer, so that the film layer has been specifically defined to make the metal substrate appear outside 8/19 201134681 The shape or sense is relatively limited, which is not conducive to the application of the fabricated metal shell member. In view of the above, the prior art of various composite sheets does have some disadvantages and problems: the present invention is directed to US 3,654,062, US 4,391,954 > US 6,465} 102 having a plastic shell member in the prior art. ^ US6,117,384 > US65136,441, the disadvantages of the technique such as the decorative outer covering film (ie, the plastic film AMD film) and/or the plastic thinning member (ie, the resin matrix/resinbase) are further defined so as to be relatively limited. It is solved by reducing the selectivity of the materials used and/or increasing the inconvenience of the process.丨 [Summary of the Invention] - The object of the present invention is to provide a plastic thin shell member having a decorative outer cover film and a method for producing the same, which provide a decorative outer cover film which can be a cloth layer from a natural Fiber such as cotton of plant fiber, wool of animal or animal fiber, silk composition or composed of rayon such as nylon, polyester fiber, acrylic fiber bee or Shanghai; or a synthetic leather layer such as PU, PVC or PU Formed with PVC; and a TPR adhesive layer is formed on the inner surface of the outer film. The TI sweet potato layer is a thermoplastic rubber film synthesized from a styrene-butadiene block copolymer and a hydrocarbon petroleum resin, and a thickness. About 4〇〇_5〇〇μιη, the setting manner is not limited to the bonding method by the hot pressing method of the roller, and the film provided with the TPR adhesive layer has appropriate ductility; and the TPR adhesive layer is already provided. The outer film is flattened in a cavity of the injection molding cooker of a plastic thin shell member, and can be used to pull the outer cover film by using a plurality of elastic pressure columns as positioning points outside the circumference of the die 6 It can keep the flat state in the cavity when the male and female molds are closed. After shrinking and fixing, the peripheral boundary of the outer film exceeds the peripheral boundary of the cavity; and the plastic thin-film case is formed by injection molding on the TPR adhesive layer, wherein the peripheral boundary of the cavity is beyond The peripheral edge of the plastic thin shell member forms a circumferential edge and a thin flashing area 'the flashing area is regarded as the preset burr area of the plastic thin shell member; and then the finished product is finished by the mold, and then Forming a burr area to complete a plastic thin shell member having a decorative outer cover; wherein the injection molded plastic thin shell member can be welded to the butyl PR adhesive layer by the pressure and temperature of the shot material during injection molding The integration is integrated, and at the same time, a part of the thickness of the TPR adhesive layer is forced to penetrate into the plurality of fine recesses on the surface of the outer cover film, so that the integrated formation can be enhanced. The structural strength of the composite structure 9/19 201134681, and the preset flash area can form a burr area for neat cutting, so that the quality of the peripheral edge of the finished product can be improved. 5 and avoid. Prior art such as IMD (in -mold decorating process) The outside film layer with a cloth easily emitted because of high temperature or pressure molding occurs. Melting or bleeding or damage of poor quality, the present invention can be achieved bee simplify the process and improve the quality of the product is completed object. In order to enable the reviewing committee to further understand the detailed structure and function of the present invention, it will be described with reference to the drawings. [Embodiment]
^參考圖1及圖2·4,其分別係本發明具有裝飾用外覆膜之塑質 薄殼件之製法流程圖及結構之立體及剖面示意圖。本發明具有裝 飾用外覆膜之塑質薄殼件1的結構依序包含：一裝飾用外覆膜 10、一 TPR黏著層20及一塑質薄殼件40等主要部分，玆藉由說 明製$之各步驟關時說财結構沐發明之製法包含町步驟： 提供-裝飾用外覆膜1〇;本發明之裝飾用外覆膜⑴係通指一 般，產品之核φ上所設置之.㈣做麟，該產品尤其是電子 產品包含：電腦（computer)產品如筆記型電腦⑽編冰 C=P^r)、，(C〇m_kati〇n)產品如手機或消費性（__〇 ‘ 品f不限制，在此以一筆記型電腦之塑質薄殼件(外 f體）如圖2、3、4所示為例說明；該外覆膜1〇可為下列各 種或其組合：—布料層|其可·由天然纖維如植物纖維之棉、 麻或動物纖維之毛、蠶絲#構成，或由龍’、纖 ^曰，I>〇lyurethane)、PVC (氯乙稀樹脂）或阳與^ 皮Referring to Fig. 1 and Fig. 2 and 4, respectively, it is a perspective view and a schematic cross-sectional view showing a process flow chart and a structure of a plastic thin shell member having a decorative outer cover according to the present invention. The structure of the plastic thin shell member 1 having the decorative outer covering of the present invention comprises: a decorative outer covering film 10, a TPR adhesive layer 20 and a plastic thin shell member 40, etc., by way of illustration. Each step of the system is said to be closed. The method of manufacturing the invention includes the step of providing the outer cover film for decoration. The outer cover film for decoration of the present invention (1) is generally referred to as the core φ of the product. (4) Do Lin, the product, especially the electronic products include: computer products such as notebook computers (10) iced C=P^r), (C〇m_kati〇n) products such as mobile phones or consumer (__〇 ' Product f is not limited, here is a plastic thin shell of a notebook computer (outer f body) as shown in Figure 2, 3, 4 as an example; the outer cover 1 〇 can be the following various or a combination :—cloth layer|may be composed of natural fiber such as cotton of plant fiber, wool of animal or animal fiber, silk #, or by dragon', fiber, I> 〇lyurethane, PVC (vinyl chloride resin) Or yang and ^ skin
之内、外表面1:1 .、12之表層面基本上S 夕ί製作過程如織製作射所自·生的；該外覆膜10 他的加工處理而具有透明保護膜^、以保 ifd f 光澤及觸感；作業時，該外覆膜10 製成/、有相專寬度之一長條形外覆膜1〇並呈捲筒狀，供可藉由 10/19 201134681 輸送裝置導引而拉送至工作機 進行後續作業； 之作檯面上再裁成一單位片，供 再於該外覆膜ίο之内表面丨丨μThe surface of the inner and outer surfaces is 1:1. The surface of the 12th surface is basically S 夕 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作f Gloss and touch; during operation, the outer film 10 is made of /, one of the strip widths of the outer strip 1 〇 and is in the form of a roll for guiding by 10/19 201134681 conveying device And pulling to the working machine for subsequent operations; the surface of the table is further cut into a unit piece for reapplying the inner surface of the outer film ίμ
之表面，設置一層TPR點甚展Λ '土:，即欲射出成型塑質薄殼件 黏著層係由丁苯喪段共致物與石灰約气00-500㈣，該丁PR 膜；設置方式不限制，如换用^5;石油樹脂合成之熱塑性橡磾薄 貼合在外覆膜1〇 =™黏著層2〇 I 膜10具有適當程度之延展性:置TPR黏者層2〇後之外覆On the surface, a layer of TPR is set to Λ '土:, that is, to form a plastic thin shell, the adhesive layer is composed of styrene-butadiene and the lime is about 00-500 (four), the D-PR film; the setting method is not Restriction, such as replacement of ^5; thermoplastic resin synthetic thermoplastic rubber thinly bonded to the outer cover 1〇=TM adhesive layer 2〇I film 10 has an appropriate degree of ductility: after the TPR adhesive layer 2
疴狀，供可藉由輸送裝丨 w 郝考層20並呈捲 薄殼件二dn::膜1()平整固定在-塑質 巧灌注口位置、㈣料流料的 > 有。^ r定·内後，其 ，模八31之周緣界線32 ;又，其中該模穴S1之周 机 薄fi4G之成型用周緣界線(或稱周緣端面)41，'且又 ^-環周緣且較薄之溢料區33，也就是該溢料區 殼件40之周緣界線41之交界處形成—落差如圖6辭與=，質在專 模穴31之周緣外邊可設置數支彈性壓力柱S4供作為定位點用 如圖7所示，該等彈性壓力柱34之數目不限如圖7中只顯示一 邊設有三支彈性壓力柱34;而藉該數支彈性壓力柱34 點夾住 ，用以彈性拉撐該外覆膜1〇之外緣部分，以使設在模穴Μ中之 該外覆膜10當公、母模30a、30b閉合時仍能保持拉平狀能而不 致内縮或產生皺褶；.. . 再利用塑料射出成型工藝，於該外覆膜10之内表面n之該 TPR黏著層20上射出成型該塑質薄殼件40 ;其中該塑質薄殼^Braided, can be transported by the packaging w Hao Hao layer 20 and rolled thin shell parts two dn:: film 1 () flat fixed in the - plastic mouth filling position, (four) material flow > After r, the inner boundary line 32 of the die eight 31; and the peripheral edge line (or the peripheral end face) 41 of the peripheral machine fi4G of the cavity S1 is formed, and the circumference of the ring is The thinner flash zone 33, that is, the boundary of the peripheral boundary line 41 of the flash zone shell member 40, is formed as follows - the drop is shown in Fig. 6 and =, and a plurality of elastic pressure columns can be disposed outside the periphery of the die hole 31. As shown in FIG. 7 , the number of the elastic pressure columns 34 is not limited as shown in FIG. 7 , and only three elastic pressure columns 34 are disposed on one side; and the plurality of elastic pressure columns 34 are clamped by the points. The outer cover portion of the outer cover 1 is elastically stretched so that the outer cover 10 disposed in the cavity can maintain the flatness without being retracted when the male and female molds 30a, 30b are closed. Or generating wrinkles; . . . using a plastic injection molding process, forming the plastic thin shell member 40 on the TPR adhesive layer 20 of the inner surface n of the outer cover film 10; wherein the plastic thin shell ^
4〇藉由射出成型時射出料40a的射出壓力及溫度，即可與該TpR 11/19 ' 201134681 黏著層20熱熔結合成一體，並同時迫使該 厚，10%，約40-50卿，得渗透至該外之部分 形成-费耆結合之-體化複合式▲構-於模^膜ίο結合 線32係超出該塑質薄殼件4〇 八1之周緣界 裝電子構件如電路板等，可於射成 1 3上直碑安 表面43上同時射出成型所需之結合件4°4H#件於該内 殼件二與結，卿出成型而形成體觸薄 ί==出ΐϊ#具3<r中取出該塑質薄殼件40; 月一具有㈣用外覆膜之塑質薄殼件丨如圖2_4所示/成本發 本發明之上述製法，由於該TpR黏菩 程中渗透至該外覆臈10之内表面u在射過 ^薄殼件4g _地麵密¥結料 薄殼之該外覆膜1G與塑質=0 、σ σ肖b保持相g良好之密者性，在鄉會辨 j- ntXM- ^=上〇具有足夠的抗剝離性，故本發明之上述製L確Ϊ可ΐ 進所形成一體化複合式結構體之結構強度。 ’ 且較Id明ΐ別*該模穴31辑緣界線32之外緣設計一環周緣 由Ϊ溢料區33，當射出成型時，射出㈣ 中^/央部位進入模穴31，即灌注口設在該模穴31之 央雜’再住四周之騎界線32輻概流動崎較快速地流至 12/19 k - 201134681 區33，即^^ 平效果，且一直延伸至溢i ，奶在鱗歡凸緣42 塑質薄 ϊί )或^與雨合成皮構成，且均可_塑料射出ii 工藝ΐΐΐ—具良好品f <歸#殼件1，達成製賴化之目ί 述製程中’當利用塑料射出成型工藝以於該外覆膜10之内 之TPR黏著層20上射出成型該塑質薄殼件4〇時，該塑 f设件40之射出料40a可選擇不同的塑料，如：(苯乙稀樹 月旨）、PC (聚碳酸酯 ’ p〇1yCarbpnate resin)i Acrylic resin (壓 克力樹脂/丙烯酸樹脂）、Nylon (尼、龍/聚醯胺樹脂）等；又該等射 出料40a在射出成型時之壓力及溫度分別為：之射出壓"力1 8〇kg/mm2，射出溫度2〇〇°C ; PC之射出壓力120kg/刪2，射出溫 ，260 C’Acrylic resin 之射出壓力 l〇〇kg/mm2，射出溫度 240 C ;及Nylon (尼龍/聚醯胺樹脂:）.之射出壓力gokg/麵2，射出溫 度 260°〇 / ^ 玆藉以下各實施例，以進一_說明本發明之結構及其所紙填 成之作用功效： <實施例1> :: 本實施例塑質薄殼件1中外覆膦40係一以人造纖維，如尼 龍、聚脂纖維、壓克力纖維或混紡材料構成之布料層，厚度約 為0.55mm; TPR黏著層係由丁苯嵌段共聚物與碳氫石油樹脂舍成， 13/19 ^ 201134681 ί=== rte resin)為射出料40a，而利用塑 面ϋ約為2麵，長、寬為262麵*178随；又在i内ΐ i^ 黏型之數_ f結合件44其高度為9.54, by the injection pressure and temperature of the injection material 40a during injection molding, the TpR 11/19 '201134681 adhesive layer 20 can be thermally integrated into one body, and at the same time force the thickness, 10%, about 40-50 qing, The part that has been infiltrated into the outer part is formed - the combination of the structure and the structure of the composite structure of the thin film 32 is beyond the peripheral edge of the plastic thin shell member. Etc., it can be shot on the surface of the straight surface of the straight surface of the on-line 43 to simultaneously project the joints required for the forming of the joint 4 ° 4H # pieces in the inner shell member and the knot, the formation of the body to form a thin touch ί = = out #具3<r, the plastic thin-shell member 40 is taken out; a plastic thin-shell member having a (4) outer covering film as shown in Fig. 2_4/cost according to the above-mentioned manufacturing method of the present invention, due to the TpR The outer surface of the outer cover 10 that penetrates into the outer cover 10 is in a good condition, and the outer cover 1G of the thin shell member 4g_the ground cover is kept in a good phase with the plasticity=0, σ σ The denseness of the character, the j-ntXM-^= upper jaw has sufficient peeling resistance in the township, so the above-mentioned system of the present invention can improve the structural strength of the integrated composite structure formed. ' And the Id clearly distinguishes * The outer edge of the edge of the hole 31 of the cavity 31 is designed to be surrounded by the overflow area 33. When the injection is formed, the injection (4) is entered into the cavity 31, that is, the perfusion port is set. In the cavity 31 of the cavity 31, the surrounding boundary of the riding line 32 is more rapid and flows to the 12/19 k - 201134681 area 33, that is, the ^^ flat effect, and extends to the overflow i, milk in the scale Huan Flange 42 plastic thin ϊ ί ) or ^ with rain synthetic leather, and can be _ plastic injection ii process ΐΐΐ - good product f < return to the shell 1, to achieve the goal of the system ί in the process of ' When the plastic thin-shell member 4 is injection-molded on the TPR adhesive layer 20 in the outer film 10 by using a plastic injection molding process, the injection material 40a of the plastic component 40 can be selected from different plastics, such as : (phenylethyl sulphate), PC (polycarbonate 'p〇1yCarbpnate resin) i Acrylic resin (acrylic resin / acrylic resin), Nylon (Nylon, dragon / polyamide resin), etc.; The pressure and temperature of the injection material 40a during injection molding are: the injection pressure "force 1 8〇kg/mm2, the injection temperature 2〇〇°C; the injection pressure of PC 120kg/deletion 2, injection temperature, injection pressure of 260 C'Acrylic resin l〇〇kg/mm2, injection temperature 240 C; and Nylon (nylon/polyamide resin:) injection pressure gokg/face 2, injection temperature 260°〇/ ^ By the following examples, the structure of the present invention and the effect of the paper filling thereof are further explained: <Example 1>: The phosphine of the plastic thin shell member 1 of the present embodiment is coated with phosphine 40 series of fabric layers made of rayon, such as nylon, polyester fiber, acrylic fiber or blended material, thickness of about 0.55mm; TPR adhesive layer is composed of styrene-butadiene block copolymer and hydrocarbon resin , 13/19 ^ 201134681 ί=== rte resin) is the injection material 40a, and the plastic surface is about 2 faces, the length and width are 262 faces *178; and in i, the number of the adhesive is _ The f-joint member 44 has a height of 9.5
實施例之外覆臈10與塑質薄殼件40之間的剝 2度為每平方公分8公斤，.環境測試密著性為由-40t至 ^以及虹至-贼每分鐘升溫或降溫代且經心欠循環巧外 覆膜10與塑質薄殼件40不剝離。 〈實施例2>In the embodiment, the peeling degree between the covering 10 and the plastic thin shell member 40 is 8 kg per square centimeter, and the environmental test adhesion is from -40t to ^ and the rainbow to the thief is heated or lowered every minute. Moreover, the outer membrane 10 and the plastic thin shell member 40 are not peeled off. <Example 2>
本實施例之塑質薄殼件1中，外覆膜.1.0係一以PU (聚氨酯， ol^urethane)合成皮構成之皮革層，厚度約為〇 55麵，·該TpR 黏者層20係由丁本喪段共聚物與碳氫石油樹脂合成孰 膠薄膜顧，錢約_捕哗，以雜漏^齡在^橡 10之内表面11上，·該塑質薄殼件40係以PC歸⑽ycarb〇nate resin，聚碳酸酯）為射出料4如?而利用塑料射 出 成型在外鶴H)之誠面MTPR歸層2G上:^度約 mm，長、寬為262mm*l78mm ;又該内表面11上設有同時一:體 成型之數個塑質結合件44其高度‘ 9.5 mm ;結果發現，本實‘例 =外覆膜10與塑質薄殼件40之間的剝離強度密著性為每平方公 ^ 8公斤，環境測試密著性為由-40°C至85Ϊ以及85Ϊ至-4(TC每 分鐘升溫或降溫1且經4次循環，.該外覆膜與塑質薄殼件不剝 離。 <實施例3> ‘ . 本實施例之塑質薄殼件1中，外覆膜10係一以人造纖維，1如 尼龍、聚脂纖維、壓克力纖維或混紡材料，構成之布料層，厚i度 約為0.55mm ;該TPR黏著層20係由丁苯嵌哚共聚物與碳氫石油 ••.,14/19 ^ ； 201134681 執』^目上ill性橡膠薄膜構成’厚*約4〇〇_5〇〇卿，以滾輪 ABS.:姑乂卜、覆臈10之内表面11上；該塑質薄殼件40係以 成型在月曰）為射出料術，而利用塑料射出成型工藝射出 成3^外覆臈10之内表面仏之覆黏著層2()上，厚度約為,2 寬為262 mm木178mm;又該内表面η上設有同時一體 個歸結合件44其高度為9 5 _ ;結果發現，本實政例 八8八☆ 1 ^與塑^薄殼件4 G之’ _強度密著性為每平方'公 又越二斤：衣境測試密著性為由攸至85。。以及85。。至_4〇。〇每 ς鐘升溫或降溫rC且經4次循環，.該外覆膜與塑f薄殼件不剝 <實施例4> 本實施例之塑質薄殼件\中，外覆膜1〇係一以pu(聚氨醋， 合ΐ皮構執皮革層，厚度約為G.55mm，·該* 膠薄龜/、段共聚倾碳A石油獅合成之熱可塑性橡 3出=該塑質薄殼件4〇係以趣（苯乙稀樹脂）:為 ^yGa’而利用塑料射出成型卫藝射出成型在外覆膜1〇之'内 ^ 11之TPR黏著層20上，厚度約馬2賴，長、寬為262 該内表面11上释有同時一體成型之數個塑質結合 壤度為.5咖；結果發現，本實施例之外覆膜1G與塑質 $牛40之間。的剝離強度密著性為每平方公分8公斤，環境測& 且=為由舰至85°C以及85°c至_4(rc每分鐘升溫或降溫rc =4次循環，該外覆膜與塑質薄殼件不剝離。以上所示僅為本 優選實施例，對本發，言僅是說明性的，而非限制性的。 域具通常智識者理解，在本發明專利要求所限定的精神和 =内可對其進行許多改變，修改，甚至等效變更， 入 本發明的保護範圍内。 备 【圖式簡單說明】 圖 圖1係本發明具有裝制外肢件法 15/19 必 201134681 圖^係本發明具有裝飾用外膜層之塑質薄殼件一實施例之前^^立 體不意圖。 圖3係圖2之背視立體示意圖。 =4係本發明具有裝飾用外膜層之塑質薄殼件之斷面示意圖。. 圖5係本發明之射出成型模具之斷面示意圖。. , 之射出成型模具之斷面局部放大示意圖，其中塑質 面=。射出料通過射出成型固設在外膜層上之TPR黏著層之表 之射㈣麵職台上三_性壓力㈣為定位點 【主要元件符號說明】 外覆膜10 外表面12 周緣界線15 射出成型模具30 模穴31 溢料區33 塑質薄殼件40 周緣界線41 内表面43 内表® 11 細凹部13 TPR黏著層20 公'、母模具30a、3‘0b 周緣界線32 彈性壓力柱34 射出料40a 凸緣42 結合件44 16/19In the plastic thin shell member 1 of the present embodiment, the outer covering film .1.0 is a leather layer composed of PU (polyurethane, ol^urethane) synthetic skin, and has a thickness of about 55 faces, and the TpR adhesive layer 20 is a system. Synthetic silicone film from Dingben's segmented copolymer and hydrocarbon petroleum resin, money about _ 哗, to the surface of the inner surface 11 of the rubber 10, the plastic thin shell 40 is PC (10) ycarb〇nate resin, polycarbonate) is used for injection material 4 such as? and plastic injection molding in the outer crane H) Chengping MTPR layer 2G: ^ degrees about mm, length, width is 262mm * l78mm; The surface 11 is provided with a plurality of plastic bonding members 44 which are simultaneously formed at a height of '9.5 mm; as a result, it is found that the actual example is a peeling strength between the outer film 10 and the plastic thin shell member 40. The performance is 8 kg per square metre, and the environmental test adhesion is from -40 ° C to 85 Ϊ and 85 Ϊ to -4 (TC is heated or cooled by 1 per minute and after 4 cycles, the outer film and plastic thin The shell member is not peeled off. <Example 3> In the plastic thin shell member 1 of the present embodiment, the outer covering film 10 is made of rayon, such as nylon, polyester fiber, acrylic fiber or blended material. The cloth layer is composed of a thickness of about 0.55 mm; the TPR adhesive layer 20 is composed of a styrene-butadiene-based copolymer and a hydrocarbon oil, and is 14/19^; 201134681. The composition is 'thickness* about 4〇〇_5〇〇卿, with the roller ABS.: aunt 乂, covering the inner surface 11 of the 臈 10; the plastic thin shell 40 is formed in the moon 曰) as the injection material And using a plastic injection molding process to form an adhesive layer 2 () on the inner surface of the outer cover 10, the thickness is about 2, the width is 262 mm wood 178 mm; and the inner surface η is provided at the same time The combined component 44 has a height of 9 5 _; as a result, it is found that the actual example 8 8 8 ☆ 1 ^ and the plastic ^ thin shell member 4 G ' _ strength adhesion for each square 'gong and two pounds: clothing The environmental test adhesion is based on 85. . And 85. . To _4〇.升温 heating or cooling rC every four minutes and four cycles, the outer film and the plastic thin shell are not peeled off. [Example 4] The plastic thin shell member of the embodiment, the outer film 1〇 The system is made of pu (polyammonium vinegar, combined with the leather layer, the thickness is about G.55mm, the * rubber thin turtle /, the segmental copolymerization carbon A petroleum lion synthetic thermoplastic oak 3 out = the plastic The thin shell member 4 is made of styrene (styrene resin): it is made of plastic injection molding and is molded on the TPR adhesive layer 20 of the inner film of the outer film. The length and width are 262. The inner surface 11 is provided with a plurality of plastics which are integrally formed at the same time, and the soil density is .5 coffee; as a result, it is found that the outer film 1G and the plastic material are between the cow and the cow 40. Peel strength is 8 kg per square centimeter, environmental measurement & and = is from ship to 85 ° C and 85 ° c to _ 4 (rc per minute heating or cooling rc = 4 cycles, the outer film and The plastic thin-shell member is not peeled off. The above is only the preferred embodiment, and the present invention is merely illustrative and not limiting. The domain is generally understood by the intellectual, and is defined in the patent claim of the present invention. And many changes, modifications, and even equivalent changes can be made within the scope of protection of the present invention. [Simplified description of the drawings] Figure 1 is a method for mounting external limbs of the present invention 15/19 must 201134681 Figure 2 is a schematic perspective view of a plastic thin shell member having a decorative outer film layer of the present invention. Fig. 3 is a perspective view of the back side of Fig. 2. Fig. 4 is a decorative outer film layer of the present invention. Fig. 5 is a schematic cross-sectional view of the injection molding die of the present invention. A partial enlarged view of the section of the injection molding die, wherein the plastic surface = the injection material is formed by injection molding. The surface of the TPR adhesive layer on the outer film layer (4) is on the table. The three-dimensional pressure (four) is the positioning point. [Main component symbol description] The outer film 10 outer surface 12 peripheral boundary line 15 injection molding die 30 cavity 31 overflow Area 33 Plastic thin shell 40 Perimeter boundary 41 Inner surface 43 Inner surface® 11 Fine recess 13 TPR Adhesive layer 20 Male', Female mold 30a, 3'0b Perimeter boundary 32 Elastic pressure column 34 Injection material 40a Flange 42 Bonding Article 44 16/19